Method, system, equipment and storage medium for predicting and evaluating the hydrogen generation potential of rocks

By establishing the relationship between the Fe3+/FeTot ratio of hydrogen source rocks and the degree of serpentinization, and using the fitting analysis method to predict and evaluate the hydrogen generation potential of hydrogen source rocks, the problems of prediction and evaluation difficulties in existing technologies are solved, and reliable hydrogen resource evaluation is achieved.

CN119418810BActive Publication Date: 2025-10-03PETROCHINA CO LTD
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Patent Information

Application Number
CN202411461478.4
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-10-18
Publication Date
2025-10-03
Estimated Expiration
2044-10-18

AI Technical Summary

Technical Problem

The existing technology lacks reliable methods to predict and evaluate the hydrogen generation potential of hydrogen source rocks, especially in areas with low research level and lack of basic data, resulting in unclear hydrogen resource potential.

Method used

By establishing the relationship between the Fe3+/FeTot ratio and the degree of serpentinization in hydrogen source rocks, the degree of serpentinization of rocks is calculated using the fitting analysis method. Based on the relationship between hydrogen generation potential and serpentinization degree, the hydrogen generation potential of rocks is predicted and evaluated.

Benefits of technology

It provides a reliable method to predict and evaluate the hydrogen generation potential of hydrogen source rocks, solves the prediction problem in areas with low research level and lack of basic data, and provides reliable basic data for hydrogen resource evaluation.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention relates to a method, system, device and storage medium for predicting and evaluating the hydrogen generation potential of rocks, which belongs to the field of hydrogen source rock evaluation technology. The method includes the following steps: 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the serpentinization degree is used to calculate the serpentinization degree of the rocks in the study area; based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree, the hydrogen generation potential of the rocks in the study area is predicted. 3+ / Fe Tot The ratio is used to calculate the prediction of the hydrogen generation potential of rocks in the study area, which solves the problem of difficulty in predicting and rating the hydrogen generation potential of rocks in areas with low research level and lack of basic data, and provides more reliable basic data for the research on the hydrogen generation potential of hydrogen source rocks and hydrogen resource evaluation.
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Description

Technical Field

[0001] The present invention belongs to the technical field of hydrogen source rock evaluation, and in particular relates to a method, system, equipment and storage medium for predicting and evaluating the hydrogen generation potential of rocks. Background Art

[0002] Hydrogen source rock refers to the rock that can produce hydrogen through water-rock reaction underground, which contains Fe-rich 2+ Basic and ultrabasic rocks containing the mineral olivine are among the most important hydrogen source rocks. Serpentinization is one of the primary causes of natural hydrogen. Iron-rich minerals in rocks react with water under certain temperatures and pressures to produce hydrogen. The degree of serpentinization determines the rock's hydrogen production potential. However, the exploration and evaluation of natural hydrogen is in its infancy. Currently, there are no mature and reliable methods for predicting and evaluating the hydrogen production potential of hydrogen source rocks. Furthermore, most areas are understudied, basic data is scarce, and the potential of hydrogen resources is unknown.

[0003] During the process of hydrogen generation from serpentinization of hydrogen source rocks, the Fe-rich 2+ Minerals react with water under certain temperature and pressure, and the Fe in the minerals 2+ Converted to Fe 3+ , water is decomposed to generate hydrogen, and as the reaction proceeds, Fe 3+ Total iron (Fe Tot ) will gradually increase. Therefore, we can establish the relationship between the serpentinization degree of hydrogen source rock and the rock Fe 3+ / Fe Tot The relationship between Fe and 3+ / Fe Tot The degree of serpentinization of hydrogen source rocks is estimated, and then the hydrogen generation potential of hydrogen source rocks in the study area is predicted and evaluated. Summary of the Invention

[0004] In response to the above problems, the present invention provides a method, system, equipment and storage medium for predicting and evaluating the hydrogen generation potential of rocks.

[0005] A first object of the present invention is to provide a method for predicting the hydrogen generation potential of rocks, comprising:

[0006] According to the rock Fe 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is used to calculate the degree of serpentinization of the rocks in the study area. 3+ / Fe Tot The ratio is Fe in rock 3+ The ratio of mass to the total iron mass in the rock;

[0007] Based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree, the hydrogen generation potential of the rocks in the study area is predicted.

