Tool for friction-stir welding and additive manufacturing method for same using a material made of mo / w and c / b

Abstract

The invention relates to a tool (1) for friction-stir welding, wherein at least one active region (20) of the tool (1) consists of a material which comprises a multiplicity of individual powder particles which are melted together by a high-energy beam by means of an additive manufacturing method to form a solid structure of grains (7), and wherein the material contains at least one refractory metal from the group of molybdenum and tungsten or a refractory metal alloy based on molybdenum and / or tungsten and at least one element from the group of carbon and boron, wherein the content of refractory metal or refractory metal alloy is at least 80 at% and the total content of carbon and boron is between 1.0 and 20.0 at%.

Description

[0001] TOOL FOR FRICTION WELDING AND ADDITIVE MANUFACTURING PROCESS FOR IT USING A MATERIAL MADE OF MO / W AND C / B

[0002] The present invention relates to a tool for friction stir welding having the features of the preamble of claim 1.

[0003] A tool for friction stir welding (FSW) typically includes a shaft, over which the tool is set in rotation, as well as a shoulder and a pin.

[0004] The rotation of the pin plasticizes the material in the joining zone.

[0005] The term "working area" is defined below as the part of the tool that comes into contact with the workpiece to be joined during use.

[0006] The thermal and mechanical stresses on the pin during friction stir welding, especially with solid or higher-melting-point materials such as steel or titanium, necessitate the selection of a high-temperature-resistant material for the pin. US2014299651 A1 (Edison Welding Institute) discloses a friction stir welding tool with a pin comprising a molybdenum-based material.

[0007] EP2076352 B1 (HC Starck) discloses a tool for friction stir welding, wherein the pin comprises tungsten and an oxide and / or carbide of an element selected from the group consisting of lanthanum, hafnium, zirconium and combinations thereof.

[0008] Also known are tools for friction stir welding with pins made of hard materials, for example hard metal (tungsten carbide with metallic binder, usually cobalt) or cubic boron nitride (cBN).

[0009] Mohan, DG, Wu, C. A Review on Friction Stir Welding of Steels. Chin. J.

[0010] Meeh. Eng. 34, 137 reports on tungsten-rhenium alloys and polycrystalline cubic boron nitride for friction stir welding tools.

[0011] US20190381600 A1 (PURDUE RESEARCH FOUNDATION) discloses a method for manufacturing a friction stir welding tool in which a porous tungsten carbide (WC) body is infiltrated with liquid zirconium. This forms a structure of tungsten islands surrounded by zirconium carbide (ZrC). The publication is by Ouyang, JH, Mei, H., Valant, M., & Kovacevic, R. (2002).

[0012] The application of laser-based additive manufacturing to the production of tools for friction stir welding, http: / / dx.doi.org / 10.26153 / tsw / 3416, describes the production of a tool for friction stir welding using an additive manufacturing process. The tool is built up from powder of a tool steel and powder of a nickel-silicon-antimony alloy with tungsten carbide particles.

[0013] While friction stir welding of aluminium has long been established, there are still obstacles to applying the process to steel.

[0014] In particular, the high temperatures, typically exceeding 1000°C, and the higher force levels compared to low-melting-point metals limit the selection of economically viable materials for tools used in friction stir welding of steel.

[0015] Refractory metals such as tungsten or molybdenum can have the required fracture toughness, but show insufficient resistance to wear.

[0016] Hard materials, on the other hand, often have sufficient wear resistance but insufficient fracture toughness.

[0017] The object of the invention is to provide an improved tool for friction stir welding.

[0018] The problem is solved by a tool having the features of claim 1. Preferred embodiments are specified in dependent claims. Furthermore, a method for manufacturing the tool is specified.

