Herbicidal Composition

Abstract

The present invention provides compositions comprising herbicidally active compounds (A) and (B), wherein (A) represents one or more compounds of general formula (I) or their pesticidal salts [component (A)], and (I) and (B) represent one or more herbicides [component (B)]. The present application further relates to the use and methods of the herbicidal compositions of the present invention for controlling or regulating the growth of weeds. TIFF2022511488000332.tif41154

Description

[Technical field]

[0001] The present invention resides in the technical field of crop protection products which can be used to combat undesirable plant growth in non-arable lands, in seed preparations or in plant crops and which comprise as herbicidally active compounds a combination of at least two herbicides, wherein the composition comprises herbicidally active compounds (A) and (B), where (A) represents one or more compounds of general formula (I) or their pesticidal compatible salts [herbicide (A) or component (A)], and (B) represents one or more herbicides (component B). [Background technology]

[0002] Compounds from the structural class of 3-phenylisoxazoline-5-carboxamide are known as herbicides (see, for example, WO2012 / 130798A). These compounds are effective against a wide range of harmful plants when applied by pre-emergence or post-emergence methods, with the possibility of non-selective use in controlling undesirable plant growth or selective use in plant crops. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] WO2012 / 130798 A Summary of the Invention [Problem to be solved by the invention]

[0004] The efficacy of these herbicides against harmful plants is at a high level, but generally depends on the application rate, the form of the respective preparation, the range of harmful plants, the harmful plants to be controlled in each case, the climate, and the soil conditions, etc. A further criterion is the duration of action or the rate of decomposition of the herbicide. Also, where appropriate, the change in the susceptibility of harmful plants, which may occur with long-term use of the herbicide or with a geographically restricted method, should be taken into account. Compensation for the loss of action in the case of individual plants by increasing the application rate of the herbicide is only possible to a certain extent, for example, because such a procedure often worsens the selectivity of the herbicide or even higher application rates do not improve the action. In general, there is a need for a method to achieve herbicidal action at lower application rates of active compound. Lower application rates not only reduce the amount of active compound required for application, but also generally reduce the amount of formulation auxiliary required. Both reduce the economic expenditure and improve the environmental compatibility of herbicide treatment.

[0005] One way to improve the application profile of herbicides can be to combine active compounds with one or more other active compounds that contribute desired additional properties.However, in the combined application of multiple active compounds, there are often physical and biological incompatibility phenomena, such as lack of stability in the co-formulation, decomposition of active compounds and / or antagonism of active compounds.However, what is desired is a combination of active compounds with favorable activity profile, high stability, and unexpected synergistically enhanced activity, which ideally allows the application rate to be reduced compared with the individual application of the combined active compounds.

[0006] It is an object of the present invention to provide an alternative or advantageous herbicidal composition which has a good biological use profile and which possesses as many of the desirable and favourable properties mentioned above as possible. [Means for solving the problem]

[0007] Surprisingly, it has been found that this object can be achieved by using a composition comprising herbicidally active compounds (A) and (B), where (A) represents one or more compounds of general formula (I) or their agrochemically compatible salts [component (A)] and (B) represents one or more herbicides [component (B)] selected from the group of herbicidally active compounds (B1) to (B11). The compositions of the invention interact in a particularly favorable manner when used to control undesired plant growth in crop plants such as, for example, wheat (hard and soft), corn, soybean, sugar beet, sugarcane, cotton, rice, beans (e.g., green beans and fava beans), flax, barley, oats, rye, triticale, potato and millet / sorghum, non-crop land, pasture / turf areas and plantation crops.

[0008] The present invention therefore provides a composition comprising herbicidally active compounds (A) and (B), where (A) is a compound of general formula (I):

[0009] [ka] [In the formula, R 1 and R 2 each represents hydrogen; R 3 represents (C1-C3)-alkyl, (C3-C4)-cycloalkyl, (C2-C3)-alkenyl, (C2-C3)-alkynyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine, chlorine, cyano and (C1-C2)-alkoxy; Z represents a Z-1, Z-2, Z-8, Z-9, Z-11 or Z13 group, where Z-1, Z-2, Z-8, Z-9, Z-11 and Z13 have the following meanings: [ka] where in each case the arrow indicates the bond to the group C=O of formula (I); R 11 , R12 are each independently hydrogen, cyano, OR 7 , S(O) n R 5 , SO2NR 6 R 7 , CO2R 8 ,CONR 6 R 8 , C.O.R. 6 , N.R. 6 R 8 , N.R. 6 COR 8 , N.R. 6 SO2R 8 represents or or (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C3)-alkyl, (C2-C6)-alkenyl, (C5-C6)-cycloalkenyl or (C2-C6)-alkynyl, each of which is halogen, cyano, OR 7 , S(O) n R 5 , CO2R 8 , N.R. 6 SO2R 8 and optionally substituted with m radicals selected from the group consisting of: or R 11 and R 12 together with the nitrogen atom to which they are attached form a saturated, partially or completely unsaturated 5-, 6- or 7-membered ring, which may be selected from the group consisting of halogen, cyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, oxo, OR 7 , S(O) n R 5 , SO2NR 6 R 7 , CO2R 8 ,CONR 6 R 8 and, in addition to the nitrogen atom, r carbon atoms, n oxygen atoms, p sulfur atoms, and NR 7 and N.C.O.R. 7 containing p elements from the group consisting of: X 2 , X4 and X 6 represent, independently of each other, hydrogen or fluorine; X 3 and X 5 represent, independently of one another, hydrogen, fluorine, chlorine or cyano, or represents (C1-C3)-alkyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; R 5 represents (C1-C6)-alkyl, (C3-C6)-cycloalkyl or aryl, each of which is substituted by m radicals from the group consisting of halogen and cyano; R 6 is hydrogen or R 5 represents; R 7 represents hydrogen, or or represents (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C4)-alkenyl or (C3-C4)-alkynyl, each of which is substituted by m radicals from the group consisting of halogen, cyano and (C1-C2)-alkoxy; R 8 represents hydrogen, or or represents (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C6)-alkenyl or (C3-C6)-alkynyl, each of which is substituted by m radicals from the group consisting of halogen, cyano and (C1-C2)-alkoxy; m is an index of 0, 1, 2 or 3; n is an index of 0, 1 or 2; p is an index of 0 or 1; and r is an index of 3, 4, 5, or 6. or a salt thereof having pesticide suitability [ingredient (A)], and (B) represents one or more herbicides [component (B)] from the group of herbicidally active compounds (B1) to (B11),

[0010] (B1) represents a herbicidally active compound from the group of 1,3-diketo compounds selected from [Table 1] TIFF0007657715000004.tif85143

[0011] (B2) represents a herbicidally active compound from the group of the (sulfon)amides selected from [Table 2] TIFF0007657715000006.tif237157TIFF0007657715000007.tif238156TIFF00076577150 00008.tif240152TIFF0007657715000009.tif238152TIFF0007657715000010.tif238153

[0012] (B3) represents a herbicidally active compound from the group of the arylnitriles selected from [Table 3]

[0013] (B4) represents a herbicidally active compound from the group of the azoles selected from [Table 4] TIFF0007657715000013.tif230151TIFF0007657715000014.tif239152TIFF0007657715000015.tif30153

[0014] (B5) represents a herbicidally active compound further selected from the following: [Table 5] TIFF0007657715000017.tif240156TIFF0007657715000018.tif239151TIFF0007657715000019.tif95151

[0015] (B6) represents a herbicidally active compound from the group of the (het)aryl carboxylic acids selected from [Table 6] TIFF0007657715000021.tif137150

[0016] (B7) represents a herbicidally active compound from the group of organophosphorus compounds selected from [Table 7]

[0017] (B8) represents a herbicidally active compound from the group of the phenyl ethers selected from [Table 8] TIFF0007657715000024.tif231149TIFF0007657715000025.tif230149TIFF0007657715000026.tif37149

[0018] (B9) represents a herbicidally active compound from the group of the pyrimidines selected from [Table 9] TIFF0007657715000028.tif120154

[0019] (B10) represents a herbicidally active compound from the group of the (thio)ureas selected from [Table 10] TIFF0007657715000030.tif214129

[0020] (B11) represents a herbicidally active compound from the group of the triazines selected from: [Table 11] TIFF0007657715000032.tif222117

[0021] The common names of the herbicides listed above are supplemented by the "CAS RN" (Chemical Abstracts Service Registry Number) (abbreviated "CAS") in brackets. The CAS RN is a widely used reference number that allows an unambiguous assignment of the substance in question, since it distinguishes, inter alia, isomers, including stereoisomers, from salts and esters. For active compounds that exist in various forms, the name of the neutral compound is in each case given in the above list. The CAS given between brackets covers these and all further known forms of the active compound. Unless a specific form of the active compound is relevant in the following table examples for a specific situation, e.g. biological efficacy, only the neutral compound is described below, thus encompassing all existing forms as listed.

[0022] The compositions according to the invention may contain further components, such as other active compounds for combating harmful organisms, such as harmful plants, plant-damaging animals or plant-damaging fungi, in particular herbicides, fungicides, insecticides, acaricides, nematicides and miticides, as well as related substances, or other types of active compounds for crop protection (e.g. resistance inductors), plant growth regulators, and / or active compounds from the group of additives and / or formulation auxiliaries customary in crop protection.The components may be formulated here together (ready-to-use formulation) and used as such, or they may be formulated separately and used together, for example in tank mixes or successive applications.

[0023] The individual herbicidally active compounds of general formula (I) present as component (A) are also referred to below as compound (A), active compound (A), component (A) or herbicide (A). Similarly, the individual herbicidally active compounds present as component (B) are also referred to below as compound (B), active compound (B), component (B) or herbicide (B).

[0024] An advantageous property of the combination of herbicides (A) and (B) according to the invention is that the active compounds (A) and (B) are compatible with each other, which means that they can be used together without the occurrence of significant chemical incompatibility between the active compounds (A) and / or (B) that would result in the destruction of one or more active compounds. This avoids any reduction in the active compound content in the formulation or spray solution. The favorable compatibility also extends to the biological properties of the active compounds when used in combination. For example, antagonistic effects are generally not observed in the case of the control of harmful plants with the active compound combination according to the invention. The active compounds (A) and (B) are therefore particularly suitable for use together or in addition to further active compounds for crop protection or pesticides. The enabled combined application allows the exploitation of advantageous effects, for example the broadening of the range of harmful plants to be controlled during application, or a reduction in the application rate of the individual herbicides (A) or (B) compared to the respective application rates of the herbicides in question in the case of individual application. It is therefore possible to influence the decomposition properties of the active compounds and achieve more favorable conditions for the subsequent growth of crop plants. A further advantage is believed to be that the development of resistance of harmful plants to the active compounds can be significantly reduced or avoided by the combination of active compounds which often have different modes of action.

[0025] More specifically, surprisingly, when active compounds (A) and (B) are used in combination for more economically important harmful plants, a superadditive (=synergistic) effect occurs. Here, the activity in the combination is higher than the expected sum of the activities of the individual herbicides used. The synergistic effect allows further reduction in application rate, control of a wide range of broadleaf weeds and grass weeds, faster onset of herbicidal action, longer persistence, better control of harmful plants with only one or several applications, and extended application period. By using the composition, the amount of harmful components such as nitrogen or oleic acid and their introduction into soil are also reduced to a certain extent.

[0026] Said properties and advantages are desirable in practical weed control in order not to leave undesirable competing plants in the crop and thus to ensure and / or increase the yield in terms of quality and quantity. The novel combination significantly surpasses the state of the art in view of the described properties.

[0027] Synergistic effects are observed in the case of joint application of active compounds (A) and (B), but can also frequently occur in the case of offset application (split application). It is also possible to apply herbicides (A) or (B) or herbicidal compositions (A) and (B) in several separate applications (successive application). For example, one or more pre-emergence applications can be followed by post-emergence applications, or an early post-emergence application can be followed by a medium-late or late post-emergence application. It is preferred to apply the active compounds of each combination simultaneously or immediately in succession, if appropriate in several separate applications. However, offset application of the individual active compounds of the combination is also possible and may be advantageous in individual cases. It is also possible to incorporate the application of other crop protection agents, such as the other active compounds mentioned (other herbicides, fungicides, insecticides, acaricides, etc.) and / or various auxiliaries, adjuvants and / or fertilizers into the system for application.

[0028] Application by the pre-emergence or post-emergence method is understood to mean, according to the context in which the term is used, the application of the active compound before and after the visible emergence of harmful plants above ground, respectively, or the use of the active compound against harmful plants before the emergence of the crop plants and after the emergence of the crop plants.

[0029] In the formula (I) for the compounds of herbicidally active compound (A) and all the formulae below, the following definitions are applicable: Alkyl means saturated linear or branched hydrocarbyl groups having the number of carbon atoms specified in each case, such as C1-C6-alkyl, such as methyl, ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl.

[0030] Halogen-substituted alkyl means a straight-chain or branched alkyl group, in which some or all of the hydrogen atoms may be substituted with halogen atoms, for example, C1-C2-haloalkyl such as chloromethyl, bromomethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, and pentafluoroethyl, and 1,1,1-trifluoroprop-2-yl.

