Photo-protective and thermo-protective agrochemical composition

Abstract

The present invention relates to a synergistic combination of photoprotectants and thermo-protectants in agrochemical composition, to the corresponding agrochemical liquid composition, and to the use of synergistic combination of thermo-protectant and photo-protectant for stabilization of agrochemical compositions comprising at least one pesticide.

Description

[0001] TITLE: PHOTO-PROTECTIVE AND THERMO-PROTECTIVE AGROCHEMICAL COMPOSITION

[0002] FIELD OF INVENTION:

[0003] The following invention relates to a synergistic photoprotective and thermo-protective agrochemical composition, to the corresponding agrochemical liquid composition, and to the use of synergistic combination of thermo-protectant and photo-protectant for stabilization of agrochemical compositions comprising at least one pesticide.

[0004] SUMMARY

[0005] The present invention is directed to a photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 50 % per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photoprotectant.

[0006] Another aspect of the invention relates to an agrochemical liquid composition comprising: a) at least one pesticide, selected from insecticides, fungicides, herbicides and the mixtures thereof; b) stabilizer comprising synergistic combination of thermo-protectant and photoprotectant; c) organic solvent; d) non-ionic surfactant; e) anionic surfactant.

[0007] The present invention further directed to the use of synergistic combination of thermoprotectant and photo-protectant for stabilization of agrochemical composition comprising at least one pesticide selected from insecticide, fungicide, herbicides and the mixtures thereof. BACKGROUND:

[0008] It is well known that many pesticides tend to undergo decomposition, as a result of exposure to the direct sunlight contacting the leaves and other plant parts that have been treated with a pesticidal product. This means that the actual quantity of the applied pesticide is eventually reduced, which will cause to less efficacy of the pesticidal product and will require to repeat the treatment, or to apply higher dose, to achieve the desired efficacy.

[0009] A second factor that affects the stability of some pesticides is heat. For some pesticides, a prolonged exposure to heat causes their thermal decomposition, which also creates a similar situation in which the actual concentration of the active component in practice is not the effective concentration required or intended to be applied in the field. Protection against thermal decomposition is important in two aspects: first, in the case where the material has been applied in the field, and the retention of a high level of the active ingredient for longer time is required to achieve the desired effect. Additionally, it is also necessary to be able to preserve the pesticidal product concentration during storage, for future use.

[0010] Macrolides are a class of chemical compounds mainly characterized by a large macrocyclic lactone ring, originally produced by soil bacteria during fermentation process and possess an antibiotic and pesticidal capabilities. Amongthem, Emamectin and Spinosad are widely used as crop protectors. However, both tend to suffer from photo and thermal instability.

[0011] There are several solutions in the field which try to overcome the pesticides photodegradation by addition of certain photo protecting molecules that are able to reduce the potential damage cause by sunlight radiation:

[0012] WO 2010 / 106314 describes a pesticide composition comprising pesticide particles of avermectin (A) (abamectin and / or emamectin benzoate) in a size of from 0.1 to 100pm coated with a photo-protecting agent. Preferred photo-protecting agents are 2,6-di(tert- butyl)-4-methylphenol (commonly known as BHT); ethylenebis(oxyethylene)bis-(3-(5- tert-butyl-4-hydroxy-m-tolyl)-propionate) (available, for example, as lrganoxR245); an azo dye (available, for example, as Oil Red O™ from Sigma-Aldrich); a synthetic beeswax (available, for example, as Syncrowax™ BB4 from Croda); and a UV absorber of the hydroxyphenylbenzotriazole class (available, for example, as TinuvinR328 from BASF).

[0013] In this case the application is limited to high melting point pesticides particulates, coated with a UV blocker. The processes as described in the application is relatively complicated and require specially designed machinery. Moreover, the formulation types are limited to solid compositions such as water dispersible or water-soluble granules.

[0014] WO 2010 / 126578 & WO 2010 / 126583 describe pesticidal suspension concentrates containing spinetoram and at least one metal oxide such as: ZnO, Fe20s, TiO2 and CuO. The application exhibits an improved efficacy for formulation with high concentration of metal oxide of up to 52.6% per weight of total composition. However, high concentration of metal oxides is known to cause plant phytotoxicity as mentioned in Plants 2023, 12(4), 778.

[0015] IN202221036514 describes a synergistic pesticidal solid formulations with improved stability, comprising: Spinosad, one or more other insecticides (such as emamectin benzoate, cyantraniliprole, abamectin, and tolfenpyrad), a UV photo degradation arrester, (such as ZnO, TiO and kojic acid). The application also describes a process for formulating the composition as granular compositions (WG), its effectiveness against several pests (such as lepidopteran, thysanopteran, dipteran and hemipteran insects), and its stability, being less prone to UV degradation. However, the composition is limited only to solid granular WG formulations.

[0016] Nevertheless, despite the previous efforts there is still a need for developing new stabilized compositions for photo and thermal sensitive pesticides.

[0017] DETAILED DESCRIPTION OF INVENTION:

[0018] DEFINITIONS:

[0019] Prior to setting forth the present subject matter in detail, it may be helpful to provide definitions of certain terms to be used herein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this subject matter pertains. The following definitions are provided for clarity.

[0020] The term "a" or "an" as used herein includes the singular and the plural, unless specifically stated otherwise. Therefore, the terms "a," "an," or "at least one" can be used interchangeably in this application.

[0021] As used herein, the verb "comprise" as is used in this description and in the claims and its conjugations are used in its non-limiting sense to mean that items following the word are included, but items not specifically mentioned are not excluded.

[0022] As used herein, the term "about" when used in connection with a numerical value includes ±10% from the indicated value. In addition, all ranges directed to the same component or property herein are inclusive of the endpoints, are independently combinable, and include all intermediate points and ranges. It is understood that where a parameter range is provided, all integers within that range, and tenths thereof, are also provided by the invention.

[0023] The term "stabilizer" as used herein refers to a chemical agent that is added to a composition to prevent unwanted change in state or form of the composition and / or of the active pesticide included in the composition.

[0024] As used herein, the term "effective amount" refers to an amount of the active ingredient that is commercially recommended for use to control and / or prevent pest. The commercially recommended amount for each active ingredient, often specified as application rates of the commercial formulation, may be found on the label accompanying the commercial formulation. The commercially recommended application rates of the commercial formulation may vary depending on factors such as the plant species and the pest to be controlled.

[0025] As used herein, the term "insecticide" broadly refers to compounds or compositions that are used as acaricides, insecticides, insecticide synergists, ixodicides, nematicides, and molluscicides. For chemical classes and applications, as well as specific compounds of each class, see "The Pesticide Manual Thirteenth Edition" (British Crop Protection Council, Hampshire, UK, 2003), as well as "The e-Pesticide Manual, Version 3" (British Crop Protection Council, Hampshire, UK, 2003-04), the contents of each of which are incorporated herein by reference in their entirety.

[0026] As used herein the term "plant" or "crop" refers, but is not limited to whole plants, plant organs (e.g. leaves, stems, twigs, roots, trunks, limbs, shoots, fruits etc.), plant cells, or plant seeds. This term also encompasses plant crops such as fruits and vegetables. In some embodiments, the term "plant" may include the propagation material thereof, which may include all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers, which can be used forthe multiplication of the plant. This includes seeds, tubers, spores, corms, bulbs, rhizomes, sprouts basal shoots, stolons, and buds and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.

[0027] As used herein the term "plant propagation material" refers, but is not limited to, all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers, which can be used for the multiplication of the plant including tubers, spores, corms, bulbs, rhizomes, sprouts basal shoots, stolons, and buds and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil.

[0028] As used herein, the term "locus" refers, but is not limited to the place on which the plants are growing, the place on which the plant propagation materials of the plants are sown or the place on which the plant propagation materials of the plants will be sown including the areas under cultivation.

[0029] As used herein, the term "treating a plant or a locus against pest" includes, but is not limited to, protecting the plant or locus against pest and / or controlling pest of the plant or locus. As used herein the term "pest" refer to any biological factor that can pose a risk or can cause to any minor, or major damage to a plant or plants in general and / or to agricultural crops in particular, which includes but not limited to insects, mites, fungi, weeds, or any combination thereof.

[0030] As used herein the term "ha" refers to hectare.

[0031] As used herein, the term "mixture" or "combination" refers, but is not limited to, a combination in any physical form, e.g., blend, solution, suspension or the like.

[0032] As used herein, the term "synergistic combination" refers, but not limited to, a combination of photo-protectant and thermo-protectant that have a greater effect on the stability of the composition, compared to the effect of each component individually or compared to the sum of the effect obtained by each component individually.

[0033] As used herein, the term "photo-protectant" refers, but not limited to, a chemical compound capable of reducing the photo degradation of a component in the composition, caused by natural or artificial sunlight.

[0034] As used herein, the term "thermo-protectant" refers, but not limited to, a chemical compound that is capable of reducing the thermal degradation of a component in the composition, caused by heat.

[0035] As used herein, the term "composition" refers, but not limited to a composition of two or more components combined together. The term "composition also refers but not limited to solid composition, liquid compositions, formulations, including tank mix.

[0036] As used herein, the term "combination" refers, but not limited to a composition of two or more components combined together. The term "composition also refers but not limited to solid composition, liquid compositions, formulations, including tank mix.

[0037] The agrochemical composition subject of invention: The present invention provides a photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0038] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 40% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0039] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 30% to 40% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0040] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 20% to 30% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0041] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 10% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0042] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 10% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0043] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0044] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 1% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0045] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 2% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0046] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0047] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 1% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0048] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 1% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0049] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant. In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0050] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprises at least one pesticide a) is selected from insecticides, fungicides, herbicides and the mixtures thereof.

[0051] In some embodiment, the at least one pesticide a) is insecticide.

[0052] In some embodiment, the at least one pesticide a) is fungicide.

[0053] In some embodiment, the at least one pesticide a) is herbicide.

