Gas Analysis Systems

Abstract

A gas analysis system (1) comprises: an inflow unit (C1) into which sample gas flows; columns (41, 42); detection devices (50, 51) for detecting components of the sample gas; a sampler module (M1) and a switching module (M2) including a plurality of valves (V1 to V10); and a control device (100) for independently controlling the plurality of valves (V1 to V10). The control device (100) includes: a storage unit (120) for storing therein function pattern information that defines the correspondence relationship between a plurality of basic functions and opening / closing patterns of the plurality of valves; and an output unit (110) for outputting control signals respectively to the plurality of valves (V1 to V10) using the function pattern information stored in the storage unit (120).

Description

[Technical Field]

[0001] The present disclosure relates to a gas analysis system (gas chromatograph system). [Background technology]

[0002] Gas analysis systems (gas chromatograph systems) are used in a variety of fields, including quality and process control in petrochemical and gas production plants, and fuel cell research. Some conventional gas analysis systems have dedicated flow path configurations for each function to achieve multiple functions with different purposes (sampling, heart-cutting, pre-cutting, column switching, backflush, etc.). For example, the gas analysis system disclosed in Japanese Patent Laid-Open Publication No. 2004-101200 has a flow path configuration that uses a six-way valve and an eight-way valve to achieve the pre-cutting function. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Laid-Open No. 2004-101200 Summary of the Invention [Problem to be solved by the invention]

[0004] In conventional gas analysis systems, the flow path configuration, including valves and piping, differs depending on the required function. Therefore, when changing the function of the analysis system, it is necessary to replace the flow path configuration with one that corresponds to the new function and make adjustments according to the changed function. As a result, there is a problem that changing functions requires a lot of time and cost.

[0005] The present disclosure has been made to solve the above problems, and an object of the present disclosure is to provide a gas analysis system that can achieve multiple functions without replacing the hardware configuration of the flow path. [Means for solving the problem]

[0006] A gas analysis system according to the present disclosure includes a separation unit that separates gas components contained in a sample gas, a detection device that detects the gas components flowing out from the separation unit, a flow path fluidly connected to the separation unit and the detection device, a plurality of valves provided on the flow path and each of which can be controlled independently of one another, and a control device that independently controls the plurality of valves. The plurality of valves are arranged so that the flow path forms a first flow path pattern and a second flow path pattern depending on the control states of the plurality of valves. The control device has a memory unit that stores information regarding the control states of the plurality of valves corresponding to the first flow path pattern and the second flow path pattern, and an output unit that generates signals for controlling each of the plurality of valves using the information stored in the memory unit and outputs the signals to the plurality of valves.

[0007] According to the gas analysis system described above, multiple functions with different purposes can be realized by independently controlling multiple valves, and therefore multiple functions can be realized without replacing the hardware configuration of the flow path. [Effects of the Invention]

[0008] According to the present disclosure, it is possible to provide a gas analysis system that can achieve multiple functions without replacing the hardware configuration of the flow path. [Brief explanation of the drawings]

[0009] [Figure 1] FIG. 1 is a diagram (part 1) schematically illustrating an example of the configuration of a gas analysis system. [Figure 2] FIG. 1 is a cross-sectional view of a microvalve (part 1). [Figure 3] FIG. 2 is a cross-sectional view of a microvalve (part 2). [Figure 4] FIG. 1 is a diagram (part 1) showing the state of the switching valve and the flow of each gas. [Figure 5] FIG. 2 is a diagram (part 2) showing the state of the switching valve and the flow of each gas. [Figure 6]FIG. 3 is a diagram (part 3) showing the state of the switching valve and the flow of each gas. [Figure 7] FIG. 4 is a diagram (part 4) showing the state of the switching valve and the flow of each gas. [Figure 8] FIG. 5 is a diagram (part 5) showing the state of the switching valve and the flow of each gas. [Figure 9] FIG. 6 is a diagram (part 6) showing the state of the switching valve and the flow of each gas. [Figure 10] This is a diagram (part 7) showing the state of the switching valve and the flow of each gas. [Figure 11] This is a diagram (part 8) showing the state of the switching valve and the flow of each gas. [Figure 12] This is a diagram (part 9) showing the state of the switching valve and the flow of each gas. [Figure 13] This is a diagram (part 10) showing the state of the switching valve and the flow of each gas. [Figure 14] FIG. 10 is a diagram showing a list of patterns of the open / closed state of the switching valve. [Figure 15] FIG. 10 is a diagram illustrating an example of a function requested by a user. [Figure 16] FIG. 2 is a diagram (part 2) schematically illustrating an example of the configuration of a gas analysis system. [Figure 17] FIG. 10 is a diagram (part 3) schematically illustrating an example of the configuration of a gas analysis system. DETAILED DESCRIPTION OF THE INVENTION

[0010] The present embodiment will now be described in detail with reference to the drawings, in which the same or corresponding parts in the drawings are designated by the same reference characters and description thereof will not be repeated.

