Electrode assembly, battery, battery pack including same, and automobile

Abstract

The present invention discloses an electrode assembly, a battery, a battery pack including the same, and an automobile. The electrode assembly of the present invention is an electrode assembly in which a first electrode, a second electrode, and a separator interposed therebetween are wound around a single axis to define a core and an outer circumferential surface, at least one of the first electrode and the second electrode includes an uncoated portion at a long side edge along the winding direction that extends beyond the separator and is exposed in the axial direction, at least a portion of the uncoated portion is folded along the radial direction of the electrode assembly to define a folded surface region having overlapping layers of the uncoated portions, the folded surface region having a welding target region having a plurality of overlapping layers of the uncoated portions, and the welding target region extends in the radial direction of the electrode assembly.

Description

[Technical field]

[0001] The present invention relates to an electrode assembly, a battery, a battery pack including the same, and an automobile.

[0002] This application is a continuation of Korean Patent Application No. 10-2021-0022854 filed on February 19, 2021, Korean Patent Application No. 10-2021-0022894 filed on February 19, 2021, Korean Patent Application No. 10-2021-0022891 filed on February 19, 2021, Korean Patent Application No. 10-2021-0030300 filed on March 8, 2021, and Korean Patent Application No. 10-2021-0030300 filed on March 8, 2021. Priority is claimed based on Korean Patent Application No. 10-2021-0131215 filed on October 1, 2021, Korean Patent Application No. 10-2021-0131205 filed on October 1, 2021, and Korean Patent Application No. 10-2021-0142197 filed on October 22, 2021, and the contents disclosed in the specifications and drawings of such applications are incorporated into this application in their entirety. [Background technology]

[0003] Secondary batteries, which have high applicability to each product group and electrical properties such as high energy density, are widely used not only in portable devices but also in electric vehicles (EVs) and hybrid electric vehicles (HEVs) that are driven by electric driving sources.

[0004] Such secondary batteries not only have the primary advantage of dramatically reducing the use of fossil fuels, but also have the advantage of not producing any by-products from energy use, making them environmentally friendly and drawing attention as a new energy source for improving energy efficiency.

[0005] Currently, secondary batteries such as lithium ion batteries, lithium polymer batteries, nickel cadmium batteries, nickel hydrogen batteries, and nickel zinc batteries are widely used. The operating voltage of such unit secondary batteries, i.e., unit batteries, is about 2.5V to 4.5V. Therefore, when a higher output voltage is required, a battery pack is constructed by connecting a plurality of batteries in series. In addition, a battery pack may be constructed by connecting a plurality of batteries in parallel according to the charge / discharge capacity required for the battery pack. Therefore, the number of batteries included in the battery pack and the electrical connection form may be variously set according to the required output voltage and / or charge / discharge capacity.

[0006] Meanwhile, known types of unit secondary batteries include cylindrical, prismatic and pouch-type batteries. In the case of a cylindrical battery, a separator, which is an insulator, is interposed between a positive electrode and a negative electrode, and the separator is wound up to form a jelly-roll-type electrode assembly, which is then inserted into a battery housing to form a battery. A strip-shaped electrode tab is connected to each uncoated portion of the positive electrode and the negative electrode, and the electrode tab electrically connects the electrode assembly to an electrode terminal exposed to the outside. For reference, the positive electrode terminal is a sealed cap that seals the open portion of the battery housing, and the negative electrode terminal is the battery housing. However, according to a conventional cylindrical battery having such a structure, current is concentrated in the strip-shaped electrode tab connected to the positive electrode uncoated portion and / or the negative electrode uncoated portion, which results in high resistance, high heat generation and poor current collection efficiency.

[0007] Resistance and heat generation are not a big issue for small cylindrical batteries with form factors such as 1865 and 2170. However, when the form factor of a cylindrical battery is increased to be used in an electric vehicle, a large amount of heat is generated around the electrode tabs during the fast charging process, which can cause the cylindrical battery to catch fire.

[0008] To solve these problems, a cylindrical battery (so-called tab-less cylindrical battery) has been proposed in which positive and negative uncoated areas are designed to be located at the top and bottom of a jelly-roll type electrode assembly, respectively, and current collectors are welded to these uncoated areas to improve current collection efficiency.

[0009] Figures 1 to 4 are diagrams showing the manufacturing process of a tabless cylindrical battery. Figure 1 shows the structure of an electrode, Figure 2 shows the electrode winding process, Figure 3 shows the process of folding uncoated parts 32, 33 using a forming jig 30, and Figure 4 shows the state in which current collectors 34, 35 are welded to the folded surface areas of uncoated parts 32, 33.

[0010] 1 to 4, the positive electrode 10 and the negative electrode 11 have a structure in which an active material 21 is coated on a sheet-like conductive substrate 20, and include a plain portion 22 on one long side along the winding direction X.

[0011] The electrode assembly A is fabricated by sequentially stacking a positive electrode 10 and a negative electrode 11 together with two separators 12 as shown in Fig. 2, and then winding the stack in one direction (X-axis direction). At this time, the uncoated portion of the positive electrode 10 and the uncoated portion of the negative electrode 11 are arranged in opposite directions to each other in the direction of the winding axis (Y-axis).

[0012] After the winding process, the uncoated portion 32 of the positive electrode 10 and the uncoated portion 33 of the negative electrode 11 are folded toward the core. Then, plate-shaped current collectors 34 and 35 are welded and joined to the uncoated portions 32 and 33, respectively.

[0013] No separate electrode tabs are attached to the positive electrode uncoated region 32 and the negative electrode uncoated region 33, and current collectors 34 and 35 are connected to external electrode terminals. Since the current path is formed with a large cross-sectional area along the winding axis direction of electrode assembly A (see arrow), this has the advantage of reducing the resistance of the battery. This is because resistance is inversely proportional to the cross-sectional area of ​​the path through which the current flows.

[0014] In order to improve the welding characteristics between the uncoated portions 32, 33 and the current collectors 34, 35 in a tabless cylindrical battery, the uncoated portions 32, 33 must be bent as flat as possible by applying strong pressure to the welding points of the uncoated portions 32, 33.

[0015] In addition, the bent portions of the blank areas 32 and 33 where the current collectors 34 and 35 are welded must be overlapped in multiple places, and the open space (gap) must not be large. This ensures sufficient welding strength, and when using the latest technology such as laser welding, it is possible to prevent the laser from penetrating into the electrode assembly A and melting the separator or active material.

[0016] In order for the plain parts 32 and 33 to overlap uniformly along the radial direction of the electrode assembly A, the plain parts at the corresponding positions must be folded toward the core with the inner winding turn covering the top surface of the folded plain parts based on the position of each winding turn. In addition, when the distance between the plain parts between adjacent winding turns based on the radial direction of the electrode assembly A is d and the folding length of the plain parts located at each winding turn is e, the folding length e must be longer than "d x n (n is a natural number of 2 or more)". Otherwise, no area where the plain parts 32 and 33 overlap multiple times will be generated. In addition, in order to form an area where the same number of the plain parts 32 and 33 overlap with a sufficient length in the radial direction of the electrode assembly A, the lengths of the plain parts 32 and 33 must be sufficiently long. However, since the radius of the electrode assembly included in the small cylindrical battery is small, there is no motivation to come up with the concept of designing the folding length of the plain parts 32 and 33 to be sufficiently long.

[0017] In addition, since a small cylindrical battery has a small diameter of 18 mm, 21 mm, etc., it is difficult to fold the plain parts 32, 33 so that they overlap uniformly in multiple layers. Therefore, when folding the plain parts 32, 33, a forming jig 30 is used to randomly rub and form the ends of the plain parts 32, 33, or a jig 31 that moves up and down is used to repeatedly tap the plain parts 32, 33 to form a folded surface area.

[0018] Furthermore, even if the uncoated portions 32, 33 are folded along the radial direction of the electrode assembly A, the purpose is only to form a folded surface area, and not to finely adjust the overlapping structure of the uncoated portions 32, 33. Therefore, in the electrode assemblies used in conventional small cylindrical batteries, it is difficult to ensure a structure in which the uncoated portions 32, 33 are uniformly overlapped in multiple layers along the core direction of the electrode assembly A. Summary of the Invention [Problem to be solved by the invention]

[0019] The present invention has been made in light of the background of the conventional technology as described above, and has an object to provide an electrode assembly having a plain-portion folding structure that can prevent damage to the separator and active material layer even when the welding output is increased by securing a region of sufficient length where the plain portions are multiple and uniformly overlapped in the radial direction of the electrode assembly when the plain portions exposed at both ends of the electrode assembly are folded.

[0020] Another object of the present invention is to provide an electrode assembly having improved energy density and reduced resistance.

[0021] It is yet another object of the present invention to provide a battery including an electrode assembly of an improved structure, a battery pack including the same, and a vehicle including the battery pack.

[0022] The technical problem that the present invention is to solve is not limited to the above-mentioned problem, and other problems will be clearly understood by those skilled in the art from the following description of the invention. [Means for solving the problem]

[0023] In order to achieve the above-mentioned object, an electrode assembly according to one aspect of the present invention is an electrode assembly in which a first electrode, a second electrode, and a separator interposed therebetween are wound around a single axis to define a core and an outer peripheral surface, at least one of the first electrode and the second electrode includes an uncoated portion at a long side end along the winding direction that is exposed in the axial direction beyond the separator, at least a portion of the uncoated portion is folded along the radial direction of the electrode assembly to define a folded surface region having overlapping layers of the uncoated portions, the folded surface region includes a welding target region having a plurality of overlapping layers of the uncoated portions, and the welding target region extends in the radial direction of the electrode assembly.

[0024] The uncoated portion may have a thickness of 5 μm to 25 μm, and the distance between the uncoated portions of adjacent wound turns may be 350 to 380 μm.

[0025] In the welding target area, the overlapping layer of the non-coating portion may have an average lamination thickness of 25 μm or more.

[0026] In the weld target area, overlapping layers of the non-coated portions may be stacked substantially perpendicular to the axial direction.

[0027] The ratio of the radial length of the weld target area to the radius of the electrode assembly can be 30% or more, optionally 40% or more, optionally 50% or more, optionally 60% or more, optionally 70% or more, or optionally 80% or more.

[0028] A ratio of the radial length of the weld target area to the radius of the electrode assembly may be 30% or more and 90% or less.

[0029] The welding target area may have an average number of overlapping layers of the uncoated portion along a radial direction of the electrode assembly of 5 or more, optionally 6 or more, optionally 7 or more, optionally 8 or more, optionally 9 or more, or optionally 10 or more.

[0030] The welding target region may have an average number of overlapping layers of 5 to 15.

[0031] The remaining portion of the non-coating portion is not folded, and a boundary between the weld target area and the remaining portion of the non-coating portion may be cut along the axial direction.

[0032] The welding target areas may be arranged radially from a core center to an outer periphery of the electrode assembly.

[0033] The welding target areas may be arranged in a cross shape from a core center to an outer periphery of the electrode assembly.

[0034] A current collector may be welded to the weld target area.

[0035] The current collector may be laser or ultrasonically welded to the weld target area.

[0036] The welding pattern between the current collector and the welding target area may include a plurality of dot patterns arranged linearly along a radial direction of the electrode assembly.

[0037] The uncoated portion may include a cut portion in which the height in a direction of a winding axis of the electrode assembly is lower in a region adjacent to a core side or an outer shell side of the electrode assembly than in other regions.

[0038] The portion of the plain section remaining at the cut portion of the plain section does not need to be folded.

