Solar cell module

Abstract

This solar cell module (1) is provided with: a plurality of unit regions (2), each of which includes a solar cell element; and a connecting part. The plurality of unit regions (2) are provided in a state of being aligned in a first direction plane. The solar cell element generates power on the basis of incident light. The connection part is in a state in which the solar cell elements of the plurality of cell regions (2) are electrically connected in series. The solar cell element includes a first electrode layer, a second electrode layer, and a semiconductor layer (4b) between the first electrode layer and the second electrode layer. At least one of the plurality of unit regions (2) includes an object portion (5). The object portion (5) is provided adjacent to the semiconductor layer (4b) in plan view. The object part (5) has a semiconductor or an insulator having a different band gap energy from the semiconductor layer (4b).

Description

[0001] [Cross-reference of related applications]

[0002] This application claims the benefit of Japanese Patent Application No. 2022-085267 (filed on May 25, 2022), the entire contents of which are incorporated herein by reference. Technical Field

[0003] The invention relates to a solar cell module. Background Art

[0004] Solar cells include crystalline solar cells and thin-film solar cells. In general, thin-film solar cells have a structure in which a plurality of solar cell elements arranged on a substrate are electrically connected in series (for example, see the description of Patent Document 1).

[0005] Prior art literature

[0006] Patent Literature

[0007] Patent Document 1: Japanese Patent Application Publication No. 2007-012976 Summary of the invention

[0008] A solar cell module is disclosed.

[0009] In one embodiment, a solar cell module comprises: a plurality of unit regions, each of which comprises a solar cell element; and a connecting portion. The plurality of unit regions are arranged in a plane arranged along a first direction. The solar cell element generates electricity based on incident light. The connecting portion is arranged in a state of electrically connecting the solar cell elements of the plurality of unit regions in series. The solar cell element comprises a first electrode layer, a second electrode layer, and a semiconductor layer located between the first electrode layer and the second electrode layer. At least one of the plurality of unit regions comprises an object portion. The object portion is arranged in a state adjacent to the semiconductor layer when viewed from above. The object portion comprises a semiconductor or an insulator having a band gap energy different from that of the semiconductor layer.

[0010] In another embodiment, a solar cell module comprises: a plurality of unit areas, each of which includes a solar cell element; a connecting portion; and a component. The plurality of unit areas are arranged in a planar arrangement along a first direction. The solar cell element generates electricity based on incident light. The connecting portion is arranged in a state of electrically connecting the solar cell elements of the plurality of unit areas in series. The component is arranged in a state of overlapping with a first area of ​​at least one of the plurality of unit areas when viewed from above, and not overlapping with a second area of ​​the at least one of the plurality of unit areas. The component absorbs light of at least a portion of the wavelength range of the incident light.

[0011] In another embodiment, a solar cell module has: a plurality of unit areas, each of which includes a solar cell element; a connecting portion; and a component. The plurality of unit areas are arranged in a plane along a first direction. The solar cell element generates electricity based on incident light. The connecting portion is arranged in a state of electrically connecting the solar cell elements of the plurality of unit areas in series. The component is arranged in a state of overlapping with a first area of ​​at least one of the plurality of unit areas other than the unit areas at both ends of the first direction when viewed from above, and not overlapping with a second area of ​​the at least one of the plurality of unit areas. The component reflects light of at least a portion of the wavelength range of the incident light. BRIEF DESCRIPTION OF THE DRAWINGS

[0012] Figure 1 yes Figure 1 It is a plan view schematically showing an example of the structure of the solar cell module according to the first embodiment.

[0013] Figure 2 It is a rough representation of the Figure 1 This is a cross-sectional view of an example of a cross section of a solar cell module taken along line II-II.

[0014] Figure 3 It is a rough representation of the Figure 1 This is a cross-sectional view of an example of a cross section of a solar cell module taken along line III-III.

[0015] Figure 4 This is a cross-sectional view schematically showing an example of a state in the process of manufacturing a solar cell module.

[0016] Figure 5 This is a cross-sectional view schematically showing an example of a state in the process of manufacturing a solar cell module.

[0017] Figure 6 This is a cross-sectional view schematically showing an example of a state in the process of manufacturing a solar cell module.

[0018] Figure 7 This is a cross-sectional view schematically showing an example of a state in the process of manufacturing a solar cell module.

[0019] Figure 8 This is a cross-sectional view schematically showing an example of a state in the process of manufacturing a solar cell module.

[0020] Fig. 9 This is a cross-sectional view schematically showing an example of a state in the process of manufacturing a solar cell module.

[0021] Fig.10This is a cross-sectional view schematically showing an example of a cross section of a solar cell module according to the second embodiment.

[0022] Fig.11 It is a rough representation of the Fig.10 This is a cross-sectional view of an example of a cross section of a solar cell module taken along line XI-XI.

[0023] Fig.12 This is a graph showing an example of the wavelength dependence of the absorbance of the light absorbing layer.

[0024] Fig.13 This is a cross-sectional view schematically showing an example of a cross section of a solar cell module according to the third embodiment.

[0025] Fig.14 It is a rough representation of the Fig.13 A cross-sectional view of a first example of a cross section of a solar cell module taken along line XIV-XIV.

[0026] Fig.15 It is a rough representation of the Fig.13 This is a cross-sectional view of a second example of the cross section of the solar cell module taken along line XIV-XIV.

[0027] Fig.16 It is a rough representation of the Fig.13 This is a cross-sectional view of a third example of the cross section of the solar cell module taken along line XIV-XIV.

[0028] Fig.17 This is a cross-sectional view schematically showing an example of a cross section of a solar cell module according to a fourth embodiment.

[0029] Fig.18 is roughly along Fig.17 This is a cross-sectional view of an example of a cross section of a solar cell module taken along line XVIII-XVIII.

[0030] Fig.19 It is a rough representation of the Fig.17 This is a cross-sectional view of an example of a cross section of a solar cell module taken along line XIX-XIX.

[0031] Fig. 20 It is a rough representation of the Fig.17 This is a cross-sectional view of a first alternative embodiment of a solar cell module taken along line XIX-XIX.

[0032] Fig.21 It is a rough representation of the Fig.17 This is a cross-sectional view of a second alternative embodiment of a solar cell module taken along line XIX-XIX.

[0033] Fig. 22It is a rough representation of the Fig.17 A cross-sectional view of a third other aspect of the solar cell module taken along line XIX-XIX.

[0034] Fig.23 It is a rough representation of the Fig.17 A cross-sectional view of a fourth other embodiment of a solar cell module taken along line XIX-XIX.

[0035] Fig.24 It means along Fig.17 A cross-sectional view of the structure of a fifth other embodiment of a solar cell module taken along line XIX-XIX.

[0036] Fig.25 It is a rough representation of the Fig.17 A cross-sectional view of a sixth other aspect of the solar cell module taken along line XIX-XIX. DETAILED DESCRIPTION

[0037] The inventors have created a technology for improving the appearance of a solar cell module. Regarding this technology, first to fourth embodiments will be described below with reference to the drawings.

[0038] Various embodiments are described below with reference to the accompanying drawings. In the accompanying drawings, parts having the same or similar structures and functions are marked with the same reference numerals, and repeated descriptions are omitted in the following description. In addition, the accompanying drawings are schematic representations. Figures 1 to 24 In the XYZ coordinate system, a right-handed XYZ coordinate system is provided. In the XYZ coordinate system, the direction in which the plurality of solar cell elements 4 are arranged is the +X direction, the long side direction of the third groove portion P3 between adjacent solar cell elements 4 is the +Y direction, and the direction orthogonal to both the +X direction and the +Y direction is the +Z direction.

[0039] <1. First Embodiment>

[0040] <1-1. Overview of Solar Cell Module>

[0041] according to Figures 1 to 3 A solar cell module 1 according to the first embodiment will be described.

[0042] like Figure 1 As shown, the solar cell module 1 has a plurality of unit regions 2. In a top view, the plurality of unit regions 2 are arranged in a plane along a first direction (+X direction). Figure 1In the example of FIG. 1 , five unit regions, namely, the first unit region 21 to the fifth unit region 25, are shown as a plurality of unit regions 2. The first unit region 21 to the fifth unit region 25 are arranged in this order from the -X direction toward the +X direction. That is, the first unit region 21 is located at one end of the -X direction, and the fifth unit region 25 is located at one end of the +X direction. The inter-battery region 2g is located between the first unit region 21 and the second unit region 22. The inter-battery region 2g is also located between the other unit regions 2.

[0043] The shape of each unit region 2 is a rectangle with the second direction (+Y direction) orthogonal to the first direction as the long side direction. For example, the lengths of the unit regions 2 in the Y direction can be set to be equal to each other in the plurality of unit regions 2. For example, the widths W of the unit regions 2 in the X direction can be set to be different from each other in the plurality of unit regions 2. The width W of each unit region 2 will be described later.

[0044] As described later, the solar cell elements 4 that generate electricity based on incident light such as sunlight are located in each unit area 2. As described later, the solar cell elements 4 of the plurality of unit areas 2 are arranged in a state of being electrically connected in series with each other. The solar cell elements 4 of the first unit area 21 located at one end of the -X direction in the plurality of unit areas 2 are arranged in a state of being electrically connected to the first wiring material 91 for extracting electricity, and the solar cell elements 4 of the fifth unit area 25 located at one end of the +X direction are arranged in a state of being electrically connected to the second wiring material 92 for extracting electricity. Because the solar cell elements 4 of the plurality of unit areas 2 are connected in series with each other, the direct currents flowing through the unit areas 2 are equal to each other. The direct current is extracted to the outside of the solar cell module 1 through the first wiring material 91 and the second wiring material 92.

[0045] In this embodiment, at least one of the plurality of unit regions 2 has a plurality of regions 20. When viewed from above, the plurality of regions 20 are arranged in an adjacent state, and the current densities of the plurality of regions 20 are different from each other. That is, when viewed from above, at least one of the unit regions 2 has a current density distribution. The current density mentioned here is the amount of current per unit area. Figure 1 In the example of FIG. 1 , each of the first unit region 21 to the fifth unit region 25 has a first region 20a and a second region 20b as the plurality of regions 20. In other words, in Figure 1 In the example of FIG. 1 , the first region 20a and the second region 20b constitute each unit region 2. Figure 1 In the example of FIG. 1 , a sandy shadow is given to the portion representing the first area 20 a.

[0046] like Figure 1As shown, in each unit region 2, at least a portion of one region 20 (for example, the first region 20a) is arranged, for example, in a state of being arranged side by side with at least a portion of another region 20 (for example, the second region 20b) in the Y direction. In addition, in each unit region 2, at least a portion of one region 20 is arranged, for example, in a state of being able to be arranged side by side with at least a portion of the other region 20 in the X direction.

[0047] Here, the current density of the first region 20a is greater than the current density of the second region 20b. In addition, the current density may be zero. In other words, no current may be generated in a part of the unit region 2 (here, the second region 20b).

[0048] like Figures 1 to 3 As shown, each unit region 2 is formed by, for example, a solar cell element 4 and an object portion 5. Figure 2 In the example of FIG. 1 , as a plurality of solar cell elements 4, first solar cell elements 41 to fifth solar cell elements 45 corresponding to the first unit region 21 to the fifth unit region 25 are shown. In each unit region 2, the solar cell element 4 is located in the first region 20a. Each solar cell element 4 generates carriers including electrons or holes based on incident light. The plurality of solar cell elements 4 are connected in series with each other using the connection portion 6. Therefore, a predetermined amount of the carriers generated in the solar cell element 4 in each unit region 2 flows through the plurality of unit regions 2 as a direct current.