[0031] Alkenyl means an unsaturated, linear or branched hydrocarbyl group having in each case the indicated number of carbon atoms and one double bond in any position, for example ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2-methyl-1-butenyl, 3-methyl- 1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1-pentenyl , 4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-1-butenyl, 1,2-dimethyl-2-butenyl nyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2-butenyl, 1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,It represents C2-C6-alkenyl such as 2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1-ethyl-2-methyl-1-propenyl and 1-ethyl-2-methyl-2-propenyl.

[0032] Alkynyl means a straight-chain or branched hydrocarbyl group having the number of carbon atoms specified in each case and one triple bond in any position, such as, for example, ethynyl, 1-propynyl, 2-propynyl (or propargyl), 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 3-methyl-1-butynyl, 1-methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl,

[0036] This refers to C2-C6-alkynyl, such as C2-C6-alkynyl, 3-methyl-1-pentynyl, 4-methyl-1-pentynyl, 1-methyl-2-pentynyl, 4-methyl-2-pentynyl, 1-methyl-3-pentynyl, 2-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-4-pentynyl, 3-methyl-4-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl and 1-ethyl-1-methyl-2-propynyl.

[0033] Cycloalkyl preferably denotes a carbocyclic saturated ring system having 3 to 8 ring carbon atoms, such as cyclopropyl, cyclobutyl, cyclopentyl or cyclohexyl. In the case of optionally substituted cycloalkyl, ring systems with substituents are included, including substituents with a double bond on the cycloalkyl group, such as alkylidene groups, such as methylidene.

[0034] In the case of optionally substituted cycloalkyl, polycyclic aliphatic systems such as bicyclo[1.1.0]butan-1-yl, bicyclo[1.1.0]butan-2-yl, bicyclo[2.1.0]pentan-1-yl, bicyclo[2.1.0]pentan-2-yl, bicyclo[2.1.0]pentan-5-yl, bicyclo[2.2.1]hept-2-yl (norbornyl), adamantan-1-yl and adamantan-2-yl are also included.

[0035] Optionally substituted cycloalkyl also includes spirocyclic aliphatic systems such as spiro[2.2]pent-1-yl, spiro[2.3]hex-1-yl, spiro[2.3]hex-4-yl, 3-spiro[2.3]hex-5-yl.

[0036] Cycloalkenyl means a carbocyclic, non-aromatic, partially unsaturated ring system, preferably having 4 to 8 carbon atoms, such as 1-cyclobutenyl, 2-cyclobutenyl, 1-cyclopentenyl, 2-cyclopentenyl, 3-cyclopentenyl, or 1-cyclohexenyl, 2-cyclohexenyl, 3-cyclohexenyl, 1,3-cyclohexadienyl, or 1,4-cyclohexadienyl, and also includes substituents having a double bond on the cycloalkenyl group, such as alkylidene groups, for example methylidene. In the case of optionally substituted cycloalkenyl, the explanation for substituted cycloalkyl applies analogously.

[0037] Alkoxy means a saturated, straight or branched alkoxy group, each having the number of carbon atoms specified, e.g., methoxy, ethoxy, propoxy, 1-methylethoxy, butoxy, 1-methylpropoxy, 2-methylpropoxy, 1,1-dimethylethoxy, pentoxy, 1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy, hexoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy, 1-methyl means C1-C6-alkoxy such as pentoxy, 2-methylpentoxy, 3-methylpentoxy, 4-methylpentoxy, 1,1-dimethylbutoxy, 1,2-dimethylbutoxy, 1,3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1-ethylbutoxy, 2-ethylbutoxy, 1,1,2-trimethylpropoxy, 1,2,2-trimethylpropoxy, 1-ethyl-1-methylpropoxy and 1-ethyl-2-methylpropoxy. Halogen-substituted alkoxy means linear or branched alkoxy groups having the number of carbon atoms specified in each case, in which some or all of the hydrogen atoms in these groups can be replaced by halogen atoms as specified above, for example C1-C2-haloalkoxy such as chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-1,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy, and 1,1,1-trifluoroprop-2-oxy.

[0038] The term "aryl" means an optionally substituted monocyclic, bicyclic or polycyclic aromatic system having preferably 6 to 14, especially 6 to 10, ring carbon atoms, such as phenyl, naphthyl, anthryl, phenanthrenyl, etc., preferably phenyl.

[0039] The term "optionally substituted aryl" also encompasses polycyclic ring systems, such as tetrahydronaphthyl, indenyl, indanyl, fluorenyl, biphenylyl, where the attachment points are on the aromatic system. In systematic terms, "aryl" is also generally encompassed by the term "optionally substituted phenyl".

[0040] The aryl is preferably, for example, hydrogen, halogen, alkyl, haloalkyl, hydroxyl, alkoxy, cycloalkoxy, aryloxy, alkoxyalkyl, alkoxyalkoxy, cycloalkyl, halocycloalkyl, aryl, arylalkyl, heteroaryl, heterocyclyl, alkenyl, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl, heteroarylcarbonyl, alkoxycarbonyl, hydroxycarbonyl, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, alkoxycarbonylalkyl, arylalkoxycarbonyl, arylalkoxycarbonylalkyl, alkynyl, alkynylalkyl, alkylalkynyl, trisalkylsilylalkynyl, nitro, amino, cyano, haloalkoxy, haloalkenyl, cycloalkoxy, cycloalkylalkoxy ... Substituted by alkylthio, alkylthio, hydrothio, hydroxyalkyl, heteroarylalkoxy, arylalkoxy, heterocyclylalkoxy, heterocyclylalkylthio, heterocyclyloxy, heterocyclylthio, heteroaryloxy, bisalkylamino, alkylamino, cycloalkylamino, hydroxycarbonylalkylamino, alkoxycarbonylalkylamino, arylalkoxycarbonylalkylamino, alkoxycarbonylalkyl(alkyl)amino, aminocarbonyl, alkylaminocarbonyl, bisalkylaminocarbonyl, cycloalkylaminocarbonyl, hydroxycarbonylalkylaminocarbonyl, alkoxycarbonylalkylaminocarbonyl, arylalkoxycarbonylalkylaminocarbonyl.

[0041] The term "halogen" means fluorine, chlorine, bromine or iodine. When the term is used in a group, "halogen" means a fluorine, chlorine, bromine or iodine atom.

[0042] Depending on the nature of the substituents and the way they are attached, the compounds of formula (I) may exist as stereoisomers. For example, when one or more asymmetrically substituted carbon atoms and / or sulfoxides are present, enantiomers and diastereomers may occur. Stereoisomers can be obtained from the mixture obtained in the preparation by conventional separation methods, for example, chromatographic separation processes. Similarly, it is possible to selectively prepare stereoisomers by using stereoselective reactions using optically active starting materials and / or auxiliaries.

[0043] The present invention also relates to all stereoisomers encompassed by formula (I) but not specifically defined, and to mixtures thereof. However, the following text always refers to compounds of formula (I) for the sake of brevity, which is understood to mean not only the pure compounds, but also, where appropriate, mixtures with various amounts of isomeric compounds.

[0044] According to the nature of the substituents defined above, the compounds of formula (I) have acidic properties and can form salts, and where appropriate also inner salts or adducts with inorganic or organic bases or metal ions. When the compounds of formula (I) have hydroxyl groups, carboxyl groups or other groups which induce acidic properties, these compounds can be reacted with bases to obtain salts. Suitable bases are, for example, hydroxides, carbonates and bicarbonates of alkali metals and alkaline earth metals, in particular those of sodium, potassium, magnesium and calcium, and also primary, secondary and tertiary amines with (C1-C4)-alkyl groups, mono-, di- and trialkanolamines of (C1-C4)-alkanols, choline and chlorocholine, as well as organic amines such as trialkylamines, morpholine, piperidine or pyridine. These salts are salts in which the acidic hydrogen is present with an agriculturally suitable cation, for example the metal salts, in particular the alkali metal salts or alkaline earth metal salts, in particular the sodium salt and potassium salt, or the ammonium salt, the organic amine or the quaternary ammonium salt, for example the salts of the formula [NRR'R''R'''] +where R to R''' each independently represent an organic group, in particular alkyl, aryl, aralkyl or alkylaryl. Also suitable are alkylsulfonium and alkylsulfoxonium salts, such as (C1-C4)-trialkylsulfonium and (C1-C4)-trialkylsulfoxonium salts.

[0045] The compounds of formula (I) can form salts on a basic group, such as amino, alkylamino, dialkylamino, piperidino, morpholino or pyridino, by addition of a suitable inorganic or organic acid, such as a mineral acid, for example HCl, HBr, H2SO4, H3PO4 or HNO3, or an organic acid, for example a carboxylic acid, for example formic acid, acetic acid, propionic acid, oxalic acid, lactic acid or salicylic acid, or a sulfonic acid, for example p-toluenesulfonic acid. In such cases, these salts contain the conjugate base of the acid as the anion.

[0046] Suitable substituents that exist in deprotonated form, such as sulfonic or carboxylic acids, may form inner salts with groups on those moieties that can be protonated (eg, amino groups).

[0047] If a group is polysubstituted by a radical, this means that this group is substituted by one or more radicals which may be identical or different from the ones mentioned.

[0048] In all formulas specified below, the substituents and symbols, unless defined differently, have the same meaning as set out in general formula (I) of Herbicide (A). The arrows in the chemical formulas indicate the points of attachment to the remainder of the molecule.

[0049] In this specification, preferred, particularly preferred and very particularly preferred meanings are given for each of the individual substituents of the herbicide (A) according to the general formula (I), as described above. The other substituents of the herbicide (A) of the general formula (I) which are not specified below have the above definitions.

[0050] In the first embodiment of the present invention, R 3 preferably denotes (C1-C3)-alkyl, (C2-C3)-alkenyl or (C1-C3)-alkoxy, each substituted by m radicals from the group consisting of fluorine and chlorine.

[0051] Particularly preferably, R 3 represents methyl, vinyl, trifluoromethyl or methoxy.

[0052] In a second embodiment of the present invention, R 11 , R 12 are each independently hydrogen, cyano, OR 7 , S(O) n R 5 , CO2R 8 , C.O.R. 6 , N.R. 6 R 8 , N.R. 6 COR 8 represents or or (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C3)-alkyl, (C2-C6)-alkenyl or (C2-C6)-alkynyl, each of which is selected from halogen, cyano, OR 7 , S(O) n R 5 , CO2R 8 and optionally substituted with m radicals from the group consisting of: or R 11 and R 12 together with the nitrogen atom to which they are attached form a saturated, partially or completely unsaturated 5-, 6- or 7-membered ring, which may be selected from the group consisting of halogen, cyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, oxo, OR 7 , S(O) n R 5 , CO2R 8 and, in addition to the nitrogen atom, r carbon atoms, n oxygen atoms, p sulfur atoms, and NR 7and N.C.O.R. 7 It contains p elements from the group consisting of as ring atoms.

[0053] More preferably, R 11 , R 12 are each independently hydrogen, cyano, OR 7 , S(O) n R 5 represents or or Halogen, OR 7 , S(O) n R 5 represents (C1-C3)-alkyl, optionally substituted by m radicals each selected from the group consisting of:

[0054] In a third embodiment of the present invention, R 5 represents a (C1-C6)-alkyl, each substituted with m radicals from the group consisting of halogen and cyano.

[0055] More preferably, R 5 represents a (C1-C3)-alkyl, each substituted with m radicals from the group consisting of halogen and cyano.

[0056] Most preferably, R 5 represents a (C1-C3)-alkyl, each substituted with m radicals from the group consisting of fluorine, chlorine and bromine.

[0057] In a fourth embodiment of the present invention, R 7 represents hydrogen, or or It represents (C1-C6)-alkyl, (C3-C4)-alkenyl or (C3-C4)-alkynyl, each of which is substituted by m radicals from the group consisting of halogen, cyano and (C1-C2)-alkoxy.

[0058] More preferably, R7 represents hydrogen, or or It represents (C1-C3)-alkyl or (C3-C4)-alkenyl, each of which is substituted by m radicals from the group consisting of halogen, cyano and (C1-C2)-alkoxy.

[0059] Most preferably, R 7 represents hydrogen, or or It represents a (C1-C3)-alkyl substituted by m radicals each from the group consisting of fluorine, chlorine and bromine.

[0060] In a fifth embodiment of the present invention, R 8 represents hydrogen, or or It represents (C1-C6)-alkyl, (C3-C6)-alkenyl or (C3-C6)-alkynyl, each of which is substituted by m radicals from the group consisting of halogen and (C1-C2)-alkoxy.

[0061] More preferably, R 8 represents hydrogen, or or It represents (C1-C3)-alkyl or (C3-C4)-alkenyl, each substituted by m radicals from the group consisting of halogen and (C1-C2)-alkoxy.

[0062] In a sixth embodiment of the present invention, Z preferably represents a group Z-1 or Z13, where Z-1 and Z13 have the following meanings: [ka] Here, the arrows indicate in each case the bond to the group C═O of formula (I).

[0063] In a seventh embodiment of the present invention, X2 , X 4 and X 6 respectively represent hydrogen.

