VOC removal methods

Abstract

The present invention removes VOCs adsorbed by a VOC adsorption rotor with high energy efficiency.　A VOC removal method using a VOC adsorption rotor 10, which is equipped with a honeycomb structure carrying an adsorbent for adsorbing VOCs and is provided with an adsorption zone Z1, a desorption zone Z2, and a cooling zone Z3 along the rotation direction, the method involving: adsorbing VOCs contained in a gas being treated by passing the gas through the adsorption zone Z1 of the VOC adsorption rotor 10; desorbing the VOCs adsorbed in the adsorption zone Z1, by passing a gas through the desorption zone Z2; cooling, in the cooling zone Z3, the honeycomb structure heated in the desorption zone Z2; and heating the honeycomb structure by passing an electric current through the honeycomb structure comprising metal, in the desorption zone Z2.

Description

[Technical Field]

[0001] The present invention relates to a method for removing VOCs contained in a gas to be treated. [Background technology]

[0002] Conventionally, a technique for removing volatile organic compounds (VOCs) contained in a gas to be treated using a honeycomb-type VOC adsorption rotor that adsorbs VOCs has been known (see Patent Document 1). Conventional VOC adsorption rotors use ceramic or glass as a substrate, and carry an adsorbent that adsorbs VOCs.

[0003] The VOC adsorption rotor is provided with an adsorption zone that adsorbs VOCs contained in the gas to be treated, a desorption zone that desorbs the VOCs adsorbed in the adsorption zone by passing heated gas through it, and a cooling zone that cools the VOC adsorption rotor heated in the desorption zone. In other words, during one rotation of the VOC adsorption rotor, VOCs are adsorbed in the adsorption zone, desorbed in the desorption zone, and cooled in the cooling zone. Then, VOCs are adsorbed again in the adsorption zone. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2016-77969 Summary of the Invention [Problem to be solved by the invention]

[0005] Conventional VOC adsorption rotors heat gas in the adsorption zone and pass the heated gas through the desorption zone to desorb the VOCs. However, this does not provide high energy efficiency for desorbing VOCs, and there is room for improvement.

[0006] The present invention is intended to solve the above-mentioned problems, and aims to provide a VOC removal method that can desorb VOCs adsorbed on a VOC adsorption rotor with high energy efficiency. [Means for solving the problem]

[0007] The VOC removal method of the present invention is a VOC removal method using a VOC adsorption rotor that has a honeycomb structure supporting an adsorbent for adsorbing VOCs and is provided with an adsorption zone, a desorption zone, and a cooling zone along the rotation direction, and a gas to be treated is passed through the adsorption zone of the VOC adsorption rotor to adsorb VOCs contained in the gas to be treated, the gas is passed through the desorption zone to desorb the VOCs adsorbed in the adsorption zone, and the honeycomb structure heated in the desorption zone is cooled in the cooling zone; A voltage is applied to the honeycomb structure in the desorption zone from both outer sides in the extension direction of the rotation axis of the VOC adsorption rotor, The honeycomb structure is made of metal and is heated by passing an electric current through the honeycomb structure. [Effects of the Invention]

[0008] According to the VOC removal method of the present invention, in the desorption zone, an electric current is passed through a honeycomb structure made of metal, generating Joule heat and directly heating the honeycomb structure, which enables the adsorbed VOCs to be desorbed with high energy efficiency in the desorption zone. [Brief explanation of the drawings]

[0009] [Figure 1] 1 is a perspective view schematically illustrating the configuration of a VOC removal device, which is an example of a device for implementing a VOC removal method in one embodiment. [Figure 2] FIG. 2 is a plan view schematically showing the configuration of the VOC adsorption rotor when viewed in the extending direction of the rotation axis. DETAILED DESCRIPTION OF THE INVENTION

[0010] The features of the present invention will be specifically described below by showing embodiments of the present invention.

[0011] 1 is a perspective view schematically illustrating the configuration of a VOC removal device 100, which is an example of an apparatus for implementing a VOC removal method according to an embodiment. However, the configuration for implementing a VOC removal method according to an embodiment is not limited to the VOC removal device 100 illustrated in FIG.

