Nanofiber interwoven composite gel membrane for carbon dioxide separation and preparation method of nanofiber interwoven composite gel membrane

By in situ polymerization to form a CO2-philic gel layer on the nanofiber interwoven skeleton, the problems of nanomaterial aggregation and poor interface compatibility in the mixed matrix membrane were solved, and the efficient CO2 separation performance was improved.

CN120789953APending Publication Date: 2025-10-17ZHEJIANG UNIV
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Patent Information

Application Number
CN202510922029.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-07-04
Publication Date
2025-10-17

AI Technical Summary

Technical Problem

Existing mixed matrix membranes suffer from problems of nanomaterial aggregation and poor interfacial compatibility during carbon dioxide separation, resulting in non-selective defects and discontinuous gas transmission channels, which limit the separation performance.

Method used

The preparation method of nanofiber interwoven composite gel membrane is adopted. The carbon dioxide-philic gel layer is formed by in-situ polymerization on the nanofiber interwoven skeleton. The phase change process is avoided by thermal initiation method to form a dense and defect-free gel layer. The polar ether bonds in the polyethylene glycol gel are used to promote the dissolution of carbon dioxide molecules and repel nitrogen molecules.

Benefits of technology

It achieves high carbon dioxide permeability and selectivity, avoids defects within the membrane, enhances gas separation performance, and has excellent structural and performance stability.

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Abstract

The invention discloses a nanofiber interwoven composite gel membrane for carbon dioxide separation and a preparation method of the nanofiber interwoven composite gel membrane. The nanofiber interwoven composite gel membrane comprises a nanofiber interwoven framework and a carbon dioxide-philic gel matrix layer, wherein the surface of the nanofiber interwoven framework is coated with the carbon dioxide-philic gel matrix layer; the carbon dioxide-philic gel matrix layer is formed by in-situ polymerization and gelation of a precursor solution containing an oxidizing agent, a cross-linking agent and a functional monomer on the surface of the nanofiber interwoven skeleton. The nanofiber interwoven composite gel membrane provided by the invention has excellent carbon dioxide permeability and selectivity. The invention also discloses an application of the nanofiber interwoven composite gel membrane in separation of carbon dioxide.
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