[0019] By having at least one working area of ​​the tool consist at least partially of a material comprising a multitude of individual powder particles fused together into a solid grain structure by a high-energy beam using an additive manufacturing process, and wherein the material contains at least one refractory metal from the molybdenum-tungsten group or a refractory metal alloy based on molybdenum and / or tungsten and at least one element from the carbon-boron group, with the content of the refractory metal or refractory metal alloy being at least 80 at% and the total content of carbon and boron being between 1.0 and 20.0 at%, an excellent combination of fracture toughness and wear resistance of the friction stir welding tool is achieved. The working area can comprise the pin alone or the pin and shoulder of the tool. In particular, the working area consists entirely of the material defined above.

[0020] The material properties have proven particularly interesting for use as a tool for friction stir welding of steel. Tools according to the invention exhibit a long service life and low wear at low manufacturing costs.

[0021] The material comprises a multitude of individual powder particles that have been fused together into a solid structure consisting of numerous grains using a high-energy beam in an additive manufacturing process. The original powder particles are completely fused together to form grains and are no longer recognizable.

[0022] This means that the material differs structurally significantly from a material produced by melt metallurgy or by classical powder metallurgy (pressing and sintering).

[0023] The production process using an additive manufacturing method involving the melting of powder particles by a high-energy beam results in only local melting and solidification with a high cooling rate, leading to special microstructure and material properties.

[0024] The high carbon and / or boron content causes the locally generated melt pool to cool, resulting in a change at the solidification front from planar to cellular crystal growth. This leads to a particularly fine-grained microstructure.

[0025] Furthermore, the high carbon and / or boron content in the material leads to the formation of a ceramic phase in the form of carbides and / or borides, which, in addition to increasing strength, also contributes to the wear resistance of the tool.

[0026] Preferably, the elements carbon and boron are present in the material forming the effective area to at least 80%, more preferably to at least 90%, and even more preferably to at least 95% as a ceramic phase.

[0027] This means that the elements carbon and boron react to form one or more ceramic phases and are no longer present in their elemental form.

[0028] In particular, the elements carbon and boron have reacted completely to form carbides and borides respectively.

[0029] The carbides and / or borides are preferably formed as carbides and / or borides of the refractory metals from the molybdenum and tungsten group. Depending on the composition, carbides and / or borides of molybdenum, tungsten, or both refractory metals may be present. Mixed carbides and / or mixed borides of the refractory metals molybdenum and tungsten may also be present.

[0030] For the example of molybdenum as the metallic phase, this means that the ceramic phase is formed from molybdenum carbides and / or borides. Specifically, in this example, the carbide ceramic phase consists of molybdenum carbide, in particular dimolybdenum carbide (M02C) or molybdenum(IV) carbide. If boron is present, the ceramic phase also includes molybdenum borides.

[0031] For example, an alloy consisting of 96.5 at.% (atomic percent) molybdenum and 3.5 at.% carbon has a molybdenum carbide content of approximately 8.7 vol.% (volume percent) (MO₂C). If boron is added to the molybdenum at 3.5 at.% instead of carbon, the resulting boride content is 8.2 vol.% (MO₂B) in the microstructure. An alloy consisting of 95.0 at.% (atomic percent) molybdenum and 5.0 at.% carbon has a molybdenum carbide content of approximately 12.45 vol.% (volume percent) (MO₂C).

[0032] Preferably, the material has a carbide and / or boride content of at least 5 vol. %.

[0033] Preferably, the material has a carbide and / or boride content of at least 10 vol. %.

[0034] The metallic phase ensures high fracture toughness of the material. The ceramic phase provides high hardness and thus wear resistance, as well as high heat and creep resistance of the material.

[0035] In one variant, the material exists at least partially in a cell-like microstructure. This means that, in the present case, grains of the metallic phase exhibit at least a sub-grain structure. In this sub-grain structure, within a grain—referred to as cells in the context of this application—there are regions of metallic phase surrounded by ceramic phase. The ceramic phase forms a network around the sub-grains of the metallic phase. In particular, the working area of ​​the tool consists entirely of the material with the cell-like microstructure.