[0039] A radial width of a wound turn formed by bending the cut portion of the non-coated portion may be greater than a bending length of the non-coated portion.

[0040] The height of the uncoated portion remaining at the cut portion of the uncoated portion may be 0.2 to 4 mm.

[0041] Before the solid portion is folded, the solid portion may have a maximum height extending along the axial direction of 12 mm.

[0042] The folding depth of the non-colored portion may be 1 mm to 5 mm.

[0043] The electrode having the uncoated portion of the first electrode and the second electrode may have a pair of short sides along the axial direction, and the pair of short sides may have the same length or different lengths.

[0044] The electrode having the uncoated portion of the first electrode and the second electrode has a pair of long sides along the winding direction, and the pair of long sides may have the same length or different lengths.

[0045] In order to achieve the above object, a battery according to another aspect of the present invention is an electrode assembly in which a first electrode, a second electrode, and a separator interposed therebetween are wound around a single axis to define a core and an outer circumferential surface, the first electrode and the second electrode each include an uncoated portion at a long side end along a winding direction, the uncoated portion being exposed in the axial direction beyond the separator, at least a portion of the uncoated portion is folded along a radial direction of the electrode assembly to define a folded surface region having overlapping layers of the uncoated portions, and the folded surface region includes a welding target region having a plurality of overlapping layers of the uncoated portions. the welding target area includes an electrode assembly extending in a radial direction of the electrode assembly; a battery housing having a first end and a second end with an open portion and in which the electrode assembly is housed; a seal that seals the open portion at the first end of the battery housing; a terminal having a surface exposed to the outside through the second end of the battery housing or the seal; a first current collector electrically connected to the welding target area of ​​the uncoated portion of the first electrode and the terminal; and a second current collector electrically connected to the welding target area of ​​the uncoated portion of the second electrode and the battery housing.

[0046] The terminal may be a rivet terminal disposed in a through hole provided at the second end of the battery housing, and a sealing gasket may be interposed between the through hole at the second end of the battery housing and the rivet terminal.

[0047] The rivet terminal may be welded to the first current collector.

[0048] The sealing body may include a cap crimped with a sealing gasket at the opening of the first end of the battery housing, the sealing gasket being interposed between the cap and the opening of the first end of the battery housing to insulate the cap from the battery housing.

[0049] The battery may include a beading portion near an opening at a first end of the battery housing, the sealing body may include a cap crimped with a sealing gasket at the opening at the first end of the battery housing, and the second current collector may have at least a portion of its periphery interposed between the beading portion and the sealing gasket and in contact with an inner surface of the beading portion.

[0050] At least a portion of the periphery of the second current collector may be welded to the inner surface of the beading portion.

[0051] The cap may not have electrical polarity.

[0052] The welding target region may have an average overlapping layer number of the uncoated portion in a radial direction of the electrode assembly of five or more.

[0053] In the welding target region, the overlapping layer of the non-coating portion may have an average lamination thickness of 25 μm or more.

[0054] The first current collector may be provided with a first welding pattern formed by welding a welding target area of ​​the uncoated portion of the first electrode to the first current collector, and the second current collector may be provided with a second welding pattern formed by welding a welding target area of ​​the uncoated portion of the second electrode to the second current collector.

[0055] The first and second welding patterns may be extended along a radial direction of the electrode assembly starting from a point spaced apart from a core center of the electrode assembly by 5 mm to 10 mm.

[0056] The first and second welding patterns may extend along a radial direction of the electrode assembly starting from points spaced the same distance from a core center of the electrode assembly.

[0057] The first and second welding patterns may have the same or different lengths in a radial direction of the electrode assembly.

[0058] The first weld pattern may be longer than the second weld pattern.

[0059] Before the uncoated portion is folded, the maximum height of the uncoated portion extending along the axial direction may be 12 mm.

[0060] The remaining portion of the non-coated area is not folded and the boundary between the remaining portion of the non-coated area and the weld target area may be cut.

[0061] The folding depth of the non-colored portion may be 1 mm to 5 mm.

[0062] The first electrode and the second electrode each include a pair of short sides along the axial direction, and the pair of short sides may have the same length or different lengths.

[0063] The first electrode and the second electrode each include a pair of long sides aligned along the winding direction, and the pair of long sides may have the same length or different lengths.

[0064] The resistance measured between the terminal and the second end of the battery housing may be 4 milliohms or less.

[0065] The battery may have a height to diameter ratio of greater than 0.4.

[0066] The above object is achieved by a battery pack including the above-mentioned battery, and a vehicle including the battery pack. Effect of the Invention

[0067] According to one aspect of the present invention, when the uncoated portions exposed at both ends of the electrode assembly are folded, a sufficient area where the uncoated portions overlap uniformly in the radial direction of the electrode assembly is ensured, thereby preventing damage to the separator and active material layer even if the welding output is increased.

[0068] In addition, according to one aspect of the present invention, by improving the structure of the uncoated portion adjacent to the core of the electrode assembly, it is possible to prevent the cavity in the core of the electrode assembly from being blocked when the uncoated portion is bent, thereby facilitating the electrolyte injection process and the welding process of the battery housing and the current collector.

[0069] In addition, according to one aspect of the present invention, an electrode assembly having improved energy density and reduced resistance can be provided by directly welding a folded surface area of ​​a non-coated portion to a current collector instead of a strip-shaped electrode tab to reduce dead space.

[0070] In addition, according to one aspect of the present invention, it is possible to provide a battery having a structure with low internal resistance and improved welding strength between a current collector and an uncoated portion, and a battery pack and a vehicle including the battery.

[0071] The present invention has various other effects, which will be described later with reference to the embodiments, but the description of the effects that can be easily inferred by ordinary skilled artisans will be omitted.

[0072] The following drawings attached to this specification illustrate preferred embodiments of the present invention and, together with the detailed description of the invention, serve to further understand the technical ideas of the present invention. Therefore, the present invention should not be interpreted as being limited to only the matters described in the drawings. [Brief description of the drawings]

[0073] [Figure 1] FIG. 1 is a plan view showing the structure of an electrode used in the manufacture of a conventional tabless cylindrical battery. [Diagram 2] FIG. 1 is a diagram showing an electrode winding process for a conventional tabless cylindrical battery. [Diagram 3] 1A and 1B are diagrams showing a process of folding a non-coated portion in a conventional method for manufacturing a tabless cylindrical battery. [Figure 4] 1 is a view showing a state in which a current collector is welded to a folded surface area of ​​a non-coating portion in a conventional method for manufacturing a tabless cylindrical battery. [Diagram 5] FIG. 2 is a plan view showing a structure of an electrode according to an embodiment of the present invention. [Figure 6] 1 is a cross-sectional view of an electrode assembly according to an embodiment of the present invention taken along a winding axis (Y-axis) direction. [Figure 7] 1 is a view showing a state in which a non-coated portion exposed at an end of an electrode assembly is bent from a core toward an outer shell in an embodiment of the present invention. [Figure 8] 1 is a view showing a state in which a non-coated portion exposed at an end of an electrode assembly is bent from an outer shell toward a core in an embodiment of the present invention. [Figure 9] 11 is a diagram showing a change in the number of overlapping layers of a non-coated portion according to a bending depth when the non-coated portion exposed at an end of an electrode assembly is bent in accordance with an embodiment of the present invention. FIG. [Figure 10] 1 shows an experimental result of comparing the change in the average number of overlapping layers of the uncoated portions and the overlapping quality depending on the folding directions of the positive and negative uncoated portions of the electrode assembly in accordance with an embodiment of the present invention. [Figure 11]13 is a diagram illustrating a state in which a folding region is pre-cut before folding an uncoated portion of an electrode assembly in accordance with an embodiment of the present invention. [Figure 12] 1 shows an experimental result of comparing the change in the average number of overlapping layers of the uncoated portion and overlapping quality depending on whether the positive and negative uncoated portions of the electrode assembly are cut and folded in a certain direction in accordance with an embodiment of the present invention. [Figure 13a] 1 is a cross-sectional view of a cylindrical battery according to an embodiment of the present invention taken along the winding axis (Y-axis) direction. [Figure 13b] FIG. 2 is a top view showing the structure of a first current collector according to one embodiment of the present invention. [Figure 13c] FIG. 4 is a top view showing the structure of a second current collector according to one embodiment of the present invention. [Figure 14a] FIG. 2 is a cross-sectional view of a cylindrical battery according to another embodiment of the present invention, taken along the winding axis (Y-axis) direction. [Figure 14b] FIG. 4 is a top view showing a structure of a first current collector according to another embodiment of the present invention. [Figure 14c] FIG. 4 is a perspective view showing a structure of a second current collector according to another embodiment of the present invention. [Figure 15] FIG. 2 is a top view illustrating a state in which a plurality of cylindrical batteries are electrically connected together according to an embodiment of the present invention. [Figure 16] FIG. 16 is a partially enlarged view of FIG. [Figure 17] FIG. 2 illustrates a battery pack including a cylindrical battery according to an embodiment of the present invention. [Figure 18] FIG. 1 illustrates a vehicle including a battery pack according to an embodiment of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0074] Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the attached drawings. Prior to this, the terms and words used in the present specification and claims are not to be construed as being limited to their ordinary and dictionary meanings, but are to be construed as having meanings and concepts corresponding to the technical ideas of the present invention, in accordance with the principle that the inventors themselves can appropriately define the concepts of terms in order to best describe the invention.

[0075] Therefore, it should be understood that the embodiment described in this specification and the configurations shown in the drawings are merely the most preferred embodiment of the present invention and do not represent the entire technical idea of ​​the present invention, and therefore there may be various equivalents and modifications that can be substituted therefor at the time of this application.

[0076] In addition, in order to facilitate understanding of the invention, the accompanying drawings may not be drawn to scale, and the dimensions of some components may be exaggerated. In addition, the same reference numerals may be used to refer to the same components in different embodiments.

[0077] The expression that two comparison objects are identical means that they are "substantially identical." Therefore, "substantially identical" may include cases where there is a deviation that is considered to be a low level in the art, for example, a deviation within 5%. In addition, the expression that a certain parameter is uniform in a given region means that the parameter is uniform in the average viewpoint in the region.

[0078] In addition, although the terms "first", "second", etc. are used to indicate various components, these terms are not intended to limit the components. These terms are merely used to distinguish one component from another, and unless otherwise specified, the first component can also be the second component.

[0079] Throughout the specification, unless otherwise stated, each element may be singular or plural.

[0080] When an arbitrary structure is disposed on the "top (or bottom)" of a component or "above (or below)" a component, it does not only mean that the arbitrary structure is disposed in contact with the upper surface (or lower surface) of the component, but also that other structures may be interposed between the component and the arbitrary structure disposed above (or below) the component.

[0081] In addition, when a component is said to be "coupled," "coupled," or "connected" to another component, it includes not only the cases where the components are directly coupled or connected to each other, but also the cases where other components are "interposed" between each component, or the cases where each component is "coupled," "coupled," or "connected" through other components.

[0082] Throughout the specification, unless otherwise specified, "A and / or B" means A, B, or A and B, and "C to D" means C or more and D or less, unless otherwise specified.

[0083] For ease of explanation, in this specification, the direction along the longitudinal direction of the winding shaft of the electrode assembly wound into a jelly roll is referred to as the axial direction (Y-axis direction). The direction surrounding the winding shaft is referred to as the circumferential direction or outer circumferential direction (X-axis direction). The direction approaching the winding shaft or away from the winding shaft is referred to as the radial direction. Of these, the direction approaching the winding shaft is referred to as the centripetal direction, and the direction away from the winding shaft is referred to as the centrifugal direction.

