Method for estimating full charge capacity after deterioration of a battery, and method for creating an estimation formula for full charge capacity after deterioration

Abstract

To provide a method for creating a formula for estimating a full-charge capacity of a battery that is mounted to an electric vehicle, after degradation.SOLUTION: The method includes the following steps: a first step of determining a degradation contribution relationship that represents a relationship between each of N variables related to the battery state and a reduction amount of a full-charge capacity, by an experiment, etc; a second step of collecting variable experiment data from L electric vehicles, and finding L simple estimate values of the full-charge capacity after degradation using the degradation contribution relationship; a third step of calculating a coefficient of correlation between the L pieces of performance data of each variable and the L simple estimate values, and selecting M variables whose correlation coefficient exceeds a prescribed threshold; a fourth step of establishing a numerical expression using the selected variable as an explanatory variable and the high-accuracy estimate value of the full-charge capacity as an objective variable; and a fifth step of assigning K pieces of performance data to the variables of the numerical expression, assigning K simple estimate values to the left side of the numerical expression so as to determine the coefficient. The obtained numerical expression is an estimation expression.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The technology disclosed in this specification relates to a method for estimating the full charge capacity of a battery mounted on an electric vehicle after deterioration, and a method for creating an estimation formula for the full charge capacity after deterioration. [Background technology]

[0002] The full charge capacity of a battery that has been used for a long period of time decreases due to deterioration from the full charge capacity at the start of use (initial value of the full charge capacity). Even if the battery is left unused for a long period of time, the full charge capacity will be lower than the initial value. In this specification, the full charge capacity of a battery after a predetermined period of time is referred to as the "full charge capacity after deterioration." An example of a technique for estimating the full charge capacity after deterioration is disclosed in Patent Document 1. The method of Patent Document 1 estimates the full charge capacity after deterioration using the charge and discharge history of the battery. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2020-042036 A Summary of the Invention [Problem to be solved by the invention]

[0004] The present specification provides a technique for estimating the full charge capacity of a battery after deterioration with higher accuracy than conventional techniques. [Means for solving the problem]

[0005] There are many variables that affect battery degradation. Typical examples of variables include the time the battery is left unused and the amount of current flowing through the battery. The extent to which each variable contributes to degradation cannot be determined from the battery's history information alone. The technology disclosed in this specification selects variables that contribute significantly to battery degradation from among the many variables related to the battery state. The selected variables are then used to estimate the full charge capacity after degradation.

[0006] One technique disclosed in this specification provides a method for creating an estimation formula for full charge capacity after deterioration, which includes the following seven steps.

[0007] First step: By experiment or simulation, obtain each of N variables related to the battery state and the degradation contribution relationship that indicates how much the full charge capacity decreases from the initial value depending on the variables. The decrease in the full charge capacity from the initial value is referred to as the capacity decrease amount below. Second step: Collect actual data on variables from L electric vehicles, and use the degradation contribution relationship to obtain a simplified estimate of the full charge capacity after degradation for each of the L electric vehicles. More specifically, the actual value of each variable is substituted into the degradation contribution relationship to obtain the amount of capacity degradation for each variable. A simplified estimate of the full charge capacity after degradation is obtained by subtracting the N amounts of capacity degradation from the initial value of the full charge capacity.

[0008] Third step: Calculate the correlation coefficient between the L actual data for each variable and the L simplified estimated values, and select M variables whose correlation coefficient exceeds a predetermined threshold. Fourth step: Establish a highly accurate estimate of the current full charge capacity using the selected variables (Equation 1). Equation 1 corresponds to a multiple regression equation with the highly accurate estimate as the objective variable and the M variables as explanatory variables.

[0009]

number

[0010] Fifth step: Substitute each of the K pieces of performance data (each piece of performance data includes performance values ​​of the M variables) among the L pieces of performance data into the variables of Formula 1, and substitute the K pieces of simplified estimated values ​​corresponding to the K pieces of performance data into the left side of Formula 1. Coefficient on the right hand side (i) and constants are determined. 6th step: Determine Coefficient (i) The (LK) high-precision estimates obtained by substituting (LK) actual data into the right-hand side of Equation 1, which contains a constant, are calculated so that the correlation between the (LK) high-precision estimates and the (LK) simplified estimates corresponding to the (LK) high-precision estimates is strong. Coefficient (i) Step 7: Correct the Coefficient (i)The following equation (1) is used to estimate the full charge capacity after degradation.