[0011] [Overall system configuration] FIG. 1 is a diagram schematically illustrating an example of the configuration of a gas analysis system 1 according to this embodiment.

[0012] The gas analysis system 1 includes carrier gas supply devices 11 to 13, a sample tank 20, a pump 21, a vent 23, a sampler module M1, a switching module M2, columns 41 to 44, detection devices 50, 51, an input device 60, a display device 70, a drive device 80, and a control device 100.

[0013] Each of the carrier gas supply devices 11 to 13 adjusts the pressure of a mobile phase called a carrier gas to a predetermined value and outputs the adjusted pressure. For example, helium gas is used as the carrier gas. The pressure of the carrier gas is adjusted by an electronic automatic pressure controller (APC) (not shown).

[0014] The sample tank 20 is a device that stores the sample gas to be analyzed. The sample tank 20 is connected to the connector C1 of the sampler module M1. The connector C1 functions as an inlet port through which the sample gas from the sample tank 20 is input. Therefore, hereinafter, the connector C1 will also be referred to as the "inlet port C1." A user can change the sample gas to be analyzed by the gas analysis system 1 by replacing the sample tank 20 connected to the connector C1 of the sampler module M1.

[0015] The pump 21 is a suction pump that sucks air from the flow path of the sampler module M1 to create a negative pressure in the flow path of the sampler module M1. Note that the negative pressure here refers to a pressure lower than atmospheric pressure.

[0016] The vent 23 connects the flow path of the sampler module M1 to the outside, and discharges gas within the flow path of the sampler module M1 to the outside.

[0017] The sampler module M1 and the switching module M2 are provided on a flow path that is fluidly connected to the sample tank 20, the columns 41 to 44, and the detectors 50 and 51. Note that the term "fluid connection" as used herein means that the connection is made by a fluid directly without passing through other components, or indirectly through other components.

[0018] Each of the sampler module M1 and the switching module M2 is formed by mounting a plurality of switching valves on a flow path plate (flow path member) on which a flow path pattern is formed.

[0019] Each of the modules M1 and M2 is provided with a plurality of connectors (interfaces) for connecting external devices. The flow paths formed in each of the modules M1 and M2 are connected to the external devices via these connectors. Specifically, the sampler module M1 is provided with connectors C1 to C6. The sample tank 20, the pump 21, and the vent 23 are connected to the connectors C1 to C3, respectively. The carrier gas supply device 11 and the column 43 are connected to the connector C4. The carrier gas supply device 12 is connected to the connector C5. The column 41 is connected to the connector C6. The switching module M2 is provided with connectors C7 to C10. The columns 41 to 44 are connected to the connectors C7 to C10, respectively.

[0020] The sampler module M1 is a device for supplying a constant amount of sample gas to the column 41. The sampler module M1 includes connectors C1 to C6, a constant-volume sample loop PL, switching valves V1 to V6, and a plurality of flow paths connecting these. As described above, the connectors C1 to C6 of the sampler module M1 are connected to the sample tank 20, pump 21, vent 23, carrier gas supply device 11, carrier gas supply device 12, and column 41, respectively.

[0021] The switching valves V1 and V4 are arranged in this order in the flow path from the connector C1 to the connector C4. The switching valves V3, V5, and V6 are arranged in this order in the flow path from the connector C2 to the connector C5. The switching valve V2 is arranged in the flow path connecting the flow path between the switching valves V5 and V6 and the connector C3.

[0022] The sample loop PL is disposed in a flow path connecting the flow path between the switching valves V1 and V4 and the flow path between the switching valves V3 and V5. The sample loop PL has the function of temporarily holding the sample gas introduced from the sample tank 20 in order to supply it to the column 41. By appropriately switching the connection destination of the sample loop PL under the control of the switching valves V1 to V6, the sampler module M1 temporarily fills the sample loop PL with the sample gas supplied from the sample tank 20, and then supplies the sample gas filled in the sample loop PL to the column 41.

[0023] The switching module M2 includes connectors C7 to C10, switching valves V7 to V10, and a plurality of flow paths connecting these together. As described above, the columns 41 to 44 are connected to the connectors C7 to C10 of the switching module M2, respectively.

[0024] The switching valve V9 is disposed in the flow path between the connector C7 and the connector C8. The switching valve V8 is disposed in the flow path between the connector C9 and the connector C10.

[0025] The switching valve V7 is disposed in a flow path connecting the flow path between the connector C9 and the switching valve V8 and the flow path between the connector C8 and the switching valve V9. The switching valve V10 is disposed in a flow path connecting the flow path between the connector C7 and the switching valve V9 and the flow path between the connector C10 and the switching valve V8.

