Highly permeable and highly viscous fog seal material and method of making same

Abstract

The application provides a high-penetration and high-viscosity fog seal material and a preparation method thereof, and the material comprises emulsified asphalt, sand, a tackifier, a penetration enhancer and an additive. The tackifier is prepared from the following raw materials: polyoxyethylene sorbitan fatty acid ester, sodium carboxymethyl cellulose, diphenyl dimethoxysilane, dimethyl diethoxysilane, gamma-glycidoxypropyltrimethoxysilane and polyphenyl polymethylene polyisocyanate. The penetration enhancer is prepared from the following raw materials: bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethyl butyl phenol. The additive is prepared from the following raw materials: n-butyl dimethyl chlorosilane and 2-amino-5-bromo-4-isopropyl methyl benzoate. In addition to the high-temperature resistance of the materials themselves, the bis-ethylhexyloxyphenol methoxyphenyl triazine and the methylene bis-benzotriazolyl tetramethyl butyl phenol also have a synergistic effect, and the composite material can significantly improve the penetration performance of the fog seal material.

Description

TECHNICAL FIELD

[0001] The present application belongs to the technical field of road engineering, and relates to a fog seal material, in particular to a high-permeability and high-adhesion fog seal material and a preparation method thereof. BACKGROUND

[0002] The application of the fog seal technology can effectively improve the waterproof performance of the asphalt pavement, thereby effectively improving the anti-skid performance of the pavement, delaying the aging speed of the pavement, and improving the appearance of the asphalt pavement. The fog seal technology, namely the fog seal technology, mainly sprays emulsified asphalt, asphalt maintenance agent and other materials onto the pavement to seal the pores on the pavement, and at the same time, fixes the loose aggregate in construction, which has a positive significance in preventing pavement aging. As a preventive construction and maintenance technology, the improved pavement needs to have strong rigidity and stability without changing the original structure and strength of the pavement and increasing the bearing capacity. The fog seal technology is generally applied to the asphalt pavement with slight cracks and early water damage.

[0003] The fog seal used in China mainly includes sand-containing fog seal and sand-free fog seal. The sand-containing fog seal is generally widely used because it can improve the anti-skid performance. The cementing material used in the sand-containing fog seal is emulsified asphalt. However, the permeability of the emulsified asphalt is relatively poor, and it is difficult to penetrate into the original pavement, resulting in poor maintenance effect of the asphalt pavement. Therefore, a fog seal material with high permeability and high adhesion is needed. SUMMARY

[0004] In view of the deficiencies in the prior art, the purpose of the present application is to provide a high-permeability and high-adhesion fog seal material and a preparation method thereof, which solves the technical problem that the fog seal material in the prior art is difficult to have high permeability and high adhesion while ensuring basic performance.

[0005] In order to solve the above technical problems, the present application adopts the following technical solutions:

[0006] A high-permeability and high-adhesion fog seal material, comprising emulsified asphalt, sand, tackifier, permeability enhancer and additive.

[0007] The tackifier is made of the following raw materials: polyoxyethylene sorbitan fatty acid ester, sodium carboxymethyl cellulose, diphenyl dimethoxysilane, dimethyl diethoxysilane, gamma-glycidoxypropyltrimethoxysilane and polyphenyl polymethylene polyisocyanate.

[0008] The permeability enhancer is made of the following raw materials: bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethyl butyl phenol.

[0009] The additive is made from the following raw materials: n-butyl dimethyl chlorosilane, 2-amino-5-bromo-4-isopropyl methyl benzoate.

[0010] The application also has the following technical features:

[0011] The amount of the emulsified asphalt is 0.15-1.0 L / m 2 ; the amount of the sand is 0.09-0.36 kg / m 2 ; the amount of the tackifier is 0.011-0.029 kg / m 2 ; the amount of the penetration enhancer is 0.01-0.03 kg / m 2 ; and the amount of the additive is 0.01-0.04 kg / m 2 .

[0012] The tackifier is made from the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20-30 parts, sodium carboxymethyl cellulose 20-30 parts, diphenyl dimethoxysilane 20-30 parts, dimethyl diethoxysilane 20-30 parts, gamma-glycidoxypropyl trimethoxysilane 10-15 parts, and polyphenyl polymethylene polyisocyanate 220-270 parts.

[0013] The penetration enhancer is made from the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6-12 parts, and methylene bis-benzotriazolyl tetramethyl butyl phenol 6-12 parts.

[0014] The additive is made from the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5-10 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 5-10 parts.

[0015] The application also protects a preparation method of the high-penetration high-tack fog seal material as described above, which comprises the following steps:

[0016] Step one, preparation of epoxy-based polysiloxane:

[0017] Dimethyl diethoxysilane, diphenyl dimethoxysilane and gamma-glycidoxypropyl trimethoxysilane are stirred in a three-neck flask with a stirrer, a dropping funnel and a reflux condenser, deionized water and a catalyst, iron chloride, are added, and pre-reaction is carried out at room temperature for 15 minutes; then the three-neck flask is placed in a constant-temperature water bath, stirring is started, and reaction is carried out at 70℃ for 30 minutes; the obtained liquid is placed in a rotary evaporation flask for rotary evaporation to remove the solvent, water and by-products, and a yellowish transparent viscous liquid is obtained after rotary evaporation, which is the epoxy-based polysiloxane.

[0018] Step two, preparation of modified cyanate:

[0019] Mix the epoxy polysiloxane prepared in step one and the polyphenyl polymethylene polyisocyanate, and ultrasonic dispersion for 20-35 min to obtain the polysiloxane modified cyanate ester.

