Fragrance-enhancing composition comprising at least one sulfur-containing antioxidant compound, at least one organic UV-screening agent and at least one aroma-enhancing substance

Abstract

The present invention relates to a fragrance enhancing composition, in particular a cosmetic composition, comprising a) at least one sulfur-containing antioxidant compound selected from compounds of the formula (I) R1-S-R2 and / or (II) R1-S-S-R2, b) at least one organic UV screening agent selected from dibenzoylmethane derivatives; and c) at least one aroma enhancing substance.

Description

Technical Field

[0001] The present invention is concerned with providing a novel fragrance-enhancing composition, in particular a cosmetic composition, for use in the field of fragrance enhancement of keratin materials and / or clothing, but also in the field of care and / or cosmetic treatment of keratin materials. Prior art

[0002] In general, the formulation of environmentally friendly cosmetic products is becoming a major challenge to meet new consumer expectations, in particular with regard to natural and / or eco-friendly products, that is to say products which are designed and developed with consideration for environmental impact.

[0003] It is more particularly desirable to make it possible to protect cosmetic preparations for the consumer, in particular while avoiding the use of compounds which may give rise to suspicion on the part of the consumer, for example those compounds which are suspected of being endocrine disruptors.

[0004] These environmental issues concern all cosmetic products, especially fragranced compositions.

[0005] It is known that fragrance is a combination of different odor-emitting substances that evaporate at different times. Each fragrance exhibits a so-called "top note" (which is the first odor diffused during the application of the fragrance or when the container containing the fragrance is opened), a "middle note or heart note" corresponding to the full fragrance (which is emitted several hours after the "top note"), and a "base note" which is the most persistent odor (which is emitted several hours after the "middle note"). The persistence of the base note corresponds to the retention time of the fragrance.

[0006] People have always tried to scent themselves and the objects around them or their environment, both to mask strong and / or unpleasant odors and to give a pleasant smell.

[0007] It is common practice to incorporate fragrances into a number of products or compositions, in particular cosmetic and dermatological compositions, such as eaux de parfums. ), eau de toilette, eau de parfum, aftershave or perfume (eaux de soin).

[0008] Flavors or aromatizing compositions must be stable, in particular olfactorily stable, and must have a pleasant smell, that is to say they must not deteriorate olfactorily over time. They must be resistant to various aggressive factors, such as light and temperature differences. In addition, there are great advantages in managing to stabilize the color of flavors or aromatizing compositions.

[0009] In order to ensure the stability of scented preparations, and in particular to prevent odour changes, it is known to incorporate antioxidant systems, such as BHT, therein.

[0010] However, BHT is a controversial compound as it is considered toxic to humans. In addition, it is suspected to be environmentally unfriendly and not biodegradable.

[0011] In fact, to the best of the inventors' knowledge, there is to date no substitute for BHT for use in flavoring aqueous / alcoholic products.

[0012] Finding alternative antioxidant systems to BHT has therefore been a major research line. Summary of the invention

[0013] There is thus still a need to find novel scented compositions, in particular aqueous / alcoholic compositions, which remain stable over time under the influence of light and temperature.

[0014] In particular, there remains a need for novel scented compositions, in particular aqueous / alcoholic compositions, which are olfactory stable over time and under the influence of light and temperature.

[0015] In particular, there remains a need to have available such scented cosmetic compositions the changes in their organoleptic properties, ie odour and / or colour, in particular at least colour, controlled over time.

[0016] There remains a particular need to have available scenting compositions which make it possible to maintain the olfactory effect over time without loss of intensity.

[0017] In particular, there is still a need for additives which make it possible to olfactorily stabilize most, indeed all, olfactory categories of fragrances.

[0018] There is also a need to improve the persistence of such perfumed compositions on keratin materials without degrading the perfume, particularly upon contact with other ingredients of the composition.

[0019] Furthermore, there is still a need to have available olfactory stable formulations which can comply with industrial constraints and which in particular can be easily manufactured.

[0020] Finally, there remains a need to have available flavoring compositions which are compatible with current consumer demands, particularly from an environmental point of view.

[0021] The present invention is particularly directed to meeting these needs. SUMMARY OF THE INVENTION

[0023] Thus, according to a first aspect of the present invention, the present invention relates to a scented composition, in particular a cosmetic composition, comprising:

[0024] a) at least one sulfur-containing antioxidant compound selected from the compounds of the following formula (I) and / or (II), and their optical and geometric isomers, salts and solvates, such as hydrates:

[0025] (I)R1-S-R2

[0026] (II)R1-SS-R2

[0027] Wherein formula (I) and (II):

[0028] R1 and R2, which are the same or different, represent a linear or branched (C1-C 24 ) alkyl group, linear or branched (C2-C 18 )alkenyl group, (C5-C 12 ) a cycloalkyl group, a phenylalkyl group having 7 to 15 carbon atoms or a phenyl group,

[0029] The alkyl groups and / or the alkenyl groups are optionally substituted by one or more groups selected from -OH, -OC(O)-R3, -C(O)-O-R3, -C(O)-R3, -OR'3 and -NH2 groups, in particular -OH, -OR'3 and -NH2 groups, and / or

[0030] The alkyl group and / or the alkenyl group are optionally interrupted by one or more groups selected from heteroatoms such as -O-, or -N(H)-, -OC(O)-, -C(O)-O-, -C(O)- and -NR'3- groups,

[0031] The phenyl group and / or the phenylalkyl group, such as benzyl, is optionally substituted on the phenyl group with 1 to 3 straight or branched (C1-C 10 ) substituted with an alkyl group,

[0032] Wherein R3 independently represents a hydrogen atom, a linear or branched (C1-C 18 )alkyl group, (C5-C 12 )cycloalkyl group, linear or branched (C3-C8)alkenyl group, (C6-C 14 ) aryl group or (C7-C 15 ) an aralkyl group, and

[0033] R'3 represents a straight chain or branched chain (C1-C 18 ) alkyl group;

[0034] b) at least one organic UV screening agent selected from dibenzoylmethane derivatives; and

[0035] c) at least one aromatizing substance.

[0036] Preferably, in the composition according to the invention, the sulfur-containing antioxidant compound a) is selected from dilauryl thiodipropionate, distearyl thiodipropionate, dilauryl dithiodipropionate, distearyl dithiodipropionate and mixtures thereof, preferably selected from dilauryl thiodipropionate, distearyl thiodipropionate and mixtures thereof.

[0037] Preferably, the composition according to the invention comprises at least dilauryl thiodipropionate in combination with butyl methoxydibenzoylmethane.

[0038] The inventors have surprisingly found that the combination of specific sulphur-containing antioxidant compounds and organic UV-screening agents derived from dibenzoylmethane in the presence of fragrance substances makes it possible to obtain fragranced cosmetic compositions having an excellent olfactory stability, which is similar to, and indeed even superior to, that obtained using BHT and whose odour and olfactory power degrade only slightly over time.

[0039] In particular, as can be seen from the examples presented below, the compositions according to the invention are stable, meaning that the variations in the odor and its strength remain low over time, even under conditions simulating accelerated aging of the composition. It is also noted that the compositions according to the invention are stable in terms of color intensity, that is to say that the color intensity decreases slightly over time.

[0040] Furthermore, it is observed that the specific combinations employed in the compositions according to the invention make it possible to obtain excellent performance qualities in terms of olfactory stability for various olfactory categories of fragrances.

[0041] In particular, the use of sulphur-containing antioxidant compounds together with organic UV screeners derived from dibenzoylmethane makes it possible to formulate aqueous / alcoholic fragrance enhancing compositions having a lifespan of at least 3 years, indeed even up to 5 years.

[0042] The compositions according to the invention are particularly intended for application to keratin materials or garments.

[0043] Thus, according to another of its aspects, the invention relates to a method for the cosmetic treatment of keratin materials, in particular the skin, comprising at least one stage of applying to said keratin materials a composition according to the invention.

[0044] The invention also relates to a method for the cosmetic treatment of keratin materials, in particular the skin, or garments, comprising at least one stage of applying to said keratin materials and / or garments a perfumed composition according to the invention.

[0045] It should be understood that the cosmetic treatments targeted in this patent application are non-therapeutic.

[0046] The compositions according to the invention are particularly intended for perfuming keratin materials and / or garments.

[0047] Thus, according to another of its aspects, the present invention also relates to a method of perfuming keratin materials (and in particular skin) and / or garments, preferably skin, comprising applying to said keratin materials and / or said garments a composition as defined above.

[0048] Advantageously, the composition can be applied by spraying, in particular using a sprayer.

[0049] According to a further aspect of the invention, the invention relates to the use of at least one sulfur-containing antioxidant compound as a stabilizer in, in particular, aqueous or aqueous / alcoholic fragrance compositions, in particular cosmetic fragrance compositions, which additionally comprise at least one organic UV-screening agent, in particular as described herein, chosen from dibenzoylmethane derivatives and at least one fragrance substance, in particular as described herein, said sulfur-containing antioxidant compound, in particular as described herein, chosen from compounds of the following formulae (I) and / or (II), and their optical and geometric isomers, salts and solvates, such as hydrates:

[0050] (I)R1-S-R2

[0051] (II)R1-SS-R2

[0052] Wherein formula (I) and (II):

[0053] R1 and R2, which are the same or different, represent a linear or branched (C1-C 24 ) alkyl group, linear or branched (C2-C 18 )alkenyl group, (C5-C 12 ) a cycloalkyl group, a phenylalkyl group having 7 to 15 carbon atoms or a phenyl group,

[0054] The alkyl groups and / or the alkenyl groups are optionally substituted by one or more groups selected from -OH, -OC(O)-R3, -C(O)-O-R3, -C(O)-R3, -OR'3 and -NH2 groups, in particular -OH, -OR'3 and -NH2 groups, and / or

[0055] The alkyl group and / or the alkenyl group are optionally interrupted by one or more groups selected from heteroatoms such as -O-, or -N(H)-, -OC(O)-, -C(O)-O-, -C(O)- or -NR'3- groups,

[0056] The phenyl group and / or the phenylalkyl group, such as benzyl, is optionally substituted on the phenyl group with 1 to 3 straight or branched (C1-C 10 ) substituted with an alkyl group,

[0057] Wherein R3 independently represents a hydrogen atom, a linear or branched (C1-C 18 )alkyl group, (C5-C 12 )cycloalkyl group, linear or branched (C3-C8)alkenyl group, (C6-C 14 ) aryl group or (C7-C 15 ) an aralkyl group, and

[0058] R'3 represents a straight chain or branched chain (C1-C 18 )alkyl group.

[0059] In particular, the use according to the invention employs sulfur-containing antioxidant compounds, organic UV screeners and fragrance substances in the form of a composition according to the invention.

[0060] definition

[0061] In the context of the present invention, and unless otherwise stated, the following definitions apply:

[0062] Within the meaning of the present invention, the terms "perfuming composition" or "perfuming composition" or "parfum" are understood to mean any composition that leaves a scent on keratin materials after application.

[0063] Within the meaning of the present invention, the term "perfuming substance" is understood to mean any flavor, odorous starting material or aroma capable of emitting a pleasant odor, in particular as defined in the subsequent part of this text. Within the meaning of the present invention, "fragrant", "odorous" or "odorizing" substances are synonymous.

[0064] Within the meaning of the present invention, the term "natural" is understood to mean compounds or extracts obtained directly from the earth or the soil or from plants or animals, if appropriate via one or more physical methods, such as, for example, grinding, refining, distillation, purification or filtering, or also produced by biotechnological methods, in particular by microorganisms or cell cultures, for example by fungi or bacteria. "Natural" compounds include compounds that occur in nature and can be reproduced by chemical (semi)synthesis.

[0065] Within the meaning of the present invention, the term "natural origin" is understood to mean any compound obtained from a natural substance which has undergone one or more additional chemical or industrial treatments resulting in modifications which do not affect the essential qualities of the substance. As non-limiting examples of additional chemical or industrial treatments resulting in modifications which do not affect the essential qualities of the natural compound, mention may be made of those defined in a manual recognized in the field such as "Cosmetics and Toiletries Magazine", 2005, Vol. 120, 9 (10) or approved by regulatory agencies such as Ecocert (Reference system for biological and ecological cosmetic products, January 2003).

[0066] According to the invention, a compound is considered to be natural or of natural origin when it consists essentially of natural ingredients, that is to say when the weight ratio of natural ingredients to non-natural ingredients constituting the compound is greater than 1.

[0067] Within the meaning of the present invention, the term "keratin material" is understood in particular to mean the skin, lips, hair, scalp, eyelashes and eyebrows or nails, in particular the skin and / or lips and preferably the skin.

[0068] The term "dye" or "colorant" is understood to mean any compound capable of coloring the flavored composition, that is to say any compound that absorbs in the visible spectrum, in particular making it appear to the human eye to have a color such as yellow, orange, red, violet, blue or green.

[0069] The composition according to the invention is generally suitable for application to keratin materials, in particular topical application to the skin, and therefore generally comprises a physiologically acceptable medium, that is to say a medium compatible with the skin. It is preferably a cosmetically acceptable medium, that is to say a medium which exhibits a pleasant color, smell and sensation and which does not cause any unacceptable discomfort, that is to say stinging, tightness or redness which could tend to prevent the user from applying the composition.

[0070] Within the meaning of the present invention, "stabilizer" is understood to mean a compound capable of stabilizing the flavoring composition containing it, in particular with regard to preserving its organoleptic properties, in particular the color and / or the odor of said composition, relative to external aggressive factors, in particular light or temperature or oxygen differences.

[0071] (C x -C z )alkyl means a straight or branched hydrocarbon chain containing x to z carbon atoms. For example, (C1-C6)alkyl means a straight or branched hydrocarbon chain containing 1 to 6 carbon atoms.