[0054] Suitable insecticides are selected from allosamidin, thuringiensin, spinosad, spinetoram, spinosyns including spinosyn A, spinosyn D , 21-butenyl spinosyns and their derivatives, abamectin, doramectin, emamectin, emamectin benzoate, eprinomectin, ivermectin, selamectin, lepimectin, milbemectin, milbemycin oxime, moxidectin, calcium arsenate, copper acetoarsenite, copper arsenate, lead arsenate, potassium arsenite, sodium arsenite, anabasine, azadirachtin, d-limonene, nicotine, pyrethrins, cinerins, cinerin I, cinerin II, jasmolin I, jasmolin II, pyrethrin I, pyrethrin II, quassia, rotenone, ryania, sabadilla, bendiocarb, carbaryl, benfiiracarb, carbofuran, carbosulfan, decarbofuran, furathiocarb, dimitan, dimetilan, hyquincarb, pirimicarb, alanycarb, aldicarb, aldoxycarb, butocarboxim, butoxycarboxim, methomyl, nitrilacarb, oxamyl, tazimcarb, thiocarboxime, thiodicarb, thiofanox, allyxycarb, aminocarb, bufencarb, butacarb, carbanolate, cloethocarb, dicresyl, dioxacarb, EMPC, ethiofencarb, fenethacarb, fenobucarb, isoprocarb, methiocarb, metolcarb, mexacarbate, promacyl, promecarb, propoxur, trimethacarb, XMC, xylylcarb, dinex, dinoprop, dinosam, DNOC, barium hexafluorosilicate, cryolite, sodium fluoride, sodium hexafluorosilicate, sulflurandd; chlordimeform, formetanate, formparanate, acrylonitrile, carbon disulfide, carbon tetrachloride, chloroform, chloropicrin, para-dichlorobenzene, 1,2-dichloropropane, ethyl formate, ethylene dibromide, ethylene dichloride, ethylene oxide, hydrogen cyanide, iodomethane, methyl bromide, methylchloroform, methylene chloride, naphthalene, phosphine, sulfuryl fluoride, tetrachloroethane, borax, calcium polysulfide, copper oleate, mercurous chloride, potassium thiocyanate, sodium thiocyanate, bistrifiuron, buprofezin, chlorfluazuron, cyromazine, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron, epofenonane, fenoxycarb, hydroprene, kinoprene, methoprene, pyriproxyfen, triprene, juvenile hormone I, juvenile hormone II, juvenile hormone HI, chromafenozide, halofenozide, methoxyfenozide, tebufenozide, a- ecdysone, ecdysterone, diofenolan, precocene I, precocene II, precocene HI, dicyclanil, bensultap, cartap, thiocyclam, thiosultap, flonicamid, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, thiacloprid, bromo-DDT, camphechlor, DDT, pp'-DDT, ethyl-DDD, HCH, gamma-HCH, lindane, methoxychlor, pentachlorophenol and TDE, aldrin, bromocyclen, chlorbicyclen, chlordane, chlordecone, dieldrin, dilor, endosulfan, endrin, HEOD, heptachlor, HHDN, isobenzan, isodrin, kelevan, mirex, bromfenvinfos, chlorfenvinphos, crotoxyphos, dichlorvos, dicrotophos, dimethylvinphos, fospirate, heptenophos, methocrotophos, mevinphos, monocrotophos, naled, naftalofos, phosphamidon, propaphos, TEPP, tetrachlorvinphos, dioxabenzofos, fosmethilan, phenthoate, acethion, amiton, cadusafos, chlorethoxyfos, chlormephos, demephion, demephion-O, demephion-S, demeton, demeton-O, demeton-S, demeton-methyl, demeton-O-methyl, demeton-S-methyl, demeton-S-methylsulphon, disulfoton, ethion, ethoprophos, IPSP, isothioate, malathion, methacrifos, oxydemeton- methyl, oxydeprofos, oxydisulfoton, phorate, sulfotep, terbufos, thiometon, aliphatic amide, amidithion, cyanthoate, dimethoate, ethoate-methyl, formothion, mecarbam, omethoate, prothoate, sophamide, vamidothion, oxime, chlorphoxim, phoxim, phoxim-methyl, azamethiphos, coumaphos, coumithoate, dioxathion, endothion, menazon, morphothion, phosalone, pyraclofos, pyridaphenthion, quinothion, dithicrofos, thicrofos, azinphos- ethyl and azinphos-methyl, dialifos, phosmet, isoxathion, zolaprofos, chlorprazophos, pyrazophos, chlorpyrifos, chlorpyrifos-methyl, butathiofos, diazinon, etrimfos, lirimfos, pirimiphos-ethyl, pirimiphos-methyl, primidophos, pyrimitate, tebupirimfos, quinalphos, quinalphos- methyl, atnidathion, lythidathion, methidathion, prothidathion, isazofos, triazophos, azothoate, bromophos, bromophos- ethyl, carbophenothion, chlorthiophos, cyanophos, cythioate, dicapthon, dichlofenthion, etaphos, famphur, fenchlorphos, fenitrothion fensulfothion, fenthion, fenthion-ethyl, heterophos, jcKifenphos, mesulfenfos, parathion, parathion-methyl, phenkapton, phosnichlor, profenofos, prothiofos, sulprofos, temephos, trichlormetaphos-3, trifenofos, butonate, trichlorfon, mecarphon, fonofos, trichloronat, cyanofenphos, EPN, leptophos, crufomate, fenamiphos, fosthietan, imicyafos, mephosfolan.phosfolan, pirimetaphos, acephate, isocarbophos, isofenphos, methamidophos, propetamphos, dimefox, mazidox, mipafox, schradan, indoxacarb, dialifos, phosmet, tetramethrin, acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, tebufenpyrad, tolfenpyrad, vaniliprole, acrinathrin, allethrin, bioallethrin, barthrin, bifenthrin, bioethanomethrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma- cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha- cypermethrin, alpha-methrin, beta- cypermethrin, theta-cypermethrin, zeta- cypermethrin, beta-cypermethrin cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau- fluvalinate, furethrin, imiprothrin, metofluthrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, pyresmethrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, terallethrin, tetramethrin, tralomethrin, transfluthrin, etofenprox, fenpropathrin flufenprox, halfenprox, protrifenbute , silafluofen, flufenerim, pyrimidifen, chlorfenapyr, spirodiclofen, spiromesifen, spirotetramat, diafenthiuron, flucofiiron, sulcofuron, AKD- 3088, chlorantraniliprole, closantel, crotamiton, cyflumetofen, E2Y45, EXD, fenazaflor, fenazaquin, fenoxacrim, fenpyroximate, FKI- 1033, flubendiamide, HGW86, hydramethylnon, IKI-2002, isoprothiolane, malonoben, metaflumizone, metoxadiazone, nifluridide, NNI-9850, NNI-0101, pymetrozine, pyridaben, pyridalyl, pyrifluquinazon, Qcide, rafoxanide, rynaxypyr™, SYJ- 159, triarathene. In an embodiment, the insecticide a) is selected from the group comprising: abamectin, ivermectin, selamectin, eprinomectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tralomethrin, cyfluthrin, alpha-methrin, zeta-cypermethrin, fenvalerate, esfenvalerate, acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, beta-cyfluthrin, cyhalothrin, beta-cypermethrin, cyphenothrin, empenthrin, etofenprox, fenpropathrin, flucythrinate, tau-fluvalinate, phenothrin, prallethrin, resmethrin, tefluthrin, tetramethrin, lambda-cyhalothrin, spinosad, spinoteram, spinosyn A, spinosyn D.

[0055] In another embodiment, the pesticide a) is an insecticide selected from emamectin, emamectin benzoate, abamectin, spinosad, spinoteram, spinosyn A, spinosyn D.

[0056] In another embodiment, the pesticide a) is emamectin.

[0057] In certain embodiment, the insecticide a) is emamectin benzoate.

[0058] In another embodiment, the pesticide a) is an insecticide selected from spinosad, spinoteram, spinosyn A, spinosyn D.

[0059] In another embodiment, the pesticide a) is spinoteram, spinosyn A, spinosyn D or combination thereof.

[0060] In another embodiment, the pesticide a) is spinosad.

[0061] In another embodiment, the pesticide a) is spinosyn A.

[0062] In another embodiment, the pesticide a) is spinosyn D.

[0063] In another embodiment, the pesticide a) is spinosyn A, spinosyn D or combination thereof.

[0064] In certain embodiment, the insecticide a) is abamectin.

[0065] Suitable herbicide are selected from allidochlor, beflubutamid, benzadox, benzipram, bromobutide, cafenstrole, CDEA, chlorthiamid, cyprazole, dimethenamid, dimethenamid- P, diphenamid, epronaz, etnipromid, fentrazamide, flupoxam, fomesafen, halosafen, isocarbamid, isoxaben, napropamide, naptalam, pethoxamid, propyzamide, quinonamid and tebutam, chloranocryl, cisanilide, clomeprop, cypromid, diflufenican, etobenzanid, fenasulam, flufenacet, flufenican, mefenacet, mefluidide, metamifop, monalide, naproanilide, pentanochlor, picolinafen, propanil, benzoylprop, flamprop, flamprop-M, acetochlor, alachlor, butachlor, butenachlor, delachlor, diethatyl, dimethachlor, metazachlor, metolachlor, S-metolachlor, pretilachlor, propachlor, propisochlor, prynachlor, terbuchlor, thenylchlor, xylachlor, benzofluor, perfluidone, pyrimisulfan, profluazol, asulam, carbasulam, fenasulam, oryzalin, bilanafos, chloramben, dicamba, 2,3>6-TBA, tricamba, bispyribac, pyriminobac, pyrithiobac, chloithal, aminopyralid, clopyralid, picloram, quinclorac, quinmerac, cacodylic acid, CMA, DSMA, hexaflurate, MAA, MAMA, MSMA, potassium arsenite, sodium arsenite, mesotrione, sulcotrione, tefuryltrione, tembotrione, benfuresate, ethofumesate, asulam, carboxazole chlorprocarb, dichlormate, fenasulam, karbutilate, terbucarb, barban, BCPC, carbasulam, carbetamide, CEPC, chlorbufam, chlopropham, CPPC, desmedipham, phenisopham, phenmedipham, phenmedipham-ethyl, propham, swep, alloxydim, butroxydim, clethodim, cloproxydim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim, isoxachlortole, isoxaflutole, benzfendizone, cinidon-ethyl, flumezin, flumiclorac, flumioxazin, flumipropyn, benfluralin, butralin, dinitramine, ethalfluralin, fluchloralin, isopropalin, methalpropalin, nitralin, oryzalin, pendimethalin, prodiamine, prof I uralin and trifluralin, dinofenate, dinoprop, dinosam, dinoseb, dinoterb, DNOC, etinofen, medinoterb, ethoxyfen, acifluorfen, aclonifen, bifenox, chlomethoxyfen, chlornitrofen, etnipromid, fluorodifen, fluoroglycofen, fluoronitrofen, fomesafen, furyloxyfen, halosafen, lactofen, nitrofen, nitrofluorfen, oxyfluorfen, dazomet, metam, alorac, chloropon, dalapon, flupropanate, hexachloroacetone, iodomethane, methyl bromide, monochloroacetic acid, SMA, TCA, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, ammonium sulfamate, borax, calcium chlorate, copper sulfate, ferrous sulfate, potassium azide, potassium cyanate, sodium azide, sodium chlorate, sulfuric acid, bromobonil, bromoxynil, chloroxynil, dichlobenil, iodobonil, ioxynil, pyraclonil, amiprofos-methyl, anilofos, bensulide, bilanafos, butamifos, 2,4-DEP, DMPA, EBEP, fosamine, glufosinate, glyphosate, piperophos, bromofenoxim, clomeprop, 2,4- DEB, 2,4-DEP, difenopenten, disul, erbon, etnipromid, fenteracol and trifopsime, 4- CPA, 2,4-D, 3,4-DA, MCPA, MCPA-thioethyl, 2,4,5-T, 4-CPB, 2,4-DB, 3,4-DB, MCPB and 2,4,5-TB, cloprop, 4-CPP, dichlorprop, dichlorprop-P, 3,4-DP, fenoprop, mecoprop and mecoprop- P, chlorazifop, clodinafop, clofop, cyhalofop, diclofop, fenoxaprop, fenoxaprop-P, fenthiaprop, fluazifop, fluazifop-P, haloxyfop, haloxyfop-P, isoxapyrifop, metamifop, propaquizafop, quizalofop, quizalofop-P and trifop, dinitramine, prodiamine, benzofenap, pyrazolynate, pyrasulfotole, pyrazoxyfen, pyroxasulfone, topramezone, fluazolate, pyraflufen, credazine, pyridafol, pyridate, brompyrazon, chloridazon, dimidazon, flufenpyr, metflurazon, norflurazon, oxapyrazon, pydanon, aminopyralid, cliodinate, clopyralid, dithiopyr, fluroxypyr, haloxydine, picloram, picolinafen, pyriclor, thiazopyr, triclopyr, iprymidam, tioclorim, cyperquat, diethamquat, difenzoquat, diquat, morfamquat, paraquat, butylate, cycloate, di-allate, EPTC, esprocarb, ethiolate, isopolinate, methiobencarb, molinate, orbencarb, pebulate, prosulfocarb, pyributicarb, sulfallate, thiobencarb, tiocarbazil, tri-allate, vernolate, dimexano, EXD, proxan, methiuron, dipropetryn, triaziflam, trihydroxytriazine, atrazine, chlorazine, cyanazine, cyprazine, eglinazine, ipazine, mesoprazine, procyazine, proglinazine, propazine, sebuthylazine, simazine, terbuthylazine and trietazine, atraton, methometon, prometon, secbumeton, simeton, terbumeton, ametryn, aziprotryne, cyanatryn, desmetryn, dimethametryn, methoprotryne, prometryn, simetryn, terbutryn, ametridione, amibuzin, hexazinone, isomethiozin, metamitron, metribuzin, amitrole, cafenstrole, epronaz, flupoxam, amicarbazone, bencarbazone, carfentrazone, flucarbazone, propoxycarbazone, sulfentxazone, thiencarbazone-methyl, cloransulam, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, pyroxsulam, butafenacil, bromacil, flupropacil, isocil, Lenacil, terbacil, 3-phenyluracils, benzthiazuron, cumyluron, cycluron, dichloralurea, diflufenzopyr, isonoruron, isouron, methabenzthiazuron, monisouron, noruron, anisuron, buturon, chlorbromuron, chloreturon, chlorotoluron, chloroxuron, daimuron, difenoxuron, dimefuron, diuron, fenuron, fluometuron, fluothiuron, isoproturon, linuron, methiuron, methyldymron, metobenzuron, metobromuron, metoxuron, monolinuron, monuron, neburon, parafluron, phenobenzuron, siduron, tetrafluron, thidiazuron, amidosulfuron, azimsulfuron, bensulfuron, chlorimuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfiiron, halosulfuron, imazosulfuron, mesosulfuron, nicosulfuron, orthosulfamuron, oxasulfiiron, primisulfuron, pyrazosulfuron, rimsulfuron, sulfometuron, sulfosulfuron, trifloxysulfuron, chlorsulfuron, cinosulfuron, ethametsulfuron, iodosulfuron, metsulfuron, prosulfuron, thifensulfuron, triasulfuron, tribenuron, triflusulfuron, tritosulfuron, buthiuron, ethidimuron, tebuthiuron, thiazafluron, thidiazuron, acrolein, allyl alcohol, azafenidin, benazolin, bentazone, benzobicyclon, buthidazole, calcium cyanamide, cambendichlor, chlorfenac, chlorfenprop, chlorflurazole, chlorflurenol, cinmethylin, clomazone, CPMF, cresol, orthodichlorobenzene, dimepiperate, endothal, fluoromidine, fluridone, flurochloridone, flurtamone, fluthiacet, indanofan, methazole, methyl isothiocyanate, nipyraclofen, OCH, oxadiargyl, oxadiazon, oxaziclomefone, pentachlorophenol, pentoxazone, phenylmercury acetate, pinoxaden, prosulfalin, pyribenzoxim, pyriftalid, quinoclamine, rhodethanil, sulglycapin, thidiazimin, tridiphane, trimeturon, tripropindan, tritac.

