Emulsion cosmetic

Abstract

To provide an emulsion cosmetic that exhibits excellent spreadability during skin application and gives the skin (cheek) a natural gloss and a sense of dimensionality immediately after being applied.SOLUTION: An emulsion cosmetic comprises the following components (A), (B), (C), and (D): (A) an organic ultraviolet absorber, (B) a linear silicone including at least (B1) a linear silicone having a viscosity of 30-10000 mPa s at 25°C, (C) one or more polyhydric alcohols selected from PEG / PPG / polybutylene glycol-8 / 5 / 3 glycerin, PPG-9 diglyceryl, dipropylene glycol, and pentylene glycol, and (D) a hydrophobized metal oxide.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to an emulsion cosmetic. [Background technology]

[0002] BACKGROUND ART Sunscreen cosmetics having high UV protection effects and excellent stability have been investigated. For example, Patent Document 1 describes a sunscreen cosmetic that contains t-butyl methoxydibenzoylmethane and / or diethylamino hydroxybenzoyl hexyl benzoate, bisethylhexyloxyphenol methoxyphenyl triazine, ethylhexyl triazine, ester oil, and an ultraviolet scattering agent, which exhibits a high ultraviolet protection effect, is stable, has excellent usability, does not turn unnaturally white upon application, and is low-irritation. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Laid-Open No. 2017-78054 Summary of the Invention [Problem to be solved by the invention]

[0004] Emulsion cosmetics containing an organic UV absorber and a hydrophobically treated metal oxide have the problem that the organic UV absorber has poor compatibility, making it difficult to spread when applied to the skin, resulting in an unnatural finish and a lack of three-dimensionality. [Means for solving the problem]

[0005] The present inventors have discovered that an emulsion cosmetic obtained by combining an organic UV absorber, a hydrophobically treated metal oxide, a specific polyhydric alcohol that is compatible with the organic UV absorber, and a chain silicone of a specific viscosity spreads well when applied to the skin, and imparts a natural gloss and three-dimensional appearance to the finish of the skin (cheeks) immediately after application.

[0006] The present invention relates to a composition comprising the following components (A), (B), (C) and (D): (A) an organic ultraviolet absorber, (B) a chain silicone containing at least (B1) a chain silicone having a viscosity at 25°C of 30 to 10,000 mPa·s; (C) one or more polyhydric alcohols selected from PEG / PPG / polybutylene glycol-8 / 5 / 3 glycerin, PPG-9 diglyceryl, dipropylene glycol, and pentylene glycol; (D) Hydrophobized metal oxide The present invention relates to an emulsion cosmetic containing the above. [Effects of the Invention]

[0007] The emulsion cosmetic of the present invention spreads well, does not feel any resistance to the fingers during application, and when it dries in the latter half of application, there is an appropriate resistance (stop feeling) to the fingers. It also gives a natural glossy finish and a three-dimensional feel to the skin (cheeks) immediately after application, and the glossy feel and three-dimensional feel are sustained for a long time. DETAILED DESCRIPTION OF THE INVENTION

[0008] The organic UV absorbers of component (A) used in the present invention are those commonly used in cosmetics, such as 2-ethylhexyl methoxycinnamate, polysilicone-15, bisethylhexyloxyphenol methoxyphenyl triazine, diethylaminohydroxybenzoyl hexyl benzoate, ethylhexyl triazone, t-butylmethoxydibenzoylmethane, ethylhexyl triazone, oxybenzone-3, drometrizole trisiloxane, and dimethoxybenzylidene dioxoimidazolidine ethylhexyl propionate.

[0009] Among these, from the viewpoint of absorbing ultraviolet rays and protecting the skin, it is preferable to include one or more selected from 2-ethylhexyl methoxycinnamate, polysilicone-15, bisethylhexyloxyphenol methoxyphenyl triazine, diethylaminohydroxybenzoyl hexyl benzoate, and ethylhexyl triazone.

[0010] Component (A) can be used alone or in combination of two or more, and from the viewpoint of absorbing UV rays and protecting the skin, the content is preferably 1% by mass or more of the total composition, more preferably 2% by mass or more, even more preferably 3% by mass or more, and preferably 20% by mass or less, more preferably 12% by mass or less, and even more preferably 9% by mass or less. The content of component (A) is preferably 1 to 20% by mass of the total composition, more preferably 2 to 12% by mass, and even more preferably 3 to 9% by mass.

