Light-emitting device, electronic device, electronic device, and amine compound

Abstract

Embodiments provide an amine-based compound, a light-emitting device including the amine-based compound, an electronic device including the light-emitting device, and an electronic device including the light-emitting device. A light-emitting device including a first electrode, a second electrode facing the first electrode, and an interlayer between the first electrode and the second electrode, in which the interlayer includes an emission layer and a hole transport region between the first electrode and the emission layer, and the hole transport region includes an amine compound represented by Formula 1, where Formula 1 is explained in the specification: [Formula 1] # imgabs0 #

Description

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS

[0002] This application claims priority to and the benefit of Korean Patent Application No. 10-2023-0078353 filed in the Korean Intellectual Property Office on June 19, 2023, the entire contents of which are incorporated herein by reference. Technical Field

[0003] The present disclosure relates to a light-emitting device including an amine compound, an electronic device and an electronic device each including the light-emitting device, and the amine compound. Background Art

[0004] Among light-emitting devices, organic light-emitting devices are self-emissive devices that have wide viewing angles, high contrast, short response times, and superior characteristics in terms of brightness, driving voltage, and response speed compared to devices in the related art.

[0005] As an example, an organic light-emitting device may have a structure in which a first electrode is arranged on a substrate, and a hole transport region, an emission layer, an electron transport region, and a second electrode are sequentially formed on the first electrode. Holes provided from the first electrode move toward the emission layer through the hole transport region, and electrons provided from the second electrode move toward the emission layer through the electron transport region. Carriers (such as holes and electrons) recombine in the emission layer to generate excitons. Excitons can transition from an excited state to a ground state, thereby generating light.

[0006] It is to be understood that this background technology section is intended, in part, to provide a useful background for understanding the technology. However, this background technology section may also include ideas, concepts, or cognitions that were not part of the known or understood by a person skilled in the relevant art before the corresponding effective filing date of the subject matter disclosed herein. Summary of the invention

[0007] Embodiments include a light-emitting device including a novel amine compound, an electronic device and an electronic device each including a light-emitting device, and an amine compound.

[0008] Additional aspects will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the embodiments.

[0009] According to an embodiment, the light emitting device may include a first electrode, a second electrode facing the first electrode, and an interlayer between the first electrode and the second electrode, wherein

[0010] The interlayer may include an emissive layer and a hole transport region between the first electrode and the emissive layer, and

[0011] The hole transport region may include an amine compound represented by Formula 1:

[0012] [Formula 1]

[0013]

[0014] In formula 1,

[0015] L 1 and L 2 may be independently a single bond, unsubstituted or substituted by at least one R 10a Substituted C 5 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0016] n1 and n2 may each independently be an integer selected from 1 to 3,

[0017] Z 1 To Z 3 and E 1 can be independently deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ),

[0018] e1 can be an integer selected from 1 to 7,

[0019] R 11 , R 12 and R 2 To R 5 can be independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ),

[0020] a11 may be an integer selected from 0 to 4,

[0021] a12 may be an integer selected from 0 to 3,

[0022] a2 may be an integer selected from 0 to 3,

[0023] a3 to a5 may each independently be an integer selected from 0 to 4,

[0024] R 10a Can be:

[0025] deuterium, -F, -Cl, -Br, -I, hydroxy, cyano or nitro;

[0026] Each unsubstituted or substituted C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl or C 1 -C 60 Alkoxy: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 11 )(Q 12 )(Q 13 )、-N(Q 11 )(Q 12 )、-B(Q 11 )(Q 12 )、-C(=O)(Q 11 )、-S(=O) 2 (Q 11 )、-P(=O)(Q 11 )(Q 12 ) or any combination thereof;

[0027] Each unsubstituted or substituted C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C6 -C 60 Arylthio, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 21 )(Q 22 )(Q 23 )、-N(Q 21 )(Q 22 )、-B(Q 21 )(Q 22 )、-C(=O)(Q 21 )、-S(=O) 2 (Q 21 )、-P(=O)(Q 21 )(Q 22 ) or any combination thereof; or

[0028] -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 ) or -P(=O)(Q 31 )(Q 32 ),and

[0029] Q 1 To Q 3 , Q 11 To Q13 , Q 21 To Q 23 and Q 31 To Q 33 can be independently: hydrogen; deuterium; -F; -Cl; -Br; -I; hydroxyl; cyano; nitro; C 1 -C 60 Alkyl; C 2 -C 60 Alkenyl; C 2 -C 60 Alkynyl; C 1 -C 60 alkoxy; or each unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 C substituted by heterocyclic group or any combination thereof 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl.

[0030] In an embodiment, the hole transport region may include a hole injection layer, a hole transport layer, an emission assisting layer, an electron blocking layer, or any combination thereof, and at least one of the hole transport layer and the hole injection layer may include an amine compound.

[0031] In an embodiment, the light emitting device may further include: a nitrogen-containing C 1 -C 60 A second compound of a heterocyclic group, a third compound including a group represented by Formula 3 explained herein, a fourth compound which may be a delayed fluorescence compound, a fifth compound which is an organic metal compound containing a transition metal, or any combination thereof, wherein the second compound, the third compound, the fourth compound and the fifth compound may be different from each other, and Formula 3 is explained below.

[0032] In an embodiment, the second compound may include a pyridyl group, a pyrimidyl group, a pyrazinyl group, a pyridazinyl group, a triazinyl group, or any combination thereof.

[0033] In an embodiment, the fourth compound may include at least one cyclic group including boron (B) and nitrogen (N) as ring-forming atoms.

[0034] In an embodiment, the fifth compound may include a platinum atom and a tetradentate ligand bonded to the platinum atom; and one of bonds between the platinum atom and the tetradentate ligand may be a platinum-carbene bond.

[0035] In an embodiment, the fifth compound may include an iridium atom and a tetradentate ligand bonded to the iridium atom; and one of bonds between the iridium atom and the tetradentate ligand may be an iridium-carbene bond.

[0036] In an embodiment, the emission layer may include the second compound, the third compound, the fourth compound, the fifth compound, or any combination thereof; and the emission layer may emit blue light.

[0037] According to an embodiment, an electronic device may include a light emitting device.

[0038] In an embodiment, the electronic device may further include a color filter, a color conversion layer, a touch screen layer, a polarization layer, or any combination thereof.

[0039] In an embodiment, the electronic device may further include a thin film transistor, wherein the thin film transistor may include a source electrode and a drain electrode, and the first electrode of the light emitting device may be electrically connected to the source electrode or the drain electrode.

[0040] According to an embodiment, an electronic device may include a light emitting device.

[0041] In embodiments, the electronic device may be a flat panel display, a curved display, a computer monitor, a medical monitor, a television (TV), a billboard, an indoor light, an outdoor light, a signal light, a head-up display, a fully transparent display, a partially transparent display, a flexible display, a rollable display, a foldable display, a retractable display, a laser printer, a phone, a portable phone, a tablet personal computer, a tablet mobile computer, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a microdisplay, a three-dimensional (3D) display, a virtual reality display, an augmented reality display, a vehicle, a video wall with multiple displays stitched together, a theater screen, a stadium screen, a light therapy device, or a sign.

[0042] According to an embodiment, the amine compound may be represented by Formula 1, which is explained herein.

[0043] In an embodiment, Z 1 To Z 3 and E 1 may be each independently unsubstituted or substituted with at least one R 10a Substituted phenyl, naphthyl, fluorenyl, carbazolyl, dibenzofuranyl, dibenzothiophenyl, azacarbazolyl, azadibenzofuranyl, azadibenzothiophenyl, pyridyl, pyrimidinyl, pyrazinyl, quinolyl or quinoxalinyl.

[0044] In an embodiment, Z 1 To Z 3 and E 1 may each independently be a group represented by one of Formula 1A-1 to Formula 1A-16 explained below.

[0045] In an embodiment, in Formula 1, The moiety represented may be a moiety represented by one of Formulae 1B-1 to 1B-14 explained below.

[0046] In an embodiment, Z 2 and Z 3 Can be different from each other.

[0047] In an embodiment, the amine compound may be represented by Formula 1-1, which is explained below.

[0048] In an embodiment, the amine compound may be one of Compound 1 to Compound 206, which are explained below.

[0049] It is to be understood that the above embodiments have been described in a generic and illustrative sense only and not for purposes of limitation, and that the present disclosure is not limited to the above embodiments. BRIEF DESCRIPTION OF THE DRAWINGS

[0050] The above and other aspects and features of the present disclosure will become more apparent by describing in detail embodiments thereof with reference to the accompanying drawings, in which:

[0051] Figure 1 is a schematic cross-sectional view of a light emitting device according to an embodiment;

[0052] Figure 2 is a schematic cross-sectional view of an electronic device according to an embodiment;

[0053] Figure 3 is a schematic cross-sectional view of an electronic device according to another embodiment;

[0054] Figure 4 is a schematic perspective view of an electronic device including a light emitting device according to an embodiment;

[0055] Figure 5 is a schematic perspective view of the exterior of a vehicle as an electronic device including a light emitting device according to an embodiment; and

[0056] FIG. 6A to FIG. 6C Each is a schematic diagram of the interior of a vehicle according to an embodiment. DETAILED DESCRIPTION

[0057] The present disclosure will now be described more fully below with reference to the attached drawings in which embodiments are shown. However, the present disclosure may be embodied in different forms and should not be construed as being limited to the embodiments set forth herein. On the contrary, these embodiments are provided so that the present disclosure will be thorough and complete and will fully convey the scope of the present disclosure to those skilled in the art.

[0058] In the drawings, the size, ratio, and dimensions (eg, thickness) of elements may be exaggerated for ease of description and for clarity. Like reference numerals and reference characters refer to like elements throughout.

[0059] In the specification, it will be understood that when an element (or region, layer, portion, etc.) is referred to as being "on", "connected to" or "coupled to" another element (or region, layer, portion, etc.), it may be directly on, directly connected to or directly coupled to the other element (or region, layer, portion, etc.), or one or more intervening elements may be present therebetween. In a similar sense, when an element (or region, layer, portion, etc.) is described as "covering" another element (or region, layer, portion, etc.), it may directly cover the other element (or region, layer, portion, etc.), or one or more intervening elements may be present therebetween.

[0060] In the specification, when an element is "directly on," "directly connected to," or "directly coupled to" another element, there are no intervening elements. For example, "directly on" may mean that two layers or two elements are disposed without another element (such as an adhesive element) between them.

[0061] In the specification, expressions used in the singular such as “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.

[0062] In the specification, the term "and / or" includes any and all combinations of one or more related listed items. For example, "A and / or B" can be understood to mean "A, B, or A and B". The terms "and" and "or" can be used in a connecting sense or a separating sense and can be understood to be equivalent to "and / or".

[0063] In the specification and claims, the term "at least one of" is intended to include the meaning of "at least one selected from the group consisting of" for the purposes of its meaning and interpretation. For example, "at least one of A, B, and C" may be understood to mean only A, only B, only C, or any combination of two or more of A, B, and C, such as ABC, ACC, BC, or CC. When following a list of elements, the term "at least one of" modifies the entire list of elements and does not modify the individual elements of the list.

[0064] It will be understood that although the terms first, second, etc. may be used to describe various elements in this article, these elements should not be limited by these terms. These terms are only used to distinguish one element from another element. Therefore, without departing from the teachings of the present disclosure, the first element may be referred to as the second element. Similarly, without departing from the scope of the present disclosure, the second element may be referred to as the first element.

[0065] For ease of description, spatially relative terms such as "below," "under," "down," "above," or "on" may be used herein to describe the relationship between one element or component and another element or component as illustrated in the accompanying drawings. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the accompanying drawings. For example, in the case where the device illustrated in the accompanying drawings is turned over, a device that is "below" or "below" another device may be placed "above" the other device. Accordingly, the illustrative term "below" may include both a lower position and an upper position. The device may also be oriented in other directions, and therefore the spatially relative terms may be interpreted differently depending on the orientation.

[0066] As used herein, the term "about" or "approximately" includes the stated value and means within an acceptable range of deviation of the stated value determined by one of ordinary skill in the art taking into account the measurement in question and the errors associated with the measurement of the stated quantity (i.e., the limitations of the measurement system). For example, "about" can mean within one or more standard deviations of the stated value, or within ±20%, ±10%, or ±5% of the stated value.

[0067] It should be understood that the terms “comprises,” “comprising,” “include,” “including,” “have,” “having,” “contains,” and “containing” and the like are intended to indicate the presence of the recited features, integers, steps, operations, elements, components, or combinations thereof in the present disclosure, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, or combinations thereof.

[0068] Unless otherwise defined or implied herein, all terms (including technical terms and scientific terms) used have the same meaning as those commonly understood by those skilled in the art to which the present disclosure belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning consistent with their meaning in the context of the relevant art, and should not be interpreted in an ideal or overly formal sense unless clearly defined in the specification.

[0069] Embodiments provide a light-emitting device (eg, an organic light-emitting device), which may include: a first electrode; a second electrode facing the first electrode; and an interlayer between the first electrode and the second electrode, wherein

[0070] The interlayer may include: an emission layer; and a hole transport region between the first electrode and the emission layer, and the hole transport region may include an amine compound represented by Formula 1:

[0071] [Formula 1]

[0072]

[0073] The details of Formula 1 are the same as described herein.

[0074] In an embodiment, the first electrode of the light emitting device may be an anode,

[0075] The second electrode of the light emitting device may be a cathode,

[0076] The interlayer may further include an electron transport region between the emissive layer and the second electrode,

[0077] The hole transport region may include a hole injection layer, a hole transport layer, an emission assisting layer, an electron blocking layer, or any combination thereof, and

[0078] The electron transport region may include a hole blocking layer, an electron transport layer, an electron injection layer, or any combination thereof.

[0079] In an embodiment, at least one of the hole transport layer and the hole injection layer may include the amine compound represented by Formula 1. Accordingly, the amine compound represented by Formula 1 may be used as a hole transport material.

[0080] In another embodiment, an emission layer of a light emitting device may include an amine compound represented by Formula 1.

[0081] In an embodiment, the light emitting device may further include: a nitrogen-containing C 1 -C 60 a second compound of a heterocyclic group, a third compound including a group represented by Formula 3, a fourth compound capable of emitting delayed fluorescence (e.g., a delayed fluorescence compound), a fifth compound being an organic metal compound containing a transition metal, or any combination thereof, and

[0082] The second compound, the third compound, the fourth compound and the fifth compound may be different from each other:

[0083] [Formula 3]

[0084]

[0085] In formula 3,

[0086] Cyclo 71 and CY 72 can be independently π-electron-rich C 3 -C 60 Cyclic group or pyridyl group,

[0087] X 71 can be: a single bond; or a linking group comprising O, S, N, B, C, Si or any combination thereof, and

[0088] * indicates a bonding site to any atom included in the remaining parts other than Formula 3 in the third compound.

[0089] In an embodiment, the second compound, the third compound, the fourth compound, and the fifth compound may each include at least one deuterium atom.

[0090] In another embodiment, the second compound may include at least one silicon atom.

[0091] In another embodiment, the third compound may include at least one silicon atom.

[0092] In an embodiment, the light emitting device may further include a second compound and a third compound; and at least one of the second compound and the third compound may each independently include at least one deuterium atom, at least one silicon atom, or any combination thereof.

[0093] In an embodiment, the light emitting device (e.g., the emission layer of the light emitting device) may further include a second compound. The second compound may include at least one deuterium atom. For example, in addition to the second compound, the light emitting device (e.g., the emission layer of the light emitting device) may further include a third compound, a fourth compound, a fifth compound, or any combination thereof.

[0094] In another embodiment, the light emitting device (e.g., the emission layer of the light emitting device) may further include a third compound. The third compound may include at least one deuterium atom. For example, in addition to the third compound, the light emitting device (e.g., the emission layer of the light emitting device) may further include a second compound, a fourth compound, a fifth compound, or any combination thereof.

[0095] In another embodiment, the light emitting device (e.g., the emission layer of the light emitting device) may further include a fourth compound. The fourth compound may include at least one deuterium atom. The fourth compound may improve the color purity, luminous efficiency and life characteristics of the light emitting device. For example, in addition to the fourth compound, the light emitting device (e.g., the emission layer of the light emitting device) may further include a second compound, a third compound, a fifth compound or any combination thereof.

[0096] In another embodiment, the light emitting device (e.g., the emission layer of the light emitting device) may further include a fifth compound. The fifth compound may include at least one deuterium atom. For example, in addition to the fifth compound, the light emitting device (e.g., the emission layer of the light emitting device) may further include a second compound, a third compound, a fourth compound, or any combination thereof.

[0097] In an embodiment, the emission layer of the light emitting device may include the second compound, the third compound, the fourth compound, the fifth compound, or any combination thereof; and the emission layer may emit blue light.

[0098] According to an embodiment, the emission layer may emit light having a maximum emission wavelength in a range of about 400 nm to about 490 nm.

[0099] In an embodiment, the blue light may be deep blue light.

[0100] In an embodiment, the second compound may include a pyridyl group, a pyrimidyl group, a pyrazinyl group, a pyridazinyl group, a triazinyl group, or any combination thereof.

[0101] In an embodiment, the third compound may exclude CBP and mCBP:

[0102]

[0103] In an embodiment, the difference between the triplet energy level (eV) of the fourth compound and the singlet energy level (eV) of the fourth compound may be in the range of about 0 eV to about 0.5 eV. For example, the difference between the triplet energy level (eV) of the fourth compound and the singlet energy level (eV) of the fourth compound may be in the range of about 0 eV to about 0.3 eV.

[0104] In an embodiment, the fourth compound may include at least one cyclic group including boron (B) and nitrogen (N) as ring-forming atoms.

[0105] In an embodiment, the fourth compound may be a C-containing fused ring group including at least two shared boron atoms (B). 8 -C 60 Polycyclic compounds.

[0106] In an embodiment, the fourth compound may include a fused ring in which at least one third ring may be fused to at least one fourth ring,

[0107] The third ring can be cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, cyclooctenyl, adamantyl, norbornenyl, norbornyl, bicyclo[1.1.1]pentanyl, bicyclo[2.1.1]hexanyl, bicyclo[2.2.2]octanyl, phenyl, pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl or triazinyl, and

[0108] The fourth ring may be 1,2-azaboraphenyl, 1,3-azaboraphenyl, 1,4-azaboraphenyl, 1,2-dihydro-1,2-azaboraphenyl, 1,4-oxaboraphenyl, 1,4-thiaboraphenyl or 1,4-dihydroboraphenyl.

[0109] In an embodiment, the second compound may include a compound represented by Formula 2:

[0110] [Formula 2]

[0111]

[0112] In formula 2,

[0113] L 51 To L 53 may be independently a single bond, unsubstituted or substituted by at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0114] b51 to b53 may each independently be an integer selected from 1 to 5,

[0115] X 54 Can be N or C(R 54 ), X 55 Can be N or C(R 55 ), X 56 Can be N or C(R 56 ), and X 54 To X 56 At least one of may each be N, and

[0116] R 51 To R 56 and R 10a Each is the same as described in the specification.

[0117] In an embodiment, the third compound may include a compound represented by Formula 3-1, a compound represented by Formula 3-2, a compound represented by Formula 3-3, a compound represented by Formula 3-4, a compound represented by Formula 3-5, or any combination thereof:

[0118] [Formula 3-1]

[0119]

[0120] [Formula 3-2]

[0121]

[0122] [Formula 3-3]

[0123]

[0124] [Formula 3-4]

[0125]

[0126] [Formula 3-5]

[0127]

[0128] In Formula 3-1 to Formula 3-5,

[0129] Cyclo 71 To Ring CY 74 can be independently π-electron-rich C 3 -C 60 Cyclic group or pyridyl group,

[0130] X 82 Can be single bond, O, S, N[(L 82 ) b82 -R 82 ]、B[(L 82 ) b82 -R 82 ]、C(R 82a )(R 82b ) or Si(R 82a )(R 82b ),

[0131] X 83 Can be single bond, O, S, N[(L 83 ) b83 -R 83 ]、B[(L 83 ) b83 -R 83 ]、C(R 83a )(R 83b ) or Si(R 83a )(R 83b ),

[0132] X 84 Can be O, S, N[(L 84 ) b84 -R 84 ]、B[(L 84 ) b84 -R 84 ]、C(R 84a )(R 84b ) or Si(R 84a )(R 84b ),

[0133] X 85 Can be C or Si,

[0134] L 81 To L 85 can be independently a single bond, *-C(Q 4 )(Q 5 )-*'、*-Si(Q 4 )(Q 5 )-*', unsubstituted or replaced by at least one R 10a Substituted π-electron-rich C 3 -C 60 The cyclic group is either unsubstituted or substituted with at least one R 10a Substituted pyridyl, wherein Q 4 and Q 5 Each independently refers to Q as defined herein 1 Same as described,

[0135] b81 to b85 may each independently be an integer selected from 1 to 5,

[0136] R 71 To R 74 , R 81 To R 85 , R 82a , R 82b , R 83a , R 83b , R 84a and R 84b Each is the same as described herein,

[0137] a71 to a74 may each independently be an integer selected from 0 to 20, and

[0138] R 10a Same as described in this article.

[0139] In an embodiment, the fourth compound may be a compound represented by Formula 502, a compound represented by Formula 503, or any combination thereof:

[0140] [Formula 502]

[0141]

[0142] [Formula 503]

[0143]

[0144] In equation 502 and equation 503,

[0145] Ring A 501 To Ring A 504Can be independently C 3 -C 60 Carbocyclic or C 1 -C 60 Heterocyclic group,

[0146] Y 505 Can be O, S, N (R 505 )、B(R 505 )、C(R 505a )(R 505b ) or Si(R 505a )(R 505b ),

[0147] Y 506 Can be O, S, N (R 506 )、B(R 506 )、C(R 506a )(R 506b ) or Si(R 506a )(R 506b ),

[0148] Y 507 Can be O, S, N (R 507 )、B(R 507 )、C(R 507a )(R 507b ) or Si(R 507a )(R 507b ),

[0149] Y 508 Can be O, S, N (R 508 )、B(R 508 )、C(R 508a )(R 508b ) or Si(R 508a )(R 508b ),

[0150] Y 51 and Y 52 may be each independently B, P(=O) or S(=O),

[0151] R 500a , R 500b , R 501 To R 508 , R 505a , R 505b , R 506a , R 506b , R 507a , R 507b , R 508a and R 508b are the same as described in the specification, and

[0152] a501 to a504 may each independently be an integer selected from 0 to 20.