[0084] First, an electrode assembly according to an embodiment of the present invention will be described. The electrode assembly is a jelly-roll type electrode assembly having a structure in which sheet-shaped first and second electrodes and a separator interposed therebetween are wound in one direction.

[0085] The shape of the electrode assembly is not limited to a jelly roll type, and therefore the electrode assembly may have other known structures that can be adopted in cylindrical batteries.

[0086] Preferably, at least one of the first electrode and the second electrode includes a non-coated portion at a long side end in the winding direction where the active material is not coated, and at least a portion of the non-coated portion is used as an electrode tab by itself.

[0087] FIG. 5 is a plan view showing the structure of an electrode 40 according to an embodiment of the present invention.

[0088] 5, the electrode 40 includes a conductive substrate 40a made of a metal foil, and an active material layer 40b. The electrode 40 has a pair of short sides and a pair of long sides extending between the pair of short sides. The pair of short sides extend along the winding axis (Y-axis), and the pair of long sides extend along the winding direction X. The pair of short sides may have the same or different lengths, and the pair of long sides may also have the same or different lengths.

[0089] The metal foil may be aluminum or copper, and is appropriately selected according to the polarity of the electrode 40. The active material layer 40b is formed on at least one surface of the conductive substrate 40a extending between a pair of short sides, and includes a plain portion 40c at one end of a pair of long sides extending along the winding direction X. The plain portion 40c is an area where the active material is not coated. An insulating coating layer 40d may be formed at the boundary between the active material layer 40b and the plain portion 40c. The insulating coating layer 40d is formed so that at least a portion of the insulating coating layer 40d overlaps with the boundary between the active material layer 40b and the plain portion 40c. The insulating coating layer 40d includes a polymer resin and may include an inorganic filler such as Al2O3. The polymer resin may have a porous structure. The insulating coating layer 40d may have a width of 0.3 mm to 5 mm in the winding axis (Y-axis) direction. The part of the plain portion 40c where the insulating coating layer 40d is formed is an area where the active material is not coated, and therefore the part may also be considered as the plain portion.

[0090] Preferably, a portion of the uncoated portion 40c adjacent to the core side may be cut off through a notching process. In this case, even if the uncoated portion 40c is bent towards the core side, the core of the electrode assembly is not blocked by the bent portion of the uncoated portion 40c. For reference, the core has a cavity that is created when the bobbin used in winding the electrode assembly is removed. The cavity may be used as a passage for injecting electrolyte or a passage for inserting a welding jig. In the drawings, dotted lines indicate the positions at which the uncoated portion 40c is bent. The bending position of the uncoated portion 40c may be changed.

[0091] The cut portion B of the uncoated portion 40c forms a plurality of winding turns in the radial direction when the electrode 40 is wound. The plurality of winding turns have a predetermined width in the radial direction. Preferably, the width d of the cut portion B and the folding length h of the uncoated portion 40c can be adjusted so that the predetermined width is equal to or greater than the folding length h of the uncoated portion 40c. This prevents the core of the electrode assembly from being blocked by the folding portion of the uncoated portion 40c even when the uncoated portion 40c is folded.

[0092] Alternatively, the width d of the cut portion B and the bent length h of the uncoated portion 40c may be adjusted so that the core (cavity) of the electrode assembly is open to the outside by 90% or more based on its diameter.

[0093] When forming the cut portion B of the non-coated portion 40c, it is preferable to provide a gap between the cutting line and the insulating coating layer 40d to prevent damage to the active material layer 40b and / or the insulating coating layer 40d. The gap may be preferably 0.2 mm to 4 mm, more preferably 0.5 mm to 2 mm. If the gap is adjusted to the above numerical range, it is possible to prevent damage to the active material layer 40b and / or the insulating coating layer 40d due to cutting tolerance when the non-coated portion 40c is cut. Meanwhile, it is preferable that the cutting line of the cut portion B is separated from the end of the active material layer 40b by about 0.5 mm to 4 mm. If the separation distance is adjusted to the range of 0.5 mm to 4 mm, it is possible to prevent damage to the active material layer 40b due to cutting tolerance during the process of forming the cut portion B of the non-coated portion 40c.

[0094] As a specific example, when the electrode 40 is used to manufacture an electrode assembly for a cylindrical battery with a form factor of 4680 (diameter: 46 mm, height: 80 mm), the width d of the cut portion B of the uncoated portion may be set to 180 mm to 350 mm depending on the diameter of the core of the electrode assembly.

[0095] Meanwhile, when the core of the electrode assembly is not used in the electrolyte injection process, welding process, etc., cut portion B of the uncoated portion 40c may not be formed. Also, cut portion B of the uncoated portion 40c may be formed on the outer periphery of the electrode 40. If cut portion B of the uncoated portion 40c is formed on the outer periphery of the electrode 40, it is possible to prevent the uncoated portion 40c on the outer periphery of the electrode 40 from making electrical contact with the battery housing. This effect is useful when the polarity of the electrode 40 and the polarity of the battery housing are different.

[0096] The electrode 40 of the above embodiment may be applied to a first electrode and / or a second electrode having different polarities included in a jelly roll type electrode assembly. In addition, when the electrode structure of the embodiment is applied to either the first electrode or the second electrode, a conventional electrode structure (FIG. 1) may be applied to the other. In addition, the electrode structures applied to the first electrode and the second electrode may not be the same, but may be different.

[0097] In the present invention, the positive electrode active material coated on the positive electrode and the negative electrode active material coated on the negative electrode may be any active material known in the art without any limitations.

[0098] As an example, the positive electrode active material can be represented by the general chemical formula A[A x M y ]O 2+z (A includes at least one element of Li, Na, and K; M includes at least one element selected from Ni, Co, Mn, Ca, Mg, Al, Ti, Si, Fe, Mo, V, Zr, Zn, Cu, Al, Mo, Sc, Zr, Ru, and Cr; 0≦x, 1≦x+y≦2, −0.1≦z≦2; the stoichiometric coefficients x, y, and z are selected to maintain electrical neutrality of the compound).

[0099] As another example, the positive electrode active material is an alkali metal compound xLiM disclosed in U.S. Patent No. 6,677,082, U.S. Patent No. 6,680,143, etc. 1 O2-(1-x)Li2M 2 O3 (M 1 contains at least one element having an average oxidation state of 3; M 2 contains at least one element having an average oxidation state of 4; 0 ≦ x ≦ 1).

[0100] As yet another example, the positive electrode active material has the general chemical formula Li a M 1 x Fe 1-x M 2 y P 1-y M 3 z O 4-z (M 1 contains at least one element selected from Ti, Si, Mn, Co, Fe, V, Cr, Mo, Ni, Nd, Al, Mg, and Al; M 2 contains at least one element selected from Ti, Si, Mn, Co, Fe, V, Cr, Mo, Ni, Nd, Al, Mg, Al, As, Sb, Si, Ge, V, and S; M 3 contains a halogen group element selectively containing F; 0 < a ≦ 2, 0 ≦ x ≦ 1, 0 ≦ y < 1, 0 ≦ z < 1; the stoichiometric coefficients a, x, y, and z are selected so that the compound maintains electrical neutrality), or it can be a lithium metal phosphate represented by Li3M2(PO4)3 [M contains at least one element selected from Ti, Si, Mn, Fe, Co, V, Cr, Mo, Ni, Al, Mg, and Al].

[0101] Desirably, the positive electrode active material may include primary particles and / or secondary particles formed by aggregation of primary particles.

[0102] For example, the negative electrode active material may be a carbon material, lithium metal or a lithium metal compound, silicon or a silicon compound, tin or a tin compound, etc. Metal oxides such as TiO2 and SnO2 having a potential of less than 2 V may also be used as the negative electrode active material. The carbon material may be either low crystalline carbon or high crystalline carbon.

[0103] The separator may be a porous polymer film, for example, a porous polymer film made of a polyolefin polymer such as an ethylene homopolymer, a propylene homopolymer, an ethylene / butene copolymer, an ethylene / hexene copolymer, an ethylene / methacrylate copolymer, etc., either alone or in combination. As another example, the separator may be a conventional porous nonwoven fabric, for example, a nonwoven fabric made of a high melting point glass fiber, a polyethylene terephthalate fiber, etc.

[0104] At least one surface of the separator may include a coating layer of inorganic particles. The separator itself may also be made of a coating layer of inorganic particles. The particles constituting the coating layer may have a structure in which they are bound with a binder such that there is an interstitial volume between adjacent particles.

[0105] The inorganic particles may be made of an inorganic material having a dielectric constant of 5 or more. As a non-limiting example, the inorganic particles may be made of Pb(Zr,Ti)O3 (PZT), Pb 1-x La x Zr 1-y Ti y O3(PLZT), PB(Mg3Nb 2 / 3 )O3-PbTiO3 (PMN-PT), BaTiO3, hafnia (HfO2), SrTiO3, TiO2, Al2O3, ZrO2, SnO2, CeO2, MgO, CaO, ZnO, and Y2O3.

[0106] FIG. 6 is a cross-sectional view taken along the Y axis of a jelly-roll type electrode assembly 50 in which an electrode 40 according to an embodiment of the present invention is applied to a first electrode (positive electrode) and a second electrode (negative electrode).

[0107] Referring to FIG. 6, the electrode assembly 50 may be manufactured by the winding method described with reference to FIG. 2. The uncoated portion 41 protruding upward of the electrode assembly 50 extends from the first electrode 43. The uncoated portion 42 protruding downward of the electrode assembly 50 extends from the second electrode 44. The separator 45 is interposed between the first electrode 43 and the second electrode 44. The length of the active material coating region of the first electrode 43 in the Y-axis direction may be shorter than the length of the active material coating region of the second electrode 44 in the Y-axis direction. Therefore, the active material coating region of the second electrode 44 may extend longer in the Y-axis direction than the active material coating region of the first electrode 43.

[0108] Preferably, the insulating coating layer 47 formed at the boundary between the active material region and the uncoated portion of the first electrode 43 and the second electrode 44 may extend to the end of the separator 45 or may be exposed from the end to the outside. When the insulating coating layer 47 is exposed to the outside of the separator 45, it can play a role in supporting the folding points when the uncoated portions 41 and 42 are folded. If the folding points are supported, stress applied to the active material layer and the separator 45 when the uncoated portions 41 and 42 are folded is relieved. In addition, the insulating coating layer 47 can prevent the first electrode 43 and the second electrode 44 from contacting each other and causing a short circuit. The end of the insulating coating layer 47 may be exposed beyond the end of the separator 45 by a length of more than 0 mm and less than 2 mm in the winding axis (Y-axis) direction.

[0109] The first electrode 43 includes a conductive substrate and an active material coating layer formed on at least one surface thereof. The conductive substrate (uncoated portion 41) is made of aluminum and may have a thickness of 10 μm to 25 μm. The first electrode 43 including the active material coating layer may have a thickness of 180 μm to 220 μm. The second electrode 44 includes a conductive substrate and an active material coating layer formed on at least one surface thereof. The conductive substrate (uncoated portion 42) is made of copper and may have a thickness of 5 μm to 20 μm. The second electrode 44 including the active material coating layer may have a thickness of 140 μm to 180 μm. The separator 45 is interposed between the first electrode 43 and the second electrode 44 and may have a thickness of 8 μm to 18 μm.

