Motor insulation sheet

Abstract

To provide an insulation sheet for a motor that can relatively prevent a resin film disposed on a surface layer portion from rising from an adhesive layer.SOLUTION: An insulation sheet for a motor according to the present invention includes a first resin film layer, and a second resin film layer laminated via an adhesive layer on at least one surface of the first resin film layer, and the adhesive layer includes an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct, and has a gel fraction of 70% or less.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to an insulating sheet for a motor, and more particularly to an insulating sheet for a motor used as an insulating sheet for an oil-cooled drive motor of an automobile. [Background technology]

[0002] Conventionally, an oil-cooled drive motor for an automobile includes a rotor and a stator that generates a force to rotate the rotor. The stator includes a plurality of coils, and generates a Lorentz force by generating a magnetic field in the plurality of coils, and the Lorentz force rotates the rotor.

[0003] In an oil-cooled drive motor as described above, the coil is, for example, composed of a plurality of segment conductors connected to each other, and is usually used by being attached to a component made of laminated magnetic steel plates called a stator core or rotor core.

[0004] In the oil-cooled drive motor as described above, a core such as a stator core or a rotor core has a plurality of slot grooves, and the coil is housed in each of the plurality of slot grooves. In the oil-cooled drive motor as described above, an insulating sheet for the motor is accommodated in each of the slot grooves together with the coils to ensure insulation between the coils and the inner wall surfaces of the slot grooves. More specifically, the insulating sheet for the motor is accommodated in the slot grooves in a state where it is wrapped around the coils. The coil, which is wrapped around the motor insulating sheet, is fixed in the slot groove by an insulating resin (for example, epoxy varnish) impregnated in the slot groove.

[0005] The motor insulating sheet, as described in Patent Document 1 below, for example, has a five-layer structure including a polyester resin layer made of a polyester film, two paper-like sheet layers respectively disposed above and below the polyester resin layer, and two adhesive layers respectively disposed between the polyester resin layer and the paper-like sheets. That is, the motor insulating sheet has a five-layer structure with the paper-like sheet layer disposed on the surface layer. As described in Patent Document 1 below, the adhesive layer contains an adhesive whose main component is a thermosetting resin such as epoxy resin, and the adhesive is heat-cured (for example, heat-cured at 130°C for 24 hours) to increase the adhesive strength between the polyester resin layer and the adhesive layer, and between the paper-like sheet and the adhesive layer, resulting in a product. The paper-like sheet layer is made of a paper-like sheet as described in the following Patent Document 1, and the paper-like sheet is, for example, so-called "aramid paper" whose main material is fully aromatic polyamide fiber. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] JP 2016-54629 A Summary of the Invention [Problem to be solved by the invention]

[0007] In recent years, the demand for thickness accuracy of insulating sheets for motors has been increasing, but paper-like sheets such as aramid paper have a relatively large thickness variation of about ±20 μm, and therefore are not necessarily able to fully meet the demand for thickness accuracy as described above. For this reason, it has been considered to provide a resin film layer, which is made of a resin film with a relatively small variation in thickness of ±5 μm, on the surface layer of the insulating sheet for a motor, instead of the paper-like sheet layer.

[0008] However, when a resin film layer is disposed on the surface portion of the motor insulating sheet, when the adhesive contained in the adhesive layer is thermally cured to form a product, the resin film layer disposed on the surface portion may become wrinkled. If the resin film layer disposed on the surface portion of the motor insulating sheet becomes wrinkled, this is undesirable because it deteriorates the appearance of the sheet. In addition, this is also undesirable because it affects the adhesive strength of the adhesive layer to the resin film layer disposed on the surface portion. However, it cannot be said that sufficient consideration has been given to preventing the resin film layer disposed on the surface portion of the motor insulating sheet from wrinkling.

[0009] Therefore, an object of the present invention is to provide an insulating sheet for a motor that can relatively prevent wrinkling of the resin film layer disposed on the surface portion, and a method for manufacturing the insulating sheet for a motor. [Means for solving the problem]

[0010] As a result of extensive research, the present inventors have found that in an insulating sheet for a motor comprising a first resin film layer and a second resin film layer laminated on at least one side of the first resin film layer via an adhesive layer, by making the adhesive layer contain an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct and further setting the gel fraction of the adhesive layer to 70% or less, it is possible to relatively suppress the formation of wrinkles in the second resin film layer disposed in the surface layer portion. As a result, the present invention was achieved.

[0011] That is, the insulating sheet for a motor according to the present invention is A first resin film layer; a second resin film layer laminated on at least one surface of the first film via an adhesive layer, The adhesive layer contains an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct, and has a gel fraction of 70% or less.

[0012] According to this configuration, the motor insulating sheet can be relatively prevented from wrinkling the second resin film layer disposed on the surface layer portion.

[0013] In the motor insulating sheet, The adhesive layer preferably contains 5 parts by mass or more and 40 parts by mass or less of the trimethylolpropane / tolylene diisocyanate trimer adduct per 100 parts by mass of the acrylic polymer.

[0014] With this configuration, the insulating sheet for motors can relatively prevent the second resin film layer arranged on the surface portion from wrinkling, and can also relatively prevent the second resin film layer from lifting off the adhesive layer after being exposed to a heated environment (e.g., after being exposed to a temperature environment of 150°C for four hours).

[0015] In the motor insulating sheet, The adhesive layer preferably has a gel fraction of 50% or more.

[0016] With this configuration, the insulating sheet for motors can relatively prevent the second resin film layer arranged on the surface portion from wrinkling, and can also relatively prevent the second resin film layer from lifting off the adhesive layer after being exposed to a heated environment (e.g., after being exposed to a temperature environment of 150°C for four hours).

[0017] The method for producing an insulating sheet for a motor according to the present invention includes the steps of: a lamination step of laminating a second resin film layer on at least one surface of the first resin film layer via an adhesive layer; and a curing step of curing the adhesive layer. The adhesive layer includes an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct, In the curing step, curing is performed at room temperature so that the adhesive layer has a gel fraction of 70% or less.