[0153] In an embodiment, the light emitting device may satisfy at least one of conditions 1 to 4:

[0154] [Condition 1]

[0155] The lowest unoccupied molecular orbital (LUMO) energy level (eV) of the third compound is greater than the LUMO energy level (eV) of the fifth compound;

[0156] [Condition 2]

[0157] The LUMO energy level (eV) of the fifth compound> the LUMO energy level (eV) of the second compound;

[0158] [Condition 3]

[0159] The highest occupied molecular orbital (HOMO) energy level (eV) of the fifth compound is greater than the HOMO energy level (eV) of the third compound;

[0160] [Condition 4]

[0161] The HOMO energy level (eV) of the third compound is greater than the HOMO energy level (eV) of the second compound.

[0162] The HOMO energy level and the LUMO energy level of the fifth compound, the second compound, and the third compound may each be a negative value. The HOMO energy level and the LUMO energy level may each be measured according to a method of the related art.

[0163] In an embodiment, the absolute value of the difference between the LUMO energy level of the fifth compound and the LUMO energy level of the second compound may be in the range of about 0.1eV to about 1.0eV; the absolute value of the difference between the LUMO energy level of the fifth compound and the LUMO energy level of the third compound may be in the range of about 0.1eV to about 1.0eV; the absolute value of the difference between the HOMO energy level of the fifth compound and the HOMO energy level of the second compound may be equal to or less than 1.25eV (for example, in the range of about 0.2eV to about 1.25eV); or the absolute value of the difference between the HOMO energy level of the fifth compound and the HOMO energy level of the third compound may be equal to or less than 1.25eV (for example, in the range of about 0.2eV to about 1.25eV).

[0164] When the relationship between the LUMO energy level and the HOMO energy level satisfies the conditions as described above, a balance between holes and electrons injected into the emission layer can be achieved.

[0165] In an embodiment, the fifth compound which is a transition metal-containing organometallic compound may include a platinum atom and a tetradentate ligand bonded to the platinum atom, and one of bonds between the platinum atom and the tetradentate ligand may be a platinum-carbene bond.

[0166] In an embodiment, the fifth compound, which is a transition metal-containing organometallic compound, may include an iridium atom and a tetradentate ligand bonded to the iridium atom, and one of bonds between the iridium atom and the tetradentate ligand may be an iridium-carbene bond.

[0167] In another embodiment, the fifth compound can be represented by Formula 602:

[0168] [Formula 602]

[0169] M 31 (L 31 ) n31 (L 32 ) n32

[0170]

[0171]

[0172] In equation 602 and equations 602-1 to 602-4,

[0173] M 31 It may be a first-row transition metal of the periodic table, a second-row transition metal of the periodic table, or a third-row transition metal of the periodic table,

[0174] L 31 may be a ligand represented by one of Formula 602-1 to Formula 602-4,

[0175] L 32 It can be a monodentate ligand, a bidentate ligand or a tridentate ligand,

[0176] n31 can be 1 or 2,

[0177] n32 can be 0, 1, 2, 3 or 4,

[0178] A 31 To A 34 Can be independently C 5 -C 30 Carbocyclic or C 1 -C 30 Heterocyclic group,

[0179] T 31 To T 34 can each independently be a single bond, a double bond, *-O-*', *-S-*', *-C(=O)-*', *-S(=O)-*', *-C(R35 )(R 36 )-*'、*-C(R 35 )=C(R 36 )-*'、*-C(R 35 )=*'、*-Si(R 35 )(R 36 )-*'、*-B(R 35 )-*'、*-N(R 35 )-*' or *-P(R 35 )-*',

[0180] k31 to k34 may each independently be 1, 2 or 3,

[0181] Y 31 To Y 34 can be independently a single bond, *-O-*', *-S-*', *-C(R 37 )(R 38 )-*'、*-Si(R 37 )(R 38 )-*'、*-B(R 37 )-*'、*-N(R 37 )-*' or *-P(R 37 )-*',

[0182] * 1 ,* 2 ,* 3 and* 4 Respective instructions and M 31 The bonding site of

[0183] R 31 To R 38 can be independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10aSubstituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ),

[0184] R 31 To R 38 may be optionally bonded to each other to form an unsubstituted or substituted R 10a Substituted C 5 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0185] b31 to b34 may each independently be an integer selected from 0 to 10,

[0186] R 10a Can be:

[0187] deuterium, -F, -Cl, -Br, -I, hydroxy, cyano or nitro;

[0188] Each unsubstituted or substituted C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl or C 1 -C 60 Alkoxy: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 11 )(Q 12 )(Q 13 )、-N(Q 11 )(Q 12 )、-B(Q 11 )(Q 12 )、-C(=O)(Q 11 )、-S(=O) 2 (Q 11 )、-P(=O)(Q 11 )(Q 12 ) or any combination thereof;

[0189] Each unsubstituted or substituted C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 21 )(Q 22 )(Q 23 )、-N(Q 21 )(Q 22)、-B(Q 21 )(Q 22 )、-C(=O)(Q 21 )、-S(=O) 2 (Q 21 )、-P(=O)(Q 21 )(Q 22 ) or any combination thereof; or

[0190] -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 ) or -P(=O)(Q 31 )(Q 32 ),and

[0191] Q 1 To Q 3 , Q 11 To Q 13 , Q 21 To Q 23 and Q 31 To Q 33 can be independently: hydrogen; deuterium; -F; -Cl; -Br; -I; hydroxyl; cyano; nitro; C 1 -C 60 Alkyl; C 2 -C 60 Alkenyl; C 2 -C 60 Alkynyl; C 1 -C 60 alkoxy; or each unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 C substituted by heterocyclic group or any combination thereof 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl.

[0192] In an embodiment, the emission layer may include a hole transport compound, an electron transport compound, an organic metal compound containing a transition metal, and a delayed fluorescence compound.

[0193] In embodiments, the delayed fluorescence compound may include at least one donor group and at least one acceptor group.

[0194] In an embodiment, the delayed fluorescence compound may satisfy Equation 1:

[0195] [Equation 1]

[0196] △E ST =S1(delayed fluorescence)-T1(delayed fluorescence)≤0.3eV.

[0197] In Equation 1, S1(delayed fluorescence) is the lowest excited singlet energy level (eV) of the delayed fluorescence compound, and T1(delayed fluorescence) is the lowest excited triplet energy level (eV) of the delayed fluorescence compound.

[0198] In embodiments, the emissive layer may include a host, an emitter, a sensitizer, or any combination thereof.

[0199] In an embodiment, the emission layer may not include an anthracene-based compound.

[0200] In an embodiment, the light emitting device may further include a capping layer outside the first electrode and / or outside the second electrode.

[0201] In an embodiment, the light-emitting device may further include at least one of a first capping layer located outside the first electrode and a second capping layer located outside the second electrode, and at least one of the first capping layer and the second capping layer may each independently include an amine compound represented by Formula 1. The first capping layer and / or the second capping layer are each the same as described herein.

[0202] In an embodiment, the light emitting device may further include:

[0203] A first capping layer outside the first electrode and including an amine compound represented by Formula 1;

[0204] A second capping layer outside the second electrode and including an amine compound represented by Formula 1; or

[0205] A first capping layer and a second capping layer.

[0206] As used herein, the expression “(the interlayer and / or the capping layer) includes the amine compound represented by Formula 1” may be understood as “(the interlayer and / or the capping layer) may include one kind of the amine compound represented by Formula 1 or two or more different kinds of amine compounds each independently represented by Formula 1”.

[0207] In an embodiment, the interlayer and / or the capping layer may include only Compound 1 as an amine compound. In this regard, Compound 1 may be present in the emission layer of the light-emitting device. In an embodiment, the interlayer may include Compound 1 and Compound 2 as amine compounds. In this regard, Compound 1 and Compound 2 may be present in the same layer (e.g., Compound 1 and Compound 2 may both be present in the emission layer), or may be present in different layers (e.g., Compound 1 may be present in the emission layer, and Compound 2 may be present in the electron transport region).

[0208] The term "interlayer" as used herein may be a single layer and / or all layers between a first electrode and a second electrode of a light emitting device.

[0209] Another aspect of the embodiment provides an electronic device including a light emitting device. The electronic device may further include a thin film transistor. For example, the electronic device may further include a thin film transistor including a source electrode and a drain electrode, wherein the first electrode of the light emitting device may be electrically connected to the source electrode or the drain electrode. In an embodiment, the electronic device may further include a color filter, a color conversion layer, a touch screen layer, a polarization layer, or any combination thereof. Further details of the electronic device may be the same as provided herein.

[0210] Another embodiment provides an electronic device that may include a light emitting device.

[0211] For example, the electronic device may be a flat panel display, a curved display, a computer monitor, a medical monitor, a television (TV), a billboard, an indoor light, an outdoor light, a signal light, a head-up display, a fully transparent display, a partially transparent display, a flexible display, a rollable display, a foldable display, a retractable display, a laser printer, a phone, a portable phone, a tablet personal computer, a tablet mobile computer, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a microdisplay, a three-dimensional (3D) display, a virtual reality display, an augmented reality display, a vehicle, a video wall with multiple displays stitched together, a theater screen, a stadium screen, a light therapy device, or a sign.

[0212] Embodiments provide an amine compound that may be represented by Formula 1. Details of Formula 1 are the same as described herein.

[0213] The synthesis method of amine compounds can be recognized by those skilled in the art by referring to the synthesis examples and / or embodiments provided below.

[0214] [Description of Formula 1]

[0215] [Formula 1]

[0216]

[0217] In formula 1, L 1 and L 2 may be independently a single bond, unsubstituted or substituted by at least one R 10a Substituted C 5 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group.

[0218] In an embodiment, L 1 and L 2 Can be independently:

[0219] a single key; or

[0220] Each is unsubstituted or substituted with at least one R 10a substituted phenyl, naphthyl, fluorenyl, carbazolyl, dibenzofuranyl or dibenzothiophenyl.

[0221] In another embodiment, L 1 and L 2 may each independently be a single bond.

[0222] In Formula 1, n1 and n2 may each independently be an integer selected from 1 to 3.

[0223] In an embodiment, n1 and n2 may each independently be 1 or 2.

[0224] In an embodiment, n1 and n2 may each be 1.

[0225] In formula 1, Z 1 To Z 3 and E 1 can be independently deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ).

[0226] In an embodiment, Z 1 To Z 3 and E 1 may be each independently unsubstituted or substituted with at least one R 10a Substituted phenyl, naphthyl, fluorenyl, carbazolyl, dibenzofuranyl, dibenzothiophenyl, azacarbazolyl, azadibenzofuranyl, azadibenzothiophenyl, pyridyl, pyrimidinyl, pyrazinyl, quinolyl or quinoxalinyl.

[0227] In an embodiment, Z 1 To Z 3 and E 1 Each may be independently a group represented by any one of Formula 1A-1 to Formula 1A-16:

[0228]

[0229]

[0230] In Formula 1A-1 to Formula 1A-16,

[0231] R 10a Same as described in this article,

[0232] c4 may be an integer selected from 0 to 4,

[0233] c5 may be an integer selected from 0 to 5,

[0234] c7 may be an integer selected from 0 to 7,

[0235] X 1 Can be N(R 1 ), O or S,

[0236] R 1 With reference R 11 Same as described, and

[0237] * indicates a bonding site to N or the naphthyl group in Formula 1.

[0238] In Formula 1, e1 may be an integer selected from 1 to 7.

[0239] In an embodiment, Z 2 and Z 3 Can be the same as or different from each other.

[0240] In another embodiment, Z 2 and Z 3 Can be different from each other.

[0241] In formula 1, R 11 , R 12 and R 2 To R 5 can be independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ).

[0242] In formula 1, R 10a Can be:

[0243] deuterium, -F, -Cl, -Br, -I, hydroxy, cyano or nitro;

[0244] Each unsubstituted or substituted C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl or C 1 -C 60 Alkoxy: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 11 )(Q 12 )(Q 13 )、-N(Q 11 )(Q 12 )、-B(Q 11 )(Q 12 )、-C(=O)(Q 11 )、-S(=O) 2 (Q 11 )、-P(=O)(Q 11 )(Q 12 ) or any combination thereof;

[0245] Each unsubstituted or substituted C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 21 )(Q 22 )(Q 23 )、-N(Q 21 )(Q 22 )、-B(Q 21 )(Q 22 )、-C(=O)(Q 21 )、-S(=O) 2 (Q 21 )、-P(=O)(Q 21 )(Q 22 ) or any combination thereof; or

[0246] -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 ) or -P(=O)(Q 31 )(Q 32 ),and

[0247] Q 1 To Q 3 , Q11 To Q 13 , Q 21 To Q 23 and Q 31 To Q 33 can be independently: hydrogen; deuterium; -F; -Cl; -Br; -I; hydroxyl; cyano; nitro; C 1 -C 60 Alkyl; C 2 -C 60 Alkenyl; C 2 -C 60 Alkynyl; C 1 -C 60 alkoxy; or each unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 C substituted by heterocyclic group or any combination thereof 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl.

[0248] In an embodiment, R 11 , R 12 and R 2 To R 5 Can be independently:

[0249] Hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 20 Alkyl or C 1 -C 20 Alkoxy;

[0250] Each of the following C 1 -C 20 Alkyl or C 1 -C 20 Alkoxy: deuterium, -F, -Cl, -Br, -I, -CD 3 、-CD 2 H.-CDH 2 , -CF 3 , -CF 2 H, -CFH 2 , hydroxyl, cyano, nitro, C 1-C 10 alkyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, naphthyl, pyridinyl, pyrimidinyl, or any combination thereof;

[0251] each unsubstituted or substituted by cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, terphenyl, C 1 -C 10 Alkylphenyl, naphthyl, fluorenyl, phenanthryl, anthracenyl, fluoranthenyl, triphenylene, pyrenyl, 1,2-benzophenanthryl, pyrrolyl, thienyl, furanyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolyl, isoquinolyl, benzoquinolyl, quinoxalinyl, quinazolinyl, cinnolinyl, carbazolyl, phenanthrolinyl, benzimidazolyl oxazolyl, benzofuranyl, benzothiophenyl, benzothiazolyl, benzisoxazolyl, benzisoxazolyl, triazolyl, tetrazolyl, oxadiazolyl, triazinyl, dibenzofuranyl, dibenzothiophenyl, benzocarbazolyl, dibenzocarbazolyl, imidazopyridinyl, imidazopyrimidinyl, azacarbazolyl, azadibenzofuranyl, azadibenzothiophenyl, azafluorenyl or azadibenzothiorolyl: deuterium, -F, -Cl, -Br, -I, -CD 3 、-CD 2 H.-CDH 2 , -CF 3 , -CF 2 H, -CFH 2 , hydroxyl, cyano, nitro, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, terphenyl, C 1 -C 10Alkylphenyl, naphthyl, fluorenyl, phenanthryl, anthracenyl, fluoranthenyl, triphenylene, pyrenyl, 1,2-benzophenanthryl, pyrrolyl, thienyl, furanyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, pyridinyl, pyrazinyl, pyrimidinyl, pyridazinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolyl, isoquinolyl, benzoquinolyl, Quinoxalyl, quinazolinyl, cinnolinyl, carbazolyl, phenanthrolinyl, benzimidazolyl, benzofuranyl, benzothiophenyl, benzisothiazolyl, benzoxazolyl, benzisoxazolyl, triazolyl, tetrazolyl, oxadiazolyl, triazine, dibenzofuranyl, dibenzothiophenyl, benzocarbazolyl, dibenzocarbazolyl, imidazopyridyl, imidazopyrimidyl, -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 )、-P(=O)(Q 31 )(Q 32 ) or any combination thereof; or

[0252] -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ),and

[0253] Q 1 To Q 3 and Q 31 To Q 33 Each is independently the same as described in the specification.

[0254] In another embodiment, R 11 , R 12 and R 2 To R 5 Can be independently:

[0255] Hydrogen, deuterium, -F or cyano;

[0256] unsubstituted or deuterated, -F, cyano, phenyl, deuterated phenyl, fluorinated phenyl, (C 1 -C 20 alkyl)phenyl, biphenyl, deuterated biphenyl, fluorinated biphenyl, (C 1 -C 20 C 1 -C 20 alkyl;

[0257] Each unsubstituted or substituted C 3 -C 10 Cycloalkyl, phenyl, naphthyl, carbazolyl, dibenzofuranyl or dibenzothiophenyl: deuterium, -F, cyano, C 1 -C 20 Alkyl, deuterated C 1 -C 20 Alkyl, fluorinated C 1 -C 20 Alkyl, C 3 -C 10 Cycloalkyl, deuterated C 3 -C 10 Cycloalkyl, fluorinated C 3 -C 10 Cycloalkyl, phenyl, deuterated phenyl, fluorinated phenyl, (C 1 -C 20 alkyl)phenyl, biphenyl, deuterated biphenyl, fluorinated biphenyl, (C 1 -C 20 alkyl)biphenyl or any combination thereof; or

[0258] -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ),and

[0259] Q 1 To Q 3 may be each independently unsubstituted or substituted by the following C 3 -C 10 Cycloalkyl, phenyl, naphthyl, carbazolyl, dibenzofuranyl or dibenzothiophenyl: deuterium, -F, cyano, C 1 -C 20Alkyl, C 3 -C 10 Cycloalkyl, phenyl, deuterated phenyl, fluorinated phenyl, (C 1 -C 20 alkyl)phenyl, biphenyl, deuterated biphenyl, fluorinated biphenyl, (C 1 -C 20 alkyl)biphenyl or any combination thereof.

[0260] In formula 1,

[0261] a11 may be an integer selected from 0 to 4,

[0262] a12 may be an integer selected from 0 to 3,

[0263] a2 may be an integer selected from 0 to 3, and

[0264] a3 to a5 may be an integer selected from 0 to 4, each independently.

[0265] In an embodiment, in Formula 1, The moiety represented by may be a moiety represented by one of Formula 1B-1 to Formula 1B-14:

[0266]

[0267] In Formula 1B-1 to Formula 1B-14,

[0268] E 1 , R 11 , R 12 , a11 and a12 may be the same as those described above, respectively, and

[0269] *Indicates the bonding site to the adjacent N.

[0270] In an embodiment, the amine compound may be represented by Formula 1-1:

[0271] [Formula 1-1]

[0272]

[0273] In formula 1-1,

[0274] a5 may be an integer selected from 0 to 3, and

[0275] Z 1 To Z 3 、E 1 、e1、R 11 , R 12 , R 2 To R 5 , a11, a12 and a2 to a4 may be the same as described herein.

[0276] All descriptions about Formula 1 are also applicable to Formula 1-1.

[0277] Since the amine compound represented by Formula 1 according to an embodiment essentially introduces a substituent into a naphthyl group, color coordinates may be improved to emit deep blue light, and structural stability of the amine compound may be ensured.

[0278] The hole transport region, for example, at least one of the hole transport layer and the hole injection layer may include the amine compound represented by Formula 1. Accordingly, the amine compound represented by Formula 1 may be used as a hole transport material.

[0279] When the amine compound represented by Formula 1 is applied to a light-emitting device, light-emitting efficiency and device lifespan may be improved.

[0280] In addition, by using the amine compound, a light-emitting device (eg, an organic light-emitting device) having low driving voltage, high luminous efficiency, high color purity, and long life characteristics may be implemented.

[0281] [Description of Formula 2, Formula 3-1 to Formula 3-5, Formula 502, and Formula 503]

[0282] [Formula 2]

[0283]

[0284] In Formula 2, b51 to b53 can be L 51 To L 53 , and b51 to b53 may each independently be an integer selected from 1 to 5.

[0285] When b51 is 2 or more, two or more L 51 may be the same or different from each other. When b52 is 2 or greater, two or more L 52 may be the same as or different from each other, and when b53 is 2 or greater, two or more L 53 In an embodiment, b51 to b53 may be 1 or 2, respectively, independently of each other.

[0286] In formula 2, L 51 To L 53 Can be independently:

[0287] a single key; or

[0288] phenyl, naphthyl, anthracenyl, phenanthrenyl, triphenylene, pyrenyl, 1,2-benzophenanthryl, cyclopentadienyl, furanyl, thienyl, thirol, indenyl, fluorenyl, indolyl, carbazolyl, benzofuranyl, dibenzofuranyl, benzothienyl, dibenzothienyl, benzothirol, dibenzothirol, azafluorenyl, azacarbazolyl, azadibenzofuranyl, azadibenzothienyl, azadibenzothirol, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolyl, isoquinolyl, quinoxalinyl, quinazolinyl, phenanthrolinyl, pyrrolyl, pyrazolyl, imidazolyl, triazolyl, oxazolyl, isoxazolyl oxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, benzopyrazolyl, benzimidazolyl, benzoxazolyl, benzothiazolyl, benzoxadiazolyl, benzothiadiazolyl, dibenzooxacillinyl, dibenzothiacillinyl, dibenzodihydroazacillinyl, dibenzodihydrodicillinyl, dibenzodihydrocillinyl, dibenzodioxanyl, dibenzothioxanyl, dibenzoxazinyl, dibenzopyranyl, dibenzodithioinyl, dibenzothiazinyl, dibenzothiopyranyl, dibenzocyclohexadienyl, dibenzodihydropyridinyl or dibenzodihydropyrazinyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, phenyl, naphthyl, pyridyl, pyrimidyl, triazine, fluorenyl, dimethylfluorenyl, diphenylfluorenyl, carbazolyl, phenylcarbazolyl, dibenzofuranyl, dibenzothiophenyl, dibenzosilyl, dimethyldibenzosilyl, diphenyldibenzosilyl, -Si(Q) 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 )、-P(=O)(Q 31 )(Q 32 ) or any combination thereof, and

[0289] Q 31 To Q 33 can be independently hydrogen, deuterium, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, phenyl, biphenyl, terphenyl, pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl or triazinyl.

