Reflective device, method of manufacturing a reflective device, and vehicle
By using a sealing colloid filled with high dielectric constant filler particles to connect the transparent conductive layer and the reflective layer in the reflector, the problem of unstable dimming performance of the reflector was solved, and the reflectivity was made controllable and stable.
Patent Information
- Application Number
- CN202311075764.2
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-08-24
- Publication Date
- 2025-10-17
- Estimated Expiration
- 2043-08-24
AI Technical Summary
The breakdown voltage between the transparent conductive layer and the reflective layer of the existing reflector is low, resulting in unstable dimming performance.
A sealing colloid filled with filler particles of dielectric constant greater than or equal to 20 connects the transparent conductive layer and the reflective layer to form a cavity, and a dimming composition is injected into the cavity to improve the electric field breakdown voltage and electrochemical stability.
The reflection reliability and service life of the reflective device are improved, and the stability and controllability of the reflectivity are ensured.
Smart Images

Figure CN119511598B_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The present application relates to the technical field of reflectors, in particular to a reflector device, a reflector device manufacturing method and a vehicle. BACKGROUND
[0002] A reflector is an optical element with a smooth surface and the ability to reflect light. In order to adapt to more application scenarios, some reflectors can adjust reflectivity.
[0003] Reflectivity automatic adjustment reflectors mainly use organic small molecule compositions. Under the action of voltage, the organic small molecules between the transparent conductive layer and the reflective layer undergo electrochemical redox reactions, change the molecular structure, absorb visible light, and thus adjust the reflectivity of the device. At present, the breakdown voltage between the transparent conductive layer and the reflective layer is low, which easily makes the light adjustment performance of the reflector unstable. SUMMARY
[0004] The technical problem to be solved by the embodiments of the present application is to provide a reflector device with controllable reflectivity and high stability, a reflector device manufacturing method and a vehicle.
[0005] In a first aspect, the present application provides a reflector device, comprising:
[0006] a first transparent substrate comprising a first surface and a second surface opposite to each other;
[0007] a transparent conductive layer disposed on the second surface;
[0008] a second transparent substrate comprising a third surface and a fourth surface opposite to each other;
[0009] a reflective layer disposed on the third surface, the reflective layer facing the transparent conductive layer;
[0010] a sealing gel connected between the first transparent substrate and the second transparent substrate, the sealing gel and the transparent conductive layer and the reflective layer surrounding a cavity; the sealing gel comprises filling particles with a dielectric constant greater than or equal to 20;
[0011] a light adjustment composition disposed in the cavity.
[0012] In combination with the first aspect, in a possible implementation manner, the dielectric constant of the filling particles is 25-150.
[0013] In combination with the first aspect, in a possible implementation manner, the filling particles comprise one or more of lead titanate, barium titanate, lanthanum titanate, titanium oxide and zirconium oxide.
[0014] With reference to the first aspect, in a possible implementation manner, the sealing glue is hollow in a thickness direction, and two end surfaces of the sealing glue in the thickness direction are connected with the transparent conductive layer and the reflective layer respectively.
[0015] With reference to the first aspect, in a possible implementation manner, the sealing glue comprises a first sealing glue and a second sealing glue, and the first sealing glue and the second sealing glue jointly form the sealing glue.
[0016] With reference to the first aspect, in a possible implementation manner, the filling particles are in any one of a cuboid, a cube, a sphere, and a cylinder.
[0017] With reference to the first aspect, in a possible implementation manner, the first transparent substrate comprises one of glass, acrylic, and polyvinyl chloride, and the second transparent substrate comprises one of glass, acrylic, and polyvinyl chloride, and the visible light transmittance of the first transparent substrate and the second transparent substrate is greater than or equal to 80%.
[0018] With reference to the first aspect, in a possible implementation manner, the transparent conductive layer comprises at least one of ITO, CTO, ZnO, and InO; and / or, the thickness of the transparent conductive layer is 50 nm-500 nm; and / or, the visible light transmittance of the transparent conductive layer is greater than or equal to 80%.
