Oil-in-water perfumed emulsion with fragrance

Abstract

An oil-in-water perfumed emulsion is disclosed, suitable for personal care applications, offering enhanced fragrance delivery and stability. The emulsion comprises an oil phase containing a fragrance component (1-35 wt%), a non-ionic surfactant (1-6 wt%), and an optional emollient (0-15 wt%), and an aqueous phase with a suspending component (0.20-1.5 wt%) formed from microcrystalline cellulose and cellulose gum, an optional moisturizer, and water (≥25 wt%). The formulation achieves high fragrance concentrations while maintaining stability, avoiding alcohol-based systems, and providing a smooth, non-sticky skin feel.

Description

OIL-IN-WATER PERFUMED EMULSION WITH FRAGRANCECLAIM OF PRIORITY

[0001] This patent application claims the benefit of priority to FR Application Serial No. 2414378, filed December 17, 2024, which is incorporated by reference herein in its entirety.BACKGROUND

[0002] Oil-in-water perfumed emulsions can be used to carry a fragrance.SUMMARY

[0003] In some aspects, an oil-in-water perfumed emulsion is described including: an oil phase including: a fragrance component ranging from about 1 wt% to about 35 wt% of the emulsion; a non-ionic surfactant ranging from about 1 wt% to about 6 wt% of the emulsion: and an optional emollient ranging from about 0 wt% to about 15 wt% of the emulsion; and an aqueous phase including: an optional moisturizer component; a suspending component ranging from about 0.20 wt% to about 1.5 wt% of the emulsion, wherein the suspending component is a mixture of microcrystalline cellulose and cellulose gum; an optional thickener; and at least 25 wt% of the emulsion of an aqueous solvent being water.

[0004] In some aspects, an oil-in-water perfumed emulsion is described including: an aqueous phase including: glycerin in a range of from about 0.01 wt% to about 5 wt% of the emulsion; a mixture of Microcrystalline Cellulose and Cellulose Gum in a range of from about 0.20 wt% to about 1 wt% of the emulsion; and water; and an oil phase including: a mixture of polyglyceryl-6 stearate and polyglyceryl-6 behenate in a range of from about 2 wt% to about 6 wt%; caprylic triglyceride in a range of from about 0.01 wt% to about 7 wt%; and a fragrance in a range of from about 5 wt% to about 40 wt% of the emulsion.DETAILED DESCRIPTION

[0005] Reference will now be made in detail to certain aspects of the disclosed subject matter. While the disclosed subject matter will be described in conjunction with theenumerated claims, it will be understood that the exemplified subject matter is not intended to limit the claims to the disclosed subject matter.

[0006] Throughout this document, values expressed in a range format should be interpreted in a flexible manner to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a range of “about 0.1% to about 5%” or “about 0.1% to 5%” should be interpreted to include not just about 0.1% to about 5%, but also the individual values (e.g., 1%, 2%, 3%, and 4%) and the sub-ranges (e.g., 0.1%’ to 0.5%, 1.1%’ to 2.2%, 3.3%’ to 4.4%) within the indicated range. The statement “about X to Y” has the same meaning as “about X to about Y,” unless indicated otherwise. Likewise, the statement “about X, Y, or about Z” has the same meaning as “about X, about Y, or about Z,” unless indicated otherwise.

[0007] In this document, the terms “a,” “an,” or “the” are used to include one or more than one unless the context clearly dictates otherwise. The term “or” is used to refer to a nonexclusive “or” unless otherwise indicated. The statement “at least one of A and B” has the same meaning as “A, B, or A and B.” In addition, it is to be understood that the phraseology or terminology employed herein, and not otherwise defined, is for the purpose of description only and not of limitation. Any use of section headings is intended to aid reading of the document and is not to be interpreted as limiting; information that is relevant to a section heading may occur within or outside of that particular section.

[0008] In the methods described herein, the acts can be carried out in any order without departing from the principles of the disclosure, except when a temporal or operational sequence is explicitly recited. Furthermore, specified acts can be carried out concurrently unless explicit claim language recites that they be carried out separately. For example, a claimed act of doing X and a claimed act of doing Y can be conducted simultaneously within a single operation, and the resulting process will fall within the literal scope of the claimed process.

[0009] The term “about” as used herein can allow for a degree of variability in a value or range, for example, within 10%, within 5%, or within 1% of a stated value or of a stated limit of a range, and includes the exact stated value or range.

[0010] The term “substantially” as used herein refers to a majority of, or mostly, as in at least about 50%, 60%, 70%, 80%, 90%, 95%, 96%, 97%, 98%, 99%, 99.5%, 99.9%, 99.99%, or at least about 99.999% or more, or 100%. The term “substantially free of’ as used herein can mean having none or having a trivial amount of, such that the amount of material present does not affect the material properties of the composition including the material, such that about 0 wt% to about 5 wt% of the composition is the material, or about 0 wt% to about 1 wt%, or about 5 wt%> or less, or less than or equal to about 4.5 wt%, 4, 3.5, 3, 2.5, 2, 1.5, 1, 0.9, 0.8, 0.7, 0.6, 0.5, 0.4, 0.3, 0.2, 0.1, 0.01, or about 0.001 wt% or less, or about 0 wt%.

[0011] The present disclosure relates to oil-in-water perfumed emulsions, particularly stable fragrance -containing emulsions suitable for use in personal care applications. The present disclosure provides numerous non-limiting advantages for fragrance delivery in consumer products. The formulation allows for incorporation of unexpectedly high concentrations of fragrance (e.g., perfume) compounds while maintaining excellent stability, resulting in enhanced fragrance intensity when applied to skin. The composition achieves these benefits through a substantially (e.g., less than 1 wt%, 0.5 wt%, or 0.01 wt% or 0 wt%) alcohol-free system (e.g., free of ethanol), addressing common drawbacks of traditional ethanol-based fragrances while delivering comparable or superior performance.

[0012] The formulation demonstrates favorable characteristics including a smooth and non-sticky skin feel, achieved through optimized levels of surfactants and polymers. The manufacturing process offers additional advantages through a hot-cold production method that maintains fragrance integrity. The composition provides sustained fragrance release and extended longevity on the skin, while delivering a refined olfactory experience free from interfering alcohol or surfactant notes upon initial application.

[0013] The disclosed oil-in-water perfumed emulsion system allows for precise application to targeted areas while maintaining outstanding stability even at elevated perfume concentrations. These benefits can be achieved without requiring high levels of surfactants or polymers typically needed in conventional systems. The versatile formulation is suitable for various cosmetic and personal care applications including, but not limited to, fine fragrances, body mists, body lotions, body creams, and hair mists.

[0014] The composition demonstrates good stability characteristics while accommodating substantial fragrance loads (e.g., 20 wt% or greater), addressing a long¬ standing challenge in the field of perfumery and personal care products. This stability isachieved through the unique combination of components and processing parameters, resulting in a sprayable liquid formulation suitable for diverse applications in the cosmetic and personal care sectors.

[0015] In general, an oil-in-water perfumed emulsion is a dispersion system where oil droplets are distributed throughout a continuous aqueous (water) phase. The oil phase is suspended as microscopic droplets within the water phase, stabilized by surfactants that form interfaces between the two immiscible phases. The surfactants position themselves at the oil¬ water interface with their hydrophilic (water-loving) portions oriented toward the water phase and their lipophilic (oil-loving) portions oriented toward the oil phase, creating a stable dispersion.

[0016] The oil-in-water perfumed emulsion includes an oil phase dispersed in an aqueous phase. The oil phase contains a fragrance component, surfactant system, and emollient, while the aqueous phase, suspending agents, and water as the (primary) solvent.

[0017] The fragrance material is present in the oil phase and can range from about 1 wt% to about 35 wt% of the total emulsion, about 2 wt% to about 35 wt%, less than, equal to, or greater than about 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, 15, 15.5, 16, 16.5, 17, 17.5, 18, 18.5, 19, 19.5, 20, 20.5, 21, 21.5, 22, 22.5, 23, 23.5, 24, 24.5, 25, 25.5, 26, 26.5, 27, 27.5, 28, 28.5, 29, 29.5, 30, 30.5, 31, 31.5, 32, 32.5, 33, 33.5, 34, 34.55, or about 35 wt% of the total emulsion. The fragrance material may include various perfume ingredients and aromatic compounds.

[0018] As described herein, the “fragrance materials” may be classified as low, moderate or high volatile fragrance materials according to their volatility by their vapor pressure. This method of classifying fragrance materials by their vapor pressure avoids the problem of different classifications for the same fragrance material according to the traditional approach that relies on their subjective characteristic character. In the case that the fragrance materials are a natural oil, extract or absolute, which comprises a mixture of several compounds, the vapor pressure of the complete oil should be treated a mixture of the individual perfume raw material components using the reference program cited above. The individual components and their level, in any given natural oil or extract, can be determined by direct injection of the oil into a GC-MS column for analysis as known by one skilled in the art. In the scenario that the fragrance materials are a proprietary specialty accord, so called ‘bases’, the vapor pressure, using the reference program cited above, should preferably beobtained from the supplier. However, it is understood by one skilled in the art that they can physically analyze the composition of a full fragrance oil available commercially to identity the fragrance raw materials and their levels using standard GC-MS techniques. This would be irrespective of whether they had been added to the fragrance oil as individual chemicals, as components of naturals or from proprietary bases. Although proprietary bases and naturals are included in our examples, when analyzing a commercially available fragrance via GC-MS one could simply identify the components of the base or natural oil as part of the overall fragrance mixture and their levels, without being able to identify which proprietary base or natural oil the fragrance had come from.(i) Low Volatile Fragrance Materials

[0019] The fragrance component can include at least one low volatile fragrance material. Individual low volatile fragrance materials or aggregate low volatile fragrance materials are those having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 °C. According to some examples, the composition can include at least 3 low volatile fragrance materials, or at least 4 low volatile fragrance materials, or at least 5 low volatile fragrance materials, or at least 7 low volatile fragrance materials.

[0020] If there are more than one low volatile fragrance materials, then the ranges provided hereinabove cover the total of all the low volatile fragrance materials. Examples of suitable low volatile fragrances materials are provided in Table 1A and IB below.

[0021] The low volatile fragrance material may be selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, at least 7, at least 8, at least 10, or at least 12 low volatile fragrance materials as disclosed in Table 1A. Natural fragrance materials or oils having an aggregate vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 °C are provided in Table IB. Low Volatile Natural Oils.[Table 1 A] Low Volatile Fragrance MaterialsNo. CAS Number IUPAC Name Common VaporName** Pressure (Torr at 25°C)*1. 1211-29-6 Cyclopentaneacetic acid, Methyl 0.000965003 -oxo-2 -(2Z) -2-penten- 1 - jasmonateyl-, methyl ester,(H?,2i?)-2-Buten-l-ol, 2-methyl- Hindinol 0.00096100 4-(2,2,3-trimethyl-3- cy clopenten- 1 -yl) - Ethanone, l-(2- Methyl beta0.00095700 naphthalenyl)- naphthylketone3-Decanone, 1 -hydroxy- Methyl 0.00095100LavenderKetone Cyclopropanemethanol, Javanol® 0.00090200 1 -methyl -2-[( 1,2,2- tri methylbicyclo [3.1.0] hex-3-yl)methyl]- Benzaldehyde, 3-ethoxy- Ethyl vanillin 0.00088400 4-hydroxy- 3 -Cyclohexene- 1 - Myraldylaceta 0.00087900 methanol, 4-(4-methyl-3- tepenten-l-yl)-, 1 -acetate2H- 1,5-Benzodioxepin- Calone 0.00083100 3(4H)-one, 7-methyl- 2-Butanol, l-[[2-(1,l- Amber core 0.00080300 dimethyiethyl )cy clohexyl]oxy]- Spiro [5.5 ]undec- 8 -en - 1 - Spiro[5.5]und 0.00073100 one, 2,2,7,9 -tetramethyl- ec-8-en-l-one,2, 2,7,9- tetramethyl- Cyclopentaneacetic acid, trans-Hedione 0.00071000 3-oxo-2 -pentyl-, methylester, (17?,2 / ?)-rel- Cyclopentaneacetic acid, Methyl 0.00071000 3-oxo-2-pentyl-, methyl dihydrojasmoester nate oralternatives1Octanal, 2- Hexyl 0.00069700 (phenylmethylene ) - cinnamicaldehydeIndeno[4,5-d] -1,3-dioxin, Nebulone 0.00069200 4, 4a, 5,6, 7, 8, 9,9b- octahydro-7,7,8,9,9- pentamethyi- Cyclopentanecarboxylic Dihydro Iso 0.00067500 acid, 2-hexyl-3-oxo-, Jasmonatemethyl ester3 -Cyclopentene- 1- Sandalore® 0.00062500 butanol, a, p, 2,2,3-pentamethyl-68133-79-9 Cyclopentanone, 2-(3,7- Apritone 0.00062000 dimethvl-2.6-octadien- 1 - yl)- 7212-44-4 1.6.10-Dodecatrien -3 -ol, Nerolidol 0.000616003.7.11-trimethyl- 53243-59-7 2 -Pentenenitrile, 3- Citronitril 0.00061500 methyl-5 -phenyl-, (2Z)- 134123-93-6 Benzenepropanenitrile, Fleuranil 0.000576004-ethyl-a,a-dimethyl- 77-53-2 1 H-3a,7 -Methanoazulen- Cedrol Crude 0.000569006-ol, octahydro-3, 6,8,8- tetramethyl-,(3A,3aS,6A,7A,8aS)- 68155-66-8 Ethanone, 1- Iso Gamma 0.00056500(1,2,3,5,6,7,8,8a- Superoctahydro-2, 3,8,8- tetramethyl-2- naphthalenyl)- 54464-57-2 Ethanone, 1- Iso-E Super® 0.00053800(1, 2, 3, 4, 5, 6,7,8- octahydro-2, 3,8,8- tetramethyl-2- naphthalenyl)- 774-55-0 Ethanone, 1 -(5, 6,7,8- Florantone 0.00053000 tetrahydro-2- naphthalenyl)- 141-92-4 2-Octanol, 8,8- Hydroxyci tro 0.00052000 dimethoxy-2,6-dimethyl- nellalDimethylAcetal20665-85-4 Propanoic acid, 2- Vanillin 0.00051200 methyl-, 4-fonnyl-2- isobutyrate methoxyphenyl ester79-78-7 l,6-Heptadien-3-one, 1- Hexalon 0.00049800(2,6,6-trimethyl-2- cyclohexen-1 -yl)- 6259-76-3 Benzoic acid, 2-hydroxy- Hexyl 0.00049100, hexyl ester Salicylate93-99-2 Benzoic acid, phenyl Phenyl 0.00047900 ester Benzoate153859-23-5 Cyclohexanepropanol, Norlimbanol 0.000469002,2,6-trimethyl-a-propyl-, (1A,6S)- 70788-30-6 Cyclohexanepropanol, I ’imberol / 0.000469002,2,6-trimethyl-a-propyl- Norlinibanol68555-58-8 Benzoic acid, 2-hydroxy- Prenyl 0.00045700, 3-methyl-2-buten-l-yl Salicylateester2H- 1,5-Benzodioxepin- Cascalone 0.00045500 3(4£ / )-one, 7-(1 - methylethyl)- Butanal, 4-(octahydro- Dupical 0.00044100 4,7 -methano-5H-inden-5 - ylidene)- Cyclopenta[g]-2- Galaxolide® 0.00041400 benzopyran, 1, 3, 4, 6,7,8- hexahydro-4,6,6,7,8,8- hexamethyl- 2.6.10-Dodecatrien-l -ol, Farnesol 0.00037000 3.7.11-trimethyl- Cyclopentanone, 2-[2-(4- Nectaryl 0.00036700 methyl-3-cyclohexen- 1 - yl)propylj- 2(37 / )-Naphthalenone, Nootkatone 0.00035800 4, 4a, 5,6,7,8-hexahydro- 4,4a-dimethyl-6-( 1 - methylethenyl)-,(4 / f,4aS,6i?)- 2-Propenoic acid, 3- Amyl 0.00035200 phenyl-, pentyl ester Cinnamate2-hydroxy-2-phenylethyl Styrolyl 0.00033900 acetate Acetate42 / -Pyran-4-one, 3- Maltol 0.00033700 hydroxy-2-methyl- 1 -Propanol, 2-methyl-3- Bornafix 0.00033400 [(1,7,7- tri niethylbicyclo [2.2.1 ] hept-2-yl)oxy]- 1-Naphtlialenol, Octalynol 0.00033200 1, 2,3, 4, 4a, 5, 8,8a- octahydro-2, 2,6,8- tetramethyl- 2-Butenoic acid, 2- Geranyl 0.00033200 methyl-, (2E)-3,7- Tiglatedimethyl -2, 6-octadien- 1 - yl ester, (2E)- 1,3-Dioxane, 2-(2,4- Karanal 0.00033100 dimethyl-3-cyclohexen- l-yl)-5-methyl-5-(l- methylpropyl)- Nonadecane Nonadecane 0.00032500 4-Penten-2-ol, 3-methyl- Ebanol 0.00028100 5-(2,2,3-trimethyl-3-cyclopenten-l-yl)-Propanoic acid, 2- Maltol 0.00028000 methy 1-, 2-methy 1-4-oxo - Isobutyrate4H-pyran-3-yl ester2-Buten-l-ol, 2-ethyl-4- Laevo 0.00028000 (2,2,3 -trimethyl-3- Trisandolcyclopenten-l-yl)- 1,6-Methanonaphthalen- Healingwood 0.00027800 l(2 / / )-ol, octahydro- 4, 8a, 9,9 -tetramethyl-,(lA,4S,4aS,6A,8aS)- 2H-1,5-Benzodioxepin- Transluzone 0.00026500 3(4H)-one, 7-(l,l- dimethylethyl)- 8-Cyclohexadecen- 1 -one Cyclohexadec 0.00025300 enoneBenzoic acid, 2-hydroxy- cis-3 -Hexenyl 0.00024600, (3Z)-3-hexen-l-yl ester salicylate4H-Pyran -4-one, 2-ethyl- Ethyl Maltol 0.00022800 3-hydroxy- Cyclopentadecanone, 3- Muskone 0.00017600 methyl- Benzoic acid, 2-hydroxy- Benzyl 0.00017500, phenylmethyl ester salicylate6, 8 -Nonadien -3 -one, Labienoxime 0.00017300 2,4,4, 7-tetr amethyl -,oximeBenzoic acid, 2-hydroxy- Cyclohexyl 0.00017300, cyclohexyl ester SalicylateBenzene, [2- Amyl 0.00016300 (dimethoxy methyl )-l- Cinnamichepten-l-ylj- AldehydeDimethylAcetal3-Cyclopentene-l- Firsantol 0.00016000 butanol, p, 2,2,3 - tetrarnethyl-5-methylene- 4-Penten-l-one, 1- Spirogalbanon 0.00015300 spiro [4.5] dec-7 -en-7 -yl - e5 - Azulenemethanol, Guaiyl 0.00013400 1, 2, 3, 4, 5, 6,7,8- Acetateoctahydro-a,a,3, 8- tetrarnethyl-, 5 -acetate,(3S,5A,8S)- Acetic acid, 2-(l- Romandolide 0.00012400 oxopropoxy)-, l-(3,3- dimethyl cyclohexyl )ethylester2-Penten-l-ol, 5- cis-alpha- 0.00011800[(17?,3A,65)-2,3- Santaloldimethyltricyclo[2.2.1.02.6 ] hept- 3 -yl ] -2 -methyl -,(2Z)- 4-Penten-2-ol, 3,3- Polysantol® 0.00011700 dimethyl-5 -(2,2,3- trimeihyl-3-cvclopenien- 1-yl)- 5,8-Methano-2H-l- Florex® 0.00011000 benzopyran-2-one, 6- ethylideneoctahydro- Heptanal, 2-[(4- Acalea 0.00010100 methy lphenyl)methyl ene]4-Cyclopentadecen- 1 - Exaltenone 0.00009640 one, (4Z)- Ethanone, 1- Vertofix® 0.00008490 [(3 / ?,3a / ?,7 / ?,8a5)- 2,3,4,7,8,8a-hexahydro- 3, 6, 8, 8 -te tr amethyl - 1 H- 3 a,7 -methanoazulen -5 - yl]- 1,3 -Dioxolane, 2,4- Okoumal® 0.00007600 dimethyl-2-(5,6,7,8- tetrahydro-5,5,8,8- tetr amethyl -2- naphthalenyl)- Oxacyclohexadecan-2 - Exaltolide® 0.00006430 one1 -Propanol, 2-[l-(3,3- Helvetolide® 0.00005790 dimethylcyclohexyl)ethoxy]-2-methyl-, 1- propanoate5 -Cyclopentadecen- 1 - Delta 0.00005650 one, 3-methyl- Muscenone2-Penten-l-ol, 2-methyl- cis-beta- 0.00004810 5-[(15,27?,4 / ?)-2-methyl- Santalol3- methylenebicyclo[2.2.1 ]hept-2-yl]-, (2Z)- 2H- 1, 5-Benzodioxepin- Azurone 0.00004770 3 (4 / f) -one, 7-(3- methylbutyl)- Ethanone, l-(2,6, 10- Trimofix O 0.00004580 trimethyl-2,5,9- cyclododecatrien- 1 -yl)- lH-3a,6- Khusimol 0.00004400 Methanoazulene -3 - methanol, octahydro-7,7- dimethyl-8-methylene-,(3S,3a^,67?,8a5)-Benzeneacetonitrile, α- Peonile 0.00004290 cyclohexylidene- Benzenemethanol, a- Rosacetol 0.00004240 (trichloromethyl)-, 1- acetateBenzoic acid, 2-[(2- Mevantraal 0.00004070 methylpentylidenejamino]-, methyl ester5-Hydroxy-2-benzyl-1,3- Acetal CD 0.00004050 dioxaneBenzoic acid, 2- Phenyl Ethyl 0.00003480 phenyiethyl ester Benzoate Cyclohexadec-8-en-l - Globanone® 0.00003310 one5-Cyclohexadecen-1-One Ambretone 0.00003310 Cyclohexanol, 4-(l,7,7- Iso Bornyl 0.00003010 trimethylbicyclo[2.2. IJhe Cyclohexanolpt-2-yl)- 3-Cyclohexene-l - Lyral® 0.00002940 carboxaldehyde, 4-(4- hydroxy-4- methylpentyl)- Ethanone, 1-15,6,7,8- Musk Plus 0.00002860 tetrahydro-3,5,5,6,8,8- hexamethyi-2- naphthalenyl)- Ethanone, l-(5, 6,7,8- Fixolide 0.00002860 tetrahydro-3,5,5,6,8,8- hexamethyl-2- naphthalenyl)- 2-Cyclopentadecen-l - Muscenone 0.00002770 one, 3-methyl- Oxacycloheptadecan-2 - Silvanone Ci 0.00002600 oneBenzeneacetic acid, 4- Para Cresyl 0.00002330 methylphenyl ester PhenylAcetate Benzeneacetic acid, 2- Phenyl Ethyl 0.00002300 phenylethyl ester PhenylAcetate Cyclododecaneethanol, Hydroxyambr 0.00001800 P-methyl- an2-Propenoic acid, 3- Benzyl 0.00001050 phenyl-, phenyl methyl CinnamateesterBenzoic acid, 2,4- Veramoss / 0.00001050 dihydroxy-3, 6-dimethyl-, LRG201 / methyl ester Evernyl96. 183551-83-9 Naphtho[2,1-b]furan- Myrrhone 0.00000977 6(7H)-one, 8,9-dihydro- 1,5,8-trimethyl-, (8R)- 97. 102-17-0 Benzeneacetic acid, (4- Para Anisyl 0.00000813 methoxyphenyl)methyl Phenyl ester Acetate98. 120-11-6 Benzene, 2-methoxy-l- Benzyl Iso 0.00000676 (phenylmethoxy)-4-( 1 - Eugenolpropen- 1-yl)- 99. 102-22-7 Benzeneacetic acid, (2E)- Geranyl 0.000006453,7-dimethyl-2,6- Phenylacetateoctadien-l-yl ester100. 111879-80-2 Oxacyclohexadec - 12 -en- Habanolide 0.000004312-one, (12E)- 100%101. 87-22-9 Benzoic acid, 2-hydroxy- Phenyl Ethyl 0.00000299, 2-phenylethyl ester Salicylate102. 78-37-5 2-Propenoic acid, 3- Linalyl 0.00000174 phenyl-, 1 -ethenyl- 1,5- Cinnamatedimethyl-4-hexen-l -ylester103. 28645-51-4 Oxacycloheptadec- 10-en- Ambrettolide 0.000001392-one104. 123-69-3 Oxacycloheptadec- 8 -en- Ambrettolide 0.000001362-one, (8Z)~105. 3391-83-1 1,7- Musk RI 0.00000057 Dioxacycloheptadecan-8 - one106. 68527-79-7 7-Octen-2-ol, 8-(LH- Indolene 0.000000445 indol-l-yl)-2,6-dimethyl- 107. 89-43-0 Methyl 2-[(7-hydroxy- Aurantinol 0.00000001003,7- dimethyloctylidene)amino] benzoate108. 54982-83-1 1,4- Zenolide 0.00000000834Dioxacyclohexadecane- 5,16-dione109. 105-95-3 1,4- Ethylene 0.00000000313Dioxacycloheptadecane- Brassylate5, 17-dione110. 3681-73-0 Hexadecanoic acid, (2E)- Hexarose 0.000000003003,7-dimethyl-2,6- octadien-l-yl ester111. 4159-29-9 Phenol, 4-[3- Coniferyl 0.00000000170(benzoyloxy)-l -propen- benzoatel-yl]-2-methoxy- 112. 144761-91-1 Benzoic acid, 2-[(l- Trifone DIPG 0.00000000093 hydroxy-3- phenylbutyljami no ] -,methyl ester1Non-limiting examples of alternative qualities from various suppliers can be purchased under the following tradenames: Kharismal® Super (IFF), Kharismal® (IFF), Hedione® (Firmenich), Hedione® HC (Firmenich), Paradisone (Firmenich), Cepionate (Zenon), Super cepionate (Zenon), Claigeon® (Zenon).* Vapor Pressures are acquired as described in the Test Methods Section.** Origin: The low volatile fragrance materials may be obtained from one or more of the following companies: Firmenich (Geneva, Switzerland), Symrise AG (Holzminden, Germany), Givaudan (Argenteuil, France), IFF (Hazlet, New Jersey), Bedoukian (Danbury, Connecticut), Sigma Aldrich (St. Louis, Missouri), Millennium Specialty Chemicals (Olympia Fields, Illinois), Polarone International (Jersey City, New Jersey), and Aroma & Flavor Specialties (Danbury, Connecticut).[Table 1B] Low Volatile Natural Oils.No. Natural oil Supplier1. Beeswax Absolute Robertet2. Cedarwood Sawdust SFE Firmenich3. Cedarwood Oil Rect Firmenich4. Cedarwood Texas Light H. Reynaud & Fils 5. Ciste Absolute IFF6. Cocoa Colorless Oil Robertet7. Cypriol Coeur Essence Robertet8.. Guaiacwood Oil Global Essence Inc 9. Incense Wood Natural Robertet10. Orris CO2 Extract Mane11. Patchouli Oil IFF12. Tolu Baume Res Robertet13. Vanilla Absolute Robertet14. Vanilla CO2 Absolute Robertet15. Vetivert Oil IFF16. Vetyvert Acetate RobertetSuppliers:Firmenich, Geneva, SwitzerlandGlobal Essence Inc, New Jersey, USAH. Reynaud & Fils, Montbrun-les-Bains, FranceIFF, Hazlet, New Jersey, USAMane, Le Bar-sur-Loup, FranceRobertet, Grasse, France