[0026] The switching valves V1 to V10 are switched between an open state and a closed state by a drive unit 80. The drive unit 80 switches the states of the switching valves V1 to V10 in response to a command from the control unit 100. In other words, the states of the switching valves V1 to V10 are controlled by the control unit 100.

[0027] Columns 41 and 42 separate the various components in the supplied sample gas. Specifically, columns 41 and 42 separate and output the various components contained in the supplied sample gas in the time direction while the sample gas passes through each column on the flow of carrier gas. Column 41 is a column for primary separation. Column 42 is a column for secondary separation that further separates the various components of the sample gas that have been primarily separated by column 41. Columns 43 and 44 are resistance tubes for pressure adjustment that are not capable of separating (retaining) the various components of the sample gas.

[0028] The detector 50 is connected to the column 42 and detects various components introduced from the column 42. The detector 51 is connected to the column 44 and detects various components introduced from the column 44. Each of the detectors 50, 51 may be, for example, an absorptiometry detector (a PDA (Photo Diode Array) detector), a fluorescence detector, a differential refractive index detector, a conductivity detector, or a mass spectrometer. Data indicating the detection results by each of the detectors 50, 51 is stored in the memory unit 120 in the control device 100 and displayed on the display device 70 at the user's request.

[0029] The input device 60 is, for example, a keyboard or a pointing device such as a mouse, and receives requests or commands from a user. The requests or commands inputted by the user to the input device 60 are sent to the control device 100.

[0030] The display device 70 is configured by, for example, a liquid crystal display (LCD) panel, and displays information to the user. When a touch panel is used as the user interface, the input device 60 and the display device 70 are integrally formed.

[0031] The control device 100 includes a calculation unit (output unit) 110, a storage unit 120, an input / output interface, etc. The control device 100 comprehensively controls the entire gas analysis system 1, including the carrier gas supply devices 11 to 13, the pump 21, the switching valves V1 to V10 (drive device 80), etc. The control device 100 is connected to an input device 60 and a display device 70, which are user interfaces, by wire or wirelessly.

[0032] The calculation unit (output unit) 110 has a calculation device (Central Processing Unit) and generates control signals for controlling each of the switching valves V1 to V10 using information stored in the memory unit 120, and outputs the generated control signals to the switching valves V1 to V10 (drive device 80) via an output interface.

[0033] [Configuration of switching valves V1 to V10] An example of the configuration of the switching valves V1 to V10 according to this embodiment will be described using Figures 2 and 3. Since the switching valves V1 to V10 have the same basic configuration, the switching valves V1 to V10 will be described as microvalve 200 without distinction in Figures 2 and 3.

[0034] Figure 2 is a cross-sectional view of the microvalve 200 when the microvalve 200 is in an open state. Figure 3 is a cross-sectional view of the microvalve 200 when the microvalve 200 is in a closed state.

[0035] The microvalve 200 has a layered structure including a base layer 220, a diaphragm layer 230, and a cover layer 240, which are layered in this order. Each of the base layer 220, the diaphragm layer 230, and the cover layer 240 is made of, for example, silicon, and is microfabricated using MEMS (Micro Electric Mechanical Systems) technology to achieve the desired strength and flexibility.

[0036] The thickness (dimension in the stacking direction) of the microvalve 200 is approximately 1 to 2 mm. For convenience, in the following description, the direction from the base layer 220 toward the cover layer 240 may be referred to as the upward direction, and the direction from the cover layer 240 toward the base layer 220 may be referred to as the downward direction.

[0037] The base layer 220 is disposed as the bottom layer of the microvalve 200. The base layer 220 has a recess 221 and openings 222 to 224 formed therein. The recess 221 has a substantially circular shape when the base layer 220 is viewed in plan from above, and is formed near the approximate center of the base layer 220. The recess 221 is recessed from the upper surface side to the lower surface side of the base layer 220. The thickness of the base layer 220 is approximately 150 μm. The depth of the recess 221 is 5 to 20 μm, and preferably approximately 10 μm.

[0038] The openings 223 and 224 are formed in the bottom 225 of the recess 221. As will be described later, the openings 223 and 224 form an inlet and an outlet for the sample gas, respectively. The opening 222 is formed on the outer edge of the periphery of the recess 221 of the base layer 220, spaced apart from the recess 221. The opening 222 forms a supply port for a control fluid (pneumatic fluid) for the microvalve 200.

[0039] Diaphragm layer 230 is disposed on the upper surface side of base layer 220, facing base layer 220. Diaphragm layer 230 has an opening 232 penetrating diaphragm layer 230, a rigid portion 234, and a flexible portion 233 provided around rigid portion 234. Flexible portion 233 is thinner than rigid portion 234 and has flexibility. Elastic deformation of flexible portion 233 causes rigid portion 234 to be displaced in the vertical direction.