[0049] In each unit region 2, the object portion 5 is located in the second region 20b. Figure 3 As shown, in each unit region 2, the object portion 5 is provided, for example, in a state adjacent to the semiconductor layer 4b (described later) of the solar cell element 4. A material different from the semiconductor layer 4b of the solar cell element 4 can be used as the material of the object portion 5. Therefore, for example, the band gap energies between the semiconductor layer 4b and the object portion 5 are different from each other. The object portion 5 can be, for example, an insulating layer 50. For example, a transparent insulating material such as silicon oxide can be used as the material of the insulating layer 50. In the case where the object portion 5 is the insulating layer 50, the object portion 5 does not substantially generate carriers that can be extracted.

[0050] As mentioned above, in Figures 1 to 3 In the example of , each unit region 2 is composed of a first region 20a and a second region 20b, and in each unit region 2, the semiconductor layer 4b and the object portion 5 are located in the first region 20a and the second region 20b, respectively. Here, since the band gap energies of the semiconductor layer 4b and the object portion 5 are different, the degree of light absorption between the semiconductor layer 4b and the object portion 5 is different. Therefore, when a user observes the solar cell module 1, the first region 20a and the second region 20b have different colors in appearance.

[0051] exist Figure 1 In the example, the entire first area 20a is equivalent to the design area imitating the sun, the design area imitating the clouds, and the design area imitating the smiling face, and the entire second area 20b is equivalent to the background area relative to these design areas. Therefore, when looking down at the solar cell module 1, the user can visually recognize the designs of the sun, clouds, and smiling face.

[0052] <1-2. More specific structure of solar cell module>

[0053] like Figure 2 and Figure 3 As shown, the solar cell module 1 includes, for example, a first substrate 3, a plurality of solar cell elements 4, a body portion 5, a connection portion 6, a filling material 7, a second substrate 8, a first wiring material 91, and a second wiring material 92. The first substrate 3 and the second substrate 8 are arranged in a state facing each other in the Z direction. The solar cell element 4, the body portion 5, the connection portion 6, the filling material 7, the first wiring material 91, and the second wiring material 92 are located between the first substrate 3 and the second substrate 8, and are integrated by the filling material 7.

[0054] <1-2-1. First Substrate>

[0055] The first substrate 3 can play the role of supporting a plurality of solar cell elements 4 and protecting a plurality of solar cell elements 4. The solar cell elements 4 are arranged on the surface of the first substrate 3. Here, if the first substrate 3 is translucent to light of a specific range of wavelengths, the light passing through the first substrate 3 can be incident on the plurality of solar cell elements 4. As the first substrate 3, for example, a flat plate with a rectangular plate surface is used. One side of the first substrate 3 is, for example, along the +X direction. As the material of the first substrate 3, for example, if glass or resins such as acrylic and polycarbonate are used, the first substrate 3 can be translucent to light of a specific range of wavelengths. As glass, for example, materials with high light transmittance such as ultra-white glass, tempered glass and heat-reflective glass can be used. The first substrate 3 can be a flexible substrate. In this specification, light of a specific range of wavelengths refers to light of a wavelength range in which the solar cell element 4 can perform photoelectric conversion.

[0056] The solar cell module 1 can be installed with the first substrate 3 facing the light source, for example. The light source is the sun, for example, and the solar cell module 1 can be installed with the first substrate 3 facing the sun at noon. In this case, a light-transmitting material is used as the material of the first substrate 3.

[0057] The solar cell module 1 may be arranged with the second substrate 8 facing the light source. In this case, as long as the second substrate 8 is light-transmissive, the first substrate 3 may not be light-transmissive. For example, the first substrate 3 may be a metal plate with an insulating layer formed on the surface.

[0058] Hereinafter, as an example, the solar cell module 1 is installed in a state where the first substrate 3 faces the light source. In this case, incident light such as sunlight passes through the first substrate 3 and enters the plurality of solar cell elements 4 .

[0059] <1-2-2. Solar cell element and object portion>

[0060] The plurality of solar cell elements 4 are arranged in a plane in the +X direction. Here, the so-called plane arrangement means that each solar cell element 4 is arranged along an imaginary or actual plane, and the plurality of solar cell elements 4 are arranged side by side. Figure 2 In the example, a plurality of solar cell elements 4 are arranged along the surface of the first substrate 3 .

[0061] Each solar cell element 4 includes a first electrode layer 4a, a semiconductor layer 4b, and a second electrode layer 4c. The first electrode layer 4a is located on the first substrate 3, the semiconductor layer 4b is located on the first electrode layer 4a, and the second electrode layer 4c is located on the semiconductor layer 4b. That is, the first electrode layer 4a, the semiconductor layer 4b, and the second electrode layer 4c are stacked in this order in the Z direction.

[0062] The light transmittance of the first electrode layer 4a to light of a specific range of wavelengths is higher than that of the semiconductor layer 4b. As a material of the first electrode layer 4a, for example, a transparent conductive oxide (TCO) having light transmittance to light of a specific range of wavelengths can be used. The transparent conductive oxide may include, for example, indium tin oxide (ITO), fluorine-doped tin oxide (FTO), and zinc oxide (ZnO).

[0063] The incident light passes through the first substrate 3 and the first electrode layer 4a and enters the semiconductor layer 4b. The semiconductor layer 4b absorbs the light and generates carriers including holes or electrons. The carriers flow to one of the first electrode layer 4a and the second electrode layer 4c.

[0064] In addition, when the solar cell module 1 is installed in a state where the second substrate 8 faces the light source, the first electrode layer 4a does not need to have light-transmitting properties. For example, various metals can be used as the material of the first electrode layer 4a.

[0065] In the present embodiment, on the first substrate 3, five first electrode layers 4a are arranged in a plane in sequence along the +X direction. Here, two first electrode layers 4a belonging to two adjacent solar cell elements 4 are arranged with a gap (also referred to as a first gap) G1 between them. For example, the first electrode layer 4a of the first solar cell element 41 and the first electrode layer 4a of the second solar cell element 42 are arranged with a first gap G1 between them. Each first gap G1 has a long strip shape with the +Y direction as the long side direction. In addition, there is a first groove portion P1 with the first substrate 3 as the bottom surface and the two end surfaces of the two first electrode layers 4a in a facing state separated by the first gap G1 as the side surfaces. The first groove portion P1 is a groove extending in a straight line along the +Y direction.

[0066] The first electrode layer 4a is located at least in the entire first region 20a in each unit region 2. The first electrode layer 4a is not limited to the first region 20a, for example, but can be located in the entire second region 20b. In other words, the first electrode layer 4a can be located in the entire unit region 2. In addition, the first electrode layer 4a extends from the unit region 2 in the -X direction, and the extended portion is located in the inter-battery region 2g. When viewed from above, the first electrode layer 4a is, for example, rectangular, and the length of the first electrode layer 4a in the Y direction is, for example, approximately equal to the length of the unit region 2 in the Y direction.

[0067] In each solar cell element 4, the semiconductor layer 4b is located between the first electrode layer 4a and the second electrode layer 4c. When viewed from above, the semiconductor layer 4b is located in the entire first region 20a. The structure of the semiconductor layer 4b is, for example, a stacked semiconductor layer (also referred to as a perovskite semiconductor) layer (perovskite semiconductor layer) and a hole transport layer (HTL: HoleTransport Layer) having a perovskite structure. In the case where the semiconductor layer 4b is a perovskite semiconductor, light of a specific range of wavelengths includes visible light and infrared light.

[0068] Perovskite semiconductors can include, for example, halide organic-inorganic perovskite semiconductors. As perovskite semiconductors, for example, if a semiconductor having a perovskite structure containing an amine group is used, the photoelectric conversion efficiency of the semiconductor layer 4b can be improved. Thus, the photoelectric conversion efficiency of the solar cell element 4 can be improved. Here, for example, for semiconductors having a perovskite structure containing an amine group, a halide perovskite semiconductor having a composition of ABX3 formed by a combination of A ions, B ions, and X ions can be applied. Here, for example, methylammonium ions (MA) can be added. + ), formamide ion (FA + ) and guanidine ion (GA + ) or other amine-containing organic cations as A ions. For example, lead ions (Pb2 + ) and tin ions (Sn2 +) or other metal ions of Group 14 (Group IV-A) elements as B ions. For example, iodine ions (I - ), bromide ion (Br - ) and chloride ions (Cl - ) etc. are used as X ions.

[0069] For example, a raw material liquid is applied to the first electrode layer 4a on the first substrate 3 and dried, thereby forming a perovskite semiconductor. Here, the perovskite semiconductor is a crystalline thin film. At this time, for example, by filling the first gap G1 with a raw material liquid and drying it, a part of the perovskite semiconductor can also be formed in the first gap G1. Here, for example, the raw material liquid can be generated by dissolving alkylamine halide and lead halide as raw materials in a solvent.

[0070] The hole transport layer (HTL) can collect and transport holes. As a material of the hole transport layer (HTL), for example, spiro-OMe TAD, which is a soluble diamine derivative, can be used.

[0071] Here, for example, if the perovskite semiconductor is an intrinsic semiconductor (i-type semiconductor), the hole transport layer is a p-type semiconductor, and the TCO constituting the first electrode layer 4a is an n-type semiconductor, a PIN junction region can be formed. In the PIN junction region, power generation can be performed by photoelectric conversion based on irradiation of light. In the semiconductor layer 4b, for example, an n-type semiconductor layer can be located between the perovskite semiconductor layer and the first electrode layer 4a. At this time, a PIN junction region can be formed only by the semiconductor layer 4b.

[0072] In each unit region 2, the object portion 5 is provided adjacent to the semiconductor layer 4b of the solar cell element 4. That is, the object portion 5 and the semiconductor layer 4b are located in the same layer. Figure 2 and 3 As shown, the object portion 5 is, for example, located in the entire second region 20b. Figure 2 and Figure 3 In the example of FIG. 4 , the object portion 5 is located between the first electrode layer 4a and the second electrode layer 4c and is in contact with the side surface of the semiconductor layer 4b. The object portion 5 together with the semiconductor layer 4b can play a role in supporting the second electrode layer 4c.

[0073] The object portion 5 has a bandgap energy different from that of the semiconductor layer 4b. The difference between the bandgap energy of the object portion 5 and the bandgap energy of the semiconductor layer 4b may be, for example, 0.1 eV or more, 0.2 eV or more, or 0.5 eV or more. The bandgap energy of either the semiconductor layer 4b or the object portion 5 may be, for example, 1.7 eV or more. The object portion 5 may be, for example, an insulating layer 50 made of an insulator. For example, various insulators such as silicon oxide or resin may be used as the material of the insulating layer 50. The insulating layer 50 may be light-transmissive with respect to visible light. That is, the insulating layer 50 may be transparent or translucent. In the second region 20b of each unit region 2, since the insulating layer 50 is located between the first electrode layer 4a and the second electrode layer 4c, a short circuit between the first electrode layer 4a and the second electrode layer 4c can be avoided.