[0008] In a specific embodiment of the present invention, the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is obtained, including:

[0009] Collect Fe from target rocks 3+ / Fe Tot ratio data and serpentinization degree data;

[0010] Fe of target rock 3+ / Fe Tot The ratio data and serpentinization degree data were subjected to a first fitting analysis;

[0011] According to the first fitting analysis results, the Fe 3+ / Fe Tot Relationship between the ratio and the degree of serpentinization.

[0012] In a specific embodiment of the present invention, the target rock is a basic-ultramassic rock of the basement of a sedimentary basin.

[0013] In a specific embodiment of the present invention, the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is shown below:

[0014] S=K1φ+B1;

[0015] Among them, S is the degree of serpentinization, φ is Fe 3+ / Fe Tot Ratio, K1 is a constant, B1 is a constant.

[0016] In a specific embodiment of the present invention, obtaining the relationship between the hydrogen generation potential of the rock and the degree of serpentinization includes:

[0017] Conduct a second fitting analysis on the serpentinization degree data and hydrogen generation potential data of the target rock;

[0018] According to the results of the second fitting analysis, the relationship between the hydrogen generation potential of the rock and the degree of serpentinization was obtained.

[0019] In a specific embodiment of the present invention, the relationship between the hydrogen generation potential and the serpentinization degree includes a first stage and a second stage, the serpentinization degree value corresponding to the critical value of the first stage and the second stage is the serpentinization degree threshold, and the hydrogen generation potential value corresponding to the critical value of the first stage and the second stage is the hydrogen generation potential threshold;

[0020] In the first stage, that is, when the serpentinization degree is less than or equal to the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula:

[0021] P(H2)=K2S+B2;

[0022] In the second stage, that is, when the serpentinization degree is greater than the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula:

[0023] P(H2)=K3S -C ;

[0024] Among them, P(H2) is the hydrogen production potential, which represents the fluid hydrogen concentration produced by the formation of unit mass of serpentine, K2, K3 and C are all positive numbers, and B2 is a constant.

[0025] In a specific embodiment of the present invention, the hydrogen generation potential of the rocks in the study area is predicted based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree, including:

[0026] Compare the calculated serpentinization degree of the rocks in the study area with the serpentinization degree threshold;

[0027] When the calculated serpentinization degree of the rocks in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation potential of the rocks in the study area is predicted based on the calculated relationship between the serpentinization degree of the rocks in the study area and the first stage of the relationship between the hydrogen generation potential of the rocks and the serpentinization degree;

[0028] When the calculated serpentinization degree of the rocks in the study area is greater than the serpentinization degree threshold, the hydrogen generation potential of the rocks in the study area is predicted based on the calculated serpentinization degree of the rocks in the study area and the relationship corresponding to the second stage in the relationship between the hydrogen generation potential of the rocks and the serpentinization degree.

[0029] A second object of the present invention is to provide a method for evaluating the hydrogen generation potential of rocks, comprising:

[0030] Compare the serpentinization degree and serpentinization degree threshold of the rocks in the study area calculated by the above prediction methods;

[0031] Under the comparison result that the calculated serpentinization degree of the rocks in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation capacity of the rocks in the study area is evaluated according to the serpentinization degree of the rocks in the study area;

[0032] When the calculated serpentinization degree of the rocks in the study area is greater than the serpentinization degree threshold, the hydrogen generation potential of the rocks is predicted according to the above prediction method to evaluate the hydrogen generation capacity of the rocks in the study area.

[0033] A third object of the present invention is to provide a system for predicting the hydrogen generation potential of rocks, comprising:

[0034] Calculation module: used to calculate the Fe 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is used to calculate the degree of serpentinization of the rocks in the study area. 3+ / Fe Tot The ratio is Fe in rock 3+ The ratio of mass to the total iron mass in the rock;

[0035] Prediction module: used to predict the hydrogen generation potential of rocks in the study area based on the serpentinization degree of rocks in the study area and the relationship between the hydrogen generation potential of rocks and the serpentinization degree.

[0036] A fourth object of the present invention is to provide an electronic device, comprising: a processor, wherein the processor is coupled to a memory;

[0037] The memory is used to store computer programs;

[0038] The processor is configured to execute the computer program stored in the memory, so that the electronic device executes the above method.

