Device and method for radially zoned catalytic coatings

Abstract

The present disclosure relates to devices and methods for coating various portions of a catalyst support, such as a radially zoned catalyst support, such as those used in catalytic converters for treating the exhaust gas stream of an internal combustion engine.

Description

[Technical Field]

[0001] FIELD OF THE DISCLOSURE The present disclosure relates to devices and methods for coating catalyst supports, such as radially zoned catalyst supports used to treat exhaust gas streams from internal combustion engines, such as diesel engines.

[0002] Generally, techniques for introducing catalytic material into a monolithic catalyst support involve introducing a first open end of the support into a slurry and drawing the slurry through the channels of the catalyst support. However, because one of the open ends of the support inevitably comes into contact with the slurry, a portion of the exterior surface of the support becomes wetted or coated with the slurry.

[0003] Typically, the catalytic material contains precious metals that do not undergo catalytic reactions because the outer surface of the catalyst support does not come into contact with exhaust gases during operation due to the canning surrounding the catalyst support. Therefore, not all of the catalytic material is used in an efficient manner. To restore unused catalytic material, the outer surface of the support is washed, brushed, or sprayed. In this way, some of the material can be restored and the outer surface can be provided in a clean manner, which is important, for example, when canning involves welding. However, at the same time, the manufacture of such catalyst supports is relatively expensive due to the additional cleaning and restoration steps. In addition, it is not possible to restore all of the unused material on the outside of the support.

[0004] Accordingly, the present disclosure provides devices and methods for coating a catalyst support having an exterior surface that is free of catalytic material.

[0005] In one aspect, a method for coating a catalyst support is provided, comprising: (a) providing a catalyst slurry through a pan, the pan including a reservoir configured to receive the slurry, a sealing cover configured to receive the catalyst support, and a plurality of spring-loaded rods configured to couple the cover to the pan; (b) introducing the catalyst support into the sealing cover; (c) introducing an open input end of the catalyst support into the catalyst slurry; (d) directing a quantity of catalyst slurry through the input end and toward an interior portion of the catalyst support; (e) removing the catalyst support from the catalyst slurry; (f) rotating the catalyst support relative to the pan; and (g) directing the catalyst slurry within the catalyst support toward the open output end of the catalyst support.

[0006] In another aspect, a method of coating a catalyst support is provided, comprising: (a) providing a catalyst slurry through a slurry pan; (b) coupling a sealing cover to the slurry pan via a plurality of spring-loaded rods, the sealing cover configured to receive and seal at least a portion of the catalyst support; (c) introducing the catalyst support into the sealing cover; (d) introducing an open input end of the catalyst support into the catalyst slurry; (e) directing a quantity of catalyst slurry through the input end and toward an interior portion of the catalyst support; (f) removing the catalyst support from the catalyst slurry; (g) rotating the catalyst support relative to the pan; and (h) directing the catalyst slurry within the catalyst support toward the open removal end of the catalyst support.

[0007] In another aspect, a method for coating a catalyst support is provided, the method including the steps of: (a) coupling a sealing cover to a clamping mechanism configured to interface with the catalyst support, the sealing cover configured to receive and seal at least a portion of the catalyst support and including a spring-loaded rod configured to interface with a plurality of slurry pans; (b) introducing the catalyst support into the sealing cover; (c) introducing an open input end of the catalyst support into catalyst slurry in a slurry pan; (d) directing a quantity of catalyst slurry through the input end toward an interior portion of the catalyst support; (e) removing the catalyst support from the catalyst slurry; (f) rotating the catalyst support relative to the pan; and (g) directing the catalyst slurry in the catalyst support toward the open removal end of the catalyst support.

[0008] In some embodiments of the foregoing aspect, the catalyst support can be rotated about 180 degrees relative to the pan, e.g., 180 degrees + / - 30 degrees, + / - 15 degrees, + / - 5 degrees, or essentially + / - 0 degrees. In some embodiments, the cover includes an impermeable sealing surface configured to seal against at least one of the face or circumferential edge of the input end of the catalyst support to prevent contact between the outer surface of the catalyst support and the catalyst slurry. The cover can also be configured to prevent axial flow of the slurry through a radial portion of the face and / or through an outer ring region of the face. The orientation of the cover can be adjustable relative to the pan.

[0009] In some embodiments, introducing the catalyst support into the cover includes transporting the catalyst support through a clamping mechanism configured to press the catalyst support against the cover to create a seal therebetween. In some embodiments, introducing the open input end of the catalyst support into the catalyst slurry includes compressing a spring-loaded rod to provide a sealing force against the catalyst support. In some embodiments, directing a quantity of catalyst slurry through the input end includes applying a pressure differential between the input end of the catalyst support and the output end of the catalyst support. In some embodiments, removing the catalyst support from the catalyst slurry includes separating the catalyst support from the cover. In some embodiments, rotating the catalyst support is performed via a clamping mechanism secured to the catalyst support via a rotating mechanism. In some embodiments, directing the catalyst slurry in the catalyst support toward the open output end of the catalyst support includes directing a flow of air toward the open input end of the catalyst support.

[0010] In some embodiments, the method further includes introducing the catalyst support into a second sealing cover configured to seal a different portion of the catalyst support, introducing either the open outlet end or the open inlet end of the catalyst support into a second catalyst slurry, directing a quantity of the second catalyst slurry toward a second interior portion of the catalyst support, removing the catalyst support from the second catalyst slurry, rotating the catalyst support relative to the pan, and directing the catalyst slurry within the catalyst support toward the open end of the catalyst support. In some embodiments, the second catalyst slurry can be provided in the same pan as the first catalyst slurry. In some embodiments, the second catalyst slurry can be provided in a second pan.

[0011] In another aspect, a device is provided for enabling radial coating of a catalyst support at a coating station comprising a slurry pan and a clamping mechanism. In some embodiments, the device comprises a sealing cover configured to releasably hold the catalyst support and seal against a face or periphery of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry. In some embodiments, the device comprises a plurality of spring-loaded rods configured to couple the sealing cover to the slurry pan. In some embodiments, the coating station is a conventional coating station.

[0012] In another aspect, a device is provided for enabling radial coating of a catalyst support at a coating station comprising a slurry pan and a clamping mechanism. In some embodiments, the device comprises a sealing cover configured to seal against a face or periphery of an input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry. In some embodiments, the device comprises a plurality of spring-loaded rods configured to interface with the slurry pan, and the sealing cover is configured to couple to a clamping mechanism configured to releasably hold the catalyst support. In some embodiments, the coating station is a conventional coating station.

[0013] In some embodiments of the foregoing aspects, the sealing cover can be configured to prevent axial flow of the slurry through a radial portion of the face of the catalyst support and / or to prevent axial flow of the catalyst slurry through an outer ring region of the face. In some embodiments, the device can also include a rotation mechanism coupled to the clamping mechanism and configured to rotate the catalyst support by about 180 degrees, e.g., 180 degrees + / - 30 degrees, + / - 15 degrees, + / - 5 degrees, or essentially + / - 0 degrees. In some embodiments, the device includes an actuator coupled to the rotation mechanism and configured to drive rotation of the catalyst support.

[0014] In another aspect, a coating station for applying a catalyst to at least a portion of an inner surface area of ​​a catalyst support is provided. In some embodiments, the station includes a platform having a slurry pan in which a catalyst slurry can be positioned, a clamping mechanism configured to releasably grasp the catalyst support and provide relative movement thereto with respect to the slurry pan, a sealing cover configured to seal against a face or periphery of an input end of the catalyst support to prevent contact between the outer surface of the catalyst support and the catalyst slurry, and a plurality of spring-loaded rods configured to interface with the slurry pan.

[0015] In some embodiments, the sealing cover is further configured to prevent contact with a portion of the face of the catalyst support and any axial passages extending therefrom. In some embodiments, the sealing cover can also be configured to be releasably coupled to the clamping mechanism. In some embodiments, the coating station includes a second sealing cover also configured to be releasably coupled to the clamping mechanism, the sealing cover being interchangeable to provide different sealing configurations for the face of the catalyst support. In some embodiments, multiple spring-loaded rods can be configured to couple the sealing cover to the slurry pan. In some embodiments, the clamping mechanism can be further configured to provide vertical movement to the catalyst support to immerse the open end of the catalyst support in and remove it from the slurry pan.

[0016] In some embodiments, the coating station includes a rotation mechanism coupled to the clamping mechanism and configured to rotate the catalyst support by about 180 degrees, e.g., 180 degrees + / - 30 degrees, + / - 15 degrees, + / - 5 degrees, or essentially + / - 0 degrees. In some embodiments, the coating station includes an actuator coupled to the rotation mechanism and configured to drive the rotation of the catalyst support. In some embodiments, the coating station includes a movable hood configured to sealingly contact one or more of the upper open end of the catalyst support, the upper surface of the clamping mechanism, and the upper surface of the platform to apply pressure to a volume enclosed by the hood. In some embodiments, the coating station includes a second platform having a second slurry pan in which a second catalyst slurry can be positioned, and a second sealing cover configured to seal against different portions of a face of the input end of the catalyst support to prevent contact between the second catalyst slurry and both the exterior surface and different portions of the face of the catalyst support and any axial passages extending therefrom.