[0074] The semiconductor layer 4b and the insulating layer 50 can also be located in the inter-cell region 2g. Figure 1 In the first groove portion P1 of each inter-battery region 2g, the first region 20a and the second region 20b are arranged adjacent to each other in the Y direction. In addition, between the second groove portion P2 (described later) and the third groove portion P3 (described later) in each inter-battery region 2g, the first region 20a and the second region 20b are also arranged adjacent to each other in the Y direction. In each inter-battery region 2g, the semiconductor layer 4b can be located in the first region 20a, and the insulating layer 50 can be located in the second region 20b. Therefore, even in the inter-battery region 2g (especially, the first groove portion P1, and the region between the second groove portion P2 and the third groove portion P3), the insulating layer 50 is arranged adjacent to the semiconductor layer 4b in the Y direction.

[0075] In each solar cell element 4, the second electrode layer 4c is arranged on the semiconductor layer 4b and the insulating layer 50. The second electrode layer 4c can have high light transmittance to light of a specific range of wavelengths. For example, as a material for the second electrode layer 4c, a transparent conductive oxide (TCO) having light transmittance to light of a specific range of wavelengths can be used. Transparent conductive oxides can include, for example, indium tin oxide (ITO), fluorine-doped tin oxide (FTO) or zinc oxide (ZnO). In this case, light that passes through the solar cell element 4 and is reflected by the second substrate 8 or an external member can pass through the second electrode layer 4c again to the semiconductor layer 4b. Therefore, the photoelectric conversion efficiency of the solar cell module 1 can be improved. In addition, the second electrode layer 4c does not have to be light transmittance, for example, it can be formed of metal. In the case where the second electrode layer 4c is formed of metal, because the light that passes through the semiconductor layer 4b is reflected by the second electrode layer 4c, the reflected light can be incident on the semiconductor layer 4b. Therefore, the photoelectric conversion efficiency of the solar cell module 1 can be improved.

[0076] In the first embodiment, five second electrode layers 4c are arranged in a plane in sequence along the +X direction. Here, the second electrode layers 4c belonging to two adjacent solar cell elements 4 are arranged side by side with a gap (also referred to as a second gap) G2 between them. For example, the second electrode layer 4c of the first solar cell element 41 and the second electrode layer 4c of the second solar cell element 42 are arranged side by side with a second gap G2 between them. Each second gap G2 has, for example, a strip shape with the +Y direction as the long side direction. In addition, in the second gap G2, there is a third groove portion P3 with the first electrode layer 4a as the bottom surface and the two end surfaces of the two solar cell elements 4 facing each other across the second gap G2 as the side surfaces. The third groove portion P3 is a groove that penetrates the second electrode layer 4c, the semiconductor layer 4b and the insulating layer 50 in the Z direction and extends straight in the +Y direction.

[0077] The second electrode layer 4c is located at least in the entire first region 20a in each cell region 2. For example, the second electrode layer 4c is not limited to the first region 20a, and can be located in the entire second region 20b. That is, the second electrode layer 4c can be located in the entire cell region 2. In addition, the second electrode layer 4c extends from the cell region 2 in the +X direction, and its extended portion is located in the inter-battery region 2g. In the inter-battery region 2g, the third groove portion P3 between the second electrode layers 4c is offset in the +X direction compared to the first groove portion P1 between the first electrode layers 4a. Therefore, in the inter-battery region 2g, when viewed from above, the end portion of the first electrode layer 4a in the -X direction overlaps with the end portion of the second electrode layer 4c in the +X direction. The semiconductor layer 4b or the object portion 5 is located between the end portion of the first electrode layer 4a and the end portion of the second electrode layer 4c. When viewed from above, the second electrode layer 4c is, for example, rectangular, and the length of the second electrode layer 4c in the Y direction is, for example, substantially equal to the length of the cell region 2 in the Y direction.

[0078] The inter-battery region 2g is, for example, a region sandwiched by the edge portion of the first groove portion P1 in the -X direction and the edge portion of the third groove portion P3 in the +X direction. In the inter-battery region 2g, the solar cell elements 4 of the adjacent unit region 2 are electrically connected by the connection portion 6 described later. The unit region 2 is, for example, a region sandwiched by the edge portion of the third groove portion P3 in the +X direction and the edge portion of the first groove portion P1 in the -X direction.

[0079] <1-2-3. Connection>

[0080] The plurality of connection portions 6 are respectively located in the plurality of inter-cell regions 2g, and connect the first electrode layer 4a and the second electrode layer 4c of two adjacent solar cell elements 4. Figure 2 In the example of FIG. 1 , as the plurality of connection parts 6 , a first connection part 61 to a fourth connection part 64 are shown. Figure 2In the example of FIG. 4 , the first connecting portion 61 electrically connects the second electrode layer 4c of the first solar cell element 41 to the first electrode layer 4a of the second solar cell element 42, and the second connecting portion 62 electrically connects the second electrode layer 4c of the second solar cell element 42 to the first electrode layer 4a of the third solar cell element 43. The third connecting portion 63 electrically connects the second electrode layer 4c of the third solar cell element 43 to the first electrode layer 4a of the fourth solar cell element 44, and the fourth connecting portion 64 electrically connects the second electrode layer 4c of the fourth solar cell element 44 to the first electrode layer 4a of the fifth solar cell element 45. Thus, the plurality of solar cell elements 4 can be electrically connected in series.

[0081] The connecting portion 6 is, for example, integrally formed with the second electrode layer 4c by the same material. The connecting portion 6 is provided in a state of filling the second groove portion P2 located between the first groove portion P1 and the third groove portion P3, and is in a state of contacting the first electrode layer 4a at the bottom surface of the second groove portion P2. Thus, the connecting portion 6 electrically connects the first electrode layer 4a and the second electrode layer 4c. The second groove portion P2 has a long strip shape with the +Y direction as the long side direction. The second groove portion P2 is also a groove extending straight along the +Y direction.

[0082] <1-2-4. Extraction Electrode>

[0083] The first wiring material 91 for outputting the first polarity is disposed on an end portion 911 of the first electrode layer 4a of the first solar cell element 41, which extends further in the -X direction than the insulating layer 50 and the semiconductor layer 4b. The first wiring material 91 is formed of a metal such as copper. The first wiring material 91 may be, for example, copper foil. For example, a joint such as solder may be provided between the first wiring material 91 and the end portion 911. The first wiring material 91 is in an electrically connected state to the end portion 911. Figure 1 As shown, the first wiring material 91 has a strip shape with the +Y direction as the longitudinal direction.

[0084] exist Figure 2 In the example, the electrode layer 921 is located in the +X direction relative to the first electrode layer 4a of the fifth solar cell element 45. There is a first groove portion P1 between the electrode layer 921 and the first electrode layer 4a of the fifth solar cell element 45. The electrode layer 921 is, for example, made of the same material as the first electrode layer 4a, and has, for example, a long strip shape with the +Y direction as the long side direction when viewed from above. The electrode layer 921 is electrically connected to the second electrode layer 4c of the fifth solar cell element 45. A second wiring material 92 for output of the second polarity is arranged on the electrode layer 921. The second wiring material 92 is, for example, formed of a metal such as copper. The second wiring material 92 can be, for example, copper foil. For example, a joint such as solder can be sandwiched between the second wiring material 92 and the electrode layer 921. The second wiring material 92 is in a state of being electrically connected to the electrode layer 921. As Figure 1 As shown, the second wiring material 92 has a long strip shape with the +Y direction as the long side direction. Here, for example, if the first polarity is negative, the second polarity is positive. For example, if the first polarity is positive, the second polarity is negative.

[0085] <1-2-5. Second Substrate>

[0086] The second substrate 8 can play a role in protecting a plurality of solar cell elements 4. The second substrate 8 is arranged in a state facing the first substrate 3 in the Z direction. The second substrate 8 can be, for example, a flat plate having a rectangular plate surface that is the same as or similar to the first substrate 3. When viewed from above, the shape of the second substrate 8 can be the same as that of the first substrate 3. The second substrate 8 may or may not be light-transmitting to light of a specific range of wavelengths. As the material of the second substrate 8, for example, if glass or resins such as acrylic and polycarbonate are used, the second substrate 8 can be light-transmitting to light of a specific range of wavelengths. Alternatively, the second substrate 8 can be a metal plate with an insulating layer formed on the surface. In this case, the second substrate 8 is not light-transmitting. In addition, in the case where the solar cell module 1 is arranged in a state where the second substrate 8 faces the light source, a light-transmitting material can be used as the material of the second substrate 8. In addition, like the first substrate 3, the second substrate 8 can be a flexible substrate.

[0087] <1-2-6. Filling materials>

[0088] The insulating filling material 7 is provided between the first substrate 3 and the second substrate 8 in a state of covering the plurality of solar cell elements 4, the insulating layer 50, the first wiring material 91 and the second wiring material 92. In other words, the filling material 7 is provided in a state of filling the gap between the first substrate 3 and the second substrate 8. The filling material 7 is, for example, light-transmissive to light of a specific range of wavelengths. For example, polyvinyl acetals such as ethylene vinyl acetate copolymer (EVA), polyvinyl butyral (PVB), and acid-modified resins can be used as materials for the filling material 7. Here, for example, if relatively cheap EVA is used as the material for the filling material 7, the performance of protecting the plurality of solar cell elements 4 can be easily achieved. For example, modified polyolefin resins can be applied to the acid-modified resins, and such modified polyolefin resins can be formed by grafting and modifying resins such as polyolefins using acids. For example, acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, maleic anhydride, nadic anhydride (himic anhydride), itaconic anhydride, citraconic anhydride, etc. can be used as the graft-modified acid of the acid-modified resin.

[0089] <1-2-7. Area of ​​unit area>

[0090] In the above specific example, the stacked structure of the first electrode layer 4a, the semiconductor layer 4b and the second electrode layer 4c is located in the first region 20a of each unit region 2. Therefore, in the first region 20a, carriers are generated based on the incident light, and a specified portion thereof flows as a direct current. On the other hand, in the second region 20b of each unit region 2, the semiconductor layer 4b is not provided, but an insulating layer 50 is provided. Therefore, in the second region 20b, substantially no extractable carriers are generated, and substantially no current is generated. That is, the current density of the direct current generated in the first region 20a is greater than the current density (=0) of the second region 20b.

[0091] Here, the amount of carriers generated per unit time in each unit area 2 is examined. The larger the area of ​​the first region 20a, the larger the amount of carriers generated per unit time in each unit area 2. However, because the solar cell elements 4 of the plurality of unit areas 2 are connected in series with each other, only a specified amount of the generated carriers flows as a direct current. In other words, carriers exceeding the specified amount cannot be extracted to the outside of the solar cell module 1. Therefore, if the deviation in the amount of carriers generated per unit time between the plurality of unit areas 2 is large, the number of carriers that cannot be extracted to the outside increases, and the photoelectric conversion efficiency of the solar cell module 1 decreases.

[0092] Therefore, here, it is planned to reduce the variation in the amount of carriers generated per unit time among the plurality of cell regions 2. In addition, hereinafter, the amount of carriers generated per unit time in the cell region 2 is also referred to as the carrier generation amount.