[0019] With reference to the first aspect, in a possible implementation manner, the reflective layer comprises one of silver, silver alloy, aluminum, aluminum alloy, chromium, and chromium alloy; and / or, the thickness of the reflective layer is 10 nm-500 nm; and / or, the reflectivity of the reflective layer is greater than or equal to 70%.
[0020] With reference to the first aspect, in a possible implementation manner, the reflective device further comprises a transition layer, the transition layer is arranged between the reflective layer and the third surface, and the transition layer comprises at least one of SiO, TiO, Nb2O5, and Al2O3.
[0021] With reference to the first aspect, in a possible implementation manner, the reflective device further comprises a first electrode sheet and a second electrode sheet, the first electrode sheet is electrically connected with the transparent conductive layer, and the second electrode sheet is electrically connected with the reflective layer.
[0022] With reference to the first aspect, in a possible implementation manner, the surface of the transparent conductive layer facing the first transparent substrate comprises a contact area in contact with the second surface and a recessed area recessed away from the second surface, the recessed area surrounds the contact area, the recessed area is spaced apart from the second surface, and a decorative layer is arranged between the recessed area and the second surface, the reflectivity of the decorative layer is greater than or equal to 50%.
[0023] According to a second aspect, the present application provides a manufacturing method of a reflective device, comprising:
[0024] providing a first transparent substrate, the first transparent substrate comprising a first surface and a second surface arranged oppositely, and a transparent conductive layer arranged on the second surface;
[0025] providing a second transparent substrate, the second transparent substrate comprising a third surface and a fourth surface arranged oppositely, and a reflective layer arranged on the third surface;
[0026] arranging the transparent conductive layer to face the reflective layer, and spacing the transparent conductive layer from the reflective layer;
[0027] forming a sealing gel between the first transparent substrate and the second transparent substrate, the sealing gel and the transparent conductive layer and the reflective layer surrounding a cavity, and filling a light-adjusting composition in the cavity; the sealing gel comprises filling particles with a dielectric constant greater than or equal to 20.
[0028] With reference to the second aspect, in a possible implementation manner, the step of arranging the reflective layer on the third surface comprises:
[0029] arranging a transition layer on the third surface;
[0030] arranging the reflective layer on a surface of the transition layer away from the second transparent substrate.
[0031] With reference to the second aspect, in a possible implementation manner, the sealing gel comprises a first sealing gel and a second sealing gel, and the step of forming the sealing gel between the first transparent substrate and the second transparent substrate, the sealing gel and the transparent conductive layer and the reflective layer surrounding a cavity, and filling a light-adjusting composition in the cavity, comprises:
[0032] arranging the first sealing gel between the first transparent substrate and the second transparent substrate, the first sealing gel connecting the first transparent substrate and the second transparent substrate, and the first sealing gel and the transparent conductive layer and the reflective layer surrounding a cavity with an opening;
[0033] filling the light-adjusting composition into the cavity through the opening;
[0034] A second sealant is disposed between the first transparent substrate and the second transparent substrate to seal the opening, the second sealant connecting the first transparent substrate and the second transparent substrate.
[0035] In a third aspect, the present application discloses a vehicle, comprising the reflective device according to the first aspect.
[0036] In the present application, the sealant connects the first transparent substrate and the second transparent substrate, and the sealant has the filler particles, the dielectric constant of the filler particles is greater than or equal to 20, the breakdown voltage of the electric field formed by the reflective layer and the transparent conductive layer can be improved, the electrochemical stability of the filler particles under the electric field can be improved, the reflection reliability of the reflective device can be further improved, and the service life of the reflective device can be prolonged. BRIEF DESCRIPTION OF DRAWINGS
[0037] In order to more clearly illustrate the technical solutions in the embodiments of the present application or the background art, the drawings needed to be used in the embodiments of the present application or the background art will be described below.