[0017] To provide an understanding of embodiments of the present disclosure, reference is made to the accompanying drawings, in which reference numerals designate components of exemplary embodiments of the disclosure. The drawings are illustrative only and should not be construed as limiting the present disclosure. The disclosure described herein is illustrated by way of example, and not by way of limitation, in the accompanying figures. For simplicity and clarity of illustration, features shown in the figures have not necessarily been drawn to scale. For example, the dimensions of some features may be exaggerated relative to other features for clarity. Furthermore, where considered appropriate, reference labels have been repeated among the figures to indicate corresponding or similar elements. [Brief explanation of the drawings]

[0018] [Figure 1A] FIG. 1 is a perspective view of a honeycomb-type substrate that may be coated with a device according to one or more embodiments of the present disclosure. [Figure 1B]1B is a partially enlarged cross-sectional view of the substrate of FIG. 1A taken along a plane parallel to the end face of the substrate to show multiple gas flow paths, according to one or more embodiments of the present disclosure. [Figure 2] 1 is a graphical representation of the NO2:NOx ratio of a conventional radially coated diesel oxidation catalyst. [Figure 3] 1 is a schematic representation of an exemplary coating station, according to one or more embodiments of the present disclosure. [Figure 4] 4 illustrates a method of using the coating station of FIG. 3 in accordance with one or more embodiments of the present disclosure. [Figure 5] 1 is a schematic representation of a device for coating a catalyst support during various stages of the process, according to one or more embodiments of the present disclosure. [Figure 6] 1 is a schematic representation of a device for coating a catalyst support during various stages of the process, according to one or more embodiments of the present disclosure. [Figure 7] 1 is a schematic representation of a device for coating a catalyst support during various stages of the process, according to one or more embodiments of the present disclosure. [Figure 8] 1 is a schematic representation of a device for coating a catalyst support during various stages of the process, according to one or more embodiments of the present disclosure. [Figure 9] 1 is a schematic representation of a device for coating a catalyst support during various stages of the process, according to one or more embodiments of the present disclosure. [Figure 10] FIG. 1 is a perspective view of an exemplary coated catalyst support according to one or more embodiments of the present disclosure.

[0019] 1A and 1B illustrate an exemplary substrate 2, i.e., a catalyst support, coated with a catalyst composition described herein. In some embodiments, the catalyst support 2 is a flow-through substrate, such as a flow-through honeycomb monolithic substrate. Typically, a flow-through substrate has fine, parallel gas flow passages extending from the inlet end to the outlet end of the substrate such that the passages are open to fluid flow. The passages, which are essentially linear paths from the fluid inlet to the fluid outlet, are defined by walls on which a catalytic coating is deposited so that gas flowing through the passages contacts the catalytic material. The flow passages of the flow-through substrate can be thin-walled channels that can be of any suitable cross-sectional shape and size, such as trapezoidal, rectangular, square, sinusoidal, hexagonal, elliptical, circular, etc. The flow-through substrate can be ceramic or metallic, as described herein. The flow-through substrate can be, for example, approximately 50 in. 3 ~About 1200in 3 and a cell density (inlet opening) of from about 60 cells per square inch (cpsi) to about 900 cpsi, e.g., from about 200 to about 400 cpsi, and a wall thickness of from about 50 to about 200 microns or about 400 microns. The catalyst composition can be applied to a substrate to form a catalyst article.

[0020] In some embodiments, any suitable substrate for the catalyst article may be used, such as a type having a plurality of fine, substantially parallel gas passages extending along the longitudinal axis of the substrate, e.g., each passage being blocked at one end of the substrate body and an alternate passage being blocked at the opposite end face (a "wall-flow filter"). Flow-through and wall-flow substrates are also taught, for example, in International Application Publication No. 2016 / 070090, the entire contents of which are incorporated herein by reference.

[0021] Such monolithic wall-flow filter substrates may contain up to about 900 or more flow passages (or "cells") per square inch of cross section, although much smaller numbers may be used. For example, the substrate may have about 7 to 600, e.g., about 100 to 400, cells per square inch ("cpsi"). The cells may have a cross section that is rectangular, square, circular, oval, triangular, hexagonal, or other polygonal. Blocked or plugged ends alternate with open passages, with opposite ends being open and blocked, respectively. The wall-flow substrate also includes an inlet end, an outlet end, and porous cell walls configured to allow exhaust gas to diffuse therethrough. The plugged ends prevent gas flow and promote diffusion through the cell walls.

[0022] Wall-flow filter substrates typically have wall thicknesses ranging from about 50 microns to about 2000 microns, such as from about 50 microns to about 450 microns, or from about 150 microns to about 400 microns. Wall-flow filter walls are porous, generally having a wall porosity of at least about 50% or at least about 60% with an average pore size of at least about 5 microns prior to the application of a functional coating. For example, wall-flow filter article substrates in some embodiments will have a porosity of ≥ 50%, ≥ 60%, ≥ 65%, or ≥ 70%. For example, in some embodiments, the wall-flow filter article substrate, prior to application of the catalyst coating, will have a wall porosity of about 50%, about 60%, about 65%, or about 70% to about 75%, about 80%, or about 85%, and an average pore size of about 5 microns, about 10, about 20, about 30, about 40, or about 50 microns to about 60 microns, about 70, about 80, about 90, or about 100 microns. The terms "wall porosity" and "substrate porosity" are synonymous and interchangeable. Porosity is the ratio of the void volume divided by the total volume of the substrate. Pore size may be determined according to the ISO 15901-2 (static volume) procedure for nitrogen pore size analysis. Nitrogen pore size may be determined on a Micromeritics TRISTAR 3000 series instrument. Nitrogen pore size may be determined using the BJH (Barrett-Joyner-Halenda) calculation and a desorption point of 33. Useful wall flow filters have high porosity, allowing for high loading of catalyst composition without excessive back pressure during operation.

[0023] Referring to FIG. 1A , the exemplary catalyst support 2 shown has a cylindrical shape and a cylindrical exterior surface 4; however, other shapes are contemplated and considered within the scope of this disclosure and may be determined to suit a particular application. In some embodiments, the catalyst support can have a cross-sectional shape corresponding to an oval, rectangle, trapezoid, hexagon, or the like. The catalyst support 2 also includes an upstream (or inlet) end face 6 and a corresponding downstream (or outlet) end face 8, which may be identical to end face 6. The catalyst support 2 can have a plurality of fine, parallel gas flow passages 10 formed therein. As seen in the exemplary embodiment of FIG. 1B , the passages 10 are formed by walls 12 and extend through the catalyst support 2 from the upstream end face 6 to the downstream end face 8, and the passages 10 are unobstructed to allow a fluid, e.g., a gas stream, to flow longitudinally through the catalyst support 2 and through the gas flow passages 10. As can be more easily seen in FIG. 1B , the walls 12 can be sized and configured such that the gas flow passages 10 have a substantially regular polygonal shape. As shown in the exemplary embodiment, the catalyst composition can be applied in multiple separate layers, if desired. In the illustrated embodiment, the catalyst composition is comprised of both a separate bottom layer 14 adhered to the wall 12 of the support member and a second separate top layer 16 coated on the bottom layer 14. The present disclosure can be implemented with one or more (e.g., 1, 2, 3, 4, or more) catalyst composition layers and is not limited to the two-layer embodiment illustrated in FIG. 1B. Additional coating configurations are disclosed herein below.

[0024] To produce a catalytic article, a substrate, or catalyst support, as disclosed above, is coated with a catalytic composition. The coating is a "catalytic coating composition" or "catalytic coating." The terms "catalytic composition" and "catalytic coating composition" are synonymous. A catalytic coating can include one or more thin, adherent coating layers disposed on and attached to at least a portion of a substrate. In some embodiments, the catalytic article can include the use of one or more catalytic layers, as well as a combination of one or more catalytic layers. The catalytic material can be present only on the inlet side, only on the outlet side, on both the inlet and outlet sides of the substrate wall, or the wall itself can be composed entirely or partially of catalytic material. The catalytic coating can be on the substrate wall surface and / or within the pores of the substrate wall, i.e., "in" and / or "on" the substrate wall. Thus, the phrase "catalytic coating disposed on a substrate" refers to any surface, e.g., on the wall surface and / or pore surface. The catalyst coating layer may include individual functional components, such as a first catalyst composition and a second catalyst composition, as described in more detail below.

[0025] The catalyst composition may be applied in the form of a washcoat, typically containing a support material having catalytically active species thereon. The catalyst composition may be mixed with water (if in dry form) to form a slurry for coating the catalyst substrate. In addition to the catalyst particles, the slurry may optionally contain alumina as a binder, an associative thickener, and / or a surfactant (including anionic, cationic, nonionic, or amphoteric surfactants). In some embodiments, the pH of the slurry may be adjusted to an acidic pH, e.g., from about 3 to about 5. If present, the alumina binder is typically present in an amount of about 0.02 g / in. 3 ~approx. 0.5g / in 3 The alumina binder can be, for example, boehmite, gamma-alumina, or delta / theta alumina.

[0026] The slurry can be milled to improve particle mixing and the formation of a homogeneous material. Milling can be accomplished in a ball mill, continuous mill, or other similar equipment, and the solids content of the slurry can be, for example, about 20-60% by weight, more specifically, about 30-40% by weight. In some embodiments, the milled slurry is characterized by a D90 particle size of about 10 to about 50 microns (e.g., about 10 to about 20 microns). D90 is defined as the particle size at which about 90% of the particles have a finer particle size. Exemplary coating compositions are disclosed below.

[0027] The slurry can be coated onto the catalytic substrate using washcoat techniques known in the art. As used herein, the term "washcoat" has its conventional meaning in the art of a thin, adherent coating of material applied to a substrate, such as a honeycomb flow-through monolith substrate or a wall-flow filter substrate, that is sufficiently porous to allow the passage of the gas stream to be treated. As used herein, and as described in Heck, Ronald and Farrauto, Robert, Catalytic Air Pollution Control, New York: Wiley-Interscience, 2002, pp. 18-19, a washcoat layer comprises a compositionally distinct layer of material disposed on the surface of a monolithic substrate or an underlying washcoat layer. A substrate can contain one or more washcoat layers, and each washcoat layer can have a unique chemical catalytic function.

[0028] In some embodiments, a substrate is dipped or otherwise coated with the slurry one or more times. The coated substrate is then dried at an elevated temperature (e.g., 100-150°C) for a period of time (e.g., 1-3 hours) and then calcined, for example, by heating at 400-600°C, typically for about 10 minutes to about 3 hours. After drying and calcination, the final washcoat coating layer can be considered essentially free of solvent.

[0029] After calcination, the catalyst loading can be determined through calculation of the difference between the coated and uncoated weights of the substrate. As will be apparent to those skilled in the art, the catalyst loading can be modified by changing the rheology of the slurry. Additionally, the coating / drying / calcining process can be repeated as necessary to build the coating to a desired loading level or thickness.

[0030] The catalyst composition can be applied as a single layer or in multiple layers. A catalyst layer resulting from repeated washcoating of the same catalyst material to increase loading levels is typically considered a single layer of catalyst. In some embodiments, the catalyst composition is applied in multiple layers, each layer having a different composition. In some embodiments, the catalyst composition can be zone coated, meaning that a single substrate can be coated with different catalyst compositions in different regions along the gas outlet flow path, as described below.

