Solid composition containing sunflower wax, candelilla wax, and non-volatile ester oil, and its use

Abstract

The present invention relates to a solid composition in stick form for making up and / or caring for the skin and / or lips, comprising: - with sunflower wax; - with candelilla wax; - at least one triglyceride chosen from caprylic triglyceride, capric triglyceride, caprylic / capric triglyceride, or mixtures thereof; - at least one vegetable oil, other than castor oil, if castor oil is present, in a content not exceeding 5% by weight relative to the total weight of the composition; - Linear or branched C6-C 10 Dicarboxylic acids, diglycerol, and optionally hydroxylated linear or branched C6-C 20 and at least one polyester derived from the condensation of an ester with a monocarboxylic acid. The invention further relates to a method for making up and / or caring for the skin and / or lips, which method comprises applying said composition.

Description

[Technical Field]

[0001] The present invention relates particularly to a solid makeup and / or care composition for the lips, the composition being in the form of a stick, and also includes ester oils containing certain plant waxes and plant oils. [Background technology]

[0002] Cosmetic compositions for care and / or makeup, particularly for the lips, have been known for a very long time and are available in the form of more or less viscous fluids, such as oils and glosses for the lips, ranging from more fluid to more viscous, in the form of solid compositions in the form of rods, pencils, or compositions stored in jars, with or without support.

[0003] Historically, lip compositions were generally anhydrous, but in recent years, emulsion-type lip makeup compositions have emerged.

[0004] The use of film-forming products, particularly silicone products, improved the functional properties of this composition, such as enhanced durability and reduced migration.

[0005] This composition further allows for obtaining matte, satin, or glossy makeup results, depending on the components present, such as silicone or non-silicone volatile oils, and mineral or organic fillers.

[0006] In recent years, a new trend has become evident among consumers: while they still pay some attention to it, they are less focused solely on the performance and quality of makeup formulations. This is because the ingredients used, particularly their natural properties, are becoming increasingly important. [Overview of the project] [Means for solving the problem]

[0007] The present invention is in line with this trend and therefore relates, more specifically, to solid compositions for makeup and / or care, most specifically for lips, that promote the use of naturally derived, particularly plant-derived, compounds. Furthermore, compositions according to the present invention are advantageous in that they allow for limiting the content of components, particularly those derived from petrochemicals, such as hydrocarbon-type oils, nonpolar hydrocarbon waxes, such as polyethylene or polymethylene wax, and even more so, silicone components.

[0008] One difficulty arising from naturally derived ingredients is that, particularly due to their affinity with vegetable oils, natural waxes do not always properly structure the oils, resulting in sticks that are too soft or too hard, preventing satisfactory application of the composition and / or causing the sticks to break. Furthermore, problems with the stability of the composition, especially during storage, can arise. This phenomenon can be demonstrated by stability tests commonly employed for compositions in stick form. For example, if a stick is stored upside down ("head down") at a high temperature (45°C) for a period of one week to two months, the presence of oil seepage, accompanied by the appearance of oil droplets, may be observed on the surface of the stick body, especially at the slanted end. In fact, if this seepage is observed under such laboratory conditions, there is a high risk that it will be repeated under actual consumer use and storage conditions for lipstick, which is clearly undesirable.

[0009] Therefore, one of the objectives of the present invention is, more specifically, to propose a solid composition in the form of a stick that is stable, does not leach oil, and has appropriate hardness to allow for easy, even, and sufficient application of the composition without the stick breaking. In addition, the resulting application should be comfortable, non-drying, and show little transfer to wrinkles and fine lines around the lips.

[0010] Since these objectives are achieved by the present invention, one subject is a solid composition for makeup and / or care of the skin and / or lips, comprising the following: * Sunflower wax, * Candelilla wax, * At least one triglyceride selected from triglycerides of caprylic acid, triglycerides of capric acid, triglycerides of caprylic / capric acid, or mixtures thereof, preferably caprylic / capric triglyceride (INCI name), * At least one vegetable oil excluding castor oil (when castor oil is present, the content of castor oil does not exceed 5% by mass based on the total mass of the composition), * Linear or branched C6 - C 10 Dicarboxylic acid, diglycerol, and optionally at least one polyester derived from the condensation of esters of hydroxyl - ated linear or branched C6 - C 20 Monocarboxylic acid, preferably bis - diglyceryl polyacyl adipate - 2 (INCI name).

[0011] The present invention also relates to a process for making up and / or caring for the skin and / or lips, particularly the lips, to which the composition according to the invention is applied.

[0012] Therefore, the composition according to the invention is stable without any change in form or oil exudation when stored at 4 °C, 20 °C, and 45 °C for 1 week, 30 days, and 60 days. Furthermore, the composition retains its sensory - stimulating properties, particularly its odor and color. No crystals appear on the surface of the stick body. The composition according to the invention is also easy to apply a sufficient amount uniformly. The composition has moderate adhesiveness, almost no transfer, and provides an accurate deposit with satisfactory persistence over time. This deposit does not dry the lips and remains comfortable.

Embodiments for Carrying out the Invention

[0013] These and other advantages of the present invention will become more apparent upon reading the following description and examples.

[0014] In other parts of this specification, unless otherwise specifically indicated, it should be noted that the limit values shown for ranges are included within those ranges.

[0015] The expressions "at least one" and "several" are used interchangeably.

[0016] In addition, the sum of the amounts of the components in the composition represents 100% of the total mass of the composition.

[0017] Procedure for evaluating stability The compositions were evaluated 24 hours after casting the rods, which were stored at room temperature (20°C) prior to the test. For stability testing, the rods were placed in ovens at 4°C, 20°C (room temperature), and 45°C for two months. One sample was in an upright position (top of the rod facing up) and the other sample was in an inverted position (top of the rod facing down). For each sample, its appearance, color, and odor are analyzed before the start of the test, one week after stabilization, one month after stabilization, and finally two months after stabilization. After observation, each sample is placed in the oven as is (without wiping, in particular) and left in its original position until the next analysis. At each stage of analysis, the rods are observed for their first appearance / color / odor immediately after being removed from the oven, and for those stored at 4°C and 45°C, a second observation is performed after they have reached room temperature. Exudation refers to the appearance of gelled or non-gelled oil droplets on the surface of the rod (the rod body). This phenomenon is more pronounced when the rod is stored with its head down, in which case the droplets appear at the ends of the rod body. This phenomenon is distinct from another transient phenomenon (known as sweating) that may occur, particularly during sudden temperature changes in a rod that has been stored for at least one month (for example, when a rod body stored at 4°C returns to room temperature). This sweating is indicated by the appearance of numerous fine droplets distributed throughout the rod body.