[0038] Figure 1 A cross-sectional view of a mirror device provided for Embodiment 1 of the present application;
[0039] Figure 2 A top view of a mirror device provided for Embodiment 1 of the present application, in which the first transparent substrate and the transparent conductive layer are removed;
[0040] Figure 3 A cross-sectional view of a transparent conductive layer provided for Embodiment 1 of the present application;
[0041] Figure 4 A flowchart of a mirror device manufacturing method provided for Embodiment 2 of the present application.
[0042] BRIEF DESCRIPTION OF DRAWINGS
[0043] 10, first transparent substrate; 11, first surface; 12, second surface;
[0044] 20, transparent conductive layer; 21, contact area; 22, recessed area;
[0045] 30, second transparent substrate; 31, third surface; 32, fourth surface;
[0046] 40, reflective layer;
[0047] 50, light-adjusting composition;
[0048] 60, transition layer;
[0049] 70, sealant; 71, first sealant; 72, second sealant;
[0050] 80, the decorative layer;
[0051] 90, the first electrode sheet;
[0052] 100, the second electrode sheet. DETAILED DESCRIPTION
[0053] The mirror is an optical element with smooth surface and light reflecting ability, and is a very important object in life and science. The mirror is used for grooming in life, the rearview mirror is used for observing the driving state of the rear vehicle in the automobile, and the reflecting telescope belongs to the mirror.
[0054] In order to adapt the mirror to more application scenarios, some mirrors can adjust the reflectivity. The reflectivity automatic adjusting mirror mainly uses an organic small molecule composition to complete, under the action of voltage, the organic small molecule between the transparent conductive layer and the reflecting layer undergoes electrochemical oxidation-reduction reaction, changes the molecular structure, absorbs visible light, and thus adjusts the reflectivity of the device. At present, the breakdown voltage between the transparent conductive layer and the reflecting layer is low, which is easy to make the light adjusting performance of the mirror unstable.
[0055] In order to make the purpose, technical scheme and advantages of the present application clearer, the present application will be described in further detail below with reference to the drawings.
[0056] The present application discloses a reflecting device, a reflecting device manufacturing method and a vehicle, wherein the vehicle comprises the reflecting device, the reflecting device can reflect incident light, and the mirror can be used as the rearview mirror of the vehicle to facilitate the driver to observe the situation behind the vehicle through the rearview mirror when driving the vehicle. The vehicle can be but is not limited to a fuel automobile, an electric automobile, a motorcycle and an electric power-assisted vehicle.
[0057] Please refer to Figures 1-2 , the reflecting device comprises a first transparent substrate 10, a second transparent substrate 30, a transparent conductive layer 20, a reflecting layer 40, a sealing glue 70 and a light adjusting composition 50.
[0058] The first transparent substrate 10 comprises a first surface 11 and a second surface 12 arranged back along the thickness direction, the first transparent substrate 10 comprises at least one of glass, acrylic and polyvinyl chloride, and the visible light transmittance of the first transparent substrate 10 is greater than or equal to 80%. It should be noted that there can be an error in the visible light transmittance of the first transparent substrate 10, wherein the visible light transmittance of the first transparent substrate 10 can have an error of 10%, and in the actual application, the visible light transmittance of the first transparent substrate 10 can be set to 72% or more. The specific thickness of the first transparent substrate 10 is not limited in the present application. The first transparent substrate 10 has a high visible light transmittance, so that most of the incident light can pass through the first transparent substrate 10.
[0059] The second transparent substrate 30 includes a third surface 31 and a fourth surface 32 disposed opposite to each other in the thickness direction. The second transparent substrate 30 includes at least one of glass, acrylic, and polyvinyl chloride, and has a visible light transmittance of 80% or more. It should be noted that the visible light transmittance of the second transparent substrate 30 can have an error of 10%, and in actual applications, the visible light transmittance of the second transparent substrate 30 can be set to 72% or more. The thickness of the second transparent substrate 30 is not limited in the present application.