[0031] Washcoats may be applied such that the different coating layers are in direct contact with the substrate. Alternatively, one or more "undercoats" may be present such that the catalyst or adsorbent coating layer or at least a portion of the coating layer is not in direct contact with the substrate (rather, it is in contact with the undercoat). One or more "overcoats" may also be present such that at least a portion of the coating layer is not directly exposed to the gas stream or atmosphere (rather, it is in contact with the overcoat).

[0032] Different coating layers may be in direct contact with each other without an "intermediate" overlapping zone. Alternatively, different coating layers may have a "gap" between the two zones and not be in direct contact. In the case of an "undercoat" or "overcoat," the gap between different layers is referred to as an "intermediate layer." An undercoat is a layer "below" a coating layer, an overcoat is a layer "on" a coating layer, and an intermediate layer is a layer "between" two coating layers. Intermediate layers, undercoats, and overcoats may contain one or more functional compositions or may be free of functional compositions.

[0033] A catalytic coating may include two or more thin, adherent layers, i.e., layers that adhere to each other and to the substrate. The entire coating includes individual "coating layers." A catalytic coating may advantageously be "zoned" and include zoned catalytic layers. This may also be described as "laterally zoned." For example, a layer may extend from the inlet end toward the outlet end and extend over about 10%, about 20%, about 30%, about 40%, about 50%, about 60%, about 70%, about 80%, or about 90% of the substrate length. Another layer may extend from the outlet end toward the inlet end, extending over about 10%, about 20%, about 30%, about 40%, about 50%, about 60%, about 70%, about 80%, or about 90% of the substrate length. Different coating layers may be adjacent to each other and not overlay each other. Alternatively, different layers may overlay portions of each other to provide a third "intermediate" zone. The intermediate zone may extend, for example, from about 5% to about 80% of the substrate length, such as about 5%, about 10%, about 20%, about 30%, about 40%, about 50%, about 60%, or about 70% of the substrate length. The different layers may each extend the entire length of the substrate, or each extend a portion of the substrate length, partially or completely overlaying or underlaying each other. Each of the different layers may extend from either the inlet end or the outlet end.

[0034] As used herein, the phrase "radially zoned oxidation zones" refers to applying different catalyst compositions to at least two different regions of a substrate of a catalyst article, resulting in each of the two or more oxidation zones providing a different level of oxidation activity. As described above, a catalyst support can include an inlet side and an outlet side, and a plurality of passages extending from the inlet side to the outlet side. A first region can include a first subset of the plurality of passages, while a second region can include a second subset of the plurality of passages. For example, when viewing a cylindrical catalyst support from the gas inlet side, one region can be an outer ring of the radial surface extending axially from the surface along at least a portion of the length of the body, while a second region can be a circular region inside the radial surface and also extending a portion of the length of the body. Note that embodiments of the present disclosure are not limited to two regions. For example, a catalyst support according to the present disclosure can include three, four, or more regions, each comprising a subset of the plurality of passages of the substrate (see, for example, FIG. 10). However, for ease of discussion, only two areas will be illustrated with reference to the following figures and description of exemplary embodiments.

[0035] In some embodiments, a coating system according to the present disclosure may include a clamping mechanism for holding the catalyst support, a reservoir for containing the catalyst slurry, and a sealing arrangement for preventing contact between the exterior surface of the catalyst support and the slurry. One example of such a system is disclosed in U.S. Patent Publication No. 2012 / 0114853, the entire disclosure of which is incorporated herein by reference.

[0036] FIG. 3 illustrates an exemplary coating station according to one or more embodiments of the present disclosure. The coating station includes a loading platform 320 that holds a catalyst support 310. A sealing element 330 is supported by a sealing holder 332 connected to a lifting mechanism 336. In some embodiments, the sealing holder 332 may be connected to the lifting mechanism 336 via a quick-release fastener. In some embodiments, the lifting mechanism includes an actuator section 336a that includes a spindle rod. The exemplary coating station of FIG. 3 may further include a pan 340 below which a receiving pan 344 may be positioned that can receive residual slurry via an overrun 346.

[0037] In some embodiments, the coating station further comprises a movable hood 350, which can be raised / lowered from and onto the filling platform 320. In some embodiments, the hood is movable and connected to a lifting mechanism 354 that is carried by the support 322. In some embodiments, the coating station comprises a pivoting device 356, which can be connected to the hood 350 via the lifting mechanism 354 for pivoting the hood eccentrically relative to the longitudinal axis of the filling platform 320 and the pan 340.

[0038] The exemplary coating station shown in FIG. 3 includes an additional lifting mechanism for lifting and lowering the pan 340. As shown, in some embodiments, the pan lifting mechanism 348 and the closure element lifting mechanism 336 may be connected to the same support. Thus, in some embodiments, the exemplary coating station of FIG. 3 includes three lifting mechanisms: a first lifting mechanism 336a, 336b for lifting and lowering the closure holder to which the closure element is connected, a second lifting mechanism 348 for lifting and lowering the pan 340, and a third lifting mechanism 354 for lifting and lowering the hood 350. In some embodiments, the first lifting mechanism 336 for moving the closure element and the second lifting mechanism 348 for moving the pan are attached to the same support via individually controllable actuators. In some embodiments, another separate support is used to hold the third lifting mechanism that raises and lowers the hood 350. In some embodiments, the third lifting mechanism 354 is combined with a pivoting device 356 arranged to pivot the hood 350 about an axis of rotation provided eccentrically relative to the longitudinal axes of the vacuum hood, pan, filling platform, and sealing element. In some embodiments, the third lifting mechanism 354 is connected to the support 322.

[0039] In some embodiments, hood 350 includes an opening 350a for applying positive or negative (i.e., vacuum) pressure to the inside of hood 350. In some embodiments, opening 350a is adapted to be connected to a pump (not shown).

[0040] In some embodiments, the lifting mechanism can include guide rods and actuator elements, such as, for example, pneumatic or hydraulic pistons or electromagnetic actuators. In some embodiments, supports for the hood lifting mechanism are connected to supports for the lifting devices relative to the filling platform 322 and the seal holder 336. In some embodiments, electric servo drives can be used to drive the lifting mechanisms, with each lifting mechanism being driven by an associated individual servo drive. In some embodiments, gear mechanisms, such as, for example, worm gear or spindle gear assemblies, can be used to connect the lifting mechanisms to their respective servo drives.

[0041] 4A-4D show an exemplary catalyst support 110 held within a loading platform 120. The exemplary support has a cylindrical shape with two end faces, which are illustrated as horizontal lines in FIGS. 4A-4D. The loading platform 120 holds the support at an exterior surface extending between the ends. In FIGS. 4A-4D, only the contact elements of the loading platform 120 are shown in a symbolic manner. The exemplary embodiment shown in FIGS. 4A-4D further includes a sealing element 130 below the open input end 110a of the catalyst support 110. Additionally, a pan 140 is positioned below the support 110 and the sealing element 130, and a slurry 142 is positioned within the pan 140.

[0042] In the first step of the exemplary embodiment shown in FIG. 4A, the support 110 is held by the filling platform 120 at a distance above the sealing element 130 and above the slurry 142. The sealing element 130 is then lifted to reach the position shown in FIG. 4B. In this position, the sealing element covers the entire periphery of the input end 110a. This can be achieved by lifting the sealing element or the seal holder holding the sealing element. In FIGS. 4A-4D, only the sealing element 130 is shown in a symbolic manner; the other parts of the cover mechanism, including the seal holder, will be described with respect to the exemplary embodiment illustrated in FIGS. 5-9.

[0043] As shown in FIG. 4B, after the peripheral edge of the input end 110a is covered with the sealing element 130, the pan 140 containing the slurry 142 is raised toward the support 110 so that the surface provided by the slurry, as well as the slurry itself, contacts the input end 110a (as well as a portion of the sealing element 130). From FIG. 4C, it can be seen that the outer surface circumferentially surrounding the catalyst support 110 is not in contact with the slurry 142, and in particular, the section above the peripheral edge of the input end 110a is not in contact with the slurry 142. However, at the same time, the entire input end 110a of the support 110 is immersed in the slurry. In a subsequent step shown in FIG. 4D, a vacuum is applied to the open end 110b of the support 110 opposite the input end 110a. The end 110b of the support 110 opposite the input end 110a is open and connected to the open input end 110a via an internal channel of the support 110. A movable hood 150 is lowered onto the catalyst support 110, partially enclosing the support 110 and temporarily enclosing the removal end 110b. The hood 150 contacts the packing platform 120 such that the volume above the removal end 110b is enclosed by the hood 150. The sealed connection between the hood 150 and the packing platform 120 and between the packing platform 120 and the circumferential outer surface of the support 110 allows a vacuum to be applied to the removal end 110b via the hood 150, which is connected to a vacuum pump 152. Due to the pressure balance and connections through the internal channels of the support 110, the slurry 142 is drawn into the support 110 through the open input end 110a. For example, in some embodiments, the slurry 142 is sucked through the internal opening of the ring-shaped sealing element 130 as well as through the entire cross section of the input end 110a of the catalyst support. In this manner, the amount of slurry 142 disposed in the pan 140 is drawn into the support, thereby coating the interior surface (e.g., the interior channels) of the catalyst support 110. However, during this process of directing the amount of slurry 142 into the interior of the catalyst support 110, the slurry is not transferred to the peripheral exterior surface of the support 110 because the sealing element 130 blocks the slurry 142 at the periphery of the input end 110a.In this manner, a quantity of the slurry is directed toward the interior of the catalyst support 110 without contaminating the outer circumferential surface of the catalyst support 110. For example, in some embodiments, even a section of the outer circumferential surface of the support 110 positioned below the surface of the slurry in the pan 140, i.e., the lower section of the catalyst support 110 that is immersed in the slurry, does not contact the slurry because the sealing element 130 provides cover protection for the outer circumferential surface during immersion of the input end 110 a into the slurry.

