Compositions to limit or eliminate the perception of sweat malodor
A composition of specific ingredients in defined percentages addresses the shortcoming of existing sweat malodor products by offering long-lasting protection through a combination of Group A, B, and C ingredients, effectively reducing sweat malodor perception.
Patent Information
- Application Number
- PCT/EP2025/071007
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2024-07-23
- Filing Date
- 2025-07-22
- Publication Date
- 2026-01-29
AI Technical Summary
Existing sweat malodor control products either overwhelm consumers with fragrance or lose effectiveness beyond 6 hours, failing to provide long-lasting protection against sweat malodor.
A composition comprising a combination of at least four specific ingredients (Group A, B, and C) in defined percentages, including compounds like 2-(3-phenylpropyl)pyridine, decanal, and patchouli oil, applied in consumer products to inhibit sweat malodor perception.
The composition effectively limits and eliminates sweat malodor perception for an extended period, providing long-lasting protection beyond traditional products.
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Abstract
Description
[0001] COMPOSITIONS TO LIMIT OR ELIMINATE THE PERCEPTION OF SWEAT MALODOR
[0002] Field of the Disclosure
[0003] The present disclosure relates to volatile compositions to limit, decrease or eliminate the perception of sweat malodor, and uses thereof. The present disclosure also relates to consumer products, such as deodorants and / or antiperspirants, containing the said compositions.
[0004] Background of the Disclosure
[0005] Malodorous smells exist in many environments and are experienced in our daily life. Malodors are frequently complex mixtures of more than one malodorant compound which may typically include various amines, thiols, sulfides, short chain aliphatic and olefinic acids, e.g. fatty acids, and derivatives thereof. For example, body related malodors include, among others, those of short chain fatty acids, such as 3-hydroxy-3-methylhexanoic acid, 3-methyl-2- hexenoic acid, or 3-methyl-3-sulfanyl-hexan-1-ol (transpirol), which are typically found in axilla malodors.
[0006] Many sweat malodor control products on the market either overwhelm the customer with fragrance or lose effectiveness beyond 6 hours. Malodors are not pleasant for humans and therefore there is a constant need for malodor counteracting (MOC) compositions and / or ingredients for decreasing or suppressing the perception of malodors, particularly compositions and / or ingredients that provide long-lasting sweat malodor protection beyond 6 hours.
[0007] The present disclosure provides compositions and methods of use thereof to counteract sweat malodor by limiting, decreasing, or eliminating the perception of said malodor. The use of the compositions described herein in consumer products is also an object of the present disclosure.
[0008] Summary of the Disclosure
[0009] The following aspects of the present disclosure seek to address one or more of the problems described hereinabove.
[0010] In a first aspect, the present disclosure relates to a sweat malodor inhibiting composition comprising: a) at least one Group A ingredient, wherein the at least one Group A ingredient is selected from the group consisting of:
[0011] 2-(3-phenylpropyl)pyridine, (+-)-(2E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, 1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, methyl 2-((1 RS,2RS)-3-oxo-2-pentylcyclopentyl)acetate, (+-)-(2,5-dimethyl-2,3-dihydro-1H-inden-2-yl)methanol,
[0012] (+)-(3R,5Z)-3-methyl-5-cyclopentadecen-1-one,
[0013] (+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,
[0014] (+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,
[0015] (2E,6Z)-2,6-nonadienal,
[0016] (+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0017] (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof; b) at least one Group B ingredient, wherein the at least one Group B ingredient is selected from the group consisting of: decanal, undecanal,
[0018] 4-methoxybenzaldehyde,
[0019] (+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate,
[0020] (+-)-allyl (2-methylbutoxy)acetate,
[0021] (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan,
[0022] 3-ethoxy-4-hydroxybenzaldehyde,
[0023] (+-)-(3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0024] (+-)-(1 E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one,
[0025] 1 -(2-naphthyl)ethanone,
[0026] (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,
[0027] (+-)-4-nonanolide,
[0028] 2-phenylethanol,
[0029] (4Z)-4-dodecenal,
[0030] 3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, thymol,
[0031] (+-)-3-phenylbutanal, and mixtures thereof; and c) at least one Group C ingredient, wherein the at least one Group C ingredient is selected from the group consisting of:
[0032] (+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one,
[0033] (2E)-3-phenyl-2-propen-1-ol, patchouli oil,
[0034] (1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate,
[0035] 2-ethyl-3-hydroxy-4(4H)-pyranone,
[0036] (+-)-8-sec-butylquinoline,
[0037] (+-)-6-sec-butylquinoline, (+-)-2,6-dimethyl-5-heptenal,
[0038] (+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, (+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, 3-phenylpropanal,
[0039] (+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate,
[0040] (4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, and mixtures thereof; wherein the total number of Group A, B, and C ingredients is at least 4, typically at least 8, more typically at least 11 , and the total amount of Group A, B, and C ingredients is at least 2%, typically at least 7%, more typically at least 15% by weight relative to the total weight of the composition.
[0041] In a second aspect, the present disclosure relates to a consumer product comprising the sweat malodor inhibiting composition described herein.
[0042] In a third aspect, the present disclosure relates to a method of inhibiting a perception of a sweat malodor, the method comprising contacting a malodor source with the composition or the consumer product of the foregoing aspects, thereby inhibiting, reducing or suppressing the subject’s perception of the sweat malodor. In a related aspect, the present disclosure relates to the use of the composition of the foregoing aspects for inhibiting, reducing, or suppressing a perception of a sweat malodor.
[0043] Detailed Description
[0044] As used herein, the terms “a”, “an”, or “the” means “one or more” or “at least one” unless otherwise stated.
[0045] While compositions and methods are described in terms of “comprising,” “containing,” or “including” various components or steps, the compositions and methods can also “consist essentially of” or “consist of” the various components, substances and steps. As used herein the term “consisting essentially of” shall be construed to mean including the listed components, substances or steps and such additional components, substances or steps which do not materially affect the basic and novel properties of the composition or method. In some embodiments, a composition in accordance with embodiments of the present disclosure that “consists essentially of” the recited components or substances does not include any additional components or substances that alter the basic and novel properties of the composition.
[0046] Unless defined otherwise, all technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this specification pertains.
[0047] It should be understood that any numerical range recited herein is intended to include all sub-ranges subsumed therein. For example, a range of “1 to 10” is intended to include all subranges between and including the recited minimum value of 1 and the recited maximum value of 10; that is, having a minimum value equal to or greater than 1 and a maximum value of equal to or less than 10. Because the disclosed numerical ranges are continuous, they include every value between the minimum and maximum values. Unless expressly indicated otherwise, the various numerical ranges specified in this application are approximations.
[0048] As used herein, and unless otherwise indicated, the term “about” or “approximately” means an acceptable error for a particular value as determined by one of ordinary skill in the art, which depends in part on how the value is measured or determined. In certain embodiments, the term “about” or “approximately” means within 1 , 2, 3, or 4 standard deviations. In certain embodiments, the term “about” or “approximately” means within 50%, 20%, 15%, 10%, 9%, 8%, 7%, 6%, 5%, 4%, 3%, 2%, 1%, 0.5%, or 0.05% of a given value or range.
[0049] Throughout the present disclosure, various publications may be incorporated by reference. Should the meaning of any language in such publications incorporated by reference conflict with the meaning of the language of the present disclosure, the meaning of the language of the present disclosure shall take precedence, unless otherwise indicated.
[0050] Throughout the present disclosure, various chemical names and structures may be recited. Unless otherwise stated, any stereoisomers, such as enantiomers, diastereomers, anomers, epimers, and the like; and geometric isomers, such as cis / trans or E / Z isomers, of the recited chemical name or structure are contemplated. As would be understood by those of ordinary skill in the art, stereoisomers may possess one stereocenter, giving rise to enantiomers, or more than one stereocenter, giving rise to diastereomers, each stereocenter having one of two different stereochemistries (i.e. , R or S). Enantiomers may be characterized by their ability to rotate oncoming plane-polarized light to the right, designated as dextrorotatory, “(+)” or “D”, or to the left, designated as levorotatory, “(-)” or “L”. Enantiomers may exist as racemic mixtures or scalemic mixtures. Geometric isomers refer to isomers in which the spatial relationship of atoms around a double bond are different, typically designated E or Z according to conventional understanding in the chemical art. Geometric isomers may also exist as mixtures of E and Z isomers. All of the aforementioned isomeric variations of the chemical names or structures recited herein are included. In the first aspect, the present disclosure relates to a sweat malodor inhibiting composition comprising: a) at least one Group A ingredient, wherein the at least one Group A ingredient is selected from the group consisting of:
[0051] 2-(3-phenylpropyl)pyridine,
[0052] (+-)-(2E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one,
[0053] 1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,
[0054] 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, methyl 2-((1 RS,2RS)-3-oxo-2-pentylcyclopentyl)acetate,
[0055] (+-)-(2,5-dimethyl-2,3-dihydro-1H-inden-2-yl)methanol,
[0056] (+)-(3R,5Z)-3-methyl-5-cyclopentadecen-1-one,
[0057] (+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,
[0058] (+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,
[0059] (2E,6Z)-2,6-nonadienal,
[0060] (+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0061] (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof; b) at least one Group B ingredient, wherein the at least one Group B ingredient is selected from the group consisting of: decanal, undecanal,
[0062] 4-methoxybenzaldehyde,
[0063] (+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate,
[0064] (+-)-allyl (2-methylbutoxy)acetate,
[0065] (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan,
[0066] 3-ethoxy-4-hydroxybenzaldehyde, (+-)-(3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0067] (+-)-(1 E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one,
[0068] 1 -(2-naphthyl)ethanone,
[0069] (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,
[0070] (+-)-4-nonanolide,
[0071] 2-phenylethanol,
[0072] (4Z)-4-dodecenal,
[0073] 3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, thymol,
[0074] (+-)-3-phenylbutanal, and mixtures thereof; and c) at least one Group C ingredient, wherein the at least one Group C ingredient is selected from the group consisting of:
[0075] (+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one,
[0076] (2E)-3-phenyl-2-propen-1-ol, patchouli oil,
[0077] (1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate,
[0078] 2-ethyl-3-hydroxy-4(4H)-pyranone,
[0079] (+-)-8-sec-butylquinoline,
[0080] (+-)-6-sec-butylquinoline,
[0081] (+-)-2,6-dimethyl-5-heptenal,
[0082] (+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, (+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate,
[0083] 3-phenylpropanal, (+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, (4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, and mixtures thereof; wherein the total number of Group A, B, and C ingredients is at least 4, typically at least 8, more typically at least 11 , and the total amount of Group A, B, and C ingredients is at least 2%, typically at least 7%, more typically at least 15% by weight relative to the total weight of the composition.
