COMPOSITION OF RESIN AND ELECTROMAGNETIC WAVE ABSORBENT
Patent Information
- Application Number
- MX2022016393
- Authority / Receiving Office
- MX · MX
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2020-12-28
- Filing Date
- 2022-12-16
- Publication Date
- 2026-02-25
- Estimated Expiration
- 2041-06-16
AI Technical Summary
Millimeter wave radar systems suffer from noise due to both transmissive and reflective electromagnetic waves, leading to malfunctions and instability, with varying reflectance depending on frequency, affecting stability and productivity.
A resin composition containing a thermoplastic resin and a carbon-containing electromagnetic wave absorbing material, such as carbon nanotubes, with specific ratios and additives, achieving high absorbance, low transmittance, and minimal frequency-dependent reflectance.
The resin composition provides effective electromagnetic wave absorption with minimal transmission and reflection, maintaining stability across varying frequencies, enhancing the performance and reliability of millimeter wave radar systems.
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Figure MX431623B0
Abstract
Description
RESIN COMPOSITION AND ELECTROMAGNETIC WAVE ABSORBENT FIELD OF INVENTION This invention relates to a resin composition for an electromagnetic wave absorber, and an electromagnetic wave absorber. BACKGROUND OF THE INVENTION Millimeter-wave radar detects the presence of an obstacle, or its distance or speed relative to an object, by emitting radio waves in the millimeter-wave band with wavelengths of 1 to 10 mm, at a frequency of 30 to 300 GHz, particularly in the 60 to 90 GHz range, and by detecting a reflected wave that returns after striking the object. Millimeter-wave radar has been investigated for use in a wide range of fields, including automotive anti-collision sensors, autonomous driving systems, highway information systems, security systems, and medical / care devices. Known examples of resin compositions used for this millimeter-wave radar have been described in Patent Literature 1. Furthermore, Patent Literature 2 describes a multi-functional resin composition applicable for the purpose of shielding against electromagnetic interference or protecting against radio frequency interference. LIST OF REFERENCES PATENT LITERATURE [Patent Literature 1] JP 2019-197048 A [Patent Literature 2] JP 2010-155993 A BRIEF DESCRIPTION OF THE INVENTION TECHNICAL PROBLEM Millimeter-wave radar now suffers from noise attributed not only to the transmitting electromagnetic wave but also to the reflecting electromagnetic wave, causing malfunctions. This has increased the demand for a material that exhibits high electromagnetic wave absorption, as well as low electromagnetic wave transmittance and reflectance. A large variation in reflectance that depends on the frequency of the electromagnetic waves can affect stability and performance. This invention is directed to solving the problems, where an object is provided in a resin composition for the absorption of electromagnetic waves having high absorption of electromagnetic waves, low transmittance and low reflectance of electromagnetic waves, as well as showing a small variation of reflectance depending on the frequency of electromagnetic waves; and an absorber of electromagnetic waves. SOLUTION TO THE PROBLEM The present inventors conducted the research to address the problems mentioned above, and as a result, the problems described above are solved by the following means. PACO ίη / ZZΖΠZ / E / YΙΛΙ <1-1 > A resin composition containing a thermoplastic resin and an electromagnetic wave-absorbing material, exhibiting an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (A); exhibiting a difference between a maximum and a minimum reflectance value in the frequency range of 70 GHz to 80 GHz of 20.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); and being proposed for use as an electromagnetic wave absorber: Equation (A) Absorbance (%) = 100 - f—x 100 4- —x lOo) MO-k / io1o-t / io y (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method), Equation (B) Reflectance (%)=—^7-τ x 100 1o-·» / 10(in Equation (B), R represents the return loss measured by the free space method). < 1-2> The resin composition of <1-1 >, wherein the electromagnetic wave absorbing material is an electromagnetic wave absorbing material containing carbon. < 1-3> The resin composition of <1-1 > or <1-2>, containing 0.1 to 10.0 parts by mass of a carbon nanotube, per 100 parts by mass of the thermoplastic resin, exhibiting an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed to a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (A); which shows a difference between a maximum and a minimum reflectance value in the 70 GHz to 80 GHz frequency range of 20.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); and is intended for use as an electromagnetic wave absorber: < 1-4> The resin composition of any of <1-1> or <1-3>, further containing 10 to 100 parts by mass of a glass fiber, per 100 parts by mass of the thermoplastic resin. < 1-5> The resin composition of <1-4>, wherein the electromagnetic wave absorbing material and the glass fiber are in a mass ratio (electromagnetic wave absorbing material / glass fiber) of 0.01 to 0.30. < 1-6> The resin composition of any of <1-1> to <1-5>, further containing 0.01 to 5.0 parts by mass of a reactive compound, per 100 parts by mass of the thermoplastic resin. < 1-7> The resin composition of any of <1-1> to <1-6>, wherein the thermoplastic resin contains polybutylene terephthalate resin. < 1 -8> The resin composition of <1 -7>, further containing 1.0 to 75 parts by mass of a polycarbonate resin, per 100 parts by mass of polybutylene terephthalate resin. < 1 -9> The resin composition of <1 -7>, further containing 1.0 to 60 parts by mass of a polystyrene-based resin, per 100 parts by mass of polybutylene terephthalate resin. PACO ίη / ZZΖΠZ / E / YΙΛΙ < 1-10> The resin composition of <1-7>, further containing 1.0 to 75 parts by mass of a polycarbonate resin, and 1.0 to 60 parts by mass of a polystyrene-based resin, per 100 parts by mass of polybutylene terephthalate resin. < 1-11> The resin composition of any of <1-1> to <1-6>, wherein the thermoplastic resin contains a polypropylene resin. < 1-12> The resin composition of any of <1-1> to <1-6>, wherein the thermoplastic resin contains a polyamide resin. < 1-13> The resin composition of any of <1-1> to <1-12>, wherein the electromagnetic wave-absorbing material contains a multilayer carbon nanotube. < 1 -14> The resin composition of any of <1 -1 > to <1 -13>, wherein the resin composition does not contain carbon fiber, or has a carbon fiber content of less than 3% by mass. <1-15> The resin composition of any of <1-1> to <1-14>, which shows a reflectance at a frequency of 76.5 GHz of 40.0% or less, when formed to a size of 150 mm x 150 mm x 2 mm thick and is determined by Equation (B): Equation (B) Reflectance (%) =—x 100 10-Λ / 10(in Equation (B), R represents the return loss measured by the free space method). < 1-16> The resin composition of any of <1-1 > to <1-15>, exhibiting a transmittance at a frequency of 76.5 GHz of 15.0% or less, when formed to a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (O): Equation (C) Transmittance(%)= x 100 (in Equation (C), T represents the transmission attenuation measured by the free space method). < 1-17> A resin composition containing a thermoplastic resin, exhibiting an absorbance at a frequency of 76.5 GHz of 60.0% or greater, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (A); exhibiting a reflectance at a frequency of 76.5 GHz of 30.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); exhibiting a transmittance of 10.0% or less at a frequency of 76.5 GHz, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (C); and being proposed for use as an electromagnetic wave absorber: Equation (A) Absorbance (%) = 100 - X Ιθθ +x 10°) (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method), PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ Equation (B) Reflectance (%)=---X 100 10- / v10(in Equation (B), R represents the return loss measured by the free space method), and Equation (C) Transmittance (%) = X 10 0 (in Equation (C), T represents the transmission attenuation measured by the free space method). < 1-18> The resin composition of any of <1-1> to <1-17>, which further contains a flame retardant. < 1-19> The resin composition of <1-18>, wherein the flame retardant is a bromide-containing flame retardant. < 1-20> An electromagnetic wave absorber formed from the resin composition described in any of <1-1> to <1-19>. < 2-1 > A resin composition containing a crystalline thermoplastic resin, a carbon nanotube, and a flame retardant, exhibiting an absorbance at a frequency of 76.5 GHz, when formed to a thickness of 2 mm and determined by Equation (A), of 40.0 to 100%: Equation (A) Absorbance (%) = 100- (--X 100 +--^7-7 X 1OθΊ UQ-K / io iq-T / k) J PACO ίη / ZZΖΠZ / E / YΙΛΙ (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method). < 2-2> The resin composition of <2-1 >, which also contains a flame retardant auxiliary. < 2-3> The resin composition of <2-1 > or <2-2>, which also contains a reinforcing material. < 2-4> The resin composition of <2-3>, wherein the reinforcing material contains a glass fiber. < 2-5> The resin composition of any of <2-1> to <2-4>, wherein the crystalline thermoplastic resin contains a polybutylene terephthalate resin. < 2-6> The resin composition of any of <2-1> to <2-5>, containing 0.1 to 10.0 parts by mass of carbon nanotube, per 100 parts by mass of crystalline thermoplastic resin. < 2-7> The resin composition of any of <2-1> to <2-6>, wherein the carbon nanotube contains a multilayered carbon nanotube. < 2-8> The resin composition of any of <2-1> to <2-7>, which is classified as being V-0 or V-1, when formed into a test specimen 0.8 mm thick, and measured by the UL94 burn test. < 2-9> An article formed from the resin composition described in any of <2-1> to <2-8>. < 2-10> An electromagnetic wave absorber formed from the resin composition described in any of <2-1> to <2-8>. < 3-1 > A resin composition containing a thermoplastic resin, a carbon nanotube, and a bromide-containing flame retardant, having a mass ratio CNT / Br of the carbon nanotube (CNT) and one bromide atom (Br) contained in the bromide-containing flame retardant, which is 0.01 to 0.40. < 3-2> The resin composition of <3-1 >, which also contains an antimony compound. < 3-3> The resin composition of <3-1 > or <3-2>, which also contains a reinforcing material. < 3-4> The resin composition of <3-3>, wherein the reinforcing material contains a glass fiber. < 3-5> The resin composition of any of <3-1> to <3-4>, wherein the thermoplastic resin contains a polybutylene terephthalate resin. < 3-6> The resin composition of any of <3-1> to <3-5>, containing 0.1 to 10.0 parts by mass of the carbon nanotube, per 100 parts by mass of the thermoplastic resin. < 3-7> The resin composition of any of <3-1> to <3-6>, wherein the carbon nanotube contains a multilayered carbon nanotube. < 3-8> The resin composition of any of <3-1> to <3-7>, which is classified as being V-0 or V-1, when formed into a test specimen 0.8 mm thick, and measured by the UL94 burn test. < 3-9> The resin composition of any of <3-1> to <3-8>, showing the absorption of electromagnetic waves. < 3-10> The resin composition of any of <3-1> to <3-9>, exhibiting a frequency absorbance of 76.5 GHz, when formed to a thickness of 2 mm and determined by Equation (A), from 40.0 to 100%: Equation (A) Absorbance (%)=100-f--^77 X 100 + —^7 X 1OθΊ Y1θ-κ / ι° 1O-' / 10J (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method). < 3-11 > An article formed from the resin composition described in any of <3-1 > to <310> . < 3-12> An electromagnetic wave absorber formed from the resin composition described in any of <3-1> to <3-10>. < 4-1 > A resin composition containing a thermoplastic resin, a reinforcing fiber, a carbon nanotube, and a flame retardant, exhibiting an absorbance at a frequency of 76.5 GHz, when formed to a thickness of 2 mm and determined by Equation (A), from f 40.0 to 100%: Equation (A) Absorbance (%) = 100 - X 100 + X lOo) (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method). PACO ίη / ZZΖΠZ / E / YΙΛΙ < 4-2> The resin composition of <4-1 >, which also contains a flame retardant auxiliary. < 4-3> The resin composition of <4-1 > or <4-2>, wherein the flame retardant contains a flame retardant containing bromide. < 4-4> The resin composition of any of <4-1> to <4-3>, wherein the reinforcing fiber contains a glass fiber. < 4-5> The resin composition of any of <4-1> to <4-4>, wherein the thermoplastic resin contains a polybutylene terephthalate resin. < 4-6> The resin composition of any of <4-1> to <4-5>, containing 0.1 to 10.0 parts by mass of the carbon nanotube, per 100 parts by mass of the thermoplastic resin. < 4-7> The resin composition of any of <4-1> to <4-6>, wherein the carbon nanotube contains a multilayered carbon nanotube. < 4-8> The resin composition of any of <4-1> to <4-7>, which is classified as being V-0 or V-1, when formed into a test specimen 0.8 mm thick, and measured by the UL94 burn test. < 4-9> An article formed from the resin composition described in any of <4-1> to <4-8>. <4-10> An electromagnetic wave absorber formed from the resin composition described in any of <4-1> to <4-8>. ADVANTAGEOUS EFFECTS OF THE INVENTION This invention is the first to provide a resin composition for an electromagnetic wave absorber that has high electromagnetic wave absorbance, low transmittance and low electromagnetic wave reflectance, as well as exhibiting a small variation of reflectance depending on the frequency of electromagnetic waves; and an electromagnetic wave absorber. BRIEF DESCRIPTION OF THE FIGURES [Fig. 1] A schematic figure illustrating a template capable of applying a three-point bending load and a formed article placed on it, for evaluating chemical resistance in the Examples. DETAILED DESCRIPTION OF THE INVENTION DESCRIPTION OF THE MODALITIES The embodiments of the invention (hereafter referred to simply as “this embodiment”) are detailed below. The following embodiments are merely illustrative, and this invention is not limited to these embodiments alone. Note that all numerical intervals given in this patent specification, with “a” preceded and followed by numbers, are used to represent the intervals including these numbers respectively as the lower and upper limit values. Several physical properties and characteristic values mentioned herein are those shown at 23°C, unless specifically noted otherwise. The weight average molecular weight and number average molecular weight mentioned herein are equivalent values for polystyrene measured by GPC (permeation chromatography in PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ gel), unless specifically noted otherwise. The return loss and transmission attenuation mentioned herein are in dB (decibels). A resin composition of this type contains a thermoplastic resin and an electromagnetic wave absorbing material, which exhibits an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed in a size of 150 mm x 150 mm x 2 mm thick and is determined by Equation (A); which shows a difference between a maximum and a minimum reflectance value in the 70 GHz to 80 GHz frequency range of 20.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); and is intended for use as an electromagnetic wave absorber: Equation (A) Absorption (%) = 100 - X 100 + X lOO) (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method), Equation (B) Reflectance (%) =---^7— X 100 (in Equation (B), R represents the return loss measured by the free space method). With this structure, the resin composition obtainable for the electromagnetic wave absorber can have electromagnetic wave absorbance, small transmittance and small reflectance of electromagnetic waves, as well as show a small variation of reflectance depending on the frequency of electromagnetic waves. <Resina termoplástica> The resin composition of this modality contains a thermoplastic resin. The thermoplastic resins preferably used in this modality are exemplified by polyester resin (thermoplastic polyester resin); polyamide resin; polycarbonate resin; polystyrene-based resin; polyolefin resins such as polyethylene resin, polypropylene resin, and cyclic cycloolefin resin; polyacetal resin; polyimide resin; polyetherimide resin; polyurethane resin; polyphenylene ether resin; polyphenylene sulfide resin; polysulfone resin; and polymethacrylate resin.The resin composition most preferably contains at least one polyolefin resin (preferably polypropylene resin), polycarbonate resin, polyphenylene ether resin, polyester resin or polyamide resin; most preferably contains at least one polycarbonate resin, polyphenylene ether resin, polyester resin or polyamide resin; and most preferably contains polybutylene terephthalate resin. A preferred example of thermoplastic resin in this form contains polyester resin PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ (preferably, polybutylene terephthalate resin), wherein 90% by mass or more (preferably 95% by mass or more) of the resin composition is attributed to the polyester resin (preferably, polybutylene terephthalate resin). Another preferred example of thermoplastic resin in this modality contains polycarbonate resin, wherein 90% by mass or more (preferably 95% by mass or more) of the resin composition is attributed to polycarbonate resin. Yet another preferred example of thermoplastic resin in this embodiment contains polyphenylene ether resin, wherein 90% by mass or more (preferably 95% by mass or more) of the resin composition is attributed to polyphenylene ether resin. A preferred example of the thermoplastic resin in this embodiment contains a polyolefin resin (preferably polypropylene resin), wherein 90% by mass or more (preferably 95% by mass or more) of the resin composition is attributed to the polyolefin resin (preferably polypropylene resin). Another preferred example of the thermoplastic resin in this embodiment contains a polyamide resin, wherein 90% by mass or more (preferably 95% by mass or more) of the resin composition is attributed to the polyamide resin. The polyamide resin in this embodiment is exemplified by xylylenediamine-based polyamide resin and aliphatic polyamide resin (preferably polyamidea1010) described below. Another preferred example of thermoplastic resin in this embodiment contains a crystalline resin (preferably at least either polyester or polyamide resin, more preferably polyester resin, and even more preferably polybutylene terephthalate resin), wherein 90% by mass or more (preferably 95% by mass or more) of the resin composition is attributed to a crystalline resin. A crystalline thermoplastic resin refers to a resin that exhibits a defined melting point. The resin composition in this modality can alternatively be a polymer alloy obtained by mixing two or more types of thermoplastic resin. Combining two or more types of thermoplastic resin typically produces a marine island structure without exhibiting complete compatibility. Since the electromagnetic wave-absorbing material (preferably a carbon nanotube) is less likely to reside in the island domain, the resin composition or the electromagnetic wave absorber will consequently have a reduced region where the electromagnetic wave-absorbing material can reside. This makes it possible to effectively achieve various performance characteristics, including electromagnetic wave absorption, even with a small amount of the electromagnetic wave-absorbing material mixture. An exemplary mode typically relates to the combination of polybutylene terephthalate resin with polycarbonate resin and / or polystyrene resin. The methods for mixing the resin composition in this modality are preferably as follows. A first mixing method refers to a method containing, per 100 parts by mass of polybutylene terephthalate resin, 1.0 to 75 parts by mass of polycarbonate resin. With the resin of PACO ίη / ZZΖΠZ / E / YΙΛΙ polycarbonate mixed therein, the obtainable electromagnetic wave absorber can be effectively suppressed from deformation. In