[0012] The VOC removal device 100 includes a VOC adsorption rotor 10, a pair of electrodes 20a and 20b, and a voltage application device 30. As shown in FIG. 1 , the VOC removal device 100 may further include a first air blower 41, a second air blower 42, a third air blower 43, and a heating device 44.

[0013] FIG. 2 is a plan view schematically showing the configuration of the VOC adsorption rotor 10 when viewed in the direction in which the rotating shaft 11 extends (hereinafter, sometimes referred to as the rotation axis direction). Note that FIG. 2 also shows an electrode 20a, which will be described later. The VOC adsorption rotor 10 is configured to be rotatable around the rotating shaft 11 using a motor or other driving source. The diameter of the VOC adsorption rotor 10 is, for example, 500 mm or more and 2000 mm or less, and the dimension in the direction in which the rotating shaft 11 extends is, for example, 200 mm or more and 800 mm or less.

[0014] The VOC adsorption rotor 10 includes a honeycomb structure 1 that supports an adsorbent for adsorbing VOCs. The honeycomb structure 1 is made of a metal such as stainless steel. However, the metal that constitutes the honeycomb structure 1 is not limited to stainless steel. The VOC adsorption rotor 10 may be entirely made of metal, or a portion other than the honeycomb structure 1 may be made of a material other than metal.

[0015] The shape of the plurality of cells 2 constituting the honeycomb structure 1 can be any shape. In the example shown in Fig. 2, the shape of the cells 2 when viewed in the extension direction of the rotation axis 11 is triangular. However, the shape of the cells 2 when viewed in the rotation axis direction may be other shapes such as hexagonal or rectangular.

[0016] The adsorbent supported on the honeycomb structure 1 may be any material capable of adsorbing VOCs contained in the gas to be treated, and examples of such materials include zeolite, activated carbon, and silica. The gas to be treated is, for example, a gas containing VOCs generated by processes such as cleaning, printing, painting, and drying in a factory. The present invention is not limited by the type of VOCs to be removed or the type of adsorbent.

[0017] A catalyst for decomposing VOCs may be supported on the honeycomb structure 1. For example, platinum, palladium, or the like can be used as the catalyst for decomposing VOCs.

[0018] 1 and 2, the VOC adsorption rotor 10 is provided with an adsorption zone Z1, a desorption zone Z2, and a cooling zone Z3 along the rotation direction. The range of the adsorption zone Z1 in the rotation direction is, for example, from 230° to 270°, the range of the desorption zone Z2 is, for example, from 30° to 60°, and the range of the cooling zone Z3 is, for example, from 30° to 60°.

[0019] The adsorption zone Z1 is a region through which the gas to be treated passes to adsorb VOCs contained in the gas to be treated. In this embodiment, the gas to be treated is blown by a first blower 41.

[0020] The desorption zone Z2 is a region for desorbing the VOCs adsorbed in the adsorption zone Z1. In the present invention, as will be described later, an electric current is passed through the honeycomb structure 1, and the honeycomb structure 1 is heated and gas is passed through the honeycomb structure 1 to desorb the VOCs. The gas passed through the desorption zone Z2 may be unheated gas, but it is preferable to use heated gas to more effectively desorb the VOCs. Here, the description will be given assuming that heated gas is passed through the desorption zone Z2. That is, in the VOC removal device 100 shown in FIG. 1, the gas blown by the second blower 42 is heated by a heating device 44 such as a heater and then sent to the desorption zone Z2.

[0021] The cooling zone Z3 is a region for cooling the honeycomb structure 1 heated in the desorption zone Z2. In this embodiment, a third air blower 43 blows gas for cooling the honeycomb structure 1 into the cooling zone Z3.

[0022] The gas from which VOCs have been removed by passing through the adsorption zone Z1 may be returned to the source of the gas to be treated. Also, the gas warmed by passing through the cooling zone Z3 may be used as the gas to be passed through the desorption zone Z2.

[0023] 2, when the VOC adsorption rotor 10 rotates counterclockwise, the cells 2 located in the adsorption zone Z1 move sequentially to the desorption zone Z2 and the cooling zone Z3, and then return to the adsorption zone Z1. The honeycomb structure 1 is cooled in the cooling zone Z3, which enables it to adsorb VOCs again in the adsorption zone Z1.