[0084] As used herein, “sweat malodor” refers to an odor that originates on a human body and includes sweat malodor that is transferred to another substrate, such as a textile. This may include, for example, the odor of worn clothing, such as socks, athletic wear, and the like.
[0085] In some embodiments, the at least one Group A ingredient is selected from the group consisting of:
[0086] (+-)-(2 E)- 1 -(2, 6,6-trimethyl-2-cyclohexen- 1 -yl)-2-buten- 1 -one,
[0087] 1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,
[0088] 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,
[0089] (+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one, (+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,
[0090] (2E,6Z)-2,6-nonadienal,
[0091] (+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0092] (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof.
[0093] In some embodiments, the at least one Group B ingredient is selected from the group consisting of: decanal, undecanal,
[0094] (+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate,
[0095] (+-)-allyl (2-methylbutoxy)acetate,
[0096] (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan,
[0097] 1 -(2-naphthyl)ethanone,
[0098] (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,
[0099] (+-)-4-nonanolide,
[0100] 2-phenylethanol,
[0101] (4Z)-4-dodecenal,
[0102] 3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, (+-)-3-phenylbutanal, and mixtures thereof.
[0103] In some embodiments, the at least one Group C ingredient is selected from the group consisting of:
[0104] (+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one,
[0105] (2E)-3-phenyl-2-propen-1-ol, patchouli oil,
[0106] (1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate,
[0107] (+-)-8-sec-butylquinoline,
[0108] (+-)-6-sec-butylquinoline,
[0109] (+-)-2,6-dimethyl-5-heptenal,
[0110] (+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde,
[0111] (+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, 3-phenylpropanal, (+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate,
[0112] (4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,
[0113] (4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,
[0114] (4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,
[0115] (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,
[0116] (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,
[0117] (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, and mixtures thereof.
[0118] In other embodiments, the at least one Group A ingredient is selected from the group consisting of:
[0119] 2-(3-phenylpropyl)pyridine,
[0120] (+-)-(2 E)- 1 -(2, 6,6-trimethyl-2-cyclohexen- 1 -yl)-2-buten- 1 -one,
[0121] 1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,
[0122] 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, methyl 2-((1 RS,2RS)-3-oxo-2-pentylcyclopentyl)acetate,
[0123] (+-)-(2,5-dimethyl-2,3-dihydro-1H-inden-2-yl)methanol,
[0124] (+)-(3R,5Z)-3-methyl-5-cyclopentadecen-1-one,
[0125] (+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,
[0126] (+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,
[0127] (2E,6Z)-2,6-nonadienal,
[0128] (+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0129] (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one,
[0130] (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof.
[0131] In some embodiments, the at least one Group B ingredient is selected from the group consisting of:
[0132] 4-methoxybenzaldehyde,
[0133] (+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate,
[0134] (+-)-allyl (2-methylbutoxy)acetate,
[0135] (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan,
[0136] 3-ethoxy-4-hydroxybenzaldehyde,
[0137] (+-)-(3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,
[0138] (+-)-(1 E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one,
[0139] 1 -(2-naphthyl)ethanone,
[0140] (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,
[0141] (+-)-4-nonanolide,
[0142] 2-phenylethanol,
[0143] (4Z)-4-dodecenal,
[0144] 3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, thymol,
[0145] (+-)-3-phenylbutanal, and mixtures thereof.
[0146] In some embodiments, the at least one Group C ingredient is selected from the group consisting of:
[0147] (2E)-3-phenyl-2-propen-1-ol, patchouli oil,
[0148] 2-ethyl-3-hydroxy-4(4H)-pyranone,
[0149] (+-)-8-sec-butylquinoline,
[0150] (+-)-6-sec-butylquinoline,
[0151] (+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde,
[0152] (+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate,
[0153] 3-phenylpropanal,
[0154] (+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, and mixtures thereof.
[0155] In some further embodiments, the at least one Group A ingredient is selected from the group consisting of:
[0156] (+-)-(2 E)- 1 -(2, 6,6-trimethyl-2-cyclohexen- 1 -yl)-2-buten- 1 -one,
[0157] 1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,
[0158] 1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,
[0159] (+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,
[0160] (+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,
[0161] (+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one, (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof.
[0162] In some further embodiments, the at least one Group B ingredient is selected from the group consisting of: allyl (3-methylbutoxy)acetate,
[0163] (+-)-allyl (2-methylbutoxy)acetate,
[0164] 1 -(2-naphthyl)ethanone,
[0165] (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,
[0166] (+-)-4-nonanolide,
[0167] 3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal,
[0168] (+-)-3-phenylbutanal, and mixtures thereof. In some further embodiments, the at least one Group C ingredient is selected from the group consisting of:
[0169] (+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one,
[0170] (2E)-3-phenyl-2-propen-1-ol,
[0171] (1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate,
[0172] (+-)-2,6-dimethyl-5-heptenal,
[0173] 3-phenylpropanal,
[0174] (+-)-2,3,3-trimethyl-1-indanone,
[0175] (4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,
[0176] (4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, and mixtures thereof.
[0177] In some further embodiments, the at least one Group C ingredient is selected from the group consisting of:
[0178] (2E)-3-phenyl-2-propen-1-ol,
[0179] 3-phenylpropanal,
[0180] (+-)-2,3,3-trimethyl-1-indanone, and mixtures thereof.
[0181] The expression “patchouli oil”, as mentioned above, designates any oil extracted from patchouli, any terpenes fractions of patchouli oil or CLEARWOOD (origin: Firmenich SA, Satigny, Switzerland).
[0182] In some embodiments, the sweat malodor inhibiting composition may comprise 2-(3- phenylpropyl)pyridine in an amount of from 0.005 wt% to 0.3 wt%, typically from 0.01 wt% to 0.2 wt%, more typically from 0.02 wt% to 0.1 wt%, relative to the total weight of the composition.
[0183] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- (2E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one in an amount of from 0.01 wt% to 1 wt%, typically from 0.025 wt% to 0.5 wt%, more typically from 0.03 wt% to 0.1 wt%, relative to the total weight of the composition.
[0184] In some embodiments, the sweat malodor inhibiting composition may comprise 1- (3,3 / 5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one in an amount of from 0.01 wt% to 1 wt%, typically 0.015 wt% to 0.3 wt% more typically from 0.02 wt% to 0.1 wt%, relative to the total weight of the composition. In some embodiments, the sweat malodor inhibiting composition may comprise methyl 2-((1 RS,2RS)-3-oxo-2-pentylcyclopentyl)acetate in an amount of from 0.1 wt% to 25 wt%, typically 1 wt% to 20 wt%, more typically from 1.5 wt% to 3 wt%, relative to the total weight of the composition.
[0185] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-7- hydroxy-3,7-dimethyloctanal in an amount of from 0.05 wt% to 0.5 wt%, typically 0.01 wt% to 0.2 wt%, more typically from 0.015 wt% to 0.1 wt%, relative to the total weight of the composition.
[0186] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- (2,5-dimethyl-2,3-dihydro-1 H-inden-2-yl)methanol in an amount of from 0.1 wt% to 10 wt%, typically 0.4 wt% to 8 wt%, more typically from 0.5 wt% to 0.9 wt%, relative to the total weight of the composition.
[0187] In some embodiments, the sweat malodor inhibiting composition may comprise (+)- (3R,5Z)-3-methyl-5-cyclopentadecen-1-one in an amount of from 0.1 wt% to 10 wt%, typically 0.25 wt% to 5 wt%, more typically 0.3 wt% to 1 wt%, relative to the total weight of the composition.
[0188] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-1- (5-ethyl-5-methyl-1-cyclohexen-1-yl)-4-penten-1-one in an amount of from 0.1 wt% to 10 wt%, typically 0.3 wt% to 6 wt%, more typically 0.4 wt% to 1 wt%, relative to the total weight of the composition.
[0189] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate in an amount of from 0.05 wt% to 10 wt%, typically 0.15 wt% to 3 wt%, more typically 0.2 wt% to 1 wt%, relative to the total weight of the composition.
[0190] In some embodiments, the sweat malodor inhibiting composition may comprise (2E,6Z)- 2,6-nonadienal in an amount of from 0.0005 wt% to 1 wt%, typically 0.001 wt% to 0.02 wt%, more typically 0.0015 wt% to 0.1 wt%, relative to the total weight of the composition.
[0191] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- (3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one and / or (+-)-(1 E)-1-(2,6,6- trimethyl-2-cyclohexen-1-yl)-1-penten-3-one in an amount of from 0.1 wt% to 10 wt%, typically 0.45 wt% to 9 wt%, more typically 0.5 wt% to 0.9 wt%, relative to the total weight of the composition.
