A HB500 grade wear-resistant and corrosion-resistant steel plate and its production method

By adding microalloying elements such as Nb, Cr and Ni to the steel plate and adopting unique smelting, rolling and heat treatment processes, the problems of low plasticity and toughness and high internal stress of existing wear-resistant and corrosion-resistant steel plates are solved, and HB500 grade steel plates with high wear resistance and corrosion resistance are achieved.

CN118326271BActive Publication Date: 2025-09-30ANGANG STEEL CO LTD
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Patent Information

Application Number
CN202410366547.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-03-28
Publication Date
2025-09-30
Estimated Expiration
2044-03-28

AI Technical Summary

Technical Problem

Existing wear-resistant and corrosion-resistant steel plates have the problems of requiring heterogeneous composite or surface heat treatment, low plasticity and toughness, large internal stress after water quenching, and poor corrosion resistance and wear resistance.

Method used

Nb is used to precipitate high-hardness particles to enhance the wear resistance of the steel plate, Cr and Ni are used to increase the natural corrosion potential of the steel plate, and wear-resistant and corrosion-resistant steel plates with a Brinell hardness of 500HB are produced through unique smelting, rolling and heat treatment processes. The rolling and tempering heat treatment processes are controlled to improve the toughness and plasticity of the steel.

Benefits of technology

The wear and corrosion resistance is more than 1.2 times that of ordinary NM500, the surface hardness of the steel plate is ≥HB500, the tensile strength is ≥1400MPa, the impact energy value at -40℃ is ≥27J, and the elongation is ≥11%.

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Abstract

The present invention relates to an HB500 grade wear-resistant and corrosion-resistant steel plate and a production method thereof. The chemical composition of the steel plate is as follows by weight: C: 0.26% to 0.29%, Si: 0.2% to 0.4%, Mn: 0.2% to 0.4%, Nb: 0.10% to 0.20%, Cr: 3.40% to 3.60%, Al: 0.45% to 0.55%, Ni: 1.6% to 1.8%, 2.1%≤Al+Ni≤2.2%, and the balance is Fe and unavoidable impurities; impurity elements in the steel are controlled as follows: P≤0.010%, S≤0.002 %, [N]≤0.0030%, [H]≤0.00010%, [O]≤0.0010%, and retained austenite content of 7% to 9%; the present invention utilizes Nb to precipitate high-hardness particles to enhance the wear resistance of the steel plate, utilizes Cr and Ni to increase the natural corrosion potential of the steel plate, and plays a role in inhibiting corrosion by fluids such as seawater; adopts smelting, refining, slab continuous casting, heating and slow cooling, slab heating, controlled rolling, steel plate slow cooling, and tempering heat treatment processes to produce wear-resistant and corrosion-resistant steel plates with a Brinell hardness of 500HB, which have wear resistance and corrosion resistance that is more than 1.2 times that of ordinary low-alloy wear-resistant steel plates with the same hardness.
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Description

Technical Field

[0001] The present invention relates to the technical field of metal materials, and in particular to an HB500-grade wear-resistant and corrosion-resistant steel plate and a production method thereof. Background Art

[0002] Wear-resistant and corrosion-resistant steel is mainly used to manufacture certain moving parts of mechanical equipment working in corrosive and wear environments, such as pipelines, impellers, valves of corrosive flowing media in offshore dredging projects, urban garbage truck bodies, corrosive liquid agitators of chemical equipment, etc. The surface of the material is not only corroded by the environmental media but also wears away. In the early days, wear-resistant and corrosion-resistant projects at home and abroad were made of inexpensive Q235B and Q345B ordinary carbon structural steels, which had poor wear and corrosion resistance. Wear-resistant equipment made of stainless steel has good corrosion resistance but is expensive and not wear-resistant.