[0018] According to this configuration, it is possible to obtain an insulating sheet for a motor in which the second resin film layer disposed on the surface portion can be relatively prevented from wrinkling. Effect of the Invention

[0019] According to the present invention, it is possible to provide an insulating sheet for a motor that can relatively prevent wrinkling of a resin film layer disposed on a surface portion, and a method for manufacturing the insulating sheet for a motor. [Brief description of the drawings]

[0020] [Figure 1] 1 is a cross-sectional view showing a configuration of an insulating sheet for a motor according to an embodiment of the present invention. [Diagram 2] FIG. 2 is a flow diagram of a method for producing an insulating sheet for a motor according to an embodiment of the present invention. [Diagram 3] FIG. 1 is a schematic perspective view of a stator of an oil-cooled drive motor for a hybrid electric vehicle (HEV) or electric vehicle (EV). [Figure 4] FIG. [Diagram 5] Enlarged view of part A in Figure 4. [Figure 6] 13 is a photograph showing the appearance of the insulating sheet for a motor according to Example 4 after a heating test. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0021] Hereinafter, one embodiment of the present invention will be described.

[0022] (Insulation sheet for motors) The insulating sheet 10 for a motor according to this embodiment includes a first resin film layer 10A and a second resin film layer 10C laminated on at least one surface of the first resin film layer 10A via an adhesive layer 10B. In the following, an example will be described in which the motor insulating sheet 10 according to this embodiment is configured by laminating two second resin film layers 10C1, 10C2 on both surfaces of one first resin film layer 10A via two adhesive layers 10B1, 10B2, as shown in FIG. 1.

[0023] The motor insulating sheet 10 according to the present embodiment is used as an insulating sheet for an oil-cooled drive motor of an automobile. That is, the motor insulating sheet 10 according to the present embodiment is used as an insulating sheet for a drive motor cooled by cooling oil (e.g., ATF). Examples of the automobile include a hybrid electric vehicle (HEV) and an electric vehicle (EV). Examples of the drive motor include an HV motor, a motor generator, an alternator, a 4WD motor, an oil pump motor, an EPS motor, a compressor motor, and an in-wheel motor.

[0024] In the motor insulating sheet 10 according to this embodiment, the first resin film layer 10A is made of, for example, a polyester-based film. Examples of the polyester film include a polyethylene terephthalate (PET) film and a polyethylene naphthalate (PEN) film. From the viewpoint of providing the first resin film layer 10A with excellent hydrolysis resistance, it is preferable to use a polyethylene naphthalate film as the polyethylene-based film.

[0025] The thickness of the first resin film layer 10A is preferably not less than 50 μm and not more than 250 μm.

[0026] The first resin film layer 10A may be formed using either a stretch-molded resin film or a non-stretch-molded resin film (non-stretched resin film), but it is preferable that it be formed using a stretch-molded resin film, and it is more preferable that it be formed using a biaxially stretched resin film.

[0027] When the first resin film layer 10A is made of a polyethylene terephthalate film, the polyethylene terephthalate film is preferably made of a low-oligomer product having an oligomer content of 1% by mass or less. By making the polyethylene terephthalate film of a low-oligomer product, the first resin film layer 10A has excellent hydrolysis resistance. The oligomer content can be determined, for example, by washing a roughly square film sample with sides of about 5 cm with methanol, drying the film sample in a hot air oven at 160°C for 1 hour to determine the initial mass (M1(g)), and then subjecting the film sample to an extraction treatment for 48 hours in boiling xylene (about 400 mL) using a Soxhlet extractor or the like, measuring the mass (M2(g)) of the film sample after the extraction treatment, and calculating the ratio ((M1-M2) / M1) of the mass reduction (M1-M2) to the initial mass (M1). Here, the mass (M2 (g)) of the film sample after the extraction process cannot be accurately determined as the mass reduction unless it is measured after the xylene used in the extraction process has been thoroughly removed from the film sample. Therefore, it is preferable to wash the film sample with water after the xylene extraction and lightly wipe off any xylene adhering to the surface, and then dry it in a hot air oven at 160°C for 8 hours and allow it to cool in a desiccator before measuring it.

[0028] In the insulating sheet 10 for a motor according to this embodiment, the second resin film layers 10C1 and 10C2 are made of, for example, a polyester-based film. Examples of the polyester film include a polyethylene terephthalate (PET) film and a polyethylene naphthalate (PEN) film. From the viewpoint of excellent hydrolysis resistance, it is particularly preferable that the second resin film layers 10C1 and 10C2 are made of polyethylene naphthalate (PEN). In the motor insulating sheet 10 according to this embodiment, the second resin film layers 10C1 and 10C2 may be made of a resin film having better heat resistance than the polyester-based film. Examples of such resin films include polyimide (PI) films, polyamide films, polyphenylene sulfide (PPS) films, polyether ether ketone (PPEK) films, and films made of ethylene-tetrafluoroethylene copolymer (ETFE).

[0029] The thickness of the second resin film layers 10C1 and 10C2 is preferably 12 μm or more and 50 μm or less. The second resin film layer 10C1 and the second resin film layer 10C2 may have the same thickness or may have different thicknesses, but preferably have the same thickness.

[0030] The second resin film layers 10C1, 10C2 may be made of either a stretch-molded resin film or a non-stretch-molded resin film (non-stretched resin film), but are preferably made of a stretch-molded resin film, and more preferably made of a biaxially stretch-molded resin film. The second resin film layers 10C1 and 10C2 are preferably thinner than the first resin film layer 10A. Furthermore, the ratio T of the thickness of the second resin film layers 10C1, 10C2 to the thickness of the first resin film layer 10A (thickness of the second resin film layers 10C1, 10C2 / thickness of the first resin film layer 10A) is preferably 0.05 or more, and more preferably 0.08 or more. Furthermore, the ratio T of the thickness of the second resin film layers 10C1, 10C2 to the thickness of the first resin film layer 10A is preferably 0.2 or less, and more preferably 0.15 or less.