[0044] In some embodiments, after completing the process of directing a quantity of slurry 142 to support 110, the vacuum provided by pump 152 is terminated, and hood 150 is released by lifting the hood from loading platform 120, similar to the depiction in FIG. 4C. Pan 140 is then lowered, as shown in FIG. 4B. Subsequently, sealing element 130 is removed from the periphery of input end 110a by lowering sealing element 130. From FIGS. 4A-4D, it can be seen that in some embodiments, pan 140 is raised and lowered a distance greater than the distance sealing element 130 is raised and lowered. This ensures that sealing element 130 contacts the slurry only when necessary, i.e., when input end 110a is immersed in slurry 142, as shown in FIG. 4D. Additionally, this ensures that lowering of sealing element 130 does not result in contact between sealing element 130 and slurry 142. If the input end 110a contacts only the slurry and the sealing element 130 is provided to cover the peripheral edge of the input end 110a, the translational movement (lowering and lifting) of the sealing element 130 can be performed overlapping or during the movement (lowering or lifting) of the pan 140.

[0045] In some embodiments, the pan 140 can be fixedly positioned, and the filling platform 120 lowers and raises the support 110, as shown in Figures 4A-4D. In such embodiments, the lifting mechanism of the sealing element 130 can be active or passive.

[0046] For example, in some embodiments, the lifting mechanism that moves the sealing element can be a passive mechanism that includes a spring that urges the sealing element 130 toward the support 110. In some embodiments, the support is lowered toward the pan 140 and contacts the sealing element 130. After contacting the sealing element 130, the peripheral edge of the input end 110a, i.e., the circumferential edge of the input end of the support, remains in contact with the sealing element 130, while the force urging the sealing element toward the support 110 maintains contact between the sealing element 130 and the peripheral edge of the input end 110a. As the lowering process continues, the sealing element 130, along with the input end 110a, is immersed in the slurry 142, while the spring force exerted on the sealing element 130 ensures that the sealing element covers the peripheral edge of the input end of the support during the entire immersion process.

[0047] 5A-5D illustrate an exemplary manufacturing device 400 for radial coating that uses a cover and sealing mechanism (cover assembly) 460 configured to enable radial coating. The exemplary arrangement shown is configured for interior coating of a support 410 (e.g., coating the inner portion of a radial surface, such as a circle, extending axially along the length of the support 410). The exemplary device 400 includes a cover 462 and multiple spring-loaded rods 464 (springs 464a, rods 464b). In some embodiments, two spring-loaded rods 464 are provided, although the number and placement of the rods 464 can be varied to suit a particular application. The cover 462 includes a sealing surface 466 configured to prevent contact between the slurry 442 and portions of the catalyst support 410, such as the outer surface 410c and outer ring 410d of the radial surface of the support 410. The spring-loaded rods 464 are connected to the cover 462 and the slurry pan 440. In some embodiments, the spring-loaded rod 464 is releasably coupled to the pan 440 or an adjacent support structure or platform to interchangeably couple various cover assemblies to the coating station. The spring 464a provides a force to the sealing surface 466 to seal the surface to the support 410.

[0048] FIG. 5A illustrates the exemplary device 400 mounted to a slurry pan 440 on a conventional coating machine (e.g., an MCC4-type coater), although this arrangement can be incorporated into novel coating stations as disclosed herein. As shown, one end of a rod 464b is attached to the slurry pan 440 (e.g., via a threaded engagement or other mechanical fastener), while the other end is attached to a cover 462 with a spring 464a sandwiched therebetween. The rod 464b can be releasably or permanently attached to the cover 462 to suit a particular application. In some embodiments, the rod is slidably coupled to the cover to allow movement therebetween. The illustrated cover 462 has a recessed portion defining a centrally located opening and provides a sealing surface 466 for the support 410. In the exemplary embodiment shown, the recess and sealing surface 466 are configured to seal around the periphery of the support 410 and a portion of its face 410a. However, the exact size and shape of the cover, recess, and sealing surface will vary to suit the particular application (eg, the substrate, cross-sectional shape of the portion of the body to be coated).

[0049] In some embodiments, sealing surface 466 comprises a first portion (e.g., an edge section), which may be in the form of a frustum, such as a frustum of a cone or a similar tapered structure, with a wall thickness decreasing along a direction corresponding to the taper of the frustum. In some embodiments, sealing surface 466 further comprises a second portion comprising an outer surface extending along a plane where the frustum arises and corresponding to a portion of the radial surface of the catalyst support. In some embodiments, the first portion is adapted to receive a peripheral edge, i.e., circumferential edge, of the input end of the catalyst support, and the second portion is adapted for attachment to cover 462 and contact with a specific portion of the radial surface of the catalyst support (e.g., its outer ring).

[0050] 5B illustrates a catalyst support 410 being transported to the device via a holding clamp (or other type of loading platform) 470, inserted into a cover assembly 460, and in contact with a sealing surface 466. In some embodiments, the clamp / platform 470 is capable of movement in three dimensions (x, y, z) to allow the support 410 to be introduced into a coating station, the body to be lowered and raised relative to the slurry, and the body to be removed to another station. In some embodiments, the loading platform 470 includes a hood 450 that can be configured to seal one end of the support 410 and allow the application of a pressure differential across the support 410. In some embodiments, the hood 450 can be a separate component that contacts the platform 470, the support 410, and / or the cover assembly 460.

[0051] 5C illustrates the catalyst support 410 being pushed down via movement of the hood 450, compressing the body 410 against the sealing surface 466 of the cover assembly 460. Alternatively, in some embodiments, the slurry pan 440 can be raised to contact the slurry with the body 410, or a combination of both. The physical covering and sealing from pressure between the catalyst support 410 and the sealing surface 466 prevents any contact between the slurry 442 and a designated portion of the catalyst support 410 (e.g., the exterior surface 410c). Once sealed, the slurry 442 can be filled into the desired portion of the catalyst support 410, for example, by application of a vacuum 453 to the hood 450 and, in turn, to the interior region of the support 410.

[0052] FIG. 5D illustrates that the slurry-containing catalyst support 410 is flipped approximately 180° and then transferred to another coating station where excess slurry 442 can be extruded into another pan 480. As shown, the inlet face 410a is now positioned at the top, while the outlet face 410b is now positioned at the bottom. In some embodiments, positive pressure 455 (e.g., blowing air) can then be applied to the hood to extrude the slurry 452 along the catalyst support 410. In some embodiments, a radial coating having a given zone length or total length can be achieved by controlling various coating parameters, such as the composition of the catalyst slurry and / or the configuration of the sealing surface 466. Generally, if the sealing surface 466 is inadvertently contaminated with slurry 452, this will only affect the first millimeter or so of the total channel length, thus having little effect on catalytic function. This represents a small amount of material affecting overall catalytic function.

[0053] In the exemplary embodiment shown, the clamp or loading platform 470 includes a rotation mechanism 472, such as an electric motor or pneumatically controlled actuator, along with the necessary couplings, bearings, gears, etc., to rotate the support 410 approximately 180 degrees. In some embodiments, the hood is removed prior to rotation and then reattached to allow for the introduction of the air blast 453. In some embodiments, the coating stations described herein may be provided in accordance with or in combination with the processing stations described in U.S. Pat. No. 9,186,662, the entire disclosure of which is incorporated herein by reference. In some embodiments, the loading platform 470 is supported by a rotation or pivot mechanism 472 for inverting the support (and, optionally, the loading platform). In some embodiments, this mechanism 472 can be synchronized with a separate pivot mechanism for pivoting the hood 450. In this way, the hood can follow the pivoting movement when the support is inverted and the hood is not fully released from the support. Examples of such mechanisms are described in U.S. Pat. No. 9,186,662.

[0054] 6A-6D illustrate an exemplary device 500 according to one or more embodiments of the present disclosure, in which a cover assembly 560 is configured to allow an outer ring of a radial surface of a catalyst support to be coated (i.e., an exterior coating). Generally, the use of the exemplary device 500 in FIGS. 6A-6C is similar to the use of the exemplary device 400 described with respect to FIGS. 5A-5D. As can be seen in FIG. 6A, the cover 462 has a different configuration, with a portion of the sealing surface 566 positioned where the centrally located opening in FIG. 5A was located, and another portion of the sealing surface 466 positioned at the outer boundary of the recess 568 to engage the support 510.

[0055] As can be seen, the clamp / platform 570 introduces the support 510 into the cover assembly 560 (FIG. 6B), extruding the body 510 against the sealing surface 566 and into the slurry 542, where it may be filled (FIG. 6C). The support 510 may then be flipped 180 degrees and transported to another coating station, where excess slurry may be collected (FIG. 6D). In some embodiments, the exemplary devices 400, 500 may be interchangeably coupled to the same pan 442 (with either the same or different slurry compositions) to coat different radial zones of the support 410, 510.

[0056] 7A-7D illustrate another exemplary device 600 according to one or more embodiments of the present disclosure. In this exemplary embodiment, the cover assembly has been reconfigured so that the cover 662 comprises two parts: a base 662a for attachment to the slurry pan 642, and a spring-loaded and slidably engaged carrier 662b that provides a sealing surface 666. A rod 664b couples the cover 662 to the pan 642, while a spring 664a is positioned around the carrier portion of the cover 662b and provides a sealing force to the support 610 when introduced into the device 600. While the cover 662 shown is for an internal coating process, the cover 662 can be reconfigured to allow for an external coating process. The remaining operation is substantially similar to that described above.

[0057] 8A-8D (interior coating) and 9A-9D (exterior coating) illustrate other exemplary embodiments of devices 400, 500 in which cover assemblies 760, 860 are configured for attachment to loading platforms 770, 870 opposite slurry pans 740, 840. Generally, the use of devices 700, 800 is similar to the use of the other devices described above.

[0058] 8A-8D, cover assembly 760 is coupled to loading platform 770 via spring-loaded rod 764, which may be threadably engaged with platform 770, for example. In some embodiments, slurry pan 740 may include a clearance hole disposed in its upper surface for alignment with rod 764b. In some embodiments, spring 764a may be coupled to the rod or platform to maintain the integrity of spring-loaded rod assembly 764.

[0059] 9A-9D, cover assembly 860 is similar to that described with respect to FIGS. 7A-7D and is coupled to loading platform 870 via rod 864b. In some embodiments, cover base 862a is slidably coupled to rod 864b, which is fixedly coupled to platform 870, and cover carrier 862b is slidably coupled to cover base 862a as described with respect to FIGS. 7A-7D.