[0093] like Figure 1 As shown, the width W of the cell region 2 can be set larger as the area of ​​the second region 20b belonging to the cell region 2 (i.e., the area of ​​the insulating layer 50 when viewed from above) is larger. In other words, the area of ​​the cell region 2 is larger as the area of ​​the second region 20b belonging to the cell region 2 is larger. Figure 1 In the example of , the second region 20b of the first unit region 21 is larger than the second region 20b of the second unit region 22, and the width W of the first unit region 21 is larger than the width W of the second unit region 22. Thus, the difference between the area of ​​the first region 20a of the first unit region 21 and the area of ​​the first region 20a of the second unit region 22 can be reduced. In other words, the deviation of the area of ​​the first region 20a between the plurality of unit regions 2 can be reduced. Therefore, the deviation of the carrier generation amount between the plurality of unit regions 2 can be reduced.

[0094] In summary, the width W of each unit region 2 can be set as follows. That is, the width W of each unit region 2 is set so that the deviation of the carrier generation amount is smaller than the deviation of the carrier generation amount in a virtual structure in which a plurality of unit regions 2 have the same width. As a more specific example, the width W of the unit region 2 is set to satisfy the following formula.

[0095] J·r[k]·A[k]=constant··· (1)

[0096] Here, J represents the unit area of ​​the first region 20a and the amount of carriers generated per unit time when incident light is incident on the solar cell module 1 with a uniform spatial distribution, A[k] represents the area of ​​the kth unit region 2, and r[k] represents the ratio of the area of ​​the first region 20a belonging to the kth unit region 2 to the area A[k]. When the unit region 2 is rectangular, the area A[k] is represented by the product of the length in the Y direction and the width W in the X direction of the kth unit region 2. The left side of formula (1) represents the amount of carriers generated in each unit region 2. Therefore, according to formula (1), the width W of each unit region 2 can be set so that the amount of carriers generated between multiple unit regions 2 is constant.

[0097] By setting the width W of the cell region 2 as described above, it is possible to reduce the variation in the amount of carrier generation between the plurality of cell regions 2. Therefore, it is possible to more efficiently extract a DC current from the solar cell module 1. In other words, a larger DC current can be extracted from the solar cell module 1, and the photoelectric conversion efficiency of the solar cell module 1 can be improved.

[0098] <1-3. Method for manufacturing solar cell module>

[0099] Next, according to Figures 4 to 9 The manufacturing method of the solar cell module 1 is described below. Figure 4 As shown, prepare the first substrate 3. As the first substrate 3, for example, a rectangular flat plate that is translucent to light of a specific range of wavelengths can be used. Next, an electrode layer 4a0 is formed on one surface of the first substrate 3. The electrode layer 4a0 can be formed, for example, by a film forming method such as sputtering, deposition, and chemical vapor deposition. The electrode layer 4a0 can be composed of a transparent conductive oxide such as ITO, FTO, and ZnO. At this time, the thickness of the electrode layer 4a0 can be set to, for example, about 10nm to 1000nm. In addition, as described above, a metal can be used as the material of the electrode layer 4a0. In this case, the electrode layer 4a0 can be formed, for example, by a coating method.

[0100] Then, if Figure 5As shown, the electrode layer 4a0 is separated into a plurality of first electrode layers 4a and an electrode layer 921. For example, by forming a plurality of first grooves P1 (first gaps G1), a plurality of first electrode layers 4a and an electrode layer 921 can be formed. Thus, for example, the first to fifth first electrode layers 4a and electrode layers 921 are formed, and the first to fifth first electrode layers 4a and electrode layers 921 are arranged in a plane along the first direction (+X direction) on the surface of the first substrate 3. The plurality of first grooves P1 (first gaps G1) can be formed, for example, by laser scribing or mechanical scribing. Each first groove P1 (each first gap G1) can be formed with the long side direction being the +Y direction. Here, the width of each first groove P1 (each first gap G1) in the X direction can be set to, for example, about 30 μm to 300 μm. The length of the first groove P1 in the Y direction is, for example, substantially equal to the length of the unit region 2 in the Y direction.

[0101] In addition, the first electrode layer 4a and the electrode layer 921 can be patterned while forming the film. For example, the raw material liquid can be applied to the first substrate 3 only in the required area by inkjet printing, and then the raw material liquid can be dried to form the first electrode layer 4a and the electrode layer 921. Alternatively, the first electrode layer 4a and the electrode layer 921 can be formed on the first substrate 3 using a mask having a patterned opening corresponding to the shape of the first electrode layer 4a and the electrode layer 921. As a result, the removal process such as scribing for forming the first groove portion P1 can be omitted. In addition, similar to the first electrode layer 4a, the semiconductor layer 4b, the insulating layer 50 and the second electrode layer 4c described below can also be patterned while forming the film.

[0102] Then, if Figure 6 As shown, a semiconductor layer 4b0 for a perovskite solar cell and an insulating layer 500 for an object portion 5 are formed on a plurality of first electrode layers 4a.

[0103] For example, first, a semiconductor layer 4b0 is formed in at least the entire first region 20a. The semiconductor layer 4b0 can be formed, for example, by applying and drying a raw material liquid using a coating method such as inkjet printing, spraying, rod coating, and die coating. Here, the structure of the semiconductor layer 4b0 is a stack of multiple layers including a perovskite semiconductor layer and a hole transport layer. In this case, for example, after the perovskite semiconductor layer is formed by coating and drying a first raw material liquid, a hole transport layer can be formed on the perovskite semiconductor layer by coating and drying a second raw material liquid. The thickness of the semiconductor layer 4b0 can be set to, for example, about 100 nm to 2000 nm. At this time, the formation of the semiconductor layer 4b0 also enters a state in which the portion of the first region 20a is equivalent to the plurality of first grooves P1 (first gaps G1).

[0104] Next, an insulating layer 500 is formed on the plurality of first electrode layers 4a in the region adjacent to the semiconductor layer 4b0. The insulating layer 500 is formed so as to be located in the entire second region 20b. The insulating layer 500 can be formed, for example, by applying and drying a raw material solution using a coating method such as inkjet printing, spray coating, rod coating, and die coating. The thickness of the insulating layer 500 is, for example, substantially equal to the thickness of the semiconductor layer 4b0. At this time, the insulating layer 500 is formed to also enter the portion corresponding to the second region 20b in the plurality of first grooves P1 (first gaps G1).

[0105] In addition, the formation order of the semiconductor layer 4b0 and the insulating layer 500 may be reversed.

[0106] Here, an example of a method of forming the semiconductor layer 4b0 and the insulating layer 500 by an inkjet printer is described. For example, the inkjet printer includes an inkjet head group, a transport unit, a drying unit, and a control unit.

[0107] The inkjet head group includes: one or more first inkjet heads for ejecting raw material liquid for the semiconductor layer 4b0; and a second inkjet head for ejecting raw material liquid for the insulating layer 500. In the case where the semiconductor layer 4b0 has a plurality of semiconductor layers, the plurality of first inkjet heads are configured to eject raw material liquids corresponding to the plurality of semiconductor layers. The one or more first inkjet heads and the second inkjet heads are arranged in a state arranged in the conveying direction of the first substrate 3. The first inkjet head and the second inkjet head are in the shape of a long strip in the width direction orthogonal to the conveying direction, and a plurality of ejection ports are formed on their lower end surfaces. The plurality of ejection ports are arranged in a state arranged at least in the width direction. For example, the method for controlling the ejection of the raw material liquid from each ejection port may be a piezoelectric method, in which a voltage is applied to a piezoelectric element corresponding to each ejection port to eject the raw material liquid, or a thermal inkjet method, in which the raw material liquid is heated by energizing a heater corresponding to each ejection port to eject the raw material liquid.

[0108] The conveying unit moves the first substrate 3 relative to the inkjet group in the conveying direction in a space below the inkjet group. The drying unit has, for example, a heater, and heats the first substrate 3 to dry the raw material liquid. The drying unit can be located behind the conveying direction of each first inkjet head and behind the conveying direction of the second inkjet head.

[0109] The control unit controls the conveying unit, the inkjet head group, and the drying unit. For example, the control unit controls the conveying unit, the inkjet head group, and the drying unit according to the program stored in the non-volatile storage unit. In addition, the control unit controls the conveying unit and the inkjet head group according to the area data. The so-called area data is data indicating the area where the semiconductor layer 4b0 is coated on the first substrate 3 and the area where the insulating layer 500 is coated. The area data is set by an operator, for example. For example, at the moment when the area where the semiconductor layer 4b0 is formed in the first substrate 3 is located directly below the first inkjet head, the control unit causes the raw material liquid to be ejected from the ejection port of the first inkjet head corresponding to the area, and the drying unit dries the raw material liquid. In the case where the semiconductor layer 4b0 includes a plurality of semiconductor layers, coating using the first inkjet head and drying using the drying unit are performed multiple times. At the moment when the area where the insulating layer 500 is formed in the first substrate 3 is located directly below the second inkjet head, the control unit causes the raw material liquid to be ejected from the ejection port of the second inkjet head corresponding to the area. The drying unit appropriately dries the raw material liquid. Thus, the semiconductor layer 4 b0 and the insulating layer 500 are formed on the first substrate 3 .

[0110] Next, an example of a method for forming the semiconductor layer 4b0 and the insulating layer 500 using a mask is also described. For example, a first mask having an opening corresponding to the region where the semiconductor layer 4b0 is to be formed is placed on the first substrate 3, and a raw material liquid for the semiconductor layer 4b0 is applied to the entire first mask including the opening and dried. In the case where the semiconductor layer 4b0 includes a plurality of semiconductor layers, the coating and drying using the first mask are performed a plurality of times. Next, the first mask is removed, and a second mask having an opening corresponding to the region where the insulating layer 500 is to be formed is placed on the first substrate 3. Next, a raw material liquid for the insulating layer 500 is applied to the entire second mask including the opening and dried.

[0111] Then, if Figure 7 As shown, a plurality of second grooves P2 are formed for connecting the first electrode layer 4a and the second electrode layer 4c. The second grooves P2 can be formed, for example, by scribing or the like. Each second groove P2 extends along the +Y direction and is formed in the semiconductor layer 4b0 and the insulating layer 500. Here, the width of each second groove P2 in the X direction is set to, for example, about 30 μm to 300 μm. The length of the second groove P2 in the Y direction is, for example, substantially equal to the length of the unit region 2 in the Y direction.

[0112] Then, if Figure 8As shown, a second electrode layer 4c0 is formed on the semiconductor layer 4b0 and the insulating layer 500 in which the second groove portion P2 is formed. Here, for example, the second electrode layer 4c0 can be formed by a film forming method such as sputtering, evaporation, and chemical vapor growth. The second electrode layer 4c0 can be composed of transparent conductive oxides such as ITO, FTO, and ZnO, for example. The thickness of the second electrode layer 4c0 can be set to about 10nm to 1000nm, for example. At this time, the second electrode layer 4c0 is formed to enter the state of each second groove portion P2. Thus, a first connecting portion 61, a second connecting portion 62, a third connecting portion 63, and a fourth connecting portion 64 are formed. In addition, as described above, a metal can be used as a material for the second electrode layer 4c0. In this case, the second electrode layer 4c0 can be formed, for example, by a coating method.

[0113] Then, if Fig. 9 As shown, the second electrode layer 4c0 is separated into a plurality of second electrode layers 4c. For example, by forming a plurality of third grooves P3 (second gaps G2), a plurality of second electrode layers 4c are formed. The third grooves P3 can be formed, for example, by scribing. In addition, the semiconductor layer 4b0 is also appropriately separated into a plurality of semiconductor layers 4b, and the insulating layer 500 is also separated into a plurality of insulating layers 50. By forming the third grooves P3, a plurality of solar cell elements 4 connected in series are formed.