[0039] A fifth object of the present invention is to provide a computer-readable storage medium, wherein the computer-readable storage medium stores a program or instruction, and when the program or instruction is run on a computer, the computer executes the method as described above.

[0040] Beneficial effects of the present invention:

[0041] The rock hydrogen generation potential prediction and evaluation method, system, equipment and storage medium of the present invention are based on the serpentinization degree and rock Fe 3+ / Fe Tot The relationship between the hydrogen generation potential and the degree of serpentinization was realized based on the rock Fe 3+ / Fe Tot The ratio is used to calculate the prediction of the hydrogen generation potential of rocks in the study area, which solves the problem of difficulty in predicting and rating the hydrogen generation potential of rocks in areas with low research level and lack of basic data, and provides more reliable basic data for the research on the hydrogen generation potential of hydrogen source rocks and hydrogen resource evaluation.

[0042] Other features and advantages of the present invention will be described in the following description, and in part will become apparent from the description, or will be understood by practicing the present invention. The purpose and other advantages of the present invention can be realized and obtained by the structures pointed out in the description, claims and drawings. BRIEF DESCRIPTION OF THE DRAWINGS

[0043] In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following is a brief introduction to the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative work.

[0044] Figure 1 A flow chart of a method for predicting rock hydrogen generation potential according to an embodiment of the present invention is shown;

[0045] Figure 2 A comparison diagram showing the calculated value and the tested value of the serpentinization degree of rocks in a certain study area according to an embodiment of the present invention is shown;

[0046] Figure 3 A graph showing the serpentinization degree and hydrogen generation potential of rocks in a certain study area according to an embodiment of the present invention is shown;

[0047] Figure 4 A framework diagram of a rock hydrogen generation potential prediction system according to an embodiment of the present invention is shown;

[0048] Figure 5 A framework diagram of an electronic device according to an embodiment of the present invention is shown;

[0049] In the figure: computing module 100; prediction module 200; electronic device 300; processor 301; memory 302. DETAILED DESCRIPTION

[0050] To make the objectives, technical solutions, and advantages of the embodiments of the present invention more clear, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative efforts shall fall within the scope of protection of the present invention.

[0051] like Figure 1 As shown, a method for predicting the hydrogen generation potential of rocks according to an embodiment of the present invention includes:

[0052] S1. According to the rock Fe 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is used to calculate the degree of serpentinization of the rocks in the study area. 3+ / Fe Tot The ratio is Fe in rock 3+ The ratio of mass to the total iron mass in the rock;

[0053] S2. Predict the hydrogen generation potential of the rocks in the study area based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree.

[0054] In certain embodiments of the present invention, the Fe content of the rock in step S1 is 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is obtained, including:

[0055] A1. Collect Fe of target rock 3+ / Fe Tot Ratio data and serpentinization degree data, wherein the target rock is a hydrogen source rock to ensure the authenticity and reliability of subsequent data analysis;

[0056] Hydrogen source rocks are mostly basic-ultramassic rocks in the basement of sedimentary basins, corresponding to a depth of about 10 km;

[0057] Therefore, for example, in the embodiment of the present invention, the global Fe-rich 2+ Basic-ultrabasic rock Fe of mineral (olivine) 3+ / Fe Tot ratio data and serpentinization degree data;

[0058] A2. Fe of target rock 3+ / Fe Tot The ratio data and the serpentinization degree data are subjected to a first fitting analysis, i.e., a first fitting analysis is performed based on the data collected in step A1. The specific first fitting analysis process includes linear fitting, logarithmic fitting, and exponential fitting, etc., wherein the fitting technology is an existing mathematical analysis method and will not be described in detail here;

[0059] A3. According to the first fitting analysis result, the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization, according to the results of the first fitting analysis in step A2, shows that the Fe 3+ / Fe Tot The ratio has a good positive correlation with the degree of serpentinization, and the linear correlation coefficient R2 is 0.85;

[0060] The Fe3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is shown in formula (1):

[0061] S=K1φ+B1 (1)

[0062] In formula (1), S is the degree of serpentinization, φ is Fe 3+ / Fe Tot Ratio, K1 is a constant, B1 is a constant.