[0020] Step three, preparation of modified sodium carboxymethyl cellulose:

[0021] First, add sodium carboxymethyl cellulose into anhydrous ethanol, and ultrasonic dispersion for 15-20 min to obtain a suspension. Then, mix γ-glycidyl ether oxypropyl trimethoxysilane and water, and stir until it is cooled to room temperature. Stop stirring and then add it to the suspension, and ultrasonic dispersion for 15-20 min. In a constant temperature magnetic stirrer, condense and reflux the reaction at 70°C for 3 h. After the reaction is completed, repeatedly wash and suction filter with anhydrous ethanol until the filtrate is clear and transparent. Place the filter cake in a vacuum drying oven and dry at 70°C to obtain sodium carboxymethyl cellulose particles. Put them into a ball mill and grind for 2-3 h to obtain modified sodium carboxymethyl cellulose.

[0022] Step four, preparation of tackifier:

[0023] Add polyoxyethylene sorbitan fatty acid ester and the modified sodium carboxymethyl cellulose prepared in step three into water respectively, heat to 80-85°C and stir until completely dissolved. Then, add the two solutions respectively into the modified cyanate ester prepared in step two, and ultrasonic dispersion for 20 min to obtain a mixed solution, which is the tackifier and is recorded as component A.

[0024] Step five, preparation of permeability enhancer:

[0025] Mix bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethyl butyl phenol with water, and ultrasonic dispersion for 30 min to obtain a mixed solution, which is the permeability enhancer and is recorded as component B.

[0026] Step six, preparation of additive:

[0027] Add n-butyl dimethyl chlorosilane and 2-amino-5-bromo-4-isopropyl methyl benzoate into a reaction kettle, stir uniformly, and then discharge to obtain a mixed solution, which is the additive and is recorded as component C.

[0028] Step seven, preparation of semi-finished product:

[0029] Uniformly introduce emulsified asphalt at 130-150°C into the funnel of a high-speed shearing instrument, open the switch of the high-speed shearing instrument, and simultaneously uniformly pour component A prepared in step four into the high-speed shearing instrument. The shearing time is controlled at 40-60 s. Then, uniformly pour component C prepared in step six into the funnel of the high-speed shearing instrument, and the shearing time is controlled at 60-120 s. Then, open the valve to obtain the semi-finished product.

[0030] Step eight, preparation of emulsion:

[0031] The semi-finished product obtained in step 7 is transferred to a low-speed developing machine, and the B component obtained in step 5 is added and rotated at 800-1000 r / min for 8-10 minutes to obtain a uniformly mixed emulsion.

[0032] Step nine: prepare high-permeability and high-viscosity fog sealing material:

[0033] Pour the emulsion obtained in step eight into an electric mixer and stir at room temperature at a speed of 200-300 r / min for 2 minutes. Continue to add the dried sand into the electric mixer and stir at a speed of 400-600 r / min for 60 seconds. Then transfer the finished product to a container to obtain a high-permeability and high-viscosity fog sealing material.

[0034] Compared with the prior art, the present invention has the following technical effects:

[0035] (I) In the fog seal material of the present invention, the addition of bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethylbutylphenol alone will not improve the permeability of the fog seal material. When the two are added simultaneously, the permeability of the fog seal material is significantly enhanced. In addition to exerting the high temperature resistance of the material itself, bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethylbutylphenol also produce a synergistic effect. The composite material can significantly improve the permeability of the fog seal material.

[0036] (II) In the mist seal material of the present invention, it can be found that polyoxyethylene sorbitan fatty acid ester and modified sodium carboxymethyl cellulose have a mutually promoting effect, which enhances the bonding strength of the mist seal material. When polysiloxane-modified polyphenyl polymethylene polyisocyanate is added, polyoxyethylene sorbitan fatty acid ester and modified sodium carboxymethyl cellulose have a significant mutually promoting effect, which greatly enhances the bonding strength of the mist seal material.

[0037] (III) The mechanism of action of the present invention's fog seal material: When sprayed onto the existing asphalt pavement surface, the fog seal material can penetrate into the existing asphalt pavement to a depth of 3mm to 6mm. After curing, it can repair cracks and other defects in the existing pavement, providing a waterproofing effect. While penetrating, it can also firmly adhere to the original asphalt pavement. This effectively repairs old asphalt pavement, thereby extending the pavement's service life.

[0038] (IV) The fog seal material of the present invention is simple to prepare, easy to construct, and has significant penetration and bonding effects, and is highly valuable for promotion.

[0039] The specific contents of the present invention are further explained in detail below with reference to the embodiments. DETAILED DESCRIPTION

[0040] It should be noted that all raw materials and equipment in the present application, such as no special instructions, all use known raw materials and equipment in the prior art.

[0041] In the present application:

[0042] The emulsified asphalt adopts known commonly used water-based epoxy emulsified asphalt, SBS / styrene-butadiene rubber (SBR) composite modified emulsified asphalt or SBR / carboxylated rubber (CR) composite modified emulsified asphalt.

[0043] The sand is basalt, diabase, limestone or silicon carbide (carbonized silicon); the particle size of the sand ranges from 1.18 mm to 2.36 mm, and the angularity ranges from 50% to 70%.

[0044] The polyoxyethylene sorbitan fatty acid ester is a light yellow to yellow viscous liquid at room temperature, and the number average molecular weight is 1.3×10 3 .

[0045] The sodium carboxymethylcellulose is a white to light yellow powder, granular or fibrous material, and has strong hygroscopicity; the number average molecular weight is 9×10 4 ~ 3×10 5 .

[0046] The diphenyl dimethoxysilane is a colorless transparent liquid and can be miscible in most organic solvents.

[0047] The dimethyldiethoxysilane is a colorless transparent liquid and can be miscible in most organic solvents.

[0048] The gamma-glycidoxypropyltrimethoxysilane is a colorless transparent liquid.

[0049] The polyphenyl polymethylene polyisocyanate is a light yellow to brown viscous liquid.

[0050] The bis-ethylhexyloxyphenol methoxyphenyl triazine is a light yellow powder.

[0051] The methylene bis-benzotriazolyl tetramethylbutylphenol is a light yellow powder.

