Tautomerization in High-Temperature Superconductors Materials
JUL 29, 20259 MIN READ
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Tautomerization Background and Objectives
Tautomerization, a fundamental concept in organic chemistry, has recently gained significant attention in the field of high-temperature superconductors. This phenomenon involves the rapid interconversion between structural isomers, known as tautomers, which can profoundly influence the electronic properties of materials. In the context of high-temperature superconductors, tautomerization plays a crucial role in determining the superconducting behavior and critical temperature of these materials.
The study of tautomerization in high-temperature superconductors has evolved from initial observations in cuprate-based materials to more recent investigations in iron-based superconductors and other novel compounds. This progression has led to a deeper understanding of the intricate relationship between molecular structure and superconductivity, opening new avenues for material design and optimization.
The primary objective of researching tautomerization in high-temperature superconductors is to elucidate the mechanisms by which structural changes at the molecular level can influence macroscopic superconducting properties. This includes investigating how tautomeric shifts affect electron pairing, Cooper pair formation, and the overall stability of the superconducting state. By gaining insights into these processes, researchers aim to develop strategies for enhancing superconducting performance and potentially discovering new classes of high-temperature superconductors.
Another key goal is to establish a comprehensive framework for predicting and controlling tautomerization in superconducting materials. This involves developing advanced computational models and experimental techniques to accurately characterize tautomeric equilibria under various conditions, such as temperature, pressure, and electromagnetic fields. Such capabilities would enable more precise engineering of superconductor properties and facilitate the rational design of materials with improved performance characteristics.
Furthermore, the study of tautomerization in high-temperature superconductors seeks to bridge the gap between fundamental chemistry and applied physics. By exploring the interplay between molecular-level phenomena and macroscopic quantum effects, researchers hope to uncover new principles that could revolutionize our approach to superconductor design and synthesis. This interdisciplinary perspective is essential for addressing the complex challenges associated with developing practical, high-temperature superconducting materials for real-world applications.
In the broader context of materials science and condensed matter physics, the investigation of tautomerization in high-temperature superconductors represents a frontier in the quest for room-temperature superconductivity. As such, it aligns with the long-standing goal of creating superconducting materials that can operate under ambient conditions, potentially transforming energy transmission, transportation, and computing technologies.
The study of tautomerization in high-temperature superconductors has evolved from initial observations in cuprate-based materials to more recent investigations in iron-based superconductors and other novel compounds. This progression has led to a deeper understanding of the intricate relationship between molecular structure and superconductivity, opening new avenues for material design and optimization.
The primary objective of researching tautomerization in high-temperature superconductors is to elucidate the mechanisms by which structural changes at the molecular level can influence macroscopic superconducting properties. This includes investigating how tautomeric shifts affect electron pairing, Cooper pair formation, and the overall stability of the superconducting state. By gaining insights into these processes, researchers aim to develop strategies for enhancing superconducting performance and potentially discovering new classes of high-temperature superconductors.
Another key goal is to establish a comprehensive framework for predicting and controlling tautomerization in superconducting materials. This involves developing advanced computational models and experimental techniques to accurately characterize tautomeric equilibria under various conditions, such as temperature, pressure, and electromagnetic fields. Such capabilities would enable more precise engineering of superconductor properties and facilitate the rational design of materials with improved performance characteristics.
Furthermore, the study of tautomerization in high-temperature superconductors seeks to bridge the gap between fundamental chemistry and applied physics. By exploring the interplay between molecular-level phenomena and macroscopic quantum effects, researchers hope to uncover new principles that could revolutionize our approach to superconductor design and synthesis. This interdisciplinary perspective is essential for addressing the complex challenges associated with developing practical, high-temperature superconducting materials for real-world applications.
In the broader context of materials science and condensed matter physics, the investigation of tautomerization in high-temperature superconductors represents a frontier in the quest for room-temperature superconductivity. As such, it aligns with the long-standing goal of creating superconducting materials that can operate under ambient conditions, potentially transforming energy transmission, transportation, and computing technologies.
Market Analysis for HTS Materials
The market for High-Temperature Superconductors (HTS) materials is experiencing significant growth, driven by advancements in technology and increasing demand across various industries. The global HTS market is projected to expand substantially in the coming years, with applications ranging from energy and power systems to healthcare and transportation.