[0036] Unlike conventional composite materials, where hard materials such as carbides, borides, or silicides are largely uniformly embedded in a metallic matrix, the cellular microstructure results in particularly well-balanced material properties. This cellular microstructure allows for a high volume fraction of ceramic phase without the material becoming brittle, as would be expected with molybdenum and tungsten with such high carbon and / or boron contents.

[0037] The cellular microstructure also exhibits very good grain boundary strength. Fracture samples show a predominantly transcrystalline fracture pattern. This means that fracture propagates mainly through the grains.

[0038] In contrast, intergranular fracture occurs along grain boundaries, that is, between grains. The energy required for transgranular crack propagation is significantly higher than for intergranular fracture. Accordingly, the material with a cellular microstructure exhibits particularly high fracture toughness.

[0039] Preferably, the mean cell size of the cells of the cell-like microstructure is between 0.1 pm and 4 pm. More preferably, the mean cell size is between 0.5 pm and 2 pm.

[0040] Preferably, the ceramic phase forms a particulate and / or continuous cell boundary. This means that the ceramic phase delimits the cells in the form of discrete particles and / or as a closed pathway. In other words, carbides and / or borides form a rim around the metallic phase, which can be beaded or continuous. Mixed forms of particulate and continuous cell boundaries are also possible.

[0041] Preferably, the ceramic phase is at least partially coherent or partially coherent with the metallic phase. In this context, coherent means that a lattice structure of the cell boundary formed by the ceramic phase transitions into a lattice structure of the metallic phase.

[0042] At least partial coherence between the ceramic and metallic phases leads to increased strength through strain in the crystal lattice. Compared to an incoherent interface, a coherent or at least partially coherent interface ensures higher interfacial strength, which is reflected in higher fracture toughness.

[0043] Coherence can be demonstrated, for example, by examination using a transmission electron microscope (TEM).

[0044] Preferably, the material forming the working area has grains with a pronounced elongation along a longitudinal extension of the tool. In other words, the metallic phase exists in the form of grains elongated along a longitudinal extension of the tool. This anisotropy is particularly advantageous with regard to the mechanical stresses occurring during friction stir welding.

[0045] This microstructure characteristic can be adjusted and influenced by the manufacturing process using a high-energy beam via an additive manufacturing process.

[0046] Preferably, the mean grain size transverse to a longitudinal extent of the tool is between 5 pm and 75 pm. Individual grains are separated from each other by high-angle grain boundaries and can be distinguished by EBSD over these boundaries.

[0047] Grains contain metallic and ceramic phases.

[0048] Preferably, the mean grain size parallel to a longitudinal extent of the tool is between 20 pm and 100 pm.

[0049] Preferably, the grain size distribution ratio (mean grain size in the longitudinal direction divided by the mean grain size transverse to the longitudinal direction) is at least 1.5. More preferably, the grain size distribution ratio is at least 2. The grain size can be determined, for example, by a microstructure analysis of a metallographic section or by evaluating an EBSD analysis.

[0050] It is advantageous if the mean cell size of the cell-like microstructure is between 0.1 pm and 4 pm. More preferably, the mean cell size is between 0.5 pm and 2 pm.

[0051] Preferably, the carbon content of the material is between 1.6 at.% and 16 at.%.

[0052] It is particularly advantageous if the composition is hypoeutectic. This means that the carbon content is below the eutectic composition. If the material consists exclusively of molybdenum (Mo) and carbon (C), the eutectic composition is 17 at.% (atomic percent) of carbon. Additional alloying and / or dopant elements can shift the position of the eutectic point. This can be determined via the respective phase diagram or thermodynamic calculation.

[0053] The carbon can be wholly or partially replaced by boron. A boron (B) content between 200 pg / g and 32500 pg / g is preferred.

[0054] The volume fraction of the ceramic phase formed by carbides and / or borides is preferably between 3.5% vol.% (volume percent) and 50% vol.%.

