Battery self-discharge current measurement and monitoring with parallel cell group

Abstract

Methods and apparatuses are provided for measuring self-discharge current / sd of cells and for using differential self-discharge current of paralleled cells as a quality control (QC) criterion. For cells in a group that are connected in parallel, current / b#, which represents the current through the corresponding cell# in the group, may be measured, and self-discharge current of at least one cell (denoted as / sd#): may be calculated based on a corresponding / b# in Various ways depending on whether the group of cells are connected to a power supply and which kind of power supply. The current / b# may be used as a standard for cell quality judgment and / or cell classification, which is simpler, faster and cheaper than using self-discharge current as a QC criterion.

Description

APPLICATION FOR PATENTTitle: Battery Self-Discharge Current Measurement and Monitoring with Parallel Cell GroupInventor:College Station, TXApplicant: Chaojiong ZhangCollege Station, TXBattery Self-Dis charge Current Measurement and Monitoring with Parallel Cell GroupCROSS-REFERENCE TO RELATED APPLICATIONS[00011 This application claims priority to and the benefit of U .S. Provisional Patent Application Nos. 63 / 662,192 filed 20 June 2024 titled "Galvanostatic Battery Self-Discharge Current Measurement and Self- Discharge Measurement / Monitoring with Parallel Cell Group;163 / 633,789 filed 14 April 2024 titled "Using Current of Cells in a Parallel Battery Group at Open-Circuit Condition as a QC Method," 63 / 571 ,581 filed 29 March 2024 titled "Using Current of Cells in a Parallel Battery Group at Ope n-Circuit Condition as a QC Method;’ 63 / 560,645 filed 02 March 2024 titled “Measuring Self-Discharge of Batteries;1and International Pat ent Application No. PCT / US2023 / 081285 filed on 28 November 2023 titled “Analyzer and Method forDetermining Self-Discharge of Batteries;1each of which is incorporated by reference in its entirety for all purposes. This application is related to the present inventor's International Patent Application No. PCT / US2020 / 062548 A2 filed on 30 November 2020, which was published as International Patent Application Pub. Nd. 2021 / 113161 A2 and titled “System for Forming and Testing Batteries in Parallel and in Series,” which is incorporated by reference in its entirety for all purposes. This application is also related to the present inventor's International Patent Application No. PCT / US2022 / 021643 filed on 24 March 2022, which was published as InternationalPub. No. WO 2023 / 027766 A 1 and titled "System for Determining Battery Parameters, and which is incorporated by reference in its entirety for all purposes.BACKGROUND OF THE INVENTION1. FIELD OF THE INVENTION[00021 This patent application pertains to forming, testing and sorting batteries, particularly to high precision, high speed and low cost battery testing technology,particularly to measuring self-discharge for batteries, and more particularly to evaluating quality of batteries.2. DESCRIPTION OF THE RELATED ART

[0003] One of the important characteristics Of a battery is its leakage current or Self discharge current. Leakage current is affected by battery quality, State of charge and temperature. One method for measuring leakage current is to hold a battery at a constant voltage and measure a charging current when the current is stabilized to a constant value. A Self-Discharge Analyzer from Koysight Technologies, Inc. is believed to use this method. This method is very sensitive to the fluctuation of the open-circuit voltage (OCV) of the battery being tested, and the OCV is particularly sensitive to the fluctuation of temperature, even if a relatively expensive potentiostat with high precision and high stability is used. It is difficult to achieve the stability of the OCV required for self-discharge measurement. For example, a voltage sourcing stability of 3 pV peak may cause a disturbance of the battery's electrochemical system and make it difficult to get real leakage current. Therefore, the measurement time of this method is still relatively long, such as a few hours, and the accuracy of this method is relatively poor. It is further believed that Keysight's Self-Discharge Analyzer requires one channel per battery.100041 An indirect method is to measure a voltage drop of a battery at open circuit over a period of time. This method may take a very long time (several days or even weeks) to do and still does not provide a leakage current value, but it is popular among battery manufacturers because it does not require expensive equipment. This method assumes that capacitance of all cells is the same within a tolerable precision.100051 It is desired to have a method that can measure self-discharge (SD) of batteries quickly, precisely and ata reasonable cost for making batteries and for using batteries such as for electrical vehicles arid battery energy storage systems. Also, it is desired to have a method th at can qualify each cell in a paralleled cell group instantly and precisely.SUMMARY OF THE INVENTION

[0006] Methods and apparatuses are provided for measuring and monitoring self-discharge current of cells connected in parallel, specifically in a galvanostatic way, and for using differential self-discharge current of paralleled cells as a quality control (QC) criterion in battery testing , formation and manufacture. A battery may contain one or more cells, and a battery may also be used in a battery group.

[0007] A method for measuring self-discharge of cells in a group under a sameVoltage is disclosed that comprises the steps of: measuring current lb# for at least one pell in the group of cells, wherein lb# represents the current through the corresponding cell#; and evaluating the self-discharge of at least one cell in the group of cells based on the current lb#, preferably using abnormal distributed current through cell# (lb#) of the group of ©ells as a criterion for cell safety judgment. The group, of cells are preferably not connected to any power supply to keep in open circuit, and preferably allowing enough time for the group of cells to reach balance status prior to measuring current I b# for at least one cell in the group of cells. The method preferably includes using the lb# value as a standard for cell quality judgment and / or cell classification for evaluating the self-discharge of at least one cell in the group based on the current lb#. The cells in the group are preferably connected in parallel with each other cell, where a constant current ( / o) is preferably applied to the group of cells prior to measuring current lb# for at least one cell in the group of cells.

[0008] The self-discharge current of at least one cell# (denoted as Isd#) is preferably calculated from an equation: Isd# = Alsd - (lb# - / o / n) on the assumption that a difference of dynamic capacitance (DNC) of the cells can be ignored in calculation of self-discharge current (Isd) and Alsd is known, wherein Alsd represents average self-discharge current of all cells in the group and n represents a number of cells in the group. An absolute value of / o is preferably controlled to be equivalent to that of total self-discharge current (Tlsd) of the group of cells, and assuming Tlsd isknown, the equation becomes: Isd# — -lb# on the assumption that a difference of dynamic capacitance (DNC) of the cells can be ignored in calculation of self-discharge current.

[0009] The method preferably includes applying a constant voltage to the group of cells to make a current flow through the group of cells, preferably where evaluating the self-discharge of at least one cell in the group of cells based on the current lb#, and preferably calculating self-discharge current of at least one cell (denoted as Isd#) from the equation; Isd# = - lb#. The method for evaluating the self-discharge of at least one cell in the group based on the current lb# preferably includes using: measured or statistically obtained average self-discharge current Alsd of the parallel group to get self-discharge current (Isd#) of at least one cell#, according to Isd# = Alsd - lb# derived from lb# = Alsd - Isd#.100101 A method for measuring self-discharge of cells in a group under a same voltage is disclosed that comprises the steps of: measuring current lb# for at least one cell in the group of cells, Wherein lb# represents the current through the corresponding cell#; and evaluating the self-discharge of at least one cell in the group of cells based on the current lb#. The cells in the group are preferably connected ih series and each cell of the group is preferably Connected to an equalizer to keep the cells under a same voltage with equalizers on, where each equalizer preferably has a fully bidirectional charge / discharge channel with at least two current ranges, and where at least one current range is low enough to be capable of measuring self-discharge current (S DC), evaluating the self-discharge of at least one cell in the group of cells based on the current lb# and calculating self-discharge current of at least one cell# (denoted as Isd#) based on measured current lb# and current flowing through combinations of the cell and a corresponding equalizer, where the combinations are connected in series.

[0011] A method is disclosed for measuring self-discharge current (Isd) of cells in a group that are connected in series with an equalizer for each cell The method includes allowing enough time fora group of cells connected in series to reach balancestatus, where each cell of the group is connected to an equalizer to keep the cells under a same voltage with equalizers on, where each equalizer has a fully bidirectional charge / d is charge channel with at least two current ranges, and where at least one current range is low enough to be capable of measuring self-discharge current (S DC); measuring current leqp# for at least one equalizer in response to the cells’ reaching balance status, wherein leqp# represents the current flowing through equalizer# connected to corresponding cell#; and calculating self-discharge current of at least one cell# (denoted as Isd#) from an equation: led# = -Icq p#. The cells in the group that are connected in series with an equalizer for each cell comprises parallel cell groups (PCGs) in a group that are connected in series with an equalizer for each PCG and leqp# represents the current flowing through equalizer# connected to corresponding PCG#.|(>o 121 An auto analyzer is disclosed for evaluating batteries that includes a power supply; one or more processors; and one or more storage media storing instructions executable by the One dr more processors. Wherein the instructions, when executed, cause the auto analyzer to perform operations to execute the methods described above. The power supply preferably comprises a battery testing apparatus that includes a normal battery operating as a standard battery (SB); a constant current source configured to apply a controllable current through the normal battery (Isb) that is equal to its self-discharge current, whereby a voltage of the normal battery is held constant at its open-circuit voltage (OCV); and a positive terminal (IOH) and a negative terminal (LOL) are configured to connect a battery under test therebetween, where the voltage between the terminal (IOH) and the terminal (IOL) is kept at a constant value approximately equal to the voltage of the SB within a desired precision.100131 An equalizer plus (EQP) of a battery is disclosed that includes a control circuit configured to apply a controllable current to a normal battery as a standard battery (SB) inside the HOP, where the current through the SB (Isb) is controlled to be equal to its self-discharge current, whereby a voltage of the SB is kept constant at itsopen-circuit voltage (OCV): two terminals (IOH) and (IOL) for connecting a battery under test therebetween, where the terminal (IOH) is connected to an end of a branch where the SB is located, and the voltage between the terminal (IOH) and the terminal(IOL) is kept at a constant value approximately equal to the Voltage of the SB within a desired precision. The terminal (IOL) is connected to the other end of the branch, and a fully bidirectional charge / discharge channel between the terminals (IOH) and (IOL) is included for measuring current, where the channel has at least two current ranges, and where at least one current range is low enough to be capable of measuring self-discharge current.|()014| This summary is provided to introduce 9 selection of concepts in a simplified form that are further described herein in a detailed description. This summary is not intended to identify key factors or essential features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter. These and other features and advantages of the present invention will be described in , or will become apparent to those of ordinary skill in the art in view of, the following detailed description of example embodiments of the present invention.BRIEF DESCRIPTION OF THE DRAWINGS:|()0 ] 51 These and other features of the disclosure will now be described with reference to drawings summarized below. The drawings and the associated description are provided to illustrate example embodiments of the disclosure and are not intended to limit the scope of the disclosure,100161 Fig. 1 is a simple equivalent circuit of a battery for self-discharge current ( Isd) . For a small voltage range, OCV drop rate dV / dt is proportional to Isd.|0017| Fig. 2 is a block diagram of an example differential battery analyzer(DBA), according to the present disclosure.

[0018] Fig. 3 is a block diagram of another example DBA, according to the present disclosure

[0019] Fig. 4 is a block diagram of yet another example DBA, according to the present disclosure.

[0020] Fig. 5 is a block diagram of an example universal differential battery analyzer (UDBA), according to the present disclosure.

[0021] Fig. 6 is a block diagram of another example universal differential battery analyzer (UDBA), according to the present disclosure.

[0022] Fig. 7 is a block diagram of yet another example DBA, according to the present disclosure.