[0003] In recent years, some dredging companies have used ordinary low-alloy martensitic wear-resistant steel plates for the production of wear-resistant and corrosion-resistant structures. Although they have good wear resistance, they are not corrosion-resistant. Under the combined effects of complex environments such as seawater corrosion and coarse sand wear, they wear quickly and crack at a high rate, making it difficult to promote and apply them on a large scale. Therefore, it is urgent to develop new wear-resistant steel plates that are both wear-resistant and corrosion-resistant to meet the urgent needs of my country's wear-resistant and corrosion-resistant equipment.

[0004] The Chinese invention patent with publication number CN108930001B is a high-hardness wear-resistant steel plate for slurry dredging and its production method. The invention relates to a high-hardness wear-resistant steel for slurry dredging, whose composition by weight percentage is: C: 0.18-0.24%, Si≤0.01, Mn: 1.3-1.6%, P≤0.015%, S≤0.005%, Al: 0.2-1.0%, Cr: 0.3-1.2%, B: 0.001-0.002%, N≤0.005%; in addition, it contains one or both of Nb: 0.01-0.03% or Ti: 0.01-0.025%, and meets 6.65N <Nb+Ti≤0.045, the rest are Fe and unavoidable impurity elements; the wear-resistant steel has a yield strength of more than 1100MPa, a tensile strength of more than 1300MPa, an elongation ≥10%, a hardness of 450±30HBW, and an impact energy value of more than 20J at -40℃; the composition design of the wear-resistant steel of this invention takes into account both corrosion resistance and wear resistance, and is mainly used for the production of dredging pipelines in the fields of land reclamation and channel dredging. Its wear resistance is twice that of current ordinary pipes, thereby greatly improving dredging efficiency and reducing operating costs. However, this invention is an ordinary martensitic wear-resistant steel with low plasticity of the steel plate, large internal stress after forming, and easy formation of stress corrosion cracks.

[0005] Chinese invention patent publication number CN103725976B discloses a "highly wear-resistant bimetallic composite wear-resistant plate" comprising a low-carbon steel or low-carbon alloy steel plate welded with a wear-resistant alloy layer. The composition of the wear-resistant alloy layer, as a percentage of the total mass of the wear-resistant alloy layer, is as follows: C: 0.35-0.55%; Si: 2-2.4%; Mn: 2.7-3.2%; Cr: 11-12.5%; Mo: 2.5-2.9%; V: 0.7-1.8%; W: 2.2-3.6%; B: 0.7-1.1%; the remainder being iron. This plate has the advantages of ensuring a smooth surface and excellent wear resistance. However, this technical solution utilizes a bimetallic composite cladding process, which is complex and costly. Due to the high hardness of the cladding layer, the steel plate cannot be formed or processed.

[0006] The Chinese invention patent with publication number CN109881122A, "High wear-resistant and corrosion-resistant large tillage depth rotary blade material and its preparation method", discloses a high wear-resistant and corrosion-resistant large tillage depth rotary blade material and its preparation method. The rotary blade material is based on 60Si2Mn and 50CrVA steel alloy components, and Nb and Al elements are added. By mass fraction, it includes: C: 0.30% to 0.45%, Si: 0.20% to 0.60%, Mn: 1.50% to 2.30%, Cr: 1.50%~3.00%, Ni: 0.10%~0.30%, V: 0.10%~0.30%, Al: 0.10%~0.30%, Nb: 0.01%~0.05%, P<0.035%, S<0.035%, Fe balance. The material of the invention is hard on the surface and tough on the core, and is suitable for preparing long-life and deep-ploughing rotary tiller blades; the rotary tiller blades after surface treatment with composite rare earth boron carbonitriding and optimization of alloy composition have excellent wear resistance. The patent has good abrasion resistance, but the production process is complicated and requires surface heat treatment.

