steel plate

Abstract

Provided is a steel plate whereby excellent quality of appearance can be realized in a molded article.　A steel plate, wherein the chemical composition thereof, in terms of mass%, is 0.030-0.145% C, 0-0.500% Si, 0.50-2.50% Mn, 0-0.100% P, 0-0.020% S, 0-1.000% Al, 0-0.0100% N, etc., the metallographic structure thereof comprises 70-95% ferrite by volume fraction and 5-30% of a hard phase by volume fraction, the value X1 obtained by dividing the standard deviation of the Vickers hardness H1 / 4 at the plate thickness 1 / 4 position by the average value of the Vickers hardness H1 / 4 is 0.025 or less, and the value X2 obtained by dividing the standard deviation of the Vickers hardness H1 / 2 at the plate thickness 1 / 2 position by the average value of the Vickers hardness H1 / 2 is 0.030 or less.

Description

Technical Field

[0001] The present invention relates to a steel sheet.

Background Art

[0002] From the perspective of global environmental protection, for automobiles to improve fuel efficiency, there is an increasing need for weight reduction not only in structural parts such as members but also in panel parts such as roofs and door outers. Different from skeletal parts, these panel parts are exposed to human eyes, so high appearance quality is also required. As appearance quality, designability and surface quality can be cited.

[0003] Patent Document 1 discloses a high-strength hot-dip galvanized steel sheet with excellent surface quality. Specifically, Patent Document 1 contains, in mass%, C: 0.02 to 0.20%, Si: 0.7% or less, Mn: 1.5 to 3.5%, P: 0.10% or less, S: 0.01% or less, Al: 0.1 to 1.0%, N: 0.010% or less, Cr: 0.03 to 0.5%, and the annealing surface oxidation index A defined by the formula: A = 400Al / (4Cr + 3Si + 6Mn) with the contents of Al, Cr, Si, and Mn being in the same sign terms is 2.3 or more, the balance being Fe and inevitable impurities, and further, the structure of the steel sheet (substrate) consists of ferrite and a second phase, and the second phase is mainly martensite, and discloses a high-strength hot-dip galvanized steel sheet having a hot-dip galvanized layer on the surface of the substrate.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0005] One challenge in improving appearance quality is suppressing the occurrence of ghost lines. Ghost lines are minute irregularities on the order of 1 mm that appear on the surface of steel sheets having a hard phase and a soft phase, such as DP (Dual Phase) steel, when they are press-formed, due to the preferential deformation of the area around the soft phase. Because these irregularities appear as streaks on the surface, press-formed products with ghost lines have inferior appearance quality.

[0006] Due to the need for increased strength and thinner walls in panel components to reduce the weight of automobiles, as well as the increasing complexity of their shapes, the surface of the formed steel sheet tends to become uneven, and ghost lines are more likely to occur.

[0007] This invention was made in view of the above circumstances. The purpose of this invention is to provide a steel sheet that can achieve excellent appearance quality in molded products. [Means for solving the problem]

[0008] The present invention is essentially based on the following steel plate.

[0009] (1) The chemical composition is expressed in mass%, C: 0.030%~0.145%, Si: 0%~0.500%, Mn: 0.50%~2.50% P: 0%~0.100%, S: 0%~0.020%, Al: 0%~1.000%, N: 0%~0.0100%, B: 0%~0.0050%, Mo: 0%~0.80%, Ti: 0%~0.200%, Nb: 0%~0.10%, V: 0%~0.20%, Cr: 0%~0.80%, Ni: 0%~0.25% O: 0%~0.0100%, Cu: 0%~1.00%, W: 0%~1.00%, Sn: 0%~1.00% Sb: 0%~0.20%, Ca: 0%~0.0100%, Mg: 0%~0.0100%, Zr: 0%~0.0100%, REM: 0%~0.0100%, The remainder is iron and impurities. The metallic structure consists of ferrite with a volume fraction of 70-95% and a hard phase with a volume fraction of 5-30%. Vickers hardness H at the 1 / 4 position in the thickness direction of the plate 1 / 4 The standard deviation of the Vickers hardness H 1 / 4 The value X1 obtained by dividing by the average value is 0.025 or less. Vickers hardness H at the 1 / 2 position in the thickness direction of the plate 1 / 2 The standard deviation of the Vickers hardness H 1 / 2 The value X2 obtained by dividing by the average value is 0.030 or less. A steel plate.

[0010] (2) The steel sheet according to (1), characterized in that the average grain size of the ferrite is 5.0 to 30.0 μm and the average grain size of the hard phase is 1.0 to 5.0 μm.

[0011] (3) The steel sheet according to (1) or (2) above, characterized in that in the region of 1 / 4 to 1 / 2 in the thickness direction, the area of ​​the hard phase connected in the rolling direction by 100 μm or more is 30% or less of the total area of ​​the hard phase.

[0012] (4) The steel sheet according to any one of (1) to (3) above, characterized in that the aspect ratio Str (ISO25178) of the surface texture of the test piece after applying a 5% strain by tensile testing is 0.28 or more.

[0013] (5) Vickers hardness H at the 1 / 4 position in the thickness direction 1 / 4 The average value is 150-300. Vickers hardness H at the 1 / 2 position in the thickness direction of the plate 1 / 2The steel plate according to any one of the above (1) to (4), characterized in that the average value is 155 to 305.

[0014] (6) The steel sheet according to any one of (1) to (5) above, characterized in that the hard phase consists of one or more of martensite, bainite, tempered martensite, and pearlite.

[0015] (7) The steel plate according to any one of the above items (1) to (6), characterized in that the thickness of the steel plate is 0.20 mm to 1.00 mm.

[0016] (8) The steel plate according to any one of the above items (1) to (7), characterized in that the steel plate is an automobile exterior panel. [Effects of the Invention]

[0017] According to the above-described embodiment of the present invention, it is possible to provide a steel sheet that can achieve excellent appearance quality in molded products. [Modes for carrying out the invention]

[0018] <Background leading to the invention> The inventors of this invention have investigated a method for suppressing the occurrence of ghost lines after press forming of high-strength steel sheets. As mentioned above, in steel sheets in which hard and soft phases are mixed, such as DP (Dual Phase) steel, deformation mainly occurs around the soft phase during forming, and minute irregularities are created on the surface of the steel sheet, which can result in appearance defects called ghost lines. Ghost lines occur in a band-like (striped) pattern when the soft phase is concave while the hard phase is not concave or even bulges out during press forming of the steel sheet. The band-like structure is formed in the hard phase, such as martensite.

[0019] As a result of diligent research, the inventors have discovered that by controlling the hot-rolled structure during the manufacturing of steel sheets and suppressing the band-like structure, it is possible to suppress the formation of a band-like hard phase in the final product.

[0020] The present invention is based on the above findings, and the steel plate according to this embodiment will be described in detail below. However, the present invention is not limited to the configuration disclosed in this embodiment, and various modifications are possible without departing from the spirit of the invention.

[0021] First, the chemical composition of the steel sheet according to this embodiment will be described. The numerical limits indicated below, separated by a "~", include both a lower and upper limit. Numerical values ​​indicated as "less than" or "greater than" do not include the numerical range. In the following description, percentages related to chemical composition refer to mass percentages unless otherwise specified.

[0022] The steel sheet according to this embodiment has a chemical composition in mass%, C: 0.030%~0.145%, Si: 0%~0.500%, Mn: 0.50%~2.50% P: 0%~0.100%, S: 0%~0.020%, Al: 0%~1.000%, N: 0%~0.0100%, B: 0%~0.0050%, Mo: 0%~0.80%, Ti: 0%~0.200%, Nb: 0%~0.10%, V: 0%~0.20%, Cr: 0%~0.80%, Ni: 0%~0.25% O: 0%~0.0100%, Cu: 0%~1.00%, W: 0%~1.00%, Sn: 0%~1.00% Sb: 0%~0.20%, Ca: 0%~0.0100%, Mg: 0%~0.0100%, Zr: 0%~0.0100%, REM: 0%~0.0100%, The remainder consists of iron and impurities. The following describes each element.

[0023] (C: 0.030%~0.145%) Carbon (C) is an element that increases the strength of steel sheets. To obtain the desired strength, the C content should be 0.030% or more. To further increase the strength, the C content is preferably 0.035% or more, more preferably 0.040% or more, even more preferably 0.050% or more, and even more preferably 0.060% or more. Furthermore, by keeping the carbon content below 0.145%, the diffusion of manganese during solidification is promoted, which can suppress the formation of band-like manganese segregation. As a result, the occurrence of ghost lines after press forming of steel sheets can be suppressed. For this reason, the carbon content should be below 0.145%. Preferably, the carbon content is below 0.110%, and more preferably below 0.090%.

