Secondary battery and manufacturing method thereof

Abstract

To provide a secondary battery with high volume energy density.SOLUTION: In a secondary battery, an electrode body having a positive electrode tab group at one end terminal unit is accommodated in a battery case. A positive electrode terminal and the positive electrode tab group are electrically connected to each other via a second positive electrode current collector. The positive electrode tab group is connected to a tab connection portion of the second positive electrode current collector in a bent state. A tape as fixing means is attached across a first main surface of the electrode body, a tab connection portion of the second positive electrode current collector, and a second main surface of the electrode body.SELECTED DRAWING: Figure 10

Description

[Technical Field]

[0001] The present disclosure relates to a secondary battery and a method for manufacturing the same. [Background technology]

[0002] BACKGROUND ART Secondary batteries such as alkaline secondary batteries and non-aqueous electrolyte secondary batteries are used as driving power sources for electric vehicles (EVs), hybrid electric vehicles (HEVs, PHEVs), and the like.

[0003] In these secondary batteries, a battery case is formed by a cylindrical exterior body with a bottom and an opening, and a sealing plate that seals the opening. An electrode assembly consisting of a positive electrode plate, a negative electrode plate, and a separator is housed inside the battery case, along with an electrolyte. A positive electrode terminal and a negative electrode terminal are attached to the sealing plate. The positive electrode terminal is electrically connected to the positive electrode plate via a positive electrode current collector, and the negative electrode terminal is electrically connected to the negative electrode plate via a negative electrode current collector.

[0004] One such secondary battery that has been proposed is one that has an electrode group in which a positive electrode and a negative electrode are wound with a separator interposed therebetween, with current collecting tabs formed on both ends of the electrode group, and the current collecting tabs welded to leads in a state in which they are bent relative to the direction in which the winding axis of the electrode group extends (Patent Document 1 below). [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Laid-Open No. 2014-14881 Summary of the Invention

[0006] A secondary battery according to an embodiment of the present disclosure includes: an electrode assembly including a positive electrode plate and a negative electrode plate; a rectangular exterior body having an opening and accommodating the electrode body; a sealing plate that seals the opening; a terminal attached to the sealing plate, the electrode assembly has a positive electrode tab group at one end and a negative electrode tab group at the other end, The electrode body has a first main surface and a second main surface that are arranged facing each other, the rectangular exterior body has a bottom, a pair of first side walls arranged in an opposing direction to each other, and a pair of second side walls arranged in an opposing direction to each other; the positive electrode tab group is disposed on one of the first side walls, the negative electrode tab group is disposed on the other first side wall side, the positive electrode tab group or the negative electrode tab group and the terminal are electrically connected by a current collector, the positive electrode tab group or the negative electrode tab group is connected to the current collector in a folded state, A fixing means is attached across the first main surface, the current collector, and the second main surface.

[0007] According to the configuration of the secondary battery according to one embodiment of the present disclosure, the secondary battery has a higher volumetric energy density and a structure that is easy to assemble.

[0008] In the width direction of the current collector, a joint portion between the current collector and the positive electrode tab group or the negative electrode tab group may be configured to be eccentric toward the base side of the positive electrode tab group or the negative electrode tab group.

[0009] The positive electrode tab group or the negative electrode tab group can have a contact region in contact with the current collector, a root region arranged closer to the root of the positive electrode tab group or the negative electrode tab group than the contact region, and a tip region arranged closer to the tip of the positive electrode tab group or the negative electrode tab group than the contact region.

[0010] The fixing means may be in contact with the tip region.

[0011] The fixing means may be a tape.

[0012] an end portion of the fixing means on the sealing plate side is located closer to the sealing plate than an end portion of the positive electrode tab group or the negative electrode tab group on the sealing plate side, The bottom end of the fixing means may be configured to be located closer to the bottom than the bottom end of the positive electrode tab group or the negative electrode tab group.

[0013] The bottom-side end of the current collector may be located closer to the bottom than the bottom-side end of the positive electrode tab group or the negative electrode tab group.

[0014] A method for manufacturing a secondary battery according to an embodiment of the present disclosure includes: an electrode assembly including a positive electrode plate and a negative electrode plate; a rectangular exterior body having an opening and accommodating the electrode body; a sealing plate that seals the opening; a terminal attached to the sealing plate, the electrode assembly has a positive electrode tab group at one end and a negative electrode tab group at the other end, The electrode body has a first main surface and a second main surface that are arranged facing each other, the rectangular exterior body has a bottom, a pair of first side walls arranged in an opposing direction to each other, and a pair of second side walls arranged in an opposing direction to each other; the positive electrode tab group or the negative electrode tab group and the terminal are electrically connected by a current collector, a step of connecting the positive electrode tab group or the negative electrode tab group to the current collector; a step of bending the positive electrode tab group or the negative electrode tab group and changing the orientation of the current collector connected to the positive electrode tab group or the negative electrode tab group; The method includes a step of attaching a fixing means across the first main surface, the current collector, and the second main surface, thereby fixing the positive electrode tab group or the negative electrode tab group in a folded state.

[0015] According to the method for manufacturing a secondary battery according to an embodiment of the present disclosure, a secondary battery with a higher volumetric energy density can be easily manufactured.

[0016] In the width direction of the current collector, the joint portion between the current collector and the positive electrode tab group or the negative electrode tab group can be formed eccentrically toward the base side of the positive electrode tab group or the negative electrode tab group.

[0017] the current collectors include a first current collector and a second current collector, the positive electrode tab group or the negative electrode tab group is connected to the second current collector, The method may include a step of connecting the second current collector, to which the positive electrode tab group or the negative electrode tab group is connected and to which the fixing means is attached, to the first current collector attached to the sealing plate.

[0018] The fixing means may be a tape.