[0007] Chinese Patent 4, Hunan Valin Lianyuan Iron and Steel Co., Ltd., Liang Liang, Wang Hongbing, Wen Changfei, etc. applied for invention patent with publication number CN111575581A "A martensitic wear-resistant steel plate resistant to acid corrosion and its manufacturing method", the invention discloses a martensitic wear-resistant steel plate resistant to acid corrosion, which includes, by mass percentage, 0.14wt%≤C≤0.22wt%; 0.30wt%≤Si≤0.60wt%; 0.30wt%≤Mn≤1.00wt%; 0.010wt%≤Ti≤0.020wt%; 0.02wt%≤Nb≤0.04wt% t%; 0.50wt%≤Ni≤1.0wt%; 0.20wt%≤Cu≤0.50wt%; 0.9wt%≤Cr≤1.3wt%; 0.08wt%≤Sb≤0.12wt%; 0.0010wt%≤B≤0.0020wt%; 0<S≤0.003wt%; 0<P≤0.012wt%; The acid-corrosion-resistant martensitic wear-resistant steel plate can take into account the problems of steel plate hardness, plasticity, toughness, wear resistance and corrosion resistance. This patent requires water-cooling quenching heat treatment, has large internal stress, is prone to cracking and deformation, and is only suitable for acid corrosion.

[0008] Japanese Patent 1, invention patent of JIFI Steel Co., Ltd., Yusuke Terasawa; Naoki Takayama; Kenji Hayashi; Kazukuni Hase, application publication number CN109072367A, "Wear-resistant steel plate and method for manufacturing wear-resistant steel plate", discloses a steel plate having the following composition and structure, the composition is calculated by mass percentage: C: 0.10% to 0.23%, Si: 0.01% to 1.0%, Mn: 0.30% to 3.00%, P: less than 0.025%, S: less than 0.02% The invention relates to a wear-resistant steel plate comprising 0.01% to 2.00% Cr, 0.001% to 0.100% Al, and less than 0.01% N, with the remainder being Fe and unavoidable impurities, wherein the volume fraction of martensite at a depth of 1 mm from the surface of the wear-resistant steel plate is 90% or more, the original austenite grain size at the center of the plate thickness of the wear-resistant steel plate is less than 80 μm, and the hardness at a depth of 1 mm from the surface of the wear-resistant steel plate is 360 to 490 HBW in terms of Brinell hardness. 10 / 3000 wear-resistant steel plate and method for manufacturing wear-resistant steel plate, but the steel plate has a complex alloy composition, high cost, and only ordinary wear resistance.

[0009] It can be seen that the existing patents for wear-resistant and corrosion-resistant steel plates have the following deficiencies:

[0010] 1. Requires heterogeneous composite or surface heat treatment;

[0011] 2. Low plasticity and toughness;

[0012] 3. The internal stress is large after water quenching;

[0013] 4. Poor corrosion resistance and wear resistance. Summary of the Invention

[0014] The present invention provides an HB500-level wear-resistant and corrosion-resistant steel plate and a production method thereof. The new wear-resistant and corrosion-resistant concept is adopted, and Nb is used to precipitate high-hardness particles to enhance the wear resistance of the steel plate. Cr and Ni are used to increase the natural corrosion potential of the steel plate, thereby inhibiting corrosion by fluids such as seawater. Ni is used to expand the austenite phase region, increase the amount of retained austenite in the steel, and improve the toughness and plasticity of the steel. A unique smelting, rolling, and heat treatment production process is adopted to produce a wear-resistant and corrosion-resistant steel plate with a Brinell hardness of 500HB, which has wear resistance and corrosion resistance that is more than 1.2 times that of ordinary low-alloy wear-resistant steel plates with the same hardness.

[0015] In order to achieve the above object, the present invention adopts the following technical solutions:

[0016] A HB500 grade wear-resistant and corrosion-resistant steel plate, wherein the chemical composition of the steel plate is as follows by weight: C: 0.26% to 0.29%, Si: 0.2% to 0.4%, Mn: 0.2% to 0.4%, Nb: 0.10% to 0.20%, Cr: 3.40% to 3.60%, Al: 0.45% to 0.55%, Ni: 1.6% to 1.8%, 2.1%≤Al+Ni≤2.2%, the balance being Fe and unavoidable impurities; impurity elements in the steel are controlled as follows: P≤0.010%, S≤0.002%, [N]≤0.0030%, [H]≤0.00010%, [O]≤0.0010%, and the retained austenite content is 7% to 9%.

