Semiconductor manufacturing equipment components

JPWO2025187066A5Active Publication Date: 2026-02-10NGK CORP
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Patent Information

Application Number
JP2024541276
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Filing Date
2024-03-08
Publication Date
2026-02-10
Estimated Expiration
2044-03-08

AI Technical Summary

Technical Problem

Existing semiconductor manufacturing equipment components experience discharge issues, particularly during high-power plasma processes like deep etching, despite conventional discharge suppression technologies, necessitating more advanced measures.

Method used

A semiconductor manufacturing equipment member featuring a ceramic substrate with embedded plugs that have a gas flow path with reinforcing ribs to divide the upper end opening into segments, enhancing discharge suppression and structural integrity.

Benefits of technology

The solution effectively suppresses discharge between the wafer and ceramic substrate, improving processing reliability and reducing the risk of chipping while maintaining gas flow efficiency.

✦ Generated by Eureka AI based on patent content.

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Abstract

A semiconductor manufacturing equipment component that contributes to suppressing electrical discharge occurring between a wafer and a ceramic substrate is provided. The semiconductor manufacturing equipment component includes a ceramic substrate having upper and lower surfaces for mounting a wafer, a plug placement hole that vertically penetrates the ceramic substrate, and a plug embedded in the plug placement hole, wherein the plug is made of a dense body and has an upper end surface exposed on the upper surface side, a lower end surface exposed on the lower surface side, and a gas flow path that extends from an upper end opening provided on the upper end surface, penetrating the dense body, to a lower end opening provided on the lower end surface, and the gas flow path is provided with reinforcing ribs that divide the upper end opening into a plurality of segments.
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Description

[Technical Field]

[0001] The present invention relates to a member for a semiconductor manufacturing device. [Background technology]

[0002] Conventionally, semiconductor manufacturing equipment components have been known that are used for holding wafers, controlling their temperature, transporting them, etc. These types of semiconductor manufacturing equipment components are also called wafer mounting tables, electrostatic chucks, susceptors, etc., and generally have the function of applying electrostatic attraction power to a built-in electrode to attract the wafer by electrostatic force, and some are also known to have the function of controlling the wafer temperature by flowing gas between the wafer mounting surface and the wafer to be attracted.

[0003] A known component for semiconductor manufacturing equipment includes a ceramic substrate having an upper surface for placing a wafer, a gas passage that passes through the ceramic substrate in the vertical direction, and a conductive base plate bonded to the lower surface of the ceramic substrate. During wafer processing, a cooling gas such as helium gas is introduced to the backside of the wafer through the gas passage.

[0004] In such semiconductor manufacturing equipment components, a large potential difference can occur between the wafer and the base plate, which can lead to discharge (dielectric breakdown) between the wafer and the base plate through the gas passage. For this reason, various technologies for placing plugs in the gas passages have been investigated to suppress discharge. Plugs are often made of porous materials. Without a plug, for example, when RF voltage is applied, gas molecules are ionized, resulting in electrons that accelerate and collide with other gas molecules, causing glow discharge and eventually arc discharge. However, with a plug, the electrons strike the plug before colliding with other gas molecules, suppressing discharge.

[0005] Patent Document 1 proposes a plug having a gas flow path portion that bends and penetrates a dense main body portion in the thickness direction. It also proposes making at least a portion of the entire length of the gas flow path portion insulating and porous.

[0006] Patent Document 2 discloses an electrostatic chuck comprising: a ceramic dielectric substrate having a first main surface on which an object to be attracted is placed and a second main surface opposite the first main surface; a base plate supporting the ceramic dielectric substrate and having a gas inlet passage; and a first porous portion provided between the base plate and the first main surface of the ceramic dielectric substrate and at a position facing the gas inlet passage, wherein the ceramic dielectric substrate has a first hole portion located between the first main surface and the first porous portion, and the first porous portion has a porous portion having a plurality of holes and a first dense portion that is denser than the porous portion, and when projected onto a plane perpendicular to a first direction from the base plate toward the ceramic dielectric substrate, the first dense portion and the first hole portion overlap, but the porous portion and the first hole portion do not overlap.

[0007] Patent Document 3 describes an electrostatic chuck comprising: a ceramic dielectric substrate having a first main surface on which an object to be attracted is placed and a second main surface opposite the first main surface; a base plate supporting the ceramic dielectric substrate and having a gas inlet passage; and a first porous portion provided between the base plate and the first main surface of the ceramic dielectric substrate and facing the gas inlet passage, wherein the first porous portion has a plurality of sparse portions having a plurality of holes and a dense portion having a density higher than that of the sparse portions, each of the plurality of sparse portions extending in a first direction from the base plate toward the ceramic dielectric substrate, the dense portion being located between the plurality of sparse portions, the sparse portion having the holes and a wall portion provided between the holes, and wherein a minimum value of a dimension of the wall portion is smaller than a minimum value of a dimension of the dense portion in a second direction substantially perpendicular to the first direction.

[0008] Patent Document 4 describes an invention aimed at providing a holding device capable of controlling the temperature of an object with high precision while reducing the occurrence of abnormal discharge. Specifically, the holding device described includes a ceramic substrate having a first surface for holding an object and a second surface opposite the first surface, a base member disposed on the second surface side of the ceramic substrate and having a third surface opposite the ceramic substrate, and a bonding material disposed between the ceramic substrate and the base member, wherein (1) the ceramic substrate and the base member are formed with a flow path that allows a fluid to move between an outlet hole provided in the first surface and an inlet hole provided in the third surface, or (2) the ceramic substrate is formed with a flow path that allows a fluid to move between an outlet hole provided in the first surface and an inlet hole provided in the second surface, the flow path having a porous ceramic region, the porous ceramic region including a sparse region and a dense region that has a lower porosity than the sparse region and is disposed closer to the first surface than the sparse region.

[0009] In Patent Document 5, a wafer mounting table is provided with an insulating first porous portion disposed in a through-hole of a ceramic plate and an insulating second porous portion fitted in a recess provided on the ceramic plate side of a base plate so as to face the first porous portion. Gas supplied to a gas inlet passage passes through the second and first porous portions and flows into the space between the wafer mounting surface and the wafer, where it is used to cool the object. The publication states that the presence of the first and second porous portions ensures the flow rate of gas from the gas inlet passage to the wafer mounting surface while suppressing the occurrence of discharge (arc discharge) caused by plasma during wafer processing. [Prior art documents] [Patent documents]

[0010] [Patent Document 1] Japanese Patent Publication No. 2022-119338 [Patent Document 2] Japanese Patent Publication No. 2022-31333 [Patent Document 3] Japanese Patent Application Publication No. 2019-165194 [Patent Document 4] Japanese Patent Publication No. 2022-176701 [Patent Document 5] Japanese Patent Publication No. 2020-72262 Summary of the Invention [Problem to be solved by the invention]

[0011] As described above, in order to suppress discharges occurring between the wafer and the baseplate in semiconductor manufacturing equipment components, various technologies have been proposed to improve the structure near the plugs located in the gas passages that penetrate the ceramic substrate in the vertical direction. However, discharges are more likely to occur during wafer processing, such as deep etching, which uses high-power plasma. Therefore, more advanced discharge prevention measures are required.