[0114] Next, the first wiring material 91 is joined to the end portion 911 of the first electrode layer 4a located at the end in the -X direction, and the second wiring material 92 is joined to the electrode layer 921. For example, the first wiring material 91 is joined to the end portion 911, and the second wiring material 92 is joined to the electrode layer 921 by welding.

[0115] Then, in Fig. 9 On the structure shown, a sheet of a material serving as a filler 7 and a second substrate 8 are sequentially stacked. Then, they are integrated by lamination processing to produce a solar cell module 1.

[0116] In addition, if necessary, a frame (not shown) may be attached to the peripheral edge of the first substrate 3 and the second substrate 8. The frame is a member made of metal or resin for sealing between the first substrate 3 and the second substrate 8.

[0117] <1-4. Summary of First Embodiment>

[0118] In the solar cell module 1 of the first embodiment, at least one of the plurality of unit regions 2 has a plurality of regions 20 having different current densities. Figure 1In the example, the plurality of unit regions 2 each have a first region 20a and a second region 20b as the plurality of regions 20. In the above specific example, the semiconductor layer 4b and the object portion 5 having different band gap energies are located in the first region 20a and the second region 20b, respectively. In the above example, since the object portion 5 is an insulating layer 50, the current density of the second region 20b is substantially zero. Therefore, the current density of the first region 20a is greater than the current density of the second region 20b.

[0119] The absorption degree of incident light is different in the semiconductor layer 4b and the object portion 5 having different band gap energies. Therefore, the first region 20a and the second region 20b have different colors in appearance. Thus, the first region 20a and the second region 20b having different colors are formed, so that the design of the solar cell module 1 can be improved.

[0120] In the above example, in each unit region 2, at least a portion of the first region 20a is aligned with at least a portion of the second region 20b in the Y direction, and at least a portion of the first region 20a is aligned with at least a portion of the second region 20b in the X direction. Therefore, a two-dimensional design can be drawn on the solar cell module 1. For example, Figure 1 In the figure, the design areas representing the sun, clouds and smiling face respectively correspond to the first area 20a, and the background area around the design areas corresponds to the second area 20b. Thus, the user can visually recognize the designs of the sun, clouds and smiling face in the solar cell module 1.

[0121] In the above example, among the plurality of unit regions 2, not only the first unit region 21 and the fifth unit region 25 located at both ends in the X direction, but also the second unit region 22 to the fourth unit region 24 located at the center side have the plurality of regions 20. In this way, since at least one of the unit regions 2 located at the center side has the plurality of regions 20, a design can be formed in a more conspicuous region.

[0122] In addition, in the above example, the width W of each cell region 2 is set to reduce the variation in the amount of carrier generation between the plurality of cell regions 2. Therefore, the carriers generated in each cell region 2 can be more effectively utilized, and a direct current can be passed through the plurality of cell regions 2. In other words, the portion of the generated carriers that does not flow as a direct current can be reduced.

[0123] In addition, Figure 1In the example of , in each unit region 2, the plurality of first regions 20a are located at mutually separated positions. For example, in the second unit region 22, the first region 20a as a part of the design region imitating the sun and the first region 20a as a part of the design region imitating the smiling face are separated from each other via the second region 20b as the background region. Therefore, in each unit region 2, when viewed from above, the plurality of semiconductor layers 4b are separated from each other, and the insulating layer 50 is located between the plurality of semiconductor layers 4b.

[0124] In the above example, in each unit region 2, the first electrode layer 4a and the second electrode layer 4c are located in the entire corresponding unit region 2. Therefore, in each unit region 2, the surfaces of the plurality of semiconductor layers 4b in the -Z direction are connected to the common first electrode layer 4a, and the surfaces of the plurality of semiconductor layers 4b in the +Z direction are connected to the common second electrode layer 4c (see also Figure 3 ). Therefore, in each unit region 2, even if the plurality of semiconductor layers 4b are separated from each other, the current generated by the plurality of semiconductor layers 4b can properly flow to the first electrode layer 4a and the second electrode layer 4c. In other words, by forming a plurality of first regions 20a separated from each other in each unit region 2, a free design can be drawn using the solar cell module 1, and the current generated in each first region 20a can be properly extracted to the outside.

[0125] In addition, when the semiconductor layer 4b and the object portion 5 are formed by inkjet printing, the shape of the first area 20a and the shape of the second area 20b can be easily changed. As described above, the inkjet printer has a plurality of nozzles for ejecting the raw material liquid. By controlling the presence or absence of the raw material liquid ejection according to each nozzle, the area where the raw material liquid is applied can be easily changed. Therefore, it becomes easy to change the design. Specifically, the operator can reset the area data.

[0126] <1-5. Other methods>

[0127] In the above specific example, a perovskite semiconductor layer is used as the semiconductor layer 4b. However, it is not necessarily limited to this. A thin film semiconductor other than a perovskite semiconductor can be used as the semiconductor layer 4b. For example, various organic semiconductors other than perovskite semiconductors can be used. Or, for example, a silicon-based, compound-based or other type of semiconductor can be used. For example, a semiconductor using amorphous silicon or thin film polycrystalline silicon can be used as a silicon-based thin film semiconductor. For example, a compound semiconductor having a chalcopyrite structure such as a CIS semiconductor or a CIGS semiconductor, a compound semiconductor having a kesterite structure, or a cadmium telluride (CdTe) semiconductor can be used as a compound thin film semiconductor. A CIS semiconductor is a compound semiconductor containing copper (Cu), indium (In) and selenium (Se). A CIGS semiconductor is a compound semiconductor containing Cu, In, gallium (Ga) and Se. These thin film semiconductors can be formed on the first electrode layer 4a, for example, by evaporation. The semiconductor layer 4b can be patterned, for example, by laser scribing or mechanical scribing. Of course, by using a mask to form a film of the semiconductor layer 4b only in the desired area, removal processing such as scribing can also be omitted.

[0128] <2. Second Embodiment>

[0129] <2-1. Structure of Solar Cell Module>

[0130] In a first embodiment, if Fig.10 As shown in FIG. 1 , as a plurality of regions 20 having different current densities, a first region 20a to a fourth region 20d may be provided. Fig.10 In the example, the first area 20a is equivalent to the design area representing the sun, the third area 20c is equivalent to the design area representing the smiling face, the fourth area 20d is equivalent to the design area representing the clouds, and the second area 20b is equivalent to the background area relative to these design areas.

[0131] like Fig.10 As shown, the semiconductor layer 4b1, the semiconductor layer 4b3, and the semiconductor layer 4b4 as the semiconductor layer 4b are respectively located in the first region 20a, the third region 20c, and the fourth region 20d. That is, the semiconductor layer 4b1 is located in the entire first region 20a, the semiconductor layer 4b3 is located in the entire third region 20c, and the semiconductor layer 4b4 is located in the entire fourth region 20d. In addition, the semiconductor layer 4b2 as the object portion 5 is located in the second region 20b. That is, the semiconductor layer 4b2 is located in the entire second region 20b. Because the first region 20a to the fourth region 20d are adjacent to each other when viewed from above, the semiconductor layers 4b1 to 4b4 are located at different positions when viewed from above.

[0132] Each of the semiconductor layers 4b1 to 4b4 has, for example, a structure that is the same as or similar to the semiconductor layer 4b of the first embodiment. As a specific example, each of the semiconductor layers 4b1 to 4b4 has, for example, a structure in which a perovskite semiconductor layer and a hole transport layer are stacked. Fig.11 As shown, since the semiconductor layer 4b2 as the object portion 5 is also located between the first electrode layer 4a and the second electrode layer 4c, the semiconductor layer 4b2 also functions as a part of the solar cell element 4. That is, the semiconductor layer 4b2 as the object portion 5 also generates a current based on the incident light, and the current flows through the first electrode layer 4a, the semiconductor layer 4b2, and the second electrode layer 4c.

[0133] However, the composition ratio of the perovskite semiconductor layer is different from each other between the semiconductor layer 4b1 to the semiconductor layer 4b4. Here, a halide perovskite semiconductor can be used as the perovskite semiconductor. For example, a methylammonium ion (MA) + ), lead ion (Pb2 + ) and halide ions (I - ,Br - ) is used as the material. In this case, for example, if the value obtained by dividing the sum of the content of I and the content of Br (also referred to as the content ratio x of Br) is increased, the band gap energy in the halide perovskite semiconductor can be increased from 1.5 eV to 2.3 eV. Thus, for example, when observing the semiconductor layers 4b1 to 4b4, the color of the appearance can be changed from a color close to black to a color close to yellow.

[0134] Fig.12 It is shown that the 1-x Br x )3 is the wavelength dependence of the absorbance of the light absorbing layer. Fig.12 In the example, curves Gr1 to Gr7 are shown. Curves Gr1 to Gr7 represent the absorbance of the light absorbing layer when x=0.0, 0.12, 0.26, 0.42, 0.59, 0.72, and 0.95, respectively. When x=0.0, 0.12, 0.26, 0.42, 0.59, 0.72, and 0.95, the band gap energy of the light absorbing layer is 1.56 eV, 1.62 eV, 1.69 eV, 1.79 eV, 1.96 eV, 2.01 eV, and 2.23 eV, respectively. When x=0.0, x=0.12, or x=0.26, the absorbance of visible light is high in a wide range (see Fig.12The color of the light absorbing layer is close to black. When x=0.42 or x=0.59, the color of the light absorbing layer is close to brown, when x=0.72, the color of the light absorbing layer is close to red, and when x=0.95, the color of the light absorbing layer is close to yellow. As described above, the color tone of the light absorbing layer changes by changing the content ratio x of Br. Here, if the difference in the band gap energy of the light absorbing layer is greater than 0.1, the difference in the color of the light absorbing layer can be roughly visually recognized.

[0135] The Br content ratio x of the perovskite semiconductor layers from semiconductor layer 4b1 to semiconductor layer 4b4 is different from each other to the extent that the difference in band gap energy is 0.1 or more. In addition, the difference between the minimum and maximum values ​​of the band gap energy of the plurality of semiconductor layers 4b may be, for example, 0.2 eV or more, or 0.5 eV or more. The band gap energy of at least one of semiconductor layers 4b1 to semiconductor layer 4b4 is, for example, 1.7 eV or more.

[0136] According to the second embodiment, due to the difference in band gap energy, the first region 20a where the semiconductor layer 4b1 is located, the second region 20b where the semiconductor layer 4b2 is located, the third region 20c where the semiconductor layer 4b3 is located, and the fourth region 20d where the semiconductor layer 4b4 is located can have different appearance tones. Therefore, the design of the solar cell module 1 can be further improved.

[0137] <2-2. Area of ​​unit area>

[0138] In the second embodiment, the width W of each unit region 2 can be set as follows. That is, the width W of each unit region 2 is set so that the deviation of the carrier generation amount is smaller than the deviation of the carrier generation amount in a virtual structure in which a plurality of unit regions 2 have the same width. As a more specific example, the width W of the unit region 2 is set to satisfy the following formula.