the first mixing mode, preferably 90% by mass or more of one component contained in the resin composition is attributed to polybutylene terephthalate resin and polycarbonate resin, wherein the percentage is more preferably 95% by mass or greater, and even more preferably 99% by mass or greater. The lower limit for the polycarbonate resin content in the first mixing mode is preferably 10 parts by mass or higher, more preferably 20 parts by mass or higher, even more preferably 40 parts by mass or higher, even more preferably 45 parts by mass or higher, and additionally more preferably 50 parts by mass or higher. At or above the lower limit, the formed article will tend to have reduced deformation. The upper limit for the polycarbonate resin content in the first mixing mode is preferably 70 parts by mass or lower, and more preferably 65 parts by mass or lower. At or below the upper limit, chemical resistance and hydrolysis resistance tend to be further improved. The first mixing method can use only one class, or two or more classes of polycarbonate resin. When two or more classes are used, the total content preferably falls within any of the ranges mentioned above. A second blending mode refers to a mode containing, per 100 parts by mass of polybutylene terephthalate resin, 1.0 to 60 parts by mass of a polystyrene-based resin (preferably AS resin). With the polystyrene-based resin blended in, the resulting electromagnetic wave absorption will be effectively suppressed from distortion. In the second blending mode, preferably 90% by mass or more of one of the resin components contained in the resin composition is attributed to the polybutylene terephthalate resin and the polystyrene-based resin (preferably AS resin), wherein the percentage is more preferably 95% by mass or greater, and even more preferably 99% by mass or greater. The lower limit for the polystyrene-based resin content (preferably AS resin) in the second mixing mode is preferably 5 parts by mass or higher, more preferably 10 parts by mass or higher, even more preferably 20 parts by mass or higher, even more preferably 25 parts by mass or higher, and additionally 30 parts by mass or higher. At or above the lower limit, the formed article will tend to exhibit further reduction in deformation. The upper limit for the polystyrene-based resin content (preferably AS resin) in the second mixing mode is preferably 90 parts by mass or lower, and more preferably 80 parts by mass or lower. At or below the upper limit, an effect called chemical resistance tends to be further enhanced. The second mixing method may use only one class of, or two or more classes of, polystyrene-based resin. When two or more classes are used, the total content preferably falls within any of the ranges mentioned above. A third mixing mode refers to a mode containing, per 100 parts by mass of polybutylene terephthalate resin, 1.0 to 75 parts by mass of a polycarbonate resin, and 1.0 to 60 PACO iη / ZZΖΠZ / E / YILI parts by mass of a polystyrene-based resin (preferably HIPS). With the polystyrene-based resin and the polycarbonate resin mixed together, the obtainable electromagnetic wave absorber will be effectively suppressed from deformation. In the third mixing mode, preferably 90% by mass or more of the resin component contained in the resin composition is attributed to the polybutylene terephthalate resin and the polycarbonate resin and the polystyrene-based resin (preferably HIPS), wherein the percentage is more preferably 95% by mass or greater, and even more preferably 99% by mass or greater. The lower limit for the styrene-based resin content (preferably HIPS) in the third mixing mode is preferably 10 parts by mass or higher, more preferably 20 parts by mass or higher, even more preferably 30 parts by mass or higher, even more preferably 35 parts by mass or higher, and additionally more preferably 38 parts by mass or higher. At or above the lower limit, the formed article will tend to exhibit further reduced deformation. The upper limit for the styrene-based resin content in the third mixing mode is preferably 70 parts by mass or lower, more preferably 65 parts by mass or lower, even more preferably 60 parts by mass or lower, even more preferably 55 parts by mass or lower, and additionally more preferably 50 parts by mass or lower.At or below the upper limit value, chemical resistance tends to improve further. The lower limit for the polycarbonate resin content in the third mixing mode is preferably 4 parts by mass or higher, more preferably 8 parts by mass or higher, even more preferably 10 parts by mass or higher, and even more preferably 12 parts by mass or higher. At or above the lower limit, the formed article will tend to exhibit further reduction in deformation. The upper limit for the polycarbonate resin content in the third mixing mode is preferably 50 parts by mass or lower, more preferably 40 parts by mass or lower, even more preferably 30 parts by mass or lower, even more preferably 20 parts by mass, and additionally, more preferably 18 parts by mass or lower. At or below the upper limit, chemical resistance and hydrolysis resistance tend to be further improved. In the third mixing mode, the mass ratio of polycarbonate resin to styrene resin is preferably 1:(2.0 to 4.0), and more preferably 1:(2.5 to 3.5). With this mass ratio, the formed article will tend to suppress deformation and will further improve mechanical strength. The third blending method may use only one class, or two or more classes of the styrene-based resin and the polycarbonate resin. When two or more classes are used, the total content preferably falls within any of the ranges mentioned above. A fourth blending mode in this embodiment refers to a mode containing a polybutylene terephthalate (PBT) resin and a polyethylene terephthalate (PET) resin. The fourth blending mode preferably contains 10 to 90% by mass of PBT and 90 to 10% by mass of PET. Note that, in the first blending mode, the total PBT and PET, among the resin components contained PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ in the resin composition preferably falls in the range of 90 to 100% by mass, without exceeding 100% by mass. A fifth blending mode in this embodiment refers to a mode containing a polybutylene terephthalate (PBT) resin and a polyamide (PA) resin. The fifth blending mode preferably contains 10 to 90% by mass of PBT and 90 to 10% by mass of PA. Note that, in the second blending mode, the total PBT and PA content of the resin components in the resin composition preferably falls within the range of 90 to 100% by mass, without exceeding 100% by mass. The polyamide resin is exemplified by aliphatic polyamide resin. Polyamide 6 and polyamide 66 are preferred. A sixth blending mode in this embodiment refers to a mode containing a polybutylene terephthalate (PBT) resin and a polyethylene (PE) resin. The sixth blending mode preferably contains 10 to 90% by mass of PBT and 90 to 10% by mass of PE. Note that, in the third blending mode, the total PBT and PE, among the resin components contained in the resin composition, preferably falls within the range of 90 to 100% by mass, without exceeding 100% by mass. The resin composition of this embodiment, according to the fourth through sixth mixing steps, may contain an amorphous resin, without departing from the spirit of this invention. The content of the amorphous resin, when contained in the resin composition of this embodiment, is preferably 0.1 to 40% by mass of the crystalline resin, may be 0.1 to 10% by mass, and may also be 0.1 to 5% by mass. The individual thermoplastic resins will be detailed below. The individual thermoplastic resins will be detailed below. "Polyester Resin" The polyester resin used herein may be any of the known thermoplastic polyester resins, which is preferably polyethylene terephthalate resin or polybutylene terephthalate resin, and preferably contains at least one polybutylene terephthalate resin. The polybutylene terephthalate resin used for the resin composition of this modality has a structure in which the terephthalic acid unit and the 1,4-butanediol unit form an ester linkage between them, and includes not only this polybutylene terephthalate resin (homopolymer), but also polybutylene terephthalate copolymer containing a copolymer component other than the terephthalic acid unit and the 1,4-butanediol unit; and a mixture of the polyethylene terephthalate homopolymer and copolymer. Polybutylene terephthalate resin may contain one class, or two or more classes of dicarboxylic acid unit other than terephthalic acid. This other dicarboxylic acid is specifically exemplified by aromatic dicarboxylic acids such as isophthalic acid, orthophthalic acid, 1,5-naphthalenedicarboxylic acid, 2,5-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, biphenyl-2,2'-dicarboxylic acid, biphenyl-3,3'-dicarboxylic acid, biphenyl-4,4'-dicarboxylic acid, bis(4,4'-carboxyphenyl)methane, anthracenedicarboxylic acid and 4,4'-diphenyl dicarboxylic ether; alicyclic dicarboxylic acids such as 1,4-cyclohexanedicarboxylic acid and 4,4'-dicyclohexyldicarboxylic acid; and aliphatic dicarboxylic acids such as adipic acid, sebasic acid, azelaic acid, and dimeric acid. In the polybutylene terephthalate resin used in this embodiment, the terephthalic acid unit preferably represents 80 mol% or more of all dicarboxylic acid units, and more preferably represents 90 mol% or more. One class of, or two or more classes of, another diol unit may be contained as the diol unit, in addition to 1,4-butanediol. This other diol unit is specifically exemplified by aliphatic or alicyclic diols having 2 to 20 carbon atoms, and bisphenol derivatives. Specific examples include ethylene glycol, propylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, decamethylene glycol, cyclohexanedimethanol, 4,4'-dichlorohexylhydroxymethane, 4,4'-dichlorohexylhydroxypropane, and bisphenol α-ethylene adduct. Again, in addition to the bifunctional monomers mentioned above, trifunctional monomers such as trimellitic acid, trimesic acid, pyromellitic acid, pentaerythritol, and trimethylolpropane can also be used in small quantities to introduce a branching structure; and a monofunctional compound such as a fatty acid can be used to control the molecular weight. In the polybutylene terephthalate resin used in this embodiment, the 1,4-butanediol unit preferably represents 80 mol% or more of all diol units, and more preferably represents 90 mol% or more. Polybutylene terephthalate resin is preferably a polyethylene terephthalate homopolymer obtainable by polycondensing terephthalic acid with 1,4-butanediol, as previously described. Also acceptable is a polyethylene terephthalate copolymer containing, as the carboxylic acid unit, one or more classes of dicarboxylic acid other than terephthalic acid and / or containing, as the diol unit, one or more classes of diol other than 1,4-butanediol. In cases where the polybutylene terephthalate resin is modified by copolymerization, preferred examples of this copolymer include polyester ether resin copolymerized with polyalkylene glycols, specifically with polytetramethylene glycol; polybutylene terephthalate resin copolymerized with dimeric acid; and polybutylene terephthalate resin copolymerized with isophthalic acid. Among them, polyester ether resin copolymerized with polytetramethylene glycol is preferred. Note that these copolymers have a copolymerization amount of 1 mol% or more, and less than 50 mol%, with respect to all segments of the polybutylene terephthalate resin. In particular, the copolymerization amount is preferably 2 mol% or more and less than 50 mol%, even more preferably 3 to 40 mol%, and still more preferably 5 to 20 mol%. This copolymerization ratio is preferred because it is more likely to improve flowability, strength, and adhesion. The terminal carboxy group content of polybutylene terephthalate resin, which can be subject to appropriate selection and decision, is typically 60 eq / ton or less, preferably 50 eq / ton or less, and even more preferably 30 eq / ton or less. At or below these upper limits, alkali resistance and hydrolysis resistance tend to improve. The lower limit for terminal carboxy group content, although not specifically limited, is PACO ίη / ZZΖΠZ / E / YΙΛΙ normally 10 eq / ton or more, taking the productivity of polybutylene terephthalate resin into consideration. Note that the terminal carboxy group content of the polybutylene terephthalate resin is a measured value obtainable by dissolving 0.5 g of the polybutylene terephthalate resin in 25 mL of benzyl alcohol and titrating the solution with 0.01 mol / L sodium hydroxide solution in benzyl alcohol. The method for controlling the terminal carboxy group content is freely selectable from known methods, including a method for controlling polymerization conditions such as raw material loading ratio, polymerization temperature, and decompression scheme; and a method for reacting with a terminal blocker. Polybutylene terephthalate resin preferably has an intrinsic viscosity of 0.5 to 2 dL / g. From the standpoint of formability and mechanical properties, those with an intrinsic viscosity within the range of 0.6 to 1.5 dL / g are more preferable. With the intrinsic viscosity adjusted to 0.5 dL / g or higher, the resulting resin composition will tend to have additional improved mechanical strength. Meanwhile, at or below 2 dL / g, the resin composition will tend to have additional improved flowability, thereby improving formability. Note that the intrinsic viscosity of polybutylene terephthalate resin is a value measured in a 1:1 (mass ratio) mixed solvent of tetrachloroethane and phenol, at 30sC. Polybutylene terephthalate resin can be produced by batch or continuous melt polymerization of a dicarboxylic acid component, primarily terephthalic acid or its ester derivative, with a diol component, primarily 1,4-butanediol. Melt polymerization, after producing a low molecular weight polybutylene terephthalate resin, can be followed by solid-phase polymerization under a nitrogen gas flow or reduced pressure to increase the degree of polymerization (or molecular weight) to a desired level. Polybutylene terephthalate resin is preferably obtained by continuous melt polymerization of a dicarboxylic acid component mainly composed of terephthalic acid, with a diol component mainly composed of 1,4-butanediol. The catalyst used for esterification can be any of known substances, including titanium compounds, tin compounds, magnesium compounds, and calcium compounds. Among these, titanium compounds are particularly preferred. Examples of titanium compounds used as esterification catalysts include titanium alcoholates such as tetramethyl titanate, tetraisopropyl titanate, and tetrabutyl titanate; and titanium phenolates such as tetraphenyl titanate. Polyester resin other than that described above may be understood to refer to the description in paragraphs
[0013] to
[0016] of JP 2010-174223 A, the content of which is incorporated herein by reference. The content of polybutylene terephthalate resin in the resin composition of this embodiment, when such polybutylene terephthalate resin is contained in the resin composition of this embodiment, is preferably 30% by mass or more in the resin composition, and more preferably 35% by mass or more, even more preferably 37% by mass or more, and still more preferably 40% by mass or more. At or above the lower limit value, the chemical resistance PACO ίη / ZZΖΠZ / E / YΙΛΙ tends to improve further. Meanwhile, the content of polybutylene terephthalate resin, when contained in the resin composition, is preferably 80% by mass or less, more preferably 75% by mass or less, still more preferably 72% by mass or less, still more preferably 66% by mass or less, further preferably 60% by mass or less, and may also be 55% by mass or less, 50% by mass or less, and 47% by mass or less. At or below the upper limit value, the formed article will tend to effectively reduce deformation. The resin composition of this form may contain one, two, or more classes of polybutylene terephthalate resin. When two or more classes are contained, the total content preferably falls within any of the ranges mentioned above. "Roller Carbonate Resin" Polycarbonate resin is an optionally branched homopolymer or copolymer obtained by reacting a dihydroxy compound, occasionally along with a small amount of polyhydroxy compound, with phosgene or carbonic acid diester. The method for producing polycarbonate resin is not specifically limited, so any of the polycarbonate resins produced by known methods, including the phosgene method (interfacial polymerization) or the melt method (transesterification), can be used. The dihydroxy compound used as the raw material is preferably an aromatic dihydroxy compound, exemplified by 2,2-bis(4-hydroxyphenyl)propane (or bisphenol A), tetramethylbisphenol A, bis(4-hydroxyphenyl)-p-isopropylbenzene, hydroquinone, resorcinol, and 4,4-dihydroxybiphenyl. Bisphenol A is preferred. Alternatively, an aromatic dihydroxy compound with one or more tetraalkylphosphonium sulfonates attached may be used. Among the polycarbonate resins mentioned above, aromatic polycarbonate resin derived from 2,2-bis(4-hydroxyphenyl)propane, or aromatic polycarbonate copolymer derived from 2,2-bis(4-hydroxyphenyl)propane and another aromatic dihydroxy compound, is preferred. Alternatively, the polycarbonate resin may be a copolymer primarily composed of an aromatic polycarbonate resin copolymerized with a polymer or oligomer having a siloxane structure. Alternatively, two or more of the polycarbonate resins mentioned above may be blended for use. The molecular weight of polycarbonate resin is adjustable simply by using a monohydric aromatic hydroxy compound, exemplified by m- or p-methylphenol, m- or p-propylphenol, p-tert-butylphenol, and phenol substituted by a long-chain alkyl group in the p position. Polycarbonate resin preferably has a viscosity-average molecular weight (Mv) of 5,000 or greater, more preferably 10,000 or greater, and even more preferably 13,000 or greater. Using polycarbonate resin with a viscosity-average molecular weight of 5,000 or greater will result in a formed article with improved mechanical strength. Meanwhile, polycarbonate resin preferably has a viscosity-average molecular weight (Mv) of 60,000 or less, more preferably 40,000 or less, and even more preferably 30,000 or less. At or below 60,000, the resin composition tends to have improved flowability and formability. ίη / ZZΖΠZ / E / YΙΛΙ Note that the average molecular weight in viscosity (Mv) of the polycarbonate resin in this modality is a value determined by measuring the viscosity of a methylene chloride solution of the polycarbonate resin at 20sC using an Ubbelohde viscometer to find the limiting viscosity ([η]), followed by the calculation of the following Schnell viscosity equation. [η] = 1.23x104Mv°·83 The method for producing polycarbonate resin, although not specifically limited, can be either the phosgene method (interfacial polymerization) or the melt method (transesterification). A preferred polycarbonate resin can also be obtained by further subjecting the polycarbonate resin, produced by the melt method, to post-treatment to control the terminal OH group content. "Polystyrene-based resin" Polystyrene-based resin is exemplified by homopolymer of the styrene-based monomer and copolymer of the styrene-based monomer with another copolymerizable monomer. Polystyrene-based resin is more specifically exemplified by polystyrene resin, acrylonitrile-styrene copolymer (AS resin), high impact polystyrene-based resin (HIPS), acrylonitrile-butadiene-styrene copolymer (ABS resin), acrylonitrile-acrylic rubber-styrene copolymer (AAS resin), acrylonitrile-styrene-acrylic rubber copolymer (ASA resin), acrylonitrile-ethylene propylene-based rubber-styrene copolymer (AES resin), and styrene-IPN type rubber copolymer. The rubber component content in the polystyrene-based resin, when present, is preferably 3 to 70% by mass, more preferably 5 to 50% by mass, and even more preferably 7 to 30% by mass. With the rubber component content controlled at 3% by mass or more, impact resistance is desirably improved, while with