[0052] The n-butyl dimethyl chlorosilane is a colorless liquid.

[0053] The 2-amino-5-bromo-4-isopropylbenzoic acid methyl ester is a white crystalline powder.

[0054] The high-osmotic high-viscosity fog seal material of the present application is used for preparing the application in the construction of the fog seal.

[0055] The emulsified asphalt is used for closing the surface voids of the road and preventing the water on the road surface from infiltrating, the sand is used for preventing the road surface from reducing the anti-skid force after the emulsified asphalt is sprayed, the basic function of the tackifier is to enhance the adhesion, the basic function of the penetration enhancer is to enhance the penetration effect of the material, and the basic function of the additive is to restore the adhesion of the aged asphalt.

[0056] The high-penetration and high-viscosity fog seal material is used for preparing the construction of the fog seal.

[0057] The use method of the pavement maintenance seal material is as follows: before the construction, the pavement should be clean and dry, and there should be no sundries, pollution and accumulated water, the exposed parts of the highway artificial structure, the curbstone and the marking line should be covered to prevent pollution, the local diseases of the original pavement should be treated according to the design, the special spraying vehicle or the special spraying tool should be used, the fog seal material is sprayed or painted at the set spraying rate, the spraying edges at the starting point and the ending point should be neat, the oil felt should be pre-paved at the starting point and the ending point, and the traffic can be opened after drying and forming.

[0058] The following gives the specific embodiments of the present application, and it should be noted that the present application is not limited to the following specific embodiments, and any equivalent transformation based on the technical scheme of the present application falls within the protection scope of the present application.

[0059] Embodiment 1:

[0060] The embodiment gives a high-penetration and high-viscosity fog seal material, which comprises emulsified asphalt material, sand, tackifier, penetration enhancer and additive.

[0061] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8L / m 2 .

[0062] The sand is basalt, and the spreading amount is 0.3kg / m 2 .

[0063] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20 parts, sodium carboxymethyl cellulose 20 parts, diphenyl dimethoxysilane 20 parts, dimethyl diethoxysilane 20 parts, gamma-glycidyl ether oxypropyl trimethoxysilane 10 parts, polyphenyl polyformaldehyde polyisocyanate 220 parts, and the addition amount is 0.025kg / m 2 .

[0064] The osmophore is made of the following raw materials in parts by weight: 6-12 parts of bis-ethylhexyloxyphenol methoxyphenyl triazine, 6-12 parts of methylene bis-benzotriazolyl tetramethylbutylphenol, and an addition amount of 0.03 kg / m 2 .

[0065] The additive is made of the following raw materials in parts by weight: 5 parts of n-butyl dimethyl chlorosilane, 5 parts of 2-amino-5-bromo-4-isopropyl methyl benzoate, and an addition amount of 0.02 kg / m 2 .

[0066] The embodiment also provides a preparation method of the high-osmotic high-viscosity fog seal material, which comprises the following steps:

[0067] Step one, preparing epoxy-based polysiloxane:

[0068] The dimethyl diethoxysilane, diphenyl dimethoxysilane and gamma-glycidyl ether oxypropyl trimethoxysilane are stirred in a three-neck flask provided with a stirrer, a dropping funnel and a reflux condenser, deionized water and a catalyst, iron chloride, are added, and pre-reaction is carried out at room temperature for 15 minutes; then the three-neck flask is placed in a constant-temperature water bath, stirring is started, and reaction is carried out at 70 DEG C for 30 minutes; the obtained liquid is placed in a rotary evaporation flask for rotary evaporation to remove the solvent, water and by-products, and a yellowish transparent viscous liquid is obtained after rotary evaporation, which is the epoxy-based polysiloxane.

[0069] Step two, preparing modified cyanate:

[0070] The epoxy-based polysiloxane obtained in step one and the polyphenyl polymethylene polyisocyanate are mixed and ultrasonically dispersed for 20-35 minutes to obtain the polysiloxane-modified cyanate.

[0071] Step three, preparing modified sodium carboxymethyl cellulose:

[0072] The sodium carboxymethyl cellulose is first added to anhydrous ethanol, ultrasonically dispersed for 15-20 minutes to obtain a suspension, then the gamma-glycidyl ether oxypropyl trimethoxysilane and water are mixed and stirred until cooled to room temperature, stirring is stopped, and then the mixture is added to the suspension, ultrasonically dispersed for 15-20 minutes; in a constant-temperature magnetic stirrer, condensation reflux reaction is carried out at 70 DEG C for 3 hours; after reaction, the filter cake is repeatedly washed with anhydrous ethanol and suction filtered until the filtrate is clear and transparent, the filter cake is placed in a vacuum drying oven and dried at 70 DEG C, sodium carboxymethyl cellulose particles are obtained, and the particles are ground in a ball mill for 2-3 hours to obtain the modified sodium carboxymethyl cellulose.

[0073] Step four, preparing tackifier:

[0074] Polyoxyethylene sorbitan fatty acid ester and modified carboxymethyl cellulose sodium prepared in step three were added into water respectively and heated to 80-85℃ and stirred until completely dissolved, then the two solutions were added into the modified cyanate prepared in step two respectively, ultrasonic dispersion for 20 min, to prepare a mixed solution, which is the tackifier, recorded as component A.

[0075] Step five, preparation of the permeability enhancer:

[0076] The bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethyl butyl phenol were mixed with water, ultrasonic dispersion for 30 min, to prepare a mixed solution, which is the permeability enhancer, recorded as component B.

[0077] Step six, preparation of the additive:

[0078] The n-butyl dimethyl chlorosilane and 2-amino-5-bromo-4-isopropyl methyl benzoate were added into the reaction kettle, stirred uniformly, then discharged, to prepare a mixed solution, which is the additive, recorded as component C.