[0064] In the context of the present invention, the substituent R 3 , R 5 ~R 8 , R 11 , R 12 , X 2 ~X 6 The individual preferred, more preferred and most preferred meanings of Z may be combined with each other as desired.

[0065] This is because the present invention provides, for example, a substituent R 3 has the preferred meaning, and R 5 ~R 8 The substituents have their usual meaning or the substituent R 5 has the preferred meaning, and the substituent R 11 has a particularly preferred or very particularly preferred meaning, and the remaining substituents have their general meanings.

[0066] Substituent R 3 , R 5 ~R 8 , R 11 , R 12 , X 2 ~X 6 Two combinations of these definitions given above for Z are given below as examples, each of which is disclosed as a further embodiment.

[0067] In an eighth embodiment of the present invention, R 1 and R 2 each represents hydrogen; R 3 represents (C1-C3)-alkyl, (C2-C3)-alkenyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; R 11 , R 12 are each independently hydrogen, cyano, OR7 , S(O) n R 5 , CO2R 8 represents or or (C1-C3)-alkyl or (C2-C6)-alkenyl, each of which is halogen, cyano, OR 7 , S(O) n R 5 may be substituted with m radicals from the group consisting of: R 5 represents (C1-C3)-alkyl, each of which is substituted with m radicals from the group consisting of halogen and cyano; R 6 is hydrogen or R 5 represents; R 7 represents hydrogen, or or represents (C1-C3)-alkyl or (C3-C4)-alkenyl, each of which is substituted by m radicals from the group consisting of halogen, cyano and (C1-C2)-alkoxy; R 8 represents hydrogen, or or represents (C1-C3)-alkyl or (C3-C4)-alkenyl, each substituted by m radicals from the group consisting of halogen and (C1-C2)-alkoxy; Z represents a group Z-1 or Z-13, where Z-1 and Z-13 have the following meanings: [ka] where the arrows indicate in each case the bond to the group C═O of formula (I); X 2 , X 4 and X 6 each represents hydrogen; X 3 and X 5 represent, independently of one another, hydrogen, fluorine, chlorine or cyano, or represents (C1-C3)-alkyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; m represents an index of 0, 1, 2, or 3; and n represents an index of 0, 1 or 2.

[0068] In a ninth embodiment of the present invention, R 1 and R 2 each represents hydrogen; R 3 represents methyl, vinyl, trifluoromethyl or methoxy; R 11 , R 12 are each independently hydrogen, cyano, OR 7 , S(O) n R 5 represents or or Halogen, OR 7 , S(O) n R 5 represents (C1-C3)-alkyl, each of which may be substituted by m radicals selected from the group consisting of: R 5 represents (C1-C3)-alkyl, each of which is substituted with m radicals from the group consisting of fluorine, chlorine and bromine; R 6 is hydrogen or R 5 represents; R 7 represents hydrogen, or or represents (C1-C3)-alkyl, each of which is substituted with m radicals from the group consisting of fluorine, chlorine and bromine; Z represents a group Z-1 or Z-13, where Z-1 and Z-13 have the following meanings: [ka] where the arrows indicate in each case the bond to the group C═O of formula (I); X 2 , X 4 and X 6each represents hydrogen; X 3 and X 5 each independently represents hydrogen, fluorine, chlorine or cyano; or represents (C1-C3)-alkyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; m represents an index of 0, 1, 2, or 3; and n represents an index of 0, 1 or 2.

[0069] According to a tenth embodiment of the invention, the herbicidal composition and at least one component (B) as defined above preferably comprises one or more compounds of general formula (I) (A) [component (A)] or their pesticidal compatible salts [herbicide (A)] according to Tables 1a and 1b.

[0070] Table 1a: Preferred compounds of formula (I) (herbicides (A)): [Table 12]

[0071] Table 1b: IUPAC names and structural formulae of preferred compounds of formula (I) (herbicides (A)) [Table 13] The expression TIFF0007657715000038.tif69157rel-(2R,4R) means that both the 2- and 4-position substituents are present in a cis configuration according to IUPAC nomenclature.

[0072] In Tables 1a and 1b, the compounds are identified by the chemical formula of the main component, which is present in a chemical purity of preferably at least 95% by weight of the compound. These compounds can of course also be used in a lower purity. In particular, when the secondary components of the compound are composed entirely or predominantly of the stereoisomers of the respective compound (A), efficacy is achieved upon application. Thus, the preferred herbicides (A) are also mixtures of two or more compounds (A) according to the invention.

[0073] When the stereochemical orientation at a carbon atom is defined in Tables 1a and 1b, the majority of the compound is a stereoisomer or mixture of stereoisomers having the R or S configuration at that carbon atom.

[0074] If the stereochemistry is not defined, the compound is racemic. If multiple stereocenters are present and each configuration is identified as R or S, the compound has the stereochemistry described in the question.

[0075] If the R or S configuration is not specified for multiple centers, the compound is a racemic mixture, i.e. the enantiomeric stereoisomers present therein (the enantiomers of a pair of enantiomers) are present in equal proportions in the mixture. Unless otherwise stated, in Tables 1a and 1b, the diastereomeric components are present in approximately equal proportions in the case of racemic compounds (A) having multiple stereocenters. However, for practical use, in the case of racemic compounds having multiple stereocenters, mixtures of diastereomers with different ratios of diastereomeric components are present.

[0076] Each of the compounds listed herein is preferably present with a stereochemical purity of 60% to 100%, preferably 70% to 100%, and particularly preferably 80% to 100%.

[0077] The mixtures detailed for the stereoisomeric compounds (A) are also preferred.

[0078] The compound of formula (I) is known from the application having the reference PCT / EP2018 / 065334, which was not yet published on the priority date of the present application, and can be prepared by the methods described therein.

[0079] The application rates of the herbicides (A) are in the range of 0.01 to 2000 g of active substance per hectare (hereinafter g ai / ha), preferably 0.02 to 1000 g ai / ha, in particular 0.5 to 750 g ai / ha. In the combinations according to the invention, within the range of application rates mentioned compared to the individual applications, lower application rates of the respective active compounds are usually required, preferably 0.01 to 1000 g ai / ha, in particular 0.02 to 500 g ai / ha, most preferably 5 to 250 g ai / ha.

[0080] Suitable combination partners (B) [= component (B) or herbicide (B)] are in principle all active compounds from subgroups (B1) to (B11), where the herbicidally active compounds are primarily named by their common name (English notation) according to the reference "The Pesticide Manual", 14th Edition, British Crop Protection Council 2006, abbreviation "PM" or by their chemical name according to standard nomenclature (IUPAC or Chemical Abstracts).

[0081] However, some herbicides (B) have surprisingly been found to be particularly good combination partners. Preferred, particularly preferred and most preferred herbicides (B) are listed below as further embodiments of the present invention.

[0082] In an eleventh embodiment of the present invention, the following herbicidally active compounds (B1) are preferred: [Table 14]

[0083] Particularly preferred are the following herbicidally active compounds: [Table 15]

[0084] In a twelfth embodiment of the present invention, the following herbicidally active compounds (B2) are preferred: [Table 16] TIFF0007657715000042.tif240143TIFF0007657715000043.tif29142

[0085] Particularly preferred are the following: [Table 17]

[0086] In the thirteenth embodiment of the present invention, the following herbicidally active compounds (B3) are preferred: [Table 18]

[0087] In a fourteenth embodiment of the present invention, the following herbicidally active compounds (B4) are preferred: [Table 19] TIFF0007657715000047.tif79143

[0088] Particularly preferred are the following: [Table 20]

[0089] In a fifteenth embodiment of the present invention, the following herbicidally active compounds (B5) are preferred: [Table 21] TIFF0007657715000050.tif163144

[0090] Particularly preferred are the following: [Table 22]

[0091] In a sixteenth embodiment of the present invention, the following herbicidally active compounds (B6) are preferred: [Table 23]

[0092] Particularly preferred are the following: [Table 24]

[0093] In a seventeenth embodiment of the present invention, the following herbicidally active compounds (B7) are preferred: [Table 25]

[0094] Particularly preferred are the following: [Table 26]

[0095] In an eighteenth embodiment of the present invention, the following herbicidally active compounds (B8) are preferred: [Table 27]

[0096] Particularly preferred are the following: [Table 28]

[0097] In a nineteenth embodiment of the present invention, the following herbicidally active compounds (B9) are preferred: [Table 29]

[0098] Most preferred is (B9.10) saflufenacil.

[0099] In a twentieth embodiment of the present invention, the following herbicidally active compounds (B10) are preferred: [Table 30]

[0100] Particularly preferred are (B10.5) diuron and (B10.8) isoproturon.

[0101] In a twenty-first embodiment of the invention, the following herbicidally active compounds (B11) are preferred: [Table 31] TIFF0007657715000061.tif37142

[0102] Particularly preferred are the following: [Table 32]

[0103] In the context of the present invention, the individual preferred, particularly preferred, and most preferred embodiments can be combined with each other as desired. This means that the present invention includes a herbicidal composition comprising (A) one or more compounds of general formula (I) or their agrochemically compatible salts [component (A)] and (B) one or more herbicides selected from the group of herbicidally active compounds (B1) to (B11) [component (B)], and any desired preferred, particularly preferred, and most preferred embodiments disclosed can be combined with each other as detailed above.

[0104] (A) Some two-component compositions comprising one or more herbicidally active compounds (A) of general formula (I) or their pesticidal compatible salts [herbicide (A)] and herbicide (B) have surprisingly been found to be particularly advantageous. Preferred, particularly preferred and most preferred two-component systems are listed below as further embodiments of the present invention.

[0105] In a twenty-second embodiment of the present invention, the composition preferably comprises: (A) A compound of general formula (I) or a pesticidal salt thereof [Herbicide (A)] [ka] [Here R 1 and R 2 each represents hydrogen; R 3 represents (C1-C3)-alkyl, (C2-C3)-alkenyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; R 11 , R 12 are each independently hydrogen, cyano, OR 7 , S(O) n R 5 , CO2R 8 represents or or (C1-C3)-alkyl or (C2-C6)-alkenyl, each of which is halogen, cyano, OR7 , S(O) n R 5 may be substituted with m radicals from the group consisting of: R 5 represents (C1-C3)-alkyl, each of which is substituted with m radicals from the group consisting of halogen and cyano; R 6 is hydrogen or R 5 represents; R 7 represents hydrogen, or or represents (C1-C3)-alkyl or (C3-C4)-alkenyl, each of which is substituted by m radicals from the group consisting of halogen, cyano and (C1-C2)-alkoxy; R 8 represents hydrogen, or or represents (C1-C3)-alkyl or (C3-C4)-alkenyl, each substituted by m radicals from the group consisting of halogen and (C1-C2)-alkoxy; Z represents a group Z-1 or Z-13, where Z-1 and Z-13 have the following meanings: [ka] where the arrows indicate in each case the bond to the group C═O of formula (I); X 2 , X 4 and X 6 each represents hydrogen; X 3 and X 5 represent, independently of one another, hydrogen, fluorine, chlorine or cyano, or represents (C1-C3)-alkyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; m represents an index of 0, 1, 2, or 3; and n represents an index of 0, 1 or 2. and

[0106] (B) a herbicide from the group consisting of the following [ingredient (B)]: [Table 33] Includes TIFF0007657715000066.tif240141TIFF0007657715000067.tif240144TIFF0007657715000068.tif241143TIFF0007657715000069.tif240143TIFF0007657715000070.tif130143

[0107] In a twenty-third embodiment of the present invention, the composition preferably comprises (A) A compound of general formula (I) or a pesticidal salt thereof [Herbicide (A)] [ka] [Here R 1 and R 2 each represents hydrogen; R 3 represents methyl, vinyl, trifluoromethyl or methoxy; R 11 , R 12 are each independently hydrogen, cyano, OR 7 , S(O) n R 5 represents or or Halogen, OR 7 , S(O) n R 5 represents (C1-C3)-alkyl, each of which may be substituted by m radicals selected from the group consisting of: R 5 represents (C1-C3)-alkyl, each of which is substituted with m radicals from the group consisting of fluorine, chlorine and bromine; R 6 is hydrogen or R 5 represents; R 7 represents hydrogen, or or represents (C1-C3)-alkyl, each of which is substituted with m radicals from the group consisting of fluorine, chlorine and bromine; Z represents a group Z-1 or Z-13, where Z-1 and Z-13 have the following meanings: [ka] where the arrows indicate in each case the bond to the group C═O of formula (I); X 2 , X 4 and X 6 each represents hydrogen; X 3 and X 5 each independently represents hydrogen, fluorine, chlorine or cyano; or represents (C1-C3)-alkyl or (C1-C3)-alkoxy, each of which is substituted by m radicals from the group consisting of fluorine and chlorine; m represents an index of 0, 1, 2 or 3; and n represents an index of 0, 1 or 2. and

[0108] (B) A herbicide from the group consisting of the following [ingredient (B)]: [Table 34] Contains TIFF0007657715000074.tif114136.