[0290] In an embodiment, in Formula 2, L 51 and R 51 The key between 52 and R 52 The key between 53 and R 53 The bond between two or more L 51 The bond between two or more L 52 The bond between two or more L 53 The key between 51 and X 54 With X 55 The bonds between carbons, L 52 and X 54 With X 56 The bonds between the carbons and L 53 and X 55 With X 56 The bonds between the carbon atoms in between may each be a "carbon-carbon single bond".

[0291] In formula 2, X 54 Can be N or C(R 54 ), X 55 Can be N or C(R 55 ), X 56 Can be N or C(R 56 ), and X 54 To X 56 At least one of them may each be N. 54 To R 56 It may be the same as above. In an embodiment, X 54 To X 56 Two or three of them can each be N.

[0292] In the manual, R 51 To R 56 , R 71 To R 74 , R 81 To R 85 , R 82a , R 82b , R 83a , R 83b , R 84a , R 84b , R 500a , R 500b , R 501 To R 508 , R 505a , R 505b , R 506a , R 506b , R 507a , R 507b , R508a and R 508b can be independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, unsubstituted or substituted with at least one R 10a Substituted C 7 -C 60 Arylalkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Heteroaralkyl, -C(Q 1 )(Q 2 )(Q 3 )、-Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ). Q 1 To Q 3 Each may be the same as described herein.

[0293] For example, R in Formula 1 11 , R 12 , R 2 To R 5 , Z 1 To Z 3 and E 1 ; R in Formula 2, Formula 3-1 to Formula 3-5, Formula 502 and Formula 503 51 To R 56 , R 71 To R 74 , R 81 To R 85 , R 82a , R 82b , R 83a , R 83b , R 84a , R 84b , R 500a , R 500b , R 501 To R 508 , R 505a , R 505b , R 506a , R 506b , R 507a , R 507b , R 508a and R 508b ; and R in the manual 10a Can be independently:

[0294] Hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 20 Alkyl or C 1 -C 20 Alkoxy;

[0295] Each of the following C 1 -C 20 Alkyl or C 1 -C 20 Alkoxy: deuterium, -F, -Cl, -Br, -I, -CD 3 、-CD 2 H.-CDH 2 , -CF 3 , -CF 2 H, -CFH 2 , hydroxyl, cyano, nitro, C 1 -C 10 alkyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, naphthyl, pyridinyl, pyrimidinyl, or any combination thereof;

[0296] each unsubstituted or substituted by cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, C 1 -C 10 Alkylphenyl, naphthyl, fluorenyl, phenanthryl, anthracenyl, fluoranthene, triphenylene, pyrenyl, 1,2-benzophenanthryl, pyrrolyl, thienyl, furanyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolyl, isoquinolyl, benzoquinolyl, quinoxalinyl, quinazolinyl, cinnolinyl, carbazolyl, phenanthrolinyl, benzimidazolyl, benzo furanyl, benzothienyl, benzisothiazolyl, benzoxazolyl, benzisoxazolyl, triazolyl, tetrazolyl, oxadiazolyl, triazinyl, dibenzofuranyl, dibenzothienyl, benzocarbazolyl, dibenzocarbazolyl, imidazopyridyl, imidazopyrimidyl, azacarbazolyl, azadibenzofuranyl, azadibenzothienyl, azafluorenyl, azadibenzothiorolyl, or a group represented by Formula 91: deuterium, -F, -Cl, -Br, -I, -CD 3 、-CD 2 H.-CDH 2 , -CF 3 , -CF 2 H, -CFH 2 , hydroxyl, cyano, nitro, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, C 1 -C 10 Alkylphenyl, naphthyl, fluorenyl, phenanthryl, anthracenyl, fluoranthenyl, triphenylene, pyrenyl, 1,2-benzophenanthryl, pyrrolyl, thienyl, furanyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, pyridinyl, pyrazinyl, pyrimidinyl, pyridazinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolyl, isoquinolyl, benzoquinolyl, Quinoxalyl, quinazolinyl, cinnolinyl, carbazolyl, phenanthrolinyl, benzimidazolyl, benzofuranyl, benzothiophenyl, benzothiazolyl, benzisoxazolyl, benzisoxazolyl, triazolyl, tetrazolyl, oxadiazolyl, triazine, dibenzofuranyl, dibenzothiophenyl, benzocarbazolyl, dibenzocarbazolyl, imidazopyridyl, imidazopyrimidyl, -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32)、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 )、-P(=O)(Q 31 )(Q 32 ) or any combination thereof; or

[0297] -C(Q 1 )(Q 2 )(Q 3 )、-Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ),and

[0298] Q 1 To Q 3 and Q 31 To Q 33 Can be independently:

[0299] -CH 3 、-CD 3 、-CD 2 H.-CDH 2 、-CH 2 CH 3 、-CH 2 CD 3 、-CH 2 CD 2 H, -CH 2 CDH 2 、-CHDCH 3 、-CHDCD 2 H, -CHDCDH 2 、-CHDCD 3 、-CD 2 CD 3 、-CD 2 CD 2 H or -CD 2 CDH 2 ;or

[0300] n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, isopentyl, sec-pentyl, tert-pentyl, phenyl, naphthyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl or triazinyl, each unsubstituted or substituted by: deuterium, C 1 -C 10 Alkyl, phenyl, biphenyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl, triazinyl or any combination thereof:

[0301] [Formula 91]

[0302]

[0303] In formula 91,

[0304] Cyclo 91 and CY 92 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 5 -C 30 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 30 Heterocyclic group,

[0305] X 91 Can be single bond, O, S, N(R 91 )、B(R 91 )、C(R 91a )(R 91b ) or Si(R 91a )(R 91b ),

[0306] R 91 , R 91a and R 91b Can be compared with reference R 82 , R 82a and R 82b Same as described,

[0307] R 10a may be the same as described herein, and

[0308] *Indicates bonding sites to neighboring atoms.

[0309] For example, in Equation 91,

[0310] Cyclo 91 and CY 92 may be each independently unsubstituted or substituted with at least one R 10a substituted phenyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl or triazinyl, and

[0311] R 91, R 91a and R 91b Can be independently:

[0312] Hydrogen or C 1 -C 10 Alkyl; or

[0313] Each unsubstituted or deuterated, C 1 -C 10 Phenyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl or triazinyl substituted with alkyl, phenyl, biphenyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl or triazinyl or any combination thereof.

[0314] In an embodiment, R in Formula 1 11 , R 12 , R 2 To R 5 , Z 1 To Z 3 and E 1 ; R in Formula 2, Formula 3-1 to Formula 3-5, Formula 502 and Formula 503 51 To R 56 , R 71 To R 74 , R 81 To R 85 , R 82a , R 82b , R 83a , R 83b , R 84a , R 84b , R 500a , R 500b , R 501 To R 508 , R 505a , R 505b , R 506a , R 506b , R 507a , R 507b , R 508a and R 508b ; and R in the manual 10a can be independently hydrogen, deuterium, -F, cyano, nitro, -CH 3 、-CD 3 、-CD 2 H.-CDH 2 , -CF 3 , -CF 2 H, -CFH 2 , a group represented by one of Formulas 9-1 to 9-19, a group represented by one of Formulas 10-1 to 10-246, -Si(Q 1 )(Q 2 )(Q3 ) or -P(=O)(Q 1 )(Q 2 )(where Q 1 To Q 3 may be the same as those above respectively):

[0315]

[0316]

[0317]

[0318]

[0319]

[0320]

[0321] In Formulae 9-1 to 9-19 and 10-1 to 10-246, * indicates a bonding site to an adjacent atom, "Ph" represents a phenyl group, and "TMS" represents a trimethylsilyl group.

[0322] In Formulas 3-1 to 3-5, Formula 502, and Formula 503, a71 to a74 and a501 to a504 each indicate R 71 The number of R 74 The number and R 501 The number of R 504 and may each independently be an integer selected from 0 to 20. When a71 is 2 or greater, two or more R 71 may be the same as or different from each other. When a72 is 2 or greater, two or more R 72 may be the same as or different from each other. When a73 is 2 or greater, two or more R 73 may be the same or different from each other. When a74 is 2 or greater, two or more R 74 may be the same as or different from each other. When a501 is 2 or greater, two or more R 501 may be the same or different from each other. When a502 is 2 or greater, two or more R 502 may be the same or different from each other. When a503 is 2 or greater, two or more R 503 may be the same as or different from each other, and when a504 is 2 or greater, two or more R 504 a71 to a74 and a501 to a504 may each independently be an integer selected from 0 to 8.

[0323] In formula 2, *-(L 51 )b51 -R 51 The group represented by *-(L 52 ) b52 -R 52 The groups represented by may each be other than phenyl.

[0324] In an embodiment, in Formula 2, *-(L 51 ) b51 -R 51 The group represented by *-(L 52 ) b52 -R 52 The groups represented may be the same as each other.

[0325] In an embodiment, in Formula 2, *-(L 51 ) b51 -R 51 The group represented by *-(L 52 ) b52 -R 52 The groups represented may be different from each other.

[0326] In an embodiment, in Formula 2, b51 and b52 may each independently be 1, 2 or 3; and L 51 and L 52 may be each independently unsubstituted or substituted with at least one R 10a Substituted phenyl, pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl or triazinyl.

[0327] In an embodiment, in Formula 2, R 51 and R 52 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -C(Q 1 )(Q 2 )(Q 3 ) or -Si(Q 1 )(Q 2 )(Q 3 ),and

[0328] Q 1 To Q3 may be each independently unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, phenyl, biphenyl or any combination thereof substituted C 3 -C 60 Carbocyclic or C 1 -C 60 Heterocyclic group.

[0329] In an embodiment, in Formula 2, 51 ) b51 -R 51 The group represented by may be a group represented by one of the formulas CY51-1 to CY51-26, and / or

[0330] In formula 2, *-(L 52 ) b52 -R 52 The group represented by may be a group represented by one of the formulas CY52-1 to CY52-26, and / or

[0331] In formula 2, *-(L 53 ) b53 -R 53 The group represented by may be a group represented by one of the formulas CY53-1 to CY53-27, -C(Q 1 )(Q 2 )(Q 3 ) or -Si(Q 1 )(Q 2 )(Q 3 ):

[0332]

[0333]

[0334]

[0335] Among them, in Formula CY51-1 to Formula CY51-26, Formula CY52-1 to Formula CY52-26 and Formula CY53-1 to Formula CY53-27,

[0336] Y 63 Can be single bond, O, S, N(R 63 )、B(R 63 )、C(R 63a )(R 63b ) or Si(R 63a )(R 63b ),

[0337] Y 64 Can be single bond, O, S, N(R 64 )、B(R 64 )、C(R 64a )(R 64b ) or Si(R 64a )(R 64b ),

[0338] Y 67 Can be single bond, O, S, N(R 67 )、B(R 67 )、C(R 67a )(R 67b ) or Si(R 67a )(R 67b ),

[0339] Y 68 Can be single bond, O, S, N(R 68 )、B(R 68 )、C(R 68a )(R 68b ) or Si(R 68a )(R 68b ),

[0340] Y in formula CY51-16 and formula CY51-17 63 and Y 64 They may not all be single bonds at the same time.

[0341] Y in formula CY52-16 and formula CY52-17 67 and Y 68 They may not all be single bonds at the same time.

[0342] R 51a To R 51e , R 61 To R 64 , R 63a , R 63b , R 64a and R 64b can each be referred to as R as defined herein 51 Same as described, except that R 51a To R 51e Each of them may not be hydrogen,

[0343] R 52a To R 52e , R 65 To R 68 , R 67a , R 67b , R 68a and R 68b can each be referred to as R as defined herein52 Same as described, except that R 52a To R 52e Each of them may not be hydrogen,

[0344] R 53a To R 53e , R 69a and R 69b can each be referred to as R as defined herein 53 Same as described, except that R 53a To R 53e each may not be hydrogen, and

[0345] *Indicates bonding sites to neighboring atoms.

[0346] In an embodiment, in Formula CY51-1 to Formula CY51-26 and Formula CY52-1 to Formula CY52-26, R 51a To R 51e and R 52a To R 52e Can be independently:

[0347] each unsubstituted or substituted by cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, C 1 -C 10 Alkylphenyl, naphthyl, fluorenyl, phenanthryl, anthracenyl, fluoranthene, triphenylene, pyrenyl, 1,2-benzophenanthryl, pyrrolyl, thienyl, furanyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolyl, isoquinolyl, benzoquinolyl, quinoxalinyl, quinazolinyl, cinnolinyl, carbazolyl, phenanthrolinyl, benzimidazolyl, benzo furanyl, benzothienyl, benzisothiazolyl, benzoxazolyl, benzisoxazolyl, triazolyl, tetrazolyl, oxadiazolyl, triazinyl, dibenzofuranyl, dibenzothienyl, benzocarbazolyl, dibenzocarbazolyl, imidazopyridyl, imidazopyrimidyl, azacarbazolyl, azadibenzofuranyl, azadibenzothienyl, azafluorenyl, azadibenzothiorolyl, or a group represented by Formula 91: deuterium, -F, -Cl, -Br, -I, -CD 3 、-CD 2 H.-CDH 2 , -CF 3 , -CF 2 H, -CFH 2 , hydroxyl, cyano, nitro, C 1 -C 20 Alkyl, C 1 -C 20Alkoxy, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl, norbornenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, phenyl, biphenyl, C 1 -C 10 Alkylphenyl, naphthyl, fluorenyl, phenanthryl, anthracenyl, fluoranthenyl, triphenylene, pyrenyl, 1,2-benzophenanthryl, pyrrolyl, thienyl, furanyl, imidazolyl, pyrazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, pyridinyl, pyrazinyl, pyrimidinyl, pyridazinyl, isoindolyl, indolyl, indazolyl, purinyl, quinolyl, isoquinolyl, benzoquinolyl, quinoline oxalinyl, quinazolinyl, cinnolinyl, carbazolyl, phenanthrolinyl, benzimidazolyl, benzofuranyl, benzothiophenyl, benzisothiazolyl, benzoxazolyl, benzisoxazolyl, triazolyl, tetrazolyl, oxadiazolyl, triazinyl, dibenzofuranyl, dibenzothiophenyl, benzocarbazolyl, dibenzocarbazolyl, imidazopyridinyl, imidazopyrimidinyl, or any combination thereof; or

[0348] -C(Q 1 )(Q 2 )(Q 3 ) or -Si(Q 1 )(Q 2 )(Q 3 ),

[0349] Q 1 To Q 3 can be each independently unsubstituted or substituted with deuterium, C 1 -C 10 phenyl, naphthyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl or triazinyl substituted with alkyl, phenyl, biphenyl, pyridyl, pyrimidyl, pyridazinyl, pyrazinyl, triazinyl or any combination thereof,

[0350] In formula CY51-16 and formula CY51-17, Y 63 Can be O or S and Y 64 Can be Si(R 64a )(R 64b ), or Y 63 Can be Si(R 63a )(R 63b ) and Y 64 can be O or S, and

[0351] In formula CY52-16 and formula CY52-17, Y 67 Can be O or S, and Y 68 Can be Si(R 68a )(R 68b ), or Y 67 Can be Si(R 67a )(R 67b ), and Y68 Can be O or S.

[0352] In an embodiment, in Formula 3-1 to Formula 3-5, L 81 To L 85 Can be independently:

[0353] single bond;

[0354] *-C(Q 4 )(Q 5 )-*' or *-Si(Q 4 )(Q 5 )-*';or

[0355] phenyl, naphthyl, anthracenyl, phenanthrenyl, triphenylene, pyrenyl, 1,2-benzophenanthryl, cyclopentadienyl, furanyl, thienyl, thirol, indenyl, fluorenyl, indolyl, carbazolyl, benzofuranyl, dibenzofuranyl, benzothienyl, dibenzothienyl, benzothirol, dibenzothirol, pyridyl, pyrrolyl, benzoxadiazolyl or benzothiadiazolyl, each unsubstituted or substituted by deuterium, -F, -Cl, -Br, -I, hydroxy, cyano, nitro, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, phenyl, naphthyl, pyridyl, pyrimidyl, triazine, fluorenyl, dimethylfluorenyl, diphenylfluorenyl, carbazolyl, phenylcarbazolyl, dibenzofuranyl, dibenzothiophenyl, dibenzosilyl, dimethyldibenzosilyl, diphenyldibenzosilyl, -Si(Q) 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 )、-P(=O)(Q 31 )(Q 32 ) or any combination thereof, and

[0356] Where Q 4 , Q 5 and Q 31 To Q 33 can be independently hydrogen, deuterium, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, phenyl, biphenyl, terphenyl, pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl or triazinyl.

[0357] In an embodiment, in Formula 3-1 and Formula 3-2, The group represented by may be a group represented by one of formula CY71-1(1) to formula CY71-1(8), and / or

[0358] In equation 3-1 and equation 3-3, The group represented by may be a group represented by one of formula CY71-2(1) to formula CY71-2(8), and / or

[0359] In formula 3-2 and formula 3-4, The group represented by may be a group represented by one of formula CY71-3(1) to formula CY71-3(32), and / or

[0360] In equations 3-3 to 3-5, The group represented by may be a group represented by one of formula CY71-4(1) to formula CY71-4(32), and / or

[0361] In formula 3-5, The group represented may be a group represented by one of the formulas CY71-5(1) to CY71-5(8):

[0362]

[0363]

[0364]

[0365]

[0366] Wherein, in Formula CY71-1(1) to Formula CY71-1(8), Formula CY71-2(1) to Formula CY71-2(8), Formula CY71-3(1) to Formula CY71-3(32), Formula CY71-4(1) to Formula CY71-4(32) and Formula CY71-5(1) to Formula CY71-5(8),

[0367] X 82 To X 85 , L 81 ,b81,R 81 and R 85 may be the same as described in this article, respectively,

[0368] X 86 Can be single bond, O, S, N(R 86 )、B(R 86 )、C(R 86a )(R 86b) or Si(R 86a )(R 86b ),

[0369] X 87 Can be single bond, O, S, N(R 87 )、B(R 87 )、C(R 87a )(R 87b ) or Si(R 87a )(R 87b ),

[0370] In Formula CY71-1(2) to Formula CY71-1(4), Formula CY71-4(2) to Formula CY71-4(4), Formula CY71-4(10) to Formula CY71-4(12), Formula CY71-4(18) to Formula CY71-4(20), and Formula CY71-4(26) to Formula CY71-4(28), X 86 and X 87 They may not all be single bonds at the same time.

[0371] X 88 Can be single bond, O, S, N(R 88 )、B(R 88 )、C(R 88a )(R 88b ) or Si(R 88a )(R 88b ),

[0372] X 89 Can be single bond, O, S, N(R 89 )、B(R 89 )、C(R 89a )(R 89b ) or Si(R 89a )(R 89b ),

[0373] In Formulas CY71-2(2) to CY71-2(4), CY71-3(2) to CY71-3(4), CY71-3(10) to CY71-3(12), CY71-3(18) to CY71-3(20), CY71-3(26) to CY71-3(28), and CY71-5(2) to CY71-5(4), X 88 and X 89 may not each be a single bond at the same time, and

[0374] R 86 To R 89 , R 86a , R 86b , R 87a , R87b , R 88a , R 88b , R 89a and R 89b can each be independently identified with reference to R as defined herein 81 Same as described.

[0375] [Examples of Compounds]

[0376] In an embodiment, the amine compound may be selected from Compound 1 to Compound 206:

[0377]

[0378]

[0379]

[0380]

[0381]

[0382]

[0383]

[0384]

[0385]

[0386]

[0387] In an embodiment, the second compound may be one of compounds ETH1 to ETH100:

[0388]

[0389]

[0390]

[0391]

[0392] In an embodiment, the third compound may be one of compound HTH1 to compound HTH41:

[0393]

[0394]

[0395] In an embodiment, the fourth compound may be one of compound DFD1 to compound DFD29:

[0396]

[0397]

[0398] In an embodiment, the fifth compound may include one or any combination of Compound PD1 to Compound PD39:

[0399]

[0400]

[0401]

[0402] In the above compounds, Ph represents phenyl, D 5 indicates that it is replaced by five deuteriums, and D 4 means replaced by four deuterium. The group represented by The groups represented are the same.

[0403] [ Figure 1 Description]

[0404] Figure 1 1 is a schematic cross-sectional view of a light emitting device 10 according to an embodiment. The light emitting device 10 includes a first electrode 110 , an interlayer 130 , and a second electrode 150 .

[0405] Below, we will refer to Figure 1 A structure of a light emitting device 10 and a method of manufacturing the light emitting device 10 according to an embodiment are described.

[0406] [First electrode 110]

[0407] exist Figure 1 In the embodiment, a substrate may be further included under the first electrode 110 or on the second electrode 150. In an embodiment, the substrate may be a glass substrate or a plastic substrate. In an embodiment, the substrate may be a flexible substrate and may include plastic having excellent heat resistance and durability, such as polyimide, polyethylene terephthalate (PET), polycarbonate, polyethylene naphthalate, polyarylate (PAR), polyetherimide, or any combination thereof.

[0408] The first electrode 110 may be formed, for example, by depositing or sputtering a material for forming the first electrode 110 on a substrate. When the first electrode 110 is an anode, the material for forming the first electrode 110 may be a high work function material that facilitates injection of holes.

[0409] The first electrode 110 may be a reflective electrode, a semi-transmissive electrode, or a transmissive electrode. In an embodiment, when the first electrode 110 is a transmissive electrode, a material for forming the first electrode 110 may include indium tin oxide (ITO), indium zinc oxide (IZO), tin oxide (SnO 2 ), zinc oxide (ZnO), or any combination thereof. In an embodiment, when the first electrode 110 is a semi-transmissive electrode or a reflective electrode, the material used to form the first electrode 110 may include magnesium (Mg), silver (Ag), aluminum (Al), aluminum-lithium (Al-Li), calcium (Ca), magnesium-indium (Mg-In), magnesium-silver (Mg-Ag), or any combination thereof.

[0410] The first electrode 110 may have a single-layer structure consisting of a single layer or a multi-layer structure including a plurality of layers. For example, the first electrode 110 may have a triple-layer structure of ITO / Ag / ITO.