[0022] Exemplary low volatile fragrance materials selected from the group of Tables 1A or IB Low Volatile Fragrance Materials are preferred. However, it is understood by one skilled in the art that other low volatile fragrance materials, not recited in Tables 1A or IB, would also fall within the scope of the present invention, so long as they have a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25 °C.(ii) Moderate Volatile Fragrance Materials

[0023] The fragrance component includes at least one moderate volatile fragrance material or aggregate of volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 °C. In some examples, the composition according to the present disclosure can include at least 3 moderate volatile fragrance materials, or at least 5 moderate volatile fragrance materials, or at least 7 moderate volatile fragrance materials. If there are more than one moderate volatile fragrance materials, then the ranges provided hereinabove cover the total of all of the moderate volatile fragrance materials. Suitable examples of moderate volatile fragrances materials are provided in Table 2A and 2B below.

[0024] Preferable examples of moderate volatile fragrance materials having a vapor pressure in the range of 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 °C are provided in Table 2 Moderate Volatile Fragrance Materials. Preferably, the moderate volatile fragrance material is selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, or at least 7 moderate volatile fragrance materials as disclosed in Table 2A. Natural fragrance materials or oils having an aggregate vapor pressure between 0.1 Torr to 0.001 Torr (0.0133 kPa to 0.000133 kPa) at 25 °C are provided in Table 2B. Moderate Volatile Natural Oils.[Table 2 A] Moderate Volatile Fragrance MaterialsNo. CAS Number IUPAC Name Common VaporName** Pressure (Torrat 25 °C)*24168-70-5 Pyrazine, 2- Methoxyisobutylp 0.09950000 methoxy-3-(1- yrazine methylpropyl)- 89-79-2 Cyclohexanol, 5- Iso-Pulegol 0.09930000 methyl-2-(l- methylethenyl)-,(1R,2S,5R)~ ’112-12-9 2-Undecanone Methyl Nonyl 0.09780000Ketone103-05-9 Benzenepropanol, Phenyl Ethyl 0.09770000 α,α-dimethyl- DimethylCarbinol125-12-2 Bicyclo[2.2.1]heptan Iso Bornyl 0.09590000-2-ol, 1,7,7- Acetate trimethyl-, 2 -acetate,(1R,2R,4R)-rel- 78-70-6 1.6-Octadien-3-ol, Linalool 0.090500003.7 -dimethyl- 101-97-3 Benzeneacetic acid, Ethyl Phenyl 0.08970000 ethyl ester Acetate100-86-7 Benzeneethanol, Dimethyl Benzyl 0.08880000 α,α-dimethyl- Carbinol188570-78-7 Cyclopropanecarbox Montaverdi 0.08640000 ylic acid, (3Z)-3- hexen-l-yl ester67634-25-7 3-Cyclohexene-1- Floralate 0.08500000 methanol, 3,5- dimethyl-, 1-acetate112-44-7 Undecanal Undecyl 0.08320000Aldehyde32669-00-4 Ethanone, l-(3- Tanaisone*’ 0.08150000 cycloocten-l-yl)- 98-53-3 Cyclohexanone, 4- Patchi 0.07780000(1,1 -dimethylethyl)- 35854-86-5 6-Nonen-l-ol, (6Z)- cis-6-None-1-ol 0.07770000 5331-14-6 Benzene, (2- Butyl phenethyl 0.07760000 butoxy ethyl)- ether80-57-9 Bicyclo[3.1.1]hept- Verbenone 0.077300003-en-2-one, 4,6,6- trimethyl- 22471-55-2 Cyclohexanecarboxy Thesaron 0.07670000 lie acid, 2,2,6- trimethyl-, ethylester, (l / ?,6S)-rel- 60-12-8 Benzeneethanol Phenethyl alcohol 0.07410000 106-26-3 2,6-Octadienal, 3,7- Neral 0.07120000dimethyl-, (2Z)-5392-40-5 2,6-Octadienal, 3,7- Citral 0.07120000 dimethyl- 89-48-5 Cyclohexanol, 5- Menthyl Acetate 0.07070000 methyl-2-(l- methylethyl)-, 1- acetate, (\R,2S,5R)- rel- 119-36-8 Benzoic acid, 2- Methyl salicylate 0.07000000 hydroxy-, methylester104-46-1 Benzene, 1- Anethol 0.06870000 methoxy-4-( IE)- 1 - propen-l-yl- 7549-37-3 2,6-Octadiene, 1,1- Citral Dimethyl 0.06780000 dimethoxy-3,7- Acetal dimethyl- 25225-08-5 Cyclohexanemethan Aphermate 0.06780000 ol, a,3,3-trimethyl-,1 -formate3913-81-3 2-Decenal, (2E)- 2-Decene-1-al 0.06740000 15373-31-6 3-Cyclopentene-1- Cantryl® 0.06700000 acetonitrile, 2,2,3- trimethyl- 6485-40-1 2-Cyclohexen- 1 -one, Laevo carvone 0.065600002-methyl-5-(l- methylethenyl)-,(5R)- 16587-71-6 Cyclohexanone, 4- Orivone 0.06490000(1,1- dimethylpropyl)- 62406-73-9 6,10- Opalal CI 0.06290000Di oxaspiro [4.5] decane, 8,8-dimethyl-7- (1 -methylethyl)- 3720-16-9 2-Cyclohexen- 1 -one, Livescone 0.062700003-methyl-5-propyl- 13816-33-6 Benzonitrile, 4-(l- Cumin Nitrile 0.06230000 methyl ethyl)- 67019-89-0 2,6-Nonadieneni trile Violet Nitrile 0.06200000 53398-85-9 Butanoic acid, 2- cis-3 -Hexenyl 0.06130000 methyl-, (3Z)-3- Alpha Methylhexen-l-yl ester Butyrate208041-98-9 n / a Jasmoni trile 0.05920000 16510-27-3 Benzene, 1- Toscanol 0.05870000(cyclopropylmethyl)-4-methoxy-111-80-8 2-Nonynoic acid, Methyl Octine 0.05680000 methyl ester Carbonate103-45-7 Acetic acid, 2- Phenyl Ethyl 0.05640000 phenyl ethyl ester Acetate2550-26-7 2-Butanone, 4- Benzyl Acetone 0.05570000 phenyl- 13491-79-7 Cyclohexanol, 2- Verdol 0.05430000(1,1 -dimethylethyl)- 7786-44-9 2,6-Nonadien-l-ol 2,6-Nonadien-l- 0.0537000001103-28-6 Propanoic acid, 2- Benzyl Iso 0.05130000 methyl-, Butyrate phenylmethyl ester104-62-1 Formic acid, 2- Phenyl Ethyl 0.05050000 phenylethyl ester Formate28462-85-3 Bicyclo[2.2.1]heptan Humus Ether 0.04870000-2-ol, 1, 2,3,3- tetramethyl-,(1R,2R,4S)-rel- 122-03-2 Benzaldehyde, 4-(l- Cuminic 0.04820000 methylethyl)- Aldehyde358331-95-0 2,5 -Octadi en-4-one, Pomarose 0.048100005,6,7-trimethyl-,(2E)- 562-74-3 3-Cyclohexen- 1 -ol, Terpinenol-4 0.047800004-methyl-l-(l- methylethyl)- 68527-77-5 3 -Cyclohexene- 1 - Isocyclogeraniol 0.04640000 methanol, 2,4,6- trimethyl- 35852-46-1 Pentanoic acid, (3Z)- Ci s-3 -Hexenyl 0.045800003-hexen-l-yl ester Valerate2756-56-1 Bicyclo[2.2. l]heptan Iso Bornyl 0.04540000-2-ol, 1,7,7- Propionatetrimethyl-, 2- propanoate,(1R,2R,4R)-rel- 14374-92-6 Benzene, 1-methyl- Verdoracine 0.044600004-(1-methylethyl)-2- (1 -propen- 1-yl)- 6784-13-0 3-Cyclohexene-1- Limonenal 0.04380000 propanal, p,4- dimethyl- 8000-41-7 2-(4-methyl-l- Alpha Terpineol 0.04320000 cyclohex-3- enyl)propan-2-ol41884-28-0 1-Hexanol, 5- Tetrahydro 0.04230000 methyl-2-(l- Lavandulolmethylethyl)-, (2R)-22457-23-4 3-Heptanone, 5- Stenione® 0.04140000 methyl-, oxime104-50-7 2(3H)-Furanone, 5- Gamma 0.04080000 butyldihydro- Octalactone143-08-8 1 -Nonanol Nonyl Alcohol 0.04070000 3613-30-7 Octanal, 7-methoxy- Methoxycitronell 0.040200003, 7 -di methyl- al67634-00-8 Acetic acid, 2-(3- Allyl Amyl 0.04000000 methylbutoxy)-, 2- Glycolatepropen-l-yl ester464-45-9 Bicyclo[2.2.1]heptan 1-Borneol 0.03980000-2-ol, 1,7,7- trimethyl-,(1S,2R,4S)- 124-76-5 Bicyclo[2.2.1]heptan 1,7,7-Trimethyl- 0.03980000-2-ol, 1,7,7- Bicyclo-1.2.2- trimethyl-, Heptanol-2(1A,2A,4A)-rel- 67874-72-0 Cyclohexanol, 2- Coniferan 0.03980000(1,1- dimethylpropyl)-, 1 - acetate80-26-2 3-Cyclohexene-1- Terpinyl Acetate 0.03920000 methanol, a,a,4- trimethyl-, 1-acetate498-81-7 Cyclohexanemethan Dihydro 0.03920000 ol, a,a,4-trimethyl- Terpineol112-45-8 10-Undecenal Undecylenic 0.03900000 aldehyde35044-57-6 2,4-Cy clohexadiene - Ethyl Safranate 0.038800001 -carboxylic acid,2,6,6-trimethyl-,ethyl ester106-21-8 1 -Octanol, 3,7- Dimethyl Octanol 0.03860000 di methyl- 84560-00-9 Cyclopentanol, 2- Cyclopentol 0.03790000 pentyl- 82461-14-1 Furan, tetrahydro- Rhubafuran® 0.037800002,4-dimethyl-4- phenyl- 56011-02-0 Benzene, [2-(3- Phenyl Ethyl 0.03690000 methylbutoxy)ethyl ] Isoamyl Ether103-37-7 Butanoic acid, Benzyl Butyrate 0.03660000 phenylmethyl ester6378-65-0 Hexyl hexanoate Hexyl hexanoate 0.03490000 118-61-6 Benzoic acid, 2- Ethyl salicylate 0.03480000hydroxy-, ethyl ester98-52-2 Cyclohexanol, 4- Patchon 0.03480000 (1,1 -dimethylethyl)- 115-99-1 1.6-Octadien-3-ol, Linalyl Formate 0.034400003.7-dimethyl-, 3- formate112-54-9 Dodecanal Lauric Aldehyde 0.03440000 53046-97-2 3,6-Nonadien-l-ol, 3,6 Nonadien-l-ol 0.03360000(3Z,6Z)- 76649-25-7 3,6-Nonadien-l-ol 3,6-Nonadien-l- 0.03360000 ol141-25-3 3,7 -Dimethyloct-6- Rhodinol 0.03290000 en-l-ol1975-78-6 Decanenitrile Decanonitrile 0.03250000 2216-51-5 Cyclohexanol, 5- L-Menthol 0.03230000 methyl-2-(l- methylethyl)-,(1R,2S,5R)- 3658-77-3 4-hydroxy-2,5- Pineapple Ketone 0.03200000 di methyl furan -3 -one103-93-5 Propanoic acid, 2- Para Cresyl iso- 0.03120000 methyl-, 4- Butyrate methylphenyl ester24717-86-0 Propanoic acid, 2- Abierate 0.03110000 methyl-, (1R,2S,4R)- 1,7,7- trimethylbi cyclo [2.2.l]hept-2-yl ester,rel- 67845-46-9 Acetaldehyde, 2-(4- Aldehyde XI 0.03090000 methylphenoxy)- 67883-79-8 2-Butenoic acid, 2- Cis-3-Hexenyl 0.03060000 methyl-, (3Z)-3- Tiglate hexen-l-yl ester,(2E)- 33885-51-7 Bicyclo[3.1.1]hept- Pino 0.030400002-ene-2-propanal, Acetaldehyde6,6-dimethyl- 105-85-1 6-Octen-l-ol, 3,7- Citronellyl 0.03000000 dimethyl-, 1 -formate Formate70214-77-6 2-Nonanol, 6,8- Nonadyl 0.03010000 dimethyl- 215231-33-7 Cyclohexanol, 1- Rossitol 0.02990000 methyl-3-(2- methylpropyl)- 120-72-9 IH-lndole Indole 0.02980000 2463-77-6 2-Undecenal 2-Undecene-l-al 0.02970000 675-09-2 2H-Pyran-2-one, Levistamel 0.029400004,6-dimethyl-98-55-5 3 -Cyclohexene- 1 - Alpha-Terpineol 0.02830000 methanol, a,a,4- trimethyl- 81786-73-4 3-Hepten-2-one, Koavone 0.027500003, 4, 5,6,6- pentamethyl-, (3Z)- 122-97-4 Benzenepropanol Phenyl Propyl 0.02710000Alcohol39212-23-2 2(3H)-Furanone, 5- Methyl 0.02700000 butyldihydro-4- Octalactonemethyl- 53767-93-4 7-Octen-2-ol, 2,6- Dihydro Terpinyl 0.02690000 dimethyl-, 2-acetate Acetate35044-59-8 1,3-Cyclohexadiene- Ethyl Safranate 0.026600001 -carboxylic acid,2,6,6-trimethyl-,ethyl ester104-55-2 2-Propenal, 3- Cinnamic 0.02650000 phenyl- Aldehyde144-39-8 1.6-Octadien-3-ol, Linalyl 0.026300003.7-dimethyl-, 3- Propionatepropanoate61931-80-4 1.6-Nonadien-3-ol, 3,7-Dimethyl-1,6- 0.026300003.7-dimethyl-, 3- nonadien-3-ylacetate acetate102-13-6 Benzeneacetic acid, Iso Butyl 0.026300002 -methylpropyl ester Phenylacetate65443-14-3 Cyclopentanone, Veloutone 0.026100002,2,5-trimethyl-5- pentyl- 141-12-8 2.6-Octadien-l-ol, Neryl Acetate 0.025600003.7-dimethyl-, 1- acetate, (2Z)- 105-87-3 2.6-Octadien-l-ol, Geranyl acetate 0.025600003.7-dimethyl-, 1- acetate, (2E)- 68141-17-3 Undecane, 1,1- Methyl Nonyl 0.02550000 dimethoxy-2- Acetaldehydemethyl- Dimethyl Acetal2206-94-2 Benzenemethanol, Indocolore 0.02550000 a-methylene-, 1- acetate10528-67-3 Cyclohexanepropan Cyclohexylmagno 0.02550000 ol, a-methyl- 1 '123-11-5 Benzaldehyde, 4- Anisic Aldehyde 0.02490000 methoxy- 57576-09-7 Cyclohexanol, 5- Iso Pulegol 0.02480000methyl-2-(l- Acetatenietliylethenyl)-, 1- acetate, (1R,2S,5R)- 51566-62-2 6-Octenenitrile, 3,7- Citronellyl Nitrile 0.02470000 dimethyl- 60335-71-9 2H-Pyran, 3,6- Rosyrane Super 0.02470000 dihydro-4-methyl-2- phenyl- 30385-25-2 6-Octen-2-ol, 2,6- Dihydromyrcenol 0.02440000 di methyl- 101-84-8 Benzene, 1,1’- Diphenyl Oxide 0.02230000 oxybis- 136-60-7 Benzoic acid, butyl Butyl Benzoate 0.02170000 ester93939-86-7 5,8 -Methano-2H- 1 - Rhuboflor 0.02120000 benzopyran, 6- ethyl ideneoctah ydro83926-73-2 Cyclohexanepropan Coranol 0.02100000 ol, a,a-dimethyl- 125109-85-5 Benzenepropanal, β- Florhydral 0.02070000 methyl-3-(1- methylethyl)- 104-21-2 Benzenemethanol, Anisyl Acetate 0.020500004-methoxy-, 1- acetate1365-19-1 2 -Furanmethanol, 5- Linalool Oxide 0.02050000 ethenyltetrahydro- a, a, 5 -trimethyl- 137-03-1 Cyclopentanone, 2- Frutalone 0.02040000 heptyl- 2563-07-7 Phenol, 2-ethoxy-4- Ultravanil 0.02030000 methyl- 1128-08-1 2-Cyclopenten-l- Dihydrojasmone 0.02020000 one, 3-methyl-2- pentyl- 7493-57-4 Benzene, [2-(l- Acetaldehyde 0.01990000 propoxyethoxy)ethyl141-25-3 7-Octen-l-ol, 3,7- Rhodinol 0.01970000 dimethyl- 216970-21-7 Bicyclo[4.3. l]decan 3-Methoxy-7,7- 0.01960000 e, 3-methoxy-7,7- dimethyl-10- dimethyl-10- methylenebicyclo methylene- [4.3.1]decane319002-92-1 Propanoic acid, 2- Sclareolate® 0.01960000(1,1- dimethylpropoxy)-,propyl ester, (2S)~85-91-6 Benzoic acid, 2- Dimethyl 0.01930000 (methylamino)-, anthranilatemethyl13828-37-0 Cyclohexanemethan Mayol 0.01920000 ol, 4-(l- methylethyl)-, cis- 26330-65-4 (E)-6-ethyl-3- Super Muguet 0.01850000 methyloct-6-en- 1 -ol7540-51-4 6-Octen-l-ol, 3,7- L -Citronellol 0.01830000 dimethyl-, (3S)- 106-22-9 6-Octen-l-ol, 3,7- Citronellol 0.01830000 dimethyl- 543-39-5 7-Octen-2-ol, 2- Myrcenol 0.01820000 methyl-6-methylene- 7775-00-0 Benzenepropanal, 4- Cyclemax 0.01820000(1 -methylethyl)- 18479-54-4 4.6-Octadien-3-ol, Muguol 0.018000003.7 -dimethyl- 29214-60-6 Octanoic acid, 2- Gelsone 0.01790000 acetyl-, ethyl ester1209-61-6 5- Tobacarol 0.01730000Oxatricyclo [ 8.2.0.04,6]dodecane,4,9,12,12- tetramethyl- 57934-97-1 2-Cyclohexene-l- Givescone 0.01710000 carboxylic acid, 2- ethyl-6,6-dimethyl-,ethyl ester14901-07-6 3-Buten-2-one, 4- Beta-Ionone 0.01690000(2,6,6-trimethyl- 1 - cycl ohexen- 1 -yl)-,(3E)- 64001-15-6 4,7-Methano-l IlDihydro Cycl acet 0.01630000 in den-5 -ol,octahydro-, 5-acetate95-41-0 2-Cyclopenten-l - Iso Jasmone T 0.01600000 one, 2-hexyl- 134-20-3 Benzoic acid, 2- Methyl 0.01580000 amino-, methyl ester Anthranilate105-86-2 2.6-Octadien-l-ol, Geranyl Formate 0.015400003.7 -dimethyl-, 1- formate, (2E)~154171-77-4 Spiro[ 1,3-dioxolane- Ysaniber K® 0.014700002,8’(5’H)-[2H- 2,4a]methanonaphthalene], hexahydro- r,r,5’,5’-tetramethyl-,(2\S\4’aS,8’aS)- (9CI)154171-76-3 Spiro[1,3-dioxolane- Ysaniber 0.014700002,8’(5’H)-[2H- 2,4a]methanonaphthalene],127-41-3 3-Buten-2-one, 4- Alpha-Ionone 0.01440000(2,6,6-trimethyl-2- cyclohexen- 1 -yl)-,(3E)- 151-05-3 Benzeneethanol, Dimethyl Benzyl 0.01390000 a.a-dimethyl-, 1- Carbinyl Acetateacetate2500-83-6 4,7-Methano-lH- Flor Acetate 0.01370000 inden-5-ol,3a, 4, 5, 6, 7,7a- hexahydro-, 5- acetate150-84-5 6-Octen-l-ol, 3,7- Citronellyl 0.01370000 dimethyl-, 1-acetate acetate30310-41-9 2H-Pyran, Pelargene 0.01350000 tetrahydro-2 -methyl- 4-methylene-6- phenyl- 68845-00-1 Bicyclo[3.3. l]nonan Boisiris 0.01350000 e, 2-ethoxy-2,6,6- trimethyl-9- methylene- 106-24-1 2,6-Octadien-1-ol, Geraniol 0.013300003.7 -dimethyl-, (2E)~106-25-2 2.6-Octadien-l-ol, Nerol 0.013300003.7-dimethyl-, (2Z)- 75975-83-6 Bicyclo[7.2.0]undec Vetyvenal 0.01280000-4-ene, 4,11,11- trimethyl-8- methylene-,(1R,4E,9S)- 19870-74-7 lH-3a,7- Cedryl methyl 0.01280000Methanoazulene, etheroctahydro-6- methoxy-3, 6,8,8- tetramethyl-,(3R,3aS,6S,7R,8aS)- 87-44-5 Bicyclo[7.2.0]undec Caryophyllene 0.01280000-4-ene, 4,11,11- Extratrimethyl-8- methylene-,(1R,4E,9S)-54440-17-4 1H-Inden-1-one, Safraleine 0.01260000 2,3-dihydro-2,3,3- trimethyl- 110-98-5 2 -Propanol, 1,1’- Dipropylene 0.01250000 oxybis- Glycol41890-92-0 2-Octanol, 7- Osyrol® 0.01250000 methoxy-3,7- dimethyl- 71077-31-1 4,9-Decadienal, 4,8- Floral Super 0.01230000 dimethyl- 65-85-0 Benzoic Acid Benzoic Acid 0.01220000 61444-38-0 