[0024] (Si: 0%~0.500%) Si is a deoxidizing element in steel and is effective in increasing the strength of steel sheets without impairing their ductility. By limiting the Si content to 0.500% or less, the occurrence of surface defects due to reduced scale detachability can be suppressed. Therefore, the Si content should be 0.500% or less. A Si content of 0.450% or less is preferable, 0.250% or less is more preferable, and 0.100% or less is even more preferable. The lower limit of the Si content includes 0%, but in order to improve the strength-formability balance of the steel sheet, the Si content may be 0.0005% or more or 0.0010% or more, more preferably more than 0.090%, and even more preferably 0.100% or more.

[0025] (Mn: 0.50%~2.50%) Mn is an element that enhances the hardenability of steel and contributes to improving its strength. To obtain the desired strength, the Mn content should be 0.50% or more. Preferably, the Mn content is 1.20% or more, more preferably 1.40% or more, even more preferably more than 1.60%, and even more preferably 1.65% or more. Furthermore, if the Mn content is 2.50% or less, the occurrence of striped Mn segregation during the solidification of steel can be suppressed. For this reason, the Mn content should be 2.50% or less. The Mn content is preferably 2.25% or less, more preferably 2.00% or less, and even more preferably 1.80% or less.

[0026] (P: 0%~0.100%) P is an element that embrittles steel. A P content of 0.100% or less can suppress the embrittlement of steel sheets, which can lead to cracking during the production process. Therefore, the P content should be 0.100% or less. A P content of 0.080% or less is preferable, and 0.050% or less is more preferable. While the lower limit for phosphorus content includes 0%, manufacturing costs can be further reduced by setting the phosphorus content to 0.001% or higher. Therefore, the phosphorus content may be set to 0.001% or higher.

[0027] (S: 0%~0.020%) S is an element that forms Mn sulfides, degrading the formability of steel sheets, such as ductility, hole expandability, stretch flangeability, and bendability. A S content of 0.020% or less can suppress a significant decrease in the formability of the steel sheet. Therefore, the S content should be 0.020% or less. A S content of 0.010% or less is preferable, and 0.008% or less is more preferable. While the lower limit for sulfur content includes 0%, manufacturing costs can be further reduced by setting the sulfur content to 0.0001% or higher. Therefore, the sulfur content may be set to 0.0001% or higher.

[0028] (Al: 0%~1.000%) Al is an element that functions as a deoxidizing agent and is effective in increasing the strength of steel. Castability can be increased by keeping the Al content below 1.000%, thus increasing productivity. Therefore, the Al content should be below 1.000%. Preferably, the Al content is below 0.650%, more preferably below 0.600%, and even more preferably below 0.500%. The lower limit of the Al content includes 0%, but the Al content may be 0.005% or higher in order to obtain a sufficient deoxidizing effect from Al.

[0029] (N: 0%~0.0100%) N is an element that forms nitrides, degrading the formability of steel sheets, such as ductility, hole expandability, stretch flangeability, and bendability. When the N content is 0.0100% or less, the decrease in the formability of the steel sheet can be suppressed. Therefore, the N content is set to 0.0100% or less. In addition, N is an element that causes welding defects during welding, hindering productivity. Therefore, the N content is preferably 0.0080% or less, more preferably 0.0070% or less, and even more preferably 0.0040% or less. While the lower limit for N content includes 0%, manufacturing costs can be further reduced by setting the N content to 0.0005% or higher. Therefore, the N content may be set to 0.0005% or higher.

[0030] The steel sheet according to this embodiment may contain the following elements as optional elements. If the following optional elements are not included, the content is 0%.

[0031] (B: 0%~0.0050%) B is an element that suppresses phase transformation at high temperatures and contributes to improving the strength of steel sheets. Since B is not necessarily required, the lower limit of the B content is 0%. In order to obtain a sufficient strength-improving effect from B, the B content is preferably 0.0001% or more, more preferably 0.0005% or more, and even more preferably 0.0010% or more. Furthermore, if the B content is 0.0050% or less, the formation of B precipitates and the resulting decrease in the strength of the steel sheet can be suppressed. For this reason, the B content should be 0.0050% or less, preferably 0.0030% or less. The B content may also be between 0.0001% and 0.0050%.

[0032] (Mo: 0%~0.80%) Mo is an element that suppresses phase transformation at high temperatures and contributes to improving the strength of steel sheets. Since the inclusion of Mo is not mandatory, the lower limit of the Mo content is 0%. To obtain a sufficient strength-improving effect from Mo, the Mo content is preferably 0.001% or more, more preferably 0.05% or more, and even more preferably 0.10% or more. Furthermore, if the Mo content is 0.80% or less, it is possible to suppress the decrease in productivity due to reduced hot workability. For this reason, the Mo content is 0.80% or less, preferably 0.40% or less, and more preferably 0.20% or less. The Mo content may be between 0.001% and 0.80%, or between 0% and 0.40%. Furthermore, it is preferable to include both Cr and Mo, with their content being Cr: 0.20% to 0.80% and Mo: 0.05% to 0.80%, as this can more reliably improve the strength of the steel sheet.

[0033] (Ti: 0%~0.200%) Ti is an element that reduces the amount of sulfur, nitrogen, and oxygen, which generate coarse inclusions that act as fracture initiation points. Furthermore, Ti refines the microstructure and improves the strength-formability balance of the steel sheet. Since Ti is not strictly necessary, the lower limit of Ti content is 0%. To fully obtain the above effects, a Ti content of 0.001% or more is preferable, and 0.010% or more is more preferable. Furthermore, if the Ti content is 0.200% or less, the formation of coarse Ti sulfides, Ti nitrides, and Ti oxides can be suppressed, and the formability of the steel sheet can be ensured. For this reason, the Ti content should be 0.200% or less. Preferably, the Ti content should be 0.080% or less, and more preferably 0.060% or less. The Ti content may be between 0% and 0.100%, or between 0.001% and 0.200%.

[0034] (Nb: 0%~0.10%) Nb is an element that contributes to improving the strength of steel sheets through strengthening by precipitates, strengthening by refining due to the suppression of ferrite grain growth, and strengthening by dislocations due to the suppression of recrystallization. Since Nb is not necessarily required to be included, the lower limit of Nb content is 0%. In order to fully obtain the above effects, the Nb content is preferably 0.001% or more, more preferably 0.005% or more, and even more preferably 0.01% or more. Furthermore, if the Nb content is 0.10% or less, recrystallization can be promoted, suppressing the remaining unrecrystallized ferrite and ensuring the formability of the steel sheet. For this reason, the Nb content is set to 0.10% or less. The Nb content is preferably 0.05% or less, and more preferably 0.04% or less. The Nb content may also be between 0.001% and 0.10%.

[0035] (V: 0%~0.20%) V is an element that contributes to improving the strength of steel sheets through strengthening by precipitates, strengthening by refining due to the suppression of ferrite grain growth, and strengthening by dislocations due to the suppression of recrystallization. Since V does not necessarily have to be included, the lower limit of V content is 0%. In order to obtain a sufficient strength-improving effect from V, the V content is preferably 0.001% or more, more preferably 0.01% or more, and even more preferably 0.03% or more. Furthermore, if the V content is 0.20% or less, it is possible to suppress the precipitation of large amounts of carbonitrides, which would otherwise reduce the formability of the steel sheet. For this reason, the V content should be 0.20% or less. Preferably, the V content is 0.10% or less. The V content may be 0% to 0.10%, or 0.001% to 0.20%.

[0036] (Cr: 0%~0.80%) Cr is an element that enhances the hardenability of steel and contributes to improving the strength of steel sheets. Since Cr is not necessarily required, the lower limit of Cr content is 0%. To fully obtain the strength-enhancing effect of Cr, a Cr content of 0.001% or more is preferable, 0.20% or more is more preferable, and 0.30% or more is particularly preferable. Furthermore, if the Cr content is 0.80% or less, the formation of coarse Cr carbides, which can serve as the starting point for fracture, can be suppressed. For this reason, the Cr content is set to 0.80% or less. The Cr content is preferably 0.70% or less, and more preferably 0.50% or less. The Cr content may be 0% to 0.70%, or 0.001% to 0.80%.

[0037] (Ni: 0%~0.25%) Ni is an element that suppresses phase transformation at high temperatures and contributes to improving the strength of steel sheets. Ni is not necessarily required, so the lower limit of Ni content is 0%. To obtain a sufficient strength-improving effect from Ni, the Ni content is preferably 0.001% or more, and more preferably 0.05% or more. Furthermore, a Ni content of 0.25% or less can suppress a decrease in the weldability of the steel plate. Therefore, the Ni content should be 0.25% or less. Preferably, the Ni content is 0.20% or less, and more preferably 0.15% or less. The Ni content may also be between 0.001% and 0.20%.