[0031] In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 contain an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct. In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 have a gel fraction of 70% or less. By configuring the adhesive layers 10B1 and 10B2 as described above, the second resin film layers 10C1 and 10C2 can be relatively prevented from wrinkling.

[0032] In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 preferably have a gel fraction of 50% or more. By having a gel fraction of 50% or more, wrinkles in the second resin film layers 10C1, 10C2 can be relatively prevented, and the second resin film layers 10C1, 10C2 can be relatively prevented from lifting off the adhesive layers 10B1, 10B2 after being exposed to a heated environment (e.g., after being exposed to a temperature environment of 150°C for 4 hours).

[0033] An example of a commercially available trimethylolpropane / tolylene diisocyanate trimer adduct is "Coronate L" manufactured by Tosoh Corporation.

[0034] In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1, 10B2 are hardened at room temperature, thereby increasing the adhesive strength to the first resin film layer 10A and also increasing the adhesive strength to the second resin film layers 10C1, 10C2. Specifically, in the motor insulating sheet 10 of this embodiment, the adhesive layers 10B1, 10B2 are cured at room temperature in the presence of water (i.e., by being moisture-cured at room temperature), thereby increasing the adhesive strength to the first resin film layer 10A and also increasing the adhesive strength to the second resin film layers 10C1, 10C2. The room temperature curing is carried out in a gas containing moisture such as the atmosphere. In this specification, normal temperature means a temperature within the range of 5°C or higher and 35°C or lower. The room temperature curing is preferably carried out for 72 hours or more. If the room temperature curing is carried out for 144 hours, the gel fraction can be adjusted to within the range of 60% to 70%. The room temperature curing is preferably carried out in an environment with an absolute humidity of 0.002 kg / kg or more and 0.025 kg / kg or less. In addition, the room temperature curing is performed with a water vapor content of 2.31 mg / m 3 More than 10.3mg / m 3 It is preferable to carry out the process under the following circumstances:

[0035] The gel fractions of the adhesive layers 10B1 and 10B2 can be determined as follows. (1) Take a sample of approximately 0.1 g from the adhesive layer of the motor insulating sheet. (2) The sample is wrapped in a PTFE porous membrane having a diameter of 0.2 μm (product name "NTF1122", manufactured by Nitto Denko Corporation) and tied with kite string. (3) The samples wrapped in the PTFE porous membrane are immersed in 50 mL of ethyl acetate and left to stand at room temperature (23±2°C) for one week. One of the samples wrapped in the PTFE porous membrane (approximately 0.1 g in weight) is immersed in the 50 mL of ethyl acetate. (4) After leaving it to stand for one week, the sample wrapped in the PTFE porous membrane is removed from the 50 mL of ethyl acetate and dried at 130°C for two hours to remove the ethyl acetate. (5) The mass of the sample is measured before and after this operation, and the gel fraction is calculated using the following formula. In the following formula, W T2 is the mass of the PTFE porous membrane after drying, and W S2 is the mass of the kite string after drying, and W G is the mass of the gel after drying, and W T1 is the initial mass of the PTFE porous membrane, and W S1 is the initial mass of the kite string, and W A is the initial sample mass. Gel fraction (%) ={(W T2 +W S2 +W G )-(W T1 +W S1 )} / {(W T1 +W S1 +W A )-(W T1 +W S1 )}×100

[0036] In the motor insulating sheet 10 according to this embodiment, the adhesive layer 10B (in the example shown in FIG. 1, adhesive layers 10B1 and 10B2) contains an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct, and further has a gel fraction of 70% or less. The inventors of the present invention surmise that the reason why wrinkling of the second resin film layer 10C (in the example shown in FIG. 1, second resin film layers 10C1 and 10C2) disposed on the surface portion can be relatively suppressed is as follows.

[0037] Trimethylolpropane / tolylene diisocyanate has three isocyanate groups (-NCO) in its molecular structure. It is believed that at room temperature in the presence of water, the isocyanate groups in trimethylolpropane / tolylene diisocyanate react with water to generate urethane groups (-NHCOOH), and that amide groups (-NH) are generated by the elimination of CO from some of the urethane groups. That is, in the motor insulating sheet 10 according to this embodiment, it is considered that in the adhesive layer 10B, trimethylolpropane / tolylene diisocyanate in which the isocyanate group is a urethane group (hereinafter referred to as urethane group-containing trimethylolpropane / tolylene diisocyanate) and trimethylolpropane / tolylene diisocyanate in which the isocyanate group is an amide group (hereinafter referred to as amide group-containing trimethylolpropane / tolylene diisocyanate) coexist. In such a situation, it is believed that the urethane groups of the urethane group-containing trimethylolpropane / tolylene diisocyanate and the amide groups of the amide group-containing trimethylolpropane / tolylene diisocyanate repeatedly polymerize via urea bonds (-NHC(O)NH-), resulting in the formation of a trimethylolpropane / tolylene diisocyanate polymer in the adhesive layer 10B. Here, in the urea bond, the nitrogen atom (N) and the oxygen atom (O) function as acceptors when forming a hydrogen bond. In other words, the urea bond functions as a hydrogen acceptor. On the other hand, acrylic polymers have a carboxyl group (-COOH) in their molecular structure, and the carboxyl group functions as a donor when forming a hydrogen bond. That is, the carboxyl group functions as a hydrogen donor. In the adhesive layer 10B, it is believed that hydrogen bonds are formed by the urethane bonds (hydrogen acceptors) in the trimethylolpropane / tolylene diisocyanate polymer and the carboxyl groups (hydrogen donors) in the acrylic polymer. That is, in the adhesive layer 10B of the motor insulating sheet 10 according to this embodiment, it is believed that the acrylic polymer is bound to the trimethylolpropane / tolylene diisocyanate polymer by hydrogen bonding, causing a curing reaction to proceed. Therefore, in the adhesive layer 10B of the motor insulating sheet 10 according to this embodiment, compared to an adhesive layer in which a curing reaction due to thermal curing progresses, it is believed that a large number of pseudo-crosslinks due to hydrogen bonds are formed, while the formation of chemical bonds (covalent bonds) between molecules is suppressed, resulting in a relatively low gel fraction of 70% or less. As a result, it is believed that in the motor insulating sheet 10 according to this embodiment, even after the curing reaction has progressed, the adhesive layer 10B is prevented from shrinking excessively. The inventors surmise that by preventing the adhesive layer 10B from shrinking excessively, the second resin film layer 10C (in the example shown in Figure 1, second resin film layers 10C1 and 10C2) arranged on the surface portion can be relatively prevented from wrinkling.