[0192] In some embodiments, the sweat malodor inhibiting composition may comprise decanal in an amount of from 0.1 wt% to 10 wt%, typically 0.15 wt% to 3 wt%, more typically 0.1 wt% to 1 wt%, relative to the total weight of the composition. In some embodiments, the sweat malodor inhibiting composition may comprise undecanal in an amount of from 0.01 wt% to 5 wt%, typically 0.05 wt% to 1 wt%, more typically 0.06 wt% to 0.5 wt%, relative to the total weight of the composition.
[0193] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-2- methylundecanal in an amount of from 0.01 wt% to 5 wt%, typically 0.075 wt% to 1.5 wt%, more typically 0.1 wt% to 1 wt%, relative to the total weight of the composition.
[0194] In some embodiments, the sweat malodor inhibiting composition may comprise 4- methoxybenzaldehyde in an amount of from 0.1 wt% to 10 wt%, typically 0.25 wt% to 5 wt%, more typically 0.3 wt% to 0.9 wt%, relative to the total weight of the composition.
[0195] In some embodiments, the sweat malodor inhibiting composition may comprise allyl (3- methylbutoxy)acetate and / or (+- )-allyl (2-methylbutoxy)acetate in an amount of from 0.1 wt% to 20 wt%, typically 0.75 wt% to 15 wt%, more typically 1 wt% to 2 wt%, relative to the total weight of the composition.
[0196] In some embodiments, the sweat malodor inhibiting composition may comprise (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan in an amount of from 0.01 wt% to 10 wt%, typically 0.3 wt% to 6 wt%, more typically 0.4 wt% to 1.5 wt%, relative to the total weight of the composition.
[0197] In some embodiments, the sweat malodor inhibiting composition may comprise 3- ethoxy-4-hydroxybenzaldehyde in an amount of from 0.1 wt% to 10 wt%, typically 0.25 wt% to 5 wt%, more typically 0.3 wt% to 0.9 wt%, relative to the total weight of the composition.
[0198] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- (3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one and / or (+-)-(1 E)-1-(2,6,6- trimethyl-2-cyclohexen-1-yl)-1-penten-3-one in an amount of from 0.1 wt% to 15 wt%, typically 0.5 wt% to 10 wt%, more typically 0.6 wt% to 0.9 wt%, relative to the total weight of the composition.
[0199] In some embodiments, the sweat malodor inhibiting composition may comprise 1-(2- naphthyl)ethanone in an amount of from 0.1 wt% to 10 wt%, typically 0.25 wt% to 5 wt%, more typically 0.3 wt% to 0.9 wt%, relative to the total weight of the composition.
[0200] In some embodiments, the sweat malodor inhibiting composition may comprise (4E)-4- methyl-5-(4-methylphenyl)-4-pentenal in an amount of from 0.01 wt% to 5 wt%, typically 0.075 wt% to 1.5 wt%, more typically 0.1 wt% to 1 wt%, relative to the total weight of the composition.
[0201] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-4- nonanolide in an amount of from 0.1 wt% to 40 wt%, typically 1.5 wt% to 30 wt%, more typically 2 wt% to 10 wt%, relative to the total weight of the composition. In some embodiments, the sweat malodor inhibiting composition may comprise 2- phenylethanol in an amount of from 1 wt% to 60 wt%, typically 2.5 wt% to 50 wt%, more typically 3 wt% to 10 wt%, relative to the total weight of the composition.
[0202] In some embodiments, the sweat malodor inhibiting composition may comprise (4Z)-4- dodecenal in an amount of from 0.01 wt% to 1 wt%, typically 0.015 wt% to 0.3 wt%, more typically 0.02 wt% to 0.2 wt%, relative to the total weight of the composition.
[0203] In some embodiments, the sweat malodor inhibiting composition may comprise 3-(4,4- dimethyl-1-cyclohexen-1-yl)propanal in an amount of from 0.01 wt% to 5 wt%, typically 0.075 wt% to 1.5 wt%, more typically 0.1 wt% to 1 wt%, relative to the total weight of the composition.
[0204] In some embodiments, the sweat malodor inhibiting composition may comprise thymol in an amount of from 0.01 wt% to 5 wt%, typically 0.025 wt% to 0.5 wt%, more typically 0.03 wt% to 0.09 wt%, relative to the total weight of the composition.
[0205] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-3- phenylbutanal in an amount of from 0.01 wt% to 5 wt%, typically 0.15 wt% to 3 wt%, more typically 0.2 wt% to 1 wt%, relative to the total weight of the composition.
[0206] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- 1 ,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one in an amount of from 0.1 wt% to 20 wt%, typically 0.75 wt% to 15 wt%, more typically 1 wt% to 2 wt%, relative to the total weight of the composition.
[0207] In some embodiments, the sweat malodor inhibiting composition may comprise (2E)-3- phenyl-2-propen-1-ol in an amount of from 0.1 wt% to 10 wt%, typically 0.25 wt% to 5 wt%, more typically 0.3 wt% to 1.5 wt%, relative to the total weight of the composition.
[0208] In some embodiments, the sweat malodor inhibiting composition may comprise patchouli oil in an amount of from 1 wt% to 30 wt%, typically 1.25 wt% to 25 wt%, more typically 1.5 wt% to 10 wt%, relative to the total weight of the composition.
[0209] In some embodiments, the sweat malodor inhibiting composition may comprise 2-ethyl- 3-hydroxy-4(4H)-pyranone in an amount of from 0.1 wt% to 10 wt%, typically 0.25 wt% to 5 wt%, more typically 0.3 wt% to 1.5 wt%, relative to the total weight of the composition.
[0210] In some embodiments, the sweat malodor inhibiting composition may comprise (1 R,2R)- 1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate in an amount of from 0.5 wt% to 30 wt%, typically 1 wt% to 20 wt%, more typically 1.5 wt% to 10 wt%, relative to the total weight of the composition.
[0211] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-6- sec-butylquinoline and / or (+-)-8-sec-butylquinoline in an amount of from 0.05 wt% to 5 wt%, typically 0.1 wt% to 2 wt%, more typically 0.15 wt% to 0.5 wt%, relative to the total weight of the composition. In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-2,6- dimethyl-5-heptenal in an amount of from 0.05 wt% to 5 wt%, typically 0.2 wt% to 4 wt%, more typically 0.3 wt% to 1 wt%, relative to the total weight of the composition.
[0212] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)-3- (4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehyde and / or (+-)-4-(4-methyl-3-penten-1-yl)- 3-cyclohexene-1-carbaldehyde in an amount of from 0.05 wt% to 10 wt%, typically 0.4 wt% to 8 wt%, more typically 0.5 wt% to 2 wt%, relative to the total weight of the composition.
[0213] In some embodiments, the sweat malodor inhibiting composition may comprise methyl 2,4-dihydroxy-3,6-dimethylbenzoate in an amount of from 0.05 wt% to 10 wt%, typically 0.4 wt% to 8 wt%, more typically 0.5 wt% to 2 wt%, relative to the total weight of the composition.
[0214] In some embodiments, the sweat malodor inhibiting composition may comprise 3- phenylpropanal in an amount of from 0.0001 wt% to 1 wt%, typically 0.0005 wt% to 0.01 wt%, more typically 0.0002 wt% to 0.005 wt%, relative to the total weight of the composition.
[0215] In some embodiments, the sweat malodor inhibiting composition may comprise (+-)- 2, 3, 3-trimethyl-1 -indanone in an amount of from 0.05 wt% to 10 wt%, typically 0.075 wt% to 1.5 wt%, more typically 0.1 wt% to 1 wt%, relative to the total weight of the composition.
[0216] In some embodiments, the sweat malodor inhibiting composition may comprise tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate and / or tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate in an amount of from 0.05 wt% to 30 wt%, typically 1 wt% to 20 wt%, more typically 1 .5 wt% to 5 wt%, relative to the total weight of the composition.
[0217] In some embodiments, the sweat malodor inhibiting composition may comprise (4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1 (2H)-one, (4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1 (2H)-one, (4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1 (2H)-one, (4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1 (2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1 (2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1 (2H)-one, or a combination thereof, in an amount of from 0.01 wt% to 5 wt%, typically 0.05 wt% to 1 wt%, more typically 0.06 wt% to 0.5 wt%, relative to the total weight of the composition.
[0218] In some embodiments, the sweat malodor inhibiting composition may comprise (3E)-4- (2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one in an amount of from 0.5 wt% to 20 wt%, typically 0.75% to 15%, more typically 1 wt% to 5 wt%, relative to the total weight of the composition.
[0219] In accordance with the present disclosure, the total number of Group A, B, and C ingredients is at least 4, typically at least 8, more typically at least 11. In an embodiment, the total number of Group A, B, and C ingredients is from 4 to 20. In another embodiment, the total number of Group A, B, and C ingredients is from 8 to 15. In yet another embodiment, the total number of Group A, B, and C ingredients is from 11 to 14.
[0220] The total amount of Group A, B, and C ingredients is at least 2%, typically at least 7%, more typically at least 15% by weight relative to the total weight of the composition. In an embodiment, the total amount of Group A, B, and C ingredients is from 2% to 80%, by weight relative to the total weight of the composition. In another embodiment, the total amount of Group A, B, and C ingredients is from 7% to 50%, by weight relative to the total weight of the composition.
[0221] The sweat malodor inhibiting composition described herein may optionally comprise a perfumery solvent. A detailed description of the nature and type of solvents commonly used in perfumery, herein “perfumery solvent” cannot be exhaustive. However, exemplary solvents include, but are not limited to, solvents such as glycerol, dipropylene glycol and its monoether, 1 ,2,3-propanetriyl triacetate, dimethyl glutarate, dimethyl adipate 1 ,3-diacetyloxypropan-2-yl acetate, diethyl phthalate, isopropyl myristate, Abalyn® (rosin resins, available from Eastman), benzyl benzoate, benzyl alcohol, 2-(2-ethoxyethoxy)-1 -ethanol, tri-ethyl citrate or mixtures thereof. Naturally derived solvents, like glycerol or various vegetable oils such as palm oil, sunflower oil or linseed oil, may also be used. Other non-limiting perfumery solvents include limonene or other terpenes, isoparaffins such as those known under the trademark Isopar® (origin: Exxon Chemical) or glycol ethers and glycol ether esters such as those known under the trademark Dowanol® (origin: Dow Chemical Company), or hydrogenated castors oils such as those known under the trademark Cremophor® RH 40 (origin: BASF).