[0040] The opening 232 is formed at a distance from the flexible portion 233 and the rigid portion 234. When viewed in a plan view from above, the opening 232 is formed at a position overlapping the opening 222 of the base layer 220, and together with the opening 222 forms a supply port for pneumatic fluid.

[0041] The microvalve 200 is connected to a flow path member (flow path plate) 250 when in use. The flow path member 250 has openings 252 to 254 formed at positions corresponding to the openings 222 to 224 of the base layer 220, respectively. The opening 252 of the flow path member 250, the opening 222 of the base layer 220, and the opening 232 of the diaphragm layer 230 are in communication with each other, forming a supply port 262 for pneumatic fluid. The pneumatic fluid is supplied to the recess 241 of the cover layer 240 through the supply port 262.

[0042] An opening 253 of the flow path member 250 communicates with an opening 223 of the base layer 220, forming an inlet 263 for the sample gas. An opening 254 of the flow path member 250 communicates with an opening 224 of the base layer 220, forming an outlet 264 for the sample gas.

[0043] The microvalve 200 is a so-called normally open type valve that is open in the initial state (normal state) when no pneumatic fluid is supplied to the supply port 262 of the flow path member 250, and closes when pneumatic fluid is supplied to the supply port 262 of the flow path member 250.

[0044] When pneumatic fluid is not supplied to the supply port 262 of the flow path member 250, the rigid portion 234 is held away from the bottom 225 of the recess 221 in the base layer 220, as shown in Figure 2, so that the inlet 263 and outlet 264 of the sample gas are in an open state (open state) in which they are connected.

[0045] When pneumatic fluid is supplied to supply port 262 of flow path member 250, rigid portion 234 is pushed by the pneumatic fluid and displaced downward, whereby the lower surface of rigid portion 234 comes into close contact with bottom 225 of recess 221 in base layer 220, thereby blocking inlet 263 and outlet 264 for the sample gas and bringing them into a closed state. Note that instead of driving (displacing) rigid portion 234 with pneumatic fluid, rigid portion 234 may be electrically driven (displaced) using a piezoelectric element or the like.

[0046] [System functions and their operation] The gas analysis system 1 can achieve five basic functions - sampling, pre-cutting, heart-cutting, column switching, and backflush - by combining the open and closed states of the switching valves V1 to V10 without changing the hardware configuration of the sampler module M1 and the switching module M2. Each function of the gas analysis system 1 and its operation are explained below.

[0047] (Feature 1) Sampling function The sampling function is a function for sampling a fixed amount of sample gas. During execution of the sampling function, three patterns are transitioned in this order: sampling pattern P11, pressure balance pattern P12, and injection pattern P13.

[0048] Figure 4 shows the states of the switching valves V1 to V10 and the flow of each gas in sampling pattern P11. In Figure 4, switching valves marked with an x ​​are in the closed state, and switching valves not marked with an x ​​are in the open state. In Figure 4, solid arrows indicate the flow of carrier gas, and diagonal arrows indicate the flow of sample gas (sample). This also applies to the following Figures 5 to 13.

[0049] 4, in sampling pattern P11, switching valves V1, V3, V6, V7, and V10 are open, and the other switching valves V2, V4, V5, V8, and V9 are closed. Furthermore, pump 21 is activated. As a result, sample gas is filled from sample tank 20 into sample loop PL, as indicated by the diagonal arrow.

[0050] In the sampling pattern P11, the carrier gas supply devices 11 and 12 are operated, and the carrier gas supply device 13 is stopped.

[0051] As a result, as shown by the black arrows, carrier gas from carrier gas supply device 11 is supplied to detection device 50 via columns 43 and 42, and carrier gas from carrier gas supply device 12 is supplied to detection device 51 via columns 41 and 44. Thereafter, the operation pattern of gas analysis system 1 is switched from sampling pattern P11 to pressure balance pattern P12.

[0052] 5 shows the states of the switching valves V1 to V10 and the flow of each gas in the pressure balance pattern P12. As shown in FIG. 5, in the pressure balance pattern P12, the switching valves V1, V6, V7, and V10 are open, and the other switching valves V2 to V5, V8, and V9 are closed. In addition, the carrier gas supply devices 11 and 12 are operated, and the carrier gas supply device 13 and the pump 21 are stopped.

[0053] This brings the pressure in the sample loop PL to an equilibrium state where it is stabilized at approximately atmospheric pressure. This allows the amount of sample gas held in the sample loop PL to be stabilized at a constant amount. Thereafter, the operation pattern of the gas analysis system 1 is switched from the pressure equilibrium pattern P12 to the injection pattern P13.

[0054] 6 shows the states of the switching valves V1 to V10 and the flow of each gas in injection pattern P13. As shown in FIG. 6, in injection pattern P13, switching valves V4, V5, V7, and V10 are open, and the other switching valves V1 to V3, V6, V8, and V9 are closed. In addition, carrier gas supply devices 11 and 12 are operated, and carrier gas supply device 13 and pump 21 are stopped.