[0060] The transparent conductive layer 20 is disposed on the second surface 12, and includes at least one of ITO (indium tin oxide), CTO (cadmium tin oxide), ZnO (zinc oxide), and InO (indium oxide). It should be noted that the material of the transparent conductive layer 20 can be any one of ITO, CTO, ZnO, and InO, or a combination of multiple materials of ITO, CTO, ZnO, and InO. The thickness of the transparent conductive layer 20 is 50 nm to 500 nm, and can have an error of 10%, for example, the actual thickness of the transparent conductive layer 20 can be set to 45 nm to 550 nm. The transparent conductive layer 20 has a visible light transmittance of 80% or more, which facilitates the transmission of incident light through the transparent conductive layer 20. It should be noted that the visible light transmittance of the transparent conductive layer 20 can have an error of 10%, and in actual applications, the visible light transmittance of the transparent conductive layer 20 can be set to 72% or more. The sheet resistance of the transparent conductive layer 20 is 30 Ω or less, and can have an error of 10%, and in actual applications, the sheet resistance of the transparent conductive layer 20 can be 33 Ω or less.
[0061] The reflective layer 40 is arranged on the third surface 31. It should be noted that the reflective layer 40 arranged on the third surface 31 can be directly arranged on the third surface 31 or indirectly arranged on the third surface 31. The reflective layer 40 includes one of silver, silver alloy, aluminum, aluminum alloy, chromium, and chromium alloy. The thickness of the reflective layer 40 can be 10 nm to 500 nm, and the thickness of the reflective layer 40 can have a 10% thickness error, for example, the actual thickness of the reflective layer 40 can be 9 nm to 550 nm. The reflectivity of the reflective layer 40 is greater than or equal to 70%, and specifically, the reflectivity of the reflective layer 40 can have a 10% error, for example, the actual reflectivity of the reflective layer 40 can be greater than or equal to 63%, and the reflective layer 40 can be used to reflect incident light. The high reflectivity of the reflective layer 40 can reflect most of the incident light irradiated on the reflective layer 40. The sheet resistance of the reflective layer 40 is less than or equal to 10 Ω, and the sheet resistance of the reflective layer 40 can have a 10% error. In actual application, the sheet resistance of the reflective layer 40 can be less than or equal to 11 Ω.
[0062] In the embodiments provided in the present application, the reflective layer 40 faces the transparent conductive layer 20, the reflective layer 40 is spaced apart from the transparent conductive layer 20, the transparent conductive layer 20 can be connected to the positive electrode of the power supply, and the reflective layer 40 can be electrically connected to the negative electrode of the power supply. The transparent conductive layer 20 connected to the positive electrode of the power supply and the reflective layer 40 connected to the negative electrode of the power supply can form an electric field.
[0063] The sealing adhesive 70 is connected between the first transparent substrate 10 and the second transparent substrate 30, and surrounds the transparent conductive layer 20 and the reflective layer 40 to form a cavity. The cavity is used to accommodate the light-adjusting composition 50, and the light-adjusting composition is used to adjust the reflectivity of incident light.
[0064] The sealing adhesive 70 includes glue and filling particles. The glue can be thermosetting glue, and the sealing adhesive 70 can also be light-curing or heat-curing glue. Specifically, the glue includes but is not limited to phenolic, epoxy, polyurethane, unsaturated polyester, heterocyclic polymer, unsaturated polyvinyl, polyacrylic acid, epoxy-acrylic acid, and polyurethane-acrylic acid. The dielectric constant of the glue can be 2 to 4.
[0065] The dielectric constant of the filling particles is greater than or equal to 20, which can improve the breakdown voltage of the electric field formed by the reflective layer 40 and the transparent conductive layer 20, thereby improving the electrochemical stability of the light-adjusting composition under the action of the electric field, further improving the reflection reliability of the reflector, and prolonging the service life of the reflector. It should be noted that the dielectric constant of the filling particles can have a 10% error, and the actual dielectric constant of the filling particles can be 18 or more.
