Barrier Coatings for Paper and Paperboard

Abstract

The present invention relates to an aqueous barrier coating composition comprising 50 to 99.9 wt. % of one or more anionic low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12, and 0.1 to 10 wt. % of a polycationic polymer, based on the total dry weight of the aqueous barrier coating composition.

Description

[Technical Field]

[0001] The present disclosure relates to coating compositions for coating fibrous substrates, such as paper or paperboard, to improve their barrier properties, particularly oxygen and grease barrier properties. The present disclosure further relates to fibrous substrates coated with such coating compositions. [Background technology]

[0002] The packaging industry requires effective gas, aroma, and / or moisture barriers to shield sensitive products. Oxygen-sensitive products, in particular, require oxygen barriers to extend their shelf life. Oxygen-sensitive products include many foods, as well as pharmaceuticals and electronics. Known packaging materials with oxygen barrier properties may be composed of one or more polymeric films or fiber-based substrates, such as paper or board, coated with one or more layers of oxygen-barrier polymers, usually as part of a multilayer coating structure.

[0003] Another important property in food packaging is resistance to grease and oil.

[0004] Barriers are typically created by coating a textile substrate with a composition that provides the substrate barrier properties. Different coatings can be applied depending on the barrier properties required. The most commonly used materials for creating barriers on textile substrates are polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), ethylene vinyl alcohol (EVOH), or ethylene vinyl acetate (EVA). EVOH is typically used to create an oxygen barrier, while PE or PET is typically used to create a liquid and / or vapor barrier. Polymers are typically laminated or extrusion coated onto the textile substrate. However, the polymer layer that provides the product barrier properties typically needs to be relatively thick, making such barriers very expensive to produce.

[0005] The most common way to address the reduction of oxygen transmission (OTR) through paper or paperboard is to use multiple polymer layers. In this way, one layer can provide low OTR, while other layers can provide water repellency and / or low water vapor transmission rate.

[0006] Another commonly used barrier material is aluminum. Aluminum layers are typically used to improve the oxygen and light barrier of paper or paperboard products. The aluminum layer is thin, typically around 7-9 μm. Aluminum provides excellent barrier properties, but significantly increases the carbon dioxide load of the product.

[0007] Additionally, both the polymer layer and the aluminum layer reduce biodegradability and the ability to efficiently recycle the packaging material.

[0008] There is a demand from manufacturers, converters and end users to avoid the use of synthetic polymers and aluminum layers in paper or paperboard products in order to reduce the carbon footprint and improve the biodegradability and recyclability of the products.

[0009] Therefore, there is a need for improved methods for providing improved barrier properties to fibrous substrates such as paper or paperboard. Summary of the Invention

[0010] It is an object of the present disclosure to provide a barrier film or coating for fiber-based substrates that alleviates at least some of the problems of prior art barrier films and coatings.

[0011] It is a further object of the present disclosure to provide a barrier film or coating for fiber-based substrates that offers good resistance to oxygen and / or grease.

[0012] It is a further object of the present disclosure to provide a barrier film or coating that can be efficiently applied to fiber-based substrates using conventional coating methods.

[0013] Natural polymers from plants are biodegradable, renewable, and recyclable, making them an attractive source of raw materials for barrier films in packaging materials. Hemicellulose is a polysaccharide biosynthesized in most plants and acts as a matrix material between cellulose microfibrils and as a link between lignin and cellulose. Hemicellulose has been used commercially as a sweetener, thickener, and emulsifier in foods. Barrier films formed from hemicellulose have previously been shown to provide good oxygen and grease barrier properties. However, the high viscosity of hemicellulose compositions limits the solids content, making it difficult to efficiently manufacture such films.

[0014] According to a first aspect presented herein, based on the total dry weight of the aqueous barrier coating composition, 50 to 99.9 wt. % of one or more anionic low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12; 0.1 to 10% by weight of a polycationic polymer; An aqueous barrier coating composition is provided comprising:

[0015] The present invention is based on the surprising realization that short anionic polysaccharides, e.g., anionic hemicelluloses such as xylan, having a degree of polymerization (DP) in the range of 2 to 12 can form good barrier films when combined with polycationic polymers. Such low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12 have not previously been considered for use in barrier films.