[0055] For example, if a molybdenum composition with 3.5 at.% carbon (corresponding to 0.45 wt.% C in weight percent Mo) is chosen, the volume fraction of molybdenum carbide is approximately 8.5 vol.%. This assumes that the added carbon reacts completely to form molybdenum carbide (MO₂C).

[0056] If 3.5 at.% boron is added to the molybdenum instead of carbon, a proportion of 8.2 vol.% boride (M02B) in the microstructure is obtained.

[0057] With the eutectic composition of Mo and C (17 at.%), significantly higher volume fractions of carbides are achieved. A material of this composition exhibits very high hardness. This could be useful for certain friction stir welding applications, for example, when welding particularly hard and / or abrasive materials.

[0058] Typical impurities are usually below 1.0 at.%.

[0059] Carbon and boron are not considered impurities in connection with this application.

[0060] The total content of metallic and non-metallic impurities is preferably < 1000 pg / g, more preferably < 500 pg / g, and even more preferably < 300 pg / g.

[0061] The presence of metallic phases such as tungsten, molybdenum, tungsten carbide (e.g. W2C), molybdenum carbide (e.g. M02C), tungsten boride (e.g. W2B), and molybdenum boride (e.g. M02B) can be detected, in particular, by X-ray diffraction (XRD) or transmission electron microscopy (TEM).

[0062] The microstructure (structure) and grain sizes can be determined using metallographic methods on a polished section.

[0063] In particular, the method of electron backscatter diffraction (EBSD) is used to differentiate the phases and to determine the grain size.

[0064] The volume fraction of the metallic phase is complementary to the volume fraction of the ceramic phase, minus any porosity. In other words, the volume fractions of the ceramic phase, the metallic phase, and the pores add up to 100 vol.%.

[0065] The respective volume fractions can be obtained via a quantitative microstructure analysis.

[0066] The porosity is preferably < 3%, more preferably < 2%, and particularly < 1%. The porosity can be determined, for example, gravimetrically, according to Archimedes' principle, or using microscopic methods in conjunction with image analysis.

[0067] The metallic phase consists of molybdenum and / or tungsten or a refractory metal alloy.

[0068] In this context, a refractory metal alloy contains at least 50 at. % (atomic percent) of molybdenum and / or tungsten.

[0069] In particular, the metallic phase consists of at least 90 at.% molybdenum and / or tungsten.

[0070] Preferably, the metallic phase consists entirely of molybdenum and / or tungsten.

[0071] The material is preferably composed of molybdenum and at least one element from the group consisting of carbon and boron, as well as the unavoidable impurities.

[0072] The carbides and / or borides are, in particular, carbides and / or borides of the respective refractory metal that forms the metallic phase. The refractory metal carbides are, in particular, molybdenum carbide (especially M02C) and, if the metallic phase contains tungsten, tungsten carbide (especially W2C) as well as mixed carbides thereof. The stoichiometry of the carbide phases may, if necessary, deviate from the above-mentioned molecular formulas. Due to the preferred manufacturing route via an additive manufacturing process with extremely high solidification rates, super- and substoichiometric compositions of the carbides may occur, which may be thermodynamically unstable but kinetically stable.

[0073] The refractory metal borides are in particular the species tungsten boride (especially W2B) and molybdenum boride (especially M02B) as well as mixed borides thereof.

[0074] As explained for the carbides, deviations in stoichiometry from the above-mentioned molecular formulas can occur.

[0075] In any case, the majority of the carbides and borides have the above-mentioned molecular formulas, as a phase determination via X-ray diffraction (XRD) has shown.

[0076] A particularly advantageous aspect of forming the material with molybdenum carbide as the ceramic phase is the high thermal conductivity of molybdenum carbide. This ensures that even with high molybdenum carbide contents, the material retains favorable thermal conductivity.