[0066] Suitable fungicide are selected from 2-(thiocyanatomethylthio)- benzothiazole, 2- phenylphenol, 8-hydroxyquinoline sulfate, Ampelomyces, quisqualis, azaconazole, azoxystrobin, Bacillus subtilis, benalaxyl, benomyl, benthiavalicarb-isopropyl, benzylaminobenzene-sulfonate (BABS) salt, bicarbonates, biphenyl, bismeithiazol, bitertanol, blasticidin-S, borax, Bordeaux mixture, boscalid, bromuconazole, bupirimate, calcium polysulfide, captafol, captan, carbendazim, carboxin, carpropamid, carvone, chloroneb, chlorothalonil, chlozolinate, Coniothyrium minitans, copper hydroxide, copper octanoate, copper oxychloride, copper sulfate, copper sulfate (tribasic), cuprous oxide, cyazofamid, cyflufenamid, cymoxanil, cyproconazole, cyprodinil, dazomet, debacarb, diammonium ethylenebis-(dithiocarbamate), dichlofluanid, dichlorophen, diclocymet, diclomezine, dichloran, diethofencarb, difenoconazole, difenzoquat ion, diflumetorim, dimethomorph, dimoxystrobin, diniconazole, diniconazole- M, dinobuton, dinocap, diphenylamine, dithianon, dodemorph, dodemorph acetate, dodine, dodine free base, edifenphos, epoxiconazole, ethaboxam, ethoxyquin, etridiazole, famoxadone, fenamidone, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenoxanil, fenpiclonil, fenpropidin, fenpropimorph, fentin, fentin acetate, fentin hydroxide, ferbam, ferimzone, fluazinam, fludioxonil, flumorph, fluopicolide, fluoroimide, fluoxastrobin, fluquinconazole, flusilazole, flusulfamide, flutolanil, flutriafol, folpet, formaldehyde, fosetyl, fosetyl- aluminium, fuberidazole, furalaxyl, furametpyr, guazatine, guazatine acetates, GY-81, hexachlorobenzene, hexaconazole, hymexazol, imazalil, imazalil sulfate, imibenconazole, iminoctadine, iminoctadine triacetate, iminoctadine trisfal besilate), ipconazole, iprobenfos, iprodione, iprovalicarb, isoprothiolane, kasugamycin, kasugamycin hydrochloride hydrate, kresoxim-methyl, mancopper, mancozeb, maneb, mepanipyrim, mepronil, mercuric chloride, mercuric oxide, mercurous chloride, metalaxyl, mefenoxam, metalaxyl-M, metam, metam- ammonium, metam-potassium, metam-sodium, metconazole, methasulfocarb, methyl iodide, methyl isothiocyanate, metiram, metominostrobin, metrafenone, mildiomycin, myclobutanil, nabam, nitrothal- isopropyl, nuarimol, octhilinone, ofurace, oleic acid (fatty acids), orysastrobin, oxadixyl, oxine-copper, oxpoconazole fumarate, oxycarboxin, pefiirazoate, penconazole, pencycuron, pentachlorophenol, pentachlorophenyl laurate, penthiopyrad, phenylmercury acetate, phosphonic acid, phthalide, picoxystrobin, polyoxin B, polyoxins, polyoxorim, potassium bicarbonate, potassium hydroxyquinoline sulfate, probenazole, prochloraz, procymidone, propamocarb, propamocarb hydrochloride, propiconazole, propineb, proquinazid, prothioconazole, pyraclostrobin, pyrazophos, pyributicarb, pyrifenox, pyrimethanil, pyroquilon, quinoclamine, quinoxyfen, quintozene, Reynoutria sachalinensis extract, silthiofam, simeconazole, sodium 2-phenylphenoxide, sodium bicarbonate, sodium pentachlorophenoxide, spiroxamine, sulfur, SYP-Z071, tar oils, tebuconazole, tecnazene, tetraconazole, thiabendazole, thifluzamide, thiophanate- methyl, thiram, tiadinil, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazoxide, tricyclazole, tridemorph, trifloxystrobin, triflumizole, triforine, triticonazole, validamycin, vinclozolin, zineb, ziram, zoxamide, Candida oleophila, Fusarium oxysporum, Gliocladium spp., Phlebiopsis gigantean, Streptomyces griseoviridis, Trichoderma spp., (RS)-N-(3,5-dichlorophenyl)-2- (methoxymethyl)-succinimide, 1,2-dichloropropane, 1,3- dichloro-l, 1,3,3- tetrafluoroacetone hydrate, l-chloro-2,4-dinitronaphthalene, l-chloro-2- nitropropane, 2-(2-heptadecyl-2-imidazolin-l-yl)ethanol, 2,3-dihydro-5-phenyl- 1,4-dithi- ine 1,1,4,4-tetraoxide, 2-methoxyethylmercury acetate, 2- methoxyethylmercury chloride, 2-methoxyethylmercury silicate, 3-(4- chlorophenyl)-5-methylrhodanine, 4-(2- nitroprop- l-enyl)phenyl thiocyanateme: ampropylfos, anilazine, azithiram, barium polysulfide, Bayer 32394, benodanil, benquinox, bentaluron, benzamacril, benzamacril- isobutyl, benzamorf, binapacryl, bis(methylmercury) sulfate, bis(tributyltin) oxide, buthiobate, cadmium calcium copper zinc chromate sulfate, carbamorph, CECA, chlobenthiazone, chloraniformethan, chlorfenazole, chlorquinox, climbazole, copper bis(3- phenylsalicylate), copper zinc chromate, cufraneb, cupric hydrazinium sulfate, cuprobam, cyclafuramid, cypendazole, cyprofiiram, decafentin, dichlone, dichlozoline, diclobutrazol, dimethirimol, dinocton, dinosulfon, dinoterbon, dipyrithione, ditalimfos, dodicin, drazoxolon, EBP, ESBP, etaconazole, etem, ethirim, fenaminosulf, fenapanil, fenitropan, fluotrimazole, furcarbanil, furconazole, furconazole-cis, furmecyclox, fiirophanate, glyodine, griseofulvin, halacrinate, Hercules 3944, hexylthiofos, ICIA0858, isopamphos, isovaledione, mebenil, mecarbinzid, metazoxolon, methfuroxam, methylmercury dicyandiamide, metsulfovax, milneb, mucochloric anhydride, myclozolin, N-3,5- dichlorophenyl-succinimide, N-3-nitrophenylitaconimide, natamycin, N- ethylmercurio-4-toluenesulfonanilide, nickel bis(dimethyldithiocarbamate), OCH, phenylmercury dimethyldithiocarbamate, phenylmercury nitrate, phosdiphen, prothiocarb, prothiocarb hydrochloride, pyracarbolid, pyridinitril, pyroxychlor, pyroxyfur, quinacetol, quinacetol sulfate, quinazamid, quinconazole, rabenzazole, salicylanilide, SSF- 109, sultropen, tecoram, thiadifluor, thicyofen, thiochlorfenphim, thiophanate, thioquinox, tioxymid, triamiphos, triarimol, triazbutil, trichlamide, urbacid, XRD-563, zarilamid.

[0067] The present invention provides a photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant. In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 40% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0068] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 30% to 40% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0069] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 20% to 30% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0070] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 10% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0071] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 10% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0072] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0073] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 1% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0074] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 2% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0075] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0076] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 1% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0077] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 1% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0078] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0079] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) emamectin benzoate in an amount of from 0.5% to 5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant. The present invention provides a photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0080] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 40% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0081] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 30% to 40% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0082] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 20% to 30% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0083] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 10% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0084] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 10% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0085] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0086] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 1% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0087] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 2% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0088] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0089] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 1% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0090] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a spinosad in an amount of from 1% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0091] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant. In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) spinosad in an amount of from 0.5% to 5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0092] The present invention provides a photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0093] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 40% to 50% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0094] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 30% to 40% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0095] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 20% to 30% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0096] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 10% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0097] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 10% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0098] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 20% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0099] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 1% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0100] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 2% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0101] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0102] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 1% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0103] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 1% to 2.5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant. In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 3% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0104] In some embodiment, the photoprotective and thermo-protective agrochemical composition comprising: a) abamectin in an amount of from 0.5% to 5% per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

[0105] In some embodiment, the amount of photo-protectant in stabilizer b) is from 0.1 to 10% per weight based on the weight of total composition.

[0106] In some embodiment, the amount of photo-protectant in stabilizer b) is from 9 to 10% per weight based on the weight of total composition.

[0107] In some embodiment, the amount of photo-protectant in stabilizer b) is from 8 to 9% per weight based on the weight of total composition.

[0108] In some embodiment, the amount of photo-protectant in stabilizer b) is from 7 to 8% per weight based on the weight of total composition.

[0109] In some embodiment, the amount of photo-protectant in stabilizer b) is from 6 to 7% per weight based on the weight of total composition.

[0110] In some embodiment, the amount of photo-protectant in stabilizer b) is from 5 to 6% per weight based on the weight of total composition.

[0111] In some embodiment, the amount of photo-protectant in stabilizer b) is from 4 to 5% per weight based on the weight of total composition.

[0112] In some embodiment, the amount of photo-protectant in stabilizer b) is from 3 to 4% per weight based on the weight of total composition.

[0113] In some embodiment, the amount of photo-protectant in stabilizer b) is from 2 to 3% per weight based on the weight of total composition. In some embodiment, the amount of photo-protectant in stabilizer b) is from 1 to 2% per weight based on the weight of total composition.

[0114] In some embodiment, the amount of photo-protectant in stabilizer b) is from 0.1 to 1% per weight based on the weight of total composition.

[0115] In some embodiment, the amount of photo-protectant in stabilizer b) is from 0.1 to 1.5% per weight based on the weight of total composition.