[0017] A method for producing HB500 grade wear-resistant and corrosion-resistant steel plates, comprising the following process steps: smelting, refining, slab continuous casting, heating and slow cooling, slab heating, controlled rolling, steel plate slow cooling, and tempering heat treatment; wherein:

[0018] 1) Refining: RH vacuum cycle time ≥ 18min;

[0019] 2) Continuous casting: The target superheat of the tundish is controlled at ≤25°C, and the casting process is protected. Electromagnetic stirring or soft pressure is used, and intermediate cooling is used in the secondary cooling zone. The continuous casting billet casting speed is controlled at 1.1-1.3m / min.

[0020] 3) Rolling: The temperature of the heating and soaking section is 1200-1280°C, and the soaking time is greater than 2.0 hours. During rolling, two stages of controlled rolling are adopted, namely rough rolling and finishing rolling. The starting rolling temperature of the rough rolling stage is ≥1100°C, and the finishing rolling temperature is controlled at ≥1000°C; the starting rolling temperature of the finishing rolling is 950-1000°C, the finishing rolling reduction ratio is ≥60%, and the finishing rolling temperature is 870-920°C. After rolling, the steel is air-cooled to room temperature.

[0021] 4) Tempering heat treatment: The tempering temperature is 270-300°C, and the tempering holding time is 5-8 min / mm.

[0022] Furthermore, after the continuous casting slab comes off the line, it enters a slow cooling pit for heating and slow cooling. The starting temperature of the slab slow cooling is required to be ≥400°C, and it is heated to 630-650°C at a heating rate of ≤50°C / second. After being kept warm for 8-12 hours, it is slowly cooled to less than 400°C with the furnace and air-cooled to room temperature after being taken out of the furnace.

[0023] Furthermore, the surface hardness of the steel plate is ≥ HB500, the tensile strength is ≥ 1400 MPa, and the corrosion resistance and wear resistance are more than 1.2 times that of ordinary NM500.

[0024] Furthermore, the thickness of the ingot is 200 to 250 mm.

[0025] Compared with the prior art, the present invention has the following beneficial effects:

[0026] 1) Nb is used to precipitate high-hardness particles to increase the wear resistance of the steel plate, refine the grains to improve toughness, and Cr and Ni are used to increase the natural corrosion potential of the steel plate, which inhibits corrosion from fluids such as seawater, thereby reducing the occurrence of corrosion and ensuring the corrosion resistance of the steel. The corrosion resistance and wear resistance of the steel plate are more than 1.2 times that of ordinary NM500;

[0027] 2) The chemical composition design of the steel plate of the present invention is mainly characterized by microalloying of chromium, nickel, and niobium. The alloy content is relatively low, which facilitates smelting and continuous casting. The ingot is air-cooled through controlled rolling and then subjected to low-temperature tempering heat treatment to obtain HB500 grade steel plate with excellent plasticity, toughness, and wear resistance.

[0028] 3) Using Ni to expand the austenite phase region, increase the amount of retained austenite in the steel, and control the retained austenite content in the steel to 7% to 9%, ensuring that the steel plate has good plasticity and toughness;

[0029] 4) Ensure that the steel plate has a -40°C AKV of ≥27J and an elongation A of ≥11%;

[0030] 5) Make the surface hardness of the steel plate ≥ HB500 and the tensile strength ≥ 1400MPa;

[0031] 6) Avoid heating cracking by controlling the temperature and soaking time of the heating soaking section, ensure that the alloy elements are fully dissolved, and effectively remove the casting internal stress in the steel billet by controlling the hot delivery or heating slow cooling and tempering temperature and time. DETAILED DESCRIPTION

