Pest Monitoring System with Conductive Electrodes

The pest monitoring system addresses the challenge of accurate pest detection by using a circuit with conductive electrodes and a control unit to measure electrical properties, transforming from a high to a low impedance state upon pest interaction, thus enhancing detection accuracy and pest control effectiveness.

JP7670756B2Active Publication Date: 2025-04-30BASF CORPORATON
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Patent Information

Application Number
JP2023100833
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Priority Date
2018-05-11
Filing Date
2023-06-20
Publication Date
2025-04-30
Estimated Expiration
2038-07-06

AI Technical Summary

Technical Problem

Conventional pest monitoring systems face challenges in accurately detecting the presence or absence of pests, often resulting in false detections or missed detections, which can lead to ineffective pest control and potential damage.

Method used

A pest monitoring system that includes a circuit with conductive electrodes and a control unit, which measures electrical properties to determine the presence or absence of pests. The system transforms from a high impedance state to a low impedance state when pests interact with the electrodes, allowing for accurate detection.

Benefits of technology

The system effectively identifies the presence or absence of pests, reducing the risk of false detections and improving the likelihood of timely pest control, thereby minimizing damage and ensuring accurate monitoring.

✦ Generated by Eureka AI based on patent content.

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Abstract

To provide a pest monitoring system which quickly identifies the presence or absence of pests, increases the likelihood of controlling pests, minimizes the risk of damage, and reduces false indications of pest presence or absence.SOLUTION: The pest monitoring system generally includes a circuit, where the circuit is initially in a first impedance state that is configured to change to a second impedance state due to pest activity, where the second impedance state is lower than the first impedance state.SELECTED DRAWING: Figure 2A
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Description

[Technical field]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS This application claims the benefit of U.S. Provisional Patent Application No. 62 / 529,681, filed July 7, 2017, U.S. Provisional Patent Application No. 62 / 544,428, filed August 11, 2017, and U.S. Provisional Patent Application No. 62 / 670,248, filed May 11, 2018, the entire contents of each of which are incorporated herein by reference.

[0002] The present disclosure relates generally to pest monitoring systems, and more particularly, to pest monitoring systems with conductive electrodes. [Background technology]

[0003] Pests can cause damage to raw materials, structures, crops, food, livestock, and other human-related matter. Conventional pest monitoring devices often facilitate the detection, deterrence, and / or eradication of pests by placing an attractant (or bait) that pests tend to chew on for collection and / or consumption.

[0004] Many conventional pest monitoring devices require physical inspection (e.g., manual disassembly) to visually determine whether and to what extent pests are chewing (or devouring) the bait. For example, in current termite monitoring systems, a bait matrix (or matrices) is typically inserted into a physical station housing that is inserted into a cavity in the ground. During foraging, a foraging termite encounters the station, enters the interior of the station housing, and begins consuming one or more edible bait matrices. The bait typically consists of a non-toxic material or a mixture of non-toxic and toxic materials (i.e., pesticide active ingredients).

[0005] Pest monitoring systems can be employed to determine when control treatments should be applied and / or used, such as those disclosed in U.S. Patent No. 5,399,633, the entire contents of which are incorporated herein by reference. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] International Publication No. 2017 / 011574 Summary of the Invention [Problem to be solved by the invention]

[0007] The success of a pest monitoring system in detecting pests (e.g., termites) depends on its ability to identify the presence or absence of the pest. The relative ability of the system to determine the true presence or absence of a pest, without false positives (indication that a pest is present when in fact it is not) or false negatives (indication that a pest is absent when in fact it is), is a key factor for robust and accurate pest presence determination. Improving this system to quickly identify the presence or absence of a pest increases the chances of pest control, minimizes the risk of damage, and reduces false indications of the presence or absence of a pest. [Means for solving the problem]

[0008] In one embodiment, a pest monitoring system generally includes a circuit that is initially in a first impedance state configured to change to a second impedance state upon pest activity, the second impedance state being lower than the first impedance state.

[0009] In another aspect, a pest monitoring system generally includes a circuit, the circuit initially in a first impedance state configured to change to a second impedance state due to pest activity, the second impedance state being lower than the first impedance state, and a control unit configured to determine the presence or absence of a pest based on a measured electrical characteristic of the circuit.

[0010] In yet another aspect, a pest monitoring system generally includes a bait station, with or without bait, and a central device of a connection system for a structure. The assembled bait station includes a circuit that is initially in a first impedance state configured to change to a second impedance state due to pest activity, the second impedance state being lower than the first impedance state. The bait station also includes a control unit configured to transmit a pest presence signal based on the detected change in impedance. The central device is configured to receive the pest presence signal from the bait station. [Brief description of the drawings]

[0011] [Figure 1] FIG. 1 is a schematic diagram of one embodiment of a pest monitoring system. [Figure 2A] FIG. 2 is a bait station of the pest monitoring system of FIG. 1, showing a longitudinal cross-sectional view of the bait station with an electrode assembly. [Figure 2B] FIG. 2 is a longitudinal cross-sectional view of a bait station of the pest monitoring system of the present invention, with a sensor assembly partially connected to the station housing. [Diagram 3] FIG. 2B is a top perspective view of material applied to the electrode assembly of FIG. 2A. [Figure 4] FIG. 1 illustrates a pest monitoring or detection system that uses a magnet to activate a magnetic reed switch on a bait station or data collection system. [Diagram 5] FIG. 13 shows a bait station or data collection system control unit with magnetic reed or ultrasonic switches. [Figure 6] FIG. 2 illustrates an example of a pest monitoring network that provides a communication path for the pest monitoring and detection system of FIG. 1. [Figure 7] FIG. 2 illustrates an example of a data communication path for the pest monitoring and detection system of FIG. 1 as the data is hosted and flows through a connecting network, such as a home security company's data network, to a data management company. [Figure 8] FIG. 8 illustrates another example of a data communication path that differs from the process of FIG. 7 in that an ancillary data management company also receives pest monitoring / detection data. [Figure 9] FIG. 8 illustrates another example of a data communication path that differs from the process of FIG. 7 in that the pest monitoring / detection data is managed by the home security company itself, i.e., without the use of a separate data management company, but that allows data to be forwarded to an ancillary data management company. [Figure 10] FIG. 13 illustrates another example of a data communication path in which station data is received by a gateway via a wireless connection (or a wired connection). [Figure 11] FIG. 11 illustrates another example of a data communication path that differs from the process of FIG. 10 in that a home security company is not involved. [Figure 12] FIG. 13 illustrates another example of a data communication path involving a field inspection using a mobile device as a communication portal to communicate with a gateway. [Figure 13] 2 is a perspective view of exemplary bait matrices that may be used with the pest monitoring system shown in FIG. 1, including conductive and non-conductive bait matrices. [Figure 14] FIG. 14 shows the conductive bait matrix shown in FIG. 13 having a structurally non-uniform surface. [Figure 15] FIG. 14 is a cross-sectional view of the bait matrix shown in FIG. [Figure 16] FIG. 14 is a cross-sectional view of another embodiment of the bait matrix shown in FIG. [Figure 17A] 1 is an enlarged perspective view of an embodiment of a waterproof member of the present invention. [Figure 17B] 1 is an enlarged perspective view of an embodiment of a waterproof member of the present invention. [Figure 18A] 1 is a perspective view of an embodiment of a waterproof member of the present invention. [Figure 18B] FIG. 1 is a perspective view of an embodiment of a waterproof member of the present invention. [Figure 19A] FIG. 1 is a cross-sectional view of one embodiment of the present invention in an assembled state, including a bait matrix and an electrode assembly. [Figure 19B] FIG. 1 is an enlarged perspective cross-sectional view of the present invention including a bait matrix configured with a water-resistant member that holds an electrode assembly therein. [Figure 20] FIG. 2 is a partially transparent perspective enlarged view of one embodiment of the present invention showing the details of the mesh sleeve. [Figure 21] FIG. 2 is a perspective close-up view, partially transparent, of one embodiment of the sensor assembly of the present invention to show power supply details. [Figure 22] FIG. 2 is a perspective close-up view of one embodiment of a sensor assembly of the present invention. [Diagram 23] FIG. 2 is a perspective close-up view of one embodiment of a sensor assembly of the present invention. [Figure 24] FIG. 2 is a perspective close-up view with partial cross-section of one embodiment of a bait station showing a sensor assembly partially connected to a cage frame of the present invention. [Diagram 25] FIG. 2 is a cross-sectional close-up view of one embodiment of a cage frame connected to a sensor assembly of the present invention. [Figure 26] FIG. 2 is a perspective close-up view of one embodiment of a cage frame connected to a sensor assembly of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0012] Corresponding reference characters indicate corresponding parts throughout the several views of the drawings.

[0013] Referring now to the drawings, and in particular to FIG. 1 , a pest monitoring and / or detection system (broadly, a "pest monitoring system") according to one embodiment of the present disclosure is generally indicated by the reference numeral 100. In the illustrated embodiment, system 100 is configured to at least monitor and / or detect, and in some embodiments control, pests such as termites (or other insects / arthropods). However, in other possible embodiments, system 100 may be configured to monitor and / or detect, and in some embodiments control, other pests, including, but not limited to, insects such as cockroaches, ants, etc., rodents such as rats, mice, field mice, etc., birds, bats, etc.

[0014] System 100 can be used to monitor for pests in a variety of applications, including, but not limited to, buildings (e.g., homes, offices, storage facilities, warehouses, etc.), walls, roadways, embankments / dams, shipyards, docks, bridges, railroad tracks, crops (e.g., sugar cane), orchards, groundnuts (e.g., peanuts), and / or any other suitable application.

[0015] The illustrated system 100 includes at least one bait station 102 and a gateway 104 located remotely from the bait station 102 and capable of communicating with the bait station 102 to receive signals from, and in some embodiments, transmit signals to, the bait station 102, as described in more detail below. The expression "bait station" appears throughout this disclosure and should not be construed as requiring a bait component, but should be broadly construed as serving as a housing for the circuitry described herein capable of generating a pest presence signal. As such, a bait station should be considered any housing into which one or more pests may enter to generate a pest presence signal. Similarly, references to a "bait cage" do not necessarily include a bait component. Rather, the "bait cage" serves as a cage frame that contains the electrode assembly and other components of the present invention. The gateway 104 may suitably comprise any suitable configuration of a processor- or microprocessor-based device (such as a computer or microcontroller) with associated memory, or a reduced instruction set circuit (RISC), application specific integrated circuit (ASIC), and / or logic circuit. In other embodiments, the gateway 104 may suitably comprise any circuit and / or processor capable of performing the functions of the gateway 104 described herein. In yet another embodiment, the gateway 104 may be incorporated into a connectivity system, including, but not limited to, a smart home system and / or a home security panel / system. As used herein, the term "signal" is not limited to a particular type of signaling method, but broadly represents any suitable type of (preferably) wireless signaling (e.g., WiFi or cellular). Although only one gateway 104 is shown in FIG. 1, it is understood that multiple gateways 104 may be employed and / or the gateway 104 may be integral to another connectivity system within the structure.

[0016] In the illustrated embodiment, the gateway 104 is disposed in spaced relation to each of the bait stations 102 (though eight bait stations are shown in FIG. 1, any suitable number of bait stations 102 may be used in the system 100), although it will be understood that the gateway 104 may include components of and function as a bait station 102. Thus, in a suitable embodiment, the gateway 104 and one of the bait stations 102 may be incorporated into a common assembly.

[0017] In one possible embodiment, pest monitoring system 100 may include multiple bait stations 102 located at a site (e.g., around a home) where pest activity is to be monitored and / or detected, and gateway 104 may be located remotely from the site and immobile relative to the site and communicate with bait stations 102 from a remote location, as described in more detail below. In another possible embodiment, gateway 104 may be configured for use in the field (e.g., gateway 104 may include suitable handheld equipment (e.g., wireless equipment, etc.) that is movable relative to bait stations 102 and can be used in the field, e.g., by a technician).

[0018] 2A, each bait station 102 includes a sensor assembly, generally designated 108, and optionally a suitable cage frame 101 that encloses and / or houses the bait and electrode assembly as described in more detail herein and is coupled to the sensor assembly 108 prior to operation at a stationary location (e.g., in / above ground). The station housing 109 is configured to allow termites to enter and exit the station housing 109 (e.g., via slits or holes in the station housing) to allow the termites to feed on or move an optional bait matrix 124 disposed within the station housing 109 as described in more detail below. It will be understood that the station housing 109 is not required for all embodiments of the bait station 102 and / or gateway 104. Referring to FIG. 2B, another feature includes the station housing 109 and cap 103 that retain the sensor assembly 108 coupled to the cage frame 101 for ease of transportation, handling, and embedding, as well as for aesthetic purposes.

[0019] The illustrated sensor assembly 108 generally comprises a sensor holder 110, an electrode assembly 126, and a control unit 128. As described in more detail below, the electrode assembly 126 in the illustrated embodiment is adjacent to or surrounded by the bait matrix 124, and the control unit 128 is configured to selectively deliver an electrical stimulus to the electrode assembly 126. Additionally, in certain embodiments, the control unit 128 is operable to transmit a signal indicative of the presence or absence of pests (termites) and / or at least one electrical characteristic of the electrode assembly 126 as a function of the electrical stimulus delivered to the electrode assembly 126. In this manner, the control unit 128 facilitates remote monitoring via the gateway 104, which is operable to receive the signal transmitted by the control unit 128.

[0020] As shown in Figures 17 and 18, a water-resistant member 156 may surround the electrode assembly 126. Figures 17A and 18A show one embodiment. Figures 17B and 18B show alternative embodiments. Thus, the present invention is not intended to be limited to any particular shape or design element. The water-resistant member 156 is preferably constructed of foam and may optionally include one or more points of interest, such as ribs 125, that serve to further enhance pest collection. The water-resistant member 156 surrounds the electrode assembly 126, which in turn is surrounded by the bait matrix 124. The ribs of interest 125 may be longitudinal ribs the length of the water-resistant member 156, as shown in Figure 17A, or may be concentrated in a portion of the water-resistant member 156, such as the bottom or top, as shown in Figures 18A and 18B. Additionally, as shown in more detail in Figures 17 and 18, chamfers 127 and recesses 129 provide additional points of interest for pest collection.

[0021] With reference to FIG. 2A, the illustrated bait matrix 124 is generally tubular (e.g., in the illustrated embodiment, generally cylindrical with an internal passageway) having a first end face 130, a second end face 132, a circumferential outer surface 134, and a circumferential inner surface 136 that defines an internal cavity 137 of the bait matrix 124.

[0022] Although one embodiment is shown as a cylinder, it is understood that the bait matrix 124 may be of other suitable shapes. For example, the bait matrix 124 may have a tubular shape that is not generally cylindrical (e.g., the tubular shape may have a substantially polygonal cross section) and / or the cavity may not extend from the first end 130 to the second end 132. In other suitable embodiments, rather than being tubular, the bait matrix 124 may be generally shaped as a sphere, pyramid, cube, or other suitable shape. Regardless of shape, the bait matrix may include points of interest that promote collection of the bait matrix 124 by pests.