[0116] In some embodiment, the amount of photo-protectant in stabilizer b) is from 0.1 to 2% per weight based on the weight of total composition.

[0117] In some embodiment, the amount of photo-protectant in stabilizer b) is from 0.1 to 2.5% per weight based on the weight of total composition.

[0118] In some embodiment, the amount of photo-protectant in stabilizer b) is from 0.1 to 5% per weight based on the weight of total composition.

[0119] In some embodiment, the stabilizer b) comprises photo-protectant selected from 2-(2H- Benzotriazol-2-yl)-4,6-bis(l,l-dimethylpropyl)phenol (Tinuvin® 328), bis (1, 2, 2,6,6- pentamethyl-4-piperidinyl)-sebacate, (Tinuvin® 292), poly(oxy-l,2-ethanediyl), a-[3-[3- (2H-benzotriazol-2-yl)-5-(l,l-dimethylethyl)-4-hydroxyphenyl]-l-oxopropyl]-u)-hydroxy (Tinuvin® 1130), 2-[4,6-bis(2,4-dimethylphenyl)-l,3,5-triazin-2-yl]-5-[2-hydroxy-3- (dodecyloxy- and tridecyloxy)propoxy]phenols (Tinuvin® 400), 2-[4,6-Bis(2,4- dimethylphenyl)-l,3,5-triazin-2-yl]-5-[3-[(2-ethylhexyl)oxy]-2-hydroxypropoxy] phenol (Tinuvin® 405), 2,4,6-tris[4-(l-octyloxycarbonyl)ethyloxy-2-hydroxyphenyl]-l,3,5-triazine (Tinuvin® 477), propanoic acid, 2-[4-[4,6-bis([l,l'-biphenyl]-4-yl)-l,3,5-triazin-2-yl]-3- hydroxyphenoxy]-, isooctyl ester (Tinuvin® 479), light stabilizer 5050 (Tinuvin® 5050), decanedioic acid, l,10-bis[2,2,6,6-tetramethyl-l-(octyloxy)-4-piperidinyl] ester, mixt. with octyl 3-(2H-benzotriazol-2-yl)-5-(l,l-dimethylethyl)-4-hydroxybenzenepropanoate (Tinuvin® 5060), 2,2'-[6-(2,4-Dibutoxyphenyl)-l,3,5-triazine-2,4-diyl]bis[5-butoxyphenol] (Tinuvin® 460), UV absorber -tinuvin 5151 (Tinuvin® 5151), triazine based UV absorber (Tinuvin® 5248), benzenepropanoic acid, 3-(2H-benzotriazol-2-yl)-5-(l,l-dimethylethyl)- 4-hydroxy-, 2-ethylhexyl ester (Tinuvin® 384-2), benzenepropanoic acid, 3-(2H- benzotriazol-2-yl)-5-(l,l-dimethylethyl)-4-hydroxy-, C7-9-branched and linear alkyl esters based UV-absorber (Tinuvin® 99-2), phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(l-methyl-l- phenylethyl) (Tinuvin® 900), 1,3,5-Triazine, 2,4,6-tris([l,l'-biphenyl]-4-yl) based UV- absorber (Tinosorb® A2B), phenol, 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(l,l,3,3- tetramethylbutyl) based UV-absorber (Tinosorb® M), phenol, 2,2'-methylenebis[6-(2H- benzotriazol-2-yl)-4-(l,l,3,3-tetramethylbutyl) based UV-absorber (Tinosorb® M-WG), phenol, 2,2'-[6-(4-methoxyphenyl)-l,3,5-triazine-2,4-diyl]bis[5-[(2-ethylhexyl)oxy] based UV-absorber (Tinosorb® S), benzoic acid, 2-[4-(diethylamino)-2-hydroxybenzoyl]-, hexyl ester (Uvinul® A plus), 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-ethylhexyl ester (Uvinul® MC 80), benzoic acid , 4,4',4"-(l,3,5-triazine-2,4,6-triyltriimino)tris-, 1,1',1"- tris(2-ethylhexyl) ester (Uvinul® T 150), zinc oxide (Z-COTE®), zinc oxide and triethoxycaprylylsilane (Z-COTE® HP1), kojic acid and the mixtures thereof.

[0120] In some embodiment, the stabilizer b) comprises photo-protectant is 2-(2H-Benzotriazol- 2-yl)-4,6-bis(l,l-dimethylpropyl)phenol (Tinuvin® 328).

[0121] In some embodiment, the stabilizer b) comprises photo-protectant Bisethylhexyloxyphenol methoxyphenyl triazine (Tinosorb® S).

[0122] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 0.1 to 10% per weight based on the weight of total composition.

[0123] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 9 to 10% per weight based on the weight of total composition.

[0124] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 8 to 9% per weight based on the weight of total composition.

[0125] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 7 to 8% per weight based on the weight of total composition.

[0126] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 6 to 7% per weight based on the weight of total composition. In some embodiment, the amount of thermo-protectant in stabilizer b) is from 5 to 6% per weight based on the weight of total composition.

[0127] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 4 to 5% per weight based on the weight of total composition.

[0128] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 3 to 4% per weight based on the weight of total composition.

[0129] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 2 to 3% per weight based on the weight of total composition.

[0130] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 1 to 2% per weight based on the weight of total composition.

[0131] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 0.1 to 1% per weight based on the weight of total composition.

[0132] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 0.1 to 1.5% per weight based on the weight of total composition.

[0133] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 0.1 to 2% per weight based on the weight of total composition.

[0134] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 0.1 to 2.5% per weight based on the weight of total composition.

[0135] In some embodiment, the amount of thermo-protectant in stabilizer b) is from 0.1 to 5% per weight based on the weight of total composition.

[0136] In some embodiment, the stabilizer b) comprises thermo-protectant selected from: blend of 50% tris(2,4-ditert-butylphenyl)phosphite and 50% pentaerythritol tetrakis[3-[3,5-di- tert-butyl-4-hydroxyphenyl]propionate] (Irganox® B225), Benzenepropanoic acid, 3,5- bis(l,l-dimethylethyl)-4-hydroxy-, l,l'-[2,2-bis[[3-[3,5-bis(l,l-dimethylethyl)-4- hydroxyphenyl]-l-oxopropoxy]methyl]-l,3-propanediyl] ester (Irganox® 1010), didodecyl 3,3’-thiodipropionate (Irganox® 800FL), benzenepropanoic acid, 3-(l,l-dimethylethyl)-4- hydroxy-5-methyl-, l,l'-[l,2-ethanediylbis(oxy-2,l-ethanediyl)] ester (Irganox® 245), benzenepropanoic acid, 3,5-bis(l,l-dimethylethyl)-4-hydroxy-, octadecyl ester (Irganox® 1076), butylated hydroxytoluene (BHT), butylated hydroxyanisole (BHA), epoxol (epoxidize soybean oil) didodecyl 3,3’-thiodipropionate (Irganox® PS 800 FL), 2,4-bis(l, 1- dimethylethyl)phenol phosphite (Irgafos® 168), ascorbic acid, a tocopherol (vitamin E) and the mixtures thereof.

[0137] In some embodiment, the stabilizer b) comprises thermo-protectant is 2,4-bis(l,l- dimethylethyl)phenol phosphite (Irgafos® 168).

[0138] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:5 to 5:1.

[0139] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:4 to 4:1.

[0140] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:3 to 3:1.

[0141] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:2 to 2:1.

[0142] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:2 to 1:1.

[0143] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:1 to 1:1.

[0144] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is from 1:1 to 2:1.

[0145] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is 1:2.

[0146] In some embodiment, the weight ratio of photo-protectant to the thermo-protectant is 2:1. In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 5:1 to 1:20.

[0147] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 1:20.

[0148] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 3:1 to 1:20.

[0149] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 2:1 to 1:20.

[0150] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 1:1 to 1:20.

[0151] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 5:1 to 1:10.

[0152] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 1:10.

[0153] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 3:1 to 1:10.

[0154] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 2:1 to 1:10.

[0155] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 1:1 to 1:10.

[0156] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 5:1 to 1:4.

[0157] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 1:4. In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 3:1 to 1:4.

[0158] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 2:1 to 1:4.

[0159] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 1:1 to 1:4.

[0160] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 5:1 to 1:2.

[0161] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 1:2.

[0162] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 3:1 to 1:2.

[0163] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 2:1 to 1:2.

[0164] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 1:1 to 1:2.

[0165] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 5:1 to 3:4.

[0166] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 3:4.

[0167] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 3:1 to 3:4.

[0168] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 2:1 to 3:4. In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 1:1 to 3:4.

[0169] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 5:1 to 1:1.

[0170] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 1:1.

[0171] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 3:1 to 1:1.

[0172] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 2:1 to 1:1.

[0173] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 1:1 to 1:1.

[0174] In some embodiment, the ratio between stabilizer b) comprising synergistic combination of photo-protectant and thermo-protectant, and pesticide a) is from 4:1 to 5:1.

[0175] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 20:1.

[0176] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 10:1.

[0177] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 5:1.

[0178] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 4:1.

[0179] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 3:1. In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 2:1.

[0180] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:500 to 1:1.

[0181] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:4 to 3:1.

[0182] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:2 to 2:1.

[0183] In some embodiment, the ratio between the photo-protectant and the pesticide is from 1:2 to 3:1.

[0184] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 20:1.

[0185] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 10:1.

[0186] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 5:1.

[0187] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 4:1.

[0188] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 3:1.

[0189] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 2:1.

[0190] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:500 to 1:1. In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:4 to 3:1.

[0191] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:2 to 2:1.

[0192] In some embodiment, the ratio between the thermo-protectant and the pesticide is from 1:2 to 3:1.

[0193] In an embodiment, the present invention provides an agrochemical liquid composition comprising: a) at least one pesticide, selected from insecticides, fungicides, herbicides and the mixtures thereof; b) stabilizer comprising synergistic combination of thermoprotectant and photo-protectant; c) organic solvent; d) non-ionic surfactant; e) anionic surfactant.

[0194] In some embodiment, the at least one pesticide a) in the agrochemical liquid composition is an insecticide.

[0195] In some embodiment, the at least one pesticide a) in the agrochemical liquid composition is a fungicide.

[0196] In some embodiment, the at least one pesticide in the agrochemical liquid composition is an herbicide.

[0197] In certain embodiment, the pesticide a) in the agrochemical liquid composition is selected from the group comprising: abamectin, ivermectin, selamectin, eprinomectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tralomethrin, cyfluthrin, alpha-methrin, zeta-cypermethrin, fenvalerate, esfenvalerate, acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, beta-cyfluthrin, cyhalothrin, beta- cypermethrin, cyphenothrin, empenthrin, etofenprox, fenpropathrin, flucythrinate, tau- fluvalinate, phenothrin, prallethrin, resmethrin, tefluthrin, tetramethrin, lambda- cyhalothrin, spinosad, spinoteram, spinosyn A, spinosyn D. In certain embodiment, the pesticide a) in the agrochemical liquid composition is emamectin, or emamectin benzoate.

[0198] In certain embodiment, the pesticide a) in the agrochemical liquid composition is emamectin benzoate.

[0199] In certain embodiment, the pesticide a) in the agrochemical liquid composition is spinosad, spinoteram, spinosyn A, spinosyn D or combination thereof.

[0200] In certain embodiment, the pesticide a) in the agrochemical liquid composition is spinosad.

[0201] In certain embodiment, the pesticide a) in the agrochemical liquid composition is spinoteram.

[0202] In certain embodiment, the pesticide a) in the agrochemical liquid composition is spinosyn

[0203] A.

[0204] In certain embodiment, the pesticide a) in the agrochemical liquid composition is spinosyn

[0205] D.

[0206] In certain embodiment, the pesticide a) in the agrochemical liquid composition is selected from spinosyn A, spinosyn D or combination thereof.

[0207] In certain embodiment, the pesticide a) in the agrochemical liquid composition is selected from Emamectin benzoate, spinosyn A, spinosyn D or combination thereof.