[0055] As a result, carrier gas from the carrier gas supply device 11 is supplied to the sample loop PL through the switching valve V4, and the sample gas filled in the sample loop PL is pushed out by the carrier gas and supplied to the column 41 through the switching valve V5.

[0056] (Feature 2) Pre-cut function The pre-cut function analyzes only the components that elute early among the components contained in the sample gas supplied to the column 41, and discharges the components that elute later outside the analysis system. The pre-cut function is performed after the sampling function is executed. During the execution of the pre-cut function, three patterns are transitioned in this order: pre-separation pattern P21, secondary separation pattern P22, and pre-cut pattern P23.

[0057] 7 shows the states of the switching valves V1 to V10 and the flow of each gas in the pre-separation pattern P21. As shown in FIG. 7, in the pre-separation pattern P21, the switching valves V3, V6, V7, and V10 are open, and the other switching valves V1, V2, V4, V5, V8, and V9 are closed. In addition, the carrier gas supply devices 11 and 12 are operated, and the carrier gas supply device 13 and the pump 21 are stopped.

[0058] As a result, the target component S1, which elutes early, and the non-target component S2, which elutes later, are separated in the column 41. Thereafter, the operation pattern of the gas analysis system 1 is switched from the pre-separation pattern P21 to the secondary separation pattern P22.

[0059] 8 shows the states of the switching valves V1 to V10 and the flow of each gas in the secondary separation pattern P22. As shown in FIG. 8, in the secondary separation pattern P22, the switching valves V3, V6, V8, and V9 are open, and the other switching valves V1, V2, V4, V5, V7, and V10 are closed. In addition, the carrier gas supply devices 11 and 12 are operated, and the carrier gas supply device 13 and the pump 21 are stopped.

[0060] As a result, the target component S1 is supplied from column 41 through switching valve V9 to column 42, where it is subjected to secondary separation. The target component S1 that has been subjected to secondary separation in column 42 is supplied to detection device 50 and detected by detection device 50. After the target component S1 has been supplied to column 42, the operation pattern of gas analysis system 1 is switched from secondary separation pattern P22 to precut pattern P23.

[0061] 9 shows the states of the switching valves V1 to V10 and the flow of each gas in the pre-cut pattern P23. As shown in FIG. 9, in the pre-cut pattern P23, the switching valves V2, V3, V7, and V10 are open, and the other switching valves V1, V4 to V6, V8, and V9 are closed. In addition, the carrier gas supply devices 11 and 13 are operated, and the carrier gas supply device 12 and the pump 21 are stopped.

[0062] This causes the carrier gas from the carrier gas supply device 13 to flow back through the column 41 through the switching valve V10, and the non-target component S2 remaining in the column 41 is pushed back by the carrier gas and discharged to the outside through the vent 23 through the switching valve V2.

[0063] (Feature 3) Heart-cut function The heart-cut function is a function that separates components that are separated in the primary separation by column 41 from components that cannot be separated in the primary separation, and supplies the components that cannot be separated in the primary separation to column 42 for secondary separation. The heart-cut function is performed after the sampling function is executed. The user can select whether the function performed after the sampling function is executed is the pre-cut function or the heart-cut function. During execution of the heart-cut function, three patterns transition in this order: leading-end component detection pattern P31, secondary separation pattern (heart-cut pattern) P32, and trailing-end component detection pattern P33.

[0064] 10 is a diagram showing the states of the switching valves V1 to V10 and the flow of each gas in the front-end component detection pattern P31. As shown in FIG. 10, in the front-end component detection pattern P31, the switching valves V3, V6, V7, and V10 are open, and the other switching valves V1, V2, V4, V5, V8, and V9 are closed. In addition, the carrier gas supply devices 11 and 12 are operated, and the carrier gas supply device 13 and the pump 21 are stopped.

[0065] As a result, in the column 41, the sample is separated into a front component S10 that elutes early, a cut component S20 that elutes next to the front component S10, and a rear component S30 that elutes later than the cut component S20. The front component S10 and the rear component S30 are components that are separated in the primary separation by the column 41. The cut component S20 is a component that cannot be completely separated in the primary separation.

[0066] The front component S10 is supplied to the detection device 51 through the switching valve V10 and the column 44. As a result, the front component S10 is detected by the detection device 51. After the front component S10 is supplied to the column 42, the operation pattern of the gas analysis system 1 is switched from the front component detection pattern P31 to the secondary separation pattern P32.

[0067] 11 is a diagram showing the states of switching valves V1 to V10 and the flow of each gas in secondary separation pattern P32. As shown in FIG. 11, in secondary separation pattern P32, switching valves V3, V6, V8, and V9 are open, and the other switching valves V1, V2, V4, V5, V7, and V10 are closed. Also, carrier gas supply devices 11 and 12 are operated, and carrier gas supply device 13 and pump 21 are stopped.