the content controlled at 50% by mass or less, flame retardancy is desirably improved. The rubber component preferably has an average particle size of 0.05 to 10 µm, more preferably 0.1 to 6 µm, and even more preferably 0.2 to 3 µm. With the average particle size controlled to 0.05 pm or larger, impact resistance tends to desirably improve, while with the size controlled to 10 pm or smaller, the outward appearance tends to desirably improve. Polystyrene-based resin typically has a weight-average molecular weight of 50,000 or greater, preferably 100,000 or greater, and more preferably 150,000 or greater, while typically 500,000 or less, preferably 400,000 or less, and more preferably 300,000 or less. The number-average molecular weight is typically 10,000 or greater, preferably 30,000 or greater, and more preferably 50,000 or greater, while preferably 500,000 or less, and more preferably 300,000 or less. The polystyrene-based resin preferably has a melt flow rate (MFR), when measured in conjunction with JIS K7210 (at 200°C, under a 5 kgf load), of 0.1 to 30 g / 10 min, which is more preferably 0.5 to 25 g / 10 min. With the MFR controlled at 0.1 g / 10 min or above, the PACO Ln / 77P7 / E / YILI fluidity tends to improve, meanwhile with the MFR controlled to 30 g / 10 min or below, impact resistance tends to improve. The method for producing this polystyrene-based resin is exemplified by known methods including emulsion polymerization, solution polymerization, suspension polymerization, and bulk polymerization. "Polyphenylene ether resin" This modality may use any of the known polyphenylene ether resins, which are typically exemplified by a polymer having, as its main chain, a structural unit represented by the following formula (preferably, a polymer in which a structural unit represented by the following formula represents 90 mol% or more of all structural units while excluding the terminal group). The polyphenylene ether resin may be either a homopolymer or a copolymer. PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ (In the formula, each of the two (Ra) independently represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, an aryl group, an aminoalkyl group, a halogenated alkyl group, a hydrocarbonoxy group, or a halogenated hydrocarbonoxy group; each of the two (Rb) independently represents a hydrogen atom, a halogen atom, a primary or secondary alkyl group, an aryl group, a halogenated alkyl group, a hydrocarbonoxy group, or a halogenated hydrocarbonoxy group, while excluding a case where the two (Ra) actually represent hydrogen atoms.) Each of the elements in Ray and Rb, independently and preferably, represents a hydrogen atom, a primary or secondary alkyl group, or an aryl group. Preferred examples of primary alkyl groups include methyl, ethyl, n-propyl, n-butyl, n-amyl, isoamyl, 2-methylbutyl, 2,3-dimethylbutyl, 2-, 3-, or 4-methylpentyl, or heptyl. Preferred examples of secondary alkyl groups include isopropyl, sec-butyl, and 1-ethylpropyl. In particular, Ra preferably represents a primary or secondary alkyl group having 1 to 4 carbon atoms, or a phenyl group. Rb preferably represents a hydrogen atom. The preferred homopolymer of polyphenylene ether resin is exemplified by 2,6-dialkylphenylene ether polymers, such as poly(2,6-dimethyl-1,4-phenylene ether), poly(2,6-diethyl-1,4-phenylene ether), poly(2,6-dipropyl-1,4-phenylene ether), poly(2-ethyl-6-methyl-1,4-phenylene ether), and poly(2-methyl-6-propyl-1,4-phenylene ether). The copolymer is exemplified by 2,6-dialkylphenol / 2,3,6-trialkylphenol copolymers, such as 2,6-dimethylphenol / 2,3,6-trimethylphenol copolymer, 2,6-dimethylphenol / 2,3,6-triethylphenol copolymer, 2,6-diethylphenol / 2,3,6-trimethylphenol and 2,6-dipropylphenol / 2,3,6-trimethylphenol copolymer; graft copolymer having styrene grafted to poly(2,6-dimethyl-1,4-phenylene ether); and graft copolymer having styrene grafted to 2,6-dimethylphenol / 2,3,6-trimethylphenol copolymer. The polyphenylene ether resin particularly preferred in this embodiment is poly(2,6-dimethyl-1,4-phenylene ether) and 2,6-dimethylphenol / 2,3,6-trimethylphenol random copolymer. The polyphenylene ether resin is also described in JP 2005-344065 A, in which the number of terminal groups and the copper content ratio are specified and appropriately used. Polyphenylene ether resin preferably has an intrinsic viscosity, when measured in chloroform at 30°C, of 0.2 to 0.8 dL / g, more preferably 0.3 to 0.6 dL / g. With the intrinsic viscosity controlled at 0.2 dL / g or higher, the resin composition can have additional improved mechanical strength, while at or below 0.8 dL / g, the flowability tends to improve further, and the forming process becomes easier. These intrinsic viscosity ranges can also be achieved by combining two or more classes of polyphenylene ether resin that differ in intrinsic viscosity. The polyphenylene ether resin used for this application can be produced by any known method without special limitation, typically by oxidative polymerization of a monomer such as 2,6-dimethylphenol in the presence of a copper-amine catalyst. In this process, the intrinsic viscosity is adjustable within a desired range by appropriately selecting the reaction conditions. The intrinsic viscosity is controllable by selecting conditions that include polymerization temperature, polymerization time, catalyst quantity, etc. "Polyolefin Resin" Polyolefin resin is exemplified by polyethylene, polypropylene, polybutene-1, poly-4-methylpentene, and copolymers of these resins. Polyethylene is exemplified by low-density polyethylene and high-density polyethylene. Polypropylene is exemplified by crystalline or amorphous polypropylene. The copolymer is exemplified by ethylene-propylene random, block or graft copolymer, α-olefin copolymer with ethylene or propylene, ethylene-vinyl acetate copolymer, ethylene-methylacrylate copolymer, ethylene-ethylacrylate copolymer and ethylene-acrylic acid copolymer. Among these, crystalline or amorphous polypropylene and random ethylene-propylene block or graft copolymers are preferred, with propylene-ethylene block copolymer being the most preferred. Polypropylene resin is also preferred because it is economical and can reduce the weight of the finished article due to its low specific gravity. The polyolefin resin preferably has a melt flow rate (MFR) of 0.1 to 5.0 g / 10 min. "Polyamide Resin" Polyamide resin is a polymer that has, as a structural unit, an acidic amide obtainable by open-ring polymerization of a lactam, polycondensation of an aminocarboxylic acid, or polycondensation of a diamine and a dibasic acid, and is specifically exemplified by polyamide 6, 11, 12, 46, 66, 610, 612, 6I, 6 / 66, 6T / 6I, 6 / 6T, 66 / 6T, 66 / 6T / 6I, 1010, and the xylylenediamine-based polyamide resin detailed later, trimethyl poly(terephthalamide) PACO (hexamethylene), polybis(4-aminocyclohexyl)methanedodecamide, polybis(3-methyl-4-aminocyclohexyl)methanedodecamide, and poly-(undecamethylene hexahydroterephthalamide). Note that “I” represents an isophthalic acid component and “T” represents a terephthalic acid component. The polyamide resin may be understood to refer to the description in paragraphs
[0011] to
[0013] of JP 2011132550 A, the contents of which are incorporated herein by reference. The polyamide resin used in this embodiment contains a diamine-derived structural unit and a dicarboxylic acid-derived structural unit, and is preferably a xylylenediamine-based polyamide resin in which 50 mol% or more of the diamine-derived structural unit is derived from xylylenediamine. In the xylylenediamine-based polyamide resin, preferably 70 mol% or more of the diamine-derived structural unit is derived from at least either metaxylylenediamine or paraxylylenediamine, wherein the percentage is more preferably 80 mol% or greater, even more preferably 90 mol% or greater, and still more preferably 95 mol% or greater.In the xylylenediamine-based polyamide resin, preferably 50 mol% or more of the dicarboxylic acid-derived structural unit is derived from a straight-chain aliphatic α,ω-dicarboxylic acid having 4 to 20 carbon atoms, wherein the percentage is more preferably 70 mol% or more, even more preferably 80 mol% or more, still more preferably 90 mol% or more, and additionally preferably 95 mol% or more. For use as the straight-chain aliphatic α,ω-dibasic acid having 4 to 20 carbon atoms, adipic acid, sebasic acid, suberic acid, dodecanedioic acid, and eicosanedioic acid are preferred. Adipic acid and sebasic acid are most preferred. Diamines other than metaxylylenediamine and paraxylylenediamine, usable herein as a crude diamine component of xylylenediamine-based polyamide resin, are exemplified by aliphatic diamines such as tetramethylenediamine, pentamethylenediamine, 2-methylpentanediamine, hexamethylenediamine, heptamethylenediamine, octamethylenediamine, nonamethylenediamine, decamethylenediamine, dodecamethylenediamine, 2,2,4-trimethylhexamethylenediamine and 2,4,4-trimethylhexamethylenediamine; alicyclic diamines such as 1,3-bis(aminomethyl)cyclohexane, 1,4-bis(aminomethyl)cyclohexane, 1,3-diaminocyclohexane, 1,4-diaminocyclohexane, bis(4-aminocyclohexylmethane, 2,2-bis(4-aminocyclohexyl)propane, bis(aminomethyl)decane, and bis(aminomethyl)tricyclodecane; and diamines containing aromatic rings such as bis(4-aminophenyl) ether, paraphenylenediamine, and bis(aminomethyl)naphthalene, all of which may be used individually or in combination with two or more of the same. The dicarboxylic acid component other than straight-chain aliphatic α,ω-dicarboxylic acid having 4 to 20 carbon atoms is exemplified by the italic acid compound such as isophthalic acid, terephthalic acid, and orthophthalic acid; and isomers of naphthalenedicarboxylic acid such as 1,2-naphthalenedicarboxylic acid, 1,3-naphthalenedicarboxylic acid, 1,4-naphthalenedicarboxylic acid, 1,5-naphthalenedicarboxylic acid, 1,6-naphthalenedicarboxylic acid, 1,7-naphthalenedicarboxylic acid, 1,8-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid, 2,6-naphthalenedicarboxylic acid and 2,7-naphthalenedicarboxylic acid, wherein all of them can be used individually, or two or more of them can be used in combination. PACO Ln / Zznz / E / YIAI The content of the thermoplastic resin in the resin composition of this embodiment (preferably polybutylene terephthalate resin) is preferably 30% by mass or more, more preferably 35% by mass or more, even more preferably 37% by mass or more, and still more preferably 40% by mass or more. At or above the lower limit, chemical resistance tends to improve. Meanwhile, the content of the thermoplastic resin (preferably polybutylene terephthalate resin) is preferably 80% by mass or less, more preferably 75% by mass or less, still more preferably 72% by mass or less, still more preferably 66% by mass or less, additionally preferably 60% by mass or less, it can be 55% by mass or less, 50% by mass or less, and 47% by mass or less.At or below the upper limit value, the deformation of the formed article tends to be reduced more effectively. The resin composition of this form may contain only one class of, or two or more classes of, the thermoplastic resin. When two or more classes are contained, the total content preferably falls within any of the ranges mentioned above. <Material Absorbente de Ondas Electromagnéticas> The resin composition of this type contains electromagnetic wave absorber material. With this electromagnetic wave absorber material, the resin composition will have the capacity to absorb electromagnetic waves. Examples of electromagnetic wave-absorbing materials include metal, metal oxide, carbon-containing electromagnetic wave-absorbing materials, and conductive polymers. Carbon-containing electromagnetic wave-absorbing materials are preferred. The metal is exemplified by copper, nickel, silver, and stainless steel, preferably in the form of metal filler, stainless steel fiber, or magnetic filler. The metal oxide is exemplified by alumina and zinc oxide, preferably in the form of alumina fiber and zinc oxide nanotubes. The carbon-containing electromagnetic wave-absorbing material is exemplified by carbon black, Ketjen black, graphene, graphite, fullerene, carbon nanocoil, carbon nanotube, and carbon nanofiber. Carbon nanotube is the most preferred. Also preferred are fibers, etc., coated with metal, metal oxide, or electromagnetic wave-absorbing material containing carbon, exemplified by carbon-coated titanate fiber, and metal-coated fiber. The electromagnetic wave-absorbing material in this modality preferably has a relatively thin and long geometry, such as fiber, tube, and filament. The electromagnetic wave-absorbing material preferably has a diameter (number average fiber diameter) of 0.5 nm or larger, which is more preferably 1 nm or larger, and still more preferably 3 nm or larger, meanwhile, preferably 50 pm or smaller, more preferably 20 pm or smaller, still more preferably 500 nm or smaller, and still more preferably 100 nm or smaller. The electromagnetic wave absorbing material preferably has an aspect ratio of 5 or larger, from the point of view of achieving good wave absorption PACO ίη / ZZΖΠZ / E / YΙΛΙ electromagnetic, which is most preferably 50 or greater. The upper limit is typically 500 or below, although it is not specifically limited. As previously described, known carbonic electromagnetic wave-absorbing materials include carbon black, graphite, carbon fiber, and carbon nanotubes. With carbon nanotubes selected from these carbonic electromagnetic wave-absorbing materials, this method successfully achieves high electromagnetic wave absorbance, low electromagnetic wave transmittance and reflectance, as well as minimal frequency-independent reflectance variation. This method also successfully enhances the mechanical strength of the formed article. The carbon nanotube used in this modality can be any of the monolayer carbon nanotubes, multilayer carbon nanotubes, or a mixture, with multilayer carbon nanotubes being preferred. A carbonic material that partially has a carbon nanotube structure is also acceptable. The carbon nanotube may not only have a cylindrical shape but also a coiled shape with a coil tilt of 1 pm or less. Carbon nanotubes are commercially available, and are exemplified by those available from Bayer MateriaIScience AG, Nanocyl SA, Showa Denko KK, and Hyperion Catalysis International, Inc. Note that carbon nanotubes are preferred as alternatives to graphite fibrils or carbon fibrils. The carbon nanotube preferably has a diameter of 0.5 to 100 nm, more preferably 1 to 30 nm. The carbon nanotube preferably has an aspect ratio of 5 or greater to impart good electromagnetic absorbance, more preferably 50 or greater. The upper limit is typically 500 or less, but is not strictly restricted to it. The resin composition of this embodiment preferably contains 0.1 to 10.0 parts by mass of an electromagnetic wave-absorbing material (preferably carbon nanotube) per 100 parts by mass of thermoplastic resin (preferably polybutylene terephthalate resin). With the electromagnetic wave-absorbing material (preferably carbon nanotube) contained therein, the resin composition can effectively absorb electromagnetic waves with only a small amount of mixing, effectively suppress the transition and reflection of electromagnetic waves, and reduce the reflectance variation of electromagnetic waves at frequencies of 70 to 80 GHz. The resulting article may also have improved mechanical strength. The resin composition of this embodiment preferably contains 0.1 parts by mass or more of the electromagnetic wave-absorbing material (preferably carbon nanotube) per 100 parts by mass of a thermoplastic resin, wherein the content is more preferably 1.0 parts by mass or more, more preferably 1.5 parts by mass or more, more preferably 1.8 parts by mass or more, and additionally more preferably 2.0 parts by mass or more. At or above the lower limit, the electromagnetic wave absorbance is most effective. Meanwhile, the resin composition of this PACO in / 77P7 / B / YILI preferably contains 10.0 parts by mass or less of, per 100 parts by mass of a thermoplastic resin, wherein the content is more preferably 8.0 parts by mass or less, more preferably 7.0 parts by mass or less, and more preferably 6.0 parts by mass or less. At or below the upper limit, the relative amount of glass fiber mixed in may be increased, thereby improving the mechanical strength of the resulting formed article. In a special case where the resin composition of this embodiment contains polybutylene terephthalate resin, and in a more special case where the resin component is substantially composed of a polybutylene terephthalate resin, the resin composition of this embodiment preferably contains 0.1 parts by mass or more of the electromagnetic wave-absorbing material (preferably carbon nanotube), per 100 parts by mass of polybutylene terephthalate resin, wherein the content is more preferably 1.0 parts by mass or more, more preferably 1.5 parts by mass or more, more preferably 1.8 parts by mass or more, more preferably 2.0 parts by mass or more, more preferably 3.0 parts by mass or more, and much more preferably exceeds 3.0 parts by mass.At or above the lower limit, the electromagnetic wave absorbance is effectively displayed, while the resin composition of this embodiment preferably contains 10.0 parts by mass or less of the electromagnetic wave absorbing material (preferably carbon nanotube) per 100 parts by mass of polybutylene terephthalate resin, wherein the content is preferably 8.0 parts by mass or less, more preferably 7.0 parts by mass or less, even more preferably 6.0 parts by mass or less, further more preferably 5.0 parts by mass or less, and again, further more preferably 4.0 parts by mass or less. At or below the upper limit, for example, the relative amount of fiberglass mixed in can be increased, thereby improving the mechanical strength of the resulting article. In a special case where the resin composition of this embodiment contains the crystalline resin, the resin composition of this embodiment preferably contains 0.1 parts by mass or more of the electromagnetic wave-absorbing material (preferably carbon nanotube) per 100 parts by mass of a crystalline thermoplastic resin, wherein the content is most preferably 0.3 parts by mass or more, even more preferably 0.5 parts by mass or more, may be 1.8 parts by mass or more, may still be 2.0 parts by mass or more, and particularly may be 2.4 parts by mass or more. At or above the lower limit value, the electromagnetic wave absorbance is effectively displayed. Meanwhile, the resin composition of this embodiment preferably contains 10.0 parts by mass or less of the electromagnetic wave-absorbing material (preferably carbon nanotube), per 100 parts by mass of a crystalline thermoplastic resin, wherein the content is more preferably 8.0 parts by mass or less, more preferably 6.0 parts by mass or less, more preferably 4.0 parts by mass or less, further more preferably 3.0 parts by mass or less, and may also be 2.5 parts by mass or less. At or below the upper limit, the combustion time. PACO ίη / ZZΖΠZ / E / YΙΛΙ measured in the combustion test tends to be further shortened. One formulation of this resin contains no carbonaceous electromagnetic wave-absorbing material other than carbon nanotubes, or contains only up to 3% less by mass of such material relative to the thermoplastic resin. With this structure, the frequency dependence of electromagnetic wave reflectance tends to be further improved. In this modality, the content of the carbonaceous electromagnetic wave-absorbing material other than the carbon nanotube is preferably less than 2% by mass, more preferably less than 1% by mass, even more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, additionally more preferably less than 0.05% by mass, and again, additionally more preferably less than 0.01% by mass. Another formulation of this resin contains no carbon fiber, or contains carbon fiber only up to a content of less than 3% by mass. With this structure, the frequency dependence of electromagnetic wave reflectance tends to be further improved. The electromagnetic wave reflectance can be further reduced. In this modality, the