[0032] The specific embodiments of the present invention are further described below:

[0033] The chemical composition of the steel plate designed in this invention features microalloying of chromium, nickel, and niobium, resulting in a relatively low alloy content, facilitating smelting and continuous casting. The ingot is air-cooled through controlled rolling and then subjected to low-temperature tempering heat treatment, resulting in HB500-grade steel plate with excellent ductility, toughness, and wear resistance. The present invention provides an HB500-grade wear-resistant and corrosion-resistant steel plate. The chemical composition of the steel plate is as follows by weight: C: 0.26%-0.29%, Si: 0.2%-0.4%, Mn: 0.2%-0.4%, Nb: 0.10%-0.20%, Cr: 3.40%-3.60%, Al: 0.45%-0.55%, Ni: 1.6%-1.8%, 2.1%≤Al+Ni≤2.2%, and the balance is Fe and unavoidable impurities; impurity elements in the steel are controlled as follows: P≤0.010%, S≤0.002%, [N]≤0.0030%, [H]≤0.00010%, [O]≤0.0010%, and the retained austenite content is 7-9%.

[0034] A method for producing HB500 grade wear-resistant and corrosion-resistant steel plates, comprising the following process steps: smelting, refining, slab continuous casting, heating and slow cooling, slab heating, controlled rolling, steel plate slow cooling, and tempering heat treatment; wherein:

[0035] 1) Refining: RH vacuum cycle time ≥ 18min;

[0036] 2) Continuous casting: The thickness of the slab is 200-250mm, the target superheat of the tundish is controlled at ≤25℃, the casting is protected throughout, electromagnetic stirring or soft pressure is used, intermediate cooling is used in the secondary cooling zone, and the continuous casting slab pulling speed is controlled at 1.1-1.3m / min. After the continuous casting slab comes off the line, it is placed in a slow cooling pit for heating and slow cooling. The slab slow cooling starting temperature is required to be ≥400℃, and it is heated to 630-650℃ at a heating rate of ≤50℃ / second. After holding for 8-12 hours, it is slowly cooled to less than 400℃ with the furnace, and then air-cooled to room temperature.

[0037] 3) Rolling: The temperature of the heating and soaking section is 1200-1280°C, and the soaking time is greater than 2.0 hours. During rolling, two stages of controlled rolling are adopted, namely rough rolling and finishing rolling. The starting rolling temperature of the rough rolling stage is ≥1100°C, and the finishing rolling temperature is controlled at ≥1000°C; the starting rolling temperature of the finishing rolling is 950-1000°C, the finishing rolling reduction ratio is ≥60%, and the finishing rolling temperature is 870-920°C. After rolling, the steel is air-cooled to room temperature.

[0038] 4) Tempering heat treatment: The tempering temperature is 270-300°C, and the tempering holding time is 5-8 min / mm.

[0039] The chemical composition design reasons of the HB500 grade wear-resistant and corrosion-resistant steel plate described in the present invention are as follows:

[0040] C: To ensure that the martensite in the steel plate has a hardness of HB500 after air cooling, a considerable carbon content is required. Carbon can also form carbides with Nb and Cr, increasing wear resistance. Excessive carbon content reduces low-temperature toughness. To ensure high wear resistance and good low-temperature toughness, the carbon content in this invention is controlled to 0.26% to 0.29%.

[0041] Si: Its main functions are solid solution strengthening and deoxidation. It is a non-carbide-forming element that dissolves in ferrite and austenite in the form of solid solution, improving the strength and hardness of steel. It has a significant solid solution strengthening effect. Therefore, the Si content in the present invention is controlled at 0.2% to 0.4%.

[0042] Mn: Its main function is solid solution strengthening. However, if its content is too high, it is easy to form central segregation, which makes the center of the slab prone to cracking. Therefore, in the present invention, the Mn content is controlled at 0.2% to 0.4%.

