Fragrance Composition
A fragrance composition with ethanol, volatile perfume raw materials, and modulating agents adjusts vapor pressures to stabilize fragrance characteristics, addressing rapid evaporation issues and enhancing longevity and intensity.
Patent Information
- Application Number
- JP2021539391
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2019-10-07
- Filing Date
- 2020-05-15
- Publication Date
- 2026-02-25
- Estimated Expiration
- 2040-05-15
AI Technical Summary
Fragrance compositions with high volatility ingredients rapidly evaporate, leading to a decline in perceived fragrance intensity and profile over time, particularly in products like eau de toilette and body splashes, making it difficult to maintain fragrance characteristics for extended periods.
A fragrance composition comprising ethanol (30-75% by weight), highly volatile (0.08-0.0008 Torr) and medium-volatile (0.0008-0.08 Torr) perfume raw materials, and a modulating agent that adjusts vapor pressures to enhance fragrance retention, using Hansen solubility parameters to select compatible modifiers.
The composition extends fragrance perception for several hours, maintaining intensity and profile, and allows for new fragrance profiles by stabilizing volatile components, enhancing consumer satisfaction.
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Abstract
Description
[Technical Field]
[0001] The present disclosure relates to the field of fragrances. In particular, the present disclosure provides compositions with increased and / or improved long-lasting properties and / or fragrance profiles. Furthermore, the present disclosure provides methods for increasing and / or improving the long-lasting properties and / or fragrance profiles of fragrance compositions using such compositions. [Background technology]
[0002] The fragrance industry is constantly seeking new techniques to extend the perception of fragrances over time. This need is particularly pronounced when dealing with fragrances rich in highly volatile fragrance ingredients that evaporate so rapidly that the perceived fragrance intensity and / or fragrance profile of the fragrance diminishes and / or changes over time. This perceived decline and / or change is further exacerbated by the rapid evaporation of ethanol, which is present in large amounts in fragrances, "eau de toilette" (colognes), and body splashes. Maintaining intensity and / or profile over time is one of the important considerations for commercial fragrance compositions. In fact, consumers desire fragrance compositions that last all day. For example, it is generally accepted that a fragrance composition must maintain good intensity and / or fragrance profile for at least 8 hours to meet this consumer need, and a major challenge is maintaining the intensity of highly volatile fragrance ingredients.
[0003] A perfumer selects fragrance ingredients to blend into a fragrance composition with the goal of achieving a particular fragrance profile of intensity and character. In doing so, the perfumer must take into account the individual properties and volatility differences of the fragrance ingredients that make up the complete fragrance composition. Traditional fragrance compositions have fragrance profiles characterized by a greater amount of low-volatility fragrance ingredients and a lesser amount of more volatile fragrance ingredients. The low-volatility fragrance ingredients are known as "base notes," while the more volatile fragrance ingredients can be further divided into high-volatility fragrance ingredients identified as "top notes or head notes" and medium-volatility fragrance ingredients identified as "middle notes or heart notes."
[0004] The difference in volatility of the perfuming ingredients used to formulate a fragrance composition can lead to some limitations. For example, a common complaint by consumers is that middle notes tend to disappear too quickly after application of the fragrance composition. Furthermore, the character of the middle notes can be undesirably altered by the presence of large amounts of base notes during a period known as the "dry-down" phase.
[0005] It is therefore desirable for a fragrance composition to retain a significant portion of its initial fragrance characteristics over time, so that the floral, fruity, or spicy characteristics of the "heart note" are perceived for hours. It is also desirable for the fragrance composition's fragrance intensity to remain perceptible to the consumer for an extended period of time. It is also desirable to be able to create entirely new fragrance profiles in which one or more well-recognized heart note characteristics are maintained over time.
[0006] Thus, there remains a need for compositions that are perceived by consumers for extended periods of time after application. There is also a need for compositions that exhibit improved intensity of fragrance profile over time.
[0007] Summary of the Invention One aspect presented herein is a composition comprising: a. ethanol in an amount of 30 to 75% by weight based on the total weight of the composition; b. a fragrance ingredient present in an amount of 0.04 to 40% by weight based on the total weight of the composition, i. a. at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C, and optionally b. at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C; Highly volatile components in an amount of 0.08 to 55% by weight of the fragrance ingredients, including ii. The following a. a first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C, and optionally b. at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C; and a medium-volatile component in an amount of 0.08 to 85% by weight of the fragrance component. and a fragrance ingredient comprising: c. at least one regulator in an amount of 0.1 to 50% by weight based on the total weight of the composition; Including, a first vapor pressure of at least one first perfume raw material of the highly volatile component is determined without the at least one modifier; a first vapor pressure of at least one second perfume raw material of the highly volatile component is determined without the at least one modifier; at least one modulating agent changes the first vapor pressure of at least one second perfume raw material of the high volatility component to a second vapor pressure; a second vapor pressure of the at least one second fragrance ingredient that is a highly volatile component in the range of 0.0008 to 0.08 Torr at 22°C; a first vapor pressure range of at least one first perfume raw material of a medium volatility component is determined without the at least one modifier; a first vapor pressure range of at least one second perfume raw material of medium volatility components is determined without the at least one modifier; at least one modifier changes the first vapor pressure range of at least one second perfume raw material of the medium volatility component to a second vapor pressure; and the second vapor pressure of the at least one second fragrance raw material that is a medium-volatility component is less than 0.0008 Torr at 22°C; A composition is provided.
[0008] In one embodiment, the fragrance component is present in an amount of 0.04 to 20% by weight, based on the total weight of the composition.
[0009] In one embodiment, the composition further comprises water in an amount of 15% by weight or less, based on the total weight of the composition.
[0010] In one embodiment, the composition further comprises water in an amount of 5 to 15% by weight, based on the total weight of the composition.
[0011] In one embodiment, the composition further comprises water in an amount of 0 to 5% by weight, based on the total weight of the composition.
[0012] In one embodiment, the at least one modulating agent is i. A vapor pressure of less than 0.0008 Torr at 22°C; ii. For dissolution in compounds with vapor pressures greater than 0.08 Torr at 22°C, atomic dispersion forces (δ d ), dipole moments 1-7 (δ p ), and 2.5 to 11 hydrogen bonds (δ h At least two Hansen solubility parameters selected from the first group consisting of iii. For dissolution in compounds with vapor pressures ranging from 0.0008 to 0.08 Torr at 22°C, atomic dispersion forces (δ d ), dipole moments 1 to 8 (δ p ), and 4–11 hydrogen bonds (δ h At least two Hansen solubility parameters selected from a second group consisting of The compound includes a compound having the formula:
[0013] In one embodiment, the first group has an atomic dispersion force (δ) of 15.84±3.56 when dissolved in a compound having a vapor pressure greater than 0.08 Torr at 22° C. d ), dipole moment (δ p ), and 6.72 ± 4.11 hydrogen bonds (δ h ) at least two Hansen solubility parameters selected from the group consisting of:
[0014] In one embodiment, the second group has an atomic dispersion force (δ) of 16.86±2.72 when dissolved in compounds having a vapor pressure range of 0.0008 to 0.08 Torr at 22° C. d ), dipole moment (δ p ), and 7.66 ± 3.29 hydrogen bonds (δ h ) at least two Hansen solubility parameters selected from the group consisting of:
[0015] In one embodiment, the at least one modulator is selected from the compounds listed in Table 9.
[0016] In one embodiment, at least one modifier has an odor value of 1 to 10,000.
[0017] In one embodiment, the at least one regulator has a C between 0.1 and 10 μg / l I2.5 It has.
[0018] In one embodiment, the composition further comprises at least one hydrophilic solvent. In one embodiment, the at least one hydrophilic solvent is selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, triethyl citrate, diisopropyl glycol monomethyl ether, diethylene glycol monoethyl ether, triacetin, methyl methoxybutanol, benzyl alcohol, propylene glycol n-butyl ether, glycol ethers, esters of diethylene glycol, and cellosolve derivatives. In one embodiment, the glycol ether is the glycol ether sold under the trade name DOWANOL. In one embodiment, the ether of diethylene glycol is sold under the trade name CARBITOL.
[0019] In one embodiment, glycol ethers sold under the trade name DOWANOL include DOWANOL™ DPMA Glycol Ether; DOWANOL™ PM Glycol Ether; DOWANOL EPH ELP; DOWANOL™ EPh; DOWANOL™ PnB Glycol Ether; DOWANOL™ TPnB; DOWANOL™ DPnB Glycol Ether; DOWANOL™ TPM Glycol Ether; DOWANOL™ PPh Glycol Ether; DOWANOL™ PnP Glycol Ether; DOWANOL™ DPH 255 Glycol Ether; DOWANOL™ PGDA Glycol Ether; DOWANOL™ DPM Glycol Ether; DOWANOL™ TPnB-H Glycol Ether; DOWANOL™ Solvents for Home & Personal Care; DOWANOL™ DPnP Glycol Ether; DOWANOL™ PMA Glycol Ether; DOWANOL™ DiPPh Glycol Ether.
[0020] In one embodiment, the cellosolve derivative is selected from the group consisting of propyl cellosolve, butyl cellosolve, hexyl cellosolve, and cellosolve.
[0021] In one embodiment, the highly volatile component consists solely of at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C.
[0022] In one embodiment, the medium-volatility component consists solely of at least one first perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C.
[0023] In one embodiment, the highly volatile component comprises at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C in an amount of 0.1 to 40% by weight of the fragrance ingredients.
[0024] In one embodiment, the medium-volatility component comprises at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C in an amount of 20 to 45% by weight of the fragrance component.
[0025] In one embodiment, the fragrance ingredients further comprise at least one perfume raw material having a first vapor pressure of less than 0.0008 Torr at 22° C. in an amount of 10-55% by weight of the fragrance ingredients.
[0026] In one embodiment, the fragrance ingredients further comprise at least one perfume raw material having a first vapor pressure of less than 0.0008 Torr at 22° C. in an amount of 30-55% by weight of the fragrance ingredients.
[0027] In one embodiment, the fragrance ingredients further comprise at least one perfume raw material having a first vapor pressure of less than 0.0008 Torr at 22° C. in an amount of 10-30% by weight of the fragrance ingredients.
[0028] One aspect presented herein provides a perfumed consumer product comprising a composition according to an aspect presented herein.
[0029] One aspect presented herein provides a perfume composition comprising a composition according to an aspect presented herein.
[0030] One aspect presented herein provides a perfumed consumer product comprising a perfume composition according to an aspect presented herein.
[0031] In one aspect, the perfumed consumer product is selected from the group consisting of a fragrance, an eau de toilette, a home care product, and a personal care product.
[0032] One aspect presented herein provides a method for modifying or enhancing the odor characteristics of a body surface, such as hair or skin, comprising contacting or treating the body surface with a composition according to an aspect presented herein.