[0018] Hardness measurement procedure The hardness of the composition is measured according to the following procedure: The lipstick is stored at 20°C for 16 hours before its hardness is measured. Hardness can be measured at 20°C by the "cheese wire" method, which involves cutting a product, preferably a cylindrical rod, using a high-rigidity tungsten wire with a diameter of 250 μm, by moving the wire across the rod at a speed of 100 mm / min. The hardness of a test specimen of the composition of the present invention is Nm -1 It is expressed as and measured using the DFGS2 tensile testing machine sold by Indelco-Chatillon. The measurement is repeated three times, and the average is taken. The average of the three readings obtained using the tensile testing machine described above (represented by Y) is given in grams. This average value is converted to Newtons, and then divided by L (which represents the maximum distance the wire has traveled). In the case of a cylindrical rod, L corresponds to the diameter (in meters). Hardness is expressed in Nm using the following formula -1 Convert to: (Y×10 -3 ×9.8) / L For measurements at different temperatures, the rod is stored at the new temperature for 24 hours before measurement. According to this measurement method, the composition according to the present invention preferably has a reading of 70-200 Nm at 20°C and atmospheric pressure. -1 , advantageously 75-195 Nm -1 Preferably 100-160 Nm -1 It has a hardness of [value].

[0019] Sunflower wax As previously indicated, the compositions according to the present invention include at least sunflower wax. Sunflower wax (INCI name: Helianthus anas (sunflower) seed wax) is obtained from sunflower seeds. Sunflower wax is particularly sold by Koster Keunen.

[0020] More specifically, the composition according to the present invention has a sunflower wax content of 1% to 9% by mass, preferably 2% to 8% by mass, based on the total mass of the composition.

[0021] Candelilla wax This invention further comprises candelilla wax (INCI name: Euphorbia cerifera (candelilla) wax). Candelilla wax is particularly sold by Multiceras.

[0022] More specifically, the composition according to the present invention has a candelilla wax content of 0.25% to 7% by mass, preferably 0.5% to 6% by mass, and more specifically 1.5% to 6% by mass, based on the total mass of the composition.

[0023] Additional wax Polar wax The compositions according to the present invention may optionally further contain at least one additional polar hydrocarbon wax other than sunflower wax and candelilla wax.

[0024] More specifically, waxes are generally solid at room temperature (20°C), undergo reversible solid / liquid phase changes, and are lipophilic compounds with melting points between 40°C and 120°C, and more specifically between 90°C. For the purposes of this invention, the melting point corresponds to the temperature of the highest endothermic peak observed by thermal analysis (DSC) as described in ISO standard 11357-3;1999. The melting point of wax can be measured using a differential scanning calorimeter (DSC), such as the DSC Q2000 sold by TA Instruments with TA Universal Analysis software. The measurement procedure is as follows: A 5 mg sample of wax placed in a crucible is subjected to a first temperature increase in the range of -20°C to 120°C at a heating rate of 10°C / min, then cooled from 120°C to -20°C at a cooling rate of 10°C / min, and finally subjected to a second temperature increase in the range of -20°C to 120°C at a heating rate of 5°C / min. During the second temperature rise, when the melting point of the solid fat substance is measured, this corresponds to the temperature of the highest endothermic peak observed in the melting curve and represents the variation in the difference in energy absorbed as a function of temperature. The melting enthalpy (ΔHf) of the wax corresponding to the integral of the entire melting curve can also be measured. This heat of fusion of the wax is the amount of energy required to cause the change of the compound from the solid state to the liquid state. This is expressed in J / g.

[0025] More specifically, the additional polar hydrocarbon waxes are selected from hydrocarbon waxes containing ester functional groups. The term "polar hydrocarbon wax" means a wax that is essentially formed from carbon atoms and hydrogen atoms, or further composed of carbon atoms and hydrogen atoms, and contains at least one oxygen atom and optionally a nitrogen atom. Therefore, these compounds do not contain silicon atoms. According to the present invention, the term "ester wax" means a wax containing at least one ester functional group. The ester wax can be further hydroxylated.

[0026] Among the polar hydrocarbon waxes that can be used in the context of the present invention, the following can be mentioned: (i) A wax of the formula R1COOR2, wherein R1 and R2 represent a linear, branched or cyclic aliphatic chain having a number of atoms in the range of 10 to 50, which can contain heteroatoms, particularly oxygen, and its melting point is in the range of 40°C to 120°C, preferably 40°C to 100°C. In particular, as the ester wax, C 20 ~C 40 alkyl (hydroxystearyloxy) stearate (the alkyl group contains 20 to 40 carbon atoms), alone or as a mixture, or C 20 ~C 40Alkyl stearates can be used. These waxes are particularly sold by Koster Keunen under the names Kester Wax® K 82 P, Hydroxypolyester® K 82 P, Kester Wax® K 80 P, and Kester Wax® K82H. 14 ~C 18 Mixtures of carboxylic acid esters and alcohols can also be used, such as Koster Keunen's Cetyl Ester Wax 814, Croda's SP Crodamol MS MBAL and Crodamol MS PA, and Laserson's Miraceti. (ii) A diester wax of a dicarboxylic acid having the general formula R3-(-OCO-R4-COO-R5), where R3 and R5 are the same or different, preferably the same, and C4~C 30 R4 represents an alkyl group, and R4 may or may not contain one or more unsaturated C4-C4 atoms. 30 Represents an aliphatic group. Preferably C4~C 30 Aliphatic groups are linear and unsaturated. (iii) Saturated C, either alone or in a mixture, optionally hydroxylated 16 ~C 30 Partial or full esters of carboxylic acid and glycerol, preferably full esters, such as glyceryl tristearate (INCI name: tristearin), glyceryl trihydroxystearate (INCI name: trihydroxystearin), and glyceryl tribehenate (INCI name: tribehenin). (iv) Waxes of animal or plant origin. Examples of waxes suitable for use include beeswax, carnauba wax, macadamia wax, lanolin wax, rice bran wax, ouricury wax, African honeysuckle wax, shellac wax, cork fiber wax, sugarcane wax, wood wax (ICNI name: lacquer tree bark wax), rhodochrosite wax, montane wax, orange wax, and lemon wax, which may be refined or unrefined. (v) Waxes obtained by hydrogenation of animal or vegetable oils, especially linear or branched C8-C 32 Waxes obtained by catalytic hydrogenation of vegetable oils containing fatty chains, such as hydrogenated jojoba oil, hydrogenated sunflower oil, hydrogenated castor oil, or hydrogenated camelina oil, can also be mentioned. In addition, waxes obtained by hydrogenating castor oil esterified with cetyl alcohol or behenyl alcohol can be mentioned, such as those sold by Sophim under the names Phytowax® Ricin 16L64 and Phytowax® Ricin 22L73. Such waxes are described in French Patent Application Publication No. 2792190. Waxes obtained by hydrogenating olive oil esterified with stearyl alcohol or lauryl alcohol can be mentioned, such as those sold under the names Phytowax® Olive 18 L 57 or Phytowax® Olive 12 L 44. (vi) A mixture of these.