[0024] That is, as the VOC adsorption rotor 10 rotates, the VOCs contained in the gas to be treated are repeatedly adsorbed and desorbed. If a catalyst for decomposing VOCs is supported on the honeycomb structure 1, a VOC decomposition reaction occurs in the desorption zone Z2. However, since the decomposition of VOCs can be considered to result in the desorption of adsorbed VOCs, the decomposition of VOCs is considered to be included in the desorption of VOCs. The rotation speed of the VOC adsorption rotor 10 is, for example, 8.4 rph or more and 11.0 rph or less.

[0025] The VOC removal method in this embodiment includes the steps of passing a gas to be treated through adsorption zone Z1 to adsorb VOCs contained in the gas to be treated, passing the gas through desorption zone Z2 to desorb the VOCs adsorbed in adsorption zone Z1, and cooling the honeycomb structure 1 heated in desorption zone Z2 in cooling zone Z3. In desorption zone Z2, the honeycomb structure 1 is heated by passing an electric current through the honeycomb structure 1 made of metal. Since Joule heat is generated by passing an electric current through the honeycomb structure 1, the honeycomb structure 1 can be directly heated in desorption zone Z2. This reduces the amount of energy required to desorb VOCs in desorption zone Z2.

[0026] In other words, the VOC removal method in this embodiment has better heating efficiency and is capable of desorbing VOCs adsorbed on the VOC adsorption rotor 10 with high energy efficiency compared to conventional methods in which VOCs adsorbed on the honeycomb structure 1 are desorbed by simply passing heated gas through the desorption zone Z2.

[0027] Furthermore, when an electric current is passed through the honeycomb structure 1 to heat the honeycomb structure 1 and pass the heated gas through the desorption zone Z2, it is possible to lower the heating temperature of the gas passing through the desorption zone Z2, for example, compared to the conventional method described above.

[0028] In order to pass a current through the honeycomb structure 1 in the desorption zone Z2, for example, a voltage may be applied to the honeycomb structure 1 in the desorption zone Z2. In this case, a voltage may be applied to the honeycomb structure 1 in the desorption zone Z2 from both outer sides in the extension direction of the rotation shaft 11 of the VOC adsorption rotor 10. Hereinafter, a method of applying a voltage to the honeycomb structure 1 in the desorption zone Z2 from both outer sides in the extension direction of the rotation shaft 11 of the VOC adsorption rotor 10 in the voltage application device 100 shown in FIG. 1 will be described.

[0029] The pair of electrodes 20a, 20b are arranged on both outer sides of the VOC adsorption rotor 10 in the extension direction of the rotation shaft 11 of the VOC adsorption rotor 10, in positions where they are in contact with the VOC adsorption rotor 10. The pair of electrodes 20a, 20b are preferably arranged in opposite positions in the extension direction of the rotation shaft 11. Of the adsorption zone Z1, desorption zone Z2, and cooling zone Z3 provided in the VOC adsorption rotor 10, the pair of electrodes 20a, 20b are arranged in the desorption zone Z2. More specifically, as shown in Figures 1 and 2, the pair of electrodes 20a, 20b are arranged in a position in the desorption zone Z2 close to the adsorption zone Z1.

[0030] The pair of electrodes 20a, 20b are made of, for example, graphite, but the material of the pair of electrodes 20a, 20b is not limited to graphite, and metals such as copper may also be used.

[0031] In this embodiment, the pair of electrodes 20a, 20b each have a shape that extends in the radial direction of the VOC adsorption rotor 10. Because the pair of electrodes 20a, 20b have a shape that extends in the radial direction, when a voltage is applied to the pair of electrodes 20a, 20b by a voltage application device 30 described later, a wide area in the radial direction of the honeycomb structure 1 can be heated. In addition, as shown in Figures 1 and 2, because the pair of electrodes 20a, 20b have an elongated shape, they do not hinder the heated gas when it passes through the desorption zone Z2.