[0079] Step seven, preparation of the semi-finished product:

[0080] The emulsified asphalt at 130-150℃ was uniformly introduced into the funnel of the high-speed shearing instrument, the switch of the high-speed shearing instrument was turned on, and the component A prepared in step four was uniformly poured into it at the same time, the shearing time was controlled at 40-60s; the component C prepared in step six was uniformly poured into the funnel of the high-speed shearing instrument, the shearing time was controlled at 60-120s, then the valve was opened, to obtain the semi-finished product.

[0081] Step eight, preparation of the emulsion:

[0082] The semi-finished product obtained in step seven was transferred to the low-speed development machine, the component B prepared in step five was added and rotated at 800-1000r / min, the time was controlled at 8-10min, to prepare a uniformly mixed emulsion.

[0083] Step nine, preparation of the high-permeability high-tack fog seal material:

[0084] The emulsion prepared in step eight was poured into the electric mixer, stirred at 200-300r / min at room temperature for 2min, then the dried sand was added into the electric mixer, stirred at 400-600r / min for 60s, then the finished product was transferred to a container, to prepare the high-permeability high-tack fog seal material.

[0085] Performance test: To verify the anti-skid performance, waterproof performance, permeability, and adhesion performance of the fog seal material of the embodiment, reference is made to the Highway Engineering Asphalt and Asphalt Mixture Test Regulation (JTGE20-2011) to prepare an asphalt concrete test piece with a size of 30*30*5 cm, the test piece is prepared according to the construction steps for the application to the asphalt concrete base body, and after the preparation, the anti-skid pendulum value, water permeability coefficient, penetration depth, and adhesion strength of the test piece are tested, and the test results are shown in Table 1.

[0086] Embodiment 2

[0087] The embodiment gives a high-penetration high-viscosity fog seal material, which comprises an emulsified asphalt material, sand, a tackifier, a permeability enhancer, and an additive. The fog seal material is different from that of Embodiment 1 only in the formula of the tackifier, which is as follows:

[0088] The emulsified asphalt is a water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0089] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0090] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 25 parts, sodium carboxymethyl cellulose 25 parts, diphenyl dimethoxysilane 25 parts, dimethyl diethoxysilane 25 parts, gamma-glycidoxypropyltrimethoxysilane 10 parts, and polyphenyl polymethylene polyisocyanate 230 parts, and the addition amount is 0.025 kg / m 2 .

[0091] The permeability enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6 parts, and methylene bis-benzotriazolyl tetramethyl butyl phenol 6 parts, and the addition amount is 0.03 kg / m 2 .

[0092] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0093] The selection and specification requirements of the raw materials in the embodiment are the same as those in Embodiment 1.

[0094] The embodiment also gives a preparation method of a high-penetration high-viscosity fog seal material, and the specific steps of the method are basically the same as those of Embodiment 1.

[0095] The performance test process of the embodiment is basically the same as that of Embodiment 1, and the performance test results of the embodiment are shown in Table 1.

[0096] Example 3

[0097] The present example gives a high penetration and high viscosity fog seal material, which comprises emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The difference between the fog seal material of the present example and that of example 1 is only in the formula of the tackifier, which is as follows:

[0098] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0099] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0100] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 26 parts, sodium carboxymethyl cellulose 26 parts, diphenyl dimethoxysilane 26 parts, dimethyl diethoxysilane 26 parts, γ-glycidoxypropyltrimethoxysilane 10 parts, polyphenyl polymethylene polyisocyanate 240 parts, and the addition amount is 0.025 kg / m 2 .

[0101] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6 parts, methylene bis-benzotriazolyl tetramethyl butyl phenol 6 parts, and the addition amount is 0.03 kg / m 2 .

[0102] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0103] The selection and specification requirements of each raw material in the present example are the same as those of example 1.

[0104] The present example also gives a preparation method of a high penetration and high viscosity fog seal material, and the specific steps of the method are basically the same as those of example 1.

[0105] The performance test process of the present example is basically the same as that of example 1, and the performance test results of the present example are shown in table 1.

[0106] Example 4

[0107] The present example gives a high penetration and high viscosity fog seal material, which comprises emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The difference between the fog seal material of the present example and that of example 1 is only in the formula of the penetration enhancer, which is as follows:

[0108] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0109] Sand is basalt, the amount of 0.3kg / m 2 .

[0110] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20 parts, sodium carboxymethyl cellulose 20 parts, diphenyl dimethoxysilane 20 parts, dimethyl diethoxysilane 20 parts, gamma-glycidoxypropyltrimethoxysilane 10 parts, polyphenyl polymethylene polyisocyanate 220 parts, and the addition amount is 0.025kg / m 2 .

[0111] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 7 parts, methylene bis-benzotriazolyl tetramethyl butyl phenol 7 parts, and the addition amount is 0.03kg / m 2 .

[0112] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02kg / m 2 .

[0113] The selection and specification requirements of each raw material in this embodiment are the same as those in embodiment 1.

[0114] This embodiment also gives a preparation method of high-penetration high-tack fog seal material, and the specific steps of the method are basically the same as those in embodiment 1.

[0115] The performance test process of this embodiment is basically the same as that in embodiment 1, and the performance test results of this embodiment are shown in table 1.

[0116] Embodiment 5:

[0117] This embodiment gives a high-penetration high-tack fog seal material, which includes emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The difference between this fog seal material and embodiment 1 is only in the formula of the penetration enhancer, which is as follows:

[0118] The emulsified asphalt is water-based epoxy emulsified asphalt, and the amount of spraying is 0.8L / m 2 .

[0119] Sand is basalt, the amount of 0.3kg / m 2 .

[0120] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20 parts, sodium carboxymethyl cellulose 20 parts, diphenyl dimethoxysilane 20 parts, dimethyldiethoxysilane 20 parts, gamma-glycidoxypropyltrimethoxysilane 10 parts, polyphenyl polymethylene polyisocyanate 220 parts, and the addition amount is 0.025 kg / m 2 .