[0011] Component (B) is a chain silicone, and may be either a volatile silicone or a non-volatile silicone. Examples of volatile silicones include linear dimethylpolysiloxanes such as dimethylpolysiloxane (1cs), dimethylpolysiloxane (1.5cs), and dimethylpolysiloxane (2cs). Examples of non-volatile silicones include linear dimethylpolysiloxanes such as dimethylpolysiloxanes having a viscosity at 25°C of 30 to 10,000 mPa·s.

[0012] Component (B) contains (B1) a chain silicone having a viscosity at 25°C of 30 to 10,000 mPa·s, preferably 40 to 5,000 mPa·s, and more preferably 50 to 1,000 mPa·s. Viscosity is measured at 25°C using a B-type viscometer (Model TVB-10, manufactured by Toki Sangyo Co., Ltd., measurement conditions: rotors TM1 to TM4, 6 rpm, 1 minute). Viscosities of 30 to 1,000 mPa·s are measured using TM1, 1,000 to 5,000 mPa·s using TM2, and 5,000 to 10,000 mPa·s using TM3.

[0013] Component (B1) can be used alone or in combination of two or more types, and its content is preferably 1% by mass or more, more preferably 2% by mass or more, and even more preferably 3% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, and even more preferably 11% by mass or less, from the viewpoints of good spreadability during application, no resistance to the fingers during application, a moderate resistance (stop feeling) as it dries in the latter half of application, and imparting a natural luster and three-dimensional feel to the skin (cheeks) immediately after application. The content of component (B1) is preferably 1 to 20% by mass, more preferably 2 to 15% by mass, and even more preferably 3 to 11% by mass.

[0014] Component (B) includes component (B1), and can be used alone or in combination of two or more. From the viewpoints of good spreadability during application, no resistance to the fingers during application, and a moderate resistance (stop feeling) as the product dries in the latter half of application, the content is preferably 10% by mass or more of the total composition, more preferably 20% by mass or more, even more preferably 23% by mass or more, and preferably 50% by mass or less, more preferably 40% by mass or less, and even more preferably 36% by mass or less. The content of component (B) is preferably 10 to 50% by mass of the total composition, more preferably 20 to 40% by mass, and even more preferably 23 to 36% by mass.

[0015] In the present invention, the mass ratio (B1) / (B) of component (B1) to component (B) is preferably 0.05 or more, more preferably 0.1 or more, even more preferably 0.13 or more, and preferably 0.5 or less, more preferably 0.35 or less, and even more preferably 0.3 or less, from the viewpoints of good spreadability during application, no resistance to the fingers during application, a moderate resistance (stop feeling) as it dries in the latter half of application, and imparting a natural luster and three-dimensional feel to the finish of the skin (cheeks) immediately after application. Furthermore, the mass ratio (B1) / (B) of component (B1) to component (B) is preferably 0.05 to 0.5, more preferably 0.1 to 0.35, and even more preferably 0.13 to 0.3.

[0016] Component (C) is one or more polyhydric alcohols selected from PEG / PPG / polybutylene glycol-8 / 5 / 3 glycerin, PPG-9 diglyceryl, dipropylene glycol, and pentylene glycol. These have excellent compatibility with component (A) and reduce oily feeling during application. Of these, it is preferable to use a cream containing PEG / PPG / polybutylene glycol-8 / 5 / 3 glycerin, as it spreads easily during application, does not feel any resistance to the fingers during application, has a moderate resistance (stop feeling) as it dries in the latter half of application, and gives a natural luster and three-dimensional feel to the finish of the skin (cheeks) immediately after application. As the PEG / PPG / polybutylene glycol-8 / 5 / 3 glycerin, commercially available products such as Wilbride S-753D (manufactured by NOF Corporation) can be used.

[0017] Component (C) can be used alone or in combination of two or more. The content of component (C) is preferably 1% by mass or more, more preferably 2% by mass or more, and even more preferably 3% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, and even more preferably 10% by mass or less, from the viewpoints of good spreadability during application, no resistance to the fingers during application, a moderate resistance (stop feeling) as it dries in the latter half of application, and imparting a natural luster and three-dimensional feel to the skin (cheeks) immediately after application. The content of component (C) is preferably 1 to 20% by mass, more preferably 2 to 15% by mass, and even more preferably 3 to 10% by mass.

