Lithium-ion battery

Abstract

To provide a lithium ion battery with excellent recyclability.SOLUTION: A lithium ion battery according to the present invention includes an electrode having a current collector and an electrode layer, and an electrolyte, and the electrode layer contains a binder having a swelling degree of 120% or more with respect to the electrolyte.SELECTED DRAWING: Figure 1

Description

[Technical Field]

[0001] The present disclosure relates to lithium-ion batteries. [Background technology]

[0002] In recent years, with the rapid spread of electronic devices such as personal computers and mobile phones, the development of batteries to be used as their power sources has progressed. The automotive industry has also been developing batteries for use in hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and battery-electric vehicles (BEVs). Among various types of batteries, lithium-ion secondary batteries have the advantage of high energy density.

[0003] A battery, such as a lithium-ion secondary battery, typically includes a positive electrode, a negative electrode, and an electrolyte layer disposed between the positive and negative electrodes. The positive electrode typically includes a positive electrode current collector and a positive electrode layer containing a positive electrode active material. The negative electrode typically includes a negative electrode current collector and a negative electrode layer containing a negative electrode active material.

[0004] For example, the positive electrode of a lithium ion secondary battery may contain active materials containing valuable rare metals such as cobalt, nickel, and manganese, and recycling of these materials is required from the viewpoint of resource conservation.

[0005] In light of this background, methods have been proposed for recovering lithium-ion secondary batteries and extracting and recycling various materials, including rare metals. For example, Patent Document 1 discloses a method for recycling lithium-ion secondary batteries in which a stainless steel container is filled with a plurality of stacked positive electrodes made of aluminum foil coated with an active material and negative electrodes made of copper foil coated with an active material, with a plastic foil separator interposed therebetween, and a nonaqueous electrolyte solution is poured into the container and sealed, the method comprising: introducing the lithium-ion secondary batteries into a cylindrical body of a crusher that has a rotating shaft and a flexible wire rod, one end of which is fixed to the rotating shaft, that rotates around the rotating shaft within the cylindrical body; crushing the lithium-ion secondary batteries with the rotating wire rod; and separating and recovering the crushed material into at least the plastic, stainless steel, aluminum, copper, and active material using a separating means. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] Patent No. 5729153 Summary of the Invention [Problem to be solved by the invention]

[0007] When separating the current collector and the active material for the purpose of recycling a lithium-ion battery, a certain amount of the current collector may be contained in the active material, and complete separation may not be possible. As a result, recovery efficiency may decrease, and recyclability may also decrease. The present disclosure has been made in view of the above-mentioned problems, and a primary object of the present disclosure is to provide a lithium-ion battery with excellent recyclability. [Means for solving the problem]

[0008] [1] An electrode having a current collector and an electrode layer, and an electrolyte solution, The lithium ion battery, wherein the electrode layer contains a binder having a swelling degree with respect to the electrolyte solution of 120% or more.

[0009] [2] The lithium ion battery according to [1], wherein the swelling degree of the binder is 200% or less.

[0010] [3] The lithium ion battery according to [1] or [2], wherein the binder is a fluorine-containing polymer.

[0011] [4] the peel strength between the current collector and the electrode layer is 2.0 N / cm or more; The lithium ion battery according to any one of [1] to [3], wherein the peel strength after a high-temperature storage test is 1.0 N / cm or less.

[0012] [5] The fluorine-containing polymer has, as structural units, at least one of [-CH2-CF2-] and [-C2F4-], and [-CF2CF(CF3)-], The lithium ion battery according to [3], wherein the electrode layer contains an active material and a conductive material, and contains a composite in which the conductive material and the binder are attached to a surface of the active material. [Effects of the Invention]

[0013] The lithium ion battery according to the present disclosure has the advantage of being highly recyclable. [Brief explanation of the drawings]

[0014] [Figure 1] FIG. 1 is a schematic cross-sectional view illustrating a lithium-ion battery according to the present disclosure. [Figure 2] 1 shows the results of peel strength during electrode production and peel strength during disassembly after storage in Comparative Example 1, Comparative Example 2, and Example 1. [Figure 3] The relationship between the swelling degree of the binder used in Comparative Example 1, Comparative Example 2, and Example 1 and the peel strength (at the time of electrode production and at the time of disassembly after storage) is shown. DETAILED DESCRIPTION OF THE INVENTION

[0015] Hereinafter, embodiments of the present disclosure will be described in detail with reference to the drawings. Each of the drawings shown below is a schematic illustration, and the size and shape of each part are appropriately exaggerated for ease of understanding. Furthermore, in this specification, when expressing the manner in which another member is disposed relative to a certain member, the term "above" or "below" simply refers to both a case in which another member is disposed directly above or below the certain member so as to be in contact with the certain member, and a case in which another member is disposed above or below the certain member via another member, unless otherwise specified.