[0016] The inventors have discovered that in addition to providing barrier films and coatings with excellent oxygen and grease barrier properties, the combination of a relatively large amount of low molecular weight polysaccharide with a relatively small amount of polycationic polymer allows for the preparation of aqueous barrier coating compositions having high total solids contents, such as at least 50 wt.%, while maintaining a reasonably low viscosity, which allows the aqueous barrier coating compositions to be efficiently applied to substrates using conventional coating methods. DETAILED DESCRIPTION OF THE INVENTION

[0017] The aqueous barrier coating composition comprises a low molecular weight polysaccharide having a degree of polymerization (DP) ranging from 2 to 12 and a polycationic polymer dissolved or dispersed in an aqueous medium. The aqueous medium may be water or an aqueous solution, or may comprise a mixture of water or an aqueous solution with an organic solvent. In a preferred embodiment, the aqueous medium is aqueous-based, i.e., composed of greater than 50% water by weight. In a more preferred embodiment, the aqueous medium is water.

[0018] The aqueous barrier coating composition may be a dilute or high solids composition, however, high solids compositions are typically preferred.

[0019] An advantage of the coating compositions of the present invention is that they allow for high total solids contents, such as 30% by weight or more, while maintaining a reasonably low viscosity. As used herein, the term "total solids" or "solids" refers to the total fraction of dissolved solids plus suspended and settleable solids in an aqueous solution or suspension.

[0020] The high solids content combined with the low viscosity reduces the transportation costs of the coating composition and allows for the preparation of coatings with high basis weights in a single coating step. The high solids content also reduces the amount of water that must be removed when the film or coating is dried, thereby reducing the drying energy requirements of the coating process. Preferably, the total solids content of the coating composition is at least 10% by weight, more preferably at least 20% or at least 30% by weight, based on the total weight of the coating composition.

[0021] The total solids content of the coating composition is typically 90 wt % or less, preferably 80 wt % or less, and more preferably 70 wt % or less, based on the total weight of the coating composition.

[0022] In some embodiments, the aqueous barrier coating composition has a total solids content in the range of 10 to 90 wt %, preferably in the range of 20 to 80 wt %, and more preferably in the range of 30 to 70 wt %, based on the total weight of the coating composition.

[0023] The total solids content of the aqueous barrier coating composition comprises one or more anionic low molecular weight polysaccharides as its main component, and the total solids content of the aqueous barrier coating composition comprises 50 to 99.9 wt % of the one or more anionic low molecular weight polysaccharides.

[0024] In some embodiments, the aqueous barrier coating composition comprises 75 to 99 wt % of one or more anionic low molecular weight polysaccharides, based on the total dry weight of the aqueous barrier coating composition.

[0025] The number of monosaccharide units in a polysaccharide is called the degree of polymerization (DP). As used herein, the term "low molecular weight polysaccharide" generally refers to short sugar chains composed of 2 to 12 monosaccharide units. In some embodiments, one or more low molecular weight polysaccharides have a DP in the range of 2 to 8, preferably in the range of 2 to 7. This is a very short chain length compared to, for example, cellulose, which is composed of approximately 7,000 to 15,000 glucose molecules. The molecular weight of the low molecular weight polysaccharides used herein can typically be in the range of 250 to 2,000 g / mol, e.g., in the range of 250 to 1,500 g / mol or in the range of 250 to 1,000 g / mol.

[0026] The monosaccharide units can be of the same type (homopolysaccharides) or different (heteropolysaccharides). Low molecular weight polysaccharides can be prepared synthetically, naturally, for example, by chemical or synthetic hydrolysis of longer polysaccharides. Examples of anionic low molecular weight polysaccharides useful in the present invention include, but are not limited to, gellan, dextran, pullulan, cellulose, hemicellulose, hyaluronic acid, alginate, xanthan, zuogran, succinoglucan, and glucomannan.

[0027] The low molecular weight polysaccharides are anionic, meaning that they contain at least one anionic functional group. The anionic functional group is typically a carboxylate / carboxylic acid functional group, although other anionic functional groups are possible. The anionic functional group may be naturally present in the low molecular weight polysaccharide, such as the carboxylate / carboxylic acid functional group in glucuronic acid or galacturonic acid, or may be introduced by chemical modification, such as oxidation or grafting of the low molecular weight polysaccharide.

[0028] In some embodiments, the one or more low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12 are selected from the group consisting of anionic hemicellulose, anionic cellulose, and anionic starch, or combinations thereof.

[0029] In some embodiments, the one or more low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12 are anionic hemicelluloses.