[0018] In the present invention, the mass ratio (B1) / (C) of component (B1) to component (C) is preferably 0.2 or more, more preferably 0.4 or more, even more preferably 0.5 or more, and preferably 4 or less, more preferably 3 or less, and even more preferably 2 or less, from the viewpoints of good spreadability during application, no resistance to the fingers during application, a moderate resistance (stop feeling) as it dries in the latter half of application, a natural gloss and three-dimensional appearance to the finish of the skin (cheeks) immediately after application, and a long-lasting gloss and three-dimensional appearance. Furthermore, the mass ratio (B1) / (C) of component (B1) to component (C) is preferably 0.2 to 4, more preferably 0.4 to 3, and even more preferably 0.5 to 2.

[0019] In the present invention, the mass ratio of the total amount of components (A) and (C) to component (B1), [(A) + (C)] / (B1), is preferably 0.4 or more, more preferably 0.6 or more, even more preferably 0.8 or more, and preferably 10 or less, more preferably 4 or less, and even more preferably 2.8 or less, from the viewpoints of achieving good spreadability during application, no resistance to the fingers during application, a moderate resistance (stop feeling) as the skin dries in the latter half of application, a natural gloss and three-dimensional appearance on the skin (cheeks) immediately after application, and long-lasting gloss and three-dimensional appearance. Furthermore, the mass ratio of the total amount of components (A) and (C) to component (B1), [(A) + (C)] / (B1), is preferably 0.4 to 10, more preferably 0.6 to 4, and even more preferably 0.8 to 2.8.

[0020] Component (D) is a hydrophobically treated metal oxide. Examples of metal oxides include those commonly used in cosmetics, such as titanium oxide, zinc oxide, iron oxide, cerium oxide, and chromium oxide, and it is preferable to include one or more selected from titanium oxide, zinc oxide, and iron oxide.

[0021] Examples of hydrophobic treatments include surface treatments such as silicone treatment, alkylsilane treatment, fatty acid treatment, metal soap treatment, amino acid treatment, acylated amino acid treatment, organic titanate treatment, acrylic resin treatment, methacrylic resin treatment, and urethane resin treatment. One or more of the silicone treatment, alkylsilane treatment, amino acid treatment, and acylated amino acid treatment are preferred, and those containing at least a metal oxide treated with an amino acid or an acylated amino acid are preferred. Examples of amino acids include proline, hydroxyproline, alanine, glycine, sarcosine, lysine, aspartic acid, glutamic acid, etc., and salts thereof are also included. Furthermore, the fatty acid constituting the acyl group of the acylated amino acid is preferably a fatty acid having 1 to 23 carbon atoms, more preferably a fatty acid having 8 to 20 carbon atoms, and among these, stearoyl glutamic acid, cocoyl glutamic acid, lauroyl aspartic acid, dilauroyl glutamic acid lysine, and lauroyl lysine are even more preferred. Examples of salts thereof include Na, Ca, Al, Mg, Zn, Zr, and Ti salts. Specifically, from the viewpoint of providing a moderate sense of resistance (stop feeling) as it dries in the latter half of application and imparting a natural luster and three-dimensional feel to the finish of the skin (cheeks) immediately after application, those treated with disodium stearoyl glutamate, sodium lauroyl aspartate, or disodium cocoyl glutamate are preferred, and those treated with disodium stearoyl glutamate are more preferred. The amino acid treatment can be carried out according to a conventional method.

[0022] Component (D) can be used alone or in combination of two or more, and its content is preferably 1% by mass or more, more preferably 7% by mass or more, even more preferably 12% by mass or more, and preferably 40% by mass or less, more preferably 30% by mass or less, and even more preferably 22% by mass or less, based on the viewpoints of providing a moderate resistance (stop feeling) as the product dries in the latter half of application, imparting a natural gloss and three-dimensional feel to the skin (cheeks) immediately after application, and ensuring that the gloss and three-dimensional feel last for a long time. Furthermore, the content of component (D) is preferably 1 to 40% by mass, more preferably 7 to 30% by mass, and even more preferably 12 to 22% by mass.

[0023] In the present invention, the mass ratio (C) / (D) of component (C) to component (D) is preferably 0.1 or more, more preferably 0.15 or more, even more preferably 0.22 or more, and preferably 1 or less, more preferably 0.7 or less, and even more preferably 0.5 or less, from the viewpoints of good spreadability during application, no resistance to the fingers during application, a moderate resistance (stop feeling) as it dries in the latter half of application, a natural gloss and three-dimensional finish on the skin (cheeks) immediately after application, and long-lasting gloss and three-dimensional effect. Furthermore, the mass ratio (C) / (D) of component (C) to component (D) is preferably 0.1 to 1, more preferably 0.15 to 0.7, and even more preferably 0.22 to 0.5.

