Switchable window material

Abstract

A switchable window member (10) having a layer structure is proposed. The layer structure includes a switchable layer (20), two polarizers, and two optical retarders, wherein a first polarizer and a first optical retarder are arranged before the switchable layer (20) in an optical path (40), and a second polarizer and a second optical retarder are arranged after the switchable layer (20) in the optical path (40). Furthermore, the switchable layer (20) is a vertically aligned liquid crystal layer containing a liquid crystal medium, wherein the product of the thickness d of the switchable layer (20) and the optical anisotropy Δn of the liquid crystal medium is in the range of 0.05 μm to 3.0 μm, and the liquid crystal medium has a clearing point of at least 70°C. A further aspect of the invention relates to the use of the switchable window element as a window for a building or vehicle.

Description

[Technical field]

[0001] The present invention relates to a switchable window element comprising a switchable layer. A further aspect of the invention relates to the use of such a switchable window element as a window for an architecture or vehicle. [Background technology]

[0002] Smart windows, which include a switchable window member, allow for control of the transmission of light through the window by control of a signal. Such smart windows are known in the art.

[0003] In the review paper by R.Baetens et al. "Properties, requirements and possibilities of smart windows for dynamic daylight and solar energy control in buildings: A state-of-the-art review", Solar Energy Materials & Solar Cells 94 (2010) pp. 87-105, tintable smart windows are described. Smart windows can use several technologies to modulate the light transmittance, such as electrochromic based elements, liquid crystal elements, and electrophoretic or suspended particle elements. Liquid crystal based elements use the change in the orientation of the liquid crystal molecules between two conductive electrodes by applying an electric field, which results in a change in their transmittance.

[0004] When the window element is used as a window in a building or vehicle, it is desirable for the light transmission to be uniform and independent of viewing angle.

[0005] Seung-Hoon Ji and Gi-Dong Lee (2008), "An optical configuration for vertical alignment liquid crystal cell with wide viewing angle", Journal of Information Display, 9:2, 22-27, DOI:10.1080 / 15980316.2008.9652054, discloses an optical configuration for a vertical alignment liquid crystal cell for use in a display that includes a combination of retardation plates. The retardation plates are placed before and after the vertical alignment liquid crystal layer in the light path. The retardation plates compensate for phase dispersion, thereby reducing light leakage and providing a wide viewing angle.

[0006] EP3260913 A1 discloses a light switching element comprising a polarising layer and a switching layer, the switching layer comprising a liquid crystal material and a dichroic dye compound, the switching layer having a light state and a dark state. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] European Patent Application Publication No. 3260913 [Non-patent literature]

[0008] [Non-Patent Document 1] R. Baetens et al. “Properties, requirements and possibilities of smart windows for dynamic daylight and solar energy control in buildings: A state-of-the-art review”, Solar Energy Materials & Solar Cells 94 (2010) pages 87–105 [Non-Patent Document 2] Seung-Hoon Ji and Gi-Dong Lee (2008), “An optical configuration for vertical alignment liquid crystal cell with wide viewing angle”, Journal of Information Display, 9:2, 22-27, DOI:10.1080 / 15980316.2008.9652054 Summary of the Invention [Problem to be solved by the invention]

[0009] An object of the present invention is to provide a window member in which the viewing angle dependency of the light transmittance through the window member is reduced. [Means for solving the problem]

[0010] A switchable window member having a layer structure is proposed. The layer structure includes a switchable layer, two polarizers and two optical retarders, where the first polarizer and the first optical retarder are arranged in front of the switchable layer in the optical path, and the second polarizer and the second optical retarder are arranged in the optical path after the switchable layer. Furthermore, the switchable layer is a vertically aligned liquid crystal layer containing a liquid crystal medium, where the product of the thickness d of the switchable layer and the optical anisotropy Δn of the liquid crystal medium is in the range of 0.05 μm to 3.0 μm, and the liquid crystal medium has a clearing point of at least 70°C.