[0012] Therefore, it is desirable to develop a new discharge suppression technology. By combining such a new discharge suppression technology with a conventional discharge suppression technology, an even greater discharge suppression effect can be expected. Therefore, in one embodiment, an object of the present invention is to provide a semiconductor manufacturing equipment member that employs a discharge suppression technology different from conventional ones. [Means for solving the problem]

[0013] The present inventors have conducted extensive research to solve the above problems and have created the present invention, which is exemplified below. [Aspect 1] A semiconductor manufacturing equipment member comprising: a ceramic substrate having an upper surface and a lower surface for mounting a wafer; a plug placement hole penetrating the ceramic substrate in the vertical direction; and a plug embedded in the plug placement hole, the plug is made of a dense body and has an upper end surface exposed on the upper surface side, a lower end surface exposed on the lower surface side, and a gas flow path extending from an upper end opening provided on the upper end surface through the dense body to a lower end opening provided on the lower end surface, The gas flow path is provided with a reinforcing rib that divides the upper end opening into a plurality of segments. Components for semiconductor manufacturing equipment. [Aspect 2] 2. A member for a semiconductor manufacturing equipment according to embodiment 1, wherein the number of reinforcing ribs provided in one gas flow channel is 1 to 5. [Aspect 3] The major axis X of the upper end opening when the reinforcing rib is assumed not to exist max 3. The semiconductor manufacturing equipment member according to aspect 1 or 2, wherein the thickness is 0.1 mm or more. [Aspect 4] Each of the plurality of segments of the upper end opening has a major axis Y max and the minor axis Y of the segment min However, 0.1≦Y min / Y max 4. A member for a semiconductor manufacturing equipment according to any one of aspects 1 to 3, which satisfies the relationship of ≦0.9. [Aspect 5] Y max 5. The semiconductor manufacturing equipment member according to embodiment 4, wherein the thickness is 0.01 to 0.5 mm. [Aspect 6] A semiconductor manufacturing equipment member according to any one of aspects 1 to 5, wherein the reinforcing ribs are provided in the direction in which the gas flow path extends, at least within a range of coordinate values ​​from 0 to 0.05×H, where the coordinate axis is taken in the vertical direction and the coordinate value at the upper end surface of the plug is 0 and the coordinate value at the lower end surface is H. [Aspect 7] 7. A semiconductor manufacturing equipment member according to embodiment 6, wherein the reinforcing ribs are not provided at least in a range of coordinate values ​​exceeding 0.2×H to 1.0×H. [Aspect 8] 8. A semiconductor manufacturing equipment member according to any one of aspects 1 to 7, wherein, in a cross section extending in the vertical direction through the central axis of the plug, the gas flow path has a flat cross-sectional shape such that, assuming that the reinforcing rib does not exist, the vertical height D of the gas flow path and the horizontal width W of the gas flow path satisfy the relationship 0.1≦D / W≦0.9. [Aspect 9] 9. The member for a semiconductor manufacturing equipment according to embodiment 8, wherein the height D is 10 to 300 μm. [Aspect 10] 10. A member for a semiconductor manufacturing equipment according to any one of aspects 1 to 9, wherein the fracture toughness value (KIC) of the portion of the plug constituted by the dense body is greater than the fracture toughness value (KIC) of the ceramic substrate. [Effects of the Invention]

[0014] A semiconductor manufacturing equipment member according to one embodiment of the present invention is effective in suppressing discharge occurring between a wafer and a ceramic substrate. [Brief explanation of the drawings]

[0015] [Figure 1-1] 1 is a schematic longitudinal sectional view of a semiconductor manufacturing equipment member according to one embodiment of the present invention. [Figure 1-2] 1 is a schematic longitudinal cross-sectional view (in the case of one gas flow path) passing through the central axis of a plug provided in a member for a semiconductor manufacturing equipment according to one embodiment of the present invention. [Figure 1-3] 1 is a schematic plan view of a plug provided in a semiconductor manufacturing equipment member according to one embodiment of the present invention (in the case of four gas flow paths). FIG. [Figure 1-4] 1 is a schematic plan view of a ceramic substrate included in a semiconductor manufacturing equipment member according to a first embodiment of the present invention. [Figure 2] FIG. 10 is a schematic vertical cross-sectional view of a semiconductor manufacturing equipment member according to another embodiment of the present invention. [Figure 3] 1A to 1C are diagrams showing a manufacturing process of a semiconductor manufacturing equipment member according to an embodiment of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0016] Next, embodiments of the present invention will be described in detail with reference to the drawings. It should be understood that the present invention is not limited to the following embodiments, and that appropriate design changes, improvements, and the like may be made based on the common knowledge of those skilled in the art without departing from the spirit of the present invention. Furthermore, in this specification, "upper" and "lower" are used for convenience to represent the relative positional relationship when a semiconductor manufacturing equipment component is placed on a horizontal surface with the upper surface for mounting a ceramic substrate wafer facing up, and do not represent an absolute positional relationship. Therefore, depending on the orientation of the semiconductor manufacturing equipment component, "upper" and "lower" may become "lower" and "upper," "left" and "right," or "front" and "rear."

[0017] <1. Composition of semiconductor manufacturing equipment components> 1-1, a semiconductor manufacturing equipment member 10 according to a first embodiment of the present invention includes a ceramic substrate 20 having an upper surface 21 for placing a wafer W thereon and a lower surface 23 opposite to the upper surface 21, a plug placement hole 50 that passes through the ceramic substrate 20 in the vertical direction, and a plug 55 embedded in the plug placement hole 50. The semiconductor manufacturing equipment member 10 also includes a base plate 30 bonded to the lower surface 23 of the ceramic substrate 20 via a bonding layer 40, and a gas supply path 60 that passes through the base plate 30 and the bonding layer 40 to supply a gas to the plug 55.