[0072] (C x -C z )Alkenyl refers to a straight or branched hydrocarbon chain containing x to z carbon atoms and containing one or more conjugated or non-conjugated unsaturations, preferably only one unsaturation. 10 )Alkenyl denotes a straight or branched hydrocarbon chain containing 2 to 10 carbon atoms and containing one or more unsaturations.

[0073] (C x -C z ) alkoxy represents wherein (C x -C z )alkyl as defined above -O-(C x -C z )alkyl group.

[0074] (C x -C z )Cycloalkyl represents a non-aromatic, saturated or unsaturated, monocyclic or fused or non-fused polycyclic carbocyclic ring (cyclic hydrocarbon group) containing x to z carbon atoms.

[0075] (C x -C z )Aryl means a monocyclic or fused or non-fused polycyclic ring containing x to z carbon atoms and wherein at least one ring is aromatic; preferably, the aryl group is phenyl, biphenyl, naphthyl, indenyl, anthracenyl or tetrahydronaphthyl, preferably phenyl.

[0076] (C x -C z )Aralkyl represents an alkyl group containing x to z carbon atoms substituted by an aryl group.

[0077] The expression "at least one" is equivalent to "one or more".

[0078] Unless otherwise specified, the expressions “between and,” “including to,” “formed from to,” and “to” should be understood to include the boundaries.

[0079] Other characteristics, alternatives and advantages of the composition according to the invention will emerge more clearly on reading the description and examples that follow. DETAILED DESCRIPTION OF THE INVENTION

[0081] a) Sulfur-containing antioxidant compounds

[0082] As mentioned above, the flavoring composition according to the present invention comprises at least one sulfur-containing antioxidant compound selected from the compounds of the following formula (I) and / or (II), and their optical and geometric isomers, salts and solvates, such as hydrates:

[0083] (I)R1-S-R2

[0084] (II)R1-SS-R2

[0085] Wherein formula (I) and (II):

[0086] R1 and R2, which are the same or different, represent a linear or branched (C1-C 24 ) alkyl group, linear or branched (C2-C 18 )alkenyl group, (C5-C 12 ) a cycloalkyl group, a phenylalkyl group having 7 to 15 carbon atoms or a phenyl group,

[0087] The alkyl groups and / or the alkenyl groups are optionally substituted by one or more groups selected from -OH, -OC(O)-R3, -C(O)-O-R3, -C(O)-R3, -OR'3 and -NH2, in particular -OH, -OR'3 and -NH2 groups, and / or

[0088] The alkyl group and / or the alkenyl group are optionally interrupted by one or more groups selected from heteroatoms such as -O-, or -N(H)-, -OC(O)-, -C(O)-O-, -C(O)- or -NR'3- groups,

[0089] The phenyl group and / or the phenylalkyl group, such as benzyl, is optionally substituted on the phenyl group with 1 to 3 straight or branched (C1-C 10 ) substituted with an alkyl group,

[0090] Wherein R3 independently represents a hydrogen atom, a linear or branched (C1-C 18 )alkyl group, (C5-C 12 )cycloalkyl group, linear or branched (C3-C8)alkenyl group, (C6-C 14 ) aryl group or (C7-C 15 ) an aralkyl group, and

[0091] R'3 represents a straight chain or branched chain (C1-C 18 )alkyl group.

[0092] Preferably, R1 and R2 are the same.

[0093] In particular, R1 and R2, which are the same or different, represent a linear or branched (C1-C 24 ) alkyl, especially (C8-C 20 ) alkyl, in fact even (C 12 -C 16)alkyl, which is interrupted by one or more -OC(O)- or -C(O)-O- groups and optionally substituted by one or more groups selected from -OH, -OC(O)-R3, -C(O)-O-R3, -C(O)-R3, -O-R'3 and -NH2 groups, in particular -OH, -O-R'3 and -NH2 groups, more particularly OH and -NH2 groups, and is preferably unsubstituted.

[0094] In particular, the sulfur-containing antioxidant compound is selected from the thiol (or thio) compounds of formula (I) as defined above. More particularly, the thiol compound of formula (I) is selected from compounds wherein R1 and R2 are identical and represent a group selected from the following: i) R'3-OC(O)-ALK- and ii) R'3-C(O)-O-ALK-, preferably i) R'3-OC(O)-ALK-, wherein ALK represents a linear or branched (C1-C6) alkylene, such as methylene or ethylene, preferably ethylene, and R'3 is as defined above, in particular, R'3 represents a linear or branched (C6-C 16 ) alkyl; more particularly, R'3 represents a linear or branched (C8-C 14 ) alkyl, preferably linear or branched (C 10 -C 12 ) alkyl, more preferably R'3 is a straight chain alkyl, such as n-dodecyl (C 12 H 25 ).

[0095] In particular, the sulfur-containing antioxidant compound is selected from the group consisting of diesters of thiodipropionic acid, diesters of dithiodipropionic acid, and mixtures thereof.

[0096] Preferably, the flavoring composition comprises at least one sulfur-containing antioxidant compound a) selected from dilauryl thiodipropionate, distearyl thiodipropionate, dilauryl dithiodipropionate, distearyl dithiodipropionate and mixtures thereof, preferably dilauryl thiodipropionate (e.g., commercially available from BASF under the trade name DA), dilauryl thiodipropionate, distearyl thiodipropionate, and mixtures thereof.

[0097] According to a preferred embodiment, the scented composition comprises at least dilauryl thiodipropionate.

[0098] According to another specific embodiment, the sulfur-containing antioxidant compound a) is chosen from compounds of formula (I) having a carboxylic acid group, in particular those in which R1 and R2 are identical and represent a -ALK-C(O)-OH group, in which ALK is as defined above, in particular methylene or ethylene, preferably ethylene, and derivatives thereof.

[0099] According to another particular embodiment, the sulfur-containing antioxidant compound a) is chosen from thiodipropionic acid, dithiodipropionic acid, thiodipropionic acid derivatives, dithiodipropionic acid derivatives and mixtures thereof.

[0100] As thiodipropionic acid and dithiodipropionic acid derivatives, there may be mentioned monoesters, diesters and salts of thiodipropionic acid and monoesters, diesters and salts of dithiodipropionic acid.

[0101] The esters of thiodipropionic acid and dithiodipropionic acid can be monoesters or diesters of thiodipropionic acid and an alcohol R-OH, or monoesters or diesters of dithiodipropionic acid and an alcohol R-OH, wherein R is a linear or branched chain, preferably a linear (C4-C 20 ) alkyl, especially (C6-C 16 ) alkyl, in fact even (C8-C 14 ) alkyl group, preferably a linear or branched (C 10 -C 12 ) alkyl group; More preferably, R is a straight chain alkyl group, such as n-dodecyl (C 12 H 25 ). R can also be (C 12 -C 18 )alkyl group.

[0102] The composition may comprise at least 0.01 wt. %, in particular at least 0.05 wt. %, indeed even at least 0.08 wt. %, indeed even again at least 0.1 wt. % of sulphur-containing antioxidant compound a), in particular dilauryl thiodipropionate, relative to the total weight of the flavoured composition.

[0103] The composition may comprise at most 4% by weight, in particular at most 1% by weight, indeed even at most 0.1% by weight, of sulphur-containing antioxidant compound a), relative to the total weight of the flavoured composition.

[0104] Preferably, the composition comprises from 0.01% to 5% by weight, in particular from 0.03% to 2% by weight, especially from 0.05% to 1% by weight, preferably from 0.07% to 0.5% by weight, more preferably from 0.08% to 0.1% by weight, relative to the total weight of the flavored composition, of a sulfur-containing antioxidant compound a), in particular dilauryl thiodipropionate.

[0105] In particular, the sulfur-containing antioxidant compound a) is used in a weight ratio of sulfur-containing antioxidant compound a) / flavoring substance c) of 0.05 / 100 to 2 / 100, in particular 0.1 / 100 to 0.9 / 100, more particularly 0.3 / 100 to 0.7 / 100.

[0106] In particular, the sulfur-containing antioxidant compound a) and the organic UV screening agent b) are used in a weight ratio of sulfur-containing antioxidant compound a) / organic UV screening agent b) of less than or equal to 2, more preferably less than or equal to 1, preferably less than 1, even better 0.01 to 0.9, more particularly 0.05 to 0.6, preferably 0.1 to 0.5, such as 0.3.

[0107] Organic UV shielding agent

[0108] As mentioned above, the scented composition according to the invention also comprises at least one organic UV screening agent chosen from dibenzoylmethane derivatives.

[0109] Within the meaning of the present invention, the term "UV screening agent" is understood to mean any compound which screens ultraviolet (UV) radiation in the wavelength range from 280 nm to 400 nm.

[0110] In particular, the dibenzoylmethane derivative may be a compound conforming to the following formula (III), and their optical and geometric isomers, and their salts with organic or inorganic acids or bases, and their solvates;

[0111] [Chemical formula 1]

[0112]

[0113] in:

[0114] -R18, which are the same or different, represents a group selected from those of the following formulae (A) to (H):

[0115] [Table 1]

[0116]

[0117] in:

[0118] ·R 4 and R 5 , which are the same or different, preferably different, representing (C2-C 10 )alkyl, in particular (C2-C8)alkyl, more in particular (C2-C6)alkyl; preferably, R 4 represents ethyl and R 5 represents n-butyl;

[0119] ·R 6 , R 7 and R 8 , which are the same or different, preferably the same, and represent (C1-C6)alkyl, phenyl or benzyl, preferably (C1-C4)alkyl, such as methyl or ethyl, or R 6 and R 7 are the same, and represent (C1-C4) alkyl, such as methyl, and R8 , which is different from R 6 and R 7 , represents a (C1-C6) alkyl group, preferably a branched (C4-C6) alkyl group, such as 2,2-dimethylpropyl;

[0120] ·R' 6 , R' 7 and R' 8 , which are identical or different, preferably identical, and represent (C1-C6)alkyl, (C1-C6)alkoxy, or phenyl, benzyl, phenoxy or benzyloxy, preferably (C1-C4)alkyl, and in particular methyl;

[0121] ·R 9 represents (C1-C6)alkyl, preferably (C1-C4)alkyl, in particular methyl;

[0122] ·R 10 , R 11 , R 12 , R 13 , R 14 and R 15 , which are identical or different, preferably identical, and represent (C1-C6)alkyl, preferably (C1-C4)alkyl, in particular methyl;

[0123] ·R 16 , R 17 and R 18 , which are identical or different, preferably identical, represent a hydrogen atom, a (C1-C6)alkyl group, preferably a (C1-C4)alkyl group, in particular a methyl group;

[0124] ·R 18 represents a hydrogen atom or a (C1-C6) alkyl group, preferably a hydrogen atom or a methyl group;

[0125] n has a value of 0 or 1, preferably 1;

[0126] ·R 19 , R 20 , R 21 and R 22 , which are identical or different, preferably identical, and denote (C1-C6)alkyl, (C1-C6)alkoxy, preferably (C1-C4)alkyl, in particular methyl, it being understood that the two alkoxy groups are not carried by the same carbon atom;

[0127] ·R 23 , R 24 , R 25 , R 26 and R 27 , which are the same or different, represent a hydrogen atom or a (C1-C6) alkyl group, it is understood that R 23 , R24 , R 25 , R 26 and R 27 At least one of represents a tert-butyl group; preferably, R 23 , R 24 , R 26 and R 27 represents a hydrogen atom, and R 25 represents tert-butyl;

[0128] ·R 28 and R 29 , which are identical or different, preferably identical, and represent (C1-C6)alkyl, preferably (C1-C4)alkyl, in particular methyl;

[0129] ·R 30 represents a hydrogen atom or a (C1-C6)alkyl group, in particular a (C1-C4)alkyl group, in particular a methyl group; preferably, R 30 represents a hydrogen atom;

[0130] ·R 31 and R 32 , which are identical or different, preferably identical, and represent a hydrogen atom or a (C1-C6)alkyl group, in particular a hydrogen atom;

[0131] ·R 33 and R 34 , which are the same or different, preferably different, and represent (C1-C6)alkyl, preferably (C1-C4)alkyl, such as methyl, ethyl, propyl or isopropyl;

[0132] ·unit:

[0133] [Chemical formula 2]

[0134]

[0135] represents the moiety of the group attached to the rest of the molecule; and

[0136] ·unit:

[0137] [Chemical formula 3]

[0138]

[0139] represents a single bond or a double bond, preferably a double bond;

[0140] - or R 18 , which are the same or different, represent a hydrogen atom or a linear or branched C1-C8 alkyl group, preferably a branched C4-C8 alkyl group; more particularly, R 18 represents a group of formula (B) as defined above, or a linear or branched C1 to C6 alkyl group;

[0141] -R' 18 represents a hydrogen atom or a linear or branched, in particular branched (C1-C6) alkyl group, such as isopropyl;

[0142] -R 19 , which are the same or different, represent a hydrogen atom, a linear or branched C1 to C6 alkyl group or a linear or branched C1 to C4 alkoxy group, in particular a (C1-C4) alkyl group, such as a methyl, ethyl, propyl or isopropyl group, a methoxy group or an ethoxy group;

[0143] -m represents an integer from 1 to 5, inclusive, and in particular has a value of 1 or 2; preferably 1; more particularly, R 18 It was found at position 4;

[0144] -p represents an integer from 1 to 5, inclusive, and in particular has a value of 1 or 2; preferably 1; more particularly, R 19 It was found at the 4' position;

[0145] It is important to understand that R 18 , R' 18 and R 19 It cannot represent a hydrogen atom at the same time.

