Oil-in-water emulsion cosmetic composition
Stabilizing vitamin A or its derivatives in cosmetic compositions using a polar oil without hydroxyl groups and PEG-12 dimethicone addresses stability and usability issues, enabling effective skin benefits.
Patent Information
- Application Number
- PCT/JP2024/044164
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2023-12-27
- Filing Date
- 2024-12-13
- Publication Date
- 2025-07-03
AI Technical Summary
Vitamin A and its derivatives are unstable in existing oil-in-water emulsified cosmetic compositions, leading to issues with stability and usability.
Incorporating a polar oil without a hydroxyl group, such as glyceryl tri(caprylate/caprate), diethylhexyl succinate, or diisobutyl adipate, along with PEG-12 dimethicone, stabilizes vitamin A or its derivatives, enhancing the composition's stability and usability.
The composition achieves improved stability and usability of vitamin A or its derivatives, allowing for effective skin firming and wrinkle/stain improvement.
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Abstract
Description
Oil-in-water emulsion cosmetic composition
[0001] The present invention relates to an oil-in-water emulsion cosmetic composition.
[0002] Vitamin A and its derivatives are known to have the effect of improving wrinkles and blemishes, and are effective materials in the cosmetics industry.
[0003] For example, Patent Document 1 discloses an oil-in-water emulsion composition containing (a) polyvinyl alcohol, (b) vinyl acetate-vinylpyrrolidone copolymer, (c) polyhydric alcohol, (d) an oil-soluble drug, and (e) an oil component, the composition having a viscosity of 2000 mPa·s or less and a particle size of 5 μm or less. Retinol, a type of vitamin A, is disclosed as the oil-soluble drug (d).
[0004] International Publication No. 2021 / 172430
[0005] Vitamin A and its derivatives (e.g., vitamin A esters) are known to be unstable, and there is room for improvement in the usability of vitamin A and its derivatives.
[0006] The present invention aims to improve the above-mentioned circumstances, and its object is to provide an oil-in-water emulsion cosmetic composition containing vitamin A or a vitamin A derivative, which has excellent stability and good usability.
[0007] The present invention that achieves the above object is as follows.
[0008] Aspect 1: An oil-in-water emulsion cosmetic composition comprising vitamin A or a vitamin A derivative, a polar oil having no hydroxyl groups, and PEG-12 dimethicone. Aspect 2: The oil-in-water emulsion cosmetic composition according to Aspect 1, wherein the polar oil having no hydroxyl groups comprises at least one selected from the group consisting of pentaerythrityl tetraethylhexanoate, neopentyl glycol dicaprate, caprylic / capric triglyceride, diethylhexyl succinate, cetyl ethylhexanoate, diisopropyl sebacate, and diisobutyl adipate. Aspect 3: An oil-in-water emulsion cosmetic composition comprising vitamin A or a vitamin A derivative and a polar oil having no hydroxyl groups, wherein the polar oil having no hydroxyl groups comprises at least one selected from the group consisting of caprylic / capric triglyceride, diethylhexyl succinate, diisopropyl sebacate, and diisobutyl adipate. Aspect 4: The oil-in-water emulsion cosmetic composition according to any one of Aspects 1 to 3, wherein the vitamin A derivative is a vitamin A ester. Aspect 5: The oil-in-water emulsion cosmetic composition according to any one of Aspects 1 to 4, wherein the amount of the polar oil having hydroxyl groups is 5,000 parts by mass or less per 100 parts by mass of the vitamin A or vitamin A derivative. Aspect 6: The oil-in-water emulsion cosmetic composition according to any one of Aspects 1 to 5, wherein the amount of the polar oil having hydroxyl groups is 50 parts by mass or less per 100 parts by mass of the polar oil having no hydroxyl groups. Aspect 7: The oil-in-water emulsion cosmetic composition according to any one of Aspects 1 to 6, wherein the content of the vitamin A or vitamin A derivative is 0.05 to 1.0% by mass. Aspect 8: The oil-in-water emulsion cosmetic composition according to any one of Aspects 1 to 7, wherein the content of the polar oil having no hydroxyl group is 7.0 to 30% by mass. Aspect 9: The oil-in-water emulsion cosmetic composition according to Aspect 1 or 2, wherein the content of the PEG-12 dimethicone is 0.5 to 2.0% by mass.