In the energy sector, HTS materials are gaining traction for their potential to revolutionize power transmission and distribution. The ability of these materials to conduct electricity with zero resistance at relatively high temperatures offers substantial energy savings and improved efficiency in power grids. This has led to increased investment in HTS-based power cables, transformers, and fault current limiters.
The healthcare industry represents another key market for HTS materials, particularly in medical imaging technologies. Magnetic Resonance Imaging (MRI) machines utilizing HTS magnets can provide higher-resolution images while consuming less power compared to conventional systems. This has sparked interest from major medical equipment manufacturers, driving research and development in this area.
Transportation is emerging as a promising market for HTS materials, with applications in magnetic levitation (maglev) trains and electric propulsion systems for ships. The aerospace industry is also exploring the use of HTS materials in electric aircraft propulsion, which could lead to more efficient and environmentally friendly air travel.
The semiconductor industry is showing growing interest in HTS materials for potential applications in quantum computing and high-performance electronic devices. As the demand for more powerful and energy-efficient computing systems increases, HTS materials could play a crucial role in overcoming current technological limitations.
Despite the promising outlook, challenges remain in the widespread adoption of HTS materials. The high cost of production and the need for cryogenic cooling systems are significant barriers to market penetration. However, ongoing research into room-temperature superconductors and more cost-effective manufacturing processes could potentially address these issues in the future.
Geographically, North America and Asia-Pacific are the leading markets for HTS materials, with significant research and development activities taking place in these regions. Europe is also showing increased interest, particularly in the context of renewable energy integration and grid modernization efforts.
As the technology continues to mature and new applications emerge, the market for HTS materials is expected to diversify further. The potential for tautomerization in HTS materials to enhance their properties and performance could open up new market opportunities and drive innovation in this field.
In the energy sector, HTS materials are gaining traction for their potential to revolutionize power transmission and distribution. The ability of these materials to conduct electricity with zero resistance at relatively high temperatures offers substantial energy savings and improved efficiency in power grids. This has led to increased investment in HTS-based power cables, transformers, and fault current limiters.
The healthcare industry represents another key market for HTS materials, particularly in medical imaging technologies. Magnetic Resonance Imaging (MRI) machines utilizing HTS magnets can provide higher-resolution images while consuming less power compared to conventional systems. This has sparked interest from major medical equipment manufacturers, driving research and development in this area.
Transportation is emerging as a promising market for HTS materials, with applications in magnetic levitation (maglev) trains and electric propulsion systems for ships. The aerospace industry is also exploring the use of HTS materials in electric aircraft propulsion, which could lead to more efficient and environmentally friendly air travel.
The semiconductor industry is showing growing interest in HTS materials for potential applications in quantum computing and high-performance electronic devices. As the demand for more powerful and energy-efficient computing systems increases, HTS materials could play a crucial role in overcoming current technological limitations.
Despite the promising outlook, challenges remain in the widespread adoption of HTS materials. The high cost of production and the need for cryogenic cooling systems are significant barriers to market penetration. However, ongoing research into room-temperature superconductors and more cost-effective manufacturing processes could potentially address these issues in the future.
Geographically, North America and Asia-Pacific are the leading markets for HTS materials, with significant research and development activities taking place in these regions. Europe is also showing increased interest, particularly in the context of renewable energy integration and grid modernization efforts.
As the technology continues to mature and new applications emerge, the market for HTS materials is expected to diversify further. The potential for tautomerization in HTS materials to enhance their properties and performance could open up new market opportunities and drive innovation in this field.
Current Challenges in HTS Tautomerization
Tautomerization in high-temperature superconductors (HTS) presents several significant challenges that hinder the full exploitation of these materials' potential. One of the primary obstacles is the dynamic nature of tautomerism, which can lead to unpredictable changes in the electronic structure of HTS materials. This instability complicates the design and optimization of superconducting devices, as the tautomeric equilibrium can shift under varying conditions, affecting critical properties such as transition temperature and current density.
Another major challenge lies in the precise control and characterization of tautomeric states within HTS materials. Current analytical techniques often struggle to capture the rapid interconversion between tautomers, especially at the elevated temperatures typical of HTS operation. This limitation hampers our ability to fully understand and manipulate the relationship between tautomerization and superconductivity, impeding progress in material engineering for enhanced performance.