[0027] Preferably, if the composition contains additional polar hydrocarbon waxes, they are selected from animal or plant-derived waxes other than sunflower wax and candelilla wax; waxes obtained by hydrogenation of animal or vegetable oils; and mixtures thereof. More specifically, the additional polar hydrocarbon waxes are selected from beeswax, carnauba wax, rice bran wax, aurichalle wax, African honeysuckle wax, wood wax, shellac wax, cork fiber wax, sugarcane wax, lacquer wax, montan wax, orange wax and lemon wax; hydrogenated jojoba oil, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated camelina oil, and waxes obtained by hydrogenation of esterified castor oil; and mixtures thereof.

[0028] If the composition according to the present invention contains one or more additional polar hydrocarbon waxes other than sunflower wax and candelilla wax, their content represents 0.25% to 9% by mass, particularly 0.5% to 8% by mass, and preferably 1.5% to 8% by mass, based on the total mass of the composition.

[0029] Additional non-polar wax Preferably, the compositions according to the present invention do not contain nonpolar hydrocarbon waxes (in other words, waxes composed only of carbon and hydrogen atoms). Examples include waxes resulting from the conversion of petroleum, either alone or in mixtures, such as polyethylene wax, polymethylene wax (INCI name: synthetic wax, Fischer-Tropsch wax), or paraffin wax; in addition, ceresin or ozokerite type waxes are also included.

[0030] However, if the composition contains it, the amount thereof will not exceed 2% by mass, preferably not exceeding 1% by mass, and advantageously not exceeding 0.5% by mass, relative to the total mass of the composition.

[0031] Finally, according to a particularly advantageous embodiment of the present invention, the total content of the polar wax is in the range of 6% to 26% by mass, preferably 6% to 18% by mass, based on the total mass of the composition.

[0032] Solid polyester The composition according to the present invention is linear or branched C6-C 10 Dicarboxylic acid, diglycerol ester, and optionally hydroxylated linear or branched C6-C6 compounds. 20 The present invention includes at least one polyester obtained by condensation with a monocarboxylic acid, which is solid at room temperature, or more specifically, paste-like. Specific examples include a mixture of adipic acid and diglycerol esters, and C6-C polyesters such as caprylic acid, capric acid, stearic acid, isostearic acid, and 12-hydroxystearic acid. 20Diesters obtained by condensation with a mixture of fatty acids and having the INCI name bis-diglyceryl polyacyladipate-2 are suitable for carrying out the present invention. This type of compound is particularly marketed by Cremer Oleo under the reference name Softisan® 649.

[0033] According to a particular embodiment of the present invention, the content of solid polyester is advantageously 5% to 35% by mass, preferably 7% to 25% by mass, based on the total mass of the composition.

[0034] Paste-like hydrocarbon compounds The composition according to the present invention may optionally contain at least one paste-like hydrocarbon compound other than the solid polyester described above.

[0035] The term "hydrocarbon" refers to compounds that are essentially formed from carbon and hydrogen atoms, or further composed of carbon and hydrogen atoms, and further containing at least one oxygen atom and optionally a nitrogen atom. Therefore, this type of compound is distinct from silicone compounds.

[0036] For the purposes of this invention, the term "paste-like compound" means a lipophilic fatty compound that undergoes a reversible solid / liquid state change and contains a liquid fraction and a solid fraction at a temperature of 20°C. Therefore, paste-like compounds may have an initial melting point below 20°C. Furthermore, paste-like compounds may have an anisotropic crystalline structure in the solid state. The melting point of a paste-like fatty substance is determined according to the same principle as previously detailed for waxes. However, in the case of paste-like compounds, the measurement procedure is as follows: A 5 mg sample of a paste-like fatty substance placed in a crucible is subjected to a first temperature increase in the range of -20°C to 100°C at a heating rate of 10°C / min, then cooled from 100°C to -20°C at a cooling rate of 10°C / min, and finally subjected to a second temperature increase in the range of -20°C to 100°C at a heating rate of 5°C / min. The melting point of a paste-like fatty substance is the temperature value corresponding to the peak of the curve that represents the fluctuation of the difference in absorbed energy as a function of temperature. It should be noted that the liquid fraction (by mass) of a paste-like fatty substance at room temperature is equal to the ratio of the heat of fusion consumed at room temperature to the heat of fusion of the paste-like fatty substance. The heat of fusion of a paste-like fatty substance is the heat consumed by the substance to transition from a solid state to a liquid state. A paste-like fatty substance is said to be in a solid state if the entire substance is in a crystalline solid state. A paste-like fatty substance is said to be in a liquid state if the entire substance is in a liquid state. The heat of fusion of a paste-like fatty substance is the amount of energy required to change it from a solid state to a liquid state. It is expressed in J / g. The heat of fusion of a paste-like fatty substance is equal to the area under the curve of the resulting thermogram.