[0109] Particularly preferred compositions in the context of the present invention are those listed in Tables 2.1 to 2.5 below: Table 2.1: Particularly preferred binary compositions containing (A1) [Table 35] TIFF0007657715000076.tif190156

[0110] Table 2.2: Particularly preferred binary compositions containing (A2) [Table 36] TIFF0007657715000078.tif241157

[0111] Table 2.3: Particularly preferred binary compositions containing (A3) [Table 37] TIFF0007657715000080.tif55157

[0112] Table 2.4: Particularly preferred binary compositions containing (A4) [Table 38] TIFF0007657715000082.tif105156

[0113] Table 2.5: Particularly preferred binary compositions containing (A5) [Table 39] TIFF0007657715000084.tif157155

[0114] Furthermore, the combination according to the present invention can be used together with other active compounds, for example with the active compounds mentioned (herbicides, fungicides, insecticides, acaricides, etc.) and / or plant growth regulators, or with the additives customary in crop protection, for example with auxiliaries from the group of adjuvants and formulation auxiliaries.Here, the combination of active crop protection compounds, which comprises active compounds (A) and (B) and optionally further active compounds, is simply called "herbicidal combination".Their use forms (for example formulations or tank mixes) represent herbicidal compositions.

[0115] The invention therefore also provides herbicidal compositions which comprise a combination of active compounds according to the invention together with additives customary in crop protection, such as adjuvants and formulation auxiliaries, and optionally further active crop protection compounds.

[0116] The present invention also provides the use of the active compound combinations according to the invention as herbicides and plant growth regulators, preferably as herbicides and plant growth regulators with a synergistically active content of the respective active compound combinations present, or application methods using them.

[0117] The application rates of the herbicides (B) are known in principle and are generally in the range of 0.01 to 4000 g ai / ha, preferably in the range of 0.02 to 2000 g ai / ha, in particular in the range of 0.1 to 2000 g ai / ha. The application rates of the active compound pelargonic acid (B5.38) of group (B5) are in the range of 1 to 100,000 g ai / ha.

[0118] In the mixtures according to the invention, in the context of the application rates mentioned, lower application rates of the respective active compounds are generally required compared to individual applications.

[0119] For active compounds from group (B1), the application rates are preferably in the range from 5 to 250 g ai / ha, in particular in the range from 5 to 150 g ai / ha and most preferably in the range from 5 to 60 g ai / ha.

[0120] For active compounds from group (B2), the application rates are preferably in the range from 1 to 4000 g ai / ha, in particular in the range from 1 to 2000 g ai / ha, most preferably in the range from 1 to 400 g ai / ha.

[0121] For active compounds from group (B3), the application rates are preferably in the range from 10 to 1000 g ai / ha, in particular in the range from 10 to 500 g ai / ha, most preferably in the range from 10 to 300 g ai / ha.

[0122] For active compounds from group (B4), the application rates are preferably in the range from 1 to 700 g ai / ha, in particular in the range from 1 to 400 g ai / ha, most preferably in the range from 1 to 200 g ai / ha.

[0123] For the active compounds from group (B5), with the exception of pelargonic acid (B5.38), the application rates are preferably in the range from 1 to 2400 g ai / ha, in particular in the range from 1 to 1200 g ai / ha, most preferably in the range from 1 to 400 g ai / ha. For pelargonic acid (B.5.38), the application rates are preferably in the range from 1 to 100,000 g ai / ha, more preferably in the range from 1 to 40,000 g ai / ha, in particular in the range from 1 to 30,000 g ai / ha.

[0124] For active compounds from group (B6), the application rates are preferably in the range from 10 to 1000 g ai / ha, in particular in the range from 10 to 600 g ai / ha.

[0125] For active compounds from group (B7), the application rates are preferably in the range from 20 to 3500 g ai / ha, in particular in the range from 20 to 2500 g ai / ha, most preferably in the range from 20 to 2000 g ai / ha.

[0126] For active compounds from group (B8), the application rates are preferably in the range from 5 to 1500 g ai / ha, in particular in the range from 5 to 1000 g ai / ha, most preferably in the range from 5 to 900 g ai / ha.

[0127] For active compounds from group (B9), the application rates are preferably in the range from 2 to 2000 g ai / ha, in particular in the range from 2 to 1000 g ai / ha, more preferably in the range from 2 to 200 g ai / ha and most preferably in the range from 2 to 50 g ai / ha.

[0128] For active compounds from group (B10), the application rates are preferably in the range from 20 to 3500 g ai / ha, in particular in the range from 20 to 2000 g ai / ha.

[0129] For active compounds from group (B11), the application rates are preferably in the range from 25 to 3000 g ai / ha, in particular in the range from 25 to 2500 g ai / ha, most preferably in the range from 25 to 2000 g ai / ha.

[0130] The ratio of (A):(B) based on weight is generally in the range of 1:100000 to 2000:1, preferably 1:40000 to 750:1, particularly 1:15000 to 500:1, and more preferably 1:300 to 400:1, depending on the effective application rate.

[0131] For the active compounds from groups (B1) to (B11), the preferred weight ratios (A):(B) are as follows: (A):(B1) is preferably in the range of 30:1 to 1:30, particularly 15:1 to 1:15; (A):(B2) is preferably in the range of 400:1 to 1:400, particularly 200:1 to 1:200; (A):(B3) is preferably in the range of 30:1 to 1:30, particularly 15:1 to 1:15; (A):(B4) is preferably in the range of 300:1 to 1:300, particularly 150:1 to 1:150; (A):(B5) is preferably in the range of 400:1 to 1:300, particularly 300:1 to 1:150; (A):(B6) is preferably in the range of 60:1 to 1:60, particularly 30:1 to 1:30; (A):(B7) is preferably in the range of 10:1 to 1:200, particularly 1:1 to 1:100; (A):(B8) is preferably in the range of 30:1 to 1:300, particularly 10:1 to 1:80; (A):(B9) is preferably in the range of 80:1 to 1:200, particularly 40:1 to 1:100; (A):(B10) is preferably in the range of 10:1 to 1:300, particularly 3:1 to 1:150; The (A):(B11) ratio is preferably in the range of 30:1 to 1:300, particularly preferably 15:1 to 1:150.

[0132] The herbicidal composition according to the invention can also be combined with further herbicides and plant growth regulators, for example to complete the spectrum of activity.The active compounds that can be used as the compound of the combination partner of the invention in mixed formulations or tank mixes are, for example, known active compounds based on the inhibition of acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvylshikimate-3-phosphate synthase, glutamine synthase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase, photosystem I, photosystem II, protoporphyrinogen oxidase, as known from Weed Research 26 (1986) 441-445 or "The Pesticide Manual", 14th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2006, corresponding "e-Pesticide Manual Version 4 (2006)" and the documents cited therein. Additional trade names and "common names" are listed in the "Compendium of Pesticide Common Names," available on the Internet at http: / / www.alanwood.net / pesticides.

[0133] Known herbicides which may be mentioned as suitable for combination with the compounds of the invention are, for example, the following active compounds (note: the compounds are mentioned by their "common names" according to the International Organization for Standardization (ISO) or, where appropriate, by their chemical names together with the customary code number), in each case including all use forms such as acids, salts, esters and isomers, e.g. stereoisomers and optical isomers. In this case, one or more application forms are mentioned: 2,4-D, acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, alloxydim, alloxydim-sodium, ametryn, amicarbazone, amidosulfuron, amitrole, anilofos, asulam, atrazine, azafenidine, azimsulfuron, beflubutamid, benazolin, benazolin-ethyl, benfuresate, bensulfuron-methyl, bentazon, benzfendizone, benzobicyclon, benzofenap, bifenox, bilanafos afos), bispyribac-sodium, bromacil, bromobutide, bromofenoxime, bromoxynil, butachlor, butafenacil, butenachlor, butralin, butroxydim, butyrate, cafenstrole, carbetamide, carfentrazone-ethyl, clomethoxyfen, chloridazon, chlorimuron-ethyl, chlornitrofen, chlortoluron, chlorsulfuron, cytosine Nidon-ethyl, cinmethylin, cinosuflon, clefoxydim, clethodim, clodinafop-propargyl, clomazone, clomeprop, clopyralid, chloransulam-methyl, cumyluron, cyanazine, cyclosulfamuron, cycloxydi, cyhalofop-butyl, desmedipham, dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop-methyl, diclosulam, difenzoquat ), diflufenican, diflufenzopyr, dikegulac-sodium, dimefuron, dimepiperate, dimethachlor, dimethamethrin, dimethenamid, triaziflam, diquat-dibromide, dithiopyr, diuron, dymron, EPTC, esprocarb, ethalfluralin, ethametsurfuron-methyl, ethoxyfen, ethoxysulfuron, etobenzanid, fenoxaprop-ethyl,Fenoxaprop-P-ethyl, fentrazamide, flanprop-M-isopropyl, flanprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop-butyl, fluazolate, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, fluorochloridone, fluoroglycofen-ethyl, flupo Xam, flupyrsulfuron-methyl-sodium, fluridone, fluroxypyr, fluroxypyr-butoxypropyl, fluroxypyr-meptyl, flurprimidol, flurtamone, fluthiacet-methyl, fomesafen, foramsulfuron, glufosinate, glufosinate-ammonium, glyphosate, halosulfuron-methyl, haloxyfop, haloxyfop-ethoxyethyl, haloxyfop-methyl, haloxyfop-p-methyl, hexazinone, imazamethabenz-methyl , imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, iodosulfuron-methyl-sodium, ioxynil, isoproturon, isouron, isoxaben, isoxachlorthor, isoxaflutole, ketospiradox, lactofen, lenacil, linuron, MCPA, mecoprop, mecoprop-P, mefenacet, mesosulfuron-methyl, mesotrione, metamifop, metamitron, metazachlor, methabenzthiazuron, methylda methyldymron, metobromuron, metolachlor, metosulam, methoxron, metribuzin, metsulfuron-methyl, molinate, monolinuron, naproanilide, naproamide, nebulon, nicosulfuron, norflurazon, orbencarb, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefone, oxyfluorfen, paraquat, pelargonic acid, pendimethalin,pendralin, pentoxazone, petoxamide, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron-methyl, profluazol, profoxydim, prometryn, propachlor, propanil, propaquizafop, propisochlor, propoxycarbazone-sodium, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen-ethyl, pyrazolate, (pyrazosulfuron-ethyl, pyrazoxyfen, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac-methyl, pyrithiobac-sodium, quinclorac, (quinmerac, quinocla quinoclamine, quizalofop-ethyl, quizalofop-p-ethyl, quizalofop-p-tefuryl, rimsulfuron, sethoxydim, simazine, simetryn, S-metolachlor, sulcotrione, sulfentrazone, sulfometuron-methyl, sulfosate, sulfosulfuron, tebuthiuron, tepraloxydim, terbuthylazine, terbutryn, thenylchlor, thiazopyr, thifensulfuron-methyl, thiobencarb, thiocarbazil, tralkoxydim, triallert, triasulfuron, tribenuron-methyl, triclopyr, tridiphane, trifloxysulfuron, trifluralin, triflusulfuron-methyl, tritosulfuron, WL 110547, i.e. 5-phenoxy-1-[3-(trifluoromethyl)phenyl]-1H-tetrazole; HOK-201, HOK-202, UBH-509; D-489; LS 82-556; KPP-300; NC-324; NC-330; KH-218; DPX-N8189; SC-0774; TH-547, DOWCO-535; DK-8910; V-53482; PP-600; MBH-001; KIH-9201; ET-751; KIH-6127; KIH-2023 and KIH5996.

[0134] If each generic name includes multiple forms of the active compound, the name preferably defines the commercially available form.

[0135] The further active compound mentioned (= active compound (C * ), (C1 * ), (C2 * ) and the like), preferably according to the scheme (A)+(B)+(C * ) or according to the scheme (A) + (B) + (C1 * )+(C2 * ) or the like, can be combined with the binary combination according to the present invention.

[0136] The stated amounts are the application rates (g ai / ha = grams of active substance per hectare) and therefore also define the rates in co-formulations, premixes, tank mixes or in sequential application of the combined active compounds.

[0137] The combination can be applied by both pre-emergence and post-emergence methods.It is applied both pre-emergence and post-emergence for harmful plants, and pre-emergence and post-emergence for crop plants in selective control of harmful plants.Mixed forms can also be used to control harmful plants at their pre-emergence or post-emergence stage, for example after crop plants emerge.

[0138] The herbicidal combinations according to the invention may comprise further components, for example other active compounds against harmful organisms, such as harmful plants, plant-damaging animals or plant-damaging fungi, here in particular active compounds from the groups of herbicides, fungicides, insecticides, acaricides, nematicides, miticides and related substances.

