Composition, polymer, cured product, molded body, and method for producing poly(methyl methacrylate)

A composition of methyl methacrylate, methyl pivalate, and methyl methylbutenoate enhances the heat resistance and durability of polymethyl methacrylate, addressing the quality improvement needs in recycled materials by optimizing the monomer composition and additives.

WO2025238914A1 Publication Date: 2025-11-20SUMITOMO CHEM CO LTD
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Patent Information

Application Number
PCT/JP2024/045687
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2024-05-13
Filing Date
2024-12-24
Publication Date
2025-11-20

AI Technical Summary

Technical Problem

Existing methods for recycling polymethyl(meth)acrylate do not adequately address the need for improving the quality, particularly heat resistance, of recycled materials, and there is a lack of optimization in the composition of raw material monomers to enhance the properties of polymethyl(meth)acrylate.

Method used

A composition containing methyl methacrylate, methyl pivalate, and methyl methylbutenoate, with specific concentration ranges, is used to produce polymethyl methacrylate, which includes recycled and bio-derived methyl methacrylate, along with optional additives to enhance heat resistance and durability.

Benefits of technology

The resulting polymethyl methacrylate exhibits improved heat resistance, as indicated by higher 5% weight loss temperature and glass transition temperature, with reduced residual MMA concentration, leading to superior durability and thermal stability.

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Abstract

The present invention addresses the problem of providing: a composition able to yield a molded body having excellent heat resistance; a polymer, a cured product and a molded body which are obtained using this composition; and a method for producing poly(methyl methacrylate) using this composition. The present invention relates to a composition which contains methyl methacrylate, methyl pivalate and methyl methylbutenoate. The concentration of methyl pivalate is more than 0 ppm by mass and not more than 10,000 ppm by mass of the overall composition. The concentration of methyl methylbutenoate is more than 0 ppm by mass and not more than 2000 ppm by mass of the overall composition.
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