Anhydrous composition for caring for and / or making up keratinous materials - Patents.com

Abstract

A liquid, anhydrous composition for the care and / or make-up of keratinous materials, comprising: a) at least one organopolysiloxane elastomer powder coated with a silicone resin; b) at least one organopolysiloxane elastomer carried in a first oil; c) at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate; and d) at least one second oil which is a volatile hydrocarbon oil, the composition being free of waxes and comprising more than 15 wt.% of filler relative to the total mass of the composition.

Description

[Technical field]

[0001] The present invention relates to a composition for caring for and / or making up keratinous materials. More particularly, the present invention relates to an anhydrous composition for caring for and / or making up keratinous materials. The present invention also relates to a cosmetic method for caring for and / or making up keratinous materials. [Background technology]

[0002] The development of dedicated formulations for making up and / or caring for the skin and / or lips, which have satisfactory properties in terms of application, comfort, in particular non-greasyness, good coverage and in terms of makeup effect, is a continuing objective.

[0003] Lipstick has become a necessity and is perceived by users as the overwhelmingly predominant application method for caring for and / or making up the lips of the user. Lipstick can modify the facial features of the user. For example, thin lips can be made thicker and thick lips can be made thin. Besides modifying the shape of the lips, lipstick can be made in a multitude of colors and shades to promote a desired effect or express the wearer's mood.

[0004] However, some lipsticks are not easy to apply and the deposits produced are not sufficiently matte.

[0005] Compositions for making up the skin or lips in fluid form, conventionally called glosses in the context of making up the lips, are also known, which are generally devoid of waxes and conventionally comprise at least one non-volatile oil with a molecular weight above 600 g / mol.

[0006] However, the deposits produced by such liquid compositions are generally relatively shiny and / or have a greasy feel on the lips, which can be a source of discomfort for the user.

[0007] On the other hand, some cosmetic products for caring for and / or making up keratinous materials are unable to provide good coverage, which is undesirable.

[0008] There is therefore still a need for compositions for caring for and / or making up keratin materials, and in particular the lips, that are easy to apply and are capable of providing a matte deposit and a light feel. [Prior art documents] [Patent documents]

[0009] [Patent Document 1] U.S. Patent No. 5,538,793 [Patent Document 2] U.S. Patent No. 5,236,986 [Patent Document 3] U.S. Patent No. 5412004 [Patent Document 4] U.S. Patent No. 5,837,793 [Patent Document 5] U.S. Patent No. 5,811,487 [Patent Document 6] International Publication No. 2008 / 155059 [Patent Document 7] European Patent Application Publication No. 1086683 [Non-patent literature]

[0010] [Non-Patent Document 1] Publication: "International Cosmetic Ingredient Dictionary and Handbook", 1997 edition, pages 371-386 and 524-528, published by "The Cosmetic, Toiletries and Fragrance Association" Summary of the Invention [Problem to be solved by the invention]

[0011] The object of the present invention is therefore to develop a composition for caring for and / or making up keratinous materials, and in particular the lips, which is easy to apply and capable of providing a matte deposit and a sensation of light weight.

[0012] Another object of the present invention is to provide a cosmetic method for caring for and / or making up keratinous substances, such as the skin and the lips, in particular the lips, which results in a matte deposit with a light feel on the keratinous substances. [Means for solving the problem]

[0013] Thus, according to a first aspect, the invention relates to a liquid, anhydrous composition for the care and / or make-up of keratinous materials, comprising: a) at least one organopolysiloxane elastomer powder coated with a silicone resin; b) at least one organopolysiloxane elastomer carried in a first oil; c) at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate; and d) at least one second oil which is a volatile hydrocarbon oil; The composition comprises:

[0014] According to a second aspect, the invention provides a cosmetic method for caring for and / or making up keratinous materials, comprising the step of applying to the keratinous materials an anhydrous composition as defined above.

[0015] It has been found that the anhydrous compositions according to the invention are easy to apply and are capable of providing a matte deposit and a feeling of light weight.

[0016] Other objects and features, aspects and advantages of the present invention will become even more apparent on reading the following description and examples. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0017] As used herein, unless otherwise indicated, the limits of a range of values ​​are included within the range, particularly in the expressions "between" and "to."

[0018] As used herein, the term "comprising" is to be interpreted as embracing all specifically mentioned features as well as optionally additional unspecified features.

[0019] As used herein, use of the term "comprising" also discloses embodiments in which no features are present other than those specifically stated (i.e., "consisting of").

[0020] As used in this application, the term "at least one" is equivalent to the term "one or more."

[0021] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. If the definition of a term in this description conflicts with the meaning as commonly understood by one of ordinary skill in the art to which this invention belongs, the definition set forth herein shall prevail.

[0022] Unless otherwise specified, all numbers expressing quantities of ingredients and the like used in the description and claims are understood to be modified by the term "about." Accordingly, unless indicated to the contrary, the numbers and parameters set forth herein are approximations that can be varied as needed depending upon the desired performance to be obtained.

[0023] For the purposes of the present invention, the term "anhydrous" means that the composition according to the invention contains less than 2 wt.%, preferably less than 0.5 wt.%, of water relative to the total mass of the composition. Where appropriate, such small amounts of water may be contributed by components of the composition which contain it in residual amounts, but are not contributed intentionally.

[0024] The term "wax" is understood to mean a lipophilic compound that is solid at ambient temperature (25°C), undergoes a reversible solid / liquid state change and has a melting point above 30°C, which can range up to 120°C.

[0025] All percentages in this application refer to percentages by weight unless otherwise specified.

[0026] As used herein, the term "keratinous material" refers to the skin and lips. "Skin" is intended to mean all body skin, including the scalp. Preferably, the keratinous material is the lips.

[0027] The anhydrous composition according to the invention comprises a) at least one organopolysiloxane elastomer powder coated with a silicone resin; b) at least one organopolysiloxane elastomer carried in a first oil; c) at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate; and d) at least one second oil which is a volatile hydrocarbon oil; and comprising more than 15 wt.% of a filler relative to the total weight of the composition, and not comprising any wax.

[0028] Preferably, the composition according to the invention does not comprise a pasty compound.

[0029] The term "pasty fatty substance" is intended to denote lipophilic fatty compounds which undergo a reversible solid / liquid phase change, which exhibit an anisotropic crystalline structure in the solid state and which comprise a liquid fraction and a solid fraction at a temperature of 23° C.

[0030] Silicone resin coated organopolysiloxane elastomer powder According to a first aspect of the present invention, the anhydrous composition comprises at least one organopolysiloxane elastomer powder coated with a silicone resin, in particular a silsesquioxane resin, as described, for example, in U.S. Pat. No. 5,538,793, the contents of which are incorporated by reference.

[0031] Such elastomer powders are sold by Shin-Etsu Chemical Co., Ltd. under the names KSP-100, KSP-101, KSP-102, KSP-103, KSP-104 and KSP-105 and have the INCI name: Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer.

[0032] Preferably, the silicone resin coated organopolysiloxane elastomer powder is a compound having the INCI name: Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer.

[0033] Advantageously, the organopolysiloxane elastomer powder coated with a silicone resin is present in the composition of the invention in an amount ranging from 0.5 wt.% to 10 wt.%, preferably from 1 wt.% to 8 wt.%, more preferably from 2 wt.% to 5 wt.%, relative to the total mass of the composition.

[0034] An organopolysiloxane elastomer carried in a first oil According to a first aspect of the invention, the anhydrous composition comprises at least one organopolysiloxane elastomer (also called silicone elastomer), in particular in the form of an organopolysiloxane elastomer gel, carried in a first oil.