[0011] The above method has the following features. In the first step, the degradation contribution relationship of each variable is found through experiments or simulations. The first step clarifies the extent to which each variable contributes to battery degradation (amount of capacity loss). In the second and third steps, variables that contribute greatly to degradation are selected using simplified estimates and actual data. It is possible to extract only the variables that contribute greatly to degradation from among a large number of variables. From the third step onwards, an estimation equation for the full charge capacity after degradation is obtained through multiple regression analysis.

[0012] The method of estimating the full charge capacity after the battery has deteriorated using the above-mentioned formula 1 is also one of the techniques disclosed in this specification.

[0013] In the fifth step, the coefficients may be determined by reinforcement learning, an example of which is a genetic algorithm.

[0014] Details and further improvements of the technology disclosed in this specification are described in the following "Forms for Carrying Out the Invention". [Brief description of the drawings]

[0015] [Figure 1] 13 is a flowchart of a procedure for creating an estimation equation. [Diagram 2] This is a flowchart of the procedure for creating an estimation equation (continuation of Figure 1). [Diagram 3] 1 is a graph showing an example of a deterioration contribution relationship. [Figure 4] 1 is a graph showing an example of the correlation between variables and simplified estimated values. [Diagram 5] FIG. 13 is a diagram illustrating correction of coefficients of a multiple regression equation. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0016] Batteries mounted on electric vehicles deteriorate under the influence of various variables related to the state of the electric vehicle and the battery. Examples of variables include the time when the battery is not charged or discharged (left-standing time), the time when the battery is charged (or discharged) (power-on time), the amount of power (power-on amount) input to and output from the battery, the driving time of the electric vehicle, the driving distance, and the like. Each of these variables contributes to the deterioration of the battery. It is possible to obtain the values ​​of these variables (i.e., performance data) from an electric vehicle that is actually running. However, unless it is known to what extent each variable contributes to the deterioration of the battery, it is not possible to accurately estimate the degree of deterioration of the battery from the performance data. As mentioned above, the full charge capacity of a battery after a predetermined period of time is adopted as an index of deterioration. That is, in this specification, the full charge capacity after the predetermined period of time is referred to as the "full charge capacity after deterioration". For example, it is understood that a battery with an initial full charge capacity of 300 [kAh] and a current full charge capacity of 250 [kAh] has a full charge capacity reduced by 50 [kAh] due to deterioration.

[0017] The method of the embodiment (the estimation formula for the full charge capacity of a battery) will be described with reference to the drawings. Figures 1 and 2 show a flowchart showing the procedure for creating the estimation formula. The method for creating the estimation formula consists of seven steps.

[0018] (First step) Using experiments or simulations, we investigate the extent to which each of multiple variables related to the battery state affects battery degradation. As mentioned above, battery degradation is expressed as the amount of decrease in full charge capacity from the initial value. The amount of decrease in full charge capacity from the initial value may be referred to as the amount of capacity decrease below. The relationship between each variable and the amount of capacity decrease is referred to as the degradation contribution relationship.

[0019] An example of the degradation contribution relationship is shown in FIG. 3. FIG. 3(A) is a graph showing the relationship between the time left unattended and the amount of capacity loss. In other words, the degradation contribution relationship is a relational equation that determines the amount of capacity loss for the actual data of the variables. FIG. 3(B) is a graph showing the relationship between the amount of current flow and the amount of capacity loss. The longer the time left unattended, the greater the amount of capacity loss. The greater the amount of current flow, the greater the amount of capacity loss. These degradation contribution relationships are obtained by experiment or simulation, by changing only the target variable while holding other variables constant. The square root of the time left unattended or the square root of the amount of current flow may be used as a variable. The time left unattended or the amount of current flow for each specified temperature range may be used as a variable.