[0043] Nb: An important additive element in this patent, its main function is to increase wear resistance, refine grains and improve toughness. Nb is a strong carbon and nitrogen compound forming element. It combines with C and N in steel to form NbC and Nb(C,N) compounds, which have the characteristics of high chemical stability and high hardness, and improve the wear resistance of steel. In addition, the addition of 0.1% to 0.2% Nb element causes strain induction during the rolling process of low-temperature austenite structure, thereby causing a large amount of carbonitrides to precipitate, which has the effect of increasing hardenability and precipitation strengthening; Nb dissolved in austenite inhibits austenite recrystallization during the two-stage rolling process and refines the austenite grains. However, if the Nb content is too high, it will affect the mechanical properties of the steel plate. Therefore, in the present invention, the Nb content is controlled at 0.10% to 0.20%.

[0044] Al: An effective element for deoxidation and nitrogen fixation. It can reduce oxide inclusions in steel and purify steel quality. It can also expand the austenite phase region, which is beneficial to the stability of retained austenite. Too high an Al content will cause casting difficulties and form a large amount of Al2O3 inclusions in the steel, resulting in poor ductility. In order to control the austenite content in the steel to 5% to 8%, the Al content in the present invention is controlled to 0.45% to 0.55%.

[0045] Cr: This patent focuses on adding elements. An appropriate amount of Cr is beneficial to improving the natural corrosion potential of the material and plays a role in inhibiting corrosion, thereby reducing the occurrence of corrosion and ensuring the corrosion resistance of the steel. Cr can also reduce the critical cooling rate, improve the hardenability of the steel plate, form a fine martensite structure, and ensure that the hardness of the steel plate after air cooling is above 500HB. In addition, chromium is a strong carbide-forming element and can form a variety of carbides in steel to ensure the wear resistance of the steel plate. However, excessive addition of Cr will reduce the weldability. Therefore, the Cr content of the present invention is controlled at 3.40% to 3.60%.

[0046] Ni: It helps to increase the natural corrosion potential of the steel plate and inhibits corrosion, thereby reducing the occurrence of corrosion and ensuring the corrosion resistance of the steel. It can also expand the austenite phase, increase the amount of retained austenite in the steel, and improve the toughness and plasticity of the steel. This patent controls Ni: 1.6-1.8%. Since Al, Ni and Al both promote the content of retained austenite, to prevent excessive or insufficient retained austenite, the total amount of Al + Ni is controlled. Therefore, this patent stipulates that 2.1% ≤ Al + Ni ≤ 2.2%.

[0047] A high content of impurity elements will reduce plasticity and toughness. Therefore, in order to ensure good plasticity and toughness, the impurity elements P≤0.010%, S≤0.002%, [H]≤0.00010%, [O]≤0.0010%, and [N]≤0.0030% in this patent.

[0048] The design principle of the production method of the HB500 grade wear-resistant and corrosion-resistant steel plate described in the present invention is as follows:

[0049] The steel plate production method of the present invention includes the following process: smelting, refining, slab continuous casting, heating and slow cooling, slab heating, controlled rolling, steel plate slow cooling, and tempering heat treatment;

[0050] 1) Smelting process characteristics: The present invention carries out RH degassing time control during refining, and the RH vacuum cycle time is ≥18min. Through long-term vacuum treatment, the molten steel [N]≤0.0040%, [O]≤0.0010%, and [H]≤0.00015%. The characteristics of the continuous casting of the present invention are: the target superheat of the tundish is controlled at ≤25℃; the casting is protected throughout the process, the secondary cooling adopts a medium cooling intensity mode, the continuous casting billet pulling speed is controlled to 1.1-1.3m / min, and the billet thickness is The thickness is 200-250mm. Electromagnetic stirring or light pressure is used during continuous casting to reduce central segregation. In order to avoid cracking of the billet, the continuous casting billet is delivered hot. If hot delivery cannot be arranged, it will be put into the slow cooling pit for heating and slow cooling after leaving the line. The starting temperature of the slab slow cooling is required to be ≥400℃. It is heated to 630-650℃ at a heating rate of ≤50℃ / second. After keeping warm for 8-12 hours, it is slowly cooled to less than 400℃ with the furnace and air-cooled to room temperature. The purpose of heating and slow cooling is to effectively remove the hydrogen content and casting internal stress in the billet.

