Fragrance with cyclopropyl structure

Abstract

A cyclopropyl derivative of formula (I) R1-R2 (I) wherein R1 represents a cyclopropyl group or a C1-C6-alkyl cyclopropyl residue; r2 represents a-CO-R3 group or a-(CH2) n-R4 group; r3 represents a linear chain or branched chain C1-C6 alkyl group; r4 represents-CH2OH or-CH = O; and n represents an integer between 1 and 12. The derivatives have the characteristics that the odors are very strong, but the odors are also greatly different, and specifically depend on the structures of the derivatives.

Description

Field of the Invention

[0001] This invention relates to the field of fragrances and perfumes, and to novel fragrances having a cyclopropyl structure. Background Art

[0002] In the perfume industry, there is always a need for new fragrance creations. However, the creation of new fragrances or fragrance compositions involves many challenges. For example, it is necessary to select specific combinations of several fragrances from the virtually infinite number of possible structures known in the prior art to meet specific market demands and provide products that match the specific characteristics required by customers. Suitable fragrances may exhibit very beneficial properties, but when combined with other fragrances, they may produce unpleasant and therefore harmful odors, making them difficult or even impossible to use for a specific purpose.

[0003] The second important issue concerns the need for fragrance compositions that not only correspond to a specific odor characteristic but also possess so-called secondary beneficial properties. Indeed, many known fragrance compositions on the market have significant drawbacks in use, such as poor solubility and storage stability, and are also deficient in subjective aspects such as intensity and appeal. Furthermore, many known fragrance compositions require high doses to achieve the desired odor effect. Another requirement for fragrances today is high biodegradability and dermatological and toxicological safety. Therefore, there is a particular need to provide fragrances that can significantly influence other fragrances even at low doses, transforming rather unpleasant odor impressions into positive ones and / or enhancing pleasant ones. Related existing technologies

[0004] Some cyclopropyl derivatives are known as fragrances, for example:

[0005] US2008103085 AA (GIVAUDAN) relates to 5-(2,2-dimethyl-cyclopropyl)-3-methyl-pent-2-enonitrile and its use in fragrance or flavor applications.

[0006] US20111124924 AA (GIVAUDAN) discloses a method for preparing cyclopropylmethanol by cyclopropanation of an unsaturated alcohol, using a reagent system selected from (A) magnesium metal and dibromomethane, and (B) dibromomethane and a tertiary Grignard reagent, wherein the reaction is carried out in the presence of an ether solvent. The product can be used as a fragrance and flavoring.

[0007] US 6,025,527 B(IFF) relates to trimethylcyclohexenylcyclopropyl ketone having a structure in which one dashed line is a carbon-carbon double bond and the other dashed line is a carbon-carbon single bond, for use in adding, enhancing or imparting aroma or for adding fragrance to compositions, colognes and scented products, and mixtures thereof with acetates or propionates of 3-methyl-1-phenylpentanol-5 and / or butyrylcyclohexane derivatives and / or o-methylphenylisopropanol.

[0008] US 5,767,305 A and US 7,074,967 BA (IFF) disclose cyclopropyl carboxylate and 3-cyclopropyl-1-propanone compounds as fragrances.

[0009] CN 101503345 A (SHANGHAI INST TECHNOLOGY) discloses 2-(2-ethylcyclopropyl)aldehyde and its preparation method. Purpose of the invention

[0010] Therefore, the fundamental problem of this invention is to provide a new group of fragrances that have the added ability to enhance the positive and beneficial aroma aspects of other fragrances. In particular, the new fragrances should also have the characteristics of improving the stability, solubility, and overall properties of other fragrances, as well as reducing the amount required. Furthermore, the new fragrances should be renewable and stable. Finally, the fragrance composition itself should have excellent biodegradability and be harmless to humans and the environment. Summary of the Invention

[0011] The first object of the present invention relates to cyclopropyl derivatives of formula (I). R 1 -R 2 (I) in -R 1 Represents a cyclopropyl or C1-C6-alkylcyclopropyl residue; -R 2 Representative - CO-R 3 or -(CH2) n -R 4 Group; -R 3 Represents straight-chain or branched C1-C6 alkyl groups; -R 4 Represents -CH2OH or -CH=O; and -n represents an integer between 1 and 12.

[0012] Surprisingly, the cyclopropyl derivatives according to the invention exhibit very strong aromas, such as minty, fresh, nutty, and green notes, despite significant structural differences. The derivatives of Formula I have been found to be useful for imparting, altering, and / or enhancing flavor compositions, particularly the positive aspects, to make them more rounded, natural, richer, crisper, fresher, stronger, and / or more fruity. In addition to their primary olfactory properties, the derivatives of Formula I also possess additional positive secondary properties, particularly high affinity compared to flavorings with similar olfactory properties, as well as high stability and spreadability in certain media and formulations, and are also biodegradable. Furthermore, the novel cyclopropyl derivatives have been found to be useful for enhancing the strength of flavor mixtures. Therefore, the compounds described herein can be used to impart roundness, naturalness, richness, crispness, freshness, strength, and / or fruitiness to flavor compositions. Cyclopropyl derivatives

[0013] The preferred derivatives according to the present invention are cyclopropyl or methylcyclopropyl derivatives.

[0014] In a first alternative, the cyclopropyl derivative according to the invention can be obtained by cyclopropanation of various olefinic structures, known as the Johnson-Corey-Chaykovsky reaction. This reaction involves the addition of a thioyl ylide to a ketone, aldehyde, imine, or enone to generate the corresponding three-membered ring. This reaction is diastereoselective, regardless of how favorable the initial stereochemistry may be to trans substitution in the product, as shown in the following general scheme:

[0015] The reaction is explained in more detail in the commentary by Aggarwal et al., “The complexity of catalysis: origins of enantio-and diastere-ocontrol in sulfur ylide mediated epoxidation reactions”, Chemical Communications (21, pp. 2644–2651 (2003).

[0016] According to the second alternative, the derivative can also be obtained via the Simmons-Smith reaction, an organic chelation reaction involving an organozinc carbene that reacts with an alkene (or alkyne) to form a cyclopropane. It utilizes a methylene radical intermediate, which is simultaneously transferred to both carbons of the alkene, thus preserving the configuration of the double bond in the product, and the reaction is stereospecific. The process is illustrated by the following scheme:

[0017] The Simmons–Smith reaction is generally superior to other cyclopropaneation methods; however, it can be expensive due to the high cost of diiodomethane. Improvements have been developed involving cheaper alternatives, such as dibromomethane or diazomethane and zinc iodide. The reactivity of the system can also be improved by replacing the zinc-copper pair with diethylzinc through Furukawa modification. The reaction is explained in more detail in Simmons et al.'s article "A new synthesis of cyclopropanes from olefins," JACS 80(19), pp. 5323-5324 (1958) and Smith et al.'s article "A new synthesis of cyclopropanes," JACS 81(16), pp. 4256-4264 (1959).

[0018] Preferred types include derivatives of formula (I), wherein (a)R 2 Representative - CO-R 3 And R 3 Represents a straight-chain or branched alkyl group having 3 or 4 carbon atoms—preferably obtained according to the Johnson-Corey-Chaykovsky reaction—or (b)R 2 Representative – (CH2) n -R 4 R 4 Represents -CH=O and n represents an integer from 8 to 10 - preferably obtained according to the Simmons-Smith reaction.

[0019] Particularly preferred are cyclopropyl derivatives or mixtures thereof according to formula (II), (III) or (IV). Manufacturing method

[0020] Another object of the present invention relates to a first method for obtaining a cyclopropyl derivative of formula (I). R 1 -R 2 (I) in -R 1 Represents a cyclopropyl or C1-C6-alkylcyclopropyl residue; -R 2 Representative - CO-R 3 groups; and -R 3 Represents straight-chain or branched C1-C6 alkyl groups; via the Johnson–Corey–Chaykovsky reaction, wherein the enone according to formula (V) CH3-CH=CH-R 2 (V) where R 2 With the above meaning, in the presence of Me3S - Hal + Cyclopropanization is carried out in the presence of a thioyl ylide, where Hal represents bromine, chlorine, or preferably iodine. The method is preferably carried out in the presence of DMSO and sodium hydride, forming a dimsyl anion (“dimsyl anion”), which acts as a strong nucleophile. The reaction can be carried out with or without an aprotic solvent. However, preferred solvents are DCM or chloroform.

[0021] Another object of the present invention relates to a second method for obtaining the cyclopropyl derivative of formula (I). R 1 -R 2 (I) in -R 1 Represents a cyclopropyl or C1-C6-alkylcyclopropyl residue; -R 2 Representative – (CH2) n -R 4 Group; -R 4 Represents -CH2OH or -CH=O; and -n represents an integer between 1 and 12. The reaction is carried out via the Simmons-Smith reaction, where (a) in the first step, ω-unsaturated fatty alcohols are reacted according to formula (VI). CH2=CH-(CH2) n -CH2OH Wherein n has the above meaning, cyclopropanation is carried out in the presence of an organozinc carbene having a Hal-ZnCH2-Hal structure, and where Hal represents bromine, chlorine or preferably iodine, and optionally the hydroxyl group of the reaction product obtained in step (i) is oxidized to form an aldehyde group.

[0022] The carbene typically obtained by reacting zinc with dihalomethanes such as CH₂I₂. This reaction can be carried out with or without an aprotic solvent. However, preferred solvents are DCM or chloroform. The oxidation of the terminal hydroxyl group to form an aldehyde functional group can be accomplished by any suitable oxidizing agent. However, a particularly preferred method is the Des-Martin oxidation using a Des-Martin oxidizing agent, as shown in the following scheme:

[0023] This reaction uses a high-valent iodine reagent, similar to IBX, to selectively and gently oxidize alcohols to aldehydes or ketones. The reaction is typically carried out in chlorinated solvents such as dichloromethane or chloroform. The reaction can proceed at room temperature and is completed rapidly. Many other functional groups are unaffected by this reaction. spice mixture

[0024] Another object of the present invention relates to a fragrance mixture comprising a cyclopropyl derivative as defined above as a primary fragrance and at least one secondary fragrance different from the primary fragrance. The secondary fragrance may be selected from the group comprising: ·[(3,7-dimethyl-6-octenyl)-oxy]-acetaldehyde, ·1-(p-menthene-6(2)-yl)-1-propanone, ·1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, ·10-Undecene-1-aldehyde, ·10-Undecen-1-ol, ·1-Decanal, ·1-Dodecanal, ·1-Methyl-3-(4-methylpentyl)-3-cyclohexene-formaldehyde, ·1-Methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde, ·1-Nonal, ·1-Octanal, ·1-Octen-3-ol, ·1-p-menthene-q-formaldehyde, ·1-Undecaldehyde, ·2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)-cyclopentanone, ·2,4,4,7-Tetramethyl-oct-6-en-3-one, ·2,4,6-Trimethyl-3-cyclohexene-1-carboxaldehyde, ·2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde ·4-Methoxybenzaldehyde, ·2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde, ·2,6,10-Trimethyl-5,9-Undecanedienal, ·2,6,10-Trimethyl-9-undecenal,3-Dodecen-1-al, ·2,6-Dimethyl-5-heptenal; ·2,6-Dimethylhept-5-en-1-al, ·2,6-Dimethylhept-2-ol, ·2,6-Nonadienal, ·2-Acetyl-3,3-dimethylnorbornene, ·2-Methyldecaldehyde, ·2-Methyloctaldehyde, ·2-Methylundecaldehyde, ·2-Methyl-3-(4-tert-butyl)propionaldehyde, ·2-Methyl-3-(isopropyl-phenyl)propanal, ·2-Methyl-3-(p-methoxy-phenylpropanal), ·2-Methyl-3-phenyl-2-propen-1-aldehyde, ·2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal, ·2-Methylbutanol, ·2-Methylpentanol, ·2-Phenoxyethanol, ·2-Phenylacet-1-aldehyde, ·2-Phenylacetol, ·2-tert-butylcyclohexanol, ·3-(3,4-methylenedioxy-phenyl)-2-methylprop-1-aldehyde, ·3-(3-isopropylphenyl)-but-1-aldehyde, ·3-(4-ethylphenyl)-2,2-dimethylprop-1-aldehyde, ·3-(4-Ethylphenyl)-2,2-Dimethylpropanal, ·3-(4-isopropylphenyl)-2-methylprop-1-aldehyde, ·3-(4-methoxyphenyl)-2-methylpropanal, ·3-(4-tert-butylphenyl)-2-methylpropionaldehyde, ·3-(4-tert-butylphenyl)-propanal, ·3,4-Dimethoxybenzaldehyde, ·3,4-Methylenedioxybenzaldehyde, ·3,5,5-Trimethylcyclohexanol, ·3,5,5-Trimethylhexanal, ·3,5,6-Trimethyl-3-cyclohexenecarbaldehyde, ·3,7-Dimethyl-2-methylene-6-octenal, ·3,7-Dimethyl-6-octen-1-al, ·3,7-Dimethyloctyl-1-aldehyde, ·3-Ethoxy-4-hydroxybenzaldehyde, ·3-Hexanol, ·3-Methoxy-4-hydroxy-benzaldehyde, ·3-Methyl-5-phenyl-1-pentanal, ·3-Methyl-5-phenylpentanol, ·3-Octanol, ·3-Phenylacetyl-2-hexylprop-2-enal, ·3-Phenylacetyl-2-pentylprop-2-en-1-al, ·3-Phenylon-2-Acrolein, ·3-Phenylacet-2-en-1-aldehyde, ·3-Phenylacetol, ·3-propyl-bicyclo[2.2.1]-hept-5-ene-2-carboxaldehyde, ·4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone, ·4-(3)(4-methyl-3-pentenyl)-3-cyclohexene-formaldehyde, ·4-(4-hydroxy-3-methoxyphenyl)-2-butanone, ·4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-l-carboxaldehyde, ·4-(tricyclo[5.2.1.0(2,6)]-decylidene-8)-butyraldehyde; ·4-Dihydrodamascol ·4-Hepenool, ·4-Hydroxy-3-methoxybenzaldehyde, ·4-Isopropylbenzaldehyde, ·4-Isopropylcyclohexanol, ·4-Methoxybenzaldehyde, ·4-Methylphenylacetaldehyde, ·4-tert-butylcyclohexanol, ·5,9-Dimethyl-4,8-decadienal, ·5-Methoxyhexahydro-4,7-methyleneinden-1-carboxaldehyde, ·5-Methoxyhexahydro-4,7-methyleneinden-2-carboxaldehyde, ·6,10-Dimethyl-3-oxa-5,9-undecadien-1-aldehyde, ·6,6-Dimethylbicyclo[3.3.1]hept-2-en-2-propanal, ·6,7-Dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, ·6,8-Dimethyl-2-nonanol, 6-nonen-1-ol, ·6-Isopropyl-decahydro-2-naphtone ·6-Methoxyhexahydro-4,7-methyleneindan-1-carboxaldehyde, ·6-Methoxyhexahydro-4,7-methyleneindan-2-carboxaldehyde, ·7-Hydroxy-3,7-Dimethyloctaldehyde, ·7-Methoxy-3,7-Dimethyloctyl-1-aldehyde, ·9-Decen-1-ol, ·9-Decenoal, ·Acetophenone, ·Adornal, Allyl cyclohexylpropionate, α-Ionone Ambroxol, Amyl salicylate, ·Fennel seeds, ·Anisaldehyde, Benzaldehyde, ·Benzyl ketone, ·Benzyl acetate, ·Benzylacetone, ·Benzyl alcohol, ·Benzyl salicylate, ·Benzyl ethyl ether, ·Borghexaldehyde, ·buccoxime Butyl salicylate, Camphor, ·Concoral, • Carvone Piperylacetone (cassione) · Celery cetone ·chlorhydral, Cinnamyl alcohol, ·cis- / trans-3,7-dimethyl-2,6-octadien-1-al, ·cis-jasmone, • Citral or mixtures thereof, Citronellol Citronellol Citronelloloxyacetaldehyde, · Cuminaldehyde, Cyclamen aldehyde, Cyclohexyl salicylate, • Cymalaldehyde (rabbit ear grass) ·Damarose · Damascenone ·Decanol, ·Decanal, ·2-Pentylcyclopentanone (delphone) Dihydrojasmone, Dihydromyrcene alcohol, Dihydrocinnamaldehyde, Dihydro-β-ionone, Dimethylbenzyl alcohol, Dimethyl benzyl acetate, Dimethylheptanol, Dimethyl octyl alcohol, Dimethyloctenone, ·dulcinyl Ethyl salicylate, Ethyl vanillin, · Ethyl methylphenylglycine, Eugenol, ·Flavone, ·2-Heptylcyclopentanone (fleuramone) Floralozon ·floramat, ·florhydral ·gelsone, Geraniol Methyl dihydrojasmonic acid, New jasmine aldehyde, Piperaldehyde, Heptanol, Hexahydro-4,7-methyleneindan-1-carboxaldehyde, Hexahydro-8,8-dimethyl-2-naphthaldehyde, Hexalone Hexyl salicylate, ·Hydroxycitronellal, ·Isoborneol, Isothione, Isoeugenol, Isomosperidone, Isopleurol, ·jasmacyclatat, ·koavon, ·Lauraldehyde, Privet aldehyde, Citral ·Lily aldehyde, ·Limonene, Linalool, Linaloyl acetate, ·livescon, New lily aldehyde, • Cymen-7-formaldehyde, ·Melonaldehyde, ·melusat, Menthol Menthone, · Methyl acetophenone, ·Methyl cypressene, ·Methyl cypressone, ·Methyl cypressone, ·Methylcyclolimonone, Methyl dihydrojasmonic acid, ·Methylheptenone, ·Methyl lavenderone, Methyl dihydrojasmonic acid, ·Methylnonylacetaldehyde, ·Methyl-β-naphthone, ·Muscine indole Muskone, Myrtol, • Dodecylaldehyde, Neobutenone, ·Neroliol, • hexanol, Nonyl alcohol, • Undecaldehyde, • Octahydro-4,7-methylene-1H-indenealdehyde; Octal, Octyl alcohol, o-Methoxycinnamon, orivone, • p-Ethyl-α,α-dimethylhydrocinnamaldehyde, ·phenol, ·Phenoxyacetaldehyde; ·Phenoxy isobutyrate, ·Phenylacetaldehyde, ·Phenyl salicylate, ·Phenylacetyl acetate, ·Phenylacetyl alcohol, p-Hydroxyphenylbutanone, ·pinene · plicatone, • 7-Menthol, p-Methoxyacetophenone, p-Methylphenoxyacetaldehyde, ·P-tert.-bucinal, p-tert-butylcyclohexanone, • p-tert-butyl cyclohexylacetate, p-Tolylacetaldehyde; ·Styrax propionate, Tetrahydrogeraniol, Tetrahydrolinalool, ·tetrameran ·thymol, • Tonalid (musk) trans-2-cis-6-nonadienol, trans-2-nonen-1-ol, trans-2-octenol, trans-4-decenal, Privet aldehyde, ·Undecaldehyde, Undecyl alcohol, Undecenal, Vanillin, Vanulone, ·2-tert-butylhexanoate (verdone) ·α-Methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde, α-Damaconone, α-Methylbenzyl alcohol, α-Methyl-4-(l-methylethyl)phenylacetaldehyde, α-Methylphenylacetaldehyde, α-n-Pentylcinnamaldehyde, ·α-hexylcinnamaldehyde, α-Terpineol, β-Damastin, β-ionone, β-terpineol, γ-methylionone, ·δ-Damaconone,

[0025] The flavoring mixture may contain at least one cyclopropyl derivative according to the invention and the minor flavoring, in a weight range of about 0.01:99.99 to about 10:90, preferably about 0.1:99.9 to 1:99. solvent

[0026] In a preferred embodiment, the mixture according to the invention may contain at least one solvent. Suitable solvents are selected from the group consisting of water, ethanol, propylene glycol, dipropylene glycol, glycerol, and triethyl citrate. Typically, the content of the at least one solvent in the mixture ranges from about 10 to about 90% by weight, preferably from about 25% to about 50% by weight. Cosmetic and personal care compositions

[0027] Another object of the present invention relates to cosmetic or personal care formulations comprising the aforementioned cyclopropyl derivative or the fragrance mixture. The formulation may contain the ingredient in the range of about 0.01 to about 2% by weight, preferably about 0.1 to 1% by weight, based on formulation calculations. The composition may represent, for example, cosmetic creams, lotions, sprays, emulsions, ointments, gels, or mousses.

[0028] The formulations according to the present invention may include anti-dandruff agents, anti-irritant agents, irritant inhibitors, antioxidants, astringents, antiperspirants, bactericides, antistatic agents, adhesives, buffers, carriers, chelating agents, cell stimulants, cleansing agents, conditioning agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, color-fixing agents, foam-forming agents, foam stabilizers, defoamers, foam promoters, gelling agents, gelling agents, hair conditioning agents, hair styling agents, hair straighteners, humectants, wetting agents, moisturizers, bleaching agents, strengthening agents, stain repellents, optical brighteners, impregnating agents, stain repellents, friction reducers, lubricants, moisturizing creams, ointments, sunscreens, plasticizers, covering agents, polishing agents, gloss agents, polymers, powders, proteins, and re-oiling agents. Agents, abrasives, silicones, hair growth agents, coolants, skin coolants, warming agents, skin warming agents, stabilizers, ultraviolet absorbers, UV filters, detergents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, α-hydroxy acids, polyhydroxy fatty acids, liquefying agents, dyes, color protectants, pigments, aromatic substances, polyols, surfactants, electrolytes, organic solvents or silicone derivatives, etc., are used as additional additives and auxiliaries. surfactants

[0029] Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Suitable examples are mentioned in the paragraphs relating to emulsifiers.

