High-insulation high-strength nylon 66 composite material with topological interlocking structure and preparation method thereof

By constructing an interface design with a topological interlocking structure on the surface of modified mica and combining it with glass fiber to form a three-dimensional interlocking network, the technical challenges of high insulation and high strength were solved, and a breakthrough in the stability of material performance under extreme environments was achieved.

CN122404969APending Publication Date: 2026-07-17HENAN HAIRUIXIANG TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HENAN HAIRUIXIANG TECH CO LTD
Filing Date
2026-04-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing modification techniques cannot simultaneously achieve high insulation and high strength in high insulation materials. Traditional interface modification strategies have limited interfacial bonding strength, leading to performance degradation of materials under multi-field coupling conditions.

Method used

By constructing an interface with a topological interlocking structure, utilizing the nanopores on the surface of modified mica to form a geometric interlock with nylon 66 molecular chains, and combining it with glass fiber to construct a three-dimensional interlocking network, the material achieves high volume resistivity and high tensile strength.

Benefits of technology

A breakthrough has been achieved in the synergistic effect of high insulation (volume resistivity ≥1.5×10⁶ Ω·m) and high strength (tensile strength ≥220 MPa). The material exhibits excellent performance stability under extreme environments, meeting the needs of cutting-edge fields such as ultra-high voltage and deep-sea exploration.

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Abstract

本发明公开了一种具有拓扑互锁结构的高绝缘高强度尼龙66复合材料及其制备方法,突破了现有技术中绝缘性能与力学性能难以兼顾的技术瓶颈。所述改性云母包括云母内核、偶联剂过渡层和由超支化聚合物构成的拓扑互锁功能层,该功能层具有与尼龙66分子链回转半径相匹配的纳米孔洞结构(平均孔径3‑11 nm)。复合材料包括尼龙66树脂100份、异形截面玻璃纤维25‑40份、所述改性云母12‑22份、拓扑互锁促进剂1‑5份、纳米绝缘增强剂2‑8份。本发明通过构建分子尺度的几何互锁结构,使界面剪切强度≥10 MPa;复合材料的体积电阻率≥1.5×10¹⁶Ω·m,拉伸强度≥220 MPa,在多场耦合老化1000小时后性能保持率≥90%。本发明突破了绝缘性能与力学性能难以兼顾的技术瓶颈,适用于特高压输变电、核聚变装置、深海探测器等极端环境领域。
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Citation Information

Patent Citations

  • CN116790119A