[0038] In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 preferably contain 5 parts by mass or more and 40 parts by mass or less of the trimethylolpropane / tolylene diisocyanate trimer adduct per 100 parts by mass of the acrylic polymer. In the motor insulating sheet 10 according to this embodiment, it is more preferable that the adhesive layers 10B1 and 10B2 contain 10 parts by mass or more and 35 parts by mass or less of the trimethylolpropane / tolylene diisocyanate trimer adduct per 100 parts by mass of the acrylic polymer. By having the content of the trimethylolpropane / tolylene diisocyanate trimer adduct within the above range, high cohesive force is generated in the adhesive layers 10B1, 10B2, and wrinkles in the second resin film layers 10C1, 10C2 can be relatively prevented. In addition, after exposure to a heated environment (e.g., after exposure to a temperature environment of 150°C for 4 hours), the second resin film layers 10C1, 10C2 can be relatively prevented from lifting off the adhesive layers 10B1, 10B2.

[0039] The adhesive layer 10B1 can be formed by applying an adhesive composition containing an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct to at least one of the first resin film layer 10A and the second resin film layer 10C1, and bonding the first resin film layer 10A and the second resin film layer 10C1 together so that the surface to which the adhesive composition is applied faces inward. Similarly to the above, the adhesive layer 10B2 can be formed by bonding the first resin film layer 10A and the second resin film layer 10C2 together.

[0040] The amount of the adhesive composition to be applied to form one layer of the adhesive layers 10B1 and 10B2 is 5 to 50 g / m 2 By setting the coating amount within the above numerical range, it is possible to obtain sufficient adhesive strength between the second resin film layers 10C1, 10C2 and the first resin film layer 10A while making the thickness of the adhesive layers 10B1, 10B2 relatively thin. This makes it relatively easy to insert the motor insulating sheet 10 according to this embodiment into a narrow and small space.

[0041] The thickness of the adhesive layers 10B1 and 10B2 is preferably 4 μm or more and 50 μm or less. The adhesive layer 10B1 and the adhesive layer 10B2 may have the same thickness or may have different thicknesses, but it is preferable that they have the same thickness.

[0042] As the acrylic polymer, for example, a homopolymer of a monomer represented by the following general formula (1) or a copolymer having the monomer as a constituent unit can be used.

[0043] [ka] (In the formula, R 1 is a hydrogen atom or a lower alkyl group, and R 2 is an alkyl group having 1 to 12 carbon atoms.

[0044] Specific examples of the acrylic polymer include polyacrylic acid esters such as polymethyl acrylate, polyethyl acrylate, and polybutyl acrylate; polymethacrylic acid esters such as polymethyl methacrylate, polyethyl methacrylate, and polybutyl methacrylate; and copolymers such as ethylene-acrylic acid ester copolymers, ethylene-acrylic acid ester-acrylic acid copolymers, styrene-methacrylic acid ester-acrylic acid copolymers, acrylic acid ester-vinyl chloride copolymers, acrylic acid ester-acrylic acid copolymers, methacrylic acid ester-vinyl chloride copolymers, styrene-methacrylic acid ester-butadiene copolymers, and methacrylic acid ester-acrylonitrile copolymers, which may be used alone or in combination.

[0045] In the insulating sheet for a motor according to this embodiment, the adhesive layers 10B1 and 10B2 preferably contain polybutyl acrylate (PAB) among the above-mentioned acrylic polymers.

[0046] The adhesive layers 10B1 and 10B2 may contain various known additives. The additives include dispersants, antioxidants, antioxidants, processing aids, stabilizers, antifoaming agents, flame retardants, thickeners, pigments, and the like.

[0047] In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 do not necessarily need to contain a tackifier.

[0048] Generally, in an adhesive layer whose adhesive strength with a resin film layer can be increased by heat curing, the gel fraction after heat curing is 90% or more, and the curing reaction in the adhesive layer has progressed sufficiently. Therefore, if the adhesive layer does not contain a tackifier, the storage modulus of the adhesive layer becomes too high. In this way, when the storage modulus of the adhesive layer becomes too high, the adhesive layer becomes relatively hard accordingly, and therefore the tackiness often decreases. For the reasons mentioned above, adhesive layers that are used after being thermally cured usually contain a tackifier in order to prevent a decrease in tackiness.

[0049] In contrast, in the motor insulating sheet 10 according to this embodiment, as described above, the adhesive layers 10B1, 10B2 are cured at room temperature (more specifically, cured with moisture at room temperature) to increase the adhesive strength with the second resin film layers 10C1, 10C2, etc., and the gel fraction is relatively low at 70% or less. Therefore, in the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 exhibit a relatively low storage modulus compared to adhesive layers that are thermally cured before use, even though they do not contain a tackifier. In the motor insulating sheet 10 according to this embodiment, the adhesive layers 10B1 and 10B2 exhibit a relatively low storage modulus, and thus the decrease in tackiness is suppressed. For the reasons described above, it is believed that in the motor insulating sheet 10 of this embodiment, the adhesive layers 10B1, 10B2 can exhibit sufficient tackiness to increase the adhesive strength with the second resin film layers 10C1, 10C2, etc., even if they do not contain a tackifier.