[0208] In certain embodiment, the agrochemical liquid composition of the present invention could further contain at least one additional pesticide.

[0209] In an embodiment, at least one additional pesticide is selected from allosamidin, thuringiensin, lepimectin, milbemectin, milbemycin oxime, moxidectin, calcium arsenate, copper acetoarsenite, copper arsenate, lead arsenate, potassium arsenite, sodium arsenite, anabasine, azadirachtin, d-limonene, nicotine, pyrethrins, cinerins, cinerin I, cinerin II, jasmolin I, jasmolin II, pyrethrin I, pyrethrin II, quassia, rotenone, ryania, sabadilla, bendiocarb, carbaryl, benfiiracarb, carbofuran, carbosulfan, decarbofuran, furathiocarb, dimitan, dimetilan, hyquincarb, pirimicarb, alanycarb, aldicarb, aldoxycarb, butocarboxim, butoxycarboxim, methomyl, nitrilacarb, oxamyl, tazimcarb, thiocarboxime, thiodicarb, thiofanox, allyxycarb, aminocarb, bufencarb, butacarb, carbanolate, cloethocarb, dicresyl, dioxacarb, EMPC, ethiofencarb, fenethacarb, fenobucarb, isoprocarb, methiocarb, metolcarb, mexacarbate, promacyl, promecarb, propoxur, trimethacarb, XMC, xylylcarb, dinex, dinoprop, dinosam, DNOC, barium hexafluorosilicate, cryolite, sodium fluoride, sodium hexafluorosilicate, sulflurandd; chlordimeform, formetanate, formparanate, acrylonitrile, carbon disulfide, carbon tetrachloride, chloroform, chloropicrin, para-dichlorobenzene, 1,2-dichloropropane, ethyl formate, ethylene dibromide, ethylene dichloride, ethylene oxide, hydrogen cyanide, iodomethane, methyl bromide, methylchloroform, methylene chloride, naphthalene, phosphine, sulfuryl fluoride, tetrachloroethane, borax, calcium polysulfide, copper oleate, mercurous chloride, potassium thiocyanate, sodium thiocyanate, bistrifiuron, buprofezin, chlorfluazuron, cyromazine, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron, epofenonane, fenoxycarb, hydroprene, kinoprene, methoprene, pyriproxyfen, triprene, juvenile hormone I, juvenile hormone II, juvenile hormone HI, chromafenozide, halofenozide, methoxyfenozide, tebufenozide, a- ecdysone, ecdysterone, diofenolan, precocene I, precocene II, precocene HI, dicyclanil, bensultap, cartap, thiocyclam, thiosultap, flonicamid, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, thiacloprid, bromo-DDT, camphechlor, DDT, pp'-DDT, ethyl-DDD, HCH, gamma-HCH, lindane, methoxychlor, pentachlorophenol and TDE, aldrin, bromocyclen, chlorbicyclen, chlordane, chlordecone, dieldrin, dilor, endosulfan, endrin, HEOD, heptachlor, HHDN, isobenzan, isodrin, kelevan, mirex, bromfenvinfos, chlorfenvinphos, crotoxyphos, dichlorvos, dicrotophos, dimethylvinphos, fospirate, heptenophos, methocrotophos, mevinphos, monocrotophos, naled, naftalofos, phosphamidon, propaphos, TEPP, tetrachlorvinphos, dioxabenzofos, fosmethilan, phenthoate, acethion, amiton, cadusafos, chlorethoxyfos, chlormephos, demephion, demephion-O, demephion-S, demeton, demeton-O, demeton-S, demeton-methyl, demeton-O-methyl, demeton-S-methyl, demeton-S-methylsulphon, disulfoton, ethion, ethoprophos, IPSP, isothioate, malathion, methacrifos, oxydemeton- methyl, oxydeprofos, oxydisulfoton, phorate, sulfotep, terbufos, thiometon, aliphatic amide, amidithion, cyanthoate, dimethoate, ethoate-methyl, formothion, mecarbam, omethoate, prothoate, sophamide, vamidothion, oxime, chlorphoxim, phoxim, phoxim-methyl, azamethiphos, coumaphos, coumithoate, dioxathion, endothion, menazon, morphothion, phosalone, pyraclofos, pyridaphenthion, quinothion, dithicrofos, thicrofos, azinphos- ethyl and azinphos-methyl, dialifos, phosmet, isoxathion, zolaprofos, chlorprazophos, pyrazophos, chlorpyrifos, chlorpyrifos-methyl, butathiofos, diazinon, etrimfos, lirimfos, pirimiphos-ethyl, pirimiphos-methyl, primidophos, pyrimitate, tebupirimfos, quinalphos, quinalphos- methyl, atnidathion, lythidathion, methidathion, prothidathion, isazofos, triazophos, azothoate, bromophos, bromophos- ethyl, carbophenothion, chlorthiophos, cyanophos, cythioate, dicapthon, dichlofenthion, etaphos, famphur, fenchlorphos, fenitrothion fensulfothion, fenthion, fenthion-ethyl, heterophos, jcxifenphos, mesulfenfos, parathion, parathion-methyl, phenkapton, phosnichlor, profenofos, prothiofos, sulprofos, temephos, trichlormetaphos-3, trifenofos, butonate, trichlorfon, mecarphon, fonofos, trichloronat, cyanofenphos, EPN, leptophos, crufomate, fenamiphos, fosthietan, imicyafos, mephosfolan.phosfolan, pirimetaphos, acephate, isocarbophos, isofenphos, methamidophos, propetamphos, dimefox, mazidox, mipafox, schradan, indoxacarb, dialifos, phosmet, tetramethrin, acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, tebufenpyrad, tolfenpyrad, vaniliprole, barthrin, bioethanomethrin, cyclethrin, gamma- cyhalothrin, cypermethrin, alpha-cypermethrin, beta- cypermethrin, theta-cypermethrin, dimefluthrin, dimethrin, fenfluthrin, fenpirithrin, fenpropathrin, fluvalinate, furethrin, imiprothrin, metofluthrin, permethrin, biopermethrin, transpermethrin, profluthrin, pyresmethrin, cismethrin, terallethrin, transfluthrin, flufenprox, halfenprox, protrifenbute, silafluofen, flufenerim, pyrimidifen, chlorfenapyr, spirodiclofen, spiromesifen, spirotetramat, diafenthiuron, flucofiiron, sulcofuron, Imicyafos (AKD®- 3088), chlorantraniliprole, closantel, crotamiton, cyflumetofen, fenazaflor, fenazaquin, fenoxacrim, fenpyroximate, FKI®-1033, flubendiamide, cyantraniliprole, hydramethylnon, flonicamid, isoprothiolane, malonoben, metaflumizone, metoxadiazone, nifluridide, NNI®-9850, NNI®-0101, pymetrozine, pyridaben, pyridalyl, pyrifluquinazon, Qcide™, rafoxanide, , SYJ®- 159, triarathene.

[0210] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 50% per weight based on the weight of total composition.

[0211] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 40% to 50% per weight based on the weight of total composition.

[0212] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 30% to 40% per weight based on the weight of total composition.

[0213] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 20% to 30% per weight based on the weight of total composition.

[0214] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 10% to 20% per weight based on the weight of total composition.

[0215] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 10% per weight based on the weight of total composition.

[0216] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 20% per weight based on the weight of total composition. In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 1% per weight based on the weight of total composition.

[0217] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 2% per weight based on the weight of total composition.

[0218] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 2.5% per weight based on the weight of total composition.

[0219] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 1% to 3% per weight based on the weight of total composition.

[0220] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 2% to 4% per weight based on the weight of total composition.

[0221] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 2% to 3% per weight based on the weight of total composition.

[0222] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 5% to 10% per weight based on the weight of total composition.

[0223] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 1% to 2.5% per weight based on the weight of total composition. In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 3% per weight based on the weight of total composition.

[0224] In certain embodiment, the at least one pesticide a) in the agrochemical liquid composition is an amount of from 0.5% to 5% per weight based on the weight of total composition.

[0225] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 10% per weight based on the weight of total composition.

[0226] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 9 to 10% per weight based on the weight of total composition.

[0227] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 8 to 9% per weight based on the weight of total composition.

[0228] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 7 to 8% per weight based on the weight of total composition.

[0229] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 6 to 7% per weight based on the weight of total composition.

[0230] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 5 to 6% per weight based on the weight of total composition.

[0231] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 4 to 5% per weight based on the weight of total composition.

[0232] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 3 to 4% per weight based on the weight of total composition.

[0233] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 2 to 3% per weight based on the weight of total composition. In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 1 to 2% per weight based on the weight of total composition.

[0234] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 1% per weight based on the weight of total composition.

[0235] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 1.5% per weight based on the weight of total composition.

[0236] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 2% per weight based on the weight of total composition.

[0237] In an embodiment, the amount of photo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 2.5% per weight based on the weight of total composition.

[0238] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 10% per weight based on the weight of total composition.

[0239] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 9 to 10% per weight based on the weight of total composition.

[0240] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 8 to 9% per weight based on the weight of total composition.

[0241] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 7 to 8% per weight based on the weight of total composition.

[0242] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 6 to 7% per weight based on the weight of total composition.

[0243] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 5 to 6% per weight based on the weight of total composition. In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 4 to 5% per weight based on the weight of total composition.

[0244] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 3 to 4% per weight based on the weight of total composition.

[0245] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 2 to 3% per weight based on the weight of total composition.

[0246] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 1 to 2% per weight based on the weight of total composition.

[0247] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 1% per weight based on the weight of total composition.

[0248] In an embodiment, the amount of thermo-protectant in stabilizer b) in the agrochemical liquid composition is from 0.1 to 1.5% per weight based on the weight of total composition.

[0249] In an embodiment, the organic solvent c) in the agrochemical liquid composition is selected from the group consisting of aromatic hydrocarbons, aliphatic hydrocarbons, cycloaliphatic hydrocarbons, dimethylsulfoxide (DMSO), N-methylvalerolactam, y- butyrolacton, benzylacetate, benzyl benzoate, butyl benzoate, 2-ethoxypropylacetate, methyl proxitol acetate; tributyl phosphate, N,N-dimethyl octanamide, N,N-dimethyl decanamide; 2-heptanone, cyclohexanone, acetophenone, 4-methoxy acetophenone; cyclohexanol, 4-hydroxy-4-methyl-2-pentanone, n-octanol, 2 ethylhexanol, dimethyl glutarate, dimethyl succinate, dimethyl adipate, polyethylene glycol, glycerol, propylene glycol, dipropylene glycol, propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobuthyl ether propylene glycol monophenyl ether; propylencarbonate, butylene carbonate, N-methyl pyrrolidone, N-butyl pyrrolidone, N- octylpyrrolidone, N-ethyl pyrrolidone, N-dodecyl pyrrolidone, n-propyl lactate, methyl lactate, ethyl lactate, isopropyl lactate, butyl lactate, methyl 5-(dimethylamino)~2-methyl~ 5-oxopentanoate,N,N-Dimethyilactarnide, Altasolv™ M (I ngevity), Altasolv™ H (I ngevity), Altasolv™ L (I ngevity), and the mixtures thereof.

[0250] In an embodiment, the organic solvent c) in the agrochemical liquid composition is selected from the group consisting of Altasolv ™ M(lngevity) , Altasolv ™(lngevity) H, Altasolv™ L(lngevity) and the mixtures thereof.

[0251] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 5% to 95 % per weight based on the weight of total composition.

[0252] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 10% to 95 % per weight based on the weight of total composition.

[0253] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 15% to 95 % per weight based on the weight of total composition.

[0254] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 20% to 95 % per weight based on the weight of total composition.

[0255] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 30% to 95 % per weight based on the weight of total composition.

[0256] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 40% to 95 % per weight based on the weight of total composition.

[0257] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 50% to 95 % per weight based on the weight of total composition.

[0258] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 60% to 95 % per weight based on the weight of total composition.

[0259] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 70% to 95 % per weight based on the weight of total composition.