[0023] It will also be understood that the thickness of the tubular bait matrix 124 (i.e., the lateral width from the outer surface 134 to the inner surface 136) shown in Figure 2A is for illustrative purposes only. The thickness of the bait matrix 124 in other suitable embodiments may be substantially greater or less than the thickness shown in the figures. However, the thickness of the bait matrix 124 may be any suitable thickness without departing from the scope of the present invention.

[0024] In one suitable embodiment, the bait matrix 124 can be composed at least in part or entirely of a cellulosic material that can be ingested or moved by termites, such as wood, paper, cardboard, etc. In other suitable embodiments, an agar matrix alone or in combination with sugars (i.e., xylose, mannose, galactose, erythritol, aspartame, saccharin) and / or pure cellulosic materials can be used as the bait matrix 124. It is contemplated that any suitable material that can be ingested or moved by termites can be used as the bait matrix 124 without departing from certain aspects of the present disclosure.

[0025] In the illustrated embodiment, referring to Figure 19A, the electrode assembly 126 is disposed within an internal cavity 137 of the bait matrix 124 such that in some embodiments, the electrode assembly 126 is surrounded by the bait matrix 124. For example, the electrode assembly 126 may be surrounded by, embedded in, sealed in, or encased in the bait matrix 124. In other suitable embodiments, the electrode assembly 126 is disposed at least partially within the internal cavity 137 of the bait matrix 124. In other suitable embodiments, the electrode assembly 126 is disposed next to, above, below, near, around, or any other suitable location relative to the bait matrix 124.

[0026] In one embodiment, the sensor assembly 108 includes a water resistant member 156 (e.g., a water resistant, preferably cross-linked, closed cell foam sleeve) surrounding the electrode assembly 126. Water resistance is generally defined herein as waterproof, moisture resistant, impermeable, and / or water impermeable. The water resistant member 156 is configured to prevent water or moisture from contacting the electrode assembly 126 (and thus causing a false indication of the presence or absence of a pest) until a pest actually penetrates the electrode assembly 126. In this regard, the electrode assembly 126 may be configured with a sensitivity profile that is tailored to minimize additional false positive signaling. In the embodiment shown in FIGS. 2A and 2B, the water resistant member 156 is generally tubular and sized to fit within the interior cavity 137 of the bait matrix 124 defined by the circumferential inner surface 136. In one embodiment, as shown in cross-sectional detail in FIG. 20, an additional mesh sleeve 159 surrounds the water-resistant member 156 to create cylindrical pressure and ensure water-tightness of the internal cavity 137. The mesh sleeve 159 is preferably constructed of polyethylene and provides additional pressure and hoop stress around the water-resistant member to maintain a tight fit within the bait matrix 124. Although the invention should not be considered so limited, the inventors believe that the proximity (i.e., direct contact) of the bait matrix 124 to the water-resistant member 156 increases the likelihood that termites will continue to burrow through the bait matrix 124 and enter the water-resistant member 156, thereby generating a signal. Based on termite behavior, burrowing appears to continue unless or until open space becomes available. Thus, in one embodiment, the bait matrix 124 is configured to be in direct contact with the water-resistant member 156.

[0027] In other suitable embodiments, the water-resistant member 156 may be sized and shaped to receive the electrode assemblies 126 and may be located adjacent to, above, below, near, around, or any other suitable location relative to the bait matrix 124. In the illustrated embodiment, the water-resistant member 156 extends from approximately the first end 130 to the second end 132. However, it will be appreciated that the water-resistant member 156 may be of any suitable size or shape. In one embodiment, the water-resistant member 156 is sealed once the electrode assemblies are configured within the water-resistant member 156. To ensure a water-resistant seal, the water-resistant member 156 is preferably sealed by ultrasonic sealing. The water-resistant member 156 may have a tubular shape that is not generally cylindrical (e.g., the tubular shape may have a substantially polygonal cross-section) and / or the cavity may not extend from the first end 130 to the second end 132. In other suitable embodiments, the water-resistant member 156 may not be tubular but may be generally shaped as a sphere, pyramid, cube, or other suitable shape. In one embodiment, the bait matrix 124 may be constructed using a water-resistant material such that a separate water-resistant member 156 is not required.

[0028] The water-resistant member 156 can be formed from any suitable water-resistant material. For example, the water-resistant member 156 can be formed using a foamed or extruded polymer, such as closed cell extruded polyethylene, expanded polystyrene, expanded polypropylene, or the like. In other examples, the water-resistant member 156 can be a film or coating. For example, in one suitable embodiment, the water-resistant member 156 can be a water-resistant coating applied to the bait matrix 124.

[0029] 2 and 3, the electrode assembly 126 includes a first electrode 144 and a second electrode 148. In one embodiment, the electrodes 144, 148 are elongated strips of conductive material (e.g., copper). In the illustrated embodiment, the electrodes 144, 148 extend parallel to one another and are spaced apart so as not to touch. When attached to the bait station 102, the electrodes 144, 148 extend in a direction substantially perpendicular to the ground in which the bait station 102 is buried. In one suitable embodiment, the electrodes 144, 148 may be generally "U" shaped, with a first portion of the electrodes 144, 148 extending substantially perpendicular to the ground, a second portion of the electrodes 144, 148 extending substantially horizontally to the ground along a bottom surface of the bait station 102, and a third portion of the electrodes 144, 148 extending substantially perpendicular to the ground away from the first portion. In other embodiments, the electrodes 144, 148 may be constructed of any suitable material and may have any suitable shape, configuration, and / or orientation that enables the electrode assembly 126 to function as described herein. As shown in FIG. 19A (longitudinal cross section) and FIG. 19B (perspective cross section), in one embodiment, the electrodes 144, 148 fit tightly against the walls of the water-resistant member 156. In one aspect, a preferred embodiment configures the electrode assembly 126 to be in close proximity to the walls of the water-resistant member 156 so that pests can contact the electrode assembly 126. Thus, regardless of shape, the electrode assembly 126 preferably matches the shape of the water-resistant member 156 and the bait matrix 124. Thus, in this regard, it is preferred that the electrode assembly 126 is semi-rigid and positionable in a finite location so that the bait station 102 can be fully assembled.

[0030] In some suitable embodiments, the electrode assembly 126 includes an electrode track 157 constructed of an electrically insulating material (e.g., a rubber or plastic material), as shown in Figure 2A. The electrode track 157 provides a base to which the first and second electrodes 144, 148 may be attached to ensure proper placement of the electrodes 144, 148 and to prevent the electrodes 144, 148 from contacting one another.

[0031] As shown in FIG. 2A, the first electrode 144 is coupled to a first terminal 160 of a power circuit that transmits a signal to provide an electrical stimulus, and the second electrode 148 is coupled to a second terminal 162 to monitor the status of the sensor assembly 108. Since the electrodes 144, 148 do not contact each other, the circuit defined by the first terminal 160, the first electrode 144, the second terminal 162, and the second electrode 148 is an open circuit. When the circuit is open, a measurement of an electrical property such as impedance returns a very high value approaching infinity. Thus, when the circuit is open, it may be said to be in a "high impedance state." Alternatively, when the bait station 102, and more specifically the bait matrix 124, is harvested by termites, a conductive material (e.g., soil, water, termite excrement, termite saliva secretions, etc.) is placed across the electrodes 144, 148 to complete or close the circuit. If the circuit is a closed circuit, measuring the impedance returns a measurable value. Thus, when the circuit is closed, it may be said to be in a "low impedance state." A low impedance state means that the circuit has an impedance that is lower than the impedance of a circuit in a high impedance state, which approaches infinity. Thus, termite activity within the bait station 102 creates a measurable impedance across a normally open circuit.

[0032] In the illustrated embodiment, the control unit 128 is disposed at least partially within the interior compartment 138 of the sensor holder 110. The control unit 128 is configured to provide a known electrical stimulus to the electrode assembly 126. In one suitable embodiment, the electrical stimulus is an electric current. The control unit 128 may also be operable to transmit, via wires or wirelessly, one or more signals from the bait station 102 to the gateway 104 indicative of at least one of the presence or absence of a pest and / or one or more electrical characteristics (e.g., resistance or reactance) of the electrode assembly 126.

[0033] Control unit 128 may comprise any suitable processor-based device (e.g., a microcontroller with associated memory having executable instructions stored therein) or any suitable arrangement of reduced instruction set circuitry (RISC), application specific integrated circuit (ASIC), and / or logic circuitry, or may suitably comprise any circuitry and / or processor capable of performing the functions of control unit 128 as described herein.

[0034] Additionally, in one suitable embodiment, the control unit 128 may include a suitable power source 139 and functional circuitry (e.g., electrochemical cells, batteries, electronic circuitry, etc.) suitably disposed within the hollow interior compartment 138 of the sensor holder 110 for powering the control unit 128 and / or providing electrical stimulation to the electrode assembly 126 via suitable electrical interconnections. As shown in FIG. 21, in one embodiment, the power source 139 is a coin cell battery 141 to provide robust battery retention for the control unit 128 and to extend the operational life of the assembled bait station 102. The power source 139 is preferably located to minimize RF interference by being spaced or remote from any antennas. In one embodiment, a retaining snap 143 may be used to secure the power source 139 in place and away from the walls of the sensor holder 110 housing the control unit. Additionally, as shown in Figures 22 and 23, it is preferred that the contact pins 145 form the bottom wall of the sensor holder 110, preferably using a crimped retention which is believed to ensure a robust electrical interconnection.

[0035] Alternatively, the power source 139 may be located remotely from the bait station 102 and may be electrically connected in any suitable manner to the control unit 128 and / or electrode assembly 126 (e.g., a number of above or below ground terminals may be available external to the bait station 102 through which a remote power source and / or gateway 104 may be selectively connected to the control unit 128 and / or electrode assembly 126). Alternatively, in a passive system, power may be provided in a signal transmitted by the gateway 104 or another suitable device.

[0036] 2A and 2B, the electrode assembly 126, including electrodes 144, 148 coupled to an electrode track 157, is positioned within the water-resistant member 156 such that the electrodes 144, 148 extend in a substantially vertical direction. The water-resistant member 156 and the electrode assembly 126 disposed therein are placed within the bait matrix 124, which is in turn placed within the station housing 109.

[0037] The control unit 128 and associated power supply 139 are suitably housed within an interior compartment 138 of the sensor holder 110. The sensor holder 110 is configured to be coupled to the station housing 109 using a connection mechanism 140, which may be a threaded connection mechanism, whereby the sensor holder 110 is screwed into the station housing 109. As shown in FIG. 24, one embodiment of the connection mechanism 140 preferably includes a threaded connection mechanism, whereby the connection of the sensor holder 110 to the cage frame 101 compresses a gasket 147, thereby providing an additional water-tight seal to the electrode assembly 126 housed within the cage frame 101. As shown in more detail in FIG. 25, the cage frame 101 may include a channel 149 containing a compressible material 151, such as foam. The sensor holder 110 may include a ribbed ceiling 153 that aligns with the channel 149, and upon connection of the sensor holder 110 to the cage frame 101, the ceiling 153 compresses the compressible material 151, which fills the channel 149 and forms a water-resistant seal. The connection mechanism 140 includes a switch that is closed by the sensor holder 110 being screwed into the station housing 109. When closed, the switch couples the power source 139 to the control unit 128 to facilitate powering on and operating the bait station. Thus, the bait station 102 remains in a powered off state until the sensor holder 110 is screwed into the station housing 109. As shown in FIG. 26, in one embodiment, the sensor holder 110 has a molded stopper 155a at the bottom that is aligned with a corresponding stopper 155b at the top of the cage frame 101. When the sensor holder 110 is screwed into the cage frame 101, the stops 155a and 155b prevent over-rotation that could damage the electrical contacts. Additionally, the stops 155a and 155b provide confirmation to the installer that the connections are secure and the station 102 is assembled. Other embodiments may include visual indicators, audible indicators, or spring-loaded contacts. As shown in FIG. 24, the stops 155a and 155b are located on the perimeter to minimize physical stress on the molded plastic material and provide tighter tolerance control.

[0038] The control unit 128 is operatively connected to the electrodes 144, 148 via a power source 139 and a first terminal 160 and a second terminal 162 of the functional circuit, respectively, so as to selectively provide electrical stimulation to the electrodes 144, 148. The first electrode 144 and the second electrode 148 extend in a parallel direction to each other without any contact. In this manner, with the electrodes 144, 148 coupled to the first terminal 160 and the second terminal 162 of the functional circuit, respectively, a space between the electrodes 144, 148 forms an open circuit.

[0039] The water-resistant member 156 suitably surrounds and protects the electrodes 144, 148. More specifically, the water-resistant member 156 is configured to protect the electrodes 144, 148 from moisture. In some embodiments, as shown in Figures 2A and 2B, both the bait matrix 124 and the water-resistant member 156 surround and protect the electrodes 144, 148.

[0040] Once assembled, the sensor assembly 108 may be deployed without being included in the station housing 109, or may be suitably inserted into a station housing that includes at least a portion of the sensor assembly 108. The sensor assembly 108 may be suitably buried at least partially in the ground at a site where termite activity is suspected or detected without the use of a station housing. However, the illustrated embodiment of the sensor assembly 108 and / or its station housing may be suitably configured to facilitate deployment, monitoring, deterrence, and / or eradication of any suitable type of pest in any suitable manner by above ground deployment. For example, the sensor assembly 108 and / or its station housing may be configured for suitable above ground deployment on soil, on a surface that is generally horizontal with respect to the ground, on a surface that is inclined with respect to the ground, on a mounting surface that is vertical with respect to the ground (such as an interior or exterior wall of a home or building, a tree, a fence post or railing, a crawl space, etc.), or any other suitable above ground location. It will be appreciated that in suitable embodiments, the pest monitoring system 100 may include one or more in-ground bait stations 102, one or more above-ground bait stations 102, and / or a combination of in-ground and above-ground bait stations 102.

[0041] After deployment of the bait station 102, the control unit 128 may be operable to apply an electrical stimulus to the electrodes 144, 148. During or after application of the electrical stimulus to the electrodes 144, 148, the control unit 128 may be operable to measure an electrical characteristic (e.g., resistance or reactance) of the electrode assembly 126 and transmit a signal to the gateway 104 indicative of the presence or absence of a pest and / or the electrical characteristic.

[0042] In one embodiment, the control unit 128 may be configured to operate autonomously in the sense that it is configured to automatically (e.g., scheduled, intermittent) deliver electrical stimulation to the electrodes 144, 148 and measure electrical properties. For example, in one suitable embodiment, the control unit 128 is programmed to generate a status report at a predefined time interval (e.g., once a day, twice a day, once a week, etc.). Information included in the status report may include, but is not limited to, impedance measured low information, station low battery status information, and / or station low signal strength information. The control unit 128 transmits the status report to the gateway 104 according to the predefined time interval. Because the control unit 128 measures the electrical properties and transmits the status report immediately, no storage of data by the control unit is required. In another suitable embodiment, the control unit 128 is configured to transmit a status report signal to the gateway 104 only if the measured electrical properties indicate the presence of a pest.

[0043] In alternative embodiments, the control unit 128 may be configured to perform auxiliary operations under the direction of a suitable remote control system in the sense that the control unit 128 may be configured to provide electrical stimulation to the electrodes 144, 148 and / or transmit associated signals to the gateway 104 when instructed by the remote control system. To this end, some embodiments of the control unit 128 may transmit signals to the gateway 104 in real time (e.g., each time the bait matrix 124 is monitored, or immediately thereafter), while other embodiments of the control unit 128 may store events in its memory that cause it to transmit batch-type signals to the gateway 104 when scheduled or instructed.