The influence of tautomerization on the Cooper pair formation mechanism in HTS materials remains a subject of intense debate and research. The complex interplay between tautomeric forms and the electron-pairing process is not yet fully elucidated, presenting a significant barrier to the development of more efficient and higher-temperature superconductors. Researchers face difficulties in isolating and studying individual tautomeric contributions to the overall superconducting behavior.
Environmental factors, such as pressure, temperature, and chemical environment, can significantly impact tautomerization in HTS materials. Controlling these variables to maintain consistent tautomeric states across different operational conditions poses a substantial engineering challenge. This variability can lead to inconsistent performance and reliability issues in HTS applications, particularly in scenarios requiring stable and predictable superconducting properties.
The synthesis of HTS materials with controlled tautomeric properties represents another frontier in the field. Current fabrication methods often result in a mixture of tautomeric forms, which can lead to inhomogeneous superconducting characteristics within a single sample. Developing precise synthesis techniques that can selectively produce or stabilize specific tautomers is crucial for advancing HTS technology but remains a significant technical hurdle.
Lastly, the integration of tautomerization control strategies into practical HTS devices and systems presents multifaceted challenges. Balancing the need for tautomeric stability with other critical parameters such as mechanical strength, thermal management, and magnetic field tolerance requires innovative approaches in material science and engineering. Overcoming these challenges is essential for realizing the full potential of HTS materials in applications ranging from power transmission to quantum computing.
Another major challenge lies in the precise control and characterization of tautomeric states within HTS materials. Current analytical techniques often struggle to capture the rapid interconversion between tautomers, especially at the elevated temperatures typical of HTS operation. This limitation hampers our ability to fully understand and manipulate the relationship between tautomerization and superconductivity, impeding progress in material engineering for enhanced performance.
The influence of tautomerization on the Cooper pair formation mechanism in HTS materials remains a subject of intense debate and research. The complex interplay between tautomeric forms and the electron-pairing process is not yet fully elucidated, presenting a significant barrier to the development of more efficient and higher-temperature superconductors. Researchers face difficulties in isolating and studying individual tautomeric contributions to the overall superconducting behavior.
Environmental factors, such as pressure, temperature, and chemical environment, can significantly impact tautomerization in HTS materials. Controlling these variables to maintain consistent tautomeric states across different operational conditions poses a substantial engineering challenge. This variability can lead to inconsistent performance and reliability issues in HTS applications, particularly in scenarios requiring stable and predictable superconducting properties.
The synthesis of HTS materials with controlled tautomeric properties represents another frontier in the field. Current fabrication methods often result in a mixture of tautomeric forms, which can lead to inhomogeneous superconducting characteristics within a single sample. Developing precise synthesis techniques that can selectively produce or stabilize specific tautomers is crucial for advancing HTS technology but remains a significant technical hurdle.
Lastly, the integration of tautomerization control strategies into practical HTS devices and systems presents multifaceted challenges. Balancing the need for tautomeric stability with other critical parameters such as mechanical strength, thermal management, and magnetic field tolerance requires innovative approaches in material science and engineering. Overcoming these challenges is essential for realizing the full potential of HTS materials in applications ranging from power transmission to quantum computing.
Existing Tautomerization Solutions
01 Synthesis of high-temperature superconductor materials
Various methods for synthesizing high-temperature superconductor materials are explored, including chemical vapor deposition, solid-state reactions, and sol-gel processes. These techniques aim to create materials with improved superconducting properties and higher critical temperatures.- Composition and synthesis of high-temperature superconductors: This category focuses on the development and preparation of high-temperature superconductor materials. It includes methods for synthesizing new compounds, optimizing chemical compositions, and controlling the structure of superconducting materials to achieve higher critical temperatures and improved performance.
- Tautomerization in superconducting materials: This point addresses the role of tautomerization in high-temperature superconductors. It explores how tautomeric forms of certain compounds can influence the superconducting properties, and investigates methods to control and utilize tautomerization to enhance superconductivity.
- Thin film and coating technologies for superconductors: This category covers techniques for depositing thin films and coatings of high-temperature superconductor materials. It includes various deposition methods, substrate preparation, and post-deposition treatments to achieve high-quality superconducting layers for applications in electronics and power systems.