[0024] The emulsion cosmetic of the present invention may further contain a nonionic surfactant, making it possible to provide an emulsion cosmetic that is excellent in feel and spreads easily. Such nonionic surfactants may be any surfactant commonly used in cosmetics, and examples thereof include sorbitan fatty acid esters such as sorbitan monoisostearate, sorbitan monooleate, sorbitan sesquistearate, and sorbitan sesquioleate; glycerin fatty acid esters, diglycerin fatty acid esters, propylene glycol fatty acid esters, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid esters, polyethylene glycol fatty acid esters, polyethylene glycol dipolyhydroxystearate, alkyl glyceryl ethers, alkyl polyglyceryl ethers, polyoxyethylene alkyl ethers, polyoxyethylene alkyl ether fatty acid esters, polyoxyethylene alkylamines; polyether-modified silicones such as polyoxyethylene-methylpolysiloxane copolymers and poly(oxyethylene-oxypropylene)methylpolysiloxane copolymers; and silicone surfactants such as polyglycerin-modified silicones, alkyl-modified polyether-modified silicones, and alkyl chain-co-modified polyether-modified silicones.

[0025] From the viewpoint of enhancing dispersibility, the nonionic surfactant preferably has an HLB value of 2 to 6, more preferably 3 to 5.5. Here, HLB (Hydrophilic-Lipophilic Balance) indicates the molecular weight of the hydrophilic group portion relative to the total molecular weight of the surfactant, and is calculated using Griffin's equation. When a surfactant is composed of two or more nonionic surfactants, the HLB of the mixed surfactant is calculated as follows: The HLB of the mixed surfactant is the arithmetic average of the HLB values ​​of each nonionic surfactant based on their blending ratio. Mixed HLB=Σ(HLBx×Wx) / ΣWx HLBx indicates the HLB value of nonionic surfactant X. Wx represents the mass (g) of the nonionic surfactant X having the value of HLBx.

[0026] The nonionic surfactant preferably includes one or more selected from silicone surfactants, sugar fatty acid esters, and glycerin fatty acid esters, more preferably includes a silicone surfactant, and even more preferably includes PEG-12 dimethicone.

[0027] One or more nonionic surfactants can be used, and from the viewpoint of providing an emulsion cosmetic that is excellent in feel and spreads easily, the content is preferably 0.1% by mass or more of the total composition, more preferably 0.6% by mass or more, even more preferably 1% by mass or more, and preferably 10% by mass or less, more preferably 6% by mass or less, and even more preferably 4% by mass or less. The content of the nonionic surfactant is preferably 0.1 to 10% by mass of the total composition, more preferably 0.6 to 6% by mass, and even more preferably 1 to 4% by mass.

[0028] The emulsion cosmetic of the present invention may further contain a liquid ester oil other than component (A). Liquid means that the ester oil has flowability and is liquid at 25°C. The melting point is preferably 20°C or lower. Ester oils include monoester oils, diester oils, triester oils and tetraester oils.

[0029] Examples of monoester oils include monoesters of aliphatic or aromatic monocarboxylic or dicarboxylic acids having 2 to 24 carbon atoms, and specific examples thereof include cetyl 2-ethylhexanoate, cetyl octanoate, isononyl isononanoate, isotridecyl isononanoate, hexyl laurate, isopropyl myristate, octyldodecyl myristate, myristyl myristate, 2-hexyldecyl myristate, isopropyl palmitate, octyl palmitate, and palmitate. Examples of the hydroxybenzoates include 2-hexyldecyl butyl stearate, isocetyl stearate, isocetyl isostearate, decyl oleate, isodecyl benzoate, octyl methoxycinnamate, hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, octyldodecyl lactate, lanolin acetate, 2-ethylhexyl succinate, 2-hexyldecyl adipate, alkyl benzoate (C12 to C15), and octyldodecyl 12-stearoyl stearate.