3-Hexenoic acid, cis-3-hexenyl-cis- 0.01220000(3Z)-3-hexen-l-yl 3 -hexenoateester, (3Z)- 116044-44-1 Bicyclo[2.2. l]hept- Herbanate 0.012100005 -ene-2-carboxylicacid, 3-(l- 104-54-1 2-Propen-l-ol, 3- Cinnamic 0.01170000 phenyl- Alcohol78-35-3 Propanoic acid, 2- Linalyl 0.01170000 methyl-, 1-ethenyl- Isobutyrate1,5 -dimethyl -4- hexen- 1 -yl ester23495-12-7 Ethanol, 2-phenoxy-, Phenoxy Ethyl 0.011300001-propanoate Propionate103-26-4 2-Propenoic acid, 3- Methyl 0.01120000 phenyl-, methyl ester Cinnamate67634-14-4 Benzenepropanal, 2- Florazon (ortho - 0.01110000 ethyl -a,a-di methyl - isomer)5454-19-3 Propanoic acid, N-Decyl 0.01100000decyl ester Propionate93-16-3 Benzene, 1,2- Methyl Iso 0.01100000 dimethoxy-4-(l- Eugenol propen-l-yl)- 81782-77-6 3-Decen-5-ol, 4- 4-Methyl-3- 0.01070000 methyl- decen-5-ol67845-30-1 Bicyclo[2.2.2]oct-5- Maceal 0.01060000 ene-2- carboxaldehyde, 6- methyl-8-(l- methylethyl)- 97-53-0 Phenol, 2-methoxy- Eugenol 0.010400004-(2-propen- 1 -yl)- 120-57-0 1,3 -Benzodi ox ole-5 - Heliotropin 0.01040000 carboxaldehyde93-04-9 Naphthalene, 2- Beta Naphthyl 0.01040000 methoxy- Methyl EtherExtra 994826-62-4 2-Dodecenal 2 Dodecene- 1 -al 0.0102000020407-84-5 2-Dodecenal, (2E)- Aldehyde 0.01020000Mandarin5462-06-6 Benzenepropanal, 4- Canthoxal 0.01020000 methox y-a-meth yl- 94-60-0 1,4- Dimethyl 1,4- 0.01020000Cyclohexanedicarbo cyclohexanedicarxylic acid, 1,4- boxylate dimethyl ester57378-68-4 2-Buten-l-one, 1- delta-Damascone 0.01020000(2,6,6-trimethyl-3- cyclohexen- 1 -yl)- 17283-81-7 2-Butanone, 4- Dihydro Beta 0.01020000(2,6,6-trimethyl- 1 - Ionone cyclohexen-l-yl)- 1885-38-7 2 -Propenenitrile, 3- Cinnamalva 0.01010000 phenyl-, (2E)- 103-48-0 Propanoic acid, 2- Phenyl Ethyl Iso 0.00994000 methyl-, 2- Butyrate phenylethyl ester488-10-8 2-Cyclopenten-l - Cis Jasmone 0.00982000 one, 3-methyl-2- (2Z)-2-penten-l -yl- 7492-67-3 Acetaldehyde, 2- Citronellyloxyace 0.00967000[(3,7-dimethyl-6- taldehydeocten-l-yl)oxy]- 68683-20-5 1 -Cyclohexene- 1- Iso Bergamate 0.00965000 ethanol, 4-(l- methylethyl)-, 1- formate3025-30-7 2,4-Decadienoic Ethyl 2,4- 0.00954000 acid, ethyl ester, Decadienoate(2E,4Z)- 103-54-8 2-Propen-l-ol, 3- Cinnamyl Acetate 0.00940000 phenyl-, 1 -acetate18127-01-0 Benzenepropanal, 4- Bourgeonal 0.00934000(1,1 -dimethylethyl)- 3738-00-9 Naphtho [2,1- Ambrox® or 0.00934000 b]furan, Cetalox® ordodecahydro- Synambran3a, 6, 6,9a- tetramethyl- 51519-65-4 1,4- Tamisone 0.00932000Methanonaphthalen- 5(l / / )-one,4, 4a, 6, 7, 8,8a- hexahydro- 148-05-1 Dodecanoic acid, Dodecalactone 0.0093100012-hydroxy-, X-lactone (60,70);1,12- 6790-58-5 (3a / ?,5aS,9aS’,9bl?)- Ambronat® or 0.009300003a,6,6,9a- Ambroxan®tetramethyl- 2, 4, 5,5a, 7, 8, 9,9b- octahydro-lH- benzofej [ 1 Jbenzofuran86-26-0 1,1’ -Biphenyl, 2- Methyl Diphenyl 0.00928000 methoxy- Ether68738-94-3 2- Cyclomyral® 0.00920000NaphthalenecarboxaIdehyde, octahydro- 8,8 -dimethyl2705-87-5 Cyclohexanepropan Allyl 0.00925000 oic acid, 2-propen-l- Cyclohexanevl ester Propionate7011-83-8 2(3H)-Furanone, 5- Lactojasmone® 0.00885000 hexyldihydro-5- methyl- 61792-11-8 2.6- Lenionile® 0.00884000Nonadienenitrile,3.7-dimethyl- 692-86-4 10-Undecenoic acid, Ethyl 0.00882000 ethyl ester Undecylenate103-95-7 Benzenepropanal, a- Cymal 0.00881000 methyl-4-(l- methylethyl)- 13019-22-2 9-Decen-l-ol Rosalva 0.00879000 94201-19-1 1- Methyl Laitone 0.00872000Oxaspiro [4.5] decan- 10% TEC2 -one, 8-methyl- 104-61-0 2(3H)-Furanone, y-Nonalactone 0.00858000 dihydro-5 -pentyl- 706-14-9 2(3 / / )-Furanone, 5- y -Decalactone 0.00852000 hexyldihydro- 24720-09-0 2-Buten-l-one, 1- a-Damascone 0.00830000(2,6,6-trimethyl-2- cycl ohexen- 1 -yl)-,(2E)- 39872-57-6 2-Buten-l-one, 1- Isodamascone 0.00830000(2,4,4-trimethyl-2- cyclohexen- 1 -yl)-,(2E)- 705-86-2 2H-Pyran-2-one, Decalactone 0.00825000 tetrahydro-6 -pentyl- 67634-15-5 Benzenepropanal, 4- Floralozone 0.00808000ethyl -a,a-dimethyl-40527-42-2 1,3 -Benzodioxole, 5- Heliotropin 0.00796000 (diethoxymethyl)- Diethyl Acetal56973-85-4 4-Penten-l-one, 1- Neobutenone a 0.00763000(5,5-dimethyl-l- cyclohexen-l-yl)- 128-51-8 Bicyclo[3.1.1]hept- Nopyl Acetate 0.007510002-ene-2-ethanol, 6,6- dimethyl-, 2-acetate103-36-6 2-Propenoic acid, 3- Ethyl Cinnamate 0.00729000 phenyl-, ethyl ester5182-36-5 1,3-Dioxane, 2,4,6- Floropal® 0.00709000 trimethyl-4-phenyl- 42604-12-6 Cyclododecane, Boisambrene 0.00686000(methoxymethoxy)- 33885-52-8 Bicyclo[3.1.1]hept- Pinyl Iso Butyrate 0.006850002-ene-2-propanal, Alphaa,a,6,6-tetramethyl- 92015-65-1 2(3H)- Natactone 0.00680000Benzofuranone,hexahydro-3, 6- dimethyl- 63767-86-2 Cyclohexanemethan Mugetanol 0.00678000 ol, a-methyl-4-(l- nietliylethyl)- 3288-99-1 Benzeneacetonitrile, Marenil CI 0.006650004-(l,l- dimethylethyl)- 35044-68-9 2-Buten-l-one, 1- beta-Damascone 0.00655000(2,6,6-trimethyl- 1- cyclohexen-l-yl)- 41724-19-0 1,4- Plicatone 0.00652000Methanonaphthalen - 6(2H)-one,octahy dro-7-niethyl75147-23-8 Bicyclo[ 3.2. Ijoctan- Buccoxime® 0.006470008-o ne, 1,5-diraethyl-, oxime25634-93-9 2-Methyl-5- Ro saphen® 0.00637000 phenylpen tan-1 -ol 60006455066-48-3 3-Methyl-5- Phenyl Hexanol 0.00637000 phenylpentanol495-62-5 Cyclohexene, 4-(l,5- Bisabolene 0.00630000 dimethyl-4-hexen- 1 - y lidene) - 1 -me thyl - 2785-87-7 Phenol, 2-methoxy- Dihydro Eugenol 0.006240004-propyl- 87-19-4 Benzoic acid, 2- Iso Butyl 0.00613000 hydroxy-, 2- Salicylatemethylpropyl ester4430-31-3 2H- 1 -Benzopyran -2- Octahydro 0.00586000 one, octahydro- Coumarin38462-22-5 Cyclohexanone, 2- Ringonol 50 TEC 0.00585000(1 -mercapto- 1 - methylethyl)-5- methyl- 77-83-8 2-Oxiranecarboxylic Ethyl Methyl 0.00571000 acid, 3 -methyl -3- Phenyl Glycidatephenyl-, ethyl ester37677-14-8 3 -Cyclohexene- 1 - Iso Hexenyl 0.00565000 carboxaldehyde, 4- Cyclohexenyl(4-methyl -3-pen ten- Carboxaldehyde1-yl)- 103-60-6 Propanoic acid, 2- Phenoxy Ethyl 0.00562000 methyl-, 2- iso-Butyrate phenoxyethyl ester18096-62-3 Indeno[1,2-d]-1,3- Indoflor® 0.00557000 dioxin, 4, 4a, 5,9b- tetrahydro- 63500-71-0 2H-Pyran-4-ol, Florosa Q / Florol 0.00557000 tetrahydro-4-methyl - 2-(2-methylpropyl)- 65405-84-7 Cyclohexanebutanal, Cetonal® 0.00533000 α,2,6,6-tetramethyl- 171102-41-3 4,7-Methano-lH- Flor Acetate 0.00530000 inden-6-ol,3a, 4, 5, 6, 7,7a- hexahydro-8,8- dimethyl-, 6-acetate10339-55-6 1.6-Nonadien-3-ol, Ethyl linalool 0.005200003.7 -dimethyl- 23267-57-4 3-Buten-2-one, 4- Ionone Epoxide 0.00520000(2,2,6-trimethyl-7- Betaoxabicyclo[4.1.0]hept-l-yl)- 97-54-1 Phenol, 2-methoxy- Isoeugenol 0.005190004-( 1 -propen- 1-yl)- 67663-01-8 2(3 / f)-Furanone, 5- Peacholide 0.00512000 hexyldihydro-4- methyl- 33885-52-8 Bicyclo[3.1.1]hept- Pinyl Iso Butyrate 0.005120002-ene-2-propanal, Alphaa,a,6,6-tetramethyl- 23696-85-7 2-Buten-l-one, 1- Damascenone 0.00503000(2,6,6-trimethyl- 1,3- cyclohexadien- 1 -yl ) - 80-71-7 2-Cyclopenten-l - Maple Lactone 0.00484000 one, 2-hydroxy-3-methyl-67662-96-8 Propanoic acid, 2,2- Pivarose Q 0.00484000 dimethyl-, 2- phenyl ethyl ester2437-25-4 Dodecanenitrile Clonal 0.00480000 141-14-0 6-Octen-l-ol, 3,7- Citronellyl 0.00469000 dimethyl-, 1- Propionatepropanoate54992-90-4 3-Buten-2-one, 4- Myrrhone 0.00460000(2, 2,3,6- tetramethylcyclohexyi)- 55066-49-4 Benzenepentanal, p- Mefranal 0.00455000 methyl- 7493-74-5 Acetic acid, 2- Allyl Phenoxy 0.00454000 phenoxy-, 2-propen- Acetate1-yl ester80-54-6 Benzenepropanal, 4- Lilial® 0.00444000(1,1-dimethylethyl)- α-methyl- 86803-90-9 4,7-Methano-lH- Scentenal® 0.00439000 indene-2- carboxaldehyde,octahydro-5- methoxy- 68991-97-9 2- Melafleur 0.00436000NaphthalenecarboxaIdehyde,1, 2, 3, 4, 5, 6,7,8- octahydro-8,8- dimethyl- 18871-14-2 Pentitol, 1,5- Jasnial 0.00434000 anhydro-2,4- dideoxy-2-pentyl-,3 -acetate58567-11-6 Cyclododecane, Boisambren Forte 0.00433000(ethoxymethoxy)- 94400-98-3 Naphth[2,3- Molaxone 0.00425000 bjoxirene,la,2,3,4,5,6,7,7a- octahydro- la, 3, 3, 4,6,6- hexamethyl-,(la / ?,4S,7aS)-rel- 79-69-6 3-Buten-2-one, 4- alpha-irone 0.00419000(2,5,6,6-tetramethyl- 2-cyclohexen- 1 -yi)- 65442-31-1 Quinoline, 6-(l- Iso Butyl 0.00408000methylpropyl)- Quinoline87731-18-8 Carbonic acid, 4- Violiff 0.00401000 cycloocten-1 -ylmethyl ester173445-65-3 lH-Indene-5- Hi vernal (A- 0.00392000 propanal, 2,3- isomer) dihydro-3,3- dimethyl- 23911-56-0 Ethanone, l-(3- Nerolione 0.00383000 methyl-2- benzofuranyl)- 52474-60-9 3-Cyclohexene-l- Precyclemone B 0.00381000 carboxaldehyde, 1- methyl-3 -(4-methyl- 3-penten-l -vl)- 139539-66-5 6-Oxabicyclo Cassifix 0.00381000[3.2.1]octane, 5- methyl- 1 -(2,2,3- trimethyl-3- cyclopenten-1-yl)- 80858-47-5 Benzene, [2- Phenafleur 0.00380000(cyclohexyloxy)ethyu- 32764-98-0 2H-Pyran-2-one, Jasmolactone 0.00355000 tetrahydro-6-(3- penten-1 -yl)- 78417-28-4 2,4,7 -Decatrienoic Ethyl 2,4,7- 0.00353000 acid, ethyl ester decatrienoate140-26-1 Butanoic acid, 3- Beta Phenyl Ethyl 0.00347000 methyl-, 2- Isovaleratephenylethyl ester105-90-8 2.6-Octadien-l-ol, Geranyl 0.003360003.7-dimethyl-, 1- Propionatepropanoate, (2E)- 41816-03-9 Spiro [ 1,4- Rhubofix® 0.00332000 methanonaphthalene-2(1 / 7), 2’-oxirane],3, 4, 4a, 5,8,8a- hexahydro-3’,7- dimethyl- 7070-15-7 Ethanol, 2- Arbanol 0.00326000[[(1R,2R,4R)- 1,7,7- trimethylbicyclo [2.2.l]hept-2-yl]oxy]-,rel- 93-29-8 Phenol, 2-methoxy- Iso Eugenol 0.003240004-(l -propen- 1-yl)-, Acetate1 -acetate476332-65-7 2H-Indeno[4,5- Amber Xtreme 0.00323000 b]furan, decahydro- Compound 12,2, 6, 6, 7,8,8- heptamethyl- 68901-15-5 Acetic acid, 2- Cydogalbanate 0.00323000(cyclohexyloxy)-, 2- propen-l-yl ester107-75-5 Octanal, 7-hydroxy- Hydroxycitronella 0.003180003, 7 -dimethyl- 168611-23-4 Naphtho [2,1- Grisalva 0.00305000 b]furan, 9b- ethyldodecahydro- 3a,7,7-trimethyl- 313973-37-4 l,6-Heptadien-3- Pharaone 0.00298000 one, 2-cyclohexyl- 137-00-8 5 -Thiazoleethanol, Sulfurol 0.002970004-methyl- 7779-30-8 l-Penten-3-one, 1- Methyl Ionone 0.00286000(2,6,6-trimethyl-2- cyclohexen-l-yl)- 127-51-5 3-Buten-2-one, 3- Isoraldeine Pure 0.00282000 methyl-4-(2,6,6- trimethyl-2- cyclohexen-l-yl)- 72903-27-6 1,4- Fructalate™ 0.00274000Cyclohexanedicarboxylic acid, 1,4- diethyl ester7388-22-9 3-Buten-2-one, 4- Ionone Gamma 0.00272000(2,2-dimethyl-6- Methyl methylenecyclohexyl)-3-methyl- 104-67-6 2(3H)-Furanone, 5- gamma- 0.00271000 heptyldihydro- Undecalactone(racemic)1205-17-0 1,3 -Benzodioxole-5 - Helional 0.00270000 propanal, a-methyl- 33704-61-9 4 / 7-Inden-4-one, Cashmeran 0.002690001, 2, 3, 5,6,7- hexahy dro - 1, 1,2,3,3 - pentamethyl- 36306-87-3 Cyclohexanone, 4- Kephalis 0.00269000(1-ethoxyethenyl)- 3,3,5,5 -tetramethyl- 97384-48-0 Benzenepropanenitri Citrowanil® B 0.00265000 le, a-ethenyl-a- methyl- 141-13-9 9-Undecenal, 2,6,10- Adoxal 0.00257000 tri methyl- 2110-18-1 Pyridine, 2-(3- Corps Racine VS 0.00257000phenylpropyl)-27606-09-3 Ind eno [1,2-d]-l,3- Magnolan 0.00251000 dioxin, 4, 4a, 5,9b- tetrahydro-2,4- dimethyl- 67634-20-2 Propanoic acid, 2- Cyclabute 0.00244000 methyl-,3a, 4, 5, 6, 7,7a- hexahydro-4,7- methano-1 W-inden- 5-yl ester65405-72-3 1-Naphthalenol, Oxyoctaline 0.002360001, 2, 3, 4, 4a, 7, 8,8a- Formate octahydro-2,4a, 5,8a- tetramethyl-, 1- formate122-40-7 Heptanal, 2- Amyl Cinnamic 0.00233000(phenylmethylene)- Aldehyde103694-68-4 Benzenepropanol, Majantol® 0.00224000β,β,3-trimethyl- 13215-88-8 2-Cyclohexen- 1 -one, Tabanone Coeur 0.002230004-(2-buten-l- ylidene)-3,5,5- trimethyl- 25152-85-6 3-Hexen-l-ol, 1- Cis-3-Hexenyl 0.00203000 benzoate, (3Z)- Benzoate406488-30-0 2-Ethyl-N-methyl-N- Paradisamide 0.00200000(m-tolyl)butanami de121-33-5 Benzaldehyde, 4- Vanillin 0.00194000 hydroxy-3-methoxy- 77-54-3 lH-3a,7- Cedac 0.00192000Methanoazulen-6-ol,octahydro-3, 6,8,8- tetramethyl-, 6- acetate,(37?,3aS,67?,7J?,8aS)- 76842-49-4 4,7-Methano-lH- Frutene 0.00184000 inden-6-ol,3a, 4, 5, 6, 7,7a- hexahydro-8,8- dimethyl-, 6- propanoate121-39-1 2-Oxiranecarboxylic Ethyl Phenyl 0.00184000 acid, 3 -phenyl-, Glycidateethyl ester211299-54-6 4H-4a,9- Ambrocenide® 0.00182000Methanoazuleno [5,6-d]-l,3-dioxole,octahydro-2,2,5,8, 8, 9a-hexamethyl-,(4aR,5R,7aS,9R)- 285977-85-7 (2,5 -Dimethyl- 1,3 - Lilyflore 0.00180000 dihydroinden-2- yl)methanol10094-34-5 Butanoic acid, 1,1- Dimethyl Benzyl 0.00168000 dimethyl-2- Carbinyl Butyrate phenylethyl ester40785-62-4 Cyclododeca[c] Muscogene 0.00163000 furan, 1,3, 3a, 4, 5, 6, 7,8,9,10,11,13a- dodecahydro- 75490-39-0 Benzenebutanenitril Khusinil 0.00162000 e, a,a,y-trimethyl- 55418-52-5 2-Butanone, 4-(l,3- Dulcinyl 0.00161000 benzodioxol-5-yl)- 3943-74-6 Benzoic acid, 4- Carnaline 0.00157000 hydroxy-3-methoxy-, methyl ester72089-08-8 3-Cyclopentene-l- Brahmanol® 0.00154000 butanol, β,2,2,3- tetramethyl- 2- Methyl-4-(2,2,3- trimethyl-3- cyclopenten-1- yl)butanol3155-71-3 2-Butenal, 2-methyl- Boronal 0.001470004-(2,6,6-trimethyl-l - cyclohexen-l-yl)- 2050-08-0 Benzoic acid, 2- Amyl Salicylate 0.00144000 hydroxy-, pentylester41199-20-6 2-Naphthalenol, Ambrinol 0.00140000 decahydro-2,5,5- trimethyl- 12262-03-2 Undecanoic acid, 3- Iso Amyl 0.00140000 methylbutyl ester Undecylenate107-74-4 1,7-Octanediol, 3,7- Hydroxyol 0.00139000 dimethyl- 91-64-5 2H-1 -Benzopyran-2- Coumarin 0.00130000 one68901-32-6 1,3-Dioxolane, 2-[6- Glycolierral 0.00121000 methyl-8-(l- methylethyl)bicyclo [2.2.2]oct-5-en-2-ylJ- 68039-44-1 Propanoic acid, 2,2- Pivacyclene 0.00119000 dimethyl-, 3a, 4, 5, 6,7,7 a-hexahydro-4, 7 -methane- 1 H-inden- 6-yl ester106-29-6 Butanoic acid, (2E)~ Geranyl Butyrate 0.00116000 317. 3,7-dimethyl-2,6- octadien-l-yl ester318. 5471-51-2 2-Butanone, 4-(4- Raspberry ketone 0.00106000hydroxyphenyl)- 319. 109-42-2 10- Undecenoic acid, Butyl 0.00104000butyl ester Undecylenate320. 2785-89-9 4-Ethyl-2- 4-Ethylguaiacol 0.02000000methoxyphenol321. 27538-10-9 2-ethyl-4-hydroxy- Homofuronol 0.012100005 -methylfuran-3 -one* Vapor Pressures are acquired as described in the Test Methods Section.** Origin: Same as for Table 1 hereinabove.[Table 2BJ Moderate Volatile Natural Oils.No. Natural oil Supplier 1. Bay Oil Terpeneless IFF2. Cade Oil II. Reynaud & Fils 3. Cedar Atlas Oil Robertet 4. Cinnamon Bark Oil Robertet 5. Cinnamon Oleoresin Citrus & Allied Essences 6. Clove Bud Oil Robertet 7. Clove Leaf Oil Rectified H. Reynaud & Fils 8. Clove Stem Oil H. Reynaud & Fils 9. Davana Oil Robertet 10. Geranium Bourbon Robertet 11. Ginger Oil Fresh Madagascar IFF12. Hay Absolute MD 50 PCT IFF13. Juniperberry Oil T'less Robertet 14. Papyrus Oil Robertet 15. Rose Absolute Oil Robertet 16. Tonka Bean Absolute Robertet17. Wormwood Oil Robertet Suppliers:Citrus & Allied Essences, New York, USAH. Reynaud & Fils, Montbrun-les-Bains, France IFF, Hazlet, New Jersey, USARobertet, Grasse, France