[0032] However, the shapes of the pair of electrodes 20a, 20b are not limited to those shown in Figures 1 and 2. For example, the pair of electrodes 20a, 20b may be roller-shaped, with the surface that comes into contact with the VOC adsorption rotor 10 being the rotating surface.

[0033] As described above, the pair of electrodes 20a, 20b are positioned so as to come into contact with the VOC adsorption rotor 10. Therefore, the VOC adsorption rotor 10 rotates while maintaining contact with the pair of electrodes 20a, 20b while rubbing against them.

[0034] The voltage application device 30 is capable of applying a voltage to the pair of electrodes 20a, 20b. The voltage application device 30 applies a voltage to the pair of electrodes 20a, 20b so that the output is, for example, 2 kW or more and 10 kW or less. By the voltage application device 30 applying a voltage to the pair of electrodes 20a, 20b, a current can be passed through the honeycomb structure 1 made of metal in the desorption zone Z2, and the honeycomb structure 1 can be directly heated.

[0035] As described above, by applying a voltage to the honeycomb structure 1 in the desorption zone Z2 from both outer sides in the extension direction of the rotation shaft 11 of the VOC adsorption rotor 10, the honeycomb structure 1 can be efficiently heated in the extension direction of the rotation shaft 11. Furthermore, by applying a voltage to a pair of electrodes 20a, 20b arranged in contact with the VOC adsorption rotor 10 on both outer sides in the extension direction of the rotation shaft 11, the voltage can be easily applied to the VOC adsorption rotor 10 from both outer sides in the extension direction of the rotation shaft 11.

[0036] The present invention is not limited to the above-described embodiment, and various applications and modifications can be made within the scope of the present invention. For example, although the application of a voltage to the honeycomb structure 1 has been given as an example of a method for passing a current through the honeycomb structure 1 made of metal in the desorption zone Z2, a current may be passed through another method.

[0037] In the above-described embodiment, an example was given in which a voltage is applied to the honeycomb structure 1 in the desorption zone Z2 from both outside sides in the extension direction of the rotation axis 11 of the VOC adsorption rotor 10, but a voltage may also be applied to another position of the honeycomb structure 1 in the desorption zone Z2.

[0038] In the above-described embodiment, the honeycomb structure 1 is cooled in the cooling zone Z3 by passing a gas for cooling the honeycomb structure 1 through the cooling zone Z3, but the honeycomb structure 1 may also be cooled in the cooling zone Z3 by another method.

[0039] In the above-described VOC removal device 100, the pair of electrodes 20a, 20b arranged in the desorption zone Z2 has been described as one set, but multiple sets may be arranged and voltage may be applied to the multiple sets of electrodes. In this case, it becomes possible to heat a wide area of ​​the honeycomb structure 1 in the desorption zone Z2 at one time. [Explanation of symbols]

[0040] 1 Honeycomb structure 2 cells 10 VOC adsorption rotors 11 Rotation axis 20a, 20b Pair of electrodes 30 Voltage application device 41 First blower 42 Second blower 43 Third air blower 44 Heating device 100 VOC removal equipment Z1 adsorption zone Z2 Desorption Zone Z3 Cooling Zone

Claims

1. A VOC removal method using a VOC adsorption rotor having a honeycomb structure supporting an adsorbent for adsorbing VOCs, and having an adsorption zone, a desorption zone, and a cooling zone provided along the rotation direction, comprising: a gas to be treated is passed through the adsorption zone of the VOC adsorption rotor to adsorb the VOCs contained in the gas to be treated, the gas is passed through the desorption zone to desorb the VOCs adsorbed in the adsorption zone, and the honeycomb structure heated in the desorption zone is cooled in the cooling zone; A VOC removal method characterized by applying a voltage to the honeycomb structure in the desorption zone from both outsides in the extension direction of the rotation axis of the VOC adsorption rotor, and heating the honeycomb structure by passing an electric current through the honeycomb structure made of metal.

2. The VOC removal method described in claim 1, characterized in that a voltage is applied to a pair of electrodes arranged in contact with the VOC adsorption rotor on both outer sides of the extension direction of the rotation axis of the VOC adsorption rotor.

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