[0030] Examples of diester oils include diesters of dicarboxylic acids having 3 to 18 carbon atoms and difatty acid esters of polyhydric alcohols. Specific examples include propylene glycol dicaprylate, neopentyl glycol dicaprate, glycol distearate, propylene glycol diisostearate, glyceryl diisostearate, glyceryl monomyristate monoisostearate, glycerin di-2-heptylundecanoate, di-2-ethylhexyl succinate, diisopropyl sebacate, diisostearyl malate, ethylene glycol di-2-ethylhexanoate, diisobutyl adipate, di-2-heptylundecyl adipate, and di-2-ethylhexyl sebacate.

[0031] Triester oils include tri-fatty acid esters of trivalent or higher polyhydric alcohols, and specific examples include glyceryl trimyristate, glyceryl triisopalmitate, glyceryl tri-2-heptylundecanoate, trimethylolpropane triethylhexanoate, trimethylolpropane trioctanoate, tri(caprylic / capric)glyceryl, glyceryl trioleate, glyceryl tri-2-ethylhexanoate, glyceryl triisostearate, olive oil, jojoba oil, and dipentaerythrityl tri-polyhydroxystearate.

[0032] Examples of tetraester oils include tetra-fatty acid esters of tetrahydric or higher polyhydric alcohols, and specific examples include pentaerythritol tetra(behenate / benzoate / ethylhexanoate), pentaerythritol tetraethylhexanoate, pentaerythritol tetraoctanoate, and pentaerythritol tetra-2-ethylhexanoate.

[0033] The liquid ester oil preferably contains one or more selected from pentaerythritol fatty acid esters and dipentaerythritol fatty acid esters that are liquid at 25°C, from the viewpoint of imparting a natural gloss and three-dimensional feel to the skin.

[0034] The fatty acids constituting such ester oils may be either saturated or unsaturated fatty acids, with saturated fatty acids being preferred from the viewpoint of imparting a natural gloss and three-dimensional appearance to the skin. Furthermore, either straight-chain or branched-chain fatty acids may be used, with those having a hydroxyl group being preferred. Examples of such fatty acids include caproic acid, caprylic acid, 2-ethylhexanoic acid, isononanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, hydroxystearic acid, arachidic acid, behenic acid, lignoceric acid, cerotic acid, montanic acid, and melissic acid. Among the above saturated fatty acids, saturated fatty acids having 16 to 28 carbon atoms are preferred. Examples of such fatty acids include palmitic acid, stearic acid, isostearic acid, hydroxystearic acid, arachidic acid, behenic acid, lignoceric acid, cerotic acid, and montanic acid. More preferred are saturated fatty acids having 16 to 22 carbon atoms, such as palmitic acid, stearic acid, isostearic acid, hydroxystearic acid, arachidic acid, and behenic acid.

[0035] The alcohols constituting the ester oil are pentaerythritol and dipentaerythritol, with dipentaerythritol being preferred from the viewpoints of good spreadability during application, no resistance felt by the fingers during application, and a moderate resistance (stop feeling) as the oil dries in the latter half of application. Examples of pentaerythritol fatty acid esters include pentaerythrityl (behenic acid / polyhydroxystearate), and examples of dipentaerythritol fatty acid esters include dipentaerythrityl tri-polyhydroxystearate, dipentaerythrityl pentaisostearate, and dipentaerythrityl tetraisostearate. Dipentaerythritol fatty acid esters are preferred, and more preferred are those containing one or more selected from dipentaerythrityl tri-polyhydroxystearate, dipentaerythrityl pentaisostearate, and dipentaerythrityl tetraisostearate, and even more preferred are those containing dipentaerythrityl tri-polyhydroxystearate.

[0036] One or more liquid ester oils can be used, and from the viewpoints of good spreadability during application, no resistance to the fingers during application, and a moderate resistance (stop feeling) when drying in the latter half of application, the content is preferably 0.01 to 10 mass % of the total composition, more preferably 0.1 to 3 mass %, and even more preferably 0.2 to 1 mass %.

[0037] In the present invention, the content of water is preferably 10 to 45 mass %, more preferably 15 to 36 mass %, and even more preferably 18 to 32 mass % of the total composition, from the viewpoint of excellent spreadability during application.

[0038] In addition to the above-mentioned components, the emulsion cosmetic of the present invention may contain components that are commonly used in cosmetics, such as surfactants other than those mentioned above, oily components other than those mentioned above, powders other than those mentioned above, polymeric compounds, antioxidants, fragrances, preservatives, pH adjusters, blood circulation promoters, cooling agents, antiperspirants, disinfectants, skin activators, moisturizers, and refreshing agents.