[0139] ∑(J[k,m]·r[k,m]·A[k])=constant··· (2)

[0140] Here, ∑(Z[m]) represents the sum of Z[m] for the number of m-th regions 20 of each unit region 2 (i.e., the value of m), J[k,m] represents the amount of carrier generation per unit area and per unit time in the m-th region 20 of the k-th unit region 2, A[k] represents the area of ​​the k-th unit region 2, and r[k,m] represents the ratio of the area of ​​the m-th region 20 belonging to the k-th unit region 2 to the area A[k]. In the case where the unit region 2 is rectangular, the area A[k] is represented by the product of the length of the unit region 2 in the Y direction and the width W in the X direction. The left side of formula (2) represents the amount of carrier generation in each unit region 2. Therefore, according to formula (2), the width W of each unit region 2 is set so that the amount of carrier generation remains constant between the plurality of unit regions 2.

[0141] Furthermore, in each cell region 2 , as a ratio J[k, m] of the area of ​​the region 20 having a larger amount of carriers generated per unit area and per unit time among the plurality of regions 20 increases, the width W of the cell region 2 is set to be narrower.

[0142] By setting the width W of the cell region 2 as described above, it is possible to reduce the variation in the amount of carrier generation between the plurality of cell regions 2. Therefore, direct current can be more efficiently extracted from the solar cell module 1. That is, the photoelectric conversion efficiency of the solar cell module 1 can be improved.

[0143] In addition, in the above specific examples, semiconductor layers 4b1 to 4b4 are illustrated, but the types of semiconductor layers 4b with different composition ratios are not limited to four, as long as there are two or more. In addition, when viewed from above, the insulating layer 50 as the object part 5 and the plurality of types of semiconductor layers 4b can be arranged in a state adjacent to each other. In addition, in the above examples, although the composition of the plurality of types of semiconductor layers 4b is the same and their composition ratios are different, it is also possible that the plurality of types of semiconductor layers 4b with different compositions are arranged in a state adjacent to each other when viewed from above.

[0144] <3. Third Embodiment>

[0145] In a first embodiment, if Fig.13 As shown, in each unit region 2, the first region 20a may not be separated into a plurality of regions, and may be continuous from one end of the unit region 2 in the -X direction to one end in the +X direction. Fig.13 In the example of , each unit region 2 is formed by a first region 20a and a second region 20b. Fig.13 In the example of , the first area 20a corresponds to a design area roughly showing a heart shape, and the second area 20b corresponds to a background area relative to the design area. Fig.13In the example of , the first region 20a is provided adjacent to the second region 20b in the Y direction. The semiconductor layer 4b belonging to the solar cell element 4 is located in the entire first region 20a, and the object portion 5 is located in the entire second region 20b. Here, the object portion 5 includes an insulator.

[0146] In such a structure, Figures 14 to 16 As shown, at least one of the first electrode layer 4a and the second electrode layer 4c belonging to the solar cell element 4 can avoid the second region 20b. In other words, at least one of the first electrode layer 4a and the second electrode layer 4c can avoid the region (second region 20b) overlapping the object portion 5 in a plan view.

[0147] exist Fig.14 In the example, the second electrode layer 4c is not located in the second region 20b of each unit region 2. In each unit region 2, for example, a portion of the filling material 7 is located in the entire second region 20b. This portion of the filling material 7 is arranged in the second region 20b in a state of being continuously filled from the surface of the first electrode layer 4a to the surface of the second substrate 8. This portion of the filling material 7 is arranged in a state of also being in contact with the side surface of the semiconductor layer 4b and the side surface of the second electrode layer 4c. According to such a structure, when viewed from above, the object portion 5 adjacent to the semiconductor layer 4b is equivalent to this portion of the filling material 7. Because the filling material 7 is an insulator, the band gap energy of the filling material 7 is different from the band gap energy of the semiconductor layer 4b. Therefore, the color tones of the appearance of the first region 20a and the second region 20b are different from each other. Therefore, the design of the solar cell module 1 can be improved.

[0148] In addition, the first region 20a where the semiconductor layer 4b is located is provided in a state of being continuous from one end in the -X direction to one end in the +X direction of each unit region 2. Therefore, the first electrode layer 4a and the second electrode layer 4c are also provided in a state of being continuous from one end in the -X direction to one end in the +X direction of each unit region 2. In addition, the first electrode layer 4a is provided in a state of extending from one end in the -X direction of the unit region 2 into the inter-battery region 2g, and the second electrode layer 4c is provided in a state of extending from one end in the +X direction of the unit region 2 into the inter-battery region 2g. Since the connection portion 6 electrically connects the first electrode layer 4a and the second electrode layer 4c in the inter-battery region 2g, the solar cell elements 4 of a plurality of unit regions 2 can be connected in series with each other.

[0149] exist Fig.15 In the example of , both the first electrode layer 4a and the second electrode layer 4c are not located in the second region 20b of each unit region 2. Fig.15In the example of , in each unit region 2, a portion of the filling material 7 is located in the second region 20b. The portion of the filling material 7 is provided in the second region 20b in a state of being continuously filled from the surface of the first substrate 3 to the surface of the second substrate 8. The portion of the filling material 7 is provided in a state of being in contact with the side surface of the first electrode layer 4a, the side surface of the semiconductor layer 4b, and the side surface of the second electrode layer 4c. In such a structure, when viewed from above, the object portion 5 adjacent to the semiconductor layer 4b corresponds to the portion of the filling material 7. In this structure, since the first region 20a and the second region 20b have different colors in appearance, the design of the solar cell module 1 can be improved.

[0150] In addition, Fig.14 and Fig.15 In the example, since the object portion 5 is a part of the filling material 7, it is not necessary to separate the object portion 5 from the filling material 7, and the manufacturing cost of the solar cell module 1 can be reduced.

[0151] exist Fig.16 In the example of , the first electrode layer 4a is not located in the second region 20b of each unit region 2. The object portion 5 is located in the entire second region 20b of each unit region 2. The object portion 5 is adjacent to the first electrode layer 4a and the semiconductor layer 4b and is located in the same layer as them. The object portion 5 is provided, for example, in contact with the side surface of the first electrode layer 4a and the side surface of the semiconductor layer 4b.

[0152] In each cell region 2, the second electrode layer 4c is located in the entire region of both the first region 20a and the second region 20b. That is, the second electrode layer 4c is provided on the semiconductor layer 4b and the object portion 5. The object portion 5 supports the second electrode layer 4c together with the semiconductor layer 4b.

[0153] The object portion 5 may be, for example, an insulating layer 50 or a semiconductor layer having a bandgap energy different from that of the semiconductor layer 4b. Thus, since the first region 20a and the second region 20b have different colors in appearance, the design of the solar cell module 1 can be improved.

[0154] <4. Fourth Embodiment>

[0155] <4-1. Absorbing member>

[0156] In a first embodiment, if Figures 17 to 19 As shown, each cell region 2 of the solar cell module 1 may have a solar cell element 4 instead of the object portion 5. That is, the first electrode layer 4a, the semiconductor layer 4b, and the second electrode layer 4c are provided in a stacked state in the entire cell region 2.

[0157] exist Figures 17 to 19In the example of FIG. 1 , the solar cell module 1 further includes an absorption member 10. The absorption member 10 is, for example, located in the entire second region 20b, but not in the first region 20a. That is, the absorption member 10 is arranged to avoid the first region 20a. Fig.17 In the example of , the first area 20a corresponds to the design area, and the second area 20b corresponds to the background area. The absorbing member 10 is, for example, in a plate shape, and is provided with its thickness direction along the normal line of the surface 3a of the first substrate 3. The surface 3a is the surface of the first substrate 3 on the opposite side to the solar cell element 4.

[0158] The absorption member 10 is, for example, located closer to the light source than the light absorption layer of the semiconductor layer 4b. Here, as an example, the solar cell module 1 is set in a posture where the first substrate 3 faces the light source. Fig.18 and Fig.19 In the example shown in FIG. 2 , the absorbing member 10 is provided on the surface 3 a of the first substrate 3 .

[0159] The absorption member 10 absorbs light of at least a part of the wavelength range of the incident light. The wavelength range absorbed by the absorption member 10 includes a part of or the entire wavelength range of visible light. The peak value of the absorption rate of the absorption member 10 in the wavelength range may be, for example, 30% or more, 50% or more, 70% or more, or 90% or more. The absorption member 10 may be, for example, a colored transparent or opaque coating. Alternatively, the absorption member 10 may contain a pigment such as a dye or a colorant for absorbing light. Alternatively, the absorption member 10 may be a semiconductor layer that absorbs part or all of the wavelength range of visible light.

[0160] The absorbing member 10 can be formed on the surface 3a of the first substrate 3 by a film forming method such as coating, evaporation, sputtering, chemical vapor deposition, and electroplating. In addition, the absorbing member 10 can be patterned by laser and plasma etching, mechanical scribing, etc. Alternatively, the absorbing member 10 can be formed using a mask or by inkjet printing, thereby omitting removal processing such as etching and scribing.

[0161] Alternatively, the absorbing member 10 may be formed on a base material such as a transparent film. In this case, the base material may be bonded to the surface 3 a of the first substrate 3 .

[0162] In each cell region 2, the first electrode layer 4a, the semiconductor layer 4b, and the second electrode layer 4c of the solar cell element 4 may also be located in the entire cell region 2. That is, when viewed from above, the first electrode layer 4a, the semiconductor layer 4b, and the second electrode layer 4c, for example, have a rectangular shape with the +Y direction as the long side direction. The length of the first electrode layer 4a, the semiconductor layer 4b, and the second electrode layer 4c in the Y direction is, for example, substantially equal to the length of the cell region 2 in the Y direction. The first electrode layer 4a extends from one end of the cell region 2 in the -X direction into the inter-cell region 2g, and the semiconductor layer 4b and the second electrode layer 4c extend from one end of the cell region 2 in the +X direction into the inter-cell region 2g. In the inter-cell region 2g, the connection portion 6 electrically connects the first electrode layer 4a and the second electrode layer 4c. Thus, a plurality of solar cell elements 4 are connected in series with each other. The light absorption layer of the semiconductor layer 4b is, for example, a perovskite semiconductor layer. The content ratio x of Br in the light absorption layer may be, for example, 0.4 or more. In this case, the solar cell element 4 can generate electricity based on the light in the wavelength range absorbed by the absorption member 10.

[0163] Incident light such as sunlight passes through the absorption member 10 and the first substrate 3 in the second region 20b and enters the solar cell element 4. On the other hand, incident light passes through the first substrate 3 in the first region 20a and enters the solar cell element 4 without passing through the absorption member 10. Therefore, the amount of incident light that enters the semiconductor layer 4b in the first region 20a is different from the amount of incident light that enters the semiconductor layer 4b in the second region 20b. Here, because the absorption member 10 is located in the second region 20b, the amount of light in the first region 20a is greater than the amount of light in the second region 20b.

[0164] Therefore, the current density of the current generated by the solar cell element 4 in the first region 20a is greater than the current density of the current generated by the solar cell element 4 in the second region 20b. That is, in the fourth embodiment, in each unit region 2, the current densities of the plurality of regions 20 are different from each other.

[0165] In the fourth embodiment, as described above, the absorption member 10 is located in the entire second region 20b, and the absorption member 10 is not located in the first region 20a. That is, each unit region 2 has a plurality of regions 20 having different absorption rate spectra (i.e., spectral absorptivity) to incident light. For example, the color tones of the appearance of the plurality of regions 20, for example, the color tones of the appearance of the first region 20a and the second region 20b, are different from each other. Therefore, the design of the solar cell module 1 can be improved.