[0222] The amount of the perfumery solvent is not particularly limited. However, in some embodiments, the perfumery solvent is present in an amount from 0% to 50%, typically 0.1% to 15%, more typically 0.2% to 10%, by weight relative to the total weight of the composition.
[0223] The sweat malodor inhibiting composition may further comprise a perfuming coingredient. As used herein, a perfuming co-ingredient refers to ingredients that impart a hedonic effect, i.e., used for the primary purpose of conferring or modulating an odor. In other words, such a co-ingredient, to be considered as being a perfuming one, must be recognized by a person skilled in the art as being able to impart or modify in a positive or pleasant way the odor of a composition, and not just as having an odor. Perfuming co-ingredients may impart an additional benefit beyond that of modifying or imparting an odor, such as long-lasting, blooming, malodour counteraction, antimicrobial effect, antiviral effect, microbial stability, or pest control.
[0224] The nature and type of the perfuming co-ingredients do not warrant a more detailed description here, which in any case would not be exhaustive, the skilled person being able to select them on the basis of his general knowledge and according to the intended use or application and the desired organoleptic effect. In general terms, these perfuming co- ingredients belong to chemical classes as varied as alcohols, lactones, aldehydes, ketones, esters, ethers, acetates, nitriles, terpenoids, nitrogenous or sulphurous heterocyclic compounds, and essential oils. Perfuming co-ingredients can be of natural or synthetic origin. Suitable perfumery co-ingredients are in any case listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, New Jersey, USA, or its more recent versions, or in other works of a similar nature, as well as in the abundant patent literature in the field of perfumery. It is also understood that said co-ingredients may also be compounds known to release, in a controlled manner, various types of perfuming compounds, known as properfume or profragrance.
[0225] The sweat malodor inhibiting composition may optionally comprise a fragrance modulator.
[0226] Fragrance modulators, also known as fixatives, are agents having the capacity to affect the manner in which the odor, and in particular the evaporation rate and intensity, of the compositions incorporating said modulator can be perceived by an observer or user thereof, over time, as compared to the same perception in the absence of the modulator. In particular, the modulator allows prolonging the time during which their fragrance is perceived.
[0227] Examples of fragrance modulators suitable for use according to the present disclosure include, but are not limited to, caprylyl alcohol, octanol, butyloctanol, isotridecyl alcohol, hexyldecanol, isostearyl alcohol, octyldecanol, octyldodecanol, decyltetradecanol, tetradecyloctadecanol, PPG-20 methyl glucose ether, methyl glucoside polyol; ethyl glucoside polyol; propyl glucoside polyol; isocetyl alcohol; PPG-3 myristyl ether; neopentyl glycol diethylhexanoate; sucrose laurate; sucrose dilaurate, sucrose myristate, sucrose palmitate, sucrose stearate, sucrose distearate, sucrose tristearate, hyaluronic acid disaccharide sodium salt, sodium hyaluronate, propylene glycol propyl ether; dicetyl ether; polyglycerin-4 ethers; isoceteth-5; isoceteth-7, isoceteth-10; isoceteth-12; isoceteth-15; isoceteth-20; isoceteth-25; isoceteth-30; disodium lauroamphodipropionate; hexaethylene glycol monododecyl ether; and their mixtures; neopentyl glycol di isononanoate; cetearyl ethyl hexanoate; panthenol ethyl ether, DL-panthenol, N-hexadecyl n-nonanoate, noctadecyl n-nonanoate, a profragrance, cyclodextrin, an encapsulation, and any combination thereof.
[0228] The sweat malodor inhibiting compositions described herein may comprise a solid carrier. The sweat malodor inhibiting composition or elements of the composition can be chemically or physically bound. In general, such solid carriers are employed either to stabilize the composition, or to control the rate of evaporation of the compositions or of some ingredients. Solid carriers are of current use in the art and a person skilled in the art knows how to reach the desired effect. Suitable solid carriers include, but are not limited to, absorbing gums or polymers or inorganic materials, such as porous polymers, cyclodextrines, dextrines, maltodextrines wood-based materials, organic or inorganic gels, clays, gypsum talc or zeolites. Other suitable solid carriers include encapsulating materials. Examples of such materials may comprise wall-forming and plasticizing materials, such as glucose syrups, natural or modified starches, hydrocolloids, cellulose derivatives, polyvinyl acetates, polyvinylalcohols, proteins or pectins, plant gums such as acacia gum (Gum Arabic), urea, sodium chloride, sodium sulphate, zeolite, sodium carbonate, sodium bicarbonate, clay, talc, calcium carbonate, magnesium sulfate, gypsum, calcium sulfate, magnesium oxide, zinc oxide, titanium dioxide, calcium chloride, potassium chloride, magnesium chloride, zinc chloride, carbohydrates, saccharides such as sucrose, mono-, di-, and polysaccharides and derivatives such as chitosan, starch, cellulose, carboxymethyl methylcellulose, methylcellulose, hydroxyethyl cellulose, ethyl cellulose, propyl cellulose, polyols / sugar alcohols such as sorbitol, maltitol, xylitol, erythritol, and isomalt, polyethylene glycol (PEG), polyvinyl pyrrolidin (PVP), polyvinyl alcohol, acrylamides, acrylates, polyacrylic acid and related, maleic anhydride copolymers, amine- functional polymers, vinyl ethers, styrenes, polystyrenesulfonates, vinyl acids, ethylene glycolpropylene glycol block copolymers, vegetable gums, gum acacia, pectins, xanthanes, alginates, carragenans, citric acid or any water soluble solid acid, fatty alcohols or fatty acids and mixtures thereof.
[0229] Other suitable encapsulating materials are described in reference texts known to those of skill in the art, such as H. Scherz, Hydrokolloide: Stabilisatoren, Dickungs- und Geliermittel in Lebensmitteln, Band 2 der Schriftenreihe Lebensmittelchemie, Lebensmittelqualitat, Behr's Verlag GmbH & Co., Hamburg, 1996. The encapsulation is a well-known process to a person skilled in the art, and may be performed, for instance, by using techniques such as spraydrying, agglomeration or yet extrusion; or consists of a coating encapsulation, including coacervation and complex coacervation techniques.
[0230] Other exemplary solid carriers include core-shell capsules with resins of aminoplast, polyamide, polyester, polyurea or polyurethane type, and mixtures threof, made using techniques well-known to those of ordinary skill in the art, such as phase separation induced by polymerization, interfacial polymerization, coacervation, or a combination thereof, optionally in the presence of a polymeric stabilizer or of a cationic copolymer.
[0231] Resins may be produced by the polycondensation of an aldehyde (e.g., formaldehyde, 2,2-dimethoxyethanal, glyoxal, glyoxylic acid or glycolaldehyde, and mixtures thereof) with an amine such as urea, benzoguanamine, glycoluryl, melamine, methylol melamine, methylated methylol melamine, guanazole and the like, as well as mixtures thereof. Alternatively, one may use preformed resins like alkylolated polyamines such as those commercially available under the trademark URAC (origin: Cytec Technology Corp.), CYMEL (origin: Cytec Technology Corp.), URECOLL or LURACOLL (origin: BASF). Other suitable resins are the those produced by the polycondensation of a polyol, like glycerol, and a polyisocyanate, for example, a trimer of hexamethylene diisocyanate, a trimer of isophorone diisocyanate or xylylene diisocyanate or a Biuret of hexamethylene diisocyanate or a trimer of xylylene diisocyanate with trimethylolpropane (marketed as Takenate® by Mitsui Chemicals), among which a trimer of xylylene diisocyanate with trimethylolpropane and a Biuret of hexamethylene diisocyanate are of mention.
[0232] The encapsulation of perfumes by polycondensation of amino resins, namely melamine- based resins with aldehydes is well-known in the art. Pertinent publications include, but are not limited to, K. Dietrich et al. Acta Polymerica, 1989, vol. 40, pages 243, 325 and 683, as well as 1990, vol. 41, page 91 and US Patent No. 4,396,670 issued August 2, 1983. The general knowledge in encapsulation technology is very significant and cannot be exhaustive. More recent publications of pertinence, which disclose suitable uses of such microcapsules, are represented, for example, by the article of K. Bruyninckx and M. Dusselier, ACS Sustainable Chemistry & Engineering, 2019, vol. 7, pages 8041-8054. These publications are incorporated herein by reference.
[0233] The sweat malodor inhibiting compositions described herein may optionally comprise at least one perfumery adjuvant.
[0234] The at least one perfumery adjuvant is an ingredient capable of imparting an additional added benefit such as a color, a particular light resistance, chemical stability, etc. A detailed description of the nature and type of adjuvant commonly used in perfuming compositions cannot be exhaustive, but it has to be mentioned that said ingredients are well known to a person skilled in the art.
[0235] Exemplary perfumery adjuvants include, but are not limited to, viscosity agents (e.g., surfactants, thickeners, gelling and / or rheology modifiers), stabilizing agents (e.g., preservatives, antioxidant, heat / light and or buffers or chelating agents, such as BHT), coloring agents (e.g., dyes and / or pigments), preservatives (e.g. antibacterial or antimicrobial or antifungal or anti irritant agents), abrasives, skin cooling agents, insect repellants, ointments, vitamins and mixtures thereof.