[0411] [Interlayer 130]

[0412] The interlayer 130 may be disposed on the first electrode 110. The interlayer 130 may include an emission layer.

[0413] The interlayer 130 may further include a hole transport region between the first electrode 110 and the emission layer, and an electron transport region between the emission layer and the second electrode 150 .

[0414] In addition to various organic materials, the interlayer 130 may further include metal-containing compounds or inorganic materials (such as quantum dots), etc.

[0415] In an embodiment, the interlayer 130 may include two or more emission units stacked between the first electrode 110 and the second electrode 150 and at least one charge generation layer between the two or more emission units. When the interlayer 130 includes two or more emission units and at least one charge generation layer, the light emitting device 10 may be a tandem light emitting device.

[0416] [Hole Transport Region in Interlayer 130]

[0417] The hole transport region may have a single-layer structure composed of a single layer (composed of a single material), a single-layer structure composed of a single layer containing different materials, or a multi-layer structure including a plurality of layers containing different materials.

[0418] The hole transport region may include a hole injection layer, a hole transport layer, an emission assisting layer, an electron blocking layer, or any combination thereof.

[0419] In an embodiment, the hole transport region may have a multi-layer structure, which includes a hole injection layer / hole transport layer structure, a hole injection layer / hole transport layer / emission auxiliary layer structure, a hole injection layer / emission auxiliary layer structure, a hole transport layer / emission auxiliary layer structure or a hole injection layer / hole transport layer / emission auxiliary layer structure, wherein the layers of each structure may be stacked from the first electrode 110 in the order described in their respective descriptions, but the structure of the hole transport region is not limited thereto.

[0420] The hole transport region may include a compound represented by Formula 201, a compound represented by Formula 202, or any combination thereof:

[0421] [Formula 201]

[0422]

[0423] [Formula 202]

[0424]

[0425] In equation 201 and equation 202,

[0426] L 201 To L 204 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0427] L 205 Can be *-O-*', *-S-*', *-N(Q 201 )-*', unsubstituted or replaced by at least one R 10a Substituted C 1 -C 20 Alkylene, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 20 Alkenylene, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0428] xa1 to xa4 may each independently be an integer selected from 0 to 5,

[0429] xa5 may be an integer selected from 1 to 10,

[0430] R 201 To R 204 and Q 201 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0431] R 201 and R 202 may be optionally substituted by a single bond, unsubstituted or by at least one R 10a Substituted C 1 -C 5 Alkylene is either unsubstituted or substituted with at least one R 10a Substituted C 2 -C 5 Alkenylene groups are connected to each other to form an unsubstituted or substituted R 10a Substituted C 8 -C 60 Polycyclic groups (eg, carbazole groups, etc.) (eg, see compound HT16),

[0432] R 203 and R 204 may be optionally substituted by a single bond, unsubstituted or by at least one R 10a Substituted C 1 -C 5 Alkylene is either unsubstituted or substituted with at least one R 10a Substituted C 2 -C 5 Alkenylene groups are connected to each other to form an unsubstituted or substituted R 10a Substituted C 8 -C 60 polycyclic groups, and

[0433] na1 may be an integer selected from 1 to 4.

[0434] In an embodiment, the compound represented by Formula 201 and the compound represented by Formula 202 may each independently include at least one of the groups represented by Formulas CY201 to CY217:

[0435]

[0436] In formula CY201 to formula CY217, R 10b and R 10c Can be independently compared with reference R 10a Same as described, CY201 To Ring CY 204 Can be independently C 3 -C 20 Carbocyclic or C 1 -C 20 heterocyclic group, and at least one hydrogen in Formula CY201 to Formula CY217 may be unsubstituted or replaced by R 10a replace.

[0437] In an embodiment, ring CY in formula CY201 to formula CY217 201 To Ring CY 204 Each independently may be phenyl, naphthyl, phenanthryl or anthracenyl.

[0438] In an embodiment, the compound represented by Formula 201 and the compound represented by Formula 202 may each independently include at least one of the groups represented by Formulas CY201 to CY203.

[0439] In an embodiment, the compound represented by Formula 201 may include at least one of the groups represented by Formulas CY201 to CY203 and at least one of the groups represented by Formulas CY204 to CY217.

[0440] In an embodiment, in Formula 201, xa1 may be 1, R 201 may be a group represented by one of the formulas CY201 to CY203, xa2 may be 0, and R 202 It may be one of the groups represented by formulae CY204 to CY207.

[0441] In an embodiment, the compound represented by Formula 201 and the compound represented by Formula 202 may each not include the groups represented by Formula CY201 to Formula CY203.

[0442] In an embodiment, the compound represented by Formula 201 and the compound represented by Formula 202 may each not include the groups represented by Formula CY201 to Formula CY203, and may each independently include at least one of the groups represented by Formula CY204 to Formula CY217.

[0443] In an embodiment, the compound represented by Formula 201 and the compound represented by Formula 202 may each not include a group represented by one of Formulas CY201 to CY217.

[0444] In an embodiment, the hole transport region may include: one of compounds HT1 to HT46; m-MTDATA; TDATA; 2-TNATA; NPB (NPD); β-NPB; TPD; spiro TPD; spiro NPB; methylated NPB; TAPC; HMTPD; 4,4',4"-tri(N-carbazolyl)triphenylamine (TCTA); polyaniline / dodecylbenzenesulfonic acid (PANI / DBSA); poly(3,4-ethylenedioxythiophene) / poly(4-styrenesulfonate) (PEDOT / PSS); polyaniline / camphorsulfonic acid (PANI / CSA); polyaniline / poly(4-styrenesulfonate) (PANI / PSS); or any combination thereof:

[0445]

[0446]

[0447]

[0448]

[0449]

[0450] The thickness of the hole transport region may be about to about For example, the thickness of the hole transport region may be in the range of about to about When the hole transport region includes a hole injection layer, a hole transport layer, or any combination thereof, the thickness of the hole injection layer may be about to about and the thickness of the hole transport layer may be in the range of about to about For example, the thickness of the hole injection layer may be in the range of about to about For example, the thickness of the hole transport layer may be in the range of about to about When the thicknesses of the hole transport region, the hole injection layer, and the hole transport layer are within these ranges, satisfactory hole transport characteristics can be obtained without significantly increasing the driving voltage.

[0451] The emission auxiliary layer can increase the luminous efficiency by compensating the optical resonance distance according to the wavelength of light emitted by the emission layer, and the electron blocking layer can block the leakage of electrons from the emission layer to the hole transport region. The material that can be included in the hole transport region can be included in the emission auxiliary layer and the electron blocking layer.

[0452] [p-dopant]

[0453] In addition to these materials, the hole transport region may further include a charge generation material for improvement of conductive properties. The charge generation material may be uniformly or non-uniformly dispersed in the hole transport region (eg, in the form of a single layer composed of the charge generation material).

[0454] The charge generating material may be, for example, a p-dopant.

[0455] In an embodiment, the p-dopant may have a lowest unoccupied molecular orbital (LUMO) energy level less than or equal to about −3.5 eV.

[0456] In an embodiment, the p-dopant may include a quinone derivative, a cyano group-containing compound, a compound including the element EL1 and the element EL2, or any combination thereof.

[0457] Examples of the quinone derivative may include TCNQ, F4-TCNQ, and the like.

[0458] Examples of the cyano group-containing compound may include HAT-CN and a compound represented by Formula 221, and the like:

[0459]

[0460] [Formula 221]

[0461]

[0462] In formula 221,

[0463] R 221 To R 223 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 a heterocyclic group, and

[0464] R 221 To R 223 At least one of them may be independently C each substituted by 3 -C 60 Carbocyclic or C 1 -C 60 Heterocyclic group: cyano; -F; -Cl; -Br; -I; C substituted by cyano, -F, -Cl, -Br, -I or any combination thereof 1 -C 20 or any combination thereof.

[0465] In a compound including an element EL1 and an element EL2, the element EL1 may be a metal, a metalloid, or any combination thereof, and the element EL2 may be a nonmetal, a metalloid, or any combination thereof.

[0466] Examples of metals may include alkali metals (e.g., lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), etc.); alkaline earth metals (e.g., beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), etc.); transition metals (e.g., titanium (Ti), zirconium (Zr), hafnium (Hf), vanadium (V), niobium (Nb), tantalum (Ta), chromium (Cr), molybdenum (Mo), tungsten (W), manganese (Mn), technetium (Tc), rhenium (Re), iron (Fe), ruthenium (Ru), osmium (Os), cobalt ( Co), rhodium (Rh), iridium (Ir), nickel (Ni), palladium (Pd), platinum (Pt), copper (Cu), silver (Ag), gold (Au), etc.); late transition metals (e.g., zinc (Zn), indium (In), tin (Sn), etc.); and lanthanide metals (e.g., lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), etc.), etc.

[0467] Examples of metalloids may include silicon (Si), antimony (Sb), tellurium (Te), and the like.

[0468] Examples of non-metal may include oxygen (O) and halogen (eg, F, Cl, Br, I, etc.), and the like.

[0469] Examples of compounds including element EL1 and element EL2 may include metal oxides, metal halides (e.g., metal fluorides, metal chlorides, metal bromides, metal iodides, etc.), metalloid halides (e.g., metalloid fluorides, metalloid chlorides, metalloid bromides, metalloid iodides, etc.), metal tellurides, or any combination thereof.

[0470] Examples of metal oxides may include tungsten oxides (eg, WO, W 2 O 3 , WO 2 , WO 3 , W 2 O 5 etc.), vanadium oxides (e.g., VO, V 2 O 3 , VO 2 、V 2 O 5 etc.), molybdenum oxides (e.g., MoO, Mo 2 O 3 、MoO 2、MoO 3 、Mo 2 O 5 etc.) and rhenium oxides (e.g., ReO 3 etc.

[0471] Examples of the metal halide may include alkali metal halides, alkaline earth metal halides, transition metal halides, post-transition metal halides, lanthanide metal halides, and the like.

[0472] Examples of alkali metal halides may include LiF, NaF, KF, RbF, CsF, LiCl, NaCl, KCl, RbCl, CsCl, LiBr, NaBr, KBr, RbBr, CsBr, LiI, NaI, KI, RbI, CsI, and the like.

[0473] Examples of alkaline earth metal halides may include BeF 2 MgF 2 , CaF 2 , SrF 2 , BaF 2 、BeCl 2 MgCl 2 , CaCl 2 、SrCl 2 、BaCl 2 ,BeBr 2 MgBr 2 , CaBr 2 , SrBr 2 ,BaBr 2 ,BeI 2 MgI 2 ,CaI 2 , SrI 2 and BaI 2 wait.

[0474] Examples of transition metal halides may include titanium halides (eg, TiF 4 、TiCl 4 、TiBr 4 、TiI 4 etc.), zirconium halides (e.g., ZrF 4 、ZrCl 4 , ZrBr 4 , ZrI 4 etc.), hafnium halides (e.g., HfF 4 , HfCl 4 , HfBr 4 , HfI 4 etc.), vanadium halides (e.g., VF 3 、VCl 3 , VBr3 VI 3 etc.), niobium halides (e.g., NbF 3 、NbCl 3 , NbBr 3 , NbI 3 etc.), tantalum halides (e.g., TaF 3 、TaCl 3 、TaBr 3 、TaI 3 etc.), chromium halides (e.g., CrF 3 CrCl 3 CrBr 3 CrI 3 etc.), molybdenum halides (e.g., MoF 3 、MoCl 3 、MoBr 3 、MoI 3 etc.), tungsten halides (e.g., WF 3 、WCl 3 , WBr 3 , WI 3 etc.), manganese halides (e.g., MnF 2 、MnCl 2 、MnBr 2 、MnI 2 etc.), technetium halides (e.g., TcF 2 , TcCl 2 , TcBr 2 , TcI 2 etc.), rhenium halides (e.g., ReF 2 、ReCl 2 、ReBr 2 、ReI 2 etc.), ferrous halides (e.g., FeF 2 、FeCl 2 , FeBr 2 ,FeI 2 etc.), ruthenium halides (e.g., RuF 2 、RuCl 2 ,RuBr 2 , RuI 2 etc.), osmium halides (e.g., OsF 2 , OsCl 2 、OsBr 2 , OsI 2 etc.), cobalt halides (e.g., CoF 2 、CoCl 2 ,CoBr 2 、CoI 2 etc.), rhodium halides (e.g., RhF2 , RhCl 2 , RhBr 2 , RhI 2 etc.), iridium halides (e.g., IrF 2 、IrCl 2 ,IrBr 2 ,IrI 2 etc.), nickel halides (e.g., NiF 2 、NiCl 2 、NiBr 2 , NiI 2 etc.), palladium halides (e.g., PdF 2 , PdCl 2 , PdBr 2 , PdI 2 etc.), platinum halides (e.g., PtF 2 、PtCl 2 , PtBr 2 , PtI 2 etc.), cuprous halides (e.g., CuF, CuCl, CuBr, CuI, etc.), silver halides (e.g., AgF, AgCl, AgBr, AgI, etc.), and gold halides (e.g., AuF, AuCl, AuBr, AuI, etc.), etc.

[0475] Examples of late transition metal halides may include zinc halides (eg, ZnF 2 、ZnCl 2 、ZnBr 2 、ZnI 2 etc.), indium halides (e.g., InI 3 etc.) and tin halides (e.g., SnI 2 etc.

[0476] Examples of lanthanide metal halides may include YbF, YbF 2 , YbF 3 、SmF 3 、YbCl、YbCl 2 YbCl 3 、SmCl 3 , YbBr, YbBr 2 , YbBr 3 、SmBr 3 、YbI、YbI 2 ,YbI 3 and SmI 3 wait.

[0477] Examples of metalloid halides may include antimony halides (eg, SbCl 5 etc.

[0478] Examples of metal tellurides may include alkali metal tellurides (eg, Li 2 Te、Na 2 Te, K 2 Te、Rb 2 Te, Cs 2 Te, etc.), alkaline earth metal tellurides (e.g., BeTe, MgTe, CaTe, SrTe, BaTe, etc.), transition metal tellurides (e.g., TiTe 2 、ZrTe 2 、HfTe 2 、V 2 Te 3 , Nb 2 Te 3 、 2 Te 3 Cr 2 Te 3 、Mo 2 Te 3 , W 2 Te 3 , MnTe, TcTe, ReTe, FeTe, RuTe, OsTe, CoTe, RhTe, IrTe, NiTe, PdTe, PtTe, Cu 2 Te, CuTe, Ag 2 Te, AgTe, Au 2 Te, etc.), late transition metal tellurides (e.g., ZnTe, etc.), and lanthanide metal tellurides (e.g., LaTe, CeTe, PrTe, NdTe, PmTe, EuTe, GdTe, TbTe, DyTe, HoTe, ErTe, TmTe, YbTe, LuTe, etc.), etc.

[0479] [Emitting layer in interlayer 130]

[0480] When the light-emitting device 10 is a full-color light-emitting device, the emission layer may be patterned into a red emission layer, a green emission layer, and / or a blue emission layer according to the sub-pixel. In an embodiment, the emission layer may have a stacked structure of two or more layers of a red emission layer, a green emission layer, and a blue emission layer, wherein the two or more layers may contact each other or may be separated from each other to emit white light. In an embodiment, the emission layer may include two or more materials of a red light-emitting material, a green light-emitting material, and a blue light-emitting material, wherein the two or more materials may be mixed with each other in a single layer to emit white light.

[0481] In an embodiment, the emission layer may include a host and a dopant (or emitter). In an embodiment, in addition to the host and the dopant (or emitter), the emission layer may further include an auxiliary dopant that promotes energy transfer to the dopant (or to the emitter). When the emission layer includes a dopant (or emitter) and an auxiliary dopant, the dopant (or emitter) and the auxiliary dopant may be different from each other.

[0482] The amount of the dopant (or emitter) in the emission layer may be in the range of about 0.01 parts by weight to about 15 parts by weight based on 100 parts by weight of the host.

[0483] In an embodiment, the emissive layer may include quantum dots.

[0484] In an embodiment, the emission layer may include a delayed fluorescent material (compound). The delayed fluorescent material may be used as a host or a dopant in the emission layer.

[0485] The thickness of the emission layer can be about to about For example, the thickness of the emission layer may be in the range of about to about When the thickness of the emission layer is within any one of these ranges, excellent light emitting characteristics can be obtained without significantly increasing the driving voltage.

[0486] [main body]

[0487] In an embodiment, the host may include a compound represented by Formula 301:

[0488] [Formula 301]

[0489] [Ar 301 ] xb11 -[(L 301 ) xb1 -R 301 ] xb21 .

[0490] In formula 301,

[0491] Ar 301 and L 301 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0492] xb11 can be 1, 2 or 3,

[0493] xb1 may be an integer selected from 0 to 5,

[0494] R 301 It may be hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, -Si(Q 301 )(Q 302 )(Q 303 )、-N(Q 301 )(Q 302 )、-B(Q 301 )(Q 302 )、-C(=O)(Q 301 )、-S(=O) 2 (Q 301 ) or -P(=O)(Q 301 )(Q 302 ),

[0495] xb21 may be an integer selected from 1 to 5, and

[0496] Q 301 To Q 303 Each independently and with reference Q 1 Same as described.

[0497] In an embodiment, in Formula 301, when xb11 is 2 or greater, two or more Ar 301 Can be connected to each other via a single bond.

[0498] In an embodiment, the host may include a compound represented by Formula 301-1, a compound represented by Formula 301-2, or any combination thereof:

[0499] [Formula 301-1]

[0500]

[0501] [Formula 301-2]

[0502]

[0503] In Formula 301-1 and Formula 301-2,

[0504] Ring A 301 To Ring A 304 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0505] X 301 Can be O, S, N[(L 304 ) xb4 -R 304 ]、C(R 304 )(R 305 ) or Si(R 304 )(R 305 ),

[0506] xb22 and xb23 can each independently be 0, 1 or 2,

[0507] L 301 , xb1 and R 301 each being the same as described herein,

[0508] L 302 To L 304 Can be independently compared with reference L 301 Same as described,

[0509] xb2 to xb4 may each independently be the same as described with reference to xb1, and

[0510] R 302 To R 305 and R 311 To R 314 Can be independently compared with reference R 301 Same as described.

[0511] In embodiments, the host may include an alkaline earth metal complex, a late transition metal complex, or any combination thereof. In embodiments, the host may include a Be complex (eg, compound H55), a Mg complex, a Zn complex, or any combination thereof.

[0512] In an embodiment, the host may include: one of Compound H1 to Compound H128; 9,10-di(2-naphthyl)anthracene (ADN); 2-methyl-9,10-bis(naphthalene-2-yl)anthracene (MADN); 9,10-di(2-naphthyl)-2-tert-butyl-anthracene (TBADN); 4,4′-bis(N-carbazolyl)-1,1′-biphenyl (CBP); 1,3-di(9-carbazolyl)benzene (mCP); 1,3,5-tri(carbazolyl-9-yl)benzene (TCP); or any combination thereof:

[0513]

[0514]

[0515]

[0516]

[0517]

[0518]

[0519]

[0520] In an embodiment, the host may include a silicon-containing compound, a phosphine oxide-containing compound, or any combination thereof.

[0521] The host may have various modifications. For example, the host may include only one compound, or may include two or more different kinds of compounds.

[0522] [Phosphorescent dopant]

[0523] The emissive layer may include a phosphorescent dopant.

[0524] The phosphorescent dopant may include at least one transition metal as a central metal. Accordingly, the phosphorescent dopant may correspond to the fifth compound.

[0525] The phosphorescent dopant may include a monodentate ligand, a bidentate ligand, a tridentate ligand, a tetradentate ligand, a pentadentate ligand, a hexadentate ligand, or any combination thereof.

[0526] The phosphorescent dopant may be electrically neutral.

[0527] In an embodiment, the phosphorescent dopant may include an organometallic compound represented by Formula 401:

[0528] [Formula 401]

[0529] M(L 401 ) xc1 (L 402 ) xc2.

[0530] In formula 401,

[0531] M may be a transition metal (e.g., iridium (Ir), platinum (Pt), palladium (Pd), osmium (Os), titanium (Ti), gold (Au), hafnium (Hf), europium (Eu), terbium (Tb), rhodium (Rh), rhenium (Re), or thulium (Tm)),

[0532] L 401 may be a ligand represented by Formula 402, and xc1 may be 1, 2 or 3, wherein when xc1 is 2 or greater, two or more L 401 may be the same or different from each other,

[0533] [Formula 402]

[0534]

[0535] L 402 may be an organic ligand, and xc2 may be 0, 1, 2, 3 or 4, wherein when xc2 is 2 or greater, two or more L 402 may be the same or different from each other,

[0536] In formula 402,

[0537] X 401 and X 402 can be independently N or C,

[0538] Ring A 401 and Ring A 402 Can be independently C 3 -C 60 Carbocyclic or C 1 -C 60 Heterocyclic group,

[0539] T 401 It can be a single bond, *-O-*', *-S-*', *-C(=O)-*', *-N(Q 411 )-*'、*-C(Q 411 )(Q 412 )-*',

[0540] *-C(Q 411 )=C(Q 412 )-*'、*-C(Q 411 )=*'or*=C=*',

[0541] X 403 and X 404 can be independently a chemical bond (e.g., a covalent bond or a coordination bond), O, S, N (Q 413 )、B(Q 413)、P(Q 413 )、C(Q 413 )(Q 414 ) or Si(Q 413 )(Q 414 ),

[0542] Q 411 To Q 414 Can be independently compared with reference Q 1 Same as described,

[0543] R 401 and R 402 can be independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 20 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 20 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, -Si(Q 401 )(Q 402 )(Q 403 )、-N(Q 401 )(Q 402 )、-B(Q 401 )(Q 402 )、-C(=O)(Q 401 )、-S(=O) 2 (Q 401 ) or -P(=O)(Q 401 )(Q 402 ),

[0544] Q 401 To Q 403 Can be independently compared with reference Q 1 Same as described,

[0545] xc11 and xc12 may each independently be an integer selected from 0 to 10, and

[0546] * and *' in Formula 402 each indicate a bonding site to M in Formula 401.