[0066] The dielectric constant of the filling particles can be 25-150, and the material of the filling particles can be one of lead titanate, barium titanate, lanthanum titanate, titanium oxide and zirconium oxide, or a combination of multiple materials selected from the group consisting of lead titanate, barium titanate, lanthanum titanate, titanium oxide and zirconium oxide.
[0067] In some embodiments, the sealing glue is doped with filling particles of different dielectric constants, and the voltage resistance performance between the transparent conductive layer and the reflective layer in the reflective device is different. For details, see the following table. In the table, when the sealing glue is doped with filling particles of a dielectric constant of 26, a voltage of 7V is needed between the transparent conductive layer and the reflective layer to break down. When the sealing glue is doped with filling particles of a dielectric constant of 50, a voltage of 12V is needed between the transparent conductive layer and the reflective layer to break down. When the sealing glue is doped with filling particles of a dielectric constant of 1.56, only a voltage of 3V is needed between the transparent conductive layer and the reflective layer to break down.
[0068] Dielectric constant of the filler particles Voltage resistance performance Example 1 26 7V breakdown failure Example 2 50 12V breakdown failure Comparative Example 1 1.56 3V breakdown failure
[0069] The shape of the filling particles can be any one of a cuboid, a cube, a sphere or a cylinder. In the sealing glue 70, the shapes of the filling particles can be the same, or different shapes of the filling particles can exist in the sealing glue 70. The filling particles with regular shapes and uniform sizes can be used as supports to effectively ensure the uniform thickness of the sealing glue, thereby ensuring the uniform gap between the first transparent substrate and the second transparent substrate, and ensuring the stable and uniform electric field and reflectivity of the positive and negative electrode plates.
[0070] In the embodiments provided in the present application, when the filling particles are spheres, the size of the filling particles is 30-300 μm. The uniform size of the filling particles in the glue can make the sealing glue 70 tend to be flat as a whole, and improve the stability of the sealing glue 70 in connecting the first transparent substrate 10 and the second transparent substrate 30.
[0071] In the embodiments provided in the present application, in one possible implementation, the transparent conductive layer 20 completely covers the second surface 12, the transition layer 60 completely covers the third surface 31, the reflective layer 40 completely covers the transition layer 60, and the sealing glue 70 is connected between the transparent conductive layer 20 and the reflective layer 40 and surrounds the cavity.
[0072] In the embodiments provided in the present application, please refer to Figure 3The surface of the transparent conductive layer 20 facing the first transparent substrate comprises a contact area 21 in contact with the second surface and a recessed area 22 recessed away from the second surface 12, the recessed area 22 surrounds the contact area 21, the recessed area 22 is spaced apart from the second surface 12, and a decorative layer 80 is arranged between the recessed area 22 and the second surface 12, the reflectivity of the decorative layer 80 is greater than or equal to 50%. The reflectivity of the decorative layer 80 can have an error of 10%, and in actual application, the reflectivity of the decorative layer 80 can be greater than or equal to 45%. On the one hand, the decorative layer 80 can improve the overall aesthetics of the reflective device, and on the other hand, the decorative layer 80 can reduce the escape of light incident on the light-adjusting composition 50 from the sealing gel 70.
[0073] In the embodiments provided in the present application, the sealing gel 70 comprises a first sealing gel 71 and a second sealing gel 72, and the first sealing gel 71 and the second sealing gel 72 jointly form the sealing gel 70.
[0074] In the embodiments provided in the present application, the light-adjusting composition 50 is in contact with the transparent conductive layer 20 and the reflective layer 40, in other words, if the first transparent substrate 10 and the second transparent substrate 30 are arranged in a top-down manner, the light-adjusting composition 50 is arranged on the third surface 31 of the second transparent substrate 30, and the light-adjusting composition 50 can support the first transparent substrate 10, thereby improving the stability of the overall structure of the reflective device.