[0063] For example, in the embodiment of the present invention, K1 is 139.86, B1 is 7.3105, and substituting them into formula (1) yields formula (2);

[0064] S=139.86φ+7.3105 (2)

[0065] In some embodiments of the present invention, step S1 is to study the rock Fe 3+ / Fe Tot Substitute the ratio into the Fe 3 + / Fe Tot The serpentinization degree of the rocks in the study area was calculated from the relationship between the ratio and the serpentinization degree.

[0066] In certain embodiments of the present invention, the relationship between the hydrogen generation potential of the rock and the degree of serpentinization in step S2 includes:

[0067] B1. Performing a second fitting analysis on the serpentinization degree data and hydrogen generation potential data of the target rock, i.e., performing a second fitting analysis on the serpentinization degree data and hydrogen generation potential data of the hydrogen source rock. The specific second fitting analysis process includes linear fitting, logarithmic fitting, and exponential fitting, etc., wherein the fitting technology is an existing mathematical analysis method and is not described in detail here;

[0068] B2. Based on the second fitting analysis results, the relationship between the hydrogen generation potential and the serpentinization degree of the rock is obtained. That is, based on the results of the second fitting analysis in step B1, it is found that the relationship between the hydrogen generation potential and the serpentinization degree includes a first stage and a second stage, the serpentinization degree corresponding to the critical values ​​of the first stage and the second stage is the serpentinization degree threshold, and the hydrogen generation potential corresponding to the critical values ​​of the first stage and the second stage is the hydrogen generation potential threshold;

[0069] In the first stage, that is, when the serpentinization degree is less than or equal to the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula:

[0070] P(H2)= K2S+B2 (3)

[0071] In the second stage, that is, when the serpentinization degree is greater than the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula:

[0072] P(H2)= K3S -C (4)

[0073] In formulas (3)-(4), P(H2) is the hydrogen generation potential, which represents the fluid hydrogen concentration produced by the formation of unit mass of serpentine, K2, K3 and C are all positive numbers, and B2 is a constant.

[0074] In some embodiments of the present invention, step S2 includes:

[0075] S2-1, comparing the serpentinization degree of the rocks in the study area calculated in step S1 with the serpentinization degree threshold;

[0076] S2-2. Based on the result that the calculated serpentinization degree of the rocks in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation potential of the rocks in the study area is predicted according to the calculated serpentinization degree of the rocks in the study area and formula (3). Specifically, the calculated serpentinization degree of the rocks in the study area is substituted into formula (3) to calculate the hydrogen generation potential of the rocks in the study area, that is, the predicted value of the hydrogen generation potential of the rocks in the study area;

[0077] S2-3. Based on the result that the serpentinization degree of the rocks in the study area obtained by comparison is greater than the serpentinization degree threshold, the hydrogen generation potential of the rocks in the study area is predicted based on the calculated serpentinization degree of the rocks in the study area and formula (4). Specifically, the calculated serpentinization degree of the rocks in the study area is substituted into formula (4) to calculate the hydrogen generation potential of the rocks in the study area, that is, the predicted value of the hydrogen generation potential of the rocks in the study area.

[0078] For example, in the embodiment of the present invention, K2 is set to 13, B2 is set to 0, and substitution into formula (3) yields formula (5):

[0079] P(H2)= 13S (5)

[0080] For example, the unit of P(H2) is mM / Kg; S is the degree of serpentinization of the hydrogen source rock, in %.

[0081] For example, in the embodiment of the present invention, K3 is set to 14076, and C is set to 1.919. Substituting them into formula (4) yields formula (6):

[0082] P(H2)= 14076 S -1.919 (6)

[0083] For example, the unit of P(H2) is mM / Kg; S is the degree of serpentinization of the hydrogen source rock, in %.

[0084] For example, in an embodiment of the present invention, the serpentinization degree threshold is 10%, and when the serpentinization degree is 10%, the hydrogen generation potential reaches a maximum value, and the H2 fluid concentration generated when 1 kg of serpentine is generated is approximately 130 Mm, that is, the hydrogen generation potential threshold is 130 Mm / kg;

[0085] When the serpentinization degree is less than or equal to 10%, the calculated serpentinization degree is substituted into formula (5) to obtain the hydrogen generation potential of the rocks in the study area; when the serpentinization degree is greater than 10%, the calculated serpentinization degree is substituted into formula (6) to obtain the hydrogen generation potential of the rocks in the study area.