[0018] (1-1. Ceramic substrate) The upper surface 21 of the ceramic substrate 20 has a wafer mounting surface on which a wafer W is mounted. The ceramic substrate 20 also incorporates an electrode 22. As shown in FIGS. 1-1 and 1-4, a ring-shaped seal band 21a is formed on the upper surface 21 of the ceramic substrate 20 along its outer edge, and multiple protrusions 21b are formed over the entire inner surface of the seal band 21a. The shape of the protrusions 21b is not limited, but may be, for example, a cylindrical or rectangular column. The seal band 21a and the protrusions 21b preferably have the same height, which is, for example, 5 to 100 μm, typically 10 to 30 μm. The electrode 22 is a planar electrode used as an electrostatic electrode and is connected to an external DC power supply via a power supply member (not shown). A low-pass filter may be disposed along the power supply member. The power supply member is electrically insulated from the bonding layer 40 and the base plate 30. When a DC voltage is applied to this electrode 22, the wafer W is attracted and fixed to the wafer mounting surface (specifically, the upper surfaces of the seal bands 21a and the protrusions 21b) by electrostatic attraction, and when the application of the DC voltage is stopped, the attracting and fixing of the wafer W to the wafer mounting surface is released. Note that the portion of the upper surface 21 of the ceramic substrate 20 where the seal bands 21a and the protrusions 21b are not provided is referred to as the reference surface 21c.

[0019] A heater electrode (resistance heating element) may be built in instead of or in addition to the electrostatic electrode as the electrode 22. In this case, a heater power supply is connected to the heater electrode. The ceramic substrate 20 may have one layer of electrodes built in, or two or more layers of electrodes built in with gaps between them.

[0020] The ceramic substrate 20 may be a circular plate (e.g., 300 to 400 mm in diameter) made of ceramic, such as alumina sintered body or aluminum nitride sintered body. The thickness of the ceramic substrate 20 is not limited, but from the viewpoint of increasing the fixing strength of the plug 55, the thickness from the upper opening 50a to the lower opening 50b is preferably 1 mm or more. Furthermore, from the viewpoint of reducing heat transfer in the ceramic substrate 20 and reducing manufacturing costs, the thickness is preferably 5 mm or less, more preferably 3 mm or less, and even more preferably 2 mm or less. Therefore, the thickness from the upper opening 50a to the lower opening 50b is, for example, preferably 1 to 5 mm, more preferably 1 to 3 mm, and even more preferably 1 to 2 mm. Here, the thickness from the upper opening 50a to the lower opening 50b refers to the distance from the center of gravity of the upper opening 50a to the center of gravity of the lower opening 50b. The height of the upper opening 50a is equal to the height of the reference plane 21c of the upper surface 21 of the ceramic substrate 20. The height of the lower opening 50 b is equal to the height of the lower surface 23 of the ceramic substrate 20 .

[0021] (1-2. Plug placement hole) As shown in FIG. 1-1, the plug arrangement hole 50 is a hole that penetrates the ceramic substrate 20 in the vertical direction from the upper opening 50a to the lower opening 50b. The plug arrangement hole 50 functions as a gas passage from the lower surface 23 of the ceramic substrate 20 to the reference surface 21c of the upper surface 21. Although one plug arrangement hole 50 may be provided, it is preferable to provide multiple plug arrangement holes 50. FIG. 1-4 shows multiple (six in this case) plug arrangement holes 50, each with a plug 55 embedded therein.

[0022] The horizontal opening diameter of the plug arrangement hole 50 (meaning the equivalent circular diameter when the cross section of the plug arrangement hole is not circular) is not limited, but can be, for example, within a range of 1 to 5 mm at any height position, and typically within a range of 3 to 4 mm. The diameter of the plug arrangement hole 50 may be constant or may vary from the lower surface 23 to the upper surface 21 of the ceramic substrate 20. In one embodiment, the diameter of the plug arrangement hole 50 decreases from top to bottom, and the plug arrangement hole 50 may have a tapered inner circumferential surface 50c in which the area of ​​the upper opening 50a is larger than the area of ​​the lower opening 50b. By having such a tapered inner circumferential surface 50c, the plug 55 can be easily stopped at a predetermined height position in the plug arrangement hole 50 when embedding the plug 55 in the plug arrangement hole 50, thereby achieving the effect of enabling the plug 55 to be embedded in the plug arrangement hole 50 with high positioning accuracy. Furthermore, while the plug 55 is difficult to remove downward, it is relatively easy to remove upward, resulting in the effect of facilitating replacement of the plug 55. Furthermore, the increased creepage distance also has the effect of suppressing discharge. The plug mounting hole 50 may have a space in the shape of a truncated cone or a truncated pyramid, for example.

[0023] The inclination angle α of the inner circumferential surface 50c of the plug arrangement hole 50 with respect to the lower opening 50b is preferably 70° or more, and more preferably 75° or more, from the viewpoints of increasing the fixing strength of the plug 55 and preventing the volume of the plug 55 from becoming excessively large to ensure space for arranging electrodes around it. Furthermore, the inclination angle α is preferably 87° or less, and more preferably 85° or less, from the viewpoints of improving the positioning accuracy in the height direction of the plug when the plug 55 is press-fitted downward into the plug arrangement hole 50, facilitating replacement of the plug 55, and lengthening the creepage distance to suppress discharge. Therefore, the inclination angle α is preferably, for example, 70° to 87°, and more preferably 75° to 85°.

[0024] (1-3. Plug) A plug 55 is embedded in the plug placement hole 50. FIG. 1-2 shows a schematic vertical cross-sectional view (in the case of one gas flow path) passing through the central axis of the plug 55. FIG. 1-3 shows a schematic plan view of the plug 55 (in the case of four gas flow paths). The plug 55 is composed of a dense body 55c and has an upper end surface 55a exposed on the upper surface 21 side of the ceramic substrate 20, a lower end surface 55b exposed on the lower surface 23 side of the ceramic substrate 20, and a gas flow path 55d extending from an upper end opening 55a1 provided in the upper end surface 55a, through the dense body 55c, to a lower end opening 55b1 provided in the lower end surface 55b.

[0025] In this specification, the dense body 55c refers to a portion of the plug 55 that has a porosity of 5% or less. The partial porosity of the plug 55 is measured by the following method. First, the plug 55 is cut so that a cross section passing through the central axis extending in the vertical direction of the plug 55 is exposed. Next, the portion of the cross section to be measured for porosity is observed at a magnification of 3000 times and a resolution of 2200 μm using a scanning electron microscope (SEM). 2 The area ratio of pores observed in that area is determined. Specifically, by analyzing the SEM image, a threshold is determined using discriminant analysis (Otsu's binarization) from the brightness distribution of the brightness data of pixels in the image. Then, based on the determined threshold, each pixel in the image is binarized into object and pore areas, and the areas of the object and pore areas are calculated. Then, the ratio of the area of ​​the pores to the total area (the total area of ​​the object and pore areas) is determined, and this is the porosity of the area being measured.