[0020] Here, the number of variables to be considered is N. A deterioration contribution relationship is obtained for each of the N variables (step S1). N deterioration contribution relationships are obtained.

[0021] (Second step) Steps S2-1 and S2-2 in Figure 1 correspond to the second step. First, performance data of variables is collected from L electric vehicles that are already in use (step S2-1). Performance data of N variables means the actual values ​​of each variable in each electric vehicle. Each electric vehicle is equipped with a communication device. Each electric vehicle periodically sends the performance data of N variables to the management center. A computer at the management center collects the performance data of the variables of the L electric vehicles.

[0022] Next, the computer at the management center uses the degradation contribution relationship to calculate a simplified estimate of the full charge capacity after degradation of each battery of the L electric vehicles (step S2-2). The computer assigns the performance data of each variable to the degradation contribution relationship for each electric vehicle battery to find the capacity reduction amount corresponding to the performance data of each variable. That is, N capacity reduction amounts are obtained for each electric vehicle battery. The computer obtains the simplified estimate by subtracting the N capacity reduction amounts from the initial value of the battery's full charge capacity. The simplified estimate corresponds to the estimate of the full charge capacity after degradation calculated using the degradation contribution relationship and the performance data of the variables. The estimate at this time is called a "simplified estimate" because a highly accurate estimate is obtained later.

[0023] The computer obtains a simplified estimate for each of the L electric vehicle batteries. In other words, the computer obtains L simplified estimates. Each simplified estimate is obtained from a respective piece of actual data. Each of the L simplified estimates corresponds to each of the L pieces of actual data.

[0024] (Third step) Steps S3-1 and S3-2 in FIG. 1 correspond to the third step. The computer calculates the correlation coefficient between the variables and the simplified estimated values ​​(step S3-1). Each of the L pieces of actual data includes actual values ​​of the N variables. In other words, there are L pieces of actual data for each of the N variables. In yet another way, the computer has L sets of data for each variable, which are composed of simplified estimated values ​​and actual values ​​of the variables. The computer plots the L sets of data on a two-dimensional plane with the simplified estimated values ​​on the vertical axis (or horizontal axis) and the actual values ​​of the variables on the horizontal axis (or vertical axis). The computer finds the correlation coefficient between the simplified estimated values ​​and the actual values ​​of the variables from the plot of the L sets of data.

[0025] An example of the correlation between variables and simple estimates is shown in Figure 4. Figure 4(A) shows the relationship between the simple estimates and the time left unattended. Figure 4(A) shows that there is a strong correlation between the simple estimates and the time on the device. Figure 4(B) shows the relationship between the simple estimates and the distance traveled. The plots of the simple estimates and the distance traveled are scattered across the entire graph, and it can be seen that there is no correlation between the two.

[0026] The correlation coefficient is expressed as a number between -1.0 and 1.0. The closer the correlation coefficient is to 1.0 (or -1.0), the stronger the correlation. A correlation coefficient of zero means that there is no correlation at all. Generally, when the correlation coefficient is smaller than -0.4 or larger than 0.4, it is determined that there is a significant correlation between two variables (in this case, the simplified estimate and the variable). When the correlation coefficient is positive (negative), a positive correlation (negative correlation) is recognized between the two variables. How to calculate the correlation coefficient is well known, so we will not explain it here.

[0027] Next, the computer selects variables having correlation coefficients exceeding a threshold (step S3-2). For example, the computer selects variables having correlation coefficients smaller than -0.4 and variables having correlation coefficients larger than 0.4. That is, the computer selects variables having correlation coefficients whose absolute values ​​exceed the threshold (0.4).

[0028] For convenience of explanation, the number of selected variables is set to M. In other words, of the N variables, (NM) variables do not have a significant effect on the deterioration of the full charge capacity. Therefore, the computer will thereafter exclude the (NM) variables from the estimation equation for the battery full charge capacity. The computer creates an equation for estimating the full charge capacity after deterioration using the selected M variables.