[0019] According to the present disclosure, a secondary battery with a higher volumetric energy density can be provided. [Brief explanation of the drawings]

[0020] [Figure 1] FIG. 1 is a perspective view of a secondary battery according to an embodiment. [Figure 2] FIG. 2 is a cross-sectional view of the secondary battery taken along line II-II in FIG. [Figure 3A] FIG. 3A is a diagram showing the outer surface side of the battery of the sealing plate to which the positive electrode terminal, the negative electrode terminal, the first positive electrode current collector, and the first negative electrode current collector are attached. [Figure 3B] FIG. 3B is a diagram showing the inner surface of the battery of the sealing plate to which the positive electrode terminal, the negative electrode terminal, the first positive electrode current collector, and the first negative electrode current collector are attached. [Figure 4] FIG. 4 is a plan view of the positive electrode plate according to the embodiment. [Figure 5] FIG. 5 is a plan view of the negative electrode plate according to the embodiment. [Figure 6] FIG. 6 is a plan view of the electrode body according to the embodiment. [Figure 7A] FIG. 7A is a plan view of a second positive electrode current collector according to an embodiment. [Figure 7B]FIG. 7B is a cross-sectional view of the second positive electrode current collector taken along line VIIB-VIIB in FIG. 7B. [Figure 8] FIG. 8 is a cross-sectional view showing a state in which a positive electrode tab group is connected to a second positive electrode current collector. [Figure 9] FIG. 9 is a perspective view of an electrode assembly to which a second positive electrode current collector and a second negative electrode current collector are attached. [Figure 10] FIG. 10 is a cross-sectional view of the vicinity of the connection portion between the second positive electrode current collector and the positive electrode tab group, showing the state in which the positive electrode tab group is bent and fixed. [Figure 11] FIG. 11 is a perspective view of an electrode assembly including a plurality of electrode bodies. [Figure 12A] FIG. 12A is a diagram showing a state in which a first positive electrode current collector and a first negative electrode current collector are disposed between a second positive electrode current collector and a second negative electrode current collector. [Figure 12B] FIG. 12B is a diagram showing a state in which the distance between the second positive electrode current collector and the second negative electrode current collector is reduced. [Figure 12C] FIG. 12C is a diagram showing the state after the first positive electrode current collector and the second positive electrode current collector are connected, and the first negative electrode current collector and the second negative electrode current collector are connected. [Figure 13] FIG. 13 is a perspective view of the sealing plate and the electrode assembly after the first positive electrode current collector and the second positive electrode current collector have been connected and the first negative electrode current collector and the second negative electrode current collector have been connected. [Figure 14] FIG. 14 is a development view of the electrode holder according to the embodiment. [Figure 15] FIG. 15 is a cross-sectional view of the vicinity of the connection part between the second positive electrode current collector and the positive electrode tab group in another embodiment, showing the state in which the positive electrode tab group is bent and fixed. [Figure 16] FIG. 16 is a cross-sectional view showing a state in which a positive electrode tab group is connected to a second positive electrode current collector in another embodiment. [Figure 17] FIG. 17 is a cross-sectional view of the vicinity of the connection part between the second positive electrode current collector and the positive electrode tab group in another embodiment, showing the state in which the positive electrode tab group is bent and fixed. [Figure 18] FIG. 18 is a diagram showing a state in which a second positive electrode current collector is connected to a first positive electrode current collector in another embodiment. DETAILED DESCRIPTION OF THE INVENTION

[0021] The configuration of the secondary battery 20 according to the embodiment will be described below. Note that the present disclosure is not limited to the following embodiment.

[0022] As shown in FIGS. 1 and 2 , a secondary battery 20 includes a battery case 100 composed of a rectangular outer casing 1 having a bottomed, rectangular cylindrical shape with an opening and a sealing plate 2 sealing the opening of the rectangular outer casing 1. The rectangular outer casing 1 has a bottom 1a, a pair of first side walls 1b and 1c, and a pair of second side walls 1d and 1e. The pair of first side walls 1b and 1c are arranged facing each other, and the pair of second side walls 1d and 1e are arranged facing each other. The area of ​​the pair of first side walls 1b and 1c is smaller than the area of ​​the pair of second side walls 1d and 1e. The rectangular outer casing 1 and the sealing plate 2 are each preferably made of metal, more preferably aluminum or iron. An electrode assembly 3 including a positive electrode plate 4 and a negative electrode plate 5 is housed within the rectangular outer casing 1 together with an electrolyte. The electrode assembly 3 according to this embodiment is a flat, wound electrode assembly in which a strip-shaped positive electrode plate 4 and a strip-shaped negative electrode plate 5 are wound with a strip-shaped separator interposed therebetween. In the electrode body 3, a positive electrode tab group 40 is provided at one end in the direction in which the winding axis extends, and a negative electrode tab group 50 is provided at the other end in the direction in which the winding axis extends.

[0023] A positive electrode terminal 8 and a negative electrode terminal 9 are attached to the sealing plate 2. The positive electrode tab group 40 is electrically connected to the positive electrode terminal 8 via a positive electrode current collector 6. The positive electrode current collector 6 includes a first positive electrode current collector 61 and a second positive electrode current collector 62. The negative electrode tab group 50 is electrically connected to the negative electrode terminal 9 via a negative electrode current collector 7. The negative electrode current collector 7 includes a first negative electrode current collector 71 and a second negative electrode current collector 72.

[0024] The positive electrode tab group 40 includes multiple positive electrode tabs 4b. The second positive electrode current collector 62 has a region that is arranged along the first side wall 1b of the rectangular outer casing 1. The positive electrode tab group 40 is bent and connected to the region of the second positive electrode current collector 62 that is arranged along the first side wall 1b. The second positive electrode current collector 62 has a plate-shaped region that is arranged along the first side wall 1b of the rectangular outer casing 1, and the positive electrode tab group 40 is connected to the surface of the plate-shaped region facing the electrode body 3. The inclination of the plate-shaped region with respect to the first side wall 1b is preferably less than ±30°, more preferably less than ±15°, and even more preferably less than ±10°. It is more preferable that the plate-shaped region is approximately parallel to the first side wall 1b (for example, the inclination of the plate-shaped region with respect to the first side wall 1b is within ±5°).

[0025] The negative electrode tab group 50 includes multiple negative electrode tabs 5b. The second negative electrode current collector 72 has a region that is arranged along the first side wall 1c of the rectangular outer casing 1. The negative electrode tab group 50 is bent and connected to the region of the second negative electrode current collector 72 that is arranged along the first side wall 1c. The second negative electrode current collector 72 has a plate-shaped region that is arranged along the first side wall 1c of the rectangular outer casing 1, and the negative electrode tab group 50 is connected to the surface of the plate-shaped region that faces the electrode body 3. The inclination of the plate-shaped region with respect to the first side wall 1c is preferably less than ±30°, more preferably less than ±15°, and even more preferably less than ±10°. It is more preferable that the plate-shaped region is approximately parallel to the first side wall 1c (for example, the inclination of the plate-shaped region with respect to the first side wall 1b is within ±5°).