[0033] One aspect presented herein provides a method for modifying or enhancing the odor characteristics of substrates such as fabrics, furniture, tableware, hard surfaces, and related materials, comprising contacting or treating the body surface with a composition according to an aspect presented herein. [Brief explanation of the drawings]
[0034] While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed the present invention will be better understood from the following description of the accompanying drawings. [Figure 1] A graphical representation of conventional perfume structures is shown. [Figure 2] The figure shows a representation of the Hansen space defined in three directions by three Hansen solubility parameters, where R0 is the radius of the solubility sphere characteristic of the solute, and Ra is the distance between the solute solubility parameter (center of the solubility sphere) and the solvent solubility parameter. [Figure 3]1 shows the effect of modifiers on the amount of perfume raw material in solution over time. The solid line represents the ratio of the actual recorded value of the amount of perfume raw material (APRM) to the amount of internal standard (AINSTD) with 15% by weight of modifier (a15) or without modifier (a0) relative to the total weight of the composition. The dashed line represents the predicted ratio over time for solutions containing either 5% by weight of modifier (a5) relative to the total weight of the composition or 10% by weight of modifier (a10) relative to the total weight of the composition. [Figure 4] 1 shows a graphical representation of perfume structures according to some embodiments presented herein. [Figure 5] Illustrated are compounds suitable for use as at least one modulator according to some embodiments described herein. [Figure 6] The second represents a perfume raw material whose vapor pressure is different in a modifier comprising 15 wt. % PPG-20 methyl glucose ether ("MGE") relative to the total weight of the composition compared to a modifier comprising 10 wt. % PPG-20 methyl glucose ether and 5 wt. % isocetyl alcohol ("ICA"). [Figure 7] 1 shows the effect of either HEDIONE or IPM on the retention of fragrance components of samples over time. [Figure 8a] Figure 1 shows the effect of either HEDIONE or IPM on the amount of various perfume ingredients released into the headspace after 1 hour of dry down. [Figure 8b] Figure 1 shows the effect of either HEDIONE or IPM on the amount of various perfume ingredients released into the headspace after a 4 hour dry down. [Figure 8c] Figure 1 shows the effect of either HEDIONE or IPM on the amount of various perfume ingredients released into the headspace after 6 hours of dry down. [Figure 9a] Shows the effect of either HEDIONE or benzyl salicylate on fragrance retention of samples over time after 1 hour dry down. [Figure 9b]Shows the effect of either HEDIONE or benzyl salicylate on fragrance retention of samples over time after 4 hours dry down. [Figure 10] Figure 1 shows the effect of either HEDIONE or benzyl salicylate on fragrance retention over time for samples after 0, 1, and 4 hours of drydown, respectively. [Figure 11a] Shows the effect of either HEDIONE or benzyl salicylate on fragrance retention of samples over time after 1 hour dry down. [Figure 11b] Shows the effect of either HEDIONE or benzyl salicylate on fragrance retention of samples over time after 4 hours dry down. [Figure 12] Figure 1 shows the effect of either HEDIONE or benzyl salicylate on fragrance retention over time for samples after 0, 1, and 4 hours of drydown, respectively. DETAILED DESCRIPTION OF THE INVENTION
[0035] In the following description, reference is made to specific possible embodiments, which are shown by way of example. These embodiments are described in detail to enable those skilled in the art to practice the inventions described herein, and it is to be understood that other embodiments may be used and logical changes may be made without departing from the scope of the aspects presented herein. Therefore, the following description of exemplary embodiments should not be taken in a limiting sense, and the scope of the various aspects presented herein is defined by the appended claims.
[0036] The Abstract is drafted to comply with 37 C.FR § 1.72(b) to allow the reader to quickly ascertain the nature and gist of the technical disclosure. The Abstract is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
[0037] Compositions according to some embodiments presented herein: The terms "fragrance" and "perfume" are used interchangeably herein to refer to ingredients in fragrance compositions formed from perfuming ingredients, i.e., ingredients capable of imparting or modifying the odor of skin or hair.
[0038] As used herein, "perfuming ingredient" refers to a compound currently used in perfumery that, alone or in admixture with other such ingredients, emits a pleasant odor and is used substantially for its ability to impart a hedonic effect or a pleasant odor to a product into which it is incorporated or to a surface, such as skin or hair, to which it is applied. In other words, a perfuming ingredient has the ability to impart or modify the odor of a composition or surface in a positive or pleasant way. If the latter has a malodor, the perfuming ingredient may also be able to mask such a malodor so as to make the overall perceived odor pleasant.
[0039] "Perfume ingredient" refers to any suitable perfume raw material for fragrance applications, including, for example, alcohols, aldehydes, ketones, esters, ethers, acetates, nitriles, terpene hydrocarbons, nitrogen- or sulfur-containing heterocyclic compounds, and materials such as essential oils. However, naturally occurring plant and animal oils and exudates, which contain complex mixtures of various chemical components, are also known for use as "perfume ingredient(s)." Individual perfume raw materials, including known natural oils, can be found by consulting journals commonly used by those skilled in the art, such as "Perfume and Flavorist" or "Journal of Essential Oil Research," or may be listed in reference works such as the book "Perfume and Flavor Chemicals" by S. Arctander, 1969, Montclair, New Jersey, USA, more recently republished by Allured Publishing Corporation, Illinois (1994). Additionally, some perfume raw materials are supplied by fragrance houses as mixtures in the form of their own specialty accords. Non-limiting examples of perfuming ingredients useful herein include fragrances such as acetal fragrances, ketal fragrances, ester fragrances, hydrolyzable inorganic-organic fragrances, and mixtures thereof.Perfuming ingredients can be released from the fragrances in many ways.For example, but not limited to, the fragrance can be released as a result of simple hydrolysis, by shifting equilibrium reactions, by pH changes, or by enzyme release.
[0040] As used herein, the term "fragrance profile" refers to a description of how a fragrance, as perceived by the human nose, changes over time from its initial application. It is the result of combining the top, middle, and base notes of a fragrance, if present. A fragrance profile is composed of two characteristics: "intensity" and "character." "Intensity" relates to the perceived strength, while "character" refers to the olfactory impression or quality of the fragrance, i.e., fruity, floral, woody, etc.
[0041] Herein, a "modifier" or "fixer" is understood to be an agent capable of influencing the way an observer or user perceives the odor of a composition incorporating the modifier or fixer over time, particularly its evaporation rate and intensity, compared to the same perception without the modifier or fixer.
[0042] As used herein, the terms "include," "includes," and "including" are meant to be open-ended.
[0043] Referring to Figure 1, conventional fragrance compositions have a fragrance profile characterized by a greater amount of low-volatility fragrance ingredients and a lesser amount of more volatile fragrance ingredients. The low-volatility fragrance ingredients are known as "base notes," while the more volatile fragrance ingredients can be further divided into high-volatility fragrance ingredients identified as "top notes or head notes" and medium-volatility fragrance ingredients identified as "middle notes or heart notes."
[0044] Without intending to be limited to a particular theory, top notes tend to have a citrus, green, light, or fresh odor and typically comprise about 0.1% to 40% by weight of the total weight of a fragrance composition. Due to their high volatility, top notes tend to evaporate quickly, characterized by a vapor pressure of greater than 0.08 Torr at 22°C (calculated using Advanced Chemistry Development (ACD / Labs) Software VI 1.02 (Copyright 1994-2013 ACD / Labs)). Typically, perfumers use top notes to provide the initial impression of a composition, but do not rely on them to significantly contribute to its overall fragrance profile over time after application.
[0045] The middle or heart note comprises about 0.1% to about 40% by weight of the total weight of the fragrance composition. Typically, the middle / heart note becomes dominant to the untrained nose within a few minutes of application and can persist for up to several hours. The middle / heart note is associated with floral aromas (e.g., jasmine, rose), fruity, aromatic, marine, or spicy aromas and has a moderate volatility with a vapor pressure range of 0.0008 to 0.08 Torr at 22°C.
[0046] Base notes or bottom notes may be present in an amount greater than 30% by weight based on the total weight of the fragrance formulation. Alternatively, base notes may be present in an amount of about 45% to about 80% by weight based on the total weight of the fragrance formulation. Base notes are characterized by animalic, woody, sweet, amber, or musky notes, and are not very volatile, having a vapor pressure of less than 0.0008 Torr at 22°C. Typically, base notes are not perceived as dominant until several hours after application of the fragrance composition, or during "dry-down." Base notes may be based on improving the intensity of the overall fragrance profile over time and replacing heart notes as they diminish. When used at high levels, base notes impart specific odor characteristics, such as musky, woody, amber, warm, and sweet, that become stronger and more dominant in the fragrance's character over time. Some of these base notes are so common (e.g., hedione, galaxolide) that many fragrance drydowns appear repetitive, boring, unmemorable, and uninteresting to consumers. However, when base notes are reduced or eliminated, the fragrance loses intensity over time and does not last for a sufficient duration.
[0047] As used herein, the term "vapor pressure" refers to the partial pressure of a given chemical species in air at a defined temperature. It defines the degree to which a chemical species tends to be in the gas phase rather than in a liquid or solid state. The higher the vapor pressure, the greater the proportion of the material found in a closed headspace at equilibrium. It is also related to the evaporation rate of the perfume ingredient, defined in the open environment in which the material leaves the system. In one embodiment, vapor pressure is determined according to the reference program Advanced Chemistry Development (ACD / Labs) Software Version 11.02, (Copyright 1994-2013). An example of a suitable method for determining vapor pressure is disclosed in International Patent Application Publication No. 2015 / 089246.
[0048] As used herein, the term "impact" refers to the potency or intensity of a perfume ingredient in the first moments of product performance. For example, the top note may be perceived immediately after sniffing the perfume bottle or a few seconds after applying the product to the skin.
[0049] As used herein, the term "diffusion" is a measure of the distance over which a fragrance or perfume ingredient is perceptible immediately after application; high diffusion is desired, for example, in bath foam or dish detergent.
[0050] As used herein, the term "clinginess" refers to the long-term availability of perfume ingredients in a perfumed product, such as on the skin after use of a perfume or toilet soap.
[0051] As used herein, the term "volume" refers to the availability of a perfume ingredient at a distance at a point in time after application.
[0052] In one aspect, the present invention provides a composition comprising a fragrance component present in an amount of from about 0.04% to 40% by weight, alternatively from 1% to about 40% by weight, alternatively less than about 25% by weight, alternatively less than about 20% by weight, alternatively less than about 15% by weight, alternatively less than about 10% by weight, alternatively less than about 8% by weight, based on the total weight of the composition. Alternatively, the fragrance component is present in an amount of from about 0.04%, 0.3%, 1%, 8%, or 10% to about 15%, 20%, 25%, 30%, or 40% by weight, based on the total weight of the composition.