carbon fiber content is preferably less than 2% by mass, more preferably less than 1% by mass, even more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, additionally more preferably less than 0.05% by mass, and again, additionally more preferably less than 0.01% by mass. Another formulation of this resin contains no graphite, or contains graphite only up to a content of less than 3% by mass. With this structure, the frequency dependence of the electromagnetic wave reflectance tends to be further improved. The electromagnetic wave absorbance may also be further enhanced. Moreover, the resulting article may have additional improved mechanical strength. In this modality, the graphite content is preferably less than 2% by mass, more preferably less than 1% by mass, even more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, additionally more preferably less than 0.05% by mass, and again, additionally more preferably less than 0.01% by mass. Another formulation of this resin contains no carbon black, or contains carbon black only up to a content of less than 3% by mass. With this structure, the frequency dependence of electromagnetic wave reflectance tends to be further improved. Also, the resulting article may have additional enhanced mechanical strength. In this form, the carbon black content is preferably less than 2% by mass, more preferably less than 1% by mass, even more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, additionally more preferably less than 0.05% by mass, and again, additionally more preferably less than 0.01% by mass. PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ mass. Another formulation of this resin preferably does not contain Ketjen Black, or contains Ketjen Black only up to a content of less than 3% by mass. With this structure, the electromagnetic wave reflectance is further enhanced. Additionally, the resulting article may have improved mechanical strength. In this form, the Ketjen black content is preferably less than 2% by mass, more preferably less than 1% by mass, even more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, additionally more preferably less than 0.05% by mass, and again, additionally more preferably less than 0.01% by mass. A modality that meets two or more of the modalities mentioned above is also preferred. A modality that meets all of the modalities mentioned above is also preferred. The content of the electromagnetic wave-absorbing material (preferably carbon nanotube) in the resin composition of this embodiment is preferably 0.1% by mass or more of the resin composition, more preferably 0.5% by mass or more, and even more preferably 1.0% by mass or more. At or above the lower limit, more stabilized electromagnetic wave absorbance tends to be obtainable. Meanwhile, at or below the upper limit, the resin composition will tend to maintain a high level of impact resistance. The resin composition of this modality may contain only one type, or two or more types of electromagnetic wave-absorbing material (preferably carbon nanotube). When two or more types are contained, the total content preferably falls within any of the ranges mentioned above. <Material de Refuerzo> The resin composition of this type may contain a reinforcing material. With the reinforcing material obtained, the resulting article may have improved mechanical strength. The reinforcing material usable in this modality can be any of fiber, filler and granules, without special limitation on the types etc., where fiber (reinforcing fiber) is preferred. The reinforcing material, if in fiber form, can be either trimmed fiber or filament yarn. In a case where the reinforcing material is any of trimmed fiber, filler, granule or the like, the resin composition of this modality is exemplified by those in the form of granules, pulverized granules, and film formed from this granule. The reinforcing material, if in the form of filament yarn, is exemplified by the so-called unidirectional (UD) filament yarn, and by the sheet-like filament yarn that is woven or spun. When using this filament yarn, the component of the resin composition of this type, other than the reinforcing material, can be impregnated into the sheet-like filament yarn reinforcing material to produce a sheet-like resin composition (pre-impregnated, for example). PACO in / 77Π7 / Β / YILI The raw materials for the reinforcing material include inorganic materials such as glass, carbon (carbon fiber, etc.), alumina, boron, ceramics, and metal (steel, etc.); and organic materials such as plant-based materials (including kenaf, bamboo, etc.), aramid, polyoxymethylene, aromatic polyamide, poly(paraphenylene-benzobisoxazole), and ultra-high molecular weight polyethylene. Glass is preferred. That is, the resin composition of this embodiment preferably contains 10 to 100 parts by mass of reinforcing material (preferably fiberglass) to 100 parts by mass of a thermoplastic resin (preferably polybutylene terephthalate resin). With the fiberglass contained herein, the electromagnetic wave absorber formed from the resin composition of this embodiment may have improved mechanical strength. The fiberglass can be selected from those having a glass composition of glass A, glass C, glass E, glass R, glass D, glass M, glass S etc. Glass E (non-alkaline glass) is particularly preferred. Fiberglass is defined as a fibrous-looking material with a precisely circular or polygonal cross-section perpendicular to its longitudinal direction. Fiberglass typically has a mean fiber number (MFN) of 1 to 25 µm, preferably 5 to 17 µm. With the MFN adjusted to 1 µm or longer, the resin composition tends to further improve formability. With the MFN adjusted to 25 µm or shorter, the resulting electromagnetic absorption may have an improved appearance and will tend to enhance the reinforcing effect. Fiberglass can be a single monofilament or a stranded yarn formed from multiple monofilaments. The form of the fiberglass product can be any of the following: “glass yarn,” which is a roll in which a monofilament or braided yarn made from a plurality of monofilaments is wound continuously; “cut strand,” cut to 1 to 10 mm in length (i.e., glass fiber with an average fiber length of 1 to 10 mm); and “milled fiber,” milled to 10 to 500 pm in length (i.e., glass fiber with an average fiber length of 10 to 500 pm). Cut strand, uniformly cut to 1 to 10 mm in length, is preferred. Glass fibers with different morphologies can also be used in combination. Glass fibers having modified cross-sectional shapes are also preferred. The modified cross-sectional shape is typically represented by a flattening ratio, defined as the ratio of long diameter to short diameter of a cross-section perpendicular to the longitudinal direction of the fiber, of 1.5 to 10, preferably 2.5 to 10, more preferably 2.5 to 8, and particularly preferably 2.5 to 5. For the purpose of improving affinity with the resin component, the fiberglass can be surface-treated typically with a silane-based compound, epoxy-based compound, or urethane-based compound, or it can be subjected to oxidation treatment, without greatly undermining the properties of the resin composition in this modality. The resin composition of this embodiment preferably contains 10 parts by mass or more of the reinforcing material (preferably fiberglass), per 100 parts by mass of a thermoplastic resin (preferably polybutylene terephthalate resin), wherein the content is more preferably 20 parts by mass or more, and even more preferably 35 parts by mass or PACO iη / ZZΖΠZ / E / YΙΛΙ more, even more preferably 47 parts by mass or more, additionally more preferably 55 parts by mass or more, and again, additionally more preferably 63 parts by mass or more. At or above the lower limit, the mechanical strength tends to improve further. Meanwhile, the content of the reinforcing material (preferably glass fiber) is preferably 100 parts by mass or less, per 100 parts by mass of a thermoplastic resin (preferably polybutylene terephthalate resin), more preferably 90 parts by mass or less, even more preferably 85 parts by mass or less, even more preferably 80 parts by mass or less, and additionally more preferably 75 parts by mass or less. At or below the upper limit value, the formed article may have an improved appearance, and the molten resin will tend to have additional improved flowability. The reinforcing material content (preferably fiberglass) in the resin composition of this embodiment is preferably 10% by mass or more, more preferably 15% by mass or more, even more preferably 20% by mass or more, and even more preferably 25% by mass or more. Meanwhile, the reinforcing material content (preferably fiberglass) in the resin composition is preferably 50% by mass or less, more preferably 45% by mass or less, even more preferably 40% by mass or less, and additionally, more preferably 35% by mass or less. At or above the lower limit, the mechanical strength tends to be further improved. Meanwhile, at or below the upper limit, the formed article may have an improved appearance, and the molten resin tends to have further improved flowability. The resin composition of this modality may contain only one class of, or two or more classes of, the reinforcing materials (preferably fiberglass). When two or more classes are contained, the total content preferably falls within any of the ranges mentioned above. The resin composition of this embodiment preferably has a mass ratio of electromagnetic wave-absorbing material (preferably carbon nanotube) to glass fiber (electromagnetic wave-absorbing material / glass fiber) of 0.01 or greater, more preferably 0.02 or greater, more preferably 0.025 or greater, more preferably 0.04 or greater, and more preferably 0.05 or greater. At or above the lower limit, an additional advanced level of electromagnetic wave absorbance tends to be obtainable. Meanwhile, the mass ratio of electromagnetic wave-absorbing material to glass fiber is preferably 0.30, more preferably 0.20 or less, more preferably 0.10 or less, and more preferably 0.07 or less.At or below the upper limit value, the resin composition will tend to have additional improved impact resistance. <Compuesto Reactivo> The resin composition of this embodiment preferably contains 0.01 to 5.0 parts by mass of a reactive compound per 100 parts by mass of a thermoplastic resin (preferably polybutylene terephthalate resin). With the reactive compound contained therein, the PACO ίη / ZZΖΠZ / E / YΙΛΙ obtainable resin composition may have improved mechanical strength, and excellent resistance to hydrolysis. The reactive compound usable in this embodiment preferably contains at least one compound selected from the group consisting of an epoxy-containing compound, a carbodiimide compound, an oxazoline-containing compound, and an oxazine-containing compound. The epoxy-containing compound is most preferably included. "Compound Having an Epoxy Group (Epoxy Resin)" The compound containing an epoxy group has one or more epoxy groups in a molecule, and is exemplified by the glycidyl compound, the compound containing an aromatic ring with an epoxy group, and the alicyclic compound containing an epoxy group. At least the compound containing an aromatic ring with an epoxy group is preferably included. The compound containing an epoxy group is specifically exemplified by the aromatic ring-containing epoxy compound such as bisphenol A-type epoxy compound (including bisphenol A diglycidyl ether), bisphenol F-type epoxy compound (including bisphenol F diglycidyl ether), biphenyl-type epoxy compound (including bis(glycidyloxy)biphenyl), resorcinol-type epoxy compound (including resorcinol diglycidyl ether), novolac-type epoxy compound, glycidyl benzoate, diglycidyl terephthalate, and diglycidyl orthophthalate; (di)glycidyl ethers such as methyl glycidyl ether, butyl glycidyl ether, 2-ethylhexyl glycidyl ether, decyl glycidyl ether, stearyl glycidyl ether, phenyl glycidyl ether, butylphenyl glycidyl ether, allyl glycidyl ether, neopentyl glycol glycidyl ether, ethylene glycol glycidyl ether, glycerin glycidyl ether, and propylene glycol glycidyl ether;paraffinic (di)glycidyl esters (e.g., based on saturated fatty acids) or olefinic (e.g., based on unsaturated fatty acids) such as glycidyl sorbate, diglycidyl adipate, epoxidized linseed oil, and epoxidized soybean oil; alicyclic epoxy compounds such as vinylcyclohexene oxide, and dicyclopentadiene oxide; and epoxy-acrylic modified styrene copolymer. Among them, the most preferred are the styrene-acrylic copolymer having the glycidyl group in the side chain, bisphenol A type epoxy compound, novolac type epoxy compound, bisphenol F type epoxy compound, and biphenyl type epoxy compound; and the bisphenol A type epoxy compound is most preferred. "Carbodiimide Compound" The resin composition of this embodiment also preferably contains a carbodiimide compound as the reactive compound. The carbodiimide compound has a carbodiimide group (-N=C=N-) in its molecule. The applicable carbodiimide compound herein may be any of the aliphatic carbodiimide compounds having an aliphatic backbone, bicyclic carbodiimide compounds having an alicyclic backbone, or aromatic carbodiimide compounds having an aromatic backbone. Among these, the aliphatic carbodiimide compound that exceeds the reactivity with the polymer terminal is preferably used. The carbodiimide compound may be either a monomer or a polymer. The polymer type is preferred in this embodiment. Aliphatic carbodiimide compounds can be exemplified by diisopropylcarbodiimide and dioctyldecylcarbodiimide. Alicyclic carbodiimide compounds are preferably exemplified by PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ dicyclohexylcarbodiimide, and poly(4,4'-dicyclohexylmethane carbodiimide). Poly(4,4'-dicylohexylmethane carbodiimide) is particularly preferred. The commercial product can be exemplified by “Carbodilite” (product name; from Nisshinbo Chemical Inc.). El compuesto de carbodiimida aromático se ejemplifica por compuestos mono- y di-carbodiimida tal como difenilcarbodiimida, di-2,6-dimetilfen¡lcarbod¡¡mida, N-trill-N'-fenilcarbodiimida, di-pnitrofenilcarbodiimida, di-p-aminofenilcarbodiimida, di-p-hidroxifenilcarbodiimida, di-pclorofenilcarbodiimida, di-p-metoxifenilcarbodiimida, di-3,4-diclorofenilcarbodiimida, di-2,5diclorofenilcarbodiimida, di-o-clorofenilcarbodiimida, p-fenilen-bis-di-o-triilcarbodiimida, p-fenilen-bisdiciclohexilocarbodiimida, p-phenylene-bis-di-p-chlorophenylcarbodiimida, y ethylene-bis-diphenylcarbodiimida;and polycarbodiimide compounds such as poly(4,4'-diphenylmethane carbodiimide), poly(3,5'-dimethyl-4,4'-biphenylmethane carbodiimide), poly(p-phenylene carbodiimide), poly(m-phenylene carbodiimide), poly(3,5'-dimethyl-4,4'-diphenylmethane carbodiimide), poly(naphthylene carbodiimide), poly(1,3-diisopropylphenylene carbodiimide), poly(1-methyl-3,5-diisopropylphenylene carbodiimide), poly(1,3,5-triethylphenylene carbodiimide), and poly(triisopropylphenylene carbodiimide). Two or more of these compounds may be used in combination. "Compound that has an Oxazoline group" The compound having an oxazoline group can be exemplified by oxazoline, alkyl oxazoline (alkyl oxazoline having 1 to 4 carbon atoms, such as 2-methyloxazoline, and 2-ethyloxazoline), and the bisoxazoline compound. The composition of bisoxazoline is exemplified by 2,2'-bis(2-oxazoline); 2,2'-bis(alquil-2-oxazoline) [2,2'-bis(Ci-6 alquil-2-oxazoline) such as 2,2'-bis(4-methyl-2-oxazoline), 2,2'-bis(4-ethyl-2-oxazoline), 2,2'bis(4,4-dimethyl-2-oxazoline), etc.]; 2,2'-bis(aryl-2-oxazoline) [2,2'-bis(4-phenyl-2-oxazoline), etc.]; 2,2'bis(cycloalquil-2-oxazoline) [2,2'-bis(4-cyclohexylo-2-oxazoline), etc.]; 2,2'-bis(aralquil-2-oxazoline) [2,2'bis(4-bencyl-2-oxazoline), etc.]; 2,2'-alquilenebis(2-oxazoline) [2,2'-Ci w alquilenbis(2-oxazoline) such as 2,2'-ethylenebis(2-oxazoline), 2,2'-tetramethylenebis(2-oxazoline), etc.]; 2,2'-alquilenbis(alquil-2-oxazoline) etc.]; 2,2'-arylenebis(2-oxazol¡na) [2,2'-(1,3-phenylene)-bis(2oxazoline), 2,2'-(1,4-phenylene)-bis(2-oxazol¡na), 2,2'-(1,2-phenylene)-bis(2-oxazol¡na), 2,2'-diphenylene bis(2oxazoline), etc.]; 2,2'-allenb¡s(alqu¡l-2-oxazoline) [2,2'-phenylene-bis(C 1-6 alqu¡l-2-oxazoline) such as 2,2'(1,3-phenylene)-b¡s(4-methyl-2-oxazole), 2,2'-(1,4-phenylene)-b¡s(4,4-d¡methyl-2-oxazoline), etc.]; 2,2'allenb¡s(2-oxazoline) [2,2'-9,9'-diphenox¡etanobis(2-oxazole), etc.]; 2,2'-cycloalquileneb¡s(2-oxazoline) [2,2'-cyclohexyloenebis(2-oxazoline), etc.]; N,N'-alkylenebis(2-carbamoyl-2-oxazoline) [N,N'-Cl-w alkylenebis(2-carbamoyl-2-oxazoline) such as N,N'-ethylenebis(2-carbamoyl-2-oxazoline), N,N'tetramethylenebis(2-carbamoyl-2-oxazoline), etc.]; N,N'-alkylenebis(2-carbamoyl-alkyl-2-oxazoline) [N,N'-Cl-l alkylenebis(2-carbamoyl-C1-6 alkyl-2-oxazoline) such as N,N'-ethylenebis(2-carbamoyl-4-methyl-2-oxazoline), N,N'-tetramethylenebis(2-carbamoyl-4,4-d-methyl-2-oxazoline), etc.]; y N,N'-arylenbis(2-carbamoyl-2-oxazoline) [Ν,Ν'-phenylene bis(2-carbamoyl-oxazoline), etc.]. PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ The oxazoline-containing compound also includes vinyl polymers containing the oxazoline group (Epocros RPS Series, RAS Series, and RMS Series, etc., from Nippon Shokubai Co., Ltd.). Among these oxazoline compounds, bisoxazoline compounds are preferred. "Compound that has an Oxazine group" Oxazine or bisoxazine compound can be used as the compound containing the oxazine group. The bisoxazine compound is typically exemplified by 2,2'-bis(5,6-dihydro-4H-1,3-oxazine); 2,2'-bis(alkyl-5,6-d¡hydro-4H-1,3-oxazine) [2,2'-bis(Ci-6 alkyl-5,6-dihydro-4H-1,3-oxazine) such as 2,2'bls(4-methyl-5,6-d¡h¡h¡-4H-1,3-oxazine), 2,2'-b¡s(4,4-d¡met¡l-5,6-dih¡dro-4H-1,3-oxazine), and 2,2'-bis(4,5dimet¡l-5,6-dih¡dro-4H-1,3-oxazine), etc.]; 2,2'-alkylenbis(5,6-d¡hydro-4H-1,3-oxazine) [2,2'-Ci-io alkylenebis(5,6-d¡hydro-4H-1,3-oxazine) such as 2,2'-methyleneb¡s(5,6-d¡hydro-4H-1,3-oxazine), 2,2'ethylenebis(5,6-d¡hydro-4H-1,3-oxazine), and 2,2'-hexanemethylenebis(5,6-d¡hydro-4H-1,3-oxazine), etc.]; 2,2'arylenebis(5,6-dihydro-4H-1,3-oxazine) [2,2'-(1,3-phenylene)-bis(5,6-dihydro-4H-1,3-oxazine), 2,2'-( 1,4phenylene)-bis(5,6-dihydro-4H-1,3-oxazine), 2,2'-(1,2-phenylene)-bis(5,6-dihydro-4H-1,3-oxazine), 2,2'-naphthylene bis(5,6-dihydro-4H-1,3-oxazine), 2,2'-diphenylene bis(5,6-dihydro-4H-1,3-oxazine), etc.]; N,N'-alquilenebis(2-carbamoyl-5,6-dihydro-4H-1,3-oxazine) [Ν,Ν'-Cl-w alquilenebis(2-carbamoyl-5,6-d¡h¡dro-4H-1,3-oxazine) such as N,N'-tetramethylenebis(2-carbamoyl-5,6-d¡h¡dro-4H-1,3-oxazine), and N,N'-tetramethylenebis(2-carbamoyl-5,6dihydro-4H-1,3-oxazine), etc.]; N,N'-alqu¡lenbis(2-carbamoyl-alquil-5,6-dihydro-4H-1,3-oxazine) [N,N'-Cl 10 alqu¡lenbis(2-carbamoyl-Cl-6 alquil-5,6-dihydro-4H-1,3-oxazine) such as N,N'-ethylenebis(2-carbamol-4methyl-5,6-dihydro-4H-1,3-oxazine), and N,N'-hexamethylenebis(2-carbamol-4,4-dmethyl-5,6-dihydro-4H-1,3oxazine), etc.]; y N,N'-arylenbis(2-carbamo¡l-5,6-d¡h¡dro-4H-1,3-oxazine) [N,N'-fenilenobis(2-carbamoyloxazine), etc.]