[0110] In the winding structure of the first electrode 43, the distance between the uncoated portions 41 located on adjacent winding turns in the radial direction may be 350 μm to 380 μm. In the winding structure of the second electrode 44, the distance between the uncoated portions 42 located on adjacent winding turns in the radial direction may be 350 μm to 380 μm.

[0111] In the electrode assembly 50, the number of winding turns of the first electrode 43 varies depending on the form factor of the cylindrical battery, but may be 48 to 56. The number of winding turns of the second electrode 44 also varies depending on the form factor of the cylindrical battery, but may be 48 to 56.

[0112] The blank portions 41 and 42 are longer than the blank portions applied to the design of a small cylindrical battery. Desirably, the blank portions 41 and 42 may be 6 mm or more, optionally 7 mm or more, optionally 8 mm or more, optionally 9 mm or more, optionally 10 mm or more, optionally 11 mm or more, or optionally 12 mm or more.

[0113] Preferably, the uncoated portions 41, 42 may be folded in the radial direction of the electrode assembly 50, more preferably from the outer periphery toward the core side.

[0114] FIG. 7 is a cross-sectional view showing a state where the uncoated portion 41 of the electrode assembly 50 is bent from the core to the outer shell using a forming jig 60, and FIG. 8 is a cross-sectional view showing a state where the uncoated portion 41 of the electrode assembly 50 is bent from the outer shell to the core using a forming jig 60. In this embodiment, the material of the uncoated portion 41 is set to be aluminum, the thickness to be 10 μm, the length in the winding axis direction to be 8 mm, and the folding depth to be 2 mm. The folding depth corresponds to the difference in height of the uncoated portion 41 before and after folding. The height of the uncoated portion 41 after folding is the height of the folded surface area. The reference point for the height may be the boundary point between the active material coating layer and the uncoated portion 41.

[0115] 7 and 8, when the plain portion 41 is bent from the core to the outer shell, buckling of the plain portion 41 occurs severely near the core. On the other hand, when the plain portion 41 is bent from the outer shell to the core, the buckling phenomenon of the plain portion 41 is considerably alleviated. If the plain portion 41 is severely buckled, stress is concentrated at the boundary between the plain portion 41 and the active material layer, and cracks may occur in the conductive substrate. Furthermore, the end of the plain portion 41 may be torn due to being unable to withstand the stress. In addition, when the plain portion 41 is torn, the separator is also torn together, and a micro-short circuit may be induced between the first electrode 43 and the second electrode 44. The buckling of the plain portion 41 is caused by the curvature radius being reversed as the plain portion 41 is bent. Referring to FIG. 7 and FIG. 8, it is preferable that the plain portion 41 is bent from the outer shell to the core of the electrode assembly 50. Similarly, it is preferable that the uncoated portion 42 is also bent from the outer periphery of the electrode assembly 50 toward the core side.

[0116] On the other hand, buckling of the uncoated portions 41, 42 occurs near the core of the electrode assembly 50. Buckling of the uncoated portions 41, 42 can be prevented by forming cut portions (B in FIG. 5) in the uncoated portions 41, 42 near the core and not bending the uncoated portions near the core.

[0117] In an alternative embodiment, when cut portion B or a similar structure is applied near the core of the electrode assembly 50, the uncoated portions 41, 42 can be bent from the outer periphery of the electrode assembly 50 toward the core.

[0118] Desirably, the folding depth of the plain portions 41, 42 may be at least 1 mm, optionally 1.5 mm or more, optionally 2 mm or more, optionally 2.5 mm or more, optionally 3.0 mm or more, optionally 3.5 mm or more, optionally 4 mm or more, optionally 4.5 mm or more, and optionally 5.0 mm or more.

[0119] 9 shows the results of measuring how the number of overlapping layers of plain portion 41 changes when the folding depth is changed to 1 mm, 2 mm, and 3 mm when the end of plain portion 41 is folded using forming jig 60. The material, length, and thickness of plain portion 41 are the same as those in the experimental conditions described above.

[0120] 9, when the folding depth of the uncoated portion 41 is 1 mm, the number of overlapping layers of the uncoated portion 41 at the radial center of the electrode assembly 50 (the region indicated by the vertical dotted line) is three. When the folding depth of the uncoated portion 41 is 2 mm, the number of overlapping layers of the uncoated portion 41 at the radial center of the electrode assembly 50 is six. When the folding depth of the uncoated portion 41 is 3 mm, the number of overlapping layers of the uncoated portion 41 at the radial center of the electrode assembly 50 is nine. The number of overlapping layers of the uncoated portion according to the folding depth under the three conditions is approximately three times the folding depth. Therefore, it will be obvious to those skilled in the art that when the folding depth of the uncoated portion 41 is greater than 3 mm, the number of overlapping layers of the uncoated portion 41 at the radial center of the electrode assembly 50 will be greater than nine.

[0121] FIG. 10 shows a close-up photograph of the top of the electrode current collector after bending the plain portion while varying the number of overlapping layers, and a photograph of the cross section of the welded point taken with an optical microscope.

[0122] In the photographs of the top of the current collector, the left photo is a photo after the bending process, and the right photo is a photo after the current collector is welded. In the cross-sectional photographs of the welded part, the left photo is a photo with a magnification of 80, and the right photo is a photo with a magnification of 120. In Examples 1 and 2, the plain part was bent from the outer shell toward the core side, and in Comparative Examples 1 and 2, the plain part was bent from the core toward the outer shell side.

[0123] (Examples 1 and 2) When the uncoated portion of the electrode assembly was bent from the outer shell to the core side, the bending depth for the uncoated portion on the positive electrode side and the uncoated portion on the negative electrode side was set to 3 mm and 3 mm, respectively. The material, length and thickness of the positive electrode uncoated portion were aluminum, 8 mm and 10 μm, respectively, and the material, length and thickness of the negative electrode uncoated portion were copper, 8 mm and 15 μm, respectively.

[0124] (Comparative Examples 1 and 2) When the uncoated portion was bent from the core of the electrode assembly to the outer shell side, the bending depth for the uncoated portion on the positive electrode side and the uncoated portion on the negative electrode side were set to 3 mm and 3 mm, respectively. The material, length and thickness of the positive electrode uncoated portion were aluminum, 8 mm and 10 μm, respectively, and the material, length and thickness of the negative electrode uncoated portion were copper, 8 mm and 15 μm, respectively.

[0125] Referring to FIG. 10, in Comparative Examples 1 and 2, the average number of overlapping layers in the positive electrode uncoated area and the negative electrode uncoated area calculated within the welded section of the current collector was 3 and 4, respectively, and it can be seen that there was a large space (gap) between the uncoated areas.

[0126] In the present invention, the average number of overlapping layers was determined by setting measurement points at 1 mm intervals in the welded section and averaging the number of overlapping layers confirmed at each measurement point. The overlapping surface of the non-coated portion may be substantially perpendicular to the winding axis direction. The number of overlapping layers means the number of overlapping layers of the non-coated portion through which an imaginary line parallel to the winding axis direction is drawn at the measurement point.

[0127] In Comparative Examples 1 and 2, the number of overlapping layers in the non-coated area is small, so when the output of the laser is increased to increase the welding strength, the laser may penetrate into the electrode assembly through the overlapping area of ​​the non-coated area. Therefore, there is a limit to increasing the strength of the welding area to a desired level. Cylindrical batteries having a 4680 form factor are mounted on automobiles. When an automobile is driven, vibrations are continuously applied to the cylindrical battery, and as the cylindrical battery is used for a longer period of time, a swelling phenomenon occurs, and the stress at the welding point between the current collector and the folded surface area of ​​the non-coated area increases, which may cause problems such as cracks at the welding interface. Comparative Examples 1 and 2 are vulnerable to such problems.

[0128] Furthermore, when a large gap exists between overlapping uncoated layers, as in Comparative Examples 1 and 2, the laser may penetrate into the electrode assembly without being masked by the overlapping uncoated regions, causing the separator and / or active material layer to melt.

[0129] Meanwhile, in Examples 1 and 2, the average number of overlapping layers of the positive electrode uncoated portion and the negative electrode uncoated portion calculated within the welded section of the current collector was confirmed to be 5 and 7, respectively, and it was confirmed that the space (gap) between the uncoated portions was significantly reduced. Therefore, Examples 1 and 2 are superior to Comparative Examples 1 and 2 in weld strength, vibration resistance, and laser shielding effect.

[0130] Referring to the results of the comparative experiment shown in FIG. 10, the folded surface region formed by folding the uncoated portion from the outer periphery of the electrode assembly toward the core side is substantially flat, and the average number of overlapping layers of the uncoated portion may include 5 or more, optionally 6 or more, optionally 7 or more, optionally 8 or more, optionally 9 or more, and optionally 10 or more welding target regions.

[0131] Desirably, the folded surface region may include a welding target region in which the number of overlapping layers of the plain portion is 5 to 15.

[0132] In the folded surface region, the average number of overlapping layers can be determined to a desired value by adjusting the length of the uncoated portions and the folding depth based on the spacing between the uncoated portions protruding from adjacent winding turns in the radial direction of the electrode assembly.

[0133] For example, if the spacing between the plain areas is 350 μm and the folding depth is 3 mm, the folded portion of the plain area extending from the folding point toward the core has a length of about 3 mm. Also, the folded portion of the plain area overlaps with the plain area protruding from the radius section corresponding to at least eight winding turns (3 mm / 350 μm=8.57) inside the folding point. Therefore, the average number of overlapping layers of the plain area in the corresponding radius section can be adjusted to about eight.

[0134] The optimal average number of overlapping layers can be adaptively determined by trial and error, taking into account the power of the laser used for welding, the material and thickness of the uncoated portions, the spacing between the uncoated portions of adjacent winding turns, and the like.

[0135] In the folded surface region, the region where the average number of overlapping layers of the uncoated portion is 5 or more can be defined as a welding target region to which the current collector is welded. The welding target region extends along the radial direction of the electrode assembly 50. The welding target region includes overlapping layers of the uncoated portion. Here, overlapping means that the uncoated portion is laminated in multiple layers along the winding axis direction. When the folded surface region is formed by the uncoated portion 41 of the first electrode 43, the average lamination thickness of the overlapping layers of the uncoated portion 41 in the welding target region can be 50 μm or more. This is because the desired thickness of the uncoated portion 41 is 10 μm to 25 μm. Similarly, when the folded surface region is formed by the uncoated portion 42 of the second electrode 44, the average lamination thickness of the overlapping layers of the uncoated portion 42 in the welding target region can be 25 μm or more. This is because the desired thickness of the uncoated portion 42 is 5 μm to 20 μm. On the other hand, in the welding target region, the upper limit of the average layer thickness of the uncoated portions 41, 42 can be determined by the upper limit of the average number of overlapping layers. That is, the upper limit of the average layer thickness can be determined by the product of the upper limit of the average number of overlapping layers and the maximum thickness of the uncoated portions 41, 42.

[0136] Desirably, in the radial direction of the electrode assembly 50, the ratio of the length of the welding target area in which the number of overlapping layers is 5 or more can be designed to be 30% or more, optionally 40% or more, optionally 50% or more, optionally 60% or more, optionally 70% or more, or optionally 80% or more based on the radius of the electrode assembly 50.

[0137] Preferably, the ratio of the length of the welding target region having five or more overlapping layers in the radial direction of the electrode assembly 50 may be 30% or more and 90% or less based on the radius of the electrode assembly 50 .