[0053] As used herein, the term "composition" includes fine fragrance compositions intended to be applied to body surfaces, such as skin or hair, to impart a pleasant odor thereto or to mask a malodor. These are typically in the form of perfume concentrates, perfumes, eau de parfum, eau de toilette, aftershave, cologne, body splash, or body spray. Fine fragrance compositions may be ethanol-based compositions. The term "composition" may also include cosmetic compositions containing fragrance materials for the purpose of delivering a pleasant odor that promotes consumer acceptance of the cosmetic composition. The term "composition" may also include cleaning compositions, such as fabric care compositions or home care compositions, including air care compositions, for use on clothing or other substrates such as hard surfaces (e.g., dishes, floors, countertops). Further non-limiting examples of "compositions" may include facial or body powders, foundations, body / facial oils, mousses, creams (e.g., cold creams), waxes, sunscreens and blocks, bath and shower gels, lip balms, self-tanning compositions, masks, and patches. Further non-limiting illustrative examples are set forth below.
[0054] As used herein, the term "consumer" refers to both the user of the composition and observers near or around the user.
[0055] One aspect presented herein is a composition comprising: a. ethanol in an amount of 30 to 75% by weight based on the total weight of the composition; b. a fragrance ingredient present in an amount of 0.04 to 40% by weight based on the total weight of the composition, i. a. at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C, and optionally b. at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C; Highly volatile components in an amount of 0.08 to 55% by weight of the fragrance ingredients, including ii. The following a. a first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C, and optionally b. at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C; and a medium-volatile component in an amount of 0.08 to 85% by weight of the fragrance component. and a fragrance ingredient comprising: c. at least one regulator in an amount of 0.1 to 50% by weight based on the total weight of the composition; Including, a first vapor pressure of at least one first perfume raw material of the highly volatile component is determined without the at least one modifier; a first vapor pressure of at least one second perfume raw material of the highly volatile component is determined without the at least one modifier; at least one modulating agent changes the first vapor pressure of at least one second perfume raw material of the high volatility component to a second vapor pressure; a second vapor pressure of the at least one second fragrance ingredient that is a highly volatile component in the range of 0.0008 to 0.08 Torr at 22°C; a first vapor pressure range of at least one first perfume raw material of a medium volatility component is determined without the at least one modifier; a first vapor pressure range of at least one second perfume raw material of medium volatility components is determined without the at least one modifier; at least one modifier changes the first vapor pressure range of at least one second perfume raw material of the medium volatility component to a second vapor pressure; and the second vapor pressure of the at least one second fragrance raw material that is a medium-volatility component is less than 0.0008 Torr at 22°C; A composition is provided.
[0056] In some embodiments, the fragrance component is present in an amount of 0.04 to 20% by weight, based on the total weight of the composition.
[0057] In some embodiments, the composition further comprises water in an amount of 15% by weight or less, based on the total weight of the composition.
[0058] In some embodiments, the composition further comprises water in an amount of 5-15% by weight, based on the total weight of the composition.
[0059] In some embodiments, the composition further comprises water in an amount of 0-5% by weight, based on the total weight of the composition.
[0060] In another embodiment, water may be present in any of the compositions provided; more specifically, water should not exceed about 15% by weight, alternatively about 14% by weight or less, alternatively about 13% by weight or less, alternatively about 12% by weight or less, alternatively about 11% by weight or less, alternatively about 10% by weight or less, alternatively about 9% by weight or less, alternatively about 8% by weight or less, alternatively about 7% by weight or less, alternatively about 6% by weight or less, alternatively about 5% by weight or less, alternatively about 4% by weight or less, alternatively about 3% by weight or less, alternatively about 2% by weight or less, alternatively about 1% by weight or less, based on the total weight of the composition. Alternatively, water may be present in an amount of about 10% by weight or 20% to about 40% by weight, based on the total weight of the composition. If the composition is a cosmetic composition, the water level should not be so high that the product becomes cloudy, adversely affecting the aesthetics of the product. It is understood that the amount of water present in the composition may, in some cases, be derived from water present in the ethanol used in the composition.
[0061] The compositions according to the embodiments presented herein comprise a fragrance component and at least one modifier. i. highly volatile ingredients, including at least one fragrance ingredient, having a vapor pressure greater than 0.08 Torr at 22°C; and ii. Mid-volatile ingredients including at least one fragrance ingredient with a vapor pressure range of 0.0008 to 0.08 Torr at 22°C Includes:
[0062] The fragrance ingredients may also further comprise low volatility ingredients, including perfume raw materials having a vapor pressure of less than 0.0008 Torr at 22°C.
[0063] In some embodiments, the effect of at least one modifier on the fragrance profile, particularly on the portion of the fragrance profile that is derived from volatile fragrance materials (i.e., the top and middle notes), may be improved. By "improved," it is meant that the fragrance characteristics of the composition, particularly the fragrance characteristics of the components that are derived from volatile fragrance materials, can be perceived by the consumer at later times, such as 2 hours, 4 hours, 6 hours, 8 hours, 10 hours, or even up to 24 hours, after application, compared to a control, i.e., a conventional composition, or a composition in which the fragrance components are derived from high-volatility components, including perfume raw materials having a vapor pressure greater than 0.08 Torr at 22°C, and medium-volatility components having a vapor pressure range of 0.0008 to 0.08 Torr at 22°C, without the modifier.
[0064] Alternatively, "improved" can mean that the consumer's perception of the ingredients attributable to the volatile fragrance material is significantly increased or enhanced compared to a control. An "increased" or "enhanced" perception of a fragrance profile means that the consumer perceives the fragrance profile of the composition as unchanged from the initial impression, or that there is minimal change from when the composition is first applied to when it dissipates.
[0065] Alternatively, "improved" may mean that the perception of ingredients attributable to volatile fragrance materials may be perceived by the consumer during dry-down.
[0066] Generally, it is difficult to remove water from perfume compositions, such as eau de toilette, without adversely affecting the fragrance profile perceived by users.Without intending to be limited to a particular theory, for any given perfume raw material in a perfume composition, the perfume raw material forms an equilibrium between a liquid phase and a gas phase.When water is present, the equilibrium of the perfume raw material moves toward the gas phase, and therefore the concentration of the perfume raw material in the headspace increases.When water is removed, the concentration of the perfume raw material in the headspace decreases, and therefore the perception of the perfume raw material decreases.
[0067] The concentration of a perfume raw material in the headspace may be higher for a highly volatile perfume raw material compared to a less volatile perfume raw material. Furthermore, the perception of a fragrance raw material may be greater for a perfume raw material with a lower odor detection threshold compared to a perfume raw material with a higher odor detection threshold. However, the performance of a perfume composition may be adversely affected by using perfume raw materials with high volatility and / or low odor detection threshold to counteract the removal of water.
[0068] In some embodiments, the present application provides at least one modifier that allows for the removal of water from a perfume composition without adversely affecting the performance of the perfume composition.
[0069] Selection of perfume raw materials for formulating fragrance ingredients of compositions according to embodiments presented herein: In one embodiment, at least one modifier is selected according to its Hansen solubility parameter. Hansen solubility parameters can be used to predict whether a material will dissolve in another material to form a solution. Molecules are assigned three Hansen solubility parameters: δ d : Energy from intermolecular dispersion forces δ p : energy from dipolar intermolecular forces between molecules, and δ h : Energy from hydrogen bonds between molecules.
[0070] Referring to Figure 2, Hansen solubility parameters can be treated as the coordinates of a point in three dimensions, also known as Hansen space. Without intending to be limited to a particular theory, the closer two molecules are in Hansen space, the more likely they are to dissolve in each other.
[0071] In the case of fragrance mixtures, the simplest approach to calculate the Hansen Solubility Parameter (HSP) of a mixture is to assume an ideal mixture of compounds:
number
[0072] In the formula, φ1 is the volume fraction of the compound.
[0073] The Hansen Solubility Parameter (HSP) can be calculated. The ratio RED (Relative Energy Difference) is defined as:
number
[0074] In some embodiments, the ratio RED can be used to confirm the compatibility of at least one modifier with a particular perfume raw material. In one embodiment, the ratio RED of at least one modifier is less than or equal to 1. Without intending to be limited to a particular theory, when the ratio RED is less than or equal to 1, the particular perfume raw material is easily soluble in at least one modifier.
[0075] In one embodiment, in addition to the at least one modifier having a ratio RED of 1 or less, the at least one modifier has low volatility, where this low volatility is sufficient to ensure that the at least one modifier is present during the entire dry-down period of the perfume composition. In one embodiment, the at least one modifier has a vapor pressure of less than 0.0008 Torr at 22°C.
[0076] In one embodiment, in addition to at least one modifier having a ratio RED of 1 or less, the at least one modifier has a minimal olfactory contribution. In one embodiment, the olfactory contribution of the at least one modifier is defined by an odor detection threshold. In one embodiment, the at least one modifier has a high odor detection threshold. As used herein, the term "odor detection threshold" refers to the lowest concentration of a perfume raw material or modifier that can be perceived by the human sense of smell, expressed in μg / l.
[0077] In one embodiment, the olfactory contribution of at least one regulator is defined by odor value.As used herein, the term " odor value " or " OV " refers to the quotient of the volatility (Vol) of an odorant in saturated headspace and its ODT concentration threshold.Therefore, odor value is defined as a dimensionless number as shown in the following formula:
number
[0078] In one embodiment, the olfactory contribution of at least one regulator is defined by olfactory impact.As used herein, the term " olfactory impact " or " OI " refers to the quotient of the volatility (Vol) of an odorant in saturated headspace and its ODT concentration.Therefore, olfactory impact is defined as a dimensionless number as shown in the following formula:
number
number
[0079] The experimental points are fitted to a sigmoidal curve using nonlinear regression of the following form:
number
[0080] A sigmoid curve is defined by three parameters: max (asymptotic value for perceived intensity), Teta (logarithmic value of gas concentration corresponding to the inflection point of the curve), and the curve parameter CP. A fourth parameter, Slope, relates the tangent value at the Teta concentration by the following equation:
number
[0081] 3, the amount of a given perfume raw material in solution does not remain constant. Rather, the perfume raw material diffuses into the headspace, and the concentration of the perfume raw material in solution decreases over time. Without intending to be limited to a particular theory, a consumer will be able to detect and recognize the presence of a perfume raw material when the concentration of the perfume raw material exceeds a threshold concentration (referred to herein as the odor recognition threshold).