[0030] Typical examples of anionic and amphoteric surfactants include: amygdalinamide propylamine oxide, amygdalinamide propyl betaine, aminopropyl lauryl glutamine, C12-15 alkanol sulfate ammonium, C12-16 alkanol sulfate ammonium, octanol polyether sulfate ammonium, glyceryl monocolate sulfate ammonium, cocoyl alcohol sulfate ammonium, cocoyl hydroxyethanesulfonate ammonium, cocoyl sarcosine ammonium, C12-15 alkanol polyether sulfate ammonium, C9-10 perfluoroalkyl sulfonate ammonium, dinonyl sulfosuccinate ammonium, dodecylbenzene sulfonate ammonium, isostearate ammonium, lauryl ether-6 carboxylate ammonium, lauryl ether-8 carboxylate ammonium, lauryl ether sulfate ammonium, lauryl ether-5 sulfate ammonium, lauryl ether-7 sulfate ammonium, lauryl ether-9 sulfate ammonium, etc. Ammonium laurate ether-12 sulfate, ammonium lauroyl sarcosine, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl ether sulfate, ammonium myristyl sulfate, ammonium nonylphenol polyether-4 sulfate, ammonium nonylphenol polyether-30 sulfate, ammonium oleate, ammonium palm kernel oil sulfate, ammonium stearate, ammonium tallowate, isostearyl hydrolyzed collagen AMPD salt, rosin (acyl) hydrolyzed collagen AMPD salt, isostearyl hydrolyzed collagen AMP salt, isostearyl hydrolyzed keratin AMP salt, isostearyl hydrolyzed soybean protein AMP salt, isostearyl hydrolyzed wheat protein AMP salt, apricot oleamidopropyl betaine, arachidic acid, hexyldecyl phosphate arginine salt, avocado oleamidopropyl betaine, avocado oil glyceryl polyether-8 ester, babassu Seed oil acid, babassu oleamide propylamine oxide, babassu oleamide propyl betaine, beeswax acid, behenamidopropyl betaine, behenamine oxide, behenyl alcohol polyether-25, behenyl alcohol polyether-30, behenic acid, behenyl betaine, bis-butyldimethylsiloxane polyglycerol-3, butylphenol polyether-5 carboxylic acid, butylphenol polyether-19 carboxylic acid, butyl dimethyl (hydroxypropyl butyl glucoside) ammonium chloride, butyl dimethyl (hydroxypropyl lauryl glucoside) ammonium chloride, butyl glucoside, butyl glucoside decanoate, butyl glucoside hydroxypropyl trimethyl ammonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C 9-16 alkyl / cycloalkanes, C10-14 alkylbenzene sulfonic acid, C12-14 alkyl di(aminoethyl)glycine HCl, C9-15 alcohol phosphate esters, Candida albicans / glucose / rapeseed oil methyl ester fermentation products, low erucic acid rapeseed oil amamidopropyl betaine, decanoic acid, hexanoic acid, hexanoyl ethyl glucoside, octanoyl / decanoyl aminopropyl betaine, octanoyl polyether-4 carboxylic acid, octanoyl polyether-6 carboxylic acid, octanoyl polyether-9 carboxylic acid, octanoic acid, octanoyl collagen amino acids, octanoyl glycine, octanoyl hydrolyzed collagen, octanoyl hydrolyzed keratin, octanoyl keratin amino acids, octanoyl silk amino acids, octyl / decyl glucoside, octyl / decyl wheat bran / straw glycosides, octyl glucoside, octyl glyceryl ether, octylpyrrolidone, carnitine, cetearyl alcohol polyether-20.Cetearyl alcohol polyether-23, Cetearyl alcohol polyether-24, Cetearyl alcohol polyether-25, Cetearyl alcohol polyether-27, Cetearyl alcohol polyether-28, Cetearyl alcohol polyether-29, Cetearyl alcohol polyether-30, Cetearyl alcohol polyether-33, Cetearyl alcohol polyether-34, Cetearyl alcohol polyether-40, Cetearyl alcohol polyether-50, Cetearyl alcohol polyether-55, Cetearyl alcohol polyether-60, Cetearyl alcohol polyether-80, Cetearyl alcohol polyether-100, Cetearyl alcohol polyether-25 carboxylic acid, Cetearyl alcohol polyether-2 phosphate, Cetearyl alcohol polyether-4 phosphorus Cetearyl ester, cetearyl alcohol polyether-5 phosphate, cetearyl alcohol polyether-10 phosphate, cetearyl alcohol polyether-20, cetearyl alcohol polyether-23, cetearyl alcohol polyether-24, cetearyl alcohol polyether-25, cetearyl alcohol polyether-30, cetearyl alcohol polyether-40, cetearyl alcohol polyether-45, cetearyl alcohol polyether-150, cetearyl alcohol polyether-8 phosphate, cetearyl alcohol polyether-10 phosphate, cetearyl alcohol polyether-20 phosphate, cetearyl oil alcohol polyether-22, cetearyl oil alcohol polyether-24, cetearyl oil alcohol polyether-25, cetearyl oil alcohol polyether-30, cetyl betaine, Chrysanthemum Sinense flower extract, C12-14 hydroxyalkyl hydroxyethyl β-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropylamine oxide, cocamidopropyl betaine amide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysulfonate betaine, cocamidoamine oxide, cocoaminobutyric acid, cocoaminopropionic acid, cocoyl alcohol polyether-7 carboxylic acid, cocoyl alcohol polyether-4 glucoside, cocoamphopropionic acid, cocoyl betaine amamide amphoteric propionate, cocoyl betaine, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed rice protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed soybean protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, cocoyl glucoside, cocoyl glucoside hydroxypropyl trimethylammonium chloride, cocoyl hydroxysulfonate betaine, cocoyl morpholine oxide, coconut acid, coconut oil glyceryl polyether-8 Esters, cocamidopropyl betaine, cocoyl-sulfobetaine, (coconut oil / sunflower oil) amamidopropyl betaine, cocoylcholine methyl sulfate, cocoyl glutamate, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soybean protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn oleic acid, cotton Cottonseed oil acid, cottonseed oil glycerol polyether-8 esters, C10-16 alkanol polyether-1, C10-16 alkanol polyether-2, C11-13 alkanol polyether-6, C11-13 alkanol polyether-9, C11-13 alkanol polyether-10, C11-15 alkanol polyether-30, C11-15 alkanol polyether-40, C12-13 alkanol polyether-1, C12-13 alkanol polyether-23C12-14 Alkyl Polyether-5, C12-14 Alkyl Polyether-9, C13-15 Alkyl Polyether-21, C14-15 Alkyl Polyether-8, C20-22 Alkyl Polyether-30, C20-40 Alkyl Polyether-40, C20-40 Alkyl Polyether-95, C22-24 Alkyl Polyether-33, C30-50 Alkyl Polyether-40, C9-11 Alkyl Polyether-6 Carboxylic Acid, C9-11 Alkyl Polyether-8 Carboxylic Acid, C11-15 Alkyl Polyether-7 Carboxylic acids, C12-13 alkanol polyether-5 carboxylic acid, C12-13 alkanol polyether-7 carboxylic acid, C12-13 alkanol polyether-8 carboxylic acid, C12-13 alkanol polyether-12 carboxylic acid, C12-15 alkanol polyether-7 carboxylic acid, C12-15 alkanol polyether-8 carboxylic acid, C12-15 alkanol polyether-12 carboxylic acid, C14-15 alkanol polyether-8 carboxylic acid, C6-10 alkanol polyether-4 phosphate, C12-13 alkanol polyether-2 phosphate, C12-13 alkanol C12-15 Alkyl Polyether-6 Phosphate, C12-15 Alkyl Polyether-8 Phosphate, C12-15 Alkyl Polyether-10 Phosphate, C12-16 Alkyl Polyether-6 Phosphate, C4-18 Perfluoroalkyl Ethyl Mercaptopropyl Trimethylammonium Chloride, Cocoa Fatty Acid Aminopropyl Betaine, C12-13 Alcohol Sulfate DEA Salt, C12-15 Alcohol Sulfate DEA Salt, Cetearyl Alcohol Polyether-2 Phosphate DEA Salt, Cetyl Alcohol Sulfate DEA Salt, Cocoyl Amphoteric dipropionic acid DEA salt, C12-13 alkanol polyether-3 sulfate DEA salt, cyclocarboxypropyl oleic acid DEA salt, dodecylbenzene sulfonic acid DEA salt, isostearic acid DEA salt, lauryl ether sulfate DEA salt, lauryl sulfate DEA salt, linoleic acid DEA salt, methyl myristate sulfonic acid DEA salt, myristyl ether sulfate DEA salt, myristic acid DEA salt, myristyl sulfate DEA salt, oleyl alcohol polyether-5 phosphate DEA salt, oleyl alcohol polyether-20 phosphate DEA salt, DEA PG-Oleate, Decanol Polyether-7 Carboxylic Acid, Decanol Polyether-7 Glucoside, Decanol Polyether-9 Phosphate, Decylamine Oxide, Decyl Betaine, Decyl Glucoside, Decyl Tetradecyl Alcohol Polyether-30, Decyl Tetradecylamine Oxide, Laurylamide-MEA Sulfosuccinate Diammonium, Lauryl Sulfosuccinate Diammonium, Oleamide-based PEG-2 Sulfosuccinate Diammonium, Dibutoxymethane, DiC12-15 Alkyl Alcohol Polyether-2 Phosphate, Di C12-15 alkanol polyether-4 phosphate, diC12-15 alkanol polyether-6 phosphate, diC12-15 alkanol polyether-8 phosphate, diC12-15 alkanol polyether-10 phosphate, disodium dodecyl butane tetracarboxylate, diethylamine lauryl ether sulfate, sodium diethylhexyl sulfosuccinate, di(hydroxyethyl)C8-10 alkoxypropylamine oxide, di(hydroxyethyl)C9-11 alkoxypropylamine oxideDi(hydroxyethyl)C12-15 alkoxypropylamine oxide, Di(hydroxyethyl)cocoamine oxide, Di(hydroxyethyl)laurylamine oxide, Di(hydroxyethyl)stearylamine oxide, Di(hydroxyethyl)tallowylamine oxide, Polydimethylsiloxane PEG-7 phosphate, Polydimethylsiloxane PEG-10 phosphate, Polydimethylsiloxane PEG / PPG-7 / 4 phosphate, Polydimethylsiloxane PEG / PPG-12 / 4 phosphate, Polydimethylsiloxane / polyglycerol-3 crosspolymer, Polydimethylsiloxane propyl PG-betaine, Dimyroxymethyl phosphate, Dioleoamide ethylhydroxyethyl Methylammonium methyl sulfate, hydrogenated coconut oil acid DIPA salt, lanolin acid DIPA salt, myristic acid DIPA salt, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecenoyl glutamate, disodium babassulamamide MEA-sulfosuccinate, disodium decanoyl amphoteric acid diacetate, disodium decanoyl amphoteric acid dipropionate, disodium capryloyl amphoteric acid diacetate, disodium capryloyl amphoteric acid dipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonic acid, disodium cetyl sulfosuccinate, disodium cocamidoyl MEA-sulfosuccinate, disodium cocamidoyl MIPA Disodium PEG-4 sulfosuccinate, disodium cocamido-MIPA-sulfosuccinate, disodium cocamido-PEG-3 sulfosuccinate, disodium cocoyl alcohol polyether-3 sulfosuccinate, disodium cocoamphoyl carboxyethyl hydroxypropyl sulfonate, disodium cocoamphoyl diacetate, disodium cocoamphoyl dipropionate, disodium cocoyl glucoside sulfosuccinate, disodium cocoyl sulfosuccinate, disodium cocoyl butyl glucoside Disodium sulfosuccinate-10, disodium cocoyl glutamate, C12-14 alkanol polyether-1, disodium sulfosuccinate, C12-14 alkanol polyether-2, disodium sulfosuccinate, C12-15 alkanol polyether, disodium sulfosuccinate, C12-14 secondary alkanol polyether-3, disodium sulfosuccinate, C12-14 secondary alkanol polyether-5, disodium sulfosuccinate, C12-14 secondary alkanol polyether Disodium 7-sulfosuccinate, disodium C12-14 secondary alkanol polyether-9-sulfosuccinate, disodium C12-14 secondary alkanol polyether-12-sulfosuccinate, disodium decanol polyether-5-sulfosuccinate, disodium decanol polyether-6-sulfosuccinate, disodium decyl phenyl ether disulfonic acid, disodium dihydroxyethyl sulfosuccinoyl undecenoate, disodium dicocoyl ethylenediamine PEG-15 disulfate, hydrogenated cottonseed oil glyceryl ester sulfosuccinate Disodium succinate, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitan citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA-sulfosuccinate, disodium isostearamide MIPA-sulfosuccinate, disodium isostearate diacetate, disodium isostearate dipropionate, disodium isostearyl sulfosuccinate, disodium lanolin alcohol ether-5 sulfosuccinate, disodium lauramide MEA-sulfosuccinate.Disodium lauramide MIPA ethylene glycol sulfosuccinate, disodium lauramide PEG-2 sulfosuccinate, disodium lauramide PEG-5 sulfosuccinate, disodium lauryl ether-5 carboxyamphodiacetate, disodium lauryl ether-7 citrate, disodium lauryl ether sulfosuccinate, disodium lauryl ether-6 sulfosuccinate, disodium lauryl ether-9 sulfosuccinate, disodium lauryl ether-12 sulfosuccinate, disodium lauryliminobis(hydroxypropyl)sulfonate, disodium lauryliminodiacetate, disodium lauryliminodiapropionate, disodium lauryliminodiapropionate tocopherol phosphate salt, disodium lauroylamphodiacetate, disodium lauroylamphodiapropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate. Disodium oleamide, disodium lauryl phenyl ether disulfonate, diammonium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonylphenol polyether-10 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoyl amphoteric dipropionate, disodium oleyl alcohol polyether-3 sulfosuccinate, disodium oleyl alcohol phosphate, disodium oleyl alcohol sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium palmitamide-PEG-2 sulfosuccinate, disodium palmitamide-2 sulfosuccinate, disodium PEG-4 cocoamide MIPA-sulfosuccinate, disodium PEG-12 polydimethylsiloxane sulfosuccinate, PEG-8 palmitoleic acid Disodium sulfosuccinate of glycerides, disodium PPG-2-isodecyl alcohol polyether-7-carboxyamphodiacetate, disodium ricinoleic acid amide MEA sulfosuccinate, disodium sitosterol polyether-14 sulfosuccinate, disodium soybean oil amphoteric diacetate, disodium stearamide MEA sulfosuccinate, disodium stearyl iminodipropionate, disodium stearyl amphoteric diacetate, disodium stearyl glutamate, disodium sulfosuccinate monoacylstearamine, disodium stearyl alcohol sulfosuccinate, disodium 2-sulfolarate, disodium 2-sulfopalactate, disodium tallow oleamide MEA sulfosuccinate, disodium tallow amide MEA sulfosuccinate, disodium tallow amphoteric diacetate, disodium tallow iminodipropionate, disodium sulfosuccinate monoacyl tallowamine, tridecanol Disodium sulfosuccinate, disodium undecenoamide MEA sulfosuccinate, disodium undecenoamide PEG-2 sulfosuccinate, disodium undecenoyl glutamate, disodium monowheat germ oleoyl MEA sulfosuccinate, disodium monowheat germ oleoyl PEG-2 sulfosuccinate, disodium wheat germ oleoyl amphoteric diacetate, cocamidoyl diacetate di-TEA salt, oleamide-2 sulfosuccinate di-TEA salt, palmitoyl aspartate di-TEA salt, sodium ditridecyl sulfosuccinate, dodecylbenzene sulfonic acid, erucamide propyl hydroxysulfobetaine, ethylhexyl alcohol polyether-3 carboxylic acid, ethyl PEG-15 cocoamine sulfate salt, octyl glyceryl ether, hexyl decanoic acid, hydrogenated coconut oil acid, hydrogenated lanolin alcohol polyether-25.Hydrogenated herring oil fatty acids, hydrogenated palmitoleic acid, hydrogenated palm kernel oil amine oxide, hydrogenated tallowic acid, hydrogenated tallow-based amine oxide, hydrogenated tallow-based betaine, hydrogenated tallow alcohol polyether-25, hydrogenated tallow yl glutamic acid, hydrogenated Candida albicans extract, hydroxycetyl alcohol polyether-60, hydroxyethyl acetoxymethyl ammonium PG-polydimethylsiloxane, lauryl ether sulfate hydroxyethyl butylamine salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimide C10-40 isoalkyl ester, hydroxysuccinimide C21-22 isoalkyl ester, hydroxysulfonyl betaine, IPDI / PEG-15 soybean oil amine oxide copolymer. IPDI / PEG-15 soybean oil amine ethanol sulfate copolymer, IPDI / PEG-15 soybean oil glycine ester copolymer, lsoceteth-30, isolaurhodium-4 phosphate, isoglycerol-3 polydimethylsiloxane, isoglycerol-3 polydimethylsiloxane, isopropanolamine lanolinate, isopropanolamine dodecylbenzenesulfonate, isostearamide propylamine oxide, isostearamide propyl betaine, isostearamide propyl morpholine oxide, isostearyl alcohol polyether-8, isostearyl alcohol polyether-16, isostearyl alcohol polyether-22, isostearyl alcohol polyether-25, isostearyl alcohol polyether-50, isostearic acid, isostearyl acyl hydrolyzed collagen, jojoba oil PEG-150 esters, jojoba wax PEG-80 esters, etc. Hoba wax PEG-120 esters, lanolin alcohol polyether-20, lanolin alcohol polyether-25, lanolin alcohol polyether-40, lanolin alcohol polyether-50, lanolin alcohol polyether-60, lanolin alcohol polyether-75, lanolin acid, lauramide propylamine oxide, lauramide propyl betaine, lauramide propyl hydroxysulfonyl betaine, laurylamine oxide, lauryl aminopropionic acid, lauryl dimethyl hydroxypropyl decyl glucoside ammonium chloride, lauryl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, lauryl alcohol polyether-16, lauryl alcohol polyether-20, lauryl alcohol polyether-21, lauryl alcohol polyether-23, lauryl alcohol polyether-25, lauryl alcohol polyether-30, lauryl alcohol polyether-38, lauryl alcohol polyether-40, lauryl alcohol polyether-3 carboxylic acid, lauryl Laureth-4 carboxylic acid, Laureth-5 carboxylic acid, Laureth-6 carboxylic acid, Laureth-8 carboxylic acid, Laureth-10 carboxylic acid, Laureth-11 carboxylic acid, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citrate, Laureth-7 citrate, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartrate, Lauric acid, Laurimethylenedipropylene glycol, Laurimethylenedipropionic acid, Lauroyl amphoteric dipropionic acid, Lauroyl β-aminopropionic acidLauroyl collagen amino acids, lauroyl ethyl trimethylammonium methyl sulfate salt, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, lauroyl silk amino acids, lauryl betaine, lauryl polydimethylsiloxane / polyglycerol-3 crosspolymer, lauryl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, lauryl glucoside, lauryl glucoside hydroxypropyl trimethyl ammonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysulfonyl betaine, lauryl malic acid, lauryl methyl glucosamine, (lauryl / nutmeg)-diol hydroxypropyl ether, (lauryl / nutmeg)-based wheat bran / straw glycosides, lauryl polyglycerol-3 polydimethylsiloxane ethyl polydimethylsiloxane, lauryl pyrrolidone, lauryl dimethyl Sulfobetaine, linoleic acid, linolenic acid, linolenic acid, lysine cocoate, macadamia seed oil glyceryl polyether-8 ester, magnesium cocoyl ether sulfate, magnesium cocoyl ether sulfate, magnesium isododecylphenyl sulfonate, magnesium lauryl ether-11 carboxylate, magnesium lauryl ether sulfate, magnesium lauryl ether-5 sulfate, magnesium lauryl ether-8 sulfate, magnesium lauryl ether-16 sulfate, magnesium lauryl ether-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methyl cocoyl taurate, magnesium myristyl ether sulfate, magnesium oleyl ether sulfate, magnesium cocoyl ether sulfate / TEA salt, Mannequin glacial mud, coconut oil MEA salt, magnesium lauryl ether-6 carboxylate MEA salt, magnesium lauryl ether sulfate MEA salt, etc. Cinnamyl sulfate MEA salt, PPG-6-Lauryl ether-7-carboxylic acid MEA salt, PPG-8-Stearyl ether-7-carboxylic acid MEA salt, Undecenoic acid MEA salt, Meroxapone 108, Meroxapone 174, Meroxapone 178, Meroxapone 254, Meroxapone 255, Meroxapone 258, Meroxapone 314, MethoxyPEG-450 Amide glutaryl succinamide, MethoxyPEG-450 Amide hydroxysuccinimide succinate, MethoxyPEG-450 Maleimide, Methylmorpholine oxide, Milk amamidopropylamine oxide, Milk amamidopropyl betaine, Mink oil amamidopropylamine oxide, Mink oil amamidopropyl betaine, C12-15 Alkyl alcohol polyether sulfate MIPA salt, Dodecyl Alkylbenzene sulfonic acid MIPA salt, lauryl ether sulfate MIPA salt, lauryl sulfate MIPA salt, mixed isopropanolamine lanolinate, mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myristyl alcohol polyether-3 carboxylic acid, myristyl alcohol polyether-5 carboxylic acid, myristyl benzyl dimethyl ammonium chloride, myristamidopropylamine oxide, myristamidopropyl betaine, myristamidopropyl dimethylamine phosphate, myristamidopropyl hydroxysulfonyl betaine, myristamidopropyl PG-dimethylammonium chloride phosphate, myristamine oxide, myristaminopropionic acid, myristic acid, myristoyl ethyltrimethylammonium methyl sulfate salt, myristoyl glutamate, myristoyl hydrolyzed collagenMyristyl sarcosine, Myristyl betaine, Myristyl / Cetylamine oxide, Myristyl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, Myristyl glucoside, Myristyl phosphate, Nonylphenol polyether-20, Nonylphenol polyether-23, Nonylphenol polyether-25, Nonylphenol polyether-30, Nonylphenol polyether-35, Nonylphenol polyether-40, Nonylphenol polyether-44, Nonylphenol polyether-50, Nonylphenol polyether-100, Nonylphenol polyether-120, Nonylphenol polyether-5 carboxylic acid, Nonylphenol polyether-8 carboxylic acid, Nonylphenol polyether-10 carboxylic acid, Nonylphenol polyether-3 phosphate, Nonylphenol polyether-4 phosphate, Nonylphenol polyether-6 phosphate, Nonylphenol polyether-9 phosphate, Nonylphenol polyether-10 phosphate, Dinonylphenol Polyether-30, Dinonylphenol Polyether-49, Dinonylphenol Polyether-100, Dinonylphenol Polyether-150, Dinonylphenol Polyether-7 Phosphate, Dinonylphenol Polyether-8 Phosphate, Dinonylphenol Polyether-9 Phosphate, Dinonylphenol Polyether-10 Phosphate, Dinonylphenol Polyether-11 Phosphate, Dinonylphenol Polyether-15 Phosphate, Dinonylphenol Polyether-24 Phosphate, Oat Oleamide Propyl Betaine, Octylphenol Polyether-16, Octylphenol Polyether-25, Octylphenol Polyether-30, Octylphenol Polyether-33, Octylphenol Polyether-40, Octylphenol Polyether-70, Octylphenol Polyether-20 Carboxylic Acid, Octyldodecyl alcohol Polyether-20, Octyldodecyl alcohol Polyether-25, Octyldodecyl alcohol Polyether-30, Oleamide Propylamine Oxide, Oleamide Propyl betaine, oleamidopropyl (hydroxysulfonyl)propyl dimethylammonium, oleylamine oxide, oleic acid, oleyl acyl hydrolyzed collagen, oleyl sarcosine, oleyl alcohol polyether-20, oleyl alcohol polyether-23, oleyl alcohol polyether-24, oleyl alcohol polyether-25, oleyl alcohol polyether-30, oleyl alcohol polyether-35, oleyl alcohol polyether-40, oleyl alcohol polyether-44, oleyl alcohol polyether-50, oleyl alcohol polyether-3 carboxylic acid, oleyl alcohol polyether-6 carboxylic acid, oleyl alcohol polyether-10 carboxylic acid, oleyl betaine, olive oil amamidopropylamine oxide, olive oil amamidopropyl betaine, oleic acid, olive oil acyl hydrolyzed wheat protein, stearate of Ophiopogon japonicus extract, ozonated oleyl alcohol polyether-10, ozonated PEG-10 oleate, ozonated PEG-14 oleate, ozonated polysorbate 8 0. Palmitoleic acid, palmitopropyl betaine, palmitole alcohol polyether-2 phosphate, palmitopropylamine oxide, palmitopropyl betaine, palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptides, palmitoyl silk amino acids, palm kernel oil, palm kernel oil, peach kernel oil glycerol polyether-8 ester, arachidic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil.PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocoamine, PEG-8 cocoamine, PEG-12 cocoamine, PEG-150 dibenzyl ester, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl coconut oil PEG-78 glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate, PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 glyceryl laurate, PEG-25 glyceryl oleate, PEG-30 glyceryl oleate, PEG-30 glyceryl soybean oleate, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 glyceryl oleate, PEG- PEG-80 glyceryl triglyceride, PEG-82 glyceryl triglyceride, PEG-130 glyceryl triglyceride, PEG-200 glyceryl triglyceride, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmitamide, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG PEG-10 isostearate, PEG-12 isostearate, PEG-20 isostearate, PEG-30 isostearate, PEG-40 isostearate, PEG-26 jojoba acid, PEG-40 jojoba acid, PEG-15 jojoba alcohol, PEG-26 jojoba alcohol, PEG-40 jojoba alcohol, PEG-35 lanolin, PEG-40 lanolin, PEG-50 lanolin, PEG-55 lanolin, PEG-60 lanolin, PEG-70 lanolin, PEG-75 lanolin, PEG-85 lanolin, PEG-100 lanolin, PEG-150 lanolin, PEG-75 lanolin oil, PEG-2 laurylamide, PEG-3 laurylamine oxide,PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannitol laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucoside dioleate, PEG-80 methyl glucoside laurate, PEG-120 methyl glucoside trioleate, PEG-4 lignite, PEG-30 oleylamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglycerol-2 tristearate, PE G / PPG-28 / 21 ester polydimethylsiloxane, PEG / PPG-24 / 18 butyl ether polydimethylsiloxane, PEG / PPG-3 / 17 copolymer, PEG / PPG-5 / 35 copolymer, PEG / PPG-8 / 55 copolymer, PEG / PPG-10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate ester, PEG / PPG-4 / 2 propyl heptyl ether, PEG / PPG-6 / 2 propyl heptyl ether, PEG-7 / PPG-2-propyl heptaether, PEG / PPG-8 / 2-propyl heptaether, PEG / PPG-10 / 2-propyl heptaether, PEG / PPG-14 / 2-propyl heptaether, PEG / PPG-40 / 2-propyl heptaether, PEG / PPG-10 / 2-ricinoleate, PEG / PPG-32 / 3-ricinoleate, PEG-55 propylene glycol oleate, PEG-25 propylene glycol stearate, PEG-75 propylene glycol stearate, PEG-120 propylene glycol stearate, PEG-5 rapeseed sterol, PEG-10 rapeseed sterol, PEG-40 ricinoleamide, PEG-75 shea butter glycerides, PEG-75 salsa glycerides, PEG-20 sorbitan cocoate.PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolinate, PEG-75 Sorbitan Lanolinate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearoamide Carboxylic Acid, PEG-9 Stearoamide Carboxylic Acid, PE G-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallow ester, PEG-50 tallow amide, PEG-2 tallow amide DEA, PEG-20 tallow ester, PEG-66 trihydroxystearate Lipids, PEG-200 Trihydroxystearin, PEG-60 Camellia Oil Glycerides, Nonanoic Acid, Pentadecylphenol Polyether-200, Phenolic Polyether-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamer 908, Poloxamer 1508, Polydimethylsiloxane PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxane PPG-13 Butyl Ether Silsesquioxane, Polyglycerol Polyglycerol-6-decanoate, polyglycerol-10-dilaurate, polyglycerol-20-heptacapryate, polyglycerol-20-hexacapryate, polyglycerol-2-lauryl ether, polyglycerol-10-lauryl ether, polyglycerol-20-octaisononate, polyglycerol-6-pentacapryate, polyglycerol-10-pentacapryate, polyglycerol-3-dimethylsiloxane, polyglycerol-6-tetracapryate, polyglycerol-10-tetralauryate, polyglycerol-6-tricapryate, polyglycerol-10-trilauryate, polyquaternium-77, polyquaternium-78, polyquaternium-79, polyquaternium-80, polyquaternium-81, polyquaternium-82, Pomaderris Kumerahou flower / leaf extract, Poria cocos extract,Potassium abietic hydrolyzed collagen, potassium babassuate, potassium behenate, C9-15 potassium phosphate, C11-15 potassium phosphate, C12-13 potassium phosphate, C12-14 potassium phosphate, potassium decanoate, potassium capryloyl glutamate, potassium capryloyl hydrolyzed rice protein, potassium castor oil, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycine, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soybean protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, and cocoyl PCA. Potassium, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Corn Oleate, Potassium Cyclocarboxypropyl Oleate, Potassium Dihydroxyethyl Cocoamine Oxide Phosphate, Potassium Polydimethylsiloxane PEG-7 Phosphate, Potassium Dodecylbenzene Sulfonate, Potassium Hemp Seed Oil, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palm Oil, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolinate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Lauroyl Collagen Amino Acid, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Potassium pea amino acids, potassium lauroyl sarcosinate, potassium lauroyl silk amino acids, potassium lauroyl wheat amino acids, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octylphenol polyether-12 phosphate, potassium oleate, potassium oleyl hydrolyzed collagen, potassium olive oil, potassium olive oil acyl hydrolyzed oat protein, potassium olive oil acyl hydrolyzed wheat protein, potassium olive oil acyl / lauroyl wheat amino acids, potassium olive oil acyl PCA, potassium palmitate, potassium palmitate, potassium palmitate, potassium palmitate hydrolyzed corn protein, potassium palmitate hydrolyzed oat protein, potassium palmitate hydrolyzed rice protein, potassium palmitate hydrolyzed sweet almond protein, potassium palmitate hydrolyzed wheat protein, palm kernel oleic acid Potassium, potassium arachidate, potassium rapeseed oil, potassium ricinoleate, potassium safflower oil, potassium soybean oil, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tallowate, potassium tallowate, potassium taurate, potassium taurate laurate, potassium tridecyl alcohol polyether-3 carboxylate, potassium tridecyl alcohol polyether-4 carboxylate, potassium tridecyl alcohol polyether-7 carboxylate, potassium tridecyl alcohol polyether-15 carboxylate, potassium tridecyl alcohol polyether-19 carboxylate, potassium tridecyl alcohol polyether-6 phosphate, potassium tridecyl alcohol polyether-7 phosphate, potassium camellia oleate, potassium undecenoate, potassium undecenoyl hydrolyzed collagen, potassium undecenoyl hydrolyzed rice protein, PPG-30-butanol polyether-30, PPG-36-butanol polyether-36, PPG-38-butanol polyether-37, PPG-30-octyl alcohol polyether-4 phosphate esterPPG-10 Cetyl Ether Phosphate, PPG-2C9-11 Alcohol Polyether-8, PPG-1-Decanol Polyether-5, PPG-3-Decanol Polyether-2 Carboxylic Acid, PPG-30-Ethylhexanol Polyether-4 Phosphate, PPG-20-Glyceryl Polyether-30, PPG-2 Hydroxyethyl Coconut Oil / Isostearamide, PPG-2-Isodecyl Alcohol Polyether-8, PPG-2-Isodecyl Alcohol Polyether-10 PPG-2-Isodecyl alcohol polyether-18, PPG-2-Isodecyl alcohol polyether-25, PPG-4-Isodecyl alcohol polyether-10, Propyltrimethylammonium hydrolyzed collagen, Quaternary ammonium salt-24, Quaternary ammonium salt-52, Quaternary ammonium salt-87, Rapeseed oil acid, Rice bran acid, Rice bran oil glyceryl polyether-8 esters, Ricinoxane amylase-propyl betaine, Ricinoxane acid, Ricinoxane oil alcohol polyether-40, Sapindus Oahuensis fruit extract, Saponaria soapwort (Saponaria) (Officinalis) root powder, saponins, potassium soap, sodium / potassium soap, soap base, potassium soap base, sesame oil glyceryl polyether-8 esters, sesame oil amamidopropylamine oxide, sesame amamidopropyl betaine, shea butter amamidopropyl betaine, shea butter glyceryl polyether-8 esters, sodium arachidate, sodium arganampohoacetate, mulberry palm oil sodium oleate, sodium avocadoate, sodium babassu oleoylamphoacetate, sodium babassu oleate, sodium babassu oleate sulfate, sodium behenate. Sodium diethylene glycol castor oil sulfosuccinate, sodium dihydroxyethyl glycinate cocoyl glucoside cross-linked copolymer, sodium dihydroxyethyl glycinate lauryl glucoside cross-linked copolymer, sodium borage oleamidopropyl PG-dimethylammonium chloride phosphate, sodium butylphenol polyether-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkyl sulfonate, sodium C14-18 alkyl sulfonate, sodium C12-15 alkoxypropyliminodipropionate, sodium C10-16 alcohol sulfate, sodium C11-15 alkyl sulfate, sodium C12 -13 alkyl sulfate sodium, C12-15 alkyl sulfate sodium, C12-18 alkyl sulfate sodium, C16-20 alkyl sulfate sodium, C9-22 secondary alkyl sulfonate sodium, C14-17 secondary alkyl sulfonate sodium, sodium decanoate, sodium decanoamphoacetate, sodium decanoamphohydroxypropyl sulfonate, sodium decanoamphopropionate, sodium decanomethyl taurate, sodium octanoate, sodium octyl ether-2 carboxylate, sodium octyl ether-9 carboxylate, sodium octanoamphoacetate, sodium octanoamphohydroxypropyl sulfonate, sodium octanoamphopropionate, octanoyl glutamate Sodium octyl hydrolyzed wheat protein, sodium octyl PG-sulfonate, sodium octyl sulfonate, sodium ricinoleate, sodium cetearyl alcohol polyether-13 carboxylate, sodium cetearyl alcohol sulfate, sodium cetearyl alcohol polyether-13 carboxylate, sodium cetearyl alcohol sulfate, sodium cocamidopropyl PG-dimethylammonium chloride phosphate, sodium cocoyl aminopropionate, sodium cocoyl alcohol polyether sulfate, sodium cocoyl alcohol polyether-30 sulfate, sodium cocoa butter amphoteric acid, sodium cocoa butter ester, sodium cocoa butter amphoteric acid, sodium cocoa butter amphoteric acid, sodium cocoa butter amphoteric acid, sodium cocoa butter amphoteric hydroxypropyl sulfonate.Sodium cocoamphopropionate, Sodium cocoate, Sodium cocoyl alcohol / babassuol / adirabalol sulfate, Sodium cocoyl alcohol / babassuol sulfate, Sodium cocoyl glucoside hydroxypropyl phosphate, Sodium cocoyl glucoside hydroxypropyl sulfonate, Sodium cocoyl glucoside tartrate, Sodium cocoyl alcohol glyceryl ether sulfonate, Sodium cocoyl alcohol / hydrogenated tallow alcohol sulfate, Sodium cocoyl iminodiacetic acid, Sodium cocoyl monoglyceride sulfate, Sodium cocoyl monoglyceride sulfonate, Sodium cocoyl PG-dimethylammonium chloride phosphate, Sodium cocoyl alcohol sulfate, Sodium cocoyl alcohol sulfoacetate, Sodium cocoyl aminopropionate, Sodium cocoyl amino acid, Sodium cocoyl collagen amino acid, Sodium cocoyl glutamate, Sodium cocoyl glutamate, Sodium cocoyl glycinate, Sodium cocoyl / hydrogenated tallow glutamate Sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soybean protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl ethoxysulfonate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acid, sodium cocoyl / palmitoyl / sunfloweroyl glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl taurate, sodium cocoyl threonine, sodium cocoyl wheat amino acid, sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate, sodium C16-18 olefin sulfonate, sodium corn oleoyl amphoteric propionate. Sodium cottonseed oil acylamphoacetate, C13-15 sodium alkanol polyether-8 butanol phosphate, C9-11 sodium alkanol polyether-6 carboxylate, C11-15 sodium alkanol polyether-7 carboxylate, C12-13 sodium alkanol polyether-5 carboxylate, C12-13 sodium alkanol polyether-8 carboxylate, C12-13 sodium alkanol polyether-12 carboxylate, C12-15 sodium alkanol polyether-6 carboxylate, C12-15 sodium alkanol polyether-7 carboxylate, C12-15 sodium alkanol polyether-8 carboxylate, C14-15 sodium alkanol polyether-8 carboxylate, C12-14 sodium secondary alkanol polyether-8 carboxylate, C14-15 sodium alkanol polyether-PG sulfonate, C12-13 sodium alkanol polyether-2 phosphate, C13-15 sodium alkanol polyether-8 phosphate, C9-15 sodium alkanol polyether-6 carboxylate, C11-15 sodium alkanol polyether-7 carboxylate, C12-15 sodium alkanol polyether-8 carboxylate, C9-15 sodium alkanol polyether-PG sulfonate, C12-13 sodium alkanol polyether-2 phosphate, C13-15 sodium alkanol polyether-8 phosphate, C9-15 ...14-15 sodium alkanol polyether-PG sulfonate, C12-13 sodium alkanol polyether-2 phosphate, C13-15 sodium alkanol polyether-8 phosphate, C9-15 Sodium sulfate of C10-15 alkanol ether, sodium sulfate of C10-16 alkanol ether, sodium sulfate of C12-13 alkanol ether, sodium sulfate of C12-15 alkanol ether, sodium sulfate of C12-15 alkanol ether, sodium sulfate of C13-15 alkanol ether, sodium sulfate of C12-14 secondary alkanol ether, sodium sulfate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium 2-carboxylic acid of decanol, sodium decyl polyether sulfate, sodium decylbenzene sulfonate, sodium decyl glucoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium di(lauryl ether-7) citrate, sodium di(lauryl ether-10) phosphate.Sodium dilinoleamide propyl PG-dimethylammonium chloride phosphate, sodium dilinoleate, sodium di(oleyl alcohol polyether-8) phosphate, sodium dodecylbenzene sulfonate, sodium ethyl 2-sulfolarate, sodium glyceryl oleate phosphate, sodium grape seed oil dilamamide propyl PG-dimethylammonium chloride phosphate, sodium grape seed oil acylamphoacetate, sodium grape seed oil, sodium hemp seed oil acylamphoacetate, sodium hexyl ether-4 carboxylate, hydrogenated sodium cocoate, hydrogenated sodium cocoyl methyl hydroxyethyl sulfonate, hydrogenated sodium palmitate, hydrogenated sodium tallow, hydrogenated sodium tallow glutamate, sodium hydroxylauryl dimethylammonium ethyl phosphate, sodium palm kernel oil hydroxypropyl sulfonate, sodium hydroxypropyl phosphate decyl glucoside crosspolymer, sodium hydroxypropyl phosphate lauryl glucoside crosspolymer, sulfonic acid Sodium hydroxypropyl cocoyl glucoside crosspolymer, sodium hydroxypropyl sulfonate decyl glucoside crosspolymer, sodium hydroxypropyl sulfonate lauryl glucoside crosspolymer, sodium hydroxystearate, sodium isostearate, sodium isostearate, sodium isostearyl alcohol polyether-6 carboxylate, sodium isostearyl alcohol polyether-11 carboxylate, sodium isostearyl amphoteric acid, sodium isostearyl amphoteric propionate, sodium N-isostearoyl methyl taurate, sodium lanolin alcohol polyether sulfate, sodium lanolinate, sodium lardate, sodium lauryl diacetate, sodium lauryl aminopropionate, sodium lauryl ether, sodium lauryl alcohol polyether-3 carboxylate, sodium lauryl alcohol polyether-4 carboxylate, sodium lauryl alcohol polyether-5 carboxylate, sodium lauryl alcohol polyether-6 carboxylate, sodium lauryl alcohol polyether-8 carboxylate, sodium lauryl alcohol polyether-11 carboxylate, sodium lauryl alcohol polyether-12 carboxylate Sodium lauryl ether-13 carboxylate, sodium lauryl ether-14 carboxylate, sodium lauryl ether-16 carboxylate, sodium lauryl ether-17 carboxylate, sodium lauryl ether sulfate, sodium lauryl ether-5 sulfate, sodium lauryl ether-7 sulfate, sodium lauryl ether-8 sulfate, sodium lauryl ether-12 sulfate, sodium lauryl ether-40 sulfate, sodium lauryl ether-7 tartrate, disodium lauryliminodipropionate, sodium lauroyl amphoteric acid, sodium lauroyl amphoteric hydroxypropyl sulfonate, sodium lauroyl amphoteric PG-acetate phosphate, sodium lauroyl amphoteric propionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropyl... Sodium lauroyl ethanesulfonate, sodium lauroyl methylaminopropionate, sodium lauroyl methyl hydroxyethyl sulfonate, sodium lauroyl Millet amino acid, sodium lauroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosine, sodium lauroyl silk amino acid, sodium lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl di(ethylenediamino)aminoacetate, sodium lauryl glucocarboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, disodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamia seed oil, sodium mangoyl amphoteric acid, sodium mango seed oil ester.Sodium lauryl ether-2-sulfosuccinate / MEA, sodium methoxyPPG-2 acetate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearyl taurate, sodium methyl 2-sulfolanoate, sodium methyl 2-sulfopalmitoate, sodium isopalmitoyl methyl taurate, sodium methyl cocoyl methyl taurate, sodium myristyl ether sulfate, sodium myristate, sodium myristoyl amphoteric acetate, sodium myristoyl glutamate, myristoyl water Sodium Collagenate, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosine, Sodium Myristyl Sulfate, Sodium Nonoxynol Polyether-6 Phosphate, Sodium Nonoxynol Polyether-9 Phosphate, Sodium Nonoxynol Polyether-1 Sulfate, Sodium Nonoxynol Polyether-3 Sulfate, Sodium Nonoxynol Polyether-4 Sulfate, Sodium Nonoxynol Polyether-6 Sulfate, Sodium Nonoxynol Polyether-8 Sulfate, Sodium Nonoxynol Polyether-10 Sulfate, Sodium Nonoxynol Polyether-25 Sulfate, Sodium Octylphenol Polyether-2 Isethionate, Sodium Octylphenol Polyether-2 Sulfate, Sodium Octylphenol Polyether-6 Sulfate, Sodium Octylphenol Polyether-9 Sulfate Sodium oleate, sodium oleate, sodium oleoylamphoacetate, sodium oleoylamphohydroxypropyl sulfonate, sodium oleoylamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl ethanesulfonate, sodium oleyl alcohol polyether sulfate, sodium oleoyl methyl ethanesulfonate, sodium oleyl alcohol sulfate, sodium oleoylamphoacetate, sodium oleoyl glutamate, sodium palmitoleoylamphoacetate, sodium palmitate, sodium palmitoleate, sodium palmitoleyl glycerol sulfonate, sodium palmitate, sodium palmitoleoyl hydrolyzed collagen, sodium palmitoleoyl hydrolyzed wheat protein, sodium palmitoleoyl sarcosinate, sodium palm kernel oleate, sodium palmitoleoyl ethanesulfonate, palm Sodium oleoylglutamate, sodium passionflower seed oil, sodium arachidonic acid, sodium arachidonic acid, PEG-6 sodium cocoamide carboxylate, PEG-8 sodium cocoamide carboxylate, PEG-4 sodium cocoamide sulfate, PEG-3 sodium lauramide carboxylate, PEG-4 sodium lauramide carboxylate, PEG-8 sodium palm oil glyceride carboxylate, pentaerythritol hydroxypropyl iminodiacetic acid sodium resin, propoxylated PPG-2 sodium acetate, sodium rapeseed oil, sodium rice bran oleoylamphoacetate, sodium ricinoleate, sodium ricinoleoylamphoacetate, Sodium Rose Hipsamphoacetate, Sodium Rosinate, Sodium Safflower Oil, Sodium Saffloweroyl Hydrolyzed Soybean Protein, Sodium Sesame Seed Oil, Sodium Sesame Amphoteric Acetate, Sodium Butyl Amphoteric Acetate, Sodium Soybean Oil, Sodium Soybean Oil Hydrolyzed Collagen, Sodium Stearate, Sodium Stearyl Amphoteric Acetate, Sodium Stearyl Hydroxypropyl Sulfonate, Sodium Stearyl Amphoteric Propionate, Sodium Stearyl Casein, Sodium Stearyl Glutamate, Sodium Stearyl Hyaluronic Acid, Sodium Stearyl Hydrolyzed Collagen, Sodium Stearyl Hydrolyzed Corn Protein, Sodium Stearyl Hydrolyzed Silk, Sodium Stearyl Hydrolyzed Soybean Protein, Sodium Stearyl Hydrolyzed Wheat Protein, Sodium Stearyl Whey Protein, Sodium Stearyl Methyl Hydroxyethanesulfonate, Sodium Stearyl Oat ProteinSodium stearoyl pea protein, sodium stearoyl soybean protein, sodium stearoyl dimethyl glycinate, sodium stearyl alcohol sulfate, sodium sunflower seed oil acylamphoacetate, sodium subtilis lipopeptide, sodium sweet almond oil acylamphoacetate, sodium sweet almond oil, sodium talloyl amphotericin, sodium talloate, sodium taurate, sodium taurate, sodium taurate, sodium talloyl amphotericin, sodium taurate, sodium callophyllium folinum seed oil, sodium taurate, sodium cocoyl methyl taurate, lauryl taurate. Sodium taurate, sodium lauroyl collagen amino acid sodium / TEA salt, sodium lauroyl hydrolyzed collagen sodium / TEA salt, sodium lauroyl hydrolyzed keratin sodium / TEA salt, sodium lauroyl keratin amino acid sodium / TEA salt, sodium undecenoyl collagen amino acid sodium / TEA salt, sodium undecenoyl hydrolyzed collagen sodium / TEA salt, sodium undecenoyl hydrolyzed corn gluten sodium / TEA salt, sodium undecenoyl hydrolyzed soybean gluten sodium / TEA salt, sodium undecenoyl hydrolyzed wheat gluten sodium / TEA salt, Theobroma Grandiflorum seed oil sodium, tridecyl alcohol polyether-3 carboxylate sodium, tridecyl alcohol polyether-4 carboxylate sodium, tridecyl alcohol polyether-6 carboxylate sodium, tridecyl alcohol polyether-7 carboxylate sodium, tridecyl alcohol polyether-8 carboxylate sodium, tridecyl alcohol polyether-12 carboxylate sodium, tridecyl alcohol polyether-15 carboxylate sodium, tridecyl alcohol polyether-19 carboxylate sodium, tridecyl alcohol polyether sulfate sodium, tridecylbenzene sulfonate sodium, tridecyl alcohol sulfate sodium, trimethylolpropane hydroxypropyl iminodiacetic acid sodium resin Compounds, sodium undecanoyl alcohol polyether-5 carboxylate, sodium undecenoate, sodium undecenoyl amphoteric acid, sodium undecenoyl amphoteric propionate, disodium undecenoyl glutamate, sodium wheat germ oil amphoteric acid, sorbitol polyether-160 tristearate, soybean oleic acid, soybean oleamidopropylamine oxide, soybean oleamidopropyl betaine, soybean glyceryl polyether-8 esters, stearamidopropylamine oxide, stearamidopropyl betaine, stearylamine oxide, stearyl alcohol polyether-15, stearyl alcohol polyether Stearyl alcohol polyether-16, stearyl alcohol polyether-20, stearyl alcohol polyether-21, stearyl alcohol polyether-25, stearyl alcohol polyether-27, stearyl alcohol polyether-30, stearyl alcohol polyether-40, stearyl alcohol polyether-50, stearyl alcohol polyether-80, stearyl alcohol polyether-100, stearyl alcohol polyether-2 phosphate, stearyl alcohol polyether-3 phosphate, stearic acid, stearoxypropyltrimethylammonium chloride, stearoylglutamic acid, stearoylsarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearic acid, stearyl glutamic acid, stearyl sarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearic acid, stearyl glutamic acid, stearyl sarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearyl glutamic acid ... Aliphatic dimethyl decyl glucoside hydroxypropyl ammonium chloride, stearyl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oil oleamide MEA, sunflower seed oil acid, sunflower seed oil oleamide propyl hydroxyethyl dimethyl ammonium chloride, sunflower seed oil glyceryl polyether-8 esters, tallow acid, tallow aminopropylamine oxide, tallow aminopropyl betaine, tallow aminopropyl hydroxysulfonyl betaine,Tallow amine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow ethyl glucoside, abietic hydrolyzed collagen TEA salt, C12-14 alcohol phosphate TEA salt, C10-15 alkyl sulfate TEA salt, C11-15 alcohol sulfate TEA salt, C12-13 alkyl sulfate TEA salt, TEA-C12-14 alkyl sulfate TEA salt, TEA-C12-15 alkyl sulfate TEA salt, TEA C14-17 secondary alkyl sulfonic acid TEA salt, low erucic acid rapeseed oil TEA salt, cocamidodiacetic acid TEA salt, coconut oil acid TEA salt, coconut oil alcohol sulfate TEA salt, cocoyl alanine TEA salt, cocoyl glutamic acid TEA salt, cocoyl glutamine TEA salt, cocoyl glycine TEA salt, cocoyl hydrolyzed collagen TEA salt, cocoyl hydrolyzed soybean protein TEA salt, cocoyl sarcosine TEA salt, polydimethylsiloxane PEG-7 phosphate TEA salt, dodecylbenzene sulfonic acid TEA salt, hydrogenated coconut oil acid TEA salt, hydrogenated tallow glutamic acid TEA salt, isostearic acid TEA salt TEA-Isostearyl Hydrolyzed Collagen TEA Salt, Lauroyl Aminopropionic Acid TEA Salt, Lauric Acid TEA Salt, Lauric Acid / Myristic Acid TEA Salt, Lauroyl Polyether Sulfate TEA Salt, Lauroyl Collagen Amino Acid TEA Salt, Lauroyl Glutamate TEA Salt, Lauroyl Hydrolyzed Collagen TEA Salt, Lauroyl Keratin Amino Acid TEA Salt, Lauroyl Methaminopropionic Acid TEA Salt, Lauroyl / Myristoyl Aspartic Acid TEA Salt, Lauroyl Sarcosine TEA Salt, Lauroyl Phosphate TEA Salt, Lauroyl Sulfate TEA Salt, Myristoyl Aminopropionic Acid TEA Salt, Myristic Acid TEA Salt, Myristoyl Hydrolyzed Collagen TEA salts, oleic acid TEA salts, oleoyl hydrolyzed collagen TEA salts, oleoyl sarcosine TEA salts, oleyl alcohol sulfate TEA salts, palmitic acid TEA salts, palm kernel sarcosine TEA salts, PEG-3 cocoamide sulfate TEA salts, pinoresinic acid TEA salts, stearic acid TEA salts, tall acid TEA salts, tridecylbenzenesulfonic acid TEA salts, undecenoic acid TEA salts, undecenoyl hydrolyzed collagen TEA salts, tetramethyldecynyl glycol, tetrasodium dicarboxyethyl stearyl sulfosuccinate, lauryl ether sulfate TIPA salts, lauryl sulfate TIPA salts, myristic acid TIPA salts, stearic acid TIPA salts Tocopherol phosphate, Trehalose undecenoate, TM-C12-15 Alkyl ether-2 phosphate, TM-C12-15 Alkyl ether-6 phosphate, TM-C12-15 Alkyl ether-8 phosphate, TM-C12-15 Alkyl ether-10 phosphate, Tridecyl alcohol polyether-20, Tridecyl alcohol polyether-50, Tridecyl alcohol polyether-3 carboxylic acid, Tridecyl alcohol polyether-4 carboxylic acid, Tridecyl alcohol polyether-7 carboxylic acid, Tridecyl alcohol polyether-8 carboxylic acid, Tridecyl alcohol polyether-15 carboxylic acid, Tridecyl alcohol polyether-19 carboxylic acid, Tridecyl alcohol polyether-10 phosphate, Tridecylbenzene sulfonic acid, Tris(Lauryl alcohol polyether-9) citrate,Trimethylolpropane hydroxypropyl dihydroxyethylamine resin, tris(lauroyl amphoteric PG-acetic acid sodium chloride) phosphate, undecanoic acid, undecanoyl alcohol polyether-5 carboxylic acid, undecenoyl ammonium amine oxide, undecenoyl ammonium betaine, undecenoic acid, undecenoyl collagen amino acid, undecenoyl glycine, undecenoyl hydrolyzed collagen, undecenoyl wheat amino acids, undecyl glucoside, wheat germ fatty acids, wheat germ oleamide propylamine oxide, wheat germ oleamide propyl betaine, Yucca Schidigera leaf / root / stem extract, Yucca Schidigera stem extract, zinc cocoyl alcohol polyether sulfate and zinc cocoyl alcohol sulfate.

