PESTICIDE MIXTURES COMPRISING A PYRAZOLE COMPOUND

Abstract

Pesticide mixtures comprising as active compounds: 1) 1-[(1RS)-1,2-dimethylpropyl]-N-ethyl-5-methyl-N-pyridazin-4-yl-1H-pyrazol-4-carboxamide and 2) at least one other compound B selected from B.1) succinate dehydrogenase inhibitors as defined in the description; B.2) oxysterol-binding protein inhibitors as defined in the description; B.3) complex III inhibitors at the Qi site selected from: a) fluoroylpicoxamid, and b) fenpicoxamid; B.4) strobilurins as defined in the description; B.5) C14-demethylase inhibitors in sterol biosynthesis as defined in the description; B.6) Cell division and cytoskeleton inhibitors as defined in the descriptive memorandum, B.7) Other compounds of unknown mode of action as defined in the descriptive memorandum; and B.8) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl]methyl]cyclopropancarboxamide; wherein Component 1) and Component 2) are present in a weight ratio of 1000:1 to 1:1000; methods and use of these mixtures for combating invertebrate pests such as insects, arachnids, nematodes and / or harmful fungi in and on plants, and for protecting such plants against infestation by pests and / or harmful fungi.

Description

PESTICIDE MIXTURES COMPRISING A PYRAZOLE COMPOUND The invention relates to synergistic pesticide mixtures comprising as active compounds a pyrazole compound and at least one fungicide or insecticide. Thus, the invention relates to pesticide mixtures comprising, as active compounds, 1) 1-[(1 phyS)-1,2-dimethylpropyl]-N-ethyl-5-methylNpyridazin-4-yl-1 H-pyrazole-4-carboxamide of Formula I (common name dimpropyridaz): ch3^ch3y 2) at least one other additional Compound B selected from B.1) Selected succinate dehydrogenase inhibitors of a) pidiflumethofen, b) pyraziflumide, c) inpyrfluxam, d) pyrapropoin, e) fluindapir, f) isoflucipram, g) 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4) and phosphorus h) 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]pyr idyne-3carboxamide, i) 2-(difluoromethyl)-N-(3-ethyl-1,1 -dimet¡l-¡ndan-4-¡l)p¡r¡d¡n-3-carboxamide, jfl uoromethyl)-N-[(3 R)-3-ethyl-1,1 -dimethyl-¡ndan-4-¡l]pyridine-3-carboxam¡da, k) 2-(difluoromethyl)-N- (1,1 -dimet¡l-3-propyl-indan-4-yl)pyridine-3-carboxam¡da, I) 2-(difluoromethyl)-N-[(3R)-1,1 -dimethyl-3propyl-¡ndan-4-¡l]-p¡r¡d¡n-3-carboxamide, m) 2-(d¡fluoromethyl)-N-(3-isobutyl-1,1 -dimethyl-indan-4-yl-carboxamide) 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indan-4 yl]pyridine-3carboxamide, o) N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-5-fluoro-methyl-methyl-methyl p (E)-2-[2-[(5-cyano-2-met¡l-phenoxy)methyl]phenyl]-3-methoxy-prop-2 enoate;B.2) Selected oxysterol attachment protein inhibitors of: a) oxathiapiproline, b) 2-{3-[2-(1 {[3,5-bis(difluoromethyl-1 H-pyrazol-1 -yl]acetyl}piper¡d in-4-yl)-1,3-thiazol-4-4-1-hydro-hydro oxazole-5yljphenyl methanesulfonate, c) 2-{3-[2-(1-{[3,5-bis(difluoro methyl)-1 H-pyrazol-1 -yl]acet¡l}p¡perid¡n-4-¡l) 1,3tlazol-4-¡l]-4,5-hydrox-1-2-zol-2-5 ¡l}-3-chlorophenyl methane sulfonate, d) 4-[1-[2-[3-(difluoromethyl)-5methyl-pyrazol-1 -yl]acetyl l]-4-p¡ peridyl]-N-tetral and n-1 -yl-pyridin-2-carboxamide, e) 4-[1 -[2-[3,5bis(difluoromethyl)pyrazol-1 -yl]acetyl]-4-p¡peridyl]-N-tetralin-1 -yl-pyridine-2-carboxamide, f) 4-[1-[2-[3(difluoromethyl)-5-(tr¡fluorometh¡l)p¡razol-1 -yl]acetyl]-4-piperidyl]-N-tetralin-1 -yl-pyridine-2-carboxamide, g) 4-[1 -[2-[5-cyclopropyl-3-(difluoromethyl)pyrazol-1 -yl]acetyl]-4-piperidyl]-N-tetralin-1 -yl-pyridine-2-carboxamide, h -[2-[5-methyl-3-(trifluoromethiI)pyrazol-1 -yl]acetyl]-4-plperidyl]-N-tetralin-1 -yl-pyridine2-carboxamide,i) 4-[1 -[2-[5-(difluoromethyl)-3-(trifluoromethyl I) pyrazol-1 -yl]acet¡ I]-4-piperid il]-N-tetral i n1-yl-pyridin-2-carboxamida, j) 4 [1 [2-[3,5-bis(trifluoromethyl)pyrazol-1-yl]acetyl]-4-piper¡dyl]-N-tetralin-1yl-pyridin-2-carboxamida, yk) 4-[1 -[2-[5-cyclopropiI-3-(trifluoromethyl)pyrazol-1 -yl]acetyl]-4-piperidyl]-N-tetralin-1 -il-pyridin-2-carboxamida, B.3) Inhibitors of the complex III in the Q¡ site selected by: a) florilpicoxamid, yb) fenpicoxamid; B.4) Estrobilurinas (inhibidores del complejo III, sitio Qo) seleccionadas de a) (Z,2E) 5 [1-(2,4- d¡clorofen¡l)p¡razol-3-¡l]-ox¡-2-metox¡¡m¡no-N,3-d¡metil-pent-3-enam¡da, b) (Z,2E) 5 [1 (4clorofenil)pirazol-3-yl]oxi-2-metoxiim¡no-N,3-dimetil-pent-3-enamida, yc) metiléster del ácido 2(orto-((2,5-dimetilfenil-oximetilen)fenil)-3-metoxi-acrílico; B.5) C14-demethylase inhibitors in esteral biosynthesis (DMI fungicides) selected from a) 2-(2,4-difluorophenyI)-1,1 -difluoro-3-(tetrazol-1 -yl)-1 -[5-[4-(2,2,2-tnfluoroethoxy-b)phenyl,2]) 2-(2,4-difluorophenyl)-1,1-difluoro-3-(tetrazol-1-yl)-1 [5 [4 (tr¡fluoromethoxy¡)phen¡l]-2-p¡r¡dyl]propan2-ol, c) 2-(chloromethyl)-2-meth¡l-5-l-(methl-l¡¡-1) (1,2,4-triazol-1 ¡lmethyl)cyclopentanol, d) 4-[[6-[2-(2,4d if I uorophenyl)-1,1 -difl uoro-2-hydroxy-3-(5-su lian i I -1,2,4-triazol-1 -yl)pyrizol-3-trioxyl]]]; B.6) Selected cell division and cytoskeleton inhibitors of a) pyridaclomethyl, b) N-ethyl-2-[(3ethin¡l-8-meth¡l-6-qu¡nol¡l)oxy]butanam¡date, c) N-ethyl-2-[(3-ethyl-8 methyl-6 quinolyl)oxy]-2-methylsulfanylacetamide, d) 2-[(3-ethyn¡l-8-methyl-6-qu¡nol)oxy]-N (2-fluoroethyl)butanamide, e) 2-[(3-ethynyl-8-methyl-6qu¡nolyl)oxy]-N-(2-fluoroet¡l)-2-methoxy-acetamide, f) 2-[(3-ethynyl-8-met¡l-6-quinolyl)oxy]-N-propylbutanamide, g) 2-[(3-et¡n¡l-8-meth¡l-6-qu¡nol¡l)ox¡]-2-methox¡-N-prop¡l-acetamide, h) 2-[(3-ethynyl-8methyl-6-quinol)oxy]-2-methylsulfanyl-N-propyl-acetate [2(3) ethinyl-8-methyl-6-quinolyl)oxy]-N-(2fluoroethyl)-2-met¡lsulfan¡l-acetamide, j) 4-(2-bromo-4-fluoro-phen¡l)-N-(2-chloro-6-fluoro-phen¡l)-2,5dimethyl-pyrazole-3 amine, B.7) Other compounds of unknown mode of action selected from a) diclocimet, b) phenytropane, c) harpine, d) picarbutrazox, e) diclobenthiazox, f) pyrifenamine, g) quinofumelin, h) ipflufenoquine, i) 4 clopropyl-N-(2,4-dmethoxyphenyl)thiadiazol-5-carboxam¡da, j) N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4thiadiazol-5-¡l]ox¡]-2,5-dimethyl-phen¡l]-N-et¡lN-methyl-formam¡dine, k) N'-(5-bromo-6-indan-2-ilox¡-2methyl-3-p¡rid¡l)-N-ethyl-N-methyl-formam¡d¡na, I) N'-[5-bromo-6-[1-(3,5-difluorophen¡l)ethoxy¡]-2-met¡l-3p¡r¡d¡l]-N-et¡lN-met¡l-formam¡na, m) N'-[5-bromo-6-(4-¡soprop¡lc¡clohexox¡)-2-met¡l-3-p¡r¡d¡l]-N-et¡lN-methyl-formamidine, η) N' [5 bromo-2-met¡l-6-(1-p¡hd¡l]-N-et¡lN-methyl-formam¡na, o) ethyl (Z) 3 amino-2-cyano-3-phenyl-prop-2-enoate, p) pentyl N-[6-[[(Z) -methyltetrazol-5-yl)-phenylmethylene]amino]ox¡met¡l]-2-pyridyl]carbamate, q) but-3-inyl N-[6-[[(Z)-[(1 -methyltetrazol-5-yl)-phenylmethylene]am¡no]ox¡methl-2 (picarbutrazox),r) 2-(6-benzyl-2-pyridyl)quinazoline, s) 2[6-(3-fluoro-4-methoxy-phenyl)-5-methyl-2-pyridyl]quinazoline, t) N'-(2,5-dimethyl-4-phenoxy-phenyl)-N-ethyl-Nmethyl-formamidine, and, B.8) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1yl]phenyl]methyl]cyclopropanecarboxamide; where Component 1) and Component 2) are present in a weight ratio of 1000:1 to 1:1000. A typical problem in pest control is the need to reduce the dosage of the active ingredient to minimize or avoid adverse environmental or toxicological effects