[0026] An external insulating member 10 made of resin is disposed between the sealing plate 2 and the positive electrode terminal 8. An internal insulating member 11 made of resin is disposed between the sealing plate 2 and the first positive electrode current collector 61. An external insulating member 12 made of resin is disposed between the sealing plate 2 and the negative electrode terminal 9. An internal insulating member 13 made of resin is disposed between the sealing plate 2 and the first negative electrode current collector 71.

[0027] The electrode body 3 is placed inside an electrode body holder 14 made by folding an insulating resin sheet into a box or bag shape.

[0028] The sealing plate 2 is provided with an electrolyte injection hole 15, which is sealed with a sealing member 16. The sealing plate 2 is provided with a gas release valve 17 that breaks when the pressure inside the battery case 100 reaches or exceeds a predetermined value, thereby releasing gas inside the battery case 100.

[0029] Next, a method for manufacturing the secondary battery 20 and details of each component will be described. [Attaching the terminal and first current collector to the sealing plate]

[0030] The sealing plate 2 has a positive electrode terminal mounting hole near one end and a negative electrode terminal mounting hole near the other end. An external insulating member 10 is arranged on the outer surface of the sealing plate 2 around the positive electrode terminal mounting hole, and an internal insulating member 11 and a first positive electrode current collector 61 are arranged on the inner surface of the sealing plate 2 around the positive electrode terminal mounting hole. Then, from the outside of the battery, a positive electrode terminal 8 is inserted through the through hole in the external insulating member 10, the positive electrode terminal mounting hole in the sealing plate 2, the through hole in the internal insulating member 11, and the through hole in the first positive electrode current collector 61, and the positive electrode terminal 8 is crimped onto the first positive electrode current collector 61. More preferably, the crimped portion of the positive electrode terminal 8 is welded to the first positive electrode current collector 61.

[0031] An external insulating member 12 is arranged on the outer surface of the sealing plate 2 around the negative terminal mounting hole, and an internal insulating member 13 and a first negative electrode current collector 71 are arranged on the inner surface of the sealing plate 2 around the negative terminal mounting hole. Then, a negative electrode terminal 9 is inserted from the outside of the battery through the through hole in the external insulating member 12, the negative electrode terminal mounting hole in the sealing plate 2, the through hole in the internal insulating member 13, and the through hole in the first negative electrode current collector 71, and the negative electrode terminal 9 is crimped onto the first negative electrode current collector 71. It is more preferable to further weld the crimped portion of the negative electrode terminal 9 to the first negative electrode current collector 71.

[0032] 3A and 3B are perspective views of the sealing plate 2 to which the positive electrode terminal 8, the first positive electrode current collector 61, the negative electrode terminal 9, and the first negative electrode current collector 71 are attached. Fig. 3A shows the outside of the battery, and Fig. 3B shows the inside of the battery.

[0033] The first positive electrode current collector 61 has a first region 61a that is arranged along the sealing plate 2, and a second region 61b that is bent from an end of the first region 61a. In the state of the secondary battery 20, the first region 61a is arranged between the sealing plate 2 and the electrode body 3. The second region 61b extends from the first region 61a toward the bottom 1a of the rectangular outer casing 1. The second region 61b is arranged between the first side wall 1b of the rectangular outer casing 1 and the electrode body 3.

[0034] The first negative electrode current collector 71 has a first region 71a that is arranged along the sealing plate 2, and a second region 71b that is bent from an end of the first region 71a. In the state of the secondary battery 20, the first region 71a is arranged between the sealing plate 2 and the electrode body 3. The second region 71b extends from the first region 71a toward the bottom 1a of the rectangular outer casing 1. The second region 71b is arranged between the first side wall 1c of the rectangular outer casing 1 and the electrode body 3.

[0035] It is preferable to provide notches 61c at both widthwise ends of the second region 61b of the first positive electrode current collector 61. When connecting the second region 61b to the second positive electrode current collector 62 (described later), gripping the notches 61c enables more stable welding, resulting in the stable formation of a higher-quality joint. It is preferable that the notches 61c are located closer to the bottom 1a of the rectangular outer casing 1 than the inner insulating member 11 in the second region 61b. It is preferable that the notches 61c are located near the end of the second region 61b on the first region 61a side. It is also preferable that the second region 71b of the first negative electrode current collector 71 also have notches 71c at both widthwise ends. When the inner insulating member 11 has a wall portion covering a portion of the second region 61b, it is preferable that the notches 61c have an area that is not covered by the wall portion of the inner insulating member 11.

[0036] The positive electrode terminal 8 and the first positive electrode current collector 61 are preferably made of metal, more preferably aluminum. The negative electrode terminal 9 and the first negative electrode current collector 71 are preferably made of metal, more preferably copper. The negative electrode terminal 9 may include an area made of aluminum and an area made of copper. In this case, it is preferable that the area made of copper is connected to the first negative electrode current collector 71 made of copper, and the area made of aluminum is exposed to the outside of the battery. [Positive electrode]

[0037] First, a method for manufacturing the positive electrode plate will be described. [Preparation of positive electrode active material layer slurry]

[0038] A lithium nickel cobalt manganese composite oxide as a positive electrode active material, polyvinylidene fluoride (PVdF) as a binder, a carbon material as a conductive material, and N-methyl-2-pyrrolidone (NMP) as a dispersion medium are mixed and kneaded so that the mass ratio of lithium nickel cobalt manganese composite oxide:PVdF:carbon material is 97.5:1:1.5 to prepare a positive electrode active material layer slurry. [Preparation of positive electrode protective layer slurry]

[0039] Alumina powder, carbon material as a conductive material, polyvinylidene fluoride (PVdF) as a binder, and N-methyl-2-pyrrolidone (NMP) as a dispersion medium are mixed together so that the mass ratio of alumina powder:carbon material:PVdF is 83:3:14 to prepare a protective layer slurry. [Formation of Positive Electrode Active Material Layer and Positive Electrode Protective Layer]

[0040] The positive electrode active material layer slurry and the positive electrode protective layer slurry prepared by the above-described method are applied to both sides of an aluminum foil serving as a positive electrode core using a die coater. At this time, the positive electrode active material layer slurry is applied to the center of the positive electrode core in the width direction. In addition, the positive electrode protective layer slurry is applied to the widthwise end portions of the region where the positive electrode active material layer slurry is applied.