[0031] Preferably, it is selected from one or more compounds including sodium lauryl ether sulfate, cocamidopropyl betaine, sodium coamphoacetate, cocoyl glucoside and ammonium lauryl sulfosuccinate.

[0032] The percentage content of the surfactant in the formulation can be from 0.1 to 10% by weight, and preferably from 0.5 to 5% by weight, based on the formulation. oil body

[0033] A suitable oil body, which is a component of the O / W emulsion, is, for example, based on Guerbet alcohol containing 6 to 18, preferably 8 to 10, carbon atoms, with a straight-chain C6-C... 22 - Fatty acids and straight-chain or branched C6-C 22 -Ester or branched C6-C of aliphatic alcohols 13 -Carboxylic acids with straight-chain or branched C6-C 22- Esters of aliphatic alcohols, such as, for example, tetradecyl myristate, tetradecyl palmitate, tetradecyl stearate, tetradecyl isostearate, tetradecyl oleate, tetradecyl behenate, tetradecyl erucate, hexadecyl myristate, hexadecyl palmitate, hexadecyl stearate, hexadecyl isostearate, hexadecyl oleate, hexadecyl behenate, hexadecyl erucate, octadecyl myristate, octadecyl palmitate, octadecyl stearate, octadecyl isostearate, octadecyl oleate, octadecyl behenate, octadecyl erucate, isooctadecyl myristate, isooctadecyl palmitate, stearic acid Isooctadecyl ester, isooctadecyl isostearate, isooctadecyl oleate, isooctadecyl behenate, isooctadecyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucic acid, myristate docosyl ester, palmitate docosyl ester, stearate docosyl isostearate, isostearate docosyl ester, oleate docosyl ester, behenate docosyl ester, myristate mustard ester, palmitate mustard ester, stearate mustard ester, isostearate mustard ester, oleate mustard ester, behenate mustard ester, and mustard ester. Additionally, linear C6-C is suitable. 22 - Fatty acids and branched-chain alcohols, especially esters of 2-ethylhexanol, C 18 -C 38 -alkyl hydroxycarboxylic acid with straight-chain or branched C6-C 22 - Esters of aliphatic alcohols, particularly dioctyl malate, straight-chain and / or branched-chain fatty acids with polyols (such as propylene glycol, dimerdiol, or trimertriol) and / or Guerbet alcohols, based on C6-C 10 - Triglycerides of fatty acids, C6-C 18 -A liquid mixture of mono- / di- / triglycerides of fatty acids, C6-C 22 - Aliphatic alcohols and / or Guerbet alcohols with aromatic carboxylic acids, especially benzoic acid esters, C2-C 12 - Dicarboxylic acids and esters of straight-chain or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, straight-chain and branched C6-C... 22 - Carbonates of aliphatic alcohols, such as, for example, dioctyl carbonate ( CC), based on aliphatic alcohols having 6 to 18, preferably 8 to 10, carbon atoms, Guerbet carbonates, benzoic acid, and straight-chain and / or branched C6-C 22 -Esters of alcohols (e.g.) TN), straight-chain or branched, symmetrical or asymmetrical dialkyl ethers, each alkyl group having 6 to 22 carbon atoms, such as, for example, dioctyl ether (TN). OE), ring-opening products of epoxidized fatty acid esters and polyols, silicone oils (cyclodimethylsiloxane, silicone methyl silicone oil grade, etc.) and / or aliphatic hydrocarbons or cycloalkanes, such as squalane, squalene or dialkylcyclohexane. emulsifier

[0034] Other nonionic or cationic surfactants can also be added to formulations as emulsifiers, including, for example: • 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with straight-chain C 8-22 Aliphatic alcohols, and C 12-22 Addition products of fatty acids and alkylphenols having 8-15 carbon atoms in the alkyl group; • The C10 of the addition products of 1 to 30 moles of ethylene oxide to glycerol 12 / 18 Fatty acid monoesters and diesters; • Saturated and unsaturated fatty acid mono- and diesters containing 6 to 22 carbon atoms and dehydrated sorbitol mono- and diesters and their ethylene oxide addition products; • Addition products of 15 to 60 moles of ethylene oxide with castor oil and / or hydrogenated castor oil; • Polyol esters, especially polyglycerol esters, such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate, or polyglycerol dimeric oleoisostearate. Mixtures of several such compounds are also applicable; • Addition products of 2 to 15 moles of ethylene oxide with castor oil and / or hydrogenated castor oil; • Based on straight chain, branched chain, unsaturated or saturated C 6 / 22 Fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (e.g., sorbitol), alkyl glucosides (e.g., methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g., cellulose) are esters. • Mono-, di-, and trialkyl phosphates, as well as mono-, di-, and / or tri-PEG alkyl phosphates and their salts; • Lanolin alcohols; • Polysiloxane / polyalkyl polyether copolymers and their derivatives; • A mixture of pentaerythritol, fatty acids, citric acid, and aliphatic alcohols and / or C 6-22 A mixture of fatty acids, methyl glucose and polyols, preferably glycerol or polyglycerol; Polydiols and • Glyceryl carbonate.

[0035] The addition products of ethylene oxide and / or propylene oxide with aliphatic alcohols, fatty acids, and alkylphenols, as well as glycerol mono- and diesters and anhydrous sorbitol mono- and diesters of fatty acids or castor oil, are commercially available products. Here, we refer to homologous mixtures whose average degree of alkoxylation corresponds to the ratio of ethylene oxide and / or propylene oxide to the matrix in the addition reaction. The C1 of the ethylene oxide-glycerol addition product... 12 / 18 Fatty acid monoesters and diesters are known to be used as fat enriching agents in cosmetic formulations. Preferred emulsifiers are listed in detail below:

[0036] Metaglycerides. Typical examples of suitable metaglycerides are glyceryl monohydroxystearate, glyceryl dihydroxystearate, glyceryl isostearate, glyceryl isostearate, glyceryl monooleate, glyceryl dioleate, glyceryl ricinoleate, glyceryl ricinoleate, glyceryl linoleate, glyceryl dioleate, glyceryl monooleate, glyceryl linoleate, glyceryl erucic acid, glyceryl dioleucic acid, glyceryl tartrate, glyceryl tartrate, glyceryl monocitrate, glyceryl citrate, glyceryl malate, glyceryl malate, and technical mixtures thereof that still contain small amounts of triglycerides derived from the production process. Addition products of 1 to 30, preferably 5 to 10 moles of ethylene oxide with the above-mentioned metaglycerides are also suitable.

[0037] Sorbitol esters. Suitable sorbitol esters include sorbitol monoisostearate, sorbitol sesquiisostearate, sorbitol diisostearate, sorbitol triisostearate, sorbitol monooleate, sorbitol sesquioleate, sorbitol dioleate, sorbitol trioleate, sorbitol monoerucic acid ester, sorbitol sesquierucic acid ester, sorbitol dierucic acid ester, sorbitol trierucic acid ester, sorbitol monoricinoleate, sorbitol sesquirucic acid ester, sorbitol diricinoleate, sorbitol triricinoleate, and sorbitol monoricinoleate. Sorbitol monohydroxy stearate, sorbitan sesquihydroxy stearate, sorbitan dihydroxy stearate, sorbitan trihydroxy stearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate, and mixtures thereof. Addition products of 1 to 30, preferably 5 to 10 moles of ethylene oxide with the above-mentioned sorbitan esters are also suitable.

[0038] Polyglycerol esters. A typical example of a suitable polyglycerol ester is polyglycerol-2-dimeric hydroxystearate (…). PGPH), polyglycerol-3-diisostearate ( TGI), polyglycerol-4 isostearate ( GI 34), polyglycerol-3 oleate, diisostearoyl polyglycerol-3 diisostearoate ( PDI), polyglycerol-3-methylglucose distearate (Tego) 450), polyglycerol-3 beeswax (Cera) ), polyglycerol-4-decanoate (polyglycerol decanoate T2010 / 90), polyglycerol-3-ceryl ether ( NL), polyglycerol-3 distearate ( GS 32) and polyglycerol polyricinoleate ( WOL 1403), polyglyceryl diisostearate esters, and mixtures thereof. Other suitable examples of polyol esters are monoesters, diesters, and trimers of lauric acid, coconut oil acid, tartrate, palmitic acid, stearic acid, oleic acid, behenic acid, etc., reacted with 1 to 30 moles of ethylene oxide with trimethylolpropane or pentaerythritol.

[0039] Tetraalkyl quaternary ammonium salts. Cationic surfactants in aqueous solution contain hydrophobic polymer groups required for the surface activity of the dissociated cation. An important representative of cationic surfactants is the general formula (R...). 1 R 2 R 3 R 4 N + )X - A tetraalkyl quaternary ammonium salt. Where R1 represents a C1-C8 alkyl (alkene) group, R... 2 、R 3 and R 4 Each of these groups independently represents an alkyl (alkene) group containing 1 to 22 carbon atoms. X is a counterion, preferably from halogens, alkyl sulfates, and alkyl carbonates. Cationic surfactants are particularly preferred, wherein the nitrogen atom is replaced by two long acyl groups and two short alkyl (alkene) groups.

[0040] Ester quaternary ammonium salts. A group of cationic surfactants, particularly used as co-surfactants in this invention, are so-called ester quaternary ammonium salts. Ester quaternary ammonium salts generally refer to quaternized fatty acid triethanolamine esters. They are known compounds that can be obtained by methods related to preparative organic chemistry. Reference is made in this regard to International Patent Application WO 91 / 01295A1, in which triethanolamine is partially esterified with a fatty acid in the presence of hypophosphite, air is passed through the reaction mixture, and subsequently the entire mixture is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, German Patent DE 4308794 C1 discloses a method for preparing solid ester quaternary ammonium salts, wherein the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0041] A typical example of an ester quaternary ammonium salt suitably used according to the invention is a product whose acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, wherein RCO is an acyl group containing 6 to 10 carbon atoms, and the amino component is triethanolamine (TEA). Examples of such monocarboxylic acids are hexanoic acid, octanoic acid, decanoic acid, and technical mixtures thereof, such as, for example, so-called head fractionated fatty acids. Preferred ester quaternary ammonium salts are those whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms. Other ester quaternary ammonium salts are those whose acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid, and / or dodecanoic acid, but those of adipic acid are preferred. In general, ester quaternary ammonium salts are preferred whose acyl component is derived from a mixture of monocarboxylic acids containing 6 to 22 carbon atoms and adipic acid. In the final ester quaternary ammonium salt, the molar ratio of monocarboxylic acid to dicarboxylic acid is 1:99 to 99:1, and preferably 50:50 to 90:10 and more particularly 70:30 to 80:20. Besides quaternized fatty acid triethanolamine esters, other suitable ester quaternary ammonium salts are quaternized esters of mixtures of mono / dicarboxylic acids with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. The ester quaternary ammonium salt can be obtained from fatty acids and corresponding triglycerides mixed with the corresponding dicarboxylic acid. One such method, representative of the relevant prior art, is proposed by European Patent EP 0750606B1. To prepare the quaternized ester, a mixture of mono and dicarboxylic acids with triethanolamine in a molar ratio of 1.1:1 to 3:1 can be used—based on the available carboxyl functional groups. Considering the properties of the ester quaternary ammonium salt, a ratio of 1.2:1 to 2.2:1, and particularly 1.5:1 to 1.9:1, has proven particularly advantageous. Preferred ester quaternary ammonium salts are technical mixtures of mono-, di-, and tri-esters with an average degree of esterification of 1.5 to 1.9. Fat enrichment agents and consistency factors

[0042] The fat enrichment agent can be selected from substances such as lanolin and lecithin, as well as polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, among which fatty acid alkanolamides can also be used as foam stabilizers.

[0043] The main consistency factors used are aliphatic alcohols or hydroxyaliphatic alcohols containing 12 to 22, preferably 16 to 18, carbon atoms, as well as glycerides, fatty acids, or hydroxy fatty acids. These substances are preferably used in combination with alkyl oligoglucosides and / or fatty acids of the same chain length, N-methylglucamide, and / or polyglycerol poly-12-hydroxystearate. Thickeners and rheology modifiers

[0044] Suitable thickeners are polymeric thickeners, such as... Hydrophilic silica, polysaccharides, especially xanthan gum, guar gum, agar, alginate and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and relatively high molecular weight polyethylene glycol monoesters and diesters, polyacrylates (e.g.) [Goodrich] or [Sigma]), polyacrylamide, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as ethoxylated fatty acid glycerides, fatty acids and polyols such as pentaerythritol or trimethylolpropane esters, aliphatic alcohol ethoxylates with narrow homologue distributions, and electrolytes such as sodium chloride and ammonium chloride. polymer

[0045] Suitable cationic polymers are, for example, cationic cellulose derivatives, such as those available from Amerchol as PolymerJR. The names obtained are quaternized hydroxyethyl cellulose, cationic starch, diallyl ammonium salt and acrylamide copolymers, quaternized vinylpyrrolidone / vinylimidazol polymers, for example (BASF), condensates of polyethylene glycol and amines, quaternized collagen peptides, such as lauryl diammonium hydroxypropyl hydrolyzed collagen ( L, Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic organosilicon polymers, such as amino polydimethylsiloxane, adipic acid and a copolymer of dimethylaminohydroxypropyl diethylenetriamine ( Sandoz), a copolymer of acrylic acid and dimethyl diallyl ammonium chloride ( 550, Chemviron), polyamino polyamides and their crosslinked water-soluble polymers, cationic chitin derivatives, such as quaternized chitosan, optionally with microcrystalline distribution, dihaloalkanes, such as dibromobutane, condensation products with dialkylamines, such as dimethylamino-1,3-propane, cationic guar gum, such as Celanese CBS C-17 C-16, quaternary ammonium salt polymers, such as Miranol. A-15 AD-1, AZ-1, and can be marketed under the trade name CC or 300 found various polyquaternium salt types (e.g., 6, 7, 32, or 37).

[0046] Suitable anionic, amphoteric, amphoteric, and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked and polyol-crosslinked polyacrylic acid, acrylamide propyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacrylate / tert-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinylcaprolactam terpolymers, and optionally derived cellulose ethers and organosilicones. Pearl wax

[0047] Suitable pearlescent waxes are, for example, alkyl glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coconut fatty acid diethanolamides; glyceryl esters, especially monoglycerides of stearate; esters of poly(substituted carboxylic acids) with aliphatic alcohols having 6-22 carbon atoms, especially long-chain esters of tartaric acid; aliphatic substances having a total of at least 24 carbon atoms, such as aliphatic alcohols, aliphatic ketones, aliphatic aldehydes, aliphatic ethers and aliphatic carbonates, especially lauryl ketones and distearates; fatty acids such as stearic acid, hydroxystearic acid or behenic acid; ring-opening products of epoxyolefins having 12-22 carbon atoms and aliphatic alcohols having 12-22 carbon atoms and / or polyols having 2-15 carbon atoms and 2-10 hydroxyl groups, and mixtures thereof. silicone