[0023] Fig. 8 is an illustrative circuit for measuring differential voltage using the DBA, according to the present disclosure.

[0024] Fig. 9 is an illustrative circuit for measuring Isd by applying constantVoltage equal to the OCV of the battery, which is called a potentiostatic method . This method is believed to be used by Keysight's Self-Discharge Analyzer.

[0025] Fig. 10 is an illustrative circuit for measuring Isd by applying constant current to the battery, according to the present disclosure.

[0026] Fig. 11 is an illustrative block flow diagram for a process for measuring Isd by applying constant current to the battery, according to the present disclosure, which is called a galvanostat ic method.

[0027] Fig. 12 is an illustrative circuit for measuring Isd by applying constant current to the battery with the DBA, according to the present disclosure.

[0028] Fig. 13 is an illustrative circuit for measuring Isd of a group of batteries connected in parallel by applying constant current to the batteries with the DBA, according to the present disclosure.

[0029] Fig. 14 is another illustrative block flow diagram for a process for measuring Isd by applying constant current to the battery, according to the present disclosure.

[0030] Fig. 15 is another illustrative circuit for measuring Isd by applying constant current to the battery with the DBA, according to the present disclosure.

[0031] Fig. 16 is an illustrative block flow diagram for a process for measuring Isd without applying any current to the battery, according to the present disclosure, which is called a passive method.

[0032] Fig. 17 is an illustrative block flow diagram for a process for measuring self-discharge of cells in the group under same voltage, according to the present disclosure.

[0033] Fig. 18 is another illustrative block flow diagram for a process for measuring Isd of cells in a group that are connected in parallel, according to the present disclosure .

[0034] Fig. 19 is an illustrative circuit for using current of cells in a parallel group as a quality control method, according to the present disclosure.

[0035] Fig. 20 is an illustrative block flow diagram for a process for using current of cells in a parallel group as a quality control method, according to the present disclosure:

[0036] Fig. 21 is yet another illustrative block flow diagram for a process for measuring Isd of cells in a group that are connected in parallel, according to the present disclosure.

[0037] Fig. 22 is an illustrative circuit for a method for measuring seif-discharge current (Isd) of cells in a group that are connected in series with an equalizer for each cell, according to the present disclosure.

[0038] Fig. 23 is an illustrative circuit for a method for measuring self-discharge current (Isd) of parallel cell groups (PCGs) that are connected in series with an equalizer for each PCG, according to the present disclosure.

[0039] Fig. 24 is an illustrative block flow diagram for a process for evaluating self-discharge of a battery by means of the DBA, according to the present disclosure.

[0040] Fig. 25 is ah illustrative block flow diagram for a process for measurihg direct current internal resistance of a battery by means of the DBA, according to the present disclosureDETAILED DESCRIPTION OF THE EXEMPLARY EMBODIMENTS

[0041] Terminology used herein includes:■ OCV: Open-circuit voltage of a battery■* R: Resistor■ SDR: self-discharge resistance■ SB: Standard battery, which can maintain a constant voltage over a very long time to serve as a reference voltage.■ IM: circuit block for current measurement.■ VM: circuit block for voltage measurement.■ A, / o, Ab, A#, IH , I L, JQH , IOL: / represents current■ l / sb, VH / VL 1 / represents voltage■ Vrt: reference voltage■ , / sd: self-discharge current■ A / sdi average self-discharge current of a group of batteries■ DBA: Differential battery analyzer■ UDBA: Universal differential battery analyzer■ GST: Galvanostat to provide controlled durrent output■ PST: Potentiostat to provide controlled voltage output■ SW#: switch■ Mux: multiplexer

[0042] Fig. 1 illustrates a simple equivalent circuit of a battery for self-discharge current (Isd) according to aspects of the present disclosure. As shown in Fig. 1 , for a small voltage range, OCV drop rate dV / dt is proportional to Isd, where Isd is usually a negative value.

[0043] Fig. 2 is a block diagram showing an example differential battery analyzer (DBA), according to the present disclosure. The DBA provides a reference voltage using a normal battery as a standard battery (SB). In this DBA, a control circuitconfigured to apply a controllable current is connected to a normal battery. A battery under test may be connected between terminals (IOH) and (IOL) of the DBA. In this DBA, the terminal (IOH) is connected to an end of a branch where the SB is located and the terminal (IOL) is connected to the other end of the branch. When the current through the normal battery (denoted as Isd) is controlled to make Isd equal to selfdischarge current (denoted as Isd) of the SB, the voltage of the SB (denoted as Vsb) will be kept constant at its open-circuit voltage (OCV), whereby the voltage between the terminal (IOH) and the terminal (IOL) will be kept at a constant value approximately equal to the voltage Vsb within a desired precision. It can be seen that the use of the constant current method or galvanostatic method described herein to maintain the voltage of the standard battery and the voltage of the battery under test, is different from a potentiostatic (i.e. constant voltage) method of the prior art. The galvanostatic method has the advantages of low noise, low ripple, insensitivity to temperature changes, and little change in the SOO (State of Charge) and OCV of the battery.

[0044] In some examples, a control circuit configured to apply a controllable current may include a galvanostat (GST). In such examples, the output current from tiie GST is controlled via a control unit therein on the basis of feedback from a current sensor (eg. R 1 R2). In some examples, such battery under test may include a group of batteries connected in parallel. The DBA described, herein can maintain the standard battery voltage by making the controllable current through the SB equal to absolute value of self-discharge current of the SB. Thus, it is possible to. control the constant voltage of the battery under test and measure the self-discharge thereof.

[0045] Fig. 3 is a block diagram showing another example DBA, according to the present disclosure. As shown in Fig. 3, the DBA may further comprise a first current sensor (denoted as R1 ) outside the GST. In some examples, the current sensor R1 is connected to the SB in series for measuring the current Isd, whereby the controllable current (It) from the DBA may be controlled by feedback from the current sensor R1. In some examples, the DBA may further comprise a second current sensor (denotedas R2) inside the GST. In some examples, the current sensor R2 is for measuring the current It directly, whereby the current It may be controlled by feedback from the current sensor R2. It is worth noting that the DBA may comprise only one of the current sensors R1 and R2 or both.100461 In some examples, when a battery Is connected to the DBA via the terminals (IOH) and (IOL), the equation It = / o + Isb will be satisfied, wherein / o represents the current flowing to the terminal (IOH) . Accordingly, the current Io may be following to keep the potential of the terminal (IOH).

[0047] In some examples, a normal battery may include a secondary rechargeable battery, instead of a dedicated special primary (non-rechargeable) standard battery. In some examples, the normal battery may include a .lithium, ion battery. In some examples, a normal battery may have the same type as the battery under test. When using the same type of battery as the battery under test as the standard battery, the influence of temperature on the battery can be canceled or eliminated. A normal battery may comprise a secondary rechargeable battery.

[0048] Fig. 4 is a block diagram of yet another example DBA, according to the present disclosure. As shown in Fig. 4, the DBA may further comprise another two terminals (VH) and (VI) and a circuit block for voltage measurement (VM). Alternatively, the DBA may further comprise a first switch (denoted as SW1 ) and a second switch (denoted as SW2) as shown in Fig. 4. The switch SW1 may connect to the current sensor R1 serially and the switch SW2 may be located to connect or disconnect the current Io. When a battery being tested is connected to the DBA via the terminals (VH) and (VL) and both SW1 and SW2 (if they exist) are kept on, the VM will measure the difference between the voltage of the battery under test and the reference voltage (denoted as Vrf), which is determined on the basis of the voltage Vsb. Thus, the DBA described above can be used for high-precision battery voltage measurement / comparison through differential voltage measurement by means of applying a constant current to a normal battery to provide a constant voltage as areference voltage. In some examples, the DBA may have multiple reference voltage ranges, A programmable reference voltage can be provided through various methods.In some examples, the voltage Vrf can be selected as one of a plurality of normal batteries above with different OCVs.

[0049] Fig. 5 is a block diagram showing an example universal differential battery analyzer (UDBA), according to the present disclosure. As shown in Fig. 5, the DBA, based on the description in Fig. 4 above, may further comprise another switch (denoted as SI) to select one from a plurality of normal batteries (such as SB1 , SB2,SBn) with different OCVs. Thus, the voltage Vrf provided by the DBA can be changed with the selected battery.

[0050] In some examples, for a normal battery at nearly balanced status, the change of the current therethrough will cause voltage change thereof within a Very small voltage range, wherein such current through the normal battery is usually very small so as to not interrupt the electrochemical balance of the battery. In some examples, such current may be at the level of leakage current of the normal battery. Under these circumstances, the voltage of the normal battery can change slowly with the current therethrough. Accordingly, the voltage Vrf will be changed when the voltage of the normal battery changes Slowly: Although this method takes a long time to reach equilibrium to change the voltage Vrf, the obtained reference voltage, range has the lowest electrical signal noise.

[0051] In some examples, the voltage Vrf can be selected as one of a plurality of reference voltages within a range not greater than a value of the voltage Vsb. Fig.6 is a block diagram showing another example universal differential battery analyzer (U DBA), which provides a programmable reference voltage by dividing the voltage of the standard battery, according to the present disclosure. As shown in Fig. 6. the UDBA may further comprise a plurality of resistors (such as R4, R5, R6, R7, R8) connected serially with each other and in parallel with the branch where the SB is located. Each resistor has its respective reference voltage output terminal (such as V1 , V2, V3, V4,VL) used for being selected via a multiplexer (denoted as SW3) connected to the VM described above. Therefore, a UDBA with multiple voltage ranges is obtained. In one embodiment, a voltage range includes 4.2±0.2V (Vsb range) / 3.8±0.2V(corresponding to V1) / 3.4±0.2V (corresponding to V2) / 3.0±0.2V (corresponding to V3) 1 2.6+0.2V (corresponding to V4). In another embodiment, a voltage range includes 4.0+0.5V (corresponding to V1 ) / 3.0±0.5V (corresponding to V2) / 2.0+0.5V (corresponding to V3) / 1.0±0.5V (corresponding to V4) / 0.0+5.0V (VL range).100521 Alternatively, a switch (denoted as SW4) may be located in the branch where the divider resistors are connected serially with each other. SW4 can be turned off in Vsb range or VL range, that is, the branch of divider resistors can be cut off to reduce the noise level. The role of a DBA / UDBA in VL range is the same as that of a general VM. It should be noted that Vsb range has the lowest noise, and the noise when using voltage divider resistors is 2~3 times higher than that of Vsb range.[00531 Alternatively, a grounding resistor (denoted as R3) may be connected between the SB and the terminal (IOL) to cancel or eliminate voltage fluctuations Of ground (GND). Alternatively, one or more components of R1 , R2, SW1 and SVV2 may be eliminated.

[0054] There are advantages to using the UDBA described above. The reference voltage value can be quickly switched to obtain differential voltage measurements of different ranges, which is highly versatile and practical. Regular voltage ranging is for meeting the varied scales of voltage of the object under test, such as ±100V / ±10V / ±1 / ±0.1 V / . Reference voltage range in this disclosure is different and unique, which is to meet a requirement for a different section of a voltage scale such as 0 5V. This is especially unique to be applied to a reference voltage from a standard battery. Examples include 4.0±0.5V / 3.0±0.5V / 2.0±0.5V / 1.0±0.5V / 0.0±0.5V in voltage scale of 0 4.5V.