[0016] Fig. 1 is a schematic cross-sectional view illustrating a lithium-ion battery according to the present disclosure. The lithium-ion battery 100 shown in Fig. 1 has a positive electrode 10, a negative electrode 20, and an electrolyte layer 30 disposed between the positive electrode 10 and the negative electrode 20. The positive electrode 10 has a positive electrode current collector 1 and a positive electrode layer 2 disposed between the positive electrode current collector 1 and the electrolyte layer 30. Meanwhile, the negative electrode 20 has a negative electrode current collector 11 and a negative electrode layer 12 disposed between the negative electrode current collector 11 and the electrolyte layer 30. In the lithium-ion battery 10 shown in Fig. 1, the electrolyte layer 30 contains an electrolyte solution.

[0017] In the lithium-ion battery 100 of the present disclosure, the positive electrode layer 2 in the positive electrode 10 may have a binder having a swelling degree of 120% or more in an electrolyte solution. Also, the negative electrode layer 12 in the negative electrode 20 may have a binder having a swelling degree of 120% or more in an electrolyte solution. Furthermore, both the positive electrode layer 2 in the positive electrode 10 and the negative electrode layer 12 in the negative electrode 20 may have a binder having a swelling degree of 120% or more in an electrolyte solution. In this specification, a binder having a swelling degree of 120% or more in an electrolyte solution is also referred to as a "high swelling binder."

[0018] During the battery manufacturing process, it is preferable that the peel strength between the current collector and the electrode layer (hereinafter simply referred to as peel strength) is high. The inventors of the present application have found that such high peel strength is maintained even during disassembly for recycling, making it difficult to cleanly separate the current collector and the electrode layer. On the other hand, if the binder content in the electrode layer is reduced in order to lower the peel strength during disassembly, the electrode layer may slip off during the battery manufacturing process, resulting in a decrease in quality.

[0019] The present inventors have also found that by using a highly swellable binder in the electrode layer, which has a swelling degree in response to an electrolyte solution of a predetermined value or more, it is possible to obtain a lithium ion battery that has high peel strength during the battery manufacturing process and low peel strength when the battery is disassembled, and that is excellent in recyclability, thereby completing the present invention.

[0020] 1. Electrode The electrode in the present disclosure has a current collector and an electrode layer. The current collector and the electrode layer are preferably in direct contact with each other. The electrode may be a positive electrode or a negative electrode. The positive electrode has a positive electrode current collector and a positive electrode layer. On the other hand, the negative electrode has a negative electrode current collector and a negative electrode layer.

[0021] (1) Electrode layer The electrode layer in the present disclosure contains a highly swellable binder. A binder with a high degree of swelling easily absorbs the electrolyte into the crystalline structure of the binder, which reduces the resin strength. Therefore, while the peel strength between the current collector and the electrode layer is high during the battery manufacturing process (e.g., during electrode fabrication), the peel strength decreases when the battery is disassembled, resulting in a lithium-ion battery with excellent recyclability. Furthermore, the inclusion of a highly swellable binder increases the coverage of the conductive material with respect to the active material, thereby reducing the battery resistance.

[0022] The highly swellable binder has a swelling degree in the electrolyte of 120% or more, and may be 130% or more, while the swelling degree is, for example, 200% or less, and may be 150% or less.

[0023] In the present disclosure, the swelling degree of a binder refers to the weight increase rate of the binder alone when immersed in an electrolyte solution at 60°C for 24 hours, and is specifically a value determined as follows: Here, the swelling degree is measured using an electrolyte solution having the same composition as the electrolyte solution constituting the battery.