[0026] In one embodiment, gas flowing in through a lower end opening 55b1 provided in the lower end surface 55b of the plug 55 flows through a gas flow channel 55d provided inside the dense body 55c and can flow out through an upper end opening 55a1 provided in the upper end surface 55a of the plug 55. One plug 55 may be provided with only one gas flow channel 55d, or two or more. To ensure a sufficient gas flow rate, one plug 55 is preferably provided with two to nine gas flow channels 55d, and more preferably six to nine. For simplicity, FIG. 1-2 shows one gas flow channel 55d. FIG. 1-3 shows the upper end openings 55a1 serving as outlets for each of the four gas flow channels 55d. The gas flow channels 55d may be configured as straight lines, curves, or a combination of both. However, from the viewpoint of suppressing electrical discharge, it is preferable to form the gas flow channels 55d in a shape that makes the channel length longer than the vertical length of the plug 55, such as a bent shape such as a spiral or zigzag shape.

[0027] The gas flow path 55d may be hollow, but at least a portion thereof may be porous as long as it allows gas flow. When at least a portion of the gas flow path 55d is porous, gas flowing in from the lower end opening 55b1 of the plug 55 flows through the gas flow path 55d formed by a large number of continuous pores and flows out from the upper end opening 55a1 of the plug 55. The outflowing gas is supplied between the wafer W and the ceramic substrate 20. Because the three-dimensionally connected pores (e.g., a three-dimensional network) existing within the porous region serve as the gas flow path, the effective flow path length within the gas flow path 55d is longer than when the gas flow path 55d is hollow, resulting in the effect of making it less likely for discharge to occur. It is also possible to form one or more additional gas flow paths within the porous gas flow path.

[0028] Therefore, the gas flow channels 55d may be hollow or porous. Preferably, at least a portion of the gas flow channels 55d is porous. The gas flow channels 55d being hollow means that the porosity is 100%. The gas flow channels 55d being porous means that the porosity is greater than 5% and less than 100%. If the gas flow channels 55d are porous, a higher porosity is preferred to reduce the airflow resistance. Therefore, the porosity of the gas flow channels 55d is preferably 10% or more, more preferably 40% or more. On the other hand, the porosity of the gas flow channels 55d is preferably 50% or less to increase the flow channel length of the plug 55 and ensure structural strength. Therefore, the porosity of the gas flow channels 55d is preferably 10% or more and 50% or less, more preferably 40% or more and 50% or less. The porosity of the gas flow channels 55d is measured by mercury intrusion porosimetry (JIS R1655:2003).

[0029] During wafer processing, gas molecules present between the wafer W and the ceramic substrate 20 may be ionized, and the resulting electrons may accelerate toward the ceramic substrate 20 and collide with the upper surface 21 of the ceramic substrate 20. The higher the gas velocity caused by the colliding electrons, the more likely a discharge will occur. Therefore, shortening the distance between the wafer W and the ceramic substrate 20 is effective in suppressing the gas velocity.

[0030] However, if chipping occurs near the upper opening 55a1 of the plug 55 and causes the gas flow path 55d to break, the vertical distance from the back surface of the wafer W to the surface 55d1 of the gas flow path 55d exposed at the upper opening 55a1 may become long. Therefore, in order to reduce the risk of chipping, it is effective to provide reinforcing ribs 55a2 that divide the upper opening 55a1 into multiple segments 55a3. The opening area of ​​each segment 55a3 is smaller than the opening area of ​​the upper opening 55a1 before the reinforcing ribs 55a2 are provided, making chipping less likely to occur.

[0031] When the plug 55 has a plurality of gas flow passages 55d, it is preferable that all of the plurality of gas flow passages 55d have reinforcing ribs 55a2. max , major axis Y max , minor axis Y min Regarding preferred embodiments such as the range in which the reinforcing ribs are provided, the vertical height D of the gas flow path, and the horizontal width W of the gas flow path, if the plug 55 has multiple gas flow paths 55d, it is preferable that all of the multiple gas flow paths 55d satisfy the conditions for those preferred embodiments.

[0032] The number of reinforcing ribs 55a2 provided in one gas flow path 55d is preferably 1 to 5, more preferably 1 to 3, and even more preferably 1 to 2, in order to ensure the gas flow rate.

[0033] Chipping is likely to occur when the upper end opening 55a1 is large. Therefore, assuming that the reinforcing rib 55a2 does not exist, the major axis X of the upper end opening 55a1 is max However, when the major axis X is, for example, 0.1 mm or more, typically 0.5 mm or more, and more typically 1 mm or more, the chipping suppression effect of the reinforcing rib 55a2 is particularly large. max Although the upper limit of the major axis X is not particularly set, it is illustratively 3 mm or less, and typically 2 mm or less. max is illustratively 0.1 to 3 mm, typically 0.5 to 3 mm, and more typically 1 to 2 mm. Here, assuming that the reinforcing rib 55a2 does not exist, the major axis X of the upper end opening 55a1 is max indicates the diameter of the smallest circle that can surround the imaginary upper end opening 55a1 when it is assumed that the reinforcing rib 55a2 does not exist in a plan view (see FIG. 1-3).

[0034] The major axis Y of each segment 55a3 at the upper end opening 55a1 max The smaller the major axis Y, the greater the chipping suppression effect. maxThe major axis Y of each segment 55a3 in the upper end opening 55a1 is preferably 1 mm or less, more preferably 0.7 mm or less, and even more preferably 0.5 mm or less. max The larger the major axis Y is, the easier it is to ensure the flow rate of gas flowing out of each segment 55a3. max The major axis Y of each segment 55a3 in the upper end opening 55a1 is preferably 0.01 mm or more, more preferably 0.05 mm or more, and even more preferably 0.1 mm or more. max For example, the thickness is preferably 0.01 to 1 mm, more preferably 0.01 to 0.5 mm, and even more preferably 0.1 to 0.5 mm.

[0035] In order to ensure a sufficient gas flow rate, the plurality of segments 55a3 of the upper end opening 55a1 are each formed such that the major axis Y max and the minor axis Y of the segment 55a3 min However, 0.1≦Y min / Y max It is preferable that the relationship of 0.5≦Y min / Y max On the other hand, from the viewpoint of suppressing chipping, it is more preferable that Y min / Y max It is preferable that the relationship of Y≦0.9 is satisfied. min / Y max It is more preferable that the relationship 0.1≦Y≦0.7 is satisfied. min / Y max It is preferable that the relationship 0.1≦Y min / Y max ≦0.7, and 0.5≦Y min / Y max The relationship may be ≦0.9.