[0041] The positive electrode substrate coated with the positive electrode active material layer slurry and the positive electrode protective layer slurry is dried to remove the NMP contained in the positive electrode active material layer slurry and the positive electrode protective layer slurry. This forms the positive electrode active material layer and the positive electrode protective layer. The positive electrode active material layer is then compressed to form a positive electrode base plate. This positive electrode base plate is cut into a predetermined shape to form the positive electrode plate 4. The positive electrode base plate can be cut by irradiation with an energy beam such as a laser, using a mold, a cutter, or the like.

[0042] FIG. 4 is a plan view of a positive electrode plate 4. The positive electrode plate 4 has regions where positive electrode active material layers 4a are formed on both sides of a positive electrode core. Multiple positive electrode tabs 4b are provided at one end in the width direction of the positive electrode plate 4. The positive electrode tabs 4b are made of exposed portions of the positive electrode core. A positive electrode protective layer 4c having lower conductivity than the positive electrode active material layer 4a is provided at the base portion of the positive electrode tabs 4b. The positive electrode protective layer 4c can be a resin insulating layer, a layer containing ceramic and a resin binder, or the like. The positive electrode protective layer 4c may also contain a conductive material such as a carbon material. The positive electrode protective layer 4c does not necessarily have to be provided. [Negative electrode]

[0043] Next, a method for manufacturing the negative electrode plate will be described. [Preparation of negative electrode active material layer slurry]

[0044] Graphite as the negative electrode active material, styrene butadiene rubber (SBR) and carboxymethyl cellulose (CMC) as binders, and water as a dispersion medium are kneaded together so that the mass ratio of graphite:SBR:CMC is 98:1:1 to prepare a negative electrode active material layer slurry. [Formation of negative electrode active material layer]

[0045] The negative electrode active material layer slurry prepared by the method described above is applied to both sides of a copper foil having a thickness of 8 μm as a negative electrode substrate using a die coater.

[0046] The negative electrode substrate coated with the negative electrode active material layer slurry is dried to remove water contained in the negative electrode active material layer slurry. This forms the negative electrode active material layer. The negative electrode active material layer is then compressed to form a negative electrode base plate. This negative electrode base plate is cut into a predetermined shape to form the negative electrode plate 5. The negative electrode base plate can be cut by irradiation with energy rays such as a laser, using a mold, a cutter, or the like.

[0047] 5 is a plan view of the negative electrode plate 5. The negative electrode plate 5 has an area where a negative electrode active material layer 5a is formed on both sides of the negative electrode core. A plurality of negative electrode tabs 5b are provided at one end in the width direction of the negative electrode plate 5. The negative electrode tabs 5b are made of exposed portions of the negative electrode core. [Preparation of electrode body]

[0048] The strip-shaped positive electrode plate 4 and strip-shaped negative electrode plate 5 prepared by the above-described method are wound with a strip-shaped polyolefin separator interposed therebetween to prepare a flat, wound electrode assembly 3. The electrode assembly 3 has a flat region in the center and curved portions on both ends of the flat region. One outer surface of the flat region is the first main surface 3a, and the other outer surface of the flat region is the second main surface 3b.

[0049] 6 is a plan view of the electrode assembly 3. A positive electrode tab group 40, in which multiple positive electrode tabs 4b are stacked, is provided at one end of the electrode assembly 3 in the direction in which the winding axis extends. A negative electrode tab group 50, in which multiple negative electrode tabs 5b are stacked, is provided at the other end of the electrode assembly 3 in the direction in which the winding axis extends. Note that in a direction perpendicular to the direction in which the winding axis of the electrode assembly 3 extends and perpendicular to the thickness direction of the electrode assembly 3 (the up-down direction in FIG. 6), the center of the positive electrode tab group 40 and the center of the negative electrode tab group 50 are shifted to one side (the upper side in FIG. 6) from the winding axis.

[0050] The positive electrode tab 4b and / or the negative electrode tab 5b may have a shape in plan view that gradually increases in width from the tip to the base. With this configuration, the positive electrode tab 4b and / or the negative electrode tab 5b are less likely to be damaged in the secondary battery 20 even when the secondary battery 20 is subjected to impact or vibration. It is also more effective to form the corners of the base portion into an R-shape. As described above, by providing a positive electrode protective layer 4c at the base portion of the positive electrode tab 4b, damage to the positive electrode tab 4b can be suppressed. Furthermore, by providing a negative electrode active material layer 5a at the base portion of the negative electrode tab 5b, damage to the negative electrode tab 5b can be suppressed. [Second positive electrode current collector and second negative electrode current collector]

[0051] FIG. 7A is a plan view of the second positive electrode current collector 62. FIG. 7B is a cross-sectional view taken along line VIIB-VIIB in FIG. 7A. The second positive electrode current collector 62 has a second region connection portion 62a, an inclined portion 62b, and a tab connection portion 62c. The second region connection portion 62a is connected to the second region 61b of the first positive electrode current collector 61. The tab connection portion 62c is connected to the positive electrode tab group 40. The inclined portion 62b is inclined relative to both the second region connection portion 62a and the tab connection portion 62c, and connects the second region connection portion 62a and the tab connection portion 62c. The inclined portion 62b forms a step between the second region connection portion 62a and the tab connection portion 62c. The angle of the inclined portion 62b relative to the second region connection portion 62a and the angle of the inclined portion 62b relative to the tab connection portion 62c are not particularly limited. The shape of the second positive electrode current collector 62 is not particularly limited. The second positive electrode current collector 62 may also be in the form of a flat plate.

[0052] A recess 62d is provided in the second region connecting portion 62a. The portion where the recess 62d is provided is thinner than the surrounding area. A through-hole 62e is provided inside the recess 62d. The second region 61b and the second region connecting portion 62a are joined inside the recess 62d.

[0053] A fuse portion 62f is provided in the second region connection portion 62a. The fuse portion 62f is a portion that melts when an excessive current flows through the secondary battery 20. The fuse portion 62f is a portion whose cross-sectional area is reduced by forming a fuse hole 62g in the second region connection portion 62a. The fuse portion 62f is preferably provided in the second positive electrode current collector 62 between the position where the second region 61b is joined and the position where the positive electrode tab group 40 is joined. The fuse portion 62f may be any portion whose cross-sectional area is reduced, and may be a portion provided with a notch or a thin portion.