[0011] The switchable window member preferably has a dark state in which light is absorbed by the switchable window member and a bright state in which light may be transmitted through the switchable window member, switching between said states being achieved by applying an electric field to the switchable layer.

[0012] In some embodiments, the bright state may optionally be configured as a mode in which the liquid crystal medium twists in the range of 0° to 360° in the presence of an applied electric field. The liquid crystal medium may optionally contain one or more chiral compounds, in particular one or more chiral dopants.

[0013] Preferably, the overall transmittance τ of visible light through the switchable window member v is switchable in the range of 0% to 47%, and more preferably in the range of 2% to 37%. In the bright state, the transmittance τ of visible light through the switchable window member is v is preferably better than 20%, and more preferably better than 25%. In the dark state, the transmittance of visible light through the switchable window member is preferably less than 5%, more preferably less than 2%, and particularly preferably less than 1%. Visible light has a wavelength of 380 to 780 nm. The transmittance τ of visible light v is measured in accordance with EN 410:2011-04.

[0014] Advantageously, the switchable window member has reduced viewing angle dependence, which may minimize or even prevent unwanted light leakage or unwanted color shifts, especially in the dark state.

[0015] The switchable layer is a vertically aligned liquid crystal layer. The molecules of the liquid crystal medium are aligned perpendicular to the substrate surface and can be switched parallel to the plane of the layer structure by application of an electric field perpendicular to said plane. The liquid crystal medium has a negative dielectric anisotropy, which aligns perpendicular to the electric field.

[0016] Examples of suitable liquid crystal media with negative dielectric anisotropy are described in EP1378558 A1. The liquid crystal medium may contain additives. In particular, the liquid crystal medium preferably contains an antioxidant in a concentration of at least 5 ppm.

[0017] More preferably, the liquid crystal medium has an optical anisotropy (Δn) for light having a wavelength of 589.3 nm of 0.03 to 0.3, particularly preferably 0.04 to 0.27. The liquid crystal material also preferably has a dielectric anisotropy Δε of −0.5 to −20, preferably −1.5 to −10.

[0018] The product of the thickness d of the switchable layer and the optical anisotropy Δn of the liquid-crystalline medium is in the range from 0.05 μm to 3.0 μm, preferably in the range from 0.2 μm to 0.4 μm, for example said product is 0.3 μm.

[0019] Unless expressly stated, all physical properties and physicochemical or electro-optical parameters are measured in accordance with generally known methods, in particular "Merck Liquid Crystals, Physical Properties of Liquid Crystals", status Nov. 1997, Merck KGaA (Germany) and are stated for a temperature of 20°C.

[0020] In the above and below, Δn denotes the optical anisotropy, where Δn=n e -n o and Δε denotes the dielectric anisotropy, where Δε=ε || -ε ⊥ The dielectric anisotropy Δε is measured at 20° C. and 1 kHz. The optical anisotropy Δn is measured at 20° C. and a wavelength of 589.3 nm.

[0021] The liquid crystal medium of the switchable layer preferably has a nematic phase at the operating temperature of the switchable window member. It is particularly preferably nematic in the range of ±20° C. above and below the operating temperature of the switchable window, very particularly preferably in the range of ±30° C. The operating temperature of the switchable window member is preferably between −20° C. and 70° C.

[0022] Further preferably, the liquid crystal medium has a clearing point in the range from 70° C. to 170° C., preferably above 80° C., more preferably above 100° C., particularly preferably above 105° C., very particularly preferably above 110° C. and most preferably above 115° C. Even more preferred are higher clearing points, in particular above 120° C. and more preferably above 130° C. The clearing point indicates the temperature at which the phase transition from the nematic liquid crystal state to the isotropic state occurs.

[0023] The clearing point, in particular the phase transition temperature between the nematic and isotropic phases, can be measured and determined by generally known methods, for example using a Mettler oven or a hot stage, under a polarizing microscope, preferably using a Mettler oven.

[0024] The first and second polarizers are preferably configured as linear polarizers that transmit light of a first linear polarization and absorb and / or reflect light of an orthogonal second linear polarization, respectively. Suitable polarizers are available, for example, from Polatechno Co., Ltd.