[0547] In an embodiment, in formula 402, X 401 may be nitrogen and X 402 Can be carbon, or X401 and X 402 Each may be nitrogen.

[0548] In an embodiment, in Formula 401, when xc1 is 2 or greater, two or more L 401 The two rings A 401 Optionally, T can be used as a linking group 402 connected to each other, and two or more L 401 The two rings A 402 Optionally, T can be used as a linking group 403 Connected to each other (see Compound PD1 to Compound PD4 and Compound PD7). 402 and T 403 Can be independently compared with reference T 401 Same as described.

[0549] In formula 401, L 402 It can be an organic ligand. For example, L 402 It may include a halogen group, a diketone group (e.g., an acetylacetonate group), a carboxylic acid group (e.g., a picolinate group), -C(=O), an isonitrile group, a -CN group, a phosphorus-containing group (e.g., a phosphine group, a phosphite group, etc.), or any combination thereof.

[0550] The phosphorescent dopant may include, for example, one of Compound PD1 to Compound PD39 or any combination thereof:

[0551]

[0552]

[0553]

[0554] [Fluorescent dopant]

[0555] The emission layer may include a fluorescent dopant and / or an auxiliary dopant.

[0556] In an embodiment, the fluorescent dopant and / or the auxiliary dopant may each independently include a compound represented by Formula 501:

[0557] [Formula 501]

[0558]

[0559] In formula 501,

[0560] Ar 501 , L 501 To L 503 , R 501 and R 502may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0561] xd1 to xd3 may each independently be 0, 1, 2 or 3, and

[0562] xd4 can be 1, 2, 3, 4, 5 or 6.

[0563] In an embodiment, in Formula 501, Ar 501 It may be a condensed ring group in which three or more monocyclic groups are condensed together (for example, anthracenyl, 1,2-triphenylenyl, pyrenyl, etc.).

[0564] In an embodiment, in formula 501, xd4 may be 2.

[0565] In an embodiment, the fluorescent dopant and the auxiliary dopant may each include one of compounds FD1 to FD38, DPVBi, DPAVBi, or any combination thereof:

[0566]

[0567]

[0568]

[0569]

[0570] [Delayed fluorescence material]

[0571] The emission layer may include a delayed fluorescent material (compound).

[0572] In the specification, the delayed fluorescent material may be selected from compounds capable of emitting delayed fluorescence based on a delayed fluorescence emission mechanism.

[0573] The delayed fluorescent material included in the emission layer may serve as a host or as a dopant depending on the types of other materials included in the emission layer.

[0574] In an embodiment, the difference between the triplet energy level (eV) of the delayed fluorescent material and the singlet energy level (eV) of the delayed fluorescent material may be in the range of about 0 eV to about 0.5 eV. When the difference between the triplet energy level (eV) of the delayed fluorescent material and the singlet energy level (eV) of the delayed fluorescent material satisfies the above range, up-conversion of the delayed fluorescent material from the triplet state to the singlet state may effectively occur, and therefore, the light emitting device 10 may have improved luminous efficiency.

[0575] In an embodiment, the delayed fluorescent material may include: at least one electron donor (eg, a π-electron-rich C 3 -C 60 cyclic groups, such as carbazolyl) and at least one electron acceptor (e.g., sulfoxide, cyano, and π-electron-deficient nitrogen-containing C 1 -C 60 or a C-containing group containing at least two cyclic groups fused to each other while sharing boron (B). 8 -C 60 Materials with polycyclic groups, etc.

[0576] Examples of the delayed fluorescent material may include at least one of Compound DF1 to Compound DF14:

[0577]

[0578]

[0579] [Quantum dot]

[0580] The emissive layer may include quantum dots.

[0581] In the specification, a quantum dot may be a crystal of a semiconductor compound and may include any material capable of emitting light of various emission wavelengths according to the size of the crystal. By adjusting the ratio of elements included in the quantum dot compound, the quantum dot may emit light of various emission wavelengths.

[0582] For example, the diameter of the quantum dots may be in the range of about 1 nm to about 10 nm.

[0583] The quantum dots may be synthesized by a wet chemical process, a metal organic chemical vapor deposition (MOCVD) process, a molecular beam epitaxy (MBE) process, or any process similar thereto.

[0584] The wet chemical process is a method that includes mixing a precursor material with an organic solvent and growing a quantum dot particle crystal. When the quantum dot particle crystal grows, the organic solvent naturally acts as a dispersant coordinated on the surface of the quantum dot particle crystal and controls the growth of the quantum dot particle crystal, so that the growth of the quantum dot particle crystal can be controlled by a process that is lower in cost and easier to perform than a vapor deposition method such as metal organic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE).

[0585] The quantum dots may include Group II-VI semiconductor compounds, Group III-V semiconductor compounds, Group III-VI semiconductor compounds, Group I-III-VI semiconductor compounds, Group IV-VI semiconductor compounds, Group IV elements or compounds, or any combination thereof.

[0586] Examples of II-VI semiconductor compounds may include binary compounds such as CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnO, HgS, HgSe, HgTe, MgSe, and MgS; ternary compounds such as CdSeS, CdSeTe, CdSTe, ZnSeS, ZnSeTe, ZnSTe, HgSeS, HgSeTe, HgSTe, CdZnS, Cd ZnSe, CdZnTe, CdHgS, CdHgSe, CdHgTe, HgZnS, HgZnSe, HgZnTe, MgZnSe and MgZnS, etc.; quaternary compounds, such as CdZnSeS, CdZnSeTe, CdZnSTe, CdHgSeS, CdHgSeTe, CdHgSTe, HgZnSeS, HgZnSeTe and HgZnSTe, etc.; or any combination thereof.

[0587] Examples of III-V semiconductor compounds may include binary compounds such as GaN, GaP, GaAs, GaSb, AlN, AlP, AlAs, AlSb, InN, InP, InAs, or InSb, etc.; ternary compounds such as GaNP, GaNAs, GaNSb, GaPAs, GaPSb, AlNP, AlNAs, AlNSb, AlPAs, AlPSb, InGaP, InNP, InAlP, InNAs, InNSb, InPAs, or InPSb, etc.; quaternary compounds such as GaAlNP, GaAlNAs, GaAlNSb, GaAlPAs, GaAlPSb, GaInNP, GaInNAs, GaInNSb, GaInPAs, GaInPSb, InAlNP, InAlNAs, InAlNSb, InAlPAs, or InAlPSb, etc.; or any combination thereof. In an embodiment, the III-V semiconductor compound may further include a Group II element. Examples of the Group III-V semiconductor compound further including the Group II element may include InZnP, InGaZnP, InAlZnP, and the like.

[0588] Examples of III-VI semiconductor compounds may include binary compounds such as GaS, GaSe, Ga 2 Se 3 、GaTe、InS、InSe、In 2 S 3 、In 2 Se 3 and InTe, etc.; ternary compounds, such as InGaS 3 and InGaSe 3 etc.; or any combination thereof.

[0589] Examples of Group I-III-VI semiconductor compounds may include: ternary compounds such as AgInS, AgInS 2 、AgInSe 2 、AgGaS、AgGaS 2 、AgGaSe 2 、CuInS、CuInS 2 、CuInSe 2 、CuGaS 2 、CuGaSe 2 、CuGaO 2 、AgGaO 2 、AgAlO 2 etc.; quaternary compounds, such as AgInGaS 2 、AgInGaSe 2 etc.; or any combination thereof.

[0590] Examples of Group IV-VI semiconductor compounds may include: binary compounds, such as SnS, SnSe, SnTe, PbS, PbSe and PbTe; ternary compounds, such as SnSeS, SnSeTe, SnSTe, PbSeS, PbSeTe, PbSTe, SnPbS, SnPbSe and SnPbTe; quaternary compounds, such as SnPbSSe, SnPbSeTe and SnPbSTe; or any combination thereof.

[0591] Examples of Group IV elements or compounds may include: single element materials such as Si and Ge, etc.; binary compounds such as SiC and SiGe, etc.; or any combination thereof.

[0592] Each element included in a multi-element compound (such as a binary compound, a ternary compound, and a quaternary compound) may be present in a particle at a uniform concentration or a non-uniform concentration. For example, the above formula refers to the type of element included in the compound, wherein the ratio of the elements in the compound may vary. For example, AgInGaS 2 AgIn x Ga 1-x S 2 (where x is a real number between 0 and 1).

[0593] In an embodiment, the quantum dot may have a single structure in which the concentration of each element in the quantum dot is uniform, or the quantum dot may have a core-shell structure. In an embodiment, when the quantum dot has a core-shell structure, the material included in the core and the material included in the shell may be different from each other.

[0594] The shell of the quantum dot can be used as a protective layer to prevent chemical denaturation of the core to maintain semiconductor properties, and / or can be used as a charging layer to impart electrophoretic properties to the quantum dot. The shell can be a single layer or multiple layers. The interface between the core and the shell can have a concentration gradient, wherein the concentration of the material present in the shell decreases toward the center of the core.

[0595] Examples of the shell of the quantum dot may include metal oxides, metalloid oxides, non-metal oxides, semiconductor compounds, or any combination thereof. Examples of metal oxides, metalloid oxides, or non-metal oxides may include: binary compounds, such as SiO 2 、Al 2 O 3 、TiO 2 、ZnO、MnO、Mn 2 O 3 , Mn 3 O 4 , CuO, FeO, Fe 2 O 3 , Fe 3 O4 , CoO, Co 3 O 4 and NiO, etc.; ternary compounds, such as MgAl 2 O 4 、CoFe 2 O 4 、NiFe 2 O 4 and CoMn 2 O 4 etc.; or any combination thereof.

[0596] Examples of semiconductor compounds may include: as described herein, Group II-VI semiconductor compounds; Group III-V semiconductor compounds; Group III-VI semiconductor compounds; Group I-III-VI semiconductor compounds; Group IV-VI semiconductor compounds; or any combination thereof. Examples of semiconductor compounds may include CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnSeS, ZnTeS, GaAs, GaP, GaSb, HgS, HgSe, HgTe, InAs, InP, InGaP, InSb, AlAs, AlP, AlSb, or any combination thereof.

[0597] The quantum dots may have a full width at half maximum (FWHM) of an emission wavelength spectrum in the range of about 45 nm to about 40 nm. For example, the quantum dots may have a FWHM of an emission wavelength spectrum equal to or less than 30 nm. When the FWHM of the emission wavelength spectrum of the quantum dots is within these ranges, the quantum dots may have improved color purity or improved color reproducibility. In addition, since the light emitted by the quantum dots is emitted in all directions, a wide viewing angle may be improved.

[0598] In embodiments, the quantum dots may be in the form of spherical nanoparticles, pyramidal nanoparticles, multi-armed nanoparticles, cubic nanoparticles, nanotubes, nanowires, nanofibers, or nanoplates.

[0599] Because the energy band gap can be adjusted by controlling the size of the quantum dots, light with various wavelength bands can be obtained from the quantum dot emission layer. Accordingly, by using quantum dots of different sizes, a light-emitting device that emits light of various wavelength bands can be implemented. For example, the size of the quantum dots or the ratio of elements in the quantum dot compound can be selected to emit red light, green light, and / or blue light. In an embodiment, the size of the quantum dots can be configured to emit white light through a combination of various colors of light.

[0600] [Electron Transport Region in Interlayer 130]

[0601] The electron transport region may have a single-layer structure composed of a single layer (composed of a single material), a single-layer structure composed of a single layer including different materials, or a multi-layer structure including a plurality of layers including different materials.

[0602] The electron transport region may include a buffer layer, a hole blocking layer, an electron control layer, an electron transport layer, an electron injection layer, or any combination thereof.

[0603] In an embodiment, the electron transport region may have an electron transport layer / electron injection layer structure, a hole blocking layer / electron transport layer / electron injection layer structure, an electron control layer / electron transport layer / electron injection layer structure, or a buffer layer / electron transport layer / electron injection layer structure, wherein the layers of each structure may be stacked in their respective described order from the emission layer, but the structure of the electron transport region is not limited thereto.

[0604] The electron transport region (eg, a buffer layer, a hole blocking layer, an electron control layer, or an electron transport layer in the electron transport region) may include a nitrogen-containing C 1 -C 60 Metal-free compounds of heterocyclic groups.

[0605] In an embodiment, the electron transport region may include a compound represented by Formula 601:

[0606] [Formula 601]

[0607] [Ar 601 ] xe11 -[(L 601 ) xe1 -R 601 ] xe21 .

[0608] In formula 601,

[0609] Ar 601 and L 601 may be each independently unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group,

[0610] xe11 can be 1, 2 or 3,

[0611] xe1 can be 0, 1, 2, 3, 4 or 5,

[0612] R 601 may be unsubstituted or substituted with at least one R 10a Substituted C 3 -C60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, -Si(Q 601 )(Q 602 )(Q 603 )、-C(=O)(Q 601 )、-S(=O) 2 (Q 601 ) or -P(=O)(Q 601 )(Q 602 ),

[0613] Q 601 To Q 603 Can be independently compared with reference Q 1 Same as described,

[0614] xe21 can be 1, 2, 3, 4, or 5, and

[0615] Ar 601 , L 601 and R 601 At least one of them may be independently unsubstituted or substituted by at least one R 10a Substituted π-electron-deficient nitrogen-containing C 1 -C 60 Heterocyclic group.

[0616] In an embodiment, in Formula 601, when xe11 is 2 or greater, two or more Ar 601 Can be connected to each other via a single bond.

[0617] In an embodiment, in Formula 601, Ar 601 may be unsubstituted or substituted with at least one R 10a substituted or anthracenyl.

[0618] In an embodiment, the electron transport region may include a compound represented by Formula 601-1:

[0619] [Formula 601-1]

[0620]

[0621] In formula 601-1,

[0622] X 614 Can be N or C(R 614 ), X 615 Can be N or C(R 615 ), X 616 Can be N or C(R 616 ), and X 614 To X 616At least one of them may each be N,

[0623] L 611 To L 613 Can be independently compared with reference L 601 Same as described,

[0624] xe611 to xe613 can each independently be the same as described with reference to xe1,

[0625] R 611 To R 613 Can be independently compared with reference R 601 Same as described, and

[0626] R 614 To R 616 can be independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 20 Alkyl, C 1 -C 20 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group.

[0627] In an embodiment, in Formula 601 and Formula 601-1, xe1 and xe611 to xe613 may each independently be 0, 1, or 2.

[0628] In an embodiment, the electron transport region may include: one of Compound ET1 to Compound ET45; 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP); 4,7-diphenyl-1,10-phenanthroline (Bphen); Alq 3 ; BAlq; TAZ; NTAZ; or any combination thereof:

[0629]

[0630]

[0631]

[0632] The thickness of the electron transport region can be about to about For example, the thickness of the electron transport region may be in the range of about to about When the electron transport region includes a buffer layer, a hole blocking layer, an electron control layer, an electron transport layer, or any combination thereof, the thickness of the buffer layer, the hole blocking layer, or the electron control layer may be independently about to about and the thickness of the electron transport layer can be in the range of about to about For example, the thickness of the buffer layer, the hole blocking layer, or the electron control layer may be independently about to about For example, the thickness of the electron transport layer may be in the range of about to about When the thickness of the buffer layer, the hole blocking layer, the electron control layer, the electron transport layer and / or the electron transport region is within these ranges, satisfactory electron transport characteristics can be obtained without significantly increasing the driving voltage.

[0633] The electron transport region (eg, an electron transport layer in the electron transport region) may further include a metal-containing material in addition to the above-mentioned materials.

[0634] The metal-containing material may include an alkali metal complex, an alkaline earth metal complex, or any combination thereof. The metal ions of the alkali metal complex may be Li ions, Na ions, K ions, Rb ions, or Cs ions, and the metal ions of the alkaline earth metal complex may be Be ions, Mg ions, Ca ions, Sr ions, or Ba ions.

[0635] The ligands coordinated to the metal ion of the alkali metal complex or the metal ion of the alkaline earth metal complex can each independently include hydroxyquinoline, hydroxyisoquinoline, hydroxybenzoquinoline, hydroxyacridine, hydroxyphenanthridine, hydroxyphenyloxazole, hydroxyphenylthiazole, hydroxyphenyloxadiazole, hydroxyphenylthiadiazole, hydroxyphenylpyridine, hydroxyphenylbenzimidazole, hydroxyphenylbenzothiazole, bipyridine, phenanthroline, cyclopentadiene, or any combination thereof.

[0636] For example, the metal-containing material may include a Li complex. The Li complex may include, for example, compound ET-D1 (Liq) or compound ET-D2:

[0637]

[0638] The electron transport region may include an electron injection layer that facilitates injection of electrons from the second electrode 150. The electron injection layer may directly contact the second electrode 150.

[0639] The electron injection layer may have a single-layer structure composed of a single layer (composed of a single material), a single-layer structure composed of a single layer containing different materials, or a multilayer structure including a plurality of layers containing different materials.

[0640] The electron injection layer may include an alkali metal, an alkaline earth metal, a rare earth metal, an alkali metal compound, an alkaline earth metal compound, a rare earth metal compound, an alkali metal complex, an alkaline earth metal complex, a rare earth metal complex, or any combination thereof.

[0641] The alkali metal may include Li, Na, K, Rb, Cs, or any combination thereof. The alkaline earth metal may include Mg, Ca, Sr, Ba, or any combination thereof. The rare earth metal may include Sc, Y, Ce, Tb, Yb, Gd, or any combination thereof.

[0642] The alkali metal compound, alkaline earth metal compound, and rare earth metal compound may be oxides, halides (e.g., fluorides, chlorides, bromides, iodides, etc.), or tellurides of the alkali metal, alkaline earth metal, and rare earth metal, or any combination thereof.

[0643] The alkali metal compound may include: alkali metal oxides, such as Li 2 O, Cs 2 O, K 2 O, etc.; alkali metal halides, such as LiF, NaF, CsF, KF, LiI, NaI, CsI, KI, etc.; or any combination thereof. The alkaline earth metal compound may include alkaline earth metal oxides, such as BaO, SrO, CaO, Ba x Sr 1-x O (where x is a real number satisfying 0 < x < 1) and Ba x Ca 1-x O (where x is a real number satisfying 0 < x < 1), etc. The rare earth metal compound may include YbF 3 、ScF 3 、Sc 2 O 3 、Y 2 O 3 、Ce 2 O 3 、GdF 3 、TbF 3 、YbI 3 、ScI 3 、TbI 3 、 or any combination thereof. In an embodiment, the rare earth metal compound may include lanthanide metal tellurides. Examples of lanthanide metal tellurides may include LaTe, CeTe, PrTe, NdTe, PmTe, SmTe, EuTe, GdTe, TbTe, DyTe, HoTe, ErTe, TmTe, YbTe, LuTe, La 2 Te 3 、Ce 2 Te 3 、Pr 2 Te 3 、Nd2 Te 3 、Pm 2 Te 3 、Sm 2 Te 3 、Eu 2 Te 3 , Gd 2 Te 3 , Tb 2 Te 3 、Dy 2 Te 3 、Ho 2 Te 3 , Er 2 Te 3 、Tm 2 Te 3 , Yb 2 Te 3 He Lu 2 Te 3 wait.

[0644] The alkali metal complex, alkaline earth metal complex and rare earth metal complex may include: an alkali metal ion, an alkaline earth metal ion or a rare earth metal ion; and a ligand bonded to the metal ion (e.g., hydroxyquinoline, hydroxyisoquinoline, hydroxybenzoquinoline, hydroxyacridine, hydroxyphenanthridine, hydroxyphenyloxazole, hydroxyphenylthiazole, hydroxyphenyloxadiazole, hydroxyphenylthiadiazole, hydroxyphenylpyridine, hydroxyphenylbenzimidazole, hydroxyphenylbenzothiazole, bipyridine, phenanthroline, cyclopentadiene or any combination thereof).

[0645] In an embodiment, the electron injection layer may be composed of an alkali metal, an alkaline earth metal, a rare earth metal, an alkali metal-containing compound, an alkaline earth metal-containing compound, a rare earth metal-containing compound, an alkali metal complex, an alkaline earth metal complex, a rare earth metal complex, or any combination thereof as described above. In an embodiment, the electron injection layer may further include an organic material (e.g., a compound represented by Formula 601).

[0646] In an embodiment, the electron injection layer may be composed of an alkali metal compound (e.g., an alkali metal halide); or the electron injection layer may be composed of an alkali metal compound (e.g., an alkali metal halide), and an alkali metal, an alkaline earth metal, a rare earth metal, or any combination thereof. For example, the electron injection layer may be a KI:Yb co-deposition layer, a RbI:Yb co-deposition layer, a LiF:Yb co-deposition layer, and the like.

[0647] When the electron injection layer further includes an organic material, an alkali metal, an alkaline earth metal, a rare earth metal, an alkali metal-containing compound, an alkaline earth metal-containing compound, a rare earth metal-containing compound, an alkali metal complex, an alkaline earth metal complex, a rare earth metal complex or any combination thereof may be uniformly or non-uniformly dispersed in a matrix including the organic material.

[0648] The thickness of the electron injection layer can be about to about For example, the thickness of the electron injection layer may be about to about When the thickness of the electron injection layer is within any one of these ranges, satisfactory electron injection characteristics can be obtained without significantly increasing the driving voltage.

[0649] [Second electrode 150]

[0650] The second electrode 150 is disposed on the interlayer 130 having the aforementioned structure. The second electrode 150 may be a cathode as an electron injection electrode. The material used to form the second electrode 150 may be a material having a low work function, such as a metal, an alloy, an electrically conductive compound, or any combination thereof.

[0651] The second electrode 150 may include Li, Ag, Mg, Al, Al-Li, Ca, Mg-In, Mg-Ag, Yb, Ag-Yb, ITO, IZO, or any combination thereof. The second electrode 150 may be a transmissive electrode, a semi-transmissive electrode, or a reflective electrode.

[0652] The second electrode 150 may have a single-layer structure or a multi-layer structure.