[0035] Preferably, the first oil is a silicone oil and / or a hydrocarbon oil, which is preferably non-volatile.

[0036] Preferably, the composition comprises at least one organopolysiloxane elastomer carried in at least one non-volatile silicone oil having the INCI name Dimethicone.

[0037] The term "organopolysiloxane elastomer" or "silicone elastomer" refers to a soft, deformable organopolysiloxane that has viscoelastic properties, especially the consistency of a sponge or soft sphere. Its elastic modulus is such that the material resists deformation and has limited elongation and contraction capabilities. The material is able to return to its original shape after stretching.

[0038] It is more particularly a crosslinked silicone elastomer.

[0039] The silicone elastomer particles are carried in the form of a gel formed from an elastomeric organopolysiloxane contained in at least one hydrocarbon oil and / or one silicone oil.

[0040] In these gels, the organopolysiloxane particles are often non-spherical particles.

[0041] Non-emulsifying organopolysiloxane elastomer Thus, the organopolysiloxane elastomer can be obtained by a crosslinking addition reaction between a diorganopolysiloxane containing at least one silicon-bonded hydrogen and a diorganopolysiloxane containing an ethylenically unsaturated group bonded to silicon, especially in the presence of a platinum catalyst; or by a dehydrogenation crosslinking condensation reaction between a diorganopolysiloxane containing hydroxyl end groups and a diorganopolysiloxane containing at least one silicon-bonded hydrogen, especially in the presence of an organotin; or by a crosslinking condensation reaction between a diorganopolysiloxane containing hydroxyl end groups and a hydrolyzable organopolysiloxane; or by thermal crosslinking of the organopolysiloxane, especially in the presence of an organic peroxide catalyst; or by crosslinking of the organopolysiloxane via high-energy radiation, such as gamma radiation, ultraviolet light or an electron beam.

[0042] Preferably, the organopolysiloxane elastomer is obtained by a crosslinking addition reaction of (A) a diorganopolysiloxane, each containing at least two silicon-bonded hydrogens, with (B) a diorganopolysiloxane, each containing at least two silicon-bonded ethylenically unsaturated groups, especially in the presence of (C) a platinum catalyst.

[0043] In particular, organopolysiloxane elastomers can be obtained by reaction of a dimethylpolysiloxane containing dimethylvinylsiloxy end groups with a methylhydrogenopolysiloxane containing trimethylsiloxy end groups in the presence of a platinum catalyst.

[0044] Compound (A) is the base reactant for the formation of elastomeric organopolysiloxanes, and crosslinking occurs via an addition reaction of compound (A) with compound (B) in the presence of catalyst (C).

[0045] Compound (A) is in particular an organopolysiloxane containing in each molecule at least two hydrogen atoms bonded to different silicon atoms.

[0046] Compound (A) may have any molecular structure, in particular a linear or branched chain structure or a cyclic structure.

[0047] Compound (A) may have a viscosity in the range of 1 to 50,000 centistokes at 25° C., particularly so as to be miscible with compound (B).

[0048] The organic groups bonded to the silicon atoms of compound (A) may be alkyl groups, such as methyl, ethyl, propyl, butyl, octyl; substituted alkyl groups, such as 2-phenylethyl, 2-phenylpropyl, or 3,3,3-trifluoropropyl; aryl groups, such as phenyl, tolyl, xylyl; substituted aryl groups, such as phenylethyl; and substituted monovalent hydrocarbon groups, such as epoxy groups, carboxylate groups, or mercapto groups.

[0049] Compound (A) may therefore be chosen from methylhydrogenopolysiloxanes containing trimethylsiloxy end groups, dimethylsiloxane-methylhydrogenosiloxane copolymers containing trimethylsiloxy end groups, and dimethylsiloxane-methylhydrogenosiloxane cyclic copolymers.

[0050] Compound (B) is advantageously a diorganopolysiloxane containing at least two lower alkenyl groups (e.g. C2-C4), which can be selected from vinyl, allyl and propenyl groups. These lower alkenyl groups can be located at any position of the organopolysiloxane molecule, but are preferably located at the ends of the organopolysiloxane molecule. Organopolysiloxane (B) can have a branched, linear, cyclic or network structure, but a linear structure is preferred. Compound (B) can have a viscosity ranging from a liquid state to a rubber state. Preferably, compound (B) has a viscosity of at least 100 centistokes at 25°C.

[0051] In addition to the alkenyl groups mentioned above, other organic groups bonded to silicon atoms in compound (B) may be alkyl groups, such as methyl, ethyl, propyl, butyl, or octyl; substituted alkyl groups, such as 2-phenylethyl, 2-phenylpropyl, or 3,3,3-trifluoropropyl; aryl groups, such as phenyl, tolyl, or xylyl; substituted aryl groups, such as phenylethyl; and substituted monovalent hydrocarbon groups, such as epoxy groups, carboxylic acid ester groups, or mercapto groups.

[0052] The organopolysiloxane (B) may be selected from methylvinylpolysiloxanes, methylvinylsiloxane-dimethylsiloxane copolymers, dimethylpolysiloxanes containing dimethylvinylsiloxy end groups, dimethylsiloxane-methylphenylsiloxane copolymers containing dimethylvinylsiloxy end groups, dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane copolymers containing dimethylvinylsiloxy end groups, dimethylsiloxane-methylvinylsiloxane copolymers containing trimethylsiloxy end groups, dimethylsiloxane-methylphenylsiloxane-methylvinylsiloxane copolymers containing trimethylsiloxy end groups, methyl(3,3,3-trifluoropropyl)polysiloxanes containing dimethylvinylsiloxy end groups, and dimethylsiloxane-methyl(3,3,3-trifluoropropyl)siloxane copolymers containing dimethylvinylsiloxy end groups.

[0053] In particular, organopolysiloxane elastomers can be obtained by reaction of a dimethylpolysiloxane containing dimethylvinylsiloxy end groups with a methylhydrogenopolysiloxane containing trimethylsiloxy end groups in the presence of a platinum catalyst.

[0054] According to another alternative form, compound (B) may be an unsaturated hydrocarbon compound containing at least two lower alkenyl groups (e.g. C2-C4), which may be selected from vinyl, allyl and propenyl groups. These lower alkenyl groups may be located at any position in the molecule, but are preferably located at the terminals. As an example, hexadiene, especially 1,5-hexadiene, may be mentioned.

[0055] Advantageously, the sum of the number of ethylenic groups per molecule in compound (B) and the number of hydrogen atoms bonded to silicon atoms per molecule in compound (A) is at least 5.

[0056] Compound (A) is advantageously added in an amount such that the molar ratio between the total amount of hydrogen atoms bonded to silicon atoms in compound (A) and the total amount of all ethylenically unsaturated groups in compound (B) is within the range of 1.5 / 1 to 20 / 1.

[0057] Compounds (C) are catalysts for the crosslinking reaction and are especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, platinum black and platinum on supports.

[0058] The catalyst (C) is preferably added as clean platinum metal in an amount of 0.1 to 1000 parts by weight, better still 1 to 100 parts by weight, per 1000 parts by weight of the total amount of compounds (A) and (B).

[0059] The elastomer is advantageously a non-emulsifying elastomer.

[0060] The term "non-emulsifying" defines organopolysiloxane elastomers that do not contain any hydrophilic chains, in particular that do not contain any polyoxyalkylene units (especially polyoxyethylene or polyoxypropylene) or polyglyceryl units.