. Entre estos compuestos de oxazine, se prefiere el compuesto de bisoxazine. The content of the reactive compound in the resin composition of this embodiment is preferably 0.01 parts by mass or more per 100 parts by mass of a thermoplastic resin, wherein the content is more preferably 0.1 parts by mass or more, more preferably 0.3 parts by mass or more, and more preferably 0.5 parts by mass or more. At or above the lower limit, the resistance to hydrolysis tends to be further improved. Meanwhile, the content of the reactive compound is preferably 5.0 parts by mass or less per 100 parts by mass of a thermoplastic resin, wherein the content is more preferably 3.0 parts by mass or less, more preferably 2.0 parts by mass or less, and more preferably 1.2 parts by mass or less. At or below the upper limit, the melt viscosity tends to be further stabilized, and the formability tends to be improved. In a special case where the resin composition of this embodiment contains polybutylene terephthalate resin, and in a more special case where the resin component is substantially composed of polybutylene terephthalate resin, the content of the reactive compound in the resin composition of this embodiment is preferably 0.01 parts by mass or more per 100 parts by mass of polybutylene terephthalate resin, more preferably 0.1 parts by mass or more, even more preferably 0.3 parts by mass or more, even more preferably 0.5 parts by mass or more, and additionally more preferably 0.8 parts by mass or more. In or above the At or below the lower limit value, hydrolysis resistance tends to improve further. Meanwhile, the content of the reactive compound is preferably 5.0 parts by mass or less per 100 parts by mass of polybutylene terephthalate resin, more preferably 3.0 parts by mass or less, even more preferably 2.0 parts by mass or less, and still more preferably 1.2 parts by mass or less. At or below the upper limit value, melt viscosity tends to stabilize further, and formability tends to improve. The resin composition of this type may contain only one class of, or two or more classes of, the reactive compound. When two or more classes are present, the total content preferably falls within any of the ranges mentioned. <Retardante de Llama > The resin composition of this type may also have flame retardancy. Flame retardancy is normally achieved by using a flame retardant. Flame retardants include halogen-containing flame retardants, phosphorus-containing flame retardants (metal phosphinate, melamine polyphosphate, etc.), nitrogen-containing flame retardants (melamine cyanurate, etc.), and metal hydroxides (magnesium hydroxide, etc.), with phosphorus-containing and halogen-containing flame retardants being preferred. The phosphorus-containing flame retardant is most preferably metal phosphinate. The halogen-containing flame retardant is most preferably a bromide-containing flame retardant. The resin composition of this modality may also contain a flame retardant auxiliary. A first embodiment of a case where the resin composition of this embodiment has flame retardancy is exemplified by a resin composition containing the thermoplastic resin, the carbon nanotube, and the bromide-containing flame retardant, wherein the electromagnetic wave-absorbing material (preferably carbon nanotube) and the bromide atom (Br) contained in the bromide-containing flame retardant meet the mass ratio of electromagnetic wave-absorbing material (preferably carbon nanotube) / Br of 0.01 to 0.40. The first embodiment preferably contains a flame-retardant auxiliary, and more preferably contains an antimony compound. Particularly with the electromagnetic wave-absorbing material (preferably carbon nanotube) mixed in, the first method can improve electromagnetic wave absorbance. Furthermore, with carbon nanotubes (CNTs) mixed in with the bromide-containing flame retardant, the thermoplastic resin can be prevented from dripping during the combustion test, thus improving the UL94 flame retardancy rating. Dripping can presumably be suppressed because the CNT has a fibrous structure and is highly adhesive to the thermoplastic resin. On the other hand, if the bromide-containing flame retardant is insufficient, the CNT is relatively rich, and the CNT / Br ratio falls outside the predetermined range. The resin composition will undesirably sustain combustion for a period of time due to the abundance of CNT relative to the bromide-containing flame retardant.This is presumably because CNT is carbonic and can spontaneously combust if mixed too much. Now, this method... PACO ίη / ZZΖΠZ / E / YΙΛΙ precisely controls the mass ratio of the bromide atom (Br) contained in the bromide-containing flame retardant, to successfully achieve high flame retardation, while achieving high electromagnetic wave absorption. In the first mode of this application, the mass ratio of the electromagnetic wave-absorbing material (preferably carbon nanotube) to the bromide (Br) atom in the bromide-containing flame retardant, denoted as electromagnetic wave-absorbing material (preferably carbon nanotube) / Br, is 0.01 to 0.40. At or below the lower limit, the electromagnetic wave absorbance is enhanced. At or above the lower limit, the combustion time can be shortened. The flame retardancy of the bromide-containing flame retardant is generally believed to be proportional to the amount of bromide atom. This is based on the fact that the bromide atom is less likely to combine with oxygen, thereby suppressing combustion. Furthermore, the bromide atom reacts with antimony at high temperatures, further enhancing the flame retardancy. The electromagnetic wave-absorbing material (preferably carbon nanotube) / Br is preferably 0.05 or larger, more preferably 0.08 or larger, even more preferably 0.10 or larger, and may be 0.16 or larger, 0.20 or larger, or 0.25 or larger. Meanwhile, the electromagnetic wave-absorbing material (preferably carbon nanotube) / Br is preferably 0.38 or smaller, more preferably 0.35 or smaller, and may be 0.30 or smaller, 0.28 or smaller, or 0.16 or smaller. In particular, with the electromagnetic wave absorbing material (preferably carbon nanotube) / Br controlled to 0.05 or larger, the obtainable resin composition can have electromagnetic wave properties, particularly characterized by high absorbance and low transmittance.Meanwhile, with the electromagnetic wave absorbing material (preferably carbon nanotube) / Br controlled to 0.14 or smaller, the combustion time can be shortened. A second mode of this modality, in which the resin composition of this modality has flame retardancy, is exemplified by a resin composition containing the crystalline thermoplastic resin, the electromagnetic wave absorbing material (preferably carbon nanotube), and the flame retardant, and which shows an absorbance at a frequency of 76.5 GHz, when formed to a thickness of 2 mm and determined by Equation (A), of 40.0 to 100%. With the electromagnetic wave-absorbing material (preferably carbon nanotube) mixed in during the second mode of this process, the formed article can have improved electromagnetic wave absorbance. Also, with the carbon nanotube mixed in with the flame retardant, the formed article can have improved flame retardancy (UL94). This is attributable not only to the effect of the flame retardant but also to the fact that the carbon nanotube has a fibrous form, is highly adhesive to the crystalline thermoplastic resin, and can therefore suppress dripping. Furthermore, the use of the crystalline thermoplastic resin as the primary thermoplastic resin presumably improves the chemical resistance of the formed article. This is presumably due to the effective interaction of these components, without affecting the... PACO ίη / ZZΖΠZ / E / YΙΛΙ adversely with each other, the formed article was obtained with high absorbance of electromagnetic waves, as well as high flame retardancy and chemical resistance. The second mode of the modality preferably, and additionally, contains a flame retardant additive. It also preferably contains a reinforcing material. A third mode of this modality, in which the resin composition has flame retardancy, is exemplified by a resin composition containing the thermoplastic resin, reinforcing fiber, electromagnetic wave-absorbing material (preferably carbon nanotube), and flame retardant, and which exhibits an absorbance at a frequency of 76.5 GHz, when formed to a thickness of 2 mm and determined by Equation (A), of 40.0 to 100%. The resin composition preferably also contains a flame retardant, and more preferably a flame retardant containing bromide. With the electromagnetic wave-absorbing material (preferably carbon nanotube) mixed in during the third mode of this process, the resulting article can have improved electromagnetic wave absorbance. Also, with the flame retardant mixed in along with the CNT, the resulting article can have improved flame retardancy (UL94). This is attributed not only to the effect of the flame retardant but also to the CNT's fiber form, which is highly adhesive to the crystalline thermoplastic resin and can therefore suppress dripping. Furthermore, the addition of the reinforcing fiber presumably improved the deflection temperature under load. This is presumably because the reinforcing fiber can suppress the softening of the resin at high temperatures.Furthermore, the blending of the reinforcing fiber presumably reduces the relative content of the thermoplastic resin, thereby reducing the easily carbonizable component and improving flame retardancy. Presumably as a result of the effective interaction of these components, without adversely affecting each other, the resulting article exhibited high electromagnetic wave absorbance, as well as high flame retardancy and heat resistance. "Flame Retardant Containing Bromide" Next, the bromide-containing flame retardant will be explained. The bromide-containing flame retardant is preferably brominated phthalimide, brominated poly(meth)acrylate, brominated polycarbonate, a brominated epoxy component, or brominated polystyrene, without special limitation on the types, and is most preferably brominated poly(meth)acrylate, brominated polycarbonate, or the brominated epoxy compound. Brominated phthalimide is preferably represented by Formula (1). Oo <BO— n-°-n(1) oo (En la Fórmula (1), D representa un grupo compuesto por una combinación de dos o más grupos seleccionados del grupo alquileno, grupo arileno, -S(=O)2-, -C(=O)-, y -O-; y i representa un número entero de 1 a 4). PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ In formula (1), D represents a group composed of a combination of two or more groups selected from the alkylene group, arylene group, -S(=O)2-, -C(=O)- and -O-; preferably it represents a group composed of a combination of an alkylene group or an arylene group, with at least one of -S(=O)2-, -C(=O)-, or, -O-; more preferably it represents a group composed of a combination of an alkylene group or an arylene group, with one of -S(=O)2-, -C(=O)-, or, -O-; wherein the combination most preferably contains an alkylene group. The group consisting of a combination of an alkylene group and -O- encompasses a combination of, for example, two alkylene groups and one -O- (the same will apply to other combinations). The alkylene group at D is preferably an alkylene group having 1 to 6 carbon atoms, and is most preferably a methylene group, an ethylene group, a propylene group, or a butylene group. The arylene group is preferably a phenylene group. i Represents an integer from 1 to 4, where 4 is preferred. The brominated phthalimide represented by Formula (1) is exemplified by N,N'bis(tetrabromophthalimide)ethane, N,N'-bis(tetrabromophthalimide)propane, N,N'-bis(tetrabromophthalimide)butane, N,N'-bis(tetrabromophthalimide)-diethyl ether, N,N'-bis(tetrabromophthalimide)dipropyl ether, N,N'-bis(tetrabromophthalimide)dibutyl ether, N,N'-bis(tetrabromophthalimide)diphenylsulfone, N,N'-bis(tetrabromophthalimide)diphenylketone, and N,N'-bis(tetrabromophthalimide)diphenyl ether. The brominated phthalimide represented by Formula (1) is preferably a brominated phthalimide represented by Formula (2). PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ (In formula (2), i represents an integer from 1 to 4). i Represents an integer from 1 to 4, where 4 is preferred. Brominated poly(meth)acrylate is preferably a polymer obtainable by homopolymerizing a benzyl (meth)acrylate containing bromide atoms, or by copolymerizing two or more classes thereof, or by copolymerizing with another vinyl-based monomer, wherein the bromide atom is bonded to the benzene ring, with a bonding number per benzene ring preferably from 1 to 5, and particularly 4 or 5. Benzyl acrylate containing bromide atoms is exemplified by pentabromobenzyl acrylate, tetrabromobenzyl acrylate, tribromobenzyl acrylate, and mixtures of these compounds. Benzyl methacrylate containing bromide atoms is exemplified by methacrylates corresponding to the acrylates mentioned above. This other vinyl-based monomer used for copolymerization with benzyl (meth)acrylate containing bromide atoms is specifically exemplified by acrylic acid; acrylate esters such as methyl acrylate, ethyl acrylate, butyl acrylate, and benzyl acrylate; methacrylic acid; methacrylate esters such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, and benzyl methacrylate; styrene; acrylonitrile; unsaturated carboxylic acids such as fumaric acid and maleic acid, or anhydrides thereof; vinyl acetate; and vinyl chloride. These compounds are normally used in an amount that does not exceed the equimolar amount of benzyl (meth)acrylate containing bromide atoms, and particularly in a molar amount of 0.5 times or less. The vinyl-based monomer usable herein also includes xylene diacrylate, xylene dimethacrylate, tetrabromoxylene diacrylate, tetrabromoxylene dimethacrylate, butadiene, isoprene, and divinylbenzene. These compounds are typically usable in a molar quantity of 0.5 times or less the molar quantity of benzyl acrylate containing bromide atoms or benzyl methacrylate. Brominated poly(meth)acrylate is preferably a polymer obtainable by homopolymerizing a (meth)acrylate monomer containing bromide atoms, particularly benzyl (meth)acrylate, or by copolymerizing two or more of the same monomers, or by copolymerizing it with another vinyl-based monomer. The bromine atom is bonded to the benzene ring, with a bonding number per benzene ring preferably from 1 to 5, and particularly 4 or 5. Brominated poly(meth)acrylate is preferably pentabromobenzyl poly(meth)acrylate due to its high bromide content. Brominated poly(meth)acrylate may have a freely selectable molecular weight that can be appropriately determined, wherein the weight average molecular weight (Mw) is preferably 3,000 or greater, more preferably 10,000 or greater, still more preferably 15,000 or greater, yet still more preferably 20,000 or greater, and further preferably 25,000 or greater. At or above the lower limit, the resulting formed article may tend to have higher mechanical strength. Meanwhile, the upper limit of the weight average molecular weight (Mw) is preferably 100,000 or less, more preferably 80,000 or less, still more preferably 60,000 or less, still more preferably 50,000 or less, and further preferably 35,000 or less. At or below the upper limit value, the resin composition tends to further improve flowability. Brominated polycarbonate preferably has a free bromide content of 0.05% by mass or more and 0.20% by mass or less. Within this range, the resin composition tends to further improve heat stability. Brominated polycarbonate also preferably has a chloride atom content of 0.001% by mass or more and 0.20% by mass or less. Within this range, the die corrosion resistance during forming or molding tends to further improve. More specifically, brominated polycarbonate is preferably a brominated polycarbonate typically obtainable from brominated bisphenol A, and particularly from tetrabromobisphenol A. The terminal structure thereof is exemplified by the phenyl group, the 4-t-butylphenyl group, and the 2,4,6-tribromophenyl group, among which the 2,4,6-tribromophenyl group is particularly preferred for the terminal group structure. An average number of carbonate structural units in brominated polycarbonate can be determined by appropriate selection, which is preferably 2 to 30, more PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ preferably 3 to 15, and even more preferably 3 to 10. The molecular weight of brominated polycarbonate is freely selectable and can be determined by appropriate selection, wherein the average molecular weight at viscosity is preferably 1,000 to 20,000, and particularly preferably 2,000 to 10,000. Brominated polycarbonate obtainable from brominated bisphenol A is typically obtained by an ordinary method of reacting brominated bisphenol with phosgene. The terminal blocker is exemplified by a monohydroxy aromatic compound, which can be substituted with a halogen or organic group. The brominated epoxy compound is specifically exemplified by the bisphenol A-type brominated epoxy compound represented by the tetrabromobisphenol A epoxy compound, and the glycidyl brominated bisphenol A epoxy compound. The molecular weight of the brominated epoxy compound is freely selectable and can be determined by appropriate selection, wherein the weight average molecular weight (Mw) is preferably 3,000 or greater, more preferably 10,000 or greater, still more preferably 13,000 or greater, still more preferably 15,000 or greater, and further preferably 18,000 or greater. At or above the lower limit, the resulting formed article may tend to have additional improved mechanical strength. Meanwhile, the upper limit of the weight average molecular weight (Mw) is preferably 100,000 or less, more preferably 80,000 or less, still more preferably 78,000 or less, still more preferably 75,000 or less, and further preferably 70,000 or less. At or below the upper limit value, the resin composition tends to further improve flowability. The brominated epoxy compound preferably has an epoxy equivalent of 3,000 to 40,000 g / eq, which is more preferably 4,000 to 35,000 g / eq, and particularly preferably 10,000 to 30,000 g / eq. The brominated epoxy compound used herein may alternatively be a brominated epoxy oligomer. In this case, a typical use of approximately 50% by mass or less of an oligomer having an Mw of 5000 or less can appropriately control flame retardancy, mold release capability, and flowability. The bromine atom content in the brominated epoxy compound is freely selectable, where the content is normally 10% by mass, in view of achieving a sufficient level of flame retardancy, and is specifically 20% by mass or more, and particularly 30% by mass or more, with the upper limit preferably controlled at 60% by mass, and particularly at 55% by mass or below. Brominated polystyrene is preferably exemplified by a brominated polystyrene having a structural unit represented by Formula (3) PACO Ln / Z7nz / E / YIAI PACO ίη / ZZΖΠZ / E / YΙΛΙ (In Formula (3), t represents an integer from 1 to 5 and n represents the number of structural units). Brominated polystyrene can be produced either by brominating polystyrene or by polymerizing a brominated styrene monomer. A product obtained by polymerizing brominated styrene is preferred because of its low free bromide (atom) content. Note that in formula (3), the CH group to which the brominated benzene is attached can be replaced by a methyl group. Brominated polystyrene can alternatively be a copolymer having another vinyl-based monomer copolymerized to it. The vinyl-based monomer in this case is exemplified by styrene, α-methylstyrene, (meth)acrylonitrile, (meth)methyl acrylate, butadiene, and vinyl acetate. The brominated polystyrene used herein may alternatively be a single material, or a mixture of two or more materials having different structures, or may have, in a single molecular chain thereof, units derived from styrene monomers having different numbers of bromide atoms. Brominated polystyrene is specifically exemplified by poly(4-bromostyrene), poly(2-bromostyrene), poly(3-bromostyrene), poly(2,4-dibromostyrene), poly(2,6-dibromostyrene), poly(2,5-dibromostyrene), poly(3,5-dibromostyrene), poly(2,4,6-tribromostyrene), poly(2,4,5-tnbromostyrene), poly(2,3,5-tribromostyrene), poly(4-bromo-a-methylstyrene), poly(2,4-dibromo-a-methylstyrene), poly(2,5-dibromo-a-methylstyrene), poly(2,4,6-tribromo-a-methylstyrene), and poly(2,4,5-tribromo-a-methylstyrene), among them particularly preferred are poly(2,4,6-tribromostyrene), poly(2,4,5-tribromostyrene), and polydibromostyrene and polytribromostyrene respectively, which have 2 and 3 bromide groups on average on the benzene ring. Brominated polystyrene preferably has an n number (average degree of polymerization) of the structural unit in Formula (3) of 30 to 1,500, which is more preferably 150 to 1,000, and particularly preferably 300 to 800. The average degree of polymerization, if below 30, may make blooming more likely, while if it exceeds 1,500, it may tend to cause dispersion failure, making the mechanical property more likely to degrade. Brominated polystyrene preferably has a weight average molecular weight (Mw) of 5,000 to 500,000, which is more preferably 10,000 to 500,000, even more preferably 10,000 to 300,000, still more preferably 10,000 to 100,000, and further preferably 10,000 to 70,000.In particular, the polystyrene mentioned above produced by