[0082] In Figure 3, the decrease in the concentration of the fragrance raw material in solution is proportional to the amount of internal standard (A INSTD Amount of fragrance raw material (A PRM In the absence of at least one modifier, the rate of decrease in concentration of a perfume raw material in solution has a first value (shown on the graph as the a0 line, and referred to herein as d(A PRM / A INSTD ) / dt 1 / 2 In some embodiments, the presence of at least one modifier changes the first value to a lower second value. In the example shown in Figure 3, at least one modifier having a concentration of 15 wt% based on the total weight of the composition changes d(A PRM / A INSTD ) / dt 1 / 2 the second value (a on the graph) 15(shown as a line). Thus, the presence of at least one modifier may delay the time during which a consumer may be able to detect and recognize the presence of a perfume raw material. Alternatively, the presence of at least one modifier may extend the period during which a consumer may be able to detect and recognize the presence of a perfume raw material. Alternatively, the presence of at least one modifier may prevent a consumer from detecting and recognizing the presence of a perfume raw material.
[0083] At least one regulator is d(A PRM / A INSTD ) / dt 1 / 2 The degree to which the at least one modifier affects the perfume composition will depend on various factors such as, for example, the concentration of the at least one modifier, the composition of the at least one modifier, the volatility of the perfume raw materials in the modifier, and the like.
[0084] In some embodiments, at least one modulating agent has a d(A PRM / A INSTD ) / dt 1 / 2 The degree to which the A is affected is determined by the change in A in the presence of a known concentration (e.g., 15% w / w) of at least one modifier over the square root of time. PRM / A INSTD The decrease in the rate of A at a second known concentration of at least one modifier (e.g., 0% w / w) over the square root of time is PRM / A INSTD This is determined by comparing the decrease in the ratio of
[0085] In some embodiments, at least one modulating agent is present at any modulating agent concentration (a x ) and d(A PRM / A INSTD ) / dt 1 / 2 The degree to which the effect is exerted is determined by the addition of a known concentration of at least one modifier (e.g., 15% w / w 15 d(A PRM / A INSTD ) / dt 1 / 2 at a second known concentration of at least one modulating agent (e.g., 0% w / w (a0)).PRM / A INSTD ) / dt 1 / 2 is determined by comparing it with
[0086] In some embodiments, a 15 and a0, and a x Calculate.
[0087] a x =a 15 +(a0-a 15 )(15-x) / (15-0) (Equation 8) In some cases, a 15 , a 10 , a5, or a0 can be used to predict the amount of perfume raw material present in solution at a given time.
[0088] In another embodiment, a x The square of the ratio / a0 can be used to calculate the second vapor pressure of the perfume raw material in the presence of x wt % of at least one modifier.
[0089] For example, illustratively using at least one modifier at a concentration of 15% by weight based on the total weight of the composition, the vapor pressure of the perfume raw material in the presence of the at least one modifier (referred to herein as the second vapor pressure of the perfume raw material) can be calculated as follows: (a 15 / a0) 2* P vap =P * vap. Equation (9) During the ceremony, P vap = the first vapor pressure of the fragrance ingredient P * vap = Second vapor pressure of fragrance ingredients Thus, the present disclosure provides a method for predicting how at least one modifier can delay the time during which a consumer can detect and recognize the presence of a perfume raw material. Alternatively, the present disclosure provides a method for predicting how at least one modifier can extend the period during which a consumer can detect and recognize the presence of a perfume raw material. Alternatively, the present disclosure provides a method for predicting how at least one modifier can inhibit a consumer from detecting and recognizing the presence of a perfume raw material. Without intending to be limited to a particular theory, the second vapor pressure of a perfume raw material may be a factor that can predict how a modifier can alter a consumer's perception of a perfume raw material in the above-described manner.
[0090] Thus, the present disclosure provides a method for calculating the second vapor pressure of a given perfume raw material in the presence of a given concentration of at least one modifier.
[0091] Thus, the present disclosure provides a method for ascertaining the second vapor pressure of a perfume raw material for any modifier and / or any concentration of modifier. Further, based on the second vapor pressure, the present disclosure provides a method for determining whether a particular perfume raw material, in the presence of at least one modifier: i. remain available for selection for use in highly volatile ingredients, where the second vapor pressure of the perfume raw material is greater than 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 1); ii. no longer remains available for selection for use in the high volatility component, but becomes available for selection for use in the medium volatility component, where the second vapor pressure of the fragrance raw material is in the range of 0.0008 to 0.08 Torr at 22°C (examples of suitable fragrance raw materials are shown in Table 2); iii. remain available for selection for use in medium volatility ingredients, where the second vapor pressure of the fragrance raw material is in the range of 0.0008 to 0.08 Torr at 22°C (examples of suitable fragrance raw materials are shown in Table 3); iv. no longer remains available for selection for use in medium volatility ingredients, but becomes available for selection for use in low volatility ingredients, where the perfume raw material has a second vapor pressure of less than 0.0008 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 4), or v. Remain available for selection for use in low volatility ingredients, where the second vapor pressure of the fragrance raw material is less than 0.0008 Torr at 22°C (examples of suitable fragrance raw materials are shown in Table 5). The present invention provides a method for classifying a palette of perfume raw materials based on specific modifiers and modifier concentrations according to either
[0092] In some embodiments, the perfume raw material may no longer remain available for selection for use in the medium-volatility component because the perfume raw material may be suppressed (i.e., not perceived by the consumer) in the presence of the modifier. Examples of suitable perfume raw materials are shown in Table 6.
[0093] In some embodiments, the perfume raw materials remain available for selection for use in low volatility ingredients, and the perfume raw materials may be suppressed (i.e., not perceived by the consumer) in the presence of the modifier. Examples of suitable perfume raw materials are shown in Table 7.
[0094] Further examples of suitable classified perfume raw materials can be found in Examples 1 and 2 and the tables listed therein. With reference to Examples 1 and 2, in some embodiments, certain modifiers can affect the classification of certain perfume raw materials.
[0095] In some embodiments, a method for calculating the second vapor pressure of a given perfume raw material in the presence of a given concentration of at least one particular modifier comprises the steps of: a. A of perfume raw materials in solution without at least one modifier (A0) over time PRM / A INSTD determining b. A known concentration of modifier (A xA of a perfume raw material in solution in the presence of at least one modifier PRM / A INSTD determining c. The vapor pressure (P vap ), and d. A0, A x , a0, and a x Calculating based on e. a0, a x , and P vap , based on the second vapor pressure (P * vap ) step.
[0096] In some embodiments, the calculated second vapor pressure allows perfumers to formulate a middle note of a fragrance profile with an accord, such as a floral, fruity, aromatic, spicy, or oriental accord characteristic, that can last for a very long time, particularly over the life of the composition after application, without being overwhelmed by the stronger odor of the base note.Furthermore, in some embodiments, the calculated second vapor pressure allows perfumers to utilize modifiers in a way that does not affect the consumer's initial perception of the fragrance profile.For example, based on the calculated second vapor pressure of the fragrance raw material, perfumers can select a top note whose volatility does not decrease in the presence of a specific concentration of modifier.
[0097] In some embodiments, the calculated second vapor pressure allows a perfumer to modify the fragrance profile and / or intensity of an existing composition formulated as a first consumer product so that the existing composition has the same fragrance profile and / or intensity when formulated as a second consumer product. For example, and illustratively, the composition may be incorporated into a fine fragrance, and the methods presented herein may allow the perfumer to recreate the same fragrance profile and / or intensity as the fine fragrance in a soap, cream, household cleaner, etc.
[0098] Fragrance Ingredient Formulation: Referring to FIG. 4, the present disclosure provides a method for blending specific perfume ingredients into a fragrance composition comprising: i. remain available for selection for use in highly volatile ingredients, where the second vapor pressure of the perfume raw material is greater than 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 1); ii. no longer remains available for selection for use in the high volatility component, but becomes available for selection for use in the medium volatility component, where the second vapor pressure of the fragrance raw material is in the range of 0.0008 to 0.08 Torr at 22°C (examples of suitable fragrance raw materials are shown in Table 2); iii. remain available for selection for use in medium volatility ingredients, where the second vapor pressure of the fragrance raw material is in the range of 0.0008 to 0.08 Torr at 22°C (examples of suitable fragrance raw materials are shown in Table 3); iv. no longer remains available for selection for use in medium volatility ingredients, but becomes available for selection for use in low volatility ingredients, where the perfume raw material has a second vapor pressure of less than 0.0008 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 4), or v. Remain available for selection for use in low volatility ingredients, where the second vapor pressure of the fragrance raw material is less than 0.0008 Torr at 22°C (examples of suitable fragrance raw materials are shown in Table 5). The present invention provides a method for constructing various compositions utilizing perfume raw materials from a palette of raw materials categorized according to either:
[0099] In some embodiments, the perfume raw material may no longer remain available for selection for use in the medium-volatility component because the perfume raw material may be suppressed (i.e., not perceived by the consumer) in the presence of the modifier. Examples of suitable perfume raw materials are shown in Table 6.
[0100] In some embodiments, the perfume raw materials remain available for selection for use in low volatility ingredients, and the perfume raw materials may be suppressed (i.e., not perceived by the consumer) in the presence of the modifier. Examples of suitable perfume raw materials are provided in Example 1 and Table 7.
[0101] Further examples of suitable classified perfume raw materials can be found in Examples 1 and 2 and the tables listed therein. With reference to Examples 1 and 2, in some embodiments, certain modifiers can affect the classification of certain perfume raw materials.
[0102] Such solutions presented herein tend to extend the longevity of fragrance profiles and to intensify and alter the overall character of fragrances, especially in compositions formulated from volatile fragrance materials with a medium to high vapor pressure range, without having to rely on the presence or significant amounts of low-volatility fragrance materials, providing perfumers with options for formulating accords with new fragrance profiles.
[0103] [Table 1]
[0104] [Table 2-1]
[0105] Table 2-2
[0106] Table 3-1
[0107] Table 3-2
[0108] Table 3-3
[0109] Table 3-4
[0110] Table 4-1
[0111] Table 4-2
[0112] Table 4-3
[0113] Table 5-1
[0114] Table 5-2
[0115] Table 6
[0116] [Table 7-1]
[0117] [Table 7-2]
[0118] In one aspect, perfume raw materials suitable for inclusion in compositions according to embodiments presented herein are selected from the perfume raw materials set forth in Table 8.
[0119] [Table 8-1]
[0120] [Table 8-2]
[0121] [Table 8-3]
[0122] In some aspects, the compositions constructed using the methods described herein comprise: a. ethanol in an amount of 30 to 75% by weight based on the total weight of the composition; b. a fragrance ingredient present in an amount of 0.04 to 40% by weight based on the total weight of the composition, i. a. at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C, and optionally b. at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C; Highly volatile components in an amount of 0.08 to 55% by weight of the fragrance ingredients, including ii. The following a. a first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C, and optionally b. at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C; and a medium-volatile component in an amount of 0.08 to 85% by weight of the fragrance component. and a fragrance ingredient comprising: c. at least one regulator in an amount of 0.1 to 50% by weight based on the total weight of the composition; Including, a first vapor pressure of at least one first perfume raw material of the highly volatile component is determined without the at least one modifier; a first vapor pressure of at least one second perfume raw material of the highly volatile component is determined without the at least one modifier; at least one modulating agent changes the first vapor pressure of at least one second perfume raw material of the high volatility component to a second vapor pressure; a second vapor pressure of the at least one second fragrance ingredient that is a highly volatile component in the range of 0.0008 to 0.08 Torr at 22°C; a first vapor pressure range of at least one first perfume raw material of a medium volatility component is determined without the at least one modifier; a first vapor pressure range of at least one second perfume raw material of medium volatility components is determined without the at least one modifier; at least one modifier changes the first vapor pressure range of at least one second perfume raw material of the medium volatility component to a second vapor pressure; and The at least one second perfume raw material that is a medium volatility component has a second vapor pressure of less than 0.0008 Torr at 22°C.