[0037] Preferably, this or these paste-like hydrocarbon compounds are selected from the following: - Vegetable butters, such as mango butter, for example, the product sold by Aarhuskarlshamn under the reference name Lipex® 203; shea butter, especially products with the INCI name Shea Butter (Butyrospermum parkii Butter), for example, the product sold by Aarhuskarlshamn under the reference name Sheasoft®; cupuacu butter (Rain Forest RF3410 by Beraca Sabara); murumuru butter (Rain Forest RF3710 by Beraca Sabara); cocoa butter; babassu butter, for example, the product sold by Croda under the reference name Cropure® Babassu; in addition, orange wax, for example, the product sold by Koster Keunen under the reference name Orange Peel Wax. - Whole or partially hydrogenated vegetable oils, e.g., hydrogenated soybean oil, hydrogenated coconut kernel oil, hydrogenated rapeseed oil, mixtures of hydrogenated vegetable oils (e.g., mixtures of hydrogenated soybean oil, hydrogenated coconut kernel oil, hydrogenated palm oil and hydrogenated rapeseed oil, e.g., mixtures sold by Aarhus Karlshamn under the reference name Akogel® (INCI name: Hydrogenated Vegetable Oil)), trans-isomerized partially hydrogenated jojoba oil manufactured or sold by Desert Whale under the reference name Iso-Jojoba-50®, partially hydrogenated olive oil (e.g., compounds sold by Soliance under the reference name Beurolive), - Hydrogenated castor oil and C 16 ~C 22 Fatty acids, especially esters with isostearic acid, for example, Salacos HCIS (VL), hydrogenated castor oil isostearate (INCI name), sold by Nissin Oil. - Optionally (fully or partially) hydrogenated, saturated or unsaturated, linear or branched, optionally mono- or polyhydroxylated, preferably C 12 ~C 18 Saturated C2500 is a fatty acid triglyceride; for example, a saturated C2500 sold by Cremer Oleo under the name Softisan 100®. 12 ~C 18 Fatty acid glycerides (INCI name: hydrogenated cocoglycerides), - Esters of an alcohol or polyol diol dimer and an acid dimer, for example: *The hydroxyl group is esterified with a mixture of phytosterol, behenyl alcohol, and isostearyl alcohol, for example, the INCI name is behenyl / isostearyl / phytosteryl dimer dilinoleyl dimer dilinoleyl bis, and is particularly sold by Nippon Fine Chemical under the name Plandool G, an ester of dimer ol (e.g., dilinoleyl alcohol) and dilinoleic acid; *Esters of dilinoleic acid with a mixture of phytosterol, isostearyl alcohol, cetyl alcohol, stearyl alcohol, and behenyl alcohol, for example, INCI name: phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate, especially those sold by Nippon Fine Chemical under the names Plandool H or Plandool S; *Esters of hydrogenated castor oil and dilinoleic acid, such as hydrogenated castor oil dimer dilinoleate (INCI name), for example, those sold by Kokyu Alcohol Kogyo under the names Risocast-DA-L or Risocast-DA-H.

[0038] Preferably, if the composition contains, the paste-like hydrocarbon compound is a vegetable butter, partially hydrogenated vegetable oil, linear or branched, saturated or unsaturated, optionally monohydroxylated or polyhydroxylated, preferably C 12 ~C 18 Selected from fatty acid triglycerides and mixtures thereof.

[0039] More preferably, if the composition contains, the paste-like hydrocarbon compound is selected from vegetable butter, partially or fully hydrogenated vegetable oil, compounds whose INCI name is hydrogenated cocoglyceride, and mixtures thereof.

[0040] If the composition contains at least one paste-like hydrocarbon compound other than a solid polyester, their content is such that the amounts of the solid polyester and the paste-like hydrocarbon compound are in the range of 5% to 35% by mass, preferably 7% to 25% by mass, relative to the total mass of the composition.

[0041] Furthermore, if the composition contains, as a paste-like hydrocarbon compound, at least one compound selected from diol dimers, or esters of alcohols or polyols with dioxide dimers, particularly those having the following INCI names: bisbehenyl / isostearyl / phytosteryl dimer dilinoleyl dimer dilinoleate, phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate, hydrogenated castor oil dimer dilinoleate, or mixtures thereof, then their content is 1% to 15% by mass, more specifically 2% to 12% by mass, relative to the total mass of the composition; the content of the solid polyester and paste-like hydrocarbon compound remains 5% to 35% by mass, preferably 7% to 25% by mass, relative to the total mass of the composition.

[0042] Triglycerides As previously shown, the composition comprises at least one triglyceride selected from caprylic acid triglyceride, capric acid triglyceride, caprylic acid / capric acid triglyceride (more specifically, a triglyceride of a mixture of caprylic acid and capric acid), or a mixture thereof. These triglycerides are at room temperature (20°C) and atmospheric pressure (1.013 × 10⁻⁶). 5 At Pa), it is in liquid form. Preferably, the composition contains at least one caprylic / capric triglyceride (INCI name: caprylic / capric triglyceride). This product is sold, in particular, by Musim Mas, KLK Oleo, and Stearinerie Dubois.

[0043] Preferably, the triglyceride content is at least 10% by mass relative to the total mass of the composition. Advantageously, the triglyceride content is in the range of 10% to 35% by mass, preferably 15% to 25% by mass, relative to the total mass of the composition.

[0044] vegetable oil The composition according to the present invention further comprises at least one vegetable oil other than castor oil.

[0045] The term "vegetable oil" is defined as being measured at room temperature (20°C) and atmospheric pressure (1.013 × 10⁻⁶). 5 First, it should be remembered that Pa) refers to a compound that is in liquid state.

[0046] With respect to castor oil, if the composition contains it, its content shall not exceed 5% by mass, preferably not exceeding 2% by mass, and particularly not exceeding 1% by mass, based on the total mass of the composition. According to a more advantageous embodiment, if such oil is present in the composition, the content of castor oil shall not exceed 0.5% by mass, particularly preferably not exceeding 0.1% by mass, based on the total mass of the composition. Preferably, the composition does not contain castor oil.