[0166] In the above example, among the plurality of unit regions 2, not only the first unit region 21 and the fifth unit region 25 located at both ends in the X direction, but also the second unit region 22 to the fourth unit region 24 located on the central side have the plurality of regions 20. In this way, since at least one of the unit regions 2 located on the central side has the plurality of regions 20, a design can be formed in a more conspicuous region.

[0167] like Fig.17 As shown, the width W of the unit region 2 can be different from each other. Specifically, the width W of the unit region 2 can be set so that the deviation of the carrier generation amount is reduced. In other words, the width W of each unit region 2 can be set so that the deviation of the carrier generation amount is smaller than the deviation of the carrier generation amount in a virtual structure in which a plurality of unit regions 2 have the same width. As a more specific example, the width W of the unit region 2 can be set according to formula (2).

[0168] As described above, by setting the width W of the cell region 2 , it is possible to reduce the variation in the amount of carrier generation between the plurality of cell regions 2 . Therefore, a direct current can be extracted more efficiently from the solar cell module 1 .

[0169] In addition, in the above example, the absorbing member 10 is located on the surface 3a of the first substrate 3. That is, the absorbing member 10 is not located between the first electrode layer 4a and the second electrode layer 4c of the solar cell element 4. Therefore, the direct current flowing through the solar cell element 4 does not pass through the absorbing member 10. Therefore, the absorbing member 10 does not hinder the power generation of the solar cell element 4, and it is not easy to cause a decrease in the photoelectric conversion efficiency of the solar cell module 1.

[0170] <4-1-1. First other method>

[0171] like Fig. 20 As shown, the absorption member 10 may be provided on the surface 3b of the first substrate 3. The surface 3b is a surface on the opposite side to the surface 3a of the first substrate 3. Fig. 20 In the example of FIG. 4 , the first electrode layer 4a is provided on the first substrate 3 and the absorption member 10. The absorption member 10 is in a state of being sandwiched and covered by the first substrate 3 and the first electrode layer 4a in each cell region 2, for example.

[0172] Furthermore, the absorption member 10 may be located inside the first substrate 3. For example, in the case where the first substrate 3 is formed of a plurality of insulating layers, the absorption member 10 may be located between any two of the plurality of insulating layers.

[0173] <4-1-2. Second other method>

[0174] like Fig.21As shown, the absorption member 10 can be provided on the surface 4ab of the first electrode layer 4a. The surface 4ab is the surface on the semiconductor layer 4b side of the first electrode layer 4a. Therefore, the absorption member 10 is sandwiched and covered by the first electrode layer 4a and the semiconductor layer 4b in each unit area 2.

[0175] <4-1-3. Third other method>

[0176] like Fig. 22 As shown, the absorption member 10 may be located inside the semiconductor layer 4b. Fig. 22 In the example, the semiconductor layer 4b is a semiconductor multilayer film including a plurality of semiconductor layers from the semiconductor layer 4ba to the semiconductor layer 4bd. Here, the semiconductor layer 4bd is located on the first electrode layer 4a, the semiconductor layer 4bc is located on the semiconductor layer 4bd, the semiconductor layer 4bb is located on the semiconductor layer 4bc, the semiconductor layer 4ba is located on the semiconductor layer 4bb, the second electrode layer 4c is located on the semiconductor layer 4ba, and the semiconductor layer 4bb is a light absorbing layer. The absorbing member 10 is located closer to the light source side than the semiconductor layer 4bb, that is, on the first substrate 3 side. Fig. 22 In the example of FIG. 1 , the absorption member 10 is provided on the surface of the semiconductor layer 4bd on the second electrode layer 4c side. The semiconductor layer 4bc is provided on the semiconductor layer 4bd and the absorption member 10. The absorption member 10 is sandwiched and covered by the semiconductor layer 4bc and the semiconductor layer 4bd in each cell region 2.

[0177] The number of layers in the semiconductor layer 4b can be changed as appropriate. In short, the absorption member 10 may be located closer to the light source than the light absorption layer in the semiconductor layer 4b.

[0178] <4-1-4. Fourth other method>

[0179] Next, a description will be given of a case where the solar cell module 1 is arranged with the second substrate 8 facing the light source. Fig.23 As shown, the absorption member 10 may be provided on the surface 8a of the second substrate 8. The surface 8a is a surface of the second substrate 8 on the opposite side to the filling material 7.

[0180] <4-1-5. Fifth other method>

[0181] like Fig.24 As shown, the absorbing member 10 may be provided on the surface 8b of the second substrate 8. The surface 8b is a surface on the opposite side of the surface 8a of the second substrate 8. The filling material 7 is provided in a state of being bonded to the second substrate 8 and the absorbing member 10. The absorbing member 10 is in a state of being sandwiched and covered by the second substrate 8 and the filling material 7.

[0182] In addition, the absorption member 10 may be located inside the second substrate 8. For example, in the case where the second substrate 8 is formed of a plurality of insulating layers, the absorption member 10 may also be located between any two of the plurality of insulating layers.

[0183] <4-1-6. Sixth other method>

[0184] like Fig.25 As shown, the absorbing member 10 may be provided on the surface 4ca of the second electrode layer 4c. The surface 4ca is the surface of the second electrode layer 4c on the opposite side to the semiconductor layer 4b. The filler 7 is provided in a state of being bonded to the solar cell element 4 and the absorbing member 10. The absorbing member 10 is in a state of being sandwiched and covered by the filler 7 and the second electrode layer 4c.

[0185] In the first to sixth alternative embodiments, the absorbing member 10 is located in the entire second region 20b and not in the first region 20a in a plan view. Therefore, the first region 20a and the second region 20b have different colors in appearance. Therefore, the design of the solar cell module 1 can be improved.

[0186] In addition, according to the first to third alternative forms, the fifth alternative form, and the sixth alternative form, since the absorbing member 10 is located between the first substrate 3 and the second substrate 8, the absorbing member 10 can be protected from the external space. Therefore, the design of the solar cell module 1 can be maintained for a longer period of time.

[0187] According to the first, second, fourth, and sixth alternative embodiments, the absorption member 10 is provided away from between the first electrode layer 4 a and the second electrode layer 4 c . Therefore, the direct current does not pass through the absorption member 10 .

[0188] <4-1-7. Others>

[0189] Although the absorption member 10 is located only in the second region 20b in the above example, it may be located only in the first region 20a. In this case, the design of the solar cell module 1 can be improved. In addition, when viewed from above, a plurality of types of absorption members 10 having different absorption rate spectra may be dispersed. In other words, they may be located in three or more regions 20. For example, a plurality of types of absorption members 10 having different colors in appearance may be located in a plurality of regions 20, respectively. For example, referring to Fig.10 Different absorbing members 10 may be located in the first region 20a to the fourth region 20d, respectively. Thus, the design of the solar cell module 1 can be further improved.

[0190] <4-2. Reflection member>

[0191] In a first embodiment, if Figures 17 to 19 As shown, the solar cell module 1 may include a reflective member 11. That is, the reflective member 11 may replace the position of the absorption member 10. For example, the reflective member 11 is located in the entire second area 20b, but not in the first area 20a. That is, the reflective member 11 is located at a position avoiding the first area 20a. Fig.18 and Fig.19 In the example of FIG. 1 , the reflective member 11 is provided on the surface 3 a of the first substrate 3 . The reflective member 11 is, for example, in a plate shape, and is provided in a state where the thickness direction thereof is along the normal line of the surface 3 a of the first substrate 3 .

[0192] The reflective member 11 reflects light of at least a part of the wavelength range of the incident light. The wavelength range reflected by the reflective member 11 includes part or all of the wavelength range of visible light. The peak value of the reflectivity of the reflective member 11 within the wavelength range may be, for example, more than 30%, more than 50%, more than 70%, or more than 90%. The reflective member 11 may be, for example, a metal film. Alternatively, the reflective member 11 may include a pigment or dye that reflects light. Alternatively, the reflective member 11 may be a semiconductor layer that reflects part or all of the wavelength range of visible light. In addition, the reflective member 11 may absorb part of the visible light. In this case, it can be said that the reflective member 11 is a reflective absorption member.

[0193] The reflective member 11 can be formed on the surface 3a of the first substrate 3 by a film forming method such as coating, evaporation, sputtering, chemical vapor growth method, and electroplating. In addition, the patterning of the reflective member 11 can be achieved by laser and plasma etching, mechanical scribing, etc. Alternatively, by forming the reflective member 11 using a mask or forming the reflective member 11 by inkjet printing, removal processing such as etching and scribing can be omitted.

[0194] Alternatively, the reflective member 11 may be formed on a base material such as a transparent film. In this case, the base material may be bonded to the surface 3 a of the first substrate 3 .

[0195] Incident light such as sunlight is reflected by the reflective member 11 in the second region 20b. In the case where the reflective member 11 reflects most of the incident light, the light is hardly incident on the region of the solar cell element 4 facing the second region 20b. In the case where the reflective member 11 transmits a portion of the incident light, the portion is incident on the solar cell element 4. On the other hand, the incident light is incident on the solar cell element 4 through the first substrate 3 in the first region 20a. Therefore, the amount of incident light incident on the semiconductor layer 4b in the first region 20a is different from the amount of incident light incident on the semiconductor layer 4b in the second region 20b. Here, the amount of light in the first region 20a is, for example, greater than the amount of light in the second region 20b.

[0196] Here, the solar cell element 4 can generate electricity based on the light in the wavelength range reflected by the reflective member 11. Therefore, the current density of the current generated by the solar cell element 4 in the first region 20a is greater than the current density of the current generated by the solar cell element 4 in the second region 20b. That is, in each unit region 2, the current density of the plurality of regions 20 is different from each other.

[0197] In addition, as described above, the reflective member 11 is located in the entire second region 20b, and the reflective member 11 is not located in the first region 20a. That is, each unit region 2 has a plurality of regions 20 having different reflectivity spectra (i.e., spectral reflectivity) to incident light. Therefore, the color tones of the appearance of the plurality of regions 20, for example, the color tones of the appearance of the first region 20a and the second region 20b are different from each other. Therefore, the design of the solar cell module 1 can be improved.

[0198] Furthermore, even in the structure provided with the reflective member 11, the width W of the cell region 2 is set to reduce the variation in the amount of carrier generation in the plurality of cell regions 2. Therefore, a direct current can be extracted more efficiently from the solar cell module 1.

[0199] <4-2-1. Other methods>

[0200] like Figure 20 to Figure 25 As shown, another embodiment of the position of the reflective member 11 is the same or similar to the position of the absorbent member 10. In any other embodiment, since the reflective member 11 is located in the entire second region 20b and not in the first region 20a, the first region 20a and the second region 20b can be distinguished in color tone.

[0201] Furthermore, the reflective member 11 may be located on the side opposite to the light source relative to the light absorbing layer of the solar cell element 4. However, in this structure, the amount of incident light toward the solar cell element 4 in the second region 20b increases. Fig.23 In the second region 20b, the incident light passes through the first substrate 3, the solar cell element 4, the filling material 7, and the second substrate 8, and is incident on the reflective member 11. The incident light is reflected by the reflective member 11, passes through the second substrate 8 and the filling material 7, and is incident on the solar cell element 4 again. Therefore, the amount of incident light incident on the solar cell element 4 in the second region 20b is greater than the amount of incident light incident on the solar cell element 4 in the first region 20a. Therefore, the current density in the second region 20b is greater than the current density in the first region 20a. That is, the magnitude relationship of the current density is Fig.17The magnitude relationship of the current density in the structure is opposite to that of the structure of FIG. Since the width W of the unit region 2 is set to reduce the deviation of the carrier generation amount in the plurality of unit regions 2, the magnitude relationship of the width W of the unit region 2 is opposite to that of the structure of FIG. Fig.17 The size relationship of the width W of the unit region 2 in the structure is opposite.