[0030] Hemicelluloses are substituted / branched polysaccharides ranging from low to high molecular weight. They consist of different sugar units arranged in different parts and with different substituents.

[0031] Hemicelluloses can be divided into the following main groups: xylan, xyloglucan, glucomannan, and mixed-linkage β-glucan. Some hemicelluloses are naturally negatively charged due to the presence of glucuronic acid and / or galacturonic acid units in the sugar chain. Hemicelluloses for use in aqueous barrier coating compositions are preferably such anionic hemicelluloses. Hemicelluloses are readily hydrolyzed by dilute acid or base as well as various hemicellulase enzymes.

[0032] In some embodiments, the one or more low molecular weight polysaccharides having a degree of polymerization (DP) ranging from 2 to 12 are xylan. Xylan is present in biomass such as wood, grains, grasses, and herbs and is considered to be the second most abundant biopolymer in the plant kingdom. Water and aqueous alkaline extraction can be used to separate xylan from other components in various biomass sources.

[0033] The total solids content of the aqueous barrier coating composition further comprises 0.1 to 10 wt. % polycationic polymer. In some embodiments, the aqueous barrier coating composition comprises 0.5 to 6 wt. % polycationic polymer, based on the total dry weight of the aqueous barrier coating composition.

[0034] Polycationic polymers are synthetic or natural polymers that contain multiple cationic functional groups. Examples of polycationic polymers for use in the present invention include poly(N-methylvinylamine), polyallylamine, polyallyldimethylamine, polydiallylmethylamine, polydiallyldimethylammonium chloride (pDADMAC), polydiallyldimethylammonium trifluoromethanesulfonate (pDADMAT), polydiallyldimethylammonium nitrate (pDADMAN), polydiallyldimethylammonium perchlorate (pDADMAP), polyvinylpyridinium chloride, poly(2-vinylpyridine), poly(4-vinylpyridine), polyvinylimidazole, poly(4-aminomethylstyrene), poly(4-aminostyrene), polyvinyl(acrylamide-co-dimethylaminopropylacrylamide), polyvinyl(acrylamide-co-dimethylaminoethyl methacrylate), polyethyleneimine, polylysine, DAB-Am and PAMAM dendrimers, polyaminoamides, and polyhexamethylene biguanide. , polydimethylamine-epichlorohydrin, aminopropyltriethoxysilane, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, N-trimethoxysilylpropyl-N,N,N-trimethylammonium chloride, bis(trimethoxysilylpropyl)amine, chitosan, cationic starch, cationic gelatin, alkylation products of polyethyleneimine with methyl chloride, alkylation products of polyaminoamides with epichlorohydrin, cationic polyacrylamides with cationic monomers, dimethylaminoethyl acrylate methyl chloride (AETAC), dimethylaminoethyl methacrylate methyl chloride (METAC), acrylamidopropyl trimethylammonium chloride (APTAC), methacrylamidopropyl trimethylammonium chloride (MAPTAC), diallyldimethylammonium chloride (DADMAC), ionene, silanes, and mixtures thereof.

[0035] In some embodiments, the cationic polymer is selected from the group consisting of polyaminoamide, polyethyleneimine, polyvinylamine, polydiallyldimethylammonium chloride (pDADMAC), chitosan, cationic starch, and cationic gelatin.

[0036] In a preferred embodiment, the polycationic polymer is polyethyleneimine (PEI).

[0037] In some embodiments, the polycationic polymer has a weight average molecular weight in the range of 2,000 to 1,000,000 g / mol, preferably in the range of 10,000 to 100,000 g / mol.

[0038] The formulation of aqueous barrier coating compositions can vary widely depending on the intended use of the coating and coated substrate. In some embodiments, the total solids content of the aqueous barrier coating composition consists solely of one or more low molecular weight polysaccharides and polycationic polymers. In other embodiments, the coating composition may further include a wide range of ingredients in varying amounts to improve the final performance of the product or the processing of the coating.

[0039] In some embodiments, plasticizers are added to the aqueous barrier coating composition to increase the elasticity of the resulting film or coating and make it less brittle, allowing the formed film or coating to better withstand bending without losing its barrier properties.

[0040] In some embodiments, the aqueous barrier coating composition comprises 1 to 10 wt % of a plasticizer, based on the total dry weight of the aqueous barrier coating composition.