[0036] Here, the major axis Y of each segment 55a3 max The minor axis Y of each segment 55a3 is the diameter of the smallest circle that can surround the segment 55a3 in plan view (see FIG. 1-3).min indicates the diameter of the largest circle that can be surrounded by the segment 55a3 in plan view (see FIGS. 1-3).

[0037] There are no particular limitations on the shape of the opening of each segment 55a3. For example, the opening shape can be formed by straight lines, curves, or a combination of both. Specifically, the opening shape can be a quadrilateral such as a square, rectangle, trapezoid, or parallelogram. Among these, a quadrilateral with an aspect ratio of 0.1 to 0.9 is preferred because it reduces damage to the plug during processing. Here, the aspect ratio refers to the ratio of the length of the shortest side of the quadrilateral defining the opening of segment 55a3 to the longest side of the quadrilateral defining the opening of segment 55a3.

[0038] To enhance the chipping suppression effect, the reinforcing rib 55a2 preferably extends to a certain extent in the extension direction of the gas flow path 55d. Specifically, assuming that the coordinate axis is taken in the vertical direction and the coordinate value on the upper end surface 55a of the plug 55 is 0 and the coordinate value on the lower end surface 55b is H, the reinforcing rib 55a2 is preferably provided in the extension direction of the gas flow path 55d at least within a range of coordinate values ​​from 0 to 0.05×H, and more preferably within a range of coordinate values ​​from 0 to 0.1×H.

[0039] On the other hand, if the reinforcing ribs 55a2 extend too far in the direction of extension of the gas flow path 55d, the pressure loss during gas flow will increase. Therefore, from the viewpoint of ensuring the gas flow rate, it is preferable that the reinforcing ribs 55a2 are not provided at least in the range of coordinate values ​​exceeding 0.5×H to 1.0×H, and it is more preferable that the reinforcing ribs 55a2 are not provided at least in the range of coordinate values ​​from 0.2×H to 1.0×H.

[0040] From the viewpoint of ensuring a gas flow rate required for supplying gas between the wafer W and the ceramic substrate 20, the vertical height of the gas flow channel 55d is preferably large. Specifically, in a cross section extending in the vertical direction through the central axis of the plug 55, the vertical height D of the gas flow channel 55d is preferably 10 μm or more, more preferably 100 μm or more, and even more preferably 300 μm or more. However, from the viewpoint of reducing the risk of discharge by ensuring the flow channel length and from the viewpoint of ensuring the plug strength, it is desirable not to make the vertical height D of the gas flow channel 55d excessively large. Specifically, the vertical height D of the gas flow channel 55d is preferably 300 μm or less, more preferably 200 μm or less, and even more preferably 100 μm or less. Therefore, the vertical height D of the gas flow channel 55d is preferably, for example, 10 to 300 μm, more preferably 50 to 300 μm, and even more preferably 100 to 200 μm.

[0041] From the viewpoints of reducing the risk of discharge by ensuring sufficient flow path length and of ensuring plug strength, it is preferable that the gas flow path 55d has a flat cross-sectional shape in which, in a cross section extending in the vertical direction through the central axis of the plug, the vertical height D of the gas flow path 55d and the horizontal width W of the gas flow path 55d satisfy the relationship 0.1≦D / W≦0.9, more preferably 0.3≦D / W≦0.8, and even more preferably 0.5≦D / W≦0.8, assuming that the reinforcing rib 55a2 does not exist.

[0042] The vertical height D and horizontal width W of the gas flow path 55d are measured using the following procedure. First, the plug is cut so that a cross section extending in the vertical direction through the central axis of the plug is exposed. Next, the cross section is observed using a scanning electron microscope (SEM) at an appropriate magnification between 50 and 500 times, and the maximum distance between the opposing surfaces of the gas flow path 55d to be measured is taken as the vertical height D of the gas flow path 55d (see Figure 1-2). Furthermore, the maximum distance between the opposing surfaces of the gas flow path 55d to be measured is taken as the horizontal width W of the gas flow path 55d (see Figure 1-2).

[0043] In order to prevent chipping from occurring near the upper end opening 55a1 of the plug 55, it is desirable for the plug 55 to have a large fracture toughness value (KIC). Specifically, it is preferable that the fracture toughness value (KIC) of the portion of the plug 55 formed by the dense body 55c is greater than the fracture toughness value (KIC) of the ceramic substrate 20. Since the processing conditions for semiconductor manufacturing equipment members are often set based on the ceramic substrate 20, if the fracture toughness value (KIC) of the portion of the plug 55 formed by the dense body 55c is greater than the fracture toughness value (KIC) of the ceramic substrate 20, the risk of chipping occurring in the plug 55 is reduced.

[0044] The fracture toughness (KIC) of the part of the plug 55 that is made up of the dense body 55c is 2 MPa m 1 / 2 It is preferable that the pressure is 3 MPa m or more. 1 / 2 More preferably, it is 4 MPa m 1 / 2 Although no particular upper limit is set for the fracture toughness (KIC) of the portion of the plug 55 that is made up of the dense body 55c, from the viewpoint of ease of manufacture, it is preferable that the KIC be 13 MPa m 1 / 2 It is preferable that the temperature is 12 MPa m or less. 1 / 2 More preferably, it is 11 MPa m 1 / 2Therefore, the fracture toughness value (KIC) of the portion of the plug 55 that is made up of the dense body 55c is 2 to 13 MPa m 1 / 2 Preferably, the pressure is 3 to 12 MPa m 1 / 2 More preferably, the pressure is 4 to 11 MPa m 1 / 2 It is even more preferable that:

[0045] The fracture toughness (KIC) of the portion of the plug 55 formed by the dense body 55c and the ceramic substrate 20 is measured by the following method in accordance with the SEPB method defined in JIS R1607:2015.

[0046] The material constituting plug 55 can be an electrically insulating ceramic, and can contain, for example, one or more selected from aluminum oxide, aluminum nitride, silicon dioxide, and zirconia. Quartz is preferred as the silicon dioxide. The plug 55 can also be made of only one or two selected from aluminum oxide and aluminum nitride, excluding impurities. In particular, to control the fracture toughness value of the portion of plug 55 constituting dense body 55c within the above-mentioned range, it is preferable that the portion of plug 55 constituting dense body 55c be made of a ceramic material such as alumina (aluminum oxide).