bromination preferably has a weighted average molecular weight (Mw) of 50,000 to 70,000, while the brominated polystyrene produced by polymerization preferably has a weight average molecular weight (Mw) of approximately 10,000 to 30,000. Note that the weight average molecular weight (Mw) can be determined by GPC measurement, in terms of the equivalent value of standard polystyrene. The flame retardant containing bromide preferably has a bromide concentration of 45% by mass or more, which is more preferably 48% by mass or more, and even more preferably 50% by mass or more. At or above the lower limit, the formed article may tend to effectively improve flame retardancy. The upper limit for the bromide concentration is preferably 75% by mass or below, more preferably 73% by mass or below, and even more preferably 71% by mass. Metal phosphinate, when used as a special limitation, where a concentration represented by Formulas (4) or (5) is preferred, and which is higher than any of calcium, magnesium, aluminum, or zinc. up or down. The flame retardant can be of any type without a metal sphinate that has an anionic portion or a cationic portion whose metal ion is 12“ (5) PACO ίη / ZZΖΠZ / E / YΙΛΙ (In the formulas, each of R1 and R2 independently represents an alkyl group having 1 to 6 carbon atoms or an optionally substituted aryl group, (R1) may be the same or different; R3 represents an alkylene group having 1 to 10 carbon atoms, an optionally substituted arylene group, or a group composed of a combination thereof, (R3) may be the same or different; yn represents an integer from 0 to 2). The optionally substituted aryl group is preferably an optionally substituted phenyl group. When substituted, the substituent is preferably an alkyl group having 1 to 3 carbon atoms. The aryl group may also preferably be unsubstituted. The optionally substituted arylene group is preferably an optionally substituted phenylene group. The optionally substituted arylene group is preferably unsubstituted, or preferably has an alkyl group having 1 to 3 carbon atoms (preferably a methyl group) as the substituent. In this embodiment, the metal phosphinate represented by Formula (5) is preferred. In this embodiment, aluminum phosphinate is preferred. Metal phosphinate is specifically exemplified by calcium dimethylphosphinate, magnesium dimethylphosphinate, aluminum dimethylphosphinate, zinc dimethylphosphinate, calcium ethylmethylphosphinate, magnesium ethylmethylphosphinate, aluminum ethylmethylphosphinate, zinc ethylmethylphosphinate, calcium diethylphosphinate, magnesium diethylphosphinate, aluminum diethylphosphinate, zinc diethylphosphinate, calcium methyl-n-propylphosphinate, magnesium methyl-n-propylphosphinate, aluminum methyl-n-propylphosphinate, zinc methyl-n-propylphosphinate, calcium methanodi-(methylphosphinate), magnesium methanodi-(methylphosphinate), aluminum methanobis(methylphosphinate), zinc methanobis(methylphosphinate), calcium benzene-1,4-bis(methylphosphinate), magnesium benzene-1,4-bis(methylphosphinate), benzene-1,4-bis(methylphosphinate) of aluminum, benzene-1,4-bis(methylphosphinate) of zinc, methylphenylphosphinate of calcium, methylphenylphosphinate of magnesium, methylphenylphosphinate of aluminum, methylphenyl-phosphinate of zinc,calcium diphenylphosphinate, magnesium diphenylphosphinate, aluminum diphenylphosphinate and zinc diphenylphosphinate. The detail of metal phosphinate may be understood to refer to the description in paragraphs
[0052] to
[0058] of WO2010 / 010669, the content of which is incorporated herein by reference. The lower limit for the flame retardant content in the resin composition of this embodiment, per 100 parts by mass of the thermoplastic resin (preferably crystalline thermoplastic resin), is preferably 1.0 part by mass or higher, more preferably 3.0 parts by mass or higher, even more preferably 5.0 parts by mass or higher, still more preferably 7.0 parts by mass or higher, and additionally preferably 10.0 parts by mass or higher. At or above the lower limit, the resulting article may exhibit further flame retardancy improvements. The upper limit for the flame retardant content, per 100 parts by mass of the thermoplastic resin (preferably crystalline thermoplastic resin), is preferably 70.0 parts by mass or lower, more preferably 60.0 parts by mass or lower, and even more preferably 50.0 parts by mass or higher.0 parts by mass or below, still more preferably 45.0 parts by mass, further preferably 40.0 parts by mass or below, and again, further preferably 30.0 parts by mass or below. At or below the upper limit, the resulting formed article can more effectively suppress mechanical resistance to degradation. The resin composition of this type may contain only one class of, or two or more classes of, flame retardant. When two or more classes are contained, the total content preferably falls within any of the ranges mentioned above. <Auxiliar Retardante de Llama> The resin composition of this embodiment preferably contains a flame retardant auxiliary, and more preferably an antimony compound. The flame retardant auxiliary (preferably the antimony compound), when contained therein, interacts with the bromide-containing flame retardant, synergistically enhancing the flame retardant's effectiveness. The antimony compound is preferably antimony trioxide (Sb2Os), antimony pentoxide (SbsOs), or sodium antimony. Of these, antimony trioxide is particularly preferred. In this embodiment, the mass ratio of the bromide atom contained in the bromide-containing flame retardant to the antimony atom contained in the antimony compound (Br / Sb) is preferably 0.3 or greater, and more preferably 1.0 or greater, while preferably 5.0 or less, and more preferably 4.0 or less. Within these ranges, the flame retardant tends to be more readily visible. In the resin composition of this type, the antimony compound is preferably mixed in a masterbatch with a thermoplastic resin. This makes the antimony compound more readily present in the thermoplastic resin phase, tending to improve stability. PACO Ln / Zznz / E / YIAI in heat during the melting and forming process, tends to suppress the impact resistance of degradation and tends to reduce the variation of flame retardation and impact resistance. The antimony compound content in the master bath is preferably 20 to 90% by mass. The antimony compound content in the master bath is more preferably 30% by mass or more, even more preferably 40% by mass or more, still more preferably 50% by mass or more, further preferably 60% by mass or more, and particularly preferably 70% by mass or more. The content of the flame retardant auxiliary (preferably an antimony compound) in the resin composition of this embodiment, per 100 parts by mass of the thermoplastic resin, is preferably 0.1 parts by mass or more, more preferably 1.0 parts by mass or more, even more preferably 2.0 parts by mass or more, and still more preferably 3.0 parts by mass or more. At or above the lower limit, the resulting article may exhibit further flame retardancy improvements. Meanwhile, the upper limit value of the flame retardant auxiliary content (preferably an antimony compound), per 100 parts by mass of the thermoplastic resin, is preferably 20.0 parts by mass or below, more preferably 15.0 parts by mass or below, still more preferably 10.0 parts by mass or below, still more preferably 8.0 parts by mass or below, and further preferably 7.0 parts by mass or below.At or below the upper limit value, the obtainable formed article may tend to improve mold release capability and impact resistance. <Otros Componentes> The resin composition of this type may contain some other optional components in addition to those previously described, without seriously compromising the desired physical properties. These other components are exemplified by various resin additives. Only one of these other components may be included, or two or more may be included, according to the freely selectable combination and proportion. Other components are exemplified more specifically by the stabilizer, mold release agent, pigment, dye, UV absorber, antistatic agent, anti-fogging agent, antiblocking agent, flow modifier, plasticizer, dispersion aid, and antibacterial agent. The resin composition of this embodiment preferably contains at least either a stabilizer or a mold release agent. The resin composition of this embodiment is prepared such that the thermoplastic resin (preferably polybutylene terephthalate resin), the electromagnetic wave-absorbing material (preferably carbon nanotube), the glass fiber, and other optionally blended components total 100% by mass. In the resin composition of this embodiment, the total mass of the thermoplastic resin (preferably polybutylene terephthalate resin), the electromagnetic wave-absorbing material (preferably carbon nanotube), and the glass fiber preferably represents 95% or more by mass of the resin composition. Again, in the resin composition of this embodiment, the total mass of the thermoplastic resin (preferably polybutylene terephthalate resin), the electromagnetic wave-absorbing material (preferably carbon nanotube), and the glass fiber preferably represents 95% or more by mass of the resin composition. PACO ίη / ZZΖΠZ / E / YΙΛΙ carbon), fiberglass, stabilizer, and mold release agent preferably represent 99% by mass or more of the resin composition. The resin composition of this embodiment can alternatively be structured to contain substantially polycarbonate resins. The phrase "...does not contain substantially polycarbonate resin" means that the polycarbonate resin content is 10% by mass or less of the thermoplastic resin contained in the resin composition; the percentage is preferably 5% by mass or less, more preferably 3% by mass or less, and even more preferably 1% by mass or less. The resin composition that does not contain substantially polycarbonate resin is preferably used, particularly for a fiberglass-free resin composition. "Stabilizer" The resin composition of this modality may contain a stabilizer. The stabilizer is exemplified by a hindered phenol-based compound, a hindered amine-based compound, a phosphorus-containing compound, and a sulfur-containing stabilizer. Of these, the hindered phenol-based compound is preferred. The combined use of the hindered phenol-based compound and the phosphorus-containing compound is also preferred. The stabilizer may be understood to refer to the description in paragraphs
[0046] to
[0057] of JP 2018-070722 A, described in paragraphs
[0030] to
[0037] of JP 2019-056035 A, and description in paragraphs
[0066] to
[0078] of WO 2017 / 038949, the contents of which are incorporated herein by reference. The resin composition of this embodiment preferably contains 0.01 parts by mass or more of the stabilizer per 100 parts by mass of the thermoplastic resin (preferably polybutylene terephthalate resin), wherein the content is more preferably 0.05 parts by mass or more, and even more preferably 0.08 parts by mass or more. The upper limit of the stabilizer content is preferably 3 parts by mass or less per 100 parts by mass of the thermoplastic resin (preferably polybutylene terephthalate resin), which is more preferably 2 parts by mass or less, and even more preferably 1 part by mass or less. The resin composition of this form may contain only one class, or two or more classes of the stabilizer. When two or more classes are contained, the total content is preferably within any of the ranges mentioned above. "Mold Liberator Agent" The resin composition of this modality preferably contains a mold release agent. A wide range of known mold release agents, if applicable, among which the esterified product of aliphatic carboxylic acid, paraffin wax, and polyethylene wax are preferred, with polyethylene wax being the most preferred. The mold release agent may be understood to refer to the descriptions in paragraphs
[0115] to
[0120] of JA 2013-007058 A, in paragraphs
[0063] to
[0077] of JA 2018-070722 A, and in paragraphs
[0090] to
[0098] of JA 2019-123809 A, the contents of which are incorporated herein by reference. PACO in / 77Ω7 / Β / YILI The resin composition of this embodiment preferably contains 0.01 parts by mass or more of the mold release agent per 100 parts by mass of the thermoplastic resin (preferably polybutylene terephthalate resin), wherein the content is more preferably 0.08 parts by mass or more, and even more preferably 0.2 parts by mass or more. The upper limit of the mold release agent content is preferably 5 parts by mass or less per 100 parts by mass of the thermoplastic resin (preferably polybutylene terephthalate resin), more preferably 3 parts by mass or less, even more preferably 1 part by mass or less, and still more preferably 0.8 parts by mass or less. The resin composition may contain only one class of, or two or more classes of, the mold release agent. When two or more classes are contained, the total content is preferably within any of the ranges mentioned above. <Propiedades Físicas de la Composición de Resina> The resin composition of this modality shows high absorbance of electromagnetic waves. More specifically, the resin composition of this modality preferentially exhibits an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed to a thickness of 2 mm (e.g., in a size of 150 mm x 150 mm x 2 mm thick, or 100 mm x 100 mm x 2 mm thick), and is determined by Equation (A). Equation (A) Absrobance (%) = 100 - f--x100 + —x1OθΊ (In Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method.) The absorbance is preferably 50.0% or greater, more preferably 55.0% or greater, more preferably 60.0% or greater, and more preferably 65.0% or greater. An upper limit of 90.0% or below, although ideally 100%, will be sufficient to meet the performance requirement. The resin composition of this modality preferentially shows low reflectance of electromagnetic waves. More specifically, the resin composition of this modality preferably exhibits a reflectance at a frequency of 76.5 GHz of 40.0% or less, when formed to a thickness of 2 mm (e.g., in a size of 150 mm x 150 mm x 2 mm thick, or 100 mm x 100 mm x 2 mm thick), and is determined by Equation (B). Equation (B) Reflectance ^=77^X100 PACO ίη / ZZΖΠZ / E / YΙΛΙ (In Equation (B), R represents the return loss measured by the free space method.) The reflectance is preferably 35.0% or less, more preferably 30.0% or less, and even more preferably 25.0% or less. A lower limit of 1.0% or above, and additionally 10.0% or above, although ideally 0%, will be sufficient to meet the performance requirement. The resin composition of this modality preferentially shows low transmittance. The resin composition of this modality preferably exhibits a transmittance at a frequency of 76.5 GHz of 25.0 or less, which is more preferably 15% or less, when formed to a thickness of 2 mm (e.g., in a size of 150 mm x 150 mm x 2 mm thick, or 100 mm x 100 mm x 2 mm thick), and is determined by Equation (C). Equation (C) Transmittance (%)=---X 100 (In Equation (C), T represents the transmission attenuation measured by the free space method). The transmittance is preferably less than 25.0%, more preferably less than 20.0%, more preferably 19.0% or less, more preferably 15.0% or less, additionally more preferably 12.0% or less, again, additionally more preferably 10.0% or less, particularly, preferably less than 10.0%, and may still be 5.0% or less. A lower bound of 0.5% or above, and additionally 1.0% or above, although ideally 0%, will be sufficient to meet the performance requirement. The resin composition of this modality also preferentially has a small dependence on electromagnetic wave frequency. More specifically, the resin composition of this modality preferably shows a difference between a maximum and a minimum reflectance value in the frequency range of 70 GHz to 80 GHz of 20.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B). Equation (B) Reflectance (%)=---7777 X 100 (In Equation (B), R represents the return loss measured by the free space method.) The difference between the maximum and minimum reflectance values is preferably 18.0% or less, more preferably 17.0% or less, more preferably 12.0% or less, and more preferably 10.0% or less. A lower limit of 1.0% or higher, although ideally 0%, will be sufficient to meet the performance requirement. PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ The resin composition of this modality preferably complies with the absorbance determined by Equation (A), the difference between a maximum and a minimum reflectance value in the frequency range of 70 GHz to 80 GHz determined by Equation (B), as well as the reflectance determined by Equation (B), and / or the transmittance determined by Equation (C). The resin composition of this modality is also preferably a resin composition containing the thermoplastic resin, and preferably exhibits an absorbance determined by Equation (A) of 60.0% or greater, a reflectance determined by Equation (B) of 30.0% or less, and a transmittance determined by Equation (C) of 10.0% or less, and proposed for use as the electromagnetic wave absorber. A particularly preferred mode of the resin composition of this modality relates to a resin composition containing 0.1 to 10.0 parts by mass of the electromagnetic wave-absorbing material (preferably carbon nanotube), per 100 parts by mass of a polybutylene terephthalate resin; exhibiting an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed to a thickness of 2 mm (e.g., in a size of 150 mm x 150 mm x 2 mm thick, or 100 mm x 100 mm x 2 mm thick), and is determined by Equation (A); and which shows a difference between a maximum and a minimum reflectance value in the 70 GHz to 80 GHz frequency range of 20.0% or less, when formed to a thickness of 2 mm (e.g., in a size of 150 mm x 150 mm x 2 mm thick, or 100 mm x 100 mm x 2 mm thick), and is determined by Equation (B); it is intended for use as an absorber of electromagnetic waves. The resin composition preferably also meets the reflectance determined by Equation (B), and / or the transmittance determined by Equation (C). The resin composition of this type stands out primarily in mechanical resistance. For example, the resin composition of this embodiment preferably exhibits a maximum tensile strength of 50 MPa or greater when formed on an ISO multi-purpose test specimen (4 mm thick) and measured according to ISO 527-1 and ISO 527-2, which is more preferably 60 MPa or greater, and even more preferably 130 MPa or greater. A maximum tensile strength of 200 MPa or less, for example, is within the practical range, although the upper limit is not specifically defined. The resin composition of this modality also stands out preferentially in flexural properties. More specifically, the resin composition of this modality preferably exhibits a flexural strength of 50 MPa or greater when formed on an ISO multi-purpose test specimen (4 mm thick), which is more preferably 70 MPa or greater, even more preferably 180 MPa or greater, and even more preferably 190 MPa or greater. A flexural strength of 280 MPa or less, for example, is within the practical range, although the upper limit is not specifically defined. The resin composition of this modality, when formed in a multi-test sample PACO ίη / ZZΖΠZ / E / YΙΛΙ ISO purpose (4 mm thick), preferably exhibits a flexural modulus of 1,500 MPa or greater, which is more preferably 2,000 MPa or greater, even more preferably 8,000 MPa or greater, even more preferably 9,000 MPa or greater, and additionally more preferably 10,000 MPa or greater. A flexural modulus of 14,000 MPa or less, for example, is at the practical level, although the upper limit is not specifically limited. The resin composition of this modality, when it contains the flame retardant, excels preferentially in flame retardation. More specifically, the resin composition of this modality is preferably classified as V-0 or V-1, when formed in a test sample 0.8 mm thick, and measured by the UL94 combustion test, where the classification is most preferably V-0. The resin composition of this type stands out primarily in impact resistance. More specifically, the resin composition of this form preferably exhibits a Charpy impact strength 4.0 kJ / m² greater