[0048] Suitable silicones are selected from the group including: theophylline methylsilanol mannouronate, acetyl methionyl methylsilanol elastomeric esters, acrylates / behenol acrylates, acrylates / polydimethylsiloxane methacrylate copolymers, acrylates / behenol methacrylates / polydimethylsiloxane methacrylate copolymers, acrylates / dihydroxypropyl polydimethylsiloxane crosspolymers, acrylates / polydimethylsiloxane copolymers, acrylates / polydimethylsiloxane methacrylates / ethylhexyl acrylate copolymers, acrylates / polydimethylsiloxane alcohol acrylate copolymers, and acrylates / ethylhexyl acrylates / polydimethylsiloxane methacrylates. Ester copolymers, acrylates / octylacrylamide / diphenylamino-terminated polydimethylsiloxane copolymers, acrylates / polytrimethylsiloxane methacrylate copolymers, acrylates / propyl polytrimethylsiloxane methacrylate copolymers, acrylates / stearyl acrylate / polydimethylsiloxane methacrylate copolymers, acrylates / tridecyl acrylate / triethoxysilylpropanol methacrylate / polydimethylsiloxane methacrylate copolymers, acrylates / trifluoropropyl methacrylate / polytrimethylsiloxane methacrylate copolymers, aminodipropylpolydimethylsiloxane, aminoethylaminopropylpolydimethylsiloxane, aminopropylpolydimethylsiloxane, amino Propylphenyl polytrimethylsiloxane, aminopropyltriethoxysilane, polydimethylsiloxane PEG-7 ammonium sulfate, amino-terminated polydimethylsiloxane, amino-terminated polydimethylsiloxane hydroxystearate, amino-terminated polydimethylsiloxane / silsesquioxane copolymer, ascorbic acid carboxydecyltrisiloxane, ascorbic acid methylsilanol pectate, behenoxy polydimethylsiloxane, behenyltrimethylammonium polydimethylsiloxane PEG-8 phthalate, behenyl polydimethylsiloxane, bisaminoPEG / PPG-41 / 3 aminoethyl PG-propyl polydimethylsiloxane, bis-aminopropyl / ethoxyaminopropyl polydimethylsiloxane, bis(butyl benzoate) diaminotriazine aminopropyltrisiloxane, bis-butyl polydimethylsiloxane polyglycerol- 3. Bis-butoxy amino-terminated polydimethylsiloxane / PEG-60 copolymer, bis(C13-15alkoxy)hydroxybutamido amino-terminated polydimethylsiloxane, bis(C13-15alkoxy)PG-amino-terminated polydimethylsiloxane, bis-(C1-8 alkyllauroyl lysine decyl formamide) polydimethylsiloxane, bis-cetylcetyl polydimethylsiloxane, bis-cetyl / PEG-8cetyl PEG-8 polydimethylsiloxane, bis-diphenylethyl dipolysiloxane, bis-ethylethyl polymethylsiloxane, bis-glucamide ethyl-aminopropyl polydimethylsiloxane, bis-hydrogen polydimethylsiloxane, bis-hydroxyethoxypropyl polydimethylsiloxane bis-hydroxylauryl, polydimethylsiloxane / IPDI copolymer,Bis-hydroxy / methoxyamino-terminated polydimethylsiloxane, bis-hydroxypropyl polydimethylsiloxane behenate, bis-hydroxypropyl polydimethylsiloxane / SMDI copolymer, bis-isobutyl PEG-14 / amino-terminated polydimethylsiloxane copolymer, bis-isobutyl PEG-15 / amino-terminated polydimethylsiloxane copolymer, bis-isobutyl PEG / PPG-20 / 35 / amino-terminated polydimethylsiloxane copolymer, bis-isobutyl PEG / PPG-10 / 7 / polydimethylsiloxane copolymer, bis-isobutyl PEG-24 / PPG-7 / polydimethylsiloxane copolymer, bis-PEG-1 polydimethylsiloxane, bis-PEG-4 polydimethylsiloxane, bis-PEG-8 polydimethylsiloxane, bis-PEG -12 polydimethylsiloxane, bis-PEG-20 polydimethylsiloxane, bis-PEG-12 polydimethylsiloxane beeswax ester, bis-PEG-12 polydimethylsiloxane candelilla wax ester, bis-PEG-15 polydimethylsiloxane / IPDI copolymer, bis-PEG-15 methyl ether polydimethylsiloxane, bis-PEG-18 methyl ether dimethylsiloxane, bis-PEG / PPG-14 / 14 polydimethylsiloxane, bis-PEG / PPG-15 / 5 polydimethylsiloxane, bis-PEG / PPG-18 / 6 polydimethylsiloxane, bis-PEG / PPG-20 / 20 polydimethylsiloxane, bis-PEG / PPG-16 / 16PEG / PPG-16 / 16 polydimethylsiloxane Dimethylsiloxane, bis-PEG / PPG-20 / 5PEG / PPG-20 / 5 polydimethylsiloxane, bisphenylhexamethylsiloxane, bis-phenylpropyl polydimethylsiloxane, bispolyethylene polydimethylsiloxane, bis(polyglycerol-3-oxyphenylpropyl) polydimethylsiloxane, bis-(polyglycerol-7-oxyphenylpropyl) polydimethylsiloxane, bis-PPG-15 polydimethylsiloxane / IPDI copolymer, bis(PPG-7 undecenol polyether-21) polydimethylsiloxane, bis-stearyl polydimethylsiloxane, bis-trimethoxysilylethyltetramethyldisiloxyethyl polydimethylsiloxane, bis-vinyl polydimethylsiloxane, bis-vinyl polydimethylsiloxane / polydimethylsiloxane copolymer, borage seed oil PEG -7 Polydimethylsiloxane esters, butyl acrylate / C6-14 perfluoroalkyl ethanol acrylate / mercaptopropyl polydimethylsiloxane copolymer, butyl acrylate / hydroxypropyl polydimethylsiloxane acrylate copolymer, butyl polydimethylsiloxane acrylate / cyclohexyl methacrylate / ethylhexyl acrylate copolymer, butyl polydimethylsiloxane methacrylate / methyl methacrylate crosspolymer, tert-butyldimethylsiloxane grape seed extract, butyl polydimethylsiloxane ethylene / propylene / ethylene norbornene copolymer, C6-8 alkylC3-6 alkyl glucoside polydimethylsiloxane, C20-24 alkyl polydimethylsiloxane, C24-28 alkyl polydimethylsiloxane, C26-28 alkyl polydimethylsiloxaneC30-45 alkyl polydimethylsiloxane, C30-60 alkyl polydimethylsiloxane, C32 alkyl polydimethylsiloxane, C30-45 alkyl polydimethylsiloxane / polycyclohexene oxide crosslinked polymer, C26-28 alkanol dimethylsilane polypropylsilsesquioxane, C30-45 alkanol dimethylsilane polypropylsilsesquioxane, C20-24 alkyl polymethylsiloxane, C24-28 alkyl polymethylsiloxane, C26-28 alkyl polymethylsiloxane, C30-45 alkyl polymethylsiloxane, C20-28 alkyl polymethylsiloxane Fluorodecylethoxy polydimethylsiloxane, C26-54 alkyltetradecyl polydimethylsiloxane, octyl polydimethylsiloxane, octyl polydimethylsiloxane ethoxyglucoside, octyl polymethylsiloxane, octyl polytrimethylsiloxane, carboxydecyltrisiloxane, castor oil bis-hydroxypropyl polydimethylsiloxane esters, wax-based polydimethylsiloxane, cetearyl polydimethylsiloxane crosspolymer, cetearyl polydimethylsiloxane / vinyl polydimethylsiloxane crosspolymer, cetearyl polymethylsiloxane, cetrimonium carboxydecyl PEG-8 polydimethylsiloxane Cetyl alkyl salts, cetrimonium polydimethylsiloxane PEG-7 phthalate salts, cetyl behenyl alcohol polydimethylsiloxane salts, cetyl polydimethylsiloxane, cetyl polydimethylsiloxane / bisvinyl polydimethylsiloxane crosspolymer, cetyl hexadecyl polydimethylsiloxane, cetyloxy polydimethylsiloxane, cetyl PEG-8 polydimethylsiloxane, cetyl PEG / PPG-15 / 15 butyl ether polydimethylsiloxane, cetyl PEG / PPG-7 / 3 polydimethylsiloxane, cetyl PEG / PPG-10 / 1 polydimethylsiloxane Methylsiloxane, cetyltriethylammonium polydimethylsiloxane PEG-8 phthalate, cetyltriethylammonium polydimethylsiloxane PEG-8 succinate, acetyltyrosine copper methylsilanol, PCA methylsilanol copper, C4-14 perfluoroalkyl ethoxy polydimethylsiloxane, cycloethoxy polymethylsiloxane, cycloheptane, cyclohexylsiloxane, cyclopolydimethylsiloxane, cyclopentamethoxysiloxane, cyclophenyl polymethylsiloxane, cyclotetramethylsiloxane, cyclovinyl polymethoxysilane, cystine bis-PG-propylsilanetriol, DEA PG-propyl PEG / PPG-18 / 21 polydimethylsiloxane, diisostearoyl trimethylolpropane siloxysilicate, dilauroyl trimethylolpropane siloxane alkylsilicate, di-linoleamide propyl dimethylamine polydimethylsiloxane PEG-7 phosphate, polydimethylsiloxane, polydimethylsiloxane crosspolymer, polydimethylsiloxane crosspolymer-3, polydimethylsiloxane / divinyl polydimethylsiloxane / silsesquioxane crosspolymer, polydimethylsiloxane ethoxyglucoside, polydimethylsiloxane hydroxypropyltrimethylammonium chloride, polydimethylsiloxane / mercaptopropyl polymethylsiloxane copolymer, polydimethylsiloxane PEG-15 acetate.Polydimethylsiloxane PEG-8 adipate, polydimethylsiloxane PEG-7 avocado oleate, polydimethylsiloxane PEG-8 avocado oleate, polydimethylsiloxane PEG-8 beeswax ester, polydimethylsiloxane PEG-8 benzoate, polydimethylsiloxane PEG-8 borage oleate, polydimethylsiloxane PEG-7 cocoate, polydimethylsiloxane / PEG-10 crosspolymer, polydimethylsiloxane PEG-10 / 15 crosspolymer, polydimethylsiloxane / PEG-15 crosspolymer, polydimethylsiloxane PEG-7 isostearate, polydimethylsiloxane PEG-8 isostearate, polydimethylsiloxane PEG-7 lactate, polydimethylsiloxane PEG -8 lanolinate, polydimethylsiloxane PEG-8 lauryl ester, polydimethylsiloxane PEG-8 meadowfoam seed oleate, polydimethylsiloxane PEG-7 octyl dodecyl citrate, polydimethylsiloxane PEG-7 olive oil ester, polydimethylsiloxane PEG-8 olive oil ester, polydimethylsiloxane PEG-7 phosphate, polydimethylsiloxane PEG-8 phosphate, polydimethylsiloxane PEG-10 phosphate, polydimethylsiloxane PEG-7 phthalate, polydimethylsiloxane PEG-8 phthalate, polydimethylsiloxane PEG-8 polyacrylate, polydimethylsiloxane PEG / PPG-20 / 23 benzoate, polydimethylsiloxane PEG / PPG- 7 / 4 phosphate ester, polydimethylsiloxane PEG / PPG-12 / 4 phosphate ester, polydimethylsiloxane PEG-7 succinate, polydimethylsiloxane PEG-8 succinate, polydimethylsiloxane PEG-7 sulfate, polydimethylsiloxane PEG-7 undecanoate, polydimethylsiloxane PG-diethylmethylammonium chloride, polydimethylsiloxane / phenylvinyl polydimethylsiloxane crosspolymer, polydimethylsiloxane / polyglycerol-3 crosspolymer, polydimethylsiloxane / PPG-20 crosspolymer, polydimethylsiloxane propyl ethylenediamine behenate, polydimethylsiloxane propyl PG-betaine, polydimethylsiloxane / silsesquioxane copolymer, silylated polydimethylsiloxane, polydimethyl... Siloxane / vinyl polydimethylsiloxane crosspolymer, polydimethylsiloxane / vinyltrimethylsiloxane silicate crosspolymer, polydimethylsiloxane alcohol, polydimethylsiloxane alcohol arginine, polydimethylsiloxane alcohol beeswax ester, polydimethylsiloxane alcohol behenate, polydimethylsiloxane alcohol sorbate, polydimethylsiloxane alcohol candelilla ester, polydimethylsiloxane alcohol caraway ester, polydimethylsiloxane alcohol brassinate, polydimethylsiloxane alcohol cysteine, polydimethylsiloxane alcohol derupa ester, polydimethylsiloxane alcohol fluoroalcohol dimer linoleic acid polyester, polydimethylsiloxane alcohol hydroxystearate, polydimethylsiloxane alcohol Indian hematite resin ester, polydimethylsiloxane alcohol / IPDI copolymer, polydimethylsiloxane alcohol isostearate.Polydimethylsiloxane alcohol oleate, polydimethylsiloxane alcohol lactate, polydimethylsiloxane alcohol meadowfoam seed oleate, polydimethylsiloxane alcohol methionine, polydimethylsiloxane alcohol / methylsilanol / silicate crosspolymer, polydimethylsiloxane alcohol longleaf limonene oleate, polydimethylsiloxane alcohol panthenol, polydimethylsiloxane alcohol salicylate, polydimethylsiloxane alcohol / silica crosspolymer, polydimethylsiloxane alcohol / silsesquioxane copolymer, polydimethylsiloxane alcohol stearate, polydimethylsiloxane alcohol / stearyl polymethylsiloxane / phenyl polytrimethylsiloxane copolymer, dimethoxysilyl alkyl ethylene diaminopropyl polydimethylsiloxane, dimethylaminopropylamide PCA polydimethylsiloxane Methylsiloxane, dimethyloxobenzodioxane, dimethylsilanol hyaluronic acid ester, dioleotocopherol methylsilanol, diphenylamino-terminated polydimethylsiloxane, diphenylpolydimethylsiloxane, diphenylpolydimethylsiloxane crosspolymer, diphenylpolydimethylsiloxane / vinyldiphenylpolydimethylsiloxane / silsesquioxane crosspolymer, diphenylethylbenzyloxydimethyldisiloxane, diphenylisopropylpolydimethylsiloxane, diphenylsiloxyphenyl / propylpolytrimethylsiloxane, diphenylsiloxyphenylpolytrimethylsiloxane, dipolysiloxane, disodium disuccinate of amino-terminated polydimethylsiloxane, disodium PEG-12 polydimethylsiloxane sulfosuccinate, PEG -8 Disodium lauryl polydimethylsiloxane sulfosuccinate, divinyl polydimethylsiloxane / polydimethylsiloxane copolymer, divinyl polydimethylsiloxane / polydimethylsiloxane crosspolymer, cresoltrazol trisiloxane, ethylhexyl acrylate / VP / polydimethylsiloxane methacrylate copolymer, ethyl polymethylsiloxane, ethyl trisiloxane, fluoroC2-8 alkyl polydimethylsiloxane, glucamidopropylaminopropyl polydimethylsiloxane, 4-(2-β-pyranose glucomethoxy)propoxy-2-hydroxybenzophenone, glyceryl undecyl polydimethylsiloxane, epoxypropoxy polydimethylsiloxane, polyhexylmethylsiloxane, hexyl polydimethylsiloxane, hexyl poly Methylsiloxane, Hexyltrimethoxysilane, Hydrogenated polydimethylsiloxane, Hydrogenated polydimethylsiloxane / octylsilsesquioxane copolymer, Hydrolyzed collagen PG-propyl polydimethylsiloxane alcohol, Hydrolyzed collagen PG-propylmethylsilane diol, Hydrolyzed collagen PG-propylsilane triol, Hydrolyzed keratin PG-propylmethylsilane diol, Hydrolyzed sesame protein PG-propylmethylsilane diol, Hydrolyzed silk PG-propylmethylsilane diol, Hydrolyzed silk PG-propylmethylsilane diol crosspolymer, Hydrolyzed soybean protein / polydimethylsiloxane PEG-7 acetate, Hydrolyzed soybean protein PG-propylmethylsilane diol, Hydrolyzed plant protein PG-propylsilane triol, Hydrolyzed wheat (TRITICUM VULGARE) protein / cystine bis-PG-propylsilane triol copolymer, Hydrolyzed wheat protein / polydimethylsiloxane PEG-7 acetateHydrolyzed wheat protein / polydimethylsiloxane PEG-7 phosphate copolymer, hydrolyzed wheat protein PG-propylmethylsilanediol, hydrolyzed wheat protein PG-propylsilanetriol, hydroxyethyl acetoxymethylammonium PG-polydimethylsiloxane, hydroxypropyl polydimethylsiloxane, hydroxypropyl polydimethylsiloxane behenate, hydroxypropyl polydimethylsiloxane isostearate, hydroxypropyl polydimethylsiloxane stearate, isobutyl methacrylate / bis-hydroxypropyl polydimethylsiloxane acrylate copolymer, isobutyl methacrylate / trifluoroethyl methacrylate / bis-hydroxypropyl polydimethylsiloxane acrylate copolymer, isoamyl alcohol trimethoxycinnamate trisiloxane, isopolyglycerol-3 polydimethylsiloxane, isopolyglycerol-3 polydimethylsiloxane alcohol Isopropyl titanium triisostearate / triethoxysilyl ethyl, polydimethylsiloxane crosspolymer, isostearyl carboxydecyl PEG-8 polydimethylsiloxane, lactoyl methylsilanol elastomeric ester, lauryl polydimethylsiloxane, lauryl polydimethylsiloxane PEG-15 crosspolymer, lauryl polydimethylsiloxane PEG-10 phosphate, lauryl polydimethylsiloxane / polyglycerol-3 crosspolymer, lauryl polymethylsiloxane, lauryl PEG-8 polydimethylsiloxane, lauryl PEG-10 methyl ether polydimethylsiloxane, lauryl PEG-9 polydimethylsiloxane, lauryl PEG / PPG-18 / 18 polymethylsiloxane, lauryl benzene isocyanate Propyl polymethylsiloxane, lauryl styrene-propyl polymethylsiloxane, lauryl polydimethylsiloxane / divinyl polydimethylsiloxane crosspolymer, lauryl polyglycerol-3 polydimethylsiloxane / dimethylsiloxane, lauryl polytrimethylsiloxane, linoleamide-propyl PG-dimethylammonium chloride phosphate polydimethylsiloxane, methacrylpropyltrimethoxysilane, polymethylsiloxane, methoxyamino-terminated polydimethylsiloxane / silsesquioxane copolymer, methoxycinnamoamide-propyl polysilsesquioxane, methoxycinnamoylpropyl silsesquioxane silicate, methoxyPEG-13 ethyl polysilsesquioxane, methoxyPEG / PPG-7 / 3 aminopropyl polydimethylsiloxane, methoxyPEG / PPG-2 5 / 4 polydimethylsiloxane, methoxyPEG-10propyltrimethoxysilane, methyleugenol PEG-8 polydimethylsiloxane, methyl polysiloxane emulsion, methylsilanol acetylmethionine ester, methylsilanol acetyltyrosine ester, methylsilanol ascorbate, methylsilanol carboxymethyl theophylline, methylsilanol carboxymethyl theophylline alginate, methylsilanol elastin ester, methylsilanol glycyrrhizate, methylsilanol hydroxyproline ester, methylsilanol hydroxyproline ester aspartate, methylsilanol mannouronate, methylsilanol PCA ester, methylsilanol PEG-7 glyceryl cocoate, methylsilanol / silicate crosspolymer, methylsilanol spirulina protein ester, methylsilanol tri-PEG-8 glyceryl cocoate.Methyltrimethylsiloxane, methyltrimethoxysilane, myristamidopropyl dimethylamine polydimethylsiloxane PEG-7 phosphate, myristyl polymethylsiloxane, myristyl trisiloxane, nylon-611 / polydimethylsiloxane copolymer, PCA polydimethylsiloxane, PEG-7 amino-terminated polydimethylsiloxane, PEG-8 amino-terminated polydimethylsiloxane, PEG-8 cetyl polydimethylsiloxane, PEG-3 polydimethylsiloxane, PEG-6 polydimethylsiloxane, PEG-7 polydimethylsiloxane, PEG-8 polydimethylsiloxane, PEG-9 polydimethylsiloxane, PEG-10 polydimethylsiloxane, PEG-12 polydimethylsiloxane, PEG-14 polydimethylsiloxane, PE G-17 polydimethylsiloxane, PEG-10 polydimethylsiloxane crosslinked polymer, PEG-12 polydimethylsiloxane crosslinked polymer, PEG-8 polydimethylsiloxane dimer linoleate, PEG-8 polydimethylsiloxane / dimeric linoleic acid copolymer, PEG-10 polydimethylsiloxane / vinyl polydimethylsiloxane crosslinked polymer, PEG-8 distearate methyl ammonium chloride PG-polydimethylsiloxane, PEG-10 / lauryl polydimethylsiloxane crosslinked polymer, PEG-15 / lauryl polydimethylsiloxane crosslinked polymer, PEG-15 / lauryl polydimethylsiloxane ethyl polydimethylsiloxane crosslinked polymer, PEG-8 polymethylsiloxane, PEG-6 polymethylsiloxane acetate PEG-6 methyl ether polydimethylsiloxane, PEG-7 methyl ether polydimethylsiloxane, PEG-8 methyl ether polydimethylsiloxane, PEG-9 methyl ether polydimethylsiloxane, PEG-10 methyl ether polydimethylsiloxane, PEG-11 methyl ether polydimethylsiloxane, PEG-32 methyl ether polydimethylsiloxane, PEG-8 methyl ether triethoxysilane, PEG-10 nonafluorohexyl polydimethylsiloxane copolymer, PEG-4 PEG-12 polydimethylsiloxane, PEG-8 PG cocoyl glucoside polydimethylsiloxane, PEG-9 polydimethylsiloxane ethyl polydimethylsiloxane, PEG / PPG-20 / 22 butyl ether polydimethylsiloxane, PEG / PPG-22 / 22 butyl ether polydimethylsiloxane Alkane, PEG / PPG-23 / 23 butyl ether polydimethylsiloxane, PEG / PPG-24 / 18 butyl ether polydimethylsiloxane, PEG / PPG-27 / 9 butyl ether polydimethylsiloxane, PEG / PPG-3 / 10 polydimethylsiloxane, PEG / PPG-4 / 12 polydimethylsiloxane, PEG / PPG-6 / 4 polydimethylsiloxane, PEG / PPG-6 / 11 polydimethylsiloxane, PEG / PPG-8 / 14 polydimethylsiloxane, PEG / PPG-8 / 26 polydimethylsiloxane, PEG / PPG-10 / 2 polydimethylsiloxane, PEG / PPG-12 / 16 polydimethylsiloxane, PEG / PPG-12 / 18 polydimethylsiloxanePEG / PPG-14 / 4 polydimethylsiloxane, PEG / PPG-15 / 5 polydimethylsiloxane, PEG / PPG-15 / 15 polydimethylsiloxane, PEG / PPG-16 / 2 polydimethylsiloxane, PEG / PPG-16 / 8 polydimethylsiloxane, PEG / PPG-17 / 18 polydimethylsiloxane, PEG / PPG-18 / 6 polydimethylsiloxane, PEG / PPG-18 / 12 polydimethylsiloxane, PEG / PPG-18 / 18 polydimethylsiloxane, PEG / PPG-19 / 19 polydimethylsiloxane, PEG / PPG-20 / 6 polydimethylsiloxane, PEG / PPG-20 / 15 polydimethylsiloxane, PEG / PPG-20 / 20 polydimethylsiloxane, PEG / PPG-20 / 23 polydimethylsiloxane, PEG / PPG-20 / 29 polydimethylsiloxane, PEG / PPG-22 / 23 polydimethylsiloxane, PEG / PPG-22 / 24 polydimethylsiloxane, PEG / PPG-23 / 6 polydimethylsiloxane, PEG / PPG-25 / 25 polydimethylsiloxane, PEG / PPG-27 / 27 polydimethylsiloxane, PEG / PPG-30 / 10 polydimethylsiloxane, PEG / PPG-25 / 25 polydimethylsiloxane / acrylate copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG / PPG-24 / 24-Methyl ether epoxypropoxy polydimethylsiloxane, PEG / PPG-10 / 3 oil-based ether polydimethylsiloxane, PEG / PPG-5 / 3 trisiloxane, PEG-4 trifluoropropyl polydimethylsiloxane copolymer, PEG-8 trifluoropropyl polydimethylsiloxane copolymer, PEG-10 trifluoropropyl polydimethylsiloxane copolymer, PEG-8 trisiloxane, perfluorooctyltriethoxysilylethyl polymethylsiloxane, perfluorononyl polydimethylsiloxane, perfluorononyl polydimethylsiloxane / polymethylsiloxane / ammonia-terminated polydimethylsiloxane crosspolymer, perfluorononylethylcarboxydecylbenzyl polydimethylsiloxane, perfluorononylethylcarboxydecylhexadecyl polydimethylsiloxane, perfluorononylethylcarboxydecyl polydimethylsiloxane Lauryl / behenyl polydimethylsiloxane, perfluorononylethylcarboxydecyl lauryl polydimethylsiloxane, perfluorononylethylcarboxydecyl PEG-8 polydimethylsiloxane, perfluorononylethylcarboxydecyl PEG-10 polydimethylsiloxane, perfluorononylethyl polydimethylsiloxane / polymethylsiloxane copolymer, perfluorononylethyl PEG-8 polydimethylsiloxane, perfluorononylethyl stearyl polydimethylsiloxane, perfluorooctylethyl / diphenyl polydimethylsiloxane copolymer, perfluorooctylethyltriethoxysilane, perfluorooctylethanoltrimethoxysilane, perfluorooctylethyltrisiloxane, perfluorooctyltriethoxysilane, PG-amino-terminated polydimethylsiloxane, phenethyl polydimethylsiloxane, phenethyl disiloxane, phenyl polydimethylsiloxanePhenyl isopropyl polydimethylsiloxane, phenyl polymethylsiloxane, phenyl polymethylsiloxane alcohol, phenylpropyl dimethylsiloxysilicate, phenylpropyl ethyl polymethylsiloxane, phenylpropyl polytrimethylsiloxane, phenylpropyl polytrimethylsiloxane / diphenyl polymethylsiloxane, phenyl polytrimethylsiloxane, divinyldisiloxane platinum, polyacrylate-6, polydiethylsiloxane, polydimethylsiloxane / divinyl dimethylsiloxane crosspolymer, polydimethylsiloxane / polymethylsiloxane copolymer, polydimethylsiloxane PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxane PPG-13 butyl ether silsesquioxane, polyglycerol-3 disiloxane polydimethylsiloxane Poly(glycerol-3 / lauryl polydimethylsiloxane) crosspolymer, poly(glycerol-3) polydimethylsiloxane, poly(ethylene glycol adipate) / dihydroxyethoxypropyl polydimethylsiloxane copolymer, polymethylsilsesquioxane, polymethylsilsesquioxane / trimethylsiloxysilicate, polyphenylsilsesquioxane, polypropylsilsesquioxane, polysiloxane-1, polysiloxane-2, polysiloxane-3, polysiloxane-4, polysiloxane-5, polysiloxane-6, polysiloxane-7, polysiloxane-8, polysiloxane-9, polysiloxane-10, polysiloxane-11, polysiloxane-12, polysiloxane-13, polysiloxane-14, polysiloxane-15, polysiloxane-16, polysiloxane... Polysiloxane-17, Polysiloxane-18, Polysiloxane-19, Polysiloxane-20, Polysiloxane-21, Polysiloxane-18 Cetyl Phosphate, Polysiloxane-1 Crosspolymer, Polysiloxane-18 Stearate, Polyurethane-10, Methylsiloxane PEG-7 Panthenol Phosphate Potassium, Polydimethylsiloxane PEG-7 Phosphate Potassium, PPG-12 Butyl Ether Polydimethylsiloxane, PPG-2 Polydimethylsiloxane, PPG-12 Polydimethylsiloxane, PPG-27 Polydimethylsiloxane, PPG-4 Oleyl Alcohol Polyether-10 Polydimethylsiloxane, Propyleneoxytetramethylpiperidinyl Polydimethylsiloxane, Propylene Trimethylsiloxane, Quaternary Ammonium Salt-80, Retinoxytrimethylsilane, Silane Diol Salicylate, Silane Tri Alcohols, silanetriol arginine ester, silanetriol glutamate ester, silanetriol lysine ester, silanetriol melanin ester, silanetriol trehalose ether, silica, polydimethylsiloxane silylated silica, dimethylsilylated silica, silylated silica, silicon carbide, polysiloxane quaternary ammonium salt-1, polysiloxane quaternary ammonium salt-2, polysiloxane quaternary ammonium salt-2 panthenol succinate, polysiloxane quaternary ammonium salt-3, polysiloxane quaternary ammonium salt-4, polysiloxane quaternary ammonium salt-5, polysiloxane quaternary ammonium salt-6, polysiloxane quaternary ammonium salt-7, polysiloxane quaternary ammonium salt-8, polysiloxane quaternary ammonium salt-9, polysiloxane quaternary ammonium salt-10, polysiloxane quaternary ammonium salt-11, polysiloxane quaternary ammonium salt-12, polysiloxane quaternary ammonium salt-15, polysiloxane quaternary ammonium salt-16.Polysiloxane quaternary ammonium salt-16 / epoxypropoxy polydimethylsiloxane crosspolymer, polysiloxane quaternary ammonium salt-17, polysiloxane quaternary ammonium salt-18, polysiloxane quaternary ammonium salt-19, polysiloxane quaternary ammonium salt-20, polysiloxane quaternary ammonium salt-21, polysiloxane quaternary ammonium salt-22, polysiloxane quaternary ammonium salt-24, polysiloxane quaternary ammonium salt-25, siloxane triol alginate, siloxane triol phytate, organosilicon resin, carboxydecyl PEG-8 sodium polydimethylsiloxane, polydimethylsiloxane PEG-7 sodium acetylmethane taurate, sodium dimethylsilanol hyaluronic acid ester, sodium lactate methylsilanol, sodium mannouronate methylsilanol, sodium PCA methylsilanol, PG-propyl polydimethylsiloxane thiosulfate copolymer sodium, PG-propyl Sodium thiosulfate polydimethylsiloxane, propoxyhydroxypropyl thiosulfate sodium silicate, sorbitol silanediol, soybean triethoxysilylpropyl dimethylammonium chloride, silachlor polydimethylsiloxane PEG-8 phthalate salt, stearamide propyl polydimethylsiloxane, stearyl dimethylammonium hydroxypropyl panthenol PEG-7 polydimethylsiloxane phosphate chloride, stearyl dimethylammonium hydroxypropyl PEG-7 polydimethylsiloxane phosphate chloride, stearyloxy polydimethylsiloxane, stearyloxy polymethsiloxane / polydimethylsiloxane copolymer, stearyloxy trimethylsilane, stearyl aminopropyl polymethylsiloxane, stearyl polydimethylsiloxane, stearyl alcohol / lauryl methacrylate crosspolymer, stearyl polymethylsiloxane, stearyl trimethylsiloxane Ethoxysilane, stearyl polytrimethylsiloxane, styrene / acrylate / polydimethylsiloxane acrylate crosspolymer, styrene / acrylate / polydimethylsiloxane copolymer, polydimethylsiloxane PEG-7 phosphate TEA salt, (tetrabutoxy)propyltrisiloxane, tetramethylhexanetetraphenyltetrasiloxane, tetramethyltetraphenyltrisiloxane, tocopheryloxypropyltrisiloxane, tridecyl alcohol polyether-9PG-amino-terminated polydimethylsiloxane, triethoxyoctylsilane, triethoxysilylethyl polydimethylsiloxane / polymethylsiloxane copolymer, triethoxysilylethyl polydimethylsiloxane, triethoxysilylethyl polydimethylsiloxane, triethoxysilylethyl polydimethylsiloxane, triethoxysilylethyl polydimethylsiloxane, triethoxysilylethyl polydimethylsiloxane, triethoxysiloxane Oxymethylsilylpropylcarbamoylethoxypropylbutyl polydimethylsiloxane, trifluoromethyl C1-4 alkyl polydimethylsiloxane, trifluoropropylcyclopentasiloxane, trifluoropropylcyclotetrasiloxane, trifluoropropyl polydimethylsiloxane, trifluoropropyl polydimethylsiloxane / PEG-10 crosslinked polymer, trifluoropropyl polydimethylsiloxane / trifluoropropyl divinyl polydimethylsiloxane crosslinked polymer, trifluoropropyl polydimethylsiloxane / vinyltrifluoropropyl polydimethylsiloxane / silsesquioxane crosslinked polymer, trifluoropropyl polydimethylsiloxane alcohol, trifluoropropyl dimethyl / trimethylsiloxysilicate, trifluoropropyl polymethylsiloxane, trimethoxyoctylsilane, trimethoxysilyl polydimethylsiloxane, trimethylpentaphenyltrisiloxaneTrimethylsiloxane amino-terminated polydimethylsiloxane, trimethylsiloxane phenyl polydimethylsiloxane, trimethylsiloxane silicate, trimethylsiloxane silicate / polydimethylsiloxane crosslinked copolymer, trimethylsiloxane silicate / polydimethylsiloxane alcohol crosslinked polymer, trimethylsiloxane silylcarbamoyl amylopectin, trimethylsilyl hydrolyzed conchiolin PG-propylmethylsilanediol crosslinked polymer, trimethylsilyl hydrolyzed silk PG-propylmethylsilanediol crosslinked polymer, trimethylsilyl hydrolyzed wheat protein PG-propylmethylsilanediol crosslinked polymer, trimethylsilyl amylopectin, trimethylsilane alcohol tris(methylsiloxane)oxyethanolate, trimethylsiloxane... Trimethylsilane-3-methylsilane-3-methylsilane-3-methylsilane-3-methylsilane-3-methylsilane-3-methylsilane, trisiloxane, tris(tributoxysiloxy)methylsilane, undecene polydimethylsiloxane, vinyl polydimethylsiloxane, vinyl polydimethylsiloxane / lauryl polydimethylsiloxane crosspolymer, vinyl polydimethylsiloxane / polymethylsiloxane silsesquioxane crosspolymer, vinyl dimethyl / trimethylsiloxysilicate / stearyl polydimethylsiloxane crosspolymer, VP / dimethylaminoethyl methacrylate / polyurethane polyethylene glycol, zinc carboxydecyltrisiloxane and zinc polydimethylsiloxane PEG-8 succinate and mixtures thereof.

[0049] The silicone contained in the mixture according to the invention is more preferably polydimethylsiloxane, cyclodimethylsiloxane, phenyltrimethylsiloxane, cyclohexylsiloxane, and cyclopentadimethylsiloxane. A detailed description of suitable volatile siloxane compounds can be found in Todd et al. in Cosm. Toil. 91, 27 (1976). waxes and stabilizers

[0050] In addition to the natural oils used, the formulation may also contain waxes, especially natural waxes such as candelilla wax, carnauba wax, Japanese wax, espartograss wax, cork wax, guaruma wax, rice bran oil wax, sugarcane wax, ouricury wax, lignite wax, beeswax, shellac wax, whale wax, wool wax, uropygial fat, (pure) ceresin, ceresin (paraffin), petroleum jelly, petroleum wax and microwax; chemically modified waxes (hard waxes) such as montan ester waxes, sasolwaxes, hydrogenated jojoba waxes; and synthetic waxes such as polyalkylene waxes and polyethylene glycol waxes.

[0051] Metal salts of fatty acids, such as stearic acid or magnesium ricinoleate, aluminum and / or zinc salts, can be used as stabilizers. Main sunscreen agents

[0052] The main sunscreen agent in this invention is, for example, an organic substance (light-filtering substance) that is liquid or crystalline at room temperature, which can absorb ultraviolet radiation and release the absorbed energy, such as heat, in the form of long-wave radiation.

[0053] The formulations according to the invention advantageously contain at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic dye. The formulations according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly at least one UV-A filter and at least one UV-B filter.

[0054] The UV filter materials used in this invention, as cited below, are preferred, but not limited to, these materials. Preferably, the UV filter material is selected from one, two, three, four, five, or more of the following:

[0055] In a preferred embodiment, component (ii) forming the sunscreen filter represents a blend of UV-A and UV-B filters selected from homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate, and mixtures thereof. A mixture of all these filters is particularly preferred and is commercially available under trademarks. Flat (SYMRISE) is a commercial purchase, and it is also the theme of WO 2020 088778A1.

[0056] Suitable pigments include oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g., MnO), aluminum (Al2O3), cerium (e.g., Ce2O3), and / or mixtures thereof.

[0057] In a further preferred embodiment, the formulation according to the invention comprises a total amount of sunscreen agent, i.e., in particular UV filter and / or inorganic pigment (UV filter pigment), such that the formulation according to the invention has a photoprotective factor greater than or equal to 5 and at most 50. Such formulations according to the invention are particularly suitable for protecting skin and hair. Secondary sunscreen

[0058] In addition to the main sunscreen groups mentioned above, secondary sunscreens with antioxidants can also be used. Antioxidant-based secondary sunscreens block the photochemical reaction chain that occurs when ultraviolet rays penetrate the skin. Typical examples include amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g., uric acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine), carotenoids, carotenoids (e.g., α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g., dihydrolipoic acid), aurora thioglycosides, propylthiouracil, and other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and its glycosyl, N-acetyl, methyl groups, etc.). Ethyl, propyl, pentyl, butyl, lauryl, palmitoyl, oleylenyl, α-linoleyl, cholesterol, and their glycerides) and their salts, dilaurate thiodipropionate, dioctadecyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides, and salts), and sulfonylimine compounds with very low resistance doses (e.g., sulfonyl butyrate, sulfocysteine, sulfonyl butyrate, pentyl, hexa-, and hepta-thionine sulfonylimine), as well as (metal) chelating agents (e.g., α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids Characteristic compounds (e.g., citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and panthenol and their derivatives, vitamin C and its derivatives (e.g., ascorbate palmitate, ascorbate magnesium phosphate, ascorbate acetate), tocopherol and its derivatives (e.g., vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), as well as benzoic acid resins such as benzoyl benzoate, rutin and its derivatives, glycosylrutin, ferulic acid, and fenestrations. Sorbitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiacol, lignan, trihydroxybutyrylbenzene, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (e.g., dispersions in ethanol), zinc and its derivatives (e.g., ZnO, ZnSO4), selenium and its derivatives (e.g., selenomethionine), stilbenes and their derivatives (e.g., stilbene oxide, trans-stilbene oxide), and derivatives of these active compounds suitable for the purposes of this invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids).

[0059] Advantageous inorganic secondary photoprotective pigments are finely dispersed metal oxides and metal salts, which are also mentioned in WO2005123101A1. In the finished cosmetic formulations according to the invention, the total amount of inorganic pigments, particularly hydrophobic inorganic micropigments, is advantageously 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, based on the total weight of the formulation in each case.

[0060] Also preferred are particulate UV filters or inorganic pigments, which may optionally be hydrophobic and may be oxides of, for example, titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g., MnO), aluminum (Al2O3), cerium (e.g., Ce2O3) and / or mixtures thereof.

[0061] Biologics and antioxidants

[0062] Bioactive substances include, for example, tocopherol, tocopheryl acetate, tocopheryl palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmentation products, β-glucan, retinol, bisabolol, allantoin, phytanetriol, panthenol, AHA acid, amino acids, ceramides, pseudoceramides, essential oils, plant extracts such as plum extract, bambaranus extract, and vitamin complexes.

[0063] Antioxidants block the photochemical reaction chain that occurs when ultraviolet light penetrates the skin. Typical examples include amino acids (such as glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (such as uric acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and their derivatives (such as anserine), carotenoids, carotene (carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (such as dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (such as thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, pentyl) Butyl and lauryl, palmitoyl, oleylene, α-linoleyl, cholesterol, and glyceryl esters) and their salts, dilaurate thiodipropionate, dioctadecyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides, and salts), and sulfonyl imine compounds at very low resistance doses (pmol to mol / k) (e.g., sulfonyl butyrate, homocysteine, sulfonyl butyrate, pentyl, hexa-, and hepta-thionine sulfonyl imines), and (metal) chelating agents (e.g., hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin). Hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acids, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g., linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and panthenol and their derivatives, vitamin C and its derivatives (e.g., ascorbate palmitate, ascorbate magnesium phosphate, ascorbate acetate), tocopherol and its derivatives (e.g., vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), as well as benzoic acid benzoate, rutin decaenoic acid and its derivatives. Glycosylrutin, ferulic acid, furfuryl sorbitol, carnosine, butylated hydroxytoluene, butylated hydroxyanisole, nordihydroguaiacol, nordihydroguaiacol, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g., ZnO, ZnSO4), selenium and its derivatives (e.g., methionine selenium), stilbenes and their derivatives (e.g., stilbene oxide, trans-stilbene oxide), and derivatives of these active compounds suitable for the purposes of this invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids).

[0064] Active substances that regulate hair pigmentation

[0065] Preferred active ingredients for hair brightening are selected from the group comprising: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbate phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinol and 4-(1-phenylethyl)1,3-resorcinol (phenylethyl resorcinol), cyclohexyl carbamates (preferably WO3). One or more cyclohexyl carbamate esters disclosed in WO2010 / 122178 and WO2010 / 097480, sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), their salts and esters, N-acetyltyrosine and its derivatives, undecanoylphenylalanine, gluconic acid, chromone derivatives, preferably aloe-emodin, flavonoids, 1-aminoethylphosphonic acid, thiourea derivatives, ellagic acid, niacinamide, zinc salts, preferably zinc chloride or zinc gluconate, cypressin and its derivatives, triterpenoids, preferably crataegolic acid, sterols, preferably ergosterol, benzofuranones, preferably ligustrol, vinyl guaiacol, ethyl guaiacol, dionic acid acids), preferably octadecenoic acid and / or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelating agents (preferably α-hydroxy fatty acids, phytic acid, humic acid, cholic acid, bile extracts, EDTA, EGTA and their derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid, or other synthetic or natural active ingredients for skin and hair brightening, the latter preferably used in the form of plant extracts, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, jicama extract, cyperus extract, licorice root extract or components concentrated or isolated therefrom, preferably glycyrrhizin or glycyrrhizin chalcone M, jackfruit extract, sorrel and uncaria extracts, pine (pine tree) extracts, grape extracts or scutellaria derivatives isolated or concentrated therefrom, saxifrage extract, scutellaria extract. Extracts), grape extracts and / or microalgae extracts, especially *Tetracapterhosum* extract.

[0066] Beneficial active ingredients for skin and hair tanning in this regard are substrates or substrate analogs of tyrosinases, such as L-tyrosine, N-acetyltyrosine, L-DOPA, or L-dihydroxyphenylalanine; xanthine alkaloids, such as caffeine, theobromine, and theophylline and their derivatives; melanocortin propeptides, such as ACTH, α-MSH, their peptide analogs, and other substances that bind to melanocortin receptors; and peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys-lle-Gly-Arg-Lys, or Leu-Ile-Gly. ly-Lys, purines, pyrimidines, folic acid, copper salts such as copper gluconate, copper chloride or copper pyrrolidine, 1,3,4-oxadiazol-2-thiols such as 5-pyrazin-2-yl-1,3,4-oxadiazol-2-thiols, curcumin, zinc diglycinate (Zn(GIy)2), manganese(II) dicarbonate complexes (“pseudocat-alases”), as described, for example, in EP0584178, tetrasubstituted cyclohexene derivatives, as described, for example, in WO2005 / 032501, isoprene terpenes, such as WO The melanin derivatives described in 2005 / 102252 and WO2006 / 010661, such as Melasyn-100 and MelanZe, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogues, activators of adenylate cyclase and compounds that activate the conversion of hair melanosomes into keratinocytes, such as serine proteases or PAR-2 ​​receptor agonists, extracts of plants and parts of the genus Chrysanthemum, extracts of plants and parts of the genus Sanguisorba, walnut extract, urucum extract, rhubarb extract, microalgae extracts, especially Isochrysis galbana, trehalose, erythritol and dihydroxyacetone. Flavonoids that cause skin and hair staining or browning (such as quercetin, rhamnone, kaempferol, rutin, genistein, daidzein, apigenin and genistein, epicatechin, geraniol and geraniol, morin, quercetin, naringin, hesperidin, phlorizin, phlorizin) can also be used.

[0067] The amounts of the aforementioned examples of other active ingredients (one or more compounds) used to adjust skin and hair pigmentation in the products according to the invention are preferably 0.00001 to 30% by weight, more preferably 0.0001 to 20% by weight, and particularly preferably 0.001 to 5% by weight, based on the total amount of the formulation.

[0068] Hair growth activators or inhibitors

[0069] The formulations and products according to the present invention may also contain one or more hair growth activators, i.e., formulations that stimulate hair growth. Hair growth activators preferably comprise pyrimidine derivatives, such as 2,4-diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (Minoxidil) and their derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and their derivatives, xanthine alkaloids, such as caffeine, theobromine and theophylline and their derivatives, quercetin and its derivatives, dihydroquercetin (tacutanein) and its derivatives, potassium channel openers, anti-androgen drugs, synthetic or natural 5-reductase inhibitors, nicotinic acid esters, such as nicotinic acid tocopheryl ester, benzyl nicotinate and C1-C6 alkyl nicotinate, proteins such as tripeptides Lys-Pro-Val, diphthylpren, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cyproterone acetate. Ketones, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (tacrolimus, Fujimycin) and its derivatives, cyclosporine A and its derivatives, zinc and zinc salts, polyphenols, proanthocyanidins, phytosterols such as β-sitosterol, biotin, eugenol, (±)-β-citronellol, panthenol, glycogen, for example derived from mussels, microorganisms, algae, Extracts of plants and plant parts, such as those from the following genera: dandelion (Taraxacum or Taraxacum), ginseng, Vitex negundo, coffee, clematis, cocoa, Asarum heterotropoides, Cucurbita or Sophora japonica, saw palmetto, Sophora flavescens, African pine, millet, Cimicifuga foetida, soybean, clove, smoke tree, hibiscus, tea tree, Paraguayan tea, Isochrysis galanga, licorice, grape, apple, barley or hops, and / or rice or wheat hydrolysates.

[0070] Optionally, the formulations and products according to the present invention may further comprise one or more hair growth inhibitors (as described above), i.e., formulations that slow down or prevent hair growth. The hair growth inhibitors preferably comprise activators, activator derivatives or activator agonists, ornithine decarboxylase inhibitors, such as α-difluoromethylornithine, or pentacyclic triterpenoids such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, γ-glutamyl transpeptidase inhibitors, glutamine transaminase inhibitors, serine protease inhibitors derived from soybean, extracts from microorganisms, algae, various microalgae, or plants and plant parts, such as those from the legume family, solanaceae family, grass family, asclepiadaceae family, or cucurbitaceae family, *Chloranthus*, *Hydrocotyle*, *Gnaphalium*, *Dourville*, *Glycine*, *Sanguisorba*, *Calendula*, *Hamamelis*, *Montana*, *Salix*, *St. John's wort*, or *Gymnema*.

[0071] physiological cooling agents and warming agents

[0072] Physiological cooling agents are preferably selected from the types described in the table below (including their optical isomers and racemates):

[0073] Physiological thermogenic agents can be selected from the group including capsaicin, dihydrocapsaicin, nordihydrocapsaicin, high capsaicin, high dihydrocapsaicin, N-vanillylnonivamide, and chili extract. Anti-inflammatory agents

[0074] Suitable anti-inflammatory agents are selected from the following groups: (i) Corticosteroid anti-inflammatory substances, especially hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) Nonsteroidal anti-inflammatory drugs, especially oxoxacins such as piroxicam or tenoxac, salicylates such as aspirin, disalicylate, solprin or fendosalicylate, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tomatine or clindanac, methylphenidate such as mefenamic acid, meclofenamic acid, flufenamic acid or niflufenic acid, propionic acid derivatives such as ibuprofen, methoxynaphthylpropionic acid or benzoxalofen, pyrazoles such as phenylbutazone, hydroxyphenylbutazone, febrazone or azaacetone. (iii) Natural or naturally occurring anti-inflammatory substances or substances that relieve redness and / or itching, especially extracts or fractions of chamomile, aloe vera, myrrh, madder, willow, willow grass, oats, calendula, arnica, St. John's wort, honeysuckle, rosemary, passionflower (Passiflora incarnata), witch hazel, ginger, or purple daisy, or single active compounds thereof. (iv) Histamine receptor antagonists, serine protease inhibitors (e.g., soybean extract), TRPV1 antagonists (e.g., 4-tert-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropionamide benzoic acid), cannabinoid receptor agonists (e.g., palmitoylethanolamine), and TRPV3 antagonists. antimicrobial agents

[0075] A suitable antimicrobial agent is theoretically any substance capable of resisting Gram-positive bacteria, such as 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chlorophenol, 3-( 4-Chlorophenoxy)-1,2-propanediol, butyl 3-iodo-2-propynylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbamate (TTC), antibacterial fragrance, thymol, thymol oil, eugenol, clove oil, menthol, peppermint oil, farnesol, phenoxyethanol, glyceryl monodecanoate, glyceryl monocaprylate, glyceryl monolaurate (GML), diglyceryl monodecanoate (DMC), N-alkylamine salicylate, such as n-octylsalicylate or n-decylsalicylate.