[0060] The materials selected for the different components of exemplary devices 400, 500, 600, 700, and 800 will vary to suit particular applications. For example, in some embodiments, the cover may be made from stainless steel, aluminum, or other slurry-compatible material, either metallic or polymeric. In some embodiments, the seal may be made from rubber or other slurry-compatible elastomeric material. In some embodiments, the seal or sealing surface may be bonded to the cover via adhesive, mechanical fasteners, or an interference fit or similar engagement.

[0061] According to one or more embodiments of the present disclosure, the catalyst support may be composed of any material typically used to prepare automotive catalysts, and may comprise, for example, a metal or ceramic honeycomb structure. The substrate typically provides a plurality of wall surfaces to which the washcoat composition is applied and adheres, thereby serving as a substrate for the catalyst composition.

[0062] The ceramic catalyst support may be made from any suitable refractory material, such as cordierite, cordierite-alpha-alumina, aluminum titanate, silicon titanate, silicon carbide, silicon nitride, zircon-mullite, spodumene, alumina-silica-magnesia, zircon silicate, sillimanite, magnesium silicate, zircon, petalite, alpha-alumina, aluminosilicates, and the like.

[0063] Metal catalyst supports can be made from one or more metals or metal alloys. Metal catalyst supports can include any metal substrate, such as those with openings or "punches" in the channel walls. Examples of metal substrate materials include heat-resistant, base-metal alloys, such as those in which iron is a substantial or major component. Such alloys can contain one or more of nickel, chromium, and aluminum, the total of which metals can comprise at least about 15% by weight (weight percent), in each case based on the weight of the substrate, of the alloy, such as about 10 to about 25% by weight chromium, about 1 to about 8% by weight aluminum, and 0 to about 20% by weight nickel. Examples of metal catalyst supports include those with straight channels, those with protruding blades along the axial channels to disrupt gas flow and open gas flow communication between channels, and those with holes to improve gas transport between channels, allowing radial gas transport throughout the blades and monolith. Metal catalyst supports are advantageously used in certain embodiments, for example, in close-coupled locations, to allow for rapid heating of the body and, correspondingly, rapid heating of the catalyst composition coated therein.

[0064] In describing the amount of washcoat or catalytic metal component or other component of the composition, it is convenient to use units of component weight per unit volume of catalytic substrate. Thus, the units grams per cubic inch ("g / in") are used. 3 "), and grams per cubic foot ("g / ft 3") is used herein to mean the weight of a component per volume of substrate, including the volume of voids in the substrate. Other units of weight per volume, such as g / L, may also be used. In some embodiments, the total loading of the catalyst composition (including catalytic metal and support material) on a catalytic substrate, such as a monolithic flow-through substrate, is from about 0.5 to about 6 g / in 3 , for example, about 1 to about 5 g / in 3 In some embodiments, the total loading of the PGM or base metal component, not including the support material, ranges from about 0.5 to about 200 g / ft 3 (For example, about 10 to about 100 g / ft 3 ) These weights per unit volume are typically calculated by weighing the catalytic substrate before and after treatment with the catalytic washcoat composition, and it is noted that because the treatment process involves drying and calcining the catalytic substrate at high temperatures, these weights represent an essentially solvent-free catalytic coating, since essentially all of the water in the washcoat slurry has been removed.

[0065] The catalyst and / or sorbent compositions described herein may include one or more supports or "carriers," such as high melting point inorganic solid oxide porous powders that contain functionally active species.

[0066] The catalyst and / or adsorbent compositions may be prepared using a binder, such as a ZrO binder derived from a suitable precursor, such as zirconyl acetate, or any other suitable zirconium precursor, such as zirconyl nitrate. For example, when the catalyst is exposed to high temperatures, such as at least about 600°C, e.g., about 800°C or higher, and a high water vapor environment of about 5% or higher, the zirconyl acetate binder provides a coating that remains uniform and intact after thermal aging. Other suitable binders include, but are not limited to, alumina and silica. Alumina binders include aluminum oxide, aluminum hydroxide, and aluminum oxyhydroxide. Aluminum salts and colloidal forms of alumina may also be used. Silica binders include various forms of SiO, including silicates and colloidal silica. The binder composition may include any combination of zirconia, alumina, and silica. Other exemplary binders include boehmite, gamma-alumina, or delta / theta alumina, and silica sol. When present, binders are typically used in amounts of about 1-5 wt. % of the total washcoat loading. Alternatively, the binder may be zirconia- or silica-based, such as zirconium acetate, zirconia sol, or silica sol. When present, alumina binders are typically used in amounts of about 0.05 g / in 3 ~Approx. 1g / in 3 is used in amounts of

[0067] In some embodiments, the catalyst articles described herein include at least a first oxidation catalyst composition and a second oxidation catalyst composition. Generally, the oxidation catalyst composition (also referred to herein as a "diesel oxidation catalyst (DOC) composition") includes a platinum group metal (PGM) component dispersed on a support, such as a refractory metal support. The oxidation catalyst composition is useful in treating diesel engine exhaust to convert both hydrocarbon (HC) and carbon monoxide (CO) gaseous pollutants to carbon dioxide and water by catalyzing the oxidation of these pollutants.

[0068] In some embodiments, the oxidation catalyst composition includes a catalytically active PGM component and a metal selected from alkali metals, alkaline earth metals, and combinations thereof. The PGM component useful in the disclosed DOC compositions includes any component that includes a PGM. In some embodiments, the PGM component includes one or more platinum group metals selected from platinum, palladium, ruthenium, rhodium, osmium, iridium, gold, and combinations thereof (i.e., Pt, Pd, Ru, Rh, Os, Ir, Au, and combinations thereof). In some embodiments, the PGM may be in a zero-valence metallic form, or the PGM may be in an oxide form. The PGM component may include one or more PGMs in any valence state. Thus, terms such as "platinum (Pt) component," "rhodium (Rh) component," "palladium (Pd) component," "iridium (Ir) component," "ruthenium (Ru) component," and the like refer to the respective platinum group metal compounds, complexes, and the like that decompose or otherwise convert to a catalytically active form, such as a metal or metal oxide, upon calcination or use of the catalyst. In some embodiments, the PGM component is a metal or oxide thereof (e.g., but not limited to, platinum or an oxide thereof).

[0069] In some embodiments, the oxidation catalyst composition comprises the PGM component in an amount ranging from about 0.1 wt. % (weight percent), about 0.5 wt. %, about 1.0 wt. %, about 1.5 wt. %, or about 2 wt. % to about 3 wt. %, about 5 wt. %, about 7 wt. %, about 9 wt. %, about 10 wt. %, about 12 wt. %, about 15 wt. %, about 16 wt. %, about 17 wt. %, about 18 wt. %, about 19 wt. %, or about 20 wt. %, based on the total weight of the oxidation catalyst composition.

[0070] In some embodiments, the oxidation catalyst composition further comprises a metal component selected from an alkali metal, an alkaline earth metal, and a combination thereof. In some embodiments, the alkali metal may be selected from one or more of lithium, sodium, potassium, rubidium, or cesium. In some embodiments, the alkaline earth metal may be selected from one or more of magnesium, calcium, strontium, or barium. In some embodiments, the alkali metal comprises lithium, sodium, potassium, rubidium, cesium, or a combination thereof. In some embodiments, the alkali metal is sodium. In some embodiments, the alkali metal is lithium. In some embodiments, the alkali metal is potassium. In some embodiments, the alkali metal is rubidium. In some embodiments, the alkali metal is cesium. In some embodiments, the alkali metal is sodium in combination with at least one of lithium, potassium, rubidium, or cesium.

[0071] In some embodiments, the alkaline earth metal comprises magnesium, calcium, strontium, barium, or a combination thereof. In some embodiments, the alkaline earth metal is magnesium. In some embodiments, the alkaline earth metal is calcium. In some embodiments, the alkaline earth metal is strontium. In some embodiments, the alkaline earth metal is barium.

[0072] In some embodiments, the oxidation catalyst composition comprises a metal component selected from alkali metals, alkaline earth metals, and combinations thereof in an amount of from about 0.1 wt %, about 0.3 wt %, about 0.5 wt %, or about 1.0 wt %, to about 1.5 wt %, about 2.0 wt %, about 2.5 wt %, about 3.0 wt %, about 3.5 wt %, or about 4.0 wt %, based on the total weight of the oxidation catalyst composition.

[0073] In some embodiments, the oxidation catalyst composition may optionally further comprise one or more additional catalytically active metals selected from copper, iron, chromium, manganese, cobalt, nickel, and combinations thereof. In some embodiments, the additional catalytically active metal is manganese.

[0074] In some embodiments, the PGM components of the oxidation catalyst composition are supported on a support material. The PGM components can be supported, for example, on refractory metal oxides and / or molecular sieves.

[0075] In some embodiments, the support material on which the catalytically active PGM components are supported comprises a refractory metal oxide that exhibits chemical and physical stability at elevated temperatures, such as those associated with gasoline or diesel engine exhaust. Exemplary refractory metal oxides include alumina, silica, zirconia, titania, ceria, praseodymium, tin oxide, and the like, as well as physical mixtures or chemical combinations thereof, e.g., atomically doped combinations, and high surface area or active compounds, such as, for example, activated alumina.

[0076] High surface area refractory metal oxides that may be suitable for use in supporting the PGM components include alumina, titania, zirconia; mixtures of alumina with one or more of titania, zirconia, and ceria; ceria coated on alumina or titania coated on alumina. The refractory metal oxide may contain an oxide or mixed oxide, such as silica-alumina, aluminosilicates that may be amorphous or crystalline, alumina-zirconia, alumina-chromia, alumina-ceria, etc. In some embodiments, the refractory metal oxide is selected from gamma alumina, silica-alumina, ceria coated on alumina, titania coated on alumina, zirconia coated on alumina, and combinations thereof. Included are metal oxide combinations such as silica-alumina, ceria-zirconia, praseodymia-ceria, alumina-zirconia, alumina-ceria-zirconia, lanthana-alumina, lanthana-zirconia-alumina, baria-alumina, baria-lanthana-alumina, baria-lanthana-neodymia-alumina, and alumina-ceria. Exemplary aluminas include large pore boehmite, gamma-alumina, and delta / theta alumina. Useful commercially available aluminas used as starting materials in typical processes include activated aluminas such as high bulk density gamma-alumina, low or medium bulk density large pore gamma-alumina, and low bulk density large pore boehmite.