[0086] According to the prediction method provided in the above embodiment, the hydrogen generation potential of rocks in a certain study area was evaluated. The specific steps include:

[0087] According to step S1, the rock Fe 3+ / Fe Tot Substitute the ratio into the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization (i.e., formula (2)) is used to calculate the degree of serpentinization of the rocks in the study area;

[0088] In order to verify the accuracy of the calculated value of the serpentinization degree of the rocks in the study area obtained in step S1 of the method of the present invention, a comparison chart of the calculated value and the measured value of the serpentinization degree of the rocks in the study area is provided here, specifically see Figure 2 , where the calculated value is the point on the straight line corresponding to formula (2), and the test value is Figure 2 The data points in Figure 2 It can be seen that the error between the calculated value obtained in step S1 and the test value is very small;

[0089] According to step S2, the serpentinization degree of the rocks in the study area is calculated based on the rocks in the area, and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree is used to predict the hydrogen generation potential of the rocks in the study area. Specifically,

[0090] The calculated value of the serpentinization degree obtained in step S1 is compared with the serpentinization degree threshold value (10%), and the result of the comparison is substituted into formula (5) or (6). Here, in the embodiment of the present invention, a curve diagram of the hydrogen generation potential predicted according to the serpentinization degree is given as an example, as shown in FIG. Figure 3 .

[0091] According to certain embodiments of the present invention, a method for evaluating the hydrogen generation potential of rocks is provided, comprising:

[0092] X1. Comparing the serpentinization degree and serpentinization degree threshold of the rocks in the study area calculated by the prediction method described in the above embodiment;

[0093] X2. When the calculated serpentinization degree of the rocks in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation capacity of the rocks in the study area is evaluated based on the serpentinization degree of the rocks in the study area. For example, if the calculated serpentinization degree of the rocks in the study area is less than or equal to 10%, the hydrogen generation capacity of the rocks in the study area is considered to be the first level (the highest level);

[0094] X3. When the calculated serpentinization degree of the rocks in the study area is greater than the serpentinization degree threshold, the hydrogen generation capacity of the rocks in the study area is evaluated based on the predicted hydrogen generation potential of the rocks. For example, if the calculated serpentinization degree of the rocks in the study area is greater than 10%, the hydrogen generation capacity of the rocks in the study area is evaluated based on the predicted hydrogen generation potential of the rocks in the above embodiment.

[0095] For example, the hydrogen generation potential corresponding to a serpentinization degree of 10% (i.e., the hydrogen generation potential threshold) is used as a comparison benchmark, and the predicted rock hydrogen generation potential is compared with the benchmark value. The hydrogen generation capacity is classified according to the comparison result, such as the hydrogen generation capacity is classified according to the difference between the two values, or the hydrogen generation capacity is classified according to the quotient of the two values. The present invention does not specifically limit this specific classification.

[0096] From the relationship between the hydrogen generation potential and the degree of serpentinization reflected by formula (3) and formula (4), it can be seen that in the first stage, the hydrogen generation potential of the hydrogen source rock increases with the increase of the degree of serpentinization; in the second stage, the hydrogen generation potential of the hydrogen source rock decreases with the increase of the degree of serpentinization. Therefore, the hydrogen generation potential threshold is the maximum value of the hydrogen generation potential. When the serpentinization degree of the rock in the study area is greater than the serpentinization degree threshold, the hydrogen generation capacity of the rock in the study area is lower than the hydrogen generation capacity of the rock in the study area when the serpentinization degree of the rock in the study area is less than or equal to the serpentinization degree threshold.

[0097] like Figure 4 As shown, a rock hydrogen generation potential evaluation system according to an embodiment of the present invention includes:

[0098] Calculation module 100: used to calculate the Fe 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is used to calculate the degree of serpentinization of the rocks in the study area. 3+ / Fe Tot The ratio is Fe in rock 3+ The ratio of mass to the total iron mass in the rock;

[0099] Prediction module 200: used to predict the hydrogen generation potential of the rocks in the study area based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree.