[0061] The organopolysiloxane elastomeric particles are preferably delivered in the form of a gel formed from an elastomeric organopolysiloxane contained in at least one hydrocarbon oil and / or one silicone oil, as defined below, in which the organopolysiloxane particles may be spherical or non-spherical particles.

[0062] Spherical non-emulsifying elastomers which can be used include, for example, those sold under the names DC 9040, DC 9041, DC 9509, DC 9505 by Dow Corning.

[0063] Also usable are those sold by Shin-Etsu Chemical Co., Ltd. under the names KSG-6, KSG-15, KSG-16, KSG-18, KSG-41, KSG-42, KSG-43 and KSG-44, by Grant Industries under the names Gransil SR 5CYC Gel, Gransil SR DMF 10 Gel and Gransil SR DC556 Gel from Gransil RPS, and by General Electric under the names 1229-02-167, 1229-02-168 and SFE 839.

[0064] According to a preferred embodiment, the composition according to the invention comprises, as organopolysiloxane elastomer borne in oil, a preferably spherical non-emulsifying elastomer, preferably chosen from the compounds sold under the names DC 9040, DC 9041, DC 9509, DC 9505 by Dow Corning.

[0065] According to one particular embodiment, the elastomer can be used in a mixture with a cyclic silicone oil.Examples that may be mentioned are mixtures of crosslinked organopolysiloxane / cyclopentasiloxane or crosslinked organopolysiloxane / cyclohexasiloxane, such as Gransil RPS D5 or Gransil RPS D6 from Grant Industries.

[0066] Emulsifying organopolysiloxane elastomer According to another embodiment, the composition according to the invention comprises, as the oil-borne organopolysiloxane elastomer, an emulsifying elastomer.

[0067] The term "emulsifying organopolysiloxane elastomer" means an organopolysiloxane elastomer that contains at least one hydrophilic chain, such as polyoxyalkylenated organopolysiloxane elastomers and polyglycerolated silicone elastomers.

[0068] The emulsifying organopolysiloxane elastomer can be selected from polyoxyalkylenated organopolysiloxane elastomers.

[0069] Polyoxyalkylenated organopolysiloxane elastomers are crosslinked organopolysiloxane elastomers obtainable by crosslinking addition reaction of diorganopolysiloxanes containing at least one silicon-bonded hydrogen with polyoxyalkylenes containing at least two ethylenically unsaturated groups.

[0070] Preferably, the polyoxyalkylenated organopolysiloxane elastomer is obtained by crosslinking addition reaction of diorganopolysiloxanes (A1) each containing at least two silicon-bonded hydrogens with polyoxyalkylenes (B1) containing at least two ethylenically unsaturated groups, especially in the presence of a platinum catalyst (C1), as described, for example, in U.S. Pat. Nos. 5,236,986 and 5,412,004.

[0071] In particular, the organopolysiloxanes can be obtained by reaction of polyoxyalkylenes containing dimethylvinylsiloxy end groups (especially polyoxyethylene and / or polyoxypropylene) with methylhydrogenopolysiloxanes containing trimethylsiloxy end groups in the presence of a platinum catalyst.

[0072] The organic groups bonded to the silicon atoms of compound (A1) may be alkyl groups containing 1 to 18 carbon atoms, such as methyl, ethyl, propyl, butyl, octyl, decyl, dodecyl (or lauryl), myristyl, cetyl, or stearyl; substituted alkyl groups, such as 2-phenylethyl, 2-phenylpropyl, or 3,3,3-trifluoropropyl; aryl groups, such as phenylethyl; and substituted monovalent hydrocarbon groups, such as an epoxy group, a carboxylate group, or a mercapto group.

[0073] Thus, compound (A1) can be selected from methylhydrogenopolysiloxanes containing trimethylsiloxy end groups, dimethylsiloxane-methylhydrogenosiloxane copolymers containing trimethylsiloxy end groups, dimethylsiloxane-methylhydrogenosiloxane-cyclic copolymers, dimethylsiloxane-methylhydrogenosiloxane-laurylmethylsiloxane copolymers containing trimethylsiloxy end groups.

[0074] Compounds (C1) are catalysts for the crosslinking reaction, especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, platinum black and platinum on supports.

[0075] Advantageously, the polyoxyalkylenated organopolysiloxane elastomers can be formed from divinyl compounds, particularly polyoxyalkylenes containing at least two vinyl groups which react with the Si-H bonds of the polysiloxane.

[0076] Polyoxyalkylenated elastomers are described, inter alia, in US Pat. No. 5,236,986, US Pat. No. 5,412,004, US Pat. No. 5,837,793 and US Pat. No. 5,811,487, the contents of which are incorporated by reference.

[0077] Polyoxyalkylenated organopolysiloxane elastomers which can be used include those sold under the designations KSG-21, KSG-20, KSG-30, KSG-31, KSG-32, KSG-33, KSG-210, KSG-310, KSG-320, KSG-330 and KSG-340 by Shin-Etsu Chemical Co., Ltd., and DC9010 and DC9011 by Dow Corning.

[0078] The emulsifying organopolysiloxane elastomer can also be selected from polyglycerolized organopolysiloxane elastomers.

[0079] The polyglycerolated organopolysiloxane elastomers according to the invention are organopolysiloxane elastomers obtainable by crosslinking addition reaction, especially in the presence of a platinum catalyst, of a diorganopolysiloxane containing at least one hydrogen bonded to silicon with a polyglycerolated compound containing ethylenically unsaturated groups.

[0080] Preferably, the organopolysiloxane elastomer is obtained by a crosslinking addition reaction of (A2) a diorganopolysiloxane, each containing at least two hydrogens bonded to silicon, with (B2) a glycerolated compound containing at least two ethylenically unsaturated groups, especially in the presence of (C2) a platinum catalyst.

[0081] In particular, the organopolysiloxanes can be obtained by reaction, in the presence of a platinum catalyst, of a polyglycerolated compound containing dimethylvinylsiloxy end groups with a methylhydrogenopolysiloxane containing trimethylsiloxy end groups.

[0082] Compound (A2) is the base reactant for the formation of organopolysiloxane elastomers, and crosslinking is carried out by addition reaction of compound (A2) with compound (B2) in the presence of catalyst (C2).

[0083] Compounds (A2) are in particular organopolysiloxanes which contain in each molecule at least two hydrogen atoms bonded to different silicon atoms.

[0084] Compound (A2) can have any molecular structure, in particular a linear or branched chain structure or a cyclic structure.

[0085] Compound (A2) may have a viscosity in the range of 1 to 50,000 centistokes at 25° C., in particular so as to be miscible with compound (B2).

[0086] The organic group bonded to the silicon atom in compound (A2) may be an alkyl group containing 1 to 18 carbon atoms, such as methyl, ethyl, propyl, butyl, octyl, decyl, dodecyl (or lauryl), myristyl, cetyl, or stearyl; a substituted alkyl group, such as 2-phenylethyl, 2-phenylpropyl, or 3,3,3-trifluoropropyl; an aryl group, such as phenyl, tolyl, or xylyl; a substituted aryl group, such as phenylethyl; and a substituted monovalent hydrocarbon group, such as an epoxy group, a carboxylate group, or a mercapto group.

[0087] Preferably, the organic groups are selected from methyl, phenyl and lauryl groups.