[0025] Moderate volatile fragrance materials can be selected from the group of Tables 2A or 2B. However, it is understood by one skilled in the art that other moderate volatile fragrance materials, not recited in Tables 2A or 2B, would also fall within the scope of the present invention, so long as they have a vapor pressure of 0.1 to 0.001 Torr at 25 °C.(iii) High Volatile Fragrance Materials

[0026] The fragrance component can include at least one high volatile fragrance material having a vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25 °C. In some examples, the high volatile fragrance material can include at least 2 high volatile fragrance materials, 3 high volatile fragrance materials, or at least 5 high volatile fragrance materials, or at least 7 high volatile fragrance materials. Suitable examples of high volatile fragrances materials are provided in Tables 3 A and 3B below.

[0027] The high volatile fragrance material may be selected from at least 1 material, or at least 2 materials, or at least 3 materials, or at least 5 materials, at least 7 materials, or at least 9 high volatile fragrance materials as disclosed in Table 3A. Natural fragrance materials or oils having an aggregate vapor pressure greater than 0.1 Torr (0.0133 kPa) at 25 °C are provided in Table 3B. Moderate Volatile Natural Oils.[Table 3 A] High Volatile Fragrance MaterialsNo. CAS IUPAC Name Common Name** VaporNumber Pressure (Torrat 25 °C)*1. 107-31-3 Formic acid, Methyl Formate 732.00000000methyl ester2. 75-18-3 Methane, 1,1’- Dimethyl Sulfide 647.00000000thiobis- 1.0% In DEP3. 141-78-6 Acetic acid ethyl Ethyl Acetate 112.00000000ester105-37-3 Propanoic acid, Ethyl Propionate 44.500000004. ethyl ester110-19-0 Acetic acid, 2- Isobutyl Acetate 18.000000005. methylpropylester6. 105-54-4 Butanoic acid, Ethyl Butyrate 13.90000000ethyl ester7. 14765-30-1 1 -Butanol Butyl Alcohol 8.520000007452-79-1 Butanoic acid, 2- Ethyl-2-Methyl 7.850000008. methyl-, ethyl Butyrateester123-92-2 1 -Butanol, 3- Iso Amyl Acetate 5.68000000 methyl-, 1- acetate66576-71-4 Butanoic acid, 2- Iso Propyl 2- 5.10000000 methyl-, 1- Metliylbutyrate methylethyl ester110-43-0 2-Heptanone Methyl Amyl 4.73000000Ketone6728-26-3 2-Hexenal, (2E)- Trans-2 Hexenal 4.62000000 123-51-3 1 -Butanol, 3- Isoamyl Alcohol 4.16000000 methyl- 1191-16-8 2-Buten-l-ol, 3- Prenyl acetate 3.99000000 methyl-, 1- acetate57366-77-5 l,3-Dioxolane-2- Methyl Dioxolan 3.88000000 methanamine, N- methyl- 7785-70-8 Bicyclo [3. l.l]he Alpha Pinene 3.49000000 pt-2-ene, 2,6,6- trimethyl-,(1R, 51?)- 79-92-5 Bicyclo[2.2.1]he Camphene 3.38000000 ptane, 2,2- dimethyl-3- methylene- 94087-83-9 2-Butanethiol, 4- 4-Methoxy-2- 3.31000000 methoxy-2- Methyl-2- methyl- Butanenthiol39255-32-8 Pentanoic acid, Manzanate 2.910000002-methyl-, ethylester3387-41-5 Bicyclo [3. l. OJhe Sabinene 2.63000000 xane, 4- methylene-l-(l- methylethyl)- 127-91-3 Bicyclo[3.1.1]he Beta Pinene 2.40000000 ptane, 6,6- dimethyl-2- methylene- 105-68-0 1 -Butanol, 3- Amyl Propionate 2.36000000 methyl-, 1- propanoate123-35-3 1,6-Octadiene, 7- Myrcene 2.29000000 methyl-3- methylene- 124-13-0 Octanal Octyl Aldehyde 2.07000000 7392-19-0 2H-Pyran, 2- Limetol 1.90000000 ethenyltetrahydro-2, 6,6- tri methyl- 111-13-7 2-Octanone Methyl Hexyl 1.72000000Ketone123-66-0 Hexanoic acid, Ethyl Caproate 1.66000000 ethyl ester470-82-6 9- Eucalyptol 1.65000000Oxabicyclo [2.2.2Joctane, 1,3,3- trimethyl- 99-87-6 Benzene, 1- Para Cymene 1.65000000 methyl-4-(l- methylethyl)- 104-93-8 Benzene, 1- Para Cresyl Methyl 1.65000000 methoxy-4- Ethermethyl- 13877-91-3 1,3,6-Octatriene, Ocimene 1.560000003,7-dimethyl- 138-86-3 Cyclohexene, 1- dl-Limonene 1.54000000 methyl-4-(l- methylethenyl)- 5989-27-5 Cyclohexene, 1- d -limonene 1.54000000 methyl-4-(l- methylethenyl)-,(4R)-106-68-3 3-Octanone Ethyl Amyl Ketone 1.50000000 110-41-8 Undecanal, 2- Methyl Nonyl 1.43000000 methyl- Acetaldehyde142-92-7 Acetic acid, Hexyl acetate 1.39000000 hexyl ester110-93-0 5-Hepten-2-one, Methyl Heptenone 1.280000006-methyl- 81925-81-7 2-Hepten-4-one, Filbertone 1% in 1.250000005-methyl- TEC3681-71-8 3-Hexen-l-ol, 1- cis-3-Hexenyl 1.22000000 acetate, (3Z)- acetate97-64-3 Propanoic acid, Ethyl lactate 1.160000002-hydroxy-,ethyl ester586-62-9 Cyclohexene, 1- Terpineolene 1.13000000 methyl-4-(l- methylethylidene)- 51115-64-1 Butanoic acid, 2- Amyl butyrate 1.09000000 methylbutyl ester106-27-4 Butanoic acid, 3- Amyl Butyrate 1.09000000 methylbutyl ester99-85-4 1,4- Gamma Terpinene 1.08000000Cyclohexadiene,1-methyl-4-(1- methylethyl)- 18640-74-9 Thiazole, 2-(2- 2-Isobutylthiazole 1.07000000 methylpropyl)- 928-96-1 3-Hexen-l-ol, cis-3-Hexenol 1.04000000(3Z)- 100-52-7 Benzaldehyde Benzaldehyde 0.97400000 141-97-9 Butanoic acid, 3- Ethyl Acetoacetate 0.89000000 oxo-, ethyl ester928-95-0 2-Hexen-l-ol, Trans-2-Hexenol 0.87300000(2£)- 928-94-9 2-Hexen-l-ol, Beta Gamma 0.87300000(2Z)- Hexenol24691-15-4 Cyclohexane, 3- Herbavert 0.85200000 ethoxy-1,1,5- trimethyl-, cis- (9C1)19872-52-7 2-Pentanone, 4- 4-Methyl-4- 0.84300000 mercapto-4- Mercaptopentan-2- methyl- one 1 ppm TEC3016-19-1 2.4.6-Octatriene, Allo-Ocimene 0.816000002.6-dimethyl-,(4E,6E)- 69103-20-4 Oxirane, 2,2- Myroxide 0.80600000 dimethyl-3-(3- methyl-2,4- pentadien-1 -yl)- 189440-77- 4,7-Octadienoic Anapear 0.77700000 5 acid, methylester, (4E)- 67633-96-9 Carbonic acid, Liffarome™ 0.72100000(3Z)-3-hexen-l- yl methyl ester123-68-2 Hexanoic acid, Allyl Caproate 0.678000002-propen-l-ylester106-72-9 5-Heptenal, 2,6- Melonal 0.62200000 dimethyl- 106-30-9 Heptanoic acid, Ethyl Oenanthate 0.60200000 ethyl ester68039-49-6 3-Cyclohexene- Ligustral or Triplal 0.578000001- carboxaldehyde,2,4-dimethyl- 101-48-4 Benzene, (2,2- Phenyl 0.55600000 dimethoxyethyl)- AcetaldehydeDimethyl Acetal16409-43-1 2H-Pyran, Rose Oxide 0.55100000 tetrahydro-4- methyl-2-(2- methyl-1- propen-l-yl)- 925-78-0 3-Nonanone Ethyl Hexyl Ketone 0.55100000 100-47-0 Benzonitrile Benzyl Nitrile 0.52400000 589-98-0 3-Octanol Octanol-3 0.51200000 58430-94-7 1 -Hexanol, Iso Nonyl Acetate 0.470000003,5,5-lrimethyl-,1 - acetate10250-45-0 4-Heptanol, 2,6- Alicate 0.45400000 dimethyl-, 4- acetate105-79-3 Hexanoic acid, Iso Butyl Caproate 0.413000002-methylpropylester2349-07-7 Propanoic acid, Hexyl isobutyrate 0.413000002-methyl-, hexylester23250-42-2 Cyclohexanecarb Cyprissate 0.40500000 oxylic acid, 1,4- dimethyl-,methyl ester,trans- 122-78-1 Benzeneacetalde Phenyl 0.36800000 hyde acetaldehyde5405-41-4 Butanoic acid, 3- Eth yl - 3 -H ydroxy 0.36200000 hydroxy-, ethyl Butyrate ester105-53-3 Propanedioic Diethyl Malonate 0.34400000 acid, 1,3-diethylester93-58-3 Benzoic acid, Methyl Benzoate 0.34000000 methyl ester16356-11-9 1,3,5- Undecatriene 0.33600000Undecatriene65405-70-1 4-Decenal, (4E)- Decenal (Trans-4) 0.33100000 54546-26-8 1,3-Dioxane, 2- Herboxane 0.33000000 butyl-4,4,6- trimethyl- 13254-34-7 2-Heptanol, 2,6- Dimethyl-2,6- 0.33000000 dimethyl- Heptan-2-ol98-86-2 Ethanone, 1- Acetophenone 0.29900000 phenyl- 93-53-8 Benzeneacetalde Hydratropic 0.29400000 hyde, a-methyl- aldehyde80118-06-5 Propanoic acid, Iso Pentyrate 0.285000002-methyl-, 1,3-dimethyl-3- buten-l-yl ester557-48-2 2,6-Nonadienal, E Z-2,6-Nonadien- 0.28000000(2E,6Z)- 1-al24683-00-9 Pyrazine, 2- 2 -Methoxy -3- 0.27300000 methoxy-3-(2- Isobutyl Pyrazine methylpropyl)- 104-57-4 Formic acid, Benzyl Formate 0.27300000 phenylmethylester104-45-0 Benzene, 1- Dihydroanethole 0.26600000 methoxy-4- propyl- 491-07-6 Cyclohexanone, Iso Menthone 0.256000005-methyl-2-(l- methylethyl)-,(2R,5R)-rel- 89-80-5 Cyclohexanone, Menthone Racemic 0.256000005-methyl-2-(l- methylethyl)-,(2R,5S)-rel- 2463-53-8 2-Nonenal 2 Nonen-l-al 0.25600000 55739-89-4 Cyclohexanone, Thuyacetone 0.250000002-ethyl-4,4- dimethyl- 150-78-7 Benzene, 1,4- Hydroquinone 0.25000000 dimethoxy- Dimethyl Ether64988-06-3 Benzene, 1- Rosacene 0.24600000(ethoxymethyl)- 2-methoxy- 76-22-2 Bicyclo[2.2.1]he Camphor gum 0.22500000 ptan-2-one,1,7,7-trimethyl- 67674-46-8 2-Hexene, 6,6- Methyl 0.21400000 dimethoxy-2,5,5- Pamplemoussetri methyl- 112-31-2 Decanal Decyl Aldehyde 0.20700000 16251-77-7 Benzenepropanal Trifernal 0.20600000, P-methyl- 93-92-5 Benzenemethano Methylphenylcarbi 0.203000001, a-methyl-, 1- nol Acetate acetate143-13-5 Acetic acid, Nonyl Acetate 0.19700000 nonyl ester122-00-9 Ethanone, l-(4- Para Methyl 0.18700000 methylphenyl)- Acetophenone24237-00-1 2H-Pyran, 6- Gyrane 0.18600000 butyl-3,6-dihydro-2,4- dimethyl- 41519-23-7 Propanoic acid, Hexenyl 0.182000002-methyl-, (3Z)- Isobutyrate3-hexen-l-ylester93-89-0 Benzoic acid, Ethyl Benzoate 0.18000000 ethyl ester20780-48-7 3-Octanol, 3,7- Tetrahydro linalyl 0.18000000 dimethyl-, 3- Acetateacetate101-41-7 Methyl 2- Methylphenyl 0.17600000 phenylacetate acetate40853-55-2 1 -Hexanol, 5- Tetrahydro 0.17300000 methyl-2-(l- Lavandulyl Acetate methylethyl)-, 1- acetate933-48-2 Cyclohexanol, Trimethylcyclohexa 0.173000003,3,5-trimethyl-, nol(1R,5R)-rel- "35158-25-9 2-Hexenal, 5- Lactone of Cis 0.17200000 methyl-2-(l- Jasmone methylethyl)- 18479-58-8 7-Octen-2-ol, Dihydromyrcenol 0.166000002,6-dimethyl- 140-11-4 Acetic acid, Benzyl acetate 0.16400000 phenylmethylester14765-30-1 Cyclohexanone, 2 -sec -Butyl Cyclo 0.163000002-(l- Hexanone methylpropyl)- 20125-84-2 3-Octen-l-ol, Octenol 0.16000000(3Z)- 142-19-8 Heptanoic acid, Allyl Heptoate 0.160000002-propen-l-ylester100-51-6 Benzenemethano Benzyl Alcohol 0.15800000110032-15-2 Butanoic acid, 2- Hexyl-2-Methyl 0.15800000 methyl-, hexyl Butyrate ester695-06-7 2(3 H) -Furanone, Gamma 0.152000005-ethyldihydro- Hexalactone21722-83-8 Cyclohexaneetha Cyclohexyl Ethyl 0.15200000 nol, 1 -acetate Acetate111-79-5 2-Nonenoic acid, Methyl-2- 0.14600000methyl ester Nonenoate16491-36-4 Butanoic acid, Cis 3 Hexenyl 0.13500000 (3Z)-3-hexen-l- Butyrate yl ester111-12-6 2-Octynoic acid, Methyl Heptine 0.12500000 methyl ester Carbonate59323-76-1 1,3-Oxathiane, Oxane 0.123000002-methyl-4- propyl-, (2R,4S)- rel- 62439-41-2 Heptanal, 6- Methoxy Melonal 0.11900000 methoxy-2,6- dimethyl- 13851-11-1 Bicyclo[2.2.1]he Fenchyl Acetate 0.11700000 ptan-2-ol, 1,3,3- trimethyl-, 2- acetate115-95-7 l,6-Octadien-3- Linalyl acetate 0.11600000 ol, 3,7-dimethyl-, 3 -acetate18479-57-7 2-Octanol, 2,6- Tetra-Hydro 0.11500000 dirnethyl- Myrcenol78-69-3 3,7- Tetra-Hydro 0.11500000 dimethyloctan-3- Linalool ol111-87-5 1 -Octanol Octyl Alcohol 0.11400000 71159-90-5 3-Cyclohexene- Grapefruit 0.105000001-methanethiol, mercaptan a,a,4-trimethyl- 80-25-1 Cyclohexaneniet Menthanyl Acetate 0.10300000 hanol, a,a,4- trimethyl-, 1- acetate88-41-5 Cyclohexanol, 2- Verdox™ 0.10300000(1' 1- dimethylethyl)-,1 -acetate32210-23-4 Cyclohexanol. 4- Vertenex 0.10300000(1,1- dimethylethyl)-,1 -acetate112-44-7 Undecanal n-Undecanal 0.10200000 124-19-6 Nonanal Nonanal Aldehyde 0.53200000C-9929253-05- 6-methoxy-2,6- 6-methoxy-2,6- 0.04020000 4 dimethyloctanal dimethyl octanal68039-47-4 2-propan-2- Phenethyl Isopropyl 0.24900000 yloxyethylbenze Etherne134. 6413-10-1 ethyl 2-(2- Apple Ketal 0.21900000 methyl-1,3- dioxolan-2- yl)acetate106-23-0 3,7-diniethyloct- citronellal 0.21500000135. 6-enai136. 14667-55-1 Trimethyl Trimethyl Pyrazine- 1.72400000Pyrazine-2,3,5 2,3,5* Vapor Pressures are acquired as described in the Test Methods Section.** Origin: Same as for Table I hereinabove.[Table 3B] High Volatile Fragrance MaterialsNo. Natural oil Supplier 1. Angelica Seeds Oil Robertet 2. Basil Oil Grand Vert IFF3. Bergamot Oil Reggio Early New Crop Capua 4. Black Pepper Oil Robertet 5. Blackcurrant Buds Absolute Robertet 6. Cardamom Guatamaia Extract CO2 IFF7. Cardamom Oil Guatemala IFF8. Cedarleaf Oil Kerry9. citronella oil H. Reynaud & Fils 10. Clary Sage Oil French IFF11. Coffee Extract CO2 Firmenich 12. Cucumber Extract Firmenich 13. Cumin Oil Robertet 14. Cypress Oil IFF15. Elemi Coeur Oil Robertet 16. Ginger oil India IFF17. Grapefruit Zest Citrus & Allied Essences 18. It. Bergamot Oil Capua 19. Labdanum Cistus Absolute Biolandes 20. Lavandin Grosso Oil H. Reynaud & Fils 21. Lemon Oil Winter Capua 22. Green Mandarin Oil Simone Gatto 23. Nutmeg Oil Robertet 24. Oil Orange Sinensal Citrus & Allied Essences 25. Olibanum Oil Pyrogenous Firmenich 26. Pepper Black CO2 Oil Firmenich 27. Petitgrain Mandarinier Oil Misitano & Stracuzzi28. Pink Pepper CO2 OIL Firmenich29. Rum CO2 Oil Firmenich 30. Sichuan Pepper CO2 oil Firmenich 31. Styrax Resold IFF32. Tangerine Oil Robertet 33. Thym Oil IFF34. Violet Leaves Absolute Robertet SuppliersBiolandes, Le Sen, FranceCapua, Campo Calabro, ItalyCitrus & Al 1 ied Essences, New York, USAFirmenich, Geneva, SwitzerlandGlobal Essence Inc, New Jersey, USAII. Reynaud & Fils, Montbrun-les-Bains, FranceIFF, Hazlet, New Jersey, USAKerry, Co. Kerry, IrelandMane, Le Bar-sur-Loup, FranceMisitano & Stracuzzi, Messina, ItalyRobertet, Grasse, FranceSimone Gatto, San Pierre Niceto, Italy