[0038] In the following, preferred content levels for each of the optional additive elements O, Cu, W, Sn, Sb, Ca, Mg, Zr, and REM will be described. However, none of these O, Cu, W, Sn, Sb, Ca, Mg, Zr, and REM contribute to ghost line reduction within the content ranges exemplified below. In other words, in this embodiment, O, Cu, W, Sn, Sb, Ca, Mg, Zr, and REM do not affect the effect of reducing the anisotropy of surface irregularities after molding, which is achieved by applying a high reduction ratio in the latter half of the finish rolling process in the hot rolling process described later, resulting in fewer connected hard phases.

[0039] (O: 0%~0.0100%) O is an element that is introduced during the manufacturing process. The O content may be 0%. However, by setting the O content to 0.0001% or more, the refining time can be shortened and productivity can be increased. Therefore, the O content may be 0.0001% or more, 0.0005% or more, or 0.0010% or more. On the other hand, if the O content is 0.0100% or less, the formation of coarse oxides can be suppressed, and the formability of the steel sheet, such as ductility, hole-expandability, stretch flangeability, and / or bendability, can be improved. Therefore, the O content should be 0.0100% or less. The O content may also be 0.0070% or less, 0.0040% or less, or 0.0020% or less.

[0040] (Cu: 0%~1.00%) Cu is an element that exists in steel in the form of fine particles and contributes to improving the strength of steel sheets. The Cu content may be 0%, but to obtain this effect, it is preferable that the Cu content be 0.001% or more. The Cu content may be 0.01% or more, 0.03% or more, or 0.05% or more. On the other hand, by setting the Cu content to 1.00% or less, the weldability of the steel sheet can be improved. Therefore, the Cu content should be 1.00% or less. The Cu content may be 0.60% or less, 0.40% or less, or 0.20% or less.

[0041] (W: 0%~1.00%) W is an element that suppresses phase transformation at high temperatures and contributes to improving the strength of steel sheets. The W content may be 0%, but to obtain this effect, it is preferable that the W content be 0.001% or more. The W content may be 0.01% or more, 0.02% or more, or 0.10% or more. On the other hand, by reducing the W content to 1.00% or less, hot workability can be increased and productivity can be improved. Therefore, the W content should be 1.00% or less. The W content may be 0.80% or less, 0.50% or less, or 0.20% or less.

[0042] (Sn: 0%~1.00%) Sn is an element that suppresses grain coarsening and contributes to improving the strength of steel sheets. The Sn content may be 0%, but to obtain this effect, it is preferable that the Sn content be 0.001% or more. The Sn content may be 0.01% or more, 0.05% or more, or 0.08% or more. On the other hand, by reducing the Sn content to 1.00% or less, the embrittlement of the steel sheet can be suppressed. Therefore, the Sn content should be 1.00% or less. The Sn content may be 0.80% or less, 0.50% or less, or 0.20% or less.

[0043] (Sb: 0%~0.20%) Sb is an element that suppresses grain coarsening and contributes to improving the strength of steel sheets. The Sb content may be 0%, but to obtain this effect, it is preferable that the Sb content be 0.001% or more. The Sb content may be 0.01% or more, 0.05% or more, or 0.08% or more. On the other hand, by reducing the Sn content to 0.20% or less, the embrittlement of the steel sheet can be suppressed. Therefore, the Sb content should be 0.20% or less. The Sb content may be 0.18% or less, 0.15% or less, or 0.12% or less.

[0044] (Ca: 0%~0.0100%) (Mg: 0%~0.0100%) (Zr: 0%~0.0100%) (REM: 0%~0.0100%) Ca, Mg, Zr, and REM are elements that contribute to improving the formability of steel sheets. The content of Ca, Mg, Zr, and REM may be 0%, but to obtain this effect, it is preferable that the content of Ca, Mg, Zr, and REM be 0.0001% or more, and may be 0.0005% or more, 0.0010% or more, or 0.0015% or more. On the other hand, the ductility of the steel sheet can be ensured by keeping the content of each of Ca, Mg, Zr, and REM to 0.0100% or less. Therefore, the content of Ca, Mg, Zr, and REM may be 0.0100% or less, and may be 0.0080% or less, 0.0060% or less, or 0.0030% or less. In this specification, REM refers to the collective term for 17 elements, including scandium (Sc) with atomic number 21, yttrium (Y) with atomic number 39, and the lanthanides from lanthanum (La) with atomic number 57 to lutetium (Lu) with atomic number 71. The REM content is the total content of these elements.

[0045] The remainder of the chemical composition of the steel sheet according to this embodiment may be Fe and impurities. Examples of impurities include those introduced from steel raw materials or scrap and / or during the steelmaking process, or elements that are permissible as long as they do not impair the properties of the steel sheet according to this embodiment. Examples of impurities include H, Na, Cl, Co, Zn, Ga, Ge, As, Se, Tc, Ru, Rh, Pd, Ag, Cd, In, Te, Cs, Ta, Re, Os, Ir, Pt, Au, Pb, Bi, and Po. The total amount of impurities may be 0.200% or less.

[0046] The chemical composition of the steel sheet described above can be measured using general analytical methods. For example, it can be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). C and S can be measured using the combustion-infrared absorption method, and N can be measured using the inert gas fusion-thermal conductivity method. If the steel sheet has a plating layer on its surface, the plating layer should be removed by mechanical grinding before the chemical composition analysis can be performed.

[0047] (The metallic structure consists of ferrite, which accounts for 70-95% by volume, and a hard phase, which accounts for 5-30% by volume.) By making the volume fraction of the hard phase in the metal structure 5% or more, the strength of the steel sheet can be sufficiently improved. Therefore, the volume fraction of the hard phase is set to 5% or more. On the other hand, by making the volume fraction of the hard phase 30% or less, the hard phase can be dispersed more uniformly, so surface irregularities during forming can be reduced and the appearance after forming can be improved. Furthermore, the remainder of the metal structure, excluding the hard phase, is ferrite, and the volume fraction of ferrite is 70-95%. Preferably, the volume fraction of ferrite is 72% or more, and more preferably 75% or more. The volume fraction of the hard phase is preferably 28% or less, and more preferably 25% or less. The sum of the volume fractions of ferrite and the hard phase in the metal structure is 100%.

[0048] In the steel sheet according to this embodiment, the hard phase is a hard structure harder than ferrite, and consists of one or more of the following: martensite, bainite, tempered martensite, and pearlite. From the viewpoint of improving strength, the hard phase is preferably composed of one or more of martensite, bainite, and tempered martensite, and more preferably composed of martensite.

[0049] The volume fraction of the hard phase in a metal structure can be determined by the following method. A sample for observing the metallographic structure (microstructure) is taken from the W / 4 position or 3W / 4 position of the obtained steel sheet width W (i.e., a position W / 4 in the width direction from either end of the steel sheet in the width direction) (size is approximately 20 mm in the rolling direction × 20 mm in the width direction × thickness of the steel sheet). The metallographic structure (microstructure) is observed from the surface to half the thickness of the sheet using an optical microscope, and the area fraction of the hard phase from the surface of the steel sheet (excluding the plating layer if plating is present) to half the thickness of the sheet is calculated. As preparation of the sample, the cross-section of the sheet thickness perpendicular to the rolling direction is polished as the observation surface and etched with a repelling reagent.

[0050] Classify the "microstructure" from optical microscope photographs magnified 500 or 1000 times. When observing with an optical microscope after repeller etching, for example, bainite and pearlite are black, martensite (including tempered martensite) is white, and ferrite is gray, and each structure is observed with color separation, so it is possible to easily distinguish ferrite from other hard structures. In the optical microscope photograph, the area other than the gray indicating ferrite is the hard phase.

[0051] Observe 10 fields at a magnification of 500 or 1000 times in the region from the surface of the steel plate etched with the repeller reagent to the position half of the plate thickness in the plate thickness direction, and perform image analysis using the image analysis software of "Photoshop CS5" manufactured by Adobe to obtain the area fraction of the hard phase. As an image analysis method, for example, the maximum brightness value L max and the minimum brightness value L min are obtained from the image, and the pixels with brightness from L max -0.3(L max -L min ) to L max are defined as the white region, the pixels with brightness from L min to L min +0.3(L max -L min ) are defined as the black region, and the other parts are defined as the gray region, and the area fraction of the hard phase, which is the region other than the gray region, is calculated. For a total of 10 observation fields, perform image analysis as described above to measure the area fraction of the hard phase, average these area fractions to calculate the average value, and use this average value as the volume fraction.