[0088] Thus, compound (A2) can be selected from methylhydrogenopolysiloxanes containing trimethylsiloxy end groups, dimethylsiloxane-methylhydrogenosiloxane copolymers containing trimethylsiloxy end groups, dimethylsiloxane-methylhydrogenosiloxane cyclic copolymers, and dimethylsiloxane-methylhydrogenosiloxane-laurylmethylsiloxane copolymers containing trimethylsiloxy end groups.

[0089] The compound (B2) is represented by the following formula (B'): C m H 2m-1 -O-[Gly] n -C m H 2m-1(B') In the formula, m is an integer ranging from 2 to 6, n is an integer ranging from 2 to 200, preferably ranging from 2 to 100, preferably ranging from 2 to 50, preferably ranging from 2 to 20, preferably ranging from 2 to 10, preferentially ranging from 2 to 5, in particular, n is equal to 3, and Gly is -CH2-CH(OH)-CH2-O- or -CH2-CH(CH2OH)-O- (Indicating The polyglycerolated compound may also correspond to the following:

[0090] Advantageously, the sum of the number of ethylenic groups per molecule in compound (B2) and the number of hydrogen atoms bonded to silicon atoms per molecule in compound (A2) is at least four.

[0091] Compound (A2) is advantageously added in an amount such that the molecular ratio between the total amount of hydrogen atoms bonded to silicon atoms in compound (A2) and the total amount of all ethylenically unsaturated groups in compound (B2) falls within the range of 1 / 1 to 20 / 1.

[0092] Compounds (C2) are catalysts for the crosslinking reaction, especially chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, platinum black and platinum on supports.

[0093] The catalyst (C2) is preferably added as clean platinum group metal in an amount of 0.1 to 1000 parts by weight, better still 1 to 100 parts by weight, per 1000 parts by weight of the total amount of compounds (A2) and (B2).

[0094] The polyglycerolated organopolysiloxane elastomers are carried in the form of gels in at least one hydrocarbon oil and / or one silicone oil, in which the polyglycerolated elastomers are often in the form of non-spherical particles.

[0095] Polyglycerolized organopolysiloxane elastomers which can be used include those sold by Shin-Etsu Chemical Co., Ltd. under the designations KSG-710, KSG-810, KSG-820, KSG-830 and KSG-840.

[0096] Preferably, the silicone elastomer carried in the first oil is non-emulsifying and preferably lacks hydrophilic chains, in particular lacks polyoxyalkylene and polyglyceryl units.

[0097] Advantageously, the organopolysiloxane elastomers considered according to the invention are chosen from spherical non-emulsifying organopolysiloxane elastomers, polyglycerolized organopolysiloxane elastomers and polyoxyalkylenated organopolysiloxane elastomers.

[0098] Advantageously, the organopolysiloxane elastomer considered according to the invention is chosen from spherical non-emulsifying organopolysiloxane elastomers.

[0099] More specifically, the organopolysiloxane elastomer is obtained by the crosslinking addition reaction of (A) a diorganopolysiloxane, each containing at least two silicon-bonded hydrogens, with (B) a diorganopolysiloxane, each containing at least two silicon-bonded ethylenically unsaturated groups, in the presence of, inter alia, a platinum catalyst (C).

[0100] Thus, the composition comprises an organopolysiloxane elastomer carried in a non-volatile oil in combination with at least one organopolysiloxane elastomer powder coated with a silicone resin.

[0101] Preferably, the type of organopolysiloxane elastomer carried in the first oil is selected from dimethicone / vinyl dimethicone crosspolymer, dimethicone crosspolymer, and mixtures thereof.

[0102] Advantageously, the organopolysiloxane elastomer carried in the first oil is present in the composition of the invention in a total solids content ranging from 2 wt.% to 20 wt.%, preferably from 4 wt.% to 15 wt.%, more preferably from 6 wt.% to 10 wt.%, relative to the total mass of the composition.

[0103] In the composition according to the invention, the organopolysiloxane elastomer carried in the first oil and the organopolysiloxane elastomer powder coated with a silicone resin are present in a mass ratio, on a dry basis, of organopolysiloxane elastomer carried in the first oil (i.e., the total solids content of the organopolysiloxane elastomer carried in the first oil) / organopolysiloxane elastomer powder coated with a silicone resin (i.e., the total content of the organopolysiloxane elastomer coated with a silicone resin) of greater than 2, preferably greater than 2.5.

[0104] The organopolysiloxane elastomer carried in the first oil and the silicone resin-coated organopolysiloxane elastomer powder are present in a dry basis weight ratio of first oil-borne organopolysiloxane elastomer (i.e., total solids content of the organopolysiloxane elastomer carried in the oil) / silicone resin-coated organopolysiloxane elastomer powder (i.e., total content of the organopolysiloxane elastomer coated with the silicone resin) between 2 and 5, preferably between 2.5 and 4.

[0105] Advantageously, the composition according to the invention comprises a total content of organopolysiloxane elastomer (i.e. = organopolysiloxane elastomer carried in the first oil + organopolysiloxane elastomer powder coated with silicone resin) ranging from 2.5 wt.% to 30 wt.%, more preferably from 5 wt.% to 25 wt.%, more preferably from 8 wt.% to 15 wt.%, relative to the total mass of the composition.

[0106] The inventors have discovered that the combination of an organopolysiloxane elastomer carried in a first oil and an organopolysiloxane elastomer powder coated with a silicone resin can impart a matte and soft-focus finish to keratinous materials.

[0107] Filler According to a first aspect of the invention, the anhydrous composition comprises at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate, and comprises more than 15 wt.% of the filler relative to the total weight of the composition.

[0108] The term "fillers" should be understood to mean colorless inorganic or organic particles of any shape that are insoluble in the medium of the composition, regardless of the temperature at which the composition is prepared.

[0109] Talc, mica, silica, kaolin, bentone, fumed silica particles, optionally hydrophilically or hydrophobically treated, polyamide (Nylon®) powders (Orgasol® from Atochem, SP-500 from Toray Industries, Inc. (Dow Corning)), poly-β-alanine powders and polyethylene powders, tetrafluoroethylene polymer (Teflon®) powders, lauroyl lysine, starch, boron nitride, hollow polymer microspheres, such as polyvinylidene chloride / acrylonitrile microspheres, such as Expancel® (Nobel Industrie), acrylic acid copolymer microspheres (Polytrap® from Dow Corning) and silicone resin microbeads (e.g. Tospearls® from GE Toshiba Silicones), precipitated calcium carbonate, magnesium carbonate, basic magnesium carbonate, hydroxyapatite, hollow silica microspheres (Silica® from Maprecos) Beads®), glass or ceramic microcapsules (calcium aluminum borosilicate), and metal soaps derived from organic carboxylic acids containing 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms, such as zinc stearate, magnesium stearate, lithium stearate, zinc laurate or magnesium myristate.

[0110] They may also be particles comprising a copolymer, said copolymer comprising trimethylolhexyllactone, in particular it may be a hexamethylene diisocyanate / trimethylolhexyllactone copolymer.

[0111] Such particles are commercially available, for example, under the name Plastic Powder D-400® or Plastic Powder D-800® from Toshoku Pigment Co., Ltd.

[0112] Preferably, in addition to polymethylsilsesquioxane and calcium aluminum borosilicate, the composition according to the invention comprises at least one other filler selected from talc, mica, silica, polyamide powder, copolymers containing trimethylolhexyllactone, preferably hexamethylene diisocyanate / trimethylolhexyllactone copolymers and mixtures thereof.