while still achieving effective pest control. Another challenge is the need for readily available pest control agents that are effective against a broad spectrum of crop pests and diseases. Another difficulty related to pesticide use is that the repeated and exclusive application of a single pesticide compound often leads to the rapid selection of pests and harmful fungi that develop natural or adaptive resistance to the active ingredient. Therefore, pest control agents are needed to help prevent or overcome resistance. The compound in Formula I is known from WO 2012 / 143317. It is mentioned that this compound is useful for combating invertebrate pests. Therefore, an object of the invention is to provide pesticide mixtures that solve at least one of the analyzed problems, such as reducing the dosage, improving the spectrum of action, combining inactivating action with prolonged control, or controlling resistance. It was discovered that at least one of these objectives is achieved by combining active compounds defined at the beginning. Furthermore, it was also discovered that the simultaneous application, i.e., joint or separate, of dimpropyridaz and one or more Active Compound B, or the successive application of dimpropyridaz and one or more Active Compound B, allows for better control of pests and / or harmful fungi compared to the control rates that are possible with the individual compounds. Furthermore, the invention relates to: an agricultural composition comprising the pesticide mixture, as defined herein, and at least one acceptable liquid and / or inert solid carrier; a method for controlling or combating invertebrate pests, comprising bringing the pest or its food supply, habitat or breeding site into contact with a pesticide-effective amount of the pesticide mixture, as defined herein; the use of the pesticide mixture as defined herein to protect growing plants or plant propagation material against attack or infestation by invertebrate pests; a method for controlling harmful phytopathogenic fungi, wherein the fungi, their habitat or the plants to be protected against fungal attack, the soil or seeds are treated with an effective amount of the pesticide mixture comprising dimpropyridaz and at least one specific Compound B; a method for protecting plants from harmful phytopathogenic fungi, wherein the fungi, their habitat or the plants to be protected against fungal attack, the soil or seeds are treated with an effective amount of the pesticide mixture comprising dimpropyridaz and at least one specific Compound B; and The mixtures of the invention can be a physical mixture of dimpropyridaz and at least one compound B. Accordingly, the invention also provides a mixture comprising dimpropyridaz and at least one compound B. However, the composition can also be any MA / a / ¿U¿l / Ul U111 combination of dimpropyridaz with at least one Compound B, and it is not necessary that Compounds A and B be present together in the same formulation. The term invertebrate pest (also called animal pest) as used herein comprises populations of animals, such as insects, arachnids, and nematodes, that can attack plants and thus cause significant damage to the attacked plants. The expressions “compound according to the invention”, “compound of Formula I” or “pyrazole compound A” comprise dimpropyridaz as defined herein, and a stereoisomer, a salt, a tautomer or an N-oxide thereof. Dimpropyridaz has a chiral center; it is present as a mixture of enantiomers. The invention provides pure enantiomers or diastereomers and mixtures thereof, and the use according to the invention of pure enantiomers of dimpropyridaz or mixtures thereof. Additional commercially available Compound B products can be found in The Pesticide Manual, 17th Edition, British Crop Protection Council (2015), among other publications, and in its online database https: / / www.bcpc.org / product / bcpc-online-pesticide-manual-latest-version. Compounds B1 to B8, respectively, and their fungicidal or pesticidal action are known from CN 1456054, WO2017008583, CN 1907024, WO2015197530, WO2016097003, WO2016139189, WO2016096944, WO2016096849, WO2017220491, WO2018046431, WO2016109257, WO2016122802, WO 2016187201, WO2018098216, WO2018098243, WO2018098245, WO 2014 / 60177, WO2013116251, WO 2015036379, WO13127704, WO2015 / 65922, WO 2011 / 80044, WO2012 / 146125, WO 2009115557, WO2012045798, WO2012 / 69652, EP2865265 and WO2016 / 180802, respectively. It was found that the simultaneous application, i.e., jointly or separately, of dimpropyridaz and at least one Compound B or the successive application of dimpropyridaz and at least one Compound B allows for better control of animal pests and / or harmful fungi than is possible with the individual compounds alone (synergistic mixtures). Dimpropyridaz can be used as a synergist for various fungicidal active compounds. When applied simultaneously (i.e., jointly or separately) with at least one active compound B1 to B7, the fungicidal activity is superadditively enhanced. When applied simultaneously (i.e., jointly or separately) with compound B8, the insecticidal activity is superadditively enhanced. The observations made below regarding preferred embodiments of the variables are also valid on their own, as well as preferably in combination with each other with respect to dimpropiridaz, as appropriate, and also with respect to the uses, methods, and mixtures of the invention. The particular aspects of the invention are any of the pesticide mixtures A, B, C, D, E, F, G and H: Pesticide Mixture A comprises the following active components: A1) dimpropiridaz, and A2) succinate dehydrogenase inhibitors selected from group B.2 as defined at the outset; wherein Component A1) and Component A2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. Preferred Mixtures A are combinations of dimpropyridase with a selected Compound B of: pidiflumethofen, inpyrfluxam, pyrapropoin, isoflucipram, 2-(difluoromethyl)-N-(1,1,3-trimethyl-indan-4 yl)pyr¡d¡n-3-carboxamide,, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]p¡r¡d¡n-3-carboxam¡da, 2(difluoromethyl)-N-(3-eth¡l-1,1 -dimet¡l-¡ndan-4-¡l)p¡d¡d-carboxam¡da, 3, 2-(difluoromethyl)-N-[(3R)-3-et¡l-1,1dimeth¡l-¡ndan-4-¡l]p¡r¡d¡n-3-carboxamide, 2-(difluoromethyl)-N-(1,1 -dimeth¡l-3-prop¡l-¡ndan-4-¡l)p¡r¡din-3carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1 -dimeth¡l-3-prop¡l-¡ndan-4-¡l]-p¡r¡dboxam-3-carboxamide(dif luoromethyl)-N-(3-isobuty I-1,1 -dimethyl-indan-4-¡l)p¡r¡d¡n-3-carboxamide, and 2-(difluoromethyl)-N-[(3R)-3isobutyl-1,1-dimethyl-indan-4-yl]p¡r¡n-3-carboxamide enclave relationships mentioned earlier. In another embodiment, the preferred mixtures A are combinations of dimpropyridaz with a Compound B selected from: A2 a) to A2 n) as defined at the beginning in the mixing ratios as mentioned above. Pesticide Mixture B comprises the following active components: B1) dimpropiridaz, and B2) oxysterol-binding protein inhibitors selected from group B.2 as defined at the outset; wherein Component B1) and Component B2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excess dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excess Compound