when formed on an ISO tensile test specimen (4 mm thick), and as measured according to ISO 179, where the value is more preferably 5.0 kJ / m² greater. A Charpy impact test specimen is typically 20.0 kJ / m² smaller, and may still be 12.0 kJ / m² smaller, although the upper limit is not specifically defined. The resin composition of this modality also preferably exhibits a surface resistivity of 1.0×1011Ω or larger, when formed to a size of 100 mrnxlOO mmx2 mm and measured in accordance with IEC60093, which is more preferably 1.0×1016Ω or smaller. The resin composition of this modality also preferably exhibits a volume resistivity of 1.0×10¹⁰Ω or larger, when formed to a size of 100 mrnxlOO mmx2 mm and measured in accordance with IEC60093, which is more preferably 1.0×10¹⁷Ω or smaller. The details of the measurement method are described in the EXAMPLES. <Método para Producir una Composición de Resina > The resin composition of this modality can be produced by any of the ordinary methods for preparing a resin composition containing thermoplastic resin, typically by placing the thermoplastic resin (preferably polybutylene terephthalate resin), the electromagnetic wave-absorbing material (preferably carbon nanotube), and the other optionally mixed component (glass fiber, etc.) into an extruder, followed by melt kneading. The individual components can be premixed and then fed into the extruder as a whole; or, the individual components can be fed through a feeder without premixing, or after premixing only a portion of them. The extruder can be either a single-screw or a twin-screw extruder. Alternatively, a portion of the Ln / zznz / E / YiAi component, such as electromagnetic wave-absorbing material (preferably carbon nanotube), can be melt-kneaded with a resin component (e.g., polybutylene terephthalate resin) to prepare a master bath, into which the remaining components can be mixed and melt-kneaded. When mixed, the fiberglass is preferably fed laterally through a side feeder arranged in the middle of an extruder cylinder. The heating temperature during melt kneading is appropriately selectable, usually within the range of 170 to 350°C. <Método para Fabricar un Absorbente de Ondas Electromagnéticas> The method for manufacturing the electromagnetic wave absorber of this type is freely selectable, without special limitation, from any commonly used forming / molding methods for resin compositions that include thermoplastic resin. Examples of such methods include injection molding, ultra-high-speed injection molding, compression injection molding, two-color molding, retention molding such as gas-assisted molding, molding using heat-insulating dies, molding using rapid-heating dies, foam molding (including supercritical fluid), insert molding, IMG (in-mold coating) molding, extrusion molding, sheet forming, thermoforming, rotational molding, laminate molding, press molding, and blow molding. Injection molding is preferred among these methods. <aplicaciones> The electromagnetic wave absorber of this modality is formed from the resin composition of this modality. That is, the resin composition of this modality is intended for use as an electromagnetic wave absorber (also referred to as an electromagnetic wave absorbing member), more preferably as an electromagnetic wave absorber adapted to at least the frequency range of 60 to 90 GHz, and even more preferably as an electromagnetic wave absorber adapted to at least the frequency range of 70 to 80 GHz. This classification of the electromagnetic wave absorber is preferably applicable to a radar, and more specifically to an enclosure, cover, etc., for a millimeter-wave radar. The electromagnetic absorber of this type is suitable for use in vehicle-borne millimeter-wave radar systems used for automatic braking control, adaptive cruise control, pedestrian safety steering, wrong-start prevention, pedal misapplication prevention, rear vehicle monitoring, lane keeping assistance, rear collision prevention, parking assistance, and vehicle periphery monitoring; train / aviation radar used for platform monitoring / obstacle detection on overpasses, train content transmitter, tram / railway collision prevention, and airport runway foreign object detection;millimeter wave radar for; PACO ίη / ZZΖΠZ / E / YΙΛΙ traffic infrastructure such as a crossing monitoring device, an elevator monitor; millimeter wave radar for various safety devices; millimeter waves for medical / nursing care such as a child / elderly monitoring system; and millimeter wave radar for transmitting various information contents. EXAMPLES This invention will be further detailed with reference to the Examples. All materials, consumption quantities, proportions, process details, and procedures described in the following Examples may be appropriately modified without departing from the spirit of this invention. Accordingly, the scope of this invention is in no way limited to the following specific Examples. In a case where any measuring instrument used in the Examples is not typically available due to an interruption, the measurement can be carried out using another instrument that has equivalent performance. Raw Materials The raw materials summarized below were then used. PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ [Table 1] Component Symbol Polybutylene terephthalate resin (PBT) a-1 Polybutylene terephthalate resin (PBT) Product name: Novaduran (registered trademark) 5008, from Mitsubishi Engineering-Plastics Corporation Intrinsic viscosity: 0.85 dL / g polypropylene resin a-2 "Novatec EA8”, from Japan Polypropylene Corporation MFR: 0.5 g / 10 min polyamide resin a-3 "UBE Nylon1010X”, from UBE Corporation polycarbonate resin a-4 polycarbonate resin "lupilon H4000”, from Mitsubishi Engineering-Plastics Corporation Mv = 16000 polyethylene resin a-5 polyethylene resin Product name: HT478, from PS Japan Corporation Mw: 200,000, MFR: 3.2 g / 10 min Master batch of multicap carbon nanotubes b-1-1 Master batch of multicap carbon nanotubes 15% in mass, with PBT base "Plasticyl PBT150”, by Nanocyl SA b-1-2 Master batch of multicap carbon nanotubes 20% in mass, based on PP "Plasticyl PP2001”, by Nanocyl SAb-1-3 Master batch of multilayer carbon nanotubes 15% by mass, based on PA6 "Plasticyl PA1503", from Nanocyl SA. Carbonaceous material absorbing electromagnetic waves. b1-x1 Master batch of composite preliminary composition 80% by mass of "Novaduran 5008" and 20% by mass of "Carbon black #650" from Mitsubishi Chemical Corporation. b1-x2 Master batch of Ketjen black 15% by mass, based on PBT "FD9035K", from Lion Specialty Chemicals Co., Ltd. b1-x3 Master batch composite preliminary composition 65% by mass of "Novaduran 5510", 17% by mass of "PC99-300M" from Ito Graphite Co., Ltd., and 18% by mass of "EC-50" from Ito Graphite Co., Ltd. b1-x4 PAN-based carbon fiber Average fiber diameter in number: 6 pm "TR06UL" from Mitsubishi Chemical Corporation. PACO Ln / 77Π7 / Β / YΙΛΙ [Table 2] Component Symbol Reinforcing Material (Fiberglass) b-2 Fiberglass, Product Name: T-127, from Nippon Electric Glass Co., Ltd. Chopped fiberglass yarn with an average fiber number diameter of 13 µm, treated with novolac-type epoxy resin Epoxy Compound c-1 Bisphenol-A type epoxy compound Product Name: EP-17, from ADEKA Corporation c-2 Bisphenol-A type epoxy compound "jer1003", from Mitsubishi Chemical Corporation, epoxy compound Stabilizer d-1 Phenol-based stabilizer hindered Pentaerythritol Tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate] Product Name: ADK STAB AO-60, from ADEKA Corporation d-2 Phosphorus-containing stabilizer, octadecyl acid phosphate "AX-71", from ADEKA Corporation Mold Release Agent e-1 Polyethylene-based wax, Ήί-Wax 100P”, from Mitsui Chemicals, Inc.Dropping point: 116°C Flame retardant auxiliary (antimony compound) f-1 Antimony trioxide Master lot 80% by mass antimony trioxide, PBT-based "Composition 405001", from SICA SA Flame retardant gi Tetrabromobisphenol A-based epoxy compound Product name: CXB2000H, from Woojin copolymer Bromine concentration: 52% by mass, Mw: 20,000 g-2 Pentabromobenzyl polyacrylate Product name: FR1025, from ICL Japan Ltd. Bromine concentration: 70% by mass, Mw: 31,000 g-3 Brominated polycarbonate "FR-53", from Mitsubishi Gas Chemical Company, Inc. Bromine concentration: 58% by mass, free bromine content: 0.11% by mass, chlorine compound content: 0.02% by mass. Examples 1-1 to 1-8, Comparative Examples 1-1 to 1-10<Producción de la Composición de Resina (Gránulo)> From the raw materials listed in Table 1 or 2 above, the individual components selected as summarized in the following Tables were placed in a stainless steel drum and mixed under agitation for one hour. The resulting mixture was fed into an interleaved co-rotating twin-screw extruder ("TEX-30a", from Japan Steel Works, Ltd., screw diameter = 32 mm, L / D = 42) through a main feed port. The contents were plasticized at a preset barrel temperature of 260°C in the first kneading zone. The fiberglass, the proportion of which is given in the following Tables, was fed through a side feeder. The barrel temperature after the addition of the fiberglass was set to 250°C. The contents were melt-kneaded at a discharge rate of 40 kg / h and a screw speed of 200 rpm. PACO Ln / Zznz / E / YIAI was then extruded into strands through a four-hole nozzle (4 mm diameter round hole, 1.5 cm long). The extruded strands were placed in a water bath for cooling, and then fed into a granulator for cutting, to obtain a resin composition (granules). <Resistencia a la Tracción Máxima > The resin granule obtained in this way was dried at 120°C for 5 hours, and then injection milled into an ISO multi-purpose test specimen (4 mm thick) using an injection molding machine ("J85AD", from Japan Steel Works, Ltd.), at a cylinder temperature of 250°C, and at a die temperature of 80°C. Using the molded ISO multi-purpose test specimen, the maximum tensile strength (in MPa) and tensile modulus (in MPa) were measured in accordance with ISO527-1 and ISO527-2. <Velocidad de Incremento de la Resistencia a la Tracción Máxima> The rate of increase in ultimate tensile strength was estimated with respect to a case where carbon black was used as the carbonaceous electromagnetic wave absorber. In this study, the rate of increase was estimated between resins with the same composition. That is, the rate of increase in Example 1-1, Example 1-2, Comparative Example 1-4, Comparative Example 1-5, and Comparative Example 1-8 was estimated based on the ultimate tensile strength in Comparative Example 1-1; the rate of increase in Example 1-3, Example 1-4, Comparative Example 1-6, and Comparative Example 1-9 was estimated based on the ultimate tensile strength in Comparative Example 1-2; The rate of increase in Example 1-5, Example 1-6, Comparative Example 1-7, and Comparative Example 1-10 was estimated based on the maximum tensile strength in Comparative Example 1-3. For example, Example 1-1 shows a maximum tensile strength of 147 MPa, while Comparative Example 1-1 shows a maximum tensile strength of 134 MPa, so the rate of increase for Example 1-1 is given as (147 / 134)χ 100 = 110(%). <Propiedades Flexurales > The resin granule obtained in this way was dried at 120°C for 5 hours, and then injection molded into an ISO multi-purpose test specimen (4 mm thick) using an injection molding machine ("J85AD", from Japan Steel Works, Ltd.), at a cylinder temperature of 250°C, and a die temperature of 80°C. Using the molded ISO multipurpose test specimen, flexural strength (in MPa) and flexural modulus (in MPa) were measured in accordance with ISO178. <Deformación Baja > The resin composition granules were dried at 120°C for 5 hours and then injection molded into a 150 mm x 150 mm x 2 mm square plate test specimen using an injection molding machine ("EC160", Shibaura Machine Co., Ltd.) at a cylinder temperature of 260°C and a die temperature of 80°C. The strain (mm) of the formed article was measured. Low strain was evaluated according to the following criteria. Strain is defined by placing the 150 mm x 150 mm x 2 mm square plate on a flattened surface while being molded. PACO ίη / ZZΖΠZ / E / YΙΛΙ maintains three axes in contact with the plane, and finding a straight line distance between the residual apex and the flattened plane. A: deformation < 3 mm B: 3 mm < deformation < 15 mm C: 15 mm < deformation<Absorbancia, Transmitancia, y Reflectancia> The resin granule obtained in this way was injection molded into a 150 mm x 150 mm x 2 mm thick test sample using an injection molding machine ("EC160", Shibaura Machine Co., Ltd.), at a cylinder temperature of 260°C and a die temperature of 80°C. Using the obtained test sample, the absorbance determined by Equation (A), reflectance determined by Equation (B), and transmittance determined by Equation (C), all at a frequency of 76.5 GHz, were measured as described below. An Anritsu Corporation "MS4647B Vector Work Analyzer" was used for the measurement. The test sample was measured while aligning the transverse direction (TD) of the molded article parallel to the direction of the electric field. Equation (A) Absorbance (%) = 100 - (--^7x100 +--U7 X 1OθΊ (In Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method.) Equation (B) Reflectance PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ X loo (In Equation (B), R represents the return loss measured by the free space method.) Equation (C) Transmittance (%)=7^χΐοο (In Equation (C), T represents the transmission attenuation measured by the free space method.)<Dependencia de Frecuencia de la Reflectancia> The test sample obtained in this way was subjected to reflectance measurements over the 70–80 GHz frequency range, and the difference between the maximum and minimum reflectance was calculated. The smaller the difference between the maximum and minimum reflectance, the smaller the frequency dependence, indicating that the resulting resin composition is stable. <Evaluación de la Absorción de Ondas electromagnéticas> Performance was evaluated as follows, based on the absorbance, reflectance, and transmittance measured in this way. A: all of (1) to (3) below are fulfilled. B: at least (1) below are fulfilled (excluding the case applicable to (A)). C: different from A and B (1) absorbance > 60.0% (2) reflectance < 30.0% (3) transmittance < 10.0% <Clasificación General de la Absorción de Ondas Electromagnéticas y Resistencia Mecánica > The overall classification was made as follows, based on the absorbance thus measured, reflectance, transmittance, low deformation, maximum tensile strength, and flexural strength. 6: All of (1) to (6) below are fulfilled. 5: Five of (1) to (6) below are fulfilled. 4: Four of (1) to (6) below are fulfilled. 3: Three of (1) to (6) below are fulfilled. 2: Two of (1) to (6) below are fulfilled. 1: One of (1) to (6) below are fulfilled. (1) Absorbance > 60.0% (2) Reflectance < 30.0% (3) Transmittance < 10.0% (4) Low strain classified as A or B (5) Maximum tensile strength > 130 MPa (6) Flexural strength > 190 MPa PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ ω ω ιό σι ο σι ιό ο σι ο [Table 3] Article Unit Example 1-1 Example 1-2 Example 1-3 Example 1-3 (') Example 1-4 Example 1-4 Π Chemical composition (a-1)PBT parts by mass 100.0 100.0 100.0 62.5 100.0 65.0 (a-2) Polypropylene resin (a-3) Polyamide resin (a-4) Polycarbonate resin 60.0 37.5 53.8 35.0 (a-5) HT478 polystyrene resin (b-1-1) Multilayer carbon nanotube 1.1 2.2 1.8 1.1 3.4 2.2 (b-1-2) Multilayer carbon nanotube (b-1-3) Multilayer carbon nanotubes (b1-x1) Carbon black (b1-x2) Ketjen black (b1-x3) Graphite (b1-x4) Carbon fiber (b-2) Fiberglass T-127 43.8 44.3 70.2 44.3 68.2 44.3 H Epoxy resin EP-17 0.6 0.6 0.9 0.6 0.9 0.6 (d-1) Stabilizer AO-60 0.3 0.3 0.5 0.3 0.5 0.3 (d-2) AX-71 Stabilizer 0.2 0.2 0.2 0.2 (e-1) Mold release agent 0.3 0.3 0.5 0.3 0.5 0.3 CNT / GF (mass ratio) 0.03 0.06 0.03 0.06 Evaluation Maximum Tensile Strength MPa 147 151 138 137 Increase in Maximum Tensile Strength Rate % 110 113 107 106 Flexural Strength MPa 228 234 204 207 Flexural Modulus MPa 9650 10080 9560 10190 Low Deformation Classification BBAA Absorbance at 76.5 GHz % 66.9 76.1 70.9 75.6 Reflectance at 76.5 GHz % 22.3 21.8 19.3 22.6 Transmittance at 76.5 GHz % 10.8 2.2 9.9 1.8 Frequency Dependence of Reflectance 13.0 11.1 16.0 9.9 Electromagnetic Wave Absorbance Rating Classification BAAA Overall Classification of the capacity to absorb electromagnetic waves and mechanical resistance Classification 4 5 6 6. σι > α ι\ C hhc > Q l\ C hhc ω ω ro ro --*· ui o σι o σι o σι o J « c [Table 4] Article Unit Example 1-5 Example 1-5 (') Example 1-6 Example 1-6(Ί Example 1-7 Example 1-8 Chemical composition (a-1)PBT mass 100.0 62.5 100.0 65.0 (a-2) Polypropylene resin 100.0 (a-3) Polyamide resin 100.0 (a-4) Polycarbonate resin 15.0 9.4 13.4 8.7 (a-5) Polystyrene resin HT478 45.0 28.1 40.3 26.3 (b-1-1) Multilayer carbon nanotube 1.8 1.1 3.4 2.2 (b-1-2) Multilayer carbon nanotube 2.2 (b-1-3) Multilayer carbon nanotubes 2.2 (b1-x1) Carbon black (b1-x2) Ketjennegro (bt -x3) Graphite (b1-x4) Carbon fiber (b-2| Fiberglass T-127 70.2 44.3 68.2 44.3 44.4 44.4 (c-1) Epoxy resin EP-17 0.9 0.6 0.9 0.6 0.7 0.7 (d-1) AO-60 Stabilizer 0.5 0.3 0.5 0.3 0.3 0.3 (d-2) AX-71 Stabilizer 0.2 0.2 0.2 0.2 (e-1) Mold release agent 0.5 0.3 0.5 0.3 0.3 0.3 CNT / GF (mass ratio) 0.03 0.06 0.06 0.06 Evaluation Maximum tensile strength MPa 132 131 Increase in maximum tensile strength rate % 107 107 Flexural strength MPa 200 194 Flexural modulus MPa 9740 10050 Low deformation Classification AA Absorbance at 76.5 GHz % 69.1 77.5 66.5 61.7 Reflectance at 76.5 GHz % 23.2 20.8 16.2 36.0 Transmit it at 76.5 GHz % 7.6 1.7 17.3 2.4 Frequency dependence of reflectance 9.8 14.0 7.8 12.4 Electromagnetic wave absorbance rating Classification AAAA Overall rating of electromagnetic wave absorption capacity and mechanical strength Classification 6 6. > Q l\ C hhc ω ω ni μ -1-1σ o σι o σι o σι o J « c [Table 5] Article Unit Comparative Example 1-1 Comparative Example 1-2 Comparative Example 1-2 Comparative Example 1-3 Comparative Example W) Comparative Example 1-4 Comparative Example 1-5 Chemical composition (a-1)PBT by mass 100.0 100.0 63.5 100.0 63.6 100.0 100.0 (a-2) Polypropylene resin (a-3)Polyamide resin (a4)Polycarbonate resin 57.4 36.5 14.3 9.1 (a-5)HT478 polystyrene resin 43.0 27.3 (b-1-1)Multilayer carbon nanotube (b-1-2) Multilayer carbon nanotube (n-3)Multilayer carbon nanotubes (bl-xl)Humidity nanotube 2.2 3.5 2.2 3.5 2.2 (b1-x2)Black Ketjen 2.2 (b1-x3)Graphite 2.2 (b1-x4)Carton fiber (t>2)FiberglassT-127 44.3 69.8 44.3 69.8 44.3 44.3 44.3 (c-1j Resin epoxy¡EP-17 0.6 0.9 0.9 0.9 0.9 0.6 0.6 (d-1)StabilizerA060 0.3 0.5 0.3 0.5 0.3 0.3 0.3 (d-2)StabilizerAX-71 0.2 0.2 0.2 0.2 H Motle releasing agent 0.3 0.5 0.3 0.5 0.3 0.3 0.3 CNT / GF (mass ratio) Evaluation Maximum tensile strength MPa 134 129 123 138 133 Increase in the maximum tensile strength % 103 99 Flexible outside MPa 205 190 186 211 206 Deflection modulus MPa 9410 9380 9300 9380 9520 Low deformation Classification BAABB Absorptive frequency at 76.5GHz % 27.5 16.1 15.6 26.2 14.2 Reflectance at 76.5GHz % 14.8 8.5 0.3 19.9 42.5 Transmittance at 76.5GHz % 57.7 75.3 84.1 53.8 43.3 Frequency dependence of reflectance 21.6 21.7 28.7 25.8 42.7 Assessment of the absorption of electromagnetic waves Classification CCCCC General classification of the capacity of absorption of electromagnetic waves and mechanical resistance Classification 3 3 2 3 3. > Q l\ C hhc ω ω ni μ -1-1σ o σι o σι o σι o J « c [Table 6] Article Unit Comparative Example 18 Comparative Example W) Comparative Example 1-7 Comparative Example 1-7Π Comparative Example 1-8 Comparative Example 1-9 Comparative Example W Comparative Example 1-10 Comparative Example i-io('j Chemical composition HPBT mass 100.0 61.7 1000 61.6 100.0 100.0 60.0 100.0 60.0 (a-2) Polypropylene resin (a-3) Polyamide resin (a4) Polymethyl oxide resin 62.2 38.3 15.6 9.6 66.7 40.0 16.7 10.0 (a-5) Polypropylene resin HT478 46.7 28.8 50.0 30.0 (b-1-1)Non-multilayer carbon nanotube (Ó1-2J Multilayer fertilizer nanotube (í>1-3)Multilayer caking nanotubes (b1-x1)Carbon black (b1-x2|Keljen black (b1-x3| Graphite 3.6 2.2 3.6 2.2 (b1-x4) Caching fiber 2.2 3.6 2.2 3.6 2.2 (t>2)FbradevidiioT-127 72.0 44.3 