[0052] (The value X1 obtained by dividing the standard deviation σ 1 / 4 of the Vickers hardness H 1 / 4 at the 1 / 4 position in the plate thickness direction by the average value H 1 / 4 of the Vickers hardness H AVE1 / 4 is 0.025 or less) The inventors discovered that when there is a large bias in the Vickers hardness distribution of a steel sheet, the hard phase tends to connect in a band-like manner, and as a result, ghost lines tend to occur in press-formed products of steel sheets. In particular, they focused on the bias in the Vickers hardness distribution in a region relatively close to the surface of the steel sheet. They found that in the rolling direction of the steel sheet, where the bias in the Vickers hardness distribution is small, ghost lines are formed as if they are interrupted midway, and appearance defects caused by long ghost lines can be suppressed. As a result, the Vickers hardness H at the 1 / 4 position in the thickness direction 1 / 4 Standard deviation σ 1 / 4 Vickers hardness H 1 / 4 The mean value H AVE1 / 4 We discovered that setting the value X1 obtained by dividing by 0.025 or less is effective in improving the surface quality of steel plates and molded products formed from these steel plates.

[0053] In this embodiment, Vickers hardness refers to the hardness measured according to the JIS Z 2244:2009 Vickers hardness test. Here, the Vickers hardness is HV0.2, which is the Vickers hardness measured at a test force of 1.9614 N (0.2 kgf).

[0054] In this embodiment, the Vickers hardness is observed in a cross section parallel to the thickness direction and rolling direction of the steel plate (a cross section perpendicular to the width direction), which is the cross section in the center of the width direction of the steel plate.

[0055] Furthermore, the observation at the "1 / 4 position in the thickness direction" refers to an observation where 50 measurement points are set at a position 1 / 4 of the way from the surface of the steel plate in the thickness direction, with a 150 μm pitch in the rolling direction, and 50 measurement points are set at a position 1 / 4 of the way from the back surface of the steel plate in the thickness direction, with a 150 μm pitch in the rolling direction. In this way, by making a length of 150 μm × 50 = 7.5 mm in the rolling direction the observation target, it is possible to measure Vickers hardness including both areas where ghost lines occur and areas where ghost lines do not occur. In other words, by making the observation target a sufficient length in the rolling direction, it is possible to suppress the defect of measuring only areas without ghost lines, and also suppress the measurement of only ghost lines. This makes it possible to perform a more accurate surface quality judgment that takes into account the presence or absence of ghost lines.

[0056] Note that the observation target at the 1 / 4 position in the thickness direction does not have to be as described above. The pitch in the rolling direction of the observation target may be less than 150 μm or greater than 150 μm, but the upper limit of the pitch in the rolling direction shall be 400 μm and the lower limit shall be 50 μm. In addition, the number of measurement points in the rolling direction may be less than 50 or greater than 50, but the lower limit of the measurement points in the rolling direction shall be 30. It is preferable that the length of the observation target in the rolling direction be 5 mm or more in order to perform a more accurate surface quality judgment that takes into account the positions where ghost lines are present and where they are not. Furthermore, in this embodiment, the configuration of the cross section in the width direction of the steel plate is described, but it does not have to be as described. It is sufficient that at least one of the intermediate cross sections in the width direction of the steel plate has the same configuration as described in the cross section configuration.

[0057] The inventors have found that in order to suppress the occurrence of ghost lines in press-formed products, the bias in the Vickers hardness distribution in the rolling direction near the surface of the steel sheet can be reduced, specifically by setting the value X1 to 0.025 or less. Therefore, in this embodiment, the value X1 is set to 0.025 or less. Preferably, the value X1 is 0.020 or less. The lower limit of the value X1 is zero.

[0058] (Vickers hardness H at the 1 / 2 position in the plate thickness direction) 1 / 2 Standard deviation σ 1 / 2 Vickers hardness H 1 / 2 The mean value H AVE1 / 2 (The value obtained by dividing by X² is 0.030 or less.) As mentioned above, by keeping the value X1 below 0.025, the occurrence of ghost lines in press-formed steel sheets can be suppressed. The inventors further focused on the bias in the Vickers hardness distribution in the region deep from the surface of the steel sheet. As a result, the Vickers hardness H at the 1 / 2 position in the thickness direction of the sheet was 1 / 2 Standard deviation σ 1 / 2 Vickers hardness H 1 / 2 The mean value H AVE1 / 2 We discovered that setting the value X2 obtained by dividing by 0.030 or less is effective in further improving the surface quality of steel plates and molded products formed from these steel plates.

[0059] In this embodiment, the observation at the "1 / 2 position in the thickness direction" refers to an observation where 50 measurement points are set at a position halfway from the surface of the steel plate in the thickness direction, with a 150 μm pitch in the rolling direction. The observation at the "1 / 2 position in the thickness direction" and the observation at the "1 / 4 position in the thickness direction" are the same except that the position in the thickness direction of the observation points is different.

[0060] The inventors have found that in order to more reliably suppress the occurrence of ghost lines in press-formed products, the bias in the Vickers hardness distribution in the rolling direction at the center of the steel sheet can be reduced, specifically by setting the value X2 to 0.030 or less. Therefore, in this embodiment, the value X2 is set to 0.030 or less. Preferably, the value X2 is 0.025 or less. The lower limit of the value X2 is zero.

[0061] (The average crystal grain size of ferrite is 5.0 to 30.0 μm) By having an average crystal grain size of 30.0 μm or less, the deterioration of the appearance after molding can be suppressed. Therefore, it is preferable that the average crystal grain size of the ferrite be 30.0 μm or less. More preferably, it be 15.0 μm or less. On the other hand, having an average crystal grain size of 5.0 μm or more suppresses the aggregation and formation of ferrite particles with the {001} orientation. Even if the individual particles of ferrite with the {001} orientation are small, if these particles aggregate and form, deformation will concentrate in the aggregated area. Therefore, suppressing the aggregation of these particles can suppress the deterioration of the appearance after molding. For this reason, it is preferable to have an average crystal grain size of 5.0 μm or more. More preferably 8.0 μm or more, even more preferably 10.0 μm or more, and even more preferably 15.0 μm or more.

[0062] The average grain size of ferrite in a steel sheet can be determined by the following method. Specifically, 10 fields of view are observed at 500x magnification in the region from the surface of the steel sheet etched with Repeller reagent to a point halfway through the sheet thickness. Image analysis is then performed using Adobe Photoshop CS5 image analysis software in the same manner as described above to calculate the area fraction occupied by ferrite and the number of ferrite particles. These are then added together, and the average area fraction per ferrite particle is calculated by dividing the area fraction occupied by ferrite by the number of ferrite particles. The equivalent diameter of a circle is calculated from this average area fraction and the number of particles, and this equivalent diameter is taken as the average grain size of ferrite.

[0063] (Average grain size of the hard phase is 1.0 to 5.0 μm) By having an average grain size of 5.0 μm or less in the hard phase, the deterioration of the appearance after molding can be suppressed. Therefore, it is preferable that the average grain size of the hard phase in the steel sheet be 5.0 μm or less. More preferably, it is 4.5 μm or less, and even more preferably, 4.0 μm or less. On the other hand, if the average grain size of the hard phase is 1.0 μm or more, the aggregation of hard phase particles can be suppressed. By making the individual particles of the hard phase smaller and suppressing the aggregation of these particles, the deterioration of the appearance after molding can be suppressed. For this reason, it is preferable that the average grain size of the hard phase in the steel sheet be 1.0 μm or more. More preferably it is 1.5 μm or more, and even more preferably 2.0 μm or more.

[0064] The average grain size of the hard phase can be determined by the following method. Specifically, 10 fields of view are observed at 500x magnification in the region from the surface of a steel plate etched with Repeller reagent to a point halfway through the plate thickness in the thickness direction. Image analysis is performed using Adobe Photoshop CS5 image analysis software in the same manner as above to calculate the area fraction occupied by the hard phase and the number of particles of the hard phase. These are added together, and the average area fraction per particle of the hard phase is calculated by dividing the area fraction occupied by the hard phase by the number of particles of the hard phase. The equivalent diameter of a circle is calculated from this average area fraction and the number of particles, and the obtained equivalent diameter of a circle is taken as the average grain size of the hard phase.

[0065] (In the region of 1 / 4 to 1 / 2 of the plate thickness, the area of ​​the hard phase connected in the rolling direction by 100 μm or more is 30% or less of the total area of ​​the hard phase.) When the area of ​​the hard phase connected for 100 μm or more in the rolling direction is 30% or less of the total area of ​​the hard phase, the continuity of the upward deformation of the hard phase and the concave deformation of the soft phase surrounding the hard phase when the steel sheet is press-formed is suppressed in the rolling direction, thereby suppressing the occurrence of easily visible ghost lines. Therefore, in this embodiment, it is preferable that the area of ​​the hard phase connected for 100 μm or more in the rolling direction is 30% or less of the total area of ​​the hard phase in the region of 1 / 4 to 1 / 2 in the thickness direction. It is more preferable that this ratio be 20% or less. The lower limit of this ratio is 0%.

