Cathode plate for electrolyzing zinc by ammonia chloride method

By using a combination of aluminum and titanium plates in the zinc cathode plate of the chloramine electrolysis process, the problems of easy corrosion of pure aluminum and high cost of pure titanium are solved. This improves corrosion resistance and impact resistance, simplifies the operation process, extends service life and reduces costs.

CN121853090APending Publication Date: 2026-04-14YUANLING SHANNENG ENVIRONMENTAL PROTECTION TECH CO LTD
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Patent Information

Application Number
CN202310146596.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-02-21
Publication Date
2026-04-14

AI Technical Summary

Technical Problem

Existing cathode plates made of pure aluminum used in the chloramine electrolytic zinc process are prone to corrosion and have poor impact resistance, while pure titanium cathode plates are expensive and have poor conductivity, and the deposited zinc tends to adhere and not fall off.

Method used

The structure uses a combination of aluminum and titanium plates. The titanium plate is located above and below the liquid level line of the aluminum plate. The sidewalls of the aluminum plate are connected to the titanium plate by screws. The top of the conductive beam has a lifting lug and an insulating sleeve. The sidewalls of the aluminum plate have an insulating strip. The titanium plate is used for corrosion protection and easy peeling of zinc deposits.

Benefits of technology

It improves the corrosion resistance and impact resistance of the cathode plate, reduces the labor intensity of workers, facilitates mechanized zinc stripping, extends service life, reduces production costs, and improves economic efficiency.

✦ Generated by Eureka AI based on patent content.

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Abstract

The cathode plate comprises a conductive beam, an aluminum plate and two titanium plates, the lower end of the conductive beam is fixedly connected with the upper end of the aluminum plate, the upper portion of the side wall of the aluminum plate is connected with the two titanium plates through a plurality of screws, the top of the conductive beam is fixedly connected with two lifting lugs, one end of the conductive beam is fixedly connected with a conductive head, and the other end of the conductive beam is fixedly connected with the aluminum plate. The end, away from the conductive head, of the conductive beam is sleeved with an insulation sleeve. The cathode plate is easy and convenient to manufacture, the titanium plate can be repeatedly used and can also be directly applied to an existing cathode plate made of a pure aluminum material, and the problems that the cathode plate made of the pure titanium material is high in cost, poor in electric conductivity and firm in adhesion of separated zinc are solved. The two titanium plates are located above and below the liquid level line of the aluminum plate, the corrosion resistance and the knocking resistance of the cathode plate are improved through the liquid level upper part, zinc is conveniently separated out to be opened in the titanium plates through the liquid level lower part, the labor intensity of workers is reduced, mechanical zinc stripping is facilitated, the service life of the cathode plate can be prolonged, the production cost is saved, and the economic benefits are improved.
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Description

Technical Field

[0001] This invention relates to the field of metallurgical technology, and in particular to a cathode plate for zinc electrolysis using the chloramine process. Background Technology

[0002] Currently, ammonia electrolytic zinc production primarily uses pure aluminum cathode plates, which suffer from problems such as easy corrosion of the liquid surface, poor impact resistance, and difficulty in opening the zinc deposits. Some small factories use pure titanium cathode plates, but these have disadvantages such as high investment costs, poor conductivity compared to aluminum plates, and difficulty in adhering and detaching the deposited zinc over time. Summary of the Invention

[0003] The purpose of this invention is to address the shortcomings of existing technologies by proposing a cathode plate for zinc electrolysis using the chloramine method. This invention solves the problems of high cost, poor conductivity, and poor adhesion of zinc deposits in pure titanium cathode plates. Two titanium plates are located above and below the liquid level of the aluminum plate. The upper part above the liquid level improves the corrosion resistance and impact resistance of the cathode plate, while the lower part facilitates the opening of zinc deposits on the titanium plate. This reduces the labor intensity of workers, facilitates mechanized zinc stripping, extends the service life of the cathode plate, saves production costs, and improves economic efficiency.

[0004] To achieve the above objectives, the present invention adopts the following technical solution:

[0005] A cathode plate for zinc electrolysis using the chloramine process includes a conductive beam, an aluminum plate, and two titanium plates. The lower end of the conductive beam is fixedly connected to the upper end of the aluminum plate. The upper sidewall of the aluminum plate is connected to the two titanium plates by multiple screws. Two lifting lugs are fixedly connected to the top of the conductive beam. A conductive head is fixedly connected to one end of the conductive beam. An insulating sleeve is fitted on the end of the conductive beam away from the conductive head. Insulating strips are fitted on both sidewalls of the aluminum plate.

[0006] Preferably, the two titanium plates are arranged on both sides of the aluminum plate, and the titanium plates serve to prevent corrosion and facilitate the removal of zinc precipitates.