[0260] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 80% to 95 % per weight based on the weight of total composition. In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 85% to 95 % per weight based on the weight of total composition.

[0261] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 80% to 90 % per weight based on the weight of total composition.

[0262] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 85% to 90 % per weight based on the weight of total composition.

[0263] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 5% to 10 % per weight based on the weight of total composition.

[0264] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 10% to 20 % per weight based on the weight of total composition.

[0265] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 20% to 30 % per weight based on the weight of total composition.

[0266] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 30% to 40 % per weight based on the weight of total composition.

[0267] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 40% to 50 % per weight based on the weight of total composition.

[0268] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 50% to 60 % per weight based on the weight of total composition.

[0269] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 60% to 70 % per weight based on the weight of total composition.

[0270] In an embodiment, the amount of organic solvent c) in the agrochemical liquid composition is from 70% to 80 % per weight based on the weight of total composition.

[0271] In an embodiment, the non-ionic surfactant d) in the agrochemical liquid composition is selected from EO-PO-block copolymers, C4-C18 alcohol alkoxylates, fatty acid alkoxylates, vegetable oil alkoxylates, aryl alkoxylates, alkylaryl alkoxylates, and the mixtures thereof. In an embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 0.5 % to 10 % per weight based on the weight of total composition.

[0272] In an embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 0.5 % to 5 % per weight based on the weight of total composition.

[0273] In an embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 4 % to 5 % per weight based on the weight of total composition.

[0274] In certain embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 3% to 5 % per weight based on the weight of total composition.

[0275] In certain embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 2% to 5 % per weight based on the weight of total composition.

[0276] In certain embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 4% to 4.5 % per weight based on the weight of total composition.

[0277] In certain embodiment, the amount of non-ionic surfactant d) in the agrochemical liquid composition is from 4.2% per weight based on the weight of total composition.

[0278] In an embodiment, the anionic surfactant e) in the agrochemical liquid composition is selected from naphthalene sulfonates, alkylnaphthalene sulfonates, benzene sulfonates, alkylbenzene sulfonates, C4-C18 alcohol ethoxylated phosphates, C4-C16 alkyl phosphate esters, sodium sulfosuccinate C1-C8 alkyl esters, sodium sulfosuccinate C1-C8 dialkyl esters, and the mixtures thereof.

[0279] In an embodiment, the anionic surfactant e) in the agrochemical liquid composition is selected from naphthalene sulfonates, alkylnaphthalene sulfonates, benzene sulfonates, alkylbenzene sulfonates and the mixtures thereof.

[0280] In an embodiment, the anionic surfactant e) in the agrochemical liquid composition is selected from C4-C18 alcohol ethoxylated phosphates, C4-C16 alkyl phosphate esters, and the mixtures thereof. In an embodiment, the anionic surfactant e) in the agrochemical liquid composition is selected from sodium sulfosuccinate C1-C8 alkyl esters, sodium sulfosuccinate C1-C8 dialkyl esters, and the mixtures thereof.

[0281] In an embodiment, the amount of anionic surfactant e) in the agrochemical liquid is from 0.5 % to 10 % per weight based on the weight of total composition.

[0282] In an embodiment, the amount of anionic surfactant e) in the agrochemical liquid composition is from 0.5 % to 5 % per weight based on the weight of total composition.

[0283] In an embodiment, the amount of anionic surfactant e) in the agrochemical liquid composition is from 4 % to 5 % per weight based on the weight of total composition.

[0284] In certain embodiment, the amount of anionic surfactant e) in the agrochemical liquid composition is from 3% to 5 % per weight based on the weight of total composition.

[0285] In certain embodiment, the amount of anionic surfactant e) in the agrochemical liquid composition is from 2% to 5 % per weight based on the weight of total composition.

[0286] In certain embodiment, the amount of anionic surfactant e) in the agrochemical liquid composition is from 4% to 4.5 % per weight based on the weight of total composition.

[0287] In certain embodiment, the amount of anionic surfactant e) in the agrochemical liquid composition is from 4.2% per weight based on the weight of total composition.

[0288] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 5:1 to 1:20.

[0289] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 4:1 to 1:20.

[0290] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 3:1 to 1:20. In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 2:1 to 1:20.

[0291] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:1 to 1:20.

[0292] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 5:1 to 1:10.

[0293] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 4:1 to 1:10.

[0294] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 3:1 to 1:10.

[0295] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 2:1 to 1:10.

[0296] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:1 to 1:10.

[0297] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 5:1 to 1:4.

[0298] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 4:1 to 1:4.

[0299] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 3:1 to 1:4.

[0300] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 2:1 to 1:4.

[0301] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:1 to 1:4. In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 5:1 to 1:2.

[0302] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 4:1 to 1:2.

[0303] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 3:1 to 1:2.

[0304] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 2:1 to 1:2.

[0305] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:1 to 1:2.

[0306] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 5:1 to 3:4.

[0307] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 4:1 to 3:4.

[0308] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 3:1 to 3:4.

[0309] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 2:1 to 3:4.

[0310] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:1 to 3:4.

[0311] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 5:1 to 1:1.

[0312] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 4:1 to 1:1. In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 3:1 to 1:1.

[0313] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 2:1 to 1:1.

[0314] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:1 to 1:1.

[0315] In an embodiment, the ratio between stabilizer b) and pesticide a) in the agrochemical liquid composition is from 6:5 to 3:2.

[0316] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:500 to 500:1.

[0317] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:400 to 400:1.

[0318] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:300 to 300:1.

[0319] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:200 to 200:1.

[0320] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:100 to 100:1.

[0321] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:50 to 50:1.

[0322] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:20 to 20:1.

[0323] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:10 to 10:1. In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:5 to 5:1.

[0324] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:4 to 4:1.

[0325] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:3 to 3:1.

[0326] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:2 to 2:1.

[0327] In an embodiment, the ratio between photo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:2 to 1:1.

[0328] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:500 to 500:1.

[0329] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:400 to 400:1.

[0330] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:300 to 300:1.

[0331] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:200 to 200:1.

[0332] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:100 to 100:1.

[0333] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:50 to 50:1.

[0334] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:20 to 20:1. In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:10 to 10:1.

[0335] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:5 to 5:1.

[0336] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:4 to 4:1.

[0337] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:3 to 3:1.

[0338] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:2 to 2:1.

[0339] In an embodiment, the ratio between thermo-protectant in stabilizer b) and pesticide a) in the agrochemical liquid composition is from 1:2 to 1:1.

[0340] In an embodiment, the weight ratio between the non-ionic surfactant d) and anionic surfactant e) in the agrochemical liquid composition is from 1:5 to 5:1.

[0341] In certain embodiment, the weight ratio between the non-ionic surfactant d) and anionic surfactant e) in the agrochemical liquid composition is from 1:4 to 4:1.

[0342] In an embodiment, the weight ratio between the non-ionic surfactant d) and anionic surfactant e) in the agrochemical liquid composition is from 1:3 to 4:1.

[0343] In an embodiment, the weight ratio between the non-ionic surfactant d) and anionic surfactant e) in the agrochemical liquid composition is from 1:2 to 2:1.

[0344] In an embodiment, the weight ratio between the non-ionic surfactant d) and anionic surfactant e) in the agrochemical liquid composition is from 1:1 to 1:1.

[0345] In an embodiment, the weight ratio between the non-ionic surfactant d) and anionic surfactant e) in the agrochemical liquid composition is 1:1. In an embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:50 to 5:1.

[0346] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:50 to 4:1.

[0347] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:50 to 3:1.

[0348] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:50 to 2:1.

[0349] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:20 to 2:1.

[0350] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:10 to 2:1.

[0351] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:5 to 2:1.

[0352] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:10 to 2:1.

[0353] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 2:5 to 2:1.

[0354] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 1:1 to 2:1.

[0355] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is from 2:1 to 5:2.

[0356] In certain embodiment, the weight ratio between the non-ionic surfactant d) and pesticide a) in the agrochemical liquid composition is 2:1. In an embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:50 to 5:1.

[0357] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:50 to 4:1.

[0358] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:50 to 3:1.

[0359] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:50 to 2:1.

[0360] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:20 to 2:1.

[0361] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:10 to 2:1.

[0362] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:5 to 2:1.

[0363] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:10 to 2:1.

[0364] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 2:5 to 2:1.

[0365] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 1:1 to 2:1.

[0366] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is from 2:1 to 5:2.

[0367] In certain embodiment, the weight ratio between the anionic surfactant e) and pesticide a) in the agrochemical liquid composition is 2:1. In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:20 to 5:1.

[0368] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:20 to 4:1.

[0369] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:20 to 3:1.

[0370] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:20 to 2:1.

[0371] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:20 to 1:1.

[0372] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:10 to 5:1.

[0373] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:10 to 4:1.

[0374] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:10 to 3:1.

[0375] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:10 to 2:1.

[0376] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:10 to 1:1.

[0377] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:2 to 5:1.

[0378] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:2 to 4:1. In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:2 to 3:1.

[0379] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:2 to 2:1.

[0380] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is from 1:2 to 1:1.

[0381] In certain embodiment, the weight ratio between the solvent c) and pesticide a) in the agrochemical liquid composition is 1:1.

[0382] In an embodiment, the present invention provides the use of synergistic combination of thermo-protectant and photo-protectant for stabilization of agrochemical composition comprising at least one pesticide selected from insecticide, fungicide, herbicides and the mixtures thereof.

[0383] In an embodiment, the present invention provides the use of synergistic combination of thermo-protectant and photo-protectant as disclosed herein for stabilization of agrochemical liquid compositions as disclosed herein.

[0384] Examples are provided below to impede a more complete understanding of the present subject matter. The following examples illustrate the exemplary modes of making and practicing the present invention. However, the scope of the present invention is not limited to specific embodiments disclosed in these Examples, which are for purposes of illustration only. Other examples will be apparently constructed by one skilled in the art from consideration of the specification embodiments and examples.

[0385] EXAMPLES:

[0386] Example 1: The performance of neat emulsion concentrate compositions containing 2.11 % (w / w) per weight of emamectin benzoate and different photo and / or thermosprotectants prepared according to Table 1 was evaluated. The neat emulsion concentrate samples were not diluted in water before performing the test. Table 1. Emulsion concentrates containing different photo and / or thermo- protectants:

[0387] Active ingredient * is Emamectin benzoate or Spinosad

[0388] Emamectin benzoate is commercially available or can be prepared as disclosed by Trefzer A et al. Appl. Environ. Microbiol. 2007;73: pp 4317-4325. Spinosad is commercially available or can be prepared as disclosed in US 5,362,634 and US 5,496,931.

[0389] The following compositions were prepared as representative examples of general Table 1:

[0390] Example 1A: Emamectin benzoate 2.11% w / w emulsion concentrate

[0391] Example IB: Spinosad 2.11% w / w emulsion concentrate

[0392] Photo degradation measurements:

[0393] Samples of Emamectin emulsion concentrates prepared according to Table 1 containing different photo or thermo-protectants (20g) were inserted into a 40 mL glass vial. The sealed vials were placed in a circular position in a UV chamber UVACUBE 400 (Honle - UV technology) equipped with S-lamp (sunlight simulation). The tested samples were exposed to light for 6 h and the concentrations of Emamectin benzoate after the exposure were determined using HPLC. For each experiment, samples from the same batch were kept in dark and tested for comparison.

[0394] Thermal degradation measurements:

[0395] Samples of Emamectin emulsion concentrates prepared according to Table 1 containing different photo- or thermo-protectants (15g) were inserted into a 20 mL sealed glass vial. The vials were kept in an oven under constant temperature of 54°C for 14 days. The concentration of Emamectin benzoate after 14 days was determined using HPLC. For each experiment, samples from the same batch were kept in room temperature and tested for comparison. For all samples, degradation of sensitive active ingredient (Emamectin benzoate) concentration was calculated according to the following equation:

[0396] Co - is the concentration of Emamectin benzoate after 6 hours in dark (for photo degradation) or the concentration of Emamectin benzoate after 14 days at room temperature (for thermal degradation)

[0397] Cf - is the final concentration of Emamectin benzoate after exposure to thermal or photo degradation.

