Repairing composite layer of amorphous/nanocrystalline cooling roller and preparation method of repairing composite layer

A technology of cooling rolls and nanocrystals, which is applied in the field of material science, can solve the problems of low absorption rate of laser beams by cooling rolls, bulky laser equipment, and low efficiency of laser cladding, and achieve excellent compatibility and wettability, Effect of improving cladding efficiency and enhancing wear resistance

CN103895280AActive Publication Date: 2014-07-02QINGDAO YUNLU ADVANCED MATERIALS TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2014-07-02

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Abstract

The invention belongs to the technical field of material science, and particularly relates to a repairing composite layer of an amorphous / nanocrystalline cooling roller and a preparation method of the repairing composite layer. The composite layer consists of two layers, namely a copper-based alloy layer connected with base materials and a nickel-based alloy layer, wherein the copper-based alloy layer comprises the following components by weight percent: 7-9% of Ni, 8-12% of Sn, 5-15% of Co, 0.8-2% of Si and the balance being Cu; the nickel-based alloy layer comprises one of Ni-Co alloy, Ni-P alloy, Ni-Fe alloy and Ni-Cr alloy, and the weight content of Ni in alloy is 60-75%. The preparation method comprises the following steps of pretreating the surface of the cooling roller, electroplating the copper-based alloy layer and performing wide-strip cladding on the nickel-based alloy layer by a high-power laser. The prepared composite coating is uniform and compact, and excellent in wear resistance and heat resistance, and has the characteristics of high cladding efficiency and high energy absorptivity of the cooling roller to the laser beam.
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Description

technical field

[0001] The invention belongs to the technical field of material science, and in particular relates to a repairing composite layer of an amorphous / nanocrystalline cooling roll and a preparation method thereof. technical background

[0002] Amorphous / nanocrystalline alloys are solidified by ultra-rapid cooling. When the alloy is solidified, the atoms have no time to arrange and crystallize in an orderly manner. The obtained solid alloy has a long-range disordered structure, and there are no grains and grain boundaries of the crystalline alloy. The current amorphous / nanocrystalline production technology is to pour molten alloy steel at 1300°C on the same roll that is cooled by water that rotates at high speed, and instantly cool it below 200°C to form amorphous / nanocrystalline.

[0003] The amorphous / nanocrystalline cooling roll is the key equipment for the production of amorphous / nanocrystalline alloy strips. It is mainly lined with copper or copper alloy with...

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Embodiment Construction

[0028] The present invention will be described in detail below in conjunction with the accompanying drawings and embodiments.

[0029] The repair composite layer of the amorphous / nanocrystalline cooling roll provided by this embodiment is composed of two layers, and the copper-based alloy layer is connected to the base material, and its composition is calculated by weight percentage: Ni 7-9%, Sn 8~12%, Co 5~15%, Si 0.8~2%, and the balance is Cu; the other layer is a nickel-based alloy layer, which is selected from Ni-Co alloy, Ni-P alloy, Ni-Fe alloy, One of the Ni-Cr alloys, where the weight content of Ni in the alloy is 60-75%.

[0030] Wherein, the thickness ratio of the copper-based alloy layer to the nickel-based alloy layer is 1:1-2.

[0031] Wherein, the powder of the nickel-based alloy layer is spherical or ellipsoidal, and its particle size is 109-250 μm.

[0032] The method for preparing the repair composite layer of the amorphous / nanocrystalline cooling roll pro...