[0047] Furthermore, in order to maintain the fixing strength of the plug 55 embedded in the plug placement hole 50, it is preferable that the difference in thermal expansion coefficient between the plug 55 and the ceramic substrate 20 is small. For this reason, it is preferable that the material constituting the plug 55 and the material constituting the ceramic substrate 20 both contain one or more selected from aluminum oxide and aluminum nitride, and it is more preferable that the material compositions are the same.

[0048] The height position of the upper end surface 55a of the plug 55 is not limited. Therefore, the height position of the upper end surface 55a of the plug 55 may be the same as or different from the reference surface 21c of the ceramic substrate 20. When the upper end surface 55a of the plug 55 is made lower than the reference surface 21c, it is preferable to make it lower by 0.5 mm or less (preferably 0.2 mm or less, more preferably 0.1 mm or less) in order to suppress the occurrence of discharge. When the upper end surface 55a of the plug 55 is made higher than the reference surface 21c, there is no particular limitation as long as it is lower than the upper surface of the protrusion 21b and the outflow of gas from the plug 55 is not hindered.

[0049] There is no particular limitation on the height position of the lower end surface 55b of the plug 55. Therefore, the height position of the lower end surface 55b of the plug 55 may be the same height as the lower surface 23 of the ceramic substrate 20, or may be a different height. For example, the lower end surface 55b of the plug 55 may protrude downward from the lower surface 23 of the ceramic substrate 20, or the lower end surface 55b of the plug 55 may be positioned above the lower surface 23 of the ceramic substrate 20.

[0050] The outer peripheral surface 55e of the plug 55 and the inner peripheral surface 50c of the plug mounting hole 50 may be bonded via an adhesive, but it is preferable that they be directly fitted together without using an adhesive. Direct fitting between the two prevents the formation of a gap between the plug 55 and the plug mounting hole 50 due to deterioration of the adhesive caused by corrosion, erosion, etc. This has the advantage of suppressing discharge and detachment of the plug 55 caused by deterioration of the adhesive.

[0051] Furthermore, as shown in FIG. 1-1, when observing a longitudinal section obtained by cutting the ceramic substrate 20 in the thickness direction, it is preferable that the inner peripheral surface 50c of the plug arrangement hole 50 contacts the outer peripheral surface 55e of the plug 55 in a parallel positional relationship in order to improve the fixing strength of the plug 55. In other words, the outer peripheral surface 55e of the plug 55 has the same inclination angle as the inner peripheral surface 50c of the plug arrangement hole 50. Therefore, in a preferred embodiment, the plug 55 has an outer shape that is the same shape as the plug arrangement hole 50 (e.g., a truncated cone or a truncated pyramid). This allows the plug 55 to Placement hole 50This increases the area where the inner peripheral surface 50c of the plug 55 comes into contact with the outer peripheral surface 55e of the plug 55, thereby achieving high fixing strength.

[0052] An example of a direct fitting method is to embed the plug 55 by press-fitting it into the plug positioning hole 50. In this case, in order to obtain the desired fixing strength, it is preferable that the horizontal cross-sectional diameter of the plug 55 at any height position before press-fitting is slightly larger (for example, by about 5 to 20 μm in equivalent circle diameter) than the horizontal cross-sectional diameter of the plug positioning hole 50 at the same height position. Another example of a direct fitting method is to screw a male thread portion provided on an outer peripheral surface 55e of the plug 55 into a female thread portion provided on an inner peripheral surface 50c of the plug positioning hole 50.

[0053] One method for producing such a dense body and the plug 55 having a gas flow passage penetrating therethrough is to sinter a green body formed using additive manufacturing technology such as a 3D printer. Alternatively, the plug 55 may be formed by mold casting. Details of mold casting are disclosed, for example, in Japanese Patent No. 5458050. In mold casting, a ceramic slurry containing ceramic powder, a solvent, a dispersant, and a gelling agent is injected into the forming space of a mold, and the gelling agent is chemically reacted to gel the ceramic slurry, thereby forming a green body within the mold. In mold casting, a green body may be formed within the mold using an outer mold and a core (having the same shape as the gas flow passage 55d) made of a low-melting-point material such as wax. The green body may then be produced by heating the green body to a temperature above the melting point of the mold, melting and removing the green body or burning it away. Next, a porous raw material is placed in the cavity of the resulting green body corresponding to the gas flow passage 55d. Specifically, for example, a raw material made by adding a pore-forming agent such as resin or wax to an aggregate such as ceramic powder is made into a slurry or paste by adding a solvent as needed, and the resulting mixture is filled into the cavities corresponding to the gas flow paths 55d of the compact, and finally the entire mixture is fired. This firing process causes the pore-forming agent in the porous raw material to disappear, forming porous portions, and yields a plug 55 in which the main body and porous portions are integrated.

[0054] The porosity of the plug can be controlled, for example, by adjusting the content of the pore-forming material in the raw material composition before firing the ceramics that constitute the plug. For example, the amount of the pore-forming material may be reduced or eliminated in order to densify the plug.

[0055] (1-4. Base plate) The base plate 30 may be, for example, a circular plate (having the same diameter as or larger than the ceramic substrate 20) with good electrical and thermal conductivity. Referring to FIG. 1-1 , a refrigerant flow path 32 through which a refrigerant circulates may be formed inside the base plate 30. The refrigerant flowing through the refrigerant flow path 32 is preferably a liquid, and is preferably electrically insulating. Examples of electrically insulating liquids include fluorine-based inert liquids. The refrigerant flow path 32 may be formed, for example, in a single stroke across the entire base plate 30 in a plan view from one end (inlet) to the other end (outlet). One end and the other end of the refrigerant flow path 32 are connected to a supply port and a recovery port, respectively, of an external refrigerant device (not shown). The refrigerant supplied from the supply port of the external refrigerant device to one end of the refrigerant flow path 32 passes through the refrigerant flow path 32, returns from the other end of the refrigerant flow path 32 to the recovery port of the external refrigerant device, has its temperature adjusted, and is then supplied again from the supply port to one end of the refrigerant flow path 32. The base plate 30 is connected to a radio frequency (RF) power source and can also be used as an RF electrode.