[0123] In some embodiments, the fragrance component is present in an amount of 0.04 to 20% by weight, based on the total weight of the composition.
[0124] In some embodiments, the composition further comprises water in an amount of 15% by weight or less, based on the total weight of the composition.
[0125] In some embodiments, the composition further comprises water in an amount of 5-15% by weight, based on the total weight of the composition.
[0126] In some embodiments, the composition further comprises water in an amount of 0-5% by weight, based on the total weight of the composition.
[0127] In certain embodiments, the compositions of the present invention comprise at least 5, at least 10, at least 15, or at least 20 perfume raw materials. If there is more than one perfume raw material, the above ranges cover the total weight of all perfume raw materials.
[0128] In some embodiments, the highly volatile component consists solely of at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C. In these embodiments, the at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 55% by weight of the fragrance ingredients. Alternatively, the at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 55% by weight of the fragrance ingredients. Alternatively, the at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.15 to 55% by weight of the fragrance ingredients. Alternatively, the at least one first perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.6 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 1.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 1.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 1.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 1.95 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.7 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 3.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 3.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.45 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 5.85 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.6 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 7.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 7.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.35 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.75 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.2 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.3 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.4 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.5 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.55 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.6 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.65 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.7 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 9.75 to 55% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.8 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.85 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.9 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.95 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 10 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 15 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 20 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 25 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 30 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 35 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 40 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 45 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 50 to 55% by weight of the fragrance ingredients.
[0129] Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 50% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 45% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 40% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 35% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 30% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 25% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 20% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 15% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 10% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 9.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 9.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 8.5% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 7.2% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 5.9% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 3.4% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 2.1% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 0.8% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.09% by weight of the fragrance ingredients.
[0130] In some embodiments, the first at least one perfume ingredient having a first vapor pressure of greater than 0.08 Torr at 22° C. is selected from the group consisting of: 0.008, 0.009, 0.01, 0.015, 0.02, 0.025, 0.03, 0.035, 0.04, 0.045, 0.04, 0.045, 0.05, 0.055, 0.06, 0.065, 0.07, 0.075, 0.08, 0.085, 0.09, 0.095, 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.8, 0.9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 75, 0.8, 0.85, 0.9, 0.95, 1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, 2, 2.15, 2.2, 2.25, 2.3, 2.35, 2.4, 2.45, 2.5, 2.55, 2.6, 2.65, 2.7, 2.75, 2.8, 2.85, 2.9, 2.95, 3, 3.15, 3.2, 3.25, 3.3, 3.35, 3.4, 3.45, 3.5, 3.55, 3.6, 3.65, 3.7, 3.75, 3.8 ,3.85,3.9,3.95,4,4.15,4.2,4.25,4.3,4.35,4.4,4.45,4.5,4.55,4.6,4.65,4.7,4.75,4.8,4.85,4.9,4.95,5,5.15,5.2,5.25,5.3,5.35,5.4,5.45,5.5,5.55,5.6,5.65,5.7,5.75,5.8,5.85,5.9,5.95,6,6.15,6.2,6.25,6.3,6.35,6.4,6.45,6.5,6.55,6.6,6.65,6.7,6.75,6.8,6.85, 6.9, 6.95, 7, 7.15, 7.2, 7.25, 7.3, 7.35, 7.4, 7.45, 7.5, 7.55, 7.6, 7.65, 7.7, 7.75, 7.8, 7.85, 7.9, 7.95, 8, 8.15, 8.2, 8.25, 8.3, 8.35, 8.4, 8.45, 8.5, 8.55, 8.6, 8.65, 8.7, 8.75, 8.8, 8.85, 8.9, 8.95, 9, 9.15, 9.2, 9.25, 9.3, 9.35, 9.4, 9.45, 9.5, 9.55, 9.6, 9.65, 9.7, 9.75, 9.8, 9.85, 9.9, 9.It is present at 95, 10, 15, 20, 25, 30, 35, 40, 45, 50, or 55% by weight.
[0131] In one embodiment, the medium-volatility components consist solely of at least one first perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. In these embodiments, the at least one first perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. is present in an amount ranging from 0.08 to 85% by weight of the fragrance ingredients. Alternatively, the at least one first perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 1.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.6 to 85% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 2.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 3.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.55 to 85% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 4.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 5.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.5 to 85% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 6.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 7.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.45 to 85% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 8.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.2 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.3 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.4 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.5 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.6 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.7 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.8 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.85 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.9 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 9.95 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 10 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 15 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 25 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 30 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 35 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 40 to 85% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 45 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 50 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 55 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 60 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 65 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 70 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 75 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. is present in an amount ranging from 80 to 85% by weight of the fragrance ingredients.
[0132] Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 85% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 80% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 75% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 70% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 65% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 60% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 55% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 50% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 45% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 40% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 35% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 30% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 25% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 20% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 15% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 10% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.4% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.3% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.2% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.3% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.2% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.8% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.7% by weight of the fragrance ingredients.Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.9% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.8% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.7% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.6% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.5% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.4% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.3% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.2% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.1% by weight of the fragrance ingredients. Alternatively, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 0.08 to 0.09% by weight of the fragrance ingredients.
[0133] In some embodiments, the first at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. is selected from the group consisting of: 0.008, 0.009, 0.01, 0.015, 0.02, 0.025, 0.03, 0.035, 0.04, 0.045, 0.04, 0.045, 0.05, 0.055, 0.06, 0.065, 0.07, 0.075, 0.08, 0.085, 0.09, 0.095, 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, 1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, 2, 2.15, 2.2, 2.25, 2.3, 2.35, 2.4, 2.45, 2.5, 2.55, 2.6, 2.65, 2.7, 2.75, 2.8, 2.85, 2.9, 2.95, 3, 3.15, 3.2, 3.25, 3.3, 3.35, 3.4, 3.45, 3.5, 3.55, 3.6, 3.65, 3.7, 3.75 ,3.8,3.85,3.9,3.95,4,4.15,4.2,4.25,4.3,4.35,4.4,4.45,4.5,4.55,4.6,4.65,4.7,4.75,4.8,4.85,4.9,4.95,5,5.15,5.2,5.25,5.3,5.35 ,5.4,5.45,5.5,5.55,5.6,5.65,5.7,5.75,5.8,5.85,5.9,5.95,6,6.15,6.2,6.25,6.3,6.35,6.4,6.45,6.5,6.55,6.6,6.65,6.7,6.75,6.8,6.8 5, 6.9, 6.95, 7, 7.15, 7.2, 7.25, 7.3, 7.35, 7.4, 7.45, 7.5, 7.55, 7.6, 7.65, 7.7, 7.75, 7.8, 7.85, 7.9, 7.95, 8, 8.15, 8.2, 8.25, 8.3, 8.35, 8.4, 8.4 5, 8.5, 8.55, 8.6, 8.65, 8.7, 8.75, 8.8, 8.85, 8.9, 8.95, 9, 9.15, 9.2, 9.25, 9.3, 9.35, 9.4, 9.45, 9.5, 9.55, 9.6, 9.65, 9.7, 9.75, 9.8, 9.85, 9.9, 9.It is present at 95, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, or 85% by weight.
[0134] In one embodiment, the highly volatile component comprises at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C in an amount of 0.1 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.15 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.2 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.3 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 1.9 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 1.95 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.7 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 2.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.85 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 3.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 3.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.65 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 4.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 5.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 6.15 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.75 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 6.8 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 6.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.75 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 7.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 7.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.55 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 8.95 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.2 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.3 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.35 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.4 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.45 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.5 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.55 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.6 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.65 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.7 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.75 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.8 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.85 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 9.9 to 40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 9.95 to 40% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 10 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 15 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 20 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 25 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 30 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount in the range of 35-40% by weight of the fragrance ingredients.
[0135] Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 35% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 30% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 25% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 20% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 15% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 10% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.5% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 8.4% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.2% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 7.1% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.9% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 5.8% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.6% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 4.5% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.8% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 2.7% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.5% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 1.4% by weight of the fragrance ingredients.Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 1.3% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 1.2% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount ranging from 0.1 to 1.1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.9% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.8% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.7% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.6% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.5% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.4% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.3% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is present in an amount in the range of 0.1 to 0.2% by weight of the fragrance ingredients.
[0136] In some embodiments, the second at least one perfume raw material having a first vapor pressure of greater than 0.08 Torr at 22° C. is selected from the group consisting of 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, 1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, 2.0, 2.1, 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 2.10, 2.11, 2.12, 2.13, 2.14, 2.15, 2.16, 2.17, 2.18, 2.19, 2.20, 2.21, 2.22, 2.23, 2.24, 2.25, 2.26, 2.27, 2.28, 2.29, 2.30, 2.31, 2.32, 2.33, 2.34, 2.35, 2.36, 2.37, 2.38, 2.39, 2.40, 2.41, 2.42, 2.43, 2.44, 2.45, 2.56, 2 ,2.15,2.2,2.25,2.3,2.35,2.4,2.45,2.5,2.55,2.6,2.65,2.7,2.75,2.8,2.85,2.9,2.95,3,3.15,3.2,3.25,3.3,3.35,3.4,3.45,3.5,3.55,3.6,3.65,3.7,3.75,3.8,3.85,3.9,3.95,4,4.15,4.2,4.25,4.3,4.35,4.4,4.45,4.5,4.55,4.6,4.65,4.7,4.75,4.8 ,4.85,4.9,4.95,5,5.15,5.2,5.25,5.3,5.35,5.4,5.45,5.5,5.55,5.6,5.65,5.7,5.75,5.8,5.85,5.9,5.95,6,6.15,6.2,6.25,6.3,6.35,6.4,6.45,6.5,6.55,6.6,6.65,6.7,6.75,6.8,6.85,6.9,6.95,7,7.15,7.2,7.25,7.3,7.35,7.4,7.45,7.5,7.55,7.6,7 9.15, 9.2, 9.25, 9.3, 9.35, 9.4, 9.45, 9.5, 9.55, 9.6, 9.65, 9.7, 9.75, 9.8, 9.85, 9.9, 9.95, 10, 15, 20, 25, 30, 35, or 40% by weight.