[0054] The shape of the second negative electrode current collector 72 can be the same as that of the second positive electrode current collector 62. The second positive electrode current collector 62 is preferably made of metal, more preferably aluminum. The second negative electrode current collector 72 is preferably made of metal, more preferably copper, nickel, or iron.

[0055] The fuse portion 62f may not be provided on the second positive electrode current collector 62. Furthermore, the fuse portion may not be provided on the second negative electrode current collector 72. [Connection between the first current collector and the tab group]

[0056] 8, the positive electrode tab group 40 is placed on the tab connection portion 62c of the second positive electrode current collector 62, and the tab connection portion 62c and the positive electrode tab group 40 are joined to form a joint portion 63. For the joining, ultrasonic welding (ultrasonic welding), resistance welding, welding by irradiation of high-energy rays such as laser, etc. can be used. The tab connection portion 72c of the second negative electrode current collector 72 and the negative electrode tab group 50 can also be joined by a similar method.

[0057] In the tab connection portion 62c of the second positive electrode current collector 62, the joint portion 63 is preferably disposed eccentrically toward the base side (right side in FIG. 8) of the positive electrode tab group 40 in the width direction (left-right direction in FIG. 8) of the tab connection portion 62c. With this configuration, when the positive electrode tab group 40 is bent, a curved shape can be more reliably formed in a stable manner near the base of the positive electrode tab group 40. This can suppress damage to the positive electrode tab group 40. Furthermore, even if the positive electrode tab 4b is misaligned, the positive electrode tab group 40 and the tab connection portion 62c can be stably joined.

[0058] 8, it is preferable to join the positive electrode tab group 40 and the tab connection portion 62c in a state in which the tip portion of the positive electrode tab group 40 protrudes outward (to the left in FIG. 8) from the tab connection portion 62c of the second positive electrode current collector 62. This allows the positive electrode tab group 40 and the tab connection portion 62c to be joined more stably.

[0059] 9 is a perspective view of the electrode body 3 to which the second positive electrode current collector 62 and the second negative electrode current collector 72 are attached. The lower end portion of the second positive electrode current collector 62 (the portion that forms the end portion on the bottom 1a side of the rectangular outer casing 1) is preferably located lower than the lower end portion of the positive electrode tab group 40 (the portion that forms the end portion on the bottom 1a side of the rectangular outer casing 1). With this configuration, it becomes possible to more reliably and stably bend the positive electrode tab group 40 in the step of bending the positive electrode tab group 40, which will be described later. The same applies to the second negative electrode current collector 72 and the negative electrode tab group 50. [Bend Tabs]

[0060] The positive electrode tab group 40 is folded as shown in FIG. 10 . The tab connection portion 62c of the second positive electrode current collector 62, which was disposed substantially parallel to the first main surface 3a and the second main surface 3b of the electrode assembly 3 as shown in FIG. 9 , is folded to be oriented substantially perpendicular to the winding axis of the electrode assembly 3 (for example, the inclination of the tab connection portion 62c relative to the winding axis is less than ±15°). Then, a tape 80 is attached as a fixing means so as to span the first main surface 3a of the electrode assembly 3, the tab connection portion 62c, and the second main surface 3b of the electrode assembly 3. This configuration allows the positive electrode tab group 40 to maintain a curved state more stably. Furthermore, the curved positive electrode tab group 40 can be made elastic, and when the second positive electrode current collector 62 is pressed toward the electrode assembly 3, the second positive electrode current collector 62 can move toward the electrode assembly 3. When the positive electrode tab group 40 is bent, the second positive electrode current collector 62 itself is not bent.

[0061] As shown in FIG. 10 , the positive electrode tab group 40 has a contact region 40b that contacts the tab connection portion 62c, a root region 40a that is disposed closer to the root of the positive electrode tab group 40 than the contact region 40b, and a tip region 40c that is disposed closer to the tip of the positive electrode tab group 40 than the contact region 40b. The tip region 40c is bent from the contact region 40b and fixed with tape 80, improving the ease of assembly in subsequent steps. Note that providing the tip region 40c allows the contact region 40b to be made wider, allowing for more stable bonding when bonding the positive electrode tab group 40 and the tab connection portion 62c. Note that the tip region 40c does not necessarily have to be provided.

[0062] Like the positive electrode tab group 40, the negative electrode tab group 50 is also fixed in a bent state. [Electrode group]

[0063] A plurality of electrode assemblies 3, each with its positive electrode tab group 40 and negative electrode tab group 50 folded, are stacked and fixed together with an electrode assembly fixing means 90 such as tape to form an electrode assembly assembly 300. FIG. 11 is a perspective view of the electrode assembly assembly 300. Each positive electrode tab group 40 is arranged on the same side, and each negative electrode tab group 50 is arranged on the same side. In each electrode assembly 3, the positive electrode tab groups 40 are each folded in the same direction. In each electrode assembly 3, the negative electrode tab groups 50 are each folded in the same direction. The electrode assembly assembly 300 according to the embodiment includes two electrode assemblies 3. The number of electrode assemblies 3 included in the electrode assembly assembly 300 is not limited to two.

[0064] The tape 80 serving as fixing means affixed across the first main surface 3a of the electrode assembly 3, the tab connection portion 62c, and the second main surface 3b of the electrode assembly 3 preferably includes a first tape 80a and a second tape 80b. As shown in FIG. 11 , in the tab connection portion 62c of the second positive electrode current collector 62, it is preferable that the first tape 80a be affixed above the joint portion 63 between the tab connection portion 62c and the positive electrode tab group 40, and the second tape 80b be affixed below the joint portion 63 between the tab connection portion 62c and the positive electrode tab group 40. With this configuration, the curved state of the positive electrode tab group 40 can be stably maintained. The same applies to the tab connection portion 72c of the second negative electrode current collector 72.

[0065] 11, it is preferable that the upper end of the first tape 80a arranged on the upper side is arranged above the upper end of the positive electrode tab group 40, and the lower end of the second tape 80b arranged on the lower side is arranged below the lower end of the positive electrode tab group 40. With this configuration, the curved shape of the positive electrode tab group 40 can be maintained more reliably.

[0066] 11, in the stacking direction of the electrode bodies 3, the second positive electrode current collectors 62 attached to each electrode body 3 are arranged at intervals and connected onto the second region 61b of the first positive electrode current collector 61. The same applies to each second negative electrode current collector 72.

