Synthesis of aluminum precursors without use of pyrophoric compounds and related compositions and related methods

A method combining aluminum halides, alkoxy aluminum compounds, and Grignard reagents safely synthesizes aluminum precursors, addressing the dangers of pyrophoric compounds and producing high-purity vapor deposition precursors.

WO2026112016A1 Publication Date: 2026-05-28ENTEGRIS INC
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Patent Information

Application Number
PCT/US2025/055807
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-11-19
Filing Date
2025-11-17
Publication Date
2026-05-28

AI Technical Summary

Technical Problem

Conventional methods for synthesizing aluminum precursors involve the use of pyrophoric compounds, posing dangerous conditions due to their reactivity.

Method used

A method involving the reaction of an aluminum halide compound with an alkoxy aluminum compound, followed by a Grignard reagent, to form a vapor deposition precursor without using pyrophoric compounds.

Benefits of technology

This approach allows for the synthesis of aluminum precursors safely, eliminating the hazards associated with pyrophoric compounds and enabling the production of high-purity vapor deposition precursors.

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Abstract

Methods for forming a vapor deposition precursor are provided. The method comprises contacting an aluminum halide compound, an alkoxy aluminum compound, and a Grignard reagent to form the vapor deposition precursor. The vapor deposition precursor comprises an dialkyl aluminum alkoxide compound. The vapor deposition precursor is formed without use of a pyrophoric compound. Related compositions, related precursors, and related methods are also provided, among other things.
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