[0138] Referring to FIG. 10, the welding target area is defined as a folded surface area formed by folding at least a portion of the plain area in the radial direction of the electrode assembly. The welding target area may extend radially with respect to the core of the electrode assembly. Other parts of the plain area other than the welding target area may not be folded. The surface height of the welding target area is lower than its surroundings. The welding target area may have a groove structure extending radially from the center of the core of the electrode assembly toward the outer periphery. As an example, the groove structure shown in FIG. 10 is a cross shape. The welding pattern formed in the welding target area may include a plurality of welding dots arranged along the radial direction of the electrode assembly. The plurality of welding dots may be arranged in at least one row, preferably two rows, in the radial direction. The welding dots correspond to welding beads generated by laser welding. The welding bead is a solidified product of the metal melted by the laser. The shape of the current collector welded to the welding target area may correspond to the shape of the welding target area. In addition, a hole that can communicate with a cavity in the core of the electrode assembly 50 may be provided in the center of the current collector.

[0139] Preferably, the region where the plain portions 41 and 42 of the electrode assembly 50 are to be folded may be cut in advance to a predetermined depth. The cutting depth may be 1 mm to 5 mm. The position where the cutting is performed is the boundary between the welding target region and the remaining region. FIG. 11 is a diagram showing a state where the region where the plain portions 41 and 42 are to be folded is cut in advance. The concentric circles are a conceptual representation of the plain portions 41 and 42, and the plain portions 41 and 42 are actually wound in a spiral shape. When the plain portions 41 and 42 are cut, a cutting line 70 is formed. The plain portions 41 and 42 may be cut up to the folding point. When the plain portions 41 and 42 are cut, an ultrasonic cutting method or a laser cutting method may be applied. In addition, any method used for notching a metal foil may be used without limitation. Once the plain portions 41, 42 are cut, stress is relieved when the plain portions 41, 42 are bent in the direction indicated by the arrows, so that the number of overlapping layers of the plain portions in the target welding area becomes uniform and the volume of the empty space (gap) in the overlapping areas of the plain portions is significantly reduced.

[0140] FIG. 12 shows the results of a comparative experiment that clearly shows the difference between a case where the non-coated portions 41, 42 are cut and then folded, and a case where the non-coated portions 41, 42 are folded without being cut.

[0141] In the third column of the table, the photo on the left is a photo of the top of the positive electrode uncoated area, and the photo on the right is a photo of the top of the negative electrode uncoated area. The CT images shown in the fourth column of the table are images of the cross section taken with a CT scanner after cutting the welded area of ​​the positive electrode uncoated area. The cross-sectional photos in the fifth column of the table are images of the cross section taken with an optical microscope after cutting the welded area of ​​the negative electrode uncoated area.

[0142] In Example (1), the bend region is not cut, and the plain portion is folded from the core toward the outer shell, with the average number of overlapping layers in the welded region being 3. Example (1) is substantially the same as the above-mentioned Comparative Example 1. The plain portion is irregularly deformed in the overlapping region of the plain portion, and large open spaces are observed in the overlapping region of the plain portion.

[0143] In Example (2), the bend region is not cut, and the plain portion is bent from the outer shell toward the core, with the average number of overlapping layers in the welded region being 6. The bend depth, material, length, and thickness of the plain portion are substantially the same as in Example (1). The degree of deformation of the plain portion in the overlapped region is smaller than in Example (1), and the open space (gap) is also relatively smaller than in Example (1).

[0144] In Example (3), the bent region is cut and then the plain portion is folded from the core toward the outer shell, with the average number of overlapping layers in the welded region being 5. The material and thickness of the plain portion are the same as in Example (1), and the cut depth of the plain portion is 2 mm. Although the bent region is cut, it is confirmed that the plain portion is irregularly deformed in the overlapping region where the plain portion is folded from the core toward the outer shell. Meanwhile, the volume of the empty space (gap) in the overlapping region of the plain portion is somewhat reduced.

[0145] In Example (4), the bend region is cut and then the plain portion is folded from the outer shell toward the core, and the average number of overlapping layers in the welded region is 6. The material and thickness of the plain portion are the same as in Example (2), and the cut depth of the plain portion is 2 mm. It can be confirmed that by cutting the bend region in advance, the plain portion overlaps more evenly in the welded region than in Example (2), and the volume of the empty space (gap) in the overlapping region of the plain portion is the smallest.

[0146] Various electrode assembly structures according to the embodiments (variations) of the present invention may be applied to a jelly-roll type cylindrical battery.

[0147] Desirably, the cylindrical battery may be, for example, a cylindrical battery having a form factor ratio (defined as the diameter divided by the height of a cylindrical battery, i.e., the ratio of height (H) to diameter (Φ)) greater than about 0.4.

[0148] Here, the form factor refers to a value indicating the diameter and height of a cylindrical battery. A cylindrical battery according to an embodiment of the present invention may be, for example, a 46110 battery, a 4875 battery, a 48110 battery, a 4880 battery, or a 4680 battery. In the value indicating the form factor, the first two digits indicate the diameter of the battery, and the remaining digits indicate the height of the battery.

[0149] When an electrode assembly having a tabless structure is applied to a cylindrical battery with a form factor ratio exceeding 0.4, the stress applied in the radial direction when the plain part is bent is large, and the plain part is easily broken. Also, when welding a current collector to the bent surface area of ​​the plain part, the number of overlapping layers of the plain part must be increased sufficiently to ensure sufficient welding strength and reduce resistance. These requirements can be achieved by the electrode and electrode assembly according to the embodiment (variant) of the present invention.

[0150] A battery according to one embodiment of the present invention may be a cylindrical battery that is generally cylindrical, with a diameter of about 46 mm, a height of about 110 mm, and a form factor ratio of 0.418.

[0151] Another embodiment of the battery may be a cylindrical battery that is generally cylindrical with a diameter of about 48 mm and a height of about 75 mm, resulting in a form factor ratio of 0.640.

[0152] In yet another embodiment, the battery may be a cylindrical battery that is generally cylindrical with a diameter of about 48 mm, a height of about 110 mm, and a form factor ratio of 0.436.

[0153] In yet another embodiment, the battery may be a cylindrical battery that is generally cylindrical with a diameter of about 48 mm and a height of about 80 mm, resulting in a form factor ratio of 0.600.

[0154] In yet another embodiment, the battery may be a cylindrical battery that is generally cylindrical with a diameter of about 46 mm and a height of about 80 mm, resulting in a form factor ratio of 0.575.

[0155] Conventionally, batteries with a form factor ratio of about 0.4 or less have been used. That is, conventionally, for example, 1865 batteries, 2170 batteries, etc. have been used. In the case of an 1865 battery, the diameter is about 18 mm, the height is about 65 mm, and the form factor ratio is 0.277. In the case of a 2170 battery, the diameter is about 21 mm, the height is about 70 mm, and the form factor ratio is 0.300.

[0156] Hereinafter, a cylindrical battery according to an embodiment of the present invention will be described in detail.

[0157] FIG. 13a is a cross-sectional view of a cylindrical battery 190 according to one embodiment of the present invention taken along the Y-axis direction.

[0158] Referring to FIG. 13a, a cylindrical battery 190 according to one embodiment of the present invention includes an electrode assembly 110 including a first electrode, a separator, and a second electrode, a battery housing 142 that houses the electrode assembly 110 and has a first end and a second end at the top and bottom, respectively, and a seal 143 that seals an open portion of the battery housing 142.

[0159] The battery housing 142 is a cylindrical container having an opening at a first end and a closed portion (bottom) at a second end opposite the first end. The battery housing 142 is made of a conductive metal material such as aluminum or steel. The battery housing 142 accommodates the electrode assembly 110 in the inner space through the opening at the first end, and also accommodates the electrolyte.

[0160] The electrolyte is A + B - In this case, the salt may have the structure: + Li + , Na + , K+ or a combination thereof. - is F - , Cl - , Br - , I - , NO3 - , N(CN)2 - , BF4 - , ClO4 - , AlO4 - , AlCl4 - , PF6 - , SbF6 - , AsF6 - , BF2C2O4 - , BC4O8 - , (CF3)2PF4 - , (CF3)3PF3 - , (CF3)4PF2 - , (CF3)5PF - , (CF3)6P - , CF3SO3 - , C4F9SO3 - , CF3CF2SO3 - , (CF3SO2)2N - , (FSO2)2N - , CF3CF2(CF3)2CO - , (CF3SO2)2CH - , (SF5)3C - , (CF3SO2)3C - , CF3(CF2)7SO3, CF3CO2 - , CH3CO2 - , SCN - and (CF3CF2SO2)2N - The anion includes one or more anions selected from the group consisting of:

[0161] The electrolyte may be dissolved in an organic solvent for use. The organic solvent may be propylene carbonate (PC), ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), dimethyl sulfoxide, acetonitrile, dimethoxyethane, diethoxyethane, tetrahydrofuran, N-methyl-2-pyrrolidone (NMP), ethyl methyl carbonate (EMC), γ-butyrolactone, or a mixture thereof.

[0162] The electrode assembly 110 may have a jelly roll structure, but the present invention is not limited thereto. The electrode assembly 110 may be manufactured by winding a laminate formed by sequentially stacking a lower separator, a first electrode, an upper separator, and a second electrode at least once, as shown in FIG. 2, around a winding shaft.

[0163] The first electrode and the second electrode have different polarities. That is, if one has a positive polarity, the other has a negative polarity. At least one of the first electrode and the second electrode may have an electrode structure according to the above-mentioned embodiment (variation). The other of the first electrode and the second electrode may have a conventional electrode structure or an electrode structure according to the embodiment (variation).

[0164] At the top and bottom of the electrode assembly 110, an uncoated portion 146a of the first electrode and an uncoated portion 146b of the second electrode protrude outward from the ends of the separator, respectively.

[0165] The sealing body 143 may include a plate-shaped cap 143a with a protruding center, an insulating sealing gasket 143b that provides airtightness between the cap 143a and the battery housing 142, and a connecting plate 143c that is electrically and mechanically connected to the cap 143a.

[0166] The cap 143a is a part made of a conductive metal material and covers the opening of the battery housing 142. The cap 143a is electrically connected to the uncoated portion 146a of the first electrode and is electrically insulated from the battery housing 142 via a sealing gasket 143b. Therefore, the cap 143a can function as a first electrode terminal of the cylindrical battery 190.

[0167] The cap 143a is placed on a beading portion 147 formed on the battery housing 142 and fixed by a crimping portion 148. A sealing gasket 143b may be interposed between the cap 143a and the crimping portion 148 to ensure airtightness of the battery housing 142 and to provide electrical insulation between the battery housing 142 and the cap 143a. The cap 143a may include a protrusion 143d formed to protrude upward from the center thereof.

[0168] The battery housing 142 is electrically connected to the uncoated portion 146b of the second electrode. Therefore, the battery housing 142 has the same polarity as the second electrode. If the second electrode has a negative polarity, the battery housing 142 also has a negative polarity.

[0169] The battery housing 142 has a beading portion 147 and a crimping portion 148 at the upper end. The beading portion 147 is formed by pressing in around the outer circumferential surface of the battery housing 142. The beading portion 147 prevents the electrode assembly 110 accommodated inside the battery housing 142 from slipping out of the upper end opening of the battery housing 142, and can also function as a support portion on which the sealing body 143 is placed.

[0170] The crimping portion 148 is formed on the upper portion of the beading portion 147. The crimping portion 148 is bent inwardly of the battery housing 142 to enclose the outer circumferential surface of the cap 143a disposed on the beading portion 147 and a part of the upper surface of the cap 143a.