[0029] (Fourth step) Step S4 in FIG. 2 corresponds to the fourth step. The computer uses M variables to formulate a multiple regression equation for estimating the full charge capacity. The multiple regression equation was previously shown as Equation 1. The left side of Equation 1 corresponds to the estimated value (highly accurate estimated value) of the full charge capacity after degradation. The right side of the multiple regression equation includes each variable (variable (i)), a coefficient (coefficient (i)) by which each variable is multiplied, and a constant. The initial full charge capacity on the left side of Equation 1 is the design value of the battery and is known.

[0030] The highly accurate estimate on the left side of Equation 1 corresponds to the objective variable in the multiple regression equation, and the variable (i) on the left side of Equation 1 corresponds to the "explanatory variable" in the multiple regression equation. At this point, each coefficient and constant on the right side is unknown.

[0031] (Fifth step) Step S5 in FIG. 2 corresponds to the fifth step. The computer selects K pieces of performance data from among the L pieces of performance data. The computer determines the coefficients of the multiple regression equation using the K pieces of performance data and the simplified estimated values ​​corresponding to each piece of performance data (step S5). There are no rules for selecting the K pieces of performance data from among the L pieces of performance data. The computer can arbitrarily select K pieces of performance data from among the L pieces of performance data. A simplified estimated value is associated with each of the K pieces of performance data. The computer substitutes the simplified estimated value into the left side of Equation 1, and substitutes performance data (the actual value of each variable) into each variable on the right side. K formulas with M coefficients and one constant as unknowns are obtained. The computer determines the M coefficients and one constant using the K formulas.

[0032] A number larger than "M+1" is selected for "K". Because a multiple regression equation contains (M+1) unknowns, more than (M+1) simultaneous equations are required to determine these unknowns. Methods for determining the coefficients of a multiple regression equation (i.e., multiple regression analysis) are well known, so an explanation will be omitted. When "K" is sufficiently larger than "M+1" (specifically, 10 times or more), a method for determining the coefficients using reinforcement learning is preferable. As a specific example of reinforcement learning, it is preferable to use a genetic algorithm to determine the coefficients.

[0033] (Sixth step) Steps S6-1 and S6-2 in FIG. 2 correspond to the sixth step. The (LK) pieces of actual data are not used to determine the coefficients of the multiple regression equation (Equation 1). The computer corrects the coefficients using the (LK) pieces of actual data and the corresponding simplified estimated values. The computer substitutes the variable values ​​of the (L-K) pieces of actual data into Equation 1 to obtain (LK) pieces of high-precision estimated values. In this case, the coefficients and constants determined in the fifth step are used in Equation 1. The computer plots the obtained high-precision estimated values ​​and sets of simple estimated values ​​corresponding to each high-precision estimated value on a two-dimensional plane. Since both the simple estimated value and the high-precision estimated value are estimated values ​​of the full charge capacity after deterioration obtained from the actual data, they have a linear correspondence relationship with a slope of 45 degrees. In other words, the simple estimated value and the high-precision estimated value are correlated. FIG. 5(A) shows a diagram in which sets of simple estimated values ​​and high-precision estimated values ​​are plotted. The dashed line SL is the simple regression line of the plot of the (LK) set, and the range indicated by the symbol CV indicates the strength of the correlation. The narrower the range indicated by the symbol CV, the stronger the correlation.

[0034] The computer corrects the coefficients of Equation 1 (multiple regression equation) so that the plot of the (LK) set approaches the dashed line SL. For example, the computer finds the average error and maximum error of the plot of the (LK) set. The computer randomly shifts the coefficients of Equation 1, and determines the coefficients when the average error and maximum error are minimized as the corrected coefficients.

[0035] (Seventh step) Equation 1 obtained from steps S1 to S6-2 is obtained as an estimation equation for the full charge capacity after the battery has deteriorated (step S7).

[0036] By acquiring actual data of the variables of another electric vehicle and substituting the data into Equation 1, an estimate of the full charge capacity after deterioration of the battery of the other electric vehicle (current full charge capacity) can be obtained.

