Co-loaded nickel-iron-based three-way catalyst, and preparation method and application thereof

By constructing a multi-level pore structure and oxidative calcination treatment of a Co-loaded nickel-iron-based ternary catalyst, the problems of reduced activity and poor stability of the electrocatalyst under high current density alkaline conditions were solved, achieving efficient hydrogen evolution reaction performance and long-term stability, and having potential for industrial application.

CN120719332APending Publication Date: 2025-09-30SHIHEZI UNIVERSITY
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Patent Information

Application Number
CN202511244374.2
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-09-02
Publication Date
2025-09-30

AI Technical Summary

Technical Problem

In existing technologies, under alkaline conditions at high current density (>500 mA cm-2), electrocatalysts generally suffer from reduced activity and poor stability after long-term stability testing, which seriously restricts their industrial application process.

Method used

The preparation method of the Co-loaded nickel-iron-based ternary catalyst includes adding a divalent cobalt compound solution to a foamed nickel-iron substrate in a hydrothermal kettle for hydrothermal reaction, followed by rinsing and oxidative roasting to construct a conical network structure with multi-level pores, optimize the synergistic effect of multi-metal active sites, and enhance electron transfer efficiency and catalytic activity.

Benefits of technology

The HER activity and stability of the catalyst were significantly improved, and an overpotential of only 119 mV was required to reach an industrial-grade current density (1000 mA cm-2). Under this current condition, it can operate stably for more than 3000 hours, showing prospects for industrial application.

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Abstract

The invention relates to the technical field of catalyst preparation, and provides a Co-loaded ferronickel-based three-way catalyst, a preparation method and application, and the preparation method of the Co-loaded ferronickel-based three-way catalyst comprises the following steps: S1, adding a divalent cobalt compound solution into a liner of a hydrothermal kettle; s2, a foamed ferronickel substrate is added into the divalent cobalt compound solution for a hydrothermal reaction, washing and drying are carried out after the reaction is finished, and a Co / NiFe (at) INF electrode is obtained; and S3, oxidizing and calcining the Co / NiFe (at) INF electrode to obtain the Co / NiFeO (at) INF electrode. Compared with the prior art, the preparation method of the Co-loaded nickel-iron-based three-way catalyst, disclosed by the invention, shows excellent HER activity and excellent stability under a high-current-density alkaline condition.
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