[0236] In some embodiments, the sweat malodor compositions of the present disclosure may further comprise at least one other malodor control (MOC) compound. As used herein, the term "other MOC compound" refers to a material which is already known to provide MOC activity and is commonly used in the industry for such use. The at least one other MOC compound can be included to further boost, or complement, the MOC activity of the sweat malodor compositions of the present disclosure.
[0237] Non-limiting examples of an other MOC compound include antimicrobial agents, malodor absorbers, chemical neutralizers, e.g. acid-base reagents, thiol traps, odor blockers, cross-adaptation agents, such as those disclosed in U.S. Patent No. 5,538,719, which is incorporated herein by reference, and malodor complexation agents, e.g. cyclodextrins.
[0238] Examples of antimicrobial agents include, but are not limited to, metal salts such as zinc citrate, zinc oxide, zinc pyrethiones, and octopirox; organic acids, such as sorbic acid, benzoic acid, and their salts; parabens, such as methyl paraben, propyl paraben, butyl paraben, ethyl paraben, isopropyl paraben, isobutyl paraben, benzyl paraben, and their salts; alcohols, such as benzyl alcohol, phenyl ethyl alcohol; boric acid; 2,4,4'-trichloro-2-hydroxy-diphenyl ether; phenolic compounds, such as phenol, 2-methyl phenol, 4-ethyl phenol; essential oils such as rosemary, thyme, lavender, eugenol, geranium, tea tree, clove, lemon grass, peppermint, or their active components such as anethole, thymol, eucalyptol, farnesol, menthol, limonene, methyl salicylate, salicylic acid, terpineol, nerolidol, geraniol, and mixtures thereof.
[0239] Examples of malodor absorbers include, but are not limited to, molecular sieves, such as zeolites, silicas, aluminosilcates, and cyclodextrins; and organic absorbents, such as, for example, activated charcoal, dried citrus pulp, cherry pit extract, corncob, and mixtures thereof.
[0240] The sweat malodor inhibiting compositions according to the present disclosure may be prepared according to any method known to those of ordinary skill in the art. The ordinarily skilled artisan is perfectly able to design optimal formulations for the desired effect by admixing the above-mentioned components to arrive at the desired composition by applying standard knowledge and concepts known to those of ordinary skill and by utilizing routine optimization methodologies.
[0241] The sweat malodor inhibiting compositions according to the present disclosure may be used in combination with a delivery system. For instance, the composition or some elements of the composition may be encapsulated or the composition may further comprise a delivery system. Suitable delivery systems for the purpose of the present disclosure include but are not limited to the following:
[0242] • Passive plating supports comprising one or more of the following porous or non-porous substrates in loose powder or compacted form chosen from the following non-limiting examples: cellulose (paper / cardboard), vermiculite, other industrial absorbents, perlite, calcium carbonate, pumice, other minerals, wood, sawdust, ground corn cob, ground rice hull, rice hull ash, other agricultural by-products, biochars, starches, modified starches;
[0243] • Spray-dried moisture-activated encapsulation systems wherein the compositions according to the present disclosure are encapsulated by a spray drying process within a matrix containing but not limited to one or more of the following: maltodextrin, octenyl succinated starch (modified starch); • Core-shell encapsulation systems, such as mechanically activated microcapsules with an impermeable shell (for example, polyurea, polyurethane, and others) and composition according to the present disclosure in the core;
[0244] • Liquid mixtures containing surfactants; or
[0245] • Polymeric materials.
[0246] The sweat malodor inhibiting compositions according to the present disclosure may be combined with encapsulating materials such as polymers to form microcapsules or microparticles, or materials to form liquid delivery system for the composition such as an emulsion, a microemulsion, a miniemulsion, a gel, a microgel, an anhydrous gel or a dispersion.
[0247] In some embodiments, the sweat malodor inhibiting compositions may be absorbed on a porous or non-porous substrate in loose powder or compacted form, the substrate being selected from cellulose (paper / cardboard), vermiculite, other industrial absorbents, perlite, calcium carbonate, pumice, wood, sawdust, ground corn cob, ground rice hull, rice hull ash, biochars, starches, modified starches, and mixtures thereof.
[0248] In the second aspect, the present disclosure relates to a consumer product comprising the sweat malodor inhibiting composition described herein.
[0249] Non-limiting examples of consumer products according to the present invention include the following:
[0250] • a perfume, such as a fine perfume, an Eau de Toilette, a cologne or an after-shave lotion;
[0251] • a hair care product, such as a shampoo, a hair conditioner, a hair cream, a hair oil, a hair styling product (such as a spray, mousse or gel), a hair coloration product or a hair permanent wave product;
[0252] • a skin care product, such as a face cream, a face lotion, a shaving product (such as a foam, cream, gel or oil), a body and / or hand product (such as a lotion, cream, gel or oil), a skin firming product, a depilatory, a talcum powder, a foot care cream or lotion, baby wipes, cleansing wipes, moisturizer wipes, a sun-protection product (such as a spray, lotion, cream or oil), an after-sun lotion, or a self-tanning product;
[0253] • a fabric care product, such as a liquid detergent, a powder detergent, detergent tablets, a detergent bar, a detergent paste, a detergent pouch, a liquid fabric softener, fabric softener sheets, a fabric scent booster, a laundry pre-treatment, a fabric refresher, an ironing water, a laundry bleach, a carpet powder or a carpet cleaner;
[0254] • a body deodorant or antiperspirant product;
[0255] • a skin-cleansing product, such as a soap bar, a shower gel, a liquid hand soap, a bath foam or an intimate wash product; and
[0256] • an air freshening product, such as an air freshener spray, a gel air freshener, a liquidwick air freshener, a solid air freshener comprising a porous substrate (such as a paper or card blotter, a porous ceramic, or a porous plastic), a liquid or gel air freshener comprising a permeable membrane, an electrically operated air freshener, and a dual purpose air freshener / disinfectant spray.
[0257] In some embodiments, consumer product comprises from 0.1% to 85% by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product. In some embodiments, the consumer product comprises from 0.1% to 15%, typically 0.1% to 7%, more typically 0.1% to 5%, by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product. In some embodiments, the consumer product comprises from 0.1% to 2%, typically 0.1% to 0.5%, more typically 0.1% to 0.3%, by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product.
[0258] In some embodiments, the consumer product comprises from 0.5% to 15%, typically 0.5% to 7%, more typically 0.5% to 5%, by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product. In some embodiments, the consumer product comprises from 0.5% to 2% by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product.
[0259] In some embodiments, the consumer product comprises from 30% to 85%, typically 30% to 70%, more typically 30% to 60%, by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product. In some embodiments, the consumer product comprises from 40% to 85%, typically 40% to 70%, more typically 40% to 60%, by weight of the sweat malodor inhibiting composition, relative to the total weight of the consumer product.
[0260] In an embodiment, the consumer product is a deodorant or antiperspirant comprising 0.1 to 5.0 wt%, typically 0.2 to 5.0 wt%, of the sweat malodor inhibiting composition, and at least one deodorant or antiperspirant active base.
[0261] Non-limiting examples of suitable deodorant or antiperspirant active base may include emollients, solubilizers, deodorant actives, antioxidants, preservatives, carriers, odour entrappers, propellants, primary structurants, antiperspirant actives, additional chassis ingredients, volatile silicone solvents, gellants, buffering agent and residue masking materials. A person of ordinary skill in the art is able to select them on the basis of its general knowledge and according to intended form of the deodorant or antiperspirant product.
[0262] In an embodiment, the deodorant or anti-perspirant is in the form of a wax-based stick, soap-based stick, compressed powder stick, roll-on suspension or solution, emulsion, gel, cream, squeeze spray, pump spray, or aerosol. Each product form may contain its own selection of additional deodorant or antiperspirant active base, some essential and some optional.
[0263] For example, by way of illustration, a deodorant or anti-perspirant in the form of a roll-on suspension or solution may comprise water, emollient, solubilizer, deodorant or antiperspirant actives, antioxidants, preservatives, or combinations thereof. A deodorant or anti-perspirant in the form of a gel, typically clear gel, may comprise water, emollient, solubilizer, deodorant or antiperspirant actives, antioxidants, preservatives, ethanol, or combinations thereof. A deodorant or anti-perspirant in the form of a spray may contain a carrier, deodorant or antiperspirant actives, odor entrappers, propellant, or combinations thereof. An invisible solid deodorant or antiperspirant may contain a primary structurant, deodorant or antiperspirant actives, and additional chassis ingredient(s). A soft solid deodorant or antiperspirant may comprise volatile silicone, deodorant or antiperspirant actives, gellant, residue masking material, or combinations thereof. An aerosol deodorant or antiperspirant product may comprise a carrier, a propellant, or a combination thereof.
[0264] Emollients suitable for deodorant or antiperspirant products include, but are not limited to, propylene glycol, polypropylene glycol (like dipropylene glycol, tripropylene glycol, etc.), diethylene glycol, triethylene glycol, neopentyl glycol diheptanoate, PEG-4, PEG-8, 1,2- pentanediol, 1,2-hexanediol, hexylene glycol, glycerin, 02 to 020 monohydric alcohols, 02 to 040 dihydric or polyhydric alcohols, alkyl ethers of polyhydric and monohydric alcohols, dicaprylyl carbonate, dicaprylyl ether, diethylhexylcyclohexane, dibutyl adipate, volatile silicone emollients such as cyclopentasiloxane, nonvolatile silicone emollients such as dimethicone, mineral oils, polydecenes, petrolatum, and combinations thereof. One example of a suitable emollient comprises PPG-15 stearyl ether. Other examples of suitable emollients include dipropylene glycol and propylene glycol.