[0047] Among the vegetable oils suitable for use in this invention, excluding castor oil, are particularly olive oil, coconut oil, coconut kernel oil, jojoba oil, xymenia oil, annatto oil, pracaccus oil, coriander seed oil, macadamia oil, passionflower oil, argan oil, sesame oil, sunflower oil, grape seed oil, avocado oil, rosa canina oil, apricot kernel oil, linseed oil, sweet almond oil, cottonseed oil, soybean oil, rapeseed oil, peanut oil, kaya oil, marula oil, and camellia oil. Examples include na oil, wheat germ oil, corn oil, corn germ oil, rice bran oil, alfalfa oil, poppy oil, pumpkin oil, mallow oil, hazelnut oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, kukui oil, limnanthes oil, black cumin oil, burichii oil, sandalwood nut oil, babassu oil, liquid fraction of shea butter, and liquid fraction of cocoa butter, as well as mixtures thereof.

[0048] Preferably, the vegetable oil is selected from olive oil, coconut oil, jojoba oil, xymenia oil, macadamia oil, sesame oil, sunflower oil, grape seed oil, avocado oil, apricot kernel oil, linseed oil, sweet almond oil, cottonseed oil, soybean oil, rapeseed oil, peanut oil, wheat germ oil, corn germ oil, rice bran oil, alfalfa oil, safflower oil, limnanthes oil, liquid fraction of shea butter, liquid fraction of cocoa butter, and mixtures thereof.

[0049] More specifically, the content of vegetable oils other than castor oil is at least 3% by mass, more specifically at least 5% by mass; advantageously, it is in the range of 5% to 65% by mass, preferably 10% to 55% by mass, relative to the total mass of the composition.

[0050] additional liquid compounds The compositions according to the present invention may optionally contain at least one additional volatile or non-volatile hydrocarbon or silicone oil other than the aforementioned capric acid triglyceride and / or caprylic acid triglyceride, vegetable oil and castor oil.

[0051] The term "non-volatile oil" refers to oils that are volatile at 20°C and atmospheric pressure (1.013 × 10⁻⁶). 5 This refers to compounds that are liquid at Pa and have a vapor pressure at 20°C that is not zero but less than 2.66 Pa, more specifically less than 0.13 Pa. As an example, the vapor pressure can be measured according to the static method or by isothermal thermomass leaching (effusion method) (Standard OCDE 104).

[0052] The term "volatile oil" refers to oil that has a non-zero vapor pressure at room temperature and, in particular, in the range of 2.66 Pa to 40,000 Pa, especially up to 13,000 Pa, and more specifically, in the range of atmospheric pressure up to 1,300 Pa.

[0053] The term "hydrocarbon oil" refers to oils that are essentially formed from carbon and hydrogen atoms, or more specifically composed of carbon and hydrogen atoms, and also contain at least one oxygen atom, and optionally a nitrogen atom. Therefore, these oils are different from silicone oils.

[0054] The term "silicone oil" refers to an oil that contains at least one silicon atom, and in particular an oil that contains a Si-O group.

[0055] Preferably, the composition according to the present invention comprises a limited content of a volatile or non-volatile silicone oil and a volatile or non-volatile nonpolar hydrocarbon oil (in other words, an oil containing only carbon and hydrogen atoms) derived from petroleum conversion.

[0056] Examples of volatile or non-volatile silicone oils include volatile linear or cyclic silicones, polydimethylsiloxane (INCI name: dimethicone), and phenyl silicones.

[0057] Examples of nonpolar hydrocarbon oils include, in particular, volatile linear or branched nonpolar hydrocarbon oils containing 8 to 16 carbon atoms, and mixtures thereof, hydrogenated or non-hydrogenated poly(iso)butenes, hydrogenated or non-hydrogenated polydecenes, liquid paraffins, and further mixtures thereof.

[0058] More specifically, if the composition contains silicone oil and nonpolar hydrocarbon oils derived from petroleum conversion, the content is 7% by mass or less, more specifically 5% by mass or less, relative to the total mass of the composition. According to an advantageous embodiment of the present invention, the content of silicone oil and nonpolar hydrocarbon oils derived from petroleum conversion is 2% by mass or less, more specifically 1% by mass or less, relative to the total mass of the composition, and preferably the composition does not contain the oils.

[0059] The composition according to the present invention particularly includes, as an additional non-volatile hydrocarbon oil, plant-derived squalane, compound C15-19 alkanes (INCI names), and C 10 ~C 26 The formulation may optionally include non-volatile polar hydrocarbon oils selected from alcohols, ester-type non-volatile hydrocarbon oils containing at least 10 carbon atoms, dicaprylyl ethers, dicaprylyl carbonates, and mixtures thereof.

[0060] Saturated or unsaturated, linear or branched, C 10 ~C 26Fatty alcohols, preferably monoalcohols, include, in particular, lauryl alcohol, isostearyl alcohol, oleyl alcohol, 2-butyloctanol, 2-undecylpentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol, and mixtures thereof.

[0061] Regarding ester-type non-volatile hydrocarbon oils, the following can be listed: - Linear aliphatic hydrocarbon esters of formula RCOOR', alkylene glycols, particularly ethylene glycol or propylene glycol aliphatic hydrocarbon esters, where RCOO represents a carboxylic acid residue containing 2 to 40 carbon atoms and R' represents a hydrocarbon chain containing 1 to 40 carbon atoms, and the total number of carbon atoms is advantageously at least 10. Examples of such esters include, among others, cetostearyl octanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate or isostearate, ethyl palmitate, 2-ethylhexyl palmitate, isostearyl isostearate, octyl stearate, isostearyl heptanoate, octanoate, decanoates or ricinoates of alcohols or polyalcohols, e.g., propylene glycol dioctanoate, cetyl octanoate or tridecyl octanoate, 2-ethylhexyl palmitate, alkyl benzoates, polyethylene glycol diheptanoate, propylene glycol Ppropylene glycol bis(2-ethylhexanoate) and mixtures thereof, hexyl laurate, neopentanoate esters, such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate or 2-octyldodecyl neopentanoate, isononanoate esters, such as isononyl isononanoate, isotridecyl isononanoate or octyl isononanoate, oleyl ethyl ester, isopropyl lauroyl sarcosinate, diisopropyl sebacate, isocetyl stearate, isodecyl neopentanoate, isostearyl behenanete or myristyl myristate; - Hydroxylated esters, e.g., polyglyceryl-2 triisostearate; - Aromatic esters, e.g., tridecyl trimellitate, C 12 ~C 15 Alcohol benzoate, 2-phenylethyl ester of benzoic acid, and butyl octyl salicylate; - Linear fatty acid esters having a total number of carbon atoms in the range of 35 to 70, such as pentaerythrityl tetrapelargonate; - C 24 ~C 28 Esters of branched fatty acids or fatty alcohols, such as triisoarachidyl citrate, pentaerythrityl tetraisononanoate, glyceryl triisostearate, glyceryl tris(2-decyltetradecanoate), pentaerythrityl tetraisostearate, polyglyceryl-2 tetraisostearate, or pentaerythrityl tetrakis(2-decyltetradecanoate); - Polyesters obtained by condensation of dimers and / or trimers of unsaturated fatty acids with diols, for example, those having the INCI name dilinoleic acid / butanediol copolymer or dilinoleic acid / propanediol copolymer; polyesters obtained by condensation of fatty acid dimers with diol dimers, for example, products having the INCI name dimer dilinoleyl dimer dilinoleate; - A mixture of those.