[0025] In a first configuration of the switchable window member, the first polarizer and the second polarizer have the same orientation relative to each other such that they both transmit light of the same linear polarization, In a second configuration of the switchable window member, the first polarizer and the second polarizer are arranged in a crossed configuration relative to each other such that linear polarization transmitted by the first polarizer is absorbed and / or reflected by the second polarizer, and vice versa.

[0026] When no voltage, and therefore no electric field, is applied, the homeotropic orientation of the liquid crystal medium has no effect on the plane of polarization of the transmitted light, producing a bright state (normally bright) for the first configuration of the switchable window members and a dark state (normally dark) for the second configuration of the switchable window members.

[0027] Preferably, the first configuration is selected when a bright state of the window member is desired as the fail-safe state, and the second configuration is preferably selected when a dark state of the window member is desired as the fail-safe state. The switchable window member is in the fail-safe state when no voltage, and therefore no electric field, is applied.

[0028] The optical retarder is disposed before and after the vertically aligned liquid crystal layer in the optical path. The optical retarder compensates for phase dispersion, thereby reducing light leakage, especially in the dark state, and obtaining a low viewing angle dependence of the transmittance. The optical retarder has a slow axis in principle, and linearly polarized light with a polarization parallel to the slow axis is retarded relative to light with an orthogonal linear polarization.

[0029] Preferably, the first optical retarder and / or the second optical retarder are configured as a first / second retardation element having a layer structure including an optically isotropic substrate and a retardation layer.Furthermore, the first / second retardation element can include a first / second polarizing layer, respectively, to form a combination element of polarization and retardation.

[0030] The optically isotropic substrate is preferably selected from glass or transparent polymer. Examples of suitable glasses include, for example, alkaline earth aluminoborosilicate glass, chemically strengthened glass, aluminosilicate glass, borosilicate glass, and soda lime glass. Examples of suitable transparent polymers include polycarbonate (PC), cycloolefin polymer (COP), polyethylene terephthalate (PET), polyimide, and polyethylene naphthalate (PEN).

[0031] Optionally, the first optical retarder and / or the second optical retarder are configured as a first / second retardation element, preferably having a layer structure including an optically anisotropic substrate and a retardation layer.

[0032] In an alternative embodiment, the first optical retarder and / or the second optical retarder preferably consist of an optically anisotropic substrate.

[0033] The use of an optically anisotropic substrate is advantageous because the substrate can be used as a single element both to provide mechanical stability and to compensate for phase dispersion.

[0034] Examples of suitable optically anisotropic substrates include polyethylene terephthalate (PET), cellulose triacetate (TAC) and polycarbonate (PC). The anisotropic optical properties of polymers can be obtained, for example, by mechanical biaxial stretching, which induces preferential orientation of the macromolecular chains in the polymer.

[0035] In a further embodiment, it is also possible to use anisotropic substrates that have very large birefringence and exhibit quasi-isotropic optical behavior.

[0036] In the embodiment in which the first / second retardation element comprises or consists of an optically isotropic or anisotropic substrate, each substrate of the retardation element preferably also serves as a substrate for the liquid crystal cell, and the optically isotropic or anisotropic substrate faces towards the cell gap. In the layered retardation element, any order of retardation layers and substrate layers is possible. Furthermore, in the switchable window member, different embodiments of the retardation element can be combined, for example, the first retardation element comprises an optically isotropic substrate and the second retardation element comprises an optically anisotropic substrate.

[0037] If the substrates are not provided as part of the retardation or other functional element of the switchable window member, then it is preferable to provide two optically isotropic substrates which form the liquid crystal cell.

[0038] Preferably, the first retardation element and / or the second retardation element has an out-of-plane retardation R thAdditionally or alternatively, the retardation element has an in-plane retardation R e The absolute value of the thickness is 1 to 300 nm, preferably 5 to 70 nm.