B. The preferred Mixtures B are combinations of dimpropyridaz with a Compound B selected from: oxatiapiproline, and 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1 / 7-pyrazol-1-yl]acetyl}piperidin-4-yl) 1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate in the above-mentioned mixture ratios. In another embodiment, the preferred Mixtures B are combinations of dimpropyridaz with a Compound B selected from B.2a) to B.2c) as defined at the outset in the blending ratios mentioned above. Also in another embodiment, the preferred Mixtures E are combinations of dimpropyridaz with a Compound B selected from B2d), B2h), and B2t) as defined at the outset in the blending ratios mentioned above. Pesticide Mixture C comprises the following active components: C1) dimpropiridaz, and C2) a) florylpicoxamid, or b) fenpicoxamid; wherein Component C1) and Component C2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. A preferred mixture C is the combination of dimpropyridaz with florylpicoxamid in the above-mentioned mixing ratios. Pesticide Mixture D comprises the following active components: D1) dimpropiridaz, and D2) strobilurins selected from group B.4 as defined at the beginning; wherein Component D1) and Component D2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. The preferred D mixtures are combinations of dimpropyridaz with a Compound B selected from: (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazol-3-1]-oxy-2-methoxymino- / \ / ,3-dimethyl-pent-3-enamide, and (Z,2E)-5-[1-(4-chlorophenyl)pyrazol-3-1]oxy-2-methoxymino- / \ / ,3-dimethyl-pent-3-enamide in the above-mentioned mixture ratios. Pesticide Mixture E comprises the following active components: E1) dimpropiridaz, and E2) DMI fungicides selected from group B.5 as defined at the outset; wherein Component E1) and Component E2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. A preferred Mixture E is the combination of dimpropyridaz with 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzenitrile in the above-mentioned mixing ratios. Pesticide Mixture F comprises the following active components: F1) dimpropiridaz, and F2) cell division and cytoskeleton inhibitors selected from group B.6 as defined at the outset; wherein Component F1) and Component F2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. A preferred Mixture F is the combination of dimpropyridaz with pyridaclomethyl at the mixing rates mentioned above. Pesticide Mixture G comprises the following active components: G1) dimpropyridaz, and ινΐΛ / a / zuzi / ui u111 G2) other compounds of unknown mode of action selected from group B.6 as defined at the beginning; wherein Component G1) and Component G2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. The preferred G mixtures are combinations of dimpropyridaz with a Compound B selected from: picarbutrazox, quinofumelin, ipflufenoquin, and N-(2,5-dimethyl-4-phenoxyphenyl)-A / -ethyl- / V-methylformamidine in the above-mentioned mixture ratios. Pesticide mixture H comprises the following active components: H1) dimpropyridaz, and H2) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy¡-3-(3,4,5-trichlorophen¡l)-3-(trifluoromethyl)pyrrolidin-1yl]phenyl]methyl]cyclopropanecarboxamide; wherein Component H1) and Component H2) are present in a total weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, in particular 20:1 to 1:20. In the aforementioned ratios, one embodiment refers to ratios of 1:1 with respect to excessive dimpropiridaz; in another embodiment, the ratios are 1:1 with respect to excessive Compound B. Binary mixtures of dimpropyridaz and a Compound B are a preferred embodiment of the invention. The mixtures of the invention are particularly suitable for controlling Lepidoptera, Coleoptera, Diptera, Thysanoptera and Hemiptera. In particular, mixtures are useful for the control of Thysanoptera and Hemiptera, especially Hemiptera. In a preferred embodiment, the invention relates to Pesticide Mixtures A to H that are particularly suitable for controlling pests of the Pentatomidae and / or Cicadellidae and / or Aleyrodidae and / or Aphididae families, which are typical pests of soybean plants. In a preferred embodiment, the invention relates to the use or method comprising the application of the pesticide mixtures defined above, wherein the pests are selected from the group consisting of green stink bug (Acrosternum hilare), brown marmorated stink bug (Halyomorpha halys), redline stink bug (Piezodorus guildinii), neotropical brown stink bug (Euschistus heros), brown stink bug (Euschistus servus), kudzu stink bug (Megacopta cribraria), red-shouldered stink bug (Thyanta custator) and dark stink bug (Euschistus tristigmus), green field stink bug (Nezara viridula), and combinations thereof. In one embodiment, the target bugs are Nezara viridula, Piezodorus spp., Acrosternum spp., Euschistus, and in particular Euchistus heros. More commonly, pesticide mixtures are used to control Pentatomidae, which includes the green stink bug (Acrosternum hilare), the brown marmorated bug (Halyomorpha halys), the red-lined bug (Piezodorus guildinii), the neotropical brown bug (Euschistus heros), the brown bug (Euschistus servus), and the stink bug. MA / a / ¿U¿l / Ul U111 of kudzu (Megacopta cribraria), red-shouldered stink bug (Thyanta custator), dark stink bug (Euschistus tristigmus), and green field bug (Nezara viridula). Pesticide mixtures A to H are preferably used in Faboideae, particularly soybeans, to control stink bugs, for example, Nezara spp. (e.g., Nezara viridula, Nezara antennata, Nezara hilaris), Piezodorus spp. (e.g., Piezodorus guildinii), Acrosternum spp. (e.g., Acrosternum hilare), Euchistus spp. (e.g., Euchistus heros, Euschistus servus), Halyomorpha halys, Megacopta cribaria, Plautia crossota, Riptortus clavatus, Rhopalus musculatus, Antestiopsis orbitalus, Dectes texanus, Dichelops spp. (e.g., Dichelops furcatus, Dichelops melacanthus), Eurygaster spp. (for example, Eurygaster intergriceps, Eurygaster maurd), Oebalus spp. (for example, Oebalus mexicana, Oebalus poecilus, Oebalus pugnase), Scotinophara spp. (for example, Scotinophara lurida, Scotinophara coarctatd). Preferred targets include Acrosternum hilare, Antetiopsis orbitalus, Dichelops furcatus, Dichelops melacanthus, Euchistus heros, Euschistus servus, Megacopta cribaría, Nezara viridulá, Nezara hilare, Piezodorus guildinii, Halyomorpha halys. Other Pentatomidae pests that can be controlled according to the invention are Eysarcoris, in particular, Eysarcoris aeneus. The mixtures are preferably used in Faboideae, in particular soybeans, to control whiteflies, for example, sweet potato whitefly (Bemisia tabaci). The mixtures are preferably used in Faboideae, in particular soybeans, to control aphids, for example, the soybean aphid (Aphis glycines). The mixtures are preferably used in Faboideae, in particular soybeans, to control leafhoppers, for example, potato leafhoppers (Empoasca fabae). Preferably, the mixtures are used in Faboideae, in particular soybeans, to control cicadas, for example, Green parrot (Empoasca kraemerí). Pesticide mixtures A to H are preferably used to control lepidoptera (Lepidoptera), such as Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura; beetles (Coleoptera), such as Anthonomus grandis, Anthonomus pomorum, and thrips (Thysanoptera), such as Scirtothrips citri. The mixtures of the invention and the compositions thereof, respectively, are particularly suitable for controlling the following plant diseases: Albugo spp. (white rust) in ornamentals, vegetables (e.g., A. candida) and sunflowers (e.g., A. tragopogonis)', Alternaria spp. (Alternaria leaf spot) in vegetables (e.g., A. dauci or A. porri), oilseed rape (A. brassicicola or brassicae), sugar beet (A. tenuis), fruits (e.g., A. grandis), rice, soybeans, potatoes and tomatoes (e.g., A. solani, A. grandis or A. ainternata), tomatoes (e.g., A. solani or A. ainternata) and wheat (e.g., A. triticina); Aphanomyces spp. in sugar beet and vegetables; Ascochyta spp. in cereals and vegetables, e.g., A. tritici (anthracnose) in wheat and A. hordei in barley; Aureobasidium zeae (syn. Kapatiella zeae) in maize; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), for example, Southern leaf blight (D. maydis) or Northern leaf blight (B. zeicola) in maize, for example, leaf spot (B. sorokiniana) in cereals and, for example, B.oryzae in rice and turf; Blumeria (formerly Erysiphe) graminis (powdery mold) in cereals (e.g., wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) in fruits and berries (e.g., strawberries), vegetables (e.g., lettuce, carrots, celery and cabbages); B. squamosa or B. allü in the onion family), oilseed rape, ornamentals (e.g., B. elliptica), vines, forest plants and wheat; Bremia lactucae (downy mildew) in lettuce; Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) in broadleaf and evergreen trees, e.g., C. ulmi (Dutch elm disease) in elms; Cercospora spp. (Cercospora leaf spots) in maize (e.g., gray leaf spot: C. zeae-maydis), rice, sugar beet (e.g., C. beticola), sugarcane, vegetables, coffee, soybean (e.g., C. sojina or C. kikuchii) and rice; Cladobotryum (syn. Dactylium) spp. (e.g., C.mycophilum (formerly Dactylium dendroides, teleomorph: Nectria albertinii, Nectria resella syn. Hypomyces rosellus) in fungi; Cladosporium spp. in tomatoes (e.g., C. fulvum: leaf mold) and cereals, e.g., C. herbarum (black ear) in wheat; Claviceps purpurea (ergot) in cereals; Cochliobolus (anamorph: Helminthosporium of Bipolaris) spp. (leaf spots) in maize (C. carbonum), cereals (e.g., C. sativus, anamorph: B. sorokiniana) and rice (e.g., C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) in cotton (e.g., C. gossypii), corn (e.g., C. graminicola: anthracnose stalk rot), soft fruits, potatoes (e.g., C. coccodes: black spot), beans (e.g., C. lindemuthianum), soybeans (e.g., C. truncatum or C. gloeosporioides), vegetables (e.g., C. lagenarium or C. capsici), fruits (e.g., C. acutatum), coffee (e.g., C. coffeanum or C. kahawae) and C.Gloeosporioides in various crops; Corticium spp., for example, C. sasakii (sheath blight) in rice; Corynespora cassiicola (leaf spots) in soybeans and ornamentals; Cycloconium spp., for example, C. oleaginum in olive trees; Cylindrocarpon spp. (for example, fruit tree ulcer or young vine rot, teleomorph: Nectria or Neonectria spp.) in fruit trees, vines (for example, C. Hriodendri, teleomorph: Neonectria Hriodendri, black foot disease) and ornamentals; Dematophora (teleomorph: Roselliniá) necatrix (root and stem rot) in soybeans; Diaporthe spp., for example, D. phaseolorum (seedling damping-off) in soybeans; Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. in maize, cereals such as barley (e.g., D. teres, net blotch) and wheat (e.g., D. tritici-repentis: brown blotch), rice and turfgrass; Esca (acronecrosis (dieback), apoplexy) in grapevines, caused by Formitiporia (syn. Phellinus) punctata, F.Mediterranean, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and / or Botryosphaería obtusa; Elsinoe spp. in pome fruits (E. pyri), soft fruits (E. veneta: anthracnose) and vines (E. ampelina: anthracnose); Entyloma oryzae (leaf blight) on rice; Epicoccum spp. (black mold) on wheat; Erysiphe spp. (powdery mold) on sugar beet (E. betae), vegetables (e.g. E. pisi), such as cucurbits (e.g. E. cichoracearum), cabbage, oilseed rape (e.g. E. cruciferarum); Eutypa lata (Eutypa ulcer or acronecrosis, anamorph: Cytosporina lata, syn. Libertella blepharis) in fruit trees, vines and ornamental woodlands; Exserohilum (syn. Helminthosporium) spp. in maize (e.g., E. turcicum); Fusarium (teleomorph: Gibberella) spp. (wilt, root or stem rot) in various plants, such as F. graminearum or F.culmorum (root rot, scab, or top blight) in cereals (e.g., wheat or barley), F. oxysporum in tomatoes, F. solani (f. sp. glycines now syn. F. virguliforme) and F. tucumaniae and F. brasiliense, each of which causes sudden death syndrome in soybeans, and F. verticHIioides in maize; Gaeumannomyces graminis (take-all) in cereals (e.g., wheat or barley) and maize; Gibberella spp. in cereals (e.g., G. zeae) and rice (e.g., G. fujikuroi: Bakanae disease); Glomerella cingulata in grapevines, pome fruits, and other plants, and G. gossypü in cotton; grain staining complexes in rice; Guignardia bidwellii (black rot) in grapevines; Gymnosporangium spp. in rosaceous plants and junipers, for example, G. sabinae (rust) on pears; Helminthosporium spp. (syn. Drechslera, teleomorph: Cochliobolus) on maize, cereals, potatoes and rice; Hemileia spp., for example, H. vastatrix (coffee leaf rust) on coffee; Isariopsis clavispora (syn.Cladosporium vitis) in grapevines; Macrophomina phaseolina (syn. phaseoli) (root and stem rot) in soybeans and cotton; Microdochium (syn. Fusarium) nivale (pink snow mold) in cereals (e.g., wheat or barley); Microsphaera diffusa (powdery mold) in soybeans; Monilinia spp., e.g., M. laxa, M. fructicola, and M. fructigena (syn. Monilia spp.: blossom and twig blight, brown rot) in stone fruits and other Rosaceae plants; Mycosphaerella spp. in cereals, bananas, soft fruits and peanuts, such as, M. graminicola (anamorph: Zymoseptoria tritici formerly Septoria tritici: Septoria spot) in wheat or M. fijiensis (syn. Pseudocercospora fijiensis: black Sigatoka disease) and M. musicola in bananas, M. arachidicola (syn. M. arachidis or Cercospora arachidis), M. berkeleyi on peanuts, M. pisi on peas, and M. brassiciola on brassicas; Peronospora spp. (mildew) on cabbage (e.g. P. brassicae), oilseed rape (e.g. P. parasitica), onions (e.g. P.destructor), tobacco (P. tabaciná) and soybeans (e.g. P. manshurica); Phakopsora pachyrhizi and P. meibomiae (soybean rust) in soybeans; Phialophora spp. for example, in grapevines (e.g. P. tracheiphila and P. tetraspora) and soybeans (e.g. P. gregata: stem rot); Phoma lingam (syn. Leptosphaeria biglobosa and L. maculaos: root and stem rot) in oilseed rape and cabbage, P. betae (root rot, leaf spot and seedling drop) in sugar beet and P. zeae-maydis (syn. Phyllostica zeae) in maize; Phomopsis spp. in sunflowers, grapevines (e.g., P. viticola: canker and leaf spot) and soybeans (e.g., stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum): Physoderma maydis (brown spots) in maize; Phytophthora spp. (wilt, root, leaf, fruit and stem rot) in various plants, such as