[0041] In some embodiments, the plasticizer is selected from the group consisting of glycerol, xylitol, sorbitol, maltitol, ethylene glycol, propylene glycol, butanediol, and combinations thereof.

[0042] In some embodiments, fillers are added to the aqueous barrier coating composition to improve the barrier and mechanical properties of the resulting film or coating.

[0043] In some embodiments, the aqueous barrier coating composition further comprises 5 to 40 wt % of a filler, based on the total dry weight of the aqueous barrier coating composition.

[0044] In some embodiments, the filler is selected from the group consisting of clay (such as kaolin or calcined kaolin), talcum, CaCO (such as PCC or GCC), TiO, AlO, SiO, bentonite, fibers, or mixtures thereof. The fibers preferably have a hydrophilic surface and a density close to that of water, i.e., preferably 0.85 to 1.15 g / cm. 3 in the range of 0.90~1.10g / cm 3 The fiber may be any fiber having a density in the range of

[0045] In some embodiments, the filler is selected from the group consisting of clay, talcum, CaCO3, and fiber, or a combination thereof.

[0046] The coating composition is preferably provided in a formulation suitable for application to paper or paperboard using conventional paper coating equipment and techniques, such as blade coaters and bar coaters. Accordingly, the coating composition may contain various additives to impart suitable coating properties. Such coating additives include, but are not limited to, dispersants (e.g., surfactants), lubricants (e.g., stearates), rheology modifiers, insolubilizers, humectants, barrier chemicals, and pH adjusters (e.g., NaOH).

[0047] The aqueous barrier coating composition can be applied to a substrate and dried to form a barrier film or coating. Thus, according to a second aspect presented herein, there is provided a barrier film or coating, the barrier film or coating comprising: Based on the total dry weight of the barrier film or coating, 50 to 99.9 wt. % of one or more anionic low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12; 0.1 to 10% by weight of a polycationic polymer; Includes:

[0048] The barrier film or coating is preferably dry or substantially dry. The barrier film or coating preferably has a total solids content of 90% by weight or greater, preferably 95% by weight or greater.

[0049] It will be understood that the composition of the barrier film or coating according to the second aspect corresponds to the composition of the total solids of the aqueous barrier coating composition according to the first aspect, e.g., a dry content of 50 to 99.9 wt. % of one or more anionic low molecular weight polysaccharides in the aqueous barrier coating composition will result in a content of 50 to 99.9 wt. % of one or more anionic low molecular weight polysaccharides in the dry barrier film or coating.

[0050] The film or coating according to the invention is generally 30 g / m 2 Typically, the grammage is at least 1 g / m to provide acceptable barrier properties. 2 In some embodiments, the basis weight of the film or coating is between 5 and 15 g / m 2 The range is preferably 5 to 10 g / m 2 The range is.

[0051] Films or coatings according to the present invention generally have a thickness of 100 μm or less. In particular, films or coatings can have a thickness of 50 μm or less, and more particularly, films or coatings can have a thickness of 15 μm or less or 10 μm or less. In some embodiments, the thickness of the film or coating is in the range of 1 to 15 μm, preferably in the range of 5 to 10 μm.

[0052] The barrier film or coating is preferably prepared from an aqueous barrier coating composition as described above in relation to the first aspect.

[0053] The barrier films or coatings of the present invention have good oxygen and grease barrier properties.

[0054] In some embodiments, the film or coating has a viscosity of 100 cc / m as measured according to standard ASTM D-3985 at 50% relative humidity and 23°C. 2 / 24h / atm or less, preferably 50cc / m 2 / 24h / atm or less, preferably 10cc / m 2 It has an oxygen transmission rate (OTR) of less than 1000 kJ / 24h / atm.

[0055] In some embodiments, the film or coating has a KIT value of greater than 8, preferably greater than 10, measured according to standard TAPPI T559.

[0056] According to a third aspect presented herein, there is provided a coated substrate comprising a substrate coated with an aqueous barrier coating composition according to the first aspect.

[0057] The aqueous barrier coating composition according to the first aspect is particularly interesting for coating fiber-based substrates. Thus, in some embodiments, the coated substrate is a fiber-based substrate. The fiber-based substrate is preferably paper or paperboard.

[0058] Paper generally refers to a material made in sheets or rolls from wood pulp or other fibrous substances containing cellulose fibers, and is used, for example, for writing, drawing, or printing on the material, or as a packaging material. Paper can be bleached or unbleached, coated or uncoated, and produced in a variety of thicknesses, depending on end-use requirements.