[0009] According to the present invention, it is possible to provide an oil-in-water emulsion cosmetic composition containing vitamin A or a vitamin A derivative, which has excellent stability and good usability.
[0010] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to the preferred embodiments. However, the present invention is not limited to the following embodiments, and various modifications can be made within the scope of the present invention.
[0011] <Oil-in-Water Emulsion Cosmetic Composition> The oil-in-water emulsion cosmetic composition of the present invention (hereinafter also simply referred to as "the composition of the present invention") may be an oil-in-water emulsion cosmetic composition comprising vitamin A or a derivative of vitamin A, a polar oil having no hydroxyl groups, and PEG-12 dimethicone, or an oil-in-water emulsion cosmetic composition comprising vitamin A or a derivative of vitamin A and a polar oil having no hydroxyl groups, wherein the polar oil having no hydroxyl groups comprises at least one selected from the group consisting of caprylic / capric triglyceride, diethylhexyl succinate, and diisobutyl adipate.
[0012] The composition of the present invention is excellent in stability and ease of use, whether it contains vitamin A or a derivative of vitamin A, a polar oil having no hydroxyl groups, and PEG-12 dimethicone, or whether it contains vitamin A or a derivative of vitamin A and a polar oil having no hydroxyl groups, and the polar oil having no hydroxyl groups includes at least one selected from the group consisting of caprylic / capric triglyceride, diethylhexyl succinate, and diisobutyl adipate.
[0013] Because vitamin A is unstable, it is conceivable to select, for example, a nonionic surfactant rather than an ionic surfactant when preparing an oil-in-water emulsion cosmetic composition containing vitamin A. However, through intensive research by the present inventors, it has been found that even when a nonionic surfactant is used, the vitamin A in the prepared composition may become unstable. Furthermore, it has been found that although vitamin A esters, which are derivatives of vitamin A, appear to be relatively stable compared to vitamin A, they may undergo, for example, hydrolysis or transesterification due to the influence of an oily medium used in combination, and as a result, the vitamin A esters may also become unstable.
[0014] Further, through intensive research, the present inventors investigated the type of polar oil to be blended into the composition and various nonionic surfactants. As a result, it was found that when a polar oil without a hydroxyl group is used in combination with PEG-12 dimethicone, vitamin A or a vitamin A ester can be stably present in an oil-in-water emulsion cosmetic composition, and furthermore, the composition is easy to use.
[0015] Furthermore, surprisingly, through further intensive research, the present inventors have discovered that by using a specific type of polar oil that does not have a hydroxyl group, vitamin A or a vitamin A ester can be stably present in an oil-in-water emulsion cosmetic composition, and that the composition is easy to use.
[0016] In the present invention, the stability of vitamin A or a vitamin A derivative can be evaluated, for example, by the method described in the Examples below.
[0017] In the present invention, the usability can be evaluated comprehensively mainly based on the fresh feeling and sticky feeling when applying the cosmetic composition.
[0018] <Vitamin A or Vitamin A Derivative> The composition of the present invention contains vitamin A or a derivative of vitamin A. By containing vitamin A or a derivative of vitamin A in the composition of the present invention, it is possible to improve skin firmness and also to impart the effect of improving wrinkles and age spots. Of course, in the present invention, the composition of the present invention may contain both vitamin A and a derivative of vitamin A.
[0019] In the present invention, vitamin A is a general term for retinol, retinal, and retinoic acid, which are classified as fat-soluble vitamins. Therefore, the vitamin A that can be contained in the composition of the present invention may include at least one selected from the group consisting of retinol, retinal, and retinoic acid.
[0020] In the present invention, the vitamin A derivative is not particularly limited and may be, for example, a vitamin A ester. Examples of vitamin A esters include, but are not limited to, vitamin A acetate, vitamin A palmitate, and vitamin A propionate.
[0021] More specifically, in one embodiment of the present invention, the derivative of vitamin A may be retinol acetate, and in another embodiment of the present invention, the derivative of vitamin A may be retinol palmitate.