[0100] In some embodiments of the present invention, the calculation module 100 is connected to a data analysis module, which is used to analyze the Fe 3+ / Fe Tot The relationship between the serpentinization degree and the hydrogen generation potential of the target rock is obtained. 3+ / Fe Tot and the relationship between hydrogen generation potential and the degree of serpentinization;

[0101] The data analysis module is also connected to an information loading module, which is used to load the basic geological data information of the target rock area, including the Fe 3+ / Fe Tot The data such as ratio, serpentinization degree of target rock and hydrogen generation potential of target rock are loaded into the data analysis module.

[0102] In certain embodiments of the present invention, the calculation module 100 and the prediction module 200 are both connected to a hydrogen source rock evaluation module, which is used for the serpentinization degree and serpentinization degree threshold of the rock in the study area calculated by the calculation module 100; and when the calculated serpentinization degree of the rock in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation capacity of the rock in the study area is evaluated according to the serpentinization degree of the rock in the study area; and when the calculated serpentinization degree of the rock in the study area is greater than the serpentinization degree threshold, the hydrogen generation capacity of the rock in the study area is evaluated according to the hydrogen generation potential of the rock predicted by the prediction module 200.

[0103] like Figure 5 As shown, some embodiments of the present invention provide an electronic device, the electronic device 300 including: a processor 301, the processor 301 coupled to a memory 302;

[0104] The memory 302 is used to store computer programs;

[0105] The processor 301 is configured to execute the computer program stored in the memory 302 , so that the electronic device executes the method described in the above embodiment.

[0106] In certain embodiments of the present invention, a computer-readable storage medium is provided. The computer-readable storage medium stores a program or instruction. When the program or instruction is executed on a computer, the computer executes the method described in the above embodiments.

[0107] According to an embodiment of the present invention, the computer-readable storage medium may be a non-volatile computer-readable storage medium, such as, but not limited to, a portable computer disk, a hard disk, a random access memory (RAM), a read-only memory (ROM), an erasable programmable read-only memory (EPROM or flash memory), a portable compact disk read-only memory (CD-ROM), an optical storage device, a magnetic storage device, or any suitable combination thereof. In the present invention, a computer-readable storage medium may be any tangible medium containing or storing a program that can be used by or in conjunction with an instruction execution system, an electronic device, or a device.

[0108] Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein; and these modifications or replacements do not cause the essence of the corresponding technical solutions to deviate from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims

1. A method for predicting the hydrogen generation potential of rocks, characterized in that: include: According to the rock Fe 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is used to calculate the degree of serpentinization of the rocks in the study area. 3+ / Fe Tot The ratio is Fe in rock 3+ The ratio of mass to the total iron mass in the rock; The hydrogen generation potential of the rocks in the study area is predicted based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree; Obtaining the relationship between the hydrogen generation potential of the rock and the degree of serpentinization includes: Conduct a second fitting analysis on the serpentinization degree data and hydrogen generation potential data of the target rock; According to the results of the second fitting analysis, the relationship between the hydrogen generation potential of the rock and the degree of serpentinization was obtained; The relationship between the hydrogen generation potential and the serpentinization degree includes a first stage and a second stage, the serpentinization degree value corresponding to the critical value of the first stage and the second stage is the serpentinization degree threshold, and the hydrogen generation potential value corresponding to the critical value of the first stage and the second stage is the hydrogen generation potential threshold; In the first stage, that is, when the serpentinization degree is less than or equal to the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula: P(H2)= K2S+B2; In the second stage, that is, when the serpentinization degree is greater than the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula: P(H2)= K3S -C ; Among them, P(H2) is the hydrogen production potential, which represents the fluid hydrogen concentration produced by the formation of unit mass of serpentine, K2, K3 and C are all positive numbers, and B2 is a constant.

2. The method for predicting the hydrogen generation potential of rocks according to claim 1, characterized in that: Fe of the rock 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is obtained, including: Collect Fe from target rocks 3+ / Fe Tot ratio data and serpentinization degree data; Fe of target rock 3+ / Fe Tot The ratio data and serpentinization degree data were subjected to a first fitting analysis; According to the first fitting analysis results, the Fe 3+ / Fe Tot Relationship between the ratio and the degree of serpentinization.