[0265] Suitable deodorant actives can include any topical material that is known or otherwise effective in preventing or eliminating malodour, including malodour associated with sweat and / or perspiration. Suitable deodorant actives may be selected from the group consisting of antimicrobial agents (e.g., bacteriocides, fungicides), malodour-absorbing material, and combinations thereof. Antimicrobial agents may comprise cetyl-trimethylammonium bromide, cetyl pyridinium chloride, benzethonium chloride, diisobutyl phenoxy ethoxy ethyl dimethyl benzyl ammonium chloride, sodium N-lauryl sarcosine, sodium N-palmethyl sarcosine, lauroyl sarcosine, N-myristoyl glycine, potassium N-lauryl sarcosine, trimethyl ammonium chloride, sodium aluminum chlorohydroxy lactate, triethyl citrate, tricetylmethyl ammonium chloride, 2,4,4'-trichloro-2'hydroxy diphenyl ether (triclosan), 3,4,4'-trichlorocarbanilide (triclocarban), diaminoalkyl amides such as L-lysine hexadecyl amide, heavy metal salts of citrate, salicylate, and piroctose, especially zinc salts, and acids thereof, heavy metal salts of pyrithione, especially zinc pyrithione, zinc phenolsulfate, farnesol, and combinations thereof. Suitable odour entrappers for use herein include, for example, solubilized, water-soluble, uncomplexed cyclodextrin. As used herein, the term "cyclodextrin" includes any of the known cyclodextrins such as unsubstituted cyclodextrins containing from six to twelve glucose units, including alpha- cyclodextrin, beta-cyclodextrin, gamma-cyclodextrin and / or their derivatives and / or mixtures thereof.
[0266] A suitable solubilizer for deodorant or antiperspirant products can be, for example, a surfactant, such as a no-foaming or low-foaming surfactant. Suitable surfactants are nonionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof. Suitable solubilizers include, for example, polyethylene glycol ether of Cetearyl Alcohol, hydrogenated castor oil such as polyoxyethylene hydrogenated castor oil, polyoxyethylene 2 stearyl ether, polyoxyethylene 20 stearyl ether, and combinations thereof.
[0267] Suitable preservatives for deodorant or antiperspirant products include organic sulfur compounds, halogenated compounds, cyclic organic nitrogen compounds, low molecular weight aldehydes, parabens, propane diol materials, isothiazolinones, quaternary compounds, benzoates, low molecular weight alcohols, dehydroacetic acid, phenyl and phenoxy compounds, or mixtures thereof. Non-limiting examples of commercially available preservatives include a mixture of about 77% 5-chloro-2-methyl-4-isothiazolin-3-one and about 23% 2-methyl- 4-isothiazolin-3-one, a broad spectrum preservative available as a 1.5% aqueous solution under the trade name KATHAN CG by Rohm and Haas Co.; 5-bromo-5-nitro-1,3-dioxane, available under the tradename Bronidox LO from Henkel; 2-bromo-2-nitropropane-1,3-diol, available under the trade name Bronopol® from Index; 1,1'-hexamethylene bis(5-(p- chlorophenyl)biguanide), commonly known as chlorhexidine, and its salts, e.g., with acetic and digluconic acids; a 95:5 mixture of 1,3-bis(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidinedione and 3-butyl-2-iodopropynyl carbamate, available under the trade name Glydant Plus® from Lonza; N-[l,3-bis(hydroxymethyl)2,5-dioxo-4-imidazolidinyl]-N,N'-bis(hydroxy-methyl) urea, commonly known as diazolidinyl urea, available under the trade name Germall® II from Sutton Laboratories, Inc.; N,N"-methylenebis {N'-[l-(hydroxymethyl)-2,5-dioxo-4-imidazolidinyl]urea}, commonly known as imidazolidinyl urea, available, e.g., under the trade name Abiol® from 3V- Sigma, Unicide U-13® from Induchem, German 115® from Sutton Laboratories, Inc.; polymethoxy bicyclic oxazolidine, available under the trade name Nuosept® C from Hills America; formaldehyde; glutaraldehyde; polyaminopropyl biguanide, available under the trade name Cosmocil CQ® from ICI Americas, Inc., or under the trade name Mikrokill® from Brooks, Inc; dehydroacetic acid; and benzsiothiazolinone available under the trade name Koralone™ B- 119 from Rohm and Hass Corporation. Suitable levels of preservative can range from about 0.0001 % to about 0.5%, alternatively from about 0.0002% to about 0.2%, alternatively from about 0.0003% to about 0.1 %, by weight of the deodorant or antiperspirant.
[0268] Suitable carriers for deodorant or antiperspirant products can include, water, alcohol, or combinations thereof. Useful alcohols include C1-C3 alcohols. In some embodiments, the alcohol is ethanol. Some examples of propellants suitable for deodorant or antiperspirant products include compressed air, nitrogen, inert gases, carbon dioxide, and mixtures thereof. Propellants may also include gaseous hydrocarbons like propane, n-butane, isobutene, cyclopropane, and mixtures thereof; e.g. A-46 (a mixture of isobutane, butane and propane), A-31 (isobutane), A- 17 (n-butane), A-108 (propane), AP70 (a mixture of propane, isobutane and nbutane), AP40 (a mixture of propane, isobutene and n-butane), AP30 (a mixture of propane, isobutane and n- butane). Some non-limiting examples of propellants include 1,1 -difluoroethane, 1, 1,1, 2,2- pentafluoroethane, 1 ,1,1,2-tetrafluoroethane, 1,1,1 ,2,3,3,3-heptafluoropropane, trans- 1,3, 3,3- tetrafluoroprop-l-ene, dimethyl ether, dichlorodifluoromethane (propellant 12), 1 , l-dichloro- 1 ,1 ,2,2-tetrafluoroethane (propellant 114 ), l-chloro-1 ,l-difluoro-2,2-trifluoroethane (propellant II5), l-chloro- 1,1 -difluoroethylene (propellant 142B), 1,1 -difluoroethane (propellant 152A), monochlorodifluoromethane, and mixtures thereof.
[0269] The term "primary structural" as used herein means any material known or otherwise effective in providing suspending, gelling, viscosifying, solidifying, and / or thickening properties to the composition or which otherwise provide structure to the final product form. These primary structurants include gelling agents, and polymeric or non-polymeric or inorganic thickening or viscosifying agents. Such materials will typically be solids under ambient conditions and include organic solids, crystalline or other gellants, inorganic particulates such as clays or silicas, or combinations thereof. Non-limiting examples of suitable primary structurants include stearyl alcohol and other fatty alcohols; hydrogenated castor wax (e.g., Castorwax MP80, Castor Wax, etc.); hydrocarbon waxes include paraffin wax, beeswax, carnauba, candelilla, spermaceti wax, ozokerite, ceresin, baysberry, synthetic waxes such as Fischer-Tropsch waxes, and microcrystalline wax; polyethylenes with molecular weight of 200 to 1000 daltons; solid triglycerides; behenyl alcohol, or combinations thereof.
[0270] Antiperspirant actives may include astringent metallic salts, especially inorganic and organic salts of aluminum, zirconium and zinc, as well as mixtures thereof. Even more specifically, antiperspirant actives may be selected from the group consisting of aluminum chloride, aluminum chlorohydrate, aluminum chlorohydrex, aluminum chlorohydrex PG, aluminum chlorohydrex PEG, aluminum dichlorohydrate, aluminum dichlorohydrex PG, aluminum dichlorohydrex PEG, aluminum sesquichlorohydrate, aluminum sesquichlorohydrex PG, aluminum sesquichlorohydrex PEG, aluminum sulfate, aluminum zirconium octachlorohydrate, aluminum zirconium octachlorohydrex GLY, aluminum zirconium pentachlorohydrate, aluminum zirconium pentachlorohydrex GLY, aluminum zirconium tetrachlorohydrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate GLY and aluminum zirconium trichlorohydrate GLY.
[0271] Chassis ingredients suitable for deodorant or antiperspirant products may be an additional structurant such as stearyl alcohol and other fatty alcohols; hydrogenated castor wax (e.g., Castorwax MP80, Castor Wax, etc.); hydrocarbon waxes include paraffin wax, beeswax, carnauba, candelilla, spermaceti wax, ozokerite, ceresin, baysberry, synthetic waxes such as Fisher-Tropsch waxes, and microcrystalline wax; polyethylenes with molecular weight of 200 to 1000 daltons; and solid triglycerides; behenyl alcohol, or combinations thereof; non-volatile organic fluids such as mineral oil, PPG-14 butyl ether, isopropyl myristate, petrolatum, butyl stearate, cetyl octanoate, butyl myristate, myristyl myristate, C12-15 alkylbenzoate (e.g., Finsolv™), octyldodecanol, isostearyl isostearate, octododecyl benzoate, isostearyl lactate, isostearyl palmitate or isobutyl stearate; clay mineral powders such as talc, mica, sericite, silica, magnesium silicate, synthetic fluorphlogopite, calcium silicate, aluminum silicate, bentonite and montomorillonite; pearl pigments such as alumina, barium sulfate, calcium secondary phosphate, calcium carbonate, titanium oxide, finely divided titanium oxide, zirconium oxide, zinc oxide, hydroxy apatite, iron oxide, iron titrate, ultramarine blue, Prussian blue, chromium oxide, chromium hydroxide, cobalt oxide, cobalt titanate, titanium oxide coated mica; organic powders such as polyester, polyethylene, polystyrene, methyl methacrylate resin, cellulose, 12- nylon, 6-nylon, styrene-acrylic acid copolymers, poly propylene, vinyl chloride polymer, tetrafluoroethylene polymer, boron nitride, fish scale guanine, laked tar color dyes, laked natural color dyes; and combinations thereof.
[0272] Volatile silicone solvents suitable for use in the antiperspirant compositions include, but are not limited to, solvent such as Cyclomethicone D-5; GE 7207 and GE 7158 (commercially available from General Electric Co.); Dow Corning 344; Dow Corning 345; Dow Corning 200; and DC1184 (commercially available from Dow Corning Corp.); and SWS-03314 (commercially available from SWS Silicones).