[0653] [Capping layer]

[0654] The light-emitting device 10 may include a first capping layer outside the first electrode 110 and / or a second capping layer outside the second electrode 150. For example, the light-emitting device 10 may have a structure in which the first capping layer, the first electrode 110, the interlayer 130, and the second electrode 150 are stacked in the order described, a structure in which the first electrode 110, the interlayer 130, the second electrode 150 and the second capping layer are stacked in the order described, or a structure in which the first capping layer, the first electrode 110, the interlayer 130, the second electrode 150 and the second capping layer are stacked in the order described.

[0655] Light generated in the emission layer in the interlayer 130 of the light-emitting device 10 can be extracted toward the outside through the first electrode 110, which can be a semi-transmissive electrode or a transmissive electrode, and through the first capping layer. Light generated in the emission layer in the interlayer 130 of the light-emitting device 10 can be extracted toward the outside through the second electrode 150, which can be a semi-transmissive electrode or a transmissive electrode, and through the second capping layer.

[0656] The first capping layer and the second capping layer can each increase the external emission efficiency according to the principle of constructive interference. Accordingly, the light extraction efficiency of the light emitting device 10 is increased, so that the light emitting efficiency of the light emitting device 10 can be improved.

[0657] The first capping layer and the second capping layer may each include a material having a refractive index greater than or equal to about 1.6 (with respect to a wavelength of about 589 nm).

[0658] The first capping layer and the second capping layer may each independently be an organic capping layer including an organic material, an inorganic capping layer including an inorganic material, or an organic-inorganic composite capping layer including an organic material and an inorganic material.

[0659] At least one of the first capping layer and the second capping layer may each independently include a carbocyclic compound, a heterocyclic compound, an amine-containing compound, a porphyrin derivative, a phthalocyanine derivative, a naphthalocyanine derivative, an alkali metal complex, an alkaline earth metal complex, or any combination thereof. The carbocyclic compound, the heterocyclic compound, and the amine-containing compound may be optionally substituted with a substituent including O, N, S, Se, Si, F, Cl, Br, I, or any combination thereof.

[0660] In an embodiment, at least one of the first capping layer and the second capping layer may each independently include an amine-containing compound.

[0661] In an embodiment, at least one of the first capping layer and the second capping layer may each independently include the compound represented by Formula 201, the compound represented by Formula 202, or any combination thereof.

[0662] In an embodiment, at least one of the first capping layer and the second capping layer may each independently include one of compounds HT28 to HT33, one of compounds CP1 to CP6, β-NPB, or any combination thereof:

[0663]

[0664]

[0665] [membrane]

[0666] The amine compound represented by Formula 1 may be included in various films. Accordingly, another embodiment provides a film that may include the amine compound represented by Formula 1. The film may be, for example, an optical member (or light control device) (e.g., a color filter, a color conversion member, a capping layer, a light extraction efficiency enhancement layer, a selective light absorption layer, a polarization layer, or a quantum dot layer, etc.), a light blocking member (e.g., a light reflecting layer or a light absorbing layer, etc.), or a protective member (e.g., an insulating layer or a dielectric layer, etc.).

[0667] [Electronic equipment]

[0668] The light emitting device may be included in various electronic devices. In an embodiment, the electronic device including the light emitting device may be a light emitting device or an authentication device, etc.

[0669] In addition to the light-emitting device, the electronic device (e.g., light-emitting device) may further include: a color filter, a color conversion layer, or a color filter and a color conversion layer. The color filter and / or the color conversion layer may be arranged in at least one direction of travel of the light emitted from the light-emitting device. In an embodiment, the light emitted from the light-emitting device may be blue light, green light, or white light. The light-emitting device may be the same as described herein. In an embodiment, the color conversion layer may include quantum dots.

[0670] The electronic device may include a first substrate. The first substrate may include a plurality of sub-pixels, the color filter may include a plurality of color filter regions respectively corresponding to the plurality of sub-pixels, and the color conversion layer may include a plurality of color conversion regions respectively corresponding to the plurality of sub-pixels.

[0671] A pixel defining layer may be disposed between the plurality of sub-pixels to define each sub-pixel.

[0672] The color filter may further include a plurality of color filter regions and a plurality of light shielding patterns arranged between the plurality of color filter regions, and the color conversion layer may further include a plurality of color conversion regions and a plurality of light shielding patterns arranged between the plurality of color conversion regions.

[0673] The color filter region (or color conversion region) may include a first region emitting a first color light, a second region emitting a second color light, and / or a third region emitting a third color light, wherein the first color light, the second color light, and / or the third color light may have different maximum emission wavelengths from each other. For example, the first color light may be red light, the second color light may be green light, and the third color light may be blue light. For example, the color filter region (or color conversion region) may include quantum dots. For example, the first region may include red quantum dots, the second region may include green quantum dots, and the third region may not include quantum dots. The quantum dots may be quantum dots as described herein. The first region, the second region, and / or the third region may each further include a scatterer.

[0674] In an embodiment, the light emitting device may emit a first light, the first region may absorb the first light to emit a first first color light, the second region may absorb the first light to emit a second first color light, and the third region may absorb the first light to emit a third first color light. In this regard, the first first color light, the second first color light, and the third first color light may have different maximum emission wavelengths from each other. For example, the first light may be blue light, the first first color light may be red light, the second first color light may be green light, and the third first color light may be blue light.

[0675] In addition to the light emitting device described above, the electronic device may further include a thin film transistor. The thin film transistor may include a source electrode, a drain electrode and an active layer, wherein any one of the source electrode and the drain electrode may be electrically connected to any one of the first electrode and the second electrode of the light emitting device.

[0676] The thin film transistor may further include a gate electrode, a gate insulating film, and the like.

[0677] The active layer may include crystalline silicon, amorphous silicon, an organic semiconductor, an oxide semiconductor, or the like.

[0678] The electronic device may further include a sealing portion for sealing the light emitting device. The sealing portion may be arranged between the color filter and / or the color conversion layer and the light emitting device. The sealing portion may allow light from the light emitting device to be extracted to the outside, and may simultaneously prevent ambient air and moisture from penetrating into the light emitting device. The sealing portion may be a sealing substrate including a transparent glass substrate or a plastic substrate. The sealing portion may be a thin film encapsulation layer including at least one of an organic layer and an inorganic layer. When the sealing portion is a thin film encapsulation layer, the electronic device may be flexible.

[0679] Depending on the purpose of the electronic device, in addition to the color filter and / or the color conversion layer, various functional layers may be further included on the sealing portion. Examples of the functional layer may include a touch screen layer and a polarization layer, etc. The touch screen layer may be a pressure-sensitive touch screen layer, a capacitive touch screen layer, or an infrared touch screen layer. The authentication device may be, for example, a biometric authentication device that authenticates an individual by using biometric information of a living body (e.g., a fingertip, a pupil, etc.).

[0680] In addition to the light emitting device as described above, the authentication device may further include a biometric information collector.

[0681] The electronic device can be applied to various displays, light sources, lighting devices, personal computers (e.g., mobile personal computers), mobile phones, digital cameras, electronic notebooks, electronic dictionaries, electronic game consoles, medical tools (e.g., electronic thermometers, blood pressure monitors, blood glucose meters, pulse measuring devices, pulse wave measuring devices, electrocardiogram displays, ultrasonic diagnostic devices, or endoscope displays), fish finders, various measuring tools, instruments (e.g., instruments for vehicles, aircraft, and ships), projectors, and the like.

[0682] [Electronic devices]

[0683] The light emitting device may be included in various electronic devices.

[0684] In an embodiment, the electronic device including the light emitting device may be a flat panel display, a curved display, a computer monitor, a medical monitor, a television (TV), a billboard, an indoor light, an outdoor light, a signal light, a head-up display, a fully transparent display, a partially transparent display, a flexible display, a rollable display, a foldable display, a retractable display, a laser printer, a telephone, a portable telephone, a tablet personal computer, a tablet mobile computer, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a video camera, a viewfinder, a microdisplay, a three-dimensional (3D) display, a virtual reality display, an augmented reality display, a vehicle, a video wall with multiple displays stitched together, a theater screen, a stadium screen, a light therapy device, or a sign.

[0685] Since the light emitting device has excellent effects in terms of light emitting efficiency and long lifespan, an electronic device including the light emitting device may have characteristics such as high brightness, high resolution, and low power consumption.

[0686] [ Figure 2 and Figure 3 Description]

[0687] Figure 2 is a schematic cross-sectional view of an electronic device according to an embodiment.

[0688] Figure 2 The electronic device (eg, a light emitting device) includes a substrate 100, a thin film transistor (TFT), a light emitting device, and a packaging portion 300 that seals the light emitting device.

[0689] The substrate 100 may be a flexible substrate, a glass substrate, or a metal substrate. The buffer layer 210 may be disposed on the substrate 100. The buffer layer 210 may prevent penetration of impurities through the substrate 100 and may provide a flat surface on the substrate 100.

[0690] The TFT may be disposed on the buffer layer 210. The TFT may include an active layer 220, a gate electrode 240, a source electrode 260, and a drain electrode 270.

[0691] The active layer 220 may include an inorganic semiconductor such as silicon or polysilicon, an organic semiconductor, or an oxide semiconductor, and may include a source region, a drain region, and a channel region.

[0692] A gate insulating film 230 for insulating the active layer 220 from the gate electrode 240 may be disposed on the active layer 220 , and the gate electrode 240 may be disposed on the gate insulating film 230 .

[0693] The interlayer insulating film 250 may be disposed on the gate electrode 240. The interlayer insulating film 250 may be disposed between the gate electrode 240 and the source electrode 260 to insulate the gate electrode 240 from the source electrode 260 and between the gate electrode 240 and the drain electrode 270 to insulate the gate electrode 240 from the drain electrode 270.

[0694] Source electrode 260 and drain electrode 270 may be disposed on interlayer insulating film 250. Interlayer insulating film 250 and gate insulating film 230 may be formed to expose source and drain regions of active layer 220, and source electrode 260 and drain electrode 270 may contact exposed portions of the source and drain regions of active layer 220, respectively.

[0695] The TFT may be electrically connected to the light emitting device to drive the light emitting device, and may be covered and protected by the passivation layer 280. The passivation layer 280 may include an inorganic insulating film, an organic insulating film, or any combination thereof. The light emitting device may be provided on the passivation layer 280. The light emitting device may include a first electrode 110, an interlayer 130, and a second electrode 150.

[0696] The first electrode 110 may be disposed on the passivation layer 280. The passivation layer 280 may not completely cover the drain electrode 270 and may expose a portion of the drain electrode 270. The first electrode 110 may be electrically connected to the exposed portion of the drain electrode 270.

[0697] A pixel defining layer 290 including an insulating material may be disposed on the first electrode 110. The pixel defining layer 290 may expose a selected region of the first electrode 110, and the interlayer 130 may be formed in the exposed region of the first electrode 110. The pixel defining layer 290 may be a polyimide-based organic film or a polyacrylic organic film. Figure 2 Although not shown in the figure, at least some layers of the interlayer 130 may extend beyond the upper portion of the pixel defining layer 290 to be provided in the form of a common layer.

[0698] The second electrode 150 may be disposed on the interlayer 130, and a second capping layer 170 may be further included on the second electrode 150. The second capping layer 170 may be formed to cover the second electrode 150.

[0699] The encapsulation part 300 may be disposed on the second capping layer 170. The encapsulation part 300 may be disposed on the light emitting device to protect the light emitting device from moisture and / or oxygen. The encapsulation part 300 may include an inorganic film including silicon nitride (SiN x ), silicon oxide (SiO x), indium tin oxide, indium zinc oxide or any combination thereof; an organic film comprising polyethylene terephthalate, polyethylene naphthalate, polycarbonate, polyimide, polyvinyl sulfonate, polyoxymethylene, polyaromatic ester, hexamethyldisiloxane, an acrylic resin (e.g., polymethyl methacrylate or polyacrylic acid, etc.), an epoxy resin (e.g., aliphatic glycidyl ether (AGE), etc.) or any combination thereof; or any combination of an inorganic film and an organic film.

[0700] Figure 3 is a schematic cross-sectional view of an electronic device according to another embodiment.

[0701] Figure 3 An electronic device (eg, a light emitting device) may be used with Figure 2 The electronic device of the present invention is different from the electronic device of the present invention, and the difference is at least that the packaging part 300 further includes a light shielding pattern 500 and a functional area 400. The functional area 400 can be a color filter area, a color conversion area, or a combination of a color filter area and a color conversion area. In an embodiment, Figure 3 The light-emitting device included in the electronic device may be a series light-emitting device.

[0702] [ Figure 4 Description]

[0703] Figure 4 is a schematic perspective view of an electronic device 1 including a light emitting device according to an embodiment.

[0704] The electronic device 1 that can be used as a device or apparatus for displaying moving images or still images can be not only a portable electronic device (such as a mobile phone, a smart phone, a tablet personal computer (PC), a mobile communication terminal, an electronic notebook, an electronic book, a portable multimedia player (PMP), a navigation device, or an ultra mobile PC (UMPC)), but also various products (such as a television (TV), a laptop computer, a monitor, a billboard, or an Internet of Things (IOT) device). The electronic device 1 can be such a product as described above or a part thereof.

[0705] The electronic device 1 may be a wearable device such as a smart watch, a watch phone, a glasses-type display, or a head-mounted display (HMD), or a part of a wearable device. However, the embodiment is not limited thereto.

[0706] For example, the electronic device 1 may be a dashboard of a vehicle, a center console of a vehicle, a central information display arranged on the dashboard of a vehicle, an interior rearview mirror display replacing a side mirror of a vehicle, an entertainment display for a rear seat of a vehicle, a display arranged on the backrest of a front seat, a head-up display (HUD) mounted in front of the vehicle or projected on the front windshield, or a computer-generated holographic augmented reality head-up display (CGH AR HUD). For convenience of explanation, Figure 4 An embodiment is explained in which the electronic device 1 is a smart phone.

[0707] The electronic device 1 may include a display area DA and a non-display area NDA outside the display area DA. The display device may implement an image through a two-dimensional pixel array arranged in the display area DA.

[0708] The non-display area NDA is an area where an image is not displayed, and may surround the display area DA. A driver for providing an electrical signal or power to a display element arranged in the display area DA may be arranged in the non-display area NDA. A pad to which an electronic element or a printed circuit substrate may be electrically connected may be arranged in the non-display area NDA.

[0709] In the electronic device 1, the length in the x-axis direction and the length in the y-axis direction may be different from each other. Figure 4 As shown in , the length in the x-axis direction may be shorter than the length in the y-axis direction. In an embodiment, the length in the x-axis direction may be the same as the length in the y-axis direction. In another embodiment, the length in the x-axis direction may be longer than the length in the y-axis direction.

[0710] [ Figure 5 and FIG. 6A to FIG. 6C Description]

[0711] Figure 5 is a schematic perspective view of the exterior of a vehicle 1000 as an electronic device including a light emitting device according to an embodiment.

[0712] FIG. 6A to FIG. 6C Each is a schematic diagram of the interior of vehicle 1000 according to an embodiment.

[0713] refer to Figure 5 , Fig. 6A , Figure 6B and Figure 6C The vehicle 1000 may refer to various devices for moving an object to be transported (such as a person, object, or animal) from a starting point to a destination point. Examples of the vehicle 1000 may include a vehicle traveling on a road or track, a ship moving on an ocean or river, and an airplane flying in the air using air action.

[0714] The vehicle 1000 may travel on a road or a track. The vehicle 1000 may move in a given direction according to the rotation of at least one wheel. Examples of the vehicle 1000 may include a three-wheeled or four-wheeled vehicle, an engineering machine, a two-wheeled vehicle, a prime mover, a bicycle, and a train traveling on a track.

[0715] The vehicle 1000 may include a body having an interior and an exterior, and a chassis as a part other than the body in which mechanical equipment required for driving is installed. The exterior of the body may include a front panel, a hood, a roof panel, a rear panel, a trunk, and pillars provided at the boundaries between doors, etc. The chassis of the vehicle 1000 may include a power generation device, a power transmission device, a drive device, a steering device, a brake device, a suspension device, a transmission device, a fuel device, and front and rear left and right wheels, etc.

[0716] The vehicle 1000 may include side window glasses 1100 , a front window glass 1200 , side rearview mirrors 1300 , an instrument panel 1400 , a center console 1500 , a passenger seat instrument panel 1600 , and a display device 2 .

[0717] The side window glass 1100 and the front window glass 1200 may be divided by pillars disposed between the side window glass 1100 and the front window glass 1200 .

[0718] The side window glass 1100 may be installed on the side of the vehicle 1000. In an embodiment, the side window glass 1100 may be installed in a door of the vehicle 1000. A plurality of side window glasses 1100 may be provided and may face each other. In an embodiment, the side window glass 1100 may include a first side window glass 1110 and a second side window glass 1120. In an embodiment, the first side window glass 1110 may be arranged adjacent to the instrument panel 1400, and the second side window glass 1120 may be arranged adjacent to the passenger seat instrument panel 1600.

[0719] In an embodiment, the side window glass 1100 may be spaced apart from each other in the x-axis direction or in a direction opposite to the x-axis direction. For example, the first side window glass 1110 and the second side window glass 1120 may be spaced apart from each other in the x-axis direction or in a direction opposite to the x-axis direction. The imaginary straight line L connecting the side window glass 1100 may extend in the x-axis direction or in a direction opposite to the x-axis direction. For example, the imaginary straight line L connecting the first side window glass 1110 and the second side window glass 1120 may extend in the x-axis direction or in a direction opposite to the x-axis direction.

[0720] The front window glass 1200 may be mounted on the front of the vehicle 1000. The front window glass 1200 may be between the side window glasses 1100 facing each other.

[0721] The side rearview mirror 1300 may provide a rear view of the vehicle 1000. The side rearview mirror 1300 may be mounted on the exterior of the vehicle body. In an embodiment, a plurality of side rearview mirrors 1300 may be provided. One of the plurality of side rearview mirrors 1300 may be arranged on the outer side of the first side window glass 1110. Another of the plurality of side rearview mirrors 1300 may be arranged on the outer side of the second side window glass 1120.

[0722] Instrument panel 1400 may be arranged in front of the steering wheel. Instrument panel 1400 may include a tachometer, a speedometer, a coolant temperature gauge, a fuel gauge, a turn signal indicator, a high beam indicator, a warning light, a seat belt warning light, an odometer, a driving record system, an automatic shift selector indicator light, a door open warning light, an engine oil warning light, and / or a low fuel warning light.

[0723] The center console 1500 may include a control panel on which buttons for adjusting an audio device, an air conditioning device, and a seat heater are provided. The center console 1500 may be disposed at one side of the instrument panel 1400 .

[0724] The passenger seat instrument panel 1600 may be spaced apart from the instrument panel 1400, with the center console 1500 disposed therebetween. In an embodiment, the instrument panel 1400 may be disposed to correspond to a driver's seat (not shown), and the passenger seat instrument panel 1600 may be disposed to correspond to a passenger seat (not shown). In an embodiment, the instrument panel 1400 may be adjacent to the first side window glass 1110, and the passenger seat instrument panel 1600 may be adjacent to the second side window glass 1120.

[0725] In an embodiment, the display device 2 may include a display panel 3, and the display panel 3 may display an image. The display device 2 may be arranged inside the vehicle 1000. In an embodiment, the display device 2 may be between side window glasses 1100 facing each other. The display device 2 may be arranged in at least one of the instrument panel 1400, the center console 1500, and the passenger seat instrument panel 1600.

[0726] The display device 2 may include an organic light-emitting display device, an inorganic electroluminescent (EL) display device, or a quantum dot display device, etc. Hereinafter, as the display device 2 according to an embodiment of the present disclosure, an organic light-emitting display device including a light-emitting device according to the present disclosure will be described as an example, but various types of display devices as described herein may be used as embodiments of the present disclosure.

[0727] refer to Fig. 6A , the display device 2 may be arranged in the center console 1500. In an embodiment, the display device 2 may display navigation information. In an embodiment, the display device 2 may display information about audio settings, video settings, or vehicle settings.

[0728] refer to Figure 6B , the display device 2 may be arranged in the instrument panel 1400. When the display device 2 is arranged in the instrument panel 1400, the instrument panel 1400 may display driving information and the like through the display device 2. For example, the instrument panel 1400 may digitally implement driving information. The instrument panel 1400 may digitally display vehicle information and driving information as images. For example, the pointer and instrument of the tachometer and various warning lights or icons may be displayed through digital signals.

[0729] refer to Figure 6C , the display device 2 may be arranged in the passenger seat instrument panel 1600. The display device 2 may be embedded in the passenger seat instrument panel 1600 or arranged on the passenger seat instrument panel 1600. In an embodiment, the display device 2 arranged on the passenger seat instrument panel 1600 may display images related to the information displayed on the instrument panel 1400 and / or the information displayed on the center console 1500. In an embodiment, the display device 2 arranged on the passenger seat instrument panel 1600 may display information different from the information displayed on the instrument panel 1400 and / or different from the information displayed on the center console 1500.

[0730] [Manufacturing method]

[0731] The layer constituting the hole transport region, the emission layer and the layer constituting the electron transport region can be formed in a selected region by using various methods such as vacuum deposition, spin coating, casting, Langmuir-Blodgett (LB) deposition, inkjet printing, laser printing and laser induced thermal imaging, etc.

[0732] When the layer constituting the hole transport region, the emission layer, and the layer constituting the electron transport region are formed by vacuum deposition, the deposition may be performed at a deposition temperature in a range of about 100° C. to about 500° C., at a temperature ... -8 About 10 -3 Torr in the vacuum range, and at about to about The deposition rate is carried out at a range of , which depends on the material to be included in the layer to be formed and the structure of the layer to be formed.

[0733] [Definition of terms]

[0734] As used herein, the term "C 3 -C 60 The term "carbocyclic group" may be a cyclic group consisting of a carbon atom as the only ring-forming atom and having 3 to 60 carbon atoms, and as used herein, 1 -C 60 The "heterocyclic group" may be a cyclic group having 1 to 60 carbon atoms and further having at least one hetero atom as a ring-constituting atom in addition to the carbon atoms. 3 -C 60Carbocyclic and C 1 -C 60 The heterocyclic groups may each be a monocyclic group consisting of one ring or a polycyclic group in which two or more rings are fused to each other. 1 -C 60 The heterocyclic group can have 3 to 61 ring-forming atoms.