[0062] Preferably, the additional hydrocarbon oils, especially those that are non-volatile, are selected from plant-derived squalane, compound C15-19 alkanes (INCI names), ester-type non-volatile hydrocarbon oils containing at least 10 carbon atoms, and further mixtures thereof.

[0063] If the composition contains such additional non-volatile polar hydrocarbon oils, their content is in the range of 1% to 20% by mass relative to the total mass of the composition.

[0064] The composition is C 10 ~C 26If the composition includes at least one additional non-volatile polar hydrocarbon oil selected from alcohols, it should be noted that their content is advantageously between 1% and 7% by mass relative to the total mass of the composition.

[0065] dye According to a particular embodiment of the present invention, the composition comprises at least one synthetic, natural, or naturally derived dye.

[0066] The dyes may be selected from coated or uncoated pigments, lipid-soluble dyes, and mixtures thereof.

[0067] pigment The term "pigment" means white or colored inorganic or organic particles that are insoluble in aqueous media and are intended to color and / or opaque the resulting composition and / or deposit.

[0068] According to certain embodiments, the pigment used in accordance with the present invention is selected from inorganic pigments.

[0069] The term "inorganic pigment" means any pigment that satisfies the definition in the chapter on inorganic pigments in Ullmann's encyclopedia. Among the inorganic pigments useful in the present invention, in addition to zirconium oxide or cerium oxide, examples include zinc oxide, iron oxide (black iron oxide, yellow iron oxide, or red iron oxide) or chromium oxide, manganese violet, ultramarine blue, chromium hydroxide and ferric blue, titanium dioxide and metal powders (e.g., aluminum powder and copper powder). The following inorganic pigments can also be used: Ta2O5, Ti3O5, Ti2O3, TiO, ZrO2 as a mixture with TiO2, ZrO2, Nb2O5, CeO2, ZnS.

[0070] The diameter of pigments useful in relation to the present invention is generally greater than 100 nm and up to 10 μm, preferably in the range of 200 nm to 5 μm, and more preferably in the range of 300 nm to 1 μm. According to a particular embodiment of the present invention, the diameter of the pigment is characterized by a D

[50] greater than 100 nm, sometimes up to 10 μm, preferably in the range of 200 nm to 5 μm, and more preferably in the range of 300 nm to 1 μm. This diameter is measured by static light scattering using the Master Sizer 3000, a commercially available particle size analyzer sold by Malvern, which makes it possible to determine the particle size distribution of all particles in a wide range that may extend from 0.01 μm to 1000 μm. The data is processed based on the Mie scattering theory, which is best suited to particle size distributions in the submicron to several micron range, thereby making it possible to determine the "effective" particle size. This theory is particularly explained in the publication by Van de Hulst, HC, Light Scattering by Small Particles, Chapters 9 and 10, Wiley, New York, 1957. D

[50] represents the maximum size of the particle, which is 50% by volume.

[0071] In relation to the present invention, the inorganic pigment is more specifically iron oxide and / or titanium dioxide. More specifically, examples include titanium dioxide and iron oxide coated with aluminum stearoyl glutamate, which are sold by Miyoshi Kasei under the reference name NAI®.

[0072] An example of an inorganic pigment that can be used in the present invention is pearlescent material. The term "nacre" should be understood to mean any form of colored particles, whether iridescent or not, produced or alternatively synthesized in the exoskeletons of certain mollusks, which have a color effect through light interference. The nacreous layer can be selected from nacreous pigments, such as titanium mica coated with iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with organic dyes, and further nacreous pigments based on bismuth oxychloride. They may also be mica particles in which at least two continuous layers of metal oxides and / or organic dyes are superimposed on their surface. Examples of nacreous layers include natural mica coated with titanium dioxide, iron oxide, natural pigments, or bismuth oxychloride. The nacreous layer may, more particularly, have the colors or shades of yellow, pink, red, bronze, orange, brown, gold, and / or copper.

[0073] Among the pigments that can be used in accordance with the present invention, there are those that have optical effects different from simple conventional coloring effects, namely, unified and stabilized effects like those produced by conventional dyes, such as monochromatic pigments. In the context of this invention, the term "stabilized" means that there is no influence from color variations due to the observation angle or temperature changes. For example, the material can be selected from metallic hues, goniochromatic colorants, diffraction pigments, thermochromic agents, fluorescent whitening agents, and also fibers, particularly particles having interference fibers. Needless to say, these various materials can be combined to exhibit two effects simultaneously, and even novel effects according to the present invention.

[0074] According to certain embodiments, the composition according to the present invention comprises at least one uncoated pigment.

[0075] According to another specific embodiment, the composition according to the present invention comprises at least one pigment coated with at least one lipophilic or hydrophobic compound. This type of pigment is particularly advantageous. As long as they are treated with a hydrophobic compound, they exhibit a dominant affinity for the oily phase, which can then transport them. The coating may also include at least one additional non-lipophilic compound. For the purposes of the present invention, "coating" of a pigment according to the present invention generally means the whole or partial surface treatment of the pigment with a surface treatment agent absorbed, adsorbed, or grafted onto the aforementioned pigment.