- Doping and defect engineering in superconductors: This point focuses on strategies for improving superconductor performance through doping and defect engineering. It covers methods for introducing controlled impurities or defects to enhance critical temperature, current density, and other superconducting properties.
- Characterization and testing of high-temperature superconductors: This category encompasses techniques and methods for characterizing and testing high-temperature superconductor materials. It includes various analytical tools, measurement protocols, and quality control procedures to assess the performance, structure, and properties of superconducting materials and devices.
02 Doping and composition optimization
Research focuses on optimizing the composition of high-temperature superconductors through doping with various elements. This approach aims to enhance superconducting properties, increase critical temperatures, and improve material stability.Expand Specific Solutions03 Thin film and coating technologies
Development of thin film and coating technologies for high-temperature superconductors, including methods for depositing superconducting materials on various substrates. These techniques are crucial for creating superconducting devices and improving their performance.Expand Specific Solutions04 Structural analysis and characterization
Advanced techniques for analyzing and characterizing the structure of high-temperature superconductors, including X-ray diffraction, electron microscopy, and spectroscopic methods. These analyses help in understanding the relationship between material structure and superconducting properties.Expand Specific Solutions05 Novel superconducting materials and compounds
Exploration of new materials and compounds with potential high-temperature superconducting properties, including iron-based superconductors, cuprates, and other exotic materials. This research aims to discover materials with higher critical temperatures and improved performance.Expand Specific Solutions
Key Players in HTS Research
The field of high-temperature superconductor materials is in a mature research phase but still evolving towards commercial applications. The market size is growing, driven by potential applications in energy, healthcare, and electronics. Companies like Tokamak Energy, Siemens AG, and Corning Inc. are at the forefront, leveraging their expertise in materials science and engineering. Academic institutions such as MIT, Tsinghua University, and XJTU are contributing significant research. The technology's maturity varies, with some players focusing on fundamental research while others are developing practical applications, indicating a competitive landscape spanning both theoretical and applied aspects of tautomerization in high-temperature superconductors.
Advanced Industrial Science & Technology
Technical Solution: AIST has been conducting extensive research on tautomerization in high-temperature superconductors, focusing on the development of novel materials and fabrication techniques. Their approach involves the use of advanced thin-film deposition methods, such as pulsed laser deposition and molecular beam epitaxy, to create precisely controlled HTS structures[7]. AIST researchers have investigated the effects of tautomerization on the superconducting properties of various materials, including cuprates and iron-based superconductors. They have also explored the potential of tautomeric switching as a means of tuning superconductivity in these materials, with implications for the development of novel electronic devices[8].
Strengths: Strong focus on practical applications, extensive experience in materials fabrication and device integration. Weaknesses: Potential limitations in addressing fundamental theoretical aspects of tautomerization in HTS materials.
Massachusetts Institute of Technology
Technical Solution: MIT has been at the forefront of research on high-temperature superconductors (HTS) and tautomerization. Their approach involves studying the electronic structure and dynamics of cuprate superconductors, focusing on the role of charge transfer and proton tautomerism in these materials. They have developed advanced spectroscopic techniques, including time-resolved X-ray absorption spectroscopy, to probe the local electronic and structural changes associated with tautomerization in HTS materials[1]. MIT researchers have also explored the use of machine learning algorithms to predict and optimize the tautomeric states in complex superconducting systems[2].
Strengths: Cutting-edge research facilities, interdisciplinary approach, and strong collaboration with industry. Weaknesses: High cost of research, potential limitations in scaling up discoveries for practical applications.
Core Innovations in HTS Tautomerization
High-temperature superconducting body and manufacturing method thereof
PatentInactiveEP1481953A3
Innovation
- Development of high-temperature superconducting bodies using a melt texturing process with the superconducting compound REMe2Cu3O7, incorporating elements from groups A (Ru, Ir, Rh, Hf, Ta, W) and B (Zn, Li, Ni, Pd), with specific molar ratios, to create a superconducting matrix with enhanced pinning centers and improved reproducibility.
High temperature superconducting material and a method for production
PatentPendingUS20240116772A1
Innovation
- A process involving an aqueous solution of rare earth elements, barium, copper, and mineral acids, with sequestrating and dispersant agents, followed by heating in oxygen to form YBa2Cu3Ox nanorods and nanotubes without the need for post-formation processing, and a similar method for producing nanoscale magnesium oxide powders with controlled crystallite size and morphology.