[0077] High surface area metal oxide supports, such as alumina support materials also known as "gamma alumina" or "activated alumina," are typically 60 m 2 / g, often up to about 200m 2 Exemplary refractory metal oxides exhibit a BET surface area of ​​about 50 to about 300 m / g or greater. 2Activated aluminas include high surface area gamma-aluminas having a specific surface area of ​​about 60 to about 350 m / g. Such activated aluminas are typically mixtures of gamma and delta phases of alumina, but may also contain significant amounts of eta, kappa, and theta alumina phases. "BET surface area" has its usual meaning, referring to the Brunauer-Emmett-Teller method for determining surface area by N2 adsorption measurements. Unless otherwise specified, "surface area" refers to BET surface area. In some embodiments, activated aluminas have a specific surface area of ​​about 60 to about 350 m 2 / g, for example, about 90 to about 250 m 2 / g.

[0078] In some embodiments, the refractory metal oxide support useful in the oxidation catalyst compositions disclosed herein is a doped alumina material such as a Si-doped alumina material (including, but not limited to, 1-10 wt. % SiO-doped AlO), a doped titania material such as a Si-doped titania material (including, but not limited to, 1-10 wt. % SiO-doped TiO), or a doped zirconia material such as a Si-doped ZrO (including, but not limited to, 5-30 wt. % SiO-doped ZrO). For example, in some embodiments, the metal oxide support is 1 wt. % SiO-doped AlO or 8-14 wt. % SiO-doped TiO.

[0079] In some embodiments, the refractory metal oxide support may be doped with one or more additional basic metal oxide materials, such as lanthanum, barium, praseodymium, neodymium, samarium, strontium, calcium, magnesium, niobium, hafnium, gadolinium, terbium, dysprosium, erbium, ytterbium, tin, zinc, or combinations thereof. In some embodiments, the metal oxide dopant may be selected from lanthanum oxide, barium oxide, strontium oxide, calcium oxide, magnesium oxide, and combinations thereof. In some embodiments, the metal oxide dopant is present in an amount of about 1 to about 20 wt. % based on the total weight of the oxidation catalyst composition. Without wishing to be bound by theory, the dopant oxide material may help improve the high-temperature stability of the refractory metal oxide support or may function as an adsorbent for acid gases such as NO, SO, and / or SO.

[0080] The dopant metal oxide can be introduced, for example, using incipient wetness impregnation techniques or through the use of colloidal mixed oxide particles. In some embodiments, the dopant metal oxide is selected from colloidal barrier-alumina, barrier-zirconia, barrier-titania, zirconia-alumina, barrier-zirconia-alumina, lanthana-zirconia, mixtures thereof, and the like. In some embodiments, the refractory metal oxide or refractory mixed metal oxide in the oxidation catalyst composition is selected from alumina, zirconia, silica, titania, ceria, and mixtures thereof, such as bulk ceria, manganese oxide, zirconia-alumina, ceria-zirconia, ceria-alumina, lanthana-alumina, barrier-alumina, silica, silica-alumina, and combinations thereof. These refractory metal oxides can be further doped with base metal oxides, such as barrier-alumina, barrier-zirconia, barrier-titania, zirconia-alumina, barrier-zirconia-alumina, lanthana-zirconia, and the like. In some embodiments, the oxidation catalyst composition may include ceria, alumina, and zirconia, or doped compositions thereof.

[0081] The oxidation catalyst composition can include any of the refractory metal oxides listed above in any amount. For example, the refractory metal oxide can be present in the oxidation catalyst composition in an amount ranging from about 15 wt%, about 20 wt%, about 25 wt%, about 30 wt%, or about 35 wt%, to about 50 wt%, about 55 wt%, about 60 wt%, about 65 wt%, or about 70 wt%, based on the total dry weight of the oxidation catalyst composition. The oxidation catalyst composition can include, for example, about 10 to about 99 wt% alumina, about 15 to about 95 wt% alumina, or about 20 to about 85 wt% alumina.

[0082] The PGM components may be dispersed on the refractory metal oxide support, for example, by dispersing a soluble precursor (e.g., palladium nitrate) thereon. Alternatively, the PGM components may be provided in the composition in particulate form, such as in the form of fine particles on the order of 1 to 15 nanometers or less in diameter, as opposed to being dispersed on a support.

[0083] In some embodiments, the oxidation catalyst composition may further include one or more hydrocarbon (HC) storage components for hydrocarbon adsorption. Any known HC storage material can be used, e.g., a porous or microporous material such as a zeolite or zeolite-like material. In some embodiments, the hydrocarbon storage material is a zeolite. The zeolite can be a natural or synthetic zeolite, such as faujasite, chabazite, clinoptilolite, mordenite, silicalite, zeolite X, zeolite Y, ultrastable zeolite Y, ZSM-5 zeolite, offretite, beta zeolite, or mixtures thereof. In some embodiments, the zeolite adsorbent material has a high silica-to-alumina ratio, e.g., a silica-to-alumina molar ratio of at least about 25:1 or at least about 50:1. In some embodiments, the silica-to-alumina molar ratio ranges from about 25:1 to about 1000:1, from about 50:1 to about 500:1, or from about 25:1 to about 300:1. Preferred zeolites include ZSM-5, Y, and beta zeolites. Particularly preferred adsorbents may include beta zeolites of the type disclosed in U.S. Patent No. 6,171,556, which is incorporated herein by reference in its entirety. When present, the zeolite or other HC storage component is typically present in an amount of about 0.05 g / in 3 ~Approx. 1g / in 3 is used in amounts of

[0084] In some embodiments, the catalyst article described herein includes a first oxidation catalyst composition coating at least a portion of each passageway in a first oxidation zone of a substrate. In some embodiments, the first oxidation catalyst composition is configured to provide relatively high oxidation activity. In some embodiments, the first oxidation catalyst composition includes at least one platinum group metal (PGM) component and a first support material on which the at least one PGM component is supported. In some embodiments, the first oxidation catalyst composition includes platinum. In some embodiments, the first oxidation catalyst composition includes platinum and palladium. In some embodiments, the weight ratio of Pt:Pd in ​​the first oxidation catalyst composition ranges from about 1:0 to about 1:1, such as from about 4:1 to about 2:1. In some embodiments, the total amount of PGM in the first oxidation catalyst composition ranges from about 0.5 to about 200 g / ft 3 , for example, about 5 to 150 g / ft 3 , or approximately 10 to 100 g / ft 3 The range is as follows:

[0085] In some embodiments, the catalyst article described herein further includes a second oxidation catalyst composition coating at least a portion of each passage of the second oxidation zone of the substrate. In some embodiments, the second oxidation catalyst composition is configured to provide lower oxidation activity than the first oxidation catalyst composition, such that the second oxidation zone of the substrate provides lower oxidation activity than the first oxidation zone of the substrate. In some embodiments, the second catalyst composition includes at least one platinum group metal (PGM) component and a second support material on which the at least one PGM component is supported. In some embodiments, the second oxidation catalyst composition includes platinum and palladium. In some embodiments, the second oxidation catalyst composition is substantially free of platinum. In some embodiments, the weight ratio of Pt:Pd in ​​the second catalyst composition ranges from about 0:1 to about 4:1, such as from about 0:1 to about 1:1, or from about 0:1 to about 1:4. In some embodiments, the total amount of PGMs in the second oxidation catalyst composition ranges from about 0.5 to about 200 g / ft 3 , for example, about 5 to 150 g / ft 3, or approximately 10 to 60 g / ft 3 In some embodiments, the g / ft 3 The amount of platinum in the first oxidation catalyst composition, as measured by .gtoreq..times ...

[0086] In some embodiments, preparing the oxidation catalyst composition involves impregnating a porous support (e.g., a refractory oxide support material in particulate form, such as particulate alumina) with a PGM or base metal solution. Multiple metal components (e.g., platinum and palladium) can be impregnated simultaneously or separately, and can be impregnated into the same or separate support particles using incipient wetness techniques. The support particles are typically sufficiently dry to absorb substantially all of the solution and form a wet solid. Aqueous solutions of water-soluble compounds or complexes of the metal components, such as palladium or platinum nitrate, tetraamminepalladium or platinum nitrate, tetraamminepalladium or platinum acetate, copper(II) nitrate, manganese(II) nitrate, and cerium ammonium nitrate, are typically utilized. In certain embodiments, colloidal platinum can be used in embodiments of the catalyst compositions described herein. After treating the support particles with the metal solution, the particles are dried, for example, by heat treatment at an elevated temperature (e.g., 100-150°C) for a period of time (e.g., 1-3 hours), followed by calcination to convert the metal components to a more catalytically active form. An exemplary calcination process involves heat treatment in air at a temperature of approximately 400-550°C for 1-3 hours. The above process may be repeated as necessary to achieve the desired level of metal impregnation. The resulting material can be stored as a dry powder or in slurry form.

[0087] FIG. 10 illustrates an exemplary catalyst support 910 coated by the methods described herein. The body 910 includes multiple oxidation regions or zones, which can be any shape or size. In some embodiments, the first oxidation region comprises a circular central region and the second region comprises an annular outer region concentric with the first region, although the regions are not limited to a circular shape or a concentric first central region and an outer annular second region as generally shown in FIG. 10. Additionally, in some embodiments, the body 910 can include front and rear zones, such as a front radial zone 902, a front peripheral zone 904, and an aft zone 906. Furthermore, in some embodiments, a region can have a pie wedge shape or other irregular shape to be accommodated by a cover assembly designed accordingly. The shape or configuration of the subset of passages defining the various regions is also not meant to be limiting. For example, the regions can be configured as chords, semicircles, and other shapes known in the art. The level of oxidation activity in a given region and the number of passages in a first region compared to a second region are factors that affect the overall oxidation activity of the catalyst article.

