One-step method for synthesizing flaky zinc sulfide and centrifugal reaction device

CN122399732APending Publication Date: 2026-07-17天津市国盛防务科技有限公司
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
天津市国盛防务科技有限公司
Filing Date
2026-05-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for synthesizing sheet-like zinc sulfide involve excessively long routes, cumbersome processes, numerous raw materials, high energy consumption, long production cycles, and uneven particle size distribution of the products.

Method used

A one-step method for synthesizing flake zinc sulfide was developed using a centrifugal reaction apparatus. By controlling the ratio of zinc source, sulfur source, alkali, and surfactant, the centrifugal force was utilized to make the reaction more uniform. Combined with room temperature and pressure reaction and a simple drying step, the high purity and uniform particle size of the product were achieved.

Benefits of technology

It has achieved high-purity (100% zinc sulfide, structural purity of over 95%) and uniform particle size of flaky zinc sulfide, shortening the production cycle and reducing energy consumption and losses.

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Abstract

本发明涉及硫化锌技术领域,具体为一种一步法合成片状硫化锌的方法及离心式反应装置,包括:锌源:硫酸锌、氯化锌、硝酸锌,优选七水硫酸锌;原料液浓度0.1‑1mol / L;硫源:硫氢化钠、硫化钠、硫脲,优选硫氢化钠;原料液浓度0.05‑1.5mol / L;碱:氨水、氢氧化钠、碳酸钠、碳酸铵、氢氧化钾,优选碳酸铵,原料液浓度0.01‑0.1mol / L。本发明产物硫化锌成分纯度很高,100%硫化锌、结构纯度较高,片状结构在95%以上,通过反应仓和加料管的配合使用,反应过程中,产物颗粒逐增加,质量增加,由于离心力作用,逐渐向边缘靠近,溶质浓度由边级区域向中心位置递次升高,中间反应速度快于边缘反应速度,中间区域颗粒长大速度大于边缘长大速度,最终结果,得到颗粒大小相对均匀的粉体。
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