[0051] 2) Rolling process characteristics: The temperature of the heating and soaking section is 1200-1280°C, and the soaking time is greater than 2.0 hours. The purpose is to avoid heating cracking and ensure sufficient solid solution of alloy elements. Before rolling, the roller cooling water and controlled cooling water are turned off, and the roller cooling water is turned to the minimum; during rolling, two stages of rough rolling and finishing rolling are adopted. The purpose is to fully refine and homogenize the hot-rolled structure; the starting rolling temperature of the rough rolling stage is ≥1100°C, and the final rolling temperature is controlled at ≥1000°C; the starting rolling temperature of the finishing rolling is 950-1000°C, the finishing rolling reduction rate is ≥60%, the purpose is to refine the original austenite structure, and the final rolling temperature is 870-920°C; after rolling, the steel is air-cooled to room temperature.

[0052] 3) Heat treatment process characteristics: The tempering temperature is 270-300°C, and the tempering holding time is 5-8 min / mm. The purpose is to further remove the internal stress of the steel plate and improve the plasticity and toughness of the steel plate.

[0053] The following examples are implemented under the premise of the technical solution of the present invention, and provide detailed implementation methods and specific operating processes, but the scope of protection of the present invention is not limited to the following examples. The methods used in the following examples are conventional methods unless otherwise specified.

[0054] [Example]

[0055] According to the chemical composition and production process of the present invention, the actual chemical composition of the steel of the present invention is shown in Table 1, the smelting process is shown in Table 2, the actual rolling process parameters of the steel example of the present invention are shown in Table 3, the heat treatment process parameters are shown in Table 4, the actual performance test results of the present invention are shown in Table 5, and the wear resistance test results are shown in Table 6.

[0056] Table 1 Example of smelting composition of steel grades of the present invention, Wt%

[0057]

[0058] Table 2 Smelting process of steel grades of the present invention

[0059]

[0060] Table 3 Actual rolling process parameters of steel examples of the present invention

[0061]

[0062] Table 4 Heat treatment process of steel examples of the present invention

[0063]

[0064] Table 5 Mechanical properties of steel examples of the present invention

[0065]

[0066] The wear and corrosion resistance of the experimental steel was tested using a rotary corrosion wear tester. The slurry concentration was 3.5% NaCl in industrial tap water mixed with 75% quartz sand. The slurry rotated at a speed of 3 m / s. After rubbing against a standard cylindrical specimen, the weight loss was compared with that of ordinary NM450. The test lasted for 8 hours. The results are shown in Table 6.

[0067] Table 6 Comparison of wear resistance and corrosion resistance of the present invention

[0068] Steel Type Wear loss ΔM / g Corrosion resistance and wear resistance comparison Ordinary NM500 0.792 1 1-1 0.634 1.25 1-2 0.629 1.26 2-1 0.639 1.24 2-2 0.634 1.25 3-1 0.644 1.23 3-2 0.649 1.22 4-1 0.638 1.24 4-2 0.628 1.26

[0069] It can be seen that the wear resistance and corrosion resistance of the steel plate of the present invention are more than 1.2 times that of ordinary wear-resistant steel plates.