[0076] Surface-treated pigments can be prepared according to surface treatment techniques with chemical, electrical, mechanochemical, or mechanical properties well known to those skilled in the art. Commercially available products may also be used. Surface treatment agents can be absorbed, adsorbed, or grafted onto the pigment surface by evaporation of a solvent, chemical reactions, and the formation of covalent bonds. In one modified form, the surface treatment consists of coating the pigment. The coating may comprise 0.1% to 20% by mass, particularly 0.5% to 5% by mass, of the total mass of the pigment to be coated. The coating can be produced by, for example, simply mixing solid particles and a liquid surface treatment agent while stirring, optionally heating, and allowing the aforementioned liquid surface treatment agent to adsorb onto the surface of the solid particles, before adding the particles to other ingredients of the makeup or care composition. The coating can be produced, for example, by chemically reacting a surface treatment agent with the surface of solid pigment particles to create a covalent bond between the surface treatment agent and the particles. This method is described in particular in U.S. Patent No. 4,578,266. Chemical surface treatment may consist of diluting a surface treatment agent with a volatile solvent, dispersing a pigment in this mixture, and then slowly evaporating the volatile solvent, thereby depositing the surface treatment agent onto the pigment surface. According to certain embodiments of the present invention, pigments may be coated in accordance with the present invention with at least one compound selected from silicone-based surface treatment agents; fluorine-based surface treatment agents; fluorosilicone-based surface treatment agents; metallic soaps; N-acyl amino acids or salts thereof; lecithin and its derivatives; isopropyltriisostearyl titanate; isostearyl sebacate; natural plant-based or animal-based waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof. According to certain embodiments of the present invention, pigments can be coated with hydrophilic compounds.

[0077] According to certain embodiments, the dye is a synthetic, natural, or naturally derived organic pigment. The term "organic pigment" refers to any pigment that meets the definition in the chapter on organic pigments in Ullmann's encyclopedia. Organic pigments may be selected from, in particular, nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, and quinophthalone compounds.

[0078] Organic pigments include, for example, carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, blue pigments classified in the Colour Index by the symbols CI 42090, 69800, 69825, 73000, 74100 and 74160, yellow pigments classified in the Colour Index by the symbols CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000 and 47005, green pigments classified in the Colour Index by the symbols CI 61565, 61570 and 74260, orange pigments classified in the Colour Index by the symbols CI 11725, 15510, 45370 and 71105, and CI Red pigments classified by the symbols 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915 and 75470 can be selected, as well as pigments obtained by oxidative polymerization of indole or phenolic derivatives as described in French Patent No. 2679771.

[0079] The pigments may also be in the form of composite pigments as described in European Patent No. 1184426. These composite pigments may, in particular, consist of particles comprising an inorganic core at least partially coated with an organic pigment, and at least one binder for fixing the organic pigment to the inorganic core.

[0080] The pigment can be a lake. The term "lake" refers to an insoluble dye adsorbed onto insoluble particles, and the resulting aggregate remains insoluble during use. The mineral substance used to adsorb the dye is, for example, alumina, silica, borosilicate (Ca / Na), or borosilicate (Ca / Al) and aluminum. Among organic dyes, cochineal carmine can be mentioned. We may also mention products known by the following names: D&C Red 21 (CI 45 380), D&C Orange 5 (CI 45 370), D&C Red 27 (CI 45 410), D&C Orange 10 (CI 45 425), D&C Red 3 (CI 45 430), D&C Red 4 (CI 15). 510), D&C Red 33(CI 17 200), D&C Yellow 5(CI 19 140), D&C Yellow 6(CI 15 985), D&C Green 5(CI 61 570), D&C Yellow 10(CI 77 002), D&C Green 3(CI 42 053), D&C Blue 1(CI) 42 090). An example of a rake that can be mentioned is the product known as D&C Red 7 (CI 15 850:1).

[0081] fat soluble dye For the purposes of this invention, the term "lipid-soluble dye" means any natural or synthetic, generally organic compound that is soluble in an oily phase or in a solvent miscible with an oily phase and can impart color. Suitable lipid-soluble dyes for use in the present invention include, in particular, lipid-soluble dyes such as DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan Red, and Sudan Brown. Examples of natural fat-soluble dyes include carotenes, such as β-carotene, α-carotene, and lycopene; xanthophylls such as quinoline yellow, astaxanthin, antheraxanthin, citranaxanthin, cryptoxanthin, canthaxanthin, diatoxanthin, flavoxanthin, fucoxanthin, lutein, rhodoxanthin, rubixanthin, siphonaxanthin, violaxanthin, and zeaxanthin; annatto; curcumin; quinizalin (Ceres Green BB, D&C Green No. 6, CI 61565, 1,4-di-p-toluidinoanthraquinone, Green No. 202, Quinazine Green SS); and chlorophyll.

[0082] According to a preferred embodiment of the present invention, the composition may contain 0.01% to 20% by mass, particularly 1% to 15% by mass, and more specifically 2% to 13% by mass, of the total mass of the composition, a dye. The composition may not contain a dye.

[0083] Optional adjuvants In connection with the present invention, the composition may also include at least one optional auxiliary agent selected from those commonly used in the cosmetics field, particularly in makeup and / or care compositions for the skin and lips.

[0084] Examples of such substances include lipophilic thickeners, such as silica, organic gelling agents, clays, fillers, preservatives, antioxidants, complexing agents, solvents, and fragrances.

[0085] These auxiliary agents and their concentrations must be such that they do not alter the properties desired in the composition of the present invention.

[0086] The composition according to the present invention may optionally contain water in an amount not exceeding 5% by mass, preferably not exceeding 2% by mass, relative to the total mass of the composition. More advantageously, if the composition contains water, the water content does not exceed 1% by mass, particularly not exceeding 0.5% by mass, and more specifically not exceeding 0.2% by mass, relative to the total mass of the composition.

[0087] The following embodiments are provided as a non-limiting description of the present invention.

[0088] Unless otherwise specified, the quantities shown herein are expressed as mass percentages of the starting materials.

[0089] The starting materials are referred to by their chemical name or INCI name. [Examples]

[0090] Example 1 Prepare the following compositions, whose ingredient lists and their contents are matched in the table below:

[0091] [Table 1]

[0092] Preparation process 1. The pigment is ground in an amount of oil necessary for good dispersion using a three-roll mill or ball mill. 2. Heat the wax and remaining oil in a suitable container to 98°C to obtain a homogeneous mixture. 3. While stirring, add the pigment to the mixture from the previous step. 4. Next, add the paste-like substance at 98°C while stirring. 5. Once the mixture is completely homogenized, the preparation is kept at room temperature until casting 24 hours later. 6. After 24 hours, the mixture is reheated to 98°C and the composition is cast in a mold preheated to 42°C. 7. After waiting for the surface to harden, the surface was smoothed. 8. Leave the mold at -25°C until the mold returns to 4°C. 9. Remove the rod from the mold.

