Easy-to-recycle PETG copolyester and heat shrinkable film containing the same and recycling method thereof

By introducing the fourth monomer during the synthesis of PETG copolyester and introducing plastic degradation masterbatch into the heat shrink film, the degree of cracking of PETG copolyester during the thermal cracking process is improved, the problem of poor material performance after recovery is solved, efficient recycling and recycling of PETG copolyester materials is achieved, and the mechanical properties and aging resistance of the heat shrink film are improved.

CN118755065BActive Publication Date: 2025-03-21HENAN YINJINDA NEW MATERIALS CO LTD
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Patent Information

Application Number
CN202411252502.3
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-09-09
Publication Date
2025-03-21
Estimated Expiration
2044-09-09

AI Technical Summary

Technical Problem

After thermal cracking of existing PETG copolyester materials, the presence of dimers, trimers and other polymers leads to poor material performance after recovery, which cannot meet the use requirements of the heat-shrinkable film industry.

Method used

By introducing a certain proportion of the fourth monomer in the synthesis process of PETG copolyester and introducing plastic degradation masterbatch into each layer of the heat shrink film, the degree of cracking of the material during the thermal cracking process is improved, the generation of polymers is reduced, and the recovery capacity and performance of the material are improved.

Benefits of technology

It realizes efficient recycling and recycling of PETG copolyester materials, reduces recycling and regeneration costs, improves the mechanical properties and aging resistance of the heat shrink film, and meets the use requirements of the heat shrink film industry.

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Abstract

The present invention discloses an easily recyclable PETG copolyester and a heat shrinkable film containing the same and a recycling method thereof. The present invention introduces a certain proportion of the fourth monomer in the process of synthesizing the PETG copolyester, and introduces a certain proportion of plastic degradation masterbatch in each layer in the process of preparing the PETG heat shrinkable film, flexibly controls the chemical alcoholysis process of the heat shrinkable film, and realizes deep chemical alcoholysis of the heat shrinkable film by using a three-step alcoholysis method, better opens up the circulation process of the PETG industrial chain, realizes the free preparation of high-performance recyclable heat shrinkable films, reduces the recycling cost of the PETG heat shrinkable film, and the PETG heat shrinkable film prepared by the process has good aging resistance, which greatly improves the benefits of the enterprise.
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