[0113] More preferably, the composition comprises polymethylsilsesquioxane and calcium aluminum borosilicate, and at least one other filler selected from talc, mica, silica, polyamide powder, hexamethylene diisocyanate / trimethylol hexyllactone copolymer, and mixtures thereof.

[0114] In some preferred embodiments, the composition comprises, relative to the total weight of the composition, 0.1 wt.% to 5 wt.%, preferably 1 wt.% to 4 wt.%, of polymethylsilsesquioxane, and 0.1 wt.% to 5 wt.%, preferably 0.1 wt.% to 0.5 wt.%, of calcium aluminum borosilicate.

[0115] The inventors have found that polymethylsilsesquioxane and calcium aluminum borosilicate can enhance the matte and soft focus benefits while enhancing the glide properties of the compositions according to the present invention.

[0116] Advantageously, the at least two fillers comprising polymethylsilsesquioxane and calcium aluminium borosilicate are present in the composition of the invention in an amount ranging from 15 wt.% to 30 wt.%, preferably from 15 wt.% to 25 wt.%, more preferably from 15 wt.% to 20 wt.%, relative to the total mass of the composition.

[0117] Volatile Hydrocarbon Oils According to a first aspect of the invention, the anhydrous composition comprises at least one second oil which is a volatile hydrocarbon oil.

[0118] An "oil" differs from the pasty compounds or waxes described in this invention, in that the oils herein are liquid at room temperature (25° C.) and atmospheric pressure (760 mmHg).

[0119] The term "hydrocarbon oil" means an oil essentially formed or even consisting of carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and which does not contain any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0120] The term "volatile oil" means an oil that can evaporate in less than one hour on contact with the skin at room temperature and atmospheric pressure. Volatile oils are cosmetic volatile oils that are liquid at room temperature. More specifically, volatile oils have a viscosity of from 0.01 to 200 mg / cm, inclusive. 2 / min.

[0121] To measure this evaporation rate, 15 g of the oil or oil mixture to be tested is placed in a crystallizing dish of 7 cm diameter and cooled to 35° C. in a thermostatically controlled room at 25° C. and a humidity-controlled room at 50% relative humidity. 3 The oil or mixture is placed on a balance in a large chamber of 10 ... 2 ) and mg of oil evaporated per unit time (min).

[0122] The volatile hydrocarbon oil suitable for the present invention can be selected from hydrocarbon oils having from 7 to 16 carbon atoms. The volatile hydrocarbon oil can be selected from branched alkanes and linear alkanes.

[0123] Volatile hydrocarbon oils having 7 to 16 carbon atoms that may be mentioned in particular include branched C8-C 16 Alkanes, e.g. C8-C 16 Isoalkanes (also known as isoparaffins), isododecane, isodecane, isohexadecane, and oils sold, for example, under the trade names Isopar or Permethyl, branched C8-C 16 Esters such as isohexyl neopentanoate, and mixtures thereof. Preferably, the volatile hydrocarbon oil having 7 to 16 carbon atoms is selected from isododecane, isodecane and isohexadecane, and mixtures thereof, especially isododecane.

[0124] Volatile hydrocarbon oils that can be used for the purposes of the present invention include linear alkanes, preferably of vegetable origin, containing from 7 to 15 carbon atoms, in particular from 9 to 14 carbon atoms and more particularly from 11 to 13 carbon atoms.

[0125] Examples of linear alkanes suitable for the present invention include n-heptane (C7), n-octane (C8), n-nonane (C9), n-decane (C10), n-undecane (C11), n-dodecane (C12), n-tridecane (C13), n-tetradecane (C14) and n-pentadecane (C15), as well as mixtures thereof, in particular the mixture of n-undecane (C11) and n-tridecane (C13) described in Example 1 of WO 2008 / 155059 by Cognis. Mention may also be made of n-dodecane (C12) and n-tetradecane (C14), sold by Sasol under the references Parafol 12-97 and Parafol 14-97, respectively, as well as mixtures thereof.

[0126] Advantageously, the second oil, i.e. the volatile hydrocarbon oil, is present in the composition of the invention in an amount ranging from 10 wt.% to 40 wt.%, and preferably from 10 wt.% to 25 wt.%, relative to the total mass of the composition.

[0127] Preferably, the composition according to the present invention further comprises at least one of: (i) a non-volatile hydrocarbon oil; (ii) a colorant; and (iii) mixtures thereof.

[0128] Non-volatile hydrocarbon oil Optionally, the anhydrous composition comprises a non-volatile hydrocarbon oil.

[0129] The term "non-volatile oil" means an oil that remains on the skin or on keratin fibers at room temperature and atmospheric pressure. More precisely, a non-volatile oil has a density of exactly 0.01 mg / cm 2 It has an evaporation rate of less than 1 / min.

[0130] Non-volatile hydrocarbon oils suitable for the invention can in particular be chosen from: - Hydrocarbon oils of vegetable origin, such as triglycerides composed of fatty acid esters of glycerol, the fatty acids of which are C4 to C 28 These fatty acids may optionally be linear or branched, saturated or unsaturated, and these oils are in particular wheat germ oil, sunflower oil, beauty-leaf oil, grape seed oil, sesame oil, corn oil, apricot oil, castor oil, shea oil, avocado oil, olive oil, soybean oil, sweet almond oil, cottonseed oil, hazelnut oil, macadamia oil, jojoba oil, palm oil, alfalfa oil, poppy oil, pumpkin oil, mallow oil, rapeseed oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, kukui oil, passionflower oil and musk rose oil, or alternatively caprylic / capric triglycerides, such as those sold by the company Stearineries Dubois or those sold by the company Miglyol by Sasol. Sold under the names 810(R), 812(R) and 818(R); - synthetic ethers having 10-40 carbon atoms; linear or branched hydrocarbons of mineral or synthetic origin, such as liquid paraffin, liquid petrolatum, naphthalene oil, polybutylenes, such as Indopol H-100 (molar mass or W=965 g / mol), Indopol H-300 (MW=1340 g / mol) and Indopol H-1500 (MW=2160 g / mol) sold or manufactured by the company Amoco, polyisobutenes, hydrogenated polyisobutenes, such as Parleam® or Panalane H-300 E (MW=1340 g / mol) sold or manufactured by the company Amoco, Viseal 20000 (MW=6000 g / mol) sold or manufactured by the company Synteal and Rewopal PIB sold or manufactured by the company Witco; 1000 (MW=1000 g / mol), decene / butene copolymers, polybutene / polyisobutene copolymers, especially Indopol L-14, polydecene and hydrogenated polydecenes, such as Puresyn 10 (MW=723 g / mol) and Puresyn 150 (MW=9200 g / mol) sold or manufactured by Mobil Chemicals, and mixtures thereof; synthetic esters and / or ethers, for example oils of the formula R1COOR2 and / or R1OR2, where R1 represents a residue of a linear or branched fatty acid containing 1 to 40 carbon atoms and R2 represents a hydrocarbon chain, in particular a branched hydrocarbon chain, containing 1 to 40 carbon atoms, with the proviso that the total carbon number of R1+R2 is ≧10, such as, for example, PureCellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, butyl stearate, C12-C15 alkyl benzoates, hexyl laurate, diisopropyl adipate, isononyl isononanoate, palmitic acid 2-ethylhexyl, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecyl myristate or lactate, 2-diethylhexyl succinate, isostearyl isostearate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, for example propylene glycol dioctanoate, hydroxylated esters, for example isostearyl lactate and diisostearyl malate, lanolic, oleic, lauric or stearic acid esters, glyceryl or diglyceryl triisostearate, and pentaerythritol esters; aliphatic alcohols which are liquid at room temperature and contain a branched and / or unsaturated carbon chain having from 12 to 26 carbon atoms, such as cetanol, octyldodecanol, stearyl alcohol, linoleyl alcohol, linolenyl alcohol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2-butyloctanol or 2-undecylpentadecanol; fatty acids such as myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid; and - A mixture of these.