[0139] Fungidically active compounds which can be used in combination with the herbicidal combinations according to the invention are preferably standard, commercially available active compounds, such as (analogous to herbicides, compounds are generally named by their common name, here with normal English spelling): 1) Ergosterol biosynthesis inhibitors, for example (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamid, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010) imazalil, (1.011) imazalil sulfate, (1.012) ipconazole, (1.013) metconazole, (1.014) mitomycin, (1.015) mitomycin, (1.016) mitomycin, (1.017) mitomycin, (1.018) mitomycin, (1.019) mitomycin, (1.020) mitomycin, (1.021) mitomycin, (1.022) mitomycin, (1.023) mitomycin, (1.024) mitomycin, (1.025) mitomycin, (1.026) mitomycin, (1.027) mitomycin, (1.028) mitomycin, (1.029) mitomycin, (1.030) mitomycin, (1.031) mitomycin, (1.032) mitomycin, (1.033) mitomycin, (1.034) mitomycin, (1.035) mitomycin, (1.036) mitomycin, (1.037) mitomycin, (1.038) mitomycin, (1.039) mitomycin, (1.040) mitomycin, (1.0 Clobutanil, (1.015) Paclobutrazol, (1.016) Prochloraz, (1.017) Propiconazole, (1.018) Prothioconazole, (1.019) Pyrisoxazole, (1.020) Spiroxamine, (1.021) Tebuconazole, (1.022) Tetraconazole, (1.023) Triadimenol, (1.024) Tridemorph, (1.025) Triticonazole, (1.026) (1R,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1 ,2,4-triazol-1-ylmethyl)cyclopentanol, (1.027)(1S,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.028)(2R)-2-(1-chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.029)(2R)-2-(1-chlorocyclopropyl)- 4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.030) (2R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.031) (2S)-2-(1-chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.032) (2S)-2-(1-chlorocyclopropyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.033) (2S)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.034) (R)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.035) (S)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, ( 1.036) [3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.037) 1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole , (1.038) 1-({(2S,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.039) 1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl Thiocyanate, (1.040) 1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.041) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.042) 2-[(2R,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.043) 2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.044) 2-[(2R,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.045) 2-[(2R,4S,5S)-1-(2,4-dichlorophenyl )-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.046) 2-[(2S,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.047) 2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2 ,4-dihydro-3H-1,2,4-triazole-3-thione, (1.048) 2-[(2S,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1. 050) 2-[1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.051) 2-[2-chloro-4-(2,4-dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.052) 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.053) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.054) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1.055) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.056) 2- {[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.057) 2-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.058) 2-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl ]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.059) 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.060) 5-(arylsulfanyl)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.061) 5-(arylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole (1.062) 5-(arylsulfanyl)-1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.063) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.064) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.065) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.066) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.067) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.068) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.069) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl N-methylimidoformamide, (1.070) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-064) N'-(2,5-dimethyl-4-{[3-(2,2,2-trifluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.065) N'-(2,5-dimethyl-4-{[3-(2,2,3,3-tetrafluoropropoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.066) N'-(2,5-dimethyl-4-{[3-(pentafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide N-ethyl-N-methylimidoformamide, (1.067) N'-(2,5-dimethyl-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.068) N'-(2,5-dimethyl-4-{3-[(2,2,2-trifluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.069) N'-(2,5-dimethyl-4-{3-[(2,2,3,3-tetrafluoropropyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide (1.070) N'-(2,5-dimethyl-4-{3-[(pentafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.071) N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamide, (1.072) N'-(4-{[3-(difluoromethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1. 073) N'-(4-{3-[(difluoromethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1.074) N'-[5-bromo-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimidoformamide, (1.075) N'-{4-[(4,5-dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylimidoformamide, (1.076) N'-{5-bromo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.077) N'-{5-bromo-6-[(1S)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.078) N'-{5-bromo -6-[(cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.079) N'-{5-bromo-6-[(trans-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.080) N'-{5-bromo-6-[1-(3,5-difluorophenyl)phenyl] phenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.081) mefentrifluconazole, (1.082) ipfentrifluconazole.

[0140] 2) Inhibitors of the respiratory chain in complex I or II, such as (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanil, (2.007) fluxapyroxad, (2.008) furametpyr, (2.009) isofetamide, (2.010) isopyrazam (anti-epimer enantiomer 1R,4S,9S), (2.011) isopyrazam (anti-epimer enantiomer 1S,4R,9R), (2.012) isopyrazam (2.013) Isopyrazam (mixture of syn-epimer racemates 1RS,4SR,9RS and anti-epimer racemates 1RS,4SR,9SR), (2.014) Isopyrazam (syn-epimer enantiomers 1R,4S,9R), (2.015) Isopyrazam (syn-epimer enantiomers 1S,4R,9S), (2.016) Isopyrazam (syn-epimer racemate 1RS,4SR,9RS), (2.017) Isopyrazam, (2.018) Penthiopyrad, (2.019) Pyzip Lumetofen, (2.020) pyraziflumide, (2.021) sedaxane, (2.022) 1,3-dimethyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.023) 1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.024) 1,3-dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H- Pyrazole-4-carboxamide, (2.025) 1-methyl-3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide, (2.026) 2-fluoro-6-(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide, (2.027) 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.028) 3-(difluoromethyl)-1-methyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.029) 3-(difluoromethyl)-1-methyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.030) 3-(difluoromethyl)-N-(7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1- Methyl-1H-pyrazole-4-carboxamide, (2.031) 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.032) 3-(difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.033) 5,8-difluoro-N-[2-(2-fluoro (2.034) N-(2-cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.035) N-(2-tert-butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N-(2 -tert-butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037) N-(5-chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N-(5-chloro-2-isopropylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.039) N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.040) N-[(1S,4R)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.041) N-[1-(2,4-dichlorophenyl)-1-methoxypropan-2-yl] -3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.042) N-[2-chloro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.043) N-[3-chloro-2-fluoro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N-[5-chloro-2-(trifluoromethyl)benzyl]- (2.045) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-N-[5-methyl-2-(trifluoromethyl)benzyl]-1H-pyrazole-4-carboxamide, (2.046) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-fluoro-6-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.047) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.048) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carbothioamide, (2.049) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.050) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.051) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methyl (2.054) N-cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055) N-cyclopropyl-N-(2-cyclopropyl-5-methylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.056) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide.

[0141] 3) Respiratory chain inhibitors acting on complex III, such as (3.001) amethoctrazine, (3.002) amisulbrom, (3.003) azoxystrobin, (3.004) methoxystrobin, (3.005) cumoxystrobin, (3.006) cyazofamid, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3.009) famoxadone, (3.010) fenamidone, (3.011) flufenoxis strobin, (3.012) fluoxastrobin, (3.013) kresoxim-methyl, (3.014) metominostrobin, (3.015) orysastrobin, (3.016) picoxylostrobin, (3.017) pyraclostrobin, (3.018) pyrametostrobin, (3.019) pyraoxystrobin, (3.020) trifloxystrobin, (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[( E)-1-fluoro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy)methyl]phenyl}-2-(methoxyimino)-N-methylacetamide, (3.022) (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.023) (2R)-2-{2-[(2,5-dimethylphenoxy)methyl] phenyl}-2-methoxy-N-methylacetamide, (3.024) (2S)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.025) (3S,6S,7R,8R)-8-benzyl-3-[({3-[(isobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino]-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl 2-methylpropanoate, (3.026) 2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.027) N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide, (3.028) (2E,3Z)-5-{[1-(4-chloro-2-fluorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.029) Methyl {5-[3-(2,4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamate. .

[0142] 4) Mitosis and cytotoxic agents, such as (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide, (4.009) 3-chloro-4-(2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.010) 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl) )-6-methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridin-3-yl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.012) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.013) 4-(2-bromo-4-fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.014) 4-(2-bromo -4-fluorophenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4-(2-bromo-4-fluorophenyl)-N-(2-fluorophenyl)-1 ,3-dimethyl-1H-pyrazol-5-amine, (4.018) 4-(2-chloro-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.019) 4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.020) 4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.021) 4-(2-chloro-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.022) 4-(4-chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, (4.023) N-(2-bromo-6-fluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.024) N-(2-bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.025) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine.

[0143] 5) Compounds with multi-site activity, e.g. (5.001) Bordeaux mixture, (5.002) Captafol, (5.003) Captan, (5.004) Chlorothalonil, (5.005) Copper hydroxide, (5.006) Copper naphthenate, (5.007) Copper oxide, (5.008) Copper oxychloride, (5.009) Copper(2+) sulfate, (5.010) Dithianone, (5.011) Dodine, (5.012) Folpet, (5.013) Mancozeb, (5.014) Manet (5.015) metiram, (5.016) metiram zinc, (5.017) oxine copper, (5.018) propineb, (5.019) sulfur and sulfur preparations containing calcium polysulfide, (5.020) thiram, (5.021) zineb, (5.022) ziram, (5.023) 6-ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile.

[0144] 6) Compounds capable of inducing host defense, such as (6.001) acibenzolar-S-methyl, (6.002) isotianil, (6.003) probenazole, (6.004) thiazinil.

[0145] 7) Amino acid and / or protein biosynthesis inhibitors, such as (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline.

[0146] 8) ATP production inhibitors, such as (8.001) Silthiofam. 9) Cell wall synthesis inhibitors, such as (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamide, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one.

[0147] 10) Lipid and membrane synthesis inhibitors, such as (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl. 11) Melanin biosynthesis inhibitors, for example (11.001) tricyclazole, (11.002) 2,2,2-trifluoroethyl{3-methyl-1-[(4-methylbenzoyl)amino]butan-2-yl}carbamate. 12) Nucleic acid synthesis inhibitors, such as (12.001) benalaxyl, (12.002) benalaxyl-M (chiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam). 13) Signal transduction inhibitors, such as (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozolin. 14) Compounds capable of acting as uncouplers, such as (14.001) fluazinam, (14.002) meptyldinocap.

[0148] 15) Further compounds, for example (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazin, (15.004) capsimycin, (15.005) carvone, (15.006) thinomethionate, (15.007) kufuraneb, (15.008) cyflufenamid, (15.009) cymoxanil, (15.010) cyprosulfamide, (15.011) fluthianil, (15.012) fosetyl-aluminium, (15.013) fosetyl-calcium, (15.014) Fosetyl-sodium, (15.015) Methyl isothiocyanate, (15.016) Metrafenone, (15.017) Mildiomycin, (15.018) Natamycin, (15.019) Nickel dimethyldithiocarbamate, (15.020) Nitrothal-isopropyl, (15.021) Oxamocarb, (15.022) Oxathiapiproline, (15.023) Oxyfenthiin, (15.024) Pentachlorophenol and its salts, (15.025) Phosphorous acid and its salts, (15.026) Propylene glycol Mocarb-focetylate, (15.027) pyriophenone (clazafenone), (15.028) tebufloquine, (15.029) tecloftalam, (15.030) tolnifanide, (15.031) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.032) 1-(4 -{4-[(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.033) 2-(6-benzylpyridin-2-yl)quinazoline, (15.034) 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrole-1,3,5,7(2H,6H)-tetrone, (15.035) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.036) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-chloro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.037) 2-[3,5-bis(difluoro methyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.038) 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline, (15.039) 2-{(5R)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.040) 2-{(5S)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.041) 2-{2-[(7,8-difluoro-2-methylquinolin-3-yl)oxy]-6-fluorophenyl}propan-2-ol, (15.042) 2-{2-fluoro-6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2-ol, (15.043) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.044) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl Methanesulfonate, (15.045) 2-Phenylphenol and its salts, (15.046) 3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.047) 3-(4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.048) 4-amino-5-fluoro Fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(1H)-one), (15.049) 4-oxo-4-[(2-phenylethyl)amino]butanoic acid, (15.050) 5-amino-1,3,4-thiadiazole-2-thiol, (15.051) 5-chloro-N'-phenyl-N'-(prop-2-yn-1-yl)thiophene 2-Sulfonohydrazide, (15.052) 5-Fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.053) 5-Fluoro-2-[(4-methylbenzyl)oxy]pyrimidin-4-amine, (15.054) 9-Fluoro-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepine, (15.055) But-3-yn-1-yl{6-[({[(Z) -(1-Methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.056) ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate, (15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15.059) quinolin-8-ol, (15.060) quinolin-8-ol sulfate (2:1), (15.061) tert-Butyl {6-[({[(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.062) 5-Fluoro-4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one. .

[0149] Preferred fungicides are selected from the group consisting of benalaxyl, bitertanol, bromuconazole, captafol, carbendazium, carpropamid, cyazofamid, cyproconazole, diethofencarb, edifenphos, fenpropimorph, fentin, fluquinconazole, fosetyl, fluoroimide, fopet, iminoctadine, iprodionem, iprovalicarb, kasugamycin, maneb, nabam, pencycuron, prochloraz, propamocarb, propineb, pyrimethanil, spiroxamine, quintozene, tebuconazole, tolylfluanid, triadimefon, triadimenol, trifloxystrobin, zineb.

[0150] Insecticides, acaricidal, nematicidal, nematicidal, miticidal and related active compounds are, for example (as with herbicides and fungicides, the compounds are referred to herein by their common names, where possible with normal English spelling):

[0151] (1) acetylcholinesterase (AchE) inhibitors, preferably carbamates selected from alanylcarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC and xylylcarb; or acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyphos, chlorfenvinphos, chlormephos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoate, Organophosphate esters selected from dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, fanfur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyaphos, isofenphos, isopropyl O-(methoxyaminothiophosphoryl) salicylate, isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos-methyl, profenofos, propetamphos, prothiophos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimphos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon and vamidothion.