[0024] First, the weight of the binder processed into a sheet (weight of the binder before immersion) is measured. Next, it is immersed in an electrolyte at 60°C for 24 hours. The weight of the binder removed from the electrolyte (weight of the binder after immersion) is measured. The swelling degree of the binder can be determined using the following formula based on the value obtained by dividing the weight of the binder increased after immersion by the weight of the binder before immersion. Swelling degree of binder (%) = ((weight of binder after immersion) - (weight of binder before immersion)) / (weight of binder before immersion) x 100

[0025] The highly swellable binder is usually a polymer, and preferably a fluorine-containing polymer. The highly swellable binder preferably has, for example, [-CH2-CF2-] (hereinafter sometimes referred to as Formula 1) as a constituent unit. Furthermore, the highly swellable binder preferably has a constituent unit represented by Formula 1 as the main constituent unit. "Main constituent unit" refers to the constituent unit that has the highest proportion (molar ratio) among all constituent units that constitute the binder. The proportion of the constituent unit represented by Formula 1 to all constituent units that constitute the highly swellable binder is, for example, 50 mol% or more, or may be 70 mol% or more, or may be 90 mol% or more.

[0026] The highly swellable binder may have, for example, [-C2F4-] (hereinafter, sometimes referred to as Formula 2) as a constituent unit. Furthermore, the highly swellable binder may have a constituent unit represented by (Formula 2) as the main constituent unit. The proportion of the constituent unit represented by (Formula 2) to all constituent units constituting the highly swellable binder is, for example, 50 mol% or more, or may be 70 mol% or more, or may be 90 mol% or more.

[0027] The highly swellable binder may or may not have the structural unit [-CF2CF(CF3)-] (hereinafter sometimes referred to as Formula 3), but preferably does. In the former case, the highly swellable binder may have a structural unit represented by (Formula 1) or (Formula 2) and a structural unit represented by (Formula 3).

[0028] A specific example of a highly swellable binder is polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP), a comonomer of vinylidene fluoride and hexafluoropropylene. PVDF-HFP has a -CF3 branch structure in its polymer chain, so it has a relatively low degree of crystallinity and a high degree of swelling compared to, for example, PVDF.

[0029] When the highly swellable binder has a structural unit (HFP) represented by formula 3, the proportion of HFP contained in the highly swellable binder is, for example, 30 mol% or more, or may be 40 mol% or more, or may be 50 mol% or more, relative to all structural units constituting the highly swellable binder. On the other hand, the proportion of HFP contained in the highly swellable binder is, for example, 70 mol% or less, or may be 60 mol% or less.

[0030] The melting point of the highly swellable binder is preferably, for example, 100° C. or higher and 150° C. or lower. The melting point of the highly swellable binder can be determined, for example, by differential scanning calorimetry (DSC) in accordance with the provisions of JIS K 7121.

[0031] The highly swellable binder is, for example, in the form of particles. The particles of the highly swellable binder may have an average particle size of 10 nm to 1000 nm, 50 nm to 500 nm, or 100 nm to 300 nm.

[0032] The proportion of the highly swellable binder in the electrode layer is not particularly limited, but may be, for example, 0.1 wt % or more, or 0.5 wt % or more, or 1 wt % or more, or, for example, 15 wt % or less, or 10 wt % or less, or 5 wt % or less.

[0033] The electrode layer usually contains an active material, which may be a positive electrode active material or a negative electrode active material.

[0034] The active material in the present disclosure is, for example, a lithium transition metal composite oxide. That is, it contains Li, M1 (M1 is one or more transition metals), and O. Examples of the transition metal M1 include Ni, Co, Mn, Ti, V, Cr, Fe, Cu, and Zn. Among these, it is preferable that the active material contains at least one of Ni, Co, and Mn as the transition metal. A portion of the transition metal M1 may be substituted with a metal (including a metalloid) belonging to Groups 13 to 17 of the periodic table. A typical example of a metal belonging to Groups 13 to 17 of the periodic table is Al.

[0035] Specific examples of the active material in the electrode layer include rock salt layer-type active materials such as LiCoO2, LiMnO2, LiNiO2, Li(Ni,Co,Mn)O2, and Li(Ni,Co,Al)O2; LiMn2O4, Li(Ni 0. 5Mn 1.5 )O4, Li4Ti5O 12 and olivine type active materials such as LiFePO4, LiMnPO4, LiNiPO4, and LiCoPO4.

[0036] The active material particles may have an average particle size of, for example, 1 μm to 50 μm, 2 μm to 30 μm, or 3 μm to 10 μm. The proportion of the active material in the electrode layer is not particularly limited, but may be, for example, 40 wt % or more, 60 wt % or more, or 80 wt % or more.

[0037] The electrode layer may further contain a conductive material. Examples of the conductive material include carbon materials. Examples of the carbon material include particulate carbon materials such as carbon black, and fibrous carbon materials such as carbon fibers, carbon nanotubes (CNTs), and carbon nanofibers (CNFs). Examples of the carbon black include acetylene black (AB), ketjen black (KB), and furnace black (FB).