[0131] Preferably, the non-volatile hydrocarbon oil is selected from isostearyl isostearate, diisostearyl malate, hydrogenated polyisobutene, and mixtures thereof.

[0132] Advantageously, when present, the non-volatile hydrocarbon oils are present in the composition of the invention in an amount ranging from 10% to 40% by weight, and preferably from 10% to 25% by weight, relative to the total weight of the composition.

[0133] coloring agent The solid anhydrous composition according to the invention may optionally comprise at least one colorant. Preferably, the amount of colorant is less than 20 wt.% relative to the total weight of the composition.

[0134] For purposes of the present invention, the term "colorant" means a compound capable of producing a colored optical effect when incorporated in a suitable cosmetic medium in sufficient amount.

[0135] The colorants considered in the context of the present invention can be chosen from water-soluble or water-insoluble, fat-soluble or non-fat-soluble, organic or inorganic colorants, and materials with optical effects, as well as mixtures thereof.

[0136] water soluble dye The water-soluble colorants used according to the invention are more particularly water-soluble dyes.

[0137] For the purposes of the present invention, the term "water-soluble dye" refers to any natural or synthetic, generally organic compound that is soluble in an aqueous phase or in a water-miscible solvent and capable of imparting color. In particular, the term "water-soluble" is intended to characterize the ability of a compound to dissolve in water to a concentration at least equal to 0.1 g / l (producing a macroscopically isotropic, transparent, colored or colorless solution), measured at 25° C. This solubility is in particular equal to or greater than 1 g / l.

[0138] Suitable water-soluble dyes for use in the present invention include, in particular, synthetic or natural water-soluble dyes such as FD&C Red 4 (CI:14700), DC Red 6 (Lithol Rubine Na; CI:15850), DC Red 22 (CI:45380), DC Red 28 (CI:45410 Na salt), DC Red 30 (CI:73360), DC Red 33 (CI:17200), DC Orange 4 (CI:15510), FDC Yellow 5 (CI:19140), FDC Yellow 6 (CI:15985), DC Yellow 8 (CI:45350 Na salt), FDC Green 3 (CI:42053), DC Green 5 (CI:61570), FDC Blue 1 (CI:42090).

[0139] Non-limiting examples of sources of water-soluble colorants that can be used in the context of the present invention include, in particular, those of natural origin, such as extracts of cochineal carmine, beet root, grapes, carrot, tomato, annatto, paprika, henna, caramel and curcumin.

[0140] Thus, water-soluble colourants suitable for use in the present invention are, in particular, carminic acid, betanin, anthocyanin, enocyanin, lycopene, β-carotene, bixin, norbixin, capsanthin, capsorubin, flavoxanthin, lutein, cryptoxanthin, rubixanthin, violaxanthin, riboflavin, rhodoxanthin, canthaxanthin and chlorophyll, and mixtures thereof.

[0141] These may also be copper sulfate, ferrous sulfate, water-soluble sulfopolyesters, rhodamine, betaine, methylene blue, the disodium salt of tartrazine and the disodium salt of fuchsin.

[0142] Some of these water-soluble colouring agents are specifically approved for food use. Representatives of these dyes that may be mentioned include, more particularly, the dyes of the carotenoid family, referenced in the food codes E120, E162, E163, E160a-g, E150a, E101, E100, E140 and E141.

[0143] Pigments The term "pigments" should be understood to mean white or colored inorganic (mineral) or organic particles, which are insoluble in the liquid organic phase and are intended to color and / or opacify the composition and / or the deposit produced with the composition.

[0144] The pigments may be selected from mineral pigments, organic pigments and composite pigments (i.e. pigments based on mineral and / or organic materials).

[0145] The pigments may be selected from monochrome pigments, lakes and pigments with optical effects, such as goniochromatic pigments and pearlescent agents.

[0146] The mineral pigments may be selected from metal oxide pigments such as chromium oxide, iron oxide (black, yellow, red), titanium dioxide, zinc oxide, cerium oxide and zirconium oxide, chromium hydrate, manganese violet, Prussian blue, ultramarine blue, ferric blue, synthetic fluorphlogopite, metal powders such as aluminum powder and copper powder, and mixtures thereof.

[0147] Organic lakes are organic pigments formed from a dye bound to a substrate.

[0148] The lakes, also known as organic pigments, can be chosen from the following substances and mixtures thereof: - Cochineal carmine; - organic pigments, which are azo dyes, anthraquinone dyes, indigoid dyes, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes or fluoran dyes.

[0149] Among the organic pigments that may be mentioned in particular are the following names: D&C Blue No. 4, D&C Brown No. 1, D&C Green No. 5, D&C Green No. 6, D&C Orange No. 4, D&C Orange No. 5, D&C Orange No. 10, D&C Orange No. 11, D&C Red No. 6, D&C Red No. 7, D&C Red No. 17, D&C Red No. 21, D&C Red No. 22, D&C Red No. 27, D&C Red No. 28, D&C Red No. 30, D&C Red No. 31, D&C Red No. 33, D&C Red No. 34, D&C Red No. 36, D&C Violet No. 2, D&C Yellow No. 7, D&C Yellow No. 8, D&C Yellow No. 10, D&C Yellow No. 11, FD&C Blue No. 1, FD&C Green No. 3, FD&C Red Some are known as No. 40, FD&C Yellow No. 5, and FD&C Yellow No. 6; The organic lakes may be insoluble sodium, potassium, calcium, barium, aluminum, zirconium, strontium or titanium salts of acid dyes, optionally containing at least one carboxylic or sulfonic acid group, such as azo, anthraquinone, indigoid, xanthene, pyrene, quinoline, triphenylmethane or fluoran dyes.

[0150] The organic lake may also be supported on an organic support, such as rosin or aluminum benzoate.

[0151] Among the organic lakes, the following names are available: D&C Red No. 2 Aluminum Lake, D&C Red No. 3 Aluminum Lake, D&C Red No. 4 Aluminum Lake, D&C Red No. 6 Aluminum Lake, D&C Red No. 6 Barium Lake, D&C Red No. 6 Barium / Strontium Lake, D&C Red No. 6 Strontium Lake, D&C Red No. 6 Potassium Lake, D&C Red No. 7 Aluminum Lake, D&C Red No. 7 Barium Lake, D&C Red No. 7 Calcium Lake, D&C Red No. 7 Calcium / Strontium Lake, D&C Red No. 7 Zirconium Lake, D&C Red No. 8 Sodium Lake, D&C Red No. 9 Aluminum Lake, D&C Red No. 9 Barium Lake, D&C Red No. 9 Barium / Strontium Lake, D&C Red No. 9 Zirconium Lake, D&C Red No.10 Sodium Lake, D&C Red No.19 Aluminum Lake, D&C Red No.19 Barium Lake, D&C Red No.19 Zirconium Lake, D&C Red No.21 Aluminum Lake, D&C Red No.21 Zirconium Lake, D&C Red No.22 Aluminum Lake, D&C Red No.27 Aluminum Lake, D&C Red No.27 Aluminum / Titanium / Zirconium Lake, D&C Red No.27 Barium Lake, D&C Red No.27 Calcium Lake, D&C Red No.27 Zirconium Lake, D&C Red No.28 Aluminum Lake, D&C Red No.30 Lake, D&C Red No.31 Calcium Lake, D&C Red No.33 Aluminum Lake, D&C Red No.34 Calcium Lake, D&C Red No.36 Lake, D&C Red No.40 Aluminum Lake, D&C Blue No.1 Aluminum Lake, D&C Green No.3 Aluminum Lake, D&C Orange No.4 Aluminum Lake, D&C Orange No.5 Aluminum Lake, D&C Orange No.5 Zirconium Lake, D&C Orange No.Mention may in particular be made of those known as FD&C Blue No. 1 Aluminum Lake, FD&C Red No. 4 Aluminum Lake, FD&C Red No. 40 Aluminum Lake, FD&C Yellow No. 5 Aluminum Lake and FD&C Yellow No. 6 Aluminum Lake.