[0735] As used herein, the term "cyclic group" may be C 3 -C 60 Carbocyclic or C 1 -C 60 Heterocyclic group.

[0736] As used herein, the term "π-electron-rich C 3 -C 60 The "cyclic group" may have 3 to 60 carbon atoms and may not include a cyclic group having *-N=*' as a ring-forming part, and the term "π-electron-deficient nitrogen-containing C 1 -C 60 The "heterocyclic group" may be a heterocyclic group having 1 to 60 carbon atoms and may include *-N=*' as a ring-forming portion.

[0737] In an embodiment, C 3 -C 60 The carbocyclic group may be a T1 group, or a group in which two or more T1 groups are fused to each other (e.g., a cyclopentadienyl group, an adamantyl group, a norbornyl group, a phenyl group, a pentalenyl group, a naphthyl group, an azulenyl group, an indacenyl group, an acenaphthenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylene group, a pyrenyl group, a 1,2-triphenylene group, a peryl group, a pentaphenanthrenyl group, a heptalenyl group, a tetracenyl group, a phenanthrenyl group, a hexacenyl group, a pentacene group, a rubidenyl group, a coronet group, an ovalenyl group, an indenyl group, a fluorenyl group, a spirobifluorenyl group, a benzofluorenyl group, an indenophenanthrenyl group, or an indenoanthryl group),

[0738] C 1 -C 60The heterocyclic group may be a T2 group, a group in which two or more T2 groups are fused to each other, or a group in which at least one T2 group and at least one T1 group are fused to each other (e.g., a pyrrolyl group, a thienyl group, a furyl group, an indolyl group, a benzindolyl group, a naphthoindolyl group, an isoindolyl group, a benzisoindolyl group, a naphthoisoindolyl group, a benzothioyl group, a benzothiophenyl group, a benzofuranyl group, a carbazolyl group, a dibenzothioyl group, a dibenzothiophenyl group, a dibenzofuranyl group, an indenocarbazolyl group, an indolcarbazolyl group, a benzofuranocarbazolyl group, a benzothiophenylcarbazolyl group, a benzothiophenylcarbazolyl group, a benzothiophenylcarbazolyl group, a benzothiophenylcarbazolyl group, a benzothiophenylcarbazolyl group, a benzoindolcarbazolyl group, a benzocarbazolyl group, a benzonaphthofuranoyl group, a benzonaphthothiophenyl group, a benzonaphthothioyl group, a benzofuranodibenzofuranodibenzothiophenyl group, a ... phenyl, benzothiophene and dibenzothiophene, pyrazolyl, imidazolyl, triazolyl, oxazolyl, isoxazolyl, oxadiazolyl, thiazolyl, isothiazolyl, thiadiazolyl, benzopyrazolyl, benzimidazolyl, benzoxazolyl, benzisoxazolyl, benzothiazolyl, benzisothiazolyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolyl, isoquinolyl, benzoquinolyl quinolinyl, benzoisoquinolinyl, quinoxalinyl, benzoquinoxalinyl, quinazolinyl, benzoquinazolinyl, phenanthrolinyl, cinnolinyl, phthalazinyl, naphthyridinyl, imidazopyridinyl, imidazopyrimidinyl, imidazotriazine, imidazopyrazinyl, imidazopyridazinyl, azacarbazolyl, azafluorenyl, azadibenzothiazolyl, azadibenzothiopheneyl, azadibenzofuranyl, etc.),

[0739] Pi-electron-rich C 3 -C 60 The cyclic group may be a T1 group, a group in which two or more T1 groups are fused to each other, a T3 group, a group in which two or more T3 groups are fused to each other, or a group in which at least one T3 group and at least one T1 group are fused to each other (e.g., C 3 -C 60 carbocyclic group, 1H-pyrrolyl, thiolyl, borocyclopentadienyl, 2H-pyrrolyl, 3H-pyrrolyl, thienyl, furyl, indolyl, benzindolyl, naphthoindolyl, isoindolyl, benzisoindolyl, naphthoisoindolyl, benzothiolyl, benzothiophenyl, benzofuranyl, carbazolyl, dibenzothiolyl, dibenzothiophenyl, dibenzofuranyl, indenocarbazolyl, indolecarbazolyl, benzofuranocarbazolyl, benzothiophenylcarbazolyl, benzothiophenylcarbazolyl, benzothiophenylcarbazolyl, benzothiophenylcarbazolyl, benzoindolcarbazolyl, benzocarbazolyl, benzonaphthofuranyl, benzonaphthothienyl, benzonaphthothiolyl, benzofuranodibenzofuranyl, benzofuranodibenzothiophenyl or benzothiophenyldibenzothiophenyl, etc.),

[0740] π-electron-deficient nitrogen-containing C 1 -C 60The heterocyclic group may be a T4 group, a group in which two or more T4 groups are fused to each other, a group in which at least one T4 group and at least one T1 group are fused to each other, a group in which at least one T4 group and at least one T3 group are fused to each other, or a group in which at least one T4 group, at least one T1 group and at least one T3 group are fused to each other (e.g., pyrazolyl, imidazolyl, triazolyl, oxazolyl, isoxazolyl, oxadiazolyl, thiazolyl, isothiazolyl, thiadiazolyl, benzopyrazolyl, benzimidazolyl, benzoxazolyl, , benzisoxazolyl, benzothiazolyl, benzisothiazolyl, pyridinyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolyl, isoquinolyl, benzoquinolyl, benzisoquinolyl, quinoxalinyl, benzoquinoxalinyl, quinazolinyl, benzoquinazolinyl, phenanthrolinyl, cinnolinyl, phthalazinyl, naphthyridinyl, imidazopyridinyl, imidazopyrimidinyl, imidazotriazinyl, imidazopyrazinyl, imidazopyridazinyl, azacarbazolyl, azafluorenyl, azadibenzothioyl, azadibenzothiophenyl, azadibenzofuranyl, etc.), wherein

[0741] The T1 group can be cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane, cyclooctane, cyclobutenyl, cyclopentenyl, cyclopentadienyl, cyclohexenyl, cyclohexadienyl, cycloheptenyl, adamantyl, norbornane (or bicyclo[2.2.1]heptane) group, norbornyl, bicyclo[1.1.1]pentane, bicyclo[2.1.1]hexane, bicyclo[2.2.2]octane or phenyl,

[0742] The T2 group can be furanyl, thienyl, 1H-pyrrolyl, thiolyl, borocyclopentyl, 2H-pyrrolyl, 3H-pyrrolyl, imidazolyl, pyrazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, oxadiazolyl, thiazolyl, isothiazolyl, thiadiazolyl, azathiarolyl, azaborolyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, tetraazinyl, pyrrolidinyl, imidazolidinyl, dihydropyrrolyl, piperidinyl, tetrahydropyridinyl, dihydropyridinyl, hexahydropyrimidinyl, tetrahydropyrimidinyl, dihydropyrimidinyl, piperazinyl, tetrahydropyrazinyl, dihydropyrazinyl, tetrahydropyridazinyl or dihydropyridazinyl,

[0743] The T3 group may be a furyl group, a thienyl group, a 1H-pyrrolyl group, a thiole group or a borocyclopentadienyl group, and

[0744] The T4 group can be 2H-pyrrolyl, 3H-pyrrolyl, imidazolyl, pyrazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, oxadiazolyl, thiazolyl, isothiazolyl, thiadiazolyl, azathioyl, azaborolyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl or tetrazinyl.

[0745] As used herein, the terms "cyclic group", "C3 -C 60 Carbocyclic group, "C 1 -C 60 Heterocyclic group", "π-electron-rich C 3 -C 60 Cyclic groups" and "π-electron-deficient nitrogen-containing C 1 -C 60 The term "heterocyclic group" refers to a monovalent group or a polyvalent group (e.g., a divalent group, a trivalent group, a tetravalent group, etc.) fused (e.g., bonded together) to a cyclic group according to the structure of the formula using the corresponding term. For example, "phenyl" may be benzo, phenyl or phenylene, etc., which can be easily understood by a person of ordinary skill in the art based on the structure of the formula including "phenyl".

[0746] Unit Price C 3 -C 60 Carbocyclic groups and monovalent C 1 -C 60 Examples of the heterocyclic group may include C 3 -C 10 Cycloalkyl, C 1 -C 10 Heterocycloalkyl, C 3 -C 10 Cycloalkenyl, C 1 -C 10 Heterocycloalkenyl, C 6 -C 60 Aryl, C 1 -C 60 heteroaryl, monovalent non-aromatic fused polycyclic group and monovalent non-aromatic fused heteropolycyclic group. 3 -C 60 Carbocyclic groups and divalent C 1 -C 60 Examples of the heterocyclic group may include C 3 -C 10 Cycloalkylene, C 1 -C 10 Heterocycloalkylene, C 3 -C 10 Cycloalkenylene, C 1 -C 10 Heterocycloalkenylene, C 6 -C 60 Arylene, C 1 -C 60 a heteroarylene group, a divalent non-aromatic fused polycyclic group, and a divalent non-aromatic fused heteropolycyclic group.

[0747] As used herein, the term "C 1 -C 60The “alkyl group” may be a linear or branched aliphatic hydrocarbon monovalent group having 1 to 60 carbon atoms, and examples thereof may include methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, n-pentyl, tert-pentyl, neopentyl, isopentyl, sec-pentyl, 3-pentyl, sec-isopentyl, n-hexyl, isohexyl, sec-hexyl, tert-hexyl, n-heptyl, isoheptyl, sec-heptyl, tert-heptyl, n-octyl, isooctyl, sec-octyl, tert-octyl, n-nonyl, isononyl, sec-nonyl, tert-nonyl, n-decyl, isodecyl, sec-decyl, and tert-decyl. As used herein, the term “C 1 -C 60 The "alkylene" may be 1 -C 60 An alkyl group is a divalent group having the same structure.

[0748] As used herein, the term "C 2 -C 60 The "alkenyl" may be 2 -C 60 The alkyl group is a monovalent hydrocarbon group having at least one carbon-carbon double bond in the middle or at the end thereof, and examples thereof may include vinyl, propenyl, butenyl, and the like. As used herein, the term “C 2 -C 60 "Alkenylene" can be 2 -C 60 Alkenyl groups have divalent groups of the same structure.

[0749] As used herein, the term "C 2 -C 60 "Alkynyl" may be 2 -C 60 The alkyl group is a monovalent hydrocarbon group having at least one carbon-carbon triple bond in the middle or at the end thereof, and examples thereof include ethynyl and propynyl. 2 -C 60 "Alkyne" can be 2 -C 60 Alkynyl groups are divalent groups with the same structure.

[0750] As used herein, the term "C 1 -C 60 "Alkoxy" may be -O(A 101 )(where A 101 Can be C 1 -C 60 The monovalent group represented by an alkyl group may include a methoxy group, an ethoxy group, an isopropoxy group, and the like.

[0751] As used herein, the term "C 3 -C 10The term "cycloalkyl" may be a monovalent saturated hydrocarbon ring group having 3 to 10 carbon atoms, and examples thereof may include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl (or bicyclo[2.2.1]heptyl), bicyclo[1.1.1]pentyl, bicyclo[2.1.1]hexyl, and bicyclo[2.2.2]octyl, and the like. As used herein, the term "Cycloalkyl" may be a monovalent saturated hydrocarbon ring group having 3 to 10 carbon atoms, and examples thereof may include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, adamantyl, norbornyl (or bicyclo[2.2.1]heptyl), bicyclo[1.1.1]pentyl, bicyclo[2.1.1]hexyl, and bicyclo[2.2 3 -C 10 The cycloalkylene group may be 3 -C 10 The cycloalkyl group has a divalent group of the same structure.

[0752] As used herein, the term "C 1 -C 10 The term "heterocycloalkyl" as used herein may be a monovalent cyclic group having 1 to 10 carbon atoms which further includes at least one heteroatom as a ring-forming atom in addition to carbon atoms, and examples thereof may include 1,2,3,4-oxatriazolidinyl, tetrahydrofuranyl, tetrahydrothienyl, and the like. 1 -C 10 The heterocycloalkylene group may be 1 -C 10 The heterocycloalkyl group has a divalent group of the same structure.

[0753] As used herein, the term "C 3 -C 10 The term "cycloalkenyl" as used herein may be a monovalent cyclic group having 3 to 10 carbon atoms and at least one carbon-carbon double bond in its cyclic structure and having no aromaticity, and examples thereof may include cyclopentenyl, cyclohexenyl, cycloheptenyl, and the like. 3 -C 10 The cycloalkenylene group may be 3 -C 10 The cycloalkenyl group has a divalent group of the same structure.

[0754] As used herein, the term "C 1 -C 10 The "heterocycloalkenyl group" may be a monovalent cyclic group of 1 to 10 carbon atoms which further includes at least one heteroatom as a ring-constituting atom in addition to carbon atoms and has at least one double bond in its ring structure. 1 -C 10 Examples of heterocycloalkenyl groups may include 4,5-dihydro-1,2,3,4-oxatriazolyl, 2,3-dihydrofuranyl, 2,3-dihydrothienyl, and the like. As used herein, the term “C 1 -C 10 The heterocycloalkenylene group may be 1 -C 10 The heterocycloalkenyl group has a divalent group of the same structure.

[0755] As used herein, the term "C 6 -C 60 The term "aryl" may be a monovalent group of a carbocyclic aromatic system having 6 to 60 carbon atoms, and as used herein, the term "C 6 -C 60 The "arylene group" may be a divalent group of a carbocyclic aromatic system having 6 to 60 carbon atoms. 6 -C 60 Examples of aryl groups may include phenyl, pentalenyl, naphthyl, azulenyl, indacenyl, acenaphthenyl, phenanthrenyl, phenanthrenyl, anthracenyl, fluoranthenyl, triphenylene, pyrenyl, 1,2-triphenylenyl, peryl, pentaphenanthrenyl, heptalenyl, tetracenyl, pyrenyl, hexenyl, pentacene, rubenyl, coronenyl, and ovalenyl. 6 -C 60 Aryl and C 6 -C 60 When the arylene groups each include two or more rings, the respective rings may be fused to each other.

[0756] As used herein, the term "C 1 -C 60 The term "heteroaryl" as used herein may be a monovalent group of a heterocyclic aromatic system having 1 to 60 carbon atoms, further including at least one heteroatom as a ring-forming atom in addition to carbon atoms. 1 -C 60 The "heteroarylene group" may be a divalent group of a heterocyclic aromatic system having 1 to 60 carbon atoms, further including at least one heteroatom as a ring-forming atom in addition to carbon atoms. 1 -C 60 Examples of heteroaryl groups may include pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, quinolyl, benzoquinolyl, isoquinolyl, benzoisoquinolyl, quinoxalinyl, benzoquinoxalinyl, quinazolinyl, benzoquinazolinyl, cinnolinyl, phenanthrolinyl, phthalazinyl, and naphthyridinyl. 1 -C 60 Heteroaryl and C 1 -C 60 When the heteroarylene groups each include two or more rings, the respective rings may be fused to each other.

[0757] The term "monovalent non-aromatic fused polycyclic group" as used herein may be a monovalent group (e.g., having 8 to 60 carbon atoms) having two or more rings fused to each other, only carbon atoms as ring-forming atoms, and having no aromaticity in its molecular structure as a whole. Examples of monovalent non-aromatic fused polycyclic groups may include indenyl, fluorenyl, spirobifluorenyl, benzofluorenyl, indenophenanthryl, indenoanthryl, and the like. The term "divalent non-aromatic fused polycyclic group" as used herein may be a divalent group having the same structure as the above-mentioned monovalent non-aromatic fused polycyclic group.

[0758] The term “monovalent non-aromatic fused heteropolycyclic group” as used herein may be a monovalent group (for example, having 1 to 60 carbon atoms) having two or more rings fused to each other, further including at least one heteroatom as a ring-constituting atom in addition to carbon atoms, and having no aromaticity in its molecular structure as a whole. Examples of the monovalent non-aromatic condensed heteropolycyclic group may include pyrrolyl, thienyl, furanyl, indolyl, benzindolyl, naphthoindolyl, isoindolyl, benzisoindolyl, naphthoisoindolyl, benzothioyl, benzothiophenyl, benzofuranyl, carbazolyl, dibenzothioyl, dibenzothiophenyl, dibenzofuranyl, azacarbazolyl, azafluorenyl, azadibenzothioyl, azadibenzothiophenyl, azadibenzofuranyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl The term "divalent non-aromatic condensed heteropolycyclic group" as used herein may be a divalent group having the same structure as the monovalent non-aromatic condensed heteropolycyclic group.

[0759] As used herein, the term "C 6 -C 60 "Aryloxy" may be -O(A 102 )(where A 102 Can be C 6 -C 60 The term "C 6 -C 60 The "arylthio" group may be -S(A 103 )(where A 103 Can be C 6 -C 60A group represented by an aryl group.

[0760] As used herein, the term "C 7 -C 60 The "aralkyl" may be -(A 104 )(A 105 )(where A 104 Can be C 1 -C 54 Alkylene, and A 105 Can be C 6 -C 59 The term "C 2 -C 60 The heteroarylalkyl group may be -(A 106 )(A 107 )(where A 106 Can be C 1 -C 59 Alkylene, and A 107 Can be C 1 -C 59 A group represented by a heteroaryl group.

[0761] In the specification, the group "R 10a " can be:

[0762] Deuterium (-D), -F, -Cl, -Br, -I, hydroxy, cyano or nitro;

[0763] Each unsubstituted or substituted C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl or C 1 -C 60 Alkoxy: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 11 )(Q 12 )(Q 13 )、-N(Q 11 )(Q 12)、-B(Q 11 )(Q 12 )、-C(=O)(Q 11 )、-S(=O) 2 (Q 11 )、-P(=O)(Q 11 )(Q 12 ) or any combination thereof;

[0764] Each unsubstituted or substituted C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 21 )(Q 22 )(Q 23 )、-N(Q 21 )(Q 22 )、-B(Q 21 )(Q 22 )、-C(=O)(Q 21 )、-S(=O) 2 (Q 21 )、-P(=O)(Q 21 )(Q 22 ) or any combination thereof; or

[0765] -Si(Q 31)(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 ) or -P(=O)(Q 31 )(Q 32 ).

[0766] In the specification, group Q 1 To Q 3 , Q 11 To Q 13 , Q 21 To Q 23 and Q 31 To Q 33 can be independently: hydrogen; deuterium; -F; -Cl; -Br; -I; hydroxyl; cyano; nitro; C 1 -C 60 Alkyl; C 2 -C 60 Alkenyl; C 2 -C 60 Alkynyl; C 1 -C 60 alkoxy; or each unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 C substituted by heterocyclic group or any combination thereof 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl.

[0767] The term "heteroatom" as used herein may be any atom other than a carbon atom and a hydrogen atom. Examples of heteroatoms may include O, S, N, P, Si, B, Ge, Se, and any combination thereof.

[0768] The term "first row transition metal" as used herein may include Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, or Zn, etc. The term "second row transition metal" as used herein may include Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, or Cd, etc. The term "third row transition metal" as used herein may include Hf, Ta, W, Re, Os, Ir, Pt, or Au, etc.

[0769] In the specification, "Ph" refers to phenyl, "Me" refers to methyl, "Et" refers to ethyl, and "tert-Bu" or "Bu t ” each refers to a tert-butyl group, and “OMe” refers to a methoxy group.

[0770] As used herein, the term "biphenyl" may be a "phenyl substituted with phenyl". For example, a "biphenyl" may be a phenyl substituted with C 6 -C 60 Aryl substituted phenyl.

[0771] The term "terphenyl" as used herein may be a "phenyl group substituted with a biphenyl group". For example, a "terphenyl group" may be a phenyl group substituted with a C 6 -C 60 Aryl substituted C 6 -C 60 A phenyl group substituted with an aryl group as a substituent.

[0772] Unless otherwise defined, the symbols * and *' as used herein each refer to a bonding site to the adjacent atom in the corresponding formula or moiety.

[0773] In the specification, the terms "x-axis", "y-axis", and "z-axis" are not limited to three axes in an orthogonal coordinate system (e.g., a Cartesian coordinate system), and may be interpreted in a broader sense than the aforementioned axes that are orthogonal to each other. For example, the x-axis, y-axis, and z-axis may describe axes that are orthogonal to each other, or may describe axes in different directions that are not orthogonal to each other.

[0774] Hereinafter, the compound according to the embodiment and the light-emitting device according to the embodiment will be described in detail with reference to the following synthesis examples and examples. The phrase "using B instead of A" used in describing the synthesis examples means using B instead of A in the same molar equivalent.

[0775] [Synthesis example]

[0776] [Synthesis Example 1: Synthesis of Compound 1]

[0777]

[0778] (Synthesis of Compound 1-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (Compound 1-2) (26 mmol, 1.3 equivalents), N,1-diphenylnaphthalene-2-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3 (1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of toluene (Tol.) were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0779] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 14 mmol of compound 1-1 (yield = 70%).

[0780] (Synthesis of Compound 1) Compound 1-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of toluene (Tol.) were added to a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0781] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 8.0 mmol of Compound 1 (yield = 80%).

[0782] [Synthesis Example 2: Synthesis of Compound 2]

[0783]

[0784] (Synthesis of Compound 2) Compound 1-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-4-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0785] After the reaction is completed, the reaction product is washed with ether / H 2O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.8 mmol of Compound 2 (yield = 78%).

[0786] [Synthesis Example 3: Synthesis of Compound 3]

[0787]

[0788] (Synthesis of Compound 3) Compound 1-1 (12 mmol, 1.2 equivalents), 4-cyclohexyl-N-phenylaniline (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0789] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.9 mmol of compound 3 (yield = 79%).

[0790] [Synthesis Example 4: Synthesis of Compound 5]

[0791]

[0792] (Synthesis of Compound 5) Compound 1-1 (12 mmol, 1.2 equivalents), N-phenylnaphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0793] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.5 mmol of compound 5 (yield = 75%).

[0794] [Synthesis Example 5: Synthesis of Compound 7]

[0795]

[0796] (Synthesis of Compound 7) Compound 1-1 (12 mmol, 1.2 equivalents), N-phenyldibenzo[b,d]furan-1-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0797] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.0 mmol of compound 7 (yield = 70%).