[0050] (Method of manufacturing insulating sheets for motors) As shown in FIG. 2, the method for producing an insulating sheet for a motor according to this embodiment includes a lamination step S1 of laminating a second resin film layer 10C on at least one surface of a first resin film layer 10A via an adhesive layer 10B; and a curing step S2 for curing the adhesive layer 10B. In the method for producing an insulating sheet for a motor according to the present embodiment, the adhesive layer 10B contains an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct. In the method for producing an insulating sheet for a motor according to this embodiment, room temperature curing is performed so that the gel fraction of the adhesive layer 10B becomes 70% or less.

[0051] <Lamination process S1> The lamination step S1 can be carried out, for example, by applying an adhesive composition containing an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct to at least one surface of the first resin film layer 10A to form at least one adhesive layer 10B, and then bonding one surface of the second resin film layer 10C to the at least one adhesive layer 10B. Alternatively, the lamination step S1 can be performed, for example, by applying the adhesive composition to one side of at least one second resin film layer 10C to form an adhesive layer 10B, and then bonding at least one side of the first resin film layer 10A to the adhesive layer 10B.

[0052] <Curing process S2> In the curing step S2, curing is performed at room temperature so that the gel fraction of the adhesive layer 10B becomes 70% or less. Specifically, the gel fraction of the adhesive layer 10B is set to 70% or less by performing room temperature curing in the presence of water (that is, room temperature moisture curing). As described above, in this specification, normal temperature means a temperature within the range of 5°C or higher and 35°C or lower. As described above, the room temperature curing is preferably carried out for 72 hours or more. By carrying out the room temperature curing for 72 hours or more, it becomes easier to adjust the gel fraction of adhesive layer 10B to 70% or less. If the room temperature curing is carried out for 144 hours, the gel fraction can be adjusted to within the range of 60% to 70%. As described above, the room temperature curing is preferably carried out in an environment with an absolute humidity of 0.002 kg / kg or more and 0.025 kg / kg or less. Furthermore, as described above, the room temperature curing has a water vapor content of 2.31 mg / m 3 More than 10.3mg / m 3 It is preferable to carry out the process under the following conditions: By carrying out the room temperature curing in the above-mentioned environment, it becomes easy to adjust the gel fraction of the adhesive layer 10B to 70% or less.

[0053] The curing step S2 may be performed with the motor insulating sheet wound in a roll. When the curing step S2 is performed in a state where the motor insulating sheet is wound in a roll, the curing step S2 may be performed in a state where the motor insulating sheet is wound with an interleaf paper interposed therebetween. By inserting the slip sheet, air gaps are created between the wound motor insulating sheets, allowing water (e.g., water from the atmosphere) to be supplied to the inside of the motor insulating sheet, allowing room temperature curing to proceed sufficiently throughout the entire motor insulating sheet. Alternatively, inorganic particles having an average particle size (D50) of 0.1 μm or more and 3 μm or less may be attached to the surface of the insulating sheet for a motor, and the insulating sheet for a motor may be wound into a roll before the curing step S2 is performed. By attaching inorganic particles having an average particle size (D50) of 0.1 μm or more and 3 μm or less, gaps can be created between the insulating sheet for motors in a rolled up state, allowing room temperature curing to proceed sufficiently throughout the insulating sheet for motors.

[0054] As described above, the motor insulating sheet 10 according to this embodiment is used in an oil-cooled drive motor for an automobile. Specific examples of use of the motor insulating sheet 10 according to this embodiment will be described below with reference to Figs. In the following, an example will be described in which the oil-cooled drive motor is used as an oil-cooled drive motor for a hybrid vehicle or an electric vehicle.

[0055] The oil-cooled drive motor includes a rotor having a permanent magnet and a stator having a coil, the coil being formed by a segment conductor. The motor insulating sheet 10 according to this embodiment is used for insulation between the coil and the core in the stator.

[0056] FIG. 3 is a perspective view of a stator 1 of an oil-cooled drive motor. As shown in the figure, the stator 1 has a stator core 20 and a coil 30. FIG. 4 is a plan view of this stator 1 as viewed from the direction of the rotation axis (arrow AD) of a rotor (not shown), and FIG. 5 is a cross-sectional view showing the state in which multiple coils 30 are housed in part A of the stator core 20 shown in FIG. 4.

[0057] As shown in these figures, in the stator 1, a plurality of slot grooves 21 are formed on the inner peripheral surface side of a cylindrical stator core 20. The stator 1 has a stator core 20 and a plurality of coils 30 housed in a plurality of slot grooves 21 formed in the stator core 20 . The multiple slot grooves 21 extend along the rotational axis direction (AD in FIG. 3) of the stator core 20, and are arranged in the stator core 20 at regular intervals from each other in the circumferential direction (RD in FIG. 3) of the stator core 20. The slot groove 21 is formed over the entire length of the stator core 20 in the rotational axis direction AD, and an opening 21b having the same shape as the cross-sectional shape of the slot groove 21 is formed in one end face 20a (the upper side in Figure 3, hereinafter also referred to as the "upper end face 20a") and the other end face 20b (hereinafter also referred to as the "lower end face 20b") of the stator core 20.

[0058] In the stator core 20, since the plurality of slot grooves 21 are parallel to each other as described above, the plate-shaped protrusions 22 are formed between the adjacent slot grooves 21. A plurality of the plate-like projections 22 (hereinafter also referred to as "teeth 22") are formed so as to protrude inward in the radial direction of the stator core 20 (direction DD in FIG. 3). As shown in Figs. 4 and 5, teeth 22 have wide portions 22a at their protruding ends that widen in the circumferential direction RD of stator core 20, and have a T-shaped cross section. Therefore, on the inner peripheral surface side of the stator core 20, the width of the slot groove 21 is narrowed, and only a small linear opening 21a is formed.