[0038] The proportion of the conductive material in the electrode layer is not particularly limited, but may be, for example, 0.5% by weight or more, or 1% by weight or more, while the proportion of the conductive material may be, for example, 20% by weight or less, or 10% by weight or less.

[0039] The electrode layer usually contains an electrolyte, which will be described later.

[0040] The electrode layer preferably contains a composite in which a conductive material and a highly swellable binder are attached to the surface of an active material, because this improves contact between the conductive material and the active material. In the composite, the conductive material and the highly swellable binder are preferably attached in a dispersed state to the surface of the active material.

[0041] The composite is usually in the form of particles. The coverage of the highly swellable binder and the conductive material in the composite is, for example, 70% or more and less than 100%, or may be 80% or more and 95% or less. The coverage of the conductive material and the highly swellable binder can be calculated, for example, by observing the composite with a scanning electron microscope (SEM), obtaining a secondary electron image, and performing a binarization process.

[0042] The thickness of the electrode layer is, for example, 1 μm or more and 500 μm or less, and is, for example, 5 μm or more and 250 μm or less. It may be 15 μm or more and 150 μm or less.

[0043] The electrode layer is preferably formed by a dry method. In the present disclosure, the dry method refers to a method of forming a film without using a dispersion medium such as an organic solvent. Specifically, the electrode layer is preferably formed by dry-coating a composite, in which a conductive material and a highly swellable binder are attached to the surface of an active material, onto a current collector.

[0044] An example of a method for producing the composite is a method in which an active material, a highly swellable binder, and a conductive material are combined using a composite processing device. The composite processing is preferably performed dry. For example, the composite can be performed by mixing using a mixer, a bead mill, a ball mill, a mortar, or the like, with a mixer being particularly preferred. In this case, the rotation speed during the composite processing (under load) may be, for example, 500 rpm to 20,000 rpm, or 1,000 rpm to 10,000 rpm. The processing time may be 0.5 minutes to 2 hours, 1 minute to 1 hour, 1 minute to 30 minutes, or 1 minute to 20 minutes.

[0045] The electrode layer may be formed, for example, by preparing an electrode mixture containing a composite, dry-coating the electrode mixture on the surface of a current collector, and, if necessary, heating to enhance adhesion or compressing to enhance the density of the mixture. The mixture preferably does not contain any materials other than the composite. Even if materials other than the composite are included, the amount is preferably small, such as 5% by weight or less or 1% by weight or less relative to the composite. Examples of materials other than the composite include additional conductive materials and additional binders. Examples of the additional conductive materials, additional binders, and current collectors that can be used include those exemplified in the description of the electrodes above. Performing the film formation process in a dry manner can reduce the drying time and the amount of organic solvent used. Furthermore, the composite described above has a coverage of conductive materials and binders suitable for forming an electrode in a dry manner. For example, electrostatic coating using an electrostatic screen or the like is a suitable dry coating method.

[0046] (2) Current collector The current collector in the present disclosure collects current from the electrode layer. The current collector may be a positive electrode current collector or a negative electrode current collector. Examples of materials for the positive electrode current collector include SUS, aluminum, nickel, iron, titanium, and carbon. Examples of materials for the negative electrode current collector include SUS, copper, nickel, and carbon. The electrode current collector may be in the form of, for example, a foil or a mesh.

[0047] (3) Electrode The electrode in the present disclosure has a current collector and an electrode layer. The electrode in the present disclosure may be at least one of a positive electrode or a negative electrode, or may be both a positive electrode and a negative electrode. When the electrode in the present disclosure is a positive electrode, the positive electrode has a positive electrode current collector and a positive electrode layer. When the electrode in the present disclosure is a negative electrode, the negative electrode has a negative electrode current collector and a negative electrode layer.

[0048] 2. Electrolyte The lithium ion battery in the present disclosure contains an electrolytic solution as an electrolyte.

[0049] The electrolyte solution contains, for example, a lithium salt and a solvent. Examples of the lithium salt include inorganic lithium salts such as LiPF6, LiBF4, LiClO4, and LiAsF6; and organic lithium salts such as LiCF3SO3, LiN(SO2CF3)2, LiN(SO2C2F5)2, and LiC(SO2CF3)3. Examples of the solvent include ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), dimethyl carbonate (DMC), diethyl carbonate (DEC), and ethyl methyl carbonate (EMC). The solvent may be one type only, or two or more types.