[0075] The light-adjusting composition 50 has a cathode active substance and an anode active substance, and under the action of an electric field, the light-adjusting composition 50 can undergo an electrochemical oxidation-reduction reaction, so that the molecular structure in the light-adjusting composition 50 changes, thereby improving the absorption of incident light by the light-adjusting composition 50 and reducing the reflectivity of the reflective device. For example, under the action of an electric field, the light-adjusting composition 50 can change the absorption of incident light, and if the light-adjusting composition 50 increases the ability to absorb light under the action of an electric field, the reflectivity of the reflective device can be reduced from more than 60% to less than 15%. It should be noted that when the reflectivity of the reflective device is adjusted, the reflectivity of the reflective device can be controlled by adjusting the intensity of the electric field.
[0076] In the embodiments provided in the present application, the reflective device further comprises a transition layer 60, the transition layer 60 is arranged between the reflective layer 40 and the third surface 31, and the transition layer 60 comprises at least one of SiO (silicon monoxide), TiO (indium tin oxide), Nb2O5 (diniobium pentoxide) and Al2O3 (aluminum trioxide). It should be noted that the second transparent substrate 30 comprises one of glass, acrylic and polyvinyl chloride, and the reflective layer 40 comprises one of silver, silver alloy, aluminum, aluminum alloy, chromium and chromium alloy. If the reflective layer 40 is directly arranged on the second transparent substrate 30, the connection between the reflective layer 40 and the second transparent substrate 30 is unstable. The transition layer 60 comprises at least one of SiO, TiO, Nb2O5 and Al2O3, the transition layer 60 can be well attached to the second transparent substrate 30, and the reflective layer 40 can also be well attached to the transition layer 60. By arranging the transition layer 60 on the third surface 31 of the second transparent substrate 30 and then arranging the reflective layer 40 on the transition layer 60, the reflective layer 40 can be more stably arranged on the second transparent substrate 30. The thickness of the transition layer 60 can be 1 nm-300 nm, and an error of 10% is allowed in the process of forming the transition layer 60. The thickness of the transition layer 60 can be 0.9 nm-330 nm.
[0077] In the embodiments provided in the present application, the reflective device further comprises a first electrode sheet 90 and a second electrode sheet 100, the first electrode sheet 90 is electrically connected with the transparent conductive layer 20, and the second electrode sheet 100 is electrically connected with the reflective layer 40. By arranging the first electrode sheet 90 and the second electrode sheet 100 on the reflective device, the reflective device can be conveniently electrically connected with an external power supply. Specifically, the first electrode sheet 90 is connected with the positive electrode of the external power supply, and the second electrode sheet 100 is connected with the negative electrode of the external power supply, so that the transparent conductive layer 20 and the reflective layer 40 form an electric field.
[0078] Please refer to Figure 4 The embodiments of the present application also provide a manufacturing method of a reflective device. The specific structure of the reflective device is described in the embodiment 1, and the method comprises the following steps.
[0079] S101, providing a first transparent substrate, the first transparent substrate comprises a first surface and a second surface arranged oppositely, and a transparent conductive layer is arranged on the second surface;
[0080] The transparent conductive layer is arranged on the second surface by vacuum plating.
[0081] S102, providing a second transparent substrate, the second transparent substrate comprises a third surface and a fourth surface arranged oppositely, and a reflective layer is arranged on the third surface.
[0082] Specifically, in order to enable the reflection layer to be stably arranged on the second transparent substrate, a transition layer is vacuum-plated on the third surface, and then the reflection layer is vacuum-plated on the transition layer.
[0083] S103, the transparent conductive layer faces the reflection layer, and the transparent conductive layer is spaced apart from the reflection layer.
[0084] S104, a first sealant is arranged between the first transparent substrate and the second transparent substrate, the first sealant connects the first transparent substrate and the second transparent substrate, and the first sealant, the transparent conductive layer, and the reflection layer form a cavity with an opening.
[0085] The first sealant can connect the first transparent substrate and the second transparent substrate, so as to improve the connection stability of the first transparent substrate and the second transparent substrate.