[0076] enzyme inhibitors

[0077] Suitable enzyme inhibitors are, for example, esterase inhibitors. These inhibitors are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, and, in particular, triethyl citrate (HydagenCAT). These substances inhibit enzyme activity, thereby reducing odor formation. Other suitable substances as esterase inhibitors are sterol sulfates or phosphates, such as lanosterol sulfate or phosphate, cholesterol sulfate or phosphate, campesterol sulfate or phosphate, stigmasterol sulfate or phosphate, and sitosterol sulfate or phosphate; dicarboxylic acids and their esters, such as glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipic acid, diethyl adipic acid, malonic acid, and diethyl malonate; hydroxycarboxylic acids and their esters, such as citric acid, malic acid, tartaric acid, or diethyl tartarate; and zinc glycinate.

[0078] Odor absorbents and antiperspirants

[0079] Suitable odor absorbers are substances capable of absorbing and largely retaining odor-forming compounds. They lower the partial pressure of the components, thereby reducing their diffusion rate. It is important that the fragrance remains undamaged during this process. Odor absorbers have no effect on bacteria. They contain, for example, complex zinc salts of ricinoleic acid as a main component, or specific main odor-neutralizing fragrances known to those skilled in the art as "fragrance fixatives," such as extracts of rockrose or styrax, or some abietic acid derivatives. Odor masking agents are fragrances or aromatic oils that, in addition to their function as odor maskers, also impart their respective fragrance to deodorants. Aromatic oils that may be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, fruits, peels, roots, wood, herbs and grasses, pine needles and twigs, as well as resins and balsams. Animal products, such as civet and castoreum, are also suitable. Typical synthetic aromatic compounds are esters, ethers, aldehydes, ketones, alcohols, and hydrocarbon products. Ester aromatic compounds include, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styraxyl propionate, and benzyl salicylate. Ethers include, for example, benzyl ethyl ether; aldehydes include, for example, straight-chain alkanes containing 8 to 18 carbon atoms, citral, citronellol, citronelloloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellol, lily of the valley aldehyde, and bourgeonal; ketones include, for example, ionone and methyl cedrol; alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenethyl alcohol, and terpineol; hydrocarbons mainly include terpenes and balsams. However, it is preferable to use mixtures of different aromatic compounds that together produce a pleasant fragrance. Essential oils with low volatility that are commonly used as aromatic components are also suitable as aromatic oils, such as sage oil, chamomile oil, clove oil, bee pollen oil, peppermint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, frankincense oil, galbanum oil, rockrose oil, and lavender oil.Bergamot oil, dihydromyrcenol, lily aldehyde, neolily aldehyde, citronellol, phenethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamate aldehyde, linalool, boisambrene forte, ambergris, indole, methyl dihydrojasmone, sandelice, lemon oil, citrus oil, orange oil, isopentoxyethyl acetate, cyclovertal, lavender oil, sage oil, β-damascone, bourbon geranium oil, cyclohexyl salicylate, VertofixCoeur, Iso-E-Super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geraniol acetate, benzyl acetate, rose ether, romilat, ethyl 2-ethylhexanoate, and 2-tert-butylcyclohexylethyl carbonate.

[0080] Suitable astringent and antiperspirant active ingredients are primarily salts of aluminum, zirconium, or zinc. These suitable antihydrotic active ingredients include, for example, aluminum chloride, aluminum hydrochloride, aluminum dihydrochloride, aluminum sesquihydrochloride, and their complexes, such as complexes with 1,2-propanediol; aluminum allantoinate; aluminum tartrate chloride; aluminum zirconium trihydrochloride, aluminum zirconium tetrahydrochloride, aluminum zirconium pentahydrochloride, and their complexes, such as complexes with amino acids like glycine.

[0081] Film-forming agents and anti-dandruff agents

[0082] Standard film-forming agents include, for example, chitosan, microcrystalline chitosan, quaternary ammonium chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, acrylic polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts and similar compounds.

[0083] A suitable anti-dandruff agent is Pirocton Olamin (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridone monoethanolamine salt). (clomibazole) (4-Acetyl-1-{4-[2-(2,4-dichlorophenyl)r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxylan-c-4-ylmethoxyphenyl}-piperazine, ketoconazole, neoconazole, selenium disulfide, colloidal sulfur, sulfur-modified polyethylene glycol dehydrated sorbitan monooleate, sulfur-modified ricinoleic acid polyethoxylate, sulfur tar fraction, salicylic acid (or conjugated hexachlorophenol), undecanoic acid, sodium monoethanolamide sulfosuccinate. UD (protein / undecenoic acid concentrate), zinc pyrithione, aluminum pyrithione, and magnesium pyrithione / bispyrithione magnesium sulfate.

[0084] Carrier and water-soluble agent

[0085] Preferred cosmetic carrier materials are solid or liquid (including high-viscosity substances) at 25°C and 1013 mbar, such as glycerol, 1,2-propanediol, 1,2-butanediol, 1,3-propanediol, 1,3-butanediol, ethanol, water, and mixtures of two or more of the said liquid carrier materials with water. Optionally, these formulations of the present invention can be prepared using preservatives or solubilizers. Other preferred liquid carrier materials that can be used as components of the formulations of the present invention are selected from the group consisting of oils, such as vegetable oils, neutral oils, and mineral oils.

[0086] Preferred solid carrier substances that can be used as components of the formulations of the present invention are hydrocolloids, such as starch, degraded starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a glucose value of 5 to 25, more preferably 10 to 20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, gum agar, guanosine gum, carrageenan, pullulan, gelatin, xanthan gum, gellan gum, guar gum, carob powder, alginate, agar, pectin and inulin, as well as mixtures of two or more of these solid substances, especially maltodextrin (preferably with a glucose value of 15 to 20), lactose, silicon dioxide and / or glucose.

[0087] In addition, water-soluble agents, such as ethanol, isopropanol, or polyols, can be used to improve flowability. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. Such polyols may contain other functional groups, more specifically amino groups, or may be nitrogen-modified. Typical examples include: ·glycerin; Alkanediols, such as ethylene glycol, diethylene glycol, propylene glycol, butanediol, hexanediol, and polyethylene glycol with an average molecular weight of 100 to 1000 Daltons; • Oligoglyceride technical mixtures with a degree of self-condensation of 1.5 to 10, such as diglyceride technical mixtures with a diglyceride content of 40 to 50% by weight; • Hydroxymethyl compounds, particularly, for example, trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; • Lower alkyl glycosides, especially those alkyl glycosides containing 1 to 8 carbon atoms in the alkyl group, such as methyl glycosides and butyl glycosides; • Sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol or mannitol; • Sugars containing 5 to 12 carbon atoms, such as glucose or sucrose; Amino sugars, such as glucosamine; Diolamines, such as diethanolamine or 2-aminopropane-1,3-diol Preservatives and / or product protectants

[0088] Suitable preservatives are listed in Annex 6A and B of the Cosmetics Directive.

[0089] Suitable preservatives may be selected from the following group: benzoic acid and p-hydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, o-, m- and p-anisaldehyde, cinnamaldehyde, cinnamyl alcohol, 2-hydroxydiphenyl ether and its salts, 2-zinc-thiopyridine N-oxide, inorganic sulfites and bisulfites, sodium iodate, chlorobutanol, 4-ethylmercuric-(II)5-amino-1,3-bis(2-hydroxybenzoic acid) Acids), their salts and esters, anhydroacetic acid, formic acid, 1,6-bis(4-amidinyl-2-bromophenoxy)-n-hexane and its salts, sodium salt of ethylmercury(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecenoic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyridine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 4-chloro-m-cresol, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether, 4-chloro-3,5 -Dimethylphenol, 1,1'-methylene-di(3-(1-hydroxymethyl-2,4-dioximidazolidine-5-yl)urea), poly-(hexamethylene biguanide) hydrochloride, (benzyloxymethoxy)-methanol, hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azamonoadamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-di(hydroxymethyl)-5,5-dimethyl-2,4-imidazolinide, 1,2-dibromo-2,4-dicyanbutane, 2, 2'-Methylene-di(6-bromo-4-chlorophenol), bromochlorobenzene, 5-chloro-2-methyl-3(2H)-isothiazolinone and 2-methyl-3(2H)-isothiazolinone mixed with magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazolinone, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy)-1,2-propanediol (Chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, N-alkyl(C12-C22)trimethylammonium bromide and N-alkyl(C 12 -C22 Trimethylammonium chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazoline-4-yl)-N'-hydroxymethylurea, 1,6-di(4-formamidinyl-phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamines, alkyl-(C8-C 18 )-Dimethyl-benzylammonium chloride, alkyl-(C8-C 18 )-Dimethyl-benzylammonium bromide, alkyl-(C8-C 18Dimethyl-benzylammonium saccharide, benzyl hemiacetal, 3-iodo-2-propynyl butylcarbamate, sodium hydroxymethyl-aminoacetate or sodium hydroxymethyl-aminoacetate, imidazolidinyl urea, diazolidinyl urea, sodium hydroxymethylglycinate, DMDM ​​hydantoin, tolphenone, (ethylenedioxy)diethanol, 2-bromo-2-(bromomethyl)pentanilonitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α',α“-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetra(hydroxymethyl)imidazo[4,5-d]imidazo-2,5(1H,3H)-di Ketones, 1,3-bis(hydroxymethyl)-1-(1,3,4-tris(hydroxy-methyl)-2,5-dioxoimidazolidine-4-yl)urea (bisidazolidine urea), 1,3-bis(hydroxy-methyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, 1,3-bis(hydroxymethyl)-1-(1,3,4-tris(hydroxy-methyl)-2,5-dioxoimidazolidine-4-yl)urea (bisidazolidine urea), 1,3-bis(hydroxy-methyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, hexadecylpyridine chloride, octanoyl hydroxamic acid, sorbitol Sorbohydroxamica acid and mixtures thereof, 1,3-propanediol, methylpropanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,2-decanediol, ethylhexylglycerol, hexoxy-prop-1,2-diol, heptaoxy-prop-1,2-diol, octoxy-prop-1,2-diol, 3-phenoxy-prop-1,2-diol, 3-benzyloxy-prop-1,2-diol, 3-phenethoxy-prop-1,2-diol, 3-phenylpropoxy-prop-1,2-diol, 3-methylbenzoxy-prop-1,2-diol, sorbitanolic acid Esters, triclosan, chlorfenapyrazole, Octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-benzylhept-1-ol, glyceryl monolaurate, bis(2-pyridinylthio)zinc 1,1'-dioxide, N,N'-(decylidene 1,10-dipyridin-1-yl-4-ylidene)-dioctane-1-amine dihydrochloride (octinidin dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenylethanol, 3-phenylpropanol, 2-phenoxyethanol, 1-phenoxy-prop-2-ol, 3-phenoxypropanol, benzyl methoxymethanol, 4-hydroxyacetophenone and mixtures thereof.

[0090] aromatic oils

[0091] Appropriate aromatic oils are mixtures of natural and synthetic fragrances. Natural fragrances include extracts of flowers (lily, lavender, rose, jasmine, orange blossom, ylang-ylang), stems and leaves (geranium, patchouli, bitter orange), fruits (fennel, coriander, cilantro, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus root, iris, calamus), woods (pine, sandalwood, guaiac, cedar, mahogany), herbs and grasses (tarragon, lemongrass, sage, thyme), conifers and branches (spruce, fir, pine, dwarf pine), resins and balsams (galbanum, elemi, benzoin, myrrh, frankincense, opoponax). Animal ingredients, such as civet and castoreum, may also be used. spices with woody notes

[0092] Suitable spices with woody notes are selected from the following group: Fragrances with amber notes

[0093] Suitable fragrances with amber notes are selected from the following group: Fruity fragrance

[0094] Suitable fruity fragrances are selected from the following group: Fragrances with musky notes

[0095] Suitable fragrances with a musky note are selected from the following group: The fragrances compiled above also represent preferred embodiments of the secondary fragrances that form the main components of the claimed fragrance composition. dye

[0096] Suitable dyes are, for example, the publications of the German Research Society for Dyes, "Kosmetische". Any of the substances listed in Verlag Chemie, Weinheim, 1984, pp. 81-106 that are suitable for and approved for use in cosmetics. Examples include Carmine A (CI16255), Patent Blue V (CI42051), Indigo (CI73015), Folate (CI75810), Quinoline Yellow (CI47005), Titanium Dioxide (CI77891), Indanthrene Blue RS (CI69800), and Madder Red (CI58000). Luminol can also be used as a fluorescent dye. Advantageous coloring pigments are, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes are, for example, Carmine, Berlin Blue, Chromium Oxide Green, Ultramarine, and / or Manganese Violet. preparation

[0097] The preferred compositions according to the invention are selected from products for treating, protecting, caring for and cleansing skin and / or hair or as cosmetic products, preferably as leave-on products (meaning one or more compounds remain on the skin and / or hair for a longer time compared to rinse-off products).

[0098] The formulations according to the invention are preferably in the form of emulsions, such as W / O (water-in-oil), O / W (oil-in-water), W / O / W (oil-in-water), O / W / O (oil-in-water-in-oil), PIT emulsions, Pickling emulsions, low-oil-content emulsions, micron emulsions or nano emulsions, solutions, such as solutions in oils (fatty oils or fatty acid esters, especially C6-C32 fatty acid C2-C30 esters) or silicone oils, dispersions, suspensions, creams, emulsions or milks, depending on the preparation method and ingredients, gels (including hydrogels, aqueous dispersions, oleogels), sprays (e.g., pump sprays or sprays containing propellants) or foams or impregnation solutions for wiping cosmetics, detergents such as soaps, synthetic detergents, washes, shower and bath formulations, bath products (capsules, oils, tablets, salts, bath salts, soaps, etc.); effervescent formulations, skin care products such as emulsions (as described above), ointments. Pastes, gels (as described above), oils, sesame oils, whey, powders (such as face powder, body powder), perfumes, eau de toilette, aftershave, face masks, eyebrow pencils, lipsticks, roll-ons, pump dispensers, aerosols (foaming, non-foaming, or post-foaming), deodorants and / or antiperspirants, mouthwash and oral cleansers, foot care products (including exfoliants and deodorants), insect repellents, sunscreens, after-sun products, shaving products, aftershave creams, pre- and post-shave washes, depilatory products, hair care products. Products such as shampoos (including 2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, dry hair shampoos, and concentrated shampoos), conditioners, hair growth oils, hair growth solutions, hair dyes, styling creams, hair oils, perming and curling solutions, hair gels, styling aids (such as gels or waxes), hair smoothing agents (conditioners, relaxants), hair dyes such as short-term direct hair dyes, semi-permanent hair dyes, permanent hair dyes, conditioners, hair mousses, eye care products, cosmetics, makeup removers, or baby products.

[0099] The content of auxiliary substances and additives is 5 to 99% by weight, preferably 10 to 80% by weight, based on the total amount of the formulation. Those skilled in the art can readily determine the amount of cosmetic or skin care auxiliary substances, additives, and fragrances used in each case by simple trial and error, based on the properties of the specific product.

[0100] The formulation may also contain up to 99% by weight, preferably about 5% to about 80% by weight, and more preferably about 10% to about 50% or about 60% to about 80% by weight, water, based on the total weight of the formulation. Detergent composition

[0101] Another object of the present invention relates to a detergent formulation comprising the cyclopropyl derivative or the fragrance composition as described above. The formulation may contain about 0.01 to about 2% by weight, preferably about 0.1 to 1% by weight, of the stated ingredient—based on the formulation. Suitable examples for detergents include heavy-duty powder detergents, heavy-duty liquid detergents, light-duty powder detergents, light-duty liquid detergents, detergent sheets, fabric softeners, hand dishwashing liquids, multi-purpose detergents, etc.

[0102] The detergent compositions according to the invention may contain any of the ingredients commonly used in such compositions, such as anionic, nonionic, cationic, amphoteric or amphoteric (auxiliary) surfactants, organic solvents, builders, enzymes, and additional additives such as stain repellents, thickeners, colorants, and fragrances. Anionic and amphoteric surfactants