[0152] Mention may also be made of liposoluble dyes such as Sudan Red, DC Red 17, DC Green 6, β-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5 and quinoline yellow.

[0153] The chemicals corresponding to each of the organic dyes listed above are referenced in the publication "International Cosmetic Ingredient Dictionary and Handbook", 1997 Edition, pages 371-386 and 524-528, published by "The Cosmetic, Toiletries and Fragrance Association", the contents of which are incorporated by reference into this patent application.

[0154] The pigment may also be subjected to a hydrophobic treatment.

[0155] The hydrophobic treatment agent may be selected from silicones such as methicone, dimethicone, alkoxysilanes and perfluoroalkylsilanes; fatty acids such as stearic acid; metal soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamic acid, perfluoroalkyl phosphates, perfluoroalkylsilanes, perfluoroalkylsilazanes, polyhexafluoropropylene oxide, polyorganosiloxanes and amino acids containing perfluoroalkylperfluoropolyether groups; N-acylamino acids or salts thereof; lecithin, isopropyl triisostearyl titanate, and mixtures thereof.

[0156] The N-acyl amino acid may contain an acyl group containing 8 to 22 carbon atoms, such as 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl or cocoyl groups. The salts of these compounds may be aluminum, magnesium, calcium, zirconium, zinc, sodium or potassium salts. The amino acid may be, for example, lysine, glutamic acid or alanine.

[0157] The term "alkyl" referred to in the compounds listed above specifically denotes alkyl groups containing from 1 to 30 carbon atoms, preferably from 5 to 16 carbon atoms.

[0158] Hydrophobically treated pigments are described, inter alia, in EP-A-1 086 683.

[0159] Pearlizing Agent For the purposes of this patent application, the term "pearlescent agent" refers to colored particles of any shape, which may or may not be iridescent, particularly produced by certain mollusks in their shells or alternatively synthesized, and which have a color effect via optical interference.

[0160] Examples of pearlescent agents that may be mentioned include pearlescent pigments, such as titanium mica coated with iron oxide, mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with organic dyes, in particular of the type mentioned above, and also pearlescent pigments based on bismuth oxychloride.

[0161] They may also be mica particles on whose surface at least two successive layers of metal oxides and / or organic colorants are superimposed.

[0162] The pearlescent agent may more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or copper color or hue.

[0163] Examples of pearlescent agents which may be introduced as interference pigments in the first composition include the gold-colored pearlescent agents sold in particular under the names Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica) and Monarch gold 233X (Cloisonne); the bronze-colored pearlescent agents sold in particular under the names Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) by Merck and under the name Super bronze (Cloisonne) by BASF; the orange-colored pearlescent agents sold in particular under the names Orange 363C (Cloisonne) by BASF and under the names Passion orange (Colorona) and Matte orange (17449) (Microna) by Merck; the Nu-antique copper 340XB (Cloisonne) and Brown (17449) (Microna) by Engelhard; a pearlescent agent having a brown shade, sold in particular under the name CL4509 (Chromalite); a pearlescent agent having a copper shade, sold in particular under the name Copper 340A (Timica) by BASF; a pearlescent agent having a red shade, sold in particular under the name Sienna fine (17386) (Colorona) by Merck; a pearlescent agent having a yellow shade, sold in particular under the name Yellow (4502) (Chromalite) by BASF; a red pearlescent agent having a golden shade, sold in particular under the name Sunstone G012 (Gemtone) by BASF; a pink pearlescent agent sold in particular under the name Tan opale G005 (Gemtone) by BASF;Mention may be made of the black pearlescent agent with a golden hue, sold in particular under the name Nu antique bronze 240 AB (Timica) by BASF, the blue pearlescent agent sold in particular under the name Matte blue (17433) (Microna) by Merck, the white pearlescent agent with a silvery hue, sold in particular under the name Xirona Silver by Merck, and the gold-green pink-orange pearlescent agent sold in particular under the name Indian summer (Xirona) by Merck, and mixtures thereof;

[0164] According to a preferred embodiment, the colorants used in the present invention are selected from metal oxide pigments, organic lakes, synthetic or natural water-soluble dyes and mixtures thereof.

[0165] According to certain preferred embodiments, the colorants used in the present invention are selected from YELLOW 6 Lake, Blue 1 Lake, RED 28 Lake, RED 21, RED 7, titanium dioxide, iron oxide, synthetic fluorophlogopite and mixtures thereof.

[0166] When present, the colorant is present in an amount ranging from 1 wt.% to 20 wt.%, preferably from 2 wt.% to 10 wt.%, relative to the total weight of the composition.

[0167] Other Ingredients The solid anhydrous composition according to the invention may further comprise other ingredients commonly used in the fields under consideration.

[0168] For example, the solid anhydrous composition according to the present invention may further comprise other ingredients selected from thickeners, antioxidants (e.g., tocopherol, tocopheryl acetate, pentaerythrityl tetra-di-t-butyl hydroxyhydrocinnamate), film formers (e.g., trimethylsiloxysilicate), preservatives, antimicrobials (e.g., capryly glycol, ethylhexylglycerin), fragrances, neutralizing agents, preservatives, additional cosmetic actives such as vitamins, collagen protectants, and mixtures thereof.

[0169] It is routine for a person skilled in the art to adjust the nature and amounts of other components present in the compositions according to the invention so that the beneficial properties of the compositions used according to the invention are not adversely affected, or are not substantially adversely affected, by the envisaged addition.

[0170] According to a preferred embodiment, the present invention provides a composition comprising, relative to the total weight of the composition: a) 2 wt.% to 5 wt.% vinyl dimethicone / methicone silsesquioxane crosspolymer, b) 6 wt.% to 10 wt.% of an organopolysiloxane elastomer carried in a first oil selected from dimethicone / vinyl dimethicone crosspolymer, dimethicone crosspolymer, and mixtures thereof; c) 15 wt.% to 20 wt.% of at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate, and other fillers selected from talc, mica, silica, polyamide powder, hexamethylene diisocyanate / trimethylol hexyllactone copolymer, and mixtures thereof; d) 10 wt.% to 25 wt.% of a volatile hydrocarbon oil selected from isododecane, isodecane and isohexadecane, and mixtures thereof; e) 10 wt.% to 25 wt.% of a non-volatile hydrocarbon oil selected from isostearyl isostearate, diisostearyl malate, hydrogenated polyisobutene, and mixtures thereof; and f) 2wt.% to 10wt.% of a coloring agent selected from YELLOW 6 Lake, Blue 1 Lake, RED 28 Lake, RED 21, RED 7, titanium dioxide, iron oxide, synthetic fluorophlogopite, and mixtures thereof. and is free of wax and pasty compounds.