[0152] (2) GABA-gated chloride channel blockers, preferably cyclodiene-organochlorines selected from chlordane and endosulfan or phenylpyrazoles (fiproles) selected from ethiprole and fipronil.

[0153] (3) sodium channel modulators, preferably acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, β-cyfluthrin, cyhalothrin, λ-cyhalothrin, γ-cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ) -(1R)-isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadesrin, momfluorothrin, permethrin, fenothrin [(1R)-trans isomer], prallethrin, pyrethrins (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomer], tralomethrin and transfluthrin, or DDT or methoxychlor.

[0154] (4) Nicotinic acetylcholine receptor (nAChR) competitive modulators, preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sulfoximines selected from sulfoxaflor, or butenolides selected from flupyradifurone.

[0155] (5) Nicotinic acetylcholine receptor (nAChR) allosteric modulators, preferably spinosyns selected from spinetoram and spinosad.

[0156] (6) Glutamate-gated chloride channel (GluCl) allosteric modulators, preferably avermectins / milbemycins selected from abamectin, emamectin benzoate, lepimectin and milbemectin.

[0157] (7) Juvenile hormone mimetics, preferably juvenile hormone analogs selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen.

[0158] (8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides; or methyl isocyanate generators selected from chloropicrin or sulfuryl fluoride or borax or tartar emetic or dazomet and metam.

[0159] (9) A chordotonal organ TRPV channel modulator selected from pymetrozine and pyrifluquinazone.

[0160] (10) Mite growth inhibitors selected from clofentezine, hexythiazox, diflovidazine and etoxazole.

[0161] (11) A microbial disruptor of an insect gut membrane selected from Bacillus thuringiensis subsp. israelensis, Bacillus sphaericus, Bacillus thuringiensis subsp. aizawai, Bacillus thuringiensis subsp. kurstaki, and Bacillus thuringiensis subsp. tenebrionis, and a Bt plant protein selected from Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, VIP3A, mCry3A, Cry3Ab, Cry3Bb, and Cry34Ab1 / 35Ab1.

[0162] (12) Inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide, or propargite or tetradifon.

[0163] (13) An uncoupler of oxidative phosphorylation via collapse of the proton gradient selected from chlorfenapyr, DNOC, and sulfluramide.

[0164] (14) A nicotinic acetylcholine receptor channel blocker selected from bensultap, cartap hydrochloride, thiocyclam and thiosultap-sodium.

[0165] (15) An inhibitor of chitin biosynthesis, type 0, selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

[0166] (16) An inhibitor of chitin biosynthesis selected from buprofezin, type 1.

[0167] (17) A molting disruptor selected from cyromazine (especially for Diptera).

[0168] (18) An ecdysone receptor agonist selected from chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

[0169] (19) An octopamine receptor agonist selected from amitraz.

[0170] (20) A mitochondrial complex III electron transport inhibitor selected from hydramethylnon, acequinocyl, or fluacrytripyrim.

[0171] (21) Mitochondrial complex I electron transport inhibitors, preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad, or rotenone (Derris).

[0172] (22) A voltage-dependent sodium channel blocker selected from indoxacarb and metaflumizone.

[0173] (23) Inhibitors of acetyl-CoA carboxylase, preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen and spirotetramat.

[0174] (24) Mitochondrial complex IV electron transport inhibitors, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.

[0175] (25) Mitochondrial complex II electron transport inhibitors, preferably β-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from piflubumid.

[0176] (28) Ryanodine receptor modulators, preferably diamides selected from chlorantraniliprole, cyantraniliprole and flubendiamide.

[0177] (29) Chordotonal organ modulators selected from flonicamides (with undefined target structure).

[0178] (30) Acinonapyr, afidopiropen, afoxolaner, azadirachtin, benclothiaz, benzoximate, benzpyrimoxane, bifenazate, brofuranilide, bromopropylate, quinomethionate, chloropralthrin, cryolite, cyclaniliprole, cycloxapride, cyhalodiamide, dichloromezothiaz, dicofol, epsilon-metofluthrin, epsilon-momfluorotrin, flometoquin, fluazaindolizine, fluensulfone, flufenerim, flufenoxystrobin, flufiprole, fluhexafon, fluopyram, flupirimine, fluralaner, fluxamethamide, fufe Further active compounds selected from nozide, guadipyr, heptafluthrin, imidaclothiz, iprodione, kappa-bifenthrin, kappa-tefluthrin, lotilaner, meperfluthrin, oxazosulfil, paichongding, pyridalyl, pyrifluquinazone, pyriminostrobin, spirobudiclofen, spiropydione, tetramethylfluthrin, tetraniliprole, tetrachlorantraniliprole, tigolaner, thioxazaphen, thiofluoximate, triflumezopyrim and iodomethane; furthermore, Bacillus firmus (Bacillus firmus) (I-1582, BioNeem, Votivo), as well as the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO 2006 / 043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro [indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS637360-23-7), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]dec-3-en-2-one (known from WO2010052161) (CAS1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-ylethyl carboxylate carbonate (known from EP2647626) (CAS-1440516-42-6), 4-(but-2-yn-1-yloxy)-6-(3,5-dimethylpiperidin-1-yl)-5-fluoropyrimidine (known from WO2004 / 099160) (CAS792914-58-0), PF1364 (known from JP2010 / 018586) (CAS Reg. No. 1204776-60-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoropropan-2-one (known from WO2013 / 144213) (CAS1461743-15-6), N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl-3-(pentafluoroethyl)-4-(trifluoromethyl)-1H-pyrazole-5-carboxamide (known from WO2010 / 051926) (CAS1226889-14-0), 5-bromo-4-chloro-N-[4-chloro-2-methyl-6-(methylcarbamoyl) phenyl]-2-(3-chloro-2-pyridyl)pyrazole-3-carboxamide (known from CN103232431) (CAS 1449220-44-3), 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxido-3-thietanyl)-benzamide, 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxido-3-thietanyl)benzamide and 4-[(5S)-5-(3,5-dichlorophenyl)-4,5-Dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxide-3-thietanyl)benzamide (known from WO2013 / 050317A1) (CAS1332628-83-7), N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]-propanamide, (+)-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]-propanamide, (-)-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide (known from WO2013 / 162715A2, WO2013 / 162716A2, US2014 / 0213448A1) (CAS1477923-37-7), 5-[[(2E)-3-chloro-2-propen-1-yl]amino]-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoropropyl)sulfinyl]propanamide 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)thioxomethyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide (Liudaibenjiaxuanan, known from CN103109816A) (CAS1232543-85-9); N-[4-chloro-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methyl N-[2-(5-amino-1,3,4-thiadiazol-2-yl)-4-chloro-6-methylphenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide (known from WO2011 / 085575A1) (CAS1233882-22-8), 4-[3-[2,6-dichloro-4-[(3,3-Dichloro-2-propen-1-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluoromethyl)-pyrimidine (known from CN101337940A) (CAS 1108184-52-6); (2E)- and 2(Z)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]-hydrazinecarboxamide (known from CN101715774A) (CAS 1232543-85-9); 3-(2,2-dichloroethenyl)-2,2-dimethyl-4-(1H-benzimidazo[pi]yl)cyclopropanecarboxylate (4aS)-7-chloro-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]carbonyl]indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylic acid methyl ester (known from CN102391261A) (CAS1370358-69-2); 6-deoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-1H-1,2,4-Triazol-3-yl]phenyl]carbamate]-α-L-mannopyranose (known from US2014 / 0275503A1) (CAS1181213-14-8); 8-(2-cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS1253850-56-4), (8-anti)-8-(2-cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)- (8-syn)-8-(2-cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS 933798-27-7), (8-syn)-8-(2-cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (known from WO2007040280A1 and WO2007040282A1) (CAS 934001-66-8), N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl] -N-ethyl-3-[(3,3,3-trifluoropropyl)thio]propanamide (known from WO2015 / 058021A1, WO2015 / 058028A1) (CAS1477919-27-9) and N-[4-(aminothioxomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide (known from CN103265527A) (CAS1452877-50-7), 5-(1,3-difluoropropyl)thio]propanamide (known from WO2015 / 058021A1, WO2015 / 058028A1) (CAS1477919-27-9) 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dione (known from WO2014 / 187846A1) (CAS1638765-58-8), ethyl 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-Diazaspiro[4.5]dec-3-en-4-yl-carboxylate (known from WO2010 / 066780A1, WO2011151146A1) (CAS1229023-00-0), 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2-ethyl-3-oxo-4-isoxazolidinyl]-2-methylbenzamide (known from WO2011 / 067272, WO2013 / 050302) (CAS1309959-62-3).

[0179] Insecticides which are preferably used together with the herbicides are, for example: Acetamiprid, Acrinathrin, Aldicarb, Amitraz, Acinphos-methyl, Cyfluthrin, Carbaryl, Cypermethrin, Deltamethrin, Endosulfan, Ethoprophos, Fenamiphos, Fenthion, Fipronil, Imidacloprid, Methamidophos, Methiocarb, Niclosamide, Oxydemeton-methyl, Prothiofos, Silafluofen, Thiacloprid, Thiodicarb, Tralomethrin, Triazophos, Trichlorofon, Triflumuron, Terbufos, Fonofos, Phorate, Chlorpyrifos, Carbofuran, Tefluthrin.

[0180] The active compound combinations according to the invention are suitable for controlling a wide range of weeds in plantation crops, such as non-crop land, roads, railway facilities, industrial areas ("industrial weed control"), or in temperate, subtropical and tropical climates or geographies. Examples of plantation crops are oil palm, nuts (e.g. almonds, hazelnuts, walnuts, macadamia), coconuts, berries, rubber trees, citrus (e.g. oranges, lemons, mandarins), bananas, pineapples, cotton, sugar cane, tea, coffee, cocoa, etc. They are also suitable for use in fruit growing (e.g. pome fruits such as apples, pears, cherries, mangoes, kiwis, etc.) and viticulture. The compositions can also be used for preparation of sowing ("burn-down", "no-till" or "zero-till" methods) or for post-harvest treatment ("chemical fallow"). The possible use of the active compound combinations also extends to weed control in tree crops, for example young Christmas tree crops or eucalyptus crops, in each case before or after transplanting (including over-top treatment).

[0181] The compositions can also be used to prevent undesirable vegetative growth in economically important crop plants such as wheat (hard and soft wheat), corn, soybean, sugar beet, sugarcane, cotton, rice, legumes (e.g., green beans and broad beans), flax, barley, oats, rye, triticale, potato and millet / sorghum, pastures, and areas of grass / turf and plantation crops. Plantation crops are: pome fruits (apple, pear, quince), Ribes (blackberry, raspberry), citrus, Prunus (cherry, nectarine, almond), nuts (walnut, pecan, hazelnut, cashew, macadamia), mango, cacao, coffee, grapes (for eating or to make wine), palms (oil palm, date palm, coconut palm, etc.), eucalyptus, persimmon, rubber, pineapple, banana, avocado, lychee, forest crops (Eucalypteae, Piniaceae, Piceae, Meliaceae, etc.).

[0182] The combination of herbicidally active compounds according to the invention in each application form (=herbicidal composition) has synergistic effects in terms of herbicidal activity and selectivity, and has favorable effects in terms of the range of weeds. They have excellent herbicidal activity against a wide range of economically important annual harmful monocotyledonous and dicotyledonous plants. The active compounds also provide good control of difficult-to-control perennial harmful plants that produce shoots from rhizomes, root stocks or other perennial organs.

[0183] For application, the active compound combinations can be spread onto the plants (e.g. harmful plants such as monocotyledonous or dicotyledonous weeds or undesirable crop plants), onto the seeds (e.g. vegetative propagation organs such as grains, seeds, tubers or shoot parts bearing buds) or onto the area in which the plants grow (e.g. arable land).

[0184] These substances can be deployed pre-sowing (also by incorporation into the soil, if appropriate), pre-emergence or post-emergence. They are preferably used in plantation crops by the pre-emergence method after early sowing or by the post-emergence method against harmful plants that have not yet emerged or that have already emerged. The application can also be integrated into a weed management system using split repeated applications (sequential).

[0185] Specific examples of some representatives of the food phase of monocotyledonous and dicotyledonous weeds which can be controlled by the combinations of active compounds according to the invention are given below, but the list is not intended to be limited to any particular species.

[0186] From the group of monocotyledonous weed species, for example the genera Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachicaria, Bromus, Cynodon, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristyl The genera Is, Imperata, Ischaemum, Heteranthera, Imperata, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum, Sphenoclea and Cyperus are included in the annual group.

[0187] In the case of dicotyledonous weed species the spectrum of action is e.g. Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium album, Cornweed, Prunus armeniaca, Prunus subhirtella ... henopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erodium, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Geranium, Hibiscus, Ipomoea, omoea), Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Buttercup Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi,These include the genera Trifolium, Urtica, Veronica, Viola, and Xanthium.

[0188] When the active compound combinations according to the invention are applied pre-emergence to the soil surface, the emergence of weed seedlings is either completely prevented or the weeds grow until they reach the cotyledon stage, after which they stop growing and finally die completely after a period of 3-4 weeks.