[0146] In particular, the dibenzoylmethane derivatives may be selected from compounds of formula (III), wherein R 18 and R 19 , which are identical or different, preferably different, and represent a group selected from (A) to (H) as defined above, in particular a linear or branched C1 to C 16 Alkyl; or a linear or branched C1 to C 16 an alkoxy group, in particular a (C1-C8)alkoxy group; or a hydrogen atom; preferably, R 19 represents a C1-C6, preferably a C1-C4 alkoxy group, such as a methoxy group, and R 18 represents a group selected from (A) to (H), and is particularly a linear or branched C1-C8 alkyl group, preferably a branched C4-C8 alkyl group, and more particularly, R 18 represents a group selected from the formula (B), in particular tert-butyl, wherein in particular, R' 18 represents a hydrogen atom, m and p have a value of 1, and R 18 and R 19 Appearing at positions 4 and 4' respectively.

[0147] In particular, the dibenzoylmethane derivatives may be selected from compounds of formula (III), wherein:

[0148] -R 18 represents a hydrogen atom or a linear or branched C1 to C6 alkyl group, preferably a hydrogen atom; and

[0149] -R19 represents a linear or branched C1 to C6 alkyl group or a linear or branched C1 to C4 alkoxy group, in particular a (C1-C8) alkyl group, such as a methyl group, an ethyl group, a propyl group or an isopropyl group;

[0150] In particular, R' 18 represents a hydrogen atom, m and p have a value of 1, and R 18 and R 19 Appearing at positions 4 and 4' respectively.

[0151] In particular, the dibenzoylmethane derivative may be selected from 2-methyldibenzoylmethane, 4-methyldibenzoylmethane, 4-isopropyldibenzoylmethane, 4-tert-butyldibenzoylmethane, 2,4-dimethyldibenzoylmethane, 2,5-dimethyldibenzoylmethane, 4,4'-diisopropyldibenzoylmethane, 4,4'-dimethoxydibenzoylmethane, 4-tert-butyl-4'-methoxydibenzoylmethane, 2-methyl-5-isopropyl-4'-methoxydibenzoylmethane, 2-methyl-5-tert-butyl-4'-methoxydibenzoylmethane, 2,4-dimethyl-4'-methoxydibenzoylmethane and 2,6-dimethyl-4-tert-butyl-4'-methoxydibenzoylmethane.

[0152] Preferably, the dibenzoylmethane derivative is chosen from butyl methoxydibenzoylmethane, also known as tert-butyl methoxydibenzoylmethane or 4-tert-butyl-4'-methoxydibenzoylmethane, for example sold under the trade name Parsol 1789 by Hoffmann-La Roche, and isopropyl dibenzoylmethane, also known as 4-isopropyl dibenzoylmethane, for example sold under the trade name Eusolex 8020 by Merck, and mixtures thereof.

[0153] Preferably, the scented composition comprises at least butyl methoxydibenzoylmethane.

[0154] According to a particular embodiment, the fragranced composition may comprise at least 0.05% by weight, in particular at least 0.1% by weight, more particularly at least 0.2% by weight, indeed even at least 0.25% by weight of organic UV-screening agent b) chosen from dibenzoylmethane derivatives, in particular butyl methoxydibenzoylmethane, relative to the total weight of the fragranced composition.

[0155] Preferably, the composition comprises from 0.01% to 5% by weight, in particular from 0.05% to 2% by weight, especially from 0.1% to 1% by weight, preferably from 0.2% to 0.5% by weight, more preferably from 0.25% to 0.35% by weight, such as 0.3% by weight, of an organic UV-screening agent b) chosen from dibenzoylmethane derivatives, in particular butyl methoxydibenzoylmethane, relative to the total weight of the perfumed composition.

[0156] In particular, the organic UV screener b) is used in an organic UV screener b) / perfuming substance c) weight ratio of 0.1 / 100 to 5 / 100, in particular 0.5 / 100 to 3 / 100, more particularly 1 / 100 to 2 / 100.

[0157] c) Fragrance substances

[0158] As stated above, the composition according to the invention comprises at least one flavoring substance.

[0159] Fragrances are compositions containing, inter alia, starting materials described in S. Arctander, Perfume and Flavor Chemicals (Montclair, NJ, 1969), S. Arctander, Perfume and Flavor Materials of Natural Origin (Elizabeth, NJ, 1960), and Flavor and Fragrance Materials—1991, Allured Publishing Co., Wheaton, 111.

[0160] The scented composition according to the invention preferably comprises at least one scenting substance chosen from essential oils, essences and aromas of synthetic or natural origin, and mixtures thereof.

[0161] They may be natural products, such as essential oils, absolutes, extracts, resins, gels and / or synthetic products, such as terpenes or sesquiterpene hydrocarbons, alcohols, phenols, aldehydes, ketones, ethers, acids, esters, nitriles or peroxides, which may be saturated or unsaturated, aliphatic or cyclic.

[0162] According to the definition given by the international standard ISO 9235 and adopted by the European Pharmacopoeia Commission, essential oils are odoriferous products, usually of complex composition, obtained from botanically defined plant starting materials by steam distillation, or by dry distillation, or by appropriate mechanical processes without heating (cold pressing). Essential oils are usually separated from the aqueous phase by physical methods which do not result in any significant change in composition.

[0163] The choice of the method used to obtain the essential oil depends mainly on the starting material: its original state and its characteristics, its natural nature. The yield of "essential oil / plant starting material" is extremely variable, depending on the plant: 15 ppm to more than 20%. This choice determines the characteristics of the essential oil, in particular viscosity, color, solubility, volatility, and the richness or poverty of certain components.

[0164] Steam distillation corresponds to the evaporation of substances sparingly soluble in water in the presence of steam. The starting material is brought into contact with boiling water or steam in a distiller. The steam entrains the essential oil vapors, which are condensed in a condenser in order to be recovered as a liquid phase in a round-bottom flask (or perfume pot), in which the essential oils are separated from the water by sedimentation. The terms "aromatic water" or "hydrosol" or "distilled floral water" are used to describe the aqueous distillate remaining after steam distillation, once the essential oils have been separated.

[0165] Production by dry distillation consists in obtaining the essential oil by distilling the wood, bark or roots without adding water or steam in a closed chamber designed to recover the liquid at its bottom. Juniper oil is the best known example of this production method.

[0166] The cold pressing production method is applied exclusively to citrus fruits (Citrus) by mechanical processing at ambient temperature. The principle of this method is as follows: the peel is shredded and the contents of the secretory cavities that have been ruptured are recovered by physical methods. The traditional method consists in applying a grinding action over the entire surface of the fruit under a stream of water. After the solid waste has been removed, the essential oil is separated from the aqueous phase by centrifugation. In fact, most industrial plants allow the simultaneous or sequential recovery of juice and essential oil.

[0167] Essential oils are generally volatile and liquid at ambient temperature, which distinguishes them from "solidified" oils. They are more or less pigmented, and their density is generally lower than that of water. They have a high refractive index, and most turn polarized light. They are soluble in fats, and in standard organic solvents, can be steam distilled, and exhibit very low solubility in water.

[0168] Among the essential oils that can be used according to the invention, mention may be made of those obtained from plants belonging to the following plant families: Abietaceae or Pinaceae, for example conifers; Amaryllidaceae; Anacardiaceae; Annonaceae, for example Ylang-ylang; Apiaceae, for example umbellifers, in particular dill, angelica, coriander, sea fennel, carrot or parsley; Araceae; Aristolochiaceae; Asteraceae, for example Achillea, Artemisia, Chamomile, Helichrysum; Betulaceae; Cruciferae; Oleaceae, e.g. frankincense; Caryophyllaceae; Cinnamomum officinale, e.g. Copaiba; Chenopodiaceae; Helianthus annuus, e.g. Cistus; Cyperaceae; Dipterocarpon; Ericaceae, e.g. Gaultheria; Euphorbiaceae; Fabaceae; Geraniaceae, e.g. Pelargonium; Garciniaceae; Hamamelis; Nelumbo; Hypericaceae, e.g. St. John's wort; Iridaceae; Juglandaceae; Lamiaceae, e.g. Thyme, Oregano, Horse mint, Celery, Basil, Origanum vulgare, Mint, Patchouli incense, lavender, sage, camphor grass, rosemary, hyssop or balsam; Lauraceae, such as laurel, bay, dalbergia, cinnamon, litsea; Liliaceae, such as garlic; Magnoliaceae, such as magnolia; Malvaceae; Meliaceae; Cup-coleaceae; Moraceae, such as hemp seed or hemp; Myricaceae; Myristicaceae, such as nutmeg; Myrtaceae, such as eucalyptus, tea tree, Melaleuca alternifolia, Melaleuca alternifolia, Backhousia, clove, myrtle; Oleaceae; Piperaceae, such as pepper ; Pittosporum family; Poaceae, such as citronella, lemongrass, rockgrass; Polygonaceae; Ranunculaceae; Rosaceae, such as rose; Rubiaceae; Rutaceae, such as the entire citrus family; Salicaceae; Santalaceae, such as sandalwood; Saxifragaceae; Schisandraceae; Styracaceae, such as benzoin; Thymelaeaceae, such as agarwood; Tiliaceae; Patriniaceae, such as valerian, spikenard; Verbenaceae, such as lantana, verbena; Violaceae; Zingiberaceae, such as galangal, turmeric, cardamom, ginger; Tribulus family.

[0169] Mention may also be made of essential oils extracted from flowers (lily, lavender, rose, jasmine, ylang-ylang, neroli), from stems and leaves (patchouli, geranium, bitter orange), from fruits (coriander, fennel, cumin, juniper berry), from peels (bergamot, lemon, orange), from roots (angelica, celery, cardamom, iris, calamus, ginger), from wood (pine, sandalwood, guaiac, acrolein, camphor), from grasses and grasses (tarragon, rosemary, basil, lemongrass, sage, thyme), from needles and branches (spruce, fir, pine, dwarf pine) or from resins and balsams (galbanum, elemi, benzoin, myrrh, frankincense, opoponax).

[0170] Examples of aroma substances are, in particular, geraniol, geranyl acetate, farnesol, borneol, bornyl acetate, coriander alcohol, linalyl acetate, linalyl propionate, linalyl butyrate, tetrahydrocoriander alcohol, citronellol, citronellol acetate, citronellol formate, citronellol propionate, dihydromyrcenol, dihydromyrcenol acetate, tetrahydromyrcenol, terpineol, terpineol acetate, nopol, nopol acetate, nerol, nerol acetate, 2-phenylethanol, 2-phenylethyl acetate, benzyl alcohol, benzyl acetate, water Benzyl salicylate, styryl acetate, benzyl benzoate, amyl salicylate, dimethylbenzyl alcohol, trichloromethylbenzene acetate, tert-butylcyclohexyl acetate, isononyl acetate, vetiver acetate, vetiver alcohol, α-hexylcinnamaldehyde, 2-methyl-3-(tert-butylphenyl)propanal, 2-methyl-3-(p-isopropylphenyl)propanal, 3-(p-tert-butylphenyl)propanal, 2,4-dimethylcyclohex-3-enylcarboxaldehyde, tricyclodecenyl acetate, tricyclodecenyl propionate, 4-(4-hydroxy-4- 4-(4-methyl-3-pentenyl)-3-cyclohexenecarboxaldehyde, 4-acetoxy-3-pentyltetrahydropyran, 3-carboxymethyl-2-pentylcyclopentane, 2-(n-heptyl)cyclopentanone, 3-methyl-2-pentyl-2-cyclopentenone, menthone, carvone, tagetone, geranylacetone, n-decanal, n-dodecal, 9-decen-1-ol, phenoxyethyl isobutyrate, phenylacetaldehyde dimethyl acetal, phenylacetaldehyde diethyl acetal, lemon nitrile, citronellal, acetic acid Cedryl ester, 3-isobornyl cyclohexanol, cedryl methyl ether, isolongifolia alkane, anise nitrile, anise aldehyde, piperonal, coumarin, eugenol, vanillin, diphenyl ether, citral, citronellal, hydroxycitronellal, dihydrodamascone, ionone, methyl ionone, isomethyl ionone, solanone, irone, cis-3-hexenol and its esters, indane musk compounds, tetralin musk compounds, isochroman musk compounds, macrocyclic ketones, macrocyclic lactone musk compounds, aliphatic musk compounds, ethyl ester of bacil and mixtures thereof.

[0171] In particular, the flavoured composition according to the invention may comprise one or more flavouring substances which are natural or of natural origin.

[0172] The flavouring composition according to the invention may in particular have a content of flavouring substances of natural or natural origin which is greater than that of flavouring substances of synthetic origin.

[0173] According to a preferred embodiment of the invention, a mixture of different aromatizing substances is used which together generate a fragrance note which is pleasing to the user.

[0174] Thus, according to a preferred embodiment, the flavouring composition comprises at least a flavouring substance, in particular a mixture of at least two different flavouring substances, relative to the total weight of said composition, and preferably a mixture of at least three different flavouring substances.

[0175] The aromatizing substances will preferably be chosen such that they produce notes (top, middle and base notes) from the following categories: orange peel, aromatic, floral, in particular pink and white flowers, spicy, woody, foody, cypress, fumes, leather and musk.

[0176] For obvious reasons, the amount of perfuming substance present in the composition according to the invention is susceptible to varying considerably depending on the odour or odour intensity sought by its presence.

[0177] For example, the flavoring composition according to the invention may comprise at least 0.5% by weight, in particular at least 1% by weight, more particularly 1% to 35% by weight, preferably 5% to 30% by weight, more preferably 10% to 25% by weight of flavoring substances relative to the total weight of the composition.

[0178] The aromatizing substance may be introduced into the aromatizing composition according to the invention in the form of an aroma concentrate.

[0179] The flavor concentrate may be a gelled fat or a pure oil, preferably a pure oil.