72.0 44.3 44.3 74.0 44.3 74.0 44.3 (c-1)Epoxy resinEP-17 1.0 1.0 1.0 1.0 0.6 1.0 1.0 1.0 1.0 (d-1) Stabilized· AOffl 0.5 0.3 0.5 0.3 0.3 0.5 0.3 0.5 0.3 (d-2) Stabilizer AX-71 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 (el)Agertemoble releaser 0.5 0.3 0.5 0.3 0.3 0.5 0.5 0.5 0.5 CNT / GF (mass ratio) Evaluation Maximum tensile strength MPa 133 121 142 141 130 Increase in maximum tensile strength % 103 98 106 109 1(8 Flexural strength MPa 197 183 216 205 197 Flexural modulus MPa 9820 9520 9860 10120 9910 Low deformation Classification AABAA Absorbance at 76.5GHz % 13.8 15.1 20.1 23.8 28 Reflectance at 76.5GHz % 42.8 36.3 39.5 57.4 54 Transmittance at 76.5GHz % 43.5 48.6 40.4 18.8 18 Dependence on the frequency of the electromagnetic array 42.9 39.6 42.5 35.4 44.4 Value where the absorption of electromagnetic waves Classification CCCCC General classification of the capacity for absorption of electromagnetic waves and mechanical resistance Classification 3 2 2 3 3. TO In the Tables above, * represents the cases rewritten to adjust the total resin content to 100 parts by mass. In the Tables, CNT / GF represents the mass ratio of carbon nanotube and glass fiber (carbon nanotube / glass fiber). In the Tables, carbon nanotubes (b-1—1) to (b-1-3) are not given in terms of the amount in the master bath, but in terms of the carbon nanotube per se. The same will apply to the master bath (b1-x1) etc. As is clear from the results, the resin compositions of this invention exhibit high electromagnetic wave absorbance, low electromagnetic wave transmittance, and low reflectance, as well as minimal reflectance variation depending on the electromagnetic wave frequency. The resin compositions of this invention were further found to excel in mechanical strength. Example 2-1 to Example 2-6, Comparative Example 2-1 to Comparative Example 2-4<Producción de la Composición de Resina (Gránulos)> From among the raw materials listed in Table 1 or 2 above, the individual components selected as summarized in the following Tables were placed in a stainless steel drum and mixed under agitation for one hour. The resulting mixture was fed into an interleaved co-rotating twin-screw extruder ("TEX-30a", from Japan Steel Works, Ltd., screw diameter = 32 mm, L / D = 42) through a main feed port.The contents were plasticized at a preset barrel temperature in the first kneading zone of 260°C (exceptionally 280°C for Comparative Examples 2-5, 2-6), the reinforcing material (glass fiber) whose proportion is given in the following Tables was fed through a side feeder, the barrel temperature after the addition of the glass fiber was set to 250°C (exceptionally 280°C for Comparative Examples 2-5, 2-6), the contents were melt-kneaded at a discharge rate of 40 kg / h, and a screw speed of 200 rpm, and then extruded into strands through a four-hole nozzle (4 mm diameter round hole, 1.5 cm long). The extruded strands were introduced into a water bath for cooling, and then inserted into a pellet former for cutting, to obtain a resin composition (granule). <Clasificación por la Prueba de Combustión UL94 > The resulting granule was dried at 120°C for 5 hours, and then injection molded into a test specimen of 125 mm x 13 mm x 0.8 mm thick, using an injection molding machine ("J50", from Japan Steel Works, Ltd.), at a cylinder temperature of 260°C (exceptionally 280°C for Comparative Examples 2-5, 2-6), and a die temperature of 80°C. Using the obtained test sample, the dripping during combustion and the combustion time were measured according to the UL94 combustion test, and were rated. <Propiedad de la Tracción > The resulting resin granule was dried at 120°C for 5 hours, and then injection molded into an ISO multi-purpose test specimen (4 mm thick), using a molding machine. PACO ίη / 77Ω7 / Β / YΥΙΛΙ by injection ("J85AD", from Japan Steel Works, Ltd.), at a cylinder temperature of 250°C (exceptionally 280°C for Comparative Examples 2-5, 2-6), and a die temperature of 80°C. Using the ISO multipurpose test specimen molded in this manner, the maximum tensile strength (in MPa), tensile modulus (in MPa), and tensile strength (in %) were measured in accordance with ISO527-1 and ISO527-2. <Propiedades Flexurales > Flexural properties were measured in the same manner as described in Examples 1-1 to 1-8, and Comparative Examples 1-1 to 1-10. <Resistencia a Impactos Charpy con Muescas > The granule obtained by the method mentioned above for production was dried at 120°C for 5 hours, and then injection molded into an ISO tensile test specimen (4 mm thick), using an injection molding machine ("J85AD", from Japan Steel Works, Ltd.), at a cylinder temperature of 250°C, and a die temperature of 80°C. Note, however, that a cylinder temperature of 280°C, and a die temperature of 80°C were applied to Comparative Example 2-5 and Comparative Example 2-6. The ISO multipurpose test specimen was cut to a predetermined size according to ISO179, and the Charpy notched impact strength was measured and noted in kJ / m2. <Absorbancia, Transmitancia, y Reflectancia> The resulting granule was injection molded using an injection molding machine (“NEX80”, from Nissei Plastic Industrial Co., Ltd.), at a preset cylinder temperature of 260°C (exceptionally 280°C for Comparative Examples 2-5, 2-6), and a die temperature of 80°C, to obtain a test sample 100 mm x 100 mm x 2 mm thick. Using the obtained test sample, the absorbance determined by Equation (A) above, the reflectance determined by Equation (B) above, and the transmittance determined by Equation (C) above, all at a frequency of 76.5 GHz, were measured as described below. A Keysight Technologies "N5252A" network analyzer was used for the measurement. For the measurement, the test sample was placed while aligned to the transverse direction of the injection-molded article parallel to the direction of the electric field. <Dependencia de Frecuencia de la Reflectancia> The test sample obtained in this way was subjected to reflectance measurements over the 70–80 GHz frequency range, and the difference between the maximum and minimum reflectance was calculated. The smaller the difference between the maximum and minimum reflectance, the smaller the frequency dependence, indicating that the resulting resin composition is stable. <Clasificación de la Absorción de Ondas Electromagnéticas> The absorption of electromagnetic waves was classified as A if all of the absorbance, reflectance and transmittance requirements were met, it was classified as B if at least the absorbance met the requirements of the following articles (excluding the case applicable to A), and it was classified as C if it did not meet the requirements of A PACO ίη / ΖΖΠΖ / Ε / ΥΙΛΙ neither B. Classification Criteria: absorbance > 50.0%, reflectance < 30.0%, transmittance < 25.0%<Resistiv¡dad de Superficie> The granule obtained in this way was injection molded using an injection molding machine ("NEX80", from Nissei Plastic Industrial Co., Ltd.), at a preset cylinder temperature of 260°C (exceptionally 270°C for Comparative Examples 2-5, 2-6), and a die temperature of 80°C, to obtain a test sample 100 mm x 100 mm x 2 mm thick. The obtained test sample was subjected to surface resistivity measurement (in Ω), in accordance with IEC60093. The measurement was performed using the "R8340 ultra-high resistance meter" from ADVANTEST Corporation. < Volume Resistivity > The granule obtained in this way was injection molded using an injection molding machine ("NEX80", from Nissei Plastic Industrial Co., Ltd.), at a preset cylinder temperature of 260°C (exceptionally 270°C for Comparative Examples 2-5, 2-6), and a die temperature of 80°C, to obtain a test sample 100 mm x 100 mm x 2 mm thick. The obtained test sample was subjected to volume resistivity measurement (in Ω-cm), in accordance with IEC60093. For the measurement, an "R8340 ultra-high resistance meter" from ADVANTEST Corporation was used. <Clasificac¡ón General del Retardo de Llama y Absorbancia de Ondas Electromagnéticas> The overall classification was made as follows, based on the results of the combustion test mentioned above and the absorption of electromagnetic waves. Cases classified as V-0 were given a score of 3, V-1 as 2, V-2 as 1, and "incompatible" as 0. Cases classified as A for electromagnetic wave absorption were given a score of 2, those classified as B were given a score of 1, and those classified as C were given a score of 0. The total score for the combustion test and the electromagnetic wave absorbance rating was used for the overall rating on a five-point scale. <Resistencia Química > A template capable of applying a three-point flexural load, illustrated in Fig. 1, was used in an environment at 23°C. The obtained ISO multipurpose test specimen (4 mm thick) (indicated by the reference symbol 1 in Fig. 1) was fixed to the lower center portion of a test specimen fitting template 2. The amount of deformation was adjusted and fixed at 1% by attaching an adjustment cylinder 3. PACO ίη / ZZΖΠZ / E / YΙΛΙ control the amount of tension to the test sample adjustment template 2, and when fixing the cylinder with a wing screw 4. The distance between the adjustment cylinders 3 was set to 100 mm. A 10 mm x 20 mm gauze, impregnated with regular lead-free gas, was placed in the center of the fixed test sample, and the appearance of the test sample was visually observed 24 hours later, and evaluated from 5 according to the following criteria. A: Without cracks. B: Cracked or broken. <Temperatura de Deflexión Bajo Carga> The ISO multipurpose test sample obtained in this way (4 mm thick) was subjected to 10 deflection temperature measurement under load (in °C) under a load of 1.80 MPa, in accordance with ISO75-1 and 75-2. For measuring the deflection temperature under load, the "AUTO HDT Tester 6A-2V" from Toyo Seiki Seisaku-sho, Ltd. was used. paco Ln / zznz / E / YiAi > Q ω ω ιυ not -1-1σι in ο σι or σι or C hh [Table 7] ¿ Article Unit Example 2-1 Example 2-2 Example 2-3 Example 2-4 Example 2-5 Chemical composition a-1) PBT mass 100 100 100 100 b-1) Carbon nanotube 0.8 0.9 2.7 2.6 2.7 f-1) Flame retardant auxiliary (antimony compound) 4.5 5.8 5.9 6.1 6.3 g-1) Flame retardant auxiliary CXB2000H 11.2 15.7 16.0 g-2) Flame retardant FR1025 11.5 g-3) Flame retardant FR-53 13.9 b-2) Reinforcing material (glass fiber) T-127 51 54 55 53 54 d-1) Stabilizer AO-60 0.3 0.4 0.4 0.4 0.4 e-1) Mold Release Agent 10OP 0.3 0.4 0.4 0.4 0.4 c-2) Epoxy Resin jer1003 1.7 1.8 1.8 1.8 1.8 CNT / Br 0.14 0.11 0.32 0.33 0.33 Evaluation UL94 Burn Test Rating (0.8 mm Thick) Rating V-1 V-0 V-0 V-0 V-0 Drip During Burn - No No No No No No Burn Time s 67.0 5.0 31.0 15.0 18.0 Ultimate Tensile Strength MPa 142 143 138 143 143 Tensile Modulus MPa 10460 10710 10985 11230 11230 Tensile strain % 2.3 2.2 2.1 2.2 2.2 Flexural strength MPa 218 216 212 213 221 Flexural modulus MPa 10140 10480 11100 10570 11020 Notched Charpy impact strength kJ / m2 7.9 7.9 6.9 8.1 7.2 Absorbance at 78.5 GHz % 57.8 58.9 74.2 73.4 74.1 Reflectance at 76.6 GHz % 22.2 24.0 24.5 20.0 22.5 Transmittance at 76.7 GHz % 20.0 17.1 1.3 6.6 3.4 Frequency dependence of reflectance 12.6 10.2 0.9 8.0 2.3 Wave absorbance rating Electromagnetic Classification AAAAA Surface Resistivity Ω 2.3x1014 6.8x10'4 1.2x10 9.9x10'3 2.7x10'4 Volume Resistivity Ω-cm 1.2x10'° 94x10'° 7.7x10'° 4.24x10'3 1.7x1012 General Classification of Flame Retardation and Electromagnetic Wave Absorption 4 5 5 5 5 Chemical Resistance AAAAA Deflection Temperature Under Load °C 210 210 210 206 208. oc « c [Table 8] ω σι σι > α ιυ σι k ο σι och hc Article Unit Example 2-6 Comparative Example 2-1 Comparative Example 2-2 Comparative Example 2-3 Comparative Example 2-4 Chemical Composition a-1) PBT per unit mass 100 100 100 100 100 b-1) Carbon Nanotube 2.6 f-1) Flame Retardant Auxiliary (Antimony Compound) 4.5 4.4 6.2 6.0 6.1 g-1) Flame Retardant Auxiliary CXB2000H 11.4 11.1 15.6 g-2) Flame Retardant FR1025 11.2 g-3) Flame Retardant FR-53 13.5 b-2) Reinforcing Material (Fiberglass) T127 52 51 53 51 52 d-1) Stabilizer AO-60 0.4 0.3 0.4 0.3 0.3 e-1) Mold Release Agent 10OP 0.4 0.3 0.4 0.3 0.3 c-2) Epoxy Resin 1003 1.7 1.7 1.8 1.7 1.7 CNT / Br 0.44 0.00 0.00 0.00 0.00 Evaluation UL94 Burn Test Rating (0.8 mm Thick) Rating Not Applicable V-2 V-2 V-2 V-2 Drip During Burn - No Yes Yes Yes Yes Burn Time s 271.0 44.0 38.0 40.0 15.0 Ultimate Tensile Strength MPa 138 146 145 142 146 Tensile Modulus MPa 10720 10080 10060 10370 10260 Tensile strain % 1.9 2.5 2.6 2.5 2.4 Flexural strength MPa 214 218 217 214 212 Flexural modulus MPa 10850 9950 9950 9780 9490 Notched Charpy impact strength kJ / m2 7.1 9.0 8.9 9.8 9.4 Absorbance at 76.5 GHz % 74.6 5.8 6.0 5.5 5.5 Reflectance at 76.6 GHz % 23.9 8.0 7.8 8.6 8.3 Transmittance at 76.7 GHz % 1.4 86.2 86.2 85.8 86.2 Frequency dependence of reflectance Electromagnetic wave absorbance rating ACCCC Surface resistivity Ω 1.2x10” 4.9x10'5 1.9x10'5 1.3x10'5 2.0x10'5 Volume resistivity Ω-cm 4.7x10'° 3.0x10'7 1.8x10'6 6.6x10'6 2.1x10'7 General classification of flame retardation and electromagnetic wave absorption 2 1 1 1 1 Chemical resistance AAAA Deflection temperature under load °C. In the Tables, the carbon nanotubes (b-1—1) to (b-1-3) were provided not in terms of the amount of master bath, but in terms of carbon nanotube per se. The articles formed from the resin compositions in Examples 2-1 to 2-5 were found to exhibit high absorbance, excellent flame retardancy and heat resistance, as well as high mechanical strength. On the other hand, the articles formed from the resin compositions in Examples 2-1 to 2-5 were found to exhibit low transmittance and reflectance. INDUSTRIAL APPLICABILITY Millimeter-wave radar has suffered from malfunctions due to noise associated not only with the transmitting electromagnetic wave but also with the reflecting electromagnetic wave. Consequently, a material with high electromagnetic wave absorption, low transmittance, and low reflectance has become increasingly in demand. The resin composition of this invention can meet these requirements and can also meet the demands for higher levels of flame retardancy and chemical resistance. The resin composition of this invention is therefore widely expected for applications where flame retardancy, chemical resistance, and electromagnetic wave absorption are required. LISTS OF REFERENCE SIGNS ISO Multipurpose Test Sample Test sample adjustment template Adjustment cylinder for controlling the amount of tension Butterfly< / aplicaciones>
Claims
1. A resin composition, characterized in that it contains a thermoplastic resin and an electromagnetic wave absorbing material, exhibiting an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (A); exhibiting a difference between a maximum value and a minimum reflectance value in the frequency range of 70 GHz to 80 GHz of 20.0% or smaller, when formed to a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); and intended for use as an electromagnetic wave absorber: Equation (A) Absorbance (%)=100 - (—X 100 + —X θθΊ yio-K / 10 lo-7 / io j (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method), Equation (B) Reflectance (%)=_£_ χ 100 (in Equation (B), R represents the return loss measured by the free space method).
2. The resin composition according to claim 1, further characterized in that the electromagnetic wave absorbing material is a carbon-containing electromagnetic wave absorbing material.
3. The resin composition according to claim 1 or 2, further characterized in that it contains 0.1 to 10.0 parts by mass of a carbon nanotube, per 100 parts by mass of a thermoplastic resin, exhibiting an absorbance at a frequency of 76.5 GHz of 40.0 to 100%, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (A); exhibiting a difference between a maximum value and a minimum value of reflectance in the frequency range of 70 GHz to 80 GHz of 20.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); and intended for use as an electromagnetic wave absorber.
4. The resin composition according to any of claims 1 to 3, further characterized in that it additionally contains 10 to 100 parts by mass of a glass fiber, per 100 parts by mass of a thermoplastic resin.
5. The resin composition according to claim 4, further characterized in that the electromagnetic wave-absorbing material and the glass fiber are in a mass ratio (electromagnetic wave-absorbing material / glass fiber) of 0.01 to 0.
30. PACO ίη / ZZΖΠZ / E / YΙΛΙ 6. The resin composition according to any of claims 1 to 5, further characterized in that it additionally contains 0.01 to 5.0 parts by mass of a reactive compound, per 100 parts by mass of a thermoplastic resin.
7. The resin composition according to any of claims 1 to 6, further characterized in that a thermoplastic resin contains a polybutylene terephthalate resin.
8. The resin composition according to claim 7, further characterized in that it contains 1.0 to 75 parts by mass of a polycarbonate resin, per 100 parts by mass of a polybutylene terephthalate resin.
9. The resin composition according to claim 7, further characterized in that it additionally contains 1.0 to 60 parts by mass of a polystyrene-based resin, per 100 parts by mass of a polybutylene terephthalate resin.
10. The resin composition according to claim 7, further characterized in that it additionally contains 1.0 to 75 parts by mass of a polycarbonate resin, and 1.0 to 60 parts by mass of a polystyrene-based resin, per 100 parts by mass of a polybutylene terephthalate resin.
11. The resin composition according to any of claims 1 to 6, further characterized in that a thermoplastic resin contains a polypropylene resin.
12. The resin composition according to any of claims 1 to 6, further characterized in that a thermoplastic resin contains a polyamide resin.
13. The resin composition according to any of claims 1 to 12, further characterized in that the electromagnetic wave-absorbing material contains a multi-layered carbon nanotube.
14. The resin composition according to any of claims 1 to 13, further characterized in that the resin composition does not contain carbon fiber, or has a carbon fiber content of less than 3% by mass.
15. The resin composition according to any of claims 1 to 14, further characterized in that it exhibits a reflectance at a frequency of 76.5 GHz of 40.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and is determined by Equation (B): Equation (B) Reflectance (%)=---X 100 (in Equation (B), R represents the return loss measured by the free space method).
16. The resin composition according to any of claims 1 to 15, further characterized in that it exhibits a transmittance at a frequency of 76.5 GHz of 15.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (C): Equation (C) Transmittance (%) = *, χ 100 (in Equation (C), T represents the transmission attenuation measured by the free space method).
17. A resin composition, characterized in that it contains a thermoplastic resin, exhibiting an absorbance at a frequency of 76.5 GHz of 60.0% or greater, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (A); exhibiting a reflectance at a frequency of 76.5 GHz of 30.0% or less, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (B); exhibiting a transmittance of 10.0% or less at a frequency of 76.5 GHz, when formed in a size of 150 mm x 150 mm x 2 mm thick and determined by Equation (C); and intended for use as an electromagnetic wave absorber: Equation (A) Absorbance (%) = 100 - (—7— x 100 H--x loo) (in Equation (A), R represents the return loss measured by the free space method, and T represents the transmission attenuation measured by the free space method), Equation (B) Reflectance (%)=---X 100 lQ-K / io (in Equation (B), R represents the return loss measured by the free space method), and Equation (C) Transmittance (%)=—X 100 io-viao (in Equation (C), T represents the transmission attenuation measured by the free space method).
18. The resin composition according to any of claims 1 or 17, further characterized in that it additionally contains a flame retardant.
19. The resin composition according to claim 18, further characterized in that the flame retardant is a bromide-containing flame retardant.
20. An electromagnetic wave absorber formed from a resin composition described in any of claims 1 to 19.