[0039] The exact out-of-plane and / or in-plane retardation is preferably selected within these ranges such that the phase dispersion of the light passing through one or more layers and / or elements of the layer structure is compensated. In particular, the out-of-plane and in-plane retardations of the first and second optical retarders are preferably set in a bright state for the switchable layer such that the light passing through the first polarizer layer, the first optical retarder, the switchable layer and the second optical retarder is linearly polarized, with the polarization being parallel to the orientation of the second polarizer. When the switchable layer is set in a dark state, the light passing through the first polarizer layer, the first optical retarder, the switchable layer and the second optical retarder is linearly polarized, with the polarization being orthogonal to the orientation of the second polarizer.

[0040] R of the retardation element or layer e and R th The value of can be determined, for example, using an automatic birefringence analyzer. Such an automatic analyzer is available, for example, under the trade name KOBRA-21ADH from Oji Instruments Co., Ltd. The retardation analysis is preferably carried out at a wavelength of 590 nm.

[0041] The required retardation can be determined by measuring the phase dispersion of each layer / element of the layer structure. Additionally or alternatively, a model of the layer structure can be used to determine the R required to compensate for the phase dispersion. e and R th The value of can be calculated.

[0042] Some functional layers of the layer structure may be provided as a combined element, for example a polarizer and an optical retarder may be provided in the form of a combined element providing the functionality of a polarizer and an optical retarder.

[0043] Furthermore, the substrate layers, in particular the optically isotropic substrate layers, may be provided separately from the polarizer and / or the optical retarder. In particular, it is possible to provide the polarizer and the optical retarder as a combined element which is then applied to the optically isotropic substrate of the liquid crystal cell.

[0044] In a preferred embodiment of the switchable window member, one or more anti-reflective coatings may be applied to one or more of the provided layers and / or to the substrate to reduce and minimize unwanted light reflection.

[0045] To form a liquid crystal cell, the switchable element is sandwiched between two substrate layers that define a cell gap. The substrates are preferably optically transparent and may be rigid or flexible. Preferably, one of the functional layers or elements of the layer structure serves as a substrate layer. For example, an optical retarder and / or a polarizer can serve as a substrate. The two substrates are arranged such that a cell gap is formed between the two substrates. The cell gap preferably has a width of 1 μm to 35 μm, and more preferably 2 μm to 30 μm. The switchable layer is located inside the cell gap. The switchable layer therefore preferably has a thickness d of 1 μm to 35 μm.

[0046] In order to maintain a suitable thickness d of the switchable layer, a spacer can be placed in the cell gap of the switchable layer. Typically, the spacer has the shape of a sphere with a diameter in the range of the cell gap. For example, a non-conductive spacer made of polymer or glass can be used, with the shape of a sphere with a predetermined diameter. In some embodiments, it may be useful to have a sticky spacer, i.e. a spacer with some inherent adhesive properties, for good adhesion to the surface. For example, it may be useful to use a black spacer, to avoid or minimize undesirable light leakage. In some embodiments, it may be particularly beneficial to use a black and sticky spacer. Alternatively, the cell thickness can be set or minimized by other suitable means, for example by using a column spacer. The column spacer can also be formed to provide compartments, thus allowing a structure that can be cut freely in some cases. Thus, in some embodiments, the switchable layer can include separated compartments, each of which contains a liquid crystal medium, for example using a prismatic or honeycomb structure.

[0047] In combination with flexible substrates, thinner switchable layers are preferred, as applying thinner switchable layers leads to more stable devices, especially less prone to undesired movement of the spacers relative to the substrate layer.

[0048] In order to apply an electric field to the switchable layer, preferably two electrodes are provided. An electric field is generated between the two electrodes, for example by applying a voltage to the electrodes using a driving signal. Preferably, the electrodes are transparent electrode layers, and the switchable layer is disposed between the two transparent electrode layers. A power supply, which may include a driving signal generator and a cable, can be used to supply a voltage to the electrodes.

[0049] The transparent electrodes are for example based on thin layers of indium tin oxide (ITO). The electrodes are preferably applied to the two substrates and are arranged such that the transparent electrodes face each other.