[0398] The results are summarized in Table 2.

[0399] Table 2: Photo and thermal degradation studies of Emamectin benzoate (2.11 % wM emulsion concentrates prepared according to Table 1.

[0400] It is shown that Emamectin benzoate photodegradation decreased by a factor of 3.64, 3.64, 3.0, 3.21 and 3.94 for Tinuvin® 328, Tinuvin® 1130, Tinuvin® 405, Tinuvin® 5050 and Tinuvin® 460, respectively, compared to the degradation obtained without any photo protectant, no decrease established in the samples containing thermo-protectants only . Photodegradation decrease factor was calculated as follows:

[0401] Photodegradation decrease factor - degradation (in %) of emamectin benzoate after 6 hours exposure to sunlight without photo protectant / degradation (in %) of emamectin benzoate after 6 hours exposure to sunlight with photo protectant.

[0402] Emamectin benzoate thermal degradation decreased by a factor 3.98, 2.75, and 9.32 for Irganox® B225, Irganox® PS 800 FL and Irgafos® 168, respectively, compared to the degradation obtained without any thermo-protectant, no decrease established in the samples containing photo-protectants only.

[0403] Thermal degradation factor was calculated as follows:

[0404] Thermal degradation factor - degradation (in %) of emamectin benzoate after 14 days at 54 °C without thermos-protectant / degradation (in %) of emamectin benzoate after 14 days at 54 °C with thermal protectant.

[0405] Example 2: Photo degradation of 2.11 % w / w Emamectin benzoate emulsion concentrate diluted in water 10% (w / w) using Tinuvin® 328 as photo protectant.

[0406] The performance of Tinuvin® 328 as photo protectant using the same protocol described above in Example 1 was evaluated for Emamectin benzoate emulsion concentrate diluted in water 10% (w / w) and summarized in Table 3. Each measurement was taken as an average of 5 repetitions (1A-1E), (2A-2E). Table 3. Photo degradation of 2.11 % VJ / VJ Emamectin benzoate emulsion concentrate diluted in water 10% (w / w) using Tinuvin® 328 as photo protectant.

[0407] As shown above in Table 3, for Emamectin benzoate emulsion concentrate diluted in water as 10% (w / w), 1% Tinuvin 328 reduced photodegradation of Emamectin benzoate by a factor of 4.38, compared to the degradation obtained without any photo protector.

[0408] Example 3. Photo degradation and thermal degradation of 2.11 % w / w emulsion concentrate of Emamectin benzoate (within a sealed glass vial) containing combinations of Tinuvin® 328 and Irgafos® 168.

[0409] Various compositions of 2.11% w / w Emamecting benzoate prepared according to Table 1, containing both Tinuvin® 328 (photo protectant) and Irgafos® 168 (thermo-protectant) were prepared, and the effect of the presence of both photo and thermo-protectants on photo and thermal degradation was tested and summarized in Table 4. Thermal degradation was tested on the neat emulsion concentrate of 2.11 % w / w of emamectin benzoate and photodegradation on 2.11% w / w of emamectin benzoate emulsion concentrate diluted in water as 10% (w / w).

[0410] Table 4. Effect of different combinations of Tinuvin® 328 (photo-protectant) and lrgafos®168 (thermo-protectant) on photo and thermal degradation of Emamectin benzoate.

[0411] As shown above, the presence of both Tinuvin® 328 and Irgafos® 168 resulted in surprisingly high factors of reduction of the photodegradation and thermal degradation of emamectin benzoate compared to the degradation obtained without the combination of said photo and thermo-protectants.

[0412] Photo and thermal degradation factors were calculated according to the Example 1.

[0413] Example 4. Synergy of Tinuvin® 328 and Irgafos® 168 combination (6 hours sunlight exposure) for Emamectin benzoate.

[0414] Photodegradation of Emamectin benzoate 2.11 % w / w emulsion concentrates prepared according to Table 1 and diluted in water as 10% (w / w) emulsion was evaluated for 6 hours of exposure to sunlight according to procedures described in Example 1. Table 5 summarizes the results of this study. Photodegradation factors were calculated according to the Example 1. Table 5. Synergy of Tinuvin® 328 and Irgafos® 168 combination (6 hours sunlight exposure) for Emamectin benzoate

[0415] Example 5. Synergy of Tinuvin® 328 and Irgafos® 168 combination (24 hours sunlight exposure) for Emamectin benzoate Photodegradation of Emamectin benzoate 2.11 % w / w emulsion concentrates prepared according to Table 1 and diluted in water as 10% (w / w) emulsion was evaluated for 24 hours of exposure to sunlight according to procedures described in Example 1. Table 6 summarizes the results of this study. Photodegradation factors were calculated according to the Example 1. Table 6. Synergy of Tinuvin ®328 and Irgafos® 168 combination for Emamectin benzoate

[0416] (24 hours sunlight exposure)

[0417] Example 6. Synergy of Tinuvin® 328 and Irgafos® 168 combination for Spinosad (24 hours sunlight exposure) Photodegradation of Spinosad 2.11 % w / w emulsion concentrates prepared according to Table 1 and diluted in water as 10% (w / w) emulsion was evaluated for 24 hours of exposure to sunlight according to procedures described in Example 1. Table 7 summarizes the results of this study. Photodegradation factors were calculated according to the Example 1.

[0418] Table 7. Synergy of Tinuvin® 328 and Irgafos® 168 combination for Spinosad (24 hours sunlight exposure)

[0419] Example 7. Tinuvin® 328 and Irgafos® 168 combination for Emamectin benzoate (6 hours sunlight exposure) in a dried sample

[0420] All photodegradation experiments represented as Examples 1-6 were performed with a glass vial using 20g of emulsion or neat formulation as described above. For simulation of the experiments to photodegradation which takes place on the foliage of treated plants, the following set up was established.

[0421] 2 g samples of Emamectin benzoate 2.11 % w / w emulsion concentrates prepared according to Table 1 and diluted in water as 10% (w / w) emulsion were placed in 100 mL glass beakers. The beakers were placed in a circular position in a UV chamber UVACUBE 400 (Honle - UV technology) equipped with S-lamp (sunlight simulation). The emulsion samples were completely dried creating a thin film at the bottom of the beaker. The samples were exposed to sunlight for 6 hours, and the Emamectin benzoate content of the thin film on the bottom of the beakers was extracted with Acetonitrile. The amount of Emamectin benzoate after the exposure to sunlight (mf) [mg] was determined using HPLC. For each experimental group, samples from the same batch that were kept in dark were also tested to determine the amount of Emamectin benzoate without exposure to light (mo). Photodegradation factors were calculated according to the Example 1.

[0422] For all tested samples, photodegradation % was calculated according to the following equation: m0- mf%Deg = 100% x — - - m0

[0423] Table 8 below summarizes the results of Example 7.

[0424] Table 8. Tinuvin 328 and Irgafos 168 combination for Emamectin benzoate (6 hours sunlight exposure) in a dried sample

[0425] As represented above, the combination of Tinuvin® 328 and Irgafos® 168 (photo protectant and thermo-protectant) show improved photoprotection including liquid and dried samples, wherein synergistic effect is observed for certain ratio of photo protectant and thermo-protectant.

[0426] Example 8. Synergy of Tinosorb® S and Irgafos® 168 combination (24 hours sunlight exposure) for Emamectin benzoate The following compositions 8A-8D summarized in Table 9 were prepared as representative examples of general Table 1:

[0427] Table 9: Emamectin benzoate 2.11% w / w emulsion concentrate with Tinosorb S as photo protectant In this experiment, the Synergy of Irgafos® 168 and Tinosorb® S (Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) was evaluated

[0428] Photodegradation of Emamectin benzoate emulsion concentrates prepared according to Table 9 and diluted in water as 10% (w / w) emulsion was evaluated for 24 hours of exposure to sunlight according to procedures described in Example 1. Table 10 summarizes the results of this study. Each measurement was taken as an average of 4 repetitions. Photodegradation factors were calculated as described in Example 1.

[0429] Table 10. Synergy of TINOSORB ®S and Irgafos® 168 combination for Emamectin benzoate (24 hours sunlight exposure)

[0430] As represented above, the combination of TINOSORB ®S and Irgafos® 168 (photo protectant and thermo-protectant) show improved photoprotection, synergistic effect is observed for certain ratio of photo protectant and thermo-protectant similar to the synergistic effect obtained for Tinuvin® 328 and Irgafos® 168. Indicating, that the described phenomenon is not districted to a specific photo-protectant and thermoprotectant blend.

[0431] Example 9. Synergy of TINOSORB® S and Irganox® 245 combination (26 hours sunlight exposure) for Emamectin benzoate and spinosad

[0432] Photodegradation of Emamectin benzoate and Spinosad emulsion concentrates prepared according to Table 11 and diluted in water as 5% (w / w) emulsion was evaluated for 26 hours of exposure to sunlight according to procedures described in Example 1. Table 12 summarizes the results of this study. Each measurement was taken as an average of 2 repetitions. Photodegradation factors were calculated as described in Example 1.

[0433] Table 11: Emamectin benzoate 2% w / w and Spinosad 10 % emulsion concentrate Table 12. Synergy of TINOSORB® S and Irganox® 245 combination (26 hours sunlight exposure) for Emamectin benzoate and spinosad

[0434] Example 10. Synergy of TINOSORB® S and Irganox® 245 combination (24h direct sunlight exposure) for Emamectin benzoate and Spinosad in a dried sample 2 g samples of Emamectin benzoate and Spinosad emulsion concentrates prepared according to Table 11 and diluted in water as 5% (w / w) emulsion were placed in 100 mL glass beakers. The beakers were exposed to direct sunlight for 24 h (May, South Israel). The emulsion samples were completely dried creating a thin film at the bottom of the beaker. After 24h, the Emamectin benzoate and Spinosad content of the thin film on the bottom of the beakers was extracted with Acetonitrile.

[0435] All above photodegradation experiments represented as Examples 8-10 were performed with a UV chamber UVACUBE 400 (Honle - UV technology) equipped with S-lamp (sunlight simulation). To simulate the photodegradation conditions as much a possible to the actual photodegradation occurred on the leaf surface, Example 10 was conducted. Table 13 summarizes the results of Example 10. Each measurement was taken as an average of 7 repetitions. Photodegradation % were calculated as described in Example 7 (for dried samples). Photodegradation factors were calculated as described in Example 1.

[0436] Table 13. Synergy of TINOSORB® S and Irganox® 245 combination (24h direct sunlight exposure) for Emamectin benzoate and Spinosad in a dried sample

[0437] As represented above, the combination of TINOSORB ®S and Irganox® 245 (photo protectant and thermo-protectant) show improved photoprotection compared to the photoprotection obtained by each component by itself, for both liquid or dry samples and simulate or direct sunlight exposure. These results also reinforce that the described phenomenon is not districted to a specific formulation composition.

Claims

Claims:

1. Photoprotective and thermo-protective agrochemical composition comprising: a) at least one pesticide in an amount of from 0.5% to 50 % per weight based on the weight of total composition; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant.

2. Photoprotective and thermo-protective agrochemical composition according to claim 1 wherein the at least one pesticide a) is selected from insecticides, fungicides, herbicides and the mixtures thereof.

3. Photoprotective and thermo-protective agrochemical composition according to any of claims 1, 2 wherein the amount of photo-protectant in stabilizer b) is from 0.1 to 10% per weight based on the weight of total composition.

4. Photoprotective and thermo-protective agrochemical composition according to any of claims 1- 3 wherein the amount of thermo-protectant in stabilizer b) is from 0.1 to 10% per weight based on the weight of total composition.

5. Photoprotective and thermo-protective agrochemical composition according to any of claims 1- 4 wherein the ratio between stabilizer b) and pesticide a) is from 5:1 to 1:20.