[0088] In some embodiments, the first region can comprise about 10 to 70, about 30 to 60, or about 25 to 40 percent of the plurality of passages in the substrate. In some embodiments, the second region can comprise about 30 to 90, about 40 to 70, or about 60 to 75 percent of the plurality of passages in the substrate. In some embodiments, the ratio of the number of passages in the first region to the number of passages in the second region can be in the range of about 10:90 to about 90:10, or about 20:80 to about 80:20, or about 30:70 to about 70:30. In some embodiments, the ratio of the surface area of ​​the catalyst support coated with the catalyst composition in the first region to the surface area of ​​the substrate coated with the catalyst composition in the second region can be in the range of about 10:90 to about 90:10, or about 20:80 to about 80:20, or about 30:70 to about 70:30. The ratio of substrates defined by each of the different oxidation regions determines the NO / NO ratio of the gas leaving the catalytic article.x The ratio can be influenced.

[0089] At least a portion of each passage of a subset of passages defining each region can be coated with a catalyst composition. Different catalyst compositions can be used to coat each region of the catalyst support. In some embodiments, the same catalyst composition can be applied as a catalyst coating layer to two or more regions of the catalyst support. In some embodiments, the entire axial length of each passage, i.e., from the inlet end to the outlet end of the catalyst support, can be coated with the catalyst composition. In some embodiments, only a portion of the axial length of each passage can be coated with the catalyst composition. In some embodiments, the axial length of each passage can be zone-coated laterally with two or more catalyst compositions. In some embodiments, one or more regions can be free of a catalyst coating and / or free of a PGM-based catalyst coating.

[0090] In some embodiments of the present disclosure, a first oxidation catalyst composition coats at least a portion of each passage in the first region of the substrate. In some embodiments, the first catalyst composition is a high-oxidation catalyst composition, meaning that exhaust gas contacting the first catalyst composition undergoes a high level of oxidation of hydrocarbons and carbon monoxide present in the inlet gas stream. In some embodiments, the first catalyst composition can be positioned as the only PGM-containing catalyst layer in each passage in a first subset of passages defining the first oxidation region or a zoned portion thereof. In some embodiments, the first catalyst composition can be positioned as an upper, lower, or middle PGM-containing catalyst layer in each passage in a first subset of passages defining the first oxidation region or a zoned portion thereof. The first catalyst composition is positioned such that exhaust gas entering the inlet side of the substrate in the first oxidation region contacts the first catalyst composition.

[0091] In some embodiments, the second oxidation catalyst composition coats at least a portion of each passage in the second region of the substrate. In some embodiments, the second catalyst composition is a lower oxidation catalyst composition in terms of oxidation activity compared to the first oxidation catalyst composition. In some embodiments, the second catalyst composition can be positioned in the second oxidation region as the only PGM-containing catalyst layer in each passage in a second subset of passages defining the second oxidation region or a zoned portion thereof. In some embodiments, the second catalyst composition can be positioned as an upper, lower, or middle PGM-containing catalyst layer in each passage in a second subset of passages defining the second oxidation region or a zoned portion thereof. The second catalyst composition is positioned in the second oxidation region such that exhaust gases entering the inlet side of the substrate contact the second catalyst composition.

[0092] In some embodiments of the present invention, the total weight ratio of Pt:Pd in ​​the first oxidation zone (i.e., the high oxidation zone) ranges from about 1:0 to about 1:1, such as from about 4:1 to about 2:1. The total amount of PGM in the first oxidation zone ranges from about 0.5 to about 200 g / ft 3 , about 5~150g / ft 3 , or approximately 10 to 100 g / ft 3 The total weight ratio of Pt:Pd in ​​the second oxidation zone (i.e., the lower oxidation zone) can be from about 0:1 to about 1:0, or from about 0:1 to about 4:1. The total amount of PGM in the second oxidation zone can be from about 0.5 to about 200 g / ft 3 , about 5~150g / ft 3 , or approximately 10 to 100 g / ft 3 The total weight ratios and amounts are based on the total dry weight of the PGMs in each zone, regardless of whether a single catalyst composition or multiple catalyst compositions are applied to the passages of each zone.

[0093] Figure 2 shows the NO2:NO ratio at the DOC outlet from engine tests of DOCs with and without radially zoned oxidation regions. XFor conventional DOC designs without radial coating (see Engine), the ratio is NO2:NO X The ratio ignites rapidly in the temperature range of 200°C to 300°C and reaches its thermodynamic limit in the temperature range of 300°C to 400°C. For the radially coated design ("HGA2 on Engine") according to some embodiments of the present disclosure, the NO2:NO X The ratio does not have a steep ignition curve, but gradually increases in the temperature range of 200°C to 300°C and stabilizes in the temperature range of 300°C to 400°C.

[0094] In some embodiments, catalytic articles prepared according to the present disclosure can be provided in exhaust gas treatment systems, such as, for example, exhaust gas treatment systems for treating exhaust gas streams from diesel engines. In some embodiments, the exhaust gas treatment systems include selective catalytic reduction (SCR) catalysts (e.g., zeolite-based SCR catalysts), soot filters, ammonia oxidation (AMOx) catalysts, lean NOx catalysts, and the like. X The catalyst may further include one or more additional catalytic articles selected from: a liquid nitrogen trap (LNT); and combinations thereof.

[0095] Example of embodiment: Some embodiments according to the present disclosure include, but are not limited to: Embodiment 1. A method of coating a catalyst support, comprising: providing a catalyst slurry through a pan, the pan comprising: a reservoir configured to receive the slurry; a sealing cover configured to receive the catalyst support; and providing a cover comprising a plurality of spring-loaded rods configured to couple the cover to the pan; Introducing a catalyst support into the sealing cover; introducing the open input end of the catalyst support into the catalyst slurry; directing a quantity of catalyst slurry through an input end onto an interior portion of a catalyst support; removing the catalyst support from the catalyst slurry; rotating the catalyst support relative to the pan; directing the catalyst slurry within the catalyst support toward an open withdrawal end of the catalyst support. Embodiment 2. A method of coating a catalyst support, comprising: providing a catalyst slurry via a slurry pan; coupling a sealing cover to the slurry pan via a plurality of spring-loaded rods, the sealing cover configured to receive and seal at least a portion of the catalyst support; Introducing a catalyst support into the sealing cover; introducing the open input end of the catalyst support into the catalyst slurry; directing a quantity of catalyst slurry through an input end onto an interior portion of a catalyst support; removing the catalyst support from the catalyst slurry; rotating the catalyst support relative to the pan; directing the catalyst slurry within the catalyst support toward an open withdrawal end of the catalyst support. Embodiment 3. A method of coating a catalyst support, comprising: coupling a sealing cover to a clamping mechanism configured to interface with the catalyst support, the sealing cover configured to receive and seal at least a portion of the catalyst support, the sealing cover comprising a plurality of spring-loaded rods configured to interface with a slurry pan; Introducing a catalyst support into the sealing cover; introducing the open input end of the catalyst support into the catalyst slurry in the slurry pan; directing a quantity of catalyst slurry through an input end onto an interior portion of a catalyst support; removing the catalyst support from the catalyst slurry; rotating the catalyst support relative to the pan; directing the catalyst slurry within the catalyst support toward an open withdrawal end of the catalyst support. Embodiment 4. The method of any one of embodiments 1-3, wherein the catalyst support is rotated about 180 degrees relative to the pan. Embodiment 5. The method of any one of embodiments 1-4, wherein the cover includes an impermeable sealing surface configured to seal against at least one of the face or circumferential edge of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry. Embodiment 6. The method of embodiment 5, wherein the cover is further configured to prevent axial flow of the slurry through the radial portion of the face. Embodiment 7. The method of embodiment 6, wherein the cover is configured to prevent axial flow of the catalyst slurry through the outer ring region of the face. Embodiment 8. The method of embodiment 5, wherein the orientation of the cover is adjustable relative to the pan. Embodiment 9. The method of any one of embodiments 1-8, wherein the step of introducing the catalyst support into the cover comprises transporting the catalyst support through a clamping mechanism configured to press the catalyst support against the cover to create a seal therebetween. Embodiment 10. The method of any one of embodiments 1-9, wherein the step of introducing the open input end of the catalyst support into the catalyst slurry comprises compressing a spring-loaded rod to provide a sealing force against the catalyst support. Embodiment 11. The method of any one of embodiments 1-10, wherein the step of directing a quantity of catalyst slurry through the input end comprises applying a pressure differential between the input end of the catalyst support and the output end of the catalyst support. Embodiment 12. The method of any one of embodiments 1-11, wherein the step of removing the catalyst support from the catalyst slurry comprises separating the catalyst support from the cover. Embodiment 13. The method of any one of embodiments 1 to 12, wherein the step of rotating the catalyst support is performed via a clamping mechanism fixed to the catalyst support via the rotating mechanism. Embodiment 14. The method of any one of embodiments 1-13, wherein the step of directing the catalyst slurry within the catalyst support toward the open discharge end of the catalyst support comprises directing a stream of air toward the open input end. Embodiment 15. introducing the catalyst support into a second sealing cover configured to seal a different portion of the catalyst support; introducing either the open withdrawal end or the open input end of the catalyst support into a second catalyst slurry; directing a quantity of a second catalyst slurry to a second interior portion of the catalyst support; removing the catalyst support from the second catalyst slurry; rotating the catalyst support relative to the pan; 15. The method of any one of embodiments 1-14, further comprising: directing the catalyst slurry within the catalyst support toward an open end of the catalyst support. Embodiment 16. A device for enabling radial coating of a catalyst support at a coating station comprising a slurry pan and a clamping mechanism, comprising: a sealing cover configured to releasably retain the catalyst support and seal against a face or periphery of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry; a plurality of spring-loaded rods configured to couple the sealing cover to the slurry pan. Embodiment 17. A device for enabling radial coating of a catalyst support at a coating station comprising a slurry pan and a clamping mechanism, comprising: a sealing cover configured to seal against a face or periphery of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry; a plurality of spring-loaded rods configured to interface with a slurry pan, wherein the sealing cover is configured to couple to a clamping mechanism configured to releasably hold a catalyst support. Embodiment 18. The device of embodiment 16 or 17, wherein the sealing cover is configured to prevent axial flow of the slurry through the radial portion of the face of the catalyst support. Embodiment 19. The device of embodiment 18, wherein the sealing cover is configured to prevent axial flow of the catalyst slurry through the outer ring region of the face. Embodiment 20. The device of embodiment 16 or 17, further comprising a rotation mechanism coupled to the clamping mechanism and configured to rotate the catalyst support 180 degrees. Embodiment 21. The device of embodiment 20, further comprising an actuator coupled to the rotation mechanism and configured to drive rotation of the catalyst support. Embodiment 22. A coating station for applying a catalyst composition to at least a portion of the interior surface area of ​​a catalyst support, comprising: a platform comprising a slurry pan in which a catalyst slurry can be placed; a clamping mechanism configured to releasably grasp the catalyst support and provide relative movement thereto with respect to the slurry pan; a sealing cover configured to seal against a face or periphery of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry; a plurality of spring-loaded rods configured to interface with the slurry pan. Embodiment 23. The coating station of embodiment 22, wherein the sealing cover is further configured to prevent contact with a portion of the surface and the axial passage extending therefrom. Embodiment 24. A coating station as described in embodiment 22, wherein the sealing cover is configured to be releasably coupled to the clamping mechanism. Embodiment 25. The coating station of embodiment 22, further comprising a second sealing cover also configured to be releasably coupled to the clamping mechanism, the sealing cover being interchangeable to provide different sealing configurations for the surface of the catalyst support. Embodiment 26. The coating station of embodiment 22, wherein a plurality of spring-loaded rods are configured to couple the sealing cover to the slurry pan. Embodiment 27. The coating station of embodiment 22, wherein the clamping mechanism is further configured to provide vertical movement to the catalyst support to immerse the open end of the catalyst support in and remove it from the slurry pan. Embodiment 28. The coating station of embodiment 22, further comprising a rotation mechanism coupled to the clamping mechanism and configured to rotate the catalyst support 180 degrees. Embodiment 29. The coating station of embodiment 28, further comprising an actuator coupled to the rotation mechanism and configured to drive rotation of the catalyst support. Embodiment 30. The coating station of embodiment 22, further comprising a movable hood configured to sealingly contact at least one of the top open end of the catalyst support, the top surface of the clamping mechanism, or the top surface of the platform to apply pressure to a volume enclosed by the hood. Embodiment 31. a second platform comprising a second slurry pan in which a second catalyst slurry may be positioned; 23. The coating station of embodiment 22, further comprising: a second sealing cover configured to seal against a different portion of the face of the input end of the catalyst support to prevent contact between the second catalyst slurry and both the different portions of the exterior surface and face of the catalyst support and any axial passages extending therefrom. Embodiment 32. A device according to embodiment 16 or 17, wherein the coating station is a conventional coating station.