[0059] Paperboard generally refers to a strong, thick paper or cardboard containing cellulose fibers, used, for example, as flat substrates, trays, boxes, and / or other types of packaging. Paperboard can be bleached or unbleached, coated or uncoated, and produced in a variety of thicknesses, depending on end-use requirements.

[0060] The aqueous barrier coating composition can be added either to the paper machine (on-machine coating) or to a separate machine (off-machine coating). A variety of paper coating equipment and techniques can be used to apply the coating composition, such as blade coaters, air knife coaters, and cast coaters. The coating composition can be applied to one or both sides of the paper or paperboard.

[0061] The surface of the paper or paperboard to which the aqueous barrier coating is applied may preferably be pretreated, for example with a dispersion-coated mineral coating, to reduce the porosity of the surface. In this way, the amount of aqueous barrier coating can be reduced. Thus, in some embodiments, the coated substrate is a dispersion-coated, preferably mineral-coated, paper or paperboard.

[0062] The coated substrate is preferably suitable for repulping. In some embodiments, the coated substrate has a repulpability characterized by a rejection rate (determined according to PTS RH 021 / 97 test method) of less than 20%, preferably less than 10%, more preferably less than 5%, and most preferably less than 1%. It has.

[0063] According to a fourth aspect presented herein, a) preparing an aqueous barrier coating composition according to the first aspect; b) forming a wet film or wet coating of the aqueous barrier coating composition; and c) drying the wet film or wet coating to obtain a barrier film or coating.

[0013] A method for producing a barrier film or coating is provided, comprising:

[0064] In some embodiments, the aqueous barrier coating composition has a total solids content in the range of 10 to 90 wt %, preferably in the range of 20 to 80 wt %, and more preferably in the range of 30 to 70 wt %, based on the total weight of the coating composition.

[0065] In the drying step c), the total solids content of the wet film or coating is increased by evaporation of water. The resulting barrier film or coating preferably has a total solids content of more than 90% by weight.

[0066] In some embodiments, the basis weight of the dried barrier film or barrier coating is between 5 and 15 g / m 2 The range is preferably 5 to 10 g / m 2 The range is.

[0067] In some embodiments, the thickness of the dried barrier film or coating is in the range of 5 to 15 μm, preferably in the range of 5 to 10 μm.

[0068] The term coating, as used herein, generally refers to a finishing operation in which the surface of a substrate, for example a fiber-based substrate such as paper or paperboard, is coated with a composition to impart a desired finish or texture to the substrate or to improve its printability or other properties, such as optical or barrier properties. The term barrier coating, as used herein, generally refers to a coating designed to impart improved barrier properties to a substrate.

[0069] The term film as used herein generally refers to a thin continuous sheet-forming material. The term barrier film as used herein generally refers to a film designed to provide good barrier properties.

[0070] Generally, products, polymers, materials, layers, and methods are described in terms of "comprising" various components or steps, but the products, polymers, materials, layers, and methods can also "consist essentially of" or "consist of" various components and steps.

[0071] While the present invention has been described with reference to various exemplary embodiments, those skilled in the art will recognize that various changes can be made and equivalents can be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications can be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is not intended that the invention be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but rather, the invention is intended to include all embodiments falling within the scope of the appended claims. [Example]

[0072] material: Dry xylan powder, DP2-7, 95% purity, 8% moisture content (Coreychem) Glycerol, 87% concentration in water (Merck) Clay, 72% concentration in water (Omya) PEI, 50% concentration by weight in water (Sigma Aldrich)

[0073] Example 1 - Preparation of xylan / water mixture A 20% xylan mixture was prepared by slowly adding 20 g of xylan powder to a stirred vessel containing 80 g of water. The mixture had a very low viscosity of approximately 16 LmPa (Brookfield viscosity of a 19% solution, spindle 2, 21°C).

[0074] 47%, 51%, and 53% xylan mixtures were prepared by gradually adding 47 g, 51 g, and 53 g of xylan powder to stirred vessels containing 53 g, 49 g, and 47 g of water, respectively. The mixtures had a moderate viscosity level of approximately 16 LmPa (Brookfield viscosity at 21 °C for a 39% solution, spindle 2).

[0075] Example 2 - Preparation of Coating Color Xylan-based coating colors with different chemical compositions were prepared at room temperature by mixing xylan and additives (glycerol, clay, and PEI), as shown in Table 1.