[0066] The method for measuring the above ratio in this embodiment is as follows. First, an observation range (connected hard phase observation range) is defined for a cross section of the steel plate parallel to the thickness direction and the rolling direction, specifically the cross section in the width direction of the steel plate, in a region from the surface of the steel plate from 1 / 4 to 1 / 2 of the thickness direction, and extending 400 μm in the rolling direction. The length of the connected hard phase observation range in the rolling direction may be less than 400 μm (for example, 300 μm) or greater than 400 μm (for example, 500 μm). However, the lower limit of the length of the connected hard phase observation range in the rolling direction is 250 μm.

[0067] Next, within the observation range of the linked hard phase, the area AR1 of the linked hard phases that are linked for 100 μm or more in the rolling direction is measured. Specifically, within the observation range of the linked hard phase, the linked hard phases that are linked for 100 μm or more in the rolling direction are extracted by image processing using the hard phase measurement method described above. In this case, "linked" means that the grain boundaries of the hard phases are in contact. Next, within the observation range of the linked hard phase, the area AR2 of the total hard phase is measured using the hard phase measurement method described above. Then, AR1 / AR2 is calculated.

[0068] (The surface texture aspect ratio Str (ISO25178) of the test specimen after applying a 5% strain by tensile testing is 0.28 or higher.) The aspect ratio Str of the surface texture of a test specimen after applying a 5% strain through tensile testing (hereinafter referred to as the "post-tensile test specimen") is an indicator of the anisotropy of the surface irregularities of a molded product obtained by forming a steel sheet (e.g., press forming). The aspect ratio Str is defined in ISO (International Organization for Standardization) 25178 and is a value between zero and 1. The closer the aspect ratio Str is to zero, the greater the anisotropy, and the more visible the surface texture will be within the observed area. On the other hand, the closer the aspect ratio Str is to 1, the less the surface shape within the observed area depends on a specific direction.

[0069] For example, if there are minute convex shapes extending in a predetermined first direction on the surface of the observation area, and multiple such convex shapes are arranged along a second direction perpendicular to the first direction, the surface shape viewed from the first direction and the surface shape viewed from the second direction will have significantly different regularity. In such cases, the surface shape viewed from the first direction and the surface shape viewed from the second direction are significantly different, resulting in high anisotropy, and the aspect ratio Str will be close to zero. On the other hand, if the surface of the tensile test specimen has no directionality in its uneven shape and there are no convex or concave shapes extending long in one direction, the aspect ratio Str will be close to 1. To improve the surface quality of the molded product, it is preferable that the aspect ratio Str of the surface of the tensile test specimen is large and the anisotropy in the surface shape is small. Therefore, it is preferable that the aspect ratio Str of the surface properties of the tensile test specimen is 0.28 or higher. By having an aspect ratio Str of 0.28 or higher on the tensile test specimen, the ghost lines on the surface of the molded product are not excessively long, and the degree of surface quality degradation caused by ghost lines can be reduced. Preferably, the aspect ratio Str of the tensile test specimen is 0.30 or greater, and more preferably 0.35 or greater.

[0070] The method for measuring the aspect ratio Str of a tensile test specimen in this embodiment is as follows. Specifically, a JIS No. 5 test specimen is cut from a position 1 / 4 of the way from the edge of the steel plate in the width direction, perpendicular to the rolling direction of the steel plate (width direction), and the surface of this test specimen is polished with sandpaper to a mirror finish. Next, a tensile test is performed on the test specimen to apply a 5% strain. The surface irregularities of the test specimen with 5% strain are measured using a laser microscope. The aspect ratio Str is calculated from the measurement results. The aspect ratio Str can be calculated in accordance with ISO 25178 by processing the coordinate data of the surface shape obtained by the laser microscope using analysis software. In the analysis, no S filter was used, and the L filter was set to 0.8 mm.

[0071] (Vickers hardness H at the 1 / 4 position in the plate thickness direction) 1 / 4 The mean value H AVE1 / 4 (The value is between 150 and 300.) Vickers hardness H at the 1 / 4 position in the thickness direction of the plate 1 / 4 The mean value H AVE1 / 4 A value of 150 or higher ensures a tensile strength of 540 MPa or higher for the steel plate. Furthermore, the Vickers hardness H at the 1 / 4 position in the plate thickness direction is also important. 1 / 4 The mean value H AVE1 / 4 By keeping the value below 300, the steel plate does not become excessively hard at the 1 / 4 position in the thickness direction, and the effect of smoothing out surface irregularities during the rolling of the steel plate is fully realized.

[0072] In this embodiment, Vickers hardness refers to the hardness measured according to the JIS Z 2244:2009 Vickers hardness test. Vickers hardness H at the 1 / 4 position in the plate thickness direction. 1 / 4 The mean value H AVE1 / 4 It is measured by the following method: 100 points are measured at 50 points each at a 150 μm pitch in the rolling direction, at a position 1 / 4 of the way from the surface and back of the steel plate in the thickness direction, and the average value is taken as H AVE1 / 4 That's what I decided.

[0073] (Vickers hardness H at the 1 / 2 position in the plate thickness direction) 1 / 2 The mean value H AVE1 / 2 (The range is 155-305) Vickers hardness H at the 1 / 2 position in the thickness direction of the plate 1 / 2 The mean value H AVE1 / 2 A value of 155 or higher ensures a tensile strength of 540 MPa or higher for the steel plate. Furthermore, the Vickers hardness H at the 1 / 2 position in the plate thickness direction is also important. 1 / 2 The mean value H AVE1 / 2 By keeping the value below 305, the steel plate does not become excessively hard at the 1 / 2 position in the thickness direction, and the effect of smoothing out surface irregularities during the rolling of the steel plate is fully realized.

[0074] Vickers hardness H at the 1 / 2 position in the thickness direction of the plate 1 / 2 The mean value H AVE1 / 2 The measurement method is the same except that the measurement position in the thickness direction is different, and the Vickers hardness H at the 1 / 4 position in the thickness direction is the same. 1 / 4 The mean value H AVE1 / 4 This is the same measurement method as [another method].

[0075] (The width of the steel plate is 1000 mm or more) The steel sheet molded product of this embodiment is suitable as an automobile panel. Examples of automobile panels include panel-type components such as door outer panels. Examples of panel-type components include hood outer panels, quarter panels such as fender panels, door outer panels, roof panels, etc. In automotive panels, as with automotive structural components, efforts are being made to increase strength, and the strength of hot-rolled sheets during the manufacturing process of steel sheets that will become automotive panels is also increasing. Furthermore, with the thinning of automotive panels, the reduction ratio in the cold rolling process during steel sheet manufacturing is also increasing. Automotive panel steel sheets, especially those for door panels, can exceed 1000 mm in width, and those for hood panels can exceed 1500 mm in width. Such wide steel sheets tend to have a large reduction load (load on the rolling mill) during the cold rolling process. For example, for steel sheets with a tensile strength of 540 MPa, the reduction load during cold rolling becomes particularly large when the width exceeds about 1500 mm, and for steel sheets with a tensile strength of 780 MPa, the reduction load during cold rolling becomes particularly large when the width exceeds about 1200 mm. If the increased reduction load during cold rolling is not addressed, the accuracy of the steel sheet shape will deteriorate. Conventionally, methods to address this increased reduction load during cold rolling have included softening annealing before cold rolling or dividing the cold rolling process into two stages, but these methods have resulted in low productivity and increased manufacturing costs. On the other hand, in this embodiment, (i) it has the chemical composition and metallographic structure of this embodiment, and (ii) the Vickers hardness H at the 1 / 4 position in the thickness direction. 1 / 4 Standard deviation σ 1 / 4 Vickers hardness H 1 / 4 The mean value H AVE1 / 4 The value X1 obtained by dividing by is 0.025 or less, and (iii) the Vickers hardness H at the 1 / 2 position in the plate thickness direction is 1 / 2 Standard deviation σ 1 / 2 Vickers hardness H 1 / 2 The mean value H AVE1 / 2The steel plate is defined as having a value X2 of 0.030 or less when divided by the specified factor. This makes it possible to (a) reduce the rolling load during cold rolling by making the hot-rolled sheet structure softer, and (b) reduce ghost lines in the formed product, even with wide panels as described above.