[0273] The gellant material may comprise saturated or unsaturated, substituted or unsubstituted, fatty alcohols or mixtures of fatty alcohols having from about 20 to about 60 carbons atoms, alternatively from about 20 to about 40 carbon atoms. In some embodiments, the gallant materials comprise combinations of the fatty alcohols. In some embodimens, the fatty alcohol gellants are may be saturated, unsubstituted monohydric alcohols or combinations thereof, which have a melting point of at less than about I1O°C, alternatively from about 60° to about I 10°C, alternatively between about 100 °C and 110°C. Specific examples of fatty alcohol gellants for use in the antiperspirant products that are commercially available include, but are not limited to, llnilin® 425, llnilin® 350, llnilin® 550 and llnilin® 700 (supplied by Petrolite).
[0274] A suitable buffering agent for deodorant or antiperspirant products may be alkaline, acidic or neutral. The buffer may be used in the composition or product for maintaining the desired pH. Suitable buffering agents include, for example, hydrochloric acid, sodium hydroxide, potassium hydroxide, and combinations thereof.
[0275] Non-limiting examples of suitable residue masking materials for use in the antiperspirant products include butyl stearate, diisopropyl adipate, petrolatum, nonvolatile silicones, octyldodecanol, phenyl trimethicone, isopropyl myristate, C12-15 ethanol benzoates and PPG- 14 Butyl Ether.
[0276] The deodorant or antiperspirant products disclosed herein may comprise other optional ingredients such as emulsifiers, distributing agents, antimicrobials, pharmaceutical or other topical actives, surfactants, and the like.
[0277] The nature, amount and type of ingredients does not warrant a more detailed description here, which in any case would not be exhaustive, the person of ordinary skill in the art being able to select them on the basis of general knowledge and according to intended form.
[0278] In some embodiments, the deodorant or antiperspirant comprises less than 95 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 90 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 85 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 80 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 75 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 70 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 65 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 60 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 55 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant comprises less than 50 wt%, or less than 40 wt%, or less than 30 wt%, or less than 20 wt%, or less than 10 wt% of water, relative to the total weight of the deodorant or antiperspirant. In some embodiments, the deodorant or antiperspirant is water-free.
[0279] In the third aspect, the present disclosure relates to a method to inhibit, reduce, or suppress the perception of a sweat malodor in a subject, the method comprising contacting the subject with the sweat malodor inhibiting composition or the consumer product described herein, thereby inhibiting, reducing or suppressing the subject’s perception of the sweat malodor. In a related aspect, the present disclosure relates to the use of the sweat malodor inhibiting compositions described herein for inhibiting, reducing, or suppressing perception of a sweat malodor in a subject.
[0280] In an embodiment, contacting the subject with the sweat malodor inhibiting composition or the consumer product described herein comprises administering to the subject the sweat malodor inhibiting composition or the consumer product, wherein the administering results in dosing the subject with an effective amount of the sweat malodor inhibiting composition. Administration may be via any method readily selected by one of ordinary skill in the art. Methods include, but are not limited to, topical administration and inhalation.
[0281] In an embodiment, contacting the subject with the sweat malodor inhibiting composition or the consumer product described herein comprises dispensing or dispersing the sweat malodor inhibiting composition or the consumer product described herein into a volume in need thereof, wherein the dispensing or dispersing results in dosing the subject with an effective amount of the sweat malodor inhibiting composition. Dispersion or dispensing of the sweat malodor inhibiting composition may be achieved by any method readily selected by one of ordinary skill in the art. Examples include, but are not limited to, a spray, a nebulizer, evaporation of a solution containing the sweat malodor inhibiting composition described herein, and the like. Accordingly, the present disclosure contemplates formulating the sweat malodor inhibiting composition described herein with a suitable carrier to facilitate treating a surface or volume with the sweat malodor inhibiting composition or the consumer product as described herein to the subject.
[0282] In an embodiment, contacting the subject with the sweat malodor inhibiting composition or the consumer product described herein comprises contacting a surface of a sweat malodor source with the sweat malodor inhibiting composition or the consumer product described herein, wherein the contacting results in an effective amount of the sweat malodor inhibiting composition being deposited on the surface. The sweat malodor inhibiting composition may be contacted on a surface by any method known in the art. Examples include, but are not limited to, a spray, a wipe, a solution, laundry care product, and the like. The surface may be any surface that contains a source of sweat malodor, such as human skin or hair, or substrates to which sweat malodor has been transferred, such as a textile.
[0283] The amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is not particularly limited. However, in some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 100 ppm.
[0284] In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 20 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 30 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 40 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 50 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 60 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 70 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 80 to 100 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 90 to 100 ppm.
[0285] In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 90 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 80 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 70 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 60 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 50 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 40 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 30 ppm. In some embodiments, the amount sufficient to reduce, prevent, or inhibit the subject’s perception of sweat malodor is from 10 to 20 ppm.
[0286] The compositions, methods, and uses according to the present disclosure are further illustrated by the following non-limiting examples.
[0287] Example 1. Sweat malodor inhibiting compositions according to some aspects of the present disclosure and comparative compositions
[0288] Sweat malodor inhibiting compositions were prepared by admixing the following ingredients as indicated in Table 1 to Table 3 below. Unless otherwise indicated, amounts are represented as percentages by weight relative to the total weight of the composition.
[0289] Table 1. Sweat malodor inhibiting composition 1
[0290] Table 2. Sweat malodor inhibiting composition 2
[0291] Table 3. Sweat malodor inhibiting composition 3
[0292] Table 4. Sweat malodor inhibiting composition 4
[0293] Comparative compositions were prepared by admixing the following ingredients as indicated in Table 5 to Table 7 below. Table 5. Comparative composition C1
[0294] Table 6. Comparative composition C2
[0295] Table 7. Comparative composition C3
[0296] Example 2. Preparation of deodorant spray emulsion formulations
[0297] A typical deodorant spray emulsion formulation was prepared by mixing and dissolving all the ingredients shown in Table 8. A composition described in Example 1 (0.1 to 1.5% by weight relative to the total weight of the deodorant spray formulation) was then added under gentle shaking. The aerosol can was then filled, and the propellant was crimped and added. Aerosol filling: 40% active solution 60% propane I butane (2.5 bar). A deodorant spray emulsion formulation was prepared for each composition described in Example 1.
[0298] Table 8. Composition of a typical unperfumed deodorant spray formulation.
[0299] (1)Irgasan® DP 300; origin: BASF
[0300] Example 3. Sensory Evaluation
[0301] The deodorant sprays comprising the sweat malodor inhibiting compositions according to some aspects of the present disclosure (sweat malodor inhibiting compositions 1-4, “test formulation”) and comparative compositions (comparative compositions C1-C3, “comparative formulation”) made according to the procedure described in Example 2 were evaluated.
[0302] An amount of 0.8 gram (+ / -0.05 gram) of the test formulation was applied to separate large blotters (5 cm width) from a distance of 12 cm from the aerosol can. The aerosol can was shaken before each spray. In parallel, the comparative formulations were similarly applied to separate large blotters. Each blotter was placed on a 35°C hot plate for 6 hours.
[0303] A minimum of 20 skilled panelists were asked to evaluate the intensity of the fragrance of the formulation and the intensity of the perceived malodor, in a blind, balanced, randomized study, with a 60 second break between samples. About 35 minutes prior to the study, 1.2 grams of sweat body odor solution was applied to a filter paper placed at the bottom of a 500 mL glass jar. 20 minutes prior to the study, each blotter with a fragrance formulation was placed into each related jar. Jars were placed into a 40°C oven for 15 minutes. 5 minutes prior to the study, jars were taken out of the oven and left to cool for 5 minutes. The panelists were asked to (i) rank the intensity of the fragrance from 0 (not perceptible), to 10 (very strong odour), and (ii) rank the intensity of the perceived malodor from 0 (not perceptible), to 10 (very strong odour). The results of the evaluation were analyzed using Analysis of Variance with Duncan’s post-hoc analysis (a= 0.05), wherein:
[0304] The results are shown in Tables 9-12 below.
[0305] Table 9. Percentage reduction in the perceived malodor intensity 6 hours after application of a spray deodorant formulation comprising sweat malodor inhibiting composition 1 or comparative composition C1.
[0306] Referring to Table 9, the test formulation comprising sweat malodor inhibiting composition 1 demonstrated a greater percentage reduction in the perceived malodor intensity 6 hours after application than the formulation comprising comparative composition C1.
[0307] Table 10. Percentage reduction in the perceived malodor intensity 6 hours after application of a spray deodorant formulation comprising sweat malodor inhibiting composition 2 or comparative composition C2. Referring to Table 10, the test formulation comprising sweat malodor inhibiting composition 2 demonstrated a greater percentage reduction in the perceived malodor intensity 6 hours after application than the formulation comprising comparative composition C2.
[0308] Table 11. Percentage reduction in the perceived malodor intensity 6 hours after application of a spray deodorant formulation comprising sweat malodor inhibiting composition 3 or comparative composition C3.
[0309] Referring to Table 11 , the test formulation comprising sweat malodor inhibiting composition 3 demonstrated a greater percentage reduction in the perceived malodor intensity 6 hours after application than the formulation comprising comparative composition C3.
[0310] Table 12. Percentage reduction in the perceived malodor intensity 6 hours after application of a spray deodorant formulation comprising sweat malodor inhibiting composition 4 or comparative composition C3.
[0311] Referring to Table 12, the test formulation comprising sweat malodor inhibiting composition 4 demonstrated a greater percentage reduction in the perceived malodor intensity 6 hours after application than the formulation comprising comparative composition C3.