[0050] 3. Lithium-ion battery The lithium ion battery of the present disclosure has, for example, a positive electrode, a negative electrode, and an electrolyte layer disposed between the positive electrode and the negative electrode. At least one of the positive electrode and the negative electrode corresponds to the electrode described above. The electrolyte layer contains at least the above-described electrolytic solution (liquid electrolyte) as an electrolyte. The thickness of the electrolyte layer is, for example, 0.1 μm or more and 1000 μm or less. The electrolyte layer may have a separator.

[0051] In the lithium ion battery according to the present disclosure, the peel strength between the current collector and the electrode layer during disassembly of the battery is lower than the peel strength between the current collector and the electrode layer during electrode fabrication. The peel strength during electrode fabrication can generally be defined as the peel strength between the current collector and the electrode layer in a lithium ion battery. The peel strength between the current collector and the electrode layer in a lithium ion battery is, for example, 2.0 N / cm or more, preferably 3.0 N / cm or more, and more preferably 4.0 N / cm or more. The peel strength between the current collector and the electrode layer in a lithium ion battery is, for example, the peel strength measured using a 90° peel tester after forming an electrode by forming an electrode layer on a current collector. The peel strength during battery disassembly can also be defined as the peel strength after a high-temperature storage test described below. In the lithium ion battery according to the present disclosure, the peel strength after a high-temperature storage test is, for example, 1.5 N / cm or less, preferably 1.0 N / cm or less. The peel strength after the high-temperature storage test is measured by, for example, storing a battery after charge / discharge cycles in a thermostatic chamber at 60°C for 10 days, disassembling it, cleaning the electrodes, and vacuum-drying it at room temperature for 5 hours, followed by measuring the peel strength using a 90° peel tester.

[0052] The lithium ion battery in the present disclosure is typically a lithium ion secondary battery. Examples of uses of the battery include power sources for vehicles such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), electric vehicles (BEVs), gasoline-powered vehicles, and diesel-powered vehicles. The battery in the present disclosure may also be used as a power source for mobile objects other than vehicles (e.g., trains, ships, and aircraft), or as a power source for electrical appliances such as information processing devices.

[0053] The present disclosure is not limited to the above-described embodiments. The above-described embodiments are merely examples, and any configuration that is substantially identical to the technical idea described in the claims of the present disclosure and that provides similar effects is included within the technical scope of the present disclosure. [Example]

[0054] (Comparative Example 1) (1) Composite cathode materials First, a positive electrode active material (NCM, particle size 3 to 10 μm, manufactured by Sumitomo Metal Mining Co., Ltd.), a conductive material (acetylene black (Li400, manufactured by Denka Co., Ltd.), and a binder (HSV1810 (polyvinylidene fluoride), particle size 150 nm, manufactured by Arkema) were weighed in a ratio of positive electrode active material:conductive material:binder = 97.5 / 1.5 / 1 (wt%), and then placed in an MP mixer manufactured by Nippon Coke and Engineering Co., Ltd., and stirred at 10,000 rpm for 10 minutes to perform a composite treatment, thereby obtaining a composite.

[0055] (2) Film formation The resulting composite was dry-coated onto a current collector foil (aluminum foil with a thickness of 12 μm) using an electrostatic screen film-forming machine (Berg Industries) at a voltage of 1.5 kV and a distance of 1 cm between the current collector foil and the screen.

[0056] (3) Settlement A load of 5 ton was applied for 1 minute using flat plates heated to 180°C on both sides, softening (melting) the binder and fixing the composite to the current collector foil, producing a positive electrode structure having a positive electrode current collector (current collector foil) and a positive electrode layer.

[0057] (4) Preparation of evaluation cells Next, the negative electrode active material (natural graphite) and binder (SBR and CMC) were mixed to obtain A dispersion medium was added to the mixture and stirred to obtain a negative electrode slurry. The slurry was applied to the negative electrode current collector using a film applicator, and then heated at 80°C for 5 minutes. This resulted in a negative electrode structure having a negative electrode current collector and a negative electrode layer.

[0058] The positive electrode layer of the positive electrode structure and the negative electrode layer of the negative electrode structure were arranged opposite each other with a separator interposed between them, wound, and then an electrolyte solution was injected to obtain an evaluation cell. The electrolyte solution used was a mixed solvent containing EC, DMC, and EMC in a volume ratio of EC:DMC:EMC = 3:4:3, with LiPF dissolved to a concentration of 1 M.