[0044] Additionally, in some embodiments, a termite presence threshold may be established as a single reading or measurement of the electrical property. The control unit 128 may store or record the occurrence of a single measurement of the electrical property and transmit the occurrence when requested (i.e., via a timing algorithm, an external request by the gateway 104, etc.). For example, in one suitable embodiment, the control unit 128 may monitor for the presence of termites by checking once a day. Alternatively, a termite presence threshold may be established to require multiple measurements of the electrical property.

[0045] When the illustrated embodiment of the sensor assembly 108 is deployed, the termites locate the bait matrix 124 and the sensor assembly 108. As the termites penetrate the bait matrix 124 and the water-resistant member 156, they remove particles from the bait matrix 124 and the water-resistant member 156 (e.g., by drilling, foraging, eating, digging, moving, or detaching). Some particles may be returned to the nest and / or gallery system for consumption / accumulation. It should be understood that the bait station 102 may include only the bait matrix 124, only the water-resistant member 156, or both the bait matrix 124 and the water-resistant member 156.

[0046] As the termites remove particles from the bait matrix 124 and water resistant member 156, the electrodes 144, 148 are exposed to moisture intrusion and / or termites (see FIG. 3) depositing material 200 across the electrodes 144, 148. Material 200 may include, for example, water, soil, termite excreta, termite saliva secretions, dead termites, etc. The material 200 or moisture disposed across the electrodes 144, 148 closes the open circuit formed by the electrodes 144, 148 and the terminals 160, 162 of the functional circuit, resulting in a measurable electrical characteristic. For example, an open circuit typically has a resistance approaching infinity, while a low impedance circuit has a measurable value. Because the electrodes 144, 148 are in relatively close proximity to one another, when termites penetrate the waterproof member 156, material 200 spreads, deposits, or accumulates on the electrode track 157, creating electrical contact between the electrodes 144, 148. Thus, termite activity closes the circuit between the electrodes 144, 148, placing the circuit in a low impedance state.

[0047] It is to be understood that the electrodes 144, 148 may be arranged in any configuration relative to the ground in which they are buried, including but not limited to a vertical configuration relative to the ground, a horizontal configuration relative to the ground, an oblique configuration relative to the ground, combinations thereof, or any suitable configuration as desired. It is further understood that the electrodes may be arranged at various distances from one another, and the shortest distance between the electrodes may be any distance greater than 0, 10 micrometers (μm), 100 μm, 1 millimeter (mm), 10 mm, and more preferably up to 5 centimeters (cm), up to 2 cm, up to 10 mm, up to 5 mm, up to 1 mm, up to 100 μm, or up to 10 μm. However, such ranges may be adjusted for the size and configuration of the desired device.

[0048] In the illustrated embodiment, the occurrence of a measurable electrical characteristic is sufficient for the control unit 128 to determine the presence or absence of termites and to indicate such presence or absence in a signal transmitted to the gateway 104. The circuit is normally in an open circuit, high impedance state, so that the high impedance state provides a known baseline measurable characteristic (a high impedance value approaching infinity). The circuit only goes to a low impedance state when the material 200 makes contact between the electrodes 144, 148, indicating that termites have penetrated the waterproof member 156. Thus, since obtaining a measurable electrical characteristic, as opposed to a change in the actual value of the measurement, is an indicator of the presence or absence of pests (termites), it is not necessary for the control unit 128 to store / transmit the measurement results in order to detect the presence or absence of pests.

[0049] In an alternative embodiment, the electrical impedance changes based on the amount of material 200 placed on the electrodes 144, 148. For example, the more material 200 placed on the electrodes 144, 148, the lower the electrical resistance. The measured level of electrical resistance may be periodically transmitted to the gateway 104 for additional determinations, such as changes in termite activity over time.

[0050] In the illustrated embodiment, each pulse of current provided to the electrodes 144, 148 causes the control unit 128 to measure an electrical property and determine whether termites are present based on the measured electrical property. For example, in one suitable embodiment, the electrical property is electrical resistance. While the circuit is open, a measurement of the electrical resistance returns a value close to infinity, but when the circuit is closed, the electrical resistance returns a measurable value. Alternatively, in another suitable embodiment, the electrical property is electrical reactance. While the circuit is open, a measurement of the electrical reactance returns a value close to zero, but when the circuit is closed, the electrical reactance has a different, measurable value. If the presence of termites is determined, the control unit 128 transmits a signal to the gateway 104 indicative of the presence of termites.

[0051] It is contemplated that the control unit 128 may similarly transmit signals indicative of other suitable characteristics of the bait matrix 124. Furthermore, any such characteristics of the bait matrix 124 and its environment may be utilized by the control unit 128 and / or gateway 104 to develop predictive or indicator models by which pest status reports can be provided to property owners.

[0052] Also, in an alternative embodiment, as shown in Figures 4 and 5, the control unit 128 may include one or more switches that can be turned on, activated, reset, or other such functions initiated by the bait station 102 and / or gateway 104 when powered by the external device 304. Such switches may include mechanically actuated contacts and interconnects, magnetic switches, RF switches, ultrasonic switches, manual switches, or any other such switches that one may choose to add. Given the possible underground location of the pest monitoring system 100, passive and / or proximity type switches may be preferred over active and / or manual type switches, such as magnetic reed, inductive and capacitive, seismic, infrared, photographic, thermal, electric field, chemical, and / or ultrasonic switches.

[0053] In yet another embodiment, the pest monitoring system 100 may preferably use a magnetic reed switch 302 to activate, turn on, and / or reset one or more bait stations 102 and / or one or more gateways 104, as shown in Figure 5. As shown in Figure 5, the magnetic reed switch 302 may provide power to the circuit board. Given that the pest monitoring system 100 may be installed in an underground environment, the magnetic reed switch 302 offers various advantages, such as being a locking switch, using less power than other options such as ultrasonic switches, and being able to be installed internally to allow for a secure peripheral sealed enclosure.

[0054] Prior to activation of the magnetic reed switch 302 by the external device 304, one or more of the bait stations 102 and / or gateways 104 may be in a sleep or off state to conserve energy. Once power is provided to the one or more bait stations 102 and / or one or more gateways 104 using the magnetic reed switch 302, the one or more bait stations 102 may now be in a discovery or management mode and may search for one or more gateways 104. It is understood that other types of switches may be used to activate, turn on, and / or reset one or more bait stations 102 and / or one or more gateways 104.

[0055] FIG. 6 is a diagram illustrating an example of a pest monitoring network 600 that provides communication paths for the pest monitoring and detection system 100 of FIG.

[0056] The pest monitoring network 600 includes a bait station 102 communicatively coupled to a gateway 104. The pest monitoring network 600 is configured as a private network with one gateway 104 and multiple bait stations 102 per installation location. The gateway 104 acts as a packet forwarder to a long range wireless (LoRa) network server residing in a cloud service 602. The gateway 104 is connected to the Internet through the homeowner's WiFi or Ethernet connection or cellular backhaul with a cellular SIM card. A smartphone application may be used to assist with installation setup and provisioning of communication devices. The network server sends the packets to a middleware / application platform, which decodes the packets and uses them to interpret and route the collected data, perform analytics, and notify project management professionals (PMPs) of important events, such as termite detection and the need for equipment maintenance.

[0057] When the bait station 102 is first powered up by screwing the sensor holder 110 into the station housing 109, closing the switch and applying power 139 to the control unit 128, the control unit 128 enters a "setup mode." During the setup mode, the bait station 102 periodically sends a registration request to the gateway 104 via the control unit 128 until confirmation of registration is received from the gateway 104. After registration is confirmed, the bait station 102 transitions to a normal operating mode and sends status updates in the form of status transmission packets to the gateway 104 according to a predetermined time interval (e.g., once a day). The status transmission packets include, but are not limited to, the station ID, report number, sensor impedance measurements, battery voltage measurements, and / or signal strength of the most recently received confirmation from the gateway 104.

[0058] The packet structure from the bait station 102 to the gateway 104 is Preamble>PHDR>PHDR_CRC>PHY payload>CRC.

[0059] The transmission mode chosen between the bait station 102 and the gateway 104 is LoRa, a low bandwidth modulation scheme using unlicensed frequency spectrum that takes advantage of a transmission range of over 1 kilometer and can penetrate many obstacles. Because LoRa uses low power and has a short receiving window after each transmission from the bait station 102, the bait station 102 can also go into a low power mode between reporting intervals to save power.

[0060] The gateway 104 is configured to collect data from the bait stations 102 and pass the information to a network server residing in the cloud. In addition to the data received from each bait station 102, the gateway 104 may add additional parameters, such as a timestamp of each station report and / or the measured signal strength from each bait station 102.

[0061] The uplink from the gateway 104 to the cloud is an Internet connection that can be configured to connect using any suitable method known in the art. In one embodiment, the Internet connection is made using a digital cellular network (e.g., 3G or 4G), similar to what is used with a smart phone to access the Internet. In another embodiment, a WiFi connection may be established to a customer WiFi network to pass the data to an Internet cloud database. In another embodiment, the gateway 104 may also connect directly to the homeowner's router through a wired Ethernet connection.

[0062] A network server resides in the cloud service 602 and is used to keep track of which bait stations 102 are associated with which gateways 104 and locations within the customer premises. It is also responsible for processes such as (a) device activation to allow a device to join the network, (b) radio adjustments depending on the region / band to be used, such as device duty cycle negotiation (e.g., waiting X seconds between each frame) or bandwidth negotiation, (c) radio channel selection, (d) device class support (A, C, B), (e) frame deduplication (if multiple gateways receive device frames), (f) frame downlink routing (selecting the optimal downlink path), (g) frame integrity (ensuring that data is not corrupted), (h) frame encryption / decryption (avoiding data eavesdropping), (i) frame counter check (preventing replay attacks), (j) backward compatibility across LoRaWAN versions, (k) real-time routing of data packets from endpoints to application servers, (l) authentication of security keys between end nodes, network servers, and application servers, and (m) management of network efficiency metrics such as network throughput, network availability, packet loss, packet delay, and / or packet delay jitter.

[0063] The network server sends the data through the IP address to the application server, which is then accessed by the monitoring entity to perform (a) packet decryption, (b) analysis, (c) PMP related tasks, (d) SAP related tasks, (e) fulfillment, and / or (f) marketing communications.

[0064] The gateway will send the uplink message to the network in the format Preamble>PHDR>PHDR_CRC>PHY payload>CRC.

[0065] The network server is also responsible for sending the necessary downlink messages to the gateway. The packet structure is Preamble > PHDR > PHDR_CRC > PHY Payload.

[0066] At a high level, the middleware / application platform is a set of micro-cloud services that constitute an on-demand, scalable, and secure computing system that resides on a public or private cloud. This platform is capable of discovering, identifying, cataloging, connecting, and controlling gateways 104 and bait stations 102 for an IoT project.

[0067] The devices connect to the platform through MQTT, WiFi, IP, cellular, or satellite. This connection may be direct or integrated through a gateway / network or mobile device. Once the devices are connected to the platform, the data is normalized (if applicable) and through the REST API, the following features are available: (a) data storage / management when data is made available to the service provider for historical data mining through the API, (b) scheduling of timed events based on specific dates and times, (c) SMS / email alerts based on exceeding or meeting certain thresholds, (d) If / Then event triggers that facilitate notification to the service provider, such as termite detection, low battery, and / or low signal strength between the gateway 104 and any of the bait stations 102, (e) data visualization, and (f) LoRa tracking. The REST API allows external business intelligence, artificial intelligence, and other third party services to consume or interact with the middleware / application layer.

[0068] The installation of the system 100 begins with an installer installing the gateway 104 at the customer premises. It is usually installed indoors with access to utility power and a planned method of Internet access. After the gateway 104 is powered and connected via WiFi, Ethernet, or cellular, it enters a verification mode indicated by LED status illumination. Once the gateway 104 connection status is complete (i.e., solid green LED illumination), the installer uses a smartphone application to read the gateway ID from the barcode label and the gateway 104 is registered through authentication steps such as (a) gateway uplink to network server (with downlink verification), (b) network server packet authentication, (c) network server and application server authentication, (d) downlink from network server to gateway, and (e) application to smartphone application authentication.

[0069] If a cellular network is used as the uplink, gateway communication is enabled by inputting SIM card data in the gateway 104. If a customer WiFi network is used, it may be necessary to establish a local WiFi connection between the installer's smartphone and the gateway and input the customer's network SSID and password.

[0070] The installer selects the layout of the bait stations 102 according to the guidelines and installs each bait station 102 in the ATBS housing. The installer registers each station by reading the barcode ID of each bait station 102 using an installation smartphone application.

[0071] As described above, once the installer screws the electronic module into the bait assembly, the bait station 102 powers up and goes into a setup mode, periodically broadcasting a registration request (e.g., every 30 seconds). The gateway 104 then receives the request and sends it to a network application server for authentication. The application server communicates with a smartphone application to verify that the installation of the bait station 102 is complete. The smartphone application then notifies the installer to move on to the next station.

[0072] After the installer installs the last bait station 102, he selects the option to complete the installation on the smartphone application. The system turns on and performs a test check by sending and checking all real-time station data to the gateway 104, which communicates with the network and application server. The smartphone application confirms that the installation is complete and notifies the installer of the installation location. The system then goes into normal operation mode, sending data at predetermined time intervals as previously described.

[0073] The gateway 104 is capable of (a) internal and / or (b) external communication. The internal communication of the gateway 104 may be performed using a network. The external communication of the gateway 104 may be sent to a home security (HS) hub 402 and further to a communication portal 404 as shown in Figures 7-12. It is understood that the gateway 104 and the HS hub 402 may use a WiFi connection, an Internet connection, an Ethernet connection, a cellular connection, and / or any other suitable form of communication to transmit data from the gateway 104 and / or the HS hub 402 and / or the communication portal 404 to the outside. The HS hub 402 and / or the communication portal 404 may be provided by a customer using the pest monitoring system 100 and / or any other external source. The HS hub 402 and / or the communication portal 404 allow for periodic logging of sensor / network data to an externally hosted cloud. An application programming interface (API) may be used to transmit data from the gateway 104 to the cloud. An API may also be used to transfer data from the bait station 102 to the gateway 104. An API may also be used to transfer data from the cloud to the web interface. The API may be written in a variety of different formats, such as JSON, XML, or other text-based formats or binary serializations, such as MessagePack, protobuf, bson, avro, or any other binary format.

[0074] It will be appreciated that in some suitable embodiments, the gateway 104 may be incorporated into a connected system or network, including, but not limited to, a smart home system and / or a home security panel / system (as shown in FIGS. 7-12). In such embodiments, the HS hub 402 and / or communication portal 404 may function as the gateway 104, and the bait station 102 may communicate directly with the HS hub 402 and / or communication portal 404. Such communication preferably uses a WiFi connection, although an internet connection, an Ethernet connection, a cellular connection, and / or any other suitable form of communication means may be used for data transmission. Additionally, if the bait station 102 is at least partially underground, a low power wide area network (LPWAN or LoRaWAN) connection may be used for communication between the bait station 102 and the HS hub 402 and / or communication portal 404.