[0076] (The thickness of the steel plate is 0.20 to 1.00 mm.) The thickness of the steel plate according to this embodiment is not limited to a specific range, but considering versatility and manufacturability, 0.20 to 1.00 mm is preferred. By setting the plate thickness to 0.20 mm or more, it becomes easier to maintain the flatness of the molded product shape, and dimensional accuracy and shape accuracy can be improved. For this reason, the plate thickness is preferably 0.20 mm or more, preferably 0.35 mm or more, and more preferably 0.40 mm or more. On the other hand, reducing the plate thickness to 1.00 mm or less significantly increases the weight reduction effect of the component. Therefore, the plate thickness is preferably 1.00 mm or less, preferably 0.70 mm or less, and more preferably 0.60 mm or less. The thickness of the steel plate can be measured with a micrometer.

[0077] (The tensile strength of the steel plate is 540-980 MPa.) The tensile strength of the steel sheet according to this embodiment is not limited to a specific range, but is preferably 540 to 980 MPa. A tensile strength of 540 MPa or higher allows for the realization of a thin-walled, high-strength steel sheet. Furthermore, a tensile strength of 980 MPa or lower makes it easier to ensure formability when pressing the steel sheet. Tensile strength is measured by taking a JIS No. 5 tensile test specimen from a steel plate with the longitudinal direction perpendicular to the rolling direction, and conducting a test in accordance with JIS (Japanese Industrial Standards) Z2241:2011 Tensile Test Method for Metallic Materials.

[0078] The steel sheet according to this embodiment may have a plating layer on at least one surface of the steel sheet. Examples of plating layers include zinc plating layers and zinc alloy plating layers, as well as alloyed zinc plating layers and alloyed zinc alloy plating layers obtained by alloying these.

[0079] The zinc plating layer and the zinc alloy plating layer are formed by hot-dip galvanizing, electroplating, or vapor deposition. A zinc plating layer with an Al content of 0.5% by mass or less is preferable because it ensures sufficient adhesion between the steel sheet surface and the zinc plating layer. When the zinc plating layer is a hot-dip galvanized layer, the Fe content of the hot-dip galvanized layer is preferably 3.0% by mass or less in order to improve adhesion between the steel sheet surface and the zinc plating layer. When the zinc plating layer is an electro-zinc plated layer, the Fe content of the electro-zinc plated layer is preferably 0.5% by mass or less in terms of improving corrosion resistance.

[0080] The zinc plating layer and zinc alloy plating layer may contain one or more of the following elements: Al, Ag, B, Be, Bi, Ca, Cd, Co, Cr, Cs, Cu, Ge, Hf, Zr, I, K, La, Li, Mg, Mn, Mo, Na, Nb, Ni, Pb, Rb, Sb, Si, Sn, Sr, Ta, Ti, V, W, Zr, and REM, to the extent that they do not impair the corrosion resistance and formability of the steel sheet. In particular, Ni, Al, and Mg are effective in improving the corrosion resistance of the steel sheet.

[0081] The zinc plating layer or zinc alloy plating layer may be an alloyed zinc plating layer or an alloyed zinc alloy plating layer that has undergone an alloying treatment. When an alloying treatment is applied to a hot-dip zinc plating layer or a hot-dip zinc alloy plating layer, it is preferable that the Fe content of the hot-dip zinc plating layer (alloyed zinc plating layer) or hot-dip zinc alloy plating layer (alloyed zinc alloy plating layer) after the alloying treatment be 7.0% by mass to 13.0% by mass, from the viewpoint of improving adhesion between the steel sheet surface and the alloyed plating layer. By applying an alloying treatment to a steel sheet having a hot-dip zinc plating layer or a hot-dip zinc alloy plating layer, Fe is incorporated into the plating layer, and the Fe content increases. As a result, the Fe content can be made 7.0% by mass or more. That is, a zinc plating layer with an Fe content of 7.0% by mass or more is an alloyed zinc plating layer or an alloyed zinc alloy plating layer.

[0082] The Fe content in the plating layer can be obtained by the following method: Dissolve and remove only the plating layer using a 5 vol% HCl aqueous solution with an inhibitor added. The Fe content (mass%) in the plating layer is obtained by measuring the Fe content in the resulting solution using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry).

[0083] (The steel plate is the exterior panel of the automobile.) Next, we will describe press-formed products that can be manufactured by press-forming the steel sheets described above. These press-formed products have the same chemical composition as the steel sheets described above. Furthermore, the press-formed products may have the plating layer described above on at least one surface. Since the press-formed products are obtained by press-forming the steel sheets described above, the occurrence of ghost lines is suppressed, and they have excellent appearance quality. As a result, it is possible to realize highly marketable automobiles with excellent appearance that is directly visible to consumers. Specific examples of press-formed products include, as mentioned above, panel-type parts (automobile exterior panels) such as door outers for automobile bodies. Examples of panel-type parts include hood outer panels, quarter panels such as fender panels, door outer panels, roof panels, etc.

[0084] <About the manufacturing method> Next, a preferred manufacturing method for the steel sheet according to this embodiment will be described. The steel sheet according to this embodiment will have the above-mentioned characteristics regardless of the manufacturing method, as long as it has them. However, the following method is preferred because it can be manufactured stably.

[0085] Specifically, the steel sheet according to this embodiment can be manufactured by a manufacturing method that includes the following steps (i) to (iv). (i) A slab forming process in which molten steel having the above chemical composition is solidified to form a slab, (ii) A hot rolling process in which the slab is heated and hot-rolled to obtain a hot-rolled steel sheet at a rolling end temperature of 950°C or less, and then wound up at 450-650°C. (iii) A cold rolling process in which the wound hot-rolled steel sheet is unwound and cold-rolled to obtain a cold-rolled steel sheet with a cumulative reduction ratio (RCR) of 50-90%. (iv) A step of annealing the cold-rolled steel sheet and then forming the plating layer described above as necessary, The following describes each step.

[0086] [Slab forming process] In the slab forming process, molten steel having a predetermined chemical composition is formed into a slab. The manufacturing method for the slab forming process is not limited. For example, molten steel with the above chemical composition can be produced using a converter or electric furnace, and slabs manufactured by continuous casting can be used. Instead of continuous casting, methods such as ingot casting or thin slab casting may be employed.

[0087] [Hot rolling process] Prior to hot rolling, the slab is heated to over 1100°C. By heating to over 1100°C, the rolling reaction force during the subsequent hot rolling process does not become excessively large, making it easier to obtain the desired product thickness. Furthermore, it allows for higher precision in the sheet shape and smoother winding. While there is no need to limit the upper limit of the heating temperature, from an economic standpoint, it is preferable to keep the heating temperature of the steel billet below 1300°C.

[0088] In the hot rolling process, steel billets heated to the above-mentioned heating temperature are hot-rolled. During hot rolling, rough rolling is followed by finish rolling. In finish rolling, multiple reductions are performed. Finish rolling is performed on multiple consecutive rolling stands, with the reduction ratio in the later rolling stands being greater than that in the earlier rolling stands. The reduction ratio in the first finish rolling is kept below 35%, while the reduction ratio in the second finish rolling is kept above 35%. This allows for a higher reduction ratio in the second finish rolling, resulting in a moderately softened hot-rolled sheet. Consequently, the load on the rolling mill during the cold rolling process can be reduced. Furthermore, the formation of hard phases such as pearlite and martensite in a band-like manner in the structure of the hot-rolled sheet can be suppressed, and the formation of hard phases such as martensite in a band-like manner in the structure of the final molded product can also be suppressed. The ratio P2 / P1 of the reduction ratio P1 at the first rolling stand to the reduction ratio P2 at the second rolling stand is preferably greater than 1.0 and less than or equal to 1.6. By setting P2 / P1 to greater than 1.0, the hot-rolled sheet can be sufficiently softened, and the formation of hard phases in a band-like manner in the structure of the final molded product can be suppressed. Furthermore, by setting P2 / P1 to 1.6 or less, the load on the second rolling stand can be reduced. The reduction ratio at the final rolling stand is preferably 40% or more. This makes it easier to suppress the formation of hard phases such as pearlite and martensite in a band-like manner in the structure of the hot-rolled sheet, and also makes it easier to suppress the formation of hard phases such as martensite in a band-like manner in the structure of the final molded product.

[0089] For finish rolling, for example, seven rolling stands are provided in a row. In this embodiment, the first to third stands are the first half of the rolling process, and the fifth to seventh stands are the second half of the rolling process. The number of rolling stands is not limited; it is sufficient that the rolling rate of the second half of the rolling stands in a group of rolling stands is greater than the rolling rate of the first half of the rolling stands.

[0090] The rolling process should end at 950°C or below. By ending the rolling process at 950°C or below, the average grain size of the hot-rolled steel sheet can be prevented from becoming excessively large. In this case, the average grain size of the final product sheet can also be kept small, ensuring sufficient yield strength and high surface quality after forming.