[0022] In the composition of the present invention, the content of vitamin A or a vitamin A derivative is not particularly limited and may be adjusted appropriately depending on the purpose and use. For example, the content of vitamin A or a vitamin A derivative (when both vitamin A and a vitamin A derivative are contained, the total content thereof) may be 0.05% by mass or more, 0.06% by mass or more, 0.07% by mass or more, 0.08% by mass or more, 0.09% by mass or more, 0.10% by mass or more, 0.15% by mass or more, 0.20% by mass or more, 0.25% by mass or more, 0.30% by mass or more, 0.35% by mass or more, 0.40% by mass or more, 0.45% by mass or more, 0.50% by mass or more, 0.60% by mass or more, 0.70% by mass or more, 0.80% by mass or more, 0.90% by mass or more, 0.10% by mass or more, 0.15% by mass or more, 0.20% by mass or more, 0.25% by mass or more, 0.30% by mass or more, 0.35% by mass or more, 0.40% by mass or more, 0.55% by mass or more, 0.60% by mass or more, 0.70% by mass or more, 0.80% by mass or more, 0.90% by mass or more, 0.10% by mass or more, 0.15% by mass or more, 0.20% by mass or more, 0.25% by mass or more, 0.30% by mass or more, 0.35% by mass or more, 0.40% by mass or more, 0.45% by mass or more, 0.50% by mass or more, 0.60% by mass or more, 0.7 It may be 50% by mass or more, 0.55% by mass or more, 0.60% by mass or more, 0.65% by mass or more, 0.70% by mass or more, 0.75% by mass or more, 0.80% by mass or more, 0.85% by mass or more, 0.90% by mass or more, 0.95% by mass or more, or 1.0% by mass or more, and may be 1.0% by mass or less, 0.9% by mass or less, 0.8% by mass or less, 0.7% by mass or less, 0.6% by mass or less, 0.5% by mass or less, 0.4% by mass or less, 0.3% by mass or less, or 0.2% by mass or less.
[0023] <Polar Oil Having No Hydroxyl Group> The composition of the present invention contains a polar oil having no hydroxyl group. In the present invention, a polar oil having no hydroxyl group is preferred from the viewpoint of not undergoing a transesterification reaction with the vitamin A ester.
[0024] In the present invention, polar oil refers to oils other than silicone oils that have high polarity among oils that can be used in cosmetics, and for example, refers to oils with an IOB value of 0.10 or more, 0.15 or more, 0.20 or more, 0.25 or more, 0.30 or more, 0.35 or more, 0.40 or more, 0.45 or more, 0.50 or more, or 0.55 or more. The IOB value of the polar oil according to the present invention may be 0.60 or less, 0.55 or less, 0.50 or less, 0.45 or less, 0.40 or less, 0.35 or less, 0.30 or less, 0.25 or less, or 0.20 or less. The IOB value is an abbreviation for Inorganic / Organic Balance (inorganic / organic ratio), and is a value that represents the ratio of inorganic value to organic value, and is an index showing the degree of polarity of an organic compound. Specifically, the IOB value is expressed as IOB value = inorganic value / organic value. The "inorganic value" and "organic value" are set according to the type of atom or functional group, such as 20 for one carbon atom in a molecule and 100 for one hydroxyl group. The IOB value of an organic compound can be calculated by integrating the "inorganic values" and "organic values" of all atoms and functional groups in the organic compound (see, for example, "Organic Conceptual Diagram - Fundamentals and Applications" by Yoshio Koda, pp. 11-17, Sankyo Publishing, 1984).
[0025] The polar oil may include, for example, an ester oil, an ultraviolet absorber, or a mixture thereof. Therefore, in the present invention, the polar oil having no hydroxyl groups may include, for example, at least one of an ester oil having no hydroxyl groups, an ultraviolet absorber having no hydroxyl groups, or a mixture thereof.
[0026] More specifically, the polar oil having no hydroxyl group may include, for example, at least one selected from the group consisting of pentaerythrityl tetraethylhexanoate, neopentyl glycol dicaprate, caprylic / capric triglyceride, diethylhexyl succinate, cetyl ethylhexanoate, diisopropyl sebacate, and diisobutyl adipate.
[0027] Among the above, the polar oil having no hydroxyl group preferably contains at least one selected from the group consisting of caprylic / capric triglyceride, diethylhexyl succinate, diisopropyl sebacate, and diisobutyl adipate, because when the polar oil having no hydroxyl group contains at least one selected from the group consisting of caprylic / capric triglyceride, diethylhexyl succinate, and diisobutyl adipate, vitamin A or a derivative of vitamin A can be stably present in the composition of the present invention and the composition is easy to use.