[0075] In an exemplary embodiment, the gateway 104 is communicatively coupled to the plurality of bait stations 102 and the HS hub 402 and / or communication portal 404. The gateway 104 acts as a gateway between the plurality of bait stations 102 and the HS hub 402 and / or communication portal 404. In an exemplary embodiment, the gateway 104 provides a secure communication link between the bait stations 102 and the HS hub 402 and / or communication portal 404 while filtering the communications to prevent cyber security threats. In an exemplary embodiment, the gateway 104 establishes a secure communication channel with each of the bait stations 102. The secure communication channel is a two-way communication channel. In some embodiments, the secure communication channel transmits and receives encrypted data. In some other embodiments, the secure communication channel requires that authentication information be included in the communication. The secure communication channel may be protected in other ways to enable the systems and methods described herein to function.

[0076] The gateway 104 may have two different modes of operation: (a) a management mode (which may also be referred to as a maintenance mode or discovery mode) that allows the gateway 104 to detect and add bait stations 102 to the network; or (b) a report mode. When the gateway 104 is set to management mode, it searches for bait stations 102 to add to its network and sends test packets to any bait stations 102 it finds. It may be desirable for the gateway 104 to automatically default to management mode when it first starts up. Once a bait station 102 is attached to the gateway 104 network, it will not attempt to join any other networks unless otherwise specified and / or reset. It should be understood that both the gateway 104 and the bait station 102 may need to be set to management mode for the network to be formed. The gateway 104 may also be set to management mode using a mobile device application. To set up the pest monitoring system 100, an installer may first turn on the gateway 104 and place it in management mode, and then activate the individual bait stations 102 to form a network of pest monitoring systems. The pest monitoring systems 100 preferably communicate using a star network, as described herein, in which each bait station 102 communicates directly with the gateway 104.

[0077] Additionally, the gateway 104 may have two different communication modes: (a) internal communication on the pest monitoring system network to send and receive information to and from the bait stations 102, or (b) external communication to send and receive information to and from remote devices and / or the cloud. To receive data from the bait stations 102, each bait station 102 may be configured to automatically send a signal to the gateway 104 in response to determining whether or not there is pest activity, and / or the gateway 104 may check each individual bait station 102 on the network at predetermined intervals.

[0078] The gateway 104 may be aware of the bait stations 102 that belong to its network, while the bait stations 102 themselves are not aware of who they are specifically interacting with. The gateway 104 is configured to store data sent from the bait stations 102 at least until it transmits the data to an external location and / or device. The gateway 104 preferably transmits data to the cloud or external source upon receiving instructions and / or upon the expiration of time intervals programmed into firmware of the bait stations 102 and / or gateway 104. It will be appreciated that the gateway 104 may transmit data to the cloud and / or external source at programmed time intervals and / or in response to a request from a mobile application used on a remote device, as described in more detail below.

[0079] It will be appreciated that a gateway 104 may be adapted to function as both a bait station 102 and / or a gateway 104 and may be capable of internal communication with both other bait stations 102 and / or gateways 104 as well as external communication.

[0080] As shown in FIG. 5, the gateway 104 may have a magnetic reed switch 302 and / or an ultrasonic switch 301. An ultrasonic sensor may power the ultrasonic switch 301 on the gateway 104 and may be used to stop / start cycle the gateway 104. The ultrasonic switch 301 may allow remote activation of the gateway 104 using a remote device. This allows data stored in the gateway 104 to be downloaded instantly at the time rather than waiting for the gateway 104 to send out data for each scheduled download. It is understood that the data stored in the gateway 104 may be the latest report data from the bait station 102 to the gateway 104.

[0081] It is understood that a mobile client, such as a phone or handheld device, can perform the following actions: (a) get a list of all bait stations 102 connected to the gateway 104; (b) reset the bait stations and / or the gateway 104; (c) link the gateway 104 to the customer's home network (such as a WiFi network or a cellular network); (d) configure a host cloud report; (e) check the customer's home network; (f) erase a bait station 102 from the network; (g) put the bait station 102 and / or the gateway 104 into discovery mode; and / or (h) erase the entire network.

[0082] It is understood that in some embodiments, the ultrasonic switch 301 may be preferred over other types of switches, such as infrared switches, because it may work better in underground environments. The ultrasonic switch 301 relies on a combination of an ultrasonic transmitter and an ultrasonic receiver. The transmitter emits an ultrasonic signal, which is wirelessly transmitted to the ultrasonic receiver, which then converts it into an electrical signal that can be used for various functions. In the pest monitoring system 100 that is the subject of this disclosure, the ultrasonic switch 301 or device resides in a sensor holder 110 that is part of the pest monitoring system 100. The gateway 104 and / or bait station 102 in the pest monitoring system 100 may be located in a plastic sensor housing (not shown) that is located underground, on the surface, or above ground. Also, the components of the pest monitoring system 100 may be located underground, on the surface, or above ground as well, without the use of a plastic sensor housing. The signal emitted by the ultrasonic transmitter must pass through any sensor housing material in addition to the sensor cover. Additionally, ultrasonic signals may need to pass through soil, mulch, or other materials (i.e., organic or inorganic), such as walls, concrete, and / or man-made barriers. The use of ultrasonic signals is preferred over infrared due to their increased ability to travel through underground environments as well as plastic materials surrounding the device. The use of ultrasonic switch 301 has been field tested and proven effective in activating the desired operational functions within pest monitoring system 100. It is understood that the ultrasonic transmitter may be any type of handheld device capable of emitting an ultrasonic signal.

[0083] In one embodiment illustrated in FIGS. 7-12, the pest monitoring system 100 may be directly integrated into the connectivity system or HS hub 402. For purposes of this application, a connectivity system is understood to mean any automated or wireless interconnection and / or connectivity system within an industrial, residential, and / or commercial facility. The connectivity system may have a central communication point or device, such as the HS hub 402, that aggregates all device communications. It is also understood that the connectivity system allows various devices within the industrial, residential, or commercial facility to communicate with each other or with a central location. Such devices may include, but are not limited to, fire / smoke detectors, intrusion detectors, medical alarm devices, energy management devices, water / leak detection devices, irrigation systems, smart appliances, lighting mechanisms, door locks, window sensors, video / audio devices, and the like. It is also understood that the connectivity system may provide external communication from the facility 400 through the HS hub 402 and / or communication portal 404 to a distributed network system or communication portal 404, or to another external source, such as a cloud, single server system, or similar system. Pest monitoring system 100 may be compatible with residential and / or commercial connectivity systems and / or distributed network systems. Pest monitoring system 100 may be directly installed and integrated into existing and / or privately connected systems by service providers, including, but not limited to, home security providers, construction contractors, pest control professionals, other technical service providers, and / or facility owners.

[0084] As previously discussed, the pest monitoring system 100 is designed to detect pest activity in, on, or around a consumable and / or movable bait matrix 124. One or more bait stations 102 and at least one gateway 104 may be located adjacent to industrial, commercial, and / or residential structures 400, as well as seawalls, docks, railroad tracks, and other such wood-based structures, spaced at distances determined to be effective for detecting pest activity. Such spacing between the various bait stations 102 and / or gateways 104 may be 5 to 30 feet, 5 to 15 feet, and 1 to 100 feet.

[0085] Removal of a portion of the bait matrix 124 by a pest may trigger a signal that is communicated from the individual bait stations 102 to the gateway 104 or distributed network system for data management, storage, analysis, and / or transmission to authorized parties, including but not limited to technology providers, installation companies, and facility owners. As shown in Figures 7-12, the signal may be transmitted from the gateway 104 through the HS hub 402 of the connected system to the communication portal 404 and beyond. The signal indicative of pest activity may be further routed by the service provider (406, 412) of the connected system to the appropriate recipient (410, 413, 414, 416, 418, etc.), including but not limited to the technology owner, authorized service provider, and / or facility / property owner 400. The authorized service provider (414, 416) may be notified of a potential pest threat and may be required to respond.

[0086] Leveraging existing technology, infrastructure, and expertise common to the security and surveillance industry, including but not limited to, reduces the complexity of the monitoring process and facilitates threat communication and response. Incorporation of the pest monitoring system 100 into a connected system, including but not limited to, may provide a similar level of facility protection and peace of mind as originally provided by the security and surveillance industry, including but not limited to, life safety (fire, intrusion, medical) and / or lifestyle (temperature, lighting, doors, etc.) management without the need for traditional visual inspection for pest activity. Combining pest monitoring with another home security / surveillance system provides a broader level of comfort and peace of mind to the property owner. It is understood that if a pest is detected by the pest monitoring system 100, an alert may be sent directly to the security company, to the pest monitoring provider, to the person in charge, manager, or owner of the facility being monitored, and / or to the company providing the pest monitoring system 100.

[0087] In some embodiments, upon receiving a signal from the bait station 102 indicating the presence of termites, the HS Hub 402 generates an alert to notify the building / structure owner / contact, which may include, but is not limited to, displaying a pest alert on a smart TV connected to the HS Hub 402, flashing lights in the building / structure in a predetermined sequence, and / or ringing the building / structure doorbell in a predetermined sequence.

[0088] It will be appreciated that communication of data collected by the gateway 104 may occur through a variety of means and may include communication with one or more of: (a) an HS hub 402 that receives data from the bait station 102 (or gateway 104); (b) a communication portal 404 that allows data to be sent from a data source (with or without an HS hub 402) to the cloud and may comprise devices such as a WiFi router, a cell phone, etc.; (c) an HS company data service 406 that may host cloud data that may have been sent from the communication portal; (d) a service provider 410 such as a home security company; (e) a direct mailing company or data management company 412 / 413; (f) a pest management professional "PMP" (with or without a routing service 414 / 416) that may address any pests detected; (g) a PM routing service 418 that notifies the PMP; (h) the residence or property owner 400; and / or (i) a cloud service network provider 407. Figures 7-12 provide examples of various communication paths. It is understood that these paths are adjustable, and that a common goal of pest monitoring system 100 is to provide data regarding the presence of pests from the location of system 100 ultimately to a property owner and / or a service provider, such as a pest control professional. It is understood that a variety of intermediate communication paths can be used to accomplish this goal.

[0089] Another embodiment of the present disclosure is a method for determining, after a traditional or conventional bait has been placed at a site, whether the termites (or other insects / arthropods) consuming the bait are the same as the termites (or other insects / arthropods) infesting the facility at the site. It would therefore be useful to provide a bait that facilitates such a determination.

[0090] In one embodiment, the bait generally comprises a polysaccharide carrier material and a marker material mixed with the carrier material, the marker material comprising a substance that is consumable by an insect (or other arthropod) and that, upon observation of the insect (or other arthropod), facilitates determining that the insect (or other arthropod) is actively eating the bait.

[0091] In another embodiment, a method of monitoring insects generally includes placing a bait at a first location at a site, the bait including a marker material that facilitates determining that an insect / arthropod is actively feeding on the bait. The method also includes monitoring insect / arthropod activity at the bait, detecting a level of insect / arthropod activity at the bait as a result of the monitoring, and visually inspecting a second location at the site for insect / arthropod activity as a result of the detection. The method further includes observing the insect / arthropod at the second location to determine that the insect / arthropod has consumed the marker material and is actively feeding on the bait.

[0092] 13 is a perspective view of an exemplary bait matrix 124 that may be used with the pest monitoring system 100 (shown in FIG. 1 ), including a conductive bait matrix 1400 and a non-conductive bait matrix 1402. In a preferred embodiment, "conductive bait matrix" is understood to generally refer to a bait matrix that includes conductive particles. It should also be understood that a bait may include conductive particles but not be conductive itself. For purposes of this disclosure, this type of bait may also be referred to as a "conductive bait." In one embodiment, the bait matrix 124 includes only a conductive bait matrix 1400.

[0093] However, in other embodiments, it may be preferred that the bait matrix 124 comprises one or more portions, where at least one portion comprises a conductive bait matrix 1400 and a second portion comprises a non-conductive bait matrix 1402.

[0094] Moreover, it is understood that in other suitable embodiments, the bait matrix 124 can be non-conductive (ie, comprises only a bait matrix 1402 that is substantially free of conductive particles).

[0095] The conductive bait matrix 1400 may be up to 5% of the size of the entire bait matrix 124 (conductive portion 1400 and non-conductive portion 1402), up to 10% of the entire bait matrix 124, up to 15% of the entire bait matrix 124, up to 30% of the entire bait matrix 124, up to 50% of the entire bait matrix 124, up to 75% of the entire bait matrix 124, and / or up to 100% of the entire bait matrix 124.

[0096] In one suitable embodiment, as shown in Table 2 below and more fully in Example 1 herein, the conductive bait matrix 1400 is highly acceptable to pests and may even be favored for consumption or transportation by the pests.

[0097] It will be further appreciated that the bait matrix 124 shown in FIG. 1 may be highly acceptable to pests and may even be favored for consumption or transportation by pests without the inclusion of conductive bait matrix 1400.

[0098] In one embodiment, the bait matrix 124 is of a generally solid composition. Alternatively, in other embodiments, the bait matrix 124 may be semi-solid (e.g., in the form of a gel) or generally liquid (e.g., in the form of a fluid suspension). In one particularly suitable embodiment, the bait matrix 124 is an extruded bait matrix.

[0099] In one suitable embodiment, the bait matrix 124 and / or the conductive bait matrix 1400 includes a carrier material and a plurality of conductive particles and / or a plurality of acceptability enhancing particles. It is understood that the non-conductive bait matrix 1402 may not include or may not include enough conductive particles for electrical conductivity and / or charge transport. It is also understood that the conductive bait matrix 1400 may be only a portion (conductive portion 1400) of the bait matrix 124. It is further understood that an electrical charge may or may not be applied to the conductive bait matrix 1400. In one embodiment, the conductive or phagostimulant particles may be metal particles such as, but not limited to, iron, zinc, magnesium, copper, or aluminum. The particles may be in any suitable particulate form, such as dust, oxide, powder, slug, flake, or other suitable particulate form.

[0100] In other embodiments, the conductive or phagostimulatory particles are semi-metallic or non-metallic conductive particles. Suitable examples according to one embodiment include, but are not limited to, carbon-based particles such as graphite, carbon nanotube flakes, carbon black, coke, and carbonized carbon powder.

[0101] In one particularly suitable embodiment, the conductive or phagostimulant particles are particles of graphite, which is available in a variety of types, such as flake graphite, amorphous graphite, scaly graphite, expandable graphite, or highly oriented pyrolytic graphite (HOPG).

[0102] Graphite may be used in a variety of applications, including EDM grade (e.g., as described in “Properties and Characteristics of Graphite, For the EDM Industry”, Fifth Printing-February 2002, 1987, Poco Graphite, Inc., POCO Graphite, Inc., 300 Old Greenwood Rd. Decatur, TX 76234), industrial grade (e.g., as described in “Industrial Material Solutions”, Poco Graphite Inc., brochures IND-92480-0514, 6204-7085INK-0414, all 2014), semiconductor grade, ion implantation grade, biomedical grade (e.g., as described in “Biomedical Grade Graphites”, Poco Graphite Inc., Brochure IND-7334-0514), and Glassmate grade (e.g., as described in “Glassmate”, Poco Graphite Inc., brochure GLA 102930-0214, 2014) and various grades for various applications are commercially available.