[0202] <4-2-2. Others>

[0203] Although in the above example, the reflective member 11 is only located in the second area 20b, it can also be located only in the first area 20a. In this case, the design of the solar cell module 1 can also be improved. In addition, when viewed from above, a plurality of types of reflective members 11 with different reflectivity spectra are dispersedly arranged. For example, a plurality of types of reflective members 11 with different colors in appearance can be respectively located in a plurality of areas 20. As a result, the design of the solar cell module 1 can be further improved.

[0204] In a plan view, the absorption member 10 and the reflection member 11 may be provided in a mixed manner. In short, the unit region 2 may include a plurality of regions 20 having at least one of an absorptivity spectrum and a reflectivity spectrum that is different from each other.

[0205] In addition, the reflective member 11 may be a component of the solar cell element 4. For example, the second electrode layer 4c may be formed of metal and function as the reflective member 11. In this case, the second electrode layer 4c may be located only in the first region 20a, for example. Therefore, the first region 20a and the second region 20b have different appearance tones. Thus, the design of the solar cell module 1 can also be improved.

[0206] The solar cell module 1 is described in detail above, but the above description is illustrative in all aspects and does not limit the solar cell module 1. It should be understood that many examples not illustrated can be conceived without departing from the scope of this disclosure. The various structures described in the above embodiments and examples can be appropriately combined or omitted as long as they do not contradict each other.

[0207] Of course, all or part of the above-mentioned embodiments can be configured in combination as appropriate and within a range that does not contradict each other.

[0208] The present invention includes the following contents.

[0209] In one embodiment, (1) a solar cell module comprises: a plurality of unit regions arranged in a plane along a first direction, each unit region comprising a solar cell element for generating electricity based on incident light; and a connecting portion arranged to electrically connect the solar cell elements of the plurality of unit regions in series. The solar cell element comprises a first electrode layer, a second electrode layer, and a semiconductor layer located between the first electrode layer and the second electrode layer. At least one of the plurality of unit regions comprises an object portion, the object portion being arranged adjacent to the semiconductor layer when viewed from above, and comprising a semiconductor or an insulator having a band gap energy different from that of the semiconductor layer.

[0210] (2) In the solar cell module of (1) above, the object portion is located between the first electrode layer and the second electrode layer in the at least one of the plurality of unit regions.

[0211] (3) In the solar cell module of (2) above, the object portion may include a semiconductor having a band gap energy different from that of the semiconductor layer.

[0212] (4) In any one of the solar cell modules described above (1) to (3), in at least one of the plurality of unit regions, the semiconductor layer includes a first semiconductor layer and a second semiconductor layer with different band gap energies, and the first semiconductor layer and the second semiconductor layer can be located at different positions when viewed from above.

[0213] (5) In any one of the solar cell modules described in (1) to (4) above, in at least one of the plurality of unit regions, the object portion can be arranged to be adjacent to the semiconductor layer at least in a second direction orthogonal to the first direction.

[0214] (6) In the solar cell module of any one of (1) to (5) above, in at least one of the plurality of unit areas, the semiconductor layer is arranged in a continuous state between the two ends of the first direction of the at least one of the plurality of unit areas, and in at least one of the plurality of unit areas, at least one of the first electrode layer and the second electrode layer can avoid the area overlapping with the above-mentioned object portion when viewed from above.

[0215] (7) The solar cell module of (6) above comprises: a first substrate on which the solar cell element is provided; a second substrate provided in a state facing the first substrate; and an insulating filler provided between the first substrate and the second substrate in a state covering the solar cell element. The second electrode layer is located on the second substrate side relative to the semiconductor layer, and in at least one of the plurality of unit regions, the second electrode layer avoids a region overlapping with the object portion when viewed from above, and the object portion may be a part of the filler.

[0216] (8) In the solar cell module of (1) or (2) above, the object portion includes an insulator, and at least one of the plurality of unit regions includes a first unit region and a second unit region, a top-view area of ​​the object portion in the first unit region is larger than an area of ​​the object portion in the second unit region, and a width of the first unit region in the first direction may be larger than a width of the second unit region in the first direction.

[0217] In another embodiment, (9) the solar cell module comprises: a plurality of unit areas arranged in a plane along a first direction, each unit area including a solar cell element that generates electricity based on incident light; a connecting portion arranged to electrically connect the solar cell elements of the plurality of unit areas in series; and a component arranged to overlap with a first area of ​​at least one of the plurality of unit areas and not overlap with a second area of ​​at least one of the plurality of unit areas when viewed from above, and to absorb light in a wavelength range of at least a portion of the incident light.

[0218] In another embodiment, (10) the solar cell module comprises: a plurality of unit areas arranged in a plane along a first direction, each unit area comprising a solar cell element for generating electricity based on incident light; a connecting portion arranged to electrically connect the solar cell elements of the plurality of unit areas in series; and a component arranged to overlap with a first area of ​​at least one of the plurality of unit areas except for the unit areas at both ends of the first direction when viewed from above, and not to overlap with a second area of ​​at least one of the plurality of unit areas, so as to reflect light of at least a portion of the wavelength range of the incident light.

[0219] (11) The solar cell module of (9) or (10) above includes a first substrate on which the solar cell element is provided, and the member can be provided on or inside the first substrate.

[0220] (12) The solar cell module of (9) or (10) above includes: a first substrate on which the solar cell element is provided; a second substrate provided to face the first substrate; and a filling material provided between the first substrate and the second substrate to cover the solar cell element. The member can be provided on or inside the second substrate.

[0221] (13) In the solar cell module of (9) or (10) above, the member can be provided on or inside the solar cell element.

[0222] (14) In the solar cell module of (1), (2), (9) or (10) above, the width of the first direction of the plurality of unit regions is set so that the deviation in the amount of carrier generation per unit time in the plurality of unit regions is smaller than the deviation in a hypothetical structure in which the widths of the plurality of unit regions are equal to each other.

[0223] Description of Reference Numerals

[0224] 1Solar cell module

[0225] 2. Units 21 to 25

[0226] 21First unit area (unit area)

[0227] 22 Second unit area (unit area)

[0228] 3. First substrate

[0229] 4. 41~45 solar cell elements

[0230] 4a First electrode layer

[0231] 4b Semiconductor layer

[0232] 4b1 first semiconductor layer (semiconductor layer)

[0233] 4b2 Second semiconductor layer (semiconductor layer)

[0234] 4c Second electrode layer

[0235] 5 Objects

[0236] 50 insulation layer

[0237] 6. 61-64 connection

[0238] 7 Filling Materials

[0239] 8 Second substrate

[0240] 10 components (absorption components)

[0241] 11 Components (Reflection Components)

Claims

1. A solar cell module comprising: A plurality of unit regions are arranged in a plane along a first direction, and each unit region includes a solar cell element that generates electricity based on incident light; as well as a connecting portion provided to electrically connect the solar cell elements of the plurality of unit regions in series, The solar cell element comprises: a first electrode layer; a second electrode layer; and a semiconductor layer, located between the first electrode layer and the second electrode layer, At least one of the plurality of unit regions comprises: The object portion is provided adjacent to the semiconductor layer in a plan view and includes a semiconductor or an insulator having a band gap energy different from that of the semiconductor layer.

2. The solar cell module according to claim 1, wherein: In the at least one of the plurality of unit regions, the object portion is located between the first electrode layer and the second electrode layer.

3. The solar cell module according to claim 2, wherein: The object portion includes a semiconductor having a band gap energy different from that of the semiconductor layer.

4. The solar cell module according to any one of claims 1 to 3, wherein: In the at least one of the plurality of unit regions, the semiconductor layer includes a first semiconductor layer and a second semiconductor layer having band gap energies different from each other, The first semiconductor layer and the second semiconductor layer are located at different positions from each other in a plan view.

5. The solar cell module according to any one of claims 1 to 4, wherein: In the at least one of the plurality of unit regions, the object portion is provided adjacent to the semiconductor layer at least in a second direction orthogonal to the first direction.

6. The solar cell module according to any one of claims 1 to 5, wherein: In the at least one of the plurality of unit regions, the semiconductor layer is provided in a state of being continuous between both ends of the at least one of the plurality of unit regions in the first direction. In the at least one of the plurality of unit regions, at least one of the first electrode layer and the second electrode layer avoids a region overlapping with the object portion in a plan view.

7. The solar cell module according to claim 6, wherein: have: A first substrate, provided with the solar cell element; a second substrate disposed to face the first substrate; and An insulating filling material is provided between the first substrate and the second substrate so as to cover the solar cell element. The second electrode layer is located on the second substrate side relative to the semiconductor layer. In the at least one of the plurality of unit regions, the second electrode layer avoids a region overlapping the object portion when viewed from above. The object portion is a portion of the filling material.

8. The solar cell module according to claim 1 or 2, wherein: The object portion includes an insulator, The at least one of the plurality of unit regions includes a first unit region and a second unit region, The area of ​​the object portion in the first unit region when viewed from above is larger than the area of ​​the object portion in the second unit region, The width of the first unit region in the first direction is greater than the width of the second unit region in the first direction.

9. A solar cell module comprising: A plurality of unit regions are arranged in a plane along a first direction, and each unit region includes a solar cell element that generates electricity based on incident light; a connecting portion provided to electrically connect the solar cell elements of the plurality of unit regions in series; and The component is arranged to overlap with a first region of at least one of the plurality of unit regions and not overlap with a second region of at least one of the plurality of unit regions when viewed from above, and absorbs light in at least a portion of a wavelength range of the incident light.

10. A solar cell module comprising: A plurality of unit regions are arranged in a plane along a first direction, and each unit region includes a solar cell element that generates electricity based on incident light; a connecting portion provided to electrically connect the solar cell elements of the plurality of unit regions in series; and The component is arranged in a state where it overlaps with a first area in at least one of the plurality of unit areas except the unit areas located at both ends of the first direction when viewed from above, and does not overlap with a second area in at least one of the plurality of unit areas, so as to reflect light in at least a portion of the wavelength range of the incident light.

11. The solar cell module according to claim 9 or 10, wherein: A first substrate provided with the solar cell element is provided. The component is disposed on or inside the first substrate.

12. The solar cell module according to claim 9 or 10, wherein: have: A first substrate having the solar cell element provided thereon; A second substrate is disposed facing the first substrate; as well as A filling material is provided between the first substrate and the second substrate so as to cover the solar cell element. The component is disposed on or inside the second substrate.

13. The solar cell module according to claim 9 or 10, wherein: The member is disposed on or inside the solar cell element.

14. The solar cell module according to claim 1, 2, 9 or 10, wherein: The widths of the plurality of cell regions in the first direction are set so that a variation in the amount of carriers generated per unit time in the plurality of cell regions is smaller than the variation in a hypothetical structure in which the widths of the plurality of cell regions are equal to each other.

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