[0055] In some examples, the DBA, based on the DBA described above, may further comprise another two terminals (IH) and (VL) connected to a circuit block forcurrent measurement (IM). In these circumstances, a DBA with current reading terminals is provided,

[0056] Fig. 7 is a block diagram of yet another example DBA, according to the present disclosure. In terms of components of the DBA shown in Fig. 7, reference can be made to the above.

[0057] Fig. 8 is an illustrative circuit for measuring differential voltage using the DBA, according to the present disclosure. As shown in Fig. 8, a battery under test may be. connected to the DBA described above via the terminals (VH) and (VL). Detailed descriptions of components of the DBA shown in Fig. 8 are provided above. In this way, a differential voltage representing a difference between the voltage Vrf and the voltage of the terminal (VH) can be measured by means of the VM inside the DBA. In some examples, such: battery under test includes a group of batteries connected or not connected in parallel. Thus, this circuit can be used for differential Voltage measurement for single or multiple batteries.

[0058] Fig. 9 is an illustrative Circuit for measuring Isb by applying constant voltage equal to the OCV of a battery under test, which is called a potentiostatic method. This method is believed to be used in Keysight’s Self-Discharge Analyzer.

[0059] Fig. 10 is an illustrative circuit for measuring Isd by applying constant current to a battery under test, according to the present disclosure. As shown in Fig.10, a galva nostatic method is used to measure the self-discharge current of a battery. This disclosure illustrates a mechanism that uses the concept of dynamic capacitance to model a battery, preferably using this modeling during self-discharge current measurement. Using the above model, a galvanostat to provide controlled current output may give small currents 11 and I2 to a battery under test. By measuring (dV / dt) 1 at 11 and (dV / dt) 2 at I2 respectively, self-discharge current Isd and dynamic capacitance (DNC) of the battery under test can be calculated by solving the two equations: (dV / dt) 1 * DNC = 11 + Isd , and (dV / dt)2 * DNC = I2 + led.

[0060] Fig. 11 depicts an example process 1100 for measuring Isd by applyingconstant current to a battery under test, in accordance with examples of the disclosure, which is called a galvanostatic method. For example, some or all of the process 1100 may be performed by one or more components in the DBA shown in Figs. 2- Fig. 8, as described herein.

[0061] At operation 1110, the. process may include applying a first constant current (11) and a second constant current (12): to a battery being tested for a period of time (dtl) and for the same or a different period of time (dt2), respectively. The current 11 and I2 are low enough not to interrupt the electrochemical balance of the battery being tested, but preferably high enough to accelerate the test.

[0062] In some examples, each of currents 11 and 12 is less than 100 pA. In some examples, each of currents 11 and !2 is less than 50 pA. In some examples, each of currents 11 and I2 can be larger than 100pA even in mA range depending on the dynamic capacity of the battery being tested. In some examples, such battery being tested includes a group of batteries connected in parallel.

[0063] At operation 1120, the process may include measuring a first voltage change (dV1) and a second voltage Change (dV2) of the battery being tested over the period of time dtl and dt2 respectively. In some examples, the two voltage changes may be measured by various means, such as the DBA with the VM described above. In some examples, each of the periods of time dtl and dt2 is less than 24 hours.

[0064] At operation 1130, the process may include calculating a first voltage change rate (dV1 / dt1) for the period of time dtl at the current 11 and a second voltage change rate (dV2 / dt2) for the period of time dt2 at the current 12.

[0065] At operation 1140, the process may include calculating Isd and dynamic capacitance (DNC) of the battery being tested by solving two equations: (dV1 / dt1 ) * DNC = 11 + Isd, and (dV2 / dt2) * DNC = 12 + Isd. It can be seen that using the current control (Galvanostatic) method described herein is different from the prior art voltage control (Potentiostatic) method to analyze self-discharge current of a battery. The galvanostatic method is useful especially in a battery formation procedure and in abattery testing procedure.

[0066] Fig. 12 is an illustrative circuit for measuring Isd by applying constant current to the battery with a DBA, according to the present disclosure. As shown in Fig.12, a battery being tested is connected to the above DBA via the terminals (IOH) and (IOL). The DBA may be used to provide a first constant current II and a second constant current 12. As discussed above, a first voltage change and a second voltage change of the battery being tested over the periods of t i me dt 1 arid dt2 may be measured respectively. Then , Isd and dynamic capacitance of the battery being tested can be calculated by solving the two equations above.

[0067] In some examples, the DBA may further comprise another two terminals (VH) and (VL) and a circuit block for voltage measurement (VM) for measuring differential voltage between a reference voltage (Vrf) and the voltage of the battery being tested, as described in Fig. 4. In such examples, the voltage Vrf is determined on the basis of the voltage Vsb. As shown in Fig. 12, the battery being tested may be further connected to the DBA via the terminals (VH) arid (V L) , whereby the two voltage changes can be measured by means of the VM.

[0068] Fig- 13 is an illustrative circuit for measuring Isd of a group of batteries connected in parallel by applying constant Current to the batteries with the DBA, according to the present disclosure. As shown in Fig. 13, a group of batteries connected in parallel can be connected to the DBA via the terminals (IOH) and (IOL). Besides, the group of batteries are further connected to the IM inside the DBA via terminals (I H) and (IL). In such examples,, each of the IM and the VM has a plurality of channels for measuring multiple batteries simultaneously. That is, the current through each battery of the group, of batteries and the voltage change due to the current can be measured by means of the IM and the VM, respectively.

[0069] With reference to Fig. 13, a galvanostatic method for measuring selfdischarge current (Isd) of batteries connected in parallel is provided as follows. For example, small currents 11 and 12 from the GST can be applied to the batteries whenSW2 is on. For one battery of the batteries connected in parallel, the current therethrough and the voltage change thereof can be measured by means of the IM andthe VM, respectively. Then, Isd and dynamic capacitance (DNC) of the battery can be calculated by solving the two equations provided above. Thus, a ga Iva nostatic method to obtain Isd and DNC of every battery in the group, as well as the SB, is provided.

[0070] Fig. 14 depicts another example process 1400 for measuring Isd by applying constant current to the battery, in accordance with examples of the disclosure.For example, some or all of the process 1400 may be performed by one or more components in the DBA shown in Figs. 2- Fig. 8, as described herein.

[0071] At operation 1410, the process may include using the control circuit inside the DBA described above to control the current Isb to be equivalent to the current Isd of the SB to keep the voltage Vsb constant, wherein a group of batteries are connected in parallel to the DBA via the terminals (IOH) and ( IOL) . In some examples, the means includes the GST Alternatively, the GST may control the current Isb using the feedback from the sensor R 1. In such examples, the current Isd of the battery SB is predetermined. Alternatively, the current Isd of the battery SB can be determined using the galvanostatic method described above with reference to Fig. 11 .100721 At operation 1420, the process may include allowing enough time for the group of batteries to reach a balanced status. In such examples, voltage of each battery under test will reach and remain constant at its OCV under that balanced status,

[0073] At operation 1430, the process may include measuring current through each battery, whereby the value of the self-discharge current Isd of each battery is determined as being equal to the value of the current passed through the battery. In some: examples, current through one battery (denoted as battery#) of the batteries(denoted as lb#) will reach the self-discharge current of the battery# (denoted as Isd#) when the batteries reach their balanced status. Thus, there is no need to measure voltage and dV / dt of each battery.

[0074] Fig. 15 is another illustrative circuit for measuring Isd by applying constant current to the battery with the DBA, according to the present disclosure. As shown in Fig. 15, a group of batteries in parallel can be connected to the DBA described above via the terminals (IOH) and ( IO L) .

[0075] In some examples, the DBA may further comprise an IM as discussed above. In such examples, the IM can measure current through each battery by means of a plurality of channels. It can be understood that the value of the current Isd of each battery is determined as equal to the value of the current through its corresponding battery with reference to the method illustrated in Fig 14 with both SW1 and SW2 on.

[0076] Fig. 16 depicts another example process 1600 for measuring Isd of batteries in a group that are connected in parallel, in accordance with examples of the disclosure, which is called a passive method. For example. Fig. 15 provides ah illustrative circuit for carrying put the passive method, where the batteries can be in open circuit when SW2 is left off.

[0077] At operation 1610, the process may include allowing enough time for the group of batteries to reach a balanced status, and measuring current through each battery, wherein the group of batteries are connected in parallel with each other, but without connecting to any power supply to keep the group of batteries in open circuit. In some examples, current through one battery of the batteries (battery#) can be denoted as lb#. In some examples, balanced status may be considered to have been reached when the current through the battery or voltage change rate of the battery no longer varies or varies within a predetermined small range,

[0078] At operation 1620, the process may include calculating self-discharge current of each battery (denoted as Isd#) from the equation: Isd# = Alsd - lb#. Alsd represents average self-discha rge current of all batteries i n t h e group, lb# represents the current through the corresponding battery#. Assuming the difference of dynamic capacitance (DNC) of all batteries in the group can be ignored in calculation of selfdischarge current and Alsd is known, self-discharge current of each battery can becalculated from the above equation. Thus, there is no need to measure voltage and dV / dt of each battery, assuming the DNC of batteries is known and the difference of DNC between batteries cap be ignored. This method is especially useful in a finishing procedure in battery manufacturing.

[0079] Fig. 17 depicts an illustrative, block flow diagram for a process 1700 for measuring self-discharge of cells in the group under same voltage, according to the present disclosure. At operation 1710, the process may include measuring current lb# for at least one cell in the group of cells, where lb# represents the current through the corresponding cell#. In this embodiment, cells in the group are under same voltage. In some examples, the current lb# is measured after allowing enough time for the group of cells to reach a balanced status. In some examples, current lb# for at least one cell can be measured. In some examples, each current flowing through each Cell# can be measured. In some examples, the cells in the group are connected in parallel with each other cell. At operation 1720, the process may include evaluating the selfdischarge of at least one cell in the group of cells based on the current lb#. In this embodiment, the. Isd# can be reflected by the lb# value, where cells in the group are under same voltage. In some examples, lb# value may be used as a standard for cell quality judgment and / or cell classification.

[0080] Fig. 18 depicts another example process 1800 for measuring Isd of cells in a group that are connected in parallel, in accordance with examples of the disclosure. For example, Fig. 15 provides an illustrative circuit for carrying out the process 1800, where a current (denoted as / o) is applied to cells connected in parallel with SW1 opened and SW2 closed.

[0081] At operation 1810, the process may include applying a constant current ( / o) to cells in a group that are connected in parallel, and assuming the difference of dynamic capacitance (DNC) of the cells can be ignored in calculation of self-discharge current. This means a n average current / o / n is applied to each cell in the group, where n represents the number of cells in the group.

[0082] In some examples, the current ( / o) is applied using a galvanostat. In some examples, the current ( / o) is applied using the DBA described above. In some examples, the process may include applying a constant voltage to cells jn a parallel group to make a current (jo) flowing through the cell group. This potentiostat operation is equivalent to applying a current Io to the cell group. In some examples, the constant voltage is applied using a potentiostat.

[0083] In some examples, the absolute value of Io can be controlled to be equivalent to that of total self-discharge current (Tlsd) of the cell group. In these examples, Tlsd is assumed known. In some examples, Tlsd can be obtained by statistics. In some examples, Tlsd can be calculated as described below.

[0084] At operation 1820, the process may include measuring current lb# for at least one cell, where lb# represents the current through the corresponding cell#.