paprika and cucurbits (e.g., P. capsici), soybeans (e.g., P. megasperma, syn. P.soybeans), potatoes and tomatoes (e.g., P. infestaos: late blight) and broadleaf trees (e.g., P. ramorum: oak sudden death); Plasmodiophora brassicae (club root) in cabbage, rapeseed, radish and other plants; Plasmopara spp., e.g., P. viticola (grapevine downy mildew) in grapevines and P. halstedii in sunflowers; Podosphaera spp. (powdery mildew) on rosaceous plants, hops, pome fruits and soft fruits (e.g., P. leucotricha on apple) and cucurbits (P. xaothii), Polymyxa spp., for example, on cereals, such as barley and wheat (P. gramiois) and sugar beet (P. betae) and thus transmitted viral diseases; Pseudocercosporella herpotrichoides (syn. Oculimacula yalluodae, O. acuformis: eyespot, teleomorph: Tapesia yalluodae) on cereals, for example, wheat or barley; Pseudoperooospora (downy mildew) on various plants, for example, P. cubensis on cucurbits or P.humili in hops; Pseudopezicula tracheiphila (disease causing red color or rotbrenner, anamorph: Phialophora) in vines; Puccinia spp. (ruffles) on several plants, for example, P. triticina (leaf or brown rust), P. striiformis (striped or yellow rust), P. hordei (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust) on cereals, such as, for example, wheat, barley or rye; kuehnii (orange roya) on sugarcane and P. asparagi on asparagus; Pyrenopeziza spp., for example, P. brassicae in oilseed rape; Pyrenophora (anamorph: Drechslera) tritici-repentis (brown spot) in wheat or P. teres (red spot) in barley; Pyricularia spp., for example, P. oryzae (teleomorph: Magnaporthe grisea: rice fungus) on rice and P. grisea on turf and cereals; Pythium spp. (seedling drop) in turf, rice, maize, wheat, cotton, oilseed rape, sunflower, soybean, sugar beet, vegetables and various other plants (e.g., P .ultimum or P. aphanidermatum) and P. oligandrum in fungi; Ramularia spp., for example, R. collo-cygni (Ramularia leaf spots, physiological leaf spots) in barley and R. beticola in sugar beet; Rhizoctonia spp. in cotton, rice, potato, turfgrass, corn, rapeseed, potato, sugar beet, vegetables and various other plants, for example, R. solani (root and stem rot) in soybeans, R. solani (sheath blight) in rice or R. cerealls (Rhizoctonia spring blight) in wheat or barley; Rhizopus stolonifer (black mold, mild rot) in strawberry, carrot, cabbage, grapevines and tomato; Rhynchosporium secalis and R. commune (scald) in barley, rye and triticale; Sarocladium oryzae and S. attenuatum (sheath rot) in rice; Sclerotinia spp. (stem rot or white mold) in vegetables (S. minor and S. sclerotiorum) and field crops such as oilseed rape, sunflower (e.g., S. sclerotiorum) and soybean, S. rolfsii (syn.Athelia rolfsii) in soybeans, peanuts, vegetables, maize, cereals and ornamentals; Septoria spp. in several plants, for example, S. glycines (brown spots) in soybean, S. tritici (sin. Zymoseptoria tritici, Septoria spot) in wheat and S. (sin. Stagonospora) nodorum (Stagonospora spot) in cereals; Uncinula (sin. Erysiphe) necator (powdery mildew, anamorph: Oidium tucken) in vines; Sethospaeria spp. (leaf blight) in maize (eg, S. turcicum, sin. Helminthosporium turcicum) and turf; Sphacelotheca spp. (tizne) in maize, (for example, S. reiliana, sin. Ustilago reiliana: tizne of upper part), sorghum and sugarcane; Sphaerotheca fuliginea (sin. Podosphaera xanthii: powdery mildew) in cucurbits; Subterranean spongospora (powdery costra) in potatoes and, therefore, transmitted viral diseases; Stagonospora spp. in cereals, for example, S. nodorum (spot Stagonospora, teleomorph: Leptosphaeria [sin. Phaeosphaeria] nodorum, sin.Septoria nodorum) in wheat; Synchytrium endobioticum in potato (potato wart disease); Taphrina spp., for example, T. deformans (leaf curl disease) in peach and T. pruni (plum pit) in plums; Thielaviopsis spp. (black root rot) in tobacco, pome fruits, vegetables, soybeans, and cotton, for example, T. basicola (syn. Chalara elegans); Tilletia spp. (common smut or stinking sooty) in cereals, such as T. tritici (syn. T. caries, wheat smut) and T. controversa (dwarf smut) in wheat; Trichoderma harzianum in fungi; Typhula incarnata (gray snow mold) in barley or wheat; Urocystis spp., for example, U. occulta (stem sooty) on rye; Uromyces spp. (rust) on vegetables, such as beans (for example, U. appendiculatus, syn. U. phaseoli), sugar beet (for example, U. betae or U. beticola) and on pulses (for example, U. vignae, U. pisi, U. víciae-fabae and U. fabae); Ustilago spp.(loose sooty) on cereals (e.g., U. nuda and U. avaenae), maize (e.g., U. maydis: corn sooty) and sugar cane; Venturia spp. (scab) on apples (e.g., V. inaequalis) and pears; and Verticillium spp. (wilt) on various plants, such as fruits and ornamentals, vines, soft fruits, vegetables and field crops, e.g., V. longisporum on rapeseed, V. dahliae on strawberries, rapeseed, potatoes and tomatoes, and V. fungicola on fungi; Zymoseptoria tritici on cereals. The mixtures of the invention can be converted into the usual types of agrochemical compositions, for example, solutions, emulsions, suspensions, powders, pastes, granules, pressed products, capsules, and mixtures thereof. These and other types of compositions are defined in “Catalogue of pesticide formulation types and International coding system, Technical Monograph No. 2, 6th edition, May 2008, CropLife International.” The compositions are prepared in the known way, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005. The mixtures of the invention are used as such or in the form of compositions by treating insects, fungi, or plants, plant propagation materials such as seeds, soil, surfaces, materials, or rooms that are to be protected against insect or fungal attack, with an effective pesticide quantity of the active compounds. Application can be carried out before and after insects infest the plants or plant propagation materials such as seeds, soil, surfaces, materials, or rooms. The invention also includes a method for combating harmful animal and fungal pests, comprising bringing the fungi and / or animal pests, their habitat, breeding site, food supply, cultivated plants, seeds, soil, area, material or environment where the animal pests grow or may grow, or the materials, plants, seeds, soils, surfaces or spaces that are to be protected against attack or infestation by animals, into contact with an effective pesticide quantity of a mixture according to the invention. Typically, dimpropyridaz and compound B or compounds B are applied in a weight ratio of 1000:1 to 1:1000, preferably 100:1 to 1:100, or 20:1 to 1:20, in particular 10:1 to 1:10. In general, the effective amount as a pesticide means the quantity of the mixtures of the invention or of the compositions comprising the mixtures, necessary to achieve a perceptible effect on the growth, including effects of necrosis, death, retardation, prevention and elimination, destruction, or reduction of the occurrence and activity of the target organism. The effective amount as a pesticide may vary depending on the different mixtures and / or compositions used in the invention. An effective amount as a pesticide of the