[0028] Exemplary high volatile fragrance materials selected from the group of Tables 3A or 3B are preferred. However, it is understood by one skilled in the art that other high volatile fragrance materials, not recited in Tables 3A or 3B, would also fall within the scope of the present invention, so long as they have a vapor pressure of greater than 0.1 Torr (0.0133 kPa) at 25 °C.

[0029] The non-ionic surfactant system is present in the oil phase. The surfactant system helps stabilize the oil-in-water perfumed emulsion. The surfactant system can range from about 1 wt% to about 6 wt% of the emulsion, about 2 wt% to about 5 wt%, less than, equal to, or greater than about 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5or about 6 wt% of the emulsion.

[0030] While not so limited, suitable surfactants for the surfactant system can include several categories of emulsifying agents. Polyglycerol esters include polyglyceryl-6 stearate, polyglyceryl-6 behenate, polyglyceryl- 10 laurate, polyglyceryl-4 oleate, and polyglyceryl-3 diisostearate. Polyethylene glycol derivatives include PEG-40 hydrogenated castor oil, PEG-20 glyceryl laurate, PEG -7 glyceryl cocoate, PEG-200 hydrogenated glyceryl palmate, and PEG-90 glyceryl isostearate.

[0031] Sorbitan esters include sorbitan laurate, sorbitan palmitate, sorbitan stearate, sorbitan oleate, and sorbitan tristearate. Citrate esters include dilauryl citrate, triethyl citrate, tributyl citrate, and acetyl tributyl citrate.

[0032] Other surfactants include the polysorbate family (including polysorbate 20, 60, and 80), cetearyl alcohol, and various ethoxylated derivatives like ceteareth-20 and steareth-20. Glyceryl-based emulsifiers include glyceryl stearate and glyceryl oleate. Other surfactants include sucrose palmitate, sodium stearoyl lactylale, cetyl alcohol, stearyl alcohol, laureth-23, and oleth-20. Other surfactants can include tri(polyglyceryl-3 / lauryl) hydrogenated rilinoleate. a mixture of glyceryl tearate and polyglyceryl-6 almitate / succinate and cetearyl alcohol and dicetyl phosphate and ceteth-10 phosphate, trilaureth-4 phosphate

[0033] The optional emollient component is present in the oil phase. The emollient can range from about 0.0 wt% to about 15 wt% of the emulsion, about 0.1 wt% to about 10 wt%, less than, equal to, or greater than about 0.01 wt%, 0.1, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14, 14.5, or about 15 wt% of the emulsion. Suitable emollients provide moisturization and improve skin feel. Caprylic capric triglyceride, can be used as it offers excellent spreading properties and a light, non-greasy skin feel. Other suitable emollients include isopropyl myristate, isopropyl palmitate, and cetyl palmitate, which provide varying degrees of moisturization and texture enhancement. Natural oils such as sweet almond oil, jojoba oil, and argan oil contribute both emollient properties and skin-beneficial nutrients. Synthetic emollients like dimethicone, cyclomethicone, and other silicone-based materials offer unique sensory properties and help create barrier protection. Additional effective emollients include CT 2- 15 alkyl benzoate, dicaprylyl carbonate, and isononyl isononanoate, which provide excellent spreadability and absorption characteristics. Esters such as ethylhexyl palmitate, octyl palmitate, and decyl oleate contribute to the overall skin conditioning properties while maintaining a pleasant skin feel. Hydrogenated polyisobutene, pentaerythrityl tetraethylhexanoate, and neopentyl glycol dicaprate round out the emollient options, each offering unique benefits in terms of viscosity, spreading, and moisturization properties.

[0034] The aqueous phase can include a suspending component. The suspending component can be present at a concentration in a range of from about 0.20 wt% to about 1.5Owt% of the emulsion, about 0.10 wt% to about 1.50 wt%, less than, equal to, or greater than about 0.20 wt%, 0.25, 0.30, 0.35, 0.40, 0.45, 0.50, 0.55, 0.60, 0.65, 0.70, 0.75, 0.80, 0.85, 0.90, 0.95, 1, 1.10, 1.15, 1.20, 1.25, 1.30, 1.35, 1.40, 1.45, or about 1.50 wt% of the emulsion.

[0035] Microcrystalline cellulose and cellulose gum are suitable suspending agents, and can be used in combination to provide synergistic stabilization effects. Additional effective suspending components include xanthan gum, which offers excellent suspension properties through its unique rheological behavior, and carbomer, which provides both suspending and thickening properties. Natural polymers such as carrageenan, alginate, and pectin serve as versatile suspending agents while contributing to the overall stability of the emulsion. Synthetic suspending agents like acrylates copolymer and carbomer homopolymer provide robust suspension capabilities across v arious pH ranges. Other valuable suspending components include hydroxypropyl methylcellulose, methylcellulose, and hydroxyethylcellulose, which offer varying degrees of suspension and viscosity control. Guar gum and its derivatives, along with acacia gum and tragacanth gum, represent natural alternatives that provide effective suspension properties. Polyquaternium compounds and polyacrylamides round out the selection of suspending agents, offering unique benefits in terms of stability and compatibility with various formulation components.

[0036] The oil-in-water perfumed emulsion can include numerous additional optional components. For example, the aqueous phase can include a moisturizer component. The moisturizer component can be present in a range from about 0.1 wt% to about 6 wt% of the emulsion, about 0.5 wt% toa bout 5 wt%, less than, equal to, or greater than about 0.1 wt%, 0.5, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, or about 6 wt.% of the emulsion.

[0037] Moisturizing components suitable for the aqueous phase of oil-in-water perfumed emulsions include glycerin, which serves as a highly effective humectant by attracting and retaining moisture. Additional humectants include propylene glycol, butylene glycol, and pentylene glycol, which provide varying degrees of moisturization while also serving as potential preservative boosters. Natural moisturizers such as sodium hyaluronate, hyaluronic acid, and sodium PCA offer excellent hydration properties through their ability to bind multiple times their weight in water. Panthenol (pro-vitamin B5) and allantoin contribute both moisturizing and soothing properties to the formulation. Sugar-based moisturizers including sorbitol, mannitol, and xylitol provide effective hydration whilecontributing to the overall stability of the emulsion. Urea and its derivatives offer deep moisturization properties while also serving as natural exfoliating agents. Betaine, derived from sugar beets, provides excellent moisturization while acting as an osmoprotectant.Poly glycerins and glycereth compounds offer varying degrees of hydration while maintaining compatibility with a wide range of formulation components. Trehalose, a natural sugar compound, provides both moisturizing properties and preservation benefits to the aqueous phase. A more specific list includes glycerine, diglycerin (cas 261-605-5) and glycerin (cas 56-81-5), polyglycerin, hyaluronic acid, 1,2-hexanediol, urea, lactic acid, propylene glycol, dipropylene glycol, butylene glycol, sorbitol, propane-l,3-diol, propanediol, caprylyl glycol, isopropene glycol, hexylene glyol, pentylene glycol, honey, ethylene glycol, polypropylene glycol, hydrolyzed collagen, sodium pea, alanine, fructose, glucose, allantoin, trimethylglycine, sodium lactate, aloe barbadensis leaf juice, or a mixture thereof

[0038] Another optional component can include a thickener in the aqueous phase. The thickner can range from about 0.05 wt% to about 1 wt% of the emulsion, about 0.2 wt% to about 0.7 wt%, less than, equal to, or greater than about 0.05 wt%, 0.10, 0.15, 0.20, 0.25, 0.30, 0.35, 0.40, 0.45, 0.50, 0.55, 0.60, 0.65, 0.70, 0.75, 0.80, 0.85, 0.90, 0.95, or about 1 wt% of the emulsion.

[0039] Thickeners suitable for the aqueous phase of oil-in-water perfumed emulsions include ammonium acryloyldimethyltaurate / VP copolymer, which provides excellent stabilizing and thickening properties across a wide pH range. Carbomer polymers offer robust thickening capabilities while contributing to emulsion stability through their unique rheological properties. Natural polysaccharides like xanthan gum provide pseudoplastic flow behavior and excellent suspension properties, while diutan gum offers enhanced stability at elevated temperatures and electrolyte tolerance. Sclerotium gum provides unique rheological properties and creates pleasant skin feel in cosmetic applications. Acrylates / C 10-30 alkyl acrylate crosspolymer offers versatile thickening and stabilizing properties with excellent electrolyte tolerance. Additional effective thickeners include sodium polyacrylate, hydroxyethylcellulose, and hydroxypropyl guar, which provide varying degrees of viscosity control. Polyacrylamide and its derivatives offer excellent thickening properties while maintaining clarity in aqueous systems. Carboxymethylcellulose sodium, polyquaternium-37, and acrylic acid / VP crosspolymer provide additional options for viscosity modification while maintaining formulation stability. Magnesium aluminum silicate and hectorite clay materials serve as natural thickening alternatives while contributing to suspension properties.

[0040] Another optional component can include a preservative system present in the oil phase. The preservative system can be present in a range of from about 0.1 wt% to about 1 wt% of the emulsion, about 0.2 wt% to about 0.7 wt%, less than, equal to, or greater than about 0.1 wt%, 0.15, 0.20, 0.25, 0.30, 0.35, 0.40, 0.45, 0.50, 0.55, 0.60, 0.65, 0.70, 0.75, 0.80, 0.85, 0.90, 0.95, or about 1.0 wt% of the emulsion, comprising ingredients like 1,2- hexanediol, 1,2-octanediol, and hydroxy acetophenone.

[0041] Preservatives suitable for oil-in-water perfumed emulsions include 1,2- hexanediol and 1,2-octanediol, which serve as multifunctional ingredients offering both preservative and moisturizing properties. Hydroxy acetophenone provides broad-spectrum antimicrobial protection while maintaining formulation stability. Additional effective preservatives include phenoxyethanol, which offers broad-spectrum protection against various microorganisms, and ethylhexylglycerin, which works synergistically with other preservatives while providing skin conditioning benefits. Caprylyl glycol serves as both a preservative booster and moisturizing agent, while benzyl alcohol provides antimicrobial activity particularly against gram-positive bacteria. Dehydroacetic acid and benzoic acid offer preservation particularly in acidic conditions. Sorbic acid and its salts provide effective protection against mold and yeast. Propanediol serves as a natural alternative preservative while contributing moisturizing properties. Pentylene glycol offers both preservative and humectant properties. Sodium benzoate and potassium sorbate represent food-grade preservatives that are particularly effective in water-based systems. Phenylpropanol provides both preservative function and pleasant olfactory properties, while chlorphenesin offers broad-spectrum antimicrobial activity.

[0042] The aqueous phase can further include an optional modulator component. The modulator can range from about 0.05 wt% to about 10 wt% of the emulsion, about 0.1 wt% to about 0.8 wt%, less than, equal to, or greater than about 0.05 wt%, 0.1, 0.5, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, or about 10 w't% of the emulsion.

[0043] The modulator can be a liquid at temperatures lower than 100 °C, such as at ambient temperature. The modulator may be fully miscible with the fragrance materials to form a single phase liquid. However, if the fragrance materials are not entirely miscible, or are immiscible, then co-sol vents (e.g., dipropylene glycol (DPG), triethyl citrate, or others well known to those skilled in the art) can be added to aid in the solubility of the fragrance materials.

[0044] Suitable examples of modulators can include methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, or mixtures thereof. Further examples can include from polypropylene glycol- 10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl / capryl glucoside, undecyl glucoside, and mixtures thereof. In some examples, the composition can be substantially free of isocetyl alcohol, diisobutyl adipate, diisoamyl adipate, polypropylene glycol-3 myristyl ether, and neopentyl glycol diethyl hexanoate, neopentyl glycol diisononanoate, cetearyl ethyl hexanoate, and their mixtures, or a mixture thereof. Tables 4(a) and 4(b) provide a list of additional modulators.Tables 4(a) and 4(b) provide lists of suitable modulators.[Table 4(a)] Fragrance ModulatorsCASNo. Group Chemical Name Supplier Number1. PPG- 10 Methyl Glucose Ether 61849-72-72. PPG-20 Methyl Glucose Ether761849-72-7Lubrizol Ethoxylated Methyl Glucose3. 68239-42-9(a) Ether24. Caprylyl / Capryl Glucoside568515-73-1 BASF SEPPIC5. Undecyl Glucoside2,7-- (France) Ashland6. (b) Isocetyl Alcohol436653-82-4 Speciality Ingredients7. PPG-3 Myristyl Ether5— Evonik(c) Neopentyl Glycol8. 28510-23-8 Lubrizol Diethylhexanoate6Alfa9. Sucrose laurate 25339-99-5 Chemicals Ltd. (UK) Alfa10. Sucrose dilaurate 25915-57-5 Chemicals(d) Ltd. (UK) Mitsubishi11. Sucrose Myristate 27216-47-3Chemicals12. Sucrose Palmitate 26446-38-8 Alfa Chemicals13. Sucrose Stearate 25168-73-4Ltd. (UK) Mitsubishi14. Sucrose Distearate 27195-16-0 Chemicals(IP)Mitsubishi 27923063- Sucrose Tristearate Chemicals 3(•TP) (E)-l -(2,2,6- Takasago (e) trimethylcyclohexyl)oct- 1 -en-3- (Japan) one82-( 1 -menthoxy)ethane- 1 -ol9l-(l-menthoxy)propane-2-ol93-( 1 -menthoxy)propane- 1 -ol9— 3-( 1 -menthoxyjpropane- 1,2- Takasago (f) __diol9(Japan) 2-methyl-3-(l- __ nienthoxy)propane-l,2-diol94-(l-menthoxy) butane-l-ol9__1, 1,4,4-tetramethyl-6-acetyl-7 - formyl-1, 2,3,4- Givaudan tetrahydronaphthalene10(g) (Switzerland 1, 1,2,4,4-pentamethyl-6-acetyl- 7-formyl-l,2,3,4- ) tetrahydronaphthalene10Hyaluronic acid disaccharide Sigma 9004-61-9(h) sodium salt 11 Aldrich Sodium Hyaluronate119067-32-7 (UK) Mono -o -(linalyl) -glucopyranose12 __Di-o-(linalyl)-glucopyranose12Tri -o-(linalyl )-glucopyranose12__ T etra-o -(linalyl) -glucopyranose' n "' __Penta-o -(linalyl) -glucopyranose12 __Mono-o -(cis-3-hexenyl)- (i) -- glactopyranose12Di-o-(cis-3-hexenyl)- — glactopyranose12Tri-o-(cis-3-hexenyl)- __ Kanebo glactopyranose12(Japan) Tetra-o-(cis-3-hexenyl)- __glacto pyranose12Pen ta -o-(ci s-3 -hexen yl)- glactopyranose12Bis-O-(3,6-dioxadecanyl)- — glucopyranose13Tris-O-(3,6-dioxadecanyl)- __ glucopyranose13(j) Tetrakis-O-(3,6-dioxadecanyl)- __glucopyranose13Pentaki s-0 -(3, 6-di oxadecanyl )- --glucopyranose13Bis-O-(3,6-dioxaoctanyl)- — galactopyranose13Tris-O-(3,6-dioxaoctanyl)- __ galactopyranose13Tetraki s-O-(3, 6-dioxaoc tanyl) - __ galactopyranose75Pen takis-0 -(3, 6-di oxaoctany 1 ) - -- galactopyranose13Bis-O-(3,6-dioxaheptanyl)- __ xvlopyranose75Tris-O-(3,6-dioxaheptanyl)- __ xylopyranose13Tetrakis-O-(3,6-dioxaheptanyl)- -- xylopyranose13Bi s-0 -(3, 6-diox adodecany 1 ) - — glucopyranose75Tris-O-(3,6-dioxadodecanyl)- __ glucopyranose75Tetrakis-O-(3,6- dioxadodecanyll-glucopyranose —' 13Pentakis-O-(3,6- dioxadodecanyl)- -- glucopyranose13Hydroquinone beta-D-glycoside(k) 14 497-76-7 Shiseido Propylene Glycol Propyl Ether 1569-01-3 Sigma Aldrich Di cetyl Ether 4113-12-6(UK) Solvay Polyglycerin-4 Ethers 25618-55-7Chemicals Isoceteth-5 69364-63-2 Isoceteth-7 69364-63-2 Isoceteth-10 69364-63-2 Nihon Isoceteth-12 69364-63-2 Emulsion (1) Isoceteth-15 69364-63-2 Company Isoceteth-20 69364-63-2 Ltd. Isoceteth-25 69364-63-2 Isoceteth-30 69364-63-2 Disodium68929-04-4 Rhodia LauroamphodipropionateSigma Hexaethylene glycol3055-96-7 Aldrich monododecyl ether14b(UK) Neopentyl Glycol27841-07-2(m) Diisononanoate13Symrise (Germany) Cetearyl Ethylhexnoate7690411-68-0Takasago (n) 2 -ethylhexyloxypropanediol1770455-33-9(JP)DSM Nutritional Panthenol Ethyl Ether18667-83-4Products, (o)Inc. (USA) Roche Inc. DL-Panthenol 16485-10-2(USA) Diisobutyl Adipate19141-04-8 Sigma (P) Aldrich Diisoamyl Adipate196624-70-0 (UK) (q) PPG- 11 Stearyl Ethert9a25231-21-4 Kao (JP)N-hexadecyl n-nonanoate19b72934-15-7(e.g., cetyl nonanoate) Symrise (r) Noctadecyl n-nonanoate19b107647-13- (Germany)(e.g., stearyl nonanoate) 2methanone, (morphonyl) __tricyclo[3.3.1.13,7]dec-l -yl-20methanone, (piperidinyl) -- tricyclo[3.3.1. l3,7]dec-l-yl-20methanone, (pyrrolidinyl)—tricyclo[3.3.1.13,7]dec-1-yl20methanone, (azetidinyl) __tricyclo[3.3.1.13,7]dec-l -yl-20methanone,(hexahydroazepinyl) -- tricyclo[3.3.1.13,7]dec-1-yl-20methanone, (4-cyano- piperidinyl)tricyclo [3.3.1.13”' ] de -- c- 1-yl-20methanone, (4-amido-piperidinyl)tricyclo[3.3.1.13,7]dec-1-yl-20Unilever (s) methanone, (Tricyclo[3.3.1.13,7]decanyl)-N- -- tricyclo[3.3.1.13,7]dec-1-yl-20methanone,(decahydroisoquinolinyl)tricycl — o[3.3.1.13,7]dec-l-yl-20methanone,(decahydroisoquinol iny 1 ) tri cy cl __ o[3.3.1.13,7]dec-l-yl-20’methanone,(decahvdroquinolinyl)tricyclo[3 __.3.1.13’7]dec-l-yl-20methanone, (3,3-dimethyl-l- piperidinyl)tricyclo[3.3.1.13”'] -- dec- 1-yl-20methanone, (2-methyl-l- piperidinyl)tricyclo[3.3.1.13”'] __dec-l-yl-20methanone, (4-methyl-l- 89. piperidinyl)tricyclo[3.3.1.1J’ / l __dec-l-yl-20methanone, (3-methyl-l- 90. piperidinyl)tricyclo[3.3.1.13,7]dec-l-yl-20methanone, (3,5-dimethyl-l- 91. piperidinyl)tricyclo[3.3.1.1J’7] __dec-l-yl-20methanone, (4-methyl-4-ethy- 92. piperidinyl)tricyclo[3.3.1.13,7] —dec-l-yl-20methanone, (3,3-diethyl-1-pyrrolidinyl)tricyclo[3.3.1.13,7]dec-l-yl-20methanone, (N,N-diisopropyl)94. __tricyclo[3.3.1.13’7]dec-l -y\-20methanone, (3,3- 95. dimethylbutylaminyl) __tricydo[3.3.1.13’7ldec-l-yl-20methanone, (2,2-dimethylpropylaminyl) __tricyclo[3.3.1.13’7]dec-l -yl-20methanone, (1, l-dimethyl-3,3- 97. dimethylbutylaminyl) __tricyclo[3.3.1.13,7]dec-l -yl-20methanone, (1,3-dimethyl- 98. butylaminyl)tricyclo[3.3.1.13,7]dec-1-yl-20Bis-methoxy PEG-13 PEG-438 / PPG-110 SMDI Copolymer 936645-35-1 PolymerExpert S.A. (Pessac,France) propyl {4-[2-(diethylamino)-2-oxoethoxy]-3-methoxyphenyl}acetate2261791-12-6 Sigma Aldrich (US) 3-((2-ethylhexyl)oxy)propane-1,2-diol2370445-33-93-((2- 102. (v) propylheptyl)oxy)propane-l,2- - - diol1-amino-3-((2-ethylhexyl)oxy)propan-2-ol2399509-00-9 -available as GLUCAM™ P-20.available as Glucam™ E-20.available as Plantacare® 810 UP.3aavailable as Simulsol® SL 11W.4available as CERAPHYL® ICA.5available as Tegosoft® APM.6available as Schercemol™ NGDO.7disclosed in U. S. Patent No. 6,737,396B2 (Firmenich), column 1, lines 43-47.6diclosed as compound 1 ’i in U. S. Patent No. 6,440,400Bl (Takasago Int. Corp.), col. 5.8adiclosed in U. S. Patent No. 4,313,855 (Dragoco Gerberding & Co. GmbH), col. 1, lines 12- 13.9disclosed in U. S. Patent No. 7,538,081B2 (Takasago Int. Corp.), column 7, lines 50-53.10disclosed in U. S. Patent No. 6,147,049 (Givaudan Roure), col. 5, line 24, to col. 6, line 17.11disclosed in PCT Publication No. W085 / 04803 (Diagnostic), pg. 2, line 1 to pg. 4, line 2.12disclosed in JP Patent No. 61-083114 (Kanebo).13disclosed in JP Patent No. 61-063612 (Kanebo).14disclosed in JP Patent No. 62-084010 (Shiseido).14t>available as: Laureth-6.15disclosed in U. S. Patent Publication No. 2011 / 0104089A1 (Symrise), para.