[0180] Thus, the flavored composition according to the invention comprises in particular at least 0.5% by weight, in particular at least 1% by weight, more particularly from 1% to 35% by weight, preferably from 5% to 30% by weight, more preferably from 10% to 25% by weight, of flavor concentrate relative to the total weight of the composition.

[0181] Additional UV shielding agent

[0182] The scented composition according to the invention may also comprise one or more additional UV-screening agents different from the organic UV-screening agent b) chosen from the dibenzoylmethane derivatives defined above. The additional UV-screening agent may in particular be chosen from UV-A screeners and / or UV-B screeners.

[0183] The UV-screening agent may be selected from organic UV-screening agents, which are hydrophilic or hydrophobic, and / or inorganic UV-screening agents.

[0184] Preferably, they are chosen from hydrophilic or hydrophobic organic UV screeners.

[0185] The term "UV-B screening agent" is understood to mean any compound that screens (or absorbs) ultraviolet (UV) radiation in the wavelength range extending from 280 nm to 320 nm.

[0186] The term "UV-A screener" is understood to mean any compound that screens (or absorbs) ultraviolet (UV) radiation in the wavelength range extending from 320 nm to 400 nm. A distinction can be made between short UV-A screeners (which absorb radiation with a wavelength of 320 to 340 nm) and long UV-A screeners (which absorb radiation with a wavelength of 340 to 400 nm).

[0187] The term "hydrophilic UV screener" refers to any organic or inorganic cosmetic or dermatological compound which screens UV radiation and which readily dissolves completely in a molecular state or readily solubilizes in a liquid aqueous phase in a colloidal form, for example in the form of micelles.

[0188] The term "hydrophobic UV screener" is understood to mean any cosmetic or dermatological screener which readily dissolves completely in the molecular state or readily solubilizes in the liquid fatty phase in the liquid fatty phase in the colloidal form, for example in the form of micelles.

[0189] Hydrophobic organic UV-B and / or UV-A screeners

[0190] The UV screening agent is selected from hydrophobic organic UV-B and / or UV-A screening agents selected from:

[0191] i) p-aminobenzoic acid derivatives,

[0192] ii) cinnamic acid derivatives,

[0193] iii) salicylic acid derivatives,

[0194] iv) 3,3-diphenylacrylate and 4,4-diarylbutadiene derivatives,

[0195] v) benzophenone derivatives,

[0196] vi) benzylidene camphor derivatives,

[0197] vii) phenylbenzotriazole derivatives,

[0198] viii) triazine derivatives,

[0199] ix) anthranilic acid derivatives,

[0200] x) imidazoline derivatives,

[0201] xi) benzalmalonate derivatives,

[0202] xii) merocyanine derivatives,

[0203] and mixtures thereof.

[0204] More particularly, the hydrophobic organic UV-B and / or UV-A screening agent may be chosen from:

[0205] i) para-aminobenzoic acid (PABA) derivatives or esters, in particular of formula (IV), as well as their optical and geometric isomers and their solvates:

[0206] [Chemical formula 4]

[0207]

[0208] in:

[0209] - R20 and R21, which are identical or different, preferably identical, represent a hydrogen atom or a (C1-C6)alkyl group, in particular a (C1-C4)alkyl group, such as methyl, ethyl, propyl, n-butyl and isobutyl group;

[0210] -R22 represents a group selected from the groups of formulae (A) to (H) as defined above, or (C1-C 20 ) alkyl, especially (C1-C 10 )alkyl, more particularly (C1-C6)alkyl, such as methyl, ethyl, propyl and butyl or a radical of formula (A) as defined above.

[0211] In particular, the para-aminobenzoic acid (PABA) derivative or ester may be selected from (C1-C6)alkyl PABA of formula (IV), wherein:

[0212] - R20 and R21, which are identical or different, preferably identical, represent a hydrogen atom or a (C1-C6)alkyl group, in particular a (C1-C4)alkyl group, such as methyl, ethyl, propyl, n-butyl and isobutyl group;

[0213] -R22 means (C1-C 20 ) alkyl, especially (C1-C 10 )alkyl, more particularly (C1-C6)alkyl, such as methyl, ethyl, propyl and butyl.

[0214] In particular, the para-aminobenzoic acid (PABA) derivative or ester is chosen from ethyl PABA, ethyldihydroxypropyl PABA, ethylhexyldimethyl PABA, for example sold under the name Escalol 507 by ISP, and mixtures thereof.

[0215] More particularly, the para-aminobenzoic acid (PABA) derivative or ester may be chosen from ethyl PABA, ethyl dihydroxypropyl PABA or mixtures thereof.

[0216] ii) Cinnamic acid derivatives or esters, in particular of formula (V), as well as their optical and geometric isomers and their solvates:

[0217] [Chemical formula 5]

[0218]

[0219] in:

[0220] - R20 represents a hydrogen atom or a (C1-C6)alkyl group, in particular a (C1-C4)alkyl group, such as a methyl group; and

[0221] -R22 represents a group selected from the groups of formulae (A) to (H) as defined above, or (C1-C 20 ) alkyl, especially (C1-C 10 )alkyl, more particularly (C1-C6)alkyl, such as methyl, ethyl, isopropyl, butyl and isopentyl.

[0222] In particular, the cinnamic acid derivative or ester may be selected from compounds of formula (V), wherein:

[0223] - R20 represents a hydrogen atom or a (C1-C6)alkyl group, in particular a (C1-C4)alkyl group, such as a methyl group;

[0224] -R22 means (C1-C 20 ) alkyl, especially (C1-C 10 )alkyl, more particularly (C1-C6)alkyl, such as methyl, ethyl, isopropyl, butyl and isopentyl.

[0225] In particular, the cinnamic acid derivative or ester may be chosen from ethylhexyl methoxycinnamate, for example sold under the trade name Parsol MCX by Hoffmann-La Roche, isopropyl methoxycinnamate, isoamyl methoxycinnamate, for example sold under the trade name Neo Heliopan E 1000 by Haarmann and Reimer, cinoxate, diisopropyl methylcinnamate, glyceryl ethylhexanoate dimethoxycinnamate and mixtures thereof.

[0226] More particularly, the cinnamic acid derivative or ester may be chosen from isopropyl methoxycinnamate, isoamyl methoxycinnamate, cinoxate, diisopropyl methylcinnamate and mixtures thereof.

[0227] It may in particular be isoamyl methoxycinnamate.

[0228] iii) salicylic acid derivatives or esters, in particular of formula (VI), as well as their optical and geometric isomers and their solvates:

[0229] [Chemical formula 6]

[0230]

[0231] in:

[0232] -R13 represents a group selected from the groups of formulae (A) to (H) as defined above, a benzyl group or a branched C4-C 20 Alkyl, especially C6-C 12 Alkyl, more preferably branched C8-C 10 Alkyl; more particularly, R13 represents a group of formula (A) or benzyl;

[0233] -R14 represents a hydrogen atom, a straight or branched C1-C 20 Alkyl groups, optionally forming a ring, denote in particular a group selected from the groups of the formulae (A) to (H) as defined above, preferably a hydrogen atom.

[0234] In particular, the salicylic acid derivative or ester may be selected from compounds of formula (VI), wherein:

[0235] -R13 represents a group selected from the groups of formulae (A) to (H) as defined above or a branched C4-C 20 Alkyl, especially C6-C 12 Alkyl, more preferably branched C8-C 10 More particularly, R13 represents a C6 to C6 alkyl group substituted by at least one methyl, ethyl, propyl, isopropyl and / or tert-butyl group. 16 Alkyl groups;

[0236] -R14 represents a hydrogen atom, a straight or branched C1-C 20 An alkyl group, if appropriate cyclic, denotes in particular a group which is selected from the groups of the formulae (A) to (H) and is preferably a hydrogen atom.

[0237] The salicylic acid derivative or ester may be chosen in particular from homosalate, sold for example under the name Eusolex HMS by Rona / EM Industries, ethylhexyl salicylate, sold for example under the name Neo Heliopan OS by Haarmann and Reimer, benzyl salicylate, dipropylene glycol salicylate, sold in particular under the name Dipsal by Scher, TEA salicylate, sold in particular under the name Neo Heliopan TS by Symrise, and mixtures thereof.

[0238] Preferably, the salicylic acid derivative is 2-ethylhexyl salicylate, corresponding in particular to the commercial product NeoHeliopan OS.

[0239] iv) 3,3-diphenylacrylate derivatives or esters, in particular having the formula (VII), as well as their optical and geometric isomers and their solvates, and 4,4-diarylbutadiene derivatives or diesters, in particular having the formula (VII'), as well as their optical and geometric isomers and their solvates:

[0240] [Chemical formula 7]

[0241]

[0242] [Chemical formula 8]

[0243]

[0244] in:

[0245] - R15 and R'15, which are identical or different, represent a radical selected from the radicals of formulae (A) to (H) as defined above, or a linear or branched C1 to C6 alkyl group, such as methyl, ethyl, propyl, isopropyl or tert-butyl, preferably ethyl, hexyl or a radical of formula (A) as defined above;

[0246] - R16, R'16, R17 and R'17, which are the same or different, represent a hydrogen atom, a linear or branched C1-C 12 Alkyl or linear or branched C1-C 16 Alkoxy group; preferably, R16, R'16, R17 and R'17 represent a hydrogen atom or a C1-C4 alkyl group, such as a methyl group.

[0247] In particular, the 3,3-diphenylacrylate derivative or ester may be selected from compounds of formula (VII), wherein:

[0248] - R15 represents a linear or branched, preferably linear, C1 to C6 alkyl group, such as methyl, ethyl, propyl or n-butyl, more preferably ethyl; and

[0249] - R16 and R17, which are the same or different, represent a hydrogen atom, a linear or branched C1-C 10 Alkyl or linear or branched C1-C 10 The alkoxy group preferably represents a hydrogen atom.

[0250] In particular, the 3,3-diphenylacrylate derivative or ester may be chosen from 3,3-diphenyl-2-cyanoacrylate derivatives, in particular having formula (VII), and their optical or geometric isomers and their solvates, wherein:

[0251] - R15 represents a group selected from the groups of formulae (A) to (H) as defined above, in particular a linear or branched C6 to C 16 alkyl, substituted with at least one methyl, ethyl, propyl, isopropyl or tert-butyl group;

[0252] - R16 and R17, which are the same or different, represent a hydrogen atom, a linear or branched C1-C 12 Alkyl or linear or branched C1-C 16Alkoxy group; preferably, R16 and R17 represent hydrogen atoms.

[0253] Preferably, R15 represents a C6 to C8 alkyl group substituted by at least one ethyl, propyl or isopropyl group; more particularly, R15 represents a C6 alkyl group substituted by at least one ethyl, propyl or isopropyl group; even more preferably, R15 represents a group of formula (A).

[0254] In particular, it relates to octocrylene, such as is sold, for example, by BASF under the trade name Uvinul N539, etorylene, such as is sold, for example, by BASF under the trade name Uvinul N35, and the following screening agents (1), (2) and (3) and mixtures thereof:

[0255] [Chemical formula 9]

[0256]

[0257] [Chemical formula 10]

[0258]

[0259] [Chemical formula 11]

[0260]

[0261] Etocrylene, as sold, for example, by BASF under the trade name Uvinul N35, is very particularly suitable for the present invention.

[0262] v) Benzophenone derivatives or esters, in particular of formula (VIII), as well as their optical and geometric isomers and their solvates:

[0263] [Chemical formula 12]

[0264]

[0265] in:

[0266] -G 1 represents a hydrogen atom, a R1R2N- or R1-O- group, wherein R1 and R2, which are the same or different, represent a hydrogen atom, a straight or branched C1-C 10 Alkyl, preferably linear C1-C8 alkyl, or R1 and R2 together with the nitrogen atom carrying them form a saturated or unsaturated, preferably saturated, 5- or 6-membered heterocyclic ring, such as pyrrolidino, piperazino, piperidino or morpholino;

[0267] -G 2 represents a hydrogen atom or a hydroxyl group, a (C1-C4) alkyl group such as a methyl group, or a -C(O)-O-R3 group, wherein R3 represents a linear or branched C1-C 12carbon chain, optionally forming one or more rings, in particular (C4-C 10 ) alkyl, preferably (C6-C 10 ) alkyl, which is linear or branched, preferably linear, such as n-butyl, preferably -C(O)-O-R3 group; in particular, G 2 in the ortho position relative to the carbonyl group;

[0268] -G 1 It may be at the 3 or 5 position relative to the carbonyl group (either at the meta position relative to the hydroxyl group or at the para position relative to the hydroxyl group).

[0269] Preferably, G 1 represents an R1R2N- group, and the R1 and R2 groups are selected from a hydrogen atom, a linear or branched C1-C4 alkyl group, such as a methyl, ethyl, propyl, isopropyl, tert-butyl or pentyl group, which is optionally substituted by a methyl or ethyl group at the 2 or 3 position.

[0270] Preferably, R1 and R2 are selected from ethyl, propyl and butyl.

[0271] When R1 and R2 form a heterocycle together with the nitrogen atom carrying them, in particular a morpholino, pyrrolidinyl or piperidinyl group optionally substituted with one or more (C1-C4) alkyl groups such as methyl. Preferably, R1 and R2 form a morpholino, pyrrolidinyl or piperidinyl group together with the nitrogen atom carrying them.

[0272] It very particularly concerns benzophenone-3 or oxybenzone, such as are sold for example under the trade name Uvinul M40 by BASF, benzophenone-4, such as are sold for example under the trade name Uvinul MS40 by BASF, benzophenone-8, such as are sold for example under the trade name Spectra-Sorb UV-24 by American Cyanamid, benzophenone-12, n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate and mixtures thereof.