[0056] Examples of materials constituting the base plate 30 include metal materials and composite materials of metal and ceramics. Metal materials include Al, Ti, Mo, W, and alloys thereof. Composite materials of metal and ceramics include metal matrix composites (MMCs) and ceramic matrix composites (CMCs). Specific examples of such composite materials include materials containing Si, SiC, and Ti (also referred to as SiSiCTi), porous SiC impregnated with Al and / or Si, and composite materials of Al2O3 and TiC. A material in which porous SiC is impregnated with Al is called AlSiC, and a material in which porous SiC is impregnated with Si is called SiSiC. It is preferable to select a material for the base plate 30 that has a thermal expansion coefficient close to that of the material of the ceramic substrate 20. For example, if the ceramic substrate 20 is made of alumina, the base plate is preferably made of SiSiCTi or AlSiC.

[0057] (1-5. Bonding layer) As shown in FIG. 1-1 , the upper surface 31 of the base plate 30 can be bonded to the lower surface 23 of the ceramic substrate 20 via a bonding layer 40. The bonding layer 40 is formed, for example, by thermal compression bonding (TCB). TCB is a well-known method in which a metal bonding material is sandwiched between two components to be bonded and heated to a temperature below the solidus temperature of the metal bonding material, and the two components are pressure-bonded together. The bonding layer 40 can be formed of a metal bonding layer using, for example, an Al-Mg bonding material or an Al-Si-Mg bonding material. The bonding layer 40 may also be formed of solder or a metal brazing material. Alternatively, the bonding layer 40 may be formed of a resin adhesive layer instead of a metal bonding layer. Examples of materials for the resin adhesive layer include a silicone resin adhesive, an epoxy resin adhesive, and an acrylic resin adhesive. To improve the uniformity of the thickness of the resin adhesive layer, a spacer (not shown) may be placed between the upper surface 31 of the base plate 30 and the lower surface 23 of the ceramic substrate 20.

[0058] The bonding layer 40 has a through hole 42. The through hole 42 is located opposite the large-diameter portion 34a of the gas hole 34 (described later). The through hole 42 is located coaxially with the large-diameter portion 34a, and the diameter of the through hole 42 may be the same as the diameter of the large-diameter portion 34a. In this specification, "matching" includes not only a perfect match but also a substantial match (e.g., within a tolerance range) (the same applies hereinafter). A single plug 55 may have multiple through holes 42. In this case, the multiple through holes 42 are preferably arranged point-symmetrically with respect to the central axis extending in the vertical direction of the plug 55. Providing multiple through holes 42 rather than a single large through hole 42 allows the size of each through hole 42 to be smaller, thereby reducing the risk of discharge. Providing multiple through holes 42 also ensures the necessary gas flow rate.

[0059] (1-6. Gas supply line) 1-1 , the gas supply path 60 for passing through the base plate 30 and the bonding layer 40 and supplying gas to the plug 55 includes, for example, a through hole 42 that passes through the bonding layer 40 in the vertical direction, and a gas hole 34 that communicates with the through hole 42 and passes through the base plate 30 from the upper surface 31 to the lower surface 33. A large diameter portion 34a may be further provided on the upper surface 31 of the base plate 30 at a position facing the through hole 42. By providing the through hole 42 and the large diameter portion 34a, when the plug 55 is placed in the plug placement hole 50, even if there is a manufacturing error in the plug placement hole 50 and / or the plug 55, a space that allows the plug 55 to enter is created, and therefore, such manufacturing error can be absorbed.

[0060] The configuration of the gas supply path 60 is not particularly limited. For example, as shown in FIG. 2, a semiconductor manufacturing equipment member 10 according to another embodiment of the present invention may be provided with one or more ring portions 64a extending concentrically around the base plate 30 in a plan view, one or more gas inlet portions 64b for supplying gas introduced from the underside 33 of the base plate 30 to the ring portion 64a, and a gas distributor 64c for distributing the gas from the ring portion 64a to each plug 55. In this embodiment, the upper end of the distributor 64c communicates with the through-hole 42 in the bonding layer 40. In FIG. 2, the same components as those in the embodiment shown in FIG. 1-1 are denoted by the same reference numerals. The number of gas inlet portions 64b may be fewer than the number of distributor portions 64c, for example, one. This allows the number of gas pipes connected to the base plate 30 to be fewer than the number of plugs 55. Other auxiliary passages (not shown) may also be provided.

[0061] (1-7.Other) Lift pin holes may be provided penetrating the semiconductor manufacturing equipment member 10. The lift pin holes are holes for inserting lift pins that move the wafer W up and down relative to the upper surface 21 of the ceramic substrate 20. When the wafer W is supported by, for example, three lift pins, the lift pin holes are provided in three locations.

[0062] <2. How to use semiconductor manufacturing equipment parts> Next, an example of how to use the semiconductor manufacturing equipment member 10 configured as described above will be described. First, with the semiconductor manufacturing equipment member 10 installed in a chamber (not shown), a wafer W is placed on the upper surface 21 of the ceramic substrate 20. Then, the chamber is depressurized using a vacuum pump to adjust the chamber to a predetermined degree of vacuum, and a voltage is applied to the electrodes 22 of the ceramic substrate 20 to generate an electrostatic adsorption force, thereby adsorbing and fixing the wafer W to the wafer-mounting surface (specifically, the upper surfaces of the seal bands 21a and the protrusions 21b).

[0063] Next, the chamber is filled with a reactive gas atmosphere at a predetermined pressure (e.g., several tens to several hundreds of Pa). In this state, a high-frequency voltage, such as an RF voltage, is applied between an upper electrode (not shown) provided on the ceiling of the chamber and the base plate 30 of the semiconductor manufacturing equipment member 10 to generate plasma. The surface of the wafer W is processed by the generated plasma. A coolant circulates through the coolant flow path 32 of the base plate 30. A backside gas is introduced into the gas supply path 60 from a gas cylinder (not shown) for cooling purposes. A thermally conductive gas (e.g., He gas) can be used as the backside gas. The backside gas is supplied to the plug placement holes 50 through the gas supply path 60 and is then supplied and sealed in the space between the backside of the wafer W and the reference surface 21c of the wafer mounting surface. The presence of this backside gas efficiently conducts heat between the wafer W and the ceramic substrate 20.

[0064] Furthermore, the provision of the plug 55 in the plug arrangement hole 50 can suppress discharge within the plug arrangement hole 50. Without the plug 55, electrons generated as a result of ionization of gas molecules by application of RF voltage accelerate and collide with other gas molecules, causing glow discharge and eventually arc discharge; however, with the plug 55, the electrons strike the plug 55 before colliding with other gas molecules, suppressing discharge.