[0001] ,16available as PCL-Liquid® 100.17disclosed in U. S. Patent No. 7,196,052 (Takasago Int. Corp.), col. 4, lines 34-35.18disclosed in EP Patent Publication No. 616800A2 (Givaudan), pg. 2, lines 12-25.19disclosed in U. S. Patent No. 4,110,626 (Shiseido), column 3, lines 54-56.19adisclosed in PCT Publication No. WO2014 / 155019 (LVMH).19bdisclosed in U. S. Patent No. 9,050,261 (Symrise).20disclosed as compounds C1-C22 in WO2014 / 139952 (Unilever).21available as Expert Gel® EG56.22available as Kolliphor® EL.23disclosed in U. S. Patent No. 9,050,261 (Symrise).Further examples of non-odorous fragrance modulator is selected from the group of materials disclosed in Table 4(b).[Table 4(b)] Fragrance ModulatorsNo. Chemical or INCITrade Name CAS Number Supplier NameTergitol® 15-S- Sigma Aldrich C 12-14 Sec-Pareth-31. 68131-40-87 (UK) Polyethylene glycol- PPG-7-Buteth- Sigma Aldrich 2. ran-propylene glycol) 9038-95-3~ (UK) monobutyl ether 103. PPG-4-Ceteth-10 Nikkol PBC-33 37311-01-6 Chemical Navi 4. Ethox Chemicals, Deceth-4 Ethal DA-4 5703-94-6Inc.A & E Con nock AEC PPG-5- 5. PPG-5-Ceteth-20 9087-53-0 (Perfumery &Ceteth-20Cosmetics) Ltd.Neodol 45-7Shell Chemical C14-15 Pareth-7 alcohol 68951-67-7 Company ethoxylatelinear alcohol (C12- 15) Pareth-3ethoxylate, Bio-soft N25-7 68131-39-5POE-7 Stephan Linear alcohol (C12- Company (USA)Bio-soft N23- 13) Pareth- 66455-14-96.53ethoxylated, POE-6.5)Polyethylene glycol1100 " Cremophor® A Sigma Aldrich 68439-49-6mono (hexadecyl / octade 25 ~ (UK) cyl) etherLinear alcohol (C9-11)Stephan ethoxylated POE -8 Bio-soft N91-8 68439-46-3Company (USA) Pareth-3Coceth-10 orGenapol® C- Sigma Aldrich Polyoxyethylene (10) 61791-13-7100 (UK) dodecyl etherAlcohols, C 12-14, Rhodasurf® LA Solvay Solutions 68439-50-9ethoxylated 30 Italia S.p. A.Poly(ethylene glycol) methyl ether 9004-74-4 Sigma Aldrich (UK)Neodol® PCCl 0-16 Pareth-1 Shell Chemical 68002-97-1110 Company Arlamol™PPG-11 Stearyl Ether 25231-21-4 Croda (UK)PS HESigma Aldrich Steareth-100 Brij® SI 00 9005-00-9 ~ (UK) Polyethylene glycol Sigma Aldrich hexadecyl ether Brij® C-58 9004-95-9(UK) Sigma Aldrich Plutonic® F-127 Plutonic® F-127 9003-11-6 (UK) Linear Alcohol (C l 1) Stepan Canada Bio-soft Nl-5 34398-01-1Ethoxylate, POE-5 Inc.Intrasol FA Evonik Industries Laureth-10 6540-99-412 / 18 / 10 AG PolyoxyethylenDecaethylene glycol Sigma Aldrich Polyoxyethylene (10) lauryl 9002-92-0mono -dodecyl ether " (UK)etherEthylene glycol 2- 109-86-4 Sigma Aldrich monomethyl ether Methoxyethanol (UK)Grau Aromatics Homulgator 920Myreth-4 27306-79-2 GmbH & GCompany KG Oleth-16 Alkoxylated Toho Chemical Pegnol 0-16 A 25190-05-0Alcohols Industry Co., Ltd.Nihon Emulsion Isosteareth-5 Emalex 1805 52292-17-8Company, Ltd. Arlamol™PPG- 10 Cetyl Ether 9035-85-2 Croda (UK)PC 10Poly(oxyethylene) (18) tridecyl ether 24938-91-8 Sigma-Aldrich (UK)Poly(oxy-1,2- ALFONIC® 10- Sasol Chemicals ethanediyl), a-decyl-w- 26183-52-88 Ethoxylate (USA) LLC hydroxy- Mackam™Laureth- 1 4536-30-5 Rhodia (DE)2LSFPEG-5 Hydrogenated Ethox Chemicals,Ethox HTAM-5 61791-26-2Tallow Amine Inc.Nikkol Nikko Chemicals PEG-15 Oleamine 26635-93-8TAMNO-15 Co., Ltd. Polyoxyethylene (20) Sigma Aldrich Brij® O20-SS 9004-98-2oleyl ether (UK) Cetoleth-10 Brij® CO 10 8065-81-4 Croda, Inc.Sanyo Chemical Talloweth-7 Emulmin 70 61791-28-4Industries Ltd. Isobutoxypropanol Isobutoxypropa34150-35-1 MolPort Alcohols nolIsobutoxypropanol Isobutoxypropa AKos Consulting 23436-19-3Alcohols nol & Solutions Diethylene Glycol Twincide EDG 111-46-6 Roda Toho Chemical Methoxyethanol Hisolve MC 109-86-4Industry Co., Ltd. Ethoxyethanol 2- Sigma-Aldrich 110-80-5Alcohols Ethoxyethanol (UK)The Dow MethoxyisopropanolDowanol™ PM 107-98-2 Chemical AlcoholsCompany Toho Chemical Methoxyethanol Hisolve MC 32718-54-0Industry Co., Ltd. Methylal Dimethoxymeth Sigma-Aldrich 109-87-5Ethers ane (UK)Hans Methoxybutano3 -Methoxybutanol 2517-43-3 Schwarzkopf 1GmbH / Co. KG Shell Chemical Butoxyethanol Butyl OXITOL 111-76-2Company The Dow Propylene Glycol n- Dowanol ™ 5131-66- Chemical Butyl Ether PnB 8 / 29387-86-8Company PropylenePropylene Glycol Butyl Sigma Aldrich Glycol Butyl 15821-83-7Ether (UK)EtherDiethylene2-(2- Sigma Aldrich glycol butyl 112-34-5 butoxyethoxy)ethanol ~ (UK) etherCrodafos™Deceth-4 Phosphate 52019-36-0 Croda, Inc.D4AEthylene glycolSigma-Aldrich monohexadecyl 2136-71-2 (Hexadecyloxy)ethanol (UK) etherPolypropylenePolypropylene glycol) Sigma-Aldrich glycol) 9003-13-8monobutyl ether (UK) nionobutyl etherThe Dow Propylene GlycolDowanol™ PnP 30136-13-1 Chemical Propyl EtherCompany The Dow Propylene Glycol n-Butyl Ether Dowanol™ PnB 29387-86-8 / 5131-66-8Company DipropyleneDipropylene glycol glycol) methyl Sigma Aldrich 34590-94-8monomethyl ether ether, mixture (UK) of isomersThe Dow Dipropylene Glycol Dimethyl Ether Proglyde™ DMM 111109-77-4Company The Dow Dowanol ™PPG-2 Methyl Ether 13429-07-7 Chemical DPMCompany Methoxydiglycol OriStar111-77-3 Orient Stars LLC Ethers DEGMEDi(ethyleneDiethylene glycol ethyl Sigma Aldrich glycol) ethyl 111-90-0ether (UK) etherDimethoxydiglycol Dimethyldiglyc111-96-6 H& V Chemicals Ethers 01The Dow Dowanol™PPG-3 Methyl Ether 37286-64-9 Chemical TPMCompany 224286Methyl Morpholine N-oxide / Amine Oxides 4-Methylmorpholine N-oxide 7529-22-8 Sigma-Aldrich (UK)Croda Europe, Oleth-3 Brij® 03 5274-66-8Ltd. Tri(propylene glycol) Dowanol™ Sigma-Aldrich 55934-93-5n-butyl ether TPnB (UK) Tripropylene Sigma-Aldrich Tripropylene Glycol 24800-44-0Glycol (UK)The Dow PPG-3 Methyl Ether Dowanol™25498-49-1 Chemical Alkoxylated Alcohols TPMCompany Sigma Aldrich Tri ethylene glycol Triglycol 112-27-6(UK) Toho Chemical PEG-3 Methyl Ether Hymol™ 112-35-6Industry Co., Ltd. A & E Connock Laureth-3 AEC Laureth-3 3055-94-5 (Perfumery & Cosmetics) Ltd. Ethylhexylglycerin AG-G-75008 70445-33-9 Angene Chemical Tetraethylene Sigma Aldrich Tetra(ethylene glycol) 112-60-7glycol ' (UK) Steareth-3 Isoxal 5 4439-32-1 Vevy Europe SpA Nihon Emulsion Ceteth-3 Emalex 103 4484-59-7Company, Ltd. Myreth-3 Isoxal 5 26826-30-2 Vevy Europe SpA Alfonic® TDA- __ Sasol North Trideceth-33 Ethoxylate America, Inc.Croda Europe, Ceteth-2 Brij® 02 5274-61-3Ltd.Oleth-2 Brij® 02 5274-65-7 Croda, Inc. Steareth-2 Brij® S2 16057-43-5 Croda, Inc. Cetoleth-10 Brij® CO 10 8065-81-4 Croda, Inc.TrimethylTrimethyl PentanolPentanolHydroxyethyl Ether 68959-25-1 Angene Chemical HydroxyethylAlcoholsEtherSteareth-10 Allyl Ether Salcare® SC80 109292-17-3 BASF TEA-Lauryl Ether AG-J-99109 1733-93-3 Angene ChemicalPolyglyceryl-2 Oleyl71032-90-1 Chimex Ether Chimexane NBB402 Sigma-Aldrich Batyl Alcohol 544-62-7ALDRICH (UK) 15879 Sigma-Aldrich Octaethylene Glycol 5117-19-1ALDRICH (UK) Triglycerol Cithrol™ 66082-42-6 Croda (UK) diisostearateSakamoto Diglycerin Diglycerin 801 59113-36-9 Yakuhin Kogyo Co., Ltd. Sakamoto PolyglycerinPolyglycerin #310 25618-55-7 Yakuhin KogyoCo., Ltd. Sasol Germany Distearyl Ether Cosmacol® SE 6297-03-6GmbHCaprylyl Glyceryl Caprylyl AKos Consulting 10438-94-5Ether Glyceryl Ether & Solutions Nikko Chemicals Chimyl Alcohol Chimyl Alcohol 506-03-6Co., Ltd. Dipentaerythrityl Hexacaprylate / Hexacaprate Liponate® DPC-6 68130-24-5 Lipo Chemicals, Inc.394467 Sigma-Aldrich Morpholine 110-91-8ALDRICH (UK) The Dow Dimethyl Oxazolidine OXABAN™ -A 51200-87-4 Chemical Company 4- Ethyl HydroxymethylOxazolemethan 68140-98-7 Angene Chemical Oleyl OxazolineolMethyl Hydroxymethyl Adeka Nol GE- Adeka 14408-42-5Oleyl Oxazoline RF Corporation OriStarPramoxine HCl 637-58-1 Orient Stars LLC PMHCLAllantoinAllantoin Ascorbate 57448-83-6 ABI Chem AscorbateStearamidopropyl Mackalene™55852-14-7 Rhodia Inc. Morpholine Lactate 326Lambiotte & CIE Dioxolane Elcotal DX 646-06-0S. A. Glycerol Sigma Aldrich Glycerol Formal 5464-28-8Formal (UK) StearamidopropylMackine 321 55852-13-6 Rhodia Inc. MorpholinePoly(melamine-co-formaldehyde) methylated 2,4,6-Tris[bis(methoxymethyl)amino]-1,3,5-triazine 68002-20-0 Sigma-Aldrich (UK)Poloxamine 1307 Pluracare® 1307 11111-34-5 BASF Nonoxynol-8 Igepal® CO-610 27177-05-5 Rhodia Inc. Nonoxynol-10 Igepal® CO-710 27177-08-8 Rhodia Inc.Nikko Chemicals Octoxynol-10 Nikkol OP- 10 2315-66-4Co., Ltd. Nonoxynol-9 Igepal® CO-630 68987-90-6 Rhodia Inc.Nonoxynol-9Nonoxynol-9 Iodine 94349-40-3 Angene Chemical iodineOctylphenoxypoly(ethyleneoxy)ethan Igepal® CA-630 68987-90-6 Rhodia Inc.ol, branchedThe Dow Sodium Octoxynol-2Triton™ X-200 55837-16-6 Chemical Ethane SulfonateCompany Lanxess Benzylhemiformal Preventol D2 14548-60-8CorporationNonoxynol-2 Igepal® CO-210 27176-93-8 Rhodia Inc.The Dow Octoxynol-3 Igepal® CA-420 2315-62-0 Chemical Company Marlophen NP Sasol Germany Nonoxynol-3 27176-95-03 GmbH Alkoxylated Alcohols Alkasurf NP-4 7311-27-5 Rhodia Inc.Tri ethyleneGlycol Mono(p- Santa Cruz Nonoxynol-3 51437-95-7nonylphenyl) Biotechnology EtherJos. H. Nonoxynol-7 Lowenol 2689 27177-03-3 Lowenstein &Sons, Inc. Nonoxynol-6 Igepal® CO-530 27177-01-1 Rhodia Inc. Nonoxynol-5 Igepal® CO-520 20636-48-0 Rhodia Inc. Nonoxynol-5 Igepal® CO-520 26264-02-8 Rhodia Inc. Nonoxynol-4 Alkasurf NP-4 27176-97-2 Rhodia Inc. Polyglyceryl-10 Trioleate Nikkol Decaglyn 3-OV 102051-00-3 Nikko Chemicals Co., Ltd. Polyglyceryl-10 Dioleate Nikkol Decaglyn 2-O 33940-99-7 Nikko Chemicals Co., Ltd. Polyglyceryl-10 Abitec Caprol 10G40 34424-98-1Tetraoleate Corporation NikkoiPolyglyceryl-10 Nikko Chemicals Decaglyn 1-SV 79777-30-3Stearate Co., Ltd.EXSakamoto S-Face 0-1001Polyglyceryl-10 OleateP 79665-93-3 Yakuhin Kogyo Co., Ltd. NikkoiPolyglyceryl-10 Nikko Chemicals Decaglyn 1-MV 87390-32-7Myristate Co., Ltd.EXDermofeel® GDermofeel® G 10 L Dr. Straetmans 10 L 34406-66-1NIKKOL. Polyglyceryl-6 Laurate Hexaglyn 1-L 51033-38-6 Chemical Navi Sakamoto Polyglyceryl-6S-Face IS-601 P 126928-07-2 Yakuhin Kogyo IsostearateCo., Ltd.VNihon Emulsion Choleth-10 Emalex CS-10 27321-96-6Company, Ltd. Steareth-10 AllylEther / Acrylates Salcare® SC80 109292-17-3 BASF CopolymerPhoenix Polyvinyl Stearyl Ether Giovarez® 1800 9003-96-7Chemical, Inc.Cosmacol Ether Sasol Germany Dicetyl Ether —16 GmbH Pola Chemical PPG-23-Steareth-34 Unisafe 34S-23 9038-43-1Industries, Inc. Stearoxypropyl Farmin DM E- 17517-01-0 Kao Corp. Dimethylamine 80Sasol Germany Distearyl Ether Cosmacol SE 6297-03-6GmbH AEC A & E Connock Polyquaterni um- 10 Polyquaterni um 55353-19-0 (Perfumery &-10 Cosmetics) Ltd.Sigma Adlrich Octyl ether Dioctyl ether 629-82-3' (UK) Ethyl Ether Diethyl Ether 60-29-7 EMD Chemicals Methyl Hexyl Ether methyl hexyl4747-07-3 TCI AMERICA Ethers etherNihon Emulsion Ceteth-12 Emalex 112 94159-75-8 Company, Ltd. Ceteth-10 or cetylJeecol CA-10 14529-40-9 Jeen International alcohol POE- 10Steareth-10 Jeecol SA- 10 13149-86-5 Jeen International NonaethyleneNonaethylene glycol glycol Sigma Aldrich 3055-99-0monododecyl ether monododecyl (UK) etherOleth-10 Brij® O10 71976-00-6 Croda, Inc. Oleth-10 Brij® O10 24871-34-9 Croda, Inc.The Dow Carbowax™PEG- 12 6790-09-6 Chemical PEG 600Company PEG-9 Sabopeg 400 3386-18-3 Sabo s.p.a.DECAETHYL PEG- 10 5579-66-8 MolPort ENE GLYCOLThe Dow Carbowax™PEG-6 2615-15-8 Chemical PEG 300Company Glycerol Sigma Aldrich Glycerol propoxylate 25791-96-2propoxylate ~ (UK) Glycerol Sigma Aldrich Glycerol ethoxylate 31694-55-0ethoxylate (UK) A & E Connock Laureth-8 AEC Laureth-8 3055-98-9 (Perfumery &Cosmetics) Ltd. Nihon Emulsion Oleth-8 Emalex 508 27040-03-5Company, Ltd. Alfonic Sasol North Laureth-7 1216CO-7 3055-97-8America, Inc.EthoxylatePolyoxyethylenSteareth-7 e (7) stearyl 66146-84-7 Sigma Aldrich etherAlfonic 1012- Sasol North Deceth-6 5168-89-86.0 Ethoxylate America, Inc.Nihon Emulsion Steareth-6 Emalex 606 2420-29-3Company, Ltd. HexaethyleneHexaethylene glycol glycol Sigma- Aldrich 3055-96-7nionododecyl ether nionododecyl (UK) etherHexaethyleneHexaethylene glycol glycol Sigma-Aldrich 5168-91-2monohexadecyl ether monohexadecyl (UK) etherNikko Chemicals Beheneth-5 Nikkol BB-5 136207-49-3Co., Ltd. Myreth-5 Isoxal 12 92669-01-7 Vevy Europe SpA Jeen International Steareth-5 Jeecol SA-5 71093-13-5Corporation Nihon Emulsion Ceteth-5 Emalex 105 4478-97-1Company, Ltd. Oleth-5 Brij® 05 5353-27-5 Croda, Inc.Safol® 23E5 Sasol North Laureth-5 3055-95-6Ethoxylate America, Inc.Jeen International Steareth-4 Jeecol SA-4 59970-10-4Corporation Laureth-4 Brij® L4 5274-68-0 Croda, Inc.Homulgator 920 Grau Aromatics Myreth-4 39034-24-7 GmbH & GCompany KG Protameen Ceteth-4 Procol CA-4 5274-63-5Chemicals Oleth-4 Chemal OA-4 5353-26-4 Chemax, Inc. Oleth-4 Chenial OA-4 103622-85-1 Chemax, Inc.Aquaflex™Polyimide- 1 497926-97-3 Chemwill XL-30Polymethoxy Bicyclic Caswell No.56709-13-8 Angene Chemical Oxazolidine 494CAHydroxymethyl Angus Chemical Zoldine™ Z. T 6542-37-6 ioxoazabicyclooctane Company 5-Ethyl-l-aza- Dihydro-7a- ethyloxazolo[3,4- 3,7- Sigma Aldrich 7747-35-5dioxabicyclo[3. (UK) c] oxazole3.0]octaneRoquette Dibenzylidene Sorbitol Disorbene® 32647-67-9177. America, Inc.178. Dimethyldi benzylidene Milliken Millad® 3988 135861-56-2Sorbitol Chemicals AlfonicSasol North 179. Laureth-2 1216CO-2 3055-93-4America, Inc.Ethoxylate2-(2- Piperonyl Sigma-Aldrich 180. Butoxyethoxy)ethyl (6- 51-03-6Butoxide (UK) propyl piperonyl) etherMenthone Glycerin Frescolat®63187-91-7 Symrise 181. Acetal MGAPropylene Glycol Mackaderm68332-79-6 Rhodia Inc.182. Caprylate PGC183. Diethoxynonadiene SBB016951 67674-36-6 Ambinter Takasago Menthoxypropanedi ol184. Coolact® 10 87061-04-9 International AlcoholsCorporation 2-Diphenylmethoxy- 185. N, N- Diphenhydrami Sigma-Aldrich 147-24-0dimethylethylamine ne HQ (UK) hydrochloride3-((2- 186. ethylhexyl)oxy)propan __ 70445-33-9 __e-l,2-diol3-((2- 187. propylheptyl)oxy)propa __ __ __ne-l,2-dioll-amino-3-((2- 188. ethylhexyl)oxy)propan- __ 99509-00-92-oil-(l-Methyl-2- Di (propyleneSigma Aldrich propoxyethoxy)-2- glycol) propyl 29911-27-1189. (UK)propanol ether