[0085] At operation 1830, the process may include calculating self-discharge current of at least one cell (denoted as Isd#) from the equation: Isd# = Alsd — (lb# - IO / n) on the assumption that Alsd is known, where Alsd represents average selfdischarge current of the cells. In some examples, self-discharge current of each cell can bo calculated from the above equation. In some examples, compared with the passive method described above, the current IO / n may be included in lb# under these circumstances. Thus, the equation Isd# - Alsd r- (lb# - IO In) cap be derived from the equation Isd# - Alsd - lb# described in the above operation 1620.

[0086] Thus, there is ho need to measure voltage and dV / dt of each cell, assuming the DNC of cells is known and the difference of DNC between cells can be ignored. This method is especially useful in a finishing procedure in battery manufacturing for being able to identify a bad cell with high Isd value and hence to prevent a hazardous situation.

[0087] In some examples, since IO. = -Tlsd, and Alsd ■= Tlsd / n, for each coll# in the cell group, the equation: Isd# = Alsd - (lb# - IO / n) becomes Isd# = - lb#, which means Isd# can be directly and precisely gotten by measuring lb# by applying constantvoltage to the cell group or applying Io to the cell group, where Io = -Tlsd.| DOS'S | In some examples, such Alsd is determined as a ratio of total selfdischarge current (Tlsd) of the group of batteries to the number of the batteries in the group being tested. In such examples, the group of batteries can be regarded as an equivalent battery in calculation of total self-discharge current. For example, Fig. 13 provides an illustrative circuit for calculating the total self-discharge current. In such example, both SW1 and SW2 are left on. In some examples, the total self-discharge current can be determined with reference to the galva nostatic method described above .To be specific, the galvanostatic method can comprise the steps of: applying a first constant current (11) and a second constant current (12) to the group of batteries connected in parallel for a- period of time (dt 1 ) and for the same or a different period of time (dt2) respectively, wherein the currents 11 and 12 are low enough not to interrupt the electrochemical balance of the group of batteries being tested; measuring a first voltage change (dV1) and a second voltage change (dV2) of the group of batteries being tested over the periods of time dt1 and dt2, respectively; calculating a first voltage change rate (dV1 / dt1) for the period of time dtl at the current 11 and a second voltage change rate (dV2 / dt2) for the period of time dt2 at the current I2; calculating total self-discharge: current (Tlsd) and total dynamic capacitance (TDNC) of the group of batteries being tested by solving two equations: (dV1 / dtl) * TDNC = 11 + Tlsd , and(dV2 / dt2) * TDNC = 12 + Tlsd. Thus, a galvanostatic method to obtain Alsd of the battery group is provided.

[0089] Fig. 19 is an illustrative circuit for using current of cells in a parallel group as a quality control method, according to the present disclosure.|00*)0| As shown in Fig. 19, a group of cells (denoted as Bl -Bn) in parallel can be connected to a power supply. For each cell in the group, a sensor may be connected with the cell# in series for measuring the current (lb#) through the cell#. In some examples, the power supply may be a galvanostat. In some examples, the power supply may be a potentiostat. In some examples, the group of cells in parallelcan be connected to the DBA described above Via the terminals (IOH) and (IOL) as shown in Fig, 15 with both SW1 and SW2 on.

[0091] In some examples, the group of cells (denoted as B1 ~Bn) are connected in parallel with each other but without connecting to any power supply to keep the group of cells in open circuit. For example, the power supply shown in Fig.19 is off; For example, the group of cells can be in open circuit as shown in Fig.15 when SW2 is left off.

[0092] Fig. 20 depicts an example process 2000 for using current of cells in a parallel group as a quality control method, in accordance with examples of the disclosure.

[0093] At operation 2010, the process may include determining if cells in a parallel group are connected to a power supply.

[9094] If yes, at operation 2012, the process may include applying current to the cells connected in a parallel group.

[0095] If no, at operation 2014, the process may include allowing enough time for the group of cells being tested to reach balance status.

[0096] In this embodiment, the lb# value measured directly can reflect differences among self-discharge current, of cells connected in parallel.. In some examples, current flowing into each cell can be measured.

[0097] At operation 2020, the process may include measuring current lb# flowing into corresponding cell#.

[0098] At operation 2030, the process may include using the lb# value as a standard for cell quality judgment and / or cell classification.

[0099] In this embodiment, the Isd# can be reflected by the lb# value, because lb#=Alsd-lsd# and average self-discharge current Alsd is approximately the same for each; cell#. Thus, the lb# value obtained by the above method can be used as the standard for cell quality judgment and / or cell classification in the same: way as Isd#, especially in battery testing and production.

[0100] Generally, the larger the Isd#, the better the cell quality, wherein Isd# is negative. Accordingly, the smaller the lb#, the better the cell quality. In some examples, if lb# value is negative, it means that the corresponding cell# is charging at least one other cell, which implies the corresponding cell# usually has better quality than the at least one other cell being charged.

[0101] In some examples, the cells can be classified or sorted according to the consistency of the lb# value or the Isd# value, especially in forming and testing batteries.

[0102] In some examples, the Isd# can be measured by the passive method for measuring self-discharge current (Isd) of cells in a group that are connected in parallel mentioned above.

[0103] In some examples, abnormal distributed current through cell (lb#) of parallel cell group can be used as a criterion for battery safety judgment. In some examples, parallel cells tested in the same group may be prepared to be designed as one battery. In some examples, if an lb# value is significantly larger than current through other cells or lb# value is larger than a first preset Safe Current threshold, we can consider that there are certain safety risks associated with the corresponding cell#. Typically, an internal short circuit in cell# can cause an increase in the corresponding self-discharge current (Isd#). Considering the Isd# is difficult to measure quickly, this technology may diagnose celt's internal micro-shortage effectively in advance to prevent thermo-runaway and hence greatly improve safety protection level, especially in testing, formation and storage.

[0104] In some embodiments, the process may further include using abnormal distributed current through cell (lb#) of the parallel group, as a criterion for cell safety judgment.

[0105] In some examples, current lb# flowing into each cell# can be measured when charging the cell group. In some examples, potential risks can be diagnosed when a measured lb# is significantly larger than current through other cells or themeasured lb# value is larger than a second preset safe current threshold. The principle of this method is similar to that of using current of cells in a parallel group at open circuit condition as a quality control method described above, differing only in whether or not a current is applied to the cell group.

[0106] Fig. 21 is yet another illustrative block flow diagram for a process 2100 for measuring lb# of cells in a parallel group, according to the present disclosure. For example, Fig. 15 provides an illustrative circuit for carrying out the method, where the cells can bo in open circuit when SW2 is left off..

[0107] At operation 2110, the process may include allowing enough time for the group of cells being tested to reach balance status, and measuring current lb# flowing into corresponding cell#, where the group of cells are connected in parallelWith each other but without connecting to any power supply to keep the group of cells in open circuit.

[0108] In this embodiment, descriptions of operation 2110 may be consistent with that of operation 2014 and operation 1710.

[0199] At operation 2120, the process may include using measured or statistically obtained average self-discharge current Alsd of the parallel battery group to get a self-discharge: current ( Isd#) of corresponding cell#, according to Isd# - Alsd - lb# derived from lb# = Alsd - Isd#. In some examples, Alsd can be calculated as described above. In some examples, self-discharge current of each cell can be calculated.

[0110] Alternatively, at operation 2130, the process may further include using the Isd# value obtained as a standard for cell quality judgment and / or cell classification. Thus, this method provides another standard for cell quality judgment and / or cell classification, which can use the value of Isd# directly.

[0111] Fig. 22 is an illustrative circuit for a method for measuring self-discharge current (Isd) of cells in a group that are connected in series with an equalizer for each cell, according to the present disclosure1001 12] As shown in Fig. 22 , a group of cells (denoted as C1 ~Cn) are connected in series with an equalizer for each cell. In this embodiment, each equalizer is used to keep corresponding cell under controllable voltage. In some examples, all cells connected in a serial group can be under sa me voltage all the time with the equalizers on. This is similar to paralleling cells where cells are under same voltage.

[0113] In this embodiment, each equalizer may have a fully bidirectional charge / discharge channel with at least two current ranges, and at least one current range is low enough to be capable of measuring self-discharge current. This means the equalizer here is hot a traditional equalizer. In some examples, a battery management system (BMS) with current ranges matching requirements above can act as the equalizer. In come examples, the equalizer may be called equalizer plus (EQP).An EQP may include a DDBBAA ddeessccrriibbeedd aabboovvee, plus a fully bidirectional charge / discharge channel between the terminals (IOH) and (IOL) for measuring current. The channel has at least two current ranges, and at least one current range is low enough to be capable of measuring self-discharge current.

[0114] In some embodiments, current (denoted as leqp#) flowing through equalizer# connected to corresponding cell# can be measured when there are fairly good balance status among cells in the group., In some examples, when leqp# is nearly stable, it can be considered to reach balanced status:. In some examples, each current flowing through each equalizer# connected to corresponding cell# can be measured.

[0115] In some embodiments, current (denoted as leqp#) flowing through equalizer# connected to corresponding cell# can be calculated according to equation: leqp# = lb# — / o, where Io represents the current flowing through combination# of the cell# and corresponding equalizer#.|(>01 16] In this embodiment, self-discharge current of at least one cell# (denoted as Isd#) can be calculated from the equation: Isd# = -leqp#. In some examples, selfdischarge current of each cell# can be calculated. This is based on the principle that all cells connected in the serial group are under same voltage.| ()<> 1 17 J In some examples, a power supply cart be connected to the cell group with SW closed to apply a current ( / o) to the group of cells. In these examples, fc is low enough not to interrupt the electrochemical balance of the cells. In some examples, the group of cells are at open circuit condition with SW opened, i.e. / c = 0.

[0118] This invention can be applied to battery testing and formation, as well as in a battery pack such as for electrical vehicles and battery energy storage systems, where it is impossible to measure current for each cell via a transducer dr a sensor. Thus, this method is especially useful in a battery pack for being able to identify a bad cell with high Isd value and hence to prevent a hazardous situation.

[0119] Fig. 23 is an illustrative circuit for a method for measuring self-discharge current (Isd) of parallel cell groups (PCGs) that are connected in series with an equalizer for each PCG, according to the present disclosure.

[0120] As shown in Fig. 23, a group of PCGs (denoted as PCG1 ~PCGn) are connected in series with an equalizer for each PCG. For each PCG, a group of cells(denoted as C1~Cm) are connected in parallel and each cell of one PCG has very similar specifications and characters. The number of cells in each PCG is preferably the same.

[0121] In this embodiment, each equalizer is used to keep corresponding PCG under controllable voltage. In some examples, all PCGs connected in a serial group can be under same Voltage all the time with the equalizers on. This is similar to paralleling PCGs where PCGs are under same voltage. Each equalizer may have a fully bidirectional charge / discharge channel with at least two current ranges, and at least one current range is low enough to be capable of measuring self-discharge current. The descriptions of the equalizer here can be consistent with the previous One.

[0122] In this embodiment, current (denoted as leqp#) flowing through equalizer# connected to corresponding PCG# can be measured when there is fairly good balance status among PCGs in the group. In some examples, when leqp# is nearly stable, it can be considered to reach balanced status. In some examples,current leqp# for at least one equalizer can be measured, tri some examples, each current flowing through each equalizer# connected to corresponding PCG# can be measured. Thereby, self-discharge current of at least one PCG# (denoted as Isd#) can be calculated from the equation: Isd# = -leqp#.