[0096] While several exemplary embodiments of the present invention have been described herein, it should be apparent to those skilled in the art that the foregoing are merely illustrative and not limiting, and have been presented by way of example only. Numerous modifications and other embodiments are within the purview of those skilled in the art and are contemplated to be within the scope of this disclosure. In particular, while many of the examples presented herein involve specific combinations of method acts or system elements, it should be understood that those acts and those elements may be combined in other ways to achieve the same purpose.

[0097] Furthermore, those skilled in the art should understand that the parameters and configurations described herein are exemplary, and that the actual parameters and / or configurations will depend on the particular application in which the inventive systems and techniques are used. Those skilled in the art will also recognize, or be able to ascertain using no more than routine experimentation, equivalents to the specific embodiments of the invention. Accordingly, it is to be understood that the embodiments described herein are presented by way of example only and that within the scope of the appended claims and their equivalents, the invention may be practiced otherwise than as specifically described.

[0098] The phraseology and terminology used herein are for purposes of description and should not be considered limiting. As used herein, the term "plurality" refers to two or more items or components. The terms "comprising," "including," "carrying," "having," "containing," and "involving," whether in the written description or claims, are open-ended terms, i.e., mean "including but not limited to." Thus, the use of such terms is meant to encompass the items listed thereafter, and equivalents thereof, as well as additional items. With respect to the claims, only the transitional phrases "consisting of" and "consisting essentially of" are closed or semi-closed transitional phrases, respectively. The use of ordinal terms such as "first," "second," and "third" in the claims to modify claim elements does not, by itself, imply a priority, precedence, or order of a claim element relative to another order in which method actions are performed, or a temporal order, but is used solely as a label to distinguish one claim element having a particular name from another element having the same name (but using ordinal terms) to distinguish between claim elements.

Claims

1. 1. A method for coating a catalyst support, comprising: providing a catalyst slurry through a pan, said pan comprising: a reservoir configured to receive the slurry; a sealing cover configured to receive the catalyst support; and providing a plurality of spring-loaded rods configured to couple the cover to the pan; introducing the catalyst support into the sealing cover; introducing the open input end of the catalyst support into the catalyst slurry; directing a quantity of the catalyst slurry through the input end onto an interior portion of the catalyst support; removing the catalyst support from the catalyst slurry; rotating the catalyst support relative to the pan; directing the catalyst slurry within the catalyst support toward an open discharge end of the catalyst support; and The method of claim 1, wherein the cover includes an impermeable sealing surface configured to seal a first sealing area and a second sealing area, different from the first sealing area, against at least one of a face or a circumferential edge of the input end of the catalyst support to prevent contact between the outer surface of the catalyst support and the catalyst slurry.

2. The method of claim 1 , wherein the catalyst support is rotated approximately 180 degrees relative to the pan.

3. The method of claim 1, wherein the cover includes an impermeable sealing surface configured to seal a second sealing region, the second sealing region including an annular ring, a wedge, or an irregular shape to facilitate coating of specific areas within the catalyst support.

4. 4. The method of claim 3, wherein the cover is further configured to prevent axial flow of the slurry through a radial portion of the face, or the cover is further configured to prevent axial flow of the catalyst slurry through an outer ring region of the face.

5. 10. The method of claim 1, wherein the step of introducing the catalyst support into the cover comprises transporting the catalyst support through a clamping mechanism configured to press the catalyst support against the cover to create a seal therebetween.

6. 10. The method of claim 1, wherein the step of introducing the open input end of the catalyst support into the catalyst slurry comprises compressing the spring-loaded rod to provide a sealing force against the catalyst support.

7. 10. The method of claim 1, wherein directing a quantity of the catalyst slurry through the input end comprises applying a pressure differential between the input end of the catalyst support and the withdrawal end of the catalyst support.

8. The method of claim 1 , wherein removing the catalyst support from the catalyst slurry comprises separating the catalyst support from the cover.

9. The method of claim 1 , wherein the step of rotating the catalyst support is performed via a clamping mechanism secured to the catalyst support via a rotating mechanism.

10. 10. The method of claim 1, wherein the step of directing the catalyst slurry within the catalyst support toward an open withdrawal end of the catalyst support comprises directing a flow of air toward the open input end.

11. introducing the catalyst support into a second sealing cover configured to seal a different portion of the catalyst support; introducing either the open withdrawal end or the open input end of the catalyst support into a second catalyst slurry; directing a quantity of the second catalyst slurry to a second interior portion of the catalyst support; removing the catalyst support from the second catalyst slurry; rotating the catalyst support relative to the pan; 10. The method of claim 1, further comprising: directing the catalyst slurry within the catalyst support toward the open withdrawal end or the open input end of the catalyst support.

12. 1. A device for enabling radial coating of a catalyst support at a coating station comprising a slurry pan and a clamping mechanism, comprising: a sealing cover configured to releasably retain the catalyst support and seal against a face or periphery of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and a catalyst slurry; a plurality of spring-loaded rods configured to couple the sealing cover to the slurry pan.

13. 13. The device of claim 12, wherein the sealing cover is configured to prevent axial flow of the slurry through a radial portion of the face of the catalyst support, or the sealing cover is configured to prevent axial flow of the catalyst slurry through an outer ring region of the face.

14. 13. The device of claim 12, further comprising a rotation mechanism coupled to the clamping mechanism and configured to rotate the catalyst support 180 degrees, and further comprising an actuator coupled to the rotation mechanism and configured to drive rotation of the catalyst support.

15. a coating station for applying a catalyst composition to at least a portion of the interior surface area of ​​a catalyst support, comprising: a platform comprising a slurry pan in which a catalyst slurry can be placed; a clamping mechanism configured to releasably grasp the catalyst support and provide relative movement thereto with respect to the slurry pan; a sealing cover configured to seal against a face or periphery of the input end of the catalyst support to prevent contact between the exterior surface of the catalyst support and the catalyst slurry; a plurality of spring-loaded rods configured to interface with the slurry pan.

16. 16. The coating station of claim 15, wherein the sealing cover is further configured to prevent contact with a portion of the face and any axial passage extending therefrom, or the sealing cover is configured to be releasably coupled to the clamping mechanism.

17. 16. The coating station of claim 15, further comprising: a second sealing cover also configured to be releasably coupled to the clamping mechanism, wherein the sealing cover is interchangeable to provide different sealing configurations for the face of the catalyst support; or a movable hood configured to sealingly contact at least one of the upper open end of the catalyst support, an upper surface of the clamping mechanism, or an upper surface of the platform to apply pressure to a volume enclosed by the hood; or a second platform comprising a second slurry pan in which a second catalyst slurry may be positioned; or a second sealing cover configured to seal against a different portion of the face of the input end of the catalyst support to prevent contact between the second catalyst slurry and both the exterior surface and portions of the face of the catalyst support and any axial passages extending therefrom.

18. The coating station of claim 15 , wherein the plurality of spring-loaded rods are configured to couple the sealing cover to the slurry pan.

19. 16. The coating station of claim 15, wherein the clamping mechanism is further configured to provide vertical movement to the catalyst support to immerse an open end of the catalyst support in and remove it from the slurry pan.

20. 16. The coating station of claim 15, further comprising: a rotation mechanism coupled to the clamping mechanism and configured to rotate the catalyst support 180 degrees; and an actuator coupled to the rotation mechanism and configured to drive the rotation of the catalyst support.

21. A method for coating a catalyst support, comprising: providing a catalyst slurry through a pan, said pan comprising: a reservoir configured to receive the slurry; a sealing cover configured to receive the catalyst support; and providing a plurality of spring-loaded rods configured to couple the cover to the pan; introducing the catalyst support into the sealing cover; introducing the open input end of the catalyst support into the catalyst slurry; directing a quantity of the catalyst slurry through the input end onto an interior portion of the catalyst support; removing the catalyst support from the catalyst slurry; rotating the catalyst support relative to the pan; directing the catalyst slurry within the catalyst support toward an open withdrawal end of the catalyst support.

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