[0273] In particular, the benzophenone derivative or ester may be selected from compounds of formula (VIII'):

[0274] [Chemical formula 13]

[0275]

[0276] in:

[0277] - R1 and R2, which are identical or different, represent a hydrogen atom, a linear or branched C1-C8 alkyl group, preferably a C1-C6 alkyl group, or R1 and R2 together with the nitrogen atom carrying them form a saturated or unsaturated, preferably saturated, 5- or 6-membered heterocyclic ring, such as pyrrolidino, piperazino, piperidino or morpholino;

[0278] -R3 represents a straight or branched C1-C 12 carbon chain, optionally forming one or more rings, in particular (C4-C 10 ) alkyl, preferably (C6-C 10 ) alkyl, which is linear or branched, preferably linear, such as n-butyl; and

[0279] -NR1R2 can be at the 3 or 5 position of the phenol ring (in the meta position relative to the hydroxyl group).

[0280] Preferably, the R1 and R2 groups are selected from hydrogen atoms, linear or branched C1-C4 alkyl groups optionally substituted at the 2 or 3 position by methyl or ethyl groups, such as methyl, ethyl, propyl, isopropyl, tert-butyl or pentyl.

[0281] Preferably, R1 and R2 are selected from ethyl, propyl and butyl.

[0282] When R1 and R2 form a heterocycle together with the nitrogen atom carrying them, in particular a morpholino, pyrrolidinyl or piperidinyl group optionally substituted with one or more (C1-C4) alkyl groups such as methyl. Preferably, R1 and R2 form a morpholino, pyrrolidinyl or piperidinyl group together with the nitrogen atom carrying them.

[0283] The benzophenone derivative may be chosen in particular from benzophenone-1, in particular sold under the trade name Uvinul 400 by BASF; benzophenone-2, in particular sold under the trade name Uvinul D50 by BASF; benzophenone-3 or oxybenzone, in particular sold under the trade name Uvinul M40 by BASF; benzophenone-6, in particular sold under the trade name Helisorb 11 by Norquay; benzophenone-8, in particular sold under the trade name Spectra-Sorb UV-24 by American Cyanamid; benzophenone-10; benzophenone-11; benzophenone-12.

[0284] The benzophenone derivative is preferably selected from n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate, sold, for example, by BASF under the trade name Uvinul A+.

[0285] vi) benzylidene camphor derivatives, in particular of the formula (IX), as well as their optical and geometric isomers and their solvates:

[0286] [Chemical formula 14]

[0287]

[0288] in:

[0289] -R 16 , R17 , R 18 and n is as defined above in formula (E);

[0290] - R23 represents a hydrogen atom or a (C1-C4) alkyl group, preferably a hydrogen atom;

[0291] -R24 represents a hydrogen atom or a (C1-C6) alkyl group, a (C1-C6) alkoxy group, a (di) (C1-C6) (alkyl) amino group or R27-C(O)-X-(CH2) p - a group in which R27 represents a (C1-C4)alkyl group or a (C2-C4)alkenyl group, X represents an oxygen atom or NH, and p is an integer from 0 to 4, in particular 1; in particular, R24 represents a (C1-C6)alkyl group, such as a methyl group; preferably, R24 is in the para position relative to the styryl group; and

[0292] - R25 and R26, which are the same or different, represent a hydrogen atom or a hydroxyl group, a (C1-C6)alkyl group, a (C1-C6)alkoxy group or a (di)(C1-C6)(alkyl)amino group, preferably a hydrogen atom; preferably, R25 and R26 are in the meta position relative to the styryl group;

[0293] In particular, the screening agent is chosen from 3-benzylidene camphor, for example sold under the name Mexoryl SD by Chimex, 4-methylbenzylidene camphor, for example sold under the name Eusolex 6300 by Merck, polyacrylamidomethylbenzylidene camphor, for example manufactured under the name Mexoryl SW by Chimex, and mixtures thereof.

[0294] vii) phenylbenzotriazole derivatives, in particular those selected from the group consisting of formula (X), and their optical and geometric isomers and their solvates:

[0295] [Chemical formula 15]

[0296]

[0297] in:

[0298] - q has a value of 0, 1, 2, 3 or 4; preferably, q is 0;

[0299] -R 31 , when q has a value of 1, 2, 3 or 4, it indicates a linear or branched (C1-C 10 ) alkyl or linear or branched (C1-C 10 ) alkoxy;

[0300] -R 32 represents a hydrogen atom or a hydroxyl group, a (di)(C1-C6)(alkyl)amino group, a straight-chain or branched (C1-C 10) alkyl or linear or branched (C1-C 10 ) alkoxy, preferably hydroxy; more particularly, R 32 Located in the ortho position relative to the benzotriazolyl group on the phenyl group;

[0301] -R 33 represents a hydrogen atom, a group selected from the groups of formulae (A) to (H) as defined above, a group selected from: i) - (ALK) t -(A), ii)–(ALK) t -(B), iii)–(ALK) t -(C), iv)–(ALK) t -(D), v)–(ALK) t -(E), vi)–(ALK) t -(F) or –(ALK) t -(F'), vii)–(ALK) t -(G) and viii)–(ALK) t -(H), wherein t has a value of 0 or 1, ALK represents a linear or branched, preferably branched, (C1-C6)alkylene, more preferably a linear or branched, preferably branched, (C1-C4)alkylene, and (A) to (H) represent a group selected from the groups of formulae (A) to (H) as defined above, the following group (J):

[0302] [Chemical formula 16]

[0303]

[0304] Wherein ALK is as defined above, preferably methylene, and R' 31 , R' 32 , R' 34 and q' are respectively as for R 31 , R 32 , R 34 and q are defined; preferably, R' 31 =R 31 , R' 32 =R 32 , R' 34 =R 34 And q'=q;

[0305] - Preferably, R 33 It is located in the meta position relative to the benzotriazolyl group on the phenyl group;

[0306] -R 34 represents a hydrogen atom or a straight or branched, preferably branched, (C1-C 12 )alkyl, more preferably selected from the groups (A) and (B) as defined above, still more preferably selected from the group (B), such ast -Bu-CH2-C(CH3)2-.

[0307] The phenylbenzotriazole derivatives may be chosen from 2-(2H-benzotriazol-2-yl)phenol derivatives, in particular from those of formula (XI), as well as their optical isomers and their solvates:

[0308] [Chemical formula 17]

[0309]

[0310] in:

[0311] -R4 represents a saturated or unsaturated, preferably saturated, linear or branched C1-C 12 carbon chain, optionally forming one or more saturated or unsaturated rings; preferably, R4 represents a linear or branched (C1-C6) alkyl group, in particular a (C1-C4) alkyl group, such as methyl; more preferably, the R4 group is located in the para position relative to the hydroxyl group on the phenyl group;

[0312] - R5 represents a saturated or unsaturated, preferably saturated, linear or branched C1-C6 carbon chain; R5 more particularly represents a linear or branched (C1-C6)alkyl, in particular a (C1-C4)alkyl, and preferably a methyl group;

[0313] - R6 represents a group selected from the groups of formulae (A) to (H) as defined above; preferably, R6 represents RR'R"Si-, wherein R, R" and R"', which are the same or different, represent (C1-C6)alkyl, (C1-C6)alkoxy or tri(C1-C4)alkylsiloxy; preferably, R6 represents a group selected from the groups of formulae (C) or (D); more preferably, R6 has formula (XII):

[0314] [Chemical formula 18]

[0315]

[0316] wherein R6 represents a linear or branched C1-C6 alkyl group, in particular a methyl group.

[0317] Preferably, R4, R5 and R6 represent a methyl, ethyl, propyl or isopropyl group, and more particularly a methyl group.

[0318] In particular, the phenylbenzotriazole derivative can be chosen from silatrizole, such as Mexoryl XL, drometrizole trisiloxane, such as sold under the name Silatrizole by Rhodia Chimie, methylenebis-benzotriazolyltetramethylbutylphenol, such as sold in solid form under the trade name Mixxim BB / 100 by Fairmount Chemical or in micronized form in aqueous dispersion under the trade name Tinosorb M by Ciba Specialty Chemicals, 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, such as sold under the name HMPB2 or Eversorb 89.

[0319] It may preferably be silatrizole.

[0320] viii) triazine derivatives, in particular those selected from the group consisting of formula (XIII) or (XIII'), and their optical or tautomers and their solvates:

[0321] [Chemical formula 19]

[0322]

[0323] [Chemical formula 20]

[0324]

[0325] in:

[0326] -X a , X b and X c , which are the same or different, preferably the same, and represent a bond, an oxygen atom or -N(R a )-, where R a represents a hydrogen atom or a (C1-C4) alkyl group; preferably, X a , X b and X c are identical and represent a bond or -N(H)-, more preferably -N(H)-;

[0327] -R 35 , R 37 and R 39 , which are the same or different, represent a hydrogen atom or a hydroxyl group, a linear or branched (C1-C6) alkyl group, a linear or branched (C1-C6) alkoxy group or a (di)(C1-C6)(alkyl)amino group, preferably a hydrogen atom or a hydroxyl group;

[0328] In particular, R 35 , R 37 and R39 located in the ortho position to the phenyl group bonded to the triazine group;

[0329] -G represents a group selected from the groups of formulae (A) to (H) as defined above, preferably a group of formula (A) as defined above;

[0330] -R 36 , R 38 and R 40 , which are the same or different, represent a hydrogen atom or a group selected from the following: a) linear or branched (C1-C6) alkyl, b) (C1-C6) alkylcarbonyl, c) linear or branched (C1-C6) alkoxy, such as methoxy, d) (C1-C6) alkoxycarbonyl, e) (di) (C1-C6) (alkyl) amino, f) (di) (C1-C4) (alkyl) aminocarbonyl, in particular such as tert-butylaminocarbonyl, g) (C1-C4) (alkyl) carbonylamino, h) –C(R 41 )=C[C(O)-OR 42 ]2, i)–(X') t -(A),j)–(X') t -(B), k)–(X') t -(C), l)–(X') t -(D), m)–(X') t -(E),n)–(X') t -(F) or –(X') t -(F'), o)–(X') t -(G), p)–(X') t -(H), q) 2-(benzo)oxazolyl optionally substituted by one or more straight-chain or branched, preferably branched, (C1-C6) alkyl groups, r) 2-(benzo)imidazolyl optionally substituted by one or more straight-chain or branched, preferably branched, (C1-C6) alkyl groups, s) 2-(benzo)triazolyl optionally substituted by one or more straight-chain or branched, preferably branched, (C1-C6) alkyl groups; wherein (A) to (H) are radicals of formula (A) to (H) as defined above; R 41 represents a hydrogen atom or a (C1-C4) alkyl group, R 42 represents a linear or branched, preferably branched, (C1-C6) alkyl group, such as tert-butyl, t has a value of 0 or 1, preferably 1, X' represents an ALK group as defined above or Y; wherein Y represents an oxygen atom, -N(H)-, -C(O)-, -C(O)-O-, -OC(O)-, -C(O)-N(H)-, -N(H)-C(O)-, -OC(O)-N(H)- or -N(H)-C(O)-O-, or -N(H)-C(O)-N(H)-; preferably, Y represents an ester;

[0331] More specifically, the R 36 The group represents a linear or branched (C1-C6) alkoxy group, such as methoxy, or -C(O)-O-(A), R 38 and R 40 , which are identical or different, preferably identical, and represent —O—(A) or —C(O)—O—(A), wherein (A) is a radical of formula (A) as defined above;

[0332] In particular, R 36 , R 38 and R 40 located in the para position to the phenyl group bonded to the triazine group;

[0333] It is important to understand that at least two R 35 To R 40 The radical is not a hydrogen atom.

[0334] In particular, the triazine derivative may be chosen from 2,4-bis(hydroxyphenyl-2-yl)-1,3,5-triazine derivatives, preferably those of formula (XIV), as well as their optical isomers and their solvates:

[0335] [Chemical formula 21]

[0336]

[0337] in:

[0338] - R7 and R8, which are identical or different, preferably identical, represent a group selected from the groups of formulae (A) to (H) as defined above or a branched C4-C4 group optionally forming one or more rings; 20 , especially C6-C 12 , more preferably C8-C 10 alkyl; preferably, R7 and R8 represent a group selected from the groups of formula (A) as defined above; and

[0339] -R9 represents a linear or branched C1-C6 alkoxy group, such as a methoxy group.

[0340] In particular, the triazine derivative may also be chosen from 2,4,6-tris(anilino)-1,3,5-triazine compounds, in particular having formula (XV), as well as their optical isomers and their solvates:

[0341] [Chemical formula 22]

[0342]

[0343] in:

[0344] -X 1 , X 2 and X3 , which are the same or different, preferably the same, represent an oxygen atom or a NR'12 group; preferably, X 1 , X 2 and X 3 represents oxygen atom;

[0345] - R10, R11 and R12, which are identical or different, preferably identical, represent a group or a branched C4-C 20 , especially C6-C 12 , more preferably C8-C 10 Alkyl; and

[0346] -R'12 represents a hydrogen atom, a straight or branched C7-C 20 an alkyl group, or a group selected from the groups of formulae (A) to (H) as defined above, or a branched C4-C 20 , especially C6-C 12 , more preferably C8-C 10 Alkyl; in particular, R'12 represents a hydrogen atom or a group of formula (A);

[0347] Preferably, R10, R11 and R12 represent a group of formula (A); in particular, the triazine derivative of formula (XV) is selected from tris(2-propylhexyl)-4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate, tris(2-ethylhexyl)-4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate (also known as ethylhexyl triazone, octyl triazone or sold under the name Uvinul T150), tris(2-ethyl-2-propylhexyl)-4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate and tris(2-ethyloctyl)-4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate and mixtures thereof.