[0045] The aqueous phase can also include an optional film former component. The film former component can be present in a range of from about 0.1 wt% to about 10 wt% of the emulsion, about 0.2 wt% to about 0.8 wt%, less than, equal to, or greater than about 0.1 wt%, 0.2, 0.4, 0.6, 0.8, 1, 1.5, 2, 2.5, 3, 3.5, 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5, or about 10 wl% of the emulsion.

[0046] Film formers suitable for the aqueous phase of oil-in-water perfumed emulsions include polyvinylpyrrolidone (PVP) and its copolymers, which provide excellentfilm-forming properties while maintaining water solubility. Polyvinyl alcohol offers good film formation with flexibility and water resistance upon drying. Acrylic acid polymers and copolymers, including acrylates copolymer and VA / butyl maleate / isobornyl acrylate copolymer, provide durable film formation with varying degrees of water resistance. Natural film formers such as pullulan and hydroxypropyl methylcellulose create flexible films while contributing to the overall stability of the emulsion. Polyquatemium compounds, particularly polyquaternium-11 and polyquaternium-28, offer film-forming properties while providing conditioning benefits. Sodium polystyrene sulfonate creates robust films with good adhesion properties. VP / VA copolymer provides excellent film formation with good flexibility and shine. Maltodextrin and various modified starches serve as natural alternatives for film formation. Additional effective film formers include polyimide- 1, polyurethane-35, and hydrolyzed wheat protein, which provide varying degrees of film strength and flexibility while maintaining compatibility with aqueous systems. A more specific list includes dermacryl 79 (acrylates / octylacrylamide copolymer), polyglyceryl-3 stearate / sebacate crosspolymer, polyurethanes

[0047] In some examples, the fragrance component can be encapsulated and located in the oil phase of the oil-in-water perfumed emulsion. This can be achieved through various microencapsulation techniques utilizing a diverse range of capsule wall materials. The fragrance component can be enclosed within microscopic capsules composed of materials such as polyacrylates, polyethylenes, polyamides, polystyrenes, polyisoprenes, polycarbonates, polyesters, polyureas, and polyurethanes. These polymeric materials create robust shell walls that protect the volatile compounds and provide controlled release properties. Additional encapsulation options include polysaccharides, epoxy resins, and vinyl polymers, which offer varying degrees of permeability and stability.

[0048] Cross-linked systems provide another effective approach to fragrance encapsulation, including urea cross-linked with formaldehyde or gluteraldehyde, and melamine cross-linked with formaldehyde. Natural polymer systems such as gelatinpolyphosphate coacervates (optionally cross-linked with gluteraldehyde) and gelatin-gum Arabic coacervates offer biocompatible alternatives. Other specialized encapsulation materials include cross-linked silicone fluids, polyamine reacted with polyisocyanates, and acrylate monomers polymerized via free radical polymerization. Natural protein-based materials like silk, wool, gelatin, cellulose, and various proteins can also serve as encapsulation matrices.

[0049] The encapsulated fragrance particles, can range from 1 to 50 microns, about 10 microns to about 40 microns, less than, equal to, or greater than about 1 micron, 5, 10, 15, 20, 25, 30, 35, 40, 45, or about 50 microns in diameter. They can be incorporated into the oil phase of the emulsion during the manufacturing process. This integration is achieved by dispersing the capsules in the oil phase components before emulsification with the aqueous phase. The presence of appropriate surfactants and stabilizers in the formulation helps maintain the uniform distribution of both the capsules within the oil phase and the oil phase within the continuous aqueous medium. This multi-layer protection system enhances fragrance stability, provides controlled release properties, and can improve the overall performance of the fragrance delivery system.

[0050] A viscosity of the oil-in-water perfumed emulsion can range from about 50 cP to about 1000 cP, about 100 cP to about 500 cP, less than, equal to, or greater than about 50 cP, 100, 150, 200, 250, 300, 350, 400, 450, 500, 550, 600, 650, 700, 750, 800, 850, 900, 950, or about 1000 cP. Viscosity was measured using a Brookfield Viscometer at 25 °C with Spindler RV-01 for viscosities between 100-2000 cP and Spindler RV-02 for viscosities between 100-8000 cP. Viscosities such as these allow' the oil-in-w'ater perfumed emulsion to be spray able. Thus, can be contained in a spray bottle. The oil-in-water perfumed emulsion also demonstrates exceptional stability after freeze-thaw cycles and extended storage at elevated temperatures (45 °C). The stability is demonstrated by the lack of the emulsion separating.

[0051] The oil-in-w'ater perfumed emulsion can be formed by combining the components of the aqueous phase, including any of the optional components described hereinabove. The components of the aqueous phase are stirred until the aqueous phase is well dispersed. Stirring can be accomplished with a rotor stator, or the like. The aqueous phase is then set aside. The components of the oil phase as well as any of the optional components, aside from the fragrance component, are gently mixed. The mixed components of the oil phase are heated to a temperature in a in a range of from about 70 °C to about 100 °C, about 75 °C to about 85 °C, less than, equal to, or greater than about 70 °C, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99, or about 100 °C. Once the oil phase is substantially homogenously mixed, it is cooled to a temperature in a range of from about 50 °C to about 70 °C, about 55 °C to about 65 °C, less than, equal to, or greater than about 50 °C, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, or about 70 °C. After the oil phase is cooled, the fragrance componentis added to the oil phase. Heating the oil phase allows for better mixing, but adding the fragrance component after the oil phase is cooled helps to prevent degradation of the fragrance component.

[0052] Although the aqueous phase is described as being formed first, the order is not critical. The oil phase can be prepared first. Alternatively, the oil phase and aqueous phase can be prepared simultaneously.

[0053] Once the oil phase and aqueous phase are combined they may not immediately be subjected to shearing. The mixture is subjected to shearing with a rotor stator, or the like, with the speed of rotation being slowly increased to create the oil-in-water perfumed emulsion being substantially free of air bubbles.Examples

[0054] Various aspects of the present disclosure can be better understood by reference to the following Examples which are offered by way of illustration. The present disclosure is not limited to the Examples given herein.

[0055] An oil-in-water perfumed emulsion (Formula 1) was prepared along with three comparative formulas (Comparative Formulas 1-3). Each formula included about 30 wt% of a fragrance component. The concentration of other components varied. Each formula was evaluated for stability. A formula was deemed stable if there was no visible phase separation between the oil and aqueous phase. Stability was assessed when the respective formulas were frozen and thawed, stored for 1 -month at room temperature (e.g., about 25 °C), and stored for 2-months at 45 °C.EXAMPLE 1Formula 4 Comparative Comparative Comparative INCI Name / CommercialFormula 1 Formula 2 Formula formula 1 formula 2 formula 3 name30%; 0% 2% 2%;Glycerin1.5-2.5% 1.5- 2.5% 2%Phase A Water Qsp 100% Qsp 100% 100% 100% Qsp 100%; Qsp 100% Qsp 100% Microcrystalline Cellulose 0.75% - 0.4%- 0.6% 0,8%; 0,8% 0.8% 0.8%;(and) Cellulose Gum 0.85% 0%)Polyglyceryl-6 Stearate l%-3% 0% 3-5%(and) Polyglyceryl-6 0% 0%; Behenate 3-5% 4%Glycerin (and) Glycine 0% 0%Soja (Soybean) Seed Extract(Lysofix from Lucas Meyer) 0% 0% 0% 0% 5% PEG-40 Hydrogenated 0% 4%; 0%; 0% Phase B castor oil 0% 0% 0%1-4%; 0% 0%Caprylic / capric triglyceride4-6% 5% 5%; 5%o Fragrance 10-25% 2-7%; 20% 20% 5-25%; 20% 10% 1,2 Hexanediol & Caprylyl 0.45-0.55%; 0.45- 0.45-0.55%glycol 0.45-0.55% 0.55% 0.50% 0.50%; 0.50%;0.45-0.55% 0.45- 0.45-0.55%;Hydroxyacetophenone0.45-0.55% 0.55% 0.50% 0.50% 0.50% Total 100%; 100% 100%amount 100%; 100% 100%; 100% Stabilityresults Freezing test Stable Stable Stable Stable Not stable Not stable Not stable1 month at Room Stable Stable Stable Not stable Stable Temperature Stable Not stable2 months at 45°C Stable Stable Stable Stable Not stable Not stable Stable

[0056] The terms and expressions that have been employed are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the aspects of the present disclosure. Thus, it should be understood that although the present disclosure has been specifically disclosed by specific aspects and optional features, modification and variation of the concepts herein disclosed may be resorted to by those of ordinary skill in the art, and that such modifications and variations are considered to be within the scope of aspects of the present disclosure.Exemplary Aspects.

[0057] The following exemplary aspects are provided, the numbering of which is not to be construed as designating levels of importance:

[0058] Aspect 1 provides an oil-in-water perfumed emulsion comprising:an oil phase comprising:a fragrance component ranging from about 0.01 wt% to about 45 wt% of the emulsion;a surfactant ranging from about 0.05 wt% to about 10 wt% of the emulsion; andan optional emollient ranging from about 0.1 wt% to about 15 wt% of the emulsion; andan aqueous phase comprising:an optional moisturizer component;a suspending component ranging from about 0.20 wt% to about 1.5 wt% of the emulsion; andan aqueous solvent ranging from about 25 wt% to about 99 wt% of the emulsion.

[0059] Aspect 2 provides the oil-in-water perfumed emulsion of Aspect 1, wherein the fragrance component ranges from about 2 wt% to about 35 wt% of the emulsion.

[0060] Aspect 3 provides the oil-in-water perfumed emulsion of any of Aspects 1 or 2, wherein the fragrance component comprises musk oil, civet, castoreum, ambergris, plant fragrances such as nutmeg extract, cardomon extract, ginger extract, cinnamon extract, patchouli oil, geranium oil, orange oil, mandarin oil, orange flower extract, cedarwood, vetyver, lavandin, ylang extract, tuberose extract, sandalwood oil, bergamot oil, rosemary oil, spearmint oil, peppermint oil, lemon oil, lavender oil, citronella oil, chamomille oil, clove oil, sage oil, neroli oil, labdanum oil, eucalyptus oil, verbena oil, mimosa extract, narcissus extract, carrot seed extract, jasmine extract, olibanum extract, rose extract, acetophenone, adoxal, aldehyde C-12, aldehyde C-14, aldehyde C-18, allyl caprylate, ambroxan, amyl acetate, dimethylindane derivatives, a-amylcinnamic aldehyde, anethole, anisaldehyde, benzaldehyde, benzyl acetate, benzyl alcohol and ester derivatives, benzyl propionate, benzyl salicylate, borneol, butyl acetate, camphor, carbitol, cinnamaldehyde, cinnamyl acetate, cinnamyl alcohol, cis-3-hexanol and ester derivatives, cis-3-hexenyl methyl carbonate, citral, citronellol and ester derivatives, cumin aldehyde, cyclamen aldehyde, cyclo galbanate, damascenes, decalactone, decanol, estragole, dihydromyrcenol, dimethyl benzyl carbinol, 6,8-dimethyl-2-nonanol, dimethyl benzyl carbinyl butyrate, ethyl acetate, ethyl isobutyrate, ethyl butyrate, ethyl propionate, ethyl caprylate, ethyl cinnamate, ethyl hexanoate, ethyl valerate, ethyl vanillin, eugenol, exaltolide, fenchone, fruity esters such as ethyl 2-methyl butyrate, galaxolide, geraniol and ester derivatives, helional, 2-heptonone, hexenol, a-hexylcinnamic aldehyde, hydroxycitrolnellal, indole, isoamyl acetate, isoeugenol acetate, ionones, isoeugenol, isoamyl iso-valerate, iso E super, limonene, linalool, lilial, linalyl acetate, lyral, majantol, mayol, melonal, menthol, p-methylacetophenone, methyl anthranilate, methyl cedrylone, methyl dihydrojasmonate, methyl eugenol, methyl ionone, methyl-p-naphthyl ketone, methylphenylcarbinyl acetate, mugetanol, y-nonalactone, octanal, phenyl ethyl acetate, phenyl-acetaldehyde dimethyl acetate, phenoxyethyl isobutyrate, phenyl ethyl alcohol, pinenes, sandalore, santalol, stemone, thymol, terpenes, triplal, triethyl citrate, 3,3,5-trimethylcyclohexanol, y-undecalactone, undecenal, vanillin, veloutone, verdox, or mixtures thereof.

[0061] Aspect 4 provides the oil-in-water perfumed emulsion of any of Aspects 1-3, wherein the surfactant ranges from about 0.1 wi% to about 6 wt% of the emulsion.

[0062] Aspect 5 provides the oil-in-water perfumed emulsion of any of Aspects 1-4, wherein the surfactant comprises a polyglycerol ester, a polyethylene glycol, polyglycerol ester, polypropylene glycol or a mixture thereof.

[0063] Aspect 6 provides the oil-in-water perfumed emulsion of any of Aspects 1-5, wherein the surfactant comprises polyglyceryl-6 stearate, polyglyceryl-6 behenate, polyethylene glycol 40 hydrogenated castor oil, sorbitan laurate, dilauryl citrate,■ ri(pc yglyeiayl-3 / laur l) hyd genated rilinoleaux a mixture, d’ glyceryl stearate and polyglyceryl-6 palmitate / succinate and cetearyl alcohol and dicetyl phosphate and ceteth-10 phosphate, trilaureth-4 phosphate, or a mixture thereof..

[0064] Aspect 7 provides the oil-in-water perfumed emulsion of any of Aspects 1-6, wherein the optional emollient ranges from about 0.1 wt% to about 10 wt% of the emulsion.

[0065] Aspect 8 provides the oil-in-water perfumed emulsion of any of Aspects 1-7, wherein the optional emollient comprises caprylic capric triglyceride, isopropyl myristate, isopropyl palmitate, triethyl citrate, caprylic / capric / succinic triglyceride, diisopropyl adipate, diethylhexyl malate, cetyl ethylhexanoate, ethylhexyl palmitate, ethylhexyl stearate, sismondsia chinensis (jojoba) seed oil, primus amygdalus dulcis (sweet almond) oil, olea europaea (olive) fruit oil, cocos nucifera (coconut) oil, helianthus anuus (sunflower) seed oil, argania spinosa kernel oil, persea gratissima (avocado) oil, butyrosperm um parkii (shea) buter, theobroma cacao (cocoa) seed butter, lanolin, cera alba (beeswax), copernica cerifera (carnauba) wax, isononyl isononanoate, or a mixture thereof.

[0066] Aspect 9 provides the oil-in-water perfumed emulsion of any of Aspects 1-8, wherein the optional moisturizer component ranges from about 0.1 wt% to about 6 wt% of the emulsion.

[0067] Aspect 10 provides the oil-in-water perfumed emulsion of any of Aspects 1-9, wherein the optional moisturizer component comprises glycerine, diglycerin (cas 261-605-5) and glycerin (cas 56-81-5), polyglycerin, hyaluronic acid, 1,2-hexanediol, urea, lactic acid, propylene glycol, dipropylene glycol, butylene glycol, sorbitol, propane-1, 3-diol, propanediol, caprylyl glycol, isopropene glycol, hexylene glyol, pentylene glycol, honey, ethylene glycol, polypropylene glycol, hydrolyzed collagen, sodium pea, alanine, fructose,glucose, allantoin, trimethylglycine, sodium lactate, aloe barbadensis leaf juice, or a mixture thereof.

[0068] Aspect 11 provides the oil-in-water perfumed emulsion of any of Aspects 1- 10, wherein the suspending component ranges from about 0.1 wt% to about 1.5 wt% of the emulsion.

[0069] Aspect 12 provides the oil-in-water perfumed emulsion of any of Aspects 1- 11, wherein the suspending component comprises microcrystalline cellulose, cellulose gum, or a mixture thereof.

[0070] Aspect 13 provides the oil-in-water perfumed emulsion of any of Aspects 1- 12, wherein the water further comprises a thickener component ranging from about 0.05 wt% to about 1 wt% of the emulsion.

[0071] Aspect 14 provides the oil-in-water perfumed emulsion of Aspect 13, wherein the thickener ranges from about 0.2 wt% to about 0.7 wt% of the emulsion.

[0072] Aspect 15 provides the oil-in-water perfumed emulsion of any of Aspects 13 or 14, wherein the thickener comprises ammonium acryloyldimethyltaurate / VP copolymer, carbomer, xanthan gum, diutan gum, sclerotium gum, acrylates / C 10-30 alkyl acrylate crosspolymer, or a mixture thereof.

[0073] Aspect 16 provides the oil-in-water perfumed emulsion of any of Aspects 1- 15, wherein the water phase further comprises a preservative component ranging from about 0.1 wt% to about 1 wt% of the emulsion.

[0074] Aspect 17 provides the oil-in-water perfumed emulsion of Aspect 16, wherein the preservative ranges from about 0.2 wt% to about 0.7 wt% of the emulsion.

[0075] Aspect 18 provides the oil-in-water perfumed emulsion of any of Aspects 16 or 17, wherein the preservative comprises 1,2-hexanediol, 1,2 -octanediol, hydroxy acetophenone, or a mixture thereof.

[0076] Aspect 19 provides the oil-in-water perfumed emulsion of any of Aspects 1- 18, wherein the water further comprises a modulator component ranging from about 0.05 wt% to about 10 wt% of the emulsion.

[0077] Aspect 20 provides the oil-in-water perfumed emulsion of Aspect 19, wherein the modulator ranges from about 0.1 wt% to about 0.8 wt% of the emulsion.

[0078] Aspect 21 provides the oil-in-water perfumed emulsion of any of Aspects 19 or 20, wherein the modulator comprises glucam, methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, a cyclodextrin, an acrylate, a carboxylated acrylate / octyacrylamide copolymer, Pentane- 1,2-diol, or a mixture thereof.