[0123] In some examples, a power supply can be connected to the PCG group with SWclosed to apply a current (7o) to the PCGs. In these examples, fo is low enough not to interrupt the electrochemical balance of the cells. In some examples, the group of PCGs are at open circuit condition with SW opened, i.e. / p = 0.

[0124] In this embodiment, all cells in parallel of one PCG can be regarded as an equivalent cell. The principle of this method is similar to the method for measuring self-discharge current (I sd) of cells in a group that are connected in series with an equalizer for each cell described above, differing only in replacing a cell with a PCG.

[0125] This invention can be applied in battery packs such as for electrical vehicles and battery energy storage systems, where it is impossible to measure current for each cell via a transducer or a sensor. Thus, this method is especially useful in battery packs for measuring SDC of a parallel cell group efficiently.

[0126] Fig. 24 depicts an example process 2400 for evaluating self-discharge of a battery by means of a DBA with a VM. in accordance with examples of the disclosure. For example, some or all of the process 2400 may be performed by one or more components in the DBA shown in Figs. 4- Fig, 8, as described herein.|ooi27] At operation 2410, the process may include using the DBA described above to measure a first differential OCV (denoted as DOCV1) and a second differential OCV (denoted as DOC V2) against the standard battery (SB) representing a difference between the reference voltage described above and the voltage of a terminal (VH) at two different times T1 and T2, wherein a battery being tested is connected to the DBA with a VM described above via terminals (VH) arid (VL). In some examples, the DBA further comprises a first current sensor connected to the SB in series for measuring: the current through the SB and providing feedback to control anoutput current from the control circuit. In such examples, the current through the SB is controlled to be equal to self-discharge current of the SB, whereby the voltage of the SB is kept consta nt at its open-circuit voltage (OCV). For example, an illustrative circuit for carrying out the method can be referred to Fig. 8 with SW1 on. In some examples, DOCV1 = V1-Vrf and DOCV2 = V2-Vrf are Satisfied, where VI and V2 represent the voltage of the terminal at times T1 and T2, respectively: In some examples, each of TT and T2 is less than 24 hours.

[0128] At operation 2420, the process may include calculating a differentialDOCV (ADOCV) between two differential OCVs for a period from T1 to T2 (At). In such examples, ADOCV=DOCV2-DOCV1 and At= T2 - T1 .

[0129] At operation 2430, the process may include evaluating, on the basis of a ratio of ADOCV to At, self-discharge status of the battery being tested. In some examples, a K value representing the ratio of ADOCV to At of a battery can be calculated to evaluate self-discharge status of the battery under test. This method for measuring differential OCV can be particularly useful in making batteries

[0130] In some examples, a battery being tested includes a group of batteries. Each of the group of batteries can connect or disconnect to the VIVI via a switch. In such examples:, the process; may further include sorting the group of batteries according to the self-discharge status. In such examples, the group of batteries can be sorted according to their values of self-discharge parameters. These parameters may include, but not be limited to, at least one of the following; OCV, SD representing a differential DOCV (ADOCV) between two differential OCVs for a period of time, and the K value mentioned above. In some examples, these parameters may further include, but not be limited to, at least one of Isd and SDR. In this way, batteries having reasonably consistent values for the parameters can be sorted into one group.Compared with other methods for grading and sorting batteries that include modeling, algorithms and electrochemical analysis, this method provided in the present disclosure is much easier, thereby saving or reducing storage time and improving thebattery manufacturing process.

[0131] In some examples, the process may further include calculating selfdischarge current (Isd) of one or more batteries in the group on the basis of known dynamic capacitance (DNC) value of one or more batteries in the group or average DNC value of the group of batteries. In such examples, self-discharge current of each battery is calculated from the equation: Isd# = AQ / At = DNC (or ADNC) * ADOCV / At, where Isd# represents the self-discharge current of the target battery#, AQ represents change of electricity, whore r=AQ / At, and ADNC represents average DNC value of all batteries in the group.

[0132] In some examples, ADNC- can be calculated from obtained historical DNCs. In some examples, an ADNC value of the group of batteries can. be determined as a ratio of total DNC (TDNC) of all batteries in the group to the number of the batteries in the group being tested. Alternatively, the TDNC can be determined with reference to the galvanostatic method described above regarding the group of batteries as an equivalent battery by solving two equations: (dV1 / dt1 ) * TDNC = 11 + Tlsd, and (dV2'dt2) * TDNC = I2 + Tlsd.

[0133] Fig. 25 depicts an example process 2500 for measuring direct current internal resistance of a battery by means of a DBA, in accordance with examples of the disclosure. For example, Fig. 13 provides an illustrative circuit for carrying out this method with both SW1 and SW2 on.100134] At operation 2510, the process may include applying a first Current and a second current to a battery being tested at two different times T1 and T2, wherein a battery being tested is connected to the DBA described above via terminals (VH) and (VL). The DBA further comprises two terminals (I H) and (IL) connected to a circuit block for current measurement (IM), wherein a sensor is connected between terminals(IH) and (IL) and connected with the battery in series for measuring the current through the battery. In some examples, the first current and the second current are low enough not to interrupt the electrochemical system of the battery. In some examples, the IMmay have a plurality of channels for measuring current through each battery in a group connected thereto.

[0135] At operation 2520, the process may include measuring a differential current (Al) representing a difference between a first measured current and a second measured current of the battery being tested for a period from T1 to T2 by means of the IM. In some examples, for one battery of a group of batteries (denoted as battery#), a differential current is determined by the equation: Al b# = lb#2 - lb#1. Ib#1 and lb#2 represent the first measured current and the second measured current through battery# using the IM, respectively.| ()(> 136 J At operation 2530, the process may include measuring a first differential voltage and a second, differential voltage representing a difference between the reference voltage and the voltage of the terminal (VH) while applying the first current and the second current respectively by means of the VM. In some examples, for one battery of the batteries (denoted as battery#), a first differential voltage is determined by the equation: Vb#1 = V#1 - Vrf. V#1 represents the voltage of the terminal (VH) of battery# while applying the first current. And a second differential voltage is determined by the equation: Vb#2= V#2 - Vrf. V#2 represents the voltage of the terminal (VH) of battery# while applying the second current.1001371 At operation 2540, the process may include calculating a change of differential voltage (AV) of the battery representing the difference between the first differentia I vo ltage and the second differential voltage for a period from T1 to T2. In some: examples, for one battery of the batteries (denoted as battery#), the change of differential voltage (AV) of the battery being tested for a period from T1 to T2 is determined by the equation: AV# = Vb#2 - Vb#1 .

[0138] At operation 2550, the process may include calculating the DCI R of the battery being tested as equal to AV / AI . In some examples, for one battery of the group of batteries (denoted as battery#), the DO R of the battery being tested is determined by the equation: DCIR# = AV# / AI#. Similarly, the equivalent resistance of a group ofbatteries under test can be calculated with reference to the above method regarding the group of batteries as an equivalent battery. This method usually can be applied to battery testing, especially in battery formation.| ()(> 139 J Ari auto analyzer for evaluating batteries is provided in this disclosure. In some examples, an auto analyzer for evaluating batteries may comprise a power supply; one or more processors and one or more storage media storing instructions executable by the one or more processors, wherein the instructions, when executed, cause the auto analyzer to perform operations according to any one of the following: a method for measuring differentia I voltage, a galvanostatic method for measuring selfdischarge current of a battery, a galvanostatic method for measuring self-discharge current of a battery using a differential analyzer described above, a passive method for measuring self-discharge current of batteries in a group that are connected in parallel, a method for evaluating self-discharge of a battery and a method for measuring direct current internal resistance of a battery. Detailed descriptions of these methods have been: discussed above with reference to Fig. 8 to Fig. 25.

[0140] In some examples, the processor(s) may be any suitable processor capable of executing instructions to process data and perform operations as described herein. By way of example and not limitation, the processor(s) may include one or more central processing units (CPUs), graphics, processing u nits (G PUs), or any other device or portion of a device that processes electronic data to transform that electronic data into other electronic data that can be stored in registers and / or memory. In some examples, the processor(s) may include a circuit assembly, such as integrated circuits(e g, ASICs, etc.), gate arrays (e.g, FPGAs, etc.), arid other hardware devices in so far as they are configured to implement encoded instructions.|001 -11 ] In some examples, the storage media may include non-transitory computer-readable media, such as a memory. In such examples, the memory may store an operating system and one or more software applications, instructions, programs, and / or data to implement the methods described herein and the functionsattributed to the various systems. In various implementations, the memory can be implemented using any suitable memory technology, such as static random access memory (SRAM), synchronous dynamic RAM (SDRAM), nonvolatile / flash-type memory, or any other type of memory capable of storing information.

[0142] In some instances, the memory may include at least a working memory and a storage memory. For example, the working memory may be a high-speed memory of limited capacity (e.g, cache memory) that is used for storing data to be operated on by the processor(s). In some instances, the memory may include a storage memory that may be a lower-speed memory of relatively large capacity that is used for long-term storage of data. In some cases, the processor(s) may not operate directly on data that is stored in the storage memory, and data may need to be loaded into a working memory for performing operations based on the data, as discussed herein.

[0143] In some examples, the auto analyzer may be integrated into a DBA described above. In such cases, the DBA with the auto analyzer is capable of testing various parameters of a battery automatically.

[0144] It can be understood that the architectures, systems, and individual elements described herein can include many other logical, programmatic, and physical components, of which those shown in the accompanying figures are merely examples that are related to the discussion herein.FURTHER EMBODIMENTS OF THE INVENTION

[0145] For a battery at a fully balanced status, a very small current at the level of leakage current of the battery will cause a linear voltage change against time within very small voltage range such as 10's of microvolts to a few millivolts. In this invention, a battery at its fully balanced status is considered as behaving like a suporca pacitor Within a small voltage range at a very small current. Supercapacitor behavior follows(dV / dt)*C=l+LC, where LC is leakage current and C is capacitance and 1 is the currentapplied to the capacitor. For a supercapacitor, C is a constant value and does not change with SOC (State, of Charge), while, leakage current LC will change along with SOC of supercapacitor. When voltage change rate dV / dt is measured with constant current I, LC can be calculated with known C value as LC=(dV / dt)'C-l. Using a supercapacitor to model a battery, a battery Will have dynamic LC and dynamic C at certain SOC and follow (dV / dt)*C=l+LC, where both LC and C will change with different SOC. If two different currents 11 and I2 are applied at a same SOC and one measures (dV / dt) 1 and(dV / dt)2 correspondingly, assuming both LC and C are same for the two currents, one can get LC and C values of the battery by solving two equations(dV / dt)1AC=I1 +LC and(dV / dt)2AC=l2+LC. When the battery is fully balanced and this SOO and current 11 and I2 would not interrupt significantly the electrochemical balance of the battery, the dynamic LC calculated accordingly can be considered as leakage current at this SOC. When 11 and 12 is multiple times larger than LC, dV / dt is larger and needs less time to measure and / or needs less voltage precision from aVoltmeter. Ohly a few hours is enough to measure LC of a battery at 95%~100% SOC.