[0028] In the composition of the present invention, the content of the polar oil having no hydroxyl group is not particularly limited, and may be, for example, 7.0 mass% or more, 8.0 mass% or more, 9.0 mass% or more, 10 mass% or more, 11 mass% or more, 12 mass% or more, 13 mass% or more, 14 mass% or more, or 15 mass% or more, relative to the entire composition, or 30 mass% or less, 29 mass% or less, 28 mass% or less, 27 mass% or less, 26 mass% or less, 25 mass% or less, 24 mass% or less, 23 mass% or less, 22 mass% or less, 21 mass% or less, 20 mass% or less, 19 mass% or less, 18 mass% or less, 17 mass% or less, 16 mass% or less, or 15 mass% or less.
[0029] In addition, in the composition of the present invention, the polar oil not having a hydroxyl group is, for example, 3000 parts by mass or more, 3500 parts by mass or more, 4000 parts by mass or more, 4500 parts by mass or more, 500 parts by mass or more, 5500 parts by mass or more, 6000 parts by mass or more, 6500 parts by mass or more, 7000 parts by mass or more, 7500 parts by mass or more, 8000 parts by mass or more, 9000 parts by mass or more, 100 parts by mass or more of vitamin A or a derivative of vitamin A (when both vitamin A and a derivative of vitamin A are contained, the total of these is 100 parts by mass). or more, 8,000 parts by mass or more, 8,500 parts by mass or more, 9,000 parts by mass or more, 9,500 parts by mass or more, 10,000 parts by mass or more, 11,000 parts by mass or more, 12,000 parts by mass or more, 13,000 parts by mass or more, 14,000 parts by mass or more, or 15,000 parts by mass or more, and may be 18,000 parts by mass or less, 15,000 parts by mass or less, 12,000 parts by mass or less, 10,000 parts by mass or less, 8,000 parts by mass or less, or 5,000 parts by mass or less.
[0030] <PEG-12 Dimethicone> The composition of the present invention may contain PEG-12 dimethicone. In particular, when the composition of the present invention contains any of the above-mentioned polar oils having no hydroxyl group, it is preferable that the composition of the present invention contains PEG-12 dimethicone.
[0031] PEG-12 dimethicone is a polymer obtained by substituting a portion of the methyl groups present in the dimethicone side chain with ethylene oxide (approximately 12 moles). It is a silicone surfactant classified as a linear silicone polyether-modified silicone. PEG-12 dimethicone also falls under the category of nonionic surfactants. It can also function as an emulsifier in PEG-12 dimethicone compositions.
[0032] When the composition of the present invention contains PEG-12 dimethicone, the content of PEG-12 dimethicone is not particularly limited and may be, for example, 0.5% by mass or more, 0.6% by mass or more, 0.7% by mass or more, 0.8% by mass or more, 0.9% by mass or more, or 1.0% by mass or more, and may be 2.0% by mass or less, 1.9% by mass or less, 1.8% by mass or less, 1.7% by mass or less, 1.6% by mass or less, 1.5% by mass or less, 1.4% by mass or less, 1.3% by mass or less, 1.2% by mass or less, 1.1% by mass or less, or 1.0% by mass or less, relative to the entire composition.
[0033] <Water> The composition of the present invention contains water. Water constitutes the external phase of the oil-in-water emulsion composition.
[0034] The water used in the composition of the present invention is not particularly limited and may be, for example, water used in cosmetics and quasi-drugs, such as ion-exchanged water, distilled water, ultrapure water, and tap water.
[0035] In the composition of the present invention, the content of water is not particularly limited and may be appropriately adjusted according to the purpose and use.For example, the content of water may be 20% by mass or more, 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, or 85% by mass or more, and may be 90% by mass or less, 85% by mass or less, 80% by mass or less, 75% by mass or less, 70% by mass or less, 65% by mass or less, 60% by mass or less, or 55% by mass or less, based on the total mass of the composition.
[0036] <Other Components> The following describes other components that may be contained in the composition of the present invention. These other components may be appropriately selected based on the desired formulation and intended use of the cosmetic, and may be blended in an appropriate amount. The present invention is not limited to the other components listed below.
[0037] (Polar Oil Having a Hydroxyl Group) The composition of the present invention may further contain a polar oil having a hydroxyl group, as long as the effects of the present invention are not impaired.