[0059] The coil 30 is composed of a plurality of segment conductors 31 connected to each other. As shown in FIG. 3, the segment conductor 31 before the coil is formed is a rectangular enamel wire bent into a U-shape and has two legs 31b and a head 31a connecting the two legs 31b.

[0060] The segment conductor 31 has an exposed copper wire portion where the insulating coating has been peeled off at a tip portion 31bx of the leg portion 31b on the opposite side to the head portion 31a. The coil 30 is produced by inserting the legs 31b of the segment conductors 31 through the openings 21b of the slot grooves 21 in the upper end surface 20a of the stator core 20 and exposing the tip portions 31bx from the lower end surface 20b of the stator core 20, electrically connecting the legs 31b of one segment conductor 31 to the legs 31b of another segment conductor 31 at the exposed copper wire portions to form connection portions 31x, and further insulating the connection portions 31x. The two legs 31b of one segment conductor 31 are inserted into different slots 21, respectively.

[0061] Since the coil 30 is manufactured as described above, the stator 1 has an upper coil end portion formed by the head 31a of the segment conductor 31 on the upper end surface 20a side of the stator core 20, and a lower coil end portion formed by the connection portion 31x formed by connecting the leg portions 31b together on the lower end surface 20b side.

[0062] As shown in FIG. 5, each slot groove 21 of the stator core 20 accommodates four legs 31b of the segment conductors 31 forming the coil 30 (each of the four segment conductors 31 accommodates one of the legs 31b), and each slot groove 21 accommodates a total of four legs 31b lined up in a row from the inner circumferential surface side to the outer circumferential surface side.

[0063] As shown in FIG. 5, the motor insulating sheet 10 according to this embodiment is interposed between the four leg portions 31b and the inner wall surface of the slot groove 21. The motor insulating sheet 10 is affixed vertically along the longitudinal direction of the legs 31b of the segment conductor 31 and arranged in the slot groove 21 so as to wrap around the four legs 31b one or more times, and is arranged in the slot groove 21 with both ends in the rotational axis direction AD protruding outward in the rotational axis direction AD from the upper end face 20a and the lower end face 20b of the stator core 20. As described above, the motor insulating sheet 10 is arranged in the slot groove 21 in a manner that wraps around the four leg portions 31b more than once, and thus both ends in the wrapping direction are overlapped and arranged in the slot groove 21. That is, in the stator 1, overlapping portions 10d where the motor insulating sheets 10 overlap each other are formed in the slot grooves 21 (see FIG. 5). As shown in FIG. 5, in the stator 1, the overlapping portion 10d is located on the outer side in the radial direction DD. In addition, the portions protruding from the upper end face 20a and the lower end face 20b of the stator core 20 in the rotational axis direction AD may be bent outward from the slot groove 21 so as to be hooked (engaged) onto at least one of the upper end side and the lower end side of the slot groove 21.

[0064] The coil 30 wound around the motor insulating sheet 10 is fixed in the slot groove 21 by impregnating the slot groove 21 with insulating resin (for example, epoxy varnish).

[0065] The motor insulating sheet and the manufacturing method of the motor insulating sheet according to the present invention are not limited to the above-mentioned embodiment. Furthermore, the motor insulating sheet and the manufacturing method of the motor insulating sheet according to the present invention are not limited by the above-mentioned action and effect. The motor insulating sheet and the manufacturing method of the motor insulating sheet according to the present invention can be modified in various ways without departing from the gist of the present invention. EXAMPLES

[0066] The present invention will now be described in more detail with reference to examples and comparative examples. The following examples are provided to further explain the present invention in detail, and are not intended to limit the scope of the present invention.

[0067] Example 1 As the insulating sheet for a motor according to Example 1, a sheet (a five-layered sheet) having layers laminated in the following order was produced. Polyethylene naphthalate resin layer (second resin film layer. Thickness: 16 μm) Acrylic polymer layer (adhesive layer. Thickness: 15 μm) Polyethylene terephthalate resin layer (first resin film layer. Thickness: 188 μm) Acrylic polymer layer (adhesive layer. Thickness: 15 μm) Polyethylene naphthalate resin layer (second resin film layer. Thickness: 16 μm) The insulating sheet for a motor according to Example 1 had a thickness of 250 μm. In the motor insulating sheet of Example 1, the acrylic polymer layer (adhesive layer) was formed by applying a first adhesive composition obtained by adding 1 part by mass of a trimethylolpropane / tolylene diisocyanate trimer adduct (product name "Coronate L" manufactured by Tosoh Corporation) to 100 parts by mass of polybutylacrylate (PAB) as an acrylic polymer, to both sides of a polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the first adhesive composition was 50 g / m 2 It was. In Example 1, room temperature aging was adopted as the aging condition. Specifically, the temperature is 35°C and the water vapor amount is 2.31 mg / m 3 With this in mind, an aging time of 72 hours was adopted. That is, in the insulating sheet for a motor according to Example 1, the acrylic polymer layer serving as the adhesive layer was cured at room temperature.

[0068] Example 2 As the insulating sheet for a motor according to Example 2, a five-layer laminate sheet was produced in the same manner as in Example 1. In Example 2, the thickness of the polyethylene naphthalate resin layer serving as the second resin film layer was 16 μm, the thickness of the acrylic polymer layer serving as the adhesive layer was 15 μm, the thickness of the polyethylene terephthalate resin layer serving as the first resin film layer was 188 μm, and the thickness of the motor insulating sheet was 250 μm. In the motor insulating sheet of Example 2, the acrylic polymer layer (adhesive layer) was formed by applying a second adhesive composition obtained by adding 2 parts by mass of Coronate L to 100 parts by mass of polybutylacrylate (PAB) to both sides of the polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the second adhesive composition was 50 g / m 2 It was. For Example 2, the same aging conditions as those for Example 1 were adopted. That is, also in the insulating sheet for a motor according to Example 2, the acrylic polymer layer serving as the adhesive layer was cured at room temperature.