[0137] In one embodiment, the medium-volatility component comprises at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C in an amount of 20-45% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20-40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 25-40% by weight of the fragrance ingredients. Alternatively, the at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 30-40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. is present in an amount ranging from 35 to 40% by weight of the fragrance ingredients.
[0138] Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 40% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 35% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 30% by weight of the fragrance ingredients. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 25% by weight of the fragrance ingredients.
[0139] In some embodiments, the at least one second perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22° C. is present at 20, 25, 30, 35, 40, or 45% by weight of the fragrance ingredients.
[0140] In one embodiment, the fragrance ingredients further comprise at least one perfume raw material having a first vapor pressure of less than 0.0008 Torr at 22° C. in an amount of 10-55% by weight of the fragrance ingredients.
[0141] In one embodiment, the fragrance ingredients further comprise at least one perfume raw material having a first vapor pressure of less than 0.0008 Torr at 22° C. in an amount of 30-55% by weight of the fragrance ingredients.
[0142] In one embodiment, the fragrance ingredients further comprise at least one perfume raw material having a first vapor pressure of less than 0.0008 Torr at 22° C. in an amount of 10-30% by weight of the fragrance ingredients.
[0143] At least one modifier: The compositions presented herein further comprise at least one modifier. Without intending to be limited to a particular theory, the at least one modifier is configured to allow the perfumer to formulate a middle note of a fragrance profile with an accord, such as a floral, fruity, aromatic, spicy, or oriental accord characteristic, that can be sustained for a very long period of time, particularly over the life of the composition after application, without being overwhelmed by the stronger odor of the base note. Furthermore, the modifier is configured to allow the perfumer to utilize the modifier in a manner that does not affect the consumer's initial perception of the fragrance profile. For example, the perfumer can select a top note whose volatility does not decrease in the presence of a specific concentration of modifier based on the calculated second vapor pressure of the fragrance raw material. Furthermore, the modifier is configured to reduce, prevent, or improve the formation of a film on the consumer's skin.
[0144] In another embodiment, the at least one modifier is configured to allow for the removal of water from the perfume composition without adversely affecting the performance of the perfume composition.
[0145] In one embodiment, the at least one modulating agent is i. A vapor pressure of less than 0.0008 Torr at 22°C; ii. For dissolution in compounds with vapor pressures greater than 0.08 Torr at 22°C, atomic dispersion forces (δ d ), dipole moments 1-7 (δ p ), and 2.5 to 11 hydrogen bonds (δ h At least two Hansen solubility parameters selected from the first group consisting of iii. For dissolution in compounds with vapor pressures ranging from 0.0008 to 0.08 Torr at 22°C, atomic dispersion forces (δ d ), dipole moments 1 to 8 (δ p ), and 4–11 hydrogen bonds (δ h At least two Hansen solubility parameters selected from a second group consisting of The compound includes a compound having the formula:
[0146] In one embodiment, the first group has an atomic dispersion force (δ) of 15.84±3.56 when dissolved in a compound having a vapor pressure greater than 0.08 Torr at 22° C. d ), dipole moment (δ p ), and 6.72 ± 4.11 hydrogen bonds (δ h ) at least two Hansen solubility parameters selected from the group consisting of:
[0147] In one embodiment, the second group has an atomic dispersion force (δ) of 16.86±2.72 when dissolved in compounds having a vapor pressure range of 0.0008 to 0.08 Torr at 22° C. d ), dipole moment (δ p ), and 7.66 ± 3.29 hydrogen bonds (δ h ) at least two Hansen solubility parameters selected from the group consisting of:
[0148] Without intending to be limited to a particular theory, (i) for dissolution in compounds with vapor pressures greater than 0.08 Torr at 22°C, atomic dispersion forces (δ d), dipole moments 1-7 (δ p ), and 2.5 to 11 hydrogen bonds (δ h (ii) at least two Hansen solubility parameters selected from a first group consisting of: (i) an atomic dispersion force (δ) of 14 to 20 for dissolution in a compound having a vapor pressure range of 0.0008 to 0.08 Torr at 22°C; d ), dipole moments 1 to 8 (δ p ), and 4–11 hydrogen bonds (δ h At least one modifier having at least two Hansen solubility parameters selected from the second group consisting of 1.5 and 3.5 is within the area represented by the dashed and solid lines. Additionally, compounds with cLogP values between 1.5 and 3.5 are marked with triangles. Such compounds can be incorporated into capsules or cyclodextrins.
[0149] In some embodiments, at least one modulator is selected from the compounds listed in Table 9.
[0150] In some embodiments, at least one modulating agent has an odor value of 1 to 10,000.
[0151] In some embodiments, at least one regulator has a C between 0.1 and 10 μg / l I2.5 It has.
[0152] [Table 9-1]
[0153] [Table 9-2]
[0154] [Table 9-3]
[0155] The at least one modulating agent is present in an amount of 0.1 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.2 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.3 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.4 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.5 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.6 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.7 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.8 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.9 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.1 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.2 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.3 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.4 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.5 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.6 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.7 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 1.8 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of from 1.9 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of from 2 to 20% by weight relative to the total weight of the composition.Alternatively, the at least one modulating agent is present in an amount of 2.1 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.2 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.3 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.4 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.5 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.6 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.7 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.8 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 2.9 to 20% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.1 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.2 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 3.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.1 to 20% by weight, relative to the total weight of the composition.Alternatively, the at least one modulating agent is present in an amount of 4.2 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 4.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.1 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.2 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 5.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.1 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.2 to 20% by weight, relative to the total weight of the composition.Alternatively, the at least one modulating agent is present in an amount of 6.3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 6.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.1 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.2 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 7.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.1 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.2 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.3 to 20% by weight, relative to the total weight of the composition.Alternatively, the at least one modulating agent is present in an amount of 8.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 8.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.1 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.2 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.3 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.4 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.5 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.6 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.7 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.8 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 9.9 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 10 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 11 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 12 to 20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 13 to 20% by weight, relative to the total weight of the composition.Alternatively, the at least one modulating agent is present in an amount of 14-20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 15-20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 16-20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 17-20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 18-20% by weight, relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 19-20% by weight, relative to the total weight of the composition.
[0156] Alternatively, the at least one modulating agent is present in an amount of 0.1 to 19% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 18% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 17% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 16% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 15% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 14% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 13% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 12% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 11% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 10% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 9% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 8% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 7% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 6% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 5% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 4% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 3% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 2% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 1% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.9% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.8% by weight relative to the total weight of the composition.Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.7% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.6% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.5% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.4% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.3% by weight relative to the total weight of the composition. Alternatively, the at least one modulating agent is present in an amount of 0.1 to 0.2% by weight relative to the total weight of the composition.
[0157] In some embodiments, the at least one modulating agent is present in an amount of 0.1, or 0.2, or 0.3, or 0.4, or 0.5, or 0.6, or 0.7, or 0.8, or 0.9, or 1, or 1.1, or 1.2, or 1.3, or 1.4, or 1.5, or 1.6, or 1.7, or 1.8, or 1.9, or 2, or 2.1, or 2.2, or 2.3, or 2.4, or 2.5, or 2.6, or 2.7, or 2.8, or 2.9, or 3, or 3.1, or 3.2, based on the total weight of the composition. , or 3.3, or 3.4, or 3.5, or 3.6, or 3.7, or 3.8, or 3.9, or 4, or 4.1, or 4.2, or 4.3, or 4.4, or 4.5, or 4.6, or 4.7, or 4.8, or 4.9, or 5, or 5.1, or 5.2, or 5.3, or 5.4, or 5.5, or 5.6, or 5.7, or 5.8, or 5.9, or 6, or 6.1, or 6.2, or 6.3, or 6.4, or 6.5, or 6.6, or 6.7, or 6.8, or 6.9, or 7, 7.1, or 7.2, or 7.3, or 7.4, or 7.5, or 7.6, or 7.7, or 7.8, or 7.9, or 8, or 8.1, or 8.2, or 8.3, or 8.4, or 8.5, or 8.6, or 8.7, or 8.8, or 8.9, or 9, or 9.1, or 9.2, or 9.3, or 9.4, or 9.5, or 9.6, or 9.7, or 9.8, or 9.9, or 10, or 10.1, or 10.2, or 10.3, or 10.4, or 10. 5, or 10.6, or 10.7, or 10.8, or 10.9, or 11, or 11.1, or 11.2, or 11.3, or 11.4, or 11.5, or 11.6, or 11.7, or 11.8, or 11.9, or 12, or 12.1, or 12.2, or 12.3, or 12.4, or 12.5, or 12.6, or 12.7, or 12.8, or 12.9, or 13, or 13.1, or 13.2, or 13.3, or 13.4, or 13.5, or 13.6, or 13.7, or 13.8, or 13.9, or 14, or 14.1, or 14.2, or 14.3, or 14.4, or 14.5, or 14.6, or 14.7, or 14.8, or 14.9, or 15, or 15.1, or 15.2, or 15.3, or 15.4, or 15.5, or 15.6, or 15.7, or 15.8, or 15.9, or 16, or 16.1, or 16.2, or 16.3, or 16.4, or 16.5, or 16.6, or 16.7, or 16.8, or 16.9, or 17, or 17.1, or 17.2, or 17.3, or 17.4, or 17.5, or 17.6, or 17.7, or 17.8, or 17.9, or 18, 18.1, or 18.2, or 18.3, or 18.4, or 18.5, or 18.6, or 18.7, or 18.8, or 18.9, or 19, or 19.1, or 19.2, or 19.3, or 19.4, or 19.5, or 19.6, or 19.7, or 19.8, or 19.9, or 20, or 20.1, or 20.2, or 20.3, or 20.4,. or 20.5, or 20.6, or 20.7, or 20.8, or 20.9, or 21, or 21.1, or 21.2, or 21.3, or 21.4, or 21.5, or 21.6, or 21.7, or 21.8, or 21.9, or 22, or 22.1, or 22.2, or 22.3, or 22.4, or 22.5, or 22.6, or 22.7, or 22.8, or 22.9, or 23, or 23.1, or 23.2, or 23.3, or 23.4, or 23.5, or 23.6, or 23.7, or 23.8, or 23.9, or 24, or 24.1, or 24.2, or 24.3, or 24.4, or 24.5, or 24.6, or 24.7, or 24.8, or 24.9, or 25, or 25.1, or 25.2, or 25.3, or 25.4, or 25.5, or 25.6, or 25.7, or 25.8, or 25.9, or 26, or 26.1, or 26.2, or 26.3, or 26.4, or 26.5, or 26.6, or 26.7, or 26.8, or 26.9, or 27, or 27.1, or 27.2, or 27.3, or 27.4, or 27.5, or 27.6, or 27.7, or 27.8, or 27.9, or 28, 28.1, or 28.2, or 28.3, or 28.4, or 28.5, or 28.6, or 28.7, or 28.8, or 28.9, or 29, or 29.1, or 29.2, or 29.3, or 29.4, or 29.5, or 29.6, or 29.7, or 29.8, or 29.9, or 30, or 30 .1, or 30.2, or 30.3, or 30.4, or 30.5, or 30.6, or 30.7, or 30.8, or 30.9, or 31, or 31.1, or 31.2, or 31.3, or 31.4, or 31.5, or 31.6, or 31.7, or 31.8, or 31.9, or 32, or 32.1, or 32.2, or 32.3, or 32.4, or 32.5, or 32.6, or 32.7, or 32.8, or 32.9, or 33, or 33.1, or 33.2, or 33.3, or 33.4, or 33.5, or 33.6, or 33.7, or 33.8, or 33.9, or 34, or 34.1, or 34.2, or 34.3, or 34.4, or 34.5, or 34.6, or 34.7, or 34.8, or 34.9, or 35, or 35.1, or 35.2, or 35.3, or 35.4, or 35.5, or 35.6, or 35.7, or 35.8, or 35.9, or 36, or 36.1, or 36.2, or 36.3, or 36.4, or 36.5, or 36.6, or 36.7, or 36.8, or 36.9, or 37, or 37.1, or is 37.2, or 37.3, or 37.4, or 37.5, or 37.6, or 37.7, or 37.8, or 37.9, or 38, 38.1, or 38.2, or 38.3, or 38.4, or 38.5, or 38.6, or 38.7, or 38.8, or 38.9, or 39, or 39.1, or 39.2, or 39.3, or 39.4, or 39.5, or 39.6, or 39.7, or 39.8, or 39.9, or 40, or 40.1, or 40.2, or 40.3, or 40.4, or 40.5, or 40.6, or 40.7, or 40.8, or 40.9, or 41,. or 41.1, or 41.2, or 41.3, or 41.4, or 41.5, or 41.6, or 41.7, or 41.8, or 41.9, or 42, or 42.1, or 42.2, or 42.3, or 42.4, or 42.5, or 42.6, or 42.7, or 42.8, or 42.9, or 43, or 43.1, or 43.2, or 4 3.3, or 43.4, or 43.5, or 43.6, or 43.7, or 43.8, or 43.9, or 44, or 44.1, or 44.2, or 44.3, or 44.4, or 44.5, or 44.6, or 44.7, or 44.8, or 44.9, or 45, or 45.1, or 45.2, or 45.3, or 45.4, or 45.5, or or 45.6, or 45.7, or 45.8, or 45.9, or 46, or 46.1, or 46.2, or 46.3, or 46.4, or 46.5, or 46.6, or 46.7, or 46.8, or 46.9, or 47, or 47.1, or 47.2, or 47.3, or 47.4, or 47.5, or 47.6, or 47.7, or 47. 8, or 47.9, or 48, 48.1, or 48.2, or 48.3, or 48.4, or 48.5, or 48.6, or 48.7, or 48.8, or 48.9, or 49, or 49.1, or 49.2, or 49.3, or 49.4, or 49.5, or 49.6, or 49.7, or 49.8, or 49.9, or 50% by weight.