mixtures and / or compositions will also vary according to the prevailing conditions, such as the desired pesticide effect and duration, the climate, the target species, the locus, the mode of application, and the like. EXAMPLES The invention is illustrated in greater detail by the following examples. Synergy can be described as an interaction in which the combined effect of two or more compounds is greater than the sum of the individual effects of each compound. The presence of a synergistic effect, in terms of percentage control or efficacy, between two mixture components (X and Y) can be calculated using the Colby equation (Colby, SR, 1967, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds, 15, 20-22): E = X+Y- — 100 The measured parameters were compared with the growth of the active compound-free control variant (100%) and with the fungus-free blank to determine the relative growth percentage of the pathogens on the respective active compounds. These percentages were then converted into efficacies. An efficacy of 0 means that the level of pathogen growth corresponds to that of the untreated control; an efficacy of 100 means that the pathogens were not growing. The predicted efficacies of the mixtures of active compounds were determined using the Colby formula [RS Colby, “Calculating synergistic and antagonistic responses of herbicide combinations, Weeds 15, 20-22 (1967)] and were compared with the observed efficacies. The following tests can demonstrate the control efficacy of the mixtures or compositions of this invention against specific fungi. However, the pest control protection obtained through the compounds, mixtures, or compositions is not limited to these species. In some cases, combinations of a compound of the present invention with other invertebrate pest control compounds or agents have been found to exhibit synergistic effects against certain important invertebrate pests and / or harmful fungi. The active compounds were formulated separately as a stock solution that had a concentration of 10,000 ppm in dimethyl sulfoxide. The oxatiapiproline product was used as the final commercial formulation and was diluted with water to the indicated concentration of active compound. 1. Activity against the late blight pathogen Phytophthora infestans in the microtiter test The stock solutions were mixed according to the specified ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. A Phytophthora infestans spore suspension containing an aqueous nutrient medium based on pea juice or DDC medium was then added. The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, the MTP concentrations were measured at 405 nm, 7 days post-inoculation. Active compound / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 0.063 0.016 - 4 0 Oxatiapiprolin B.5 a) 0.063 0.016 - 11 0 Dimpropyridaz Oxatiapiprolin 0.063 0.063 1 : 1 45 15 30 Dimpropyridaz Oxatiapiprolin 0.063 0.016 4 : 1 65 4 61 Dimpropyridaz Oxatiapiprolin 0.016 0.063 1 : 4 40 11 29 2. Activity against gray mold Botrytis cinerea in the microtiter plate test The stock solutions were mixed according to the specified ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. A suspension of Botrytis cinerea spores in an aqueous solution of biomalt or yeast-bactopeptone-sodium acetate was then added. The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, the MTP concentrations were measured at 405 nm, 7 days post-inoculation. Active ingredient / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 1 0.25 0.063 - 0 1 0 Pidiflumetophen B.2 a) 0.063 - 42 Isoflucipram B.2 f) 0.25 - 57 Pyrapropion B.2 d) 1 - 26 Dimpropyridaz Pidiflumetophen 0.063 0.063 1 : 1 60 42 18 Dimpropyridaz Pidiflumetophen 0.25 0.063 4 : 1 70 43 27 Dimpropyridaz Isoflucipram 0.25 0.25 1 : 1 81 57 24 Dimpropyridaz Isoflucipram 1 0.25 4 : 1 73 57 16 Dimpropyridaz Isoflucipram 0.063 0.25 1 : 4 78 57 21 Dimpropyridaz Pyrapropoin 0.25 1 1 : 4 45 27 18 3. Activity against leaf spots of wheat caused by Septoria tritici The stock solutions were mixed according to the ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. Next, a suspension of Septoria triticin spores was added to an aqueous solution of biomalt or yeast-bactopeptone-glycerin or DOB. The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, MTPs were measured at 405 nm, 7 days after inoculation. Active ingredient / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 0.25 0.063 - 7 5 Isoflucipram B.2) f) 0.063 - 40 Dimpropyridaz Isoflucipram 0.063 0.063 1 : 1 81 43 38 Dimpropyridaz Isoflucipram 0.25 0.063 4 : 1 74 44 30 4. Activity against Cercospora sojina in the microtiter test The stock solutions were mixed according to the specified ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. A suspension of Cercospora sojina spores in an aqueous biomalt or yeast-bactopeptone-sodium acetate solution was then added. The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, the MTP concentrations were measured at 405 nm, 7 days post-inoculation. Active compound / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 63 0.25 - 23 0 Florylpicoxamid B.3)a) 16 0.25 - 61 6 Dimpropyridaz Florylpicoxamid 0.25 0.25 1 : 1 29 6 23 Dimpropyridaz Florylpicoxamid 63 16 4 : 1 100 70 30 5. Activity against Colletotrichum orbiculare in the microtiter plate test The stock solutions were mixed according to the specified ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. A suspension of Colletotrichum orbiculare spores in an aqueous solution of biomalt or yeast-bactopeptone-sodium acetate was then added. The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, the MTP concentrations were measured at 405 nm, 7 days post-inoculation. Active compound / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 63 - 14 Pidiflumetophen B.1) a) 16 - 59 Dimpropyridaz Pidiflumetophen 63 16 4 : 1 96 65 31 6. Activity against Rhynchosporium secalis in the microtiter test The stock solutions were mixed according to the specified ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. A suspension of Rhynchosporium secalis spores was then added to an aqueous solution of biomalt or yeast-bactopeptone-glycerin (DOB). The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, the MTP concentrations were measured at 405 nm, 7 days post-inoculation. Active ingredient / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 63 - 12 B.5)d) 63 - 70 Dimpropyridaz B.5)d) 63 63 1 : 1 92 74 18 7. Activity against Sclerotinia sclerotiorum in the microtiter plate test The stock solutions were mixed according to the specified ratio, pipetted onto a microtiter plate (MTP), and diluted with water to the indicated concentrations. A suspension of Sclerotinia sclerotiorum spores was then added to an aqueous solution of biomalt or yeast-bactopeptone-glycerin or DOB. The plates were placed in a steam-saturated chamber at 18°C. Using an absorption photometer, the MTP concentrations were measured at 405 nm, 7 days post-inoculation. Active compound / mixture of active ingredients Concentration (ppm) Mixture Observed efficacy Calculated efficacy (%) Synergy (%) Dimpropyridaz 0.25 - 0 Pyrapropoine B.1)d) 1 - 27 Dimpropyridaz Pyrapropoine 0.25 1 1 :4 48 27 21 CLAIMS