[0079] Aspect 22 provides the oil-in-water perfumed emulsion of any of Aspects 1- 21, wherein the water further comprises a film former component ranging from about 0.1 wt% to about 10 wt% of the emulsion.

[0080] Aspect 23 provides the oil-in-water perfumed emulsion of Aspect 22, wherein the film former ranges from about 0.2 wt% to about 0.8 wt% of the emulsion.

[0081] Aspect 24 provides the oil-in-water perfumed emulsion of any of Aspects 22 or 23,wherein the film former comprises dermacryl 79 (acrylates / octylacrylamide copolymer), polyglyceryl-3 stearate / sebacate crosspolymer, polyurethanes, or a mixture thereof.

[0082] Aspect 25 provides the oil-in-water perfumed emulsion of any of Aspects 1-24, further comprising at least one capsule dispersed in the composition.

[0083] Aspect 26 provides the oil-in-water perfumed emulsion of Aspect 25, wherein the at least one capsule comprises a fragrance component located therein.

[0084] Aspect 27 provides the oil-in-water perfumed emulsion of any of Aspects 25 or 26, wherein the at least one capsule comprises a capsule wall comprising polyacrylates; polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyureas; polyurethanes; polyolefins; polysaccharides; epoxy resins; vinyl polymers; urea cross-linked with formaldehyde or gluteraldehyde; melamine cross-linked with formaldehyde; gelatin-polyphosphate coacervates optionally cross-linked with gluteraldehyde; gelatin-gum Arabic coacervates; cross-linked silicone fluids; polyamine reacted with polyisocyanates; acrylate monomers polymerized via free radical polymerization; silk; wool; gelatine; cellulose; proteins; and combinations thereof.

[0085] Aspect 28 provides an oil-in-water perfumed emulsion comprising:an aqueous phase comprising:an aqueous phase comprising:a mixture of Microcrystalline Cellulose and Cellulose Gum in a range of from about 0.20 wt% to about 1 wt% of the emulsion; andwater; andan oil phase comprising:a mixture of polyglyceryl-6 stearate and polyglyceryl-6 behenate in a range of from about 2 wt% to about 6 wt%;a fragrance in a range of from about 2 wt% to about 40 wt% of the emulsion.

[0086] Aspect 29 provides the oil-in-water perfumed emulsion of any of Aspects 1-28, wherein the emulsion is stable following freezing and thawing, after one month, or after two months at about 45 degrees C.

[0087] Aspect 30 provides a method of making the oil-in-water perfumed emulsion of any of Aspects 1-29, the method comprising:combining components of the aqueous phase and the fragrance, wherein the components of the aqueous phase are not mixed with the fragrance;combining and dispersing the components of the oil phase, aside from the fragrance component, at a temperature in a range of from about 70 degrees C to about 100 degrees C, under high shear mixing;reducing temperature of the oil phase to about 55 degrees C to about 65 degrees C; adding the fragrance component to the cooled oil phase; andcombining the aqueous phase with the oil phase including the fragrance component.

[0088] Aspect 31 provides the oil-in-water perfumed emulsion of any of Aspects 1- 30, wherein the emulsion is sprayable.

[0089] Aspect 32 provides the oil-in-water perfumed emulsion of any of Aspects 1- 31, wherein a viscosity of the emulsion is in a range of from about 50 cP to about 1000 cP.

[0090] Aspect 33 provides the oil-in-water perfumed emulsion of any of Aspects 1- 32, wherein a viscosity of the emulsion is in a range of from about 100 cP to about 500 cP.

[0091] Aspect 34 provides a spray container having the oil-in-water perfumed emulsion of any of Aspects 1-33, disposed therein.

[0092] Aspect 35: An oil-in-water emulsion comprising:an oil phase comprising:a fragrance component ranging from about 0.01 wt% to about 45 wt% of the emulsion;a surfactant ranging from about 0.05 wt% to about 10 wt% of the emulsion; andan optional emollient ranging from about 0 wt% to about 15 wt% of the emulsion; andan aqueous phase comprising:an optional moisturizer component;a suspending component ranging from about 0.20 wt% to about 1.5 wt% of the emulsion; andan optional thickeneran aqueous solvent ranging from about 25 wt% to about 99 wt% of the emulsion.

[0093] Aspect 36: The oil-in-water emulsion of aspect 35, wherein the fragrance component ranges from about 2 wt% to about 35 wt% of the emulsion.

[0094] Aspect 37: The oil-in-water emulsion of any of aspects 35 or 36, wherein the fragrance component comprises musk oil, civet, castoreum, ambergris, plant fragrances such as nutmeg extract, cardomon extract, ginger extract, cinnamon extract, patchouli oil, geranium oil, orange oil, mandarin oil, orange flower extract, cedarwood, vetyver, lavandin,ylang extract, tuberose extract, sandalwood oil, bergamot oil, rosemary oil, spearmint oil, peppermint oil, lemon oil, lavender oil, citronella oil, chamomille oil, clove oil, sage oil, neroli oil, labdanum oil, eucalyptus oil, verbena oil, mimosa extract, narcissus extract, carrot seed extract, jasmine extract, olibanum extract, rose extract, acetophenone, adoxal, aldehyde C-12, aldehyde C-14, aldehyde C-18, allyl caprylate, ambroxan, amyl acetate, dimethylindane derivatives, a-amylcinnamic aldehyde, anethole, anisaldehyde, benzaldehyde, benzyl acetate, benzyl alcohol and ester derivatives, benzyl propionate, benzyl salicylate, borneol, butyl acetate, camphor, carbitol, cinnamaldehyde, cinnamyl acetate, cinnamyl alcohol, cis-3-hexanol and ester derivatives, cis-3-hexenyl methyl carbonate, citral, citronellol and ester derivatives, cumin aldehyde, cyclamen aldehyde, cyclo galbanate, damascenes, decalactone, decanol, estragole, dihydromyrcenol, dimethyl benzyl carbinol, 6,8-dimethyl-2-nonanol, dimethyl benzyl carbinyl butyrate, ethyl acetate, ethyl isobutyrate, ethyl butyrate, ethyl propionate, ethyl caprylate, ethyl cinnamate, ethyl hexanoate, ethyl valerate, ethyl vanillin, eugenol, exaltolide, fenchone, fruity esters such as ethyl 2-methyl butyrate, galaxolide, geraniol and ester derivatives, helional, 2-heptonone, hexenol, a-hexylcinnamic aldehyde, hydroxycitrolnellal, indole, isoamyl acetate, isoeugenol acetate, ionones, isoeugenol, isoamyl iso-valerate, iso E super, limonene, linalool, lilial, linalyl acetate, lyral, majantol, mayol, melonal, menthol, p-methylacetophenone, methyl anthranilate, methyl cedrylone, methyl dihydrojasmonate, methyl eugenol, methyl ionone, methyl-P-naphthyl ketone, methyiphenyl carbinyl acetate, mugetanol, y-nonalactone, octanal, phenyl ethyl acetate, phenyl-acetaldehyde dimethyl acetate, phenoxyethyl isobutyrate, phenyl ethyl alcohol, pinenes, sandalore, santalol, stemone, thymol, terpenes, triplal, triethyl citrate, 3,3,5-trimethylcyclohexanol, y-undecalactone, undecenal, vanillin, veloutone, verdox, or mixtures thereof.

[0095] Aspect 38: The oil-in-water emulsion of any of Aspects 35-37, wherein the surfactant ranges from about 0.1 wt% to about 6 wt% of the emulsion.

[0096] Aspect 39: The oil-in-water emulsion of any of Aspects 35-38, wherein the surfactant comprises a polyglycerol ester, a polyethylene glycol, poly glycerol ester, polyoxyethylene ether, polypropylene glycol or a mixture thereof.

[0097] Aspect 40 The oil-in-water emulsion of any of Aspects 35-38, wherein the surfactant comprises polyglyceryl-6 stearate, polyglyceryl-6 behenate, polyethylene glycol 40 hydrogenated castor oil, sorbitan laurate, dilauryl citrate, tri (polyglyceryl -3 / lauryl)hydrogenated Trilinoleate, a mixture of glyceryl tearate and polyglyceryl-6 almitate / succinate and cetearyl alcohol and dicetyl phosphate and ceteth-10 phosphate, trilaureth-4 phosphate, or a mixture thereof.

[0098] Aspect 41: The oil-in-water emulsion of any of Aspects 35-40, wherein the optional emollient ranges from about 0.1 wt% to about 10 wt% of the emulsion.

[0099] Aspect 42 The oil-in-water emulsion of any of Aspects 35-41, wherein the optional emollient comprises caprylic capric triglyceride, isopropyl myristate, isopropyl palmitate, triethyl citrate, caprylic / capric / succinic triglyceride, diisopropyl adipate, diethylhexyl malate, cetyl ethylhexanoate, ethylhexyl palmitate, ethylhexyl stearate, sismondsia chinensis (jojoba) seed oil, prunus amygdalus dulcis (sweet almond) oil, olea europaea (olive) fruit oil, cocos nucifera (coconut) oil, helianthus anuus (sunflower) seed oil, argania spinosa kernel oil, persea gratissima (avocado) oil, butyrospermum parkii (shea) butter, theobroma cacao (cocoa) seed butter, lanolin, cera alba (beeswax), copernica cerifera (carnauba) wax, isononyl isononanoate, or a mixture thereof.

[0100] Aspect 43 The oil-in-water emulsion of any of Aspects 35-42, wherein the optional moisturizer component ranges from about 0.1 wt% to about 6 wt% of the emulsion.

[0101] Aspect 44 The oil-in-water emulsion of any of Aspects 35-43, wherein the optional moisturizer component comprises glycerine, diglycerin (cas 261-605-5) and glycerin (cas 56-81-5), polyglycerin, hyaluronic acid, 1,2 -hexanediol, urea, lactic acid, propylene glycol, dipropylene glycol, butylene glycol, sorbitol, propane- 1,3-diol, propanediol, caprylyl glycol, isopropene glycol, hexylene glyol, pentylene glycol, honey, ethylene glycol, polypropylene glycol, hydrolyzed collagen, sodium pea, alanine, fructose, glucose, allantoin, trimethylglycine, sodium lactate, aloe barbadensis leaf juice, or a mixture thereof.

[0102] Aspect 45 The oil-in-water emulsion of any of Aspect 35-44, wherein the suspending component ranges from about 0.1 wt% to about 1.5 wt% of the emulsion.

[0103] Aspect 46 The oil-in-water emulsion of any of Aspect 35-45, wherein the suspending component comprises microcrystalline cellulose, cellulose gum, or a mixture thereof.

[0104] Aspect 47 The oil-in-water emulsion of any of Aspect 35-46, wherein the water further comprises optionally a thickener component ranging from about 0.05 wt% to about 1 wt% of the emulsion.

[0105] Aspect 48 The oil-in-water emulsion of Aspect 47, wherein the thickener ranges from about 0.2 wt% to about 0.7 wt% of the emulsion.

[0106] Aspect 49 The oil-in-water emulsion of any of Aspect 47 or 48, wherein the thickener comprises ammonium acryloyldimethyltaurate / VP copolymer, carbomer, xanthan gum, diutan gum, sclerotium gum, acrylates / C 10-30 alkyl acrylate crosspolymer, or a mixture thereof.

[0107] Aspect 50 The oil-in-water emulsion of any of claims Aspect 35-49, wherein the water phase further comprises a preservative component ranging from about 0.1 wt% to about 1 wt% of the emulsion.

[0108] Aspect 51 The oil-in-water emulsion of Aspect 50, wherein the preservative ranges from about 0.2 wt% to about 0.7 wt% of the emulsion.

[0109] Aspect 52 The oil-in-water emulsion of any of Aspect 50 or 51, wherein the preservative comprises 1,2-hexanediol, 1,2-octanediol, hydroxy acetophenone, or a mixture thereof.

[0110] Aspect 53 The oil-in-water emulsion of any of Aspect 35-52, wherein the water further comprises a modulator component ranging from about 0.05 wt% to about 10 wt% of the emulsion.

[0111] Aspect 54 The oil-in-water emulsion of Aspect 53, wherein the modulator ranges from about 0.1 wt% to about 0.8 wt% of the emulsion.

[0112] Aspect 55 The oil-in-water emulsion of any of claims 53 or 54, wherein the modulator comprises glucam, methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, polypropylene glycol- 10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, a cyclodextrin, an acrylate, a carboxylated acrylate / octyacrylamide copolymer, Pentane- 1,2-diol, or a mixture thereof.

[0113] Aspect 56 The oil-in-water emulsion of any of Aspect 35-55, wherein the water further comprises a film former component ranging from about 0.1 wt% to about 10 wt% of the emulsion.

[0114] Aspect 57 The oil-in-water emulsion Aspect 56, wherein the film former ranges from about 0.2 wt% to about 0.8 wt% of the emulsion.

[0115] Aspect 58 The oil-in-water emulsion of any of Aspects 56 or 57, wherein the film former comprises dermacryl 79 (acrylates / octylacrylamide copolymer), polyglyceryl-3 stearate / sebacate crosspolymer, polyurethanes, or a mixture thereof.

[0116] Aspect 59 The oil-in-water emulsion of any of Aspect 35-58, further comprising at least one capsule dispersed in the composition.

[0117] Aspect 60 The oil-in-water emulsion of Aspect 59, wherein the at least one capsule comprises a fragrance component located therein.

[0118] Aspect 61 The oil-in-water emulsion of any of Aspects 59 or 60, wherein the at least one capsule comprises a capsule wall comprising polyacrylates; polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyureas; polyurethanes; polyolefins; polysaccharides; epoxy resins; vinyl polymers; urea cross-linked with formaldehyde or gluteraldehyde; melamine cross-linked with formaldehyde; gelatin-polyphosphate coacervates optionally cross-linked with gluteraldehyde; gelatin-gum Arabic coacervates; cross-linked silicone fluids; polyamine reacted with polyisocyanates; acrylate monomers polymerized via free radical polymerization; silk; wool; gelatine; cellulose; proteins; and combinations thereof.

[0119] Aspect 62 An oil-in-water emulsion comprising:an aqueous phase comprising:glycerin in a range of from about 0.01 wt% to about 5 wt% of the emulsion;a mixture of Microcrystalline Cellulose and Cellulose Gum in a range of from about 0.20 wt% to about 1 wt% of the emulsion; andwater; andan oil phase comprising:a mixture of polyglyceryl-6 stearate and polyglyceryl-6 behenate in a range of from about 2 wt% to about 6 wt%;caprylic triglyceride in a range of from about 0.01 wt% to about 7 wt%; anda fragrance in a range of from about 5 wt% to about 40 wt% of the emulsion.

[0120] Aspect 63 The oil-in-water emulsion of any of Aspect 35-62, wherein the emulsion is stable following freezing and thawing, after one month, or after two months at about 45 degrees C.

[0121] Aspect 64 A method of making the oil-in-water emulsion of any of Aspect 35-63, the method comprising:combining components of the aqueous phase and the fragrance, wherein the components of the aqueous phase are not mixed with the fragrance;combining and dispersing the components of the oil phase, aside from the fragrance component, at a temperature in a range of from about 70 degrees C to about 100 degrees C under high shear mixing;reducing temperature of the oil phase to about 55 degrees C to about 65 degrees C;adding the fragrance component to the cooled oil phase; andcombining the aqueous phase with the oil phase including the fragrance component.

[0122] Aspect 65 The oil-in-water emulsion of any of Aspect 35-63, wherein the emulsion is sprayable.

[0123] Aspect 66 The oil-in-water emulsion of any of Aspect 35-63 and 65, wherein a viscosity of the emulsion is in a range of from about 50 cP to about 1000 cP.

[0124] Aspect 67 The oil-in-water emulsion of any of Aspect 35-63, 65 and 66, wherein a viscosity of the emulsion is in a range of from about 100 cP to about 500 cP.

[0125] Aspect 68 A spray container having the oil-in-water emulsion of any of Aspect 35-63 and 65-67, disposed therein.

Claims

1. Claims2.What is claimed is:

1. An oil-in-water emulsion comprising:4.A. an oil phase comprising:5.a. a fragrance component ranging from about 1 wt.% to about 35 wt% of the emulsion;6.b. a non-ionic surfactant ranging from about 1 wt% to about 6 wt% of the emulsion; and7.c. an optional emollient ranging from about 0 wt% to about 15 wt% of the emulsion; and8.B. an aqueous phase comprising:9.d. an optional moisturizer component;10.e. a suspending component ranging from about 0.20 wt% to about 1.5 wt% of the emulsion, wherein the suspending component is a mixture of microcrystalline cellulose and cellulose gum;11.f. an optional thickener; and12.g. at least 2.5 wt% of the emulsion of an aqueous solvent being water wt%.

2. The oil-in-water emulsion of claim 1, wherein the fragrance component ranges from about 2 wt% to about 25 wt% of the emulsion.

3. The oil-in-water emulsion of any of claims 1-2, wherein the surfactant ranges from about 2 wt% to about 4 wt% of the emulsion.

4. The oil-in-water emulsion of any of the preceding claims, wherein the surfactant is solid at room temperature.

5. The oil-in-water emulsion of any of the preceding claims, wherein the surfactant comprises a solid polyglycerol ester, a solid polyethylene glycol, a solid polyglycerol ester, a solid polyoxyethylene ether, a solid polypropylene glycol or a mixture thereof, in particular wherein the surfactant comprises polyglyceryl-6 stearate (and) polyglyceryl-6 behenate (Tegocare PBS 6), polyethylene glycol 40 hydrogenated castor oil (PEG-40 Hydrogenated Castor Oil), sorbitan laurate, dilauryl citrate, tri(polyglyceryl-3 / lauryl) hydrogenated Trilinoleate, glyceryl stearate (and) polyglyceryl-6 palmitate / succinate (and) cetearyl alcohol or a mixture thereof.

6. The oil-in- water emulsion of any of the preceding claims, wherein the suspending component ranges from about 0.4 wt% to about 0.8 wt% of the emulsion.

7. The oil-in-water emulsion of any of claims 1-6, wherein the water phase further comprises optionally a thickener component ranging from about 0.05 wt% to about 1 wt% of the emulsion, preferably from about 0.2 wt% to about 0.7 wt% of the emulsion.

8. The oil-in-water emulsion of claim 7, wherein the thickener comprises ammonium acryloyldimethyltaurate / VP copolymer, carbomer, xanthan gum, diutan gum, sclerotium gum, acrylates / C 10-30 alkyl acrylate crosspolymer, or a mixture thereof.

9. The oil-in-water emulsion of any of claims 1 -8, wherein the water phase further comprises a preservative component ranging from about 0.1 wt% to about 1 wt% of the emulsion, preferably from about 0.2 wt% to about 0.7 wt% of the emulsion.

10. The oil-in-water emulsion of claim 9, wherein the preservative comprises 1,2- hexanediol, 1,2-octanediol, hydroxy acetophenone, or a mixture thereof.

11. The oil-in- water emulsion of any of claims 1-10, wherein the water further comprises a modulator component ranging from about 0.05 wt% to about 10 wt% of the emulsion, preferably from about 0.1 wt% to about 0.8 wt% of the emulsion.

12. The oil-in-water emulsion of claim 11, wherein the modulator comprises glucam, methyl glucoside polyol, ethyl glucoside polyol, propyl glucoside polyol, polypropylene glycol-10 methyl glucose ether, ethoxylated methyl glucose ether, polypropylene glycol-20 methyl glucose ether, caprylyl, capryl glucoside, undecyl glucoside, a cyclodextrin, an acrylate, a carboxylated acrylate / octyacrylamide copolymer, Pentane- 1,2-diol, or a mixture thereof.

13. The oil-in-water emulsion of any of claims 1-12, wherein the water further comprises a film former component ranging from about 0.1 wt% to about 10 wt% of the emulsion, preferably from about 0.2 wt% to about 0.8 wt% of the emulsion.

14. The oil-in-water emulsion of claim 13, wherein the film former comprises dermacryl 79 (acrylates / octylacrylamide copolymer), polyglyceryl-3 stearate / sebacate crosspolymer, polyurethanes, or a mixture thereof.

15. The oil-in-water emulsion of any of claims 1-14, further comprising at least one capsule dispersed in the composition, preferably wherein the at least one capsule comprises a fragrance component located therein.

16. An oil-in-water emulsion of any of the preceding claims comprising:26.A. an aqueous phase comprising:27.a.glycerin in a range of from about 0.01 wt% to about 5 wt% of the emulsion;28.b. a mixture of Microcrystalline Cellulose and Cellulose in a range of from about 0.20 wt% to about 1.5 wt% of the emulsion; and29.c. water; and30.B. an oil phase comprising:31.d. a mixture of polyglyceryl -6 stearate and poly glyceryl -6 behenate in a range of from about 2 wt% to about 6 wt%;32.e. caprylic triglyceride in a range of from about 0.01 wt% to about 7 wt%; and33.f. a fragrance in a range of from about 2 wt% to about 25 wt% of the emulsion.

17. The oil-in-water emulsion of any of claims 1 -16, wherein the emulsion is sprayable.

18. The oil-in-water emulsion of any of claims 1-17, wherein a viscosity of the emulsion is in a range of from about 50 cP to about 1000 cP, preferably in a range of from about 100 cP to about 500 cP.

19. A method of making the oil-in-water emulsion of any of claims 1-18, the method comprising:36.combining components of the aqueous phase and the fragrance, wherein the components of the aqueous phase are not mixed with the fragrance;37.combining and dispersing the components of the oil phase, aside from the fragrance component, at a temperature in a range of from about 70 degrees C to about 100 degrees C under high shear mixing;38.reducing temperature of the oil phase to about 55 degrees C to about 65 degrees C; adding the fragrance component to the cooled oil phase; and39.combining the aqueous phase with the oil phase including the fragrance component.

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