[0798] [Synthesis Example 6: Synthesis of Compound 9]

[0799]

[0800] (Synthesis of Compound 9) Compound 1-1 (12 mmol, 1.2 equivalents), N-(4-cyclohexylphenyl)naphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0801] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.2 mmol of compound 9 (yield = 72%).

[0802] [Synthesis Example 7: Synthesis of Compound 12]

[0803]

[0804] (Synthesis of Compound 12) Compound 1-1 (12 mmol, 1.2 equivalents), N,1-diphenylnaphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0805] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.1 mmol of compound 12 (yield = 71%).

[0806] [Synthesis Example 8: Synthesis of Compound 16]

[0807]

[0808] (Synthesis of Compound 16) Compound 1-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0809] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.0 mmol of compound 16 (yield = 70%).

[0810] [Synthesis Example 9: Synthesis of Compound 33]

[0811]

[0812] (Synthesis of Compound 33-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (26 mmol, 1.3 equivalents), N-(4-cyclohexylphenyl)-1-phenylnaphthalene-2-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3 (1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0813] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 12 mmol of compound 33-1 (yield = 60%).

[0814] (Synthesis of Compound 33) Compound 33-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0815] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.8 mmol of compound 33 (yield = 78%).

[0816] [Synthesis Example 10: Synthesis of Compound 37]

[0817]

[0818] (Synthesis of Compound 37) Compound 33-1 (12 mmol, 1.2 equivalents), N-phenylnaphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0819] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.6 mmol of compound 37 (yield = 76%).

[0820] [Synthesis Example 11: Synthesis of Compound 41]

[0821]

[0822] (Synthesis of Compound 41-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (26 mmol, 1.3 equivalents), N,3-diphenylnaphthalene-2-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3(1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0823] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 14 mmol of compound 41-1 (yield = 70%).

[0824] (Synthesis of Compound 41) Compound 41-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0825] The reaction product was washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 8.2 mmol of compound 41 (yield = 82%).

[0826] [Synthesis Example 12: Synthesis of Compound 42]

[0827]

[0828] (Synthesis of Compound 42) Compound 41-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-4-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0829] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.5 mmol of compound 42 (yield = 75%).

[0830] [Synthesis Example 13: Synthesis of Compound 43]

[0831]

[0832] (Synthesis of Compound 43) Compound 41-1 (12 mmol, 1.2 equivalents), 4-cyclohexyl-N-phenylaniline (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0833] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.6 mmol of compound 43 (yield = 76%).

[0834] [Synthesis Example 14: Synthesis of Compound 45]

[0835]

[0836] (Synthesis of Compound 45) Compound 41-1 (12 mmol, 1.2 equivalents), N-phenylnaphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0837] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.0 mmol of compound 45 (yield = 70%).

[0838] [Synthesis Example 15: Synthesis of Compound 47]

[0839]

[0840] (Synthesis of Compound 47) Compound 41-1 (12 mmol, 1.2 equivalents), N-phenyldibenzo[b,d]furan-1-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0841] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.0 mmol of compound 47 (yield = 70%).

[0842] [Synthesis Example 16: Synthesis of Compound 49]

[0843]

[0844] (Synthesis of Compound 49) Compound 41-1 (12 mmol, 1.2 equivalents), N-(4-cyclohexylphenyl)naphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0845] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 6.9 mmol of compound 49 (yield = 69%).

[0846] [Synthesis Example 17: Synthesis of Compound 52]

[0847]

[0848] (Synthesis of Compound 52) Compound 41-1 (12 mmol, 1.2 equivalents), N,1-diphenylnaphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0849] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 6.8 mmol of compound 52 (yield = 68%).

[0850] [Synthesis Example 18: Synthesis of Compound 56]

[0851]

[0852] (Synthesis of Compound 56) Compound 41-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0853] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 6.9 mmol of compound 56 (yield = 69%).

[0854] [Synthesis Example 19: Synthesis of Compound 73]

[0855]

[0856] (Synthesis of Compound 73-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (26 mmol, 1.3 equivalents), N-(4-cyclohexylphenyl)-3-phenylnaphthalene-2-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3 (1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0857] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 15 mmol of compound 73-1 (yield = 75%).

[0858] (Synthesis of Compound 73) Compound 73-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0859] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 8.2 mmol of compound 73 (yield = 82%).

[0860] [Synthesis Example 20: Synthesis of Compound 77]

[0861]

[0862] (Synthesis of Compound 77) Compound 73-1 (12 mmol, 1.2 equivalents), N-phenylnaphthalene-2-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0863] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.2 mmol of compound 77 (yield = 72%).

[0864] [Synthesis Example 21: Synthesis of Compound 101]

[0865]

[0866] (Synthesis of Compound 101-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (26 mmol, 1.3 equivalents), 1-([1,1'-biphenyl]-4-yl)-N-phenylnaphthalen-2-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3 (1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0867] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 14 mmol of compound 101-1 (yield = 70%).

[0868] (Synthesis of Compound 101) Compound 101-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0869] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 8.0 mmol of compound 101 (yield = 80%).

[0870] [Synthesis Example 22: Synthesis of Compound 102]

[0871]

[0872] (Synthesis of Compound 102) Compound 101-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-4-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0873] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.9 mmol of compound 102 (yield = 79%).

[0874] [Synthesis Example 23: Synthesis of Compound 103]

[0875]

[0876] (Synthesis of Compound 103) Compound 101-1 (12 mmol, 1.2 equivalents), 4-cyclohexyl-N-phenylaniline (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0877] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.5 mmol of compound 103 (yield = 75%).

[0878] [Synthesis Example 24: Synthesis of Compound 141]

[0879]

[0880] (Synthesis of Compound 141-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (26 mmol, 1.3 equivalents), N-phenyl-[1,2'-dinaphthyl]-2-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3 (1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0881] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 13 mmol of compound 141-1 (yield = 65%).

[0882] (Synthesis of Compound 141) Compound 141-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0883] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 8.0 mmol of compound 141 (yield = 80%).

[0884] [Synthesis Example 25: Synthesis of Compound 142]

[0885]

[0886] (Synthesis of Compound 142) Compound 141-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-4-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0887] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.4 mmol of compound 142 (yield = 74%).

[0888] [Synthesis Example 26: Synthesis of Compound 161]

[0889]

[0890] (Synthesis of Compound 161-1) 2,2'-dibromo-9,9'-spirobi[fluorene] (26 mmol, 1.3 equivalents), N-(1-phenylnaphthalen-2-yl)dibenzo[b,d]furan-1-amine (20 mmol, 1 equivalent), Pd 2 (dba) 3 (1 mmol, 0.05 eq.), t-BuONa (40 mmol, 2 eq.), BINAP (2 mmol, 0.1 eq.) and 300 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0891] After the reaction is completed, the reaction product is washed with ether / H 2 O treatment and purification by column chromatography using dichloromethane / hexane (volume ratio of 1 / 5) to obtain 15 mmol of compound 161-1 (yield = 75%).

[0892] (Synthesis of Compound 161) Compound 161-1 (12 mmol, 1.2 equivalents), diphenylamine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0893] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 8.0 mmol of Compound 161 (yield = 80%).

[0894] [Synthesis Example 27: Synthesis of Compound 162]

[0895]

[0896] (Synthesis of Compound 162) Compound 161-1 (12 mmol, 1.2 equivalents), N-phenyl-[1,1'-biphenyl]-4-amine (10 mmol, 1 equivalent), Pd 2 (dba) 3 (0.5 mol, 0.05 equivalent), t-BuONa (20 mmol, 2 equivalents), t-Bu 3 P (0.1 mmol, 0.1 eq.) and 150 ml of Tol. were added into a single-necked round-bottom flask and stirred at 110° C. for 1 hour.

[0897] After the reaction is completed, the reaction product is washed with ether / H 2 O and purified by column chromatography using dichloromethane / hexane (volume ratio of 1 / 8) to obtain 7.6 mmol of compound 162 (yield = 76%).

[0898] [Example 1]

[0899] As an anode, a 15Ω / cm 2 A glass substrate of ITO electrode (product of Corning Incorporated) was cut into a size of 50 mm×50 mm×0.7 mm, ultrasonically treated with isopropyl alcohol and pure water for 5 minutes each, cleaned by ultraviolet irradiation and ozone exposure for 30 minutes, and mounted on a vacuum deposition apparatus.

[0900] NPD is deposited on the anode to form a A hole injection layer having a thickness of , and compound 1 is deposited on the hole injection layer to form a A hole transport layer having a thickness of , and CzSi is deposited on the hole transport layer to form a The thickness of the emission auxiliary layer is .

[0901] HTH33+ETH2 (host), PD39 (phosphorescent sensitizer) and t-DABNA (boron dopant) were co-deposited on the emission auxiliary layer in a weight ratio of 42:42:15:1 to form a The emission layer is formed by depositing TSPO1 on the emission layer to form a A hole blocking layer with a thickness of TPBi is deposited on the hole blocking layer to form a An electron transport layer having a thickness of , LiF is deposited on the electron transport layer to form a An electron injection layer having a thickness of , and Al is deposited on the electron injection layer to form a A cathode having a thickness of , thereby manufacturing an organic light-emitting device.

[0902]

[0903]

[0904] [Example 2 to Example 27 and Comparative Example 1 to Comparative Example 6]

[0905] Organic light-emitting devices were manufactured in substantially the same manner as in Example 1, except that the compounds shown in Table 1 were each used instead of Compound 1 when forming a hole transport layer.

[0906] [Comparative Example 7]

[0907] An organic light-emitting device was manufactured in substantially the same manner as in Example 1, except that C7 was used instead of Compound 1 when forming the hole transport layer and host EB (4% dopant BD) was used in the emission layer.

[0908] [Comparative Example 8]

[0909] An organic light-emitting device was manufactured in substantially the same manner as in Example 1, except that C3 was used when forming the hole transport layer, and C8 was deposited thereon to form a The emission auxiliary layer is formed by co-depositing the compound H1-a (host) and the compound FD38 (fluorescent dopant) on the emission auxiliary layer at a weight ratio of 95:5 to form a The thickness of the emission layer.

[0910] [Evaluation Example 1]

[0911] The driving voltage, luminous efficiency, maximum emission wavelength and lifetime of the organic light-emitting devices manufactured according to Examples 1 to 27 and Comparative Examples 1 to 8 were measured using Keithley SMU 236 and luminance meter PR650. The results are shown in Table 1.

[0912] [Table 1]

[0913]

[0914]

[0915]

[0916]

[0917] Referring to Table 1, it is confirmed that the organic light-emitting devices of Examples 1 to 27 have better driving voltage, luminous efficiency, and lifespan than those of Comparative Examples 1 to 8.

[0918] By including the amine compound represented by Formula 1, the light-emitting device may have excellent characteristics such as low driving voltage, high luminous efficiency, and long lifespan, and high-quality electronic devices and electronic devices may be manufactured using the light-emitting device.

[0919] Embodiments have been disclosed herein, and although terms are employed, they are used and interpreted in a general and descriptive sense only, and not for purposes of limitation. In some cases, as will be apparent to one of ordinary skill in the art, features, characteristics, and / or elements described in conjunction with embodiments may be used alone or in combination with features, characteristics, and / or elements described in conjunction with other embodiments, unless specifically indicated otherwise. Accordingly, one of ordinary skill in the art will understand that various changes in form and detail may be made without departing from the spirit and scope of the present disclosure as set forth in the claims.

Claims

1. A light emitting device, include: a first electrode; a second electrode facing the first electrode; as well as a layer between the first electrode and the second electrode, wherein The interlayer comprises: Emission layer; as well as a hole transport region between the first electrode and the emissive layer, and The hole transport region includes an amine compound represented by Formula 1: Formula 1 In formula 1, L 1 and L 2 Each is independently a single bond, unsubstituted or substituted by at least one R 10a Substituted C 5 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, n1 and n2 are each independently an integer selected from 1 to 3, Z 1 To Z 3 and E 1 Each is independently deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or replaced by at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ), e1 is an integer selected from 1 to 7, R 11 , R 12 and R 2 To R 5 Each is independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or replaced by at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ), a11 is an integer selected from 0 to 4, a12 is an integer selected from 0 to 3, a2 is an integer selected from 0 to 3, a3 to a5 are each independently an integer selected from 0 to 4, R 10a for: deuterium, -F, -Cl, -Br, -I, hydroxy, cyano or nitro; Each unsubstituted or substituted C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl or C 1 -C 60 Alkoxy: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 11 )(Q 12 )(Q 13 )、-N(Q 11 )(Q 12 )、-B(Q 11 )(Q 12 )、-C(=O)(Q 11 )、-S(=O) 2 (Q 11 )、-P(=O)(Q 11 )(Q 12 ) or any combination thereof; Each unsubstituted or substituted C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 21 )(Q 22 )(Q 23 )、-N(Q 21 )(Q 22 )、-B(Q 21 )(Q 22 )、-C(=O)(Q 21 )、-S(=O) 2 (Q 21 )、-P(=O)(Q 21 )(Q 22 ) or any combination thereof; or -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 ) or -P(=O)(Q 31 )(Q 32 ),and Q 1 To Q 3 , Q 11 To Q 13 , Q 21 To Q 23 and Q 31 To Q 33 Each independently represents: hydrogen; deuterium; -F; -Cl; -Br; -I; hydroxyl; cyano; nitro; C 1 -C 60 Alkyl; C 2 -C 60 Alkenyl; C 2 -C 60 Alkynyl; C 1 -C 60 alkoxy; or each unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 C substituted by heterocyclic group or any combination thereof 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl.

2. The light emitting device according to claim 1, wherein The hole transport region includes a hole injection layer, a hole transport layer, an emission auxiliary layer, an electron blocking layer or any combination thereof, and At least one of the hole transport layer and the hole injection layer includes the amine compound.

3. The light emitting device according to claim 1, further comprising: include: Includes at least one π-electron-deficient nitrogen-containing C 1 -C 60 a second compound comprising a heterocyclic group, a third compound comprising a group represented by Formula 3, a fourth compound being a delayed fluorescence compound, a fifth compound being an organic metal compound containing a transition metal, or any combination thereof, wherein The second compound, the third compound, the fourth compound and the fifth compound are different from each other: Formula 3 In formula 3, Cyclo 71 and CY 72 Each is independently a π-electron-rich C 3 -C 60 Cyclic group or pyridyl group, X 71 is a single bond; or a linking group comprising O, S, N, B, C, Si or any combination thereof, and * indicates a bonding site with atoms included in the remaining parts other than Formula 3 in the third compound. 4 . The light-emitting device according to claim 3 , wherein the second compound comprises a pyridyl group, a pyrimidyl group, a pyrazinyl group, a pyridazinyl group, a triazinyl group, or any combination thereof. 5 . The light-emitting device according to claim 3 , wherein the fourth compound includes at least one cyclic group including boron and nitrogen as ring-forming atoms.

6. The light emitting device according to claim 3, wherein The fifth compound includes a platinum atom and a tetradentate ligand bonded to the platinum atom, and One of the bonds between the platinum atom and the tetradentate ligand is a platinum-carbene bond.

7. The light emitting device according to claim 3, wherein The fifth compound includes an iridium atom and a tetradentate ligand bonded to the iridium atom, and One of the bonds between the iridium atom and the tetradentate ligand is an iridium-carbene bond.

8. The light emitting device according to claim 3, wherein The emission layer includes the second compound, the third compound, the fourth compound, the fifth compound, or any combination thereof, and The emission layer emits blue light.

9. An electronic device comprising the light emitting device according to any one of claims 1 to 8.

10. The electronic device of claim 9, further comprising a color filter, a color conversion layer, a touch screen layer, a polarization layer, or any combination thereof.

11. The electronic device according to claim 9, further comprising: include: Thin film transistors, where The thin film transistor includes a source electrode and a drain electrode, and The first electrode of the light emitting device is electrically connected to the source electrode or the drain electrode.

12. An electronic device comprising the light emitting device according to any one of claims 1 to 8.

13. The electronic device of claim 12, wherein the electronic device is a flat panel display, a curved display, a computer monitor, a medical monitor, a television, a billboard, an indoor light, an outdoor light, a signal light, a head-up display, a fully transparent display, a partially transparent display, a flexible display, a rollable display, a foldable display, a retractable display, a laser printer, a phone, a portable phone, a tablet personal computer, a tablet mobile computer, a personal digital assistant, a wearable device, a laptop computer, a digital camera, a video camera, a viewfinder, a microdisplay, a three-dimensional display, a virtual reality display, an augmented reality display, a vehicle, a video wall with multiple displays stitched together, a theater screen, a stadium screen, a light therapy device, or a sign.

14. An amine compound represented by formula 1: Formula 1 In formula 1, L 1 and L 2 Each is independently a single bond, unsubstituted or substituted by at least one R 10a Substituted C 5 -C 60 The carbocyclic group is either unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, n1 and n2 are each independently an integer selected from 1 to 3, Z 1 To Z 3 and E 1 Each is independently deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or replaced by at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ), e1 is an integer selected from 1 to 7, R 11 , R 12 and R 2 To R 5 Each is independently hydrogen, deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, unsubstituted or replaced by at least one R 10a Substituted C 1 -C 60 Alkyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkenyl, unsubstituted or substituted with at least one R 10a Substituted C 2 -C 60 Alkynyl, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Alkoxy, unsubstituted or substituted with at least one R 10a Substituted C 3 -C 60 Carbocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 1 -C 60 Heterocyclic group, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Aryloxy, unsubstituted or substituted with at least one R 10a Substituted C 6 -C 60 Arylthio, -Si(Q 1 )(Q 2 )(Q 3 )、-N(Q 1 )(Q 2 )、-B(Q 1 )(Q 2 )、-C(=O)(Q 1 )、-S(=O) 2 (Q 1 ) or -P(=O)(Q 1 )(Q 2 ), a11 is an integer selected from 0 to 4, a12 is an integer selected from 0 to 3, a2 is an integer selected from 0 to 3, a3 to a5 are each independently an integer selected from 0 to 4, R 10a for: deuterium, -F, -Cl, -Br, -I, hydroxy, cyano or nitro; Each unsubstituted or substituted C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl or C 1 -C 60 Alkoxy: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 11 )(Q 12 )(Q 13 )、-N(Q 11 )(Q 12 )、-B(Q 11 )(Q 12 )、-C(=O)(Q 11 )、-S(=O) 2 (Q 11 )、-P(=O)(Q 11 )(Q 12 ) or any combination thereof; Each unsubstituted or substituted C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl: deuterium, -F, -Cl, -Br, -I, hydroxyl, cyano, nitro, C 1 -C 60 Alkyl, C 2 -C 60 Alkenyl, C 2 -C 60 Alkynyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 6 -C 60 Aryloxy, C 6 -C 60 Arylthio, C 7 -C 60 Aralkyl, C 2 -C 60 Heteroaralkyl, -Si(Q 21 )(Q 22 )(Q 23 )、-N(Q 21 )(Q 22 )、-B(Q 21 )(Q 22 )、-C(=O)(Q 21 )、-S(=O) 2 (Q 21 )、-P(=O)(Q 21 )(Q 22 ) or any combination thereof; or -Si(Q 31 )(Q 32 )(Q 33 )、-N(Q 31 )(Q 32 )、-B(Q 31 )(Q 32 )、-C(=O)(Q 31 )、-S(=O) 2 (Q 31 ) or -P(=O)(Q 31 )(Q 32 ),and Q 1 To Q 3 , Q 11 To Q 13 , Q 21 To Q 23 and Q 31 To Q 33 Each independently represents: hydrogen; deuterium; -F; -Cl; -Br; -I; hydroxyl; cyano; nitro; C 1 -C 60 Alkyl; C 2 -C 60 Alkenyl; C 2 -C 60 Alkynyl; C 1 -C 60 alkoxy; or each unsubstituted or substituted with deuterium, -F, cyano, C 1 -C 60 Alkyl, C 1 -C 60 Alkoxy, C 3 -C 60 Carbocyclic group, C 1 -C 60 C substituted by heterocyclic group or any combination thereof 3 -C 60 Carbocyclic group, C 1 -C 60 Heterocyclic group, C 7 -C 60 Arylalkyl or C 2 -C 60 Heteroaralkyl.

15. The amine compound according to claim 14, wherein Z 1 To Z 3 and E 1 are each independently unsubstituted or substituted with at least one R 10a Substituted phenyl, naphthyl, fluorenyl, carbazolyl, dibenzofuranyl, dibenzothiophenyl, azacarbazolyl, azadibenzofuranyl, azadibenzothiophenyl, pyridyl, pyrimidinyl, pyrazinyl, quinolyl or quinoxalinyl.

16. The amine compound according to claim 14, wherein Z 1 To Z 3 and E 1 Each is independently a group represented by one of Formula 1A-1 to Formula 1A-16: Wherein in Formula 1A-1 to Formula 1A-16, R 10a Same as defined in Formula 1, c4 is an integer selected from 0 to 4, c5 is an integer selected from 0 to 5, c7 is an integer selected from 0 to 7, X 1 N(R 1 ), O or S, R 1 Compared with R in formula 1 11 The description is the same, and * indicates a bonding site to N or the naphthyl group in Formula 1.

17. The amine compound according to claim 14, wherein in Formula 1, The moiety represented by is a moiety represented by one of Formula 1B-1 to Formula 1B-14: Wherein in Formula 1B-1 to Formula 1B-14, E 1 , R 11 , R 12 , a11 and a12 are each the same as defined in Formula 1, and *Indicates the bonding site to the adjacent N.

18. The amine compound according to claim 14, wherein Z 2 and Z 3 Different from each other.

19. The amine compound according to claim 14, wherein the amine compound is represented by Formula 1-1: Formula 1-1 In formula 1-1, a5 is an integer selected from 0 to 3, and Z 1 To Z 3 、E 1 、e1、R 11 , R 12 , R 2 To R 5 , a11, a12 and a2 to a4 are each the same as defined in Formula 1.

20. The amine compound according to claim 14, wherein the amine compound is one of Compound 1 to Compound 206:

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