[0103] It is well known that different types and grades of graphite differ in one or more of the following properties, for example: density, Shore hardness, Rockwell hardness, flexural strength, thermal expansion, thermal conductivity, heat capacity, emissivity, compressive strength, electrical resistivity, or average grain size.

[0104] Generally, any type and grade of graphite may be used, provided that its incorporation into the bait matrix enhances the palatability of the bait matrix. In one suitable embodiment, the material containing the conductive particles is graphite provided by a graphite manufacturer (e.g., Asbury Graphite Mills, Inc.) as a conductive filler for producing conductive polymers. In one embodiment, the material containing the conductive particles is ultra-fine graphite and / or ultra-high surface area graphite.

[0105] In one suitable embodiment, the average particle size of the graphite may be 1 μm to 20 μm, 1 μm to 15 μm, 1 μm to 10 μm, 1 μm to 5 μm, or 1 μm to 3 μm. Methods for determining the average particle size are well known to those skilled in the art. In one embodiment, the surface area of ​​the graphite is 1 m 2 / g~500m 2 / g, 20m 2 / g~400m 2 / g, 50m 2 / g~300m 2 / g range.

[0106] Electrical resistivity (also known as resistivity, electrical resistivity, or volume resistivity) is an intrinsic property that quantifies the strength of a given material to oppose the flow of electric current. Those skilled in the art are familiar with methods for measuring electrical resistivity. For example, one standard method for measuring the electrical resistivity of a graphite sample is described in ASTM C611-98.

[0107] Table 1: Graphite types offered by Asbury Graphite Mills, Inc. for the manufacture of conductive polymers.

[0108] [Table 1]

[0109] In one embodiment, the conductive bait matrix 1400 comprises a sufficient amount of conductive particles, preferably graphite, to provide an electrical resistance of the conductive bait matrix 1400 in the range of 1 kΩ to 500 kΩ, 10 kΩ to 100 kΩ, preferably 40 kΩ to 80 kΩ, and more preferably 1 kΩ to 20 kΩ.

[0110] In one embodiment, the conductive bait matrix 1400 comprises about 0.1% to about 50%, 1% to about 25%, preferably about 5% to about 15%, and more preferably about 8% to about 12% by weight of graphite particles relative to the total weight of the conductive bait matrix 1400. The remaining portion of the conductive bait matrix 1400 in such an embodiment is the carrier material. In other embodiments, a toxin such as an active ingredient may be included in the bait matrix 124 to reduce the concentration of the graphite particles, the concentration of the carrier material, or both.

[0111] It should be understood that some feeding stimulants, such as erythritol, can also be used as active insecticide ingredients.

[0112] Also, other suitable conductive particles may be used and still remain within the scope of certain aspects of the present disclosure. Additionally, it is understood that the bait matrix 124 shown in Figure 1 may include a toxin without including the conductive bait matrix 1400. Additionally, it should be understood that the conductive bait matrix 1400 may be used with the device without having any electrical current flowing through it itself.

[0113] The carrier material of the bait matrix 124 in one embodiment comprises a consumable material (e.g., a material that can be consumed and digested by the pests being monitored using the bait matrix). For example, in one particularly suitable embodiment, the carrier material comprises a polysaccharide material (e.g., a cellulosic material such as wood flour, alpha cellulose, microcrystalline cellulose, or other suitable cellulosic material that is consumable by termites). It will be understood that the carrier material may comprise other consumable materials without departing from the scope of the present disclosure. In other suitable embodiments, an agar matrix alone or in combination with sugars (i.e., xylose, mannose, galactose, erythritol, aspartame, saccharin) and / or pure cellulosic materials may be used as the carrier material for the bait matrix 124.

[0114] Alternatively or additionally, the carrier material may include a consumable but non-digestible or essentially non-digestible material (e.g., a material that is consumable but not digestible by the pests being monitored using the bait matrix 124). In one example, a suitable consumable but non-digestible or essentially non-digestible material for use as the carrier material is a thermosetting material and / or a resin-based material. Such materials may be melted and mixed with the conductive particles (and digestible material, if present) and extruded together to form the bait matrix 124.

[0115] However, it is understood that the bait matrix 124 can function as described in FIG. 1 without including the conductive bait matrix 1400.

[0116] By "essentially indigestible" it is understood that less than 50%, preferably less than 10%, more preferably less than 1%, and even more preferably less than 0.1% by weight of the material orally acquired is subsequently digested by the pest being monitored using the bait matrix 124. Digestible for purposes of this application means capable of being broken down into simpler forms by the consumer after consumption.

[0117] Alternatively or additionally, it is contemplated that the carrier material may comprise a mobile material, i.e., a material that the pests can push aside without ingesting and / or digesting. Thermoplastic materials are generally well known materials that are easy to mold or cast above a certain temperature and solidify upon cooling. Suitable thermoplastic materials include high temperature thermoplastics such as polyphthalamide (PPA), polyphenylene sulfide (PPS), liquid crystal polymer (LCP), polyetheretherketone (PEEK), polyetherimide (PEI), polyarylsulfone (PSU), polyethersulfone (PES), polyphenylsulfone (PPSU), syndiotactic polystyrene (SPS), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyoxymethylene (POM), polyamide (PA), polypropylene (PP), polycarbonate (PC), poly(p-butylene sulfone ... Many examples exist, but are not limited to, engineering thermoplastics such as poly(phenylene oxide) (PPE), poly(methyl methacrylate) (PMMA), acrylonitrile butadiene styrene (ABS), styrene-acrylonitrile copolymer (SAN), acrylonitrile styrene acrylate (ASA), standard thermoplastics such as high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), poly(butylene adipate-co-terephthalate) (PBAT), acrylonitrile butadiene styrene (ABS), etc.

[0118] In one embodiment, the carrier material comprises a thermoplastic material having a melting point less than about 220°C, less than about 180°C, less than about 160°C, or less than about 140°C.

[0119] Additionally, in one embodiment, the bait matrix 124 and / or the conductive bait matrix 1400 includes at least one pesticide active ingredient.

[0120] Additionally, when the bait matrix 124 and / or the conductive bait matrix 1400 includes a pesticide active ingredient, the processing temperature used to melt or soften the thermoplastic material in preparing the carrier material is preferably below a temperature at which the pesticide active ingredient becomes ineffective and / or the molecular integrity of the active ingredient is compromised.

[0121] Suitable thermoplastic materials include, but are not limited to, cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), or polyester. US Patent Application Publication No. 2015 / 0305326A1 describes particularly suitable thermoplastic materials in paragraphs

[0077] and

[0078] , the contents of which are incorporated herein by reference. In a particularly suitable embodiment, the thermoplastic carrier material is a polyester having a relatively low melting point, for example, less than 170°C, less than 160°C, less than 150°C, less than 140°C, less than 130°C. Suitable polyesters are, for example, those disclosed in WO-A 92 / 09654 and WO-A 96 / 15173, the contents of which are incorporated herein by reference.

[0122] The preferred suitable polyesters are those having a 150-320 cm 3 The polyesters are aliphatic or aliphatic / aromatic (semi-aromatic) polyesters having an intrinsic viscosity of 1.0 mg KOH / g and an acidity index according to DIN EN 12634 of less than 1.2 mg KOH / g, preferably less than 1.0 mg KOH / g.

[0123] Another preferred polyester is 160 cm 3 / g, an acidity index of less than 1.0 mg KOH / g, and a viscosity of 6.0 cm (measured at 190° C. with a weight of 216 kg). 3 It is a compostable semi-aromatic polyester with a melt volume flow rate (MVR) of less than 10 min.

[0124] The above-mentioned preferred compostable semi-aromatic polyesters and their manufacturing process are disclosed in WO-A 09 / 127556, the contents of which are incorporated herein by reference. The thermoplastic material may also comprise a mixture of biodegradable semi-aromatic polyesters with hydrolysis-susceptible polymers, examples of which are PLA (polylactide), PHA (polyhydroxyalkanoic acid), PBS (polybutylene polysaccharide), and starch. A particularly suitable polyester is sold by BASF SE under the trade name Ecoflex®. This material is a compostable statistical aliphatic-aromatic copolyester based on the monomers 1,4-butanediol, adipic acid, and terephthalic acid in the polymer chain. The melting point of Ecoflex® is about 110-120°C.

[0125] The thermoplastic polymer may comprise a single polymer or a mixture of at least two different polymers. For example, in one embodiment, the thermoplastic polymer comprises a mixture of a relatively high molecular weight polymer and a relatively low molecular weight polymer. Polyesters, such as Ecoflex®, their manufacture and use are described in patent applications EP-A 1656423, EP-A 937120, EP-A 950689, EP-A 1838784, EP-A 947559, EP-A 965615, the contents of which are incorporated herein by reference. In one embodiment, the thermoplastic polymer comprises a mixture of polylactic acid (PLA), such as Ecoflex® and ecovio®.

[0126] The advantage of using a low melting polyester polymer as a carrier material (e.g., as opposed to CAP or CAB) is in the extrusion of bait matrices containing active ingredients that decompose at higher temperatures, e.g., above 160°C, 180°C, 200°C. For example, CAP and CAB typically have melting points close to about 180°C. Extrusion of this polyester polymer (e.g., Ecoflex®) at higher temperatures may have a more detrimental effect on the active ingredients than extrusion at lower temperatures. It is understood that melting points higher than 180°C may be used. Also, based on preliminary studies, it is believed that termites prefer a bait matrix composed of graphite and Ecoflex® over a bait matrix composed of graphite and CAB or CAP at the same relative concentrations shown in Tables 3 and 4 and more fully shown in Example 2.

[0127] As used herein, a substance or mixture of substances is considered to be "biodegradable" if it has a percentage of biodegradability of at least 60% in the process specified in DIN EN 13432. Other methods for determining biodegradability are described, by way of example, in ABNT 15448-1 / 2 and ASTM D6400. As used herein, a substance or mixture of substances is considered to be "compostable" if it can be broken down by biological processes, such as microorganisms, during composting to produce CO2, water, inorganic compounds, and biomass at rates consistent with other known compostable materials, without leaving visible, identifiable, or harmful residues, and / or if it meets the criteria set forth in any of the composting standards, such as the European DIN EN 13432, the American ASTM D 6400, or the Japanese GreenPla standard.

[0128] Biodegradability and / or compostability generally result from the decomposition of a substance (e.g., polyester) within a suitable and demonstrable period of time. Decomposition may be enzymatic, hydrolytic, oxidative, and / or caused by exposure to electromagnetic radiation, such as UV radiation, and is primarily caused by exposure to microorganisms, such as bacteria, yeasts, fungi, and algae. In one example of a method for quantifying biodegradability, polyester is mixed with compost and stored for a certain time. As an example, according to DIN EN 13432, CO2-free air is passed through the mature compost during the composting process, and the compost is subjected to a predefined temperature profile. Here, biodegradability is defined by the ratio of the net amount of CO2 released by the sample (after subtracting the amount of CO2 released by the compost without the sample) to the maximum possible amount of CO2 released by the sample (calculated from the carbon content of the sample), which is defined as percentage biodegradability. Even after a few days of composting, biodegradable polyester or biodegradable polyester blends typically show significant signs of degradation, such as mold growth, cracks, and perforations.

[0129] Polyesters are well known polymers. They contain monomers in polymerized form, such as diols and dibasic acids (or diesters) or hydroxy acids (or hydroxy esters). Suitable polyesters are, for example, aliphatic polyesters. They include homopolymers of aliphatic hydroxycarboxylic acids or lactones, as well as copolymers or block copolymers of different hydroxycarboxylic acids or lactones or mixtures thereof. These aliphatic polyesters may also contain units of diols and / or isocyanates. They may also contain units derived from trifunctional or polyfunctional compounds, such as epoxides, acids or triols. They may contain the latter units as individual units or many of these, possibly in combination with diols and / or isocyanates. The processes for making aliphatic polyesters are well known to those skilled in the art. In making the aliphatic polyesters, it is of course also possible to use mixtures composed of two or more comonomers and / or other units, such as epoxides, polyfunctional aliphatic or aromatic acids or polyfunctional alcohols. The aliphatic polyesters generally have a molar mass (number average) of 10,000 to 100,000 g / mol.

[0130] Examples of aliphatic polyesters are the polymeric reaction products of lactic acid, poly-3-hydroxybutanoic acid, or polyesters composed of aliphatic or cycloaliphatic dicarboxylic acids and aliphatic or cycloaliphatic diols. The aliphatic polyesters may also be random or block copolyesters containing other monomers. The proportion of other monomers is generally up to 10% by weight. Preferred comonomers are hydroxycarboxylic acids, lactones, or mixtures thereof.

[0131] The polymeric reaction products of lactic acid may be known per se or may be prepared by processes known per se. In addition to polylactic acid, copolymers or block copolymers based on lactic acid containing other monomers may be used. Linear polylactic acid is most used. However, branched lactic acid polymers can also be used. Examples of branching agents are polyfunctional acids or alcohols. By way of example, polylactic acid may be mentioned which contains at least one aliphatic C4-C 10 Dicarboxylic acid and at least one C3-C 10 The polylactic acid is essentially derived from an alkanol of lactic acid having 3 to 5 hydroxyl groups, its C1-C4-alkyl esters, or mixtures thereof.

[0132] Poly-3-hydroxybutanoic acid is a homopolymer or copolymer of 4-hydroxybutanoic acid and 3-hydroxybutanoic acid, in particular with 3-hydroxyvaleric acid in a weight ratio of up to 30%, preferably up to 20% of 3-hydroxybutanoic acid, or a mixture thereof. Suitable polymers of this type also include polymers with R stereospecific configuration. These polyhydroxybutanoic acids or copolymers can be produced by microorganisms.

[0133] Processes for making stereospecific polymers are known, as well as processes for making them from various bacteria and fungi. Block copolymers of the above-mentioned hydroxy carboxylic acids or lactones, or mixtures, oligomers, or polymers thereof, can also be used.

[0134] Suitable polyesters made of aliphatic or cycloaliphatic dicarboxylic acids and aliphatic or cycloaliphatic diols are polyesters made of aliphatic or cycloaliphatic dicarboxylic acids or mixtures thereof and aliphatic or cycloaliphatic diols or mixtures thereof. According to the present disclosure, random or block copolymers may be used.

[0135] Suitable aliphatic dicarboxylic acids generally have 2 to 10 carbon atoms. They may be linear or branched. Cycloaliphatic dicarboxylic acids as used herein generally have 7 to 10 carbon atoms, in particular 8 carbon atoms. In principle, however, dicarboxylic acids with more carbon atoms (e.g. up to 30 carbon atoms) may be used. Examples include, but are not limited to, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, azelaic acid, sebacic acid, fumaric acid, 2,2-dimethylglutaric acid, suberic acid, 1,3-cyclopentanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, oxydiacetic acid, itaconic acid, maleic acid, and 2,5-norbornanedicarboxylic acid, in particular adipic acid. Mention should also be made of the ester-forming derivatives of the abovementioned aliphatic or cycloaliphatic dicarboxylic acids, which can be used as well as the di-C1-C6-alkyl esters, such as, in particular, the dimethyl, diethyl, di-n-propyl, diisopropyl, di-n-butyl, diisobutyl, di-t-butyl, di-n-pentyl, diisopentyl and di-n-hexyl esters. The anhydrides of the dicarboxylic acids can likewise be used. The dicarboxylic acids or their ester-forming derivatives can be used individually or as a mixture of two or more.