6. Photoprotective and thermo-protective agrochemical composition according to any of claims 1-5 wherein the pesticide a) is an insecticide selected from the group comprising: abamectin, ivermectin, selamectin, eprinomectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tralomethrin, cyfluthrin, alpha-methrin, zeta-cypermethrin, fenvalerate, esfenvalerate, acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, beta-cyfluthrin, cyhalothrin, beta-cypermethrin, cyphenothrin, empenthrin, etofenprox, fenpropathrin, flucythrinate, tau-fluvalinate, phenothrin, prallethrin, resmethrin, tefluthrin, tetramethrin, lambda-cyhalothrin, spinosad, spinoteram, spinosyn A, spinosyn D.

7. Photoprotective and thermo-protective agrochemical composition according to any of claims 1-6, wherein the stabilizer b) comprises photo-protectant selected from 2-(2H- Benzotriazol-2-yl)-4,6-bis(l,l-dimethylpropyl)phenol (Tinuvin® 328), bis (1, 2, 2,6,6- pentamethyl-4-piperidinyl)-sebacate, (Tinuvin® 292), poly(oxy-l,2-ethanediyl), a-[3-[3- (2H-benzotriazol-2-yl)-5-(l,l-dimethylethyl)-4-hydroxyphenyl]-l-oxopropyl]-u)-hydroxy (Tinuvin® 1130), 2-[4,6-bis(2,4-dimethylphenyl)-l,3,5-triazin-2-yl]-5-[2-hydroxy-3- (dodecyloxy- and tridecyloxy)propoxy]phenols (Tinuvin® 400), 2-[4,6-Bis(2,4- dimethylphenyl)-l,3,5-triazin-2-yl]-5-[3-[(2-ethylhexyl)oxy]-2-hydroxypropoxy] phenol (Tinuvin® 405), 2,4,6-tris[4-(l-octyloxycarbonyl)ethyloxy-2-hydroxyphenyl]-l,3,5-triazine (Tinuvin® 477), propanoic acid, 2-[4-[4,6-bis([l,l'-biphenyl]-4-yl)-l,3,5-triazin-2-yl]-3- hydroxyphenoxy]-, isooctyl ester (Tinuvin® 479), light stabilizer 5050 (Tinuvin® 5050), decanedioic acid, l,10-bis[2,2,6,6-tetramethyl-l-(octyloxy)-4-piperidinyl] ester, mixt. with octyl 3-(2H-benzotriazol-2-yl)-5-(l,l-dimethylethyl)-4-hydroxybenzenepropanoate (Tinuvin® 5060), 2,2'-[6-(2,4-Dibutoxyphenyl)-l,3,5-triazine-2,4-diyl]bis[5-butoxyphenol] (Tinuvin® 460), UV absorber -tinuvin 5151 (Tinuvin® 5151), triazine based UV absorber (Tinuvin® 5248), benzenepropanoic acid, 3-(2H-benzotriazol-2-yl)-5-(l,l-dimethylethyl)- 4-hydroxy-, 2-ethylhexyl ester (Tinuvin® 384-2), benzenepropanoic acid, 3-(2H- benzotriazol-2-yl)-5-(l,l-dimethylethyl)-4-hydroxy-, C7-9-branched and linear alkyl esters based UV-absorber (Tinuvin® 99-2), phenol, 2-(2H-benzotriazol-2-yl)-4,6-bis(l-methyl-l- phenylethyl) (Tinuvin® 900), 1,3,5-Triazine, 2,4,6-tris([l,l'-biphenyl]-4-yl) based UV- absorber (Tinosorb® A2B), phenol, 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(l,l,3,3- tetramethylbutyl) based UV-absorber (Tinosorb® M), phenol, 2,2'-methylenebis[6-(2H- benzotriazol-2-yl)-4-(l,l,3,3-tetramethylbutyl) based UV-absorber (Tinosorb® M-WG), phenol, 2,2'-[6-(4-methoxyphenyl)-l,3,5-triazine-2,4-diyl]bis[5-[(2-ethylhexyl)oxy] based UV-absorber (Tinosorb® S), benzoic acid, 2-[4-(diethylamino)-2-hydroxybenzoyl]-, hexyl ester (Uvinul® A plus), 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-ethylhexyl ester (Uvinul® MC 80), benzoic acid , 4,4',4"-(l,3,5-triazine-2,4,6-triyltriimino)tris-, 1,1',1"- tris(2-ethylhexyl) ester (Uvinul® T 150), zinc oxide (Z-COTE®), zinc oxide and triethoxycaprylylsilane (Z-COTE® HP1) and the mixtures thereof.

8. Photoprotective and thermo-protective agrochemical composition according to any of claims 1-7, wherein the stabilizer b) comprises thermo-protectant selected from: blend of 50% tris(2,4-ditert-butylphenyl)phosphite and 50% pentaerythritol tetrakis[3-[3,5-di-tert- butyl-4-hydroxyphenyl]propionate] (Irganox® B225), Benzenepropanoic acid, 3,5-bis(l,l- dimethylethyl)-4-hydroxy-, l,l'-[2,2-bis[[3-[3,5-bis(l,l-dimethylethyl)-4-hydroxyphenyl]- l-oxopropoxy]methyl]-l,3-propanediyl] ester (Irganox® 1010), didodecyl 3,3’- thiodipropionate (Irganox® 800FL), benzenepropanoic acid, 3-(l,l-dimethylethyl)-4- hydroxy-5-methyl-, l,l'-[l,2-ethanediylbis(oxy-2,l-ethanediyl)] ester (Irganox® 245), benzenepropanoic acid, 3,5-bis(l,l-dimethylethyl)-4-hydroxy-, octadecyl ester (Irganox® 1076), butylated hydroxytoluene (BHT), butylated hydroxyanisole (BHA), epoxol (epoxidize soybean oil), didodecyl 3,3’-thiodipropionate (lrganox®PS 800 FL), 2,4-bis(l,l- dimethylethyl)phenol phosphite (3:1) (Irgafos® 168) and the mixtures thereof.

9. Photoprotective and thermo-protective agrochemical composition according to any of claims 1-8, wherein the weight ratio of photo-protectant to the thermo-protectant is from 1:5 to 5:1.

10. An agrochemical liquid composition comprising: a) at least one pesticide, selected from insecticides, fungicides, herbicides and the mixtures thereof; b) stabilizer comprising synergistic combination of thermo-protectant and photo-protectant; c) organic solvent; d) non-ionic surfactant; e) anionic surfactant.

11. The agrochemical liquid composition according to claim 10, wherein the organic solvent c) is selected from the group comprising aromatic hydrocarbons, aliphatic hydrocarbons, cycloaliphatic hydrocarbons, dimethylsulfoxide (DMSO), N- methylvalerolactam, y-butyrolacton, benzylacetate, benzyl benzoate, butyl benzoate, 2- ethoxypropylacetate, methyl proxitol acetate; tributyl phosphate, N,N-dimethyl octanamide, N,N-di methyl decanamide; 2-heptanone, cyclohexanone, acetophenone, 4- methoxy acetophenone; cyclohexanol, 4-hydroxy-4-methyl-2-pentanone, n-octanol, 2 ethylhexanol, dimethyl glutarate, dimethyl succinate dimethyl adipate, polyethylene glycol, glycerol, propylene glycol, dipropylene glycol, propylene glycol monomethyl etheracetate, dipropylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobuthyl ether propylene glycol monophenyl ether; propylencarbonate, butylene carbonate, N-butyl pyrrolidone, N- octylpyrrolidone, N-ethyl pyrrolidone, N-dodecyl pyrrolidone, n-propyl lactate, methyl lactate, ethyl lactate, isopropyl lactate, butyl lactate, Altasolv™ M , Altasolv™ H, Altasolv ™ L and the mixtures thereof.

12. The agrochemical liquid composition according to any of claims 10, 11, wherein the non-ionic surfactant d) is selected from EO-PO-block copolymers, C4-C18 alcohol alkoxylates, fatty acid alkoxylates, vegetable oil alkoxylates, aryl alkoxylates, alkylaryl alkoxylates, and the mixtures thereof.

13. The agrochemical liquid composition according to any of claims 10-12, wherein the anionic surfactant e) is selected from naphthalene sulfonates, alkylnaphthalene sulfonates, benzene sulfonates, alkylbenzene sulfonates, C4-C18 alcohol ethoxylated phosphates, C4-C16 alkyl phosphate esters, sodium sulfosuccinate C1-C8 alkyl esters, sodium sulfosuccinate C1-C8 dialkyl esters, and the mixtures thereof.

14. The agrochemical liquid composition according to any of claims 10-13, wherein the amount of photo-protectant in stabilizer b) is from 0.1 to 10% per weight based on the weight of total composition.

15. The agrochemical liquid composition according to any of claims 10-14, wherein the amount of thermo-protectant in stabilizer b) is from 0.1 to 10% per weight based on the weight of total composition.

16. The agrochemical liquid composition according to any of claims 10-15, wherein the ratio between stabilizer b) and pesticide a) is from 5:1 to 1:20.

17. The agrochemical liquid composition according to any of claims 10-16, wherein the pesticide a) is insecticide selected from the group comprising: abamectin, ivermectin, selamectin, eprinomectin, doramectin, emamectin, emamectin benzoate, deltamethrin,tralomethrin, cyfluthrin, alpha-methrin, zeta-cypermethrin, fenvalerate, esfenvalerate, acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, beta- cyfluthrin, cyhalothrin, beta-cypermethrin, cyphenothrin, empenthrin, etofenprox, fenpropathrin, flucythrinate, tau-fluvalinate, phenothrin, prallethrin, resmethrin, tefluthrin, tetramethrin, lambda-cyhalothrin, spinosad, spinoteram, spinosyn A, spinosyn D.

18. The agrochemical liquid composition according to any of claims 10-17, wherein the amount of organic solvent c) is from 5% to 95 % per weight based on the weight of total composition.

19. The agrochemical liquid composition according to any of claims 10-18, wherein the amount of non-ionic surfactant d) is from 0.5 % to 10 % per weight based on the weight of total composition.

20. The agrochemical liquid composition according to any of claims 10-19, wherein the amount of anionic surfactant e) is from 0.5 % to 10 % per weight based on the weight of total composition.

21. The agrochemical liquid composition according to any of claims 10-20, wherein the weight ratio between the non-ionic surfactant d) and anionic surfactant e) is from 1:5 to 5:1.

22. The agrochemical liquid composition according to any of claims 10-21, wherein the weight ratio between the non-ionic surfactant d) and pesticide a) is from 1:50 to 5:1.

23. The agrochemical liquid composition according to any of claims 10-22, wherein the weight ratio between the anionic surfactant e) and pesticide a) is from 1:50 to 5:1.

24. The agrochemical liquid composition according to any of claims 10-23, wherein the amount of pesticide a) is from 0.5% to 50 % per weight based on the weight of total composition.

25. The agrochemical liquid composition according to any of claims 10-24, wherein the pesticide a) is insecticide selected from the group comprising: abamectin, ivermectin, selamectin, eprinomectin, doramectin, emamectin, emamectin benzoate, deltamethrin, tralomethrin, cyfluthrin, alpha-methrin, zeta-cypermethrin, fenvalerate, esfenvalerate, acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprothrin, beta- cyfluthrin, cyhalothrin, beta-cypermethrin, cyphenothrin, empenthrin, etofenprox, fenpropathrin, flucythrinate, tau-fluvalinate, phenothrin, prallethrin, resmethrin, tefluthrin, tetramethrin, lambda-cyhalothrin, spinosad, spinoteram, spinosyn A, spinosyn D.

26. Use of synergistic combination of thermo-protectant and photo-protectant for stabilization of agrochemical composition comprising at least one pesticide selected from insecticide, fungicide, herbicides and the mixtures thereof.

27. Use according to claim 26, wherein the agrochemical composition is the composition according to any of claims 1-9.

28. Use according to claim 26, wherein the agrochemical composition is the agrochemical liquid composition according to any of claims 10-25.

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