[0086] When the first sealant is arranged, dispensing can be performed on the third surface of the second transparent substrate or the reflection layer to form the cavity with the opening, pressure is applied to the first transparent substrate and the second transparent substrate, and the first sealant is cured.
[0087] S105, the light-adjusting composition is injected into the cavity through the opening.
[0088] The first sealant connecting the first transparent substrate and the second transparent substrate can also form the cavity accommodating the light-adjusting layer, and specifically, the cavity has the opening, and the light-adjusting composition is injected into the cavity from the opening in a vacuum injection manner.
[0089] S106, a second sealant is arranged between the first transparent substrate and the second transparent substrate to block the opening, and the second sealant connects the first transparent substrate and the second transparent substrate.
[0090] The second sealant can block the opening and limit the light-adjusting composition in the cavity, and can also connect the first transparent substrate and the second transparent substrate, so as to improve the connection stability of the first transparent substrate and the second transparent substrate.
[0091] It should be noted that all directional indications (such as up, down, left, right, front, back, etc.) in the embodiments of the present application are only used to explain the relative positional relationship, movement condition, etc. between components in a certain posture (as shown in the drawings), and if the certain posture changes, the directional indications also change accordingly.
[0092] In addition, the descriptions such as "first", "second", etc. in the present application are only for the purpose of description, and cannot be understood as indicating or implying the relative importance of the technical features or implicitly indicating the number of the technical features indicated. Therefore, the features defined with "first", "second" can explicitly or implicitly include at least one of the features. In the description of the present application, the meaning of "a plurality of" is at least two, for example, two, three, etc., unless otherwise explicitly specified and limited.
[0093] In the present application, unless otherwise explicitly specified and limited, the terms "connection", "fixing" and the like should be understood broadly, for example, "fixing" can be fixed connection, or detachable connection, or integral; can be mechanical connection, or electrical connection; can be direct connection, or indirect connection through intermediate medium; can be internal communication of two elements or interaction relationship between two elements, unless otherwise explicitly limited. For those skilled in the art, the specific meaning of the above terms in the present application can be understood according to the specific circumstances.
[0094] In addition, the technical solutions of various embodiments of the present application can be combined with each other, but it must be based on the fact that a person skilled in the art can realize it, when the combination of technical solutions appears contradictory or cannot be realized, it should be considered that the combination of technical solutions does not exist, nor is it within the protection scope of the present application.
[0095] The above is only a specific embodiment of the present application, but the protection scope of the present application is not limited to this, any person skilled in the art can easily think of changes or replacements within the technical range disclosed by the present application, which should be covered within the protection scope of the present application. Therefore, the protection scope of the present application should be subject to the protection scope of the claims.
Claims
1. A reflective device, characterized in that: include: A first transparent substrate comprising a first surface and a second surface opposite to each other; a transparent conductive layer, disposed on the second surface; A second transparent substrate including a third surface and a fourth surface facing each other; a reflective layer, disposed on the third surface, the reflective layer facing the transparent conductive layer; A sealing colloid, the sealing colloid being connected between the first transparent substrate and the second transparent substrate, the sealing colloid, the transparent conductive layer, and the reflective layer forming a cavity; the sealing colloid comprising filling particles having a dielectric constant greater than or equal to 20; The dimming composition is arranged in the cavity.
2. The reflective device according to claim 1, wherein: The dielectric constant of the filling particles is 25-150.
3. The reflective device according to claim 2, wherein: The filling particles include one or more of lead titanate, barium titanate, lanthanum titanate, titanium oxide and zirconium oxide.
4. The reflective device according to any one of claims 1 to 3, wherein: The sealing colloid is hollowed along the thickness direction, and two end surfaces of the sealing colloid along the thickness direction are respectively connected to the transparent conductive layer and the reflective layer.
5. The reflective device according to claim 1, wherein: The sealing colloid comprises a first sealing glue and a second sealing glue, and the first sealing glue and the second sealing glue are combined to form the sealing colloid.