[0136] Suitable aliphatic or cycloaliphatic diols generally have 2 to 10 carbon atoms. They may be linear or branched. Examples are 1,4-butanediol, ethylene glycol, 1,2- or 1,3-propanediol, 1,6-hexanediol, 1,2- or 1,4-cyclohexanediol, or mixtures thereof.

[0137] Examples of aliphatic polyesters are the aliphatic copolyesters described in WO 94 / 14870, in particular aliphatic copolyesters composed of succinic acid, its diesters, or mixtures with other aliphatic acids, diesters (e.g., glutaric acid and butanediol), or mixtures of this diol with ethylene glycol, propanediol, or hexanediol, respectively, or mixtures thereof. In another embodiment, preferred aliphatic polyesters include polycaprolactones.

[0138] In this specification, semi-aromatic polyester refers to a polyester containing aliphatic and aromatic monomers in polymerized form. The term semi-aromatic polyester is also intended to include derivatives of semi-aromatic polyesters, such as semi-aromatic polyetheresters, semi-aromatic polyesteramides, or semi-aromatic polyetheresteramides. Suitable semi-aromatic polyesters include linear non-chain-extended polyesters (WO 92 / 09654). Chain-extended and / or branched semi-aromatic polyesters are preferred. The latter are disclosed, for example, in WO 96 / 15173, WO 96 / 15174, WO 96 / 15175, WO 96 / 15176, WO 96 / 21689, WO 96 / 21690, WO 96 / 21691, WO 96 / 21689, WO 96 / 25446, WO 96 / 25448 and WO 98 / 12242, which are hereby expressly incorporated by reference. Mixtures of different semi-aromatic polyesters may also be used. In particular, the term semi-aromatic polyester is intended to mean products such as Ecoflex® (BASF SE), Eastar® Bio and Origo-Bi (Novamont).

[0139] Particularly preferred semi-aromatic polyesters include those having an acid component (A) composed of (a1) 30 to 99 mol % of at least one aliphatic or at least one alicyclic dicarboxylic acid or an ester-forming derivative thereof, or a mixture thereof, (a2) 1 to 70 mol % of at least one aromatic dicarboxylic acid or an ester-forming derivative thereof, or a mixture thereof, and (a3) ​​0 to 5 mol % of a sulfonic acid group-containing compound; and (B) at least one C2-C 12 Alkanediol and at least one C5-C 10 Some polyesters contain an important component, a diol component selected from cycloalkanediols or mixtures thereof. The semi-aromatic polyesters may also optionally contain one or more components selected from (C) and (D). (C) is (c1) at least one ether-functional dihydroxy compound having the formula: HO-[(CH2) n -O] m -H (I) [wherein n is 2, 3, or 4, and m is an integer from 2 to 250] (c2) at least one hydroxycarboxylic acid of formula IIa or IIb,

[0140] [ka]

[0141] [ka] [wherein p is an integer from 1 to 1500, r is an integer from 1 to 4, and G is phenylene, (CH2) q - (wherein q is an integer from 1 to 5), -C(R)H-, and -C(R)HCH2 (wherein R is methyl or ethyl). (c3) at least one amino-C2-C 12 Alkanol, at least one amino-C5-C 10 Cycloalkanols, or mixtures thereof, (c4) at least one diamino-C1-C8 alkane; (c5) at least one 2,2′-bisoxazoline of formula III,

[0142] [ka] [Where, R 1 is a single bond, (CH2) z - an alkylene group (where z=2, 3, or 4), or a phenylene group. (c6) at least one aminocarboxylic acid selected from the group consisting of naturally occurring amino acids, polyamides obtained by polycondensation of dicarboxylic acids having 4 to 6 carbon atoms with diamines having 4 to 10 carbon atoms, and compounds of formula IVa and formula IVb;

[0143] [ka]

[0144] [ka] [wherein s is an integer from 1 to 1500, t is an integer from 1 to 4, and T is phenylene, (CH2) u - (wherein u is an integer from 1 to 12), C(R2)H, and C(R2)HCH2 (wherein R2 is methyl or ethyl), and a polyoxazoline having repeating units V,

[0145] [ka] [Where, R 3 is hydrogen, C1-C6-alkyl, C5-C8-cycloalkyl, phenyl (unsubstituted or with up to three C1-C4-alkyl substituents), or tetrahydrofuryl. Or, it is a compound selected from a mixture consisting of (c1) to (c6). (D) is (d1) at least one compound having at least three groups capable of ester formation; (d2) at least one isocyanate; (d3) at least one divinyl ether; Or, it is a compound selected from a mixture consisting of (d1) to (d3).

[0146] The acid component A of the semi-aromatic polyester may contain 30 to 70 mol %, in particular 40 to 60 mol %, of a1 and 30 to 70 mol %, in particular 40 to 60 mol % of a2.

[0147] The usable aliphatic acids and corresponding derivatives a1 generally have 2 to 10 carbon atoms. They may be linear or branched. The cycloaliphatic dicarboxylic acids generally have 7 to 10 carbon atoms, in particular 8 carbon atoms. In principle, however, it is also possible to use dicarboxylic acids with more carbon atoms (for example up to 30 carbon atoms). Examples include, but are not limited to, malonic acid, succinic acid, 2-methylglutaric acid, 3-methylglutaric acid, adipic acid, pimelic acid, azelaic acid, sebacic acid, fumaric acid, 2,2-dimethylglutaric acid, suberic acid, 1,3-cyclopentanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, oxydiacetic acid, itaconic acid, maleic acid, brassylic acid, and 2,5-norbornanedicarboxylic acid. Also usable and mentionable are the ester-forming derivatives of the abovementioned aliphatic or cycloaliphatic dicarboxylic acids, in particular the di-C1-C6-alkyl esters, such as the dimethyl, diethyl, di-n-propyl, diisopropyl, di-n-butyl, diisobutyl, di-t-butyl, di-n-pentyl, diisopentyl or di-n-hexyl esters. It is also possible to use the anhydrides of the dicarboxylic acids.

[0148] The dicarboxylic acids or ester-forming derivatives thereof may be used individually or in the form of a mixture composed of two or more of them.

[0149] In another embodiment, succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, or their respective ester-forming derivatives, or mixtures thereof, may be used. When preparing a polymer mixture containing a "hard" or "brittle" component (e.g., polyhydroxybutyrate or especially polylactide), the aliphatic dicarboxylic acid may include sebacic acid or a mixture of sebacic acid and adipic acid. In another embodiment, when preparing a polymer mixture containing a "soft" or "tough" component (e.g., polyhydroxybutyrate-co-valerate), the aliphatic dicarboxylic acid may include succinic acid or a mixture of succinic acid and adipic acid.

[0150] Another advantage of succinic acid, azelaic acid, sebacic acid, and brassylic acid is that they are readily available, renewable raw materials.

[0151] The aromatic dicarboxylic acids a2 which may be mentioned generally have 8 to 12 carbon atoms, preferably 8 carbon atoms. By way of example, mention may be made of terephthalic acid, isophthalic acid, 2,6-naphthoic acid and 1,5-naphthoic acid, as well as their ester-forming derivatives. Here, mention may be made in particular of di-C1-C6-alkyl esters, such as the dimethyl, diethyl, di-n-propyl, diisopropyl, di-n-butyl, diisobutyl, di-t-butyl, di-n-pentyl, diisopentyl or di-n-hexyl esters. Also suitable ester-forming derivatives are the anhydrides of the dicarboxylic acids a2.

[0152] In principle, however, aromatic dicarboxylic acids (a2) with more carbon atoms (eg up to 20 carbon atoms) can be used.

[0153] The aromatic dicarboxylic acids or their ester-forming derivatives (a2) may be used individually or as a mixture of two or more thereof.

[0154] The sulfonic acid group-containing compound (a3) ​​is usually one of the alkali metal or alkaline earth metal salts of a dicarboxylic acid or an ester-forming derivative thereof containing a sulfonic acid group, such as the alkali metal salts of 5-sulfoisophthalic acid or mixtures thereof.

[0155] In one embodiment, acid component A comprises 40-60 mol% of a1, 40-60 mol% of a2, and 0-2 mol% of a3, in another embodiment, acid component A comprises 40-59.9 mol% of a1, 40-59.9 mol% of a2, and 0.1-1 mol% of a3, in particular 40-59.8 mol% of a1, 40-59.8 mol% of a2, and 0.2-0.5 mol% of a3.

[0156] Diol B is generally selected from the group consisting of branched or linear alkanediols having 2 to 12 carbon atoms or from the group consisting of cycloalkanediols having 5 to 10 carbon atoms. Examples of alkanediols are ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,4-butanediol, 1,5-pentanediol, 2,4-dimethyl-2-ethyl-1,3-hexanediol, 2,2-dimethyl-1,3-propanediol, 2-ethyl-2-butyl-1,3-propanediol, 2-ethyl-2-isobutyl-1,3-propanediol, and 2,2,4-trimethyl-1,3-hexanediol. ,6-hexanediol, in particular ethylene glycol, 1,3-propanediol, 1,4-butanediol, or 2,2-dimethyl-1,3-propanediol (neopentyl glycol), cyclopentanediol, 1,4-cyclohexanediol, 1,2-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, 1,4-cyclohexanedimethanol, or 2,2,4,4-tetramethyl-1,3-cyclobutanediol. Particular preference is given to 1,4-butanediol, in particular in combination with adipic acid as component (a1) and to 1,3-propanediol, in particular in combination with sebacic acid as component (a1). Another advantage of 1,3-propanediol is that it is an easily available and renewable raw material. It is also possible to use mixtures of different alkanediols.

[0157] Depending on whether excess acid groups or excess OH end groups are required, either component A or component B may be used in excess. In a preferred embodiment, the molar ratio of components A and B used may be from 0.4:1 to 1.5:1, preferably from 0.6:1 to 1.1:1.

[0158] In addition to components A and B, the polyester may contain other components.

[0159] Dihydroxy compounds (c1) that can be used are diethylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol and polytetrahydrofuran (polyTHF), particularly preferably diethylene glycol, triethylene glycol and polyethylene glycol, and mixtures thereof can also be used. Likewise, compounds with different n variables (see formula I) can also be used, such as polyethylene glycols containing propylene units (n=3) (obtained, for example, by polymerization methods known per se, first with ethylene oxide and then with propylene oxide), particularly preferably polymers based on polyethylene glycols with different n variables (units formed from ethylene oxide predominate). The molar mass (M n ) is generally selected within the range of 250 to 8000 g / mol, preferably 600 to 3000 g / mol.

[0160] In one embodiment for preparing a semi-aromatic polyester, for example, 15 to 98 mol %, preferably 60 to 99.5 mol %, of diol B and 2 to 85 mol %, preferably 0.5 to 40 mol %, of dihydroxy compound (c1) may be used, based on the molar amounts of B and (c1).

[0161] In a preferred embodiment, the hydroxycarboxylic acids (c2) used are glycolic acid, D-, L- or D,L-lactic acid, 6-hydroxyhexanoic acid, their cyclic derivatives such as glycolide (1,4-dioxane-2,5-dione), D- or L-dilactide (3,6-dimethyl-1,4-dioxane-2,5-dione), p-hydroxybenzoic acid, or their oligomers and polymers such as 3-polyhydroxybutyric acid, polyhydroxyvaleric acid, polylactide (available, for example, as NatureWorks® 4042D (NatureWorks)), or mixtures of 3-polyhydroxybutyric acid and polyhydroxyvaleric acid (available from PHB Industrial, Tianan or Metabolix), and, for the preparation of semi-aromatic polyesters, particularly preferred are their low molecular weight cyclic derivatives.

[0162] Examples of amounts of hydroxycarboxylic acid that can be used are, based on the amounts of A and B, 0.01 to 50% by weight, preferably 0.1 to 40% by weight.

[0163] Amino-C2-C 12 Alkanol or Amino-C5-C 10 The cycloalkanol (component c3) may comprise 4-aminomethylcyclohexanemethanol, preferably an amino-C2-C6 alkanol such as 2-aminoethanol, 3-aminopropanol, 4-aminobutanol, 5-aminopentanol, or 6-aminohexanol, or an amino-C5-C6 cycloalkanol such as aminocyclopentanol and aminocyclohexanol, or mixtures thereof.

[0164] The diamino-C1-C8 alkane used (component c4) is preferably a diamino-C4-C6 alkane such as 1,4-diaminobutane, 1,5-diaminopentane or 1,6-diaminohexane (hexamethylenediamine "HMD").

[0165] In one embodiment for preparing a semi-aromatic polyester, 0.5 to 99.5 mol %, preferably 0.5 to 50 mol %, of (c3) based on the molar amount of B, and 0 to 50 mol %, preferably 0 to 35 mol %, of (c4) based on the molar amount of B may be used.

[0166] The 2,2'-bisoxazoline (c5) of formula III can generally be obtained by the process of Angew. Chem. Int. Edit., Vol. 11 (1972), pp. 287-288. 1 is a single bond, (CH2) z -alkylene (where z=2, 3 or 4), for example methylene, ethane-1,2-diyl, propane-1,3-diyl or propane-1,2-diyl, or a phenylene group. Particularly preferred bisoxazolines which may be mentioned are 2,2'-bis(2-oxazoline), bis(2-oxazolinyl)methane, 1,2-bis(2-oxazolinyl)ethane, 1,3-bis(2-oxazolinyl)propane and 1,4-bis(2-oxazolinyl)butane, in particular 1,4-bis(2-oxazolinyl)benzene, 1,2-bis(2-oxazolinyl)benzene or 1,3-bis(2-oxazolinyl)benzene.

[0167] In preparing the semi-aromatic polyester, for example, 70 to 98 mol % of B, up to 30 mol % of (c3), 0.5 to 30 mol % of (c4), and 0.5 to 30 mol % of (c5), in each case based on the total molar amount of components B, c3, c4, and c5, may be used. In another embodiment, 0.1 to 5 wt %, preferably 0.2 to 4 wt %, of (c5), based on the total weight of A and B, may be used.

[0168] The component (c6) used may be a naturally occurring aminocarboxylic acid, including valine, leucine, isoleucine, threonine, methionine, phenylalanine, tryptophan, lysine, alanine, arginine, aspartic acid, cysteine, glutamic acid, glycine, histidine, proline, serine, tyrosine, asparagine and glutamine.

[0169] Preferred aminocarboxylic acids of formula IVa and formula IVb are those in which s is an integer from 1 to 1000, t is an integer from 1 to 4, preferably 1 or 2, and T is phenylene and -(CH2) u - (wherein u is 1, 5, or 12).

[0170] (c6) may also be a polyoxazoline of formula V, provided that (c6) may be a mixture of different aminocarboxylic acids and / or polyoxazolines.

[0171] In one embodiment, the amount of (c6) used may be 0.01 to 50% by weight, preferably 0.1 to 40% by weight, based on the total amount of components A and B.

[0172] Other compounds which can optionally be used to prepare the semi-aromatic polyester include compounds (d1) which contain at least three groups capable of ester formation.