[0171] The cylindrical battery 190 may further include a first current collector 144 and / or a second current collector 145 and / or an insulator 146 .

[0172] 13b and 13c are top views showing the structures of the first current collector 144 and the second current collector 145, respectively.

[0173] 13a and 13b, a first current collector 144 is coupled to the upper part of the electrode assembly 110. The first current collector 144 is made of a conductive metal material such as aluminum, copper, nickel, etc., and is welded to a welding target area of ​​a bent surface area formed by bending the uncoated portion 146a of the first electrode. The welding target area may have a radial groove structure as shown in Figs. 10 and 12. The radial groove structure may extend from the core center of the electrode assembly 110 to the outer periphery.

[0174] Desirably, the welding target area may have an average number of overlapping layers of the non-coating portion 146a of 5 or more. Also, the welding target area may have an average thickness of the overlapping layers of the non-coating portion 146a of 50 μm or more.

[0175] The first current collector 144 may have a structure that allows it to be placed in the groove structure of the welding target area. As an example, if the welding target area has a cross-shaped groove structure as shown in Figures 10 and 12, the first current collector 144 may also be a cross-shaped plate.

[0176] The first current collector 144 may include a support portion 144a, a plurality of legs 144b extending outward from the support portion 144a, and a lead portion 149 extending outward from the support portion 144a between adjacent legs 144b.

[0177] The support portion 144a is placed near the core of the electrode assembly 110, and the legs 144b are placed on the folded surface region and can be welded to a weld target area of ​​the folded surface region.

[0178] A hole H1 is provided at the center of the support 144a. An electrolyte may be injected through the hole H1. The diameter of the hole H1 is 0.5 times or more the diameter of the cavity in the core of the electrode assembly 110. If the diameter of the hole H1 is smaller than the diameter of the cavity in the core, it is possible to prevent the electrodes and separator from being pushed out through the cavity in the core when venting occurs in the cylindrical battery 190. In addition, if the diameter of the hole H1 is the same as or larger than the diameter of the cavity in the core, it is easy to insert a welding jig during the process of welding the second current collector 145 to the bottom of the battery housing 142, and the electrolyte may be smoothly injected.

[0179] The lead portion 149 may extend above the electrode assembly 110 and be connected to the connection plate 143c or may be directly connected to the lower surface of the cap 143a. The connection plate 143c may be connected to the lower surface of the cap 143a. The connection between the lead portion 149 and other components may be performed by welding.

[0180] The folded surface region of the non-coating portion 146a may be bonded to the first current collector 144 by, for example, laser welding. Laser welding may be performed by partially melting the base material of the current collector. Laser welding may be replaced by resistance welding, ultrasonic welding, etc.

[0181] 13a and 13c, a plate-shaped second current collector 145 may be coupled to a lower surface of the electrode assembly 110.

[0182] The second current collector 145 may include a support portion 145a having a hole H2 formed therein, a plurality of legs 145b extending outward from the support portion 145a, a connection portion 145c provided inside the hole H2 and coupled to the bottom surface of the battery housing 142, and a bridge portion 145d connecting the connection portion 145c and the support portion 145a.

[0183] The second current collector 145 is made of a conductive metal material such as aluminum, copper, nickel, etc. The support portion 145a is placed near the core on the lower surface of the electrode assembly 110. The legs 145b are welded to welding target areas of the bent surface area formed by bending the uncoated portion 146b. The connection portion 145c may be welded onto the inner bottom surface of the battery housing 142.

[0184] The diameter of the connection portion 145c is larger than the diameter of the cavity in the core of the electrode assembly 110. The bridge portion 145d connects the inner surface of the hole H2 to the outer surface of the connection portion 145c. The bridge portion 145d acts to buffer the vibration or stress when the vibration or stress is applied to the second current collector 145. The width or thickness of the bridge portion 145d may be partially reduced. As a result, when an overcurrent flows through the bridge portion 145d, the bridge portion 145d is melted and cut off, thereby cutting off the overcurrent.

[0185] The welding target area defined in the folded surface area of ​​the lower surface of the electrode assembly 110 may have a radial groove structure as shown in Figures 10 and 12. The radial groove structure may extend from the core center of the electrode assembly 110 to the outer periphery.

[0186] Desirably, in the welding target area, the average number of overlapping layers in the non-coating portion 146b may be 5 or more, and the average thickness of the overlapping layers in the non-coating portion 146a may be 25 μm or more.

[0187] The legs 145b of the second current collector 145 may have a structure that allows them to be placed in the groove structure of the radially extended welding target area. For example, if the welding target area has a cross-shaped groove structure as shown in Figures 10 and 12, the legs 145b of the second current collector 145 may also extend in a cross shape from the support 145a.

[0188] 13b and 13c, the weld pattern W1 formed on the leg 144b of the first current collector 144 and the weld pattern W2 formed on the leg 145b of the second current collector 145 may extend radially starting from a point spaced substantially the same distance from the core center of the electrode assembly 110. The radial length of the weld pattern W1 may be the same as or different from the radial length of the weld pattern W2. The weld patterns W1 and W2 may be continuous weld beads or discontinuous weld bead arrangements.

[0189] 13a, an insulator 146 may cover the first current collector 144. The insulator 146 may cover the first current collector 144 on the upper surface of the first current collector 144, thereby preventing direct contact between the first current collector 144 and the inner peripheral surface of the battery housing 142.

[0190] The insulator 146 has a lead hole 151 through which the lead portion 149 extending upward from the first current collector 144 is pulled out. The lead portion 149 is pulled out upward through the lead hole 151 and coupled to the lower surface of the connection plate 143c or the lower surface of the cap 143a.

[0191] The peripheral region of the insulator 146 is interposed between the first current collector 144 and the beading portion 147 to fix the combination of the electrode assembly 110 and the first current collector 144. As a result, the movement of the combination of the electrode assembly 110 and the first current collector 144 in the height direction of the cylindrical battery 190 is restricted, and the assembly stability of the cylindrical battery 190 can be improved.

[0192] The insulator 146 may be made of an insulating polymer resin. As an example, the insulator 146 may be made of polyethylene, polypropylene, polyimide, or polybutylene terephthalate.

[0193] The battery housing 142 may further include a venting portion 152 formed on the lower surface thereof. The venting portion 152 corresponds to a region on the lower surface of the battery housing 142 that is thinner than the surrounding region. The venting portion 152 is structurally weaker than the surrounding region. Therefore, if an abnormality occurs in the cylindrical battery 190 and the internal pressure increases above a certain level, the venting portion 152 may burst and gas generated inside the battery housing 142 may be discharged to the outside.

[0194] The vents 152 may be formed continuously or discontinuously in a circular pattern on the underside of the battery housing 142. Alternatively, the vents 152 may be formed in a linear pattern or other patterns.

[0195] Since the diameter of the connection portion 145c of the second current collector 145 is larger than the diameter of the cavity in the core of the electrode assembly 110, when the venting portion 152 bursts and gas generated inside the battery housing 142 is discharged to the outside, it is possible to prevent the electrodes and separators near the core from being pushed out.

[0196] FIG. 14a is a cross-sectional view of a cylindrical battery 200 according to another embodiment of the present invention taken along the Y axis.

[0197] Referring to FIG. 14a, a cylindrical battery 200 differs from the cylindrical battery 190 shown in FIG. 13a in that the structure of the electrode assembly is substantially the same, but other structures except for the electrode assembly have been changed.

[0198] Specifically, the cylindrical battery 200 includes a battery housing 171 having a rivet-type terminal 172 extending therethrough. The terminal 172 is attached to a through hole in a closed portion (bottom) at a second end of the battery housing 171. A lower peripheral portion of the terminal 172 is riveted to the through hole in the battery housing 171 with an insulating first sealing gasket 173 interposed therebetween. The riveting can be achieved by applying pressure to the lower peripheral portion of the terminal 172 with a caulking tool, thereby plastically deforming the corresponding portion toward the bottom of the battery housing 171. The terminal 172 is exposed to the outside in the direction opposite to the direction of gravity.

[0199] The terminal 172 includes a terminal exposure portion 172a and a terminal insertion portion 172b. The terminal exposure portion 172a is exposed to the outside of the closed portion of the battery housing 171. The terminal exposure portion 172a may be located at an approximately central portion of the closed portion of the battery housing 171. The maximum diameter of the terminal exposure portion 172a may be larger than the maximum diameter of a through hole formed in the closed portion of the battery housing 171. The terminal insertion portion 172b may penetrate approximately the central portion of the closed portion of the battery housing 171 to be electrically connected to the uncoated portion 146a of the first electrode. The terminal insertion portion 172b may be rivet-connected to the inner surface of the battery housing 171. That is, a lower peripheral portion of the terminal insertion portion 172b may have a shape bent toward the inner surface of the battery housing 171. The maximum diameter of the lower edge of the terminal insertion portion 172b may be larger than the maximum diameter of a through hole formed in the closed portion of the battery housing 171. The lower surface of the terminal insertion portion 172b is substantially flat and can be welded to the first current collector 144' connected to the uncoated portion 146a of the first electrode.

[0200] FIG. 14b is a top view showing the structure of the first current collector 144'. Referring to FIG. 14b, the first current collector 144' has substantially the same structure as the current collector 145 shown in FIG. 13c. That is, the first current collector 144' may include a support portion 144a' including a hole H3, a plurality of legs 144b' extending radially from the support portion 144', a connection portion 144c' provided inside the hole H3, and a bridge portion 144d' connecting the support portion 144a' and the connection portion 144c'. The connection portion 144c' of the first current collector 144' may be welded to a flat lower surface of the terminal insertion portion 172b of the terminal 172. The plurality of legs 144b' may be welded to a welding target area defined in a bent surface area on the upper part of the electrode assembly 110.

[0201] 14a, an insulator 174 made of an insulating material may be interposed between the first current collector 144' and the inner surface of the battery housing 171. The insulator 174 contacts the upper surface of the first current collector 144' and the inner surface of the closed part of the battery housing 171. The insulator 174 covers the upper part of the first current collector 144' and the upper peripheral edge part of the electrode assembly 110. This prevents the uncoated part on the outer periphery of the electrode assembly 110 from contacting the inner surface of the battery housing 171 of the opposite polarity and causing a short circuit. The insulator 174 is made of an insulating polymer resin.

[0202] The terminal insertion portion 172b of the terminal 172 may be welded to the first current collector 144' through the insulator 174. Therefore, a hole exposing the lower portion of the terminal insertion portion 172b is provided in the center of the insulator 174. The diameter of the hole may be larger than the diameter of the lower portion of the terminal insertion portion 172b.

[0203] The first sealing gasket 173 is interposed between the battery housing 171 and the terminal 172 to prevent electrical contact between the battery housing 171 and the terminal 172, which have opposite polarities. This allows the upper surface 175 of the battery housing 171, which has a substantially flat shape, to function as an electrode terminal of the cylindrical battery 200.

[0204] The first sealing gasket 173 includes a gasket exposing portion 173a and a gasket inserting portion 173b. The gasket exposing portion 173a is interposed between the terminal exposing portion 172a of the terminal 172 and the battery housing 171. The gasket inserting portion 173b is interposed between the terminal inserting portion 172b of the terminal 172 and the battery housing 171. The gasket inserting portion 173b may be deformed together with the terminal inserting portion 172b during riveting, and may be closely attached to the inner surface of the battery housing 171. The first sealing gasket 173 may be made of, for example, a polymer resin having insulating properties.