[0348] In particular, the triazine derivative may be selected from bis-ethylhexyloxyphenol methoxyphenyl triazine, for example sold under the trade name Tinosorb S by CibaGeigy, ethylhexyl triazone, for example sold under the trade name Uvinul T150 by BASF, diethylhexyl butyramido triazone, for example sold under the trade name Uvasorb by Sigma 3V HEB sells, for example, 2,4,6-tris(diisobutyl 4'-aminobenzylidenemalonate)-s-triazine, 2,4,6-tris(dineopentyl 4'-aminobenzylidenemalonate)-s-triazine, 2,4-bis(dineopentyl 4'-aminobenzylidenemalonate)-6-(n-butyl 4'-aminobenzoate)-s-triazine; 2,4-bis(n-butyl 4'-aminobenzoate)-6-(aminopropyltrisiloxane)-s-triazine; 2,4-bis[5-(1,1-dimethylpropyl)benzoxazol-2-yl(4-phenyl)imino]-6-(2-ethylhexyl)imino-1,3,5-triazine, for example from Sigma 3V under the name Uvasorb K2A sells tris(2-propylhexyl)4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate, tris(2-ethylhexyl)4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate, tris(2-ethyl-2-propylhexyl)4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate, tris(2-ethyloctyl)4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate and mixtures thereof.

[0349] Preferably, the triazine derivative can be selected from 2,2'-[6-(4-methoxyphenyl)-1,3,5-triazine-2,4-diyl]bis{5-[(2-ethylhexyl)oxy]phenol}, also known as bis-ethylhexyloxyphenol methoxyphenyl triazine, Bemotrizinol or Tinosorb S, Anisotriazine and mixtures thereof. The shielding agent sold under the name Tinosorb S is very particularly suitable.

[0350] Preferably, the triazine derivative can be selected from tris(2-ethylhexyl)-4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)tribenzoate (Uvinul T150) and / or 2-ethylhexyl-4-[[4,6-bis[[4-(2-ethylhexyloxy-oxymethyl)phenyl]amino]-1,3,5-triazin-2-yl]amino]benzoate.

[0351] Preferably, it is 2,4,6-tris(anilino)-1,3,5-triazine, sold in particular under the name ethylhexyl triazone or Uvinul T150.

[0352] ix) anthranilic acid derivatives, in particular of formula (XVI), as well as their optical and geometric isomers and their solvates:

[0353] [Chemical formula 23]

[0354]

[0355] in:

[0356] -Y is as defined above, in particular -C(O)-O- or -OC(O)-; preferably, Y represents -C(O)-O-;

[0357] -R 43 to R 46 , which are the same or different, preferably the same, and represent a hydrogen atom or a (C1-C6)alkyl, a (C1-C6)alkoxy or a (di)(C1-C6)(alkyl)amino group, preferably a hydrogen atom;

[0358] -R 47 represents a group of formula (A) to (H) as defined above, preferably a group of formula (F) or (F'), more preferably a group of (F') such as menthyl;

[0359] And in particular menthol anthranilate, sold in particular by Symrise under the trade name Neo Heliopan MA.

[0360] x) imidazoline derivatives, in particular those of formula (XVII), as well as their optical and geometric isomers, their tautomers and their solvates:

[0361] [Chemical formula 24]

[0362]

[0363] in:

[0364] -R 47 , R 48 and R 49 , which are the same or different, represent a hydrogen atom or a linear or branched (C1-C6) alkyl group or a linear or branched (C1-C6) alkoxy group; in particular, R 47 represents a hydrogen atom, and R 48 and R 49 represents a (C1-C4)alkoxy group, in particular a methoxy group;

[0365] -R 50 represents a hydrogen atom or a linear or branched (C1-C6) alkyl group, preferably hydrogen;

[0366] -R 51represents a hydrogen atom or a linear or branched (C1-C6) alkyl group, preferably hydrogen, -ALK'-(Y) t -(A), -ALK'–(Y) t -(B), -ALK'–(Y) t -(C),–ALK'–(Y) t -(D),–ALK'–(Y) t -(E),–ALK'–(Y) t -(F) or –ALK'–(Y) t -(F'),–ALK'–(Y) t -(G) and –ALK'–(Y) t -(H), wherein t has a value of 0 or 1, preferably 1, (A) to (H) represent a radical of the formula (A) to (H) as defined above, wherein Y is as defined above; preferably, Y represents an ester, and more particularly -C(O)-O-(A);

[0367] And in particular ethylhexyl dimethoxybenzylidene dioxoimidazolinium propionate.

[0368] xi) Benzalmalonate derivatives, in particular polyorganosiloxanes having a benzylidenemalonate function, especially polysilicone-15, sold in particular under the trade name Parsol SLX by DSM Nutritional Products Inc., and dineopentyl 4'-methoxybenzylidenemalonate.

[0369] xii) merocyanine derivatives, in particular octyl 5-N,N-diethylamino-2-phenylsulfonyl-2,4-pentadienoate.

[0370] Hydrophilic organic UV-B and / or UV-A screeners

[0371] Among the hydrophilic organic UV-B and / or UV-A screeners, mention may in particular be made of the hydrophilic UV-A screeners such as the bisbenzoxazolyl derivatives described in patents EP 669 323 and US Pat. No. 2 463 264, and more particularly the compound disodium phenyldibenzimidazoletetrasulfonate sold by Symrise under the trade name Neo Heliopan AP.

[0372] Mention may also be made of terephthalylidene dicamphorsulfonic acid (sold for example under the trade name Mexoryl SX).

[0373] Among the hydrophilic organic UV-B and / or UV-A screeners, mention may in particular be made of hydrophilic UV-B screeners such as:

[0374] - the following para-aminobenzoic acid (PABA) derivatives: PABA; glyceryl PABA; and PEG-25 PABA, sold in particular by BASF under the trade name Uvinul P25;

[0375] - phenylbenzimidazolesulfonic acid, sold in particular under the trade name Eusolex 232 by Merck;

[0376] -Ferulic acid;

[0377] - Salicylic acid;

[0378] -DEA methoxycinnamate;

[0379] - benzalcamphorsulfonic acid, sold in particular under the name Mexoryl SL by Chimex;

[0380] - Camphorbenzalkonium methosulfate, sold in particular under the name Mexoryl SO by Chimex.

[0381] Inorganic UV shielding agent

[0382] The composition according to the invention may also use an inorganic UV screener, which is generally an uncolored pigment. The pigment may or may not be coated.

[0383] Within the meaning of the present invention, the term "pigments" is understood to mean solid particles that are white or colored and inorganic or organic.

[0384] The term "unpigmented" means that the pigment does not absorb in the visible spectrum and appears white or colorless to the naked eye.

[0385] The coated pigment is a pigment which has been subjected to one or more surface treatments of a chemical, electrical, mechanochemical and / or mechanical nature with compounds such as those described, for example, in Cosmetics & Toiletries, February 1990, Vol. 105, pp. 53-64, such as amino acids, beeswax, fatty acids, fatty alcohols, anionic surfactants, lecithin, sodium, potassium, zinc, iron or aluminum salts of fatty acids, metal alkoxides (titanium or aluminum alkoxides), polyethylene, silicones, proteins (collagen, elastin), alkanolamines, silicon oxide, metal oxides or sodium hexametaphosphate.

[0386] As is known, silicones are silicone polymers or oligomers of linear or cyclic, branched or crosslinked structure, of variable molecular weight, obtained by polymerization and / or polycondensation of suitably functionalized silanes and consisting essentially of recurring main units in which silicon atoms are linked together by oxygen atoms (siloxane bonds) and to which optionally substituted hydrocarbon radicals are directly attached via carbon atoms.

[0387] The term "silicone" also covers the silanes required for its preparation, in particular alkylsilanes.

[0388] The silicone used for coating the pigments suitable for the present invention is preferably selected from alkylsilanes, polydialkylsiloxanes and polyalkylhydrogensiloxanes. Even more preferably, the silicone is selected from octyltrimethylsilane, polydimethylsiloxane and polymethylhydrogensiloxane.

[0389] Of course, before the treatment with the silicone, the metal oxide pigments may have been treated with other surfactants, in particular with cerium oxide, aluminum oxide, silicon dioxide, aluminum compounds, silicon compounds or mixtures thereof.

[0390] Coated pigments are, for example, titanium oxide coated with:

[0391] - coating with silica, in particular the product Sunveil from Ikeda and the product Eusolex T-Avo from Merck,

[0392] - coating with silica and iron oxide, in particular the product Sunveil F from Ikeda,

[0393] - coating with silicon dioxide and aluminum oxide, in particular the products Microtitanium Dioxide MT500SA and Microtitanium Dioxide MT 100SA from Tayca, Tioveil from Tioxide and Mirasun TiW 60 from Rhodia,

[0394] - coating with aluminum oxide, in particular the products Tipaque TTO-55(B) and Tipaque TTO-55(A) from Ishihara and UVT 14 / 4 from Kemira,

[0395] - coating with aluminum oxide and aluminum stearate, in particular the products Microtitanium Dioxide MT100TV, MT 100TX, MT 100Z and MT-01 from Tayca and the products Solaveil CT-10W, Solaveil CT 100 and Solaveil CT 200 from Uniqema,

[0396] - coating with silica, alumina and alginic acid, in particular the product MT-100AQ from Tayca,

[0397] - coating with aluminum oxide and aluminum laurate, in particular the product Microtitanium Dioxide MT100S from Tayca,

[0398] - coating with iron oxide and iron stearate, in particular the product Microtitanium Dioxide MT100F from Tayca,

[0399] - coated with zinc oxide and zinc stearate, in particular the product BR351 from Tayca,

[0400] - coated with silicon dioxide and aluminum oxide and treated with silicone, in particular the products Microtitanium Dioxide MT 600SAS, Microtitanium Dioxide MT 500SAS and Microtitanium Dioxide MT 100SAS from Tayca,

[0401] - coated with silica, alumina and aluminum stearate and treated with silicone, in particular the product STT-30-DS from Titan Kogyo,

[0402] - coated with silica and treated with silicone, in particular the product UV-Titan X 195 from Kemira or the product SMT-100WRS from Tayca,

[0403] - coated with aluminum oxide and treated with silicone, in particular the products Tipaque TTO-55(S) from Ishihara and UV Titan M 262 from Kemira,

[0404] - coating with triethanolamine, in particular the product STT-65-S from Titan Kogyo,

[0405] - coating with stearic acid, in particular the product Tipaque TTO-55 (C) from Ishihara,

[0406] - Coating with sodium hexametaphosphate, in particular the product Microtitanium Dioxide MT 150W from Tayca.

[0407] Other titanium oxide pigments treated with silicones are, for example, TiO2 treated with octyltrimethylsilane, such as the product sold under the trade name T 805 by Degussa Silices, TiO2 treated with polydimethylsiloxane, such as the product sold under the trade name 70250Cardre UF TiO2SI3 by Cardre, anatase / rutile TiO2 treated with polydimethylhydrogensiloxane, such as the product sold under the trade name Microtitanium Dioxide USP Grade Hydrophobic by Color Techniques.

[0408] Uncoated titanium oxide pigments are sold, for example, under the trade names Microtitanium Dioxide MT500 B and Microtitanium Dioxide MT 600B by Tayca, P 25 by Degussa, Transparent Titanium Oxide PW by Wackher, UFTR by Myoshi Kasei, ITS by Tomen and Tioveil AQ by Tioxide.

[0409] Uncoated zinc oxide pigments are for example:

[0410] - those sold by Sunsmart under the name Z-Cote;

[0411] - those sold by Elementis under the name NanoX;

[0412] - Those sold under the name Nanogard WCD 2025 by Nanophase Technologies.

[0413] The coated zinc oxide pigments are for example:

[0414] - those sold under the name Z-Cote HP1 by Sunsmart (dimethicone-coated ZnO),

[0415] - those sold under the name Zinc Oxide CS-5 by Toshibi (ZnO coated with polymethylhydrogensiloxane),

[0416] - those sold under the name Nanogard Zinc Oxide FN by Nanophase Technologies (as in Finsolv TN, C 12 -C 15 40% dispersion in alkyl esters),

[0417] - those sold under the names Daitopersion Zn-30 and Daitopersion Zn-50 by Daito (dispersions in oxyethylenated dimethicone / cyclomethicone containing 30% or 50% of zinc oxide coated with silica and polymethylhydrogensiloxane),

[0418] - those sold under the name NFD Ultrafine ZnO by Daikin (ZnO coated with a perfluoroalkyl phosphate and a perfluoroalkylethyl-based copolymer, as a dispersion in cyclopentasiloxane),

[0419] - those sold under the name SPD-Z1 by Shin-Etsu (ZnO coated with silicone-grafted acrylic polymer, dispersed in cyclomethicone),

[0420] - those sold under the name Escalol Z100 by ISP (ZnO treated with alumina, dispersed in a mixture of ethylhexyl methoxycinnamate / PVP-hexadecene copolymer / methicone),

[0421] - those sold under the name Fuji ZnO-SMS-10 by Fuji Pigment (ZnO coated with silica and polymethylsilsesquioxane),

[0422] - those sold under the name Nanox Gel TN by Elementis (55% dispersion in benzoic acid C containing hydroxystearic acid polycondensate 12 -C 15 ZnO in alkyl esters).

[0423] Uncoated cerium oxide pigments are sold, for example, under the name Colloidal Cerium Oxide.

[0424] Uncoated iron oxide pigments are sold, for example, by Arnaud under the names Nanogard WCD 2002 (FE 45B), Nanogard Iron FE 45BLAQ, Nanogard FE45RAQ and Nanogard WCD 2006 (FE 45R) or by Mitsubishi under the name TY-220.