6. The reflective device according to claim 1 or 5, characterized in that: The filling particles are in any one of a cuboid, a cube, a sphere and a cylinder.
7. The reflective device according to claim 1, wherein: The filling particles are spherical in shape, and have a diameter of 30 μm to 300 μm.
8. The reflective device according to claim 1, wherein: The first transparent substrate comprises one of glass, acrylic, and polyvinyl chloride; the second transparent substrate comprises one of glass, acrylic, and polyvinyl chloride; and visible light transmittances of the first transparent substrate and the second transparent substrate are both greater than or equal to 80%.
9. The reflective device according to claim 1, wherein: The transparent conductive layer includes at least one of ITO, CTO, ZnO, and InO; and / or the thickness of the transparent conductive layer is 50 nm-500 nm; and / or the visible light transmittance of the transparent conductive layer is greater than or equal to 80%.
10. The reflective device according to claim 1, wherein: The reflective layer includes one of silver, silver alloy, aluminum, aluminum alloy, chromium and chromium alloy; and / or the thickness of the reflective layer is 10nm-500nm; and / or the reflectivity of the reflective layer is greater than or equal to 70%.
11. The reflective device according to claim 10, wherein: The reflective device further includes a transition layer, which is provided between the reflective layer and the third surface, and the transition layer includes at least one of SiO, TiO, Nb2O5, and Al2O3.
12. The reflective device according to claim 1, wherein: The reflective device further includes a first electrode sheet and a second electrode sheet. The first electrode sheet is electrically connected to the transparent conductive layer, and the second electrode sheet is electrically connected to the reflective layer.
13. The reflective device according to claim 1, wherein: The surface of the transparent conductive layer facing the first transparent substrate includes a contact area in contact with the second surface and a recessed area recessed in a direction away from the second surface, the recessed area surrounds the contact area, the recessed area is spaced from the second surface, and a decorative layer is arranged between the recessed area and the second surface, and the reflectivity of the decorative layer is greater than or equal to 50%.
14. A method for manufacturing a reflective device, characterized in that: include: Providing a first transparent substrate, wherein the first transparent substrate comprises a first surface and a second surface disposed opposite to each other, and a transparent conductive layer is disposed on the second surface; Providing a second transparent substrate, wherein the second transparent substrate includes a third surface and a fourth surface disposed opposite to each other, and a reflective layer is disposed on the third surface; The transparent conductive layer faces the reflective layer, and the transparent conductive layer and the reflective layer are spaced apart; A sealing colloid is formed between the first transparent substrate and the second transparent substrate. The sealing colloid, the transparent conductive layer and the reflective layer form a cavity, and a dimming composition is poured into the cavity. The sealing colloid includes filling particles with a dielectric constant greater than or equal to 20.
15. The method for manufacturing a reflective device according to claim 14, wherein: The providing of a reflective layer on the third surface comprises: providing a transition layer on the third surface; A reflective layer is provided on the surface of the transition layer away from the second transparent substrate.
16. The method for manufacturing a reflective device according to claim 14, wherein: Providing a dimming layer between the transparent conductive layer and the reflective layer includes: The sealing colloid includes a first sealant and a second sealant, the sealing colloid is formed between the first transparent substrate and the second transparent substrate, the sealing colloid, the transparent conductive layer, and the reflective layer form a cavity, and the dimming composition is poured into the cavity, including: A first sealant is provided between the first transparent substrate and the second transparent substrate, the first sealant connects the first transparent substrate and the second transparent substrate, and the first sealant, the transparent conductive layer, and the reflective layer form a cavity with an opening; pouring a dimming composition into the cavity through the opening; A second sealant is provided between the first transparent substrate and the second transparent substrate to seal the opening, and the second sealant connects the first transparent substrate and the second transparent substrate.
17. A vehicle, characterized in that: The vehicle comprises the reflecting device according to any one of claims 1-13.
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