[0205] The gasket exposing portion 173a of the first sealing gasket 173 may have an extended shape so as to cover an outer circumferential surface of the terminal exposing portion 172a of the terminal 172. When the first sealing gasket 173 covers the outer circumferential surface of the terminal 172, it is possible to prevent a short circuit from occurring during the process of coupling an electrical connection part such as a bus bar to the upper surface of the battery housing 171 and / or the terminal 172. Although not shown, the gasket exposing portion 173a may have an extended shape so as to cover not only the outer circumferential surface of the terminal exposing portion 172a but also a part of the upper surface.

[0206] When the first sealing gasket 173 is made of a polymer resin, the first sealing gasket 173 may be joined to the battery housing 171 and the terminal 172 by heat sealing. In this case, the airtightness at the joining interface between the first sealing gasket 173 and the terminal 172 and at the joining interface between the first sealing gasket 173 and the battery housing 171 is strengthened. Meanwhile, when the gasket exposing portion 173a of the first sealing gasket 173 has a shape that extends to the upper surface of the terminal exposing portion 172a, the terminal 172 may be joined integrally with the first sealing gasket 173 by insert injection.

[0207] On the upper surface of the battery housing 171 , a region 175 other than the region occupied by the terminal 172 and the first sealing gasket 173 corresponds to an electrode terminal having a polarity opposite to that of the terminal 172 .

[0208] Fig. 14c is a perspective view showing the structure of the second current collector 176. Referring to Figs. 14a and 14c, the second current collector 176 is coupled to the lower part of the electrode assembly 110. The second current collector 176 is made of a conductive metal material such as aluminum, steel, copper, nickel, etc. At least a portion of the second current collector 176 may be coupled to a welding target area included in the bent surface area of ​​the uncoated portion 146b of the second electrode by welding.

[0209] The second current collector 176 includes a support portion 176a and a plurality of legs 176b extending radially from the support portion 176a and welded to a welding target area. The support portion 176a includes a hole H4 in the center. An electrolyte can be injected through the hole H4. The diameter of the hole H4 is 0.5 times or more the diameter of the cavity in the core of the electrode assembly 110. The function of the hole H4 is substantially the same as the function of the hole H1 described above.

[0210] Preferably, at least a portion of the second current collector 176 may be electrically connected to the battery housing 171. As an example, at least a portion of the peripheral edge of the second current collector 176 may be interposed and fixed between the inner surface of the battery housing 171 and the second sealing gasket 178b. To this end, the second current collector 176 includes a housing connection portion 176c. The housing connection portion 176c includes a connection portion 176c2 that extends from an end of the leg portion 176b at an angle toward the lower surface of the beading portion 180, and a contact portion 176c1 that is disposed on the lower surface of the beading portion 180. The contact portion 176c1 may be extended in an arc shape along the circumferential direction of the beading portion 180 to increase the contact area with the beading portion 180.

[0211] At least a portion of the peripheral edge of the second current collector 176, for example, the contact portion 176c1, may be fixed to the beading portion 180 by welding while being supported by the lower end surface of the beading portion 180 formed at the lower end of the battery housing 171. In a modified example, at least a portion of the peripheral edge of the second current collector 176 may be directly welded to the inner wall surface of the battery housing 171.

[0212] Preferably, the second current collector 176 and a welding target area included in the folded surface region of the non-coated portion 146b may be joined by welding, for example, laser welding, in an area of ​​the folded surface region of the non-coated portion 146b where the average number of overlapping layers of the non-coated portion 146b is 5 or more or the average layer thickness of the non-coated portion 146b is 25 μm or more.

[0213] Meanwhile, the welding pattern W1 formed on the leg 144b' of the first current collector 144' and the welding pattern W2 formed on the leg 176b of the second current collector 176 may extend in the radial direction starting from a point spaced substantially the same distance from the core center of the electrode assembly 110. The radial length of the welding pattern W1 may be the same as or different from the radial length of the welding pattern W2. For example, the radial length of the welding pattern W1 is longer than the radial length of the welding pattern W2. This is because the second current collector 176 includes the connecting portion 176c2, and therefore the leg 176b of the second current collector 176 is shorter than the leg 144b' of the first current collector 144'. At least one welding pattern W3 is also formed on the contact portion 176c1 of the second current collector 176. The welding pattern W3 may be linear or arc-shaped. The weld patterns W1, W2, W3 may be an arrangement of continuous weld beads or discontinuous weld beads.

[0214] The seal 178 that seals the opening at the first end of the battery housing 171 includes a cap 178a and a second sealing gasket 178b. The second sealing gasket 178b electrically isolates the cap 178a from the battery housing 171. A crimping portion 181 fixes the periphery of the cap 178a and the second sealing gasket 178b together. The cap 178a is provided with a venting portion 179. The configuration of the venting portion 179 is substantially the same as that of the above-described embodiment (variation).

[0215] Preferably, the cap 178a is made of a conductive metal material. However, the cap 178a does not have electrical polarity because the second sealing gasket 178b is interposed between the cap 178a and the battery housing 171. The seal 178 seals the open end of the lower part of the battery housing 171 and functions to discharge gas when the internal pressure of the battery 200 increases above a critical value.

[0216] Preferably, the terminal 172 electrically connected to the uncoated portion 146a of the first electrode is used as the first electrode terminal. Also, a portion 175 of the upper surface of the battery housing 171 electrically connected to the uncoated portion 146b of the second electrode through the second current collector 176, excluding the terminal 172, is used as a second electrode terminal having the opposite polarity to the first electrode terminal. In this way, when the two electrode terminals are located at the upper portion of the cylindrical battery 200, it is possible to arrange electrical connection parts such as a bus bar only on one side of the cylindrical battery 200. This can simplify the structure of the battery pack and improve the energy density. Also, since the portion 175 used as the second electrode terminal has a substantially flat shape, it is possible to secure a sufficient joining area for joining electrical connection parts such as a bus bar. As a result, the cylindrical battery 200 can reduce the resistance at the joining portion of the electrical connection parts to a desired level.

[0217] In the present invention, even if the uncoated portions 146a, 146b are bent toward the core side, the cavity 112 of the core of the electrode assembly 110 is not blocked and may be open to the top. Therefore, the first electrode and the second electrode may include a cut portion of the uncoated portion (see B in FIG. 5) near the core. The design conditions for the width d of the cut portion B of the uncoated portion and the bending length h of the uncoated portions 146a, 146b have been described above.

[0218] If the cavity 112 is not blocked, the electrolyte injection process can be performed without any problems, and the efficiency of the electrolyte injection can be improved. Also, a welding tool can be inserted through the cavity 112 to easily perform the welding process between the second current collector 145 and the bottom of the battery housing 142 or the welding process between the first current collector 144′ and the terminal 172.

[0219] The cylindrical battery 200 according to an embodiment of the present invention has the advantage that electrical connections can be made from the top side.

[0220] FIG. 15 is a top view showing a state in which a plurality of cylindrical batteries 200 are electrically connected, and FIG. 16 is a partially enlarged view of FIG.

[0221] 15 and 16, a plurality of cylindrical batteries 200 may be connected in series and parallel at the top of the cylindrical batteries 200 using a bus bar 210. The number of cylindrical batteries 200 may be increased or decreased depending on the capacity of the battery pack.

[0222] In each cylindrical battery 200, the terminal 172 may have a positive polarity, and the flat surface 171a around the terminal 172 of the battery housing 171 may have a negative polarity. Of course, the opposite is also possible.

[0223] Preferably, the cylindrical batteries 200 may be arranged in a plurality of rows and columns. In the drawings, the columns are provided in the vertical direction, and the rows are provided in the horizontal direction. In addition, to maximize space efficiency, the cylindrical batteries 200 may be arranged in a closest packing structure. The closest packing structure is formed when an equilateral triangle is drawn when the centers of the terminals 172 exposed to the outside of the battery housing 171 are connected to each other. Preferably, the bus bar 210 connects the cylindrical batteries 200 arranged in the same row in parallel with each other, and connects the cylindrical batteries 200 arranged in two adjacent rows in series with each other.

[0224] Preferably, the bus bar 210 may include a body portion 211, a plurality of first bus bar terminals 212, and a plurality of second bus bar terminals 213 for series and parallel connection.

[0225] The body portion 211 may extend along the row of cylindrical batteries 200 between adjacent terminals 172. Alternatively, the body portion 211 may extend along the row of cylindrical batteries 200 but be bent regularly, such as in a zigzag shape.

[0226] The plurality of first bus bar terminals 212 may extend from one side of the body portion 211 and be electrically coupled to the terminals 172 of the cylindrical battery 200 located in the one side direction. The electrical coupling between the first bus bar terminals 212 and the terminals 172 may be performed by laser welding, ultrasonic welding, or the like.

[0227] The second bus bar terminals 213 may extend from the other side of the body portion 211 and be electrically coupled to the flat surface 171a around the terminals 172 located in the other direction. The electrical coupling between the second bus bar terminals 213 and the flat surface 171a may be performed by laser welding, ultrasonic welding, or the like.

[0228] Preferably, the body part 211, the plurality of first busbar terminals 212, and the plurality of second busbar terminals 213 may be formed of a single conductive metal plate. The metal plate may be, for example, an aluminum plate or a copper plate, but the present invention is not limited thereto. Alternatively, the body part 211, the plurality of first busbar terminals 212, and the second busbar terminals 213 may be manufactured as separate pieces and then joined to each other by welding or the like.

[0229] The cylindrical battery 200 of the present invention described above has a structure in which resistance is minimized by expanding the welding area through the bent surface area, multiplying the current path using the second current collector 176, minimizing the length of the current path, etc. The AC resistance of the cylindrical battery 200 measured by a resistance meter between the positive and negative electrodes, i.e., between the terminal 172 and the surrounding flat surface 171a, may be 0.5mΩ to 4mΩ, which is suitable for fast charging, and preferably 1mΩ to 4mΩ.

[0230] In the cylindrical battery 200 according to the present invention, the terminal 172 having a positive polarity and the flat surface 171a having a negative polarity are positioned in the same direction, so that electrical connection between the cylindrical batteries 200 can be easily implemented using the bus bar 210.

[0231] In addition, since the terminal 172 of the cylindrical battery 200 and the surrounding flat surface 171a have a large area, the connection area of ​​the bus bar 210 can be sufficiently secured, thereby sufficiently reducing the resistance of the battery pack including the cylindrical battery 200.

[0232] In addition, since electrical wiring can be performed on the upper portion of the cylindrical battery 200, the energy density per unit volume of the battery module / pack can be maximized.

[0233] The cylindrical battery according to the above-described embodiment (variation) can be used to manufacture a battery pack.

[0234] FIG. 17 is a diagram illustrating a schematic configuration of a battery pack according to an embodiment of the present invention.

[0235] 17, a battery pack 300 according to an embodiment of the present invention includes an assembly of electrically connected cylindrical batteries 301, and a pack housing 302 that accommodates the cylindrical batteries 301. The cylindrical battery 301 may be any one of the batteries according to the above-mentioned embodiments (variations). For convenience of illustration, components such as a bus bar for electrical connection of the cylindrical battery 301, a cooling unit, and external terminals are not shown.

[0236] The battery pack 300 is mounted on a vehicle. The vehicle may be, for example, an electric vehicle, a hybrid vehicle, or a plug-in hybrid vehicle. The vehicle may include a four-wheeled vehicle or a two-wheeled vehicle.

[0237] FIG. 18 is a diagram for explaining an automobile including the battery pack 300 of FIG.

[0238] 18, an automobile V according to an embodiment of the present invention includes a battery pack 300 according to an embodiment of the present invention. The automobile V operates by receiving power from the battery pack 300 according to an embodiment of the present invention.