[0068] As a result, the cut component S20 is supplied from the column 41 through the switching valve V9 to the column 42, and after secondary separation by the column 42, is supplied to the detection device 50. As a result, the cut component S20 is detected by the detection device 50. After the cut component S20 is supplied to the column 42, the operation pattern of the gas analysis system 1 is switched from the secondary separation pattern P32 to the rear end component detection pattern P33.

[0069] 12 is a diagram showing the states of the switching valves V1 to V10 and the flow of each gas in the rear end component detection pattern P33. As shown in FIG. 12, in the rear end component detection pattern P33, the switching valves V3, V6, V7, and V10 are open, and the other switching valves V1, V2, V4, V5, V8, and V9 are closed. In addition, the carrier gas supply devices 11 and 12 are operated, and the carrier gas supply device 13 and the pump 21 are stopped.

[0070] As a result, the rear end component S30 passes through the switching valve V10 and the column 44 and is supplied to the detection device 51. As a result, the detection device 51 detects the rear end component S30.

[0071] (Feature 4) Column switching function The column switching function switches columns according to the target components during a single analysis. In this function, column 44, which is not capable of retaining the various components of the sample gas, is changed to a column for separation, and the same operation as the heart-cut function described above is performed.

[0072] The column switching function can be realized by simply changing the column connected to the connector C10, without changing the flow path configuration inside the sampler module M1 and the switching module M2.

[0073] (Feature 5) Backflush function The backflush function is a function for causing the carrier gas to flow backward to discharge the remaining components in the column to the outside. During the execution of the backflush function, the operation pattern of the gas analytical system 1 is set to the backflush pattern P4.

[0074] 13 shows the states of the switching valves V1 to V10 and the flow of each gas in the backflush pattern P4. As shown in FIG. 13, in the backflush pattern P4, the switching valves V2, V3, V7, and V10 are open, and the other switching valves V1, V4 to V6, V8, and V9 are closed. In addition, the carrier gas supply devices 11 and 13 are operated, and the carrier gas supply device 12 and the pump 21 are stopped.

[0075] As a result, the carrier gas from the carrier gas supply device 13 flows backward through the column 41, and the remaining components in the column 41 are pushed back by the carrier gas and discharged to the outside from the vent 23 through the switching valve V2.

[0076] [Control for realizing each function] FIG. 14 is a diagram showing a list of open / closed state patterns of the switching valves V1 to V10 in the above-mentioned five basic functions (sampling, pre-cutting, heart-cutting, column switching, and back-flushing).

[0077] The storage unit 120 of the control device 100 stores in advance information (hereinafter also referred to as "function pattern information") that defines the correspondence between each basic function and the open / closed state of the switching valves V1 to V10, as shown in FIG.

[0078] The calculation unit (output unit) 110 of the control device 100 generates control signals for controlling the open / closed states of the switching valves V1 to V10 using the function pattern information stored in the storage unit 120, and outputs the generated control signals to the switching valves V1 to V10 (drive device 80). This makes it possible to achieve the five basic functions without switching the hardware configurations of the sampler module M1 and the switching module M2.

[0079] The user can select a desired function from the five basic functions and specify the duration of the selected function by performing an input operation on the input device 60. The state input by the user to the input device 60 is sent from the input device 60 to the control device 100 as user request information.

[0080] Fig. 15 is a diagram showing an example of user request information. Fig. 15 shows an example in which the user requests execution of the pre-cut function after executing the sampling function. As described above, during execution of the sampling function, three patterns, sampling pattern P11, pressure balance pattern P12, and injection pattern P13, transition in this order. Then, during execution of the pre-cut function, three patterns, pre-separation pattern P21, secondary separation pattern P22, and pre-cut pattern P23, transition in this order. The user can specify the duration of each of these patterns.

[0081] When user request information such as that shown in FIG. 15 is input from the input device 60, the calculation unit 110 plans a control schedule in accordance with the user request information while referring to the function pattern information stored in the memory unit 120, and controls the opening and closing of the switching valves V1 to V10 in accordance with the planned schedule.

[0082] As described above, the gas analysis system 1 according to this embodiment includes columns 41 and 42 that separate gas components contained in a sample gas, detectors 50 and 51 that detect the gas components flowing out of the columns 41 and 42, flow paths (flow paths inside the sampler module M1 and the switching module M2) that fluidly connect the columns 41 and 42 and the detectors 50 and 51, switching valves V1 to V10 that can be controlled independently of each other, and a controller 100 that independently controls the switching valves V1 to V10. The controller 100 includes a memory unit 120 that stores "function pattern information" that defines the correspondence between a plurality of basic functions having different purposes and the opening and closing patterns of the switching valves V1 to V10, and a calculation unit (output unit) 110 that generates signals for controlling the switching valves V1 to V10 using the function pattern information stored in the memory unit 120 and outputs the signals to the switching valves V1 to V10.