[0067] In the electrode assembly 3 according to this embodiment, the joint 63 between the positive electrode tab group 40 and the tab connection portion 62c is disposed between the lower end of the first tape 80a and the upper end of the second tape 80b.

[0068] In the embodiment, the first tape 80a and the second tape 80b are separated into two tapes, one above the other, but the second tape 80b may be a single tape. In this case, it is preferable that the upper end of one tape is disposed above the upper end of the positive electrode tab group 40, and the lower end of the other tape is disposed below the lower end of the positive electrode tab group 40. The tape 80 may cover the portion of the tab connection portion 62c where the joint portion 63 is formed. A similar configuration may be used for the second negative electrode current collector 72 and the negative electrode tab group 50. [Connection between the first and second current collectors]

[0069] The second region 61b of the first positive electrode current collector 61 is disposed inside the second region connection portion 62a of the second positive electrode current collector 62, and the second region 71b of the first negative electrode current collector 71 is disposed inside the second region connection portion 72a of the second negative electrode current collector 72. The second region 61b of the first positive electrode current collector 61 is then connected to the second region connection portion 62a of the second positive electrode current collector 62. The second region 71b of the first negative electrode current collector 71 is joined to the second region connection portion 72a of the second negative electrode current collector 72. Examples of joining methods that can be used include ultrasonic welding (ultrasonic bonding), resistance welding, and welding using high-energy rays such as lasers. Welding using high-energy rays such as lasers is particularly preferred.

[0070] 12A to 12C are cross-sectional views taken along the winding axis of the electrode body 3 of the second region 61b of the first positive electrode current collector 61, the second region 71b of the first negative electrode current collector 71, the second region connection portion 62a of the second positive electrode current collector 62, and the second region connection portion 72a of the second negative electrode current collector 72 at each stage.

[0071] 12A, the second region 61b of the first positive electrode current collector 61 and the second region 71b of the first negative electrode current collector 71 are disposed between the second region connection portion 62a of the second positive electrode current collector 62 and the second region connection portion 72a of the second negative electrode current collector 72. In this case, the distance D1 between the inner surface of the second region connection portion 62a and the inner surface of the second region connection portion 72a is preferably larger than the distance D2 between the outer surface of the second region 61b and the outer surface of the second region 71b. Note that D1 is preferably larger than D2 by 0.1 to 5 mm, and more preferably by 0.2 to 3 mm.

[0072] 12B, the second region connecting portion 62a and / or the second region connecting portion 72a are displaced inward to reduce the distance between the second region connecting portion 62a and the second region connecting portion 72a. This changes the distance D1 between the inner surface of the second region connecting portion 62a and the inner surface of the second region connecting portion 72a to D1'. At this time, the difference between D2 and D1' is preferably 0 to 0.2 mm.

[0073] 12B, a high-energy beam such as a laser is irradiated onto each of the second region connection portion 62a and the second region connection portion 72a, thereby joining the second region 61b of the first positive electrode current collector 61 and the second region connection portion 62a of the second positive electrode current collector 62 by welding, and joining the second region 71b of the first negative electrode current collector 71 and the second region connection portion 72a of the second negative electrode current collector 72 by welding.

[0074] 12C, a joint 64, which is a weld between second region 61b and second-region connecting portion 62a, is formed in recess 62d. Also, a joint 74, which is a weld between second region 71b and second-region connecting portion 72a, is formed in recess 72d.

[0075] 12A to 12C, it is possible to more stably weld the first positive electrode current collector 61 and the second positive electrode current collector 62, and the first negative electrode current collector 71 and the second negative electrode current collector 72, by a simpler method, thereby forming highly reliable joints 64 and 74.

[0076] The portions where recesses 62d and 72d are formed are thinner than the surrounding areas. By performing welding so that joints 64 and 74 are formed in these thinner portions, higher quality joints can be formed more stably. This results in a more reliable secondary battery. Furthermore, by using through-hole 62e to measure the presence or size of a gap between second region 61b and second-region connecting portion 62a, second region 61b and second-region connecting portion 62a can be joined by welding more stably. The same applies to through-hole 72e.

[0077] FIG. 13 is a perspective view showing the state after the first positive electrode current collector 61 and the second positive electrode current collector 62, and the first negative electrode current collector 71 and the second negative electrode current collector 72 have been connected, respectively. [Electrode holder]

[0078] Figure 14 is a development view of the electrode assembly holder 14. The insulating sheet that constitutes the electrode assembly holder 14 is folded along the dashed lines in Figure 14 to form the box-shaped electrode assembly holder 14. The electrode assembly holder 14 has a holder bottom 14a, a holder first main surface 14b, a holder second main surface 14c, a holder first side surface 14d, a holder second side surface 14e, a holder third side surface 14f, a holder fourth side surface 14g, a holder fifth side surface 14h, and a holder sixth side surface 14i.

[0079] When the electrode holder 14 is box-shaped, it has an area where the holder first side 14d, the holder second side 14e, and the holder third side 14f overlap, and it has an area where the holder fourth side 14g, the holder fifth side 14h, and the holder sixth side 14i overlap.

[0080] With the electrode assembly group 300 arranged in the box-shaped electrode assembly holder 14, the electrode assembly group 300 is inserted into the rectangular exterior body 1. Then, a sealing plate 2 is joined to the rectangular exterior body 1, and the opening of the rectangular exterior body 1 is sealed with the sealing plate 2. An electrolyte is poured through an electrolyte pouring hole 15 provided in the sealing plate 2, and the electrolyte pouring hole 15 is sealed with a sealing member 16. This completes the secondary battery 20. [Secondary battery]

[0081] In the secondary battery 20 according to this embodiment, the positive electrode current collector 6 includes a first positive electrode current collector 61 and a second positive electrode current collector 62. This configuration allows the positive electrode tab group 40 to be folded without bending the positive electrode current collector 6, resulting in a secondary battery with a high volumetric energy density and a simpler method. This is particularly effective when the number of electrode assemblies 3 housed in the battery case 100 is two or more. The present disclosure provides greater flexibility in determining the number of electrode assemblies 3 housed in the battery case 100. The present disclosure enables stable production of highly reliable secondary batteries, even when the number of electrode assemblies 3 housed in the battery case 100 is greater than two, without requiring the positive electrode current collector 6 to have a complex shape. The present disclosure is particularly effective when the number of electrode assemblies 3 housed in the battery case 100 is greater than two, i.e., an odd number.