[0039] From the viewpoints of being environmentally friendly and providing an excellent feel when used, the emulsion cosmetic of the present invention preferably contains no more than 1% by mass of organic resin powder such as microplastics in the total composition, more preferably no more than 0.1% by mass, and even more preferably is substantially free of such powder. Specifically, it refers to organic resin powder other than cellulose powder that is highly biodegradable. Examples of organic resin powders include crosslinked or non-crosslinked organic resin powders such as powders of one or more polymers or copolymers selected from polyamide resin, nylon resin, polyester resin, polyethylene resin, polytetrafluoroethylene resin, polypropylene resin, polystyrene resin, benzoguanamine resin, polymethylbenzoguanamine resin, polyurethane resin, vinyl resin, fluororesin, acrylic resin, and melamine resin; butyl acrylate-vinyl acetate copolymer, styrene-acrylic acid copolymer, silicone resin, and divinylbenzene-styrene copolymer.

[0040] The emulsified cosmetic of the present invention can be produced by a conventional method and can be made into a dosage form such as a liquid, emulsion, paste, cream, gel, or solid. Furthermore, the emulsion cosmetic of the present invention may be either a water-in-oil emulsion cosmetic or an oil-in-water emulsion cosmetic, and is preferably a water-in-oil emulsion cosmetic.

[0041] The emulsion cosmetic of the present invention can be used, for example, as makeup cosmetics such as a makeup base, foundation, concealer, blusher, and eye shadow; and as ultraviolet protection cosmetics such as a sunscreen emulsion and sunscreen cream, and is therefore suitable as a makeup cosmetic. [Example]

[0042] Examples 1 to 9, Comparative Examples 1 to 2 Water-in-oil emulsion cosmetics (liquid foundations) were prepared with the compositions shown in Tables 1 and 2, and the following were evaluated: finger resistance during application, finger resistance as the application dries, natural glossiness of the skin (cheeks) immediately after application, three-dimensional skin feel of the skin (cheeks) immediately after application, natural glossiness of the skin (cheeks) 6 hours after application, and three-dimensional skin feel of the skin (cheeks) 6 hours after application. The results are shown in Tables 1 and 2.

[0043] (Manufacturing method) A powder phase containing component (D) was added to an oil phase containing components (A) and (B) and dispersed, and then an aqueous phase containing component (C) was added and stirred with a homomixer to obtain a water-in-oil emulsion cosmetic (liquid foundation).

[0044] (Evaluation method) (1) Resistance of fingers during application: Five expert evaluators applied each water-in-oil emulsion cosmetic to the skin and evaluated the resistance felt by the fingers during application according to the following criteria. The results are shown as the total score of the five evaluators. 5. No resistance is felt by the fingers while applying to the skin. 4. No resistance is felt by the fingers while applying to the skin. 3. There is little resistance felt by the fingers when applying to the skin. 2: You may feel a slight resistance with your fingers while applying the product to your skin. 1: You feel resistance with your fingers while applying to the skin.

[0045] (2) Resistance to fingers when drying during application: Five expert evaluators applied each water-in-oil emulsion cosmetic to the skin and evaluated the resistance felt by the fingers (stop feeling) as the cosmetic dried in the latter half of application, according to the following criteria. The results are shown as the total score of the five evaluators. Furthermore, when the product dries in the latter half of application, there is a resistance (stop feeling) on ​​the fingers, which is preferable as it prevents the product from remaining sticky for a long time. 5: When the product dries in the latter half of application, there is a resistance (stop feeling) in the fingers. 4: When drying in the latter half of application, there is a slight resistance (stop feeling) in the fingers. 3: When it dries in the latter half of application, there is little resistance (stop feeling) to the fingers. 2: When the product dries in the latter half of application, there is no resistance (stop feeling) in the fingers. 1: When it dries in the latter half of application, there is no resistance (stop feeling) to the fingers and it feels slippery.

[0046] (3) Natural glow on the skin (cheeks) immediately after application: Five expert evaluators applied each water-in-oil emulsion cosmetic to the skin and evaluated the natural, lustrous feel of the finished skin (cheeks) immediately after application according to the following criteria. The results are shown as the total score of the five evaluators. 5. Immediately after application, the skin (cheeks) has a very natural glow. 4. Immediately after application, the skin (cheeks) has a natural glow. 3: Immediately after application, the skin (cheeks) has a slight natural glow. 2: Immediately after application, the skin (cheeks) does not have much of a natural glow. 1: Immediately after application, the skin (cheeks) lacks a natural glow.