[0173] The compound (d1) may contain 3 to 10 functional groups capable of forming ester bonds. Particularly preferred compounds (d1) have 3 to 6 functional groups of this type in the molecule, in particular 3 to 6 hydroxyl and / or carboxyl groups. Examples to be mentioned are tartaric acid, citric acid, maleic acid, trimethylolpropane, trimethylolethane, pentaerythritol, polyethertriols, glycerol, trimesic acid, trimellitic acid, trimellitic anhydride, pyromellitic acid, pyromellitic dianhydride, and hydroxyisophthalic acid.

[0174] The amount of compound (d1) used is generally 0.01 to 15 mol %, preferably 0.05 to 10 mol %, particularly preferably 0.1 to 4 mol %, based on component A.

[0175] The component (d2) used is an isocyanate or a mixture of different isocyanates. Aromatic or aliphatic diisocyanates may be used. However, polyfunctional isocyanates may also be used. The aromatic diisocyanate d2 is in particular tolylene 2,4-diisocyanate, tolylene 2,6-diisocyanate, diphenylmethane 2,2'-diisocyanate, diphenylmethane 2,4'-diisocyanate, diphenylmethane 4,4'-diisocyanate, naphthylene 1,5-diisocyanate or xylene diisocyanate. By way of example, it is also possible to use the isocyanates available under the trademark Basonat® from BASF SE.

[0176] Of these, diphenylmethane 2,2'-, 2,4'- and 4,4'-diisocyanates are particularly preferred as component (d2), the latter diisocyanates generally being used as mixtures.

[0177] A tricyclic isocyanate (d2) which can also be used is tri(4-isocyanophenyl)methane. Polycyclic aromatic diisocyanates arise, for example, during the preparation of monocyclic or bicyclic diisocyanates.

[0178] Component (d2) may also contain subsidiary amounts (eg up to 5% by weight), based on the total weight of component (d2), of uretdione groups, for example to cap isocyanate groups.

[0179] The aliphatic diisocyanates (d2) are primarily linear or branched alkylene or cycloalkylene diisocyanates having 2 to 20 carbon atoms, preferably 3 to 12 carbon atoms, such as hexamethylene 1,6-diisocyanate, isophorone diisocyanate, or methylenebis(4-isocyanatocyclohexane). Hexamethylene 1,6-diisocyanate and isophorone diisocyanate are particularly preferred aliphatic diisocyanates (d2).

[0180] Preferred isocyanurates include C2-C 20 (Preferably C3-C 12 ) or aliphatic isocyanurates derived from alkylene diisocyanates (e.g., isophorone diisocyanate or methylene bis(4-isocyanatocyclohexane)), where the alkylene diisocyanates may be linear or branched. Particularly preferred are isocyanurates based on n-hexamethylene diisocyanate, such as cyclic trimers, pentamers, or higher oligomers of n-hexamethylene diisocyanate.

[0181] The amount of the compound (d2) used is generally 0.01 to 5 mol %, preferably 0.05 to 4 mol %, and particularly preferably 0.1 to 4 mol %, based on the total molar amount of A and B.

[0182] The divinyl ethers (d3) which can be used are generally any of the customary divinyl ethers available commercially. It is preferable to use 1,4-butanediol divinyl ether, 1,6-hexanediol divinyl ether, 1,4-cyclohexanedimethanol divinyl ether, or mixtures thereof.

[0183] The amount of the divinyl ether used is preferably 0.01 to 5% by weight, particularly preferably 0.2 to 4% by weight, based on the total weight of A and B.

[0184] Examples of semi-aromatic polyesters are based on components such as (A, B, d1), (A, B, d2), (A, B, d1, d2), (A, B, d3), (A, B, c1), (A, B, c1, d3), (A, B, c3, c4), (A, B, c3, c4, c5), (A, B, d1, c3, c5), (A, B, c3, d3), (A, B, c3, d1), (A, B, c1, c3, d3), or (A, B, c2). Of these, particularly preferred are semi-aromatic polyesters based on (A, B, d1), (A, B, d2), or (A, B, d1, d2). In another preferred embodiment, the semi-aromatic polyester is based on (A, B, c3, c4, c5) or (A, B, d1, c3, c5).

[0185] The polyester polymers according to the above disclosure are biodegradable polyester polymers, however, it is understood that they may be non-biodegradable without departing from the scope of the present disclosure.

[0186] In one suitable example, the carrier material includes both a polysaccharide material, such as a cellulosic material, and a thermoplastic material, such as a polyester, For example, in such an embodiment, the thermoplastic material may comprise from about 20 to about 40 weight percent, 20 to about 60 weight percent, or 20 to about 80 weight percent of the bait matrix 124.

[0187] Some suitable compositions for the conductive bait matrix 1400 are shown in Table 1a.

[0188] Table 1a:

[0189] [Table 2]

[0190] Some suitable compositions for the non-conductive bait matrix 1402 are shown in Table 1b.

[0191] Table 1b:

[0192] [Table 3]

[0193] It will be appreciated that other suitable manufacturing processes are contemplated for combining the carrier materials, such as, but not limited to, co-extrusion, compression, dipping, molding, suspension, and the like.

[0194] One way to create a workpiece is to (1) A mixture of the following: a. A softening or melting thermoplastic polymer with a softening or melting point below about 220°C b. Target pest feeding stimulant materials (i.e., materials that increase the palatability of the matrix for consumption purposes and are considered "digestible" or "nutritious," although such benefits may not be present). c. Materials containing conductive particles and / or phagostimulant particles and (2) shaping the mixture to provide a workpiece of a desired shape; (3) cooling the workpiece to a temperature below the softening or melting point of the plastic to provide a solid composite article; Includes.

[0195] Preferably, one work piece is or includes a conductive bait matrix 1400 .

[0196] Another way to create a workpiece is (1) A mixture of the following: a. A softening or melting thermoplastic polymer with a softening or melting point below about 220°C b. Feeding stimulant material for the target pest (i.e., a "digestible" or "nutritious" ingredient); c. Optional additional ingredients. and (2) shaping the mixture to provide a workpiece of a desired shape; (3) cooling the workpiece to a temperature below the softening or melting point of the plastic to provide a solid composite article; Includes.

[0197] Another suitable work piece may be or may include a non-conductive bait matrix 1402 .

[0198] As used herein, the term "molten" is intended to refer to the state of a material where a thermoplastic material is completely melted, partially melted, softened or viscous enough to allow the polymer to be formed into a plastic matrix, for example, by extrusion or molding and subsequent cooling. Similarly, the term "melting point" as used herein is intended to refer to the temperature at which a given material (polymer or mixture of polymers) melts, softens or viscous, including the glass transition temperature of an amorphous polymer. As will be appreciated by those skilled in the art, the melting point of a given material (polymer or mixture of polymers) can be altered by contacting the material (polymer or mixture of polymers) with certain solvents and / or other additives. In one embodiment, the workpiece is formed by extrusion.

[0199] To make a solid composite article according to one embodiment, a mixture of granular or particulate thermoplastic polymer, a feeding stimulant material for a target pest, and a material including a plurality of conductive and / or phagostimulant particles is prepared, and then the components are combined by compounding and extruded or molded at a predetermined temperature and pressure. In one suitable embodiment, the combination of graphite and polymer is phagostimulant, as opposed to the polymer alone. The polymer, the feeding stimulant material, and the material including a plurality of phagostimulant particles can be combined by combining the components and driving off excess moisture using standard mixing or compounding techniques. For example, the materials can be combined in a rotary mixer or compounding extruder. Heat is optionally applied to heat the mixture to a temperature high enough to render the thermoplastic polymer flexible or plastic and suitable for molding, such as by extrusion. In one embodiment, the temperature is at least as high as the melting point of the polymer. In another embodiment, the temperature is at least as high as the glass transition temperature of the polymer.

[0200] Those skilled in the art will recognize that higher temperatures may be required and that the processing temperature can be optimized to process the polymer without increasing the temperature to a temperature that would cause significant harm to other components of the composite, such as charring of digestible or nutritious materials. Those skilled in the art will also recognize that the softening temperature of a thermoplastic material can be modified by including a solvent in the mixture. It is understood that in embodiments where a solvent is present, softening at the surface of the polymer when modified by the solvent will begin at a temperature below the normal melting point of the polymer in the absence of the solvent. In other words, a temperature below the normal melting point of the polymer is considered a suitable molding temperature in embodiments where the solvent is effective to soften the surface of the polymer below its normal melting point.

[0201] A variety of extrusion or molding techniques can be used, many examples of which are known in the art. Although the present application is not limited by any theory, it is believed that under the extrusion or molding conditions applied in the methods described herein, the polymer granules soften, thicken, or completely melt. When this occurs, the pressure applied to the mixture causes the softened polymer granules to contact and adhere to each other, or the polymer to completely melt, so that the molten polymer forms a continuous phase in the mixture. The temperature at which compression is applied is high enough to achieve the desired level of polymer particle adhesion or polymer melting. It is understood that the use of various material specifications (such as type of polymer, polymer size, granule size distribution, and ratio of ingredients) and various process parameters (such as temperature and pressure) can provide products with various advantageous properties. It is within the ability of one of ordinary skill in the art, armed with the present disclosure, to select advantageous combinations of materials and parameters to provide products with different amounts of conductive particles, different levels of palatability, and different physical properties for use as an effective bait matrix in the above-mentioned system without undue experimentation.

[0202] In one aspect of practicing this method, a molten mixture is provided by combining a material comprising a polymer, a phagostimulant (i.e., digestively aiding or nutritious) material, and a plurality of conductive and / or phagostimulant particles to form a mixture, and then kneading the mixture under high pressure and temperature to form a molten material.

[0203] In another mode of carrying out the method, the method includes forming pellets or flakes of the mixture prior to blending.

[0204] In one mode of making a workpiece, all components are mixed together and then heated above the melting point of the thermoplastic polymers involved (e.g., to about 220° C. in some embodiments) in an apparatus that can be cooled in a water bath or spray, after which a particular cross-sectional profile is imparted to the composite, such as a twin-screw mixer, by extrusion through a die.

[0205] In another aspect of forming a workpiece, a material including a polymer, a phagostimulant material, and a plurality of conductive particles and / or phagostimulant particles are combined under positive pressure and elevated temperature in an extruder and then extruded to provide an elongated workpiece.

[0206] In another aspect of forming a workpiece, materials including a thermoplastic polymer and a plurality of conductive particles and / or phagostimulant particles are fed separately and simultaneously upstream into an extruder, and phagostimulant material is added downstream to the extruder.

[0207] In another aspect of forming a workpiece, a thermoplastic polymer, a material including a plurality of conductive particles and / or phagostimulant particles, and a phagostimulant material are fed separately and simultaneously into an extruder.

[0208] It should be appreciated that the manner of forming the workpiece described above may allow for the production of suitable workpieces without using a material that includes a plurality of conductive and / or phagostimulatory particles.

[0209] In a preferred embodiment, the surface of the finished workpiece is structurally non-uniform on the mm to cm scale. In an embodiment, the surface comprises a plurality of cavities with widths of 0.1 mm to 100 mm, 1 mm to 50 mm, 1 mm to 20 mm, and depths of 0.1 mm to 10 mm, 1 mm to 5 mm, 1 mm to 3 mm. The cavities can be of any shape. The cavities can be interconnected or isolated from each other. Individual cavities in the same workpiece can vary in size and shape.

[0210] FIG. 14 shows an exemplary bait matrix 124 having a structurally non-uniform surface.

[0211] In one embodiment, one or more of the parameters of the extrusion process, e.g., temperature, duration, extrusion rate, extrusion additives, post-extrusion treatment, etc., are selected so that the surface of the extruded workpiece contains separate or interconnected cavities having widths between 0.1 mm and 20 mm and depths between 0.1 mm and 5 mm.

[0212] Those skilled in the art will appreciate that parameters of the extrusion process that result in surface imperfections / structural inhomogeneities on the workpiece. For example, the melting point of the thermoplastic semi-crystalline polymer being extruded may be T m As a result, at most T m +80℃, T m +70℃ or T m By applying an extrusion temperature of +60° C., the surface can be made structurally non-uniform.

[0213] Cooling can be accomplished, for example, by immersing the workpiece in a water bath or by spraying the workpiece with water.

[0214] In another embodiment, the surface of the finished workpiece is structurally uniform, i.e., has few or no visible voids on the mm- to cm-scale.

[0215] 15 is a cross-section of one suitable embodiment of the bait matrix 124. As can be readily seen, the phagostimulatory or non-soluble biomarkers (schematically represented by circles 1600) and carrier material particles (schematically represented by squares 1602) are randomly interspersed throughout both the thickness and height of the bait matrix 124.

[0216] 16, in another possible embodiment of the bait matrix 124, the bait matrix 124 may be formed by a process of co-extrusion to have multiple distinct layers 1700. In such an embodiment, a layer of conductive particles 1600 is extruded simultaneously with a layer of support material particles 1602 such that the layer of support material particles 1602 covers the outer surface of the layer of conductive particles 1600. Optionally, the layer of conductive particles 1600 may be sandwiched between layers of support material particles 1602. EXAMPLES

[0217] Termite preferences for specific bait matrix compounds [Example 1] Termite preference for graphite (conductive bait matrix) Activity areas comprised of 100 mm x 20 mm polystyrene dishes were filled (approximately 5 mm deep) with QuickStone® experimental rocks (Whip Mix Corp., Louisville, KY) mixed according to the manufacturer's instructions. The QuickStone® experimental rocks were stored for 24 hours before use. 5 ml of purified water was added to each activity area for initial hydration, and excess water was discarded after 2 hours, and the surface was wiped lightly. Uniformly sized (approximately 1.0 x 1.0 x 0.5 cm (10 replicates of each composition)) bait portions of two different bait matrix compositions, either with Ecoflex® and graphite or with Ecoflex® and no graphite, were weighed and individually placed into plastic shipping dishes (4 cm x 4 cm with openings cut into both walls for termite access). Nutrient-free 5% agar plugs (approximately 0.5 cm x 1.0 cm) were added to each arena as a water source. Agar plugs were replaced every 3-4 days, and approximately 0.25 ml of purified water was added to the surface of each arena every 4 days. Approximately 100 termites (workers and approximately 10% soldiers by weight) were transferred to each arena. Test specimens were maintained at 27°C and 80% RH. After 2 weeks, bait samples were removed from the arena and oven-dried at 110°F for approximately 24 hours. Baits were weighed and the difference in weight before and after removal of the bait by termites was compared as an indicator of bait acceptance. Bait removal resulted from a combination of consumption, presentation (feeding of soldiers by workers), and application of bait to the arena surface.

[0218] conclusion As shown by the data in Table 2, the matrix acceptance of Ecoflex® with graphite was much greater than that of Ecoflex® without graphite.

[0219] Table 2. Relative consumption data for the "conductive part of the assembly" ("KA" containing a mixture of Ecoflex®, Lattice® NT 100 (a form of microcrystalline cellulose), and graphite (Asbury® 4848)) and the "non-conductive part of the assembly" ("HW" containing Ecoflex® and Lattice® NT 100 (a form of microcrystalline cellulose)). In a no-choice test (t-test, 0.05% level), acceptance of KA was significantly greater than acceptance of HW.