[0059] (Comparative Example 2) A positive electrode structure was produced in the same manner as in Comparative Example 1, except that the binder for the positive electrode material was changed to HSV900 (polyvinylidene fluoride, particle size 150 nm, manufactured by Arkema), and an evaluation cell was produced.

[0060] Example 1 (1) Composite cathode materials First, a positive electrode active material (NCM, particle size 3-10 μm, manufactured by Sumitomo Metal Mining Co., Ltd.), a conductive material (acetylene black (Li400, manufactured by Denka Co., Ltd.)), and a binder (LBG8200, particle size 150 nm, manufactured by Arkema) were weighed out in a ratio of positive electrode active material:conductive material:binder = 97.5 / 1.5 / 1 (wt%) and placed in an MP mixer manufactured by Nippon Coke and Engineering Co., Ltd., where the mixture was stirred at 10,000 rpm for 10 minutes to form a composite. LBG8200 is a copolymer of PVDF and HFP (hexafluoropropylene).

[0061] (2) Preparation of evaluation cells Except for using the obtained composite, a positive electrode layer was formed on a current collector foil (aluminum foil with a thickness of 12 μm) to produce a positive electrode structure in the same manner as in Comparative Example 1. Except for using the obtained positive electrode structure, an evaluation cell was produced in the same manner as in Comparative Example 1.

[0062] [Measurement of the swelling point of the binder] The swelling degree of the binders used in the comparative examples and examples was measured by the method described above, and the results are shown in Table 1.

[0063] [Peel strength measurement during electrode fabrication] In the comparative examples and examples, after the positive electrode structure was fabricated, the peel strength between the positive electrode current collector and the electrode layer was measured using a 90° peel tester. The results are shown in Table 1 and FIG.

[0064] [Peel strength measurement when disassembled after storage] The evaluation cells manufactured in the comparative examples and examples were subjected to one initial charge-discharge cycle. They were then stored in a constant temperature bath at 60°C for 10 days. After storage, the evaluation cells were disassembled, and the electrodes were washed with DMC (dimethyl carbonate) and vacuum dried at room temperature for 5 hours. After vacuum drying, the peel strength between the positive electrode current collector and the electrode layer in the positive electrode was measured using a 90° peel tester. The results are shown in Table 1 and Figure 2.

[0065] FIG. 3 shows the relationship between the swelling degree of the binder used in Comparative Example 1, Comparative Example 2, and Example 1 and the peel strength between the positive electrode current collector and the electrode layer (at the time of electrode preparation and at the time of disassembly after storage).

[0066] [Table 1]

[0067] 2 and 3, it was confirmed that Example 1 had high peel strength during electrode fabrication and low peel strength during battery disassembly. It is presumed that the use of a binder with a swelling degree of 120% or more caused the electrolyte to be absorbed into the crystalline structure of the binder, reducing the resin strength of the binder and resulting in a decrease in peel strength. [Explanation of symbols]

[0068] 1...Positive electrode current collector 2...Positive electrode layer 10...Positive electrode 20...Negative electrode 11...Negative electrode current collector 12...Anode layer 30...Electrolyte layer 100...battery

Claims

1. An electrode having a current collector and an electrode layer, and an electrolyte solution, the electrode layer contains an active material, a conductive material, and a binder having a swelling degree with respect to the electrolytic solution of 120% or more; the electrode layer contains a composite in which the conductive material and the binder are attached to a surface of the active material, In the composite, a coverage of the surface of the active material with the conductive material and the binder is 70% or more.

2. 2. The lithium ion battery of claim 1, wherein the swelling degree of the binder is 200% or less.

3. 3. The lithium ion battery of claim 1, wherein the binder is a fluorine-containing polymer.

4. the peel strength between the current collector and the electrode layer is 2.0 N / cm or more; 3. The lithium ion battery according to claim 1, wherein the peel strength after a high-temperature storage test is 1.0 N / cm or less.

5. The fluorine-containing polymer has a structural unit of [—CH ２ -CF ２ -] and [-C ２ F ４ -] and at least one of [-CF ２ CF (CF ３ )-].

6. 2. The lithium ion battery according to claim 1, wherein the coverage is 95% or less.

7. A method for manufacturing an electrode for use in a lithium ion battery including an electrolyte, comprising: a step of dry-composite-treating an active material, a conductive material, and a binder having a swelling degree of 120% or more in the electrolyte solution to prepare a composite in which the conductive material and the binder are attached to a surface of the active material; a step of dry-coating the composite on a surface of a current collector to form an electrode layer on the current collector; The method for manufacturing an electrode comprising the steps of:

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