[0146] Because current control is much easier than voltage control in very low current level and because a battery is very sensitive to even very small voltage noise / ripple, this method requires much simpler and low cost testing systems and needs much shorter time to get reliable results as compared to methods using voltage control. A regular battery testing system and battery formation system with high enough measurement accuracy / precision can be used for this method, instead of using special equipment, which could be very expensive and not precise enough.

[0147] If dynamic capacitance (DNC) of battery is known within a certain accuracy, dynamic LC(DNLC) can be calculated directly from (dV / dt)*C=l+LC, where dV / dt, C and I are known or measured.

[0148] When a number (N) of batteries with very similar characters are connected in parallel we can assume that the parallel group of batteries has a certainaverage dynamic capacitance ADNC=sum(DNC(1 ):DNC(N)) / N and certain average dynamic leakage current ADN LC= sum(DN LC(1 ):DNLC(N)) / N. When the paralleled battery group reaches an electrochemical balanced status, one should have DNLC(n)=ADN LC-l(n)+lg / N , where l(n) is the current flow into the battery n and Ig is the total current flow into the parallel battery group, If we can assume that batteries with same chemical and mechanical structure and same specifications have fairly constant ADNC arid. ADN LC. which may be true in a massive battery testing and formation process, where battery cells are connected in parallel, one can directly measure each battery’s leakage current by measuring current flow into each battery While the battery group is under balanced status and there is zero or very small external current flow Ig through the parallel group by DNLC(n)=ADN LC-l(n)+lg / N . This process involves only current measurement under open circuit or very small current to the battery group, and can be done instantly when the battery group reaches balancing status without need of a long time for voltage control / change and measurement. This invention will significantly lower the time and equipment heeded for battery manufacturing.

[0149] Even if one does not have an exact value of AD NLC and DNLC(n), one still can compare DN LG of each battery in the para lie! group by the value Of 1(h) once the parallel battery group is in balanced status:. The effect of comparing l(n), orALC(h)=LC(n)-ALC, instantly would be similar to comparing voltage drop AV(n) over a long period of time.

[0150] Additional embodiments of the invention include the following: a mechanism that uses a dynamic supercapacitor with dynamic capacitance and dynamic leakage current to model a battery during leakage current measurement; using the above model, applying two different currents, which are low enough not to interrupt the electrochemical balance of the battery but high enough to accelerate the test, to get two eqiiation(dV / dt)1‘C=l1+LC and(dV / dt)2*C=l2+LC. LC and C value of the battery can be solved from these 2 equations; using current control insteadVoltage control to batteries for leakage current measurement; connect a number of batteries in parallel without applying any current to the group (open circuit), measure current through each battery to get the difference of leakage current from average leakage current ALC(n)=LC(n)-ALC. LC(n) = ALC(n) - lb(n); by solving the two equation (dVg / dt)1* ADNC=ADNLC and (dVg / dt)2* ADNC= Ig+ADNLC to get ADNC and ADNLC, assuming ADNC=sum(LC1 :LCn) / n and ADNC= sum(C1: Cn) / n; by applying lg=-N* ALC to the parallel battery group and check if dVg / dt is close to 0 (in pV level), to check if ALC is the right value, and one can calculate the. actual ALC; and using only one current source to or even without a current source to measure multiple cells’ leakage current simultaneously.EMBODIMENTS DISCLOSED IN APPLICATION NO. PCT / US2023 / 081285

[0151] The apparatus, equipment and methods described herein builds on and includes description from the present inventor's International Patent Application No.PCT / US2023 / 081285 titled "Analyzer and Method for Determining Self-Discharge of Batteries,” which was published as Publication No. WO 2024 / 129355. The disclosure in the present inventor’s International Patent Application No.PCT / US2023 / 081285 is ALSO included in the inventor’s: US Provisional PatentApplication Serial No. 63 / 560,645 filed on 02 March 2024 titled ’‘Measuring SelfDischarge of Batteries,” Which is claimed as a priority document.

[0152] The following is a brief summary of the disclosure in the present inventor's International Patent Application No. PCT / US2023 / 081285. A differential battery analyzer (DBA) for testing a battery includes a control circuit configured to apply a controllable current to a normal battery as a standard battery (SB) inside the DBA, wherein the current through the SB (Isb) is controlled to be equal to its selfdischarge current, whereby a voltage of the SB is kept constant at its open-circuit voltage (OCV); and two terminals (IOH) and (IOL) for connecting a battery under test therebetween, wherein the terminal (IOH) is connected to an end of a branch wherethe SB is located, and the voltage between the terminal (IOH) and the terminal (IOL) is kept ata constant value approximately equal to the voltage of the SB within a desired precision, and the terminal (IOL) is connected to the other end of the branch, The normal battery preferably includes a secondary rechargeable battery, which preferably has the same type as the battery under test. The DBA preferably further comprises another two terminals (IH) and (IL) connected to a circuit block for current measurement (IM) .

[0153] The DBA preferably further comprises a first current sensor connected to the SB in series for measuring the current through the SB and providing feedback to control an output current (It) from the control circuit. The DBA, more preferably further comprises a second current sensor for measuring an output current from the control circuit and providing feedback to control the output current, preferably wherein the current flowing to the terminal (IOH) (to) is following to. maintain the potential of the terminal (IOH) when a battery is connected to the DBA Via the terminals(IOH) and (IOL), wherein It = to + Isb.

[0154] The DBA preferably further comprises another two terminals (VH) and (VL) and a circuit block for voltage measurement (VM) for measuring differential Voltage between a reference Voltage and the voltage of the battery under test which is connected to the DBA via the terminals (VH) and (VL), wherein the reference voltage is determined on the basis of the voltage of the SB. The reference voltage is preferably selected as one of a plurality of reference voltages within a range hot greater than a value of the voltage of the SB. This DBA preferably further comprises a plurality of resistors connected serially with each other and in parallel with the branch where the SB is located, wherein each resistor has its respective reference voltage output terminal which is selected via a multiplexer connected to the VM, whereby the voltage of the SB is divided into a plurality of reference voltages.

[0155] Regarding the current flowing to the terminal (IOH) (to) following to maintain the potential of the terminal (IOH) when a battery is connected to the DBAvia. the terminals (IOH) and (IOL)11 , preferably the control circuit includes a galvanostat, and the. DBA preferably further includes a second current sensor, two terminals (VH) and (VL), another two terminals (IH) and (IL) connected to a circuit block for current measuremerit (IM) , a circuit block for voltage measurement (VM), a first switch connected to the first sensor serially, a second Switch located to connect or disconnect the current flowing to the terminal (IOH)., a grounding resistor connected between the SB and. the terminal (IOL), and a plurality of resistors connected Serially with each other and in parallel with the branch where the SB is located, wherein each resistor has its respective reference voltage output terminal which is selected via a multiplexer connected to the VM, whereby the voltage of the SB is divided into a plurality of reference voltages, wherein the second sensor is configured to measure an output current from the galvanostat and providing feedback to control it, wherein the VM is configured to measure differential voltage between a reference voltage and the voltage of the battery under test which is connected to the DBA via the terminals(VH ) and (VL) , and wherein the reference voltage is determined on the basis of the voltage of the SB.

[0156] A method has been disclosed for measuring differential voltage using the DBA that includes the two terminals (VH) and (VL) and the and circuit block for voltage measurement (VM) for measuring differential voltage between a reference voltage and the voltage of the battery under test which is connected to the DBA via the terminals (VH) and (VL) and measuring a differential voltage representing a difference between the reference voltage and the voltage of the terminal (VH) by means of the VM, wherein a battery under test is connected to the terminals (VH) and (VL). The battery under test preferably includes a group of batteries connected in parallel.

[0157] A galvanostatic method for measuring self-discharge current (Isd) of a battery has been disclosed that comprises the steps of: applying a first constant current (11) and a second constant current (12): to a battery being tested for a period oftime (dt1 ) and for the same or a different period of time (dt2) respectively, wherein the currents II and 12 are low enough not to interrupt the electrochemical balance of the battery being tested; measuring a first voltage change (dV1) and a second voltage change (dV2) of the battery being tested over the periods of time dt1 and dt2, respectively; calculating a first voltage: change, rate (dV1 / dt1 ) for the period of time dt1 at the current 11 and a second voltage change rate (dV2 / dt2) for the period of time dt2 at the current 12 ; calculating fed and dynamic capacitance (DNC) of the battery being tested by solving equations (1 ) and (2), wherein equation (1 ) is (dV1 / dt1 ) * DNC - 11+ Isd:, and equation (2) is (dV2 / dt2) ‘ DNC = 12 + fed. The battery being tested preferably includes a group of batteries connected in parallel.

[0158] The DBA described above can be used to apply a first constant current(11 ) and a second constant current (I2) to a battery being tested for a period of time (dt1 ) and for the same or a different period of time (dt2), respectively, with the control circuit inside the DBA, wherein the battery being tested is connected to the DBA via the terminals (IOH) and (IOL), and the currents 11 and I2 are low enough not to interrupt the electrochemical balance of the battery being tested; measure a first voltage change (dV1) and a second voltage change (dV2) of the battery being tested Over the periods of time dtl arid dt2, respectively; calculate a first voltage change rate (d V1 / dt 1 ) for the period of time dt 1 at the current 11 and a second voltage change rate(dV2 / dt2) for the period of time dt2 at the current 12 ; calculate Isd and dynamic capacitance (DNC) of the battery being tested by solving equations (1) and (2) in which equation (1) is (dV1 / dt1) * DNC = 11 + Isd , and equation (2) is (dV2 / dt2) * DNC = I2 + fed.

[0159] The DBA used preferably includes, the two terminals (VH) and (VI) and a circuit block for voltage measurement (VM) for measuring differential voltage between a reference voltage and the voltage of the battery being tested, wherein the reference voltage is determined on the basis of the voltage of the SB, and wherein the battery being tested is further connected to the DBA via the terminals (VH) and (VL),whereby the first Voltage change and the second voltage change are measured by means of the VM. The battery being tested is preferably a group of batteries connected in parallel, wherein the group of batteries is further connected to a circuit block for current measurement (IM) inside the DBA via terminals (IH) and (IL), and wherein each of the IM and the VM has a plurality of channels and each of the channels is configured to measure current or voltage of a battery.

[0160] The DBA described a few paragraphs above that has the two terminals (IOH) and (IOL) can be used to measure self-discharge current of a group of batteries by using the control circuit inside the DBA to control the current through the SB to be equivalent to the current Isd thereof to keep the voltage of the SB constant, wherein the group of batteries are connected in parallel to the DBA via the terminals (IOH) and(IOL) ; allowing enough time for the group of batteries to reach a balanced status; and measuring current through each battery, whereby the value of the self-discharge current Isd of each battery is determined as being equal to the value of the current passed through the battery. The current Isd of the battery SB is preferably determined using the galva nostatic method described a few paragraphs above. The current through each battery is preferably measured by means of a circuit block for current measurement (IM) inside the DBA, and the DBA preferably includes two: terminals (IH) and (IL) connected to the IM. wherein the IM has a plurality of channels and each of the channels is configured to measure current of a battery.