[0082] In the secondary battery 20, the tab connection portion 62c of the second positive electrode current collector 62 is disposed closer to the first side wall 1b of the rectangular exterior body 1 than the second region connection portion 62a of the second positive electrode current collector 62. With this configuration, the space between the first side wall 1b and the electrode body 3 can be more effectively utilized, allowing the power generation portion of the electrode body 3 to be larger, resulting in a secondary battery with a higher volumetric energy density. The same applies to the second negative electrode current collector 72.

[0083] In the electrode body 3, the positive electrode tab group 40 is preferably eccentric toward the sealing plate 2. This allows the conductive path from the positive electrode tab group 40 to the positive electrode terminal 8 to be short, resulting in a secondary battery 20 with low internal resistance. In the electrode body 3, the negative electrode tab group 50 is preferably eccentric toward the sealing plate 2. This allows the conductive path from the negative electrode tab group 50 to the negative electrode terminal 9 to be short, resulting in a secondary battery 20 with low internal resistance.

[0084] It is preferable to dispose an insulating member (not shown) other than the electrode assembly holder 14 between the region where the second region 61b of the first positive electrode current collector 61 and the second region connecting portion 62a of the second positive electrode current collector 62 overlap and the first side wall 1b of the rectangular outer casing 1. It is also preferable to dispose an insulating member (not shown) other than the electrode assembly holder 14 between the region where the second region 71b of the first negative electrode current collector 71 and the second region connecting portion 72a of the second negative electrode current collector 72 overlap and the first side wall 1c of the rectangular outer casing 1. With this configuration, even when the secondary battery 20 is subjected to impact or vibration, damage to the joints between the respective members, the positive electrode tab group 40, and the negative electrode tab group 50 can be suppressed.

[0085] 15 is a cross-sectional view of the vicinity of the tab connection portion 62c of the second positive electrode current collector 62 and the joint portion 63 of the positive electrode tab group 40 in another embodiment, and illustrates a state in which the positive electrode tab group 40 is folded and fixed. As shown in FIG. 15, the portion of the tab connection portion 62c of the second positive electrode current collector 62 where the joint portion 63 is formed can be covered with tape 80. Even if burrs or metal powder generated when the joint portion 63 is formed are present in the portion of the tab connection portion 62c of the second positive electrode current collector 62 where the joint portion 63 is formed, the tape 80 can prevent the burrs or metal powder from moving.

[0086] 15 , the portion of the positive electrode tab group 40 where the joint 63 is formed can be covered with tape 81. Even if burrs or metal powder generated when the joint 63 is formed are present in the portion of the positive electrode tab group 40 where the joint 63 is formed, the tape 81 can prevent the burrs or metal powder from moving. The tape 81 is preferably applied before the positive electrode tab group 40 is folded.

[0087] An adhesive material can be applied or attached to the portion of the tab connection portion 62c of the second positive electrode current collector 62 where the joint portion 63 is formed and / or the portion of the positive electrode tab group 40 where the joint portion 63 is formed. Also, the portion of the tab connection portion 62c of the second positive electrode current collector 62 where the joint portion 63 is formed and / or the portion of the positive electrode tab group 40 where the joint portion 63 is formed can be covered with a thermal welding resin. Also, the tab connection portion 72c of the second negative electrode current collector 72 and the negative electrode tab group 50 can be configured in a similar manner.

[0088] In the secondary battery 20 according to the above embodiment, one second positive electrode current collector 62 and one second negative electrode current collector 72 are attached to one electrode body 3. However, this is not limited to this. Multiple second positive electrode current collectors and / or multiple second negative electrode current collectors may be attached to one electrode body 3. Another embodiment in which multiple second positive electrode current collectors are attached to one electrode body 3 will be described below. Note that multiple second negative electrode current collectors may be attached to one electrode body 3 in a similar manner. In other embodiments, descriptions of parts common to the secondary battery 20 according to the above embodiment will be omitted.

[0089] 16, the positive electrode tab group 40 is divided into two, and one of the two divided positive electrode tab groups 40A and the other positive electrode tab group 40B are connected to the tab connection portion 162c of the second positive electrode current collector 162 by welding, respectively, to form a joint portion 163. It is preferable that one positive electrode tab group 40A is collected on the first main surface 3a side, and the other positive electrode tab group 40B is collected on the second main surface 3b side. The second positive electrode current collector 162 can have a configuration similar to that of the second positive electrode current collector 62 according to the above-described embodiment.

[0090] As shown in FIG. 17, the positive electrode tab group 40A bundled on the first main surface 3a side is bent toward the center in the thickness direction of the electrode body 3, and the positive electrode tab group 40B bundled on the second main surface 3b side is bent toward the center in the thickness direction of the electrode body 3, and they are fixed with tape 80 as a fixing means.

[0091] As shown in FIG. 18 , a second positive electrode current collector 162 connected to the positive electrode tab group 40A of one electrode assembly 3 and a second positive electrode current collector 162 connected to the positive electrode tab group 40B are connected to the first positive electrode current collector 61 by welding. The second positive electrode current collector 162 has a second region connection portion 162a, an inclined portion 162b, and a tab connection portion 162c. The second region connection portion 162a is connected to the second region 61b of the first positive electrode current collector 61. Note that the configuration in this other embodiment is particularly effective when the thickness of one of the electrode assemblies 3 is large. <Other>

[0092] In the above-described embodiment, the electrode body is a wound type electrode body in which a positive electrode plate and a negative electrode plate are wound with a separator interposed therebetween, but the present invention is not limited to this. A laminated type electrode body including a plurality of positive electrode plates and a plurality of negative electrode plates may also be used.

[0093] In the above-described embodiment, an example was shown in which a wound electrode body was produced by winding a positive electrode plate on which a plurality of positive electrode tabs were formed and a negative electrode plate on which a plurality of negative electrode tabs were formed, but this is not limiting. A group of positive electrode tabs or a group of negative electrode tabs can also be produced by cutting the exposed positive electrode substrate or exposed negative electrode substrate portion wound in the wound electrode body.

[0094] In the above-described embodiment, an example has been shown in which the positive electrode current collector 6 and the negative electrode current collector 7 each consist of two parts, but the positive electrode current collector 6 and the negative electrode current collector 7 may each consist of a single part.

[0095] Known materials can be used for the positive electrode plate, negative electrode plate, separator, electrolyte, and the like.