[0158] In some embodiments, the concentration of the at least one modulating agent is 15% by weight based on the total weight of the composition.
[0159] In one embodiment, the at least one modifier is liquid at a temperature below 100°C. In one embodiment, the modifier is liquid at ambient temperature. In some embodiments, the at least one modifier is completely miscible with the perfume raw materials added to the compositions according to some embodiments presented herein, thereby forming a single-phase liquid. However, if the perfume raw materials are not completely miscible or are immiscible, a co-solvent (e.g., dipropylene glycol (DPG), triethyl citrate, or others familiar to those skilled in the art) may be added to aid in the solubility of the perfume raw materials in the at least one modifier.
[0160] The compositions provided herein may further comprise additional components, such as polymers, capsules, microcapsules and nanocapsules, liposomes, absorbents, cyclic oligosaccharides, and mixtures thereof. Examples of suitable additional components are described in International Patent Application Publication No. 2015 / 089246. In some embodiments, the additional component comprises a cyclodextrin. In some embodiments, the cyclodextrin further comprises at least one compound having a cLogP value of 1.5 to 3.5. In some aspects, the cLogP value is 2 to 3.
[0161] In some embodiments, at least one compound has an odor value of 1 to 10,000.
[0162] In some embodiments, at least one compound in the capsule has a C of between 0.1 and 10 μg / l. I2.5 It has.
[0163] [Table 10-1]
[0164] [Table 10-2]
[0165] [Table 10-3]
[0166] The compositions presented herein can be formulated in any suitable solvent. Examples of suitable solvents include, but are not limited to, ethanol or other alcohols commonly found in commercial fine fragrance products (e.g., methanol, propanol, isopropanol, butanol, and mixtures thereof). Thus, ethanol can be present in any of the compositions of the present disclosure; more specifically, ethanol will form from about 10% to about 80% by weight, or even from about 25% to about 75% by weight, of the composition or combination thereof, based on the total weight of the composition. Alternatively, ethanol can be present in an amount from about 10% or 25% by weight to about 75% or 80% by weight, based on the total weight of the composition. Any acceptable quality of ethanol is compatible with the specific intended use of the composition, such as topical application of a fine fragrance or cosmetic composition, and is safe and convenient for use in the compositions according to the present invention.
[0167] The compositions provided herein can contain non-volatile solvent or a mixture of non-volatile solvents.Non-limiting examples of non-volatile solvents include benzyl benzoate, diethyl phthalate, isopropyl myristate, propylene glycol, dipropylene glycol, triethyl citrate, and their mixtures.These solvents are often introduced into products through perfume oils, because many perfume raw materials can be purchased as dilutions in one of these solvents.If non-volatile solvents exist and are introduced together or separately with perfume materials, the total fragrance ingredients for the purpose of calculating vapor pressure do not include non-volatile solvents.
[0168] In some embodiments, the composition further comprises at least one hydrophilic solvent. In one embodiment, the at least one hydrophilic solvent is selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, triethyl citrate, diisopropyl glycol monomethyl ether, diethylene glycol monoethyl ether, triacetin, methyl methoxybutanol, benzyl alcohol, propylene glycol n-butyl ether, glycol ethers, esters of diethylene glycol, and cellosolve derivatives. In one embodiment, the glycol ether is the glycol ether sold under the trade name DOWANOL. In one embodiment, the ether of diethylene glycol is sold under the trade name CARBITOL.
[0169] In some embodiments, glycol ethers sold under the trade name DOWANOL include DOWANOL™ DPMA Glycol Ether; DOWANOL™ PM Glycol Ether; DOWANOL EPH ELP; DOWANOL™ EPh; DOWANOL™ PnB Glycol Ether; DOWANOL™ TPnB; DOWANOL™ DPnB Glycol Ether; DOWANOL™ TPM Glycol Ether; DOWANOL™ PPh Glycol Ether; DOWANOL™ PnP Glycol Ether; DOWANOL™ DPH 255 Glycol Ether; DOWANOL™ PGDA Glycol Ether; DOWANOL™ DPM Glycol Ether; DOWANOL™ TPnB-H Glycol Ether; DOWANOL™ Solvents for Home & Personal Care; DOWANOL™ DPnP Glycol Ether; DOWANOL™ PMA Glycol Ether; DOWANOL™ DiPPh Glycol Ether.
[0170] In some embodiments, the cellosolve derivative is selected from the group consisting of propyl cellosolve, butyl cellosolve, hexyl cellosolve, and cellosolve.
[0171] Products and formulations according to some embodiments presented herein: One aspect presented herein provides a perfumed consumer product comprising a composition according to an aspect presented herein.
[0172] One aspect presented herein provides a perfume composition comprising a composition according to an aspect presented herein.
[0173] One aspect presented herein provides a perfumed consumer product comprising a perfume composition according to an aspect presented herein.
[0174] In one aspect, the perfumed consumer product is selected from the group consisting of a fragrance, an eau de toilette, a home care product, and a personal care product.
[0175] In some embodiments, the perfumed consumer product is selected from the group consisting of air care products, home care products, and laundry care products.
[0176] It will be understood by those skilled in the art that the compositions defined herein can be added in neat form or in a solvent to a perfume composition or perfumed consumer product. Alternatively, the compositions can be first modified by being entrapped with an entrapment material such as, for example, a polymer, capsule, microcapsule, nanocapsule, liposome, precursor, film former, absorbent, for example, by using carbon or zeolite, cyclic oligosaccharides, and mixtures thereof.
[0177] Accordingly, some aspects presented herein include: a. a composition according to an embodiment presented herein; and b. at least one ingredient selected from the group consisting of a perfume carrier and a perfume base; c. optionally at least one flavoring adjuvant; The present invention provides a fragrance composition or a fragranced consumer product comprising:
[0178] In some embodiments, the perfumed consumer product comprises a formulation selected from the group consisting of aerosol and / or water-based air freshener sprays, wick / lead air fresheners, liquid electric (plug-in) air fresheners, solid support air fresheners, gel-based air fresheners, film-containing air fresheners, bleaches, cleaning agents, cleaning detergent powders, liquid all-purpose cleaners, specialty cleaners, and liquid detergents.
[0179] As used herein, the term "perfume carrier" refers to a material that is substantially neutral from a perfumery point of view, i.e., that does not significantly alter the sensory properties of the perfuming ingredients. Perfume carriers can be liquid or solid.
[0180] Non-limiting examples of liquid perfume carriers include emulsifying systems, i.e., solvent and surfactant systems, or solvents commonly used in perfumery.A detailed description of the nature and type of solvents commonly used in perfumery cannot be exhaustive.However, non-limiting examples of solvents include dipropylene glycol, diethyl phthalate, isopropyl myristate, benzyl benzoate, 2-(2-ethoxyethoxy)-1-ethanol, or ethyl citrate.In addition, for compositions containing both a perfume carrier and a perfume base, suitable perfume carriers other than those specified above may be ethanol, water / ethanol mixtures, limonene or other terpenes, isoparaffins, such as those known under the trademark Isopar® (manufactured by Exxon Chemical), or glycol ethers and glycol ether esters, such as those known under the trademark DOWANOL® (manufactured by Dow Chemical Company).
[0181] Non-limiting examples of solid perfume carriers include absorbent gums or polymers, or encapsulating materials.Examples of such materials can include wall-forming and plasticizing materials such as monosaccharides, disaccharides or trisaccharides, natural or modified starches, hydrocolloids, cellulose derivatives, polyvinyl acetate, polyvinyl alcohol, proteins or pectins, or materials cited in references such as H. Scherz, Hydrokolloides: Stabilisers, Digestions- and Geliermittel in Lebensmitteln, Band 2 der Schriftenreihe Lebensmittelchemie, Lebensmittelqualitaet, Behr's Verlag GmbH & Co., Hamburg, 1996.Encapsulation is a method well known to those skilled in the art, and can be carried out using techniques such as spray drying, coagulation or extrusion, or can be comprised of coating encapsulation, including coacervation and complex coacervation techniques.