[0312] The disclosed subject matter has been described with reference to specific details of particular embodiments thereof. It is not intended that such details be regarded as limitations upon the scope of the disclosed subject matter except insofar as and to the extent that they are included in the accompanying claims.
[0313] Therefore, the exemplary embodiments described herein are well adapted to attain the ends and advantages mentioned as well as those that are inherent therein. The particular embodiments disclosed above are illustrative only, as the exemplary embodiments described herein may be modified and practiced in different but equivalent manners apparent to those of ordinary skill in the art having the benefit of the teachings herein. Furthermore, no limitations are intended to the details of construction or design herein shown, other than as described in the claims below. It is therefore evident that the particular illustrative embodiments disclosed above may be altered, combined, or modified and all such variations are considered within the scope and spirit of the exemplary embodiments described herein. The exemplary embodiments described herein illustratively disclosed herein suitably may be practiced in the absence of any element that is not specifically disclosed herein and / or any optional element disclosed herein.
Claims
CLAIMS1. A composition for inhibiting sweat malodor, the composition comprising: a) at least one Group A ingredient, wherein the at least one Group A ingredient is selected from the group consisting of:2-(3-phenylpropyl)pyridine,(+-)-(2E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one,1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, methyl 2-((1 RS,2RS)-3-oxo-2-pentylcyclopentyl)acetate,(+-)-(2,5-dimethyl-2,3-dihydro-1H-inden-2-yl)methanol,(+)-(3R,5Z)-3-methyl-5-cyclopentadecen-1-one,(+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,(+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,(2E,6Z)-2,6-nonadienal,(+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,(3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one,(+-)-7-hydroxy-3,7-dimethyl octanal, and mixtures thereof; b) at least one Group B ingredient, wherein the at least one Group B ingredient is selected from the group consisting of: decanal, undecanal,4-methoxybenzaldehyde,(+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate,(+-)-allyl (2-methylbutoxy)acetate,(3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan,3-ethoxy-4-hydroxybenzaldehyde, (+-)-(3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,(+-)-(1 E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one,1 -(2-naphthyl)ethanone,(4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,(+-)-4-nonanolide,2-phenylethanol,(4Z)-4-dodecenal,3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal,thymol,(+-)-3-phenylbutanal, and mixtures thereof; and c) at least one Group C ingredient, wherein the at least one Group C ingredient is selected from the group consisting of:(+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one,(2E)-3-phenyl-2-propen-1-ol, patchouli oil,(1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate,2-ethyl-3-hydroxy-4(4H)-pyranone,(+-)-8-sec-butylquinoline,(+-)-6-sec-butylquinoline,(+-)-2,6-dimethyl-5-heptenal,(+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, (+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate,3-phenylpropanal, (+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate, (4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, and mixtures thereof; wherein the total number of Group A, B, and C ingredients is at least 4, typically at least 8, more typically at least 11 , and the total amount of Group A, B, and C ingredients is at least 2%, typically at least 7%, more typically at least 15% by weight relative to the total weight of the composition.
2. The composition of claim 1, wherein the at least one Group A ingredient is selected from the group consisting of:(+-)-(2 E)- 1 -(2, 6,6-trimethyl-2-cyclohexen- 1 -yl)-2-buten- 1 -one,1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,(+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one, (+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate, (2E,6Z)-2,6-nonadienal, (+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one, (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof; the at least one Group B ingredient is selected from the group consisting of: decanal, undecanal, (+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate, (+-)-allyl (2-methylbutoxy)acetate, (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan, 1 -(2-naphthyl)ethanone, (4E)-4-methyl-5-(4-methylphenyl)-4-pentenal, (+-)-4-nonanolide,2-phenylethanol, (4Z)-4-dodecenal,3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, (+-)-3-phenylbutanal, and mixtures thereof; and the at least one Group C ingredient is selected from the group consisting of: (+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one, (2E)-3-phenyl-2-propen-1-ol, patchouli oil, (1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate, (+-)-8-sec-butylquinoline, (+-)-6-sec-butylquinoline, (+-)-2,6-dimethyl-5-heptenal, (+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, (+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, 3-phenylpropanal, (+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1 ,0(2,6)]dec-3-en-8-yl propanoate,tricyclo[5.2.1.0(2,6)]dec-4-en-8-yl propanoate,(4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,(4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,(4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,(4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, and mixtures thereof.
3. The composition of claim 1 , whereinthe at least one Group A ingredient is selected from the group consisting of:2-(3-phenylpropyl)pyridine,(+-)-(2 E)- 1 -(2, 6,6-trimethyl-2-cyclohexen- 1 -yl)-2-buten- 1 -one,1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one, methyl 2-((1 RS,2RS)-3-oxo-2-pentylcyclopentyl)acetate, (+-)-(2,5-dimethyl-2,3-dihydro-1H-inden-2-yl)methanol, (+)-(3R,5Z)-3-methyl-5-cyclopentadecen-1-one,(+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,(+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,(2E,6Z)-2,6-nonadienal,(+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,(3E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one, (+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof; the at least one Group B ingredient is selected from the group consisting of: 4-methoxybenzaldehyde, (+-)-2-methylundecanal, allyl (3-methylbutoxy)acetate, (+-)-allyl (2-methylbutoxy)acetate, (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan,3-ethoxy-4-hydroxybenzaldehyde, (+-)-(3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one, (+-)-(1 E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one,1 -(2-naphthyl)ethanone,(4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,(+-)-4-nonanolide,2-phenylethanol,(4Z)-4-dodecenal,3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, thymol,(+-)-3-phenylbutanal, and mixtures thereof; and the at least one Group C ingredient is selected from the group consisting of:(2E)-3-phenyl-2-propen-1-ol, patchouli oil,2-ethyl-3-hydroxy-4(4H)-pyranone,(+-)-8-sec-butylquinoline,(+-)-6-sec-butylquinoline,(+-)-3-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde,(+-)-4-(4-methyl-3-penten- 1 -yl)-3-cyclohexene- 1 -carbaldehyde, methyl 2,4-dihydroxy-3,6-dimethylbenzoate,3-phenylpropanal,(+-)-2,3,3-trimethyl-1-indanone, tricyclo[5.2.1.0(2,6)]dec-3-en-8-yl propanoate, tricyclo[5.2.1 ,0(2,6)]dec-4-en-8-yl propanoate, and mixtures thereof.
4. The composition of any one of claims 1 to 3, wherein the at least one Group A ingredient is selected from the group consisting of:(+-)-(2E)- 1 -(2,6,6-trimethyl-2-cyclohexen- 1 -yl)-2-buten- 1 -one,1-(3,3-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-one,(+-)- 1 -(5-ethyl-5-methyl- 1 -cyclohexen- 1 -yl)-4-penten- 1 -one,(+-)-methyl 2,2-dimethyl-6-methylidenecyclohexanecarboxylate,(+-)-(3E)-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one,(+-)-7-hydroxy-3,7-dimethyloctanal, and mixtures thereof.
5. The composition of any one of claims 1 to 4, wherein the at least one Group B ingredient is selected from the group consisting of: allyl (3-methylbutoxy)acetate,(+-)-allyl (2-methylbutoxy)acetate,1 -(2-naphthyl)ethanone,(4E)-4-methyl-5-(4-methylphenyl)-4-pentenal,(+-)-4-nonanolide,3-(4,4-dimethyl-1-cyclohexen-1-yl)propanal, (+-)-3-phenylbutanal, and mixtures thereof.
6. The composition of any one of claims 1 to 5, wherein the at least one Group C ingredient is selected from the group consisting of:(+-)-1,1 ,2,3,3-pentamethyl-1 ,2,3,5,6,7-hexahydro-4H-inden-4-one,(2E)-3-phenyl-2-propen-1-ol,(1 R,2R)-1 ,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl acetate,(+-)-2,6-dimethyl-5-heptenal,3-phenylpropanal,(+-)-2,3,3-trimethyl-1-indanone,(4RS,4aSR,8SR,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,(4RS,4aRS,8RS,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,(4RS,4aSR,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one,(4RS,4aRS,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aRS,8SR,8aRS)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, (4RS,4aSR,8RS,8aSR)-4-ethyl-8-methyloctahydronaphthalen-1(2H)-one, and mixtures thereof.
7. The composition of any one of claims 1 to 6, wherein the at least one Group C ingredient is selected from the group consisting of:(2E)-3-phenyl-2-propen-1-ol,3-phenylpropanal,(+-)-2,3,3-trimethyl-1-indanone, and mixtures thereof.
8. The composition of any one of claims 1 to 7, wherein the total number of Group A, B, and C ingredients is from 4 to 20, typically from 8 to 15, more typically from 11 to 14.
9. The composition of one of claims 1 to 8, wherein the total amount of Group A, B, and C ingredients is from 2% to 80%, typically from 7% to 50%, by weight relative to the total weight of the composition.
10. A consumer product comprising the composition of any one of claims 1 to 9.
11. The consumer product of claim 10, wherein the consumer product is a deodorant or antiperspirant comprising 0.1 to 5.0 wt%, typically 0.2 to 5.0 wt%, of the sweat malodor inhibiting composition, and at least one deodorant or antiperspirant active base.
12. The consumer product of claim 11 , wherein the deodorant or anti-perspirant is in the form of a wax-based stick, soap-based stick, compressed powder stick, roll-on suspension or solution, emulsion, gel, cream, squeeze spray, pump spray, or aerosol.
13. A method of reducing a perception of a sweat malodor, the method comprising contacting a source of the sweat malodor with the composition of any one of claims 1 to 9 or the consumer product of any one of claims 10 to 12.
14. The method of claim 13, wherein the source is a human skin surface or an article of clothing.
15. Use of the composition of any one of claims 1 to 9 for inhibiting a perception of sweeat malodor.
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