[0121] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 8 parts, methylene bis-benzotriazolyl tetramethyl butyl phenol 8 parts, and the addition amount is 0.03 kg / m 2 .

[0122] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0123] The selection and specification requirements of each raw material in this embodiment are the same as those in Embodiment 1.

[0124] This embodiment also gives a preparation method of a high-penetration high-tack fog seal material, and the specific steps of the method are basically the same as those in Embodiment 1.

[0125] The performance test process of this embodiment is basically the same as that in Embodiment 1, and the performance test results of this embodiment are shown in Table 1.

[0126] Embodiment 6:

[0127] This embodiment gives a high-penetration high-tack fog seal material, which includes emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The fog seal material is different from that in Embodiment 1 only in the formula of the penetration enhancer, and the specific formula is as follows:

[0128] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0129] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0130] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20 parts, sodium carboxymethyl cellulose 20 parts, diphenyl dimethoxysilane 20 parts, dimethyldiethoxysilane 20 parts, gamma-glycidoxypropyltrimethoxysilane 10 parts, polyphenyl polymethylene polyisocyanate 220 parts, and the addition amount is 0.025 kg / m 2 .

[0131] The seepage-increasing agent is made of the following raw materials in parts by weight: 9 parts of bis-ethylhexyloxyphenol methoxyphenyl triazine and 9 parts of methylene bis-benzotriazolyl tetramethylbutylphenol, with an addition amount of 0.03 kg / m 2 .

[0132] The additive is made of the following raw materials in parts by weight: 5 parts of n-butyl dimethyl chlorosilane and 5 parts of 2-amino-5-bromo-4-isopropyl methyl benzoate, with an addition amount of 0.02 kg / m 2 .

[0133] The selection and specification requirements of the raw materials in this embodiment are the same as those in Embodiment 1.

[0134] This embodiment also provides a preparation method of the high-seepage high-viscosity fog seal material, and the specific steps of the method are basically the same as those in Embodiment 1.

[0135] The performance test process of this embodiment is basically the same as that in Embodiment 1, and the performance test results of this embodiment are shown in Table 1.

[0136] Embodiment 7:

[0137] This embodiment provides a high-seepage high-viscosity fog seal material, which comprises emulsified asphalt material, sand, tackifier, seepage-increasing agent and additive. The fog seal material is different from that in Embodiment 1 only in that the formula of the additive is different, and the specific formula is as follows:

[0138] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0139] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0140] The tackifier is made of the following raw materials in parts by weight: 20 parts of polyoxyethylene sorbitan fatty acid ester, 20 parts of sodium carboxymethyl cellulose, 20 parts of diphenyl dimethoxy silane, 20 parts of dimethyl diethoxy silane, 10 parts of γ-glycidoxypropyl trimethoxysilane and 220 parts of polyphenyl polymethylene polyisocyanate, with an addition amount of 0.025 kg / m 2 .

[0141] The seepage-increasing agent is made of the following raw materials in parts by weight: 6-12 parts of bis-ethylhexyloxyphenol methoxyphenyl triazine and 6-12 parts of methylene bis-benzotriazolyl tetramethylbutylphenol, with an addition amount of 0.03 kg / m 2 .

[0142] The additive is made of the following raw materials in parts by weight: 6 parts of n-butyl dimethyl chlorosilane and 6 parts of 2-amino-5-bromo-4-isopropyl methyl benzoate, with an addition amount of 0.02 kg / m2 .

[0143] The selection and specification of each raw material in this embodiment are the same as in Embodiment 1.

[0144] This embodiment also provides a preparation method of the high-penetration and high-viscosity fog seal material, and the specific steps of the method are basically the same as in Embodiment 1.

[0145] The performance test process of this embodiment is basically the same as in Embodiment 1, and the performance test results of this embodiment are shown in Table 1.

[0146] Embodiment 8:

[0147] This embodiment provides a high-penetration and high-viscosity fog seal material, which includes emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The fog seal material is different from that in Embodiment 1 only in the formula of the additive, and the specific formula is as follows:

[0148] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0149] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0150] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20 parts, sodium carboxymethyl cellulose 20 parts, diphenyl dimethoxysilane 20 parts, dimethyl diethoxysilane 20 parts, γ-glycidoxypropyltrimethoxysilane 10 parts, and polyphenyl polyformal polyisocyanate 220 parts, and the addition amount is 0.025 kg / m 2 .

[0151] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6-12 parts, and methylene bis-benzotriazolyl tetramethyl butyl phenol 6-12 parts, and the addition amount is 0.03 kg / m 2 .

[0152] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 8 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 8 parts, and the addition amount is 0.02 kg / m 2 .

[0153] The selection and specification of each raw material in this embodiment are the same as in Embodiment 1.

[0154] This embodiment also provides a preparation method of the high-penetration and high-viscosity fog seal material, and the specific steps of the method are basically the same as in Embodiment 1.

[0155] The performance test process of this embodiment is basically the same as that of Embodiment 1, and the performance test results of this embodiment are shown in Table 1.

[0156] Embodiment 9:

[0157] This embodiment gives a high-penetration high-viscosity fog seal material, which comprises emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The difference between this embodiment and Embodiment 1 is only in the formula of the additive, which is as follows:

[0158] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0159] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0160] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20 parts, sodium carboxymethyl cellulose 20 parts, diphenyl dimethoxysilane 20 parts, dimethyl diethoxysilane 20 parts, γ-glycidoxypropyltrimethoxysilane 10 parts, and polyphenyl polymethylene polyisocyanate 220 parts, and the addition amount is 0.025 kg / m 2 .

[0161] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6-12 parts, and methylene bis-benzotriazolyl tetramethyl butyl phenol 6-12 parts, and the addition amount is 0.03 kg / m 2 .

[0162] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 9 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 9 parts, and the addition amount is 0.02 kg / m 2 .