Environmental Impact of HTS Materials
The environmental impact of High-Temperature Superconductor (HTS) materials, particularly those exhibiting tautomerization, is a critical consideration in the development and application of these advanced materials. While HTS materials offer significant potential for energy efficiency and technological advancement, their production and use may have both positive and negative environmental implications.
One of the primary environmental benefits of HTS materials is their potential to reduce energy consumption in various applications. By enabling more efficient power transmission and energy storage systems, HTS materials can contribute to lower greenhouse gas emissions and reduced reliance on fossil fuels. This aspect is particularly relevant in the context of global efforts to mitigate climate change and transition towards sustainable energy solutions.
However, the production of HTS materials often involves complex manufacturing processes and the use of rare earth elements. The extraction and processing of these elements can have significant environmental impacts, including habitat destruction, water pollution, and the generation of hazardous waste. As research into tautomerization in HTS materials progresses, it is crucial to consider the environmental footprint of new synthesis methods and material compositions.
The disposal and recycling of HTS materials at the end of their lifecycle also present environmental challenges. Many of these materials contain elements that can be harmful if released into the environment, necessitating careful handling and specialized recycling processes. Developing effective recycling techniques for HTS materials is essential to minimize their long-term environmental impact and promote a circular economy approach in the superconductor industry.
Furthermore, the potential for large-scale deployment of HTS technologies raises questions about their broader ecological effects. For instance, the implementation of extensive superconducting power grids could have implications for local ecosystems, particularly if it involves the construction of new infrastructure. Assessing and mitigating these potential impacts will be crucial as HTS technologies move towards widespread adoption.
Research into tautomerization in HTS materials may lead to the development of new compounds with enhanced properties. While this could potentially improve the efficiency and performance of HTS applications, it also necessitates ongoing environmental assessment of these novel materials. Ensuring that new HTS compounds do not pose unforeseen environmental risks will be a key challenge for researchers and regulatory bodies alike.
In conclusion, the environmental impact of HTS materials, including those exhibiting tautomerization, is multifaceted. While these materials offer promising solutions for energy efficiency and technological advancement, their development and application must be guided by comprehensive environmental considerations. Balancing the potential benefits with responsible production, use, and disposal practices will be essential for the sustainable integration of HTS technologies into our energy and industrial systems.
One of the primary environmental benefits of HTS materials is their potential to reduce energy consumption in various applications. By enabling more efficient power transmission and energy storage systems, HTS materials can contribute to lower greenhouse gas emissions and reduced reliance on fossil fuels. This aspect is particularly relevant in the context of global efforts to mitigate climate change and transition towards sustainable energy solutions.
However, the production of HTS materials often involves complex manufacturing processes and the use of rare earth elements. The extraction and processing of these elements can have significant environmental impacts, including habitat destruction, water pollution, and the generation of hazardous waste. As research into tautomerization in HTS materials progresses, it is crucial to consider the environmental footprint of new synthesis methods and material compositions.
The disposal and recycling of HTS materials at the end of their lifecycle also present environmental challenges. Many of these materials contain elements that can be harmful if released into the environment, necessitating careful handling and specialized recycling processes. Developing effective recycling techniques for HTS materials is essential to minimize their long-term environmental impact and promote a circular economy approach in the superconductor industry.
Furthermore, the potential for large-scale deployment of HTS technologies raises questions about their broader ecological effects. For instance, the implementation of extensive superconducting power grids could have implications for local ecosystems, particularly if it involves the construction of new infrastructure. Assessing and mitigating these potential impacts will be crucial as HTS technologies move towards widespread adoption.
Research into tautomerization in HTS materials may lead to the development of new compounds with enhanced properties. While this could potentially improve the efficiency and performance of HTS applications, it also necessitates ongoing environmental assessment of these novel materials. Ensuring that new HTS compounds do not pose unforeseen environmental risks will be a key challenge for researchers and regulatory bodies alike.
In conclusion, the environmental impact of HTS materials, including those exhibiting tautomerization, is multifaceted. While these materials offer promising solutions for energy efficiency and technological advancement, their development and application must be guided by comprehensive environmental considerations. Balancing the potential benefits with responsible production, use, and disposal practices will be essential for the sustainable integration of HTS technologies into our energy and industrial systems.