[0076] Example 3 - Coating of Paperboard The coating colors were applied to the surface of a paperboard substrate (Tambrite 200 gsm, print coating) using a laboratory rod coater equipped with IR drying. All samples were coated twice with a grooved rod (red). Samples were conditioned at 23°C and 50% RH for several days before analysis.

[0077] analysis The samples were tested for pinhole development, grease resistance (KIT) and oxygen permeability (oxygen transmission rate, OTR) as follows. Oxygen transfer rate (OTR) was measured according to ASTM D3985 at a temperature of 23°C and 50% relative humidity (RH). The pinhole count is measured according to EN 13676:2001. The measurement involves treating the packaging material with a colouring solution (e.g. dye E131 blue in ethanol) and examining the surface under a microscope. The KIT value is a measure of grease resistance and is measured according to TAPPI T559.

[0078] The results of the analysis are shown in Table 1. TIFF0007731383000001.tif77170

Claims

1. 1. An aqueous barrier coating composition comprising: based on the total dry weight of the aqueous barrier coating composition, 50 to 99.9% by weight of one or more anionic low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12; 0.1 to 10% by weight of a polycationic polymer; 1. An aqueous barrier coating composition comprising:

2. 10. The aqueous barrier coating composition of claim 1 comprising 75 to 99 wt. % of the one or more anionic low molecular weight polysaccharides, based on the total dry weight of the aqueous barrier coating composition.

3. 3. The aqueous barrier coating composition of claim 1, wherein the one or more low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12 are selected from the group consisting of anionic hemicellulose, anionic cellulose and anionic starch, or combinations thereof.

4. 4. The aqueous barrier coating composition of claim 1, wherein the one or more low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12 are anionic hemicelluloses.

5. 5. The aqueous barrier coating composition of any one of claims 1 to 4, wherein the one or more low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12 is xylan.

6. 6. The aqueous barrier coating composition of any one of claims 1 to 5, wherein the one or more low molecular weight polysaccharides have a DP in the range of 2 to 8.

7. 7. The aqueous barrier coating composition of any one of claims 1 to 6, comprising 0.5 to 6 wt. % of said polycationic polymer, based on the total dry weight of the aqueous barrier coating composition.

8. 8. The aqueous barrier coating composition of claim 7, wherein the polycationic polymer is polyethyleneimine (PEI).

9. 9. The aqueous barrier coating composition of claim 7 or 8, wherein the polycationic polymer has a weight average molecular weight in the range of 2,000 to 1,000,000 g / mol.

10. 10. The aqueous barrier coating composition of any one of claims 1 to 9, further comprising 1 to 10 wt% of a plasticizer, based on the total dry weight of the aqueous barrier coating composition.

11. 11. The aqueous barrier coating composition of claim 10, wherein the plasticizer is selected from the group consisting of glycerol, xylitol, sorbitol, maltitol, ethylene glycol, propylene glycol, butanediol, and combinations thereof.

12. 12. The aqueous barrier coating composition of any one of claims 1 to 11, further comprising 5 to 40 wt. % of a filler, based on the total dry weight of the aqueous barrier coating composition.

13. The filler is clay, CaCO ３ 13. The aqueous barrier coating composition of claim 12, wherein the polymer is selected from the group consisting of:

14. A barrier film or coating comprising: Based on the total dry weight of the barrier film or barrier coating, 50 to 99.9% by weight of one or more anionic low molecular weight polysaccharides having a degree of polymerization (DP) in the range of 2 to 12; 0.1 to 10% by weight of a polycationic polymer; A barrier film or coating comprising:

15. The basis weight of the film or coating is 5 to 15 g / m ２ 15. The barrier film or coating of claim 14, wherein the viscosity of the barrier film or coating is in the range of

16. A coated substrate comprising a substrate coated with the aqueous barrier coating composition of any one of claims 1 to 13.

17. 17. The coated substrate of claim 16, wherein the coated substrate is a fiber-based substrate.

18. 18. The coated substrate of claim 16 or 17, having repulpability characterized by a rejection rate (determined according to PTS RH 021 / 97 test method) of less than 20%.

19. 1. A method for producing a barrier film or coating, comprising: a) preparing an aqueous barrier coating composition according to any one of claims 1 to 13, b) forming a wet film or coating of the aqueous barrier coating composition; and c) drying the wet film or coating to obtain a barrier film or coating. A method comprising:

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