[0189] If the active compounds are applied to the green parts of the plants after emergence, growth stops after treatment and the harmful plants either remain in the growth stage they were in at the time of application or they die completely after a certain period of time, so that in this way competition with weeds harmful to the crop plants is very quickly and persistently eliminated.

[0190] The herbicidal composition according to the invention is notable for a fast onset and long duration of herbicidal action.In general, the rain resistance of the active compounds in the combination according to the invention is favorable.A particular advantage is that the effective dose of the compounds (A) and (B) used in the combination can be adjusted to a low level, so that their soil action is optimally low.Therefore, not only is its use in sensitive crops possible, but groundwater pollution is also virtually prevented.The combination according to the invention of active compounds allows the required application rate of active compounds to be significantly reduced.

[0191] The combined use of herbicides (A) and (B) achieves performance characteristics that exceed those expected due to the known properties of the individual herbicides for the combination, e.g., herbicidal efficacy against a particular harmful plant species exceeds predicted values ​​as might be estimated by standard methods, e.g., by Colby or other extrapolation methods.

[0192] A synergistic effect exists whenever the effect of a combination of active compounds (here herbicidal effect) is greater than the sum of the effects of the active compounds applied individually. The expected activity for a given combination of two active compounds can be calculated according to SR Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15 (1967), 20-22) (see below).

[0193] Thus, synergistic effects allow, for example, a reduction in the application rate of the individual active compounds, higher efficacy at the same application rate, control of harmful plant species that have not yet been covered (gaps), increased residual action, extended duration of efficacy, increased rate of action, extended application period and / or a reduction in the number of individual applications required, thus allowing for a more economically and ecologically advantageous weed control system for the user.

[0194] The combinations according to the invention have excellent herbicidal activity against monocotyledonous and dicotyledonous weeds, whereas many economically important crop plants are only slightly damaged, if at all, depending on the structure of the respective active compound combination according to the invention and its application rate, where economically important crop plants are, for example, those of the genus Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, , dicotyledonous crops from the genera Pisum, Solanum, Vicia, or monocotyledonous crops from the genera Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Rye, Secale, Sorghum, Triticale, Wheat, and Zea.

[0195] Furthermore, the compositions according to the invention may have significant growth-regulating properties in crop plants.They can intervene in the plant's own metabolism with regulating effects and therefore be used for the controlled influence of plant components and for example to facilitate harvesting by inducing desiccation and stunting.In addition, they are also suitable for general suppression and inhibition of undesirable vegetative growth without killing the plant in the process.Inhibition of vegetative growth plays a major role for many monocotyledonous and dicotyledonous crops, since it can reduce or completely prevent lodging.

[0196] Due to their herbicidal and plant growth regulating properties, they can be used to control harmful plants in known plant crops or resistant crop plants that are modified by conventional mutagenesis or genetically modified. In general, transgenic plants are distinguished by certain advantageous properties, such as resistance to plant diseases or causative organisms of plant diseases (e.g., certain insects or microorganisms (e.g., fungi, bacteria or viruses)) in addition to resistance to the composition of the present invention. Other specific properties relate to the harvested product, for example in terms of quantity, quality, storability, composition and specific components. For example, transgenic plants with high starch content or altered starch quality, or transgenic plants with different fatty acid composition in the harvested product are known. Other specific properties can be tolerance or resistance to abiotic stressors, such as heat, low temperature, drought, salinity and UV light.

[0197] Preferably, the active compound combinations according to the invention can be used as herbicides in crops of crop plants which are resistant or have been made resistant by genetic engineering to the phytotoxic effects of herbicides.

[0198] Conventional methods of producing new plants with modified properties compared to existing plants consist, for example, in conventional breeding methods and in the generation of mutants. Alternatively, new plants with modified properties can be produced using recombinant methods (see, for example, EP-A-0221044, EP-A-0131624). For example, the following are mentioned in some cases: - the genetic modification of crop plants with the aim of modifying the starch synthesised in the plant (e.g. WO 92 / 11376, WO 92 / 14827, WO 91 / 19806), - transgenic crops which are resistant to other herbicides, for example sulfonylurea herbicides (EP-A-0257993, US-A-5013659), - transgenic crops capable of producing Bacillus thuringiensis toxins (Bt toxins) which render the plants resistant to certain pests (EP-A-0142924, EP-A-0193259); - transgenic crops with altered fatty acid composition (WO91 / 13972); - crop plants genetically engineered with novel compounds or secondary metabolites, e.g. novel phytoalexins that enhance disease resistance (EPA309862, EPA0464461); - Transgenic plants with reduced photorespiration, with higher yields and greater stress tolerance (EPA0305398); - transgenic crops producing proteins of pharmaceutical or diagnostic importance ("molecular pharming"); - transgenic crop plants characterized by higher yields or better quality, - transgenic crop plants featuring, for example, combinations of said novel traits ("gene stacking").

[0199] Numerous molecular biology techniques are known in principle which can be used to produce new transgenic plants with modified properties; see, for example, I. Potrykus and G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, or Christou, "Trends in Plant Science" 1 (1996) 423-431.

[0200] For such recombinant manipulations, nucleic acid molecules that allow sequence modification by mutagenesis or recombination of DNA sequences can be introduced into plasmids. Using standard methods, it is possible, for example, to perform base exchanges, to remove parts of sequences, or to add natural or synthetic sequences. To join DNA fragments to one another, adapters or linkers can be placed on the fragments (see, for example, Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Gene und Klone" [Genes and clones], VCH Weinheim, 2nd ed., 1996).

[0201] For example, the generation of plant cells with reduced activity of a gene product can be achieved by expressing at least one corresponding antisense RNA, a sense RNA to achieve a co-suppression effect or by expressing at least one appropriately constructed ribozyme that specifically cleaves the transcript of said gene product.

[0202] For this purpose, it is possible to use, firstly, DNA molecules which include the entire coding sequence of the gene product, including any adjacent sequences which may be present, and also DNA molecules which include only parts of the coding sequence, in which case these parts must be long enough to have an antisense effect in the cell. It is also possible to use DNA sequences which are highly homologous to the coding sequences of the gene products, but which are not completely identical to them.

[0203] When expressing nucleic acid molecules in plants, the synthesized protein can be localized in any desired compartment of plant cells. However, to achieve localization in a specific compartment, it is possible to, for example, link the coding region to a DNA sequence that ensures localization in a specific compartment. Such sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106). Nucleic acid molecules can also be expressed in organelles of plant cells.

[0204] Transgenic plant cells can be regenerated by known techniques to give whole plants. In principle, the transgenic plants can be of any desired plant species, i.e. monocotyledonous as well as dicotyledonous plants. In this way, transgenic plants can be obtained whose properties are modified by overexpression, suppression or inhibition of a homologous (= natural) gene or gene sequence, or by expression of a heterologous (= foreign) gene or gene sequence.

[0205] The active compound combinations according to the invention can preferably be used in transgenic crops which are tolerant or have been made tolerant to the active compounds used.

[0206] The active compound combinations according to the invention can also be used in transgenic crops which are preferably tolerant to growth regulators, such as dicamba, or herbicides which inhibit essential plant enzymes, such as acetolactate synthase (ALS), EPSP synthase, glutamine synthase (GS) or hydroxyphenylpyruvate dioxygenase (HPPD), or herbicides from the group of the sulfonylureas, glyphosate, glufosinate or benzoylisoxazoles and similar active compounds.

[0207] The present invention therefore also provides a method for controlling undesired plant growth, optionally in crops of crop plants, preferably in non-arable land or in plantation crops, characterized in that one or more herbicides of type (A) together with one or more herbicides of type (B) are applied to crop plants, plant parts or plant seeds thereof (seeds) or to the growing area.

[0208] The present invention also provides the use of the novel combinations of compounds (A)+(B) for the control of harmful plants, optionally in crops of crop plants, preferably in non-arable and plantation crops, but also for the control of harmful plants before sowing of a subsequent crop plant, in particular for the preparation of sowing ("burn-down application").

[0209] The active compound combinations according to the invention can be prepared as mixed formulations of the two components, if appropriate together with further active compounds, additives and / or customary formulation auxiliaries, and then applied in the customary manner by dilution with water, or can be prepared as so-called tank mixes by co-diluting the separately formulated or partly separately formulated components with water.

[0210] Compounds (A) and (B) or combinations thereof can be formulated in various ways depending on the biological and / or physicochemical parameters required. Examples of common formulation options are: wettable powders (WP), water-soluble powders (SP), emulsifiable concentrates (EC), water-soluble concentrates, aqueous solutions (SL), emulsions (EW), e.g. oil-in-water and water-in-oil emulsions, sprays or emulsions, oil-based or water-based dispersions, oil dispersions (OD), suspensions, suspension concentrates (SC), oil-miscible solutions, capsule suspensions (CS), dusts (DP), seed dressings, granules for soil application or scattering, granules in the form of microgranules (GR), spray granules, absorbent and adsorbent granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules or waxes.

[0211] The present invention therefore also provides herbicidal and plant growth regulating compositions which contain the active compound combinations according to the invention.

[0212] The individual formulation types are known in principle and are described, for example, in: Winnacker-Kuechler, "Chemische Technologie" [Chemical technology], Volume 7, C. Hanser Verlag Munich, 4th edition. 1986; van Valkenburg, "Pesticide Formulations", Marcel Dekker, NY, 1973; K. Martens, "Spray Drying Handbook", 3rd edition. 1979, G. Goodwin Ltd. London.

[0213] The necessary formulation auxiliaries, such as inert materials, surfactants, solvents and further additives, are likewise known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd ed., Darland Books, Caldwell NJ; HvOlphen, "Introduction to Clay Colloid Chemistry", 2nd ed., J. Wiley & Sons, NY; C. Marsden, "Solvents Guide", 2nd ed., Interscience, NY 1963; McCutcheon's "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridgewood NJ; Sisley and Wood, "Encyclopedia of Surface Active Agents", Chem. Publ. Co. Inc., NY 1964; Schoenfeldt, "Grenzflaechenaktive Aethylenoxidaddukte [Interface-active Ethylene Oxide and Winnacker-Kuchler, “Chemische Technologie [Chemical Technology]”, Vol. 7, C. Hanser Verlag Munich, 4th edition, 1986.

[0214] On the basis of these formulations, it is also possible to produce combinations with other pesticides, such as other herbicides, fungicides, insecticides or other pesticides (e.g. acaricides, nematicides, molluscicides, rodenticides, aphidicides, birdicides, larvicides, ovicides, bactericides, viricides, etc.), and also with safeners, fertilizers and / or growth regulators, for example in the form of ready-to-use formulations or as tank mixes.

[0215] Wettable powders are preparations which can be uniformly dispersed in water and which, in addition to the active ingredient, contain, apart from diluents and inert substances, also surfactants of the ionic and / or nonionic type (wetting agents, dispersants), such as polyoxyethylated alkylphenols, polyoxyethylated fatty alcohols, polyoxyethylated fatty amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium lignosulfonate, sodium 2,2'-dinaphthylmethane-6,6'-disulfonate, sodium dibutylnaphthalenesulfonate or else sodium oleoyl methyl taurate. To prepare wettable powders, the herbicidal active ingredient is comminuted in customary equipment, such as, for example, hammer mills, blower mills and air jet mills, and simultaneously or subsequently mixed with the formulation auxiliaries.

[0216] Emulsifiable concentrates are prepared by dissolving the active compounds in an organic solvent, such as butanol, cyclohexanone, dimethylformamide, xylene, or other mixtures of relatively high-boiling aromatic or hydrocarbon or organic solvents, together with the addition of one or more ionic and / or nonionic surfactants (emulsifiers). Examples of emulsifiers that can be used are: calcium alkylarylsulfonates, such as calcium dodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide-ethylene oxide condensation products, alkyl polyethers, sorbitan esters, such as sorbitan fatty acid esters, or polyoxyethylene sorbitan fatty acid esters.

[0217] Dusts are obtained by grinding the active compound with finely divided solids, for example talc, natural clays, such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.

[0218] Suspension concentrates may be water-based or oil-based. They can be prepared by wet milling, for example in a commercial bead mill, and the optional addition of surfactants, for example as already listed above for the other formulation types.

[0219] Emulsions, e.g. oil-in-water emulsions (EW), can be prepared, e.g., by means of stirrers, colloid mills and / or static mixers, using aqueous organic solvents and optionally surfactants, e.g. as already listed above for other formulation types.

[0220] Granules can be prepared by spraying the active compound onto a granular inert material capable of adsorbing it, or by applying an active compound concentrate to the surface of a carrier material such as sand, kaolinite or a granular inert material using an adhesive, such as polyvinyl alcohol, sodium polyacrylate or other mineral oils. If a suitable active compound is desired as a mixture with fertilizers, it can be granulated in the manner customary for the production of fertilizer granules.

[0221] Water-dispersible granules are generally prepared by methods such as spray drying, fluid bed granulation, pan granulation, mixing in a high speed mixer, and extrusion without solid inert materials.

[0222] The agrochemical formulations generally contain from 0.1 to 99% by weight, in particular from 0.2 to 95% by weight, of active compounds of type (A) and / or (B); depending on the type of formulation, the following concentrations are customary: In wettable powders, the active compound concentration is, for example, about 10% to 95% by weight, the remainder up to 100% by weight being made up of the usual formulation constituents. In the case of emulsifiable concentrates, the active compound concentration can be about 1% to 90% by weight, preferably 5 to 80 percent by weight.