3. The method for predicting the hydrogen generation potential of rocks according to claim 2, characterized in that: The target rocks are basic-ultramassic rocks in the basement of sedimentary basins.

4. The method for predicting the hydrogen generation potential of rocks according to claim 1, characterized in that: The Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is shown below: S=K1φ+B1; Where S is the degree of serpentinization, φ is the ratio of Fe3+ / FeTot, K1 is a constant, and B1 is a constant.

5. The method for predicting the hydrogen generation potential of rocks according to claim 1, characterized in that: Based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of the rocks and the serpentinization degree, the hydrogen generation potential of the rocks in the study area is predicted, including: Compare the calculated serpentinization degree of the rocks in the study area with the serpentinization degree threshold; When the calculated serpentinization degree of the rocks in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation potential of the rocks in the study area is predicted based on the calculated relationship between the serpentinization degree of the rocks in the study area and the first stage of the relationship between the hydrogen generation potential of the rocks and the serpentinization degree; When the calculated serpentinization degree of the rocks in the study area is greater than the serpentinization degree threshold, the hydrogen generation potential of the rocks in the study area is predicted based on the calculated serpentinization degree of the rocks in the study area and the relationship corresponding to the second stage in the relationship between the hydrogen generation potential of the rocks and the serpentinization degree.

6. A method for evaluating the hydrogen generation potential of rocks, characterized in that: include: Comparing the serpentinization degree and the serpentinization degree threshold of the rocks in the study area calculated by the prediction method of claim 1; Under the comparison result that the calculated serpentinization degree of the rocks in the study area is less than or equal to the serpentinization degree threshold, the hydrogen generation capacity of the rocks in the study area is evaluated according to the serpentinization degree of the rocks in the study area; When the calculated serpentinization degree of the rocks in the study area is greater than the serpentinization degree threshold, the hydrogen generation potential of the rocks is predicted by the prediction method according to claim 1 to evaluate the hydrogen generation capacity of the rocks in the study area.

7. A prediction system for rock hydrogen generation potential, characterized in that: include: Calculation module: used to calculate the Fe 3+ / Fe Tot ratio, and the Fe 3+ / Fe Tot The relationship between the ratio and the degree of serpentinization is used to calculate the degree of serpentinization of the rocks in the study area. 3+ / Fe Tot The ratio is Fe in rock 3+ The ratio of mass to the total iron mass in the rock; Prediction module: used to predict the hydrogen generation potential of rocks in the study area based on the serpentinization degree of the rocks in the study area and the relationship between the hydrogen generation potential of rocks and the serpentinization degree; Obtaining the relationship between the hydrogen generation potential of the rock and the degree of serpentinization includes: Conduct a second fitting analysis on the serpentinization degree data and hydrogen generation potential data of the target rock; According to the results of the second fitting analysis, the relationship between the hydrogen generation potential of the rock and the degree of serpentinization was obtained; The relationship between the hydrogen generation potential and the serpentinization degree includes a first stage and a second stage, the serpentinization degree value corresponding to the critical value of the first stage and the second stage is the serpentinization degree threshold, and the hydrogen generation potential value corresponding to the critical value of the first stage and the second stage is the hydrogen generation potential threshold; In the first stage, that is, when the serpentinization degree is less than or equal to the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula: P(H2)= K2S+B2; In the second stage, that is, when the serpentinization degree is greater than the serpentinization degree threshold, the relationship between the hydrogen generation potential and the serpentinization degree is shown in the following formula: P(H2)= K3S -C ; Among them, P(H2) is the hydrogen production potential, which represents the fluid hydrogen concentration produced by the formation of unit mass of serpentine, K2, K3 and C are all positive numbers, and B2 is a constant.

8. An electronic device, characterized in that: include: a processor coupled to the memory; The memory is used to store computer programs; The processor is configured to execute the computer program stored in the memory, so that the electronic device performs the method according to any one of claims 1 to 5.

9. A computer-readable storage medium, characterized in that The computer-readable storage medium stores a program or instruction, and when the program or instruction is executed on a computer, the computer is caused to perform the method according to any one of claims 1 to 5.

Citation Information

Patent Citations

  • Analysis method for mining potential of water-containing silicate type laterite nickel ore

    CN109085661A

  • Method of evaluating hydrocarbon generation potential of hydrocarbon source rock

    CN112179806A