[0161] A passive method for measuring self-discharge current (Isd) of batteries in a group that are connected in parallel has been disclosed that includes the steps of allowing enough time for a group of batteries being tested to reach balance status, and measuring current through each battery; wherein the group of batteries are connected in parallel with each other but without connecting to any power supply to keep the group of batteries in open circuit; arid calculating self-discharge current of each battery (Isd#) from the equation: Isd# = Alsd - lb# on the assumption that a difference of dynamic capacitance (DNC) of all batteries in the group can be ignoredin calculation of self-discharge current and Alsd is known, wherein Alsd represents average self-discharge current of the group of batteries, and lb# represents the current through the corresponding battery#. The average self-discharge current of the group of batteries is preferably determined as a ratio of total self-discharge current of the group of batteries to a number of the batteries in the group being tested, wherein the group of batteries is regarded as an equivalent battery in calculation of total selfdischarge current, wherein the total self-discharge current is determined using a galvanostatic method.

[0162] The galvanostatic method preferably includes the steps of applying a first constant current (11) and a second constant current (12) to the group of batteries connected in parallel for a- period of time (dt 1 ) and for the same or a different period of time (dt2) respectively, wherein the currents 11 and 12 are low enough not to interrupt the electrochemical balance of the group of batteries; measuring a first voltage change (dVI ) and a second voltage change (dV2) of the group of batteries over the periods of time dt1 and dt2, respectively; calculating a first voltage change rate (dV1 / dt1 ) for the period of time dt1 at the current H and a second voltage change rate (dV2 / dt2) for the period of time dt2 at the current 12 ; calculating total self-discharge current (Tlsd) and total dynamic capacitance (TDNC) of the group of batteries being tested by solving equations (1 ) and (2), wherein equation (1 ) is (d V1 / dt1 ) * TDNC - 11 + Tlsd , and equation (2) is (dV2 / dt2) ‘ TDNC = I2 + Tlsd.

[0163] A method has been disclosed for evaluating selfed ischarge of a battery using the DBA described a few paragraphs above that includes the two terminals (VH) and (VL) and a circuit block for voltage measurement (VM) to measure a first differential OCV (DOCV1 ) and a second differential OCV (DOCV2) against the standard battery (SB) representing a difference between the reference voltage and the voltage of the terminal (VH) at two different times T1 and T2, wherein the battery being tested is connected to the terminals (VH) and (VL), wherein the DBAfurther comprises a first current sensor connected to the SB in series for measuring the current throughthe SB and providing feedback to control an but put current from the control circuit, and wherein the current through the SB is controlled to be equal to self-discharge current of the SB, whereby the voltage of the SB is kept constant at its open-circuit voltage (OCV); calculating a differential DOCV (ADOCV) between two differential OC Vs for a period from T1 to T2 (At); and evaluating, on the basis of a ratio of ADOCV to At, the self-discharge status of the battery being tested . The battery being tested preferably includes a group of batteries, and the method preferably further comprising sorting the group of batteries according to the self-discharge status. The method preferably further comprises calculating self-discharge current (Isd) of one or more batteries in the group on the basis, of known dynamic capacitance (DNC) value of one or more batteries in the group or average DNC value of the group of batteries. The averageDNC value of the group of batteries is preferably determined as a ratio of total DNC (TDNC) of the group of batteries to a number of the batteries in the group being tested, wherein the group of batteries is regarded as an equivalent battery in calculation ofTDNC, wherein the DNC value of One or more batteries in the group or TDNC of the group of batteries is determined using a galvanostatic method.

[0164] The galvanostatic method preferably comprises the stops of applying a first constant current (11 ) and a second constant current (12) to a battery in the group or the group of batteries being tested for a period of time (dtl) and for the same or a different period of time (dt2), respectively, wherein the currents 11 and 12 are low enough hot to interrupt the electrochemical balance of the battery or the group of batteries; measuring a first voltage change (dV1) and a second voltage change (dV2) of the battery or the group of batteries over the periods of time dtl and dt2 respectively; calculating a first voltage change rate (dV1 / dt1 ) for the period of time dtl at the current 11 and a second voltage change rate (dV2 / dt2) for the period of time dt2 at the current12 ; calculating Isd and dynamic capacitance (DNC) of the battery being tested by solving equations (1) and (2), wherein equation (1) is (dV1 / dt1) * DNC = 11 + Isd , and equation (2) is (dV2 / dt2) * DNC = I2 + Isd, or calculating total self-discharge currentTlsd and total dynamic capacitance (TDNC) of the group of batteries being tested by solving equations (3) and (4), wherein equation (3) is (dV1 / dt1) * TDNC = 11 + Tlsd , and equation (4) is (dV2 / dt2) * TDNC = I2 + Tlsd.

[0165] A method for measuring direct current internal resistance (DCIR) of a battery includes the steps of: applying a first current and a second current to a battery being tested at two different times T1 and T2, wherein a battery being tested is connected to a DBA described above via terminals (VH) and (VL) , wherein the DBA further includes two terminals (IH) and (IL) connected to a circuit block for current measurement (IM) , wherein a sensor is connected between terminals (IH) and (IL) and connected with the battery in series for measuring the current through the battery; measuring a differential current (Al) representing a- difference between a first measured current and a second measured current of the battery for a period from T1 to T2 by means of the IM; measuring a first differential voltage and a second differential voltage representing a difference between the reference voltage and the voltage of the terminal (VH) while applying the first current and the second current respectively by means of the VM; calculating a change of differential voltage. (AV) of the battery representing the difference between the first differential voltage and the second differential voltage for a period from T1 to T2; calculating the DCIR of the battery being tested as equal to AV / AI.

[0166] An auto analyzer has been disclosed for evaluating batteries that includes a power supply; one or more processors; and one or more storage media storing instructions executable by the one or more processors, wherein the instructions,. when executed, cause the auto analyzer to perform Operations for executing the steps in the methods described above.|00167] A battery testing apparatus has been disclosed that includes a normal battery operating as a standard battery (SB); a constant current source configured to apply a controllable current through the normal battery (Isb) that is equal to its selfdischarge current, whereby a voltage of the normal battery is held constant at its open-circuit voltage (OCV); and a positive terminal (1OH) and a negative terminal (IOL) configured to connect a battery under test therebetween, wherein the voltage between the terminal (IOH) and the terminal (IOL) is kept at a constant value approximately equal to the voltage of the SB within a desired precision. The battery testing apparatus preferably further comprising a first current sensor configured to measure the current through the SB and to provide feedback to control an output current (It) from the constant current source. The normal battery preferably comprises a secondary rechargeable battery; which is preferably the same type as the battery under test.

[0168] The battery testing apparatus preferably further includes terminals (VH) and (VL) configured to connect a battery under test therebetween, wherein the terminal (VL) is connected to the negative terminal of the SB; and a circuit block for voltage measurement (VM) configured to measure differential voltage between a reference voltage and the voltage of the battery under test, wherein the VM has a first lead connected to the terminal (VH) and a second lead connected to the positive terminal of the SB, wherein the reference voltage is determined on the basis of the voltage of the SB. A plurality of resistors are preferably included and configured to divide the voltage of the SB into a plurality of reference voltages within a range not greater than a value of the voltage of the SB. A circuit block for voltage measurement(VM) having a first lead connected to the terminal (VH) and a second lead connected to a multiplexer configured to select one from the reference voltages is preferably included, whereby the VIVI is configured to measure differential voltage between a programmable reference voltage and the voltage of the battery under test.

[0169] A battery analyzer for testing a battery has been disclosed, which includes: a normal battery operating as a standard battery (SB); a control circuit configured to apply a controllable current through the normal battery (Isb) that is equal to its self-discharge current, whereby a voltage of the normal battery is held constant at its open-circuit voltage (OCV); a first current sensor configured to measure thecurrent through the SB and to provide feedback to control an output current (It) from the control circuit; a positive terminal (IOH) and a negative, terminal (IOL) configured to connect a battery under test therebetween, wherein the voltage between the terminal (IOH) and the terminal (LOL) is kept at a constant value approximately equal to the voltage of the SB within a desired precision; and a first switch configured to connect or disconnect the current Isb and a second switch configured to connect or disconnect the current flowing to the positive terminal.

[0170] A battery analyzer may include a secondary rechargeable battery operating as a standard battery (SB); a galvanostat configured to apply a controllable current through the normal battery (Isb) that is equal to its self-discharge current, whereby a voltage of the normal battery is held constant at its open-circuit voltage(OCV); a first current sensor configured to measure the current through the SB and to provide feedback to control an output current (It) from the galvanostat, wherein a second current sensor is configured to measure the current It; a positive terminal (IOH) and a negative termina l (IOL) configured to connect a battery under test therebetween, wherein the voltage between the terminal (IOH) and the terminal (IOL) is kept at a constant value approximately equal to the voltage of the SB within a desired precision; and a first. switch configured to connect or disconnect the current Isb and a second switch configured to connect or disconnect the current flowing to the positive terminal.

[0171] A differential battery analyzer (DBA) has been disclosed that includes a secondary rechargeable battery operating as a standard battery (SB): a galvanostat configured to apply a controllable current through the normal battery (Isb) that is equal to its self-discharge current, whereby a voltage of the norma] battery: is held constant at its open-circuit voltage (OCV); a first current sensor configured to measure the current through the SB and to provide feedback to control an output current (It) from the galvanostat, wherein a second current sensor is configured to measure the current It; a positive terminal (IOH) and a negative terminal (IOL) configured to connect a battery under test therebetween, wherein the voltage between the terminal (IOH) andthe terminal (IOL) is kept at a constant value approximately equal to the Voltage of the SB within a desired precision; a first switch configured to connect or disconnect the current Isb and a second switch configured to connect or disconnect the current flowing to the positive terminal; another two terminals (VH) and (VL) cohfigured to connect a battery under test therebetween, wherein the terminal (VL) is connected to the negative terminal of the SB; and a circuit block for voltage measurement (VM) configured to measure differential voltage between a reference voltage and the voltage of the battery under test, wherein the VM has a first lead connected to the terminal(VH ) and a second lead connected to the positive or negative terminal of the SB via a third switch, whereby the reference voltage is determined as the voltage of the SB or zero. The DBS preferably further includes a circuit block for current measurement(IM) cohfigured to measure current Of the battery under test via another two terminals (IH) and (IL); and a power supply.EMBODIMENTS OF THE PRESENT INVENTION

[0172] Embodiments of the present invention include the following.

[0173] In one aspect, the disclosure is directed to a method for measuring selfdischarge current (Ad) of cells in a group that are connected in parallel. The method Comprises the steps of: applying a constant current ( / o) to a group of cells Connected in parallel with each other; measuring current A# for at least one cell, wherein A# represents the current through the corresponding cell#; and calculating self-discharge current of at least one cell (denoted as Ad#) from the equation : Ad# = AAd - (A# - loir?) on the assumption that the difference of dynamic capacitance (DNC) of all cells in the group can be ignored in calculation of self-discharge current and AAd is known, wherein AAd represents average self-discharge current of ail cells in the group and n represents the number of cells in the group.

[0174] In another aspect, the disclosure is directed to a method for measuring Self-discharge current (Ad) of pells in a group that are connected in parallel. Themethod comprises the steps of: applying a constant current (fo) to a group of cells connected in para Del with each other, wherein the absolute value of Io is controlled to be equivalent to that of total self-discharge current (T / sci) of the group of cells, and assuming T / sd is known; measuring current / b# for at least one cell, wherein It# represents the current through the corresponding cell#; and calculating self-discharge current of at least one cell (denoted as / sd#) from the equation: / sd# = - / b# on the assumption that the difference of dynamic capacitance (DNC) of all cells in the group can be ignored in calculation of self-discharge current.