[0065] <3. Manufacturing methods for semiconductor manufacturing equipment components> Next, a manufacturing method of the semiconductor manufacturing equipment component 10 will be described with reference to FIG. 3. First, a ceramic substrate 20, a base plate 30, and a metal bonding material 90 are prepared (FIG. 3A). The ceramic substrate 20 can be manufactured by the following procedure. A circular ceramic sintered plate, which is the base of the ceramic substrate 20, is produced by hot-pressing and firing a ceramic powder compact. The compact may be produced by stacking multiple tape compacts, by mold casting, or by compressing ceramic powder. The ceramic sintered plate has an electrode 22 built in. Next, a plug placement hole 50 is formed vertically through the ceramic sintered plate while avoiding the electrode 22. The plug placement hole 50 can be formed by machining. Furthermore, multiple protrusions 21b and a seal band 21a are formed on the upper surface of the ceramic sintered plate by laser processing or the like. The multiple protrusions 21b and the seal band 21a may be formed after the ceramic substrate 20 and the base plate 30 are bonded.

[0066] The base plate 30 has a refrigerant flow path 32 and a gas hole 34. The gas hole 34 has a large diameter portion 34a facing the upper surface 31. The base plate 30 having the refrigerant flow path 32 can be manufactured, for example, by joining a plurality of MMC plate members, in which grooves and holes corresponding to the refrigerant flow path 32 have been formed by machining, using a method such as TCB. The gas hole 34 can be formed by machining in the base plate 30 after the refrigerant flow path 32 has been formed. The metal bonding material 90 has a through hole 92 at a position facing the large diameter portion 34a of the gas hole 34. The through hole 92 can be formed by machining.

[0067] Next, a metal bonding material 90 is sandwiched between the lower surface 23 of the ceramic substrate 20 and the upper surface 31 of the base plate 30 to form a laminate. Preferably, the plug placement holes 50 of the ceramic substrate 20, the through holes 92 of the metal bonding material 90, and the gas holes 34 of the base plate 30 are coaxially aligned. The laminate is then pressed and bonded at a temperature below the solidus temperature of the metal bonding material 90 (e.g., a temperature 20°C below the solidus temperature but below the solidus temperature), and then returned to room temperature (TCB). As a result, the metal bonding material 90 and the through holes 92 become the bonding layer 40 and the through holes 42, respectively, resulting in a bonded body 94 in which the ceramic substrate 20 and the base plate 30 are bonded by the bonding layer 40 (FIG. 3B). The metal bonding material 90 preferably has a thickness of approximately 100 μm (e.g., 80 to 240 μm).

[0068] Next, a plug 55 having dimensions and a shape that can fit into the plug arrangement hole 50 is prepared ( FIG. 3B ). The height of the plug 55 is the same as the depth of the plug arrangement hole 50. Next, the plug 55 is press-fitted into the plug arrangement hole 50 from the upper opening 50a toward the lower opening 50b of the ceramic substrate 20. Alternatively, a male thread portion may be formed on the outer peripheral surface 55e of the plug 55, which has been formed in advance by firing or the like, and a female thread portion may be formed on the inner peripheral surface 50c of the plug arrangement hole 50. The plug 55 may then be inserted into the plug arrangement hole 50 by threading the male thread portion of the plug 55 and the female thread portion of the plug arrangement hole 50. The semiconductor manufacturing equipment component 10 is then completed by appropriately performing processes such as adjusting the overall shape ( FIG. 3C ). [Explanation of symbols]

[0069] 10: Semiconductor manufacturing equipment components 20: Ceramic substrate 21:Top surface 21a: Seal band 21b: Protrusion 21c: Reference plane 22: Electrode 23: Bottom surface 30: Base plate 31:Top surface 32: Coolant flow path 33: Bottom surface 34: Gas hole 34a: Large diameter section 40: Bonding layer 42:Through hole 50: Plug placement hole 50a: Upper opening 50b: Bottom opening 50c: Inner surface 55: Plug 55a: Upper end surface 55a1: Top opening 55a2: Reinforcement rib 55a3 :Segment 55b: Bottom end surface 55b1: Bottom opening 55c: Dense body 55d: Gas flow path 55d1: Surface 55e: Outer surface 60: Gas supply line 64a: Ring section 64b: Gas inlet 64c:Distribution section 90: Metal bonding material 92:Through hole 94 :zygote

Claims

1. A semiconductor manufacturing equipment member comprising: a ceramic substrate having an upper surface and a lower surface for mounting a wafer; a plug placement hole penetrating the ceramic substrate in the vertical direction; and a plug embedded in the plug placement hole, the plug is made of a dense body and has an upper end surface exposed on the upper surface side, a lower end surface exposed on the lower surface side, and a gas flow path extending from an upper end opening provided on the upper end surface through the dense body to a lower end opening provided on the lower end surface, The gas flow path is provided with a reinforcing rib that divides the upper end opening into a plurality of segments. Components for semiconductor manufacturing equipment.

2. 2. The semiconductor manufacturing equipment member according to claim 1, wherein the number of reinforcing ribs provided in one gas flow path is 1 to 5.

3. The major axis X of the upper end opening when the reinforcing rib is not present max 3. The semiconductor manufacturing equipment member according to claim 1, wherein the thickness is 0.1 mm or more.

4. Each of the plurality of segments of the upper end opening has a major axis Y max and the minor axis Y of the segment min However, 0.1≦Y min / Y max 3. The semiconductor manufacturing equipment member according to claim 1, wherein the relationship of ≦0.9 is satisfied.

5. Y max 5. The semiconductor manufacturing equipment member according to claim 4, wherein the thickness is 0.01 to 0.5 mm.

6. 3. The semiconductor manufacturing equipment member according to claim 1, wherein the reinforcing ribs are provided in the direction in which the gas flow path extends within a range of coordinate values ​​from 0 to 0.05 × H, where the coordinate axis is taken in the vertical direction and the coordinate value at the upper end surface of the plug is 0 and the coordinate value at the lower end surface is H.

7. 7. A semiconductor manufacturing equipment member according to claim 6, wherein the reinforcing rib is not provided at least in the range of coordinate values ​​exceeding 0.2*H to 1.0*H.

8. 3. The semiconductor manufacturing equipment member according to claim 1, wherein, in a cross section extending in the up-down direction through the central axis of the plug, the gas flow path has a flat cross-sectional shape such that, assuming that the reinforcing rib does not exist, a height D of the gas flow path in the up-down direction and a width W of the gas flow path in the left-right direction satisfy a relationship of 0.1≦D / W≦0.

9.

9. 9. The semiconductor manufacturing equipment member according to claim 8, wherein the height D is 10 to 300 μm.

10. 3. A semiconductor manufacturing equipment member according to claim 1, wherein the fracture toughness (KIC) of the portion of the plug made of the dense body is greater than the fracture toughness (KIC) of the ceramic substrate.