[0083] Therefore, in the gas analysis system 1 according to this embodiment, the five basic functions can be realized simply by changing the combination of open / closed states of the switching valves V1 to V10 through control, without having to replace the hardware configuration of the flow paths (the flow paths in the sampler module M1 and the switching module M2).

[0084] Furthermore, in the gas analysis system 1 according to this embodiment, when a user inputs a desired function into the input device 60, the control device 100 identifies a combination of open / closed states of the switching valves V1 to V10 corresponding to the desired function by referring to the "function pattern information," and automatically controls the switching valves V1 to V10 to achieve the identified open / closed states. Therefore, the user can perform an analysis using the desired function simply by inputting the desired function into the input device 60.

[0085] Furthermore, in the gas analysis system 1 according to this embodiment, the switching valves V1 to V10 are driven independently, so the overall flow path configuration can be simplified compared to conventional systems that use rotary valves, and troubleshooting and maintenance in the event of a malfunction can be simplified.

[0086] That is, conventional systems use rotary valves with multiple ports, so when the valve is rotated to switch the flow path, half of the ports switch simultaneously in unison. As a result, the flow path configuration becomes complicated, and troubleshooting and maintenance in the event of a malfunction are difficult. In contrast, in the gas analysis system 1 according to this embodiment, the switching valves V1 to V10 can be controlled independently, allowing for a variety of flow path switching patterns and simplifying the overall flow path configuration. Furthermore, even in the event of a malfunction, the switching valves V1 to V10 can be driven independently to switch between various flow path patterns, allowing the cause of the malfunction to be analyzed. This makes it easy to identify the malfunction location and simplifies troubleshooting and maintenance in the event of a malfunction.

[0087] Furthermore, the switching valves V1 to V10 according to this embodiment are microvalves formed by microfabrication using MEMS technology, and therefore the dead volume inside the flow paths and each valve is extremely small, making it possible to suppress pressure shocks when switching flow paths.

[0088] That is, the rotary valves used in conventional systems have large internal volumes, and the volumes of the piping and connections connecting each port are large, resulting in large dead volumes when switching between flow paths. This makes it easy for pressure shocks to occur when switching between flow paths. Furthermore, sample diffusion is likely to occur in the dead volumes, which can adversely affect the analysis results. In contrast, the switching valves V1 to V10 of this embodiment are microvalves with extremely small dead volumes, which can solve the conventional problems.

[0089] <Variation 1> 16 is a diagram schematically illustrating an example of the configuration of a gas analysis system 1A according to Modification 1. In the gas analysis system 1A, the detection device 51 of the above-described gas analysis system 1 is replaced with a vent 24. The other configuration of the gas analysis system 1A is the same as that of the above-described gas analysis system 1. By modifying it in this way, the components flowing out of the column 44 can be directly discharged from the vent 24 to the outside of the analysis system.

[0090] <Variation 2> 17 is a diagram schematically illustrating an example of the configuration of a gas analysis system 1B according to Modification 2. In gas analysis system 1B, the carrier gas supply device 12 connected to connector C5 of the above-described gas analysis system 1 is eliminated, and instead connector C5 is connected to carrier gas supply device 11. The other configuration of gas analysis system 1B is the same as that of the above-described gas analysis system 1. By modifying in this way, it is possible to eliminate the carrier gas supply device 12, thereby reducing overall costs.

[0091] [Aspect] It will be understood by those skilled in the art that the above-described embodiments and their modifications are specific examples of the following aspects.

[0092] (Item 1) A gas analysis system according to one embodiment includes a separation unit that separates gas components contained in a sample gas, a detection device that detects the gas components flowing out from the separation unit, a flow path fluidly connected to the separation unit and the detection device, a plurality of valves provided on the flow path and each of which can be controlled independently of one another, and a control device that independently controls the plurality of valves. The plurality of valves are arranged so that the flow path forms a first flow path pattern and a second flow path pattern depending on the control states of the plurality of valves. The control device has a memory unit that stores information regarding the control states of the plurality of valves corresponding to the first flow path pattern and the second flow path pattern, and an output unit that generates signals for controlling each of the plurality of valves using the information stored in the memory unit and outputs the signals to the plurality of valves.

[0093] According to the gas analysis system described in paragraph 1, multiple functions with mutually different purposes can be realized by independently controlling multiple valves, and therefore multiple functions can be realized without replacing the hardware configuration of the flow path.

[0094] (Clause 2) The gas analysis system described in clause 1 may further include an input device that accepts requested functions from a user, and the output unit may identify the control states of multiple valves corresponding to the requested functions input to the input device by referring to information stored in the memory unit, and output control signals to the multiple valves so that the identified control states are achieved.