[0096] The above-mentioned aluminum includes aluminum and aluminum alloys mainly made of aluminum. The above-mentioned copper includes copper and copper alloys mainly made of copper. The above-mentioned iron includes iron alloys mainly made of iron. The above-mentioned nickel includes nickel alloys mainly made of nickel.

[0097] The tape preferably has a substrate and an adhesive layer formed on the substrate. The substrate is preferably made of polyethylene, polypropylene, polyester, nylon, vinyl chloride, Teflon (registered trademark), polyimide, Kapton (registered trademark), polyphenylene sulfide, polyethylene naphthalate, or the like. The material of the adhesive layer is preferably made of an acrylic adhesive, a silicone adhesive, a rubber adhesive, or the like. However, the material is not limited to these. The adhesive layer is preferably adhesive at room temperature.

[0098] In the embodiment, an example in which the fixing means is tape has been shown, but this is not limiting. Possible fixing means include a resin frame, a metal frame, a ceramic frame, a clip-like member, etc. Tape is more preferable as the fixing means.

[0099] A pressure-sensitive current interruption mechanism can be provided in the conductive path between the positive electrode tab group and the positive electrode terminal or the conductive path between the negative electrode tab group and the negative electrode terminal. This current interruption mechanism is activated when the pressure inside the battery case reaches or exceeds a predetermined value, and cuts off the conductive path between the positive electrode tab group and the positive electrode terminal or the conductive path between the negative electrode tab group and the negative electrode terminal, thereby interrupting the flow of current. [Explanation of symbols]

[0100] 20 Secondary battery 100 Battery Case 1. Rectangular exterior body 1a bottom 1b,1c 1st side wall 1d, 1e Second side wall 2 Sealing plate 3 Electrode body 3a 1st principal surface 3b 2nd principal surface 300 electrode group 4 positive electrode plate 4a Positive electrode active material layer 4b Positive electrode tab 4c positive electrode protective layer 40 Positive electrode tab group 40a Root area 40b Contact area 40c tip area 5 negative electrode plate 5a Negative electrode active material layer 5b Negative electrode tab 50 negative electrode tab group 6 Positive electrode current collector 61 First positive electrode current collector 61a 1st area 61b 2nd area 61c Notch 62 Second positive electrode current collector 62a Second Area Connection 62b Slope 62c Tab connection 62d Recess 62e through hole 62f Fuse section 62g fuse hole 63,64 Joint 7 Negative electrode current collector 71 First negative electrode current collector 71a 1st area 71b 2nd area 71c Notch 72 Second negative electrode current collector 72a Second area connection part 72b Slope 72c Tab Connection 72d recess 72e through hole 74 Joint 8 Positive terminal 9 Negative terminal 10, 12 External insulating member 11, 13 Inner insulating member 14 Electrode holder 14a Bottom of holder 14b holder first main surface 14c Holder second main surface 14d Holder first side 14e Holder second side 14f Holder third side 14g holder fourth side 14h Holder 5th side 14i holder 6th side 15 Electrolyte injection hole 16 Sealing member 17 Gas exhaust valve 80 Tape 80a 1st Tape 80b 2nd Tape 81 Tape 90 Electrode body fixing means 40A, 40B Positive electrode tab group 162 Second positive electrode current collector 162a Second Area Connection 162b Slope 162c Tab Connection 163 Joint

Claims

1. an electrode assembly including a positive electrode plate and a negative electrode plate; a rectangular exterior body having an opening and accommodating the electrode body; a sealing plate that seals the opening; a terminal attached to the sealing plate, the electrode assembly has a positive electrode tab group at one end and a negative electrode tab group at the other end, The electrode body has a first main surface and a second main surface that are arranged facing each other, the rectangular exterior body has a bottom, a pair of first side walls arranged in an opposing direction to each other, and a pair of second side walls arranged in an opposing direction to each other; the positive electrode tab group is disposed on one of the first side walls, the negative electrode tab group is disposed on the other first side wall side, the positive electrode tab group or the negative electrode tab group and the terminal are electrically connected by a current collector, the positive electrode tab group or the negative electrode tab group is connected to the current collector in a folded state, a joint portion between the current collector and the positive electrode tab group or the negative electrode tab group is eccentric toward a base side of the positive electrode tab group or the negative electrode tab group in the width direction of the current collector; secondary battery

2. an electrode assembly including a positive electrode plate and a negative electrode plate; a rectangular exterior body having an opening and accommodating the electrode body; a sealing plate that seals the opening; a terminal attached to the sealing plate, the electrode assembly has a positive electrode tab group at one end and a negative electrode tab group at the other end, The electrode body has a first main surface and a second main surface that are arranged facing each other, the rectangular exterior body has a bottom, a pair of first side walls arranged in an opposing direction to each other, and a pair of second side walls arranged in an opposing direction to each other; the positive electrode tab group is disposed on one of the first side walls, the negative electrode tab group is disposed on the other first side wall side, the positive electrode tab group or the negative electrode tab group and the terminal are electrically connected by a current collector, the positive electrode tab group or the negative electrode tab group is connected to the current collector in a folded state, The positive electrode tab group or the negative electrode tab group is a contact region in contact with the current collector; a root region that is positioned closer to the root of the positive electrode tab group or the negative electrode tab group than the contact region, and a tip region that is positioned closer to the tip of the positive electrode tab group or the negative electrode tab group than the contact region, Secondary battery.

3. an electrode assembly including a positive electrode plate and a negative electrode plate; a rectangular exterior body having an opening and accommodating the electrode body; a sealing plate that seals the opening; a terminal attached to the sealing plate, the electrode assembly has a positive electrode tab group at one end and a negative electrode tab group at the other end, The electrode body has a first main surface and a second main surface that are arranged facing each other, the rectangular exterior body has a bottom, a pair of first side walls arranged in an opposing direction to each other, and a pair of second side walls arranged in an opposing direction to each other; the positive electrode tab group is disposed on one of the first side walls, the negative electrode tab group is disposed on the other first side wall side, the positive electrode tab group or the negative electrode tab group and the terminal are electrically connected by a current collector, the positive electrode tab group or the negative electrode tab group is connected to the current collector in a folded state, an end portion on the bottom side of the current collector is located closer to the bottom side than an end portion on the bottom side of the positive electrode tab group or the negative electrode tab group; Secondary battery.

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