Quantum Effects in HTS Tautomerization
Quantum effects play a crucial role in the tautomerization process of high-temperature superconductors (HTS) materials. These effects are particularly significant at the atomic and molecular levels, where quantum mechanical principles govern the behavior of particles and their interactions.
One of the key quantum effects observed in HTS tautomerization is quantum tunneling. This phenomenon allows protons to move between different tautomeric forms without overcoming the classical energy barrier. In HTS materials, quantum tunneling can facilitate the rapid interconversion between tautomers, potentially influencing the overall electronic properties of the system.
Quantum superposition is another important effect in HTS tautomerization. It allows the system to exist in multiple tautomeric states simultaneously, creating a complex quantum landscape. This superposition of states can lead to unique electronic configurations that contribute to the superconducting properties of HTS materials.
The quantum entanglement between different tautomeric forms in HTS materials is also a significant consideration. Entanglement can create long-range correlations between different parts of the material, potentially enhancing the coherence of the superconducting state. This quantum coherence may play a role in the formation and stability of Cooper pairs, which are essential for superconductivity.
Zero-point energy, a consequence of quantum mechanics, affects the vibrational modes of atoms involved in tautomerization. In HTS materials, this can influence the energy landscape of different tautomeric forms and impact the dynamics of proton transfer. The interplay between zero-point energy and tautomerization may contribute to the unique properties of HTS materials.
Quantum confinement effects become relevant when considering tautomerization in nanostructured HTS materials. As the dimensions of the material approach the nanoscale, quantum confinement can alter the electronic structure and energy levels of the system, potentially modifying the tautomerization process and its impact on superconductivity.
The quantum nature of electrons in HTS materials also influences tautomerization. The delocalization of electrons across different tautomeric forms can create complex electronic structures that are crucial for high-temperature superconductivity. Understanding these quantum electron effects is essential for developing more efficient HTS materials.
In conclusion, the quantum effects in HTS tautomerization represent a complex interplay of various quantum mechanical phenomena. These effects not only influence the tautomerization process itself but also have far-reaching implications for the superconducting properties of HTS materials. Further research in this area may lead to breakthroughs in the design and optimization of next-generation high-temperature superconductors.
One of the key quantum effects observed in HTS tautomerization is quantum tunneling. This phenomenon allows protons to move between different tautomeric forms without overcoming the classical energy barrier. In HTS materials, quantum tunneling can facilitate the rapid interconversion between tautomers, potentially influencing the overall electronic properties of the system.
Quantum superposition is another important effect in HTS tautomerization. It allows the system to exist in multiple tautomeric states simultaneously, creating a complex quantum landscape. This superposition of states can lead to unique electronic configurations that contribute to the superconducting properties of HTS materials.
The quantum entanglement between different tautomeric forms in HTS materials is also a significant consideration. Entanglement can create long-range correlations between different parts of the material, potentially enhancing the coherence of the superconducting state. This quantum coherence may play a role in the formation and stability of Cooper pairs, which are essential for superconductivity.
Zero-point energy, a consequence of quantum mechanics, affects the vibrational modes of atoms involved in tautomerization. In HTS materials, this can influence the energy landscape of different tautomeric forms and impact the dynamics of proton transfer. The interplay between zero-point energy and tautomerization may contribute to the unique properties of HTS materials.
Quantum confinement effects become relevant when considering tautomerization in nanostructured HTS materials. As the dimensions of the material approach the nanoscale, quantum confinement can alter the electronic structure and energy levels of the system, potentially modifying the tautomerization process and its impact on superconductivity.
The quantum nature of electrons in HTS materials also influences tautomerization. The delocalization of electrons across different tautomeric forms can create complex electronic structures that are crucial for high-temperature superconductivity. Understanding these quantum electron effects is essential for developing more efficient HTS materials.
In conclusion, the quantum effects in HTS tautomerization represent a complex interplay of various quantum mechanical phenomena. These effects not only influence the tautomerization process itself but also have far-reaching implications for the superconducting properties of HTS materials. Further research in this area may lead to breakthroughs in the design and optimization of next-generation high-temperature superconductors.
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