[0103] Typical examples of anionic and amphoteric surfactants include: amygdalinamide propylamine oxide, amygdalinamide propyl betaine, aminopropyl lauryl glutamine, C12-15 alkanol sulfate ammonium, C12-16 alkanol sulfate ammonium, octanol polyether sulfate ammonium, glyceryl monocolate sulfate ammonium, cocoyl alcohol sulfate ammonium, cocoyl hydroxyethanesulfonate ammonium, cocoyl sarcosine ammonium, C12-15 alkanol polyether sulfate ammonium, C9-10 perfluoroalkyl sulfonate ammonium, dinonyl sulfosuccinate ammonium, dodecylbenzene sulfonate ammonium, isostearate ammonium, lauryl ether-6 carboxylate ammonium, lauryl ether-8 carboxylate ammonium, lauryl ether sulfate ammonium, lauryl ether-5 sulfate ammonium, lauryl ether-7 sulfate ammonium, lauryl ether-9 sulfate ammonium, etc. Ammonium laurate ether-12 sulfate, ammonium lauroyl sarcosine, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl ether sulfate, ammonium myristyl sulfate, ammonium nonylphenol polyether-4 sulfate, ammonium nonylphenol polyether-30 sulfate, ammonium oleate, ammonium palm kernel oil sulfate, ammonium stearate, ammonium tallowate, isostearyl hydrolyzed collagen AMPD salt, rosin (acyl) hydrolyzed collagen AMPD salt, isostearyl hydrolyzed collagen AMP salt, isostearyl hydrolyzed keratin AMP salt, isostearyl hydrolyzed soybean protein AMP salt, isostearyl hydrolyzed wheat protein AMP salt, apricot oleamidopropyl betaine, arachidic acid, hexyldecyl phosphate arginine salt, avocado oleamidopropyl betaine, avocado oil glyceryl polyether-8 ester, babassu Seed oil acid, babassu oleamide propylamine oxide, babassu oleamide propyl betaine, beeswax acid, behenamidopropyl betaine, behenamine oxide, behenyl alcohol polyether-25, behenyl alcohol polyether-30, behenic acid, behenyl betaine, bis-butyldimethylsiloxane polyglycerol-3, butylphenol polyether-5 carboxylic acid, butylphenol polyether-19 carboxylic acid, butyl dimethyl (hydroxypropyl butyl glucoside) ammonium chloride, butyl dimethyl (hydroxypropyl lauryl glucoside) ammonium chloride, butyl glucoside, butyl glucoside decanoate, butyl glucoside hydroxypropyl trimethyl ammonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid, C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C 9-16 alkyl / cycloalkanes, C10-14 alkylbenzene sulfonic acid, C12-14 alkyl di(aminoethyl)glycine HCl, C9-15 alcohol phosphate esters, Candida albicans / glucose / rapeseed oil methyl ester fermentation products, low erucic acid rapeseed oil amamidopropyl betaine, decanoic acid, hexanoic acid, hexanoyl ethyl glucoside, octanoyl / decanoyl aminopropyl betaine, octanoyl polyether-4 carboxylic acid, octanoyl polyether-6 carboxylic acid, octanoyl polyether-9 carboxylic acid, octanoic acid, octanoyl collagen amino acids, octanoyl glycine, octanoyl hydrolyzed collagen, octanoyl hydrolyzed keratin, octanoyl keratin amino acids, octanoyl silk amino acids, octyl / decyl glucoside, octyl / decyl wheat bran / straw glycosides, octyl glucoside, octyl glyceryl ether, octylpyrrolidone, carnitine, cetearyl alcohol polyether-20.Cetearyl alcohol polyether-23, Cetearyl alcohol polyether-24, Cetearyl alcohol polyether-25, Cetearyl alcohol polyether-27, Cetearyl alcohol polyether-28, Cetearyl alcohol polyether-29, Cetearyl alcohol polyether-30, Cetearyl alcohol polyether-33, Cetearyl alcohol polyether-34, Cetearyl alcohol polyether-40, Cetearyl alcohol polyether-50, Cetearyl alcohol polyether-55, Cetearyl alcohol polyether-60, Cetearyl alcohol polyether-80, Cetearyl alcohol polyether-100, Cetearyl alcohol polyether-25 carboxylic acid, Cetearyl alcohol polyether-2 phosphate, Cetearyl alcohol polyether-4 phosphorus Cetearyl ester, cetearyl alcohol polyether-5 phosphate, cetearyl alcohol polyether-10 phosphate, cetearyl alcohol polyether-20, cetearyl alcohol polyether-23, cetearyl alcohol polyether-24, cetearyl alcohol polyether-25, cetearyl alcohol polyether-30, cetearyl alcohol polyether-40, cetearyl alcohol polyether-45, cetearyl alcohol polyether-150, cetearyl alcohol polyether-8 phosphate, cetearyl alcohol polyether-10 phosphate, cetearyl alcohol polyether-20 phosphate, cetearyl oil alcohol polyether-22, cetearyl oil alcohol polyether-24, cetearyl oil alcohol polyether-25, cetearyl oil alcohol polyether-30, cetyl betaine, Chrysanthemum Sinense flower extract, C12-14 hydroxyalkyl hydroxyethyl β-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropylamine oxide, cocamidopropyl betaine amide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysulfonate betaine, cocamidoamine oxide, cocoaminobutyric acid, cocoaminopropionic acid, cocoyl alcohol polyether-7 carboxylic acid, cocoyl alcohol polyether-4 glucoside, cocoamphopropionic acid, cocoyl betaine amamide amphoteric propionate, cocoyl betaine, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed rice protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed soybean protein, cocoyl dimethyl ammonium hydroxypropyl hydrolyzed wheat protein, cocoyl glucoside, cocoyl glucoside hydroxypropyl trimethylammonium chloride, cocoyl hydroxysulfonate betaine, cocoyl morpholine oxide, coconut acid, coconut oil glyceryl polyether-8 Esters, cocamidopropyl betaine, cocoyl-sulfobetaine, (coconut oil / sunflower oil) amamidopropyl betaine, cocoylcholine methyl sulfate, cocoyl glutamate, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soybean protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn oleic acid, cotton Cottonseed oil acid, cottonseed oil glycerol polyether-8 esters, C10-16 alkanol polyether-1, C10-16 alkanol polyether-2, C11-13 alkanol polyether-6, C11-13 alkanol polyether-9, C11-13 alkanol polyether-10, C11-15 alkanol polyether-30, C11-15 alkanol polyether-40, C12-13 alkanol polyether-1, C12-13 alkanol polyether-23C12-14 Alkyl Polyether-5, C12-14 Alkyl Polyether-9, C13-15 Alkyl Polyether-21, C14-15 Alkyl Polyether-8, C20-22 Alkyl Polyether-30, C20-40 Alkyl Polyether-40, C20-40 Alkyl Polyether-95, C22-24 Alkyl Polyether-33, C30-50 Alkyl Polyether-40, C9-11 Alkyl Polyether-6 Carboxylic Acid, C9-11 Alkyl Polyether-8 Carboxylic Acid, C11-15 Alkyl Polyether-7 Carboxylic acids, C12-13 alkanol polyether-5 carboxylic acid, C12-13 alkanol polyether-7 carboxylic acid, C12-13 alkanol polyether-8 carboxylic acid, C12-13 alkanol polyether-12 carboxylic acid, C12-15 alkanol polyether-7 carboxylic acid, C12-15 alkanol polyether-8 carboxylic acid, C12-15 alkanol polyether-12 carboxylic acid, C14-15 alkanol polyether-8 carboxylic acid, C6-10 alkanol polyether-4 phosphate, C12-13 alkanol polyether-2 phosphate, C12-13 alkanol C12-15 Alkyl Polyether-6 Phosphate, C12-15 Alkyl Polyether-8 Phosphate, C12-15 Alkyl Polyether-10 Phosphate, C12-16 Alkyl Polyether-6 Phosphate, C4-18 Perfluoroalkyl Ethyl Mercaptopropyl Trimethylammonium Chloride, Cocoa Fatty Acid Aminopropyl Betaine, C12-13 Alcohol Sulfate DEA Salt, C12-15 Alcohol Sulfate DEA Salt, Cetearyl Alcohol Polyether-2 Phosphate DEA Salt, Cetyl Alcohol Sulfate DEA Salt, Cocoyl Amphoteric dipropionic acid DEA salt, C12-13 alkanol polyether-3 sulfate DEA salt, cyclocarboxypropyl oleic acid DEA salt, dodecylbenzene sulfonic acid DEA salt, isostearic acid DEA salt, lauryl ether sulfate DEA salt, lauryl sulfate DEA salt, linoleic acid DEA salt, methyl myristate sulfonic acid DEA salt, myristyl ether sulfate DEA salt, myristic acid DEA salt, myristyl sulfate DEA salt, oleyl alcohol polyether-5 phosphate DEA salt, oleyl alcohol polyether-20 phosphate DEA salt, DEA PG-Oleate, Decanol Polyether-7 Carboxylic Acid, Decanol Polyether-7 Glucoside, Decanol Polyether-9 Phosphate, Decylamine Oxide, Decyl Betaine, Decyl Glucoside, Decyl Tetradecyl Alcohol Polyether-30, Decyl Tetradecylamine Oxide, Laurylamide-MEA Sulfosuccinate Diammonium, Lauryl Sulfosuccinate Diammonium, Oleamide-based PEG-2 Sulfosuccinate Diammonium, Dibutoxymethane, DiC12-15 Alkyl Alcohol Polyether-2 Phosphate, Di C12-15 alkanol polyether-4 phosphate, diC12-15 alkanol polyether-6 phosphate, diC12-15 alkanol polyether-8 phosphate, diC12-15 alkanol polyether-10 phosphate, disodium dodecyl butane tetracarboxylate, diethylamine lauryl ether sulfate, sodium diethylhexyl sulfosuccinate, di(hydroxyethyl)C8-10 alkoxypropylamine oxide, di(hydroxyethyl)C9-11 alkoxypropylamine oxideDi(hydroxyethyl)C12-15 alkoxypropylamine oxide, Di(hydroxyethyl)cocoamine oxide, Di(hydroxyethyl)laurylamine oxide, Di(hydroxyethyl)stearylamine oxide, Di(hydroxyethyl)tallowylamine oxide, Polydimethylsiloxane PEG-7 phosphate, Polydimethylsiloxane PEG-10 phosphate, Polydimethylsiloxane PEG / PPG-7 / 4 phosphate, Polydimethylsiloxane PEG / PPG-12 / 4 phosphate, Polydimethylsiloxane / polyglycerol-3 crosspolymer, Polydimethylsiloxane propyl PG-betaine, Dimyroxymethyl phosphate, Dioleoamide ethylhydroxyethyl Methylammonium methyl sulfate, hydrogenated coconut oil acid DIPA salt, lanolin acid DIPA salt, myristic acid DIPA salt, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, dipotassium undecenoyl glutamate, disodium babassulamamide MEA-sulfosuccinate, disodium decanoyl amphoteric acid diacetate, disodium decanoyl amphoteric acid dipropionate, disodium capryloyl amphoteric acid diacetate, disodium capryloyl amphoteric acid dipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetyl phenyl ether disulfonic acid, disodium cetyl sulfosuccinate, disodium cocamidoyl MEA-sulfosuccinate, disodium cocamidoyl MIPA Disodium PEG-4 sulfosuccinate, disodium cocamido-MIPA-sulfosuccinate, disodium cocamido-PEG-3 sulfosuccinate, disodium cocoyl alcohol polyether-3 sulfosuccinate, disodium cocoamphoyl carboxyethyl hydroxypropyl sulfonate, disodium cocoamphoyl diacetate, disodium cocoamphoyl dipropionate, disodium cocoyl glucoside sulfosuccinate, disodium cocoyl sulfosuccinate, disodium cocoyl butyl glucoside Disodium sulfosuccinate-10, disodium cocoyl glutamate, C12-14 alkanol polyether-1, disodium sulfosuccinate, C12-14 alkanol polyether-2, disodium sulfosuccinate, C12-15 alkanol polyether, disodium sulfosuccinate, C12-14 secondary alkanol polyether-3, disodium sulfosuccinate, C12-14 secondary alkanol polyether-5, disodium sulfosuccinate, C12-14 secondary alkanol polyether Disodium 7-sulfosuccinate, disodium C12-14 secondary alkanol polyether-9-sulfosuccinate, disodium C12-14 secondary alkanol polyether-12-sulfosuccinate, disodium decanol polyether-5-sulfosuccinate, disodium decanol polyether-6-sulfosuccinate, disodium decyl phenyl ether disulfonic acid, disodium dihydroxyethyl sulfosuccinoyl undecenoate, disodium dicocoyl ethylenediamine PEG-15 disulfate, hydrogenated cottonseed oil glyceryl ester sulfosuccinate Disodium succinate, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitan citrate, disodium isodecyl sulfosuccinate, disodium isostearamide MEA-sulfosuccinate, disodium isostearamide MIPA-sulfosuccinate, disodium isostearate diacetate, disodium isostearate dipropionate, disodium isostearyl sulfosuccinate, disodium lanolin alcohol ether-5 sulfosuccinate, disodium lauramide MEA-sulfosuccinate.Disodium lauramide MIPA ethylene glycol sulfosuccinate, disodium lauramide PEG-2 sulfosuccinate, disodium lauramide PEG-5 sulfosuccinate, disodium lauryl ether-5 carboxyamphodiacetate, disodium lauryl ether-7 citrate, disodium lauryl ether sulfosuccinate, disodium lauryl ether-6 sulfosuccinate, disodium lauryl ether-9 sulfosuccinate, disodium lauryl ether-12 sulfosuccinate, disodium lauryliminobis(hydroxypropyl)sulfonate, disodium lauryliminodiacetate, disodium lauryliminodiapropionate, disodium lauryliminodiapropionate tocopherol phosphate salt, disodium lauroylamphodiacetate, disodium lauroylamphodiapropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate. Disodium oleamide, disodium lauryl phenyl ether disulfonate, diammonium lauryl sulfosuccinate, disodium myristamide MEA-sulfosuccinate, disodium nonylphenol polyether-10 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium oleamide PEG-2 sulfosuccinate, disodium oleoyl amphoteric dipropionate, disodium oleyl alcohol polyether-3 sulfosuccinate, disodium oleyl alcohol phosphate, disodium oleyl alcohol sulfosuccinate, disodium palmitamide PEG-2 sulfosuccinate, disodium palmitamide-PEG-2 sulfosuccinate, disodium palmitamide-2 sulfosuccinate, disodium PEG-4 cocoamide MIPA-sulfosuccinate, disodium PEG-12 polydimethylsiloxane sulfosuccinate, PEG-8 palmitoleic acid Disodium sulfosuccinate of glycerides, disodium PPG-2-isodecyl alcohol polyether-7-carboxyamphodiacetate, disodium ricinoleic acid amide MEA sulfosuccinate, disodium sitosterol polyether-14 sulfosuccinate, disodium soybean oil amphoteric diacetate, disodium stearamide MEA sulfosuccinate, disodium stearyl iminodipropionate, disodium stearyl amphoteric diacetate, disodium stearyl glutamate, disodium sulfosuccinate monoacylstearamine, disodium stearyl alcohol sulfosuccinate, disodium 2-sulfolarate, disodium 2-sulfopalactate, disodium tallow oleamide MEA sulfosuccinate, disodium tallow amide MEA sulfosuccinate, disodium tallow amphoteric diacetate, disodium tallow iminodipropionate, disodium sulfosuccinate monoacyl tallowamine, tridecanol Disodium sulfosuccinate, disodium undecenoamide MEA sulfosuccinate, disodium undecenoamide PEG-2 sulfosuccinate, disodium undecenoyl glutamate, disodium monowheat germ oleoyl MEA sulfosuccinate, disodium monowheat germ oleoyl PEG-2 sulfosuccinate, disodium wheat germ oleoyl amphoteric diacetate, cocamidoyl diacetate di-TEA salt, oleamide-2 sulfosuccinate di-TEA salt, palmitoyl aspartate di-TEA salt, sodium ditridecyl sulfosuccinate, dodecylbenzene sulfonic acid, erucamide propyl hydroxysulfobetaine, ethylhexyl alcohol polyether-3 carboxylic acid, ethyl PEG-15 cocoamine sulfate salt, octyl glyceryl ether, hexyl decanoic acid, hydrogenated coconut oil acid, hydrogenated lanolin alcohol polyether-25.Hydrogenated herring oil fatty acids, hydrogenated palmitoleic acid, hydrogenated palm kernel oil amine oxide, hydrogenated tallowic acid, hydrogenated tallow-based amine oxide, hydrogenated tallow-based betaine, hydrogenated tallow alcohol polyether-25, hydrogenated tallow yl glutamic acid, hydrogenated Candida albicans extract, hydroxycetyl alcohol polyether-60, hydroxyethyl acetoxymethyl ammonium PG-polydimethylsiloxane, lauryl ether sulfate hydroxyethyl butylamine salt, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl hydroxypropyl C12-15 alkoxypropylamine oxide, hydroxylauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimide C10-40 isoalkyl ester, hydroxysuccinimide C21-22 isoalkyl ester, hydroxysulfonyl betaine, IPDI / PEG-15 soybean oil amine oxide copolymer. IPDI / PEG-15 soybean oil amine ethanol sulfate copolymer, IPDI / PEG-15 soybean oil glycine ester copolymer, lsoceteth-30, isolaurhodium-4 phosphate, isoglycerol-3 polydimethylsiloxane, isoglycerol-3 polydimethylsiloxane, isopropanolamine lanolinate, isopropanolamine dodecylbenzenesulfonate, isostearamide propylamine oxide, isostearamide propyl betaine, isostearamide propyl morpholine oxide, isostearyl alcohol polyether-8, isostearyl alcohol polyether-16, isostearyl alcohol polyether-22, isostearyl alcohol polyether-25, isostearyl alcohol polyether-50, isostearic acid, isostearyl acyl hydrolyzed collagen, jojoba oil PEG-150 esters, jojoba wax PEG-80 esters, etc. Hoba wax PEG-120 esters, lanolin alcohol polyether-20, lanolin alcohol polyether-25, lanolin alcohol polyether-40, lanolin alcohol polyether-50, lanolin alcohol polyether-60, lanolin alcohol polyether-75, lanolin acid, lauramide propylamine oxide, lauramide propyl betaine, lauramide propyl hydroxysulfonyl betaine, laurylamine oxide, lauryl aminopropionic acid, lauryl dimethyl hydroxypropyl decyl glucoside ammonium chloride, lauryl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, lauryl alcohol polyether-16, lauryl alcohol polyether-20, lauryl alcohol polyether-21, lauryl alcohol polyether-23, lauryl alcohol polyether-25, lauryl alcohol polyether-30, lauryl alcohol polyether-38, lauryl alcohol polyether-40, lauryl alcohol polyether-3 carboxylic acid, lauryl Laureth-4 carboxylic acid, Laureth-5 carboxylic acid, Laureth-6 carboxylic acid, Laureth-8 carboxylic acid, Laureth-10 carboxylic acid, Laureth-11 carboxylic acid, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citrate, Laureth-7 citrate, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartrate, Lauric acid, Laurimethylenedipropylene glycol, Laurimethylenedipropionic acid, Lauroyl amphoteric dipropionic acid, Lauroyl β-aminopropionic acidLauroyl collagen amino acids, lauroyl ethyl trimethylammonium methyl sulfate salt, lauroyl hydrolyzed collagen, lauroyl hydrolyzed elastin, lauroyl methyl glucamide, lauroyl sarcosine, lauroyl silk amino acids, lauryl betaine, lauryl polydimethylsiloxane / polyglycerol-3 crosspolymer, lauryl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, lauryl glucoside, lauryl glucoside hydroxypropyl trimethyl ammonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysulfonyl betaine, lauryl malic acid, lauryl methyl glucosamine, (lauryl / nutmeg)-diol hydroxypropyl ether, (lauryl / nutmeg)-based wheat bran / straw glycosides, lauryl polyglycerol-3 polydimethylsiloxane ethyl polydimethylsiloxane, lauryl pyrrolidone, lauryl dimethyl Sulfobetaine, linoleic acid, linolenic acid, linolenic acid, lysine cocoate, macadamia seed oil glyceryl polyether-8 ester, magnesium cocoyl ether sulfate, magnesium cocoyl ether sulfate, magnesium isododecylphenyl sulfonate, magnesium lauryl ether-11 carboxylate, magnesium lauryl ether sulfate, magnesium lauryl ether-5 sulfate, magnesium lauryl ether-8 sulfate, magnesium lauryl ether-16 sulfate, magnesium lauryl ether-3 sulfosuccinate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium methyl cocoyl taurate, magnesium myristyl ether sulfate, magnesium oleyl ether sulfate, magnesium cocoyl ether sulfate / TEA salt, Mannequin glacial mud, coconut oil MEA salt, magnesium lauryl ether-6 carboxylate MEA salt, magnesium lauryl ether sulfate MEA salt, etc. Cinnamyl sulfate MEA salt, PPG-6-Lauryl ether-7-carboxylic acid MEA salt, PPG-8-Stearyl ether-7-carboxylic acid MEA salt, Undecenoic acid MEA salt, Meroxapone 108, Meroxapone 174, Meroxapone 178, Meroxapone 254, Meroxapone 255, Meroxapone 258, Meroxapone 314, MethoxyPEG-450 Amide glutaryl succinamide, MethoxyPEG-450 Amide hydroxysuccinimide succinate, MethoxyPEG-450 Maleimide, Methylmorpholine oxide, Milk amamidopropylamine oxide, Milk amamidopropyl betaine, Mink oil amamidopropylamine oxide, Mink oil amamidopropyl betaine, C12-15 Alkyl alcohol polyether sulfate MIPA salt, Dodecyl Alkylbenzene sulfonic acid MIPA salt, lauryl ether sulfate MIPA salt, lauryl sulfate MIPA salt, mixed isopropanolamine lanolinate, mixed isopropanolamine lauryl sulfate, mixed isopropanolamine myristate, morpholine oleate, morpholine stearate, myristyl alcohol polyether-3 carboxylic acid, myristyl alcohol polyether-5 carboxylic acid, myristyl benzyl dimethyl ammonium chloride, myristamidopropylamine oxide, myristamidopropyl betaine, myristamidopropyl dimethylamine phosphate, myristamidopropyl hydroxysulfonyl betaine, myristamidopropyl PG-dimethylammonium chloride phosphate, myristamine oxide, myristaminopropionic acid, myristic acid, myristoyl ethyltrimethylammonium methyl sulfate salt, myristoyl glutamate, myristoyl hydrolyzed collagenMyristyl sarcosine, Myristyl betaine, Myristyl / Cetylamine oxide, Myristyl dimethyl hydroxypropyl cocoyl glucoside ammonium chloride, Myristyl glucoside, Myristyl phosphate, Nonylphenol polyether-20, Nonylphenol polyether-23, Nonylphenol polyether-25, Nonylphenol polyether-30, Nonylphenol polyether-35, Nonylphenol polyether-40, Nonylphenol polyether-44, Nonylphenol polyether-50, Nonylphenol polyether-100, Nonylphenol polyether-120, Nonylphenol polyether-5 carboxylic acid, Nonylphenol polyether-8 carboxylic acid, Nonylphenol polyether-10 carboxylic acid, Nonylphenol polyether-3 phosphate, Nonylphenol polyether-4 phosphate, Nonylphenol polyether-6 phosphate, Nonylphenol polyether-9 phosphate, Nonylphenol polyether-10 phosphate, Dinonylphenol Polyether-30, Dinonylphenol Polyether-49, Dinonylphenol Polyether-100, Dinonylphenol Polyether-150, Dinonylphenol Polyether-7 Phosphate, Dinonylphenol Polyether-8 Phosphate, Dinonylphenol Polyether-9 Phosphate, Dinonylphenol Polyether-10 Phosphate, Dinonylphenol Polyether-11 Phosphate, Dinonylphenol Polyether-15 Phosphate, Dinonylphenol Polyether-24 Phosphate, Oat Oleamide Propyl Betaine, Octylphenol Polyether-16, Octylphenol Polyether-25, Octylphenol Polyether-30, Octylphenol Polyether-33, Octylphenol Polyether-40, Octylphenol Polyether-70, Octylphenol Polyether-20 Carboxylic Acid, Octyldodecyl alcohol Polyether-20, Octyldodecyl alcohol Polyether-25, Octyldodecyl alcohol Polyether-30, Oleamide Propylamine Oxide, Oleamide Propyl betaine, oleamidopropyl (hydroxysulfonyl)propyl dimethylammonium, oleylamine oxide, oleic acid, oleyl acyl hydrolyzed collagen, oleyl sarcosine, oleyl alcohol polyether-20, oleyl alcohol polyether-23, oleyl alcohol polyether-24, oleyl alcohol polyether-25, oleyl alcohol polyether-30, oleyl alcohol polyether-35, oleyl alcohol polyether-40, oleyl alcohol polyether-44, oleyl alcohol polyether-50, oleyl alcohol polyether-3 carboxylic acid, oleyl alcohol polyether-6 carboxylic acid, oleyl alcohol polyether-10 carboxylic acid, oleyl betaine, olive oil amamidopropylamine oxide, olive oil amamidopropyl betaine, oleic acid, olive oil acyl hydrolyzed wheat protein, stearate of Ophiopogon japonicus extract, ozonated oleyl alcohol polyether-10, ozonated PEG-10 oleate, ozonated PEG-14 oleate, ozonated polysorbate 8 0. Palmitoleic acid, palmitopropyl betaine, palmitole alcohol polyether-2 phosphate, palmitopropylamine oxide, palmitopropyl betaine, palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptides, palmitoyl silk amino acids, palm kernel oil, palm kernel oil, peach kernel oil glycerol polyether-8 ester, arachidic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil.PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG-6 cocamide phosphate, PEG-4 cocoamine, PEG-8 cocoamine, PEG-12 cocoamine, PEG-150 dibenzyl ester, PEG-90 diisostearate, PEG-75 dilaurate, PEG-150 dilaurate, PEG-75 dioleate, PEG-150 dioleate, PEG-75 distearate, PEG-120 distearate, PEG-150 distearate, PEG-175 distearate, PEG-190 distearate, PEG-250 distearate, PEG-30 glyceryl cocoate, PEG-40 glyceryl coconut oil PEG-78 glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate, PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 glyceryl laurate, PEG-25 glyceryl oleate, PEG-30 glyceryl oleate, PEG-30 glyceryl soybean oleate, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 glyceryl oleate, PEG- PEG-80 glyceryl triglyceride, PEG-82 glyceryl triglyceride, PEG-130 glyceryl triglyceride, PEG-200 glyceryl triglyceride, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin, PEG-50 hydrogenated palmitamide, PEG-2 isostearate, PEG-3 isostearate, PEG-4 isostearate, PEG-6 isostearate, PEG-8 isostearate, PEG PEG-10 isostearate, PEG-12 isostearate, PEG-20 isostearate, PEG-30 isostearate, PEG-40 isostearate, PEG-26 jojoba acid, PEG-40 jojoba acid, PEG-15 jojoba alcohol, PEG-26 jojoba alcohol, PEG-40 jojoba alcohol, PEG-35 lanolin, PEG-40 lanolin, PEG-50 lanolin, PEG-55 lanolin, PEG-60 lanolin, PEG-70 lanolin, PEG-75 lanolin, PEG-85 lanolin, PEG-100 lanolin, PEG-150 lanolin, PEG-75 lanolin oil, PEG-2 laurylamide, PEG-3 laurylamine oxide,PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannitol laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucoside dioleate, PEG-80 methyl glucoside laurate, PEG-120 methyl glucoside trioleate, PEG-4 lignite, PEG-30 oleylamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-150 polyglycerol-2 tristearate, PE G / PPG-28 / 21 ester polydimethylsiloxane, PEG / PPG-24 / 18 butyl ether polydimethylsiloxane, PEG / PPG-3 / 17 copolymer, PEG / PPG-5 / 35 copolymer, PEG / PPG-8 / 55 copolymer, PEG / PPG-10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate ester, PEG / PPG-4 / 2 propyl heptyl ether, PEG / PPG-6 / 2 propyl heptyl ether, PEG-7 / PPG-2-propyl heptaether, PEG / PPG-8 / 2-propyl heptaether, PEG / PPG-10 / 2-propyl heptaether, PEG / PPG-14 / 2-propyl heptaether, PEG / PPG-40 / 2-propyl heptaether, PEG / PPG-10 / 2-ricinoleate, PEG / PPG-32 / 3-ricinoleate, PEG-55 propylene glycol oleate, PEG-25 propylene glycol stearate, PEG-75 propylene glycol stearate, PEG-120 propylene glycol stearate, PEG-5 rapeseed sterol, PEG-10 rapeseed sterol, PEG-40 ricinoleamide, PEG-75 shea butter glycerides, PEG-75 salsa glycerides, PEG-20 sorbitan cocoate.PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolinate, PEG-75 Sorbitan Lanolinate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearoamide Carboxylic Acid, PEG-9 Stearoamide Carboxylic Acid, PE G-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallow ester, PEG-50 tallow amide, PEG-2 tallow amide DEA, PEG-20 tallow ester, PEG-66 trihydroxystearate Lipids, PEG-200 Trihydroxystearin, PEG-60 Camellia Oil Glycerides, Nonanoic Acid, Pentadecylphenol Polyether-200, Phenolic Polyether-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamer 908, Poloxamer 1508, Polydimethylsiloxane PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxane PPG-13 Butyl Ether Silsesquioxane, Polyglycerol Polyglycerol-6-decanoate, polyglycerol-10-dilaurate, polyglycerol-20-heptacapryate, polyglycerol-20-hexacapryate, polyglycerol-2-lauryl ether, polyglycerol-10-lauryl ether, polyglycerol-20-octaisononate, polyglycerol-6-pentacapryate, polyglycerol-10-pentacapryate, polyglycerol-3-dimethylsiloxane, polyglycerol-6-tetracapryate, polyglycerol-10-tetralauryate, polyglycerol-6-tricapryate, polyglycerol-10-trilauryate, polyquaternium-77, polyquaternium-78, polyquaternium-79, polyquaternium-80, polyquaternium-81, polyquaternium-82, Pomaderris Kumerahou flower / leaf extract, Poria cocos extract,Potassium abietic hydrolyzed collagen, potassium babassuate, potassium behenate, C9-15 potassium phosphate, C11-15 potassium phosphate, C12-13 potassium phosphate, C12-14 potassium phosphate, potassium decanoate, potassium capryloyl glutamate, potassium capryloyl hydrolyzed rice protein, potassium castor oil, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl glycine, potassium cocoyl hydrolyzed casein, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein, potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soybean protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, and cocoyl PCA. Potassium, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Corn Oleate, Potassium Cyclocarboxypropyl Oleate, Potassium Dihydroxyethyl Cocoamine Oxide Phosphate, Potassium Polydimethylsiloxane PEG-7 Phosphate, Potassium Dodecylbenzene Sulfonate, Potassium Hemp Seed Oil, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palm Oil, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolinate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Lauroyl Collagen Amino Acid, Potassium Lauroyl Glutamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Potassium pea amino acids, potassium lauroyl sarcosinate, potassium lauroyl silk amino acids, potassium lauroyl wheat amino acids, potassium lauryl phosphate, potassium lauryl sulfate, potassium linoleate, potassium metaphosphate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl glutamate, potassium myristoyl hydrolyzed collagen, potassium octylphenol polyether-12 phosphate, potassium oleate, potassium oleyl hydrolyzed collagen, potassium olive oil, potassium olive oil acyl hydrolyzed oat protein, potassium olive oil acyl hydrolyzed wheat protein, potassium olive oil acyl / lauroyl wheat amino acids, potassium olive oil acyl PCA, potassium palmitate, potassium palmitate, potassium palmitate, potassium palmitate hydrolyzed corn protein, potassium palmitate hydrolyzed oat protein, potassium palmitate hydrolyzed rice protein, potassium palmitate hydrolyzed sweet almond protein, potassium palmitate hydrolyzed wheat protein, palm kernel oleic acid Potassium, potassium arachidate, potassium rapeseed oil, potassium ricinoleate, potassium safflower oil, potassium soybean oil, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tallowate, potassium tallowate, potassium taurate, potassium taurate laurate, potassium tridecyl alcohol polyether-3 carboxylate, potassium tridecyl alcohol polyether-4 carboxylate, potassium tridecyl alcohol polyether-7 carboxylate, potassium tridecyl alcohol polyether-15 carboxylate, potassium tridecyl alcohol polyether-19 carboxylate, potassium tridecyl alcohol polyether-6 phosphate, potassium tridecyl alcohol polyether-7 phosphate, potassium camellia oleate, potassium undecenoate, potassium undecenoyl hydrolyzed collagen, potassium undecenoyl hydrolyzed rice protein, PPG-30-butanol polyether-30, PPG-36-butanol polyether-36, PPG-38-butanol polyether-37, PPG-30-octyl alcohol polyether-4 phosphate esterPPG-10 Cetyl Ether Phosphate, PPG-2C9-11 Alcohol Polyether-8, PPG-1-Decanol Polyether-5, PPG-3-Decanol Polyether-2 Carboxylic Acid, PPG-30-Ethylhexanol Polyether-4 Phosphate, PPG-20-Glyceryl Polyether-30, PPG-2 Hydroxyethyl Coconut Oil / Isostearamide, PPG-2-Isodecyl Alcohol Polyether-8, PPG-2-Isodecyl Alcohol Polyether-10 PPG-2-Isodecyl alcohol polyether-18, PPG-2-Isodecyl alcohol polyether-25, PPG-4-Isodecyl alcohol polyether-10, Propyltrimethylammonium hydrolyzed collagen, Quaternary ammonium salt-24, Quaternary ammonium salt-52, Quaternary ammonium salt-87, Rapeseed oil acid, Rice bran acid, Rice bran oil glyceryl polyether-8 esters, Ricinoxane amylase-propyl betaine, Ricinoxane acid, Ricinoxane oil alcohol polyether-40, Sapindus Oahuensis fruit extract, Saponaria soapwort (Saponaria) (Officinalis) root powder, saponins, potassium soap, sodium / potassium soap, soap base, potassium soap base, sesame oil glyceryl polyether-8 esters, sesame oil amamidopropylamine oxide, sesame amamidopropyl betaine, shea butter amamidopropyl betaine, shea butter glyceryl polyether-8 esters, sodium arachidate, sodium arganampohoacetate, mulberry palm oil sodium oleate, sodium avocadoate, sodium babassu oleoylamphoacetate, sodium babassu oleate, sodium babassu oleate sulfate, sodium behenate. Sodium diethylene glycol castor oil sulfosuccinate, sodium dihydroxyethyl glycinate cocoyl glucoside cross-linked copolymer, sodium dihydroxyethyl glycinate lauryl glucoside cross-linked copolymer, sodium borage oleamidopropyl PG-dimethylammonium chloride phosphate, sodium butylphenol polyether-12 sulfate, sodium butyl glucoside hydroxypropyl phosphate, sodium C13-17 alkyl sulfonate, sodium C14-18 alkyl sulfonate, sodium C12-15 alkoxypropyliminodipropionate, sodium C10-16 alcohol sulfate, sodium C11-15 alkyl sulfate, sodium C12 -13 alkyl sulfate sodium, C12-15 alkyl sulfate sodium, C12-18 alkyl sulfate sodium, C16-20 alkyl sulfate sodium, C9-22 secondary alkyl sulfonate sodium, C14-17 secondary alkyl sulfonate sodium, sodium decanoate, sodium decanoamphoacetate, sodium decanoamphohydroxypropyl sulfonate, sodium decanoamphopropionate, sodium decanomethyl taurate, sodium octanoate, sodium octyl ether-2 carboxylate, sodium octyl ether-9 carboxylate, sodium octanoamphoacetate, sodium octanoamphohydroxypropyl sulfonate, sodium octanoamphopropionate, octanoyl glutamate Sodium octyl hydrolyzed wheat protein, sodium octyl PG-sulfonate, sodium octyl sulfonate, sodium ricinoleate, sodium cetearyl alcohol polyether-13 carboxylate, sodium cetearyl alcohol sulfate, sodium cetearyl alcohol polyether-13 carboxylate, sodium cetearyl alcohol sulfate, sodium cocamidopropyl PG-dimethylammonium chloride phosphate, sodium cocoyl aminopropionate, sodium cocoyl alcohol polyether sulfate, sodium cocoyl alcohol polyether-30 sulfate, sodium cocoa butter amphoteric acid, sodium cocoa butter ester, sodium cocoa butter amphoteric acid, sodium cocoa butter amphoteric acid, sodium cocoa butter amphoteric acid, sodium cocoa butter amphoteric hydroxypropyl sulfonate.Sodium cocoamphopropionate, Sodium cocoate, Sodium cocoyl alcohol / babassuol / adirabalol sulfate, Sodium cocoyl alcohol / babassuol sulfate, Sodium cocoyl glucoside hydroxypropyl phosphate, Sodium cocoyl glucoside hydroxypropyl sulfonate, Sodium cocoyl glucoside tartrate, Sodium cocoyl alcohol glyceryl ether sulfonate, Sodium cocoyl alcohol / hydrogenated tallow alcohol sulfate, Sodium cocoyl iminodiacetic acid, Sodium cocoyl monoglyceride sulfate, Sodium cocoyl monoglyceride sulfonate, Sodium cocoyl PG-dimethylammonium chloride phosphate, Sodium cocoyl alcohol sulfate, Sodium cocoyl alcohol sulfoacetate, Sodium cocoyl aminopropionate, Sodium cocoyl amino acid, Sodium cocoyl collagen amino acid, Sodium cocoyl glutamate, Sodium cocoyl glutamate, Sodium cocoyl glycinate, Sodium cocoyl / hydrogenated tallow glutamate Sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soybean protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl ethoxysulfonate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acid, sodium cocoyl / palmitoyl / sunfloweroyl glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl taurate, sodium cocoyl threonine, sodium cocoyl wheat amino acid, sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate, sodium C16-18 olefin sulfonate, sodium corn oleoyl amphoteric propionate. Sodium cottonseed oil acylamphoacetate, C13-15 sodium alkanol polyether-8 butanol phosphate, C9-11 sodium alkanol polyether-6 carboxylate, C11-15 sodium alkanol polyether-7 carboxylate, C12-13 sodium alkanol polyether-5 carboxylate, C12-13 sodium alkanol polyether-8 carboxylate, C12-13 sodium alkanol polyether-12 carboxylate, C12-15 sodium alkanol polyether-6 carboxylate, C12-15 sodium alkanol polyether-7 carboxylate, C12-15 sodium alkanol polyether-8 carboxylate, C14-15 sodium alkanol polyether-8 carboxylate, C12-14 sodium secondary alkanol polyether-8 carboxylate, C14-15 sodium alkanol polyether-PG sulfonate, C12-13 sodium alkanol polyether-2 phosphate, C13-15 sodium alkanol polyether-8 phosphate, C9-15 sodium alkanol polyether-6 carboxylate, C11-15 sodium alkanol polyether-7 carboxylate, C12-15 sodium alkanol polyether-8 carboxylate, C9-15 sodium alkanol polyether-PG sulfonate, C12-13 sodium alkanol polyether-2 phosphate, C13-15 sodium alkanol polyether-8 phosphate, C9-15 ...14-15 sodium alkanol polyether-PG sulfonate, C12-13 sodium alkanol polyether-2 phosphate, C13-15 sodium alkanol polyether-8 phosphate, C9-15 Sodium sulfate of C10-15 alkanol ether, sodium sulfate of C10-16 alkanol ether, sodium sulfate of C12-13 alkanol ether, sodium sulfate of C12-15 alkanol ether, sodium sulfate of C12-15 alkanol ether, sodium sulfate of C13-15 alkanol ether, sodium sulfate of C12-14 secondary alkanol ether, sodium sulfate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium sulfonate of C12-15 alkanol ether, sodium 2-carboxylic acid of decanol, sodium decyl polyether sulfate, sodium decylbenzene sulfonate, sodium decyl glucoside hydroxypropyl phosphate, sodium decyl glucoside hydroxypropyl sulfonate, sodium di(lauryl ether-7) citrate, sodium di(lauryl ether-10) phosphate.Sodium dilinoleamide propyl PG-dimethylammonium chloride phosphate, sodium dilinoleate, sodium di(oleyl alcohol polyether-8) phosphate, sodium dodecylbenzene sulfonate, sodium ethyl 2-sulfolarate, sodium glyceryl oleate phosphate, sodium grape seed oil dilamamide propyl PG-dimethylammonium chloride phosphate, sodium grape seed oil acylamphoacetate, sodium grape seed oil, sodium hemp seed oil acylamphoacetate, sodium hexyl ether-4 carboxylate, hydrogenated sodium cocoate, hydrogenated sodium cocoyl methyl hydroxyethyl sulfonate, hydrogenated sodium palmitate, hydrogenated sodium tallow, hydrogenated sodium tallow glutamate, sodium hydroxylauryl dimethylammonium ethyl phosphate, sodium palm kernel oil hydroxypropyl sulfonate, sodium hydroxypropyl phosphate decyl glucoside crosspolymer, sodium hydroxypropyl phosphate lauryl glucoside crosspolymer, sulfonic acid Sodium hydroxypropyl cocoyl glucoside crosspolymer, sodium hydroxypropyl sulfonate decyl glucoside crosspolymer, sodium hydroxypropyl sulfonate lauryl glucoside crosspolymer, sodium hydroxystearate, sodium isostearate, sodium isostearate, sodium isostearyl alcohol polyether-6 carboxylate, sodium isostearyl alcohol polyether-11 carboxylate, sodium isostearyl amphoteric acid, sodium isostearyl amphoteric propionate, sodium N-isostearoyl methyl taurate, sodium lanolin alcohol polyether sulfate, sodium lanolinate, sodium lardate, sodium lauryl diacetate, sodium lauryl aminopropionate, sodium lauryl ether, sodium lauryl alcohol polyether-3 carboxylate, sodium lauryl alcohol polyether-4 carboxylate, sodium lauryl alcohol polyether-5 carboxylate, sodium lauryl alcohol polyether-6 carboxylate, sodium lauryl alcohol polyether-8 carboxylate, sodium lauryl alcohol polyether-11 carboxylate, sodium lauryl alcohol polyether-12 carboxylate Sodium lauryl ether-13 carboxylate, sodium lauryl ether-14 carboxylate, sodium lauryl ether-16 carboxylate, sodium lauryl ether-17 carboxylate, sodium lauryl ether sulfate, sodium lauryl ether-5 sulfate, sodium lauryl ether-7 sulfate, sodium lauryl ether-8 sulfate, sodium lauryl ether-12 sulfate, sodium lauryl ether-40 sulfate, sodium lauryl ether-7 tartrate, disodium lauryliminodipropionate, sodium lauroyl amphoteric acid, sodium lauroyl amphoteric hydroxypropyl sulfonate, sodium lauroyl amphoteric PG-acetate phosphate, sodium lauroyl amphoteric propionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, sodium lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropyl... Sodium lauroyl ethanesulfonate, sodium lauroyl methylaminopropionate, sodium lauroyl methyl hydroxyethyl sulfonate, sodium lauroyl Millet amino acid, sodium lauroyl / myristoyl aspartate, sodium lauroyl oat amino acid, sodium lauroyl sarcosine, sodium lauroyl silk amino acid, sodium lauroyl taurate, sodium lauroyl wheat amino acid, sodium lauryl di(ethylenediamino)aminoacetate, sodium lauryl glucocarboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, disodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamia seed oil, sodium mangoyl amphoteric acid, sodium mango seed oil ester.Sodium lauryl ether-2-sulfosuccinate / MEA, sodium methoxyPPG-2 acetate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearyl taurate, sodium methyl 2-sulfolanoate, sodium methyl 2-sulfopalmitoate, sodium isopalmitoyl methyl taurate, sodium methyl cocoyl methyl taurate, sodium myristyl ether sulfate, sodium myristate, sodium myristoyl amphoteric acetate, sodium myristoyl glutamate, myristoyl water Sodium Collagenate, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosine, Sodium Myristyl Sulfate, Sodium Nonoxynol Polyether-6 Phosphate, Sodium Nonoxynol Polyether-9 Phosphate, Sodium Nonoxynol Polyether-1 Sulfate, Sodium Nonoxynol Polyether-3 Sulfate, Sodium Nonoxynol Polyether-4 Sulfate, Sodium Nonoxynol Polyether-6 Sulfate, Sodium Nonoxynol Polyether-8 Sulfate, Sodium Nonoxynol Polyether-10 Sulfate, Sodium Nonoxynol Polyether-25 Sulfate, Sodium Octylphenol Polyether-2 Isethionate, Sodium Octylphenol Polyether-2 Sulfate, Sodium Octylphenol Polyether-6 Sulfate, Sodium Octylphenol Polyether-9 Sulfate Sodium oleate, sodium oleate, sodium oleoylamphoacetate, sodium oleoylamphohydroxypropyl sulfonate, sodium oleoylamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl ethanesulfonate, sodium oleyl alcohol polyether sulfate, sodium oleoyl methyl ethanesulfonate, sodium oleyl alcohol sulfate, sodium oleoylamphoacetate, sodium oleoyl glutamate, sodium palmitoleoylamphoacetate, sodium palmitate, sodium palmitoleate, sodium palmitoleyl glycerol sulfonate, sodium palmitate, sodium palmitoleoyl hydrolyzed collagen, sodium palmitoleoyl hydrolyzed wheat protein, sodium palmitoleoyl sarcosinate, sodium palm kernel oleate, sodium palmitoleoyl ethanesulfonate, palm Sodium oleoylglutamate, sodium passionflower seed oil, sodium arachidonic acid, sodium arachidonic acid, PEG-6 sodium cocoamide carboxylate, PEG-8 sodium cocoamide carboxylate, PEG-4 sodium cocoamide sulfate, PEG-3 sodium lauramide carboxylate, PEG-4 sodium lauramide carboxylate, PEG-8 sodium palm oil glyceride carboxylate, pentaerythritol hydroxypropyl iminodiacetic acid sodium resin, propoxylated PPG-2 sodium acetate, sodium rapeseed oil, sodium rice bran oleoylamphoacetate, sodium ricinoleate, sodium ricinoleoylamphoacetate, Sodium Rose Hipsamphoacetate, Sodium Rosinate, Sodium Safflower Oil, Sodium Saffloweroyl Hydrolyzed Soybean Protein, Sodium Sesame Seed Oil, Sodium Sesame Amphoteric Acetate, Sodium Butyl Amphoteric Acetate, Sodium Soybean Oil, Sodium Soybean Oil Hydrolyzed Collagen, Sodium Stearate, Sodium Stearyl Amphoteric Acetate, Sodium Stearyl Hydroxypropyl Sulfonate, Sodium Stearyl Amphoteric Propionate, Sodium Stearyl Casein, Sodium Stearyl Glutamate, Sodium Stearyl Hyaluronic Acid, Sodium Stearyl Hydrolyzed Collagen, Sodium Stearyl Hydrolyzed Corn Protein, Sodium Stearyl Hydrolyzed Silk, Sodium Stearyl Hydrolyzed Soybean Protein, Sodium Stearyl Hydrolyzed Wheat Protein, Sodium Stearyl Whey Protein, Sodium Stearyl Methyl Hydroxyethanesulfonate, Sodium Stearyl Oat ProteinSodium stearoyl pea protein, sodium stearoyl soybean protein, sodium stearoyl dimethyl glycinate, sodium stearyl alcohol sulfate, sodium sunflower seed oil acylamphoacetate, sodium subtilis lipopeptide, sodium sweet almond oil acylamphoacetate, sodium sweet almond oil, sodium talloyl amphotericin, sodium talloate, sodium taurate, sodium taurate, sodium taurate, sodium talloyl amphotericin, sodium taurate, sodium callophyllium folinum seed oil, sodium taurate, sodium cocoyl methyl taurate, lauryl taurate. Sodium taurate, sodium lauroyl collagen amino acid sodium / TEA salt, sodium lauroyl hydrolyzed collagen sodium / TEA salt, sodium lauroyl hydrolyzed keratin sodium / TEA salt, sodium lauroyl keratin amino acid sodium / TEA salt, sodium undecenoyl collagen amino acid sodium / TEA salt, sodium undecenoyl hydrolyzed collagen sodium / TEA salt, sodium undecenoyl hydrolyzed corn gluten sodium / TEA salt, sodium undecenoyl hydrolyzed soybean gluten sodium / TEA salt, sodium undecenoyl hydrolyzed wheat gluten sodium / TEA salt, Theobroma Grandiflorum seed oil sodium, tridecyl alcohol polyether-3 carboxylate sodium, tridecyl alcohol polyether-4 carboxylate sodium, tridecyl alcohol polyether-6 carboxylate sodium, tridecyl alcohol polyether-7 carboxylate sodium, tridecyl alcohol polyether-8 carboxylate sodium, tridecyl alcohol polyether-12 carboxylate sodium, tridecyl alcohol polyether-15 carboxylate sodium, tridecyl alcohol polyether-19 carboxylate sodium, tridecyl alcohol polyether sulfate sodium, tridecylbenzene sulfonate sodium, tridecyl alcohol sulfate sodium, trimethylolpropane hydroxypropyl iminodiacetic acid sodium resin Compounds, sodium undecanoyl alcohol polyether-5 carboxylate, sodium undecenoate, sodium undecenoyl amphoteric acid, sodium undecenoyl amphoteric propionate, disodium undecenoyl glutamate, sodium wheat germ oil amphoteric acid, sorbitol polyether-160 tristearate, soybean oleic acid, soybean oleamidopropylamine oxide, soybean oleamidopropyl betaine, soybean glyceryl polyether-8 esters, stearamidopropylamine oxide, stearamidopropyl betaine, stearylamine oxide, stearyl alcohol polyether-15, stearyl alcohol polyether Stearyl alcohol polyether-16, stearyl alcohol polyether-20, stearyl alcohol polyether-21, stearyl alcohol polyether-25, stearyl alcohol polyether-27, stearyl alcohol polyether-30, stearyl alcohol polyether-40, stearyl alcohol polyether-50, stearyl alcohol polyether-80, stearyl alcohol polyether-100, stearyl alcohol polyether-2 phosphate, stearyl alcohol polyether-3 phosphate, stearic acid, stearoxypropyltrimethylammonium chloride, stearoylglutamic acid, stearoylsarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearic acid, stearyl glutamic acid, stearyl sarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearic acid, stearyl glutamic acid, stearyl sarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearyl glutamic acid ... Aliphatic dimethyl decyl glucoside hydroxypropyl ammonium chloride, stearyl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oil oleamide MEA, sunflower seed oil acid, sunflower seed oil oleamide propyl hydroxyethyl dimethyl ammonium chloride, sunflower seed oil glyceryl polyether-8 esters, tallow acid, tallow aminopropylamine oxide, tallow aminopropyl betaine, tallow aminopropyl hydroxysulfonyl betaine,Tallow amine oxide, tallow betaine, tallow dihydroxyethyl betaine, tallow ethyl glucoside, abietic hydrolyzed collagen TEA salt, C12-14 alcohol phosphate TEA salt, C10-15 alkyl sulfate TEA salt, C11-15 alcohol sulfate TEA salt, C12-13 alkyl sulfate TEA salt, TEA-C12-14 alkyl sulfate TEA salt, TEA-C12-15 alkyl sulfate TEA salt, TEA C14-17 secondary alkyl sulfonic acid TEA salt, low erucic acid rapeseed oil TEA salt, cocamidodiacetic acid TEA salt, coconut oil acid TEA salt, coconut oil alcohol sulfate TEA salt, cocoyl alanine TEA salt, cocoyl glutamic acid TEA salt, cocoyl glutamine TEA salt, cocoyl glycine TEA salt, cocoyl hydrolyzed collagen TEA salt, cocoyl hydrolyzed soybean protein TEA salt, cocoyl sarcosine TEA salt, polydimethylsiloxane PEG-7 phosphate TEA salt, dodecylbenzene sulfonic acid TEA salt, hydrogenated coconut oil acid TEA salt, hydrogenated tallow glutamic acid TEA salt, isostearic acid TEA salt TEA-Isostearyl Hydrolyzed Collagen TEA Salt, Lauroyl Aminopropionic Acid TEA Salt, Lauric Acid TEA Salt, Lauric Acid / Myristic Acid TEA Salt, Lauroyl Polyether Sulfate TEA Salt, Lauroyl Collagen Amino Acid TEA Salt, Lauroyl Glutamate TEA Salt, Lauroyl Hydrolyzed Collagen TEA Salt, Lauroyl Keratin Amino Acid TEA Salt, Lauroyl Methaminopropionic Acid TEA Salt, Lauroyl / Myristoyl Aspartic Acid TEA Salt, Lauroyl Sarcosine TEA Salt, Lauroyl Phosphate TEA Salt, Lauroyl Sulfate TEA Salt, Myristoyl Aminopropionic Acid TEA Salt, Myristic Acid TEA Salt, Myristoyl Hydrolyzed Collagen TEA salts, oleic acid TEA salts, oleoyl hydrolyzed collagen TEA salts, oleoyl sarcosine TEA salts, oleyl alcohol sulfate TEA salts, palmitic acid TEA salts, palm kernel sarcosine TEA salts, PEG-3 cocoamide sulfate TEA salts, pinoresinic acid TEA salts, stearic acid TEA salts, tall acid TEA salts, tridecylbenzenesulfonic acid TEA salts, undecenoic acid TEA salts, undecenoyl hydrolyzed collagen TEA salts, tetramethyldecynyl glycol, tetrasodium dicarboxyethyl stearyl sulfosuccinate, lauryl ether sulfate TIPA salts, lauryl sulfate TIPA salts, myristic acid TIPA salts, stearic acid TIPA salts Tocopherol phosphate, Trehalose undecenoate, TM-C12-15 Alkyl ether-2 phosphate, TM-C12-15 Alkyl ether-6 phosphate, TM-C12-15 Alkyl ether-8 phosphate, TM-C12-15 Alkyl ether-10 phosphate, Tridecyl alcohol polyether-20, Tridecyl alcohol polyether-50, Tridecyl alcohol polyether-3 carboxylic acid, Tridecyl alcohol polyether-4 carboxylic acid, Tridecyl alcohol polyether-7 carboxylic acid, Tridecyl alcohol polyether-8 carboxylic acid, Tridecyl alcohol polyether-15 carboxylic acid, Tridecyl alcohol polyether-19 carboxylic acid, Tridecyl alcohol polyether-10 phosphate, Tridecylbenzene sulfonic acid, Tris(Lauryl alcohol polyether-9) citrate,Trimethylolpropane hydroxypropyl dihydroxyethylamine resin, tris(lauroyl amphoteric PG-acetic acid sodium chloride) phosphate, undecanoic acid, undecanoyl alcohol polyether-5 carboxylic acid, undecenoyl ammonium amine oxide, undecenoyl ammonium betaine, undecenoic acid, undecenoyl collagen amino acid, undecenoyl glycine, undecenoyl hydrolyzed collagen, undecenoyl wheat amino acids, undecyl glucoside, wheat germ fatty acids, wheat germ oleamide propylamine oxide, wheat germ oleamide propyl betaine, Yucca Schidigera leaf / root / stem extract, Yucca Schidigera stem extract, zinc cocoyl alcohol polyether sulfate and zinc cocoyl alcohol sulfate. nonionic surfactants

[0104] Alkyl alcohols. The added nonionic surfactant is preferably alkoxylated and / or propoxylated, particularly preferably a primary alcohol containing 8-18 carbon atoms per mole of alcohol and an average of 1-12 moles of ethylene oxide (EO) and / or 1-10 moles of propylene oxide (PO). Particularly preferred are C8-C alcohols with a degree of ethoxylation of 2-10, preferably 3-8, and / or a degree of propoxylation of 1-6, preferably 1.5-5. 16 - Alcohol alkoxylates, preferably ethoxylates and / or propoxylates C 10 -C 15 - Alcohol alkoxylates, especially C 12 -C 14 Alcohol alkoxylates. The degrees of ethoxylation and propoxylation constitute a statistical average, which may be an integer or a fraction for a particular product. Preferred alcohol ethoxylates and propoxylates have a narrow homologue distribution (narrow range ethoxylate / propoxylate, NRE / NRP). In addition to these nonionic surfactants, fatty alcohols having more than 12EO can also be used. Examples include (butter) fatty alcohols having 14EO, 16EO, 20EO, 25EO, 30EO, or 40EO.