[0038] When the composition of the present invention contains a polar oil having a hydroxyl group, for example, the amount of the polar oil having a hydroxyl group per 100 parts by mass of vitamin A or a vitamin A derivative (100 parts by mass of the total of vitamin A and a vitamin A derivative when both are included) may be 5,000 parts by mass or less, 4,500 parts by mass or less, 4,000 parts by mass or less, 3,500 parts by mass or less, 3,000 parts by mass or less, 2,500 parts by mass or less, 2,000 parts by mass or less, 1,500 parts by mass or less, 1,000 parts by mass or less, 800 parts by mass or less, 500 parts by mass or less, 300 parts by mass or less, 100 parts by mass or less, 50 parts by mass or less, 10 parts by mass or less, 5.0 parts by mass or less, or 1.0 part by mass or less.
[0039] Furthermore, when the composition of the present invention contains a polar oil having a hydroxyl group, for example, the amount of the polar oil having a hydroxyl group per 100 parts by mass of the polar oil not having a hydroxyl group may be 50 parts by mass or less, 40 parts by mass or less, 30 parts by mass or less, 20 parts by mass or less, 10 parts by mass or less, 5.0 parts by mass or less, or 1.0 part by mass or less.
[0040] (Silicone Oil) Examples of silicone oils include, but are not limited to, chain polysiloxanes (dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, etc.), silicone resins forming a three-dimensional network structure, silicone rubbers having an average molecular weight of 200,000 or more, and various modified polysiloxanes (amino-modified polysiloxanes, polyether-modified polysiloxanes, alkyl-modified polysiloxanes, fluorine-modified polysiloxanes, etc.).
[0041] (Hydrocarbon Oil) Examples of hydrocarbon oils include, but are not limited to, hydrogenated polydecene, liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, polyethylene wax, and Fischer-Tropsch wax.
[0042] (Surfactant) The composition of the present invention may further contain a surfactant other than PEG-12 dimethicone. For example, when the composition of the present invention contains the above-mentioned nonionic surfactant other than PEG-12 dimethicone, the content thereof may be, for example, 2.0% by mass or less, 1.5% by mass or less, 1.0% by mass or less, 0.5% by mass or less, 0.1% by mass or less, 0.05% by mass or less, 0.01% by mass or less, or 0.005% by mass or less, relative to the total mass of the composition.
[0043] (Moisturizing Agent) Examples of moisturizing agents include, but are not limited to, glycerin, butylene glycol, dipropylene glycol, PEG-8 (polyethylene glycol), trimethylglycine, glucose, sorbitol, and maltitol.
[0044] (Polyhydric Alcohol) Examples of polyhydric alcohols include, but are not limited to, polyethylene glycol, glycerin, diglycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, 1,2-pentanediol, and hexylene glycol.
[0045] (Water-soluble polymer) Examples of water-soluble polymers include, but are not limited to, acrylic acid / methacrylic acid copolymer, carboxyvinyl polymer, carrageenan, pectin, mannan, curdlan, chondroitin sulfate, starch, glycogen, gum arabic, sodium hyaluronate, tragacanth gum, xanthan gum, mucoitin sulfate, hydroxyethyl guar gum, carboxymethyl guar gum, guar gum, dextran, keratosulfuric acid, locust bean gum, succinoglucan, chitin, chitosan, carboxymethyl chitin, and agar.
[0046] (Other Optional Components) In addition to the components described above, the composition of the present invention may contain, for example, other aqueous components, moisturizers, antioxidants, alcohols, cosmetic ingredients, lecithin, glycolipids, plant extracts, preservatives, fragrances, pH adjusters, pigments, etc., within the scope of not impairing the effects of the present invention.
[0047] <Dosage Form> Examples of dosage forms of the composition of the present invention include, but are not limited to, solid, semi-solid, solid paste, stick, emulsion, liquid, gel, sherbet, cream, ointment, and paste.
[0048] <Uses> The composition of the present invention may be used as a cosmetic or as a raw material for a cosmetic. Furthermore, a cosmetic comprising the composition of the present invention or a cosmetic containing the composition of the present invention can be suitably used, for example, as a skin-beautifying cosmetic, a wrinkle-reducing cosmetic, or a blemish-reducing cosmetic.
[0049] <<Method for Producing the Composition of the Present Invention>> The composition of the present invention is not particularly limited and can be prepared by a conventional method, and the emulsification method is not particularly limited.
[0050] For example, the composition of the present invention can be produced by adding an oil phase (internal phase) to an aqueous phase (external phase) and emulsifying the mixture in an emulsifier. In addition, the oil phase and / or the aqueous phase may be heated as appropriate during preparation.