[0093] Evaluation of the composition

[0094] [Table 2]

Claims

1. A solid composition in stick form for applying makeup and / or care to the skin and / or lips: - Sunflower wax; - Candelilla wax; - At least one triglyceride selected from caprylic acid triglyceride, capric acid triglyceride, caprylic acid / capric acid triglyceride, or a mixture thereof; - At least one vegetable oil other than castor oil (if castor oil is present, its content shall not exceed 5% by mass of the total mass of the composition); - Linear or branched C ６ ~C １０ At least one polyester obtained by condensation of a dicarboxylic acid and a diglycerol ester, or at least one polyester obtained by condensation of a linear or branched C6-C10 dicarboxylic acid and a diglycerol ester and a hydroxylated linear or branched C6-C20 monocarboxylic acid. Including; The total content of polar wax is in the range of 6% to 18% by mass relative to the total mass of the composition; The triglyceride content is between 10% by mass and 35% by mass relative to the total mass of the composition; The vegetable oil content is in the range of 5% to 65% by mass relative to the total mass of the composition; Solid composition.

2. The composition according to claim 1, characterized in that the polyester is bis-diglyceryl polyacyladipate-2.

3. The composition according to claim 1 or 2, characterized in that the sunflower wax content is in the range of 1% to 9% by mass relative to the total mass of the composition.

4. The composition according to claim 1 or 2, characterized in that the candelilla wax content is in the range of 0.25% to 7% by mass relative to the total mass of the composition.

5. The composition according to claim 1 or 2, characterized in that the triglyceride content is 15% to 25% by mass relative to the total mass of the composition.

6. The aforementioned vegetable oils, excluding castor oil, include olive oil, coconut oil, coconut kernel oil, jojoba oil, xymenia oil, annatto oil, pracaccus oil, coriander seed oil, macadamia oil, passionflower oil, argan oil, sesame oil, sunflower oil, grape seed oil, avocado oil, rosa canina oil, apricot kernel oil, linseed oil, sweet almond oil, cottonseed oil, soybean oil, rapeseed oil, peanut oil, kaya oil, marula oil, camelina oil, wheat germ oil, corn oil, and The composition according to claim 1 or 2, characterized by being selected from sorghum germ oil, rice bran oil, alfalfa oil, poppy oil, pumpkin oil, mallow oil, hazelnut oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, kukui oil, limnanthes oil, black cumin oil, burichii oil, sandalwood nut oil, babassu oil, liquid fraction of shea butter, liquid fraction of cocoa butter, and mixtures thereof.

7. The composition according to claim 1 or 2, characterized in that the vegetable oil content is in the range of 10% to 55% by mass relative to the total mass of the composition.

8. The composition according to claim 1 or 2, characterized in that the castor oil content is less than 2% by mass relative to the total mass of the composition.

9. The composition is a hydrocarbon wax containing at least one ester functional group, other than sunflower wax and candelilla wax: i) Wax of formula R1COOR2 (where R1 and R2 represent linear, branched, or cyclic aliphatic chains with a number of atoms in the range of 10 to 50, which may contain heteroatoms, and have a melting point in the range of 40 to 120°C); ii) Dicarboxylic acid diester wax of general formula R3-(-OCO-R4-COO-R5) (R3 and R5 are the same or different and represent a C4-C30 alkyl group (an alkyl group containing 4 to 30 carbon atoms), and R4 represents a linear or branched C4-C30 aliphatic group which may or may not contain one or more unsaturated atoms); iii) Partial or total esters of saturated C16-C30 carboxylic acids with glycerol; iv) Waxes of animal or plant origin other than sunflower wax and candelilla wax; v) Waxes obtained by hydrogenating animal or vegetable oils; vi) those mixtures The composition according to claim 1 or 2, characterized by comprising at least one additional polar hydrocarbon wax selected from the following.

10. The composition according to claim 1 or 2, characterized in that the content of additional polar hydrocarbon waxes other than sunflower wax and candelilla wax is 0.25% to 9% by mass relative to the total mass of the composition.

11. The composition according to claim 1 or 2, characterized in that the composition contains at least one nonpolar hydrocarbon wax in an amount not exceeding 2% by mass relative to the total mass of the composition.

12. The composition according to claim 1 or 2, characterized in that the total content of solid polyester is 5% to 35% by mass relative to the total mass of the composition.

13. The composition is a vegetable butter, a partially or fully hydrogenated vegetable oil, saturated or unsaturated, linear or branched, monohydroxylated or unhydroxylated, and polyhydroxylated or unhydroxylated, C １２ ~C １８ The composition according to claim 1 or 2, characterized by comprising at least one paste-like hydrocarbon compound other than the solid polyester, selected from fatty acid triglycerides, diol dimers, or esters of alcohols or polyols with dioxide dimers, and mixtures thereof.

14. The composition according to claim 13, characterized in that the amount of solid polyester and paste-like hydrocarbon compound is in the range of 5% to 35% by mass with respect to the total mass of the composition.

15. The composition according to claim 1 or 2, characterized in that the composition contains at least an additional oil selected from non-volatile or volatile silicone oils and / or non-volatile or volatile non-polar hydrocarbon oils derived from petroleum conversion in an amount of 7% by mass or less based on the total mass of the composition.

16. The composition contains at least one C １０ ~C ２６ The composition according to claim 1 or 2, characterized in that it contains alcohol, the amount of which is 1% by mass to 7% by mass relative to the total mass of the composition.

17. The composition according to claim 1 or 2, characterized in that the dye is selected from pigments, lipid-soluble dyes, and mixtures thereof.

18. The composition according to claim 1 or 2, characterized in that the composition contains water in an amount not exceeding 2% by mass relative to the total mass of the composition.

19. The composition is 70 to 200 Nm at 20°C and atmospheric pressure. －１ The composition according to claim 1 or 2, characterized in that it is in the form of a rod having a hardness of [value].

20. A method for applying makeup and / or care to the skin and / or lips, comprising applying the composition described in claim 1 or 2.

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