[0077] The tool is available through an additive manufacturing process based on a beam, specifically laser powder bed fusion (LPBF). In this process, a layer of powder is applied to a substrate plate using a doctor blade. A laser beam is then passed over this powder layer. The laser locally melts the powder particles, causing them to fuse together with each other and with the previously applied layer. Each layer of the component is thus created through the successive local melting and subsequent solidification of powder particles. Another powder layer is then applied, and the process begins again. The component is built up with each new powder layer, with the build direction perpendicular to the respective planes of the powder layers.

[0078] By guiding the laser beam in a path-by-path manner, a so-called scan structure is formed in each layer of powder.

[0079] Furthermore, a characteristic layer structure forms in the build direction, which is determined by the application of a new powder layer. The scan structure and the layer structure are recognizable to a person skilled in the art on the finished component. Thus, it is possible for a person skilled in the art to determine whether a component was manufactured using a conventional or an additive manufacturing process.

[0080] Due to the density differences between carbides / borides and the metallic phase, the microstructure according to the invention is not accessible via a classic melt metallurgical route.

[0081] The invention further relates to a method for manufacturing a tool for friction stir welding.

[0082] The manufacturing process includes the following steps:

[0083] - Providing a powder mixture comprising powder of refractory metal or refractory metal alloy as well as carbon and / or boron, or providing at least a partially pre-alloyed powder comprising at least one refractory metal from the molybdenum and tungsten group as well as carbon and / or boron

[0084] - generative construction of at least one section of the tool by layering the powder mixture and consolidating the powder mixture by the action of an energy beam.

[0085] To produce the powder mixture, carbon and / or boron are added to a powder of refractory metal from the molybdenum or tungsten group, or to a refractory metal alloy. This can be done, for example, by adding the carbon and / or boron in solid form, via the gas phase, or using a slurry. Powder mixtures of refractory metal with carbon and / or boron, or partially or fully pre-alloyed powders, can be used. In partially pre-alloyed powders, alloy components may be present, at least partially, in their elemental form. In fully pre-alloyed powders, the individual powder particles themselves already possess the nominal alloy composition.

[0086] The powder mixture is homogenized by mixing.

[0087] The additive manufacturing of at least one section of the tool is achieved primarily through a beam-based process. For this, a layered powder mixture, or partially or fully pre-alloyed powder, is applied to a build plate. An energy beam locally melts the powder mixture or the partially or fully pre-alloyed powder. After solidification, a solid structure remains. The process is repeated until the desired component is obtained.

[0088] Optional follow-up treatment is available.

[0089] Heat treatment can be carried out to reduce any thermal stresses and / or to homogenize the microstructure.

[0090] The temperature of any heat treatment is preferably chosen to preserve the cell-like microstructure. At temperatures below 1400°C, the cell-like microstructure remains largely stable. At temperatures above 1400°C and with longer holding times, a degradation of the cell-like microstructure can be observed.

[0091] In particular, the Laser Powder Bed Fusion (LPBF) process is used to manufacture the tool. The energy beam here is a laser beam.

[0092] Examples of process parameters for manufacturing the tool include:

[0093] LPBF is the name given to:

[0094] Line energy: 0.66 J / mm

[0095] Installation chamber temperature: >500 °C

[0096] Layer thickness of a powder coating: 30 pm

[0097] Powder: dso between 14-17 pm. The invention is explained in more detail below with reference to the attached figures.

[0098] The figures show:

[0099] Fig. 1 shows a tool for friction stir welding

[0100] Fig. 2 shows a tool for friction stir welding in a schematic section.

[0101] Fig. 3 shows a scanning electron microscope image of the material perpendicular to the longitudinal direction of the tool.

[0102] Fig. 4 shows a scanning electron microscope image of the material along the longitudinal direction of the tool.

[0103] Fig. 5 is a scanning electron microscope image of the material. Fig. 6 is a schematic representation of the microstructure.

[0104] Fig. 7 shows a schematic representation of the manufacturing process.

[0105] Figure 1 schematically shows a tool 1 for friction stir welding. The tool 1 comprises a pin 2 with a longitudinal direction L, a shoulder 3 and a shaft 4, via which the tool 1 is set into rotation.