[0425] Coated iron oxide pigments are sold, for example, by Arnaud under the names Nanogard WCD 2008 (FE 45B FN), Nanogard WCD 2009 (FE 45B 556), Nanogard FE 45BL 345 and Nanogard FE 45BL or by BASF under the name Transparent Iron Oxide.

[0426] Mention may also be made of mixtures of metal oxides, in particular mixtures of titanium dioxide and cerium dioxide, including mixtures by weight of titanium dioxide and cerium dioxide coated with silica, sold under the name Sunveil A by Ikeda, and mixtures of titanium dioxide and zinc dioxide coated with aluminum oxide, silicon dioxide and silicone, such as the product M 261 sold by Kemira, or mixtures of titanium dioxide and zinc dioxide coated with aluminum oxide, silicon dioxide and glycerol, such as the product M 211 sold by Kemira.

[0427] The pigment can be introduced as such or in the form of a pigment paste, that is to say as a mixture with a dispersant, as described, for example, in document GB-A-2 206 339.

[0428] According to one particular embodiment, the composition according to the invention does not use inorganic UV-screening agents.

[0429] According to a particular embodiment, the amount of inorganic UV-screening agent may be 0.01% to 20% by weight relative to the total weight of the composition. It is for example 1% to 15% by weight relative to the total weight of the composition.

[0430] According to a preferred embodiment, the composition according to the invention also uses one or more additional organic UV screening agents, preferably hydrophobic screening agents.

[0431] According to a preferred embodiment, the composition according to the invention uses one or more additional UV-screening agents selected from hydrophobic organic UV-A screeners, hydrophobic organic UV-B screeners and / or hydrophobic organic mixed UV-A and UV-B screeners.

[0432] More preferably, the composition according to the present invention further uses one or more additional UV screening agents selected from p-aminobenzoic acid derivatives, 3,3-diphenylacrylate and 4,4-diarylbutadiene derivatives, benzophenone derivatives, benzylidene camphor derivatives, triazine derivatives, anthranilic acid derivatives, imidazoline derivatives, benzylidene malonate derivatives and mixtures thereof.

[0433] According to one embodiment, the additional organic UV-screening agent may be present in the composition according to the invention in an amount ranging from 0.05% to 5% by weight, in particular from 0.1% to 0.5% by weight, relative to the total weight of the composition.

[0434] In particular, the composition according to the invention comprises less than 1 wt. %, preferably less than 0.5 wt. %, more preferably less than 0.1 wt. %, in particular less than 0.01 wt. % of additional UV screening agents, and in fact even contains no additional UV screening agents.

[0435] Additional antioxidants

[0436] The flavoured composition according to the invention may additionally comprise one or more antioxidants different from the compound of formula (I) or (II).

[0437] In particular, the flavoured composition according to the invention may also comprise one or more additional antioxidants different from the sulphur-containing antioxidant compounds a) defined above and the vitamins defined below.

[0438] The antioxidant may be of a primary type or a secondary type, and may be selected from hindered phenols, aromatic secondary amines, organic phosphorus compounds, sulfur-containing compounds, lactones, bisphenol acrylates, and mixtures thereof.

[0439] Among the antioxidants very suitable for the invention, mention may in particular be made of butylated hydroxyanisole (BHA), tert-butylhydroquinone (TBHQ), 1,3,5-trimethyl-2,4,6-tris(3,5-di(tert-butyl)-4-hydroxybenzyl)benzene, octadecyl 3,5-di(tert-butyl)-4-hydroxycinnamate, pentaerythritol tetrakis(di(tert-butyl)hydroxycinnamate), such as those produced by BASF under the name TT, tetrakis-methylene-3-(3,5-di(tert-butyl)-4-hydroxyphenyl)propionate methane, octadecyl 3-(3,5-di(tert-butyl)-4-hydroxyphenyl)propionate, 2,5-di(tert-butyl)hydroquinone, 2,2-methylenebis(4-methyl-6-(tert-butyl)phenol), 2,2-methylenebis(4-ethyl-6-(tert-butyl)phenol), 4,4-butylenebis(6-(tert-butyl)-m-cresol), N,N-hexamethylenebis(3,5-di(tert-butyl)-4-hydroxyhydrocinnamic acid), pentaerythritol tetrakis(3-(3,5-di(tert-butyl)-4-hydroxyphenyl)propionate), especially by CIBA under the name 1010, octadecyl 3-(3,5-di(tert-butyl)-4-hydroxyphenyl)propionate, sold especially by CIBA under the name 1076, 1,3,5-tris(3,5-di(tert-butyl)-4-hydroxybenzyl)-1,3,5-triazine-2,4,6(1H,3H,5H)trione, sold particularly under the name 3114, sold under the name di(stearyl)pentaerythritol diphosphite, tri(2,4-di(tert-butyl)phenyl)phosphite, especially by CIBA under the name 168 sold as bis(2,4-di(tert-butyl)pentaerythritol diphosphite, especially by CIBA under the name 126, bis(2,4-bis[2-phenylpropan-2-yl]phenyl)pentaerythritol diphosphite, triphenyl phosphite, (2,4-di(tert-butyl)phenyl)pentaerythritol diphosphite, especially by GE Specialty Chemicals under the name UL 626 sold as tris(nonylphenyl)phosphite, especially by CIBA under the name TNPP is sold as a 1:1 mixture of N,N-hexamethylenebis(3,5-di(tert-butyl)-4-hydroxyhydrocinnamic acid) and tris(2,4-di(tert-butyl)phenyl)phosphate, especially by CIBA under the name B 1171, tris(2,4-di(tert-butyl)phenyl) phosphite, sold especially by CIBA under the name P-EPQ, 2,4-bis(octylthiomethyl)-o-cresol, is sold, inter alia, by CIBA under the name 1520, 4,6-bis(dodecylthiomethyl)-o-cresol, sold especially by CIBA under the name 1726 sold.

[0440] The additional antioxidant may be present in the composition according to the invention in a content ranging from 0.01% to 2.5% by weight, in particular from 0.05% to 1.5% by weight, more particularly from 0.1% to 0.5% by weight relative to the total weight of the composition.

[0441] In particular, the flavored composition according to the invention comprises less than 0.5 wt. %, preferably less than 0.1 wt. %, more preferably less than 0.05 wt. %, indeed even less than 0.01 wt. % of additional antioxidants. For example, the flavored composition according to the invention contains no additional antioxidants.

[0442] According to one particular embodiment, the composition according to the invention may also comprise butylated hydroxytoluene (BHT) as antioxidant.

[0443] According to a preferred embodiment, the composition according to the invention preferably does not contain compounds that are likely to be harmful to humans and / or the environment, that is to say, it contains less than 0.2% by weight, in particular less than 0.1% by weight, preferably less than 0.05% by weight and more preferably less than 0.01% by weight of compounds that are likely to be harmful to humans and / or the environment, relative to the total weight of the composition, and even does not contain compounds that are likely to be harmful to humans and / or the environment, in particular butylated hydroxytoluene (BHT).

[0444] Thus, the composition according to the invention is in particular free of butylated hydroxytoluene (BHT).

[0445] Additional stabilizer

[0446] The scented composition according to the invention may also comprise one or more colour stabilizers different from the sulphur-containing antioxidant compound a).

[0447] As stabilizers of the color of the flavored compositions, mention may be made of tris(tetramethylhydroxypiperidinol) citrate, such as the product sold under the name Tinoguard Q by Ciba-Geigy, sodium benzotriazolyl butylphenol sulfonate, such as the product sold under the name Tinoguard HS by Ciba-Geigy; benzotriazolyl dodecyl p-cresol, such as the product sold under the name Tinoguard TL by Ciba-Geigy; sodium benzotriazolyl butylphenol sulfonate (and) buteth-3 (and) tributyl citrate, such as the product sold under the trade name Cibafast H Liquid by Ciba-Geigy; bumetriazole, such as the product sold under the name Tinoguard AS by Ciba-Geigy.

[0448] These stabilizers may be present in a content ranging from 0.005% to 2% by weight relative to the total weight of the composition, in particular from 0.01% to 0.5% by weight relative to the total weight of the composition.

[0449] In particular, the composition according to the invention comprises less than 0.1% by weight, in particular less than 0.05% by weight, of color stabilizer, relative to the total weight of the composition, and is in fact even free of color stabilizer.

[0450] Vitamins

[0451] The flavored composition according to the invention may also contain vitamins and their derivatives, in particular their esters, such as niacinamide (3-pyridinecarboxamide), nicotinamide (vitamin B3), tocopherol (vitamin E) and its derivatives (such as tocopherol acetate), ascorbic acid and its derivatives (vitamin C), retinol (vitamin A).

[0452] In particular, the vitamins or their derivatives may be chosen from tocopherol and its derivatives. Tocopherol may be present in one of its various forms, in particular the alpha, beta, gamma and delta forms. Among the tocopherol derivatives, tocotrienols and esters may be mentioned.

[0453] Preferably, the composition according to the invention comprises at least one or more antioxidants chosen from tocopherol and tocopherol esters, in particular tocopherol acetate, more preferably alpha-tocopherol and alpha-tocopherol acetate.

[0454] In particular, the flavoring composition according to the invention comprises at least 0.001% by weight, in particular from 0.001% to 0.5% by weight, more particularly from 0.02% to 0.1% by weight, indeed even from 0.03% to 0.05% by weight, of tocopherol and / or derivatives thereof relative to the total weight of the flavoring composition.

[0455] Solvents

[0456] In particular, the scented composition according to the invention is an aqueous composition, i.e. a composition comprising at least water as solvent, an alcoholic composition, i.e. a composition comprising at least one alcohol as solvent, or an aqueous / alcoholic composition, i.e. a composition comprising a mixture of water and an alcohol as solvent.

[0457] In particular, the flavoring composition according to the invention comprises at least 50% by weight, in particular from 60% to 95% by weight, more particularly from 70% to 90% by weight, of one or more solvents chosen from water, alcohols and mixtures thereof, relative to the total weight of the flavoring composition.

[0458] Preferably, the scented composition according to the invention is an aqueous / alcoholic composition.

[0459] The scented composition according to the invention may comprise a mixture of water and alcohol in an alcohol / water weight ratio of 50 / 50 to 99.5 / 0.5, preferably 70 / 30 to 99 / 1, especially 80 / 20 to 98 / 2, in particular 85 / 15 to 95 / 5.

[0460] As mentioned above, the scented composition according to the invention may be an alcoholic composition or an aqueous / alcoholic composition.

[0461] Alcohols very particularly suitable for the invention are selected from i) monohydric alcohols having 2 to 6 carbon atoms, such as ethanol and isopropanol, and ii) diols having 2 to 8 carbon atoms, such as ethylene glycol, propylene glycol, 1,3-butanediol and dipropylene glycol.

[0462] Preferably, the alcohol is of natural origin. Bioethanol may be mentioned in particular

[0463] In particular, the scented composition according to the invention comprises, as solvent, water, (bio)ethanol, pentylene glycol or a mixture of at least two of these compounds.

[0464] As mentioned above, the scented composition according to the invention may be an aqueous composition, ie a composition comprising water as solvent, or an aqueous / alcoholic composition, ie a composition comprising a mixture of water and alcohol as solvent.

[0465] Besides water, the scented composition according to the invention may comprise at least one water-soluble solvent different from the alcohol defined above.

[0466] In the present invention, the term "water-soluble solvent" refers to a compound that is liquid at ambient temperature and miscible with water (miscibility in water greater than 50% by weight at a temperature of 20 to 25°C and at atmospheric pressure).

[0467] The water-soluble solvents that can be used in the composition according to the invention may additionally be volatile.Among the water-soluble solvents that can be used in the composition according to the invention, mention may in particular be made of C3 and C4 ketones and C2-C4 aldehydes.

[0468] Alternatively, the scented composition according to the invention may be anhydrous, ie it may comprise less than 2% by weight of water, in particular less than 1% by weight of water, more particularly less than 0.5% by weight of water, or indeed even completely free of water.

[0469] The aromatized composition according to the invention may also comprise at least one C2-C 32 Polyols. Within the meaning of the present invention, the term "polyol" is understood to mean any organic molecule containing at least three free hydroxyl (-OH) groups. Preferably, the polyols according to the invention are present in liquid form at ambient temperature. The polyols suitable for the present invention can be compounds of saturated or unsaturated, and linear, branched or cyclic alkyl type, with at least three -OH functions, in particular at least four -OH functions, on the alkyl chain.

[0470] Polyols that are advantageously suitable for formulating the compositions according to the invention are in particular those having from 2 to 32 carbon atoms, preferably from 3 to 16 carbon atoms.

[0471] Preferably, the polyol may be chosen, for example, from pentaerythritol, trimethylolpropane, glycerol, polyglycerols, in particular glycerol oligomers, preferably diglycerol, and mixtures thereof.

[0472] additive

[0473] The scented composition according to the invention may additionally comprise any additives commonly used in the field of fragrances, such as emollients or softeners, in particular sweet almond oil, almond oil, sweeteners, humectants, in particular glycerol, soothing agents, in particular α-bisabolol, allantoin and aloe vera; essential fatty acids, propellants, peptizers, fillers, cosolvents, surfactants, defoamers, polar additives, film-forming polymers, gelling agents, thickeners, pH regulators (acids or bases), neutralizers, chelating agents or preservatives, and mixtures thereof.

[0474] It is a routine matter for a person skilled in the art to adjust the nature and amount of the additives present in the composition according to the invention so as not to thereby affect the desired cosmetic properties of the composition.

[0475] When these additives are present in the composition of the invention, they may be present in an amount ranging from 0.001% to 10% by weight and better still from 0.01% to 5% by weight relative to the total weight of the composition.

[0476] d) Colorants

[0477] The scented composition according to the invention may also comprise at least one colorant.