[0050] Preferably, the layer structure of the switchable window member comprises, in that order, a first polarizer layer, a first retardation element, a first electrode layer, a first alignment layer, a switchable layer, a second alignment layer, a second electrode layer, a second retardation element, and a second polarizer layer.

[0051] Preferably, the first alignment layer and / or the second alignment layer is a homeotropic alignment layer. The homeotropic alignment layer is preferably a polyimide-based layer.

[0052] In a vertically aligned liquid crystal layer, the liquid crystal molecules are oriented such that the director is perpendicular or essentially perpendicular to the plane of the layer structure. Preferably, a small pretilt angle, for example 1°-2°, is set for the alignment of the liquid crystal layer so that the homeotropic alignment deviates slightly from 90°, for example by obtaining an orientation angle of 88°-89°. The pretilt angle can be influenced by an alignment layer. A pretilt angle of about 90° can be achieved, for example, by incorporating polyhedral oligomeric silsesquioxane (POSS) nanoparticles into the polyimide alignment layer. This and further methods for adjusting the pretilt angle are described, for example, in the publication "Controlling the Alignment of Polyimide for Liquid Crystal Devices", Shie-Chang Jeng and Shug-June Hwang, December 19, 2012, DOI 10.5772 / 53457.

[0053] In a preferred embodiment, polymer stabilized vertical alignment (PS-VA) is used.

[0054] In an alternative embodiment of the switchable window member, a self-aligned vertically aligned (SA-VA) liquid crystal layer is used. In such an embodiment, no alignment layer is required, and the layer structure preferably comprises, in this order, a first polarizer layer, a first retardation element, a first electrode layer, a switchable layer, a second electrode layer, a second retardation element, and a second polarizer layer.

[0055] In SA-VA liquid crystal medium, a small amount of additive is doped to provide vertical alignment function by the liquid crystal medium itself without the need for an alignment layer such as a polyimide layer on the substrate surface. SA-VA additive material contains two main parts: anchoring group and core structure. Since the anchoring part is vertically bonded to the substrate surface, no additional alignment layer is required.

[0056] The switchable window member may be a planar window member.

[0057] Alternatively, the switchable window member may be curved in space. For example, the switchable window member may be curved along a single direction such that the window member has a single radius of curvature. In other examples, the switchable window member is curved along two directions, where the radius of curvature may be the same or different for each of the two directions.

[0058] To provide additional mechanical strength, the switchable window member preferably comprises at least one further substrate and at least one intermediate layer, whereby the at least one further substrate is connected to the second polarizer layer and / or the second polarizer layer by means of the at least one intermediate layer.

[0059] The further substrate is preferably optically transparent and may be selected from a polymer or glass.

[0060] Suitable glass materials for the further substrate include, for example, float glass or down-draw glass. The glass may also be subjected to pre-treatment steps, such as tempering, strengthening and / or coating or sputtering. The glass may, for example, be soda-lime glass, borosilicate glass or aluminosilicate glass.

[0061] For lamination, a laminating sheet (interlayer) is placed between the at least one sheet and the switchable window member. Subsequent processing, which usually requires the application of heat and / or elevated pressure, bonds the at least one sheet, the interlayer and the switchable window member.

[0062] Suitable laminating sheets include, for example, ionoplast, ethylene vinyl acetate (EVA), polyvinyl butyral (PVB) or thermoplastic polyurethane (TPU).

[0063] A suitable ionoplast is available under the trade name SentryGlas.

[0064] Alternatively, the at least one sheet and the at least one switchable window member may be joined by applying an adhesive at the interface between the second side of the sheet and the first substrate layer.

[0065] The switchable window member is preferably combined with a further component, such as a window frame, to form a switchable window.

[0066] Preferably, the switchable window element is used as a sunroof or rear window in a vehicle, where the switchable window element is configured to be normally darkened, such that when no electric field is applied the window element is configured to be in a dark state, so that the switchable window element can be protected from bright sunlight if the drive signal cannot be applied, for example due to a power failure.

[0067] Furthermore, the switchable window element is preferably used as a windshield or window of a vehicle or a window of a building, where the switchable window element is configured to be normally bright. By configuring the window element to be in a bright state when no electric field is applied, the switchable window element can ensure that the view outside the window is not blocked when the drive signal cannot be applied, for example due to a power failure.

[0068] Thanks to the excellent dark state, the device can be useful in architectural or automotive applications, for example as switchable blinds or screens, or as an acid shield. By optionally providing segmentation of the window material, spatially selective or partial dimming can be obtained. [Brief description of the drawings]

[0069] [Figure 1] FIG. 2 shows a first embodiment of a switchable window member. [Diagram 2] FIG. 2 shows a second embodiment of a switchable window member. [Diagram 3] FIG. 4 shows a third embodiment of a switchable window member. [Figure 4a] FIG. 2 is a diagram showing the angle dependence of the dark state of a prior art window member. [Figure 4b] FIG. 4 is a diagram showing the angle dependence of the dark state of the window member of the present invention. [Figure 5a] FIG. 2 shows the angular dependence of the bright state of a prior art window member. [Figure 5b] FIG. 4 is a diagram showing the angle dependence of the bright state of the window member of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0070] 1 shows a first embodiment of a switchable window member 10. The switchable window member 10 has a layer structure comprising, in this order, a first polarizer layer 12, a first retardation element 14, a first electrode layer 16, a first alignment layer 18, a switchable layer 20, a second alignment layer 22, a second electrode layer 24, a second retardation element 26 and a second polarizer layer 28. The first and second electrode layers 16, 24 are for example based on thin layers of indium tin oxide (ITO).

[0071] Depending on the configuration of the switchable window member 10, the first and second polarizer layers 12, 28 may be arranged in a parallel or crossed configuration. In the crossed configuration, the window member 10 is normally dark. In the parallel configuration, the window member 10 is normally bright.

[0072] In the embodiment of Fig. 1, the first retardation element 14 and the second retardation element 26 serve as substrates for the liquid crystal cell. The first retardation element 14 supports the first electrode layer 16 and the first alignment layer 18, and the second retardation element 26 supports the second electrode layer 24 and the second alignment layer 22. The retardation elements 14, 26 of the first embodiment are configured as optically anisotropic substrates, which provide both mechanical stability and compensation for phase dispersion in one element.

[0073] The two substrates are arranged such that a liquid crystal cell with a cell gap is formed. A switchable layer 20 is sandwiched between the two substrates, with the two alignment layers 18 and 22 facing towards the switchable layer 20. An encapsulant 30 closes the cell.

[0074] The switchable layer 20 is a vertically aligned liquid crystal layer comprising a liquid crystal medium with negative dielectric anisotropy Δε. To achieve vertical alignment with a pretilt angle of about 90°, the alignment layers 18 and 22 are constructed as homeotropic polyimide-based alignment layers.

[0075] Light passing through the switchable window member 10 along optical path 40 is first linearly polarized by the first polarizer layer 12. The light then passes through the first retardation element 14. Depending on the state of the switchable layer 20, the light's linear polarization plane is either unaffected or rotated by approximately 90°. After the switchable layer 20, the light passes through the second retardation element 26 and then through the second polarizing layer 28.

[0076] The out-of-plane and / or in-plane retardation of the two retardation elements 14, 26 are selected to compensate for the phase dispersion of the light passing through the layers 12, 16, 18, 20, 22, 24 and the elements 14, 26 of the layer structure. In particular, the out-of-plane and in-plane retardations of the first and second retardation elements 14, 16 are set to a bright state for the switchable layer 20 such that the light passing through the first polarizer layer 12, the first retardation element 14, the switchable layer 20 and the second retardation element 26 is linearly polarized, with the polarization being parallel to the orientation of the second polarizer layer 28. When the switchable layer 20 is set to the dark state, light passing through the first polarizer layer 12, the first retardation element 14, the switchable layer 20 and the second retardation layer 26 is linearly polarized, with the polarization orthogonal to the orientation of the second polarizer layer 28.