Claims

Pesticide mixtures comprising as active components: 1) 1-(1,2-dimethylpropyl)-N-ethyl-5-methylN-pyridazin-4-ylpyrazol-4-carboxamide of Formula I: and 2) at least one other additional Compound B selected from B.1) Selected succinate dehydrogenase inhibitors of a) pidiflumethofen, b) pyraziflumide, c) inpyrfluxam, d) pyrapropoin, e) fluindapir, f) isoflucipram, g) 2(difluoromethyl)-N-3(1,1-4-indan-trimethane) yl)pyr¡d¡n-3-carboxamide, (difluoromethyl)-N-[(3R)-1,1,3-tr¡methyl¡ndan-4-yl]p¡r¡d¡n-3-carboxamide, (difluoromethyl)-N-(3-ethyl-1,1-d¡methyl-¡ndan-4-yl)p¡r¡d¡n-3-carboxamide, (difluoromethyl)-N-[(3R)-3-ethyl-1,1-d¡met¡l-¡ndan-4-¡l]p (difluoromethyl)-N-(l ,1-d¡met¡l-3-propyl-indan-4-¡l)p¡r¡n-3-carboxam¡da, h) k) (difluoromethyl)-N-[(3R)-1,1 -d¡met¡l-3-propyl-¡ndan-4-¡l]-p¡r¡d¡n-3-carboxamide, m) (dif luoromethyl)-N-(3-isobuty 1-1,1 -dimethyl-indan-4-¡l)pyr¡din-3-carboxamide, n) (difluoromethyl)-N-[(3R)-3-isobutyl-1,1 -dimethyl-indan-4 yl]pyrid¡n-3-carboxam¡da, o) 2222222NB.2) [2-[2-chloro-4-(tr¡fluorometh¡l)phenoxy¡]phenyl]-3-(difluoromethyl)-5-fluoro-1-met¡lp¡razol-4carboxamide,yp) methyl (E)-2-[2-[(5-cyano-2-methyl-phenox¡)methyl]phenyl]-3-methox¡-prop2 enoate; Selected oxysterol fixation protein inhibitors of: a) oxathiapiproline, b) 2-{3-[2-( 1 -{[3,5-bis(difluoromethiI-1 H-pyrazole-1 -íl]acet¡l}p¡perid¡n-4yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2 oxazol-5-yl}phen¡l methanesulfonate, c) 2-{3-[2-(1{[3,5-bis(d ifl gold H-methyl-pyrazo)-1 -yl]acetyl}p¡per¡d¡n-4-¡l) 1,3-thiazol-4-yl]-4,5dihydro-1,2-oxazol-5 il}-3-chlorophen¡l methane sulfonate, d) 4-[1-[2-[3-(difluoromethyl)-pyrazol-5methyl -yl]acet¡l]-4-piperidyl]-N-tetralin-1 -yl-pyridine-2-carboxamide, e) 4-[1 -[2[3,5-bis(d¡fluoromet¡l)pyrazol-1 -yl]acetyl]-4-piperidyl]-[1-2)tetralbox4dapyridin-1 -[2-[3-(d fluoromethyl)-5-(trif luomethyl)pyrazol-1 -yl]acetyl]-4piper¡d¡l]-N-tetralin-1 -yl-pyridine-2-carboxamide, g) 4-[1 -[2-[5-cyclopropyloro-Imethyl-1)difIufI -yl]acet¡l]-4-piperidyl]-N-tetralin-1 -yl-pyri-din-2-carboxamide,h) 4-[1 -[2-[5-methyl-3-(trifluoromethyl)pyrazol-1 -yl]acetyl]-4-piperidyl]-N-tetralin-1 -yl-pyridin2-carboxamida, i) 4-[1 -[2-[5-(d ifluoromethyl)-3-(trifluoromethyl)pyrazol-1 -yl]acetyl]-4 piper¡d¡l]-N-tetralin-1 -yl-pyridin-2-carboxamida, [1 [2-[3,5bis(tr¡fluoromethyl)p¡razol-1 -yl]acetyl]-4-piperidyl]-N-tetralin-1 -yl-pyridin-2-carboxamida, yk) 4-[1 -[2-[5-cyclopropyl-3-(trifIuoromethyl)pyrazol-1 -il]acetyl]-4-piperidyl]-N-tetralin-1 il-pyridin-2-carboxamida, Β.3) Inhibitors of complex III in the Q¡ site selected by: a) florilpicoxamid, yb) fenpicoxamid; B.4) Estrobilurines (inhibitors of complex III, site Qo) selected from a) (Z,2E) 5 [1-(2,4-dichlorophenyl)prazol-3-yl]-oxi-2-methoxiimino-N,3-dimet¡l-pent-3-enamida, b) (Z,2E) 5 [1 (4-chlorophenyl)p¡razol-3-¡l]oxi-2-methox¡¡m¡no-N,3-dimet¡l-pent-3-enam¡da, yc) methyléster of the acid 2-(ortho-((2,5-dimethylphenyl-oxymethylene)phenyl)-3-methoxy¡acrylic; B.5) Inhibitors of C14-demethylase in sterol biosynthesis (DMI fungicides) selected from a) 2-(2,4-difluorophenyl)-1,1 -difluoro-3-(tetrazol-1-yl)-1 -[5-[4-(2,2,2trifluoroethoxy)-phenyl-phenyl,2-2-propane) 2-(2,4-difluorophenyl)-1,1 -difluoro-3(tetrazol-1 -11)-1 [5 [4 (trifluoromethoxy)phenyl]-2-pyr¡d¡l]propan-2-ol, c) 2-(chloromethyl)-2methyl-5-(p-tolylmethyl)-1 (1,2-1-triazol ¡lmethyl)cyclopentanol, d) 4-[[6-[2-(2,4difluorophenyl)-1,1 -difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1 -yl)propyl]-3pyridyl]oxy]benzonitrile; B.6) Selected cell division and cytoskeleton inhibitors of a) pyridaclomethyl, b) N ethyl-2-[(3-et¡n¡l-8-methyl-6-quinolyl)oxy]butamide, c) N-ethyl-2-[(3-ethynyl-8 methyl-6 quinolyl)oxy]-2-methylsulfanyl-acetamide, d) 2-[(3-ethynyl-8-methyl-6-quinol)oxy]-N (2fluoroethyljbutanamide, e) 2-[(3-ethynyl-8-methyl-6-qu¡nolyl)oxy]-N-fluoroethyl-(2-acetamide),f) 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-N-propyl-butanamide, g) 2-[(3-ethynyl8-meth¡l-6-qu¡nolyl)oxy]-2-methox¡-N-propyl-acetamide, h) 2-[(3-ethynyl-8-methyl-6quinolyl)oxy]-2-methylsulfanyl-N-propyl-acetamide, i) 2 [(3 ethynyl-8-methyl-6-quinolyl)oxy]N-(2-fluoroethyl)-2-met¡lsulfanyl-acetamide, j) 4-(2-bromo-4-fluoro-phenyl)-N-(2-chloro-6fluoro-phenyl)-2,5-d¡methyl-pyrazole-3 amine; B.7) Other compounds of unknown mode of action selected from a) diclocimet, b) phenytropane, c) harpine, d) picarbutrazox, e) diclobenthiazox, f) pyrifenamine, g) quinofumelin, h) ipflufenoquine, i) 4 cyclopropyl-N-(2,4dimethoxyphenyl)thiadiazole-5-carboxamide, j) N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4t¡ad¡azol-5-¡l]oxy]-2,5-d¡met¡l-phen¡l]-N-et¡lN-met¡l-formam¡na, k) N'-(5-bromo-6indan-2-yloxy-2-methyl-3-pyridyl)-N-ethyl-N-meth¡l-formam¡dine, I) N'-[5-bromo-6-[1 -(3,5difluorophenyl)ethox¡]-2-methyl-3-pyridyl]-N-ethl-N-methyl-formamidine, m N'-[5-bromo-6(4-isopropylc¡clohexoxi)-2-methyl-3-pyridyl]-N-ethyl-N-methyl-formamidine,η) N' [5-bromo-2-methyl-6-(1-phen¡letoxy¡)-3-p¡hd¡l]-N-eth¡lN-methyl-formam¡dine, o) ethyl (Z) 3-amino-2-cyano-3-phenyl-prop-2-enoate, p) pentyl N-[6-[[(Z)-[(1 -methyltetrazol-5-yl)-phenylmethylene]amino]oxymethyl]-2-pyridyl]carbamate, q) but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate (picarbutrazox), r) 2-(6benzyl-2-pyridyl)quinazoline, s) 2-[6-(3-fluoro-4 methoxyphenyl)-5-methyl-2-pyridyl]quinazoline, t) N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylformamidine, and B.8) N-[[2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidine-1-yl]phenyl]methyl]cyclopropanecarboxamide; wherein Component 1) and Component 2) are present in a weight ratio of 1000:1 to 1:1000.

2. Mixtures according to claim 1, wherein Component 1) and Component 2) are present in a weight ratio of 100:1 to 1:

100.

3. Mixtures according to claim 1 or 2,wherein Component 1) and Component 2) are present in a weight ratio of 20:1 to 1:

20.

4. Mixtures according to claim 1 or 2, wherein Component 1) and Component 2) are present in a weight ratio of 10:1 to 1:

10.

5. Mixtures according to any one of claims 1 to 4, comprising a Compound B.

6. Mixtures according to any one of claims 1 to 5, wherein Component 2) is selected from Compounds B.1a) to B.1n).

7. Mixtures according to any one of claims 1 to 5, wherein Component 2) is selected from Compounds B.2a) to B.2c).

8. Mixtures according to any one of claims 1 to 5, wherein Component 2) is selected from Compounds B.

3.

9. Mixtures according to any one of claims 1 to 5,wherein Component 2) is selected from Compounds B.4 a) and B.4 b).

10. Mixtures according to any one of claims 1 to 5, wherein Component 2) is selected from the compounds in group B.

5.

11. Mixtures according to any one of claims 1 to 5, wherein Component 2) is selected from Compounds B.7 d), B.7 h) and B.71).

12. Mixtures according to any one of claims 1 to 5, wherein Component 2) is Compound B.

8.

13. A method for controlling harmful phytopathogenic fungi, wherein the method comprises bringing the fungi, their habitat, or the plants to be protected against fungal attack into contact with them, and treating the soil or seeds with an effective quantity of a pesticide mixture according to any one of claims 1 to 11.

14. A method for protecting growing plants or plant propagation materials against attack or infestation by invertebrate pests.whose method comprises bringing into contact a plant, plant propagation material, soil or water where the plant grows, with an effective pesticide quantity of a pesticide mixture according to any one of claims 1 to 12.