[0175] In another aspect, the disclosure is directed to a method for measuring self-discharge current ( / sd) of cells in a group that are connected in parallel. The method comprises the steps of: applying a constant voltage to a group of cells connected in parallel with each other to make a current ( / o) flowing through the group of cells; measuring current / b# for at least one cell, Wherein It# represents the current through the corresponding cell#; and calculating self-discharge current of at least one cell (denoted as / sc#) from the equation: / sd# = - It#.

[0176] In one illustrative embodiment, the current (to) is applied using a differential battery analyzer (DBA). The DBA comprises: a normal battery operating as a standard battery (SB): a constant current source configured to apply a controllable current through the normal battery ( / sb) that is equal to its self-discharge current, whereby a voltage of the normal battery is held constant at its open-circuit voltage (OCV); and a positive terminal (IOH) and a negative terminal (IOL) Configured to connect a battery under test therebetween, wherein the voltage between the terminal(IOH) and the terminal (IOL) is kept at a constant value approximately equal to the voltage of the SB within a desired precis ioh.

[0177] In another aspect, the disclosure is directed to a method for measuring self-discharge current (M of cells in a group that are connected in series with an equalizer for each cell. The method comprises the steps of: allowing enough time for a group of cells connected in series to reach balance status, wherein each cellof the group is connected to an equalizer to keep the cells under same voltage with equalizers on, and wherein each equalizer has a fully bidirectional charge / discharge channel with at least two current ranges, and wherein at least one current range is low enough to be capable of measuring self-discharge current (SDC); measuring current / eqp# for at least one equalizer in response to the cells' reaching balance status, wherein / eqp# represents the current flowing through equalizer# connected to Corresponding cell#; and calculating self-discharge current of at least one cell# (denoted as / sd#) from an equation: / sd# - - / eqp#.

[0178] In another aspect, the disclosure is directed to a method for measuring self-discharge current ( / sd) of parallel cell groups (PCGs) that are connected in series with an equalizer for each PCG; The method comprises the steps of: allowing enough time for PCGs connected in series to reach balance status, wherein each PCG is connected to an equalizer to keep the PCGs under same Voltage with equalizers on, and wherein each equalizer has a fully bidirectional charge / discharge channel with at least two current ranges, and wherein at least one current range is low enough to be capable of measuring self-discharge current (SDC); measuring current / eqp# for at least one equalizer in response to the PCGs' reaching balance: status, wherein / eqp# represents the current flowing, through equalizer# connected to corresponding PCG#; and calculating self-discharge current of at least one PCG# (denoted as / sd#) from an equation: ka# = - / eqp#.

[0179] In another aspect, the disclosure is directed to a method for using current of cells in a parallel group at open circuit condition as a quality control method used in forming and testing batteries. The method comprises the steps of: allowing enough time for a group of cells being tested to reach balance Status, and measuring current k# flowing into corresponding cell#, wherein the group of cells are connected in parallel with each other but without connecting to any power supply to keep the group of cells in open circuit; and using the / p# value as a standard for battery quality judgment and / or cell classification.

[0180] In one illustrative embodiment, the method further comprises the steps of: using abnormal distributed current through cell (A#) of a parallel battery group, at open circuit, as a criterion for cell safety judgment.

[0181] In another aspect, the disclosure is directed to a method for using current of cells in a parallel group as a quality control method used in forming and testing batteries. The method comprises the steps of: applying current to the cells connected in a parallel group; measuring current / b# flowing into a corresponding cell#; and using abnormal distributed current through coll# (A#) of the parallel group as a criterion for cell safety judgment.100182| In another aspect, the disclosure is directed to a method for using current of cells in. a parallel group at open circuit condition as a quality control method used in forming and testing batteries. The method comprises the steps of: allowing enough time for a group of cells being tested to reach balance status, and measuring current k# flowing into corresponding cell#, wherein the group of cells are connected in parallel with each other, but without connecting to any power supply to keep the group of cells in open circuit; using measured or statistically obtained average selfdischarge current A / sd of the parallel group to get a self-discharge current (Ad#) of at least one ceil#, according to Ad# = AAd - A# derived from A# = AAd - Ad#; and using the Ad# value obtained as a standard for cell quality judgment and / or cell classification.

[0183] In another aspect, the disclosure is directed to an auto analyzer for evaluating batteries. The auto analyzer for evaluating batteries comprises a power supply, one or more processors and one: or more storage media storing instructions executable by the one or more processors, wherein the instructions, when executed, cause the auto analyzer to perform operations according to any one of the methods described above.

[0184] In another aspect, the disclosure is directed to an equalizer plus (EQP) of a battery. The EQP of a battery comprises: a control circuit configured to apply a controllable current to a normal battery as a standard battery (SB) inside theEQP, wherein the current through the SB ( / sb) is controlled to be equal to its selfdischarge current, whereby a voltage of the SB is kept constant at its open-circuit voltage (OCV); and two terminals (IOH) and (IOL) for connecting a battery under test therebetween, wherein the terminal (IOH) is connected to an end of a branch where the SB is located, and the voltage between the terminal (IOH) and the terminal (IO L) is kept ata constant value approximately equal to the voltage of the SB within a desired precision, and the terminal (IOL) is connected to the other end of the branch; and a fully bidirectional charge / dischargo channel between the terminals (IOH.) and (IOL) for measuring current, wherein the channel has at least two current ranges, and wherein at least one current range is low enough to be capable of measuring self-discharge current.

[0185] The embodiments described herein are merely examples for the sake of clarity and are not intended to limit the scope of the present invention, Other variations or modifications may be made by those skilled in the field of the abovedescribed technology. There is no heed and no Way to describe all possible implementations of the principles of the difference measurement technology described herein. Obvious changes or variations resulting therefrom are still within the scope of the invention.

Claims

CLAIMSWhat is claimed is:

1. A method for measuring self-discharge of cells in a group under a same voltage comprising the steps of: measuring current Mt for at least one cell in the group of cells, wherein / b# represents the current through the corresponding cell#; and evaluating the self-discharge of at least one cell in the group of cells based on the current / b#.

2. The method of claim 1, wherein evaluating the self-discharge of at least one cell in the group based on the current Mt comprises the step of: using the / b# value as a standard for cell quality judgment and / or cell classification.

3. The method of claim 1 . wherein the cells in the group are connected in parallelMh each other cell .

4. The method of claim 3, wherein prior to measuring current / b# for at least one cell in the group of cells, the method further comprises the step of: applying a constant current (to) to the group of cells.

5. The method of claim 4, wherein evaluating the self-discharge of at least one cell in the group of cells based on the current / b# comprises the step of: calculating self-discharge current of at least one cell# (denoted as / sd#) from an equation: / sd# = A / sd - (fe# - / o / n) on the assumption that :a difference of dynamic capacitance (DNC) of the cells can be ignored in calculation of seif-discharge current( / sd) and A / sd is known, wherein A / sd represents average seif-discharge current of all cells in the group and n represents a number of cells in the group.

6. The method of claim 5, wherein an absolute value of / o is controlled to be equivalent to that of total self-discharge current (T Ad) of the group of cells,, and assuming TA; is known, the equation in claim 5 becomes; A;# = -A# on the assumption that a difference of dynamic capacitance (DNC) of the cells can be ignored in calculation of self-discharge current.

7. The method of claim 1 , further comprising the step of: using abnormal distri butod current through cell# (A#) of the group of cells as a criterion for cell safety judgment.

8. The method of claim 3, wherein prior to measuring current A# for at least one cell in the group of cells, the method further comprises the step of: applying a constant voltage to the group of cells to make a Current flow through the group of cells.

9. The method of claim 8, wherein evaluating the self-discharge of at least one cell in the group of cells based on the current A# comprises the step of: calculating self-discharge current of at least one cell (denoted as Ad#) from the equation: Ad# = - A#.

10. The method of claim 2, Wherein the group of cells are not connected to any power supply to keep in open circuit, and prior to measuring current A# for at least one cell in the gro up of cells, the method further comprises the step of: allowing enough time for the group of cells to reach balance status.

11. The method of 10, wherein evaluating the self-discharge of at least one cell in the group based on the Current / b# comprises the step of: using measured or statistically obtained average self-discharge current AAd of theparallel group to get self-discharge current ( / sd#) of at least one cell# according t12. The method of claim 1 , wherein the cells in the group are connected in series and each cell of the group is connected to an equalizer to keep the cells under same voltage with equalizers on, and wherein each equalizer has a fully bidirectional charge / discharge channel with at least two current ranges, and wherein at least one current range is low enough to be capable of measuring self-discharge current (SDC), and wherein the step of evaluating the self-discharge of at least one cell in the group of cells based on the current comprises the step of:calculating self-discharge current of at least one cell# (denoted as / sd#) based on measured currentand current flowing through combinations of the cell and corresponding equalizer, wherein the combinations are connected in series.

13. A method for measuring self-discharge current ( / sd) of cells in a group that are connected in series with an equalizer for each cell comprising the steps of: allowing enough time for a group of cells connected in series to reach balance Status, wherein each cell of the group is connected to an equalizer to keep the cells: under same voltage, with equalizers on, and wherein each equalizer has a fully bidirectional charge / discharge channel with at least two current ranges, and wherein at least one current range is low enough to be capable of measuring self-discharge current (SDC) : measuring currentfor at least one equalizer in response to the cells' teaching balance status, whereinrepresents the current flowing through equalizer# connected to correspondingcell#; and calculating self-discharge current of at least one cell# (denoted as Is#) from an equation: / 14. The method of claim 13, wherein the cells in the group that are connected in series with an equalizer for each cell comprises parallel cell groups (PCGs) in a group that are connected in series with an equalizer for each PCG , and wherein / eqp# represents the current flowing through an equalizer# connected to a corresponding PCG#.

15. An auto analyzer for evaluating batteries comprising: a power supply; one or more processors; and one or more storage media storing instructions executable by the one or more processors, wherein the instructions, when executed, cause the auto analyzer to perform Operations according to any one of claims 1-14.

16. The auto analyzer for evaluating batteries of claim 15, wherein the power supply comprises a battery testing apparatus that comprises: a normal battery operating as a standard battery (SB); a constant current source configured to apply a controllable current through the normal battery ( / sb) that is equal to its self-discharge current, whereby a voltage Of the normal battery is held constant at its open-circuit voltage (OCV); and a positive terminal ( IO H) and a negative terminal (IOL) configured to connect a battery under test therebetween, wherein the voltage between the terminal (IOH) and the terminal (IOL) is kept at a constant value approximately equal to the voltage of theSB within a desired precision.

17. An equalizer plus (EQP) of a battery comprising: a control circuit configured to apply a controllable current to a normal battery as aStandard battery (SB) inside the EQP, wherein the current through the SB ( is controlled to be equal to its self-discharge current,whereby a. Voltage of the SB is kept constant at its open-circuit Voltage (OCV): and two terminals (IOH) and ( 10 L) for connecting a battery under test therebetween, wherein the terminal (IOH) is connected to an end of a branch where the SB is located, and the voltage between the terminal (IOH) and the terminal (IOL) is kept at a constant value approximately equal to the voltage of the SB within a desired precision, and the terminal (IO L) is connected to the other end of the branch; and a fully bidirectional chargc / discharge channel between the terminals (IOH) and(IOL) for measuring current, wherein the channel has at least two current ranges, and wherein at least one current range is low enough to be capable of measuring selfdischarge current.

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