[0105] Alkyl glycosides In addition, as an extra nonionic surfactant, RO(G) can be added. x Alkyl glycosides, for example as compounds, particularly with nonionic surfactants, wherein R is a straight-chain or methyl-branched, especially 2-methyl-branched, aliphatic group having 8 to 22, preferably 12 to 18 carbon atoms, and G represents a monosaccharide unit having 5 or 6 carbon atoms, preferably glucose. The degree of glycosylation x, which defines the distribution of monosaccharides and oligosaccharides, is a value between 1 and 10, preferably between 1.1 and 1.4.

[0106] Fatty acid ester alkoxylated compounds. Another preferred class of nonionic surfactants, used either alone or in combination with other nonionic surfactants, particularly with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably containing 1 to 4 carbon atoms in the alkyl chain, and more particularly, fatty acid methyl esters prepared, for example, by the method described in Japanese Patent Application JP-A-58 / 217598 or preferably by the method described in International Patent Application WO-A-90 / 13533. Particularly preferred are those containing an average of 3 to 15 EO atoms, particularly C containing about 5 to 12 EO atoms. 12 -C 18 Fatty acid methyl esters.

[0107] Amine oxides. Nonionic surfactants of the amine oxide type, such as N-cocoalkyl-N,N-dimethylamine oxide and N-tartratealkyl-N,N-dihydroxyethylamine oxide, as well as fatty acid chain alkanolamides, are also suitable. The amount of these nonionic surfactants is preferably no greater than the amount of ethoxylated fatty alcohol, especially no more than half of it.

[0108] Gemini surfactants. Other surfactants are so-called gemini surfactants. Generally, these compounds refer to compounds containing two hydrophilic groups and two hydrophobic groups per molecule. These groups are typically separated by "spacers." These spacers are usually carbon chains, long enough to allow the hydrophilic groups sufficient distance to function independently. These surfactants are typically characterized by very low critical concentrations and a significant reduction in the surface tension of water. However, in special cases, gemini surfactants refer not only to dimer but also to trimer surfactants. Suitable gemini surfactants are, for example, sulfated hydroxyl mixed ethers according to German patent application DE 4321022A1, or dimerol-bis- and trimerol-tri-sulfates and ether sulfates according to International patent application 96 / 23768A1. According to German patent application DE 19513391 A1, the end-capped dimer and trimer mixed ethers are characterized by their bifunctionality and multifunctionality. Geminid polyhydroxy fatty acid amides or polyhydroxy fatty acid amides, such as those described in international patent applications WO 95 / 19953A1, WO 95 / 19954A1 and WO 95 / 19955A1, may also be used. cationic surfactants

[0109] Tetraalkyl quaternary ammonium salts. Cationic surfactants in aqueous solution contain hydrophobic polymer groups required for the surface activity of the dissociated cation. An important representative of cationic surfactants is the general formula (R...). 1 R 2 R 3 R 4 N + )X- Tetraalkyl quaternary ammonium salts. Among them, R... 1 Represents C1-C8 alkyl (alkene) groups, R 2 、R 3 and R 4 Each group independently represents an alkyl (alkene) group containing 1 to 22 carbon atoms. X is a counterion, preferably from halogens, alkyl sulfates, and alkyl carbonates. Cationic surfactants are particularly preferred, wherein the nitrogen atom is replaced by two long acyl groups and two short alkyl (alkene) groups.

[0110] Ester quaternary ammonium salts. Cationic surfactants, particularly those used as auxiliary surfactants in this invention, are represented by the aforementioned ester quaternary ammonium salts. Ester quaternary ammonium salts are generally understood as quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of organic chemistry. Reference can be made to International Patent Application WO 91 / 01295A1, in which triethanolamine is partially esterified with a fatty acid in the presence of hypophosphite, air is passed into the reaction mixture, and then the mixture is quaternized bulkly with dimethyl sulfate or ethylene oxide. Furthermore, German Patent DE 4308794 C1 describes a method for preparing solid ester quaternary ammonium salts, wherein the quaternization of triethanolamine esters is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0111] A typical example of an ester quaternary ammonium salt suitably used according to the invention is a product whose acyl group is derived from a monocarboxylic acid corresponding to the formula RCOOH, wherein RCO is an acyl group containing 6 to 10 carbon atoms, and the amino group is triethanolamine (TEA). Examples of such monocarboxylic acids are hexanoic acid, octanoic acid, decanoic acid, and technical mixtures thereof, such as, for example, so-called head fractionated fatty acids. Preferred ester quaternary ammonium salts are those whose acyl group is derived from a monocarboxylic acid containing 8 to 10 carbon atoms. Other ester quaternary ammonium salts are those products whose acyl group is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid, and / or dodecanoic acid, but adipic acid is preferred. In summary, preferred ester quaternary ammonium salts are those whose acyl group is derived from a mixture of monocarboxylic acids and adipic acid containing 6 to 22 carbon atoms. In the final ester quaternary ammonium salt, the molar ratio of monocarboxylic acid to dicarboxylic acid is 1:99 to 99:1, and preferably 50:50 to 90:10, and particularly 70:30 to 80:20. Besides quaternized fatty acid triethanolamine esters, other suitable ester quaternary ammonium salts are mixtures of mono / dicarboxylic acids with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Esters can be obtained by mixing fatty acids and the corresponding triglycerides with the corresponding dicarboxylic acids. One such method, which can be considered representative of the relevant prior art, is described in European Patent EP 0750606 B1. For the production of quaternized esters, the molar ratio of the mixture of mono and dicarboxylic acids and triethanolamine—based on the available carboxyl group functions—can be 1.1:1 to 3:1. Considering the properties of ester quaternary ammonium salts, ratios that have proven particularly advantageous are 1.2:1 to 2.2:1, and preferably 1.5:1 to 1.9:1. Preferred ester quaternary ammonium salts are technical mixtures of mono-, di-, and tri-esters with an average degree of esterification of 1.5 to 1.9. Amphoteric surfactants

[0112] Internal ammonium salts. Amphoteric or zwitterionic surfactants possess a variety of functional groups that can ionize in aqueous solutions and thus—depending on the medium conditions—endow compounds with anionic or cationic properties (see DIN 53900, July 1972). Near their isoelectric point (approximately pH 4), amphoteric surfactants form internal salts, thus becoming weakly soluble or insoluble in water. Amphoteric surfactants are further subdivided into amphoteric compounds and internal ammonium salts, the latter exhibiting amphoteric behavior in solution. Amphoteric compounds are amphoteric electrolytes, i.e., compounds possessing both acidic and basic hydrophilic groups, and therefore exhibiting acidic or basic behavior depending on the conditions. In particular, internal ammonium salts are known surfactants produced primarily by the carboxylation of amine compounds, preferably by carboxylmethylation. The starting material is preferably condensed with a halocarboxylic acid or its salt, especially sodium chloroacetate, forming one mole of salt per mole of internal ammonium salt. Addition to unsaturated carboxylic acids, such as acrylic acid, is also possible. Suitable examples of internal ammonium salts are carboxylation products of secondary amines, especially tertiary amines, corresponding to the general formula R. 1 R2 R 3 N-(CH2) q COOX, where R 1 It is an alkyl group having 6-22 carbon atoms, R 2 It is hydrogen or an alkyl group containing 1-4 carbon atoms, R 3 It is an alkyl group containing 1-4 carbon atoms, q is a number from 1 to 6, and X is a base and / or an alkaline earth metal or ammonium. Typical examples are hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, C 12 / 14 -Cocoyl dimethylamine, myristyl dimethylamine, cetyl dimethylamine, stearyl dimethylamine, stearyl ethyl methylamine, oleyl dimethylamine, C 16 / 18 - Tallow alkyl dimethylamine and their industrial mixtures, and in particular carboxymethylated products of dodecyl methylamine, dodecyl dimethylamine, dodecyl ethyl methylamine and their industrial mixtures.

[0113] Alkylamide inner ammonium salts. Other suitable inner ammonium salts are carboxyl alkylated products of amamide amines, corresponding to the general formula R. 1 CO(R 3 )(R 4 )-NH-(CH2) p -N-(CH2) q COOX, where R 1 CO is an aliphatic acyl group having 6-22 carbon atoms and 0 or 1 to 3 double bonds, R 2 It is hydrogen or an alkyl group having 1-4 carbon atoms, R 3 It is an alkyl group having 1-4 carbon atoms, where P is a number from 1 to 6, q is a number from 1 to 3, and X is a base and / or an alkaline earth metal or ammonium. Typical examples are fatty acids having 6-22 carbon atoms, such as hexanoic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, transoleic acid, phellandrene, linoleic acid, linolenic acid, tung oil, arachidonic acid, cis(9)-eicosenoic acid, behenic acid, erucic acid, and their industrial mixtures reacting with N,N-dimethylaminoethylamine, N,N-dimethylaminopropylamine, N,N-diethylaminoethylamine, and N,N-diethylaminopropylamine, the product of which is condensed with sodium chloroacetate. Commercially available products include K and PK (Cognis Deutschland GmbH & Co., KG) and Betaine (Goldschmidt).

[0114] Imidazoline. Other suitable starting materials for the ammonium salt used for the purposes of this invention are imidazoline. These substances are also known and can be obtained, for example, by using 1 or 2 moles of C6-C 22 The product is obtained by cyclization condensation of fatty acids with polyfunctional amines such as aminoethylethanolamine (AEEA) or diethylenetriamine. The corresponding carboxylalkylated products are mixtures of different open-chain intraammonium salts. A typical example is the condensation product of the aforementioned fatty acids and AEEA, preferably an imidazoline based on lauric acid, which is subsequently intraammonized with sodium chloroacetate. Commercially available products include... G (Cognis Deutschland GmbH & Co., KG).

[0115] The amount of (auxiliary) surfactant in the composition of the present invention is preferably 0.1 to 90% by weight, particularly 10 to 80% by weight, and especially preferably 20 to 70% by weight. organic solvents

[0116] Liquid detergents for light or heavy scale buildup may contain organic solvents, preferably those miscible with water. Polyglycols, ethers, alcohols, ketones, amides, and / or esters are preferred as organic solvents, used in amounts from 0 to 90% by weight, preferably from 0.1 to 70% by weight, particularly from 0.1 to 60% by weight. Low molecular weight polar substances are preferred, such as methanol, ethanol, propylene carbonate, acetone, acetone-based acetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerol, diethylene glycol, dipropylene glycol monomethyl ether, and dimethylformamide, or mixtures thereof. enzymes

[0117] Cellulase. Optionally, cellulase is incorporated into the detergent composition, preferably incorporating it into the composition at a concentration sufficient to provide up to about 5 mg, more preferably about 0.01 mg to about 3 mg of active enzyme per gram of composition when the enzyme is used. Unless otherwise stated, the compositions of the present invention preferably contain about 0.001% to about 5% by weight, preferably 0.01% to 1% by weight of a commercially available enzyme preparation.

[0118] The cellulases suitable for use in this invention include bacterial or fungal cellulases. Preferably, they have an optimal pH range of 5-9.5. Suitable cellulases are fungal cellulases produced by *Humicola insolens* and *Hydrocotyle* strain DSM1800, or cellulases 212 produced by fungi belonging to the genus *Aeromonas*, and cellulases extracted from the hepatopancreas of marine mollusks (*Dolabella auricula* Solander). Suitable cellulases are also disclosed in GB 2,075,028A. Furthermore, cellulases particularly suitable for use in this invention are disclosed in WO 1992 013057A1. Most preferably, the cellulases used in this detergent composition are commercially available from NOVO Industries A / S under the product names CAREZYME and CELLUZYME.

[0119] Other enzymes. To achieve various purposes of washing fabrics, including, for example, removing protein, carbohydrate, or triglyceride stains, and to prevent dye migration and for fabric recovery, other enzymes may be included in the detergent compositions of the present invention. Other enzymes that may be incorporated include proteases, amylases, lipases, and peroxidases, and mixtures thereof. Other types of enzymes may also be included. They can be from any suitable source, such as plant, animal, bacterial, fungal, and yeast sources. However, their selection is determined by several factors, such as optimal pH-activity and / or stability, thermal stability, stability against reactive detergents and builders, and their potential to produce odors during use. In this respect, bacterial or fungal enzymes, such as bacterial amylases and proteases, are preferred.

[0120] Sufficient amounts of enzyme are typically incorporated to provide up to about 5 mg of active enzyme per gram of composition, more typically about 0.01 mg to about 3 mg. Unless otherwise stated, the compositions herein generally contain about 0.001 wt% to about 5 wt%, preferably 0.01 wt% to 1 wt% of commercially available enzyme products. Proteases in such commercially available products are typically present in amounts providing 0.005 to 0.1 Anson units (AU) of activity per gram of composition.

[0121] Suitable examples of proteases include Bacillus subtilis protease, obtained from specific strains of Bacillus subtilis and Bacillus licheniformis. Another suitable protease is obtained from Bacillus strains, exhibiting maximum activity in the pH range of 8-12, and is developed and marketed by Novo Industries A / S under the registered trade name [Trade Name Missing]. The preparation of this enzyme and similar enzymes is described in Novo's British patent GB 1,243,784. Commercially available proteolytic enzymes suitable for removing protein matrix stains include those marketed by Novo Industries A / S under the trade name... and And sold by International Bio-Synthitics, Inc. Those. Other proteases include protease A, protease B, and protease produced by Genencor International, Inc. according to US 5,204,015 and US 5,244,791.

[0122] Amylases include, for example, α-amylases such as International Bio-Synthetics, Inc., and Novo Industries.

[0123] Suitable lipases for use in detergents include those produced by microorganisms in the genus *Pseudomonas*, such as *Pseudomonas stutzeri* ATCC 19154. This lipase is available from Amano Pharmaceutical Co., Ltd., Nagoya, Japan, under the trade name Lipase P "Amano". Other commercially available lipases include Amano-CES, lipase ex *Chromobacter viscosum*, for example, *Chromobacter viscosum varlipolyticum* NRRLB 3673, available from Toyo Jozo Co.; and other *Viscosum* lipases sold by USBiochemical Corp. and Disoynth Co., and lipase ex *Pseudomonas gladioli*. Lipases derived from the genus *Humicola lanuginosa* (available from Novo Industries A / S) are also available. The preferred enzyme used in this paper is the lipase.

[0124] Peroxidases are used in combination with oxygen sources, such as percarbonates, perborates, persulfates, and hydrogen peroxide. They are used for "solution bleaching," which prevents dyes or pigments detached from the substrate during washing from migrating to other substrates in the washing solution. Peroxidases are known in the art and include, for example, horseradish peroxidase, ligninase, and halogenated peroxidases, such as chlorinated and brominated peroxidases. Detergent compositions containing peroxidases are disclosed, for example, in WO1989 099813A1.

[0125] Enzyme stabilizers. The enzymes used herein can be stabilized by water-soluble calcium and / or magnesium ion sources present in the finished detergent composition (which provide these ions to the enzyme). (Calcium ions are generally more effective than magnesium ions, and calcium ions are preferred herein if only one type of cation is used). Other stabilization can be obtained by the presence of stabilizers disclosed in various other prior art, particularly borates, see US 4,537,706, which is incorporated herein by reference in its entirety. Typical detergents, especially liquid detergents, contain about 1 to about 30, preferably about 2 to about 20, more preferably about 5 to about 15, and most preferably about 8 to about 12 millimoles of calcium ions per liter of finished composition. In solid detergent compositions, the formulation may contain a sufficient amount of water-soluble calcium ion source to provide the amount required in the washing water solution. On the other hand, the hardness of natural water is sufficient.

[0126] It should be recognized that the aforementioned calcium and / or magnesium ion content is sufficient to ensure enzyme stability. More calcium and / or magnesium ions may be added to the composition to provide additional means of removing grease. Therefore, common formulations of the compositions of the present invention may contain about 0.05% by weight to about 2% by weight of a water-soluble source of calcium or magnesium ions, or both. Of course, this amount may vary depending on the quantity and type of enzyme used in the composition.

[0127] The compositions of the present invention may optionally, but preferably, contain various other stabilizers, particularly borate-type stabilizers. Typically, such stabilizers are used in the composition in an amount from about 0.25% by weight to about 10% by weight, preferably from about 0.5% by weight to about 5% by weight, more preferably from about 0.75% by weight to about 3% by weight, based on the weight of boric acid or other borate compounds capable of forming boric acid in the composition (based on boric acid). Although other compounds, such as boron oxide, borax, and other alkali metal borates (e.g., sodium orthoborate, sodium metaborate, sodium pyroborate, and sodium pentoborate), are suitable, boric acid is preferred. Substituted boric acids (e.g., phenylboronic acid, butaneboronic acid, and p-bromophenylboronic acid) may also be used in place of boric acid. builder

[0128] Zeolite. Fine-grained synthetic zeolite containing bound water, preferably zeolite A and / or zeolite P, can be used as a detergent builder. Zeolite P is particularly preferred as MAP.RTM. (a commercially available product from Crosfield). However, zeolite X and mixtures of zeolites A, X, Y, and / or P are also suitable. Zeolite P is particularly preferred under the trade name... Sodium / potassium aluminosilicate co-crystalline zeolite A and zeolite X, available from RX (a commercially available product of Condea Augusta SpA). Spray-dried powdered zeolite is preferred. When adding zeolite in suspension form, a small amount of nonionic surfactant can be added as a stabilizer, such as 1 to 3% by weight of ethoxylated C4H ... 12 -C 18 Fatty alcohols, C4 groups with 4 to 5 ethylene oxide groups 12 -C 14 Fatty alcohols or ethoxylated isotrigine alcohol. Suitable zeolites have an average particle size of less than 10 μm (measured by a Coulter volume distribution counter) and preferably contain 18 to 22% by weight, more preferably 20 to 22% by weight of bound water. Additionally, phosphates can also be used as detergent builders.

[0129] Layered silicates. Suitable alternatives or partial alternatives to phosphates and zeolites are crystalline, layered sodium silicates. Such crystalline layered sodium silicates are described, for example, in European patent application EP 0164514 A1. Preferred crystalline layered silicates are those obtained by methods described, for example, in International patent application WO 91 / 08171A1.

[0130] Amorphous silicates. Preferred detergent builders also include amorphous sodium silicate with a modulus (Na₂O:SiO₂ ratio) of 1:2 to 1:3.3, preferably 1:2 to 1:2.8 and more preferably 1:2 to 1:2.6, which exhibits delayed dissolution and multiple wash cycles. This delayed dissolution characteristic, compared to conventional amorphous sodium silicate, can be obtained by various means, such as surface treatment, compounding, compaction / compression, or excessive drying. Within the scope of this invention, the term "amorphous" also refers to "X-ray amorphous." In other words, in X-ray diffraction tests, silicates do not produce the typical X-ray reflection of any crystalline material, but at most have one or more scattered X-ray peaks with a width of a few degrees of diffraction angle. However, particularly good detergent builder properties can be achieved when silicate particles produce inconspicuous or even clear diffraction peaks in electron diffraction tests. This can be understood as the product having a microcrystalline range of 10 to several hundred nanometers, with a preferred maximum of 50 nanometers, and particularly a maximum of 20 nanometers. German patent application DE 4400024A1 discloses X-ray amorphous silicates that also exhibit delayed dissolution characteristics compared to conventional water glass. Compacted / dense amorphous silicates, composite amorphous silicates, and excessively dried X-ray amorphous silicates are particularly preferred.

[0131] Phosphates. Commonly known phosphates may also be used as detergent builders, provided that such use is not restricted for ecological reasons. Particularly suitable are sodium salts of orthophosphoric acid, pyrophosphoric acid, and especially tripolyphosphate. Their content is generally no more than 25% by weight, preferably no more than 20% by weight, based on the final composition. In some cases, especially with tripolyphosphate, at low contents of up to 10% by weight, in combination with other detergent builders has shown synergistic improvements in secondary washing power, based on the final composition. The preferred amount of phosphate is less than 10% by weight, particularly 0% by weight. Auxiliary cleaning agents

[0132] Polycarboxylic acids. Useful organic auxiliary detergent builders are, for example, polycarboxylic acids that can be used in the form of sodium polycarboxylic acid salts, wherein polycarboxylic acids refer to carboxylic acids having more than one acid function. These include, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, glycolic acid, aminocarboxylic acid, aminotriacetic acid (NTA), and their derivatives and mixtures. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, glycolic acid, and their mixtures.

[0133] Organic acids. The acid itself can also be used. Besides its detergent-enhancing properties, acids often also act as acidifiers, thus establishing a relatively low and mild pH in detergents or cleaning compositions. Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid, and mixtures thereof are particularly noteworthy. Other suitable acidifiers are known pH adjusters such as sodium bicarbonate and sodium bisulfate.

[0134] Polymers. Particularly suitable polymeric auxiliary detergent builders are polyacrylates, preferably with a molecular weight of 2000 to 20000 g / mol. Due to their excellent solubility, short-chain polyacrylates with a molar concentration of 2000 to 10000 g / mol are preferred in this group, and particularly preferred are those with a molar concentration of 3000 to 5000 g / mol. Suitable polymers may also include substances composed partly or entirely of vinyl alcohol units or their derivatives.

[0135] Other suitable copolycarboxylates are particularly copolymers of acrylic acid and methacrylic acid, and copolymers of acrylic acid or methacrylic acid and maleic acid. Copolymers of acrylic acid and maleic acid containing 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven particularly suitable. Their relative molecular weight, based on free acid, is typically 2000 to 70000 g / mol, preferably 20000 to 50000 g / mol, and especially 30000 to 40000 g / mol. The (co)polycarboxylates can be added in aqueous solution or preferably as powder. To improve water solubility, the polymer may also contain allyl sulfonic acid monomers, such as allyloxybenzenesulfonic acid and methyl allyl sulfonic acid, for example, in EP 0727448B1.

[0136] Biodegradable polymers containing more than two different monomer units are particularly preferred. Examples include those in DE 4300772A1 that contain acrylates and maleates, as well as vinyl alcohol or vinyl alcohol derivatives, as monomers; or those that contain acrylic acid and 2-alkylallyl sulfonates, as well as sugar derivatives, as monomers. Other preferred copolymers are those described in German patent applications DE 4303320A1 and DE 4417734 A1, and preferably include acrolein and acrylic acid / acrylates or acrolein and vinyl acetate as monomers.

[0137] Similarly, other preferred builders are polymeric aminodicarboxylic acids, their salts, or precursors. Particularly preferred are polyaspartic acid or its salts and derivatives disclosed in German patent application DE 19540086 A1, which, in addition to enhancing the properties of the builder, also possess bleaching stabilizing effects.

[0138] Other suitable detergent builders are polyacetals, which are obtained by reacting a dialdehyde with a polyhydroxycarboxylic acid having 5 to 7 carbon atoms and at least 3 hydroxyl groups, as described in European patent application EP 0280223 A1. Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde, and mixtures thereof with polyhydroxycarboxylic acids such as gluconic acid and / or glucoheponic acid.

[0139] Carbohydrates. Other suitable organic auxiliary detergents are dextrins, such as oligomers or polymers of carbohydrates obtained by partial hydrolysis of starch. Hydrolysis can be carried out by conventional methods, such as acid-catalyzed or enzymatically catalyzed methods. Preferably, the hydrolysate has an average molar mass of 400 to 500,000 g / mol. Preferred is a polysaccharide having a glucose equivalent (DE) of 0.5 to 40, more particularly 2 to 30, where DE is an acceptable measure of the reducing power of the polysaccharide compared to glucose with a DE of 100. Maltodextrin with a DE of 3 to 20 and dried glucose syrup with a DE of 20 to 37, as well as so-called higher molecular weight yellow and white dextrins with a molecular weight of 2,000 to 30,000 g / mol, can be used. Preferred dextrins are described in British Patent Application 94 19091.

[0140] These oxidized derivatives of dextrins involve the reaction products of dextrin and an oxidizing agent, which oxidize at least one alcohol functional group of the sugar ring to a carboxylic acid functional group. Such oxidized dextrins and methods for their preparation are known, for example, from European patent application EP0232202 A1. A product oxidized at C6 of the sugar ring is particularly preferred.

[0141] Other suitable auxiliary builders are oxodisuccinates and other derivatives of disuccinates, preferably ethyldiamine disuccinate. Ethylenediamine-N,N'-disuccinic acid (EDDS) in sodium or magnesium salt form is preferred, and its synthesis is described, for example, in US 3,158,615. Glyceryl disuccinates and glyceryl trisuccinates are particularly preferred herein, as described in US 4,524,009. The amount added to formulations containing zeolite and / or silicates is 3 to 15% by weight.

[0142] Lactones. Other usable organic auxiliary builders include, for example, acetylated hydroxycarboxylic acids or their salts, optionally in the form of lactones, and containing at least four carbon atoms, at least one hydroxyl group, and at most two acid groups. Such auxiliary builders are described, for example, in International Patent Application WO 95 / 20029A1. Bleaching compounds, bleaching agents and bleaching activators

[0143] The detergent compositions described herein may optionally contain a bleaching agent or a bleaching composition containing a bleaching agent and one or more bleaching activators. If present, the bleaching agent is typically present in an amount of at least about 1% to about 30% of the detergent composition, more particularly about 5% to about 20%, especially for washing fabrics. If a bleaching activator is contained, its amount is typically present in an amount of about 0.1% to about 60% of the bleaching composition containing the bleaching agent and the bleaching activator, more preferably about 0.5% to about 40%.

[0144] The bleach used herein may be any bleach suitable for cleaning fabrics, cleaning hard surfaces, or other cleaning purposes now known or to be known. These include oxygen bleach as well as other bleaching agents. Perborate bleaching agents, such as sodium perborate (e.g., monohydrate or tetrahydrate), may be used herein.

[0145] Another class of bleaching agents that can be used without restriction includes percarboxylic acid bleaching agents and their salts. Suitable examples of this class of bleaching agents include magnesium monoperoxyphthalate hexahydrate, magnesium m-chloroperbenzoate, magnesium 4-nonylamino-4-oxoperoxybutyrate, and magnesium disperoxydodecanoate.

[0146] Peroxide bleaching agents can also be used. Suitable peroxide bleaching compounds include sodium carbonate peroxide hydrate and its equivalents, "percarbonate" bleaching agents, sodium pyrophosphate peroxide hydrate, urea peroxide hydrate, and sodium peroxide. Persulfate bleaching agents (e.g., (Commercially manufactured by DuPont).

[0147] Preferred percarbonate bleaching agents comprise dried particles having an average particle size in the range of about 500 to about 1000 micrometers, wherein particles smaller than about 200 micrometers do not exceed about 10% by weight, and particles larger than about 1250 micrometers do not exceed about 10% by weight. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonates are available from various suppliers.

[0148] A mixture of bleach can also be used.

[0149] Peroxy bleaching agents, perborates, percarbonates, etc., are preferably used in combination with bleaching activators, which results in the in-situ generation of peroxyacids corresponding to the bleaching activator in the aqueous solution (i.e., during the washing process). Nonanoyloxybenzenesulfonate (NOBS) and tetraacetylethylenediamine (TAED) activators are typical activators, and mixtures of them can also be used.

[0150] Preferred amide-derived bleaching activators include (6-octanoylamino-hexanoyl)oxybenzenesulfonate, (6-nonanoylamino-hexanoyl)oxybenzenesulfonate, (6-decanoylamino-hexanoyl)oxybenzenesulfonate, and mixtures thereof.

[0151] Another class of bleaching activators includes benzoxazine activators disclosed in US4966723, which are cited herein.

[0152] Preferred activators of caprolactams include benzoylcaprolactam, octanoylcaprolactam, 3,5,5-trimethylcaprolactam, nonanoylcaprolactam, decanoylcaprolactam, undecenoylcaprolactam, benzoylvaleramide, octanoylvaleramide, decanoylvaleramide, undecenoylvaleramide, nonanoylvaleramide, 3,5,5-trimethylcaprolactam, and mixtures thereof, optionally adsorbed on a solid support, such as acylcaprolactam, preferably benzoylcaprolactam, which is adsorbed onto sodium perborate.

[0153] Non-oxygen bleaching agents are also well known in the art and can be used in this invention. A particularly good class of non-oxygen bleaching agents includes photosensitive bleaching agents such as sulfonated zinc phthalocyanine and / or aluminum. If used, the detergent composition generally contains about 0.025% to about 1.25% by weight of such bleaching agents, especially zinc phthalocyanine sulfonate.

[0154] If desired, the bleaching compound can be catalyzed using a manganese compound. Such manganese-based catalysts are well known in the art and include Mn. IV 2(uO)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2,Mn III 2(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2,Mn IV 4(1,4,7-triazacyclononane)4(ClO4)4,Mn III Mn IV 4(uO)1(u-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, Mn IV (1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0155] In practical applications, without limitation, the compositions and methods of the present invention can be adjusted to provide at least about one ten-millionth of an active bleaching catalyst in the washing aqueous solution, preferably about 0.1 ppm to about 700 ppm, more preferably about 1 ppm to about 500 ppm of catalyst material in the washing solution. Polymerized Stain Remover

[0156] In the detergent compositions and methods of the present invention, any polymeric stain remover known to those skilled in the art may optionally be used. Polymeric stain removers are characterized by containing a hydrophilic portion for hydrophilizing the surface of hydrophobic fabrics such as polyester and nylon, and a hydrophobic portion that deposits on the hydrophobic fibers and remains adhered thereto throughout the washing process, thus acting as a anchor for the hydrophilic portion. This makes stains treated with the stain remover easier to remove in subsequent washing procedures.