[0077] Figure 2 shows a second embodiment of a switchable window member 10. The switchable window member 10 of Figure 2 has the same layer structure as the switchable window member 10 of the first embodiment described with reference to Figure 1. The switchable window member 10 of the second embodiment has a layer structure including, in this order, a first polarizer layer 12, a first retardation element 14, a first electrode layer 16, a first alignment layer 18, a switchable layer 20, a second alignment layer 22, a second electrode layer 24, a second retardation element 26, and a second polarizer layer 28.

[0078] In a second embodiment shown in Fig. 2, the first retardation element 14 is a layer structure comprising a first retardation layer 32 and a first substrate layer 34. Similarly, the second retardation element 26 is a layer structure comprising a second retardation layer 38 and a second substrate layer 36. In the second embodiment, the substrate layers 34, 36 of the retardation elements 14, 16 face towards the switchable layer 20.

[0079] The configuration of the retardation elements 14, 26 as a layer structure allows the use of both optically isotropic and anisotropic substrates. The substrate can be selected primarily to provide the required mechanical properties, since the substrate layers 34, 36 may not provide the entire retardation required, or may only provide a portion of it. The remaining amount of retardation is provided by the first and second retardation layers 32, 38, which can be selected depending only on the required retardation, since they do not have to meet the mechanical stability requirements themselves.

[0080] Figure 3 shows a third embodiment of a switchable window member 10. The switchable window member 10 of Figure 3 has essentially the same layer structure as the switchable window member 10 of the second embodiment described with reference to Figure 2. However, the first polarizer element 12 and the first retardation layer 32 are provided in the form of a first combined polarizer-retarder element 50, and the second polarizer element 28 and the second retardation element 38 are provided in the form of a second combined polarizer-retarder element 52.

[0081] This structure allows the use of optically isotropic substrates 34 and 36, which are combined with the first and second electrode layers 16, 24, the first and second alignment layers 18, 22 and the switchable layer 20 to form a liquid crystal cell. The liquid crystal cell can be manufactured in a first step and the combined polariser and retarder elements 50, 52 applied at a later step.

[0082] Furthermore, the switchable window member 10 of the third embodiment further comprises a substrate 44 and an intermediate layer 42 .

[0083] The further substrate 44 is included to provide additional mechanical strength. In the embodiment shown in Figure 3, the further substrate 44 is connected to the second polarizer layer 28 by an intermediate layer 42. Alternatively or additionally, the further substrate 44 may be connected to the first polarizer layer 12. The further substrate 44 is preferably optically transparent and may be selected from a polymer or glass. EXAMPLES

[0084] A vertically aligned liquid crystal cell of the present invention was fabricated, in which the product of the thickness d of the switchable layer and the optical anisotropy Δn of the liquid crystal medium was set to 0.3 μm. The cell gap d was set to 3.45 μm. Two polarizer films additionally containing retardation elements provided by Polatechno Co., Ltd. were used as the first and second polarizer layers, and the first and second retardation elements. The combined films of polarizer and retarder were applied to an optically isotropic substrate to form a liquid crystal cell.

[0085] A liquid crystal cell with a Heilmeyer configuration was used as a comparative example. In a Heilmeyer cell, a guest-host system containing at least one liquid crystal as the host and a dichroic dye as the guest is used as the switchable layer. When the LC molecules change their orientation due to an applied electric field, the orientation of the dichroic dye is also changed. Since the dichroic dye absorbs or preferentially absorbs light in one direction, the light transmission can be modulated by changing the orientation of the dichroic dye. In the comparative example, a configuration using one polarizer and one liquid crystal cell was used.

[0086] The angular dependence of the transmittance of the cell of the present invention and the Heilmeyer cell was measured for the dark and bright states. The transmittance in the dark state is shown in Figures 4a and 4b. Figure 4a shows the dark state transmittance of the Heilmeyer cell, and Figure 4b shows the dark state transmittance of the switchable window member of the present invention with a vertically aligned liquid crystal layer. The switchable window member of the present invention provides an improved dark state with lower transmittance and less angular dependence than the Heilmeyer cell.