[0106] In the present application, an area of ​​effect 20 is defined which may include pin 2 or pin 2 and shoulder 3.

[0107] The functional area 20 is formed from the material defined in claim 1. In this example, pin 2 is formed from the material defined in claim 1.

[0108] The shaft is usually made of a different base material, for example steel.

[0109] Figure 2 schematically shows a cross-sectional view of a tool 1 for friction stir welding in an alternative embodiment. As can be seen from the cross-sectional view, the shoulder 3 is designed as a component separate from the shaft 4. The working area 20 comprises the pin 2 and the shoulder 3. In other words, the pin 2 and the shoulder 3 are formed from the material defined in claim 1. Figure 3 shows a scanning electron microscope image of the material forming the working area 20 with an electron backscatter diffraction (EBSD) analysis. This method allows individual grains to be distinguished by their different orientations.

[0110] The viewing direction is along the longitudinal direction L. In other words, the shown image section is perpendicular to the longitudinal direction L. The scale bar in the figure is 600 pm.

[0111] The material in this example consists of molybdenum with 4500 pg / g carbon, corresponding to 3.48 at.% (atomic percent) carbon.

[0112] The image reveals a fine structure of molybdenum grains.

[0113] The grain size determination was carried out according to Feret. This involves determining a minimum and a maximum distance between two parallel lines between which a grain can fit.

[0114] Grain size determination on the shown image section yielded a mean grain dimension in the horizontal plane of approximately 12 pm (median 7 pm) and a mean grain dimension in the vertical plane of approximately 6 pm (median 4 pm).

[0115] Figure 4 also shows a scanning electron microscope image of the material forming the effective area 20 with EBSD, on the same material as in Figure 3. The image section shown is from a longitudinal section along the longitudinal direction L. The viewing direction is normal to the longitudinal direction L. The scale bar in the figure is 700 pm.

[0116] A pronounced elongation of the grains in the longitudinal direction L is evident. The grain size determination according to Feret yielded a mean grain size in the longitudinal direction L of 53 pm (median 38 pm) and 24 pm (median 18 pm) transversely.

[0117] This results in a grain size distribution ratio (mean grain size in longitudinal direction L divided by mean grain size perpendicular to longitudinal direction L) of greater than 2.

[0118] The pronounced elongation of the grains in the longitudinal direction L is mechanically advantageous due to the bending stress on the tool.

[0119] Preferably the grain size distribution ratio is at least 1.5 (one point five), in particular at least 2. Figure 5 shows a scanning electron microscope image of the material forming the effective area 20 in a microstructure state of a further development.

[0120] A cell-like microstructure is discernible in the present structure.

[0121] Within a grain 7, there is a cell-like sub-grain structure. Sub-grain structure means that within a grain 7, there are further organized regions, called cells 8, which are smaller than the grain 7.

[0122] Preferably, the working area 20 of the tool 1 consists entirely of the material with a cell-like microstructure.

[0123] Figure 6 shows a schematic sketch of a grain 7 to illustrate the cell-like structure shown in Figure 5.

[0124] Within a grain 7, several cells 8 are formed from the metallic phase 5, which are surrounded by a ceramic phase 6.

[0125] The ceramic phase 6 forms a cell boundary 81 of the cells 8.

[0126] The cell boundary 81 can be continuous, i.e., closed, or formed as a particulate rim, as illustrated in the schematic representation by points. Clearly, a grain 7 comprises a multitude of cells 8.

[0127] For the sake of clarity, only a packet of several cells 8 within the grain 7 is shown here. Preferably, however, the entire grain 7, and more preferably all grains 7 of the material forming the effective area 20, are characterized by the cell-like microstructure. In particular, the effective area 20 is completely formed by the described material.

[0128] Fig. 7 shows a schematic representation of the manufacturing process of a pin 2 via Laser Powder Bed Fusion (LPBF).