[0239] According to one aspect of the present invention, when bending the uncoated portions exposed at both ends of the electrode assembly, a sufficient welding target area where the uncoated portions overlap evenly in the radial direction of the electrode assembly can be secured, thereby preventing damage to the separator and active material layer even when the welding output is increased.

[0240] In addition, according to one aspect of the present invention, by improving the structure of the uncoated portion adjacent to the core of the electrode assembly, it is possible to prevent the cavity in the core of the electrode assembly from being blocked when the uncoated portion is bent, thereby facilitating the electrolyte injection process and the welding process between the battery housing (or terminal) and the current collector.

[0241] According to another aspect of the present invention, instead of using a strip-shaped electrode tab, a folded surface area of ​​a non-coated portion is directly welded to a current collector, thereby providing an electrode assembly with improved energy density and reduced resistance.

[0242] In addition, according to one aspect of the present invention, it is possible to provide a cylindrical battery having a structure with low internal resistance and improved welding strength between a current collector and an uncoated portion, and a battery pack and a vehicle including the same.

[0243] As described above, the present invention has been described using limited embodiments and drawings. However, the present invention is not limited thereto, and it goes without saying that various modifications and variations can be made by a person having ordinary skill in the art to which the present invention pertains within the technical spirit of the present invention and the equivalent scope of the claims.

Claims

1. An electrode assembly in which a first electrode, a second electrode, and a separator interposed therebetween are wound around a single axis to define a core and an outer circumferential surface, each of the first electrode and the second electrode includes a non-coated portion at a long side end along the winding direction, the non-coated portion being exposed in the axial direction beyond the separator; At least a portion of the uncoated portion is folded along a radial direction of the electrode assembly to define a folded surface area having an overlapping layer of the uncoated portion; the folded surface region includes a weld target region having a plurality of overlapping layers of the non-coated portion, the weld target region extending in a radial direction of the electrode assembly; a battery housing having a first end with an open portion and a second end with a closed portion having a through hole, the battery housing housing housing the electrode assembly therein; A sealing body that seals the opening; a terminal having a surface exposed to the outside through the second end of the battery housing and insulated from the battery housing; a first current collector electrically connected to a weld target area of ​​the uncoated portion of the first electrode and to the terminal.

2. 2. The battery of claim 1, wherein the thickness of the uncoated portion is between 5 μm and 25 μm, and the spacing between the uncoated portions of adjacent wound turns is between 350 and 380 μm.

3. The battery according to claim 1 or 2, wherein in the welding target region, an average lamination thickness of the overlapping layers of the non-coating portion is 25 μm or more.

4. 4. The battery of claim 1, wherein the overlapping layers of the non-coated portions are stacked substantially perpendicular to the axial direction in the weld target area.

5. 5. The battery of claim 1, wherein a ratio of a radial length of the welding target area to a radius of the electrode assembly is 30% or greater.

6. 5. The battery of claim 1, wherein a ratio of a radial length of the welding target area to a radius of the electrode assembly is 40% or greater.

7. 5. The battery of claim 1, wherein a ratio of a radial length of the welding target area to a radius of the electrode assembly is 50% or greater.

8. 5. The battery of claim 1, wherein a ratio of a radial length of the welding target area to a radius of the electrode assembly is 60% or greater.

9. 5. The battery of claim 1, wherein a ratio of a radial length of the welding target area to a radius of the electrode assembly is 70% or greater.

10. The battery according to claim 1 , wherein the welding target region has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of five or more.

11. The battery according to claim 1 , wherein the welding target region has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of six or more.

12. The battery according to claim 1 , wherein the welding target region has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of seven or more.

13. The battery according to claim 1 , wherein the welding target region has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of eight or more.

14. The battery according to claim 1 , wherein the welding target area has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of nine or more.

15. The battery according to claim 1 , wherein the welding target area has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of 10 or more.

16. 16. The battery of claim 1, wherein the remaining portion of the non-coated area is not folded, and a boundary between the welding target area and the remaining portion of the non-coated area is cut along the axial direction.

17. 17. The battery of claim 1, wherein the weld target areas are radially disposed from a core center toward an outer periphery of the electrode assembly.

18. The battery according to claim 1 , wherein the welding target areas are arranged in a cross shape from a core center toward an outer shell side of the electrode assembly.

19. 19. The battery of any one of claims 1 to 18, comprising a current collector welded to the weld target area.

20. 20. The battery of claim 19, wherein the current collector is laser or ultrasonically welded to the weld target area.

21. 21. The battery of claim 19 or 20, wherein the welding pattern between the current collector and the welding target area comprises a plurality of dot patterns arranged linearly along a radial direction of the electrode assembly.

22. 22. The battery according to claim 1, wherein the uncoated portion includes a cut portion of the uncoated portion in a region adjacent to a core side or an outer shell side of the electrode assembly, the cut portion having a height in a winding axial direction of the electrode assembly that is lower than that of other regions.

23. 23. The battery of claim 22, wherein the portion of the solid body remaining at the cut portion of the solid body is not folded.

24. The battery of claim 22 , wherein a radial width of the wound turn formed by folding the cut portion of the non-coated portion is greater than a folding length of the non-coated portion.

25. The battery according to any one of claims 22 to 24, wherein the height of the uncoated portion remaining at the cut portion of the uncoated portion is 0.2 to 4 mm.

26. 26. The battery of claim 1, wherein the maximum height of the uncoated portion extended along the axial direction before the uncoated portion is folded is 12 mm.

27. The battery according to any one of claims 1 to 26, wherein the folding depth of the non-coated portion is 1 mm to 5 mm.

28. 28. The battery of claim 1, wherein the electrode having the uncoated portion among the first electrode and the second electrode has a pair of short sides along the axial direction, and the pair of short sides have the same length or different lengths.

29. 29. The battery of claim 1, wherein the electrode having the uncoated portion, of the first electrode and the second electrode, has a pair of long sides along the winding direction, the pair of long sides having the same length or different lengths.

30. an electrode assembly in which a first electrode, a second electrode, and a separator interposed therebetween are wound around one axis to define a core and an outer circumferential surface, the first electrode and the second electrode each including an uncoated portion at a long side end along a winding direction, the uncoated portion being exposed in the axial direction beyond the separator, at least a portion of the uncoated portion being folded along a radial direction of the electrode assembly to define a folded surface region having overlapping layers of the uncoated portion, the folded surface region including a welding target region having a plurality of overlapping layers of the uncoated portion, the welding target region extending in the radial direction of the electrode assembly; a battery housing having a first end with an open portion and a second end with a closed portion having a through hole, the battery housing housing housing the electrode assembly therein; a seal that seals the open portion at the first end of the battery housing; a terminal having a surface exposed to the outside through the second end of the battery housing and insulated from the battery housing; a first current collector electrically connected to the welding target area of ​​the uncoated portion of the first electrode and to the terminal; a second current collector electrically connected to a weld target area of ​​the uncoated portion of the second electrode and to the cell housing.

31. the terminal is a rivet terminal disposed in a through hole provided in the second end of the battery housing; 31. The battery of claim 30, wherein a sealing gasket is interposed between the through hole at the second end of the cell housing and the rivet terminal.

32. 32. The battery of claim 31, wherein the rivet terminal is welded to the first current collector.

33. the seal includes a cap crimped with a sealing gasket at the opening of the first end of the battery housing; 33. The battery of any one of claims 30 to 32, wherein the sealing gasket is interposed between the cap and an opening at a first end of the battery housing to insulate the cap from the battery housing.

34. An electrode assembly in which a first electrode, a second electrode and a separator interposed therebetween are wound around a single axis to define a core and an outer peripheral surface, wherein the first electrode and the second electrode each include an uncoated portion at a long side end along the winding direction that is exposed in the axial direction beyond the separator, and at least a portion of the uncoated portion is folded along the radial direction of the electrode assembly to define a folded surface area having overlapping layers of the uncoated portion, the folded surface area comprising a welding target area having a plurality of overlapping layers of the uncoated portion, and the welding target area extending in the radial direction of the electrode assembly; a battery housing having a first end and a second end with an open portion, the battery housing housing housing the electrode assembly therein; a seal that seals the open portion at the first end of the battery housing; a terminal having a surface exposed to the outside through the second end of the battery housing or through the seal; a first current collector electrically connected to the welding target area of ​​the uncoated portion of the first electrode and to the terminal; a second current collector electrically connected to a weld target area of ​​the uncoated portion of the second electrode and to the cell housing, a beading portion near the open portion of the first end of the battery housing; the seal includes a cap crimped with a sealing gasket at an open portion of the first end of the battery housing; At least a portion of the periphery of the second current collector is interposed between the beading portion and the sealing gasket and is in contact with an inner surface of the beading portion.

35. The battery of claim 34 , wherein at least a portion of the periphery of the second current collector is welded to the inner surface of the beading portion.

36. 36. The battery of claim 34 or 35, wherein the cap has no electrical polarity.

37. The battery according to claim 30 , wherein the welding target area has an average number of overlapping layers of the uncoated portion in a radial direction of the electrode assembly of five or more.

38. The battery according to any one of claims 30 to 37, wherein in the welding target area, the average lamination thickness of the overlapping layers of the non-coating portion is 25 µm or more.

39. the first current collector is provided with a first welding pattern formed by welding a welding target area of ​​the uncoated portion of the first electrode to the first current collector; 39. The battery of claim 30, wherein the second current collector is provided with a second weld pattern formed by welding a weld target area of ​​the uncoated portion of the second electrode to the second current collector.

40. 40. The battery of claim 39, wherein the first weld pattern and the second weld pattern extend along a radial direction of the electrode assembly starting from a point spaced 5 mm to 10 mm from a core center of the electrode assembly.

41. 40. The battery of claim 39, wherein the first weld pattern and the second weld pattern extend along a radial direction of the electrode assembly starting from a point spaced the same distance from a core center of the electrode assembly.

42. 42. The battery of any one of claims 39 to 41, wherein the first weld pattern and the second weld pattern have the same length in a radial direction of the electrode assembly.

43. 42. The battery of any one of claims 39 to 41, wherein the first weld pattern and the second weld pattern have different lengths in a radial direction of the electrode assembly.

44. 44. The battery of claim 43, wherein the first weld pattern is longer than the second weld pattern.

45. 45. The battery of claim 30, wherein the maximum height of the uncoated portion extending along the axial direction before the uncoated portion is folded is 12 mm.

46. 46. ​​The battery of any one of claims 30-45, wherein the remaining portion of the non-coated area is not folded and the boundary between the remaining portion of the non-coated area and the weld target area is cut.

47. The battery according to any one of claims 30 to 46, wherein the folding depth of the non-coated portion is 1 mm to 5 mm.

48. 48. The battery of any one of claims 30 to 47, wherein the first electrode and the second electrode each include a pair of short sides along the axial direction, the pair of short sides having the same length or different lengths.

49. 49. The battery of any one of claims 30 to 48, wherein the first electrode and the second electrode each include a pair of long sides along the winding direction, the pair of long sides having the same length or different lengths.

50. 50. The battery of any one of claims 30-49, wherein the resistance measured between the terminal and the second end of the battery housing is 4 mΩ or less.

51. 51. The battery of any one of claims 30 to 50, wherein the battery has a diameter to height ratio of greater than 0.

4.

52. 52. A battery pack comprising the battery of any one of claims 30 to 51.

53. 53. A motor vehicle comprising the battery pack of claim 52.

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