[0047] (4) Three-dimensional effect on the skin (cheeks) immediately after application: Five expert evaluators applied each water-in-oil emulsion cosmetic to the skin and evaluated the three-dimensional feel of the finished skin (cheeks) immediately after application according to the following criteria. The results are shown as the total score of the five evaluators. 5: Immediately after application, the skin (cheeks) has a very three-dimensional appearance. 4. Immediately after application, the skin (cheeks) has a three-dimensional appearance. 3: Immediately after application, the skin (cheeks) has a slight three-dimensional appearance. 2: Immediately after application, the skin (cheeks) does not have much three-dimensionality. 1: Immediately after application, the skin (cheeks) lacks a three-dimensional appearance.

[0048] (5) Natural glow on the skin (cheeks) 6 hours after application: Five expert evaluators applied each water-in-oil emulsion cosmetic to the skin, and 6 hours after application, evaluated the natural luster of the skin (cheeks) according to the following criteria. The results are shown as the total score of the five evaluators. 5: Six hours after application, the skin (cheeks) has a very natural glow. 4. Six hours after application, the skin (cheeks) has a natural glow. 3: Six hours after application, the skin (cheeks) has a slight natural glow. 2: Six hours after application, the skin (cheeks) no longer had a natural glow. 1: Six hours after application, the skin (cheeks) no longer has a natural glow.

[0049] (6) Three-dimensional effect on the skin (cheeks) 6 hours after application: Five expert evaluators applied each water-in-oil emulsion cosmetic to the skin, and evaluated the three-dimensional feel of the skin (cheeks) six hours after application according to the following criteria. The results are shown as the total score of the five evaluators. 5: Six hours after application, the skin (cheeks) has a very three-dimensional appearance. 4. Six hours after application, the skin (cheeks) has a three-dimensional appearance. 3: Six hours after application, the skin (cheeks) has a slight three-dimensional appearance. 2: Six hours after application, the skin (cheeks) lacks a three-dimensional appearance. 1: Six hours after application, the skin (cheeks) lacks a three-dimensional appearance.

[0050] [Table 1]

[0051] [Table 2]

[0052] Example 10 The water-in-oil emulsion cosmetic (liquid foundation) having the composition shown in Table 3 was produced in the same manner as in Examples 1 to 9. It spreads well when applied to the skin, and there is a resistance (stop feeling) to the fingers as it dries in the latter half of application. Immediately after application, the finish on the skin (cheeks) is given a natural glossy feel and a three-dimensional appearance, and these glossy and three-dimensional effects are sustained.

[0053] [Table 3]

Claims

1. The following components (A), (B), (C), and (D): (A) an organic ultraviolet absorber, (B) a chain silicone containing at least (B1) a chain silicone having a viscosity at 25°C of 30 to 10,000 mPa s; (C) one or more polyhydric alcohols selected from PEG / PPG / polybutylene glycol-8 / 5 / 3 glycerin, PPG-9 diglyceryl, dipropylene glycol, and pentylene glycol; (D) Hydrophobized metal oxide An emulsion cosmetic containing

2. 2. The emulsion cosmetic according to claim 1, wherein component (A) comprises at least one or more selected from the group consisting of ethylhexyl methoxycinnamate, polysilicone-15, bisethylhexyloxyphenol methoxyphenyl triazine, diethylaminohydroxybenzoylhexyl benzoate, and ethylhexyl triazone.

3. 3. The emulsion cosmetic according to claim 1 or 2, wherein the content of component (A) is 1 to 20% by mass, the content of component (B1) is 1 to 20% by mass, the content of component (B) is 1 to 50% by mass, the content of component (C) is 1 to 20% by mass, and the content of component (D) is 1 to 40% by mass.

4. 3. The emulsion cosmetic according to claim 1, wherein the metal oxide of component (D) comprises one or more metal oxides selected from titanium oxide, zinc oxide, and iron oxide.

5. 3. The emulsion cosmetic according to claim 1, wherein the mass ratio (B1) / (C) of component (B1) to component (C) is 0.2 to 4.

6. 3. The emulsion cosmetic according to claim 1, wherein the mass ratio of the total amount of component (A) and component (C) to component (B1), [(A) + (C)] / (B1), is 0.4 to 10.

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