[0182] As used herein, the term "perfume base" refers to a composition comprising at least one perfuming co-ingredient. As used herein, the term "perfuming co-ingredient" refers to a compound used in a perfuming preparation or composition to impart a pleasant effect. In other words, those skilled in the art should recognize such co-ingredients that are considered to be perfuming ingredients not simply as having an odor, but as being able to impart or modify the odor of a composition in a beneficial or pleasant way.
[0183] The nature and type of perfuming co-ingredients present in the base do not warrant further detailed description, and in any case, are not exhaustive; therefore, a person skilled in the art can select them based on his or her general knowledge, depending on the intended use or application and the desired sensory effect. Generally, these perfuming co-ingredients belong to various chemical classes, such as alcohols, lactones, aldehydes, ketones, esters, ethers, acetates, nitriles, terpenoids, nitrogen- or sulfur-containing heterocyclic compounds, and essential oils, and these perfuming co-ingredients may be of natural or synthetic origin. Many of these co-ingredients are listed in references, such as S. Arctander's book "Perfume and Flavor Chemicals," 1969, Montclair, New Jersey, USA, or its latest edition, or other works of similar content, as well as in the vast patent literature in the field of perfumery. It is also understood that these co-ingredients may be compounds known to release various types of perfuming compounds in a controlled manner.
[0184] As used herein, the term "perfuming adjuvant" refers to an ingredient capable of imparting further additional benefits such as color, specific light resistance, chemical stability, etc. A detailed description of the nature and type of adjuvants commonly used in perfuming bases cannot be exhaustive and it should be mentioned that the above ingredients are well known to those skilled in the art.
[0185] It should be appreciated by those skilled in the art that the conception and specific embodiments disclosed may be readily utilized as a basis for modifying or formulating other formulations for carrying out the same purposes of the present invention, and it should be recognized by those skilled in the art that such equivalent formulations do not depart from the spirit and scope of the present disclosure as set forth herein.
[0186] The proportions at which this composition can be incorporated into the various products or compositions mentioned above vary over a wide range, depending on the nature of the consumer product and the desired sensory effect, as well as the nature of the auxiliary ingredients in a given formulation when the composition according to the embodiments presented herein is mixed with other ingredients, solvents, or additives commonly used in the art.
[0187] Typically, for example, in the case of perfume compositions, typical concentrations are on the order of 0.001% to 5% or even more by weight of the compositions according to the embodiments presented herein, based on the formulation in which they are incorporated. When the compositions described herein are incorporated into consumer products, lower concentrations can be used, for example, on the order of 0.01% to 100% by weight, the percentages being relative to the weight of the consumer product.
[0188] The compositions described herein can contain propellant.Some examples of propellant include compressed air, nitrogen, inert gas, carbon dioxide, and their mixtures.Propellant can also include gaseous hydrocarbons such as propane, n-butane, isobutene, cyclopropane, and their mixtures.Halogenated hydrocarbons such as 1,1-difluoroethane can also be used as propellant. Some non-limiting examples of propellants include 1,1,1,2,2-pentafluoroethane, 1,1,1,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, trans-1,3,3,3-tetrafluoroprop-1-ene, dimethyl ether, dichlorodifluoromethane (propellant 12), 1,1-dichloro-1,1,2,2-tetrafluoroethane (propellant 114), 1-chloro-1,1-difluoro-2,2-trifluoroethane (propellant 115), 1-chloro-1,1-difluoroethylene (propellant 142B), 1,1-difluoroethane (propellant 152A), monochlorodifluoromethane, and mixtures thereof. Some other propellants suitable for use include, but are not limited to, A-46 (a mixture of isobutane, butane, and propane), A-31 (isobutane), A-17 (n-butane), A-108 (propane), AP70 (a mixture of propane, isobutane, and n-butane), AP40 (a mixture of propane, isobutene, and n-butane), AP30 (a mixture of propane, isobutane, and n-butane), and 152A (1,1 difluoroethane). The propellant may have a concentration of from about 15%, 25%, 30%, 32%, 34%, 35%, 36%, 38%, 40%, or 42% to about 70%, 65%, 60%, 54%, 52%, 50%, 48%, 46%, 44%, or 42% by weight of the total charge of material stored in the container.
[0189] It should be appreciated by those skilled in the art that the conception and specific embodiments disclosed may be readily utilized as a basis for modifying or formulating other formulations for carrying out the same purposes of the present invention, and it should be recognized by those skilled in the art that such equivalent formulations do not depart from the spirit and scope of the present disclosure as set forth herein.
[0190] Non-limiting examples of suitable perfumed consumer products include: - Fine fragrances, such as eau de toilette, cologne, or aftershave lotion - Fabric care products such as liquid detergent, powder detergent, detergent tablets, detergent bars, detergent paste, detergent pouches, liquid fabric softener, fabric softener sheets, fabric scent boosters, laundry pre-treats, fabric refreshers, ironing water, laundry bleach, carpet powders, or carpet cleaners - Hair care products such as shampoo, hair conditioner, hair cream, hair oil, hair styling products (such as sprays, mousses, or gels), hair coloring products, and hair permanent wave products - Skin care products such as face creams, face lotions, shaving products (such as foams, creams, gels, or oils), body and / or hand products (such as lotions, creams, gels, or oils), skin firming products, depilato...
Claims
1. 1. A composition comprising: a. ethanol in an amount of 30 to 75% by weight, based on the total weight of the composition; b. a fragrance ingredient present in an amount of 0.04 to 40% by weight, based on the total weight of the composition; i. The following a. at least one first highly volatile perfume raw material having a vapor pressure greater than 0.08 Torr at 22°C; and b. at least one second highly volatile perfume raw material having a vapor pressure greater than 0.08 Torr at 22°C; a highly volatile component in an amount of 0.08 to 55% by weight of said fragrance component, ii. The following a. at least one first medium-volatile perfume raw material having a vapor pressure range in the range of 0.0008 to 0.08 Torr at 22°C; and b. at least one second medium-volatile perfume raw material having a vapor pressure range in the range of 0.0008 to 0.08 Torr at 22°C; and a medium-volatile component in an amount of 0.08 to 85% by weight of the fragrance component. and a fragrance ingredient comprising: c. at least one modifier selected from the group consisting of methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetate; propan-2-yltetradecanoate; and combinations thereof, in an amount of 5.0 to 20 wt.%, based on the total weight of the composition; and Including, the vapor pressure of the at least one first highly volatile perfume raw material is determined without the at least one modifier; the vapor pressure of the at least one second highly volatile perfume raw material is determined without the at least one modifier; The vapor pressure of the at least one second highly volatile perfume raw material, determined in the presence of the at least one modifier, is in the range of 0.0008 to 0.08 Torr at 22°C, wherein the at least one first highly volatile perfume raw material is (3E,5Z)-1,3,5-undecatriene and the at least one second highly volatile perfume raw material is (2R)-2-methylundecanal, (1RS,2RS)-2,4-dimethyl-3- selected from the group consisting of cyclohexene-1-carbaldehyde, (1RS,2SR)-2,4-dimethyl-3-cyclohexene-1-carbaldehyde, nonanal, (4E)-4-decenal, decanal, (3E)-1,3-undecadien-5-yne, (6R)-2,6-dimethyl-7-octen-2-ol, 2,6,6-trimethyl-1,3-cyclohexadiene-1-carbaldehyde, and any mixture thereof; the vapor pressure range of the at least one first medium-volatile perfume raw material is determined without the at least one modifier; the vapor pressure range of the at least one second medium-volatile perfume raw material is determined without the at least one modifier; The vapor pressure of the at least one second medium-volatile perfume raw material, determined in the presence of the at least one modifier, is less than 0.0008 Torr at 22°C, wherein the at least one first medium-volatile perfume raw material is selected from the group consisting of (2R)-3-(4-isopropylphenyl)-2-methylpropanal, (2E)-1-[(1R)-2,6,6-trimethyl-2-cyclohexen-1-yl]-2-buten-1-one, 1H-indole, 5-pentyldihydro-2(3H)-furanone, and the like. and the at least one second medium-volatile perfume raw material is selected from the group consisting of (3R)-3-(3-isopropylphenyl)butanal, (3R)-3,7-dimethyl-6-octen-1-ol, 1,3-benzodioxole-5-carbaldehyde, (Z)-3,7-dimethyl-2,6-octadien-1-ol, (+-)-tetrahydro-2-isobutyl-4-methyl-4(2H)-pyranol, and any mixture thereof. composition.
2. 10. The composition of claim 1, wherein the fragrance component is present in an amount of 0.04 to 20% by weight, based on the total weight of the composition.
3. The composition of claim 1 , wherein the composition further comprises water in an amount of 15% by weight or less, based on the total weight of the composition.
4. The composition of claim 1, wherein the composition further comprises water in an amount of 5 to 15% by weight, based on the total weight of the composition.
5. The composition of claim 1, wherein the composition further comprises water in an amount of 0 to 5% by weight, based on the total weight of the composition.
6. The composition of claim 1, wherein the at least one regulator is present in an amount of 6.0 to 20% by weight, based on the total weight of the composition.
7. The composition of claim 1, wherein the at least one regulator is present in an amount of 7.0 to 20% by weight, based on the total weight of the composition.
8. The composition of claim 1, wherein the at least one regulator is present in an amount of 8.0 to 20% by weight, based on the total weight of the composition.
9. The composition of claim 1, wherein the at least one regulator is present in an amount of 9.0 to 20% by weight, based on the total weight of the composition.
10. The composition of claim 1, wherein the at least one regulator is present in an amount of 10.0 to 20% by weight, based on the total weight of the composition.
11. The composition of claim 1, wherein the at least one regulator is present in an amount of 11.0 to 20% by weight, based on the total weight of the composition.
12. The composition of claim 1 , wherein the composition further comprises at least one hydrophilic solvent.
13. 13. The composition of claim 12, wherein the at least one hydrophilic solvent is selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, triethyl citrate, dipropylene glycol monomethyl ether, diethylene glycol monoethyl ether, triacetin, methyl methoxybutanol, benzyl alcohol, propylene glycol n-butyl ether, esters of diethylene glycol, and cellosolve derivatives selected from the group consisting of propyl cellosolve, butyl cellosolve, hexyl cellosolve, and cellosolve.
14. A perfumed consumer product comprising the composition of claim 1.
15. 10. A method for modifying or enhancing the odor characteristics of a body surface, comprising contacting or treating said body surface with the composition of claim 1.
16. 10. A method for modifying or enhancing the odor characteristics of a substrate, comprising contacting or treating said substrate with the composition of claim 1.
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