[0037] The above method has the following features and advantages. In the first step, the degradation contribution relationship of each variable is found through experiments or simulations. The first step clarifies the extent to which each variable contributes to battery degradation (amount of capacity loss). In the second and third steps, variables that contribute greatly to the amount of capacity loss are selected using simplified estimates and actual data. By extracting only the variables that contribute greatly to the amount of capacity loss from among many variables, the number of terms in the multiple regression equation (Equation 1) is reduced. In other words, the amount of calculation required to determine the coefficients of the multiple regression equation can be reduced. From the third step onwards, an estimation equation for the full charge capacity after degradation is obtained through multiple regression analysis.

[0038] The following points should be noted regarding the technology described in the embodiment. The number L of performance data is greater than the number N of variables. Furthermore, the number K of performance data used to determine the coefficients included in Equation 1 is greater than the number M of selected variables. More preferably, the number K of performance data is greater than 10 times the number M of selected variables.

[0039] The variables may include the battery state for each predetermined temperature range. For example, the variables may include a leaving time in a temperature range of 10 to 15 degrees (first leaving time), a leaving time in a temperature range of 15 to 20 degrees (second leaving time), and a leaving time in a temperature range of 20 to 25 degrees (third leaving time).

[0040] The performance data may include performance data on the battery state for each predetermined temperature range. In this case, the states of adjacent temperature ranges may be combined into one variable. The computer may combine the adjacent temperature ranges into one variable so that the correlation between the high-precision estimated value and the simplified estimated value obtained by the multiple regression equation is reduced.

[0041] The computer applies the performance values ​​of the variables included in the performance data to the deterioration contribution relationship to obtain the capacity degradation amount for the performance values. The computer obtains an estimate (simplified estimate) of the full charge capacity after deterioration by subtracting the capacity degradation amount corresponding to each of the performance values ​​of the N variables from the initial full charge capacity.

[0042] The variables may include the state of the battery as well as the state of the electric vehicle (mileage, driving time, etc.) Variables related to the battery state may be variables other than those exemplified in the embodiment.

[0043] The method of creating an estimation equation disclosed in this specification may be performed by a computer or a human.

[0044] Although specific examples of the present invention have been described above in detail, these are merely examples and do not limit the scope of the claims. The technology described in the claims includes various modifications and variations of the specific examples exemplified above. The technical elements described in this specification or drawings exhibit technical utility alone or in various combinations, and are not limited to the combinations described in the claims at the time of filing. In addition, the technology exemplified in this specification or drawings can achieve multiple objectives simultaneously, and achieving one of these objectives is itself technically useful.

Claims

1. A method for creating an estimation formula for a full charge capacity of a battery mounted on an electric vehicle after deterioration, A first step of determining, by experiment or simulation, a degradation contribution relationship representing a relationship between each of N variables related to the state of the battery and an amount of decrease in the full charge capacity from an initial value; a second step of collecting performance data of the variables from the L electric vehicles and calculating a simplified estimate of a full charge capacity after degradation of each of the L electric vehicles using the degradation contribution relationship; a third step of calculating a correlation coefficient between the L pieces of actual data for each variable and the L pieces of the simplified estimated values, and selecting M pieces (M<N) of the variables whose correlation coefficients exceed a predetermined threshold value; A fourth step of formulating the following Equation 1 to obtain a highly accurate estimation value of the full charge capacity after degradation with the selected variables; a fifth step of substituting K pieces of actual data among the L pieces of actual data into the variables of the formula 1, substituting the K pieces of simplified estimated values ​​into the left side of the formula 1, and determining a coefficient (i) and a constant on the right side of the formula 1; a sixth step of correcting the coefficient (i) so that a correlation between the (L−K) high-precision estimated values ​​obtained by substituting the (L−K) pieces of actual data into the right side of the formula 1 including the determined coefficient (i) and the constant and the corresponding simplified estimated values ​​becomes strong; A seventh step of obtaining the equation 1 using the corrected coefficient (i) as the estimated equation; The method for creating an estimation equation for a full charge capacity of a battery after deterioration, comprising: [0025]

2. A method for estimating a full charge capacity of the battery after deterioration, using the estimation formula according to claim 1 .

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