Claims

1. A HB500 grade wear-resistant and corrosion-resistant steel plate, characterized in that: The chemical composition of the steel plate is as follows by weight: C: 0.26% to 0.29%, Si: 0.2% to 0.4%, Mn: 0.2% to 0.4%, Nb: 0.10% to 0.20%, Cr: 3.40% to 3.60%, Al: 0.45% to 0.55%, Ni: 1.6% to 1.8%, 2.1%≤Al+Ni≤2.2%, the balance being Fe and unavoidable impurities; impurity element control in the steel: P≤0.010%, S≤0.002%, [N]≤0.0030%, [H]≤0.00010%, [O]≤0.0010%, and retained austenite content is 7% to 9%; The production method of the steel plate includes the following process: smelting, refining, slab continuous casting, heating and slow cooling, slab heating, controlled rolling, steel plate slow cooling, and tempering heat treatment; wherein: 1) Refining: RH vacuum cycle time ≥ 18min; 2) Continuous casting: The target superheat of the tundish is controlled at ≤25°C, and the casting process is protected. Electromagnetic stirring or soft reduction is used, and intermediate cooling is used in the secondary cooling zone. The continuous casting billet drawing speed is controlled at 1.1-1.3 m / min. 3) Rolling: The temperature of the heating and soaking section is 1200-1280℃, and the soaking time is greater than 2.0 hours. During rolling, two stages of controlled rolling are adopted, namely rough rolling and finishing rolling. The starting rolling temperature of the rough rolling stage is ≥1100℃, and the finishing rolling temperature is controlled at ≥1000℃; the starting rolling temperature of the finishing rolling is 950-1000℃, the finishing rolling reduction rate is ≥60%, and the finishing rolling temperature is 870-920℃. After rolling, the steel is air-cooled to room temperature. 4) Tempering heat treatment: The tempering temperature is 270-300℃, and the tempering holding time is 5-8min / mm.

2. A method for producing HB500 grade wear-resistant and corrosion-resistant steel plate according to claim 1, characterized in that: The production method of the steel plate includes the following process: smelting, refining, slab continuous casting, heating and slow cooling, slab heating, controlled rolling, steel plate slow cooling, and tempering heat treatment; wherein: 1) Refining: RH vacuum cycle time ≥ 18min; 2) Continuous casting: The target superheat of the tundish is controlled at ≤25°C, and the casting process is protected. Electromagnetic stirring or soft reduction is used, and intermediate cooling is used in the secondary cooling zone. The continuous casting billet drawing speed is controlled at 1.1-1.3 m / min. 3) Rolling: The temperature of the heating and soaking section is 1200-1280℃, and the soaking time is greater than 2.0 hours. During rolling, two stages of controlled rolling are adopted, namely rough rolling and finishing rolling. The starting rolling temperature of the rough rolling stage is ≥1100℃, and the finishing rolling temperature is controlled at ≥1000℃; the starting rolling temperature of the finishing rolling is 950-1000℃, the finishing rolling reduction rate is ≥60%, and the finishing rolling temperature is 870-920℃. After rolling, the steel is air-cooled to room temperature. 4) Tempering heat treatment: The tempering temperature is 270-300℃, and the tempering holding time is 5-8min / mm.

3. The method for producing HB500 grade wear-resistant and corrosion-resistant steel plate according to claim 2, characterized in that: After the continuous casting slab comes off the line, it enters the slow cooling pit for heating and slow cooling. The starting temperature of the slab slow cooling is required to be ≥400℃, and it is heated to 630-650℃ at a heating rate of ≤50℃ / second. After keeping warm for 8-12 hours, it is slowly cooled to less than 400℃ with the furnace and air-cooled to room temperature.

4. The method for producing HB500 grade wear-resistant and corrosion-resistant steel plate according to claim 2, characterized in that: The surface hardness of the steel plate is ≥HB500, the tensile strength is ≥1400MPa, and the corrosion resistance and wear resistance are more than 1.2 times that of ordinary NM500.

5. The method for producing HB500 grade wear-resistant and corrosion-resistant steel plate according to claim 2, characterized in that: The thickness of the casting billet is 200 to 250 mm.

Citation Information

Patent Citations

  • High wear-resistant bimetallic composite wear-resistant plate

    CN103725976B

  • A high-hardness, wear-resistant steel plate for slurry dredging and its production method

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