[0129] The pin 2 is additively manufactured from a powder mixture or from partially or fully pre-alloyed powder of refractory metal and carbon and / or boron.

[0130] Powder is applied layer by layer from a powder supply onto a substrate plate 9 via a powder feeder. A laser beam 11, guided by optics 10, scans the powder layer, melting powder particles at positions specified by a control system. The substrate plate 9 is then lowered and a new layer of powder is applied. This process is repeated until the component, in this case pin 2, has reached its final shape.

[0131] The so-called build direction A corresponds here, and preferably, to the longitudinal direction L of the component, pin 2. The local heat input during the LPBF process, together with the strong heat dissipation to the surroundings of the melt zone, leads to the effect of constitutional undercooling at the solidification front. This is associated with the formation of the cell-like microstructure.

Claims

Claims 1. Tool (1) for friction stir welding, wherein at least one working area (20) of the tool (1) consists at least partially of a material comprising a plurality of individual powder particles which are fused together by a high-energy beam using an additive manufacturing process to form a solid structure of grains (7), and wherein the material contains at least one refractory metal from the group consisting of molybdenum and tungsten or a refractory metal alloy based on molybdenum and / or tungsten and at least one element from the group consisting of carbon and boron, wherein the content of refractory metal or refractory metal alloy is at least 80 at% and the total content of carbon and boron is between 1.0 and 20.0 at%.

2. Tool (1) according to claim 1, wherein the elements carbon and boron are present in the material forming the working area (20) to at least 80% as a ceramic phase (6).

3. Tool (1) according to claim 1 or 2, wherein the ceramic phase (6) is formed of carbides and / or borides of molybdenum and / or tungsten.

4. Tool (1) according to one of the preceding claims, wherein the material is at least partially in a cell-like microstructure with cells (8) consisting of a metallic phase (5) and a ceramic phase (6) surrounding these cells (8) comprising carbides and / or borides.

5. Tool (1) according to claim 4, wherein the mean cell size of the cells (8) of the cell-like microstructure is between 0.1 pm and 4 pm.

6. Tool (1) according to one of the preceding claims, wherein the material is in the form of grains (7) extended along a longitudinal extent (L) of the tool (1).

7. Tool (1) according to one of the preceding claims, wherein the mean grain size of the grains (7) transverse to the longitudinal extent (L) of the tool (1) is between 5 pm and 75 pm.

8. Tool (1) according to one of the preceding claims, wherein a mean grain size of the grains (7) parallel to the longitudinal extent (L) of the tool (1) is between 20 pm and 150 pm.

9. Tool (1) according to one of the preceding claims, wherein a grain size elongation ratio, expressed by the ratio of the mean grain size in the longitudinal direction to the mean grain size transverse to the longitudinal direction, is at least 1.

5.

10. Tool (1) according to one of the preceding claims, wherein the carbon content of the material forming the working area (20) is between 1.6 at.% and 16 at.%, wherein the composition is particularly hypoeutectic.

11. Tool (1) according to one of the preceding claims, wherein a volume fraction of the ceramic phase (6) is between 3.5 vol.% and 50 vol.%.

12. Method for manufacturing a tool (1) for friction stir welding, the method comprising the steps: - Providing a powder mixture or at least a partially pre-alloyed powder comprising at least one refractory metal from the molybdenum and tungsten group, as well as carbon and / or boron, - generative construction of at least one section of the tool (1), in particular an effective area (20) of the tool (1), by layer-by-layer application and consolidation of the powder mixture or the 13. Use of a material comprising a plurality of individual powder particles fused together to form a solid structure by means of an additive manufacturing process using a high-energy beam, wherein the material contains at least one refractory metal from the molybdenum-tungsten group and at least one element from the carbon-boron group, wherein the refractory metal content is at least 80 at% and the sum of carbon and boron content is between 1.0 and 20.0 at%, for a friction stir welding tool.

14. Friction stir welding method using a tool according to at least one of claims 1 to 11.

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