[0091] The winding temperature in the hot rolling process is preferably 450 to 650°C. By setting the winding temperature to 650°C or lower, the grain size can be made very small, ensuring sufficient steel sheet strength. Furthermore, by suppressing the scale thickness, sufficient pickling properties can be ensured. In addition, by setting the winding temperature to 450°C or higher, the strength of the hot-rolled steel sheet does not increase excessively, reducing the load on the equipment performing the cold rolling process and increasing productivity.

[0092] [Cold rolling process] In the cold rolling process, cold rolling is performed with a cumulative reduction ratio (RCR) of 50-90% to obtain cold-rolled steel sheets. By cold-rolling hot-rolled steel sheets with a predetermined residual stress at the above cumulative reduction ratio, ferrite with the desired texture is obtained after annealing and cooling.

[0093] A cumulative reduction ratio (RCR) of 50% or more ensures sufficient thickness of the steel billet during the hot rolling process, calculated backward from the sheet thickness, making the hot rolling process feasible. Furthermore, a cumulative reduction ratio (RCR) of 90% or less prevents excessive rolling loads, ensuring sufficient uniformity of the material in the width direction. In addition, sufficient production stability is ensured. Therefore, the cumulative reduction ratio (RCR) in cold rolling is set between 50% and 90%.

[0094] [Annealing process] In the annealing process, the cold-rolled steel sheet is heated to a soaking temperature of 750-900°C and held thereafter. A soaking temperature of 750°C or higher allows for sufficient recrystallization of ferrite and reverse transformation from ferrite to austenite, resulting in the desired texture. On the other hand, a soaking temperature of 900°C or lower densifies the crystal grains, resulting in sufficient strength. Furthermore, the heating temperature is not excessively high, allowing for high productivity.

[0095] [Cooling process] In the cooling process, the cold-rolled steel sheet, which has been soaked in the annealing process, is cooled. During cooling, the average cooling rate from the soaking temperature is set to 5.0 to 50°C / second. An average cooling rate of 5.0°C / second or higher prevents excessive promotion of ferrite transformation, allowing for increased formation of hard phases such as martensite, and thus achieving the desired strength. Furthermore, an average cooling rate of 50°C / second or lower allows for more uniform cooling of the steel sheet in the width direction.

[0096] [Plating process] The cold-rolled steel sheet obtained by the above method may be further subjected to a plating process to form a plating layer on its surface.

[0097] [Alloying process] The plating layer formed in the aforementioned plating process may be subjected to alloying. In the alloying process, the alloying temperature is, for example, 450 to 600°C.

[0098] According to the above manufacturing method, by applying a high reduction ratio in the latter half of the finish rolling process during the hot rolling stage, it is possible to produce a steel sheet with fewer connected hard phases. As a result, the anisotropy of the surface irregularities in the formed product is reduced, the occurrence of ghost lines is suppressed, and excellent appearance quality can be obtained. Moreover, in terms of the manufacturability of the steel sheet, the hot-rolled sheet can be softened to a moderate degree, and cold-roll workability can be improved without requiring softening annealing or two cold rollings.

[0099] In this embodiment, the steel sheet after hot rolling is not subjected to shape correction using a leveler as a shape correction device. The steel sheet in this embodiment requires high surface properties to ensure high appearance quality. For this reason, steel sheets that require shape correction by a leveler cannot be used in this embodiment. In other words, the steel sheet in this embodiment is not intended to be manufactured using a special hot rolling process that includes a leveler positioned on the stand exit side of the finish rolling process. Therefore, a leveler is not combined with the steel sheet manufacturing method in this embodiment. [Examples]

[0100] Next, embodiments of the present invention will be described. The conditions in the embodiments are merely examples of conditions adopted to confirm the feasibility and effectiveness of the present invention, and the present invention is not limited to these examples of conditions. The present invention can adopt various conditions as long as they do not depart from the spirit of the invention and achieve the objectives of the present invention.

[0101] Steel with the chemical compositions shown in Table 1 (Nos. A-K) was melted and slabs with a thickness of 200-300 mm were produced by continuous casting. A portion of the obtained slabs was hot-rolled under the conditions shown in Table 2 and then coiled. In the hot-rolling process, seven rolling stands were set up in sequence, with the first three stands (stands 1 to 3) designated as the first half stands and the last three stands (stands 5 to 7) as the second half stands.

[0102] Subsequently, the coil was unwound, and test specimens were cut from the resulting hot-rolled sheet to measure its tensile strength. The tensile strength was evaluated in accordance with JIS Z 2241:2011. The test specimens were No. 5 specimens as specified in JIS Z 2241:2011. The tensile test specimens were taken from the 1 / 4 portion from the end in the width direction of the sheet, with the longitudinal direction being perpendicular to the rolling direction.

[0103] After pickling, cold rolling was performed at the cumulative reduction ratio RCR shown in Table 2 to obtain steel sheets A1 to K1.

[0104] Subsequently, annealing and cooling were performed under the conditions of soaking temperature and cooling rate (average cooling rate) after heating shown in Table 3. In addition, various plating processes were applied to some of the steel plates to form a plating layer on the surface, and alloying treatment was performed at the alloying temperature shown in Table 3. In Table 4, CR indicates no plating, GI indicates hot-dip galvanizing, GA indicates alloyed hot-dip galvanizing, and EG indicates electro-galvanizing.

[0105] The width and thickness of the obtained product boards No. A1a to K1a (i.e., product boards No. A1a to A2a, B1a to B2a, C1a to C2a, D1a to D5a, E1a, F1a, G1a, H1a, I1a, J1a, and K1a) were measured.

[0106] Furthermore, the tensile strength was measured for product plates No. A1a to K1a. The tensile strength was evaluated in accordance with JIS Z 2241:2011. The test specimens used were No. 5 specimens as specified in JIS Z 2241:2011. The tensile test specimens were taken from the 1 / 4 portion from the edge in the width direction of the plate, with the longitudinal direction perpendicular to the rolling direction. If the obtained tensile strength was 540 MPa or higher, it was judged to be high strength and passed. On the other hand, if the obtained tensile strength was less than 540 MPa, it was judged to be weak strength and failed.

[0107] Furthermore, the volume fractions of ferrite and hard phase in the metallographic structure of the obtained product plates No. A1a to K1a were measured using the method described above. In the metallographic structure of product plates No. A1a to K1a, the sum of the volume fractions of hard phase and ferrite is 100%.

[0108] Furthermore, the average grain size of ferrite and the average grain size of the hard phase in the metallic structure of the obtained product plates No. A1a to K1a were measured using the method described above.

[0109] The results are shown in Table 4.

[0110] [Table 1]

[0111] [Table 2]

[0112] [Table 3]

[0113] [Table 4]

[0114] Furthermore, for the obtained product plates No. A1a to K1a, the Vickers hardness H was measured at 50 points in the rolling direction at a position 1 / 4 of the way from the surface in the thickness direction, with measurement intervals of 150 μm. 1 / 4 The Vickers hardness H was measured using the method described above. Furthermore, at a position 1 / 4 of the way from the back surface in the thickness direction, the Vickers hardness H was measured at 50 points in the rolling direction at measurement intervals of 150 μm. 1 / 4 The Vickers hardness H of these 100 points was measured using the method described above. 1 / 4 Standard deviation σ 1 / 4 A Vickers hardness of 100 points H 1 / 4 The mean value H AVE1 / 4 The value X1 was calculated by dividing by [the specified factor].

[0115] Furthermore, for the obtained product plates No. A1a to K1a, the Vickers hardness H was measured at 50 points in the rolling direction at a measurement interval of 150 μm, at a position halfway from the surface in the thickness direction. 1 / 2 The Vickers hardness H of these 50 points was measured using the method described above. 1 / 2 Standard deviation σ 1 / 2 A Vickers hardness of 50 points (H) 1 / 2 The mean value H AVE1 / 2 The value X2 was calculated by dividing by [the specified factor].

[0116] Furthermore, for the obtained product plates No. A1a to K1a, the area ratio of the hard phase connected in the rolling direction to a length of 100 μm or more in the region of 1 / 4 to 1 / 2 of the plate thickness direction was measured using the method described above.

[0117] Furthermore, for each of product plates No. A1a to K1a, the aspect ratio Str of the surface texture was measured using the method described above after applying a 5% strain to a tensile test specimen whose surface had been polished to a mirror finish using abrasive paper or the like.

[0118] Furthermore, for each of the product boards No. A1a to K1a, the surface roughness Wa (arithmetic mean waviness) was measured after applying a 5% strain to tensile test specimens whose surfaces had been polished to a mirror finish using abrasive paper, etc., using the following method. Using a laser displacement measuring device (Keyence VK-X1000), 50 lines of profiles were measured along a direction perpendicular to the rolling direction. At this time, components with wavelengths of 0.8 mm or less and 2.5 mm or more were removed. From the obtained results, the arithmetic mean waviness was calculated in accordance with JIS B 0601:2013, and the average value of the total 50 lines was calculated. This gave the surface roughness Wa of the product board.