[0051] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these. Unless otherwise specified, the blending amounts in the tables are expressed in mass %.
[0052] Examples 1 to 7 and Comparative Examples 1 to 3 Based on the formulations in Table 1, oil-in-water emulsion cosmetic compositions of Examples 1 to 7 and Comparative Examples 1 to 3 were prepared.
[0053] Each of the compositions obtained was evaluated for stability and usability based on the following evaluation table. The results are shown in Table 1.
[0054] <Evaluation of Stability> The pharmaceutical stability of the vitamin A derivatives contained in each composition was evaluated as follows.
[0055] More specifically, the sample was stored under high temperature conditions (about 45°C to about 55°C) for about one month, and then the rate of decrease in the vitamin A derivatives relative to the initial value was confirmed.
[0056] The evaluation criteria are as follows: "A": When the rate of decrease from the initial value is less than 11%; "B": When the rate of decrease from the initial value is 11% or more but less than 14%; "C": When the rate of decrease from the initial value is 14% or more.
[0057] <Evaluation of Usability> Each composition was evaluated for usability based on the feel when applied to the skin of a specialist panel. The evaluation criteria are as follows: "A": Fresh and not sticky "B": Fresh but slightly sticky "C": Not fresh enough and sticky
[0058]
[0059]
[0060] As is clear from the results in Table 1, all of the compositions of Examples 1 to 7 were found to be excellent in stability and ease of use. In particular, the compositions of Examples 3, 4, 6, and 7 were found to have the most excellent results in terms of stability and ease of use.
[0061] In contrast, the compositions of Comparative Examples 1 to 3 were found to be easy to use but had poor stability. The reason for this is analyzed as follows: It is presumed that the compositions of Comparative Examples 1 to 3 did not contain a polar oil without a hydroxyl group, and therefore the vitamin A derivatives contained therein could not be stably maintained.
[0062] Comparative Examples 4 and 5 Oil-in-water emulsion cosmetic compositions of Comparative Examples 4 and 5 were prepared based on the formulations in Table 3. The stability and usability were evaluated in the same manner as above, and the results are shown in Table 3.
[0063]
[0064] As is clear from the results in Table 3, the composition of Comparative Example 4 was found to be inferior in usability. Furthermore, the composition of Comparative Example 5, which had different components from those of Comparative Example 4, was found to have good usability but poor stability.
Claims
1. An oil-in-water emulsified cosmetic composition comprising vitamin A or a derivative of vitamin A, a polar oil having no hydroxyl group, and PEG-12 dimethicone.
2. The oil-in-water emulsified cosmetic composition according to claim 1, wherein the polar oil having no hydroxyl group contains at least one selected from the group consisting of pentaerythrityl tetraethylhexanoate, neopentyl glycol dicaprate, glyceryl tri(caprylate / caprate), diethylhexyl succinate, cetyl ethylhexanoate, diisopropyl sebacate, and diisobutyl adipate.
3. An oil-in-water emulsified cosmetic composition comprising vitamin A or a derivative of vitamin A and a polar oil having no hydroxyl group, and wherein the polar oil having no hydroxyl group contains at least one selected from the group consisting of glyceryl tri(caprylate / caprate), diethylhexyl succinate, diisopropyl sebacate, and diisobutyl adipate.
4. The oil-in-water emulsified cosmetic composition according to claim 1 or 3, wherein the derivative of vitamin A is a vitamin A ester.
5. The oil-in-water emulsified cosmetic composition according to claim 1 or 3, wherein the polar oil having a hydroxyl group is 5,000 parts by mass or less with respect to 100 parts by mass of vitamin A or the derivative of vitamin A.
6. The oil-in-water emulsified cosmetic composition according to claim 1 or 3, wherein the polar oil having a hydroxyl group is 50 parts by mass or less with respect to 100 parts by mass of the polar oil having no hydroxyl group.
7. The oil-in-water emulsified cosmetic composition according to claim 1 or 3, wherein the content of vitamin A or the derivative of vitamin A is 0.05 to 1.0% by mass.
8. The oil-in-water emulsified cosmetic composition according to claim 1 or 3, wherein the content of the polar oil having no hydroxyl group is 7.0 to 30% by mass.
9. The oil-in-water emulsified cosmetic composition according to claim 1 or 2, wherein the content of PEG-12 dimethicone is 0.5 to 2.0% by mass.
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