[0223] Preparations in the form of dusts usually contain 5% to 20% by weight of the active compound; sprays contain about 0.05 to 80, preferably 2 to 50 weight percent (wt. %) of the active compound.

[0224] In the case of granules, such as dispersible granules, the active compound content depends in part on whether the active compound is present in liquid or solid form and whether granulation aids and fillers are used. In general, the content in water-dispersible granules is between 1% and 95% by weight, preferably between 10% and 80% by weight.

[0225] Furthermore, the described active compound formulations optionally contain the respective customary adhesives, wetting agents, dispersants, emulsifiers, penetrants, preservatives, antifreeze agents and solvents, fillers, colorants and carriers, antifoaming agents, evaporation inhibitors and pH or viscosity adjusting compositions.

[0226] For application, the commercial formulations are, if appropriate, diluted with water in the customary manner, for example in the case of wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules. Dust-type preparations, granules for soil application or granules for scattering and sprays are usually not further diluted with other inert substances before application.

[0227] The active compounds can be applied to plants, plant parts, plant seeds or the area under cultivation (soil), preferably to green plants and plant parts and optionally the soil.

[0228] One possible use is the joint application of the active compounds in the form of a tank mix, in which optimally formulated concentrates of the individual active compounds are combined and mixed with water in a tank and the resulting spray is applied.

[0229] The synergistic herbicidal formulations of the inventive combination of active compounds (A) and (B) have the advantage that they can be applied more easily, since the amounts of the components are already adjusted to the correct ratio to one another. Furthermore, the adjuvants in the formulations can be optimally adjusted to one another, whereas tank mixing of different formulations can result in undesirable combinations of adjuvants.

[0230] A. Typical Formulation Examples a) Dusts are obtained by mixing 10 parts by weight of the active compound (A) or (B) or the active compound mixture (A)+(B) (and optionally further active compound components) and / or their salts and 90 parts by weight of talc as inert substance and grinding in a beater mill.

[0231] b) A wettable powder readily dispersible in water is obtained by mixing 25 parts by weight of active compound / active compound mixture, 64 parts by weight of kaolin-containing quartz as inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleoyl methyl taurate as wetting and dispersing agent and grinding the mixture in a pin-disk mill.

[0232] c) A dispersion concentrate which is readily dispersible in water is obtained by mixing 20 parts by weight of the active compound / active compound mixture with 6 parts by weight of an alkylphenol polyglycol ether (Triton® X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range, for example, about 255-277° C.) and grinding the mixture in a friction ball mill to a fineness of less than 5 microns.

[0233] d) An emulsifiable concentrate is obtained from 15 parts by weight of active compound / active compound mixture, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier.

[0234] e) Water-dispersible granules: 75 parts by weight of active compound / active compound mixture, 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol, and 7 parts by weight of kaolin are mixed, the mixture is milled in a pin disc mill, and the powder is granulated in a fluidized bed by spraying water as the granulating liquid.

[0235] f) Water-dispersible granules also have 25 parts by weight of active compound / active compound mixture, 5 parts by weight of sodium 2,2'-dinaphthylmethane-6,6'-disulfonate, 2 parts by weight of sodium oleoyl methyl taurate, 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate, and 50 parts by weight of water, is obtained by homogenizing and pre-grinding in a colloid mill, then grinding the mixture in a bead mill, and spraying and drying the resulting suspension through a one-phase nozzle in a spray tower.

[0236] B. Biological Examples When applying the combination of the present invention, it is often observed that the herbicidal effect on harmful plant species exceeds the formal sum of the effects of the herbicides present when applied alone.Or in some cases, it is possible to observe that the application rate of the combination of herbicides is less than that of the individual preparations to achieve the same effect on harmful plant species.Such an increase in action or increase in effectiveness or a decrease in application rate is a strong indicator of synergistic effect.

[0237] When the observed efficacies exceed the formal sum of the values ​​of the tests with the individual applications, they also exceed the predicted values ​​according to Colby, calculated using the following formula and also considered as an index of synergy (see SR Colby; in Weeds 15 (1967) p. 20-22):

number

[0238] Observations from experiments with suitable low doses (E A ) indicates the effect of the combination beyond Colby's expected value (Δ).

[0239] 1. Post-emergence action against weeds Seeds or rhizome pieces of monocotyledonous and dicotyledonous weeds are placed in sandy loam in pots, covered with soil and grown in a greenhouse under good growing conditions (temperature, air humidity, water supply). Three weeks after sowing, the test plants are treated with the compositions according to the invention at the three-leaf stage. The compositions according to the invention, formulated as spray powders or emulsifiable concentrates, are sprayed on the green plant parts in various doses, with application rates of 300-800 l / ha of water (equivalent). After leaving the test plants in the greenhouse for about 3-4 weeks under optimal growing conditions, the action of the preparations is visually evaluated in comparison with untreated controls. The compositions according to the invention also have good post-emergence herbicidal activity against a wide range of economically important grass and broadleaf weeds.

[0240] The effect of the combination according to the invention is often observed here to exceed the formal sum of the effects in the case of the individual application of the herbicides. The values ​​observed from the experiments given the suitable low doses show the effect of the combination exceeding the values ​​expected by Colby.

[0241] 2. Herbicidal pre-emergence and post-emergence action (field test) The experiment was carried out in an outdoor plot following the greenhouse conditions from section 1. The evaluation was carried out similarly to the experiment in section 1.

[0242] 3. Herbicidal activity and crop plant compatibility (field test) Crop plants were grown in outdoor plots under natural outdoor conditions, either by laying out seeds or rhizome pieces of typical harmful plants or by utilizing the natural weed fauna. Treatment with the compositions of the invention was carried out after harmful plants and crops had emerged, generally at the 2-4 leaf stage; in some cases (as specified), individual active compounds or combinations of active compounds were applied pre-emergence or partially as pre-emergence and / or post-emergence successive treatments.

[0243] In the case of plantation crops, generally only the soil between the individual crop plants was treated with the active compound.

[0244] After application (e.g., 2, 4, 6 and 8 weeks after application), the effect of the preparation was visually evaluated by comparison with untreated control. The composition according to the invention also has synergistic herbicidal activity in field tests against a wide range of economically important grass weeds and broadleaf weeds. The comparison shows that the combination according to the invention usually has a herbicidal effect that is greater than the sum of the effects of the individual herbicides, and in some cases significantly greater, thus indicating synergy. The effect over a significant portion of the evaluation period also exceeds the expected value according to Colby, thus also indicating synergy. In contrast, crop plants are only slightly, if at all, damaged as a result of treatment with the herbicidal composition.

[0245] 4. Specific Test Examples The following abbreviations are used in the descriptions and tables that follow: g ai / ha = grams of active substance (=100% active compound) per hectare; The sum of the impacts of each application is E A reported in; The expected values ​​according to Colby are E C will be reported.

[0246] The biological results of the compositions according to the invention are summarized in Tables 3.1-3.2. Evaluation periods are reported in days after application (DAT).

[0247] Table 3.1: Synergistic effect (Δ) of herbicidal binary compositions containing herbicides from group B2 applied by the post-emergence method

[0248] [Table 40]

[0249] [Table 41]

[0250]

Table 42

[0251]

Table 43

[0252]

Table 44

[0253]

Table 45

[0254]

Table 46

[0255]

Table 47

[0256]

Table 48

[0257]

Table 49

[0258]

Table 50

[0259]

Table 51

[0260]

Table 52

[0261]

Table 53

[0262]

Table 54

[0263]

Table 55

[0264]

Table 56

[0265]

Table 57

[0266]

Table 58

[0267]

Table 59

[0268]

Table 60

[0269]

Table 61

[0270]

Table 62

[0271]

Table 63

[0272]

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[0273]

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[0274]

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[0275]

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[0276]

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[0277]

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[0278]

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[0279]

Table 71

[0280]

Table 72

[0281]

Table 73

[0282]

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[0283]

Table 75

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[0285]

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[0286]

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Table 79

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Table 80

[0289]

Table 81

[0290]

Table 82

[0291]

Table 83

[0292]

Table 84

[0293]

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[0294]

Table 86

[0295]

Table 87

[0296]

Table 88

[0297]

Table 89

[0298]

Table 90

[0299]

Table 91

[0300]

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[0301]

Table 93

[0302]

Table 94

[0303]

Table 95

[0304]

Table 96

[0305]

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[0306]

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[0308]

Table 100

[0309]

Table 101

[0310] [Table 102]

[0311] [Table 103] TIFF0007657715000158.tif70150

[0312] Table 3.2: Synergistic effect (Δ) of herbicidal binary compositions containing herbicides from group B7 applied by the post-emergence method [Table 104]

[0313] [Table 105]

[0314] [Table 106]

[0315] [Table 107]

[0316] [Table 108]

[0317] [Table 109]

[0318] [Table 110]

[0319]

Table 111

[0320]

Table 112

[0321]

Table 113

[0322]

Table 114

[0323]

Table 115

[0324]

Table 116

[0325]

Table 117

[0326]

Table 118

[0327]

Table 119

[0328]

Table 120

[0329]

Table 121

[0330]

Table 122

[0331]

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[0332]

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Table 128

[0337]

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[0338]

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[0339]

Table 131

[0340]

Table 132

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[0342]

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[0343]

Table 135

[0344]

Table 136

[0345]

Table 137

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Table 138

[0347]

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[0348]

Table 140

[0349]

Table 141

[0350]

Table 142

[0351]

Table 143

[0352]

Table 144

[0353]

Table 145

[0354]

Table 146

[0355]

Table 147

[0356]

Table 148

[0357]

Table 149

[0358]

Table 150

[0359]

Table 151

[0360]

Table 152

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Table 153

[0362]

Table 154

[0363]

Table 155

[0364]

Table 156

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Table 157

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Table 158

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Table 159

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Table 160

[0369]

Table 161

[0370]

Table 162

[0371]

Table 163

[0372]

Table 164

[0373]

Table 165

[0374]

Table 166

[0375]

Table 167

[0376]

Table 168

[0377]

Table 169

[0378]

Table 170

[0379]

Table 171

[0380]

Table 172

[0381]

Table 173

[0382]

Table 174

[0383]

Table 175

[0384]

Table 176

[0385]

Table 177

[0386]

Table 178

[0387]

Table 179

[0388]

Table 180

[0389]

Table 181

[0390]

Table 182

[0391]

Table 183

[0392]

Table 184

[0393]

Table 185

[0394]

Table 186

[0395]

Table 187

[0396]

Table 188

[0397]

Table 189

[0398]

Table 190

[0399]

Table 191

[0400]

Table 192

[0401]

Table 193

[0402]

Table 194

[0403]

Table 195

[0404]

Table 196

[0405]

Table 197

[0406]

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[0407]

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[0408]

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[0409]

Table 201

[0410]

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[0411]

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[0412]

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[0413]

Table 205

[0414]

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[0415]

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[0416]

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[0417]

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[0419]

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[0421]

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[0422]

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[0423]

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[0424]

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[0425]

Table 217

[0426]

Table 218

[0427]

Table 219

[0428]

Table 220

[0429]

Table 221

[0430]

Table 222

[0431]

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[0432]

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[0436]

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[0437]

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[0438]

Table 230

Claims

1. A composition comprising herbicidally active compounds (A) and (B), wherein (A) is selected from A1, A2, A3, A4 and A5, or a pesticidal salt of these compounds; where A1 to A5 are defined as follows: 【Table 1】 and, (B) is selected from: The composition.

2. 2. The herbicidal composition according to claim 1, comprising the active compound components (A) and (B) in a weight ratio of 1:15000 to 500:

1.

3. 3. The herbicidal composition according to any of claims 1 to 2, comprising one or more further components from the group comprising other types of active crop protection compounds.

4. A herbicidal composition according to any one of claims 1 to 3, which comprises one or more additives customary in crop protection.

5. A method for controlling harmful plants or regulating the growth of plants, which comprises applying an active compound component of the herbicidal composition according to any one of claims 1 to 4 to a plant, a plant part, a plant seed, or an area under cultivation.

6. 6. The method according to claim 5, wherein the active compound components of the herbicidal composition are applied to the plant, plant part, plant seed or area under cultivation by pre-emergence, post-emergence or pre- and post-emergence methods, together or separately.

7. 7. The method according to claim 6, wherein the herbicide component (A) is applied at an application rate of 0.01 to 1000 g a.i. / ha.

8. 7. The method according to claim 6, wherein the herbicide component (B) is applied at an application rate of 0.01 to 4000 g a.i. / ha.

9. The method according to any one of claims 6 to 8 for controlling harmful plants by treatment of crop plants before sowing and in plantation crops, as well as in non-arable lands.

10. 10. The method according to claim 6, wherein the active compounds of the herbicidal composition are applied in the form of a herbicidal composition comprising one or more additives customary in crop protection, optionally after dilution with water.

11. Use of the herbicidal composition according to any one of claims 1 to 4 for controlling harmful plants or for regulating the growth of plants.

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