[0007] The present invention has the following beneficial effects:

[0008] The cathode plate of this invention is simple to manufacture, the titanium plate is reusable, and it can also be directly applied to existing pure aluminum cathode plates, solving the problems of high cost, poor conductivity, and poor adhesion of precipitated zinc in pure titanium cathode plates. Two titanium plates are located above and below the liquid level in the aluminum plate. The upper part above the liquid level improves the cathode plate's corrosion resistance and impact resistance, while the lower part facilitates the opening of zinc precipitates on the titanium plate, reducing labor intensity, facilitating mechanized zinc stripping, extending the cathode plate's service life, saving production costs, and improving economic efficiency. Attached Figure Description

[0009] Figure 1This is a schematic diagram of the structure of a cathode plate for zinc electrolysis using the chloramine process proposed in this invention;

[0010] Figure 2 for Figure 1 A schematic diagram of the side sectional structure in the middle;

[0011] Figure 3 for Figure 1 A schematic diagram showing the position of the liquid surface of electrolytic zinc on a titanium plate.

[0012] In the diagram: 1. Conductive beam, 2. Aluminum plate, 3. Lifting lug, 4. Conductive head, 5. Insulating sleeve, 6. Insulating strip, 7. Titanium plate, 8. Screw. Detailed Implementation

[0013] The technical solutions of the present invention will be clearly and completely described below with reference to the accompanying drawings of the embodiments of the present invention. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments.

[0014] Reference Figure 1-3 A cathode plate for zinc electrolysis using the chloramine process includes a conductive beam 1, an aluminum plate 2, and two titanium plates 7. The lower end of the conductive beam 1 is fixedly connected to the upper end of the aluminum plate 2. The upper side wall of the aluminum plate 2 is connected to the two titanium plates 7 by multiple screws 8. Two lifting lugs 3 are fixedly connected to the top of the conductive beam 1. A conductive head 4 is fixedly connected to one end of the conductive beam 1. An insulating sleeve 5 is fitted on the end of the conductive beam 1 away from the conductive head 4. Insulating strips 6 are fitted on both side walls of the aluminum plate 2.

[0015] Two titanium plates 7 are set on both sides of the aluminum plate 2. The titanium plates 7 serve to prevent corrosion and facilitate the removal of zinc precipitates.

[0016] Furthermore, the liquid level of the electrolytic zinc on aluminum plate 2 is as follows: Figure 3 As shown, the two titanium plates 7 are located above and below the liquid level of the aluminum plate 2. The two titanium plates 7 above the liquid level improve the corrosion resistance and impact resistance of the cathode plate, while the two titanium plates 7 below the liquid level facilitate the precipitation of zinc by opening on the titanium plates 7, reducing the labor intensity of workers, facilitating mechanized zinc stripping, extending the service life of the cathode plate, saving production costs, and improving economic efficiency.

[0017] In this invention, two titanium plates 7 are provided, which can play a role in corrosion prevention and facilitate the peeling and opening of zinc deposits. This is more suitable for zinc electrolysis using the chloramine method. The titanium plates 7 are reusable and can also be directly applied to existing pure aluminum cathode plates. This solves the problems of high cost, poor conductivity, and poor adhesion of zinc deposits on pure titanium cathode plates. At the same time, the two titanium plates 7 are located above and below the liquid level of the aluminum plate 2. The two titanium plates 7 above the liquid level improve the corrosion resistance and impact resistance of the cathode plate, while the two titanium plates 7 below the liquid level facilitate the opening of zinc deposits on the titanium plates 7, reducing the labor intensity of workers, facilitating mechanized zinc peeling, extending the service life of the cathode plate, saving production costs, and improving economic efficiency.

[0018] The above description is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Any equivalent substitutions or modifications made by those skilled in the art within the scope of the technology disclosed in the present invention, based on the technical solution and inventive concept of the present invention, should be covered within the scope of protection of the present invention.

Claims

1. A cathode plate for zinc electrolysis using the chloramine process, characterized in that, The device includes a conductive beam (1), an aluminum plate (2), and two titanium plates (7). The lower end of the conductive beam (1) is fixedly connected to the upper end of the aluminum plate (2). The upper side wall of the aluminum plate (2) is connected to the two titanium plates (7) by multiple screws (8). The top of the conductive beam (1) is fixedly connected to two lifting lugs (3). One end of the conductive beam (1) is fixedly connected to a conductive head (4). The end of the conductive beam (1) away from the conductive head (4) is fitted with an insulating sleeve (5). Both sides of the aluminum plate (2) are fitted with insulating strips (6).

2. The cathode plate for zinc electrolysis using the chloramine process according to claim 1, characterized in that, Two titanium plates (7) are arranged on both sides of the aluminum plate (2), and the titanium plates (7) serve to prevent corrosion and facilitate the removal of zinc precipitates.