Electrolyte, secondary battery and electric equipment
By adding trithiocarbonate additives with cyano and trimethoxysilane substituents and lithium salt as a second additive to the electrolyte, stable SEI and CEI passivation layers are formed, solving the problem of electrolyte oxidation and decomposition under high voltage and improving the interface stability and electrochemical performance of the secondary battery.
Patent Information
- Application Number
- CN202610251261.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2026-03-03
- Publication Date
- 2026-06-26
AI Technical Summary
Under high voltage conditions, the electrolyte in a secondary battery undergoes oxidative decomposition to generate Lewis acidic byproducts such as HF, PF5, and POF3. These byproducts attack the passivation layer at the positive electrode/electrolyte interface, leading to the dissolution of transition metals and side reactions at the negative electrode interface, thus deteriorating electrochemical performance.
Adding trithiocarbonate additives containing cyano and trimethoxysilane substituents and lithium salt secondary additives to the electrolyte works synergistically to form stable SEI and CEI passivation layers, inhibiting interfacial reactions and improving battery performance.
It significantly improves the interface stability of secondary batteries, reduces interface internal resistance, enhances cycle and storage performance under high voltage, and reduces the risk of gas generation at high temperatures.