[0087] The transmittance in the bright state is shown in Figures 5a and 5b. Figure 5a shows the transmittance in the bright state of the Heilmeyer cell, and Figure 5b shows the transmittance in the bright state of the switchable window element of the present invention with a vertically aligned liquid crystal layer. The bright state of the switchable window element of the present invention is slightly less than that of the Heilmeyer cell. However, the angle with the brightest transmittance is large for the switchable window element of the present invention, while the angle for the brightest transmittance is narrow for the Heilmeyer cell. [Explanation of symbols]

[0088] 10 Switchable window material 12 First polarizer layer 14 First Retardation Element 16 First electrode layer 18 First alignment layer 20 Switchable Layers 22 Second alignment layer 24 Second electrode layer 26 Second Retardation Element 28 Second Polarizer Layer 30 Encapsulating material 32 First retardation layer 34 1st board layer 36 Second Board Layer 38 Second Retardation Layer 40 light path 42 Middle Class 44 More Substrates 50 First combined polarizer-retarder element 52 Second Combined Polarizer-Retarder Element

Claims

1. A switchable window member (10) having a layer structure including a switchable layer (20), two polarizers and two optical retarders, a first polarizer and a first optical retarder being arranged in front of the switchable layer (20) in an optical path (40), and a second polarizer and a second optical retarder being arranged after the switchable layer (20) in the optical path (40), the switchable layer (20) is a vertically aligned liquid crystal layer comprising a liquid crystal medium, the product of the thickness d of the switchable layer (20) and the optical anisotropy Δn of the liquid-crystalline medium is in the range of 0.05 μm to 3.0 μm, said liquid-crystalline medium has a clearing point above 120° C. and said liquid-crystalline medium has an optical anisotropy Δn in the range of 0.03 to 0.3 for light having a wavelength of 589.3 nm and a dielectric anisotropy Δε of −0.5 to −20, the molecules of said liquid crystal medium are oriented perpendicular to the substrate surface and can be switched parallel to the plane of the layer structure by application of an electric field perpendicular to said plane; and The first optical retarder and / or the second optical retarder have an out-of-plane retardation R th Absolute value of 1 nm to 1000 nm, and / or in-plane retardation R e has an absolute value of 1 to 300 nm, The layer structure is a first polarizer layer (12) as a first polarizer; a first retardation element (14) as a first optical retarder; A first electrode layer (16), A first alignment layer (18), A switchable layer (20), A second alignment layer (22), A second electrode layer (24); a second retardation element (26) as a second optical retarder; and A second polarizer layer (28) as the second polarizer in this order, the first retardation element (14) and / or the second retardation element (26) are layer structures including an optically isotropic substrate and a retardation layer (32, 38); the switchable window (10) comprises at least one further substrate (44) and at least one intermediate layer (42), the at least one further substrate (44) being connected to the first polarizer layer (12) and / or the second polarizer layer (28) by the at least one intermediate layer (42); the switchable window member is curved along two directions; the switchable window member has a dark state and a light state, and switching between the states is accomplished by applying an electric field to the switchable layer; in the dark state, the transmittance of visible light through the switchable window member is less than 2%; The first alignment layer (18) and / or the second alignment layer (22) are homeotropic alignment layers. The switchable window member (10).

2. The switchable window member (10) according to claim 1, wherein the optically isotropic substrate is selected from glass or from a polymer.

3. The switchable window member (10) according to claim 1 or 2, wherein the switchable layer (20) has a thickness d of 1 to 35 μm.

4. The switchable window member (10) of claim 1, wherein the homeotropic alignment layer is a polyimide-based layer.

5. 5. Use of a switchable window element (10) according to any one of claims 1 to 4 as a sunroof in a vehicle, said switchable window element (10) being configured to be normally darkened.

6. 5. Use of a switchable window element (10) according to any one of claims 1 to 4 as a windscreen or window in a vehicle or as a window in an architectural structure, said use being such that the switchable window element (10) is configured to be normally bright.

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