Method for manufacturing pre-lithiated negative electrode and lithium secondary battery comprising pre-lithiated negative electrode manufactured thereby

By controlling the moisture content of the cathode active material layer to form a lithium oxide layer, the pre-lithiation process in lithium-ion batteries is optimized to reduce lithium nitride formation and enhance battery performance.

WO2026141978A1PCT designated stage Publication Date: 2026-07-02LG ENERGY SOLUTION LTD

Patent Information

Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
LG ENERGY SOLUTION LTD
Filing Date
2025-11-19
Publication Date
2026-07-02

AI Technical Summary

Technical Problem

The formation of by-products, particularly lithium nitride, during the pre-lithiation process in lithium-ion batteries leads to lithium loss and degrades battery performance due to the formation of a resistive layer at the cathode potential, which is not effectively addressed by existing methods.

Method used

A method for manufacturing a pre-lithiated cathode by controlling the moisture content of the cathode active material layer to form a lithium oxide layer, which acts as a buffer to slow down the pre-lithiation reaction rate and suppress the formation of lithium nitride, thereby reducing lithium loss and improving battery performance.

Benefits of technology

The method effectively minimizes lithium loss and suppresses the formation of lithium nitride, leading to lower resistive layers and improved battery performance by controlling the pre-lithiation reaction rate and heat generation.

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Abstract

The present invention relates to a method for manufacturing a pre-lithiated negative electrode capable of suppressing formation of by-products during a pre-lithiation process, and to a lithium secondary battery comprising the pre-lithiated negative electrode manufactured thereby. The method comprises the steps of: preparing a negative electrode including a negative electrode active material layer having a moisture content of 800 ppm or more on at least one surface of a negative electrode current collector layer; and contacting a transfer laminate including a lithium metal layer and a substrate layer with one surface of the negative electrode active material layer such that the lithium metal layer faces the negative electrode active material layer.
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