[0171] Galenic form The composition of the present invention is suitable for use as a skin care and / or makeup product. More particularly, the composition of the present invention is a liquid lip balm.

[0172] The compositions according to the invention may be prepared in a conventional manner.

[0173] According to a second aspect, the present invention provides a cosmetic method for the care / make-up of keratinous materials, comprising the step of applying to the keratinous materials a solid anhydrous composition as defined above.

[0174] In particular, the keratinous material is the lips.

[0175] The following examples are given as non-limiting illustrations of the invention. EXAMPLES

[0176] The main raw materials used, their trade names and suppliers are listed in Table 1.

[0177] [Table 1]

[0178] (Inventive Example 1 and Comparative Examples 1-2) Inventive Example (IE.) 1 and Comparative Examples (CE.) 1-2 liquid lip compositions were prepared from the components listed in Table 2.

[0179] [Table 2]

[0180] Preparation procedure: The detailed procedures for preparing the above compositions are as follows, taking composition 1 as an example: 1) In the first step, the pigment is milled in a three-roll mill in a portion of the oil phase (hydrogenated polyisobutene, diisostearyl malate, isostearyl isostearate and pentaerythrityl tetra-di-t-butyl hydroxyhydrocinnamate); 2) then mixing the remainder of the oil soluble ingredients with the remaining oil phase and ground color material until a homogeneous mixture is obtained; 3) adding the organopolysiloxane elastomer to the above mixture with stirring, then incorporating the ground pigment material into the mixture and continuing homogenization until the mixture is homogenous; 4) Add fillers, film formers, co-preservatives, antioxidants, actives, and flavors with stirring until uniform; 5) Finally, the resulting composition was poured into small pots and then left at ambient temperature for 24 hours.

[0181] evaluation: The prepared compositions were evaluated for spreadability, gloss and weight.

[0182] Spreadability Spreadability is used to evaluate whether a lip composition can glide easily and smoothly on the lips during application.

[0183] The spreadability was evaluated by five experts by slowly applying the lip composition twice on each side to the upper lip using the same force, while carefully feeling the force between the lip composition and the lips during the second application. The lower the friction force, the better the spreadability.

[0184] Shine and weight Gloss is used to evaluate the degree of light reflection or brightness on the lips under standard lighting.

[0185] Weight is used to assess the sensation of mass on the lips imparted by a lip product, which is the sensation of the lips being weighed down and unable to breathe freely.

[0186] Gloss and weight were evaluated by five experts by applying the lipstick twice on both sides to the upper lip using the same force. After application, the lips were not moved for 3 minutes, and the degree of light reflection or brightness was checked in the center of the upper lip under standard light, and the weight was also checked at the same time. The lower the light reflection or brightness, the lower the gloss and the better the matte effect. The lower the weight, the better.

[0187] Finally, the experts gave comments or scores on spreadability, gloss and weight based on the following criteria and took the average: 5: Very good 4: Generally good 3:Acceptable 2: Somewhat insufficient, unacceptable 1: Insufficient, unacceptable

[0188] The evaluation results for each lip composition are summarized in Table 3.

[0189] [Table 3]

[0190] It can be seen that the lip compositions of the invention examples have good spreadability and can provide a matte and light deposition on keratinous materials.

Claims

1. A liquid, anhydrous composition for the care and / or make-up of keratinous materials, comprising: a) at least one organopolysiloxane elastomer powder coated with a silicone resin; b) at least one organopolysiloxane elastomer carried in a first oil; c) at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate; and d) at least one second oil which is a volatile hydrocarbon oil; %, wherein the composition is free of wax and comprises more than 15 wt.% of a filler, based on the total weight of the composition.

2. 10. The composition of claim 1, which is free of pasty compounds.

3. 3. The composition according to claim 1, wherein the organopolysiloxane elastomer is a crosslinked adduct of (A1) a diorganopolysiloxane containing at least two ethylenically unsaturated groups bonded to silicon, and (B1) a diorganopolysiloxane each containing at least two hydrogens bonded to silicon.

4. 4. The composition of claim 1, wherein the organopolysiloxane elastomer powder coated with a silicone resin is a vinyl dimethicone / methicone silsesquioxane crosspolymer.

5. 5. The composition according to claim 1, wherein the organopolysiloxane elastomer powder coated with a silicone resin is present in an amount ranging from 0.5 wt.% to 10 wt.%, relative to the total weight of the composition.

6. 6. The composition of claim 1, wherein the type of organopolysiloxane elastomer carried in the first oil is selected from dimethicone / vinyl dimethicone crosspolymer, dimethicone crosspolymer, and mixtures thereof.

7. 7. The composition according to claim 1, wherein the organopolysiloxane elastomer carried in the first oil is present in the composition of the present invention in an amount ranging from 2 wt.% to 20 wt.%, relative to the total weight of the composition.

8. 8. The composition according to claim 1, wherein the non-powder type organopolysiloxane elastomer and the silicone resin-coated organopolysiloxane elastomer powder are present in a weight ratio of between 2 and 5.

9. 9. The composition according to claim 1, comprising, relative to the total mass of the composition, 0.1 wt.% to 5 wt.% of polymethylsilsesquioxane and 0.1 wt.% to 5 wt.% of calcium aluminum borosilicate.

10. 10. The composition of claim 1, further comprising at least one other filler selected from talc, mica, silica, polyamide powder, copolymers containing trimethylolhexyllactone, and mixtures thereof.

11. 11. The composition according to any one of claims 1 to 10, wherein the at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate are present in an amount ranging from 15 wt.% to 30 wt.%, relative to the total weight of the composition.

12. 12. The composition according to claim 1, wherein the second oil is present in an amount ranging from 10 wt.% to 40 wt.%, relative to the total weight of the composition.

13. 13. The composition of claim 1, further comprising at least one of: (i) a non-volatile hydrocarbon oil; (ii) a hydrophilic moisturizer; (iii) a colorant; and (iv) mixtures thereof.

14. Relative to the total weight of the composition, a) 2 wt.% to 5 wt.% vinyl dimethicone / methicone silsesquioxane crosspolymer; b) 6 wt.% to 10 wt.% of an organopolysiloxane elastomer selected from dimethicone / vinyl dimethicone crosspolymer, dimethicone crosspolymer, and mixtures thereof, carried in a first oil; c) 15 wt.% to 20 wt.% of at least two fillers comprising polymethylsilsesquioxane and calcium aluminum borosilicate, and other fillers selected from talc, mica, silica, polyamide powder, hexamethylene diisocyanate / trimethylol hexyllactone copolymer, and mixtures thereof; d) 10 wt.% to 25 wt.% of a volatile hydrocarbon oil selected from isododecane, isodecane and isohexadecane, and mixtures thereof; e) 10 wt.% to 25 wt.% of a non-volatile hydrocarbon oil selected from isostearyl isostearate, diisostearyl malate, hydrogenated polyisobutene, and mixtures thereof; and f) 2wt.% to 10wt.% of a coloring agent selected from YELLOW 6 Lake, Blue 1 Lake, RED 28 Lake, RED 21, RED 7, titanium dioxide, iron oxide, synthetic fluorophlogopite, and mixtures thereof. and is free of waxes and pasty compounds.

15. A cosmetic method for caring for and / or making up keratinous materials, comprising the step of applying to said keratinous materials a composition according to any one of claims 1 to 14.

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