[0095] According to the gas analysis system described in paragraph 2, the requested function can be realized by a simple operation of the user inputting the requested function into the input device.

[0096] (Item 3) In the gas analysis system described in item 1 or 2, the separation section may include a first column for primary separation and a second column for secondary separation that further separates gas components flowing out from the first column. The detection device may include a first detection device connected to the second column and a second detection device not connected to the second column. The flow path may include a sampler module arranged between the inlet section through which the sample gas flows in and the first column, and a switching module arranged between the first column, the second column, and the second detection device.

[0097] According to the gas analysis system described in paragraph 3, the sample gas can be filled into the first column by controlling the valve in the sampler module. Furthermore, by changing the control state of the valve in the switching module, it is possible to switch whether the sample gas flowing out of the first column is supplied to the second column or to the second detection device.

[0098] (Item 4) In the gas analysis system described in item 3, the information stored in the memory unit includes information defining the correspondence between a plurality of functions having mutually different purposes and the control states of a plurality of valves. The plurality of functions may include a sampling function for sampling a fixed amount of sample gas, a first cut function for detecting some components in the sample gas with a first detection device or a second detection device and discharging the remaining components to the outside, a second cut function for detecting some components in the sample gas with the first detection device and the remaining components with the second detection device, and a backflush function for causing gas in the separation unit to flow backward and discharging it to the outside.

[0099] According to the gas analysis system described in paragraph 4, by independently controlling multiple valves, basic functions such as sampling function, first cut function (pre-cut function), second cut function (heart cut function), and backflush function can be realized.

[0100] The embodiments disclosed herein should be considered to be illustrative in all respects and not restrictive. The scope of the present invention is defined by the claims, not by the description of the above embodiments, and is intended to include all modifications within the meaning and scope of the claims. [Explanation of symbols]

[0101] 1, 1A, 1B gas analysis system, 11, 12, 13 carrier gas supply device, 20 sample tank, 21 pump, 23, 24 vent, 41 to 44 column, 50, 51 detection device, 60 input device, 70 display device, 80 drive device, 100 control device, 110 calculation unit, 120 memory unit, 200 microvalve, 220 base layer, 221, 241 recess, 222, 223, 224, 232, 252, 253, 254 opening, 225 bottom, 230 diaphragm layer, 233 flexible part, 234 rigid part, 240 cover layer, 250 flow path member, 262 supply port, 263 inlet, 264 outlet, C1 to C10 connector, M1 sampler module, PL Sample loop, V1~V10 switching valve.

Claims

1. a separation unit that separates gas components contained in the sample gas; a detection device for detecting gas components flowing out from the separation unit; a flow path fluidly connected to the separation unit and the detection device; a plurality of valves provided on the flow path, each of which can be controlled independently of the others; a control device that independently controls the plurality of valves, the plurality of valves are arranged such that the flow paths form a first flow path pattern and a second flow path pattern according to control states of the plurality of valves; The control device a storage unit that stores information regarding control states of the plurality of valves corresponding to the first flow path pattern and the second flow path pattern; an output unit that generates signals for controlling each of the plurality of valves using the information stored in the storage unit and outputs the signals to the plurality of valves, the information stored in the storage unit includes information defining a correspondence between a plurality of functions having mutually different purposes and control states of the plurality of valves; the separation section includes a first column for primary separation and a second column for secondary separation that further separates the gas components flowing out from the first column; The detection device includes: a first detector connected to the second column; a second detection device not connected to the second column; The flow path is a sampler module disposed between an inlet into which a sample gas is introduced and the first column; a switching module disposed between the first column, the second column, and the second detection device; The plurality of valves are a first valve group provided within the sampler module; a second valve group provided within the switching module; The information stored in the memory unit includes information that defines a correspondence between the plurality of functions and the control states of the first valve group and the second valve group.

2. further comprising an input device for receiving a requested function from a user; 2. The gas analysis system according to claim 1, wherein the output unit identifies the control states of the plurality of valves corresponding to the required function input to the input device by referring to information stored in the memory unit, and outputs control signals to the plurality of valves so that the valves are in the identified control states.

3. The plurality of functions include: A sampling function for sampling a fixed amount of sample gas; a first cut function for detecting a part of components in the sample gas by the first detection device or the second detection device and discharging the remaining components to the outside; a second cut function for detecting a part of the components in the sample gas by the first detection device and detecting the remaining components by the second detection device; 2. The gas analysis system according to claim 1, further comprising a backflush function for causing the gas in the separation unit to flow backward and be discharged to the outside.

4. The gas analysis system of claim 1 , wherein the plurality of valves are mounted on a flow path plate.

5. 2. The gas analysis system of claim 1, wherein the plurality of valves are silicon microvalves with a diaphragm layer.

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