[0069] Example 3 As the motor insulating sheet according to Example 3, a five-layer laminate sheet was produced in the same manner as in Example 1. In Example 3, the thickness of the polyethylene naphthalate resin layer serving as the second resin film layer was 16 μm, the thickness of the acrylic polymer layer serving as the adhesive layer was 15 μm, the thickness of the polyethylene terephthalate resin layer serving as the first resin film layer was 188 μm, and the thickness of the motor insulating sheet was 250 μm. In the motor insulating sheet of Example 3, the acrylic polymer layer (adhesive layer) was formed by applying a third adhesive composition obtained by adding 3 parts by mass of Coronate L to 100 parts by mass of polybutylacrylate (PAB) to both sides of the polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the third adhesive composition was 50 g / m 2 It was. For Example 3, the same aging conditions as those for Example 1 were adopted. That is, also in the insulating sheet for a motor according to Example 3, the acrylic polymer layer serving as the adhesive layer was cured at room temperature.

[0070] Example 4 As the insulating sheet for a motor according to Example 4, a five-layer laminate sheet was produced in the same manner as in Example 1. In Example 4, the thickness of the polyethylene naphthalate resin layer serving as the second resin film layer was 16 μm, the thickness of the acrylic polymer layer serving as the adhesive layer was 15 μm, the thickness of the polyethylene terephthalate resin layer serving as the first resin film layer was 188 μm, and the thickness of the motor insulating sheet was 250 μm. In the motor insulating sheet of Example 4, the acrylic polymer layer (adhesive layer) was formed by applying a fourth adhesive composition obtained by adding 10 parts by mass of Coronate L to 100 parts by mass of polybutylacrylate (PAB) to both sides of the polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the fourth adhesive composition was 50 g / m 2 It was. For Example 4, the same aging conditions as those for Example 1 were used. That is, also in the insulating sheet for a motor according to Example 4, the acrylic polymer layer serving as the adhesive layer was cured at room temperature.

[0071] Example 5 As the insulating sheet for a motor according to Example 5, a five-layer laminate sheet was produced in the same manner as in Example 1. In Example 5, the thickness of the polyethylene naphthalate resin layer serving as the second resin film layer was 16 μm, the thickness of the acrylic polymer layer serving as the adhesive layer was 15 μm, the thickness of the polyethylene terephthalate resin layer serving as the first resin film layer was 188 μm, and the thickness of the motor insulating sheet was 250 μm. In the motor insulating sheet of Example 5, the acrylic polymer layer (adhesive layer) was formed by applying a fifth adhesive composition obtained by adding 20 parts by mass of Coronate L to 100 parts by mass of polybutylacrylate (PAB) to both sides of the polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the fifth adhesive composition was 50 g / m 2 It was. For Example 5, the same aging conditions as those for Example 1 were used. That is, also in the insulating sheet for a motor according to Example 5, the acrylic polymer layer serving as the adhesive layer was cured at room temperature.

[0072] Example 6 As the motor insulating sheet according to Example 6, a five-layer laminate sheet was produced in the same manner as in Example 1. In Example 6, the thickness of the polyethylene naphthalate resin layer serving as the second resin film layer was 16 μm, the thickness of the acrylic polymer layer serving as the adhesive layer was 15 μm, the thickness of the polyethylene terephthalate resin layer serving as the first resin film layer was 188 μm, and the thickness of the motor insulating sheet was 250 μm. In the motor insulating sheet of Example 6, the acrylic polymer layer (adhesive layer) was formed by applying a sixth adhesive composition obtained by adding 35 parts by mass of Coronate L to 100 parts by mass of polybutylacrylate (PAB) to both sides of the polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the sixth adhesive composition was 50 g / m 2 It was. For Example 6, the same aging conditions as those for Example 1 were used. That is, also in the insulating sheet for a motor according to Example 6, the acrylic polymer layer serving as the adhesive layer was cured at room temperature.

[0073] Comparative Example 1 As the insulating sheet for a motor according to Comparative Example 1, a five-layer laminate sheet was produced in the same manner as in Example 1. In addition, in Comparative Example 1, the thickness of the polyethylene naphthalate resin layer serving as the second resin film layer was 16 μm, the thickness of the acrylic polymer layer serving as the adhesive layer was 15 μm, the thickness of the polyethylene terephthalate resin layer serving as the first resin film layer was 188 μm, and the thickness of the motor insulating sheet was 250 μm. In the motor insulating sheet of Comparative Example 1, the acrylic polymer layer (adhesive layer) was formed by applying a seventh adhesive composition obtained by adding 10 parts by mass of Coronate L to 100 parts by mass of polybutylacrylate (PAB) to both sides of a polyethylene terephthalate resin layer (first resin film layer) to a thickness of 15 μm. The coating amount of the seventh adhesive composition was 50 g / m 2 It was. In Comparative Example 1, heat aging was used as the aging condition. Specifically, the temperature was set to 130° C., the amount of water vapor was not adjusted, and the aging time was 24 hours. That is, in the insulating sheet for a motor according to Comparative Example 1, the acrylic polymer layer serving as the adhesive layer was heat-cured.

[0074] <Gel fraction> For the motor insulating sheets according to the respective examples, the gel fraction of the acrylic polymer layer serving as the adhesive layer was measured. The gel fraction was measured according to the method described in the embodiment section above. The results of measuring the gel fraction are shown in Table 1 below.