[0119] Furthermore, the product of the tensile strength of each product plate (No. A1a to K1a) and the aspect ratio Str of the surface texture of the tensile test specimen was calculated. A higher tensile strength × aspect ratio Str indicates higher strength and lower anisotropy in the surface irregularities despite lower processability.

[0120] The results are shown in Table 5. [Table 5]

[0121] As shown in Tables 1 to 5, the aspect ratio Str of the surface texture of the tensile test specimens in the examples tended to be significantly higher than that of the tensile test specimens in the comparative examples, resulting in less anisotropy in the surface irregularities and superior strength and surface quality. More specifically, all of the examples demonstrated high strength, with tensile strength exceeding 540 MPa. Furthermore, the examples had an aspect ratio Str of 0.28 or higher for the surface texture of the tensile test specimens, and the area of ​​the linked hard phase of 100 μm or more was 30% or less of the total hard phase area, effectively suppressing ghost lines. Moreover, all of the examples showed sufficiently high tensile strength TS × aspect ratio Str exceeding 200, demonstrating high strength and low anisotropy in the surface irregularities despite low processability. Furthermore, the average value of (tensile strength of product sheet - tensile strength of hot-rolled sheet) in the 10 examples was 77, while the average value of (tensile strength of product sheet - tensile strength of hot-rolled sheet) in the 8 comparative examples was approximately 54. In other words, in the examples, a sufficient difference was created between the tensile strength of the product sheet and the tensile strength of the hot-rolled sheet, and softening of the hot-rolled sheet was achieved. In particular, it was demonstrated that the load on the rolling mill during the cold-rolling process was reduced for wide product sheets suitable for automobile hood panels and automobile door panels.

[0122] On the other hand, in the comparative examples, product plates No. A2a and B2a, the reduction ratio in the latter half of the finish rolling during hot rolling was small, which prevented sufficient smoothing of the streaky irregularities on the steel plate surface. As a result, in the region from 1 / 4 to 1 / 2 of the rolling direction, the area ratio of hard phases connected for 100 μm or more in the rolling direction exceeded 40%. Furthermore, the aspect ratio Str of the surface properties of the tensile test specimen was below 0.28, and the tensile strength TS × aspect ratio Str was below 180, resulting in poor surface quality after forming. Furthermore, in the comparative examples, product plates No. C2a and D2a, the reduction ratio in the latter half of the finish rolling during hot rolling was small, which prevented sufficient smoothing of the streaky irregularities on the steel plate surface. As a result, in the region from 1 / 4 to 1 / 2 of the rolling direction, the area ratio of hard phases connected for 100 μm or more in the rolling direction exceeded 30%. In addition, the aspect ratio Str of the surface properties of the test specimen after tensile strength was below 0.28, and the tensile strength TS × aspect ratio Str was below 170, resulting in poor surface quality after forming. Furthermore, in the comparative example, product plate No. D5a, although the ratio P2 / P1 of the reduction ratio P1 in the first half of the hot rolling process to the reduction ratio P2 in the second half was within the range of greater than 1.0 and less than or equal to 1.6, the small reduction ratio in the second half prevented sufficient smoothing of the streaky irregularities on the steel plate surface. In the region from 1 / 4 to 1 / 2 of the rolling direction, the area ratio of hard phases connected by 100 μm or more in the rolling direction exceeded 30%. In addition, the aspect ratio Str of the surface properties of the test specimen after tensile strength was below 0.28, and the tensile strength TS × aspect ratio Str was below 170, resulting in poor surface quality after forming.

[0123] Furthermore, in comparative example No. E1a, the carbon content exceeded the preferred range, making band-shaped Mn segregation more likely. As a result, in the 1 / 4 to 1 / 2 region of the rolling direction, the area ratio of the hard phase connected for 100 μm or more in the rolling direction exceeded 30%, and the tensile strength TS × aspect ratio Str was below 180, resulting in poor surface quality after forming. In comparative example No. F1a, the carbon content did not reach the preferred range, and the volume fraction of ferrite was excessive while the volume fraction of the hard phase was low, resulting in a low tensile strength of less than 540 MPa. In comparative example No. G1a, the Mn content exceeded the preferred range, resulting in band-shaped Mn segregation during steel solidification. As a result, in the region from 1 / 4 to 1 / 2 of the rolling direction, the area ratio of hard phases connected by 100 μm or more in the rolling direction exceeded 40%, and the tensile strength TS × aspect ratio Str was below 170, resulting in poor surface quality after molding.

[0124] Here, we compare product plates No. A1a and A2a, No. B1a and B2a, No. C1a and C2a, and No. D1a and D2a, which have the same plate thickness. The surface roughness Wa of product plates No. A1a, B1a, C1a, and D1a, which are examples, is 0.058 μm, 0.055 μm, 0.058 μm, and 0.055 μm, respectively. On the other hand, the surface roughness Wa of product plates No. A2a, B2a, C2a, and D2a, which are comparative examples, is 0.050 μm, 0.053 μm, 0.056 μm, and 0.055 μm, respectively. Thus, the surface roughness Wa of product board No. A1a, an example, is greater than or equal to the surface roughness Wa of product board No. A2a, a comparative example, and the surface roughness Wa of product boards No. B1a, C1a, and D1a, also examples, is greater than or equal to the surface roughness Wa of product boards No. B2a, C2a, and D2a, respectively. On the other hand, the aspect ratio Str of product boards No. A1a, B1a, C1a, and D1a, all examples, is greater than the aspect ratio Str of product boards No. A2a, B2a, C2a, and D2a, respectively. In this way, it has been demonstrated that product boards No. A1a, B1a, C1a, and D1a, examples, exhibit superior surface quality due to their high aspect ratio Str despite having surface roughness Wa greater than or equal to the surface roughness Wa of product boards No. A2a, B2a, C2a, and D2a, respectively, resulting in less anisotropy in surface irregularities. [Industrial applicability]

[0125] According to the above-described embodiment of the present invention, it is possible to provide a steel sheet that can achieve excellent appearance quality in molded products.

Claims

1. The chemical composition is expressed in mass percent. C: 0.030% to 0.145%, Si: 0% to 0.500%, Mn: 0.50% to 2.50%, P: 0% to 0.100%, S: 0% to 0.020%, Al: 0% to 1.000%, N: 0% to 0.0100%, B: 0% to 0.0050%, Mo: 0% to 0.80%, Ti: 0% to 0.200%, Nb: 0% to 0.10%, V: 0% to 0.20%, Cr: 0% to 0.80%, Ni: 0% to 0.25% O: 0% to 0.0100%, Cu: 0% to 1.00%, W: 0% to 1.00%, Sn: 0% to 1.00%, Sb: 0% to 0.20%, Ca: 0% to 0.0100%, Mg: 0% to 0.0100%, Zr: 0% to 0.0100%, REM: 0% to 0.0100%, The remainder is iron and impurities. The metallic structure consists of ferrite with a volume fraction of 70-95% and a hard phase with a volume fraction of 5-30%. Vickers hardness H at the 1 / 4 position in the thickness direction of the plate １／４ The standard deviation of the Vickers hardness H １／４ The value X1 obtained by dividing by the average value is 0.025 or less. Vickers hardness H at the 1 / 2 position in the thickness direction of the plate １／２ The standard deviation of the Vickers hardness H １／２ The value obtained by dividing by the average value X² is 0.030 or less. A steel plate.

2. The steel sheet according to claim 1, characterized in that the average grain size of the ferrite is 5.0 to 30.0 μm and the average grain size of the hard phase is 1.0 to 5.0 μm.

3. The steel sheet according to claim 1 or 2, characterized in that, in the region of 1 / 4 to 1 / 2 in the thickness direction, the area of ​​hard phases connected in the rolling direction by 100 μm or more is 30% or less of the total area of ​​hard phases.

4. The steel plate according to any one of claims 1 to 3, characterized in that the aspect ratio Str (ISO 25178) of the surface texture of the test piece after applying a 5% strain by tensile testing is 0.28 or more.

5. Vickers hardness H at the 1 / 4 position in the thickness direction of the plate １／４ The average value is 150-300. Vickers hardness H at the 1 / 2 position in the thickness direction of the plate １／２ The steel plate according to any one of claims 1 to 4, characterized in that the average value is 155 to 305.

6. The steel sheet according to any one of claims 1 to 5, characterized in that the hard phase consists of one or more of martensite, bainite, tempered martensite, and pearlite.

7. The steel plate according to any one of claims 1 to 6, characterized in that the thickness of the steel plate is 0.20 mm to 1.00 mm.

8. The steel plate according to any one of claims 1 to 7, characterized in that the steel plate is an automobile exterior panel.

Images