[0220] [Table 4]

[0221] [Example 2] Termite Preference for Ecoflex® Materials Objective: To determine whether Coptotermes formosanus and Reticulitermes flavipes prefer certain bait matrix components, three experimental bait matrices, shown in Table 3, were presented to termites using no-choice and single-dish choice procedures.

[0222] Table 3. Prototype matrices evaluated for acceptance by C. formosanus and R. flavipes

[0223] [Table 5]

[0224] Each type of bait sample used equal percentages (X%) of Ecoflex®, CAB, and CAP, combined with the same percentages of NT100 (Y%) and graphite (Z%). X, Y, and Z each represent a specific percentage of the bait composition and are consistent between samples (e.g., X% is the same between bait samples (Ecoflex®, CAB, and CAP)). In one suitable embodiment, X has a value of 35, Y has a value of 55, and Z has a value of 10.

[0225] No-choice test: Arenas consisting of 100 mm x 20 mm polystyrene dishes were filled (approximately 5 mm deep) with QuickStone® experimental stones (Whip Mix Corp., Louisville, KY) mixed according to the manufacturer's instructions. QuickStone® was stored for 24 hours before use. 5 ml of purified water was added to each arena for initial hydration, and excess water was discarded after 2 hours, and the surface was wiped lightly. Uniformly sized bait pieces (10 replicates) or pine pieces (4 replicates) were weighed and individually placed in plastic transfer dishes (4 cm x 4 cm with openings cut into both walls for termite access). Nutrient-free 5% agar plugs (approximately 0.5 cm x 1.0 cm) were added to each arena as a water source. Agar plugs were replaced every 3-4 days, and approximately 0.25 ml of purified water was added to the surface of each arena every 4 days. One hundred termites (workers and approximately 10% soldiers by weight) were transferred to each arena. Test samples were maintained at 27°C and 80% relative humidity. After two weeks, the bait / pine samples were removed from the arena and oven dried at 110°F for approximately 24 hours. The baits were weighed and the difference in weight before and after as a result of termite removal of the bait was compared as an indication of bait acceptance. Bait removal occurred as a result of a combination of consumption, presentation (feeding of soldiers by workers), and application of the bait to the arena surface.

[0226] Single-dish selection test: Replicates (three) of the single-plate choice were included to determine whether termites would accept / consume the bait in the presence of wood, following the same procedure as described for the no-choice assay, with pieces of wood added to the activity area.

[0227] result Summary: During the evaluation period, termites of both species were observed to walk and converge on the three prototype baits. After 48 hours, the bait (marked with graphite) was visible through the body wall in most termites in all territories. Two weeks after infestation, the bait appeared to be more visible in termites in Ecoflex® territories compared to CAB and CAP territories.

[0228] Formosan subterranean termite (Table 4) No-choice test: Bait acceptance of Ecoflex®, as indicated by the amount of material removed from the subsamples, was much greater than that of CAB, CAP, and pine.

[0229] The acceptance of CAP was much less than that of Ecoflex®, CAB, and pine.

[0230] There was no significant difference in acceptance of CAB and pine.

[0231] Single-dish selection test: Termites removed more Ecoflex® (59.37 mg) than pine (20.97 mg). Termites removed less CAB (0.83 mg) than pine (56.43 mg).

[0232] Termites removed less CAP (0.93 mg) than pine (41.60 mg).

[0233] Yamato Termite (Table 4) No-choice test: There were no significant differences in acceptance of Ecoflex®, CAB, and pine.

[0234] The acceptance of CAP was much less than that of Ecoflex®, CAB, and pine.

[0235] Single-dish selection test: Termites removed more Ecoflex® (66.63 mg) than pine (11.03 mg).

[0236] Termites removed less CAB (35.37 mg) than pine (59.17 mg).

[0237] Termites removed less CAP (11.83 mg) than pine (74.30 mg).

[0238] conclusion Ecoflex® was readily accepted by Coptotermes formosanus and Reticulitermes flavipes in both no-choice and single-dish choice (bait and pine) experimental procedures.

[0239] In the no-choice assay, bait acceptance of CAP (containing CE polymer 26627) was much less than that of Ecoflex® and CAB (containing CE polymer 24647).

[0240] In single-plate choice experimental assays, bait acceptance of CAB and CAP was greatly reduced when paired with a pine food source.

[0241] In single-plate choice experimental assays, Ecoflex® bait acceptance was greater than the pine food source.

[0242] Table 4. Acceptance of three prototype Trelona™ MY termite bait matrices, Ecoflex® (thermoplastic material = Ecoflex®), CAB (thermoplastic material = CAB), and CAP (thermoplastic material = CAP), by Coptotermes formosanus and Reticulitermes flavipes. 1 .

[0243] [Table 6]

[0244] [Example 3] The data in Table 5 below show the different preferences for Ecoflex® bait matrix. In a field study, three bait matrix compositions were exposed to Formosan subterranean termites for four weeks. The three baits used were a) a mixture of cellulose (Y%), cellulose acetate propionate CAP (X%), and graphite (Z%), b) a mixture of cellulose (Y%), Ecoflex® (X%), and graphite (Z%), and c) a mixture of cellulose (Y%), cellulose acetate butyrate CAB (X%), and graphite (Z%). X, Y, and Z each represent a specific percentage of the bait composition and are consistent between samples (e.g., X% is the same between baits a), b), and c). Replicates of the three different baits were placed in buckets in the ground and fed to termite colonies over a period of 30 days. At the beginning of the study, an estimate of the number of termites that were led to the bucket was provided, and at the completion of the study, an estimate of the number of termites remaining in the bucket was provided. Some buckets contained multiple bait matrices as shown in the table below. Other buckets contained individual matrices. Buckets 3-6 were placed close to each other around the same location (tree) and buckets 7-10 were placed close to each other around the same location (second tree). After a 30 day period, the baits were removed from the buckets and consumption was observed and assessed, and the baits were weighed.

[0245] conclusion Termites showed a clear preference for bait (b) (Ecoflex® blend) over bait (a) (CAP blend) and bait (c) (CAB blend), regardless of colony size and whether the baits were presented individually or in combination with each other.

[0246] Table 5. Preference data from field trials comparing termite preference for (a) CAP blended bait, (b) Ecoflex® blended bait, and (c) CAB blended bait after 30 days of consumption.

[0247] [Table 7]

[0248] The present invention includes the following aspects. [Section 1] 1. A pest monitoring system comprising: a circuit, the circuit initially in a first impedance state configured to change to a second impedance state due to pest activity, the second impedance state being lower than the first impedance state. [Section 2] The circuit, a first electrode having a first electrical potential; a second electrode not initially in contact with the first electrode and used in combination with the first electrode to sense pest activity; Item 1, comprising: a pest monitoring system according to item 1. [Section 3] Item 3. The pest monitoring system of item 2, further comprising an optional bait matrix disposed adjacent to the circuit. [Section 4] Item 4. The pest monitoring system of item 3, wherein the bait matrix at least partially surrounds the first electrode and the second electrode. [Section 5] Item 3. The pest monitoring system of item 2, wherein one of a) material deposited by pests harvesting the bait matrix and b) moisture ingress creates a measurable impedance between the first electrode and the second electrode that closes an open circuit. [Section 6] Item 6. The pest monitoring system of item 5, wherein a change in impedance between the first electrode and the second electrode produces a measurable electrical characteristic that, if present, is indicative of uptake of the bait matrix by a pest. [Section 7] Item 4. The pest monitoring system of item 3, further comprising a water-resistant member disposed between the bait matrix and the first and second electrodes and configured to prevent moisture ingress into the first and second electrodes prior to the presence of pest activity. [Section 8] formed of an electrically insulating material; providing a base to which the first electrode and the second electrode are attached; Facilitating proper placement of the first electrode and the second electrode; and The first electrode and the second electrode are prevented from contacting each other. Item 3. The pest monitoring system of item 2, further comprising a non-conductive gap configured to: [Section 9] Item 1. The pest monitoring system of item 1, further comprising a control unit configured to generate a first electrical signal to the first electrode via a first terminal and monitor the second electrode via a second terminal. [Section 10] The control unit: Measuring an electrical characteristic between the first electrode and the second electrode; and determining the presence or absence of pests based on the measured electrical characteristics; Item 10. The pest monitoring system of item 9, further configured to: [Section 11] a circuit initially in a first impedance state configured to change to a second impedance state due to pest activity, the second impedance state being lower than the first impedance state; a control unit configured to determine the presence or absence of pests based on the measured electrical characteristics of the circuit; A pest monitoring system comprising: [Section 12] The circuit, a first electrode having a first electrical potential; a second electrode not initially in contact with the first electrode and used in combination with the first electrode to sense pest activity; Item 12. The pest monitoring system according to item 11, comprising: [Section 13] Item 13. The pest monitoring system of item 12, wherein the control unit is further configured to detect a change in impedance between the first electrode and the second electrode. [Section 14] 12. The pest monitoring system of claim 11, wherein the control unit is further operable to transmit a signal indicative of the presence of a pest. [Section 15] Item 12. The pest monitoring system of item 11, wherein the measured electrical property is one of electrical resistance and electrical reactance. [Section 16] a circuit initially in a first impedance state configured to change to a second impedance state due to pest activity, the second impedance state being lower than the first impedance state; a control unit configured to transmit a pest presence signal based on the detected change in impedance; A bait station comprising: a central device of a structure connection system, the central device being configured to receive the pest presence signal from the bait station; and A pest monitoring system comprising: [Section 17] Item 17. The pest monitoring system of item 16, wherein the bait stations are configured to communicate directly with the central device. [Section 18] Item 18. The pest monitoring system of item 17, wherein the bait stations communicate directly with the central device using a wireless connection. [Section 19] Item 17. The pest monitoring system of item 16, wherein the central device is further configured to generate an alarm indicating the presence of a pest at the bait station. [Section 20] 20. The pest monitoring system of claim 19, wherein the central device transmits the alert to at least one of a technology owner, a certified service provider, and an owner of the structure. [Section 21] 20. The pest monitoring system of claim 19, wherein the central device is connected to a telecommunications network and transmits the alerts using at least one of a WiFi connection, a cellular connection, an Internet connection, and an Ethernet connection. [Section 22] 20. The pest monitoring system of claim 19, wherein the central device is configured to issue the alarm by controlling an output of at least one of a smart television, a light, and a doorbell of the structure. [Section 23] Item 17. The pest monitoring system of item 16, further comprising a plurality of bait stations, each of the plurality of bait stations in direct communication with the central device. [Section 24] 17. The pest monitoring system of claim 16, wherein the connection system comprises a home security system. [Section 25] A pest monitoring system comprising one or more water resistant stations, each water resistant station comprising one or more circuits for monitoring changes in impedance, said changes in impedance being used as a marker of the presence of a pest. [Section 26] a. one or more waterproof stations comprising one or more circuits, the one or more circuits monitoring impedance; b. one or more control units in communication with the one or more circuits, the one or more control units detecting any change in impedance and generating a signal; c. one or more gateways in communication with said one or more control units, said one or more gateways receiving said signals and acting as packet forwarders to a network server; d. one or more application platforms that receive the signals and interpret the change in impedance as indicative of the presence of a pest; A pest monitoring system comprising: [Section 27] A pest monitoring system comprising a control unit that detects changes in impedance between two or more electrodes, the control unit transmitting one or more signals indicative of the changes in electrical potential across the two or more electrodes. [Section 28] Item 28. The pest monitoring system of item 27, further comprising a waterproof housing that holds the electrodes. [Section 29] 30. The pest monitoring system of claim 27 or 28, wherein the signal is transmitted to a central device. [Section 30] 30. The pest monitoring system of claim 27 or 28, wherein the signal is transmitted to a data collection service. [Section 31] Item 29. The pest monitoring system of item 27 or 28, wherein the signal is transmitted to a cloud server. [Section 32] Item 29. The pest monitoring system of item 27 or 28, wherein the signal is transmitted to a home monitoring system. [Section 33] 30. The pest monitoring system of claim 27 or 28, wherein the signal is transmitted directly to a pest control professional. [Section 34] A bait matrix composition comprising a consumable marker material, said material facilitating the determination of active consumption of said consumable marker material. [Section 35] Item 35. The bait matrix of item 34, wherein the material comprises carbon-based conductive particles. [Section 36] Item 36. The bait matrix of item 34 or 35, wherein the carbon-based conductive particles are selected from one or more of graphite, carbon nanotube flakes, carbon black, coke, and carbonized carbon powder. [Section 37] 1. A method of facilitating palatability of a pest bait matrix, comprising introducing graphite into said bait matrix. [Section 38] 1. A method for enhancing the palatability of a pest bait matrix, comprising introducing graphite. [Section 39] A bait matrix having enhanced palatability to pests, the bait matrix comprising graphite. When introducing elements of the present invention or preferred embodiments thereof, the articles "a", "an", "the" and "said" mean that there is one or more of the element. The terms "comprising", "including" and "having" are inclusive and mean that there may be other elements than the listed elements, and since various changes can be made in the above configuration without departing from the scope of the present invention, all content contained in the above description or shown in the accompanying drawings is intended to be illustrative only and not to be interpreted in a limiting sense.

[0249] Since various changes may be made in the above configuration without departing from the scope of the present invention, all content contained in the above description or shown in the accompanying drawings is intended to be illustrative only and not to be interpreted in a limiting sense.

Claims

1. A method of detecting a pest infection comprising: a circuit having a first electrode and a second electrode, the circuit being initially in a first impedance state and configured to change to a second impedance state due to pest activity; a water resistant member configured to prevent moisture ingress to the first electrode and the second electrode prior to pest activity, the water resistant member being at least partially removable by termites; A pest monitoring system comprising:

2. Further comprising a control unit, the first electrode includes a first terminal having a first potential; the second electrode is not initially in contact with the first electrode, the second electrode includes a second terminal, and the second electrode is used in combination with the first electrode to sense pest activity; The pest monitoring system of claim 1 , wherein the control unit is removably connected to the first terminal and the second terminal via a connection mechanism.

3. A pest monitoring system as described in claim 2, wherein the control unit detects any change in impedance and generates a signal based on at least one of a predetermined time interval, when a request is received from a gateway, or when the control unit detects any change in impedance.

4. The pest monitoring system of claim 2, wherein the control unit generates one or more signals indicating at least one of a station ID, a report number, a battery voltage measurement result, a confirmed signal strength most recently received from a gateway, low battery status information of the station, or low signal strength information of the station.

5. A pest monitoring system as described in claim 1, wherein moisture intrusion through a water-resistant member produces a measurable impedance change between the first impedance state and the second impedance state.

6. The pest monitoring system of claim 1, wherein a change in impedance from the first impedance state to the second impedance state indicates the taking up of a bait matrix by a pest.

7. A pest monitoring system as described in claim 1, wherein one or more points of interest for pest collection are configured to prevent moisture ingress into the first electrode and the second electrode prior to the presence of pest activity.

8. The pest monitoring system of claim 1, wherein an electrically insulating material defines a non-conductive gap between the first electrode and the second electrode.

9. A pest monitoring system as described in claim 2, wherein the control unit is configured to generate a first electrical signal to the first electrode via a first terminal and monitor the second electrode via a second terminal.

10. The control unit: Measuring an electrical characteristic between the first electrode and the second electrode; and determining the presence or absence of pests based on the measured electrical characteristics; 3. The pest monitoring system of claim 2, further configured to:

Citation Information

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