[0163] The selection and specification requirements of each raw material in this embodiment are the same as those in Embodiment 1.

[0164] This embodiment also gives a preparation method of a high-penetration high-viscosity fog seal material, and the specific steps of the method are basically the same as those of Embodiment 1.

[0165] The performance test process of this embodiment is basically the same as that of Embodiment 1, and the performance test results of this embodiment are shown in Table 1.

[0166] Comparative Example 1:

[0167] This comparative example gives a fog seal material, which comprises emulsified asphalt material, sand, tackifier, penetration enhancer and additive. The difference between this comparative example and Embodiment 2 is that polyoxyethylene sorbitan fatty acid ester is not included in the tackifier.

[0168] Emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0169] Sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0170] The tackifier is made of the following raw materials in parts by weight: sodium carboxymethyl cellulose 25 parts, diphenyl dimethoxysilane 35 parts, dimethyl diethoxysilane 35 parts, gamma-glycidoxypropyltrimethoxysilane 15 parts, and polyphenyl polymethylene polyisocyanate 240 parts, and the addition amount is 0.025 kg / m 2 .

[0171] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6 parts, and methylene bis-benzotriazolyl tetramethyl butyl phenol 6 parts, and the addition amount is 0.03 kg / m 2 .

[0172] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0173] The selection and specification requirements of each raw material in the present comparative example are the same as those in Example 2.

[0174] The present comparative example also gives a preparation method of a fog seal material, and the specific steps of the method are basically the same as those of Example 2, and the difference is that 1) no polyoxyethylene sorbitan fatty acid ester is added in step four.

[0175] The performance test process of the present comparative example is basically the same as that of Example 2, and the performance test results of the present example are shown in Table 1.

[0176] Comparative Example 2:

[0177] The present comparative example gives a fog seal material, which includes emulsified asphalt material, sand, tackifier, penetration enhancer and additive, and the difference between the present comparative example and Example 2 is that no modified sodium carboxymethyl cellulose is added in the tackifier.

[0178] Emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0179] Sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0180] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 25 parts, diphenyl dimethoxysilane 35 parts, dimethyl diethoxysilane 35 parts, gamma-glycidoxypropyltrimethoxysilane 15 parts, polyphenyl polymethylene polyisocyanate 230 parts, and the addition amount is 0.025 kg / m 2 .

[0181] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6 parts, methylene bis-benzotriazolyl tetramethyl butyl phenol 6 parts, and the addition amount is 0.03 kg / m 2 .

[0182] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0183] The selection and specification requirements of each raw material in the present comparative example are the same as those in Example 2.

[0184] The present comparative example also gives a preparation method of a fog seal material, and the specific steps of the method are basically the same as those in Example 2, and the difference is that 1) no sodium carboxymethyl cellulose is added in step four; 2) step three is not performed.

[0185] The performance test process of the present comparative example is basically the same as that of Example 2, and the performance test results of the present example are shown in Table 1.

[0186] Comparative Example 3:

[0187] The present comparative example gives a fog seal material, which includes emulsified asphalt material, sand, tackifier, penetration enhancer and additive, and the difference between the present comparative example and Example 2 is that no polysiloxane modified polyphenyl polymethylene polyisocyanate is added in the tackifier.

[0188] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0189] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0190] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 220 parts, sodium carboxymethyl cellulose 220 parts, and the addition amount is 0.025 kg / m 2 .

[0191] The tackifier is made of the following raw materials in parts by weight: 45 parts of diphenyl dimethoxysilane, 45 parts of dimethyldiethoxysilane, 20 parts of γ-glycidoxypropyltrimethoxysilane, and 230 parts of polyphenyl polymethylene polyisocyanate, and the addition amount is 0.025 kg / m 2 .

[0192] The additive is made of the following raw materials in parts by weight: 5 parts of n-butyl dimethyl chlorosilane and 5 parts of 2-amino-5-bromo-4-isopropyl methyl benzoate, and the addition amount is 0.02 kg / m 2 .

[0193] The selection and specification requirements of each raw material in the present comparative example are the same as those in Example 2.

[0194] The present comparative example also gives a preparation method of a fog seal material, and the specific steps of the method are basically the same as those in Example 2, and the difference is that 1) steps one and two are not performed; 2) polyisocyanate modified polysiloxane modified polyphenyl polymethylene polyisocyanate is not added in step four.

[0195] The performance test process of the present comparative example is basically the same as that of Example 2, and the performance test results of the present example are shown in Table 1.

[0196] Comparative Example 4:

[0197] The present comparative example gives a seal coat material, which includes emulsified asphalt material, sand, tackifier, penetration enhancer and additive, and the difference between the present comparative example and Example 2 is that only polyisocyanate modified polysiloxane modified polyphenyl polymethylene polyisocyanate is added in the tackifier.

[0198] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0199] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0200] The tackifier is made of the following raw materials in parts by weight: 45 parts of diphenyl dimethoxysilane, 45 parts of dimethyldiethoxysilane, 20 parts of γ-glycidoxypropyltrimethoxysilane, and 230 parts of polyphenyl polymethylene polyisocyanate, and the addition amount is 0.025 kg / m 2 .

[0201] The penetration enhancer is made of the following raw materials in parts by weight: 6 parts of bis-ethylhexyloxyphenol methoxyphenyl triazine and 6 parts of methylene bis-benzotriazolyl tetramethyl butyl phenol, and the addition amount is 0.03 kg / m 2 .

[0202] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0203] The selection and specification requirements of each raw material in the present comparative example are the same as those in Example 2.

[0204] The present comparative example also gives a preparation method of a fog seal material, and the specific steps of the method are basically the same as those in Example 2, and the difference is that 1) step three is not performed; 2) only polysiloxane modified polyphenyl polymethylene polyisocyanate is added in step four.

[0205] The performance test process of the present comparative example is basically the same as that in Example 2, and the performance test results of the present example are shown in Table 1.

[0206] Comparative Example 5:

[0207] The present comparative example gives a fog seal material, which comprises an emulsified asphalt material, sand, a tackifier, a penetration enhancer, and an additive. The present comparative example differs from Example 2 in that bis-ethylhexyloxyphenol methoxyphenyl triazine is not added in the penetration enhancer.

[0208] The emulsified asphalt is water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0209] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0210] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 25 parts, sodium carboxymethyl cellulose 25 parts, diphenyl dimethoxy silane 25 parts, dimethyl diethoxy silane 25 parts, gamma-glycidoxypropyl trimethoxysilane 10 parts, and polyphenyl polymethylene polyisocyanate 230 parts, and the addition amount is 0.025 kg / m 2 .

[0211] The penetration enhancer is made of the following raw materials in parts by weight: methylene bis-benzotriazolyl tetramethyl butyl phenol 12 parts, and the addition amount is 0.03 kg / m 2 .

[0212] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the addition amount is 0.02 kg / m 2 .

[0213] The selection and specification requirements of each raw material in the present comparative example are the same as those in Example 2.

[0214] The comparative example also gives a preparation method of a fog seal material, the specific steps of which are basically the same as those of Example 2, except that, different from Example 2, 1) methylene bis-benzotriazyl tetramethyl butyl phenol is not added in step five.

[0215] The performance test process of the comparative example is basically the same as that of Example 2, and the performance test results of the comparative example are shown in Table 1.

[0216] Comparative Example 6:

[0217] The comparative example gives a fog seal material, which comprises an emulsified asphalt material, sand, a tackifier, a penetration enhancer, and an additive. The comparative example differs from Example 2 in that methylene bis-benzotriazyl tetramethyl butyl phenol is not added in the penetration enhancer.

[0218] The emulsified asphalt is a water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0219] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0220] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 25 parts, sodium carboxymethyl cellulose 25 parts, diphenyl dimethoxy silane 25 parts, dimethyl diethoxy silane 25 parts, gamma-glycidoxypropyl trimethoxysilane 10 parts, and polyphenyl polymethylene polyisocyanate 230 parts, and the addition amount is 0.025 kg / m 2 .

[0221] The penetration enhancer is made of the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 12 parts, and the addition amount is 0.03 kg / m 2 .

[0222] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, and 2-amino-5-bromo-4-isopropyl benzoic acid methyl ester 5 parts, and the addition amount is 0.02 kg / m 2 .

[0223] The selection and specification requirements of each raw material in the comparative example are the same as those of Example 2.

[0224] The comparative example also gives a preparation method of a fog seal material, the specific steps of which are basically the same as those of Example 2, except that, different from Example 2, 1) methylene bis-benzotriazyl tetramethyl butyl phenol is not added in step five.

[0225] The performance test process of the present comparative example is basically the same as that of Example 2, and the performance test results of the present example are shown in Table 1.

[0226] Comparative Example 7

[0227] The present comparative example gives a fog seal material, which comprises an emulsified asphalt material, sand, a tackifier, a penetration enhancer and an additive. The present comparative example differs from Example 2 in that neither bis-ethylhexyloxyphenol methoxyphenyl triazine nor methylene bis-benzotriazyl tetramethyl butyl phenol is added in the penetration enhancer.

[0228] The emulsified asphalt is a water-based epoxy emulsified asphalt, and the spreading amount is 0.8 L / m 2 .

[0229] The sand is basalt, and the spreading amount is 0.3 kg / m 2 .

[0230] The tackifier is made of the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 25 parts, sodium carboxymethyl cellulose 25 parts, diphenyl dimethoxy silane 25 parts, dimethyl diethoxy silane 25 parts, γ-glycidyl ether oxypropyl trimethoxy silane 10 parts, and polyphenyl polyformal polyisocyanate 230 parts, and the added amount is 0.025 kg / m 2 .

[0231] The additive is made of the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 5 parts, and the added amount is 0.02 kg / m 2 .

[0232] The selection and specification requirements of each raw material in the present comparative example are the same as those of Example 2.

[0233] The present comparative example also gives a preparation method of a fog seal material, and the specific steps of the method are basically the same as those of Example 2, and the difference is that step five is not performed.

[0234] The performance test process of the present comparative example is basically the same as that of Example 2, and the performance test results of the present example are shown in Table 1.

[0235] Table 1 Performance test table of high-penetration high-tack fog seal material

[0236]

[0237] From Table 1, it can be seen that:

[0238] First, by analyzing the various indexes of Example 2 and Comparative Examples 1-4, it can be found that polyoxyethylene sorbitan fatty acid ester and modified sodium carboxymethyl cellulose can promote each other, so that the adhesion strength of the fog seal material is enhanced. In the case of adding polysiloxane modified polyphenyl polymethylene polyisocyanate, polyoxyethylene sorbitan fatty acid ester and modified sodium carboxymethyl cellulose can promote each other significantly, which can well enhance the adhesion strength of the fog seal material.

[0239] Second, by analyzing the various indexes of Example 2 and Comparative Examples 5-7, it can be found that neither bis-ethylhexyloxyphenol methoxyphenyl triazine nor methylene bis-benzotriazolyl tetramethyl butyl phenol can improve the permeability of the fog seal material when added alone. However, when both are added, the permeability of the fog seal material is significantly enhanced. Bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethyl butyl phenol can not only exert the high-temperature resistance of the material itself, but also have a synergistic effect, and the composite material can significantly improve the permeability of the fog seal material.

[0240] Third, by analyzing the various indexes of Comparative Examples 1-9 and Comparative Examples 1-7, it can be found that the performance of Example 2 is the best and the best raw material composition is: the tackifier is polyoxyethylene sorbitan fatty acid ester 25 parts, sodium carboxymethyl cellulose 25 parts, diphenyl dimethoxy silane 25 parts, dimethyl diethoxy silane 25 parts, γ-glycidyl ether oxypropyl trimethoxy silane 10 parts, and polyphenyl polymethylene polyisocyanate 230 parts by weight; the permeability enhancer is bis-ethylhexyloxyphenol methoxyphenyl triazine 6 parts and methylene bis-benzotriazolyl tetramethyl butyl phenol 6 parts by weight; and the additive is n-butyl dimethyl chlorosilane 5 parts and 2-amino-5-bromo-4-isopropyl benzoic acid methyl ester 5 parts by weight.

Claims

1. A high penetration, high tack fog seal material characterized in that, The emulsified asphalt, sand, tackifier, penetration enhancer and additive are included; the amount of the emulsified asphalt is 0.15-1.0L / m 2 ; the amount of the sand is 0.09-0.36kg / m 2 ; the amount of the tackifier is 0.011-0.029kg / m 2 ; the amount of the penetration enhancer is 0.01-0.03kg / m 2 ; and the amount of the additive is 0.01-0.04kg / m 2 . The tackifier is prepared from the following raw materials in parts by weight: polyoxyethylene sorbitan fatty acid ester 20-30 parts, sodium carboxymethyl cellulose 20-30 parts, diphenyl dimethoxy silane 20-30 parts, dimethyl diethoxy silane 20-30 parts, gamma-glycidoxypropyl trimethoxy silane 10-15 parts, and polyphenyl polymethylene polyisocyanate 220-270 parts; The penetration enhancer is prepared from the following raw materials in parts by weight: bis-ethylhexyloxyphenol methoxyphenyl triazine 6-12 parts, and methylene bis-benzotriazolyl tetramethylbutylphenol 6-12 parts; The additive is prepared from the following raw materials in parts by weight: n-butyl dimethyl chlorosilane 5-10 parts, and 2-amino-5-bromo-4-isopropyl methyl benzoate 5-10 parts.

2. A method of preparing a high penetration, high tack fog seal material as claimed in claim 1, characterized by, The method comprises the following steps: Step one, preparation of epoxy polydimethylsiloxane: Dimethyl diethoxy silane, diphenyl dimethoxy silane and gamma-glycidoxypropyl trimethoxy silane are stirred in a three-neck flask with a stirrer, a dropping funnel and a reflux condenser, deionized water and a catalyst, iron chloride, are added, and pre-reaction is carried out at room temperature for 15 minutes; then the three-neck flask is placed in a constant temperature water bath, stirring is started, and reaction is carried out at 70°C for 30 minutes; the obtained liquid is placed in a rotary evaporation flask for rotary evaporation to remove solvent, water and by-products, and a yellowish transparent viscous liquid is obtained after rotary evaporation, which is epoxy polydimethylsiloxane; Step two, preparation of modified cyanate: The epoxy polydimethylsiloxane obtained in step one and polyphenyl polymethylene polyisocyanate are mixed and ultrasonically dispersed for 20-35 minutes to obtain polydimethylsiloxane modified cyanate; Step three, preparation of modified sodium carboxymethyl cellulose: Sodium carboxymethyl cellulose is first added to anhydrous ethanol and ultrasonically dispersed for 15-20 minutes to obtain a suspension, then gamma-glycidoxypropyl trimethoxy silane and water are mixed and stirred until cooled to room temperature, stirring is stopped, and then the mixture is added to the suspension and ultrasonically dispersed for 15-20 minutes; in a constant temperature magnetic stirrer, reaction is carried out at 70°C under condensation reflux for 3 hours; after reaction, the product is repeatedly washed with anhydrous ethanol and suction filtered until the filtrate is clear and transparent, the filter cake is placed in a vacuum drying oven and dried at 70°C, sodium carboxymethyl cellulose particles are obtained, and the particles are ground in a ball mill for 2-3 hours to obtain modified sodium carboxymethyl cellulose; Step four, preparation of tackifier: Polyoxyethylene sorbitan fatty acid ester and the modified sodium carboxymethyl cellulose obtained in step three are added to water, heated to 80-85°C and stirred until completely dissolved, and then added to the modified cyanate obtained in step two, ultrasonically dispersed for 20 minutes to obtain a mixed solution, which is the tackifier and is recorded as component A; Step five, preparation of penetration enhancer: Bis-ethylhexyloxyphenol methoxyphenyl triazine and methylene bis-benzotriazolyl tetramethylbutylphenol are mixed with water and ultrasonically dispersed for 30 minutes to obtain a mixed solution, which is the penetration enhancer and is recorded as component B; Step six, preparation of additive: The n-butyl dimethyl chlorosilane and 2-amino-5-bromo-4-isopropyl methyl benzoate are added into a reaction kettle, and after being stirred uniformly, the mixture is discharged to obtain an additive, which is the component C; Step seven, preparation of semi-finished product: The emulsified asphalt at 130-150℃ is uniformly introduced into the funnel of a high-speed shearing instrument, the switch of the high-speed shearing instrument is turned on, and the component A prepared in step four is uniformly poured into the high-speed shearing instrument at the same time, the shearing time is controlled to be 40-60s; then the component C prepared in step six is uniformly poured into the funnel of the high-speed shearing instrument, the shearing time is controlled to be 60-120s, and then the valve is opened to obtain a semi-finished product; Step eight, preparation of emulsion: The semi-finished product obtained in step seven is transferred into a low-speed development machine, the component B prepared in step five is added, and rotation is carried out at 800-1000r / min, and the time is controlled to be 8-10min to obtain a uniformly mixed emulsion; Step nine, preparation of high-permeability and high-viscosity fog seal layer material: The emulsion prepared in step eight is poured into an electric mixer, stirred at a speed of 200-300r / min at room temperature for 2min, then the dried sand is added into the electric mixer, and stirred at a speed of 400-600r / min for 60s, and then the finished product is transferred into a container to obtain a high-permeability and high-viscosity fog seal layer material.

Images