[0157] The polymeric stain removers used herein specifically include those stain removers comprising (a) one or more nonionic hydrophilic components, primarily composed of: (i) a polyoxyethylene segment with a degree of polymerization of at least 2, or (ii) propylene oxide or a polyoxypropylene segment with a degree of polymerization of 2 to 10, wherein the hydrophilic segment does not contain any propylene oxide units unless it is attached to adjacent portions at each end by an ether, or (iii) a mixture containing ethylene oxide and olefin oxide units of 1 to about 30 propylene oxide units, wherein the mixture contains a sufficient amount of ethylene oxide units to give the hydrophilic component sufficiently high hydrophilicity to improve the hydrophilicity of a common polyester synthetic fiber surface as measured by the deposition of the stain remover on the fabric surface, wherein the hydrophilic segment preferably contains at least about 25% ethylene oxide units and more preferably, particularly for those components having about 20 to 30 propylene oxide units, they contain at least about 50% ethylene oxide units; or (b) one or more hydrophobic components, which contain Containing (i) a C3 oxidized alkenyl terephthalate segment, wherein, if the hydrophobic component further comprises oxidized vinyl terephthalate, the ratio of oxidized vinyl terephthalate to C3 oxidized alkenyl terephthalate units is about 2:1 or less, (ii) a C4-C6 alkenyl or oxidized C4-C6 alkenyl segment, or a mixture thereof, (iii) a poly(vinyl ester) segment, preferably poly(vinyl acetate) with a degree of polymerization of at least 2, or (iv) a C1-C4 alkyl ether or C4 hydroxyalkyl ether substituent, or a mixture thereof, wherein the substituent is in the form of a C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivative or a mixture thereof, wherein the cellulose derivative is amphoteric and thus has a sufficient amount of C1-C4 alkyl ether and / or C4 hydroxyalkyl ether units to be deposited on the surface of a common polyester synthetic fiber and retains a sufficient amount of hydroxyl groups—once they are bonded to the surface of the common synthetic fiber—to improve the hydrophilicity of the fiber surface, or a combination of (a) and (b).

[0158] While higher degrees of polymerization may also be used, the polyethylene oxide segment of (a)(i) typically has a degree of polymerization of about 200, preferably 3 to about 150, and more preferably 6 to about 100. Suitable oxygen C4-C6 alkenyl hydrophobic segments include, but are not limited to, end-capping of polymeric dirt-removing agents.

[0159] Polymerized dirt-removing agents that can be used in this invention also include cellulose derivatives such as hydroxyl ether cellulose polymers, block copolymers of ethylene terephthalate or propylene terephthalate with polyethylene oxide or polypropylene oxide terephthalate, and similar substances. Such formulations are commercially available and include hydroxyl ethers of cellulose, such as... (Dow). The cellulose dirt-removing agents used in this invention also include C1-C4 alkyl and C4 hydroxyalkyl celluloses.

[0160] Fouling removers characterized by hydrophobic segments of poly(vinyl ester) include poly(vinyl ester), such as graft copolymers of C1-C6 vinyl esters, preferably poly(vinyl acetate) grafted onto a polyolefin backbone, such as a copolymer of polyethylene oxide backbone, see EP 0,219,048, which is incorporated herein by reference in its entirety. Commercially available examples of such fouling removers include... Such substances, for example, those available from BASF HP-22.

[0161] A preferred class of fouling removers is a copolymer having random blocks of ethylene glycol terephthalate and polyethylene oxide (PEO) terephthalate. The polymeric fouling remover has a molecular weight of about 25,000 to about 55,000.

[0162] Another preferred polymeric dirt-removing agent is a polyester with repeating ethylene glycol terephthalate units, containing 10%-15% by weight of ethylene glycol terephthalate units and 90%-80% by weight of polyoxyethylene terephthalate units, obtained from polyoxyethylene glycol with an average molecular weight of 300-5000. Examples of such polymers include commercially available... 5126 (manufactured by DuPont) and T (manufactured by ICI).

[0163] Another preferred polymeric fouling remover is a sulfonated product of a essentially linear ester oligomer containing a terephthaloyl and oxyalkyleneoxy repeating unit low polyester backbone, and a terminal portion covalently linked to the backbone. These fouling removers are fully described in US 4,968,451. Other suitable polymeric fouling removers include terephthalate polyesters in US 4,711,730, anionic-terminated low polyesters in US 4,721,580, and block polyester oligomers in US 4,702,857, as well as anionic, particularly sulfoaryl-terminated terephthalates in US 4,877,896, all of which are cited in full.

[0164] Another preferred fouling remover is an oligomer having the following repeating units: terephthaloyl unit, sulfoisophthaloyl unit, oxyethylidene oxygen, and oxy-1,2-propylidene unit. These repeating units constitute the skeleton of the oligomer and are preferably end-capped with a modified hydroxyethanesulfonate. Particularly preferred such fouling removers comprise about one sulfoisophthaloyl unit, five terephthaloyl units, oxyethylidene oxygen and oxy-1,2-propylidene oxygen units in a ratio of about 1.7 to about 1.8, and two end-capping units of sodium 2-(2-hydroxyethoxy)ethanesulfonate. The fouling remover also comprises about 0.5% to 20% by weight of a crystallization-reducing stabilizer based on the weight of the oligomer, preferably selected from xylenesulfonate, cumenesulfonate, toluenesulfonate, and mixtures thereof.

[0165] If a dirt-removing agent is used, its dosage is generally from about 0.01% to about 10.0% by weight of the detergent composition of the present invention, typically from about 0.1% to about 5% by weight, preferably from about 0.2% to about 3.0% by weight. polymer dispersants

[0166] In the detergent compositions of the present invention, the amount of polymeric dispersant is advantageously from about 0.1% to about 7% by weight, particularly in the presence of zeolite and / or layered silicate builder. Suitable polymeric dispersants include polymeric polycarboxylate and polyethylene glycol, although other dispersants well known in the art may also be used. While not wishing to be theoretically limited, it can be considered that when used with other builder (including low molecular weight polycarboxylate), polymeric dispersants enhance the overall performance of the detergent builder through crystal growth inhibition, particulate dirt release peptization, and anti-redeposition effects.

[0167] Polymeric polycarboxylate substances can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in the form of acids. Unsaturated monomeric acids that can polymerize to form suitable polymeric polycarboxylate include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesoconic acid, citraconic acid, and methylene malonic acid. The presence of monomeric segments containing non-carboxylic acid groups such as vinyl methyl ether, styrene, ethylene, etc., in the polymeric polycarboxylate is desirable, provided that these segments do not exceed about 40% by weight.

[0168] Particularly suitable polymerized polycarboxylate salts can be obtained from acrylic acid. The acrylic acid-based polymers used in this invention are water-soluble salts of polymerized acrylic acid. The average molecular weight of these polymers in acid form is preferably about 2,000-10,000, more preferably about 4,000-7,000, and most preferably about 4,000-5,000. The water-soluble salts of these acrylic polymers may include, for example, alkali metals, ammonium, and substituted ammonium salts. Such soluble polymers are known materials. For example, the use of such polyacrylates in detergent compositions is disclosed in US 3,308,067.

[0169] Acrylic acid / maleic acid-based copolymers are also preferred components of dispersants / anti-redeposition agents. These materials include water-soluble salts of acrylic acid and maleic acid copolymers. The average molecular weight of these acidic copolymers is preferably about 2,000-100,000, more preferably about 5,000-75,000, and most preferably about 7,000-65,000. The ratio of acrylate to maleate segments in these copolymers is generally about 30:1 to about 1:1, more preferably about 10:1 to 2:1. The water-soluble salts of these acrylic acid / maleic acid copolymers may include, for example, alkali metals, ammonium, and substituted ammonium salts. Such water-soluble acrylate / maleate copolymers are known substances disclosed in EP 0193360A1, which also describes such polymers containing hydroxypropyl acrylate. Other useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as a 45 / 45 / 10 terpolymer of maleic acid / acrylic acid / vinyl alcohol.

[0170] Another polymeric material that can be added is polyethylene glycol (PEG). PEG can exhibit dispersant properties and can also be used as a clay fouling remover and anti-redeposition agent. The typical molecular weight range used for these purposes is from about 500 to about 100,000, preferably from about 1,000 to about 50,000, and more preferably from about 1,500 to about 10,000.

[0171] Polyaspartic acid and polyglutamic acid dispersants can also be used, especially in combination with zeolite detergents. The molecular weight (average) of dispersants such as polyaspartic acid is preferably about 10,000. Foam inhibitors

[0172] In particular, conventional foam inhibitors can be advantageously added to the composition during automatic washing processes. Suitable foam inhibitors include, for example, natural or synthetic soaps containing a high amount of C. 18 -C 24Fatty acids. Non-surface-active foam inhibitors are, for example, organic polymolecular silicone ethers and mixtures thereof with fine, optionally silanized silica, and paraffin, wax, microcrystalline wax and mixtures thereof with silanized silica or distearate. Mixtures of various foam inhibitors are preferred, such as mixtures of silicone, paraffin, or wax. Preferably, the foam inhibitor, especially foam inhibitors containing silicone and / or paraffin, is loaded onto a particulate, water-soluble, or dispersible carrier material. A mixture of paraffin and distearate is particularly preferred in this case.

[0173] Compounds that reduce or inhibit foam formation can be added to the detergent compositions of the present invention. Foam suppression is particularly important in so-called "high-concentration washing processes" and front-loading European washing machines.

[0174] Various materials can be used as foam inhibitors, and foam inhibitors are known to those skilled in the art. See, for example, Kirk Othmer Encyclopedia of Chemical Technology, Third Edition, Volume 7, pages 430-447 (John Wiley & Sons, Inc., 1979). One class of foam inhibitors of particular interest includes monocarboxylic acid fatty acids and their soluble salts. Monocarboxylic acid fatty acids used as foam inhibitors and their salts typically have a hydrocarbon chain with 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium, potassium, and lithium salts, as well as ammonium and alkanol ammonium salts.

[0175] The detergent compositions of the present invention may also contain non-surfactant foam inhibitors. These substances include, for example, high molecular weight hydrocarbons such as paraffin, fatty acid esters (e.g., fatty acid triglycerides), monohydric alcohol esters of fatty acids, and aliphatic C... 18 -C 40Ketones (e.g., stearone), etc. Other foam inhibitors include N-alkylaminotriazines, such as tri- to hexa-alkylmelamines or di- to tetraalkyldiamine chlorotriazines produced as a product of cyanuric chloride and 2 to 3 moles of a primary or secondary amine containing 1 to 24 carbon atoms; propylene oxide; monooctadecyl phosphates such as monooctadecyl alcohol phosphates; monooctadecyl dialkali metal (e.g., sodium, potassium, lithium) phosphates and phosphate esters. Hydrocarbons such as paraffin and haloparaffin can be used in liquid form. Liquid hydrocarbons are liquid at room temperature and atmospheric pressure, with pour points in the range of about -40°C to about 50°C, and a minimum boiling point not lower than about 110°C (at atmospheric pressure). It is also known to use waxy hydrocarbons, preferably with melting points below about 100°C. Prior art knows hydrocarbon foam inhibitors and includes aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having about 12 to about 70 carbon atoms. The term "paraffin" as used in this discussion of foam inhibitors refers to a mixture including genuine paraffin and cyclic hydrocarbons.

[0176] Another preferred class of non-surfactant foam inhibitors includes siloxane foam inhibitors. This class includes the use of polyorganosiloxane oils, such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and compositions of polyorganosiloxanes with silica gel particles, wherein the polyorganosiloxane is chemically adsorbed or melted onto the silica gel. Siloxane foam inhibitors are well known in the art.

[0177] Other siloxane foam inhibitors are disclosed in US 3,455,839, which is incorporated herein by reference in its entirety, relating to compositions and methods for defoaming aqueous solutions by adding a small amount of polydimethylsiloxane fluid.

[0178] Mixtures of siloxanes and silanized silica gel are described, for example, in DE-OS2124526, which is incorporated herein by reference in its entirety. Siloxane defoamers and foam control agents in granular detergent compositions are disclosed in US 4,652,392, which is incorporated herein by reference in its entirety.

[0179] In preferred siloxane foam inhibitors used in this invention, the solvent of the continuous phase is composed of certain polyethylene glycol or polyethylene glycol-polypropylene glycol copolymers or mixtures thereof (preferably), or polypropylene glycol. The primary siloxane foam inhibitor is branched / crosslinked, preferably not linear.

[0180] The siloxane foam inhibitor of the present invention preferably contains polyethylene glycol and a copolymer of polyethylene glycol / polypropylene glycol, the average molecular weight of which is less than about 1,000, preferably about 100-800. The polyethylene glycol and polyethylene glycol / polypropylene glycol copolymer used in the present invention have a solubility in water at room temperature greater than about 2% by weight, preferably greater than about 5% by weight.

[0181] The preferred solvent used in this invention is polyethylene glycol, with an average molecular weight of less than about 1,000, more preferably about 100-800, and most preferably about 200-400, and polyethylene glycol / polypropylene glycol copolymer, preferably PPG200 / PEG300. The weight ratio of polyethylene glycol to polyethylene glycol / polypropylene glycol copolymer is preferably about 1:1 to 1:10, and most preferably 1:3 to 1:6.

[0182] The preferred siloxane foam inhibitors used in this invention are free of polypropylene glycol, particularly polypropylene glycol with a molecular weight of 4000. They are also preferably free of ethylene oxide and propylene oxide block copolymers, such as… L101.

[0183] Other foam inhibitors used in this invention contain secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of these alcohols with siloxane oils. Secondary alcohols include those having C1-C2 groups. 16 C6-C of the chain 16 Alkyl alcohols. A preferred alcohol is 2-butyloctyl alcohol, which is available under the trademark of Condea. Purchased for 12. A mixture of secondary alcohols can be trademarked. 123 was purchased from Enichem. Mixed foam inhibitors generally contain a mixture of alcohol and siloxane in a weight ratio of 1:5 to 5:1.

[0184] The compositions of the present invention generally contain 0% to about 5% of a foam inhibitor. When used as a foam inhibitor, monobasic fatty acids and their salts are generally used in an amount of about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of a monobasic fatty acid foam inhibitor is used. Siloxane foam inhibitors are generally used in an amount of about 2% by weight of the detergent composition, although larger amounts may also be used. The upper limit of the amount can be determined according to actual conditions, mainly considering minimizing costs and ensuring that a lower amount effectively controls the foaming effect. Preferably, about 0.01% to about 1% of a siloxane foam inhibitor is used, more preferably about 0.25% to about 0.5%, as used in the present invention. These weight percentages include any silica used for mixing with polyorganosiloxanes, and any additives that may be used. Monostearic acid phosphate foam inhibitors are generally used in an amount of about 0.1% to about 2% by weight of the composition. Hydrocarbon foam inhibitors are generally used in an amount of about 0.01% to about 5.0% by weight, although larger amounts may also be used. Alcohol foam inhibitors are generally used in an amount of 0.2% to 3% by weight of the finished composition. Multivalent chelating agents and chelating agents

[0185] Polyphosphates can be considered chelating agents or stabilizers, particularly for peroxides and enzymes sensitive to heavy metal ions. For example, sodium 1-hydroxyethane-1,1-bisphosphate, sodium diethylenetriaminepentamethylenephosphonate, or sodium ethylenediaminetetramethylenephosphonate are used in amounts ranging from 0.1 to 5% by weight.

[0186] The detergent compositions of the present invention may optionally contain one or more iron and / or manganese chelating agents. These chelating agents may be selected from the group comprising aminocarboxylates, aminophosphonates, polyfunctionally substituted aromatic chelating agents, and mixtures thereof, all of which are defined below. Without being theoretically limited, it can be considered that the benefits of these substances are partly due to their exceptional ability to remove iron and manganese ions from the washing solution by forming soluble chelates. Some of the detergent builders described above can be used as chelating agents, and if such detergent builders are present in sufficient quantities, they can provide both functions.

[0187] Aminocarboxylates used as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediaminetriacetate, hypoazinotriacetate, ethylenediaminetetrapropionate, triethylenetetraaminehexaacetate, diethylenetriaminepentaacetate, and ethanol diglycine, their alkali metal, ammonium, and substituted ammonium salts, and mixtures thereof.

[0188] Aminophosphonates are also suitable as chelating agents in the compositions of the present invention, when at least a low total phosphorus content is permitted in the detergent composition, including ethylenediaminetetra(methylenephosphonate), i.e., DEQUEST. Preferably, these aminophosphonates do not contain alkyl or alkenyl groups with more than 6 carbon atoms.

[0189] Multifunctionally substituted aromatic chelating agents are also suitable for the compositions of the present invention. Preferred compounds in this acidic form are dihydroxydisulfonylbenzenes, such as 1,2-dihydroxy-3,5-disulfonylbenzene.

[0190] Preferred biodegradable chelating agents used in this invention are ethylenediamine disuccinate ("EDDS"), particularly the [S,S] isomer.

[0191] If used, these chelating agents are typically present in the detergent composition at a concentration of about 0.1% to about 10% by weight. More preferably, if used, such compositions contain about 0.1% to about 3.0% by weight of chelating agents.

[0192] Clay Stain Remover / Anti-Resettling

[0193] The detergent compositions of the present invention may optionally contain water-soluble amine oxides with clay stain removal and anti-redeposition properties. Granular detergent compositions containing these compounds generally contain about 0.01% to about 10.0% by weight of water-soluble amine oxides; liquid detergent compositions typically contain about 0.01% to about 5%.

[0194] The most preferred clay stain remover and anti-redeposition agent is tetraethylene pentamine ethoxide. An example of ethoxide amine is further described in US 4,597,898. Another class of preferred clay stain removers and anti-redeposition agents includes cationic compounds disclosed in EP 111,965, ethoxide amine polymers disclosed in EP 111,984A1, zwitterionic polymers disclosed in EP 112,592A1, and amine oxides disclosed in US 4,548,744. Another class of preferred anti-redeposition agents includes carboxymethyl cellulose (CMC) substances. These substances are well known in the art. Browning inhibitors

[0195] The task of browning inhibitors is to keep the dirt detached from the fibers suspended in the cleaning liquid, thereby preventing the re-adsorption of dirt. For this purpose, most organic natural water-soluble sols, such as (co)polycarboxylic acids, gums, gelatin salts, starch or cellulose ether carboxylic acids or ether sulfonates, or salts of acidic sulfates of cellulose or starch, are suitable. Water-soluble polyamides containing acidic groups are also suitable for this purpose. Furthermore, soluble starch preparations, such as hydrolyzed starch, aldehyde starch, etc., can be used as the aforementioned starch products. Polyvinylpyrrolidone can also be used. However, preferred cellulose ethers are carboxymethyl cellulose (sodium salt), methyl cellulose, hydroxyalkyl cellulose, and mixed ethers such as methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, methyl carboxymethyl cellulose, and mixtures thereof, as well as polyvinylpyrrolidone, used in amounts from 0.1 to 5% by weight, based on the composition. Fluorescent whitening agents and UV absorbers

[0196] Any optical brightener or other brightening or whitening agent known in the art can typically be added to the detergent composition of the present invention in an amount of about 0.05% by weight to about 1.2% by weight. Commercially available optical brighteners that can be used in the present invention can be classified into subgroups, including but not limited to stilbene, pyrazoline, coumarin, carboxylic acid, methanecyanine, dibenzothiophene-5,5-dioxide, azoles, 5- and 6-membered heterocyclic derivatives, and various other formulations.

[0197] Preferred whitening agents include Verona's. A series of whitening agents. Other disclosed whitening agents include: UNPA, Tinopal CBS and Tinopal 5BM, purchased from Ciba-Geigy; Artic CC and ArticWhite CWD, purchased from Hilton-Davis; 2-(4-styryl-phenyl)-2H-naphthol[1,2-d]triazoles; 4,4'-di-(1,2,3-triazol-2-yl)-stilbene compounds; 4,4'-bis(styryl)biphenyls; and aminocoumarins. Specific examples of these brighteners include 4-methyl-7-diethyl-aminocoumarin, 1,2-di(benzimidazol-2-yl)ethylene, 1,3-diphenyl-pyrazoline compounds, 2,5-di(benzimidazol-2-yl)thiophene, 2-styryl-naphtho[1,2-d]oxazole, and 2-(stilbene-4-yl)-2H-naphtho[1,2-d]triazole. Anionic brighteners are preferably used in the compositions of the present invention.

[0198] The composition may contain, for example, diaminostilbene disulfonic acid derivatives and their alkali metal salts as fluorescent whitening agents. Suitable fluorescent whitening agents are, for example, compounds with a structure similar to 4,4'-bis(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-disulfonic acid, which carries a diethanolamine, methylamine, phenylamine, or 2-methoxyethylamino group in place of the morpholino group. Additionally, substituted biphenylstyrene-based whitening agents may be present, such as alkali metal salts of 4,4'-bis(2-sulfostyrene)-biphenyl, 4,4'-bis(4-chloro-3-sulfostyrene)-biphenyl, or 4-(4-chlorostyrene)-4'-(2-sulfostyrene)-biphenyl. Mixtures of the above fluorescent whitening agents may also be used.

[0199] In addition, UV absorbers can be added. UV absorbers are compounds with excellent absorption properties for ultraviolet radiation. As UV stabilizers, they can also improve the light stability of pigments and dyes used in textile fibers and protect the wearer's skin by preventing UV radiation from penetrating the fibers. Typically, highly effective non-radioactive inerting compounds are derivatives of hydroxyl and / or alkoxy groups, particularly benzophenones at the 2- and / or 4-positions. Also suitable are substituted benzotriazoles, acrylates (cinnamic acid derivatives) with a 3-phenyl substituted and optionally a 2-cyano substituted group, salicylates, organic Ni complexes, and natural substances such as umbelliferones and bulk urocanic acid. In a preferred embodiment, the UV absorber absorbs UV-A and UV-B radiation, and possibly UV-C radiation, and re-emits light at blue wavelengths, thus providing an additional optical brightening effect. Preferred UV absorbers contain triazine derivatives, such as hydroxyaryl-1,3,5-triazine, sulfonated 1,3,5-triazine, o-hydroxyphenylbenzotriazole, and 2-aryl-2H-benzotriazole, as well as bis(anilinetriazinyl-amino)stilbene disulfonic acid and its derivatives. UV-absorbing dyes such as titanium dioxide can also be used as UV absorbers. Dye transfer inhibitors

[0200] The detergent compositions of the present invention may also contain one or more substances effective in preventing dye transfer from one fabric to another during washing. Typically, such dye transfer inhibitors include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanine, peroxidase, and mixtures thereof. If these formulations are used, their content is typically from about 0.01% by weight to about 10% by weight of the composition, preferably from about 0.01% by weight to about 5% by weight, and more preferably from about 0.05% by weight to about 2% by weight.

[0201] More specifically, the polyamine N-oxide polymers preferred for use in this invention are described in US 6,491,728, which is incorporated herein by reference in its entirety.

[0202] Any polymer backbone can be used as long as the resulting amine oxide polymer is water-soluble and has dye transfer inhibiting properties. Examples of suitable polymer backbones are polyethylene, polyalkylene oxides, polyesters, polyethers, polyamides, polyimides, polyacrylates, and mixtures thereof. These polymers include random or block copolymers in which one monomer type is an amine N-oxide and the other monomer type is an N-oxide. Amine N-oxide polymers typically have an amine to amine N-oxide ratio of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by suitable copolymerization or a suitable degree of N-oxidation. Polyamine oxides can be obtained at almost any degree of polymerization. The average molecular weight is typically 500-1,000,000; more preferably 1,000-500,000; and most preferably 5,000-100,000. A preferred class of substances may be referred to as "PVNO".

[0203] The most preferred polyamine N-oxide used in the detergent composition of the present invention is poly(4-vinylpyridine-N-oxide) with an average molecular weight of about 50,000 and an amine to amine N-oxide ratio of about 1:4.

[0204] Copolymers of N-vinylpyrrolidone and N-vinylimidazolium polymers (referred to as "PVPVI") are also preferably used in this invention. The average molecular weight of the PVPVI is preferably 5,000-1,000,000, more preferably 5,000-200,000, and most preferably 10,000-20,000. The PVPVI copolymers typically have a molar ratio of N-vinylimidazolium to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably 0.8:1-0.3:1, and most preferably 0.6:1-0.4:1. These copolymers can be linear or branched.

[0205] The compositions of the present invention may also use polyvinylpyrrolidone ("PVP") with an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, more preferably about 5,000 to about 50,000, which is known to those skilled in the art of detergents. Compositions containing PVP may also contain polyethylene glycol ("PEG") with an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. Preferably, the ratio of PEG to PVP provided in the detergent solution is about 2:1 to about 50:1, more preferably about 3:1 to about 10:1.

[0206] The detergent compositions of the present invention may optionally contain about 0.005% to 5% by weight of certain hydrophilic optical brighteners, which can provide dye transfer inhibition. If used, the compositions of the present invention preferably contain about 0.01% to 1% by weight of such optical brighteners.

[0207] A preferred whitening agent is 4,4'-bis[(4-anilino-6-(N-2-di-hydroxyethyl)-s-triazine-2-yl)amino]-2,2'-stilbene disulfonic acid and its disodium salt. This particular type of whitening agent is marketed under various trade names. Sold by Ciba-Geigy. Tinopal-UNPA-GX is a hydrophilic fluorescent whitening agent preferably used in the detergent compositions of the present invention.

[0208] Another preferred whitening agent is disodium 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazine-2-yl)amino]2,2'-stilbene disulfonic acid. This particular type of whitening agent is marketed under the trade name Tinopal. Sold by Ciba-Geigy.

[0209] Another preferred brightener is sodium salt of 4,4'-bis[(4-anilino-6-morpholino-s-triazine-2-yl)amino]-2,2'-stilbene disulfonic acid. This particular type of brightener is marketed under the trade name Tinopal. Sold by Ciba-Geigy.

[0210] When used in combination with the selected polymeric dye transfer inhibitors described above, the specific optical brighteners selected for use in this invention provide particularly effective dye transfer inhibition performance. The combination of such selected polymeric materials (e.g., PVNO and / or PVPVI) with such selected optical brighteners (e.g., Tinopal UNPA-GX, Tinopal 5BM-GX, and / or Tinopal AMS-GX) provides significantly better inhibition of dye transfer in aqueous washing solutions than either of these detergent composition components used alone. Without being theoretically limited, it is believed that these brighteners act in a manner whereby they deposit relatively quickly onto the fabric due to their high affinity for the fabric in the washing solution. The extent to which the brightener is deposited on the fabric in the washing solution is defined by a parameter called the "consumption factor." This consumption factor generally refers to a) the ratio of the brightener substance deposited on the fabric to b) the initial concentration of the brightener in the washing aqueous solution. Brighteners with relatively high consumption factors are best suited for inhibiting dye transfer in this type of technical content of the invention.

[0211] Of course, it will be recognized that other types of conventional optical brighteners of these compounds can optionally be used in the compositions of the present invention to provide conventional fabric “whitening” benefits, but without actually inhibiting dye transfer. This application is conventional and well known in detergent formulation. Thickener

[0212] The composition may also contain common thickeners and anti-deposition compositions, as well as viscosity modifiers, such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, polyamine derivatives such as quaternized and / or ethoxylated hexamethylenediamine, and mixtures thereof. Preferred compositions have a viscosity below 10,000 mPa*s, measured using a Brookfield viscometer at 20°C for 50 minutes. -1 Measured at the shear rate. Inorganic salts

[0213] Other suitable components of the composition are water-soluble inorganic salts, such as bicarbonates, carbonates, amorphous silicates, or mixtures thereof; alkali metal carbonates and amorphous silicates are particularly used, primarily sodium silicate with a Na₂O:SiO₂ molar ratio of 1:1 to 1:4.5, preferably 1:2 to 1:3.5. Preferred compositions contain an alkaline salt, a detergent builder, and / or auxiliary detergent builders, preferably sodium carbonate, zeolite, crystalline, layered sodium silicate, and / or trisodium citrate, in amounts of 0.5 to 70% by weight, preferably 0.5 to 50% by weight, and particularly 0.5 to 30% by weight of anhydrous substances. Fragrances and colorants

[0214] The composition may also contain typical detergent and cleaning composition ingredients, such as fragrances and / or colorants, preferably such colorants that leave no or negligible staining on the washed fabric. The total amount of added colorant is preferably less than 1% by weight, more preferably less than 0.1% by weight, based on the composition. The composition may also contain a white pigment, such as TiO2. Industrial Applicability

[0215] Another object of the present invention relates to the use of the cyclopropyl derivative according to the invention as a fragrance. Example Example 1 Synthesis of 2-methyl-1-(2-methylcyclopropyl)but-1-one (1:1 isomer)

[0216] The cyclopropanation of 5-methylhept-2-en-4-one (by the Johnson-Corey-Chaykovsky reaction) followed the procedure known in the literature providing the title compound. MS:140,125,112,98,83,69,55,41,29. 1 H NMR (400 MHz, CDCl3) δ2.57 (dtq, J=10.6, 6.7, 3.2 Hz, 2H), 1.80–1.65 (m, 4H), 1.45 (dqt, J=13.3, 6.3, 3.1 Hz,2H),1.38–1.28(m,2H),1.29–1.17(m,2H),1.16–1.08(m,12H),0.90(t,J=7.4 Hz,3H),0.89(t,J=7.5 Hz,3H),0.74–0.62(m,2H). 13 C NMR(101 MHz, CDCl3)δ213.97,213.96,48.73,48.66,28.35,28.27,26.06,25.98,20.08,20.02,19.08,19.06,18.14,18.10,15.82,15.71,11.71,11.68. Scent: Mint, Fresh, Nutty Example 2 Two-step synthesis of 9-cyclopropylnonanal (1) Synthesis of 9-cyclopropylnon-1-ol

[0217] Under a nitrogen atmosphere, between 0 and 5 °C, a pre-dissolved solution of trifluoroacetic acid in DCM (45 mL) (6.64 mL, 89.42 mmol) was added very slowly to a suspension of Et₂Zn (99.4 mL, 89.42 mmol) and DCM (90 mL), and the reaction was maintained at the same temperature for 30 min. Subsequently, CH₂I₂ (7.21 mL, 89.42 mmol) was added to DCM (45 mL) and the reaction was maintained for 30 min, followed by the addition of an alcohol (9 mL, 44.71 mmol) to DCM (45 mL). The reaction was maintained overnight at room temperature (approximately 20 h) and quenched with saturated NH₄Cl (200 mL). The compound was extracted from the aqueous layer using cyclohexane (100 mL x 3). The combined organic layers were washed with saturated NaHCO₃, water, and brine, dried over Na₂SO₄, filtered, and evaporated to a crude product (10.6 g). The title compound (6.54 g, 79%) was purified by classical column chromatography (cyclohexane:ethyl acetate) to obtain a colorless oil. (2) Synthesis of 9-cyclopropylnonanal

[0218] Add 6.54 g (35.46 mmol) of a pre-dissolved solution of 9-cyclopropylnon-1-ol in DCM (40 mL) to a suspension (22.56 g, 53.19 mmol) of Dess-Martin periodinane in DCM (395 mL) and maintain the reaction overnight at room temperature. (hours). Add Et2O (400 mL) and wash with 1 M NaOH (500 mL × 2), dry with Na2SO4, filter and evaporate to crude product (6.3 g). Purify by classical column chromatography (cyclohexane: ether) to obtain colorless oily title compound (4.99 g, 77%) with a very strong odor. MS:182,135,126,111,97,81,67,55,41,29 1 H NMR(400MHz,C6D6)δ9.34(t,J=1.7Hz,1H),1.82(td,J=7.3,1.7Hz,2H),1.45–0.99(m, 14H),0.61(dddt,J=13.0,8.2,6.9,3.4Hz,1H),0.46–0.34(m,2H),0.06–0.00(m,2H). 13C NMR (101MHz, C6D6) δ200.71,43.91,35.15,30.06,29.86,29.72,29.72 29.41,22.25,11.32,4.86,4.86. Odor: Strong aldehyde smell, soap smell, green smell, water smell.

Claims

1. Cyclopropyl derivatives of formula (I) R 1 -R 2 (I) in -R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl residue; -R 2 Representative-CO-R 3 or -(CH2) n -R 4 Group; -R 3 represents a straight or branched C1-C6 alkyl group; -R 4 represents -CH2OH or -CH=O; and -n represents an integer between 1 and 12.

2. The cyclopropyl derivative according to claim 1, wherein R 2 Representative-CO-R 3 And R 3 represents a straight-chain or branched alkyl group having 3 or 4 carbon atoms.

3. The cyclopropyl derivative according to claim 1, wherein R 2 Representatives – (CH2) n -R 4 , R 4 represents -CH=O, and n represents an integer of 8 to 10.

4. The cyclopropyl derivative according to claim 1, which is represented by formula (II):

5. The cyclopropyl derivative according to claim 1, which is represented by formula (III) or (IV): or a mixture thereof.

6. A method for obtaining a cyclopropyl derivative of formula (I) R 1 -R 2 (I) in -R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl residue; -R 2 Representative-CO-R 3 groups; and -R 3 represents a straight or branched C1-C6 alkyl group; By the Johnson–Corey–Chaykovsky reaction, wherein an enone according to formula (V) CH3-CH=CH-R 2 (V) Where R 2 Having the above meaning, in the presence of Me3S - Hal + The cyclopropanation is carried out in the presence of a sulfur ylide of the structure, wherein Hal represents bromine, chlorine or iodine.

7. The method according to claim 6, wherein the method is carried out in the presence of DMSO and sodium hydride.

8. A method for obtaining a cyclopropyl derivative of formula (I) R 1 -R 2 (I) in -R 1 represents a cyclopropyl or C1-C6-alkylcyclopropyl residue; -R 2 Representatives – (CH2) n -R 4 Group; -R 4 represents -CH2OH or -CH=O; and -n represents an integer between 1 and 12. Through the Simmons-Smith reaction, (a) In the first step, an ω-unsaturated fatty alcohol according to formula (VI) CH2=CH-(CH2) n -CH2OH wherein n has the above meaning, the cyclopropanation is carried out in the presence of an organozinc carbene having the structure Hal-ZnCH2-Hal, and wherein Hal represents bromine, chlorine or preferably iodine, and optionally (b) The hydroxyl group of the reaction product obtained in step (i) is oxidized to form an aldehyde group.

9. The method according to claim 8, wherein the reaction is carried out in the presence of an organic zinc carbene having a Hal-ZnCH2-Hal structure, wherein Hal represents bromine, chlorine or iodine.

10. The process according to claim 6 and or 8, wherein the reaction is carried out in dichloromethane or chloroform as solvent.

11. A spice mixture comprising or consisting of the following ingredients: (a) at least one cyclopropyl derivative according to formula (I) as a primary flavorant, and (b) at least one secondary flavorant different from (a).

12. The mixture of claim 11, wherein the components (a) and (b) are present in a weight ratio of about 0.01:99.99 to 10:

90.

13. The mixture according to claim 11, further comprising a solvent.

14. A cosmetic, personal care or detergent composition comprising the cyclopropyl derivative according to claim 1 or the fragrance mixture according to claim 11.

15. Use of the cyclopropyl derivative according to claim 1 as a fragrance.

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