[0075] <Appearance evaluation after aging> After aging, the motor insulating sheet according to each example was evaluated for appearance. Specifically, the insulating sheets for motors according to each example were visually observed to see whether or not the polyethylene naphthalate layer serving as the second resin film layer was wrinkled. When no wrinkles were observed in the polyethylene naphthalate layer, the sample was rated as excellent, and when wrinkles were observed, the sample was rated as fair. The results of the appearance evaluation after aging are shown in Table 1 below.

[0076] <Peel strength> A rectangular sample having a width of 25 mm was cut out from the motor insulating sheet according to each example. Then, using a tensile testing machine, the polyethylene naphthalate resin layer (second resin film layer) was pulled from the acrylic polymer layer (adhesive layer) at a test speed of 300 mm / min under an environment of room temperature (23°C) and a relative humidity of 50% RH to perform a 180-degree peel test to determine the peel strength (N / 25 mm). The peel strength was measured and the results are shown in Table 1 below.

[0077] <Appearance evaluation after heating test> The motor insulating sheets according to the respective examples were evaluated for appearance after the heating test. Specifically, the motor insulating sheets according to each embodiment were placed in an oven and heated at 150°C for 4 hours, after which an evaluation was made as to whether or not the polyethylene naphthalate resin layer (second resin film layer) had lifted off the acrylic polymer layer (adhesive layer). The samples in which no separation of the polyethylene naphthalate resin layer (second resin film layer) from the acrylic polymer layer (adhesive layer) was observed were rated as excellent, and the samples in which separation was observed were rated as fair. The results of the appearance evaluation carried out after the heating test are shown in Table 1 below. As shown in Table 1 below, in the insulating sheet for a motor according to Comparative Example 1, it was confirmed that the polyethylene naphthalate layer was wrinkled after aging (appearance evaluation after aging was acceptable), so the appearance evaluation after the heating test was omitted.

[0078] [Table 1]

[0079] As can be seen from Table 1, in the motor insulating sheets according to each embodiment, the gel fraction of the acrylic polymer layer (adhesive layer) was 70% or less, and the results of the appearance evaluation after aging were all excellent. In contrast, in the insulating sheet for a motor according to Comparative Example 1, the gel fraction of the acrylic polymer layer (adhesive layer) was 91%, and the result of the appearance evaluation after aging was found to be acceptable. From these results, it can be seen that by making the adhesive layer contain an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct and setting the gel fraction of the adhesive layer to 70% or less, it is possible to suppress wrinkling of the second resin film layer arranged on the surface portion.

[0080] Also, it can be seen that, among the insulating sheets for a motor according to each example, the insulating sheets for a motor according to examples 4 to 6 achieved excellent results in the appearance evaluation after the heating test. These results show that by containing 5 to 40 parts by mass of trimethylolpropane / tolylene diisocyanate trimer adduct per 100 parts by mass of acrylic polymer, it is possible to prevent the second resin film layer from lifting off the adhesive layer after exposure to a heated environment. Furthermore, in the motor insulating sheets of Examples 4 to 6, the gel fraction of the adhesive layer was in the range of 50% or more and 70% or less, which shows that by setting the gel fraction of the adhesive layer to 50% or more and 70% or less, it is possible to prevent the second resin film layer from lifting up from the adhesive layer. A photograph showing the appearance of the motor insulating sheet according to Example 4 after the heating test is shown in Fig. 6. As shown in Fig. 6, in the motor insulating sheet according to Example 4, no lifting of the polyethylene naphthalate resin layer (second resin film layer) from the acrylic polymer layer (adhesive layer) was observed.

[0081] <Effects of curing temperature and water vapor amount> In order to examine the influence of the curing temperature and the amount of water vapor, the insulating sheet for a motor according to Example 4 was cured at the following temperature and amount of water vapor, and the change in gel fraction over time was examined. (1) Temperature: 5°C, water vapor content: 5.17 mg / m 3 (2) Temperature: 23°C, water vapor content: 10.3 mg / m 3 As a result, it was found that in both of the above (1) and (2), by carrying out aging for 72 hours or more, the gel fraction of the adhesive layer became 50% or more and 70% or less. Based on the results of the above examples and this result, the temperature is set to 5°C or higher and 35°C or lower, and the water vapor amount is 2.31 mg / m 3 More than 10.3mg / m 3 It can be seen that the gel fraction of the adhesive layer can be appropriately adjusted by setting the following. [Explanation of symbols]

[0082] 1 stator, 10 motor insulation sheet, 20 stator core, 21 slot groove, 22 plate-shaped protrusion (teeth), 30 coil, 31 segment conductor, 10A first resin film layer, 10B adhesive layer, 10B1 adhesive layer, 10B2 adhesive layer, 10C second resin film layer, 10C1 second resin film layer, 10C2 second resin film layer, 10d overlapping portion, 20a end surface (upper end surface), 20b end surface (lower end surface), 21a linear opening, 21b opening, 22a wide portion, 31a head, 31b leg portion, 31bx tip portion, 31x connection portion, AD is the axial direction, DD is the radial direction, and RD is the circumferential direction.

Claims

1. A first resin film layer; a second resin film layer laminated on at least one surface of the first resin film layer via an adhesive layer, The adhesive layer contains an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct, and has a gel fraction of 70% or less. Insulation sheet for motors.

2. The adhesive layer contains 5 parts by mass or more and 40 parts by mass or less of the trimethylolpropane / tolylene diisocyanate trimer adduct per 100 parts by mass of the acrylic polymer. The insulating sheet for a motor according to claim 1 .

3. The adhesive layer has a gel fraction of 50% or more. The insulating sheet for a motor according to claim 1 or 2.

4. a lamination step of laminating a second resin film layer on at least one surface of the first resin film layer via an adhesive layer; and a curing step of curing the adhesive layer. The adhesive layer includes an acrylic polymer and a trimethylolpropane / tolylene diisocyanate trimer adduct, In the curing step, the adhesive layer is cured at room temperature so that the gel fraction of the adhesive layer is 70% or less. A manufacturing method for insulating sheets for motors.

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