[0478] In general, "colorant" is understood to mean any compound capable of coloring a composition, that is to say which absorbs in the visible spectrum and in particular appears to the human eye as having a color such as yellow, orange, red, violet, blue or green.

[0479] The colorant(s) are preferably selected from particulate colorants, fat-soluble dyes, water-soluble dyes and mixtures thereof.

[0480] Within the meaning of the present invention, the term "fat-soluble dye" is understood to mean any natural or synthetic, usually organic, dye which is soluble in an oily phase or in a solvent which is miscible with fatty substances.

[0481] The particle colorants may be colored pigments (ie other than pigmented UV screeners), pearlescent agents and / or particles having a metallic sheen.

[0482] Pigments are naturally insoluble in the liquid hydrophilic and lipophilic phases typically used in cosmetics. Alternatively, they can be made insoluble by formulation in the form of lakes, if appropriate.

[0483] More particularly, the pigment has little or no solubility in aqueous / alcoholic media.

[0484] The pigments may be white or colored, inorganic and / or organic, and coated or uncoated. Among the inorganic pigments, mention may be made of metal oxides, in particular optionally surface-treated titanium dioxide, zirconium oxide, zinc oxide or cerium oxide, and also iron oxide, titanium oxide or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue.

[0485] In particular, the colorant may be selected from organic pigments and synthetic or natural water-soluble dyes, preferably synthetic or natural water-soluble dyes.

[0486] Among the organic pigments of the invention, mention may be made of carbon black, pigments of D&C type, in particular pigments of the azo, anthraquinone, nitro and / or triarylmethane form, and lakes of cochineal based on barium, strontium, calcium and aluminum, preferably pigments of D&C type.

[0487] According to a particular embodiment of the invention, the colorant of the invention is selected from water-soluble dyes. The water-soluble dyes may be anionic, cationic, zwitterionic or neutral, more particularly anionic (i.e. often referred to as "acidic" direct dyes, because of their affinity with alkaline substances).

[0488] The term "anionic dye" is understood to mean any dye comprising in its structure at least one CO2R' or SO3R' substituent, in which R' is a hydrogen atom or a cation of metallic or amine origin, or an ammonium ion.

[0489] The anionic dye may be selected from acid nitro direct dyes, acid azo dyes, acid azine dyes, acid triarylmethane dyes, acid indoleamine dyes, acid anthraquinone dyes, indigoids and acid natural dyes.

[0490] As anionic dyes suitable for the present invention, mention may be made of dyes selected from the group consisting of the following formulae (G), (G'), (J), (J'), (K), (K'), (L) and (M) and mixtures thereof, in particular those of formulae (G), (J) and (L) and mixtures thereof:

[0491] a) Anionic azo fuels of the following formulae (G) and (G'):

[0492] [Chemical formula 25]

[0493]

[0494] [Chemical formula 26]

[0495]

[0496] In this formula, R7, R8, R9, R 10 , R'7, R'8, R'9 and R'10 , which are the same or different, represent a hydrogen or halogen atom or a group selected from the following:

[0497] -alkyl;

[0498] - alkoxy, alkylthio;

[0499] -Hydroxy, thiol;

[0500] -Nitro, nitroso;

[0501] -R°-C(X)-X'-, R°-X'-C(X)- or R°-X'-C(X)-X"-, wherein R° represents a hydrogen atom or an alkyl group or an aryl group; X, X' and X", which are the same or different, represent an oxygen or sulfur atom or NR, wherein R represents a hydrogen atom or an alkyl group;

[0502] -M + (O - )S(O)2-, where M + represents a hydrogen atom or a cationic counterion;

[0503] -M + (O - )CO-, where M + As defined above;

[0504] -R"-S(O)2-, wherein R" represents a hydrogen atom or an alkyl group, an aryl group, a (di)(alkyl)amino group or an aryl(alkyl)amino group; preferably a phenylamino group or a phenyl group;

[0505] -R"'-S(O)2-X'-, wherein R"' represents an optionally substituted alkyl or aryl group, and X' is as defined above;

[0506] -(di)(alkyl)amino;

[0507] - aryl(alkyl)amino optionally substituted by one or more groups selected from the group consisting of: i) nitro; ii) nitroso; iii) M + (O - )S(O)2- and iv) alkoxy, wherein M + As defined above;

[0508] - optionally substituted heteroaryl; preferably benzothiazolyl;

[0509] - cycloalkyl; in particular cyclohexyl;

[0510] -Ar-N=N-, wherein Ar represents an optionally substituted aryl group; preferably optionally substituted with one or more alkyl groups, M + (O - )S(O)2- or phenyl substituted with phenylamino;

[0511] - or two adjacent groups R7 and R8 or R8 and R9 or R9 and R 10 together form a fused benzo group A'; and R'7 and R'8 or R'8 and R'9 or R'9 and R' 10 together to form a fused benzo group B'; wherein A' and B' are optionally substituted by one or more groups selected from the group consisting of: nitro; nitroso; M + (O - )S(O)2-; hydroxyl; mercapto; (di)(alkyl)amino; R°-C(X)-X'-; R°-X'-C(X)-; R°-X'-C(X)-X"-; Ar-N=N- and optionally substituted aryl(alkyl)amino; wherein M + , R°, X, X', X" and Ar are as defined above;

[0512] And among them:

[0513] -W represents a sigma bond, an oxygen or sulfur atom, or a divalent -NR- group, in which R is as defined above, or a methylene -C(Ra)(Rb)- group, in which Ra and Rb, which are identical or different, represent a hydrogen atom or an aryl group, or Ra and Rb together with the carbon atom that carries them form a spirocycloalkyl group; preferably, W represents a sulfur atom, or Ra and Rb together form a cyclohexyl group;

[0514] It is to be understood that formula (G) and (G') contain at least one sulfonate salt M on one of the rings A, A', B, B' or C. + (O - )S(O)2-group or a carboxylate M + (O - )CO- group; preferably sodium sulfonate.

[0515] As examples of dyes of formula (G), mention may be made of Acid Red 1, Acid Red 4, Acid Red 13, Acid Red 14, Acid Red 18, Acid Red 27, Acid Red 28, Acid Red 32, Acid Red 33, Acid Red 35, Acid Red 37, Acid Red 40, Acid Red 41, Acid Red 42, Acid Red 44, Pigment Red 57, Acid Red 68, Acid Red 73, Acid Red 135, Acid Red 138, Acid Red 184, Food Red 1, Food Red 13, Acid Orange 4, Acid Orange 6, Orange 7, Acid Orange 10, Acid Orange 19, Acid Orange 20, Acid Orange 24, Yellow 6, Acid Yellow 9, Acid Yellow 36, Acid Yellow 199, Food Yellow 3; Acid Violet 7, Acid Violet 14, Acid Blue 113, Acid Blue 117, Acid Black 1, Acid Brown 4, Acid Brown 20, Acid Black 26, Acid Black 52, Food Black 1, Food Black 2; Food Yellow 3 or Sunset Yellow; and as examples of dyes of formula (G') there may be mentioned: Acid Red 111, Acid Red 134, Acid Yellow 38;

[0516] b) anthraquinone dyes of the following formulae (J) and (J'):

[0517] [Chemical formula 27]

[0518]

[0519] [Chemical formula 28]

[0520]

[0521] Wherein formula (J) and (J'), R 22 ,R 23 ,R 24 ,R 25 ,R 26 and R 27 , which are the same or different, represent a hydrogen or halogen atom or a group selected from the following:

[0522] -alkyl;

[0523] -Hydroxy, thiol;

[0524] - alkoxy, alkylthio;

[0525] - optionally substituted aryloxy or arylthio, preferably with one or more selected from alkyl and M + (O - )S(O)2-, where M + As defined above;

[0526] -optionally one or more selected from alkyl and M + (O - )S(O)2-substituted aryl(alkyl)amino, wherein M + As defined above;

[0527] -(di)(alkyl)amino;

[0528] -(di)(hydroxyalkyl)amino;

[0529] -M + (O - )S(O)2-, where M + As defined above;

[0530] And among them:

[0531] Z' represents a hydrogen atom or NR 28 R 29 Group, where R 28 and R 29 , which are the same or different, represent a hydrogen atom or a group selected from the following:

[0532] -alkyl;

[0533] - polyhydroxyalkyl groups, such as hydroxyethyl;

[0534] - aryl, optionally substituted by one or more groups, in particular i) alkyl, such as methyl, n-dodecyl or n-butyl; ii) M + (O - )S(O)2-, where M + As defined above; iii) R°-C(X)-X'-, R°-X'-C(X)- or R°-X'-C(X)-X"-, wherein R°, X, X' and X" are as defined above; preferably, R° represents an alkyl group;

[0535] - cycloalkyl; in particular cyclohexyl;

[0536] Z represents a group consisting of hydroxyl and NR' 28 R' 29 A group in which R' 28 and R' 29 , which are the same or different, represent the same as R defined above 28 and R 29 The same atoms or groups;

[0537] It is to be understood that formula (J) and (J') contain at least one sulfonate salt M + (O - )S(O)2-group or a carboxylate M + (O - )CO- group; preferably sodium sulfonate.

[0538] As examples of dyes of formula (J), mention may be made of: Acid Blue 25, Acid Blue 43, Acid Blue 62, Acid Blue 78, Acid Blue 129, Acid Blue 138, Acid Blue 140, Acid Blue 251, Acid Green 25, Acid Green 41, Acid Violet 42, Acid Violet 43, Mordant Red 3; EXT Violet No. 2; and as examples of dyes of formula (J'), mention may be made of: Acid Black 48;

[0539] d) nitro dyes of the following formulae (K) and (K'):

[0540] [Chemical formula 29]

[0541]

[0542] [Chemical formula 30]

[0543]

[0544] Among them, R 30 , R 31 and R 32, which are the same or different, represent a hydrogen or halogen atom or a group selected from the following:

[0545] -alkyl;

[0546] - alkoxy optionally substituted by one or more hydroxyl groups, alkylthio optionally substituted by one or more hydroxyl groups;

[0547] -Hydroxy, thiol;

[0548] -Nitro, nitroso;

[0549] -polyhaloalkyl;

[0550] -R°-C(X)-X'-, R°-X'-C(X)-, R°-X'-C(X)-X"-, wherein R°, X, X' and X" are as defined above;

[0551] -M + (O - )S(O)2-, where M + As defined above;

[0552] -M + (O - )CO-, where M + As defined above;

[0553] -(di)(alkyl)amino;

[0554] -(di)(hydroxyalkyl)amino;

[0555] -heterocycloalkyl, such as piperidino, piperazino or morpholino; in particular, R 30 , R 31 and R 32 represents a hydrogen atom;

[0556] And among them:

[0557] - Rc and Rd, which are the same or different, represent a hydrogen atom or an alkyl group;

[0558] -W is as defined above; W particularly represents a -NH- group;

[0559] -ALK represents a linear or branched divalent C1-C6 alkylene group; in particular, ALK represents a -CH2-CH2- group;

[0560] -n has a value of 1 or 2;

[0561] -p represents an integer from 1 to 5, inclusive;

[0562] -q represents an integer from 1 to 4, inclusive;

[0563] -u has a value of 0 or 1;

[0564] - when n has a value of 1, J represents a nitro or nitroso group; in particular a nitro group;

[0565] - When n has a value of 2, J represents an oxygen or sulfur atom or a divalent -S(O) m - group, wherein m represents an integer of 1 or 2; preferably, J represents a -SO2- group;

[0566] -M' represents a hydrogen atom or a cationic counterion;

[0567] [Chemical formula 31]

[0568]

[0569] The presence or absence thereof indicates that one or more R as defined above are optionally 30 a benzo group substituted with a radical;

[0570] It is to be understood that formula (K) and (K') contain at least one sulfonate salt M + (O - )S(O)2-group or a carboxylate M + (O - )CO- group; preferably sodium sulfonate.

[0571] As examples of dyes of formula (K), mention may be made of: Acid Brown 13 and Acid Orange 3; as examples of dyes of formula (K'), mention may be made of: Acid Yellow 1, the sodium salt of 2,4-dinitro-1-naphthol-7-sulfonic acid, 2-piperidino-5-nitrobenzenesulfonic acid, 2-(4'-N,N-(2"-hydroxyethyl)amino-2'-nitro)anilineethanesulfonic acid, 4-β-hydroxyethylamino-3-nitrobenzenesulfonic acid; EXT D&C Yellow 7;

[0572] e) triarylmethane dyes of the following formula (L):

[0573] [Chemical formula 32]

[0574]

[0575] In formula (L):

[0576] -R 33 , R 34 , R 35 and R 36 , which are the same or different, represent a hydrogen atom or a group selected from alkyl, optionally substituted aryl and optionally substituted aralkyl; in particular, optionally replaced by M + (O - )S(O) m - substituted alkyl and benzyl groups, where M + and m are as defined above;

[0577] -R 37 , R 38 , R 39 , R 40 , R 41 , R 42 , R 43 and R 44 , which are the same or different, represent a hydrogen atom or a group selected from the following:

[0578] -alkyl;

[0579] - alkoxy, alkylthio;

[0580] -(di)(alkyl)amino;

[0581] -Hydroxy, thiol;

[0582] -Nitro, nitroso;

[0583] -R°-C(X)-X'-, R°-X'-C(X)- or R°-X'-C(X)-X"-, wherein R° represents a hydrogen atom or an alkyl group or an aryl group; X, X' and X", which are the same or different, represent an oxygen or sulfur atom or NR, wherein R represents a hydrogen atom or an alkyl group;

[0584] -M + (O - )S(O)2-, where M + represents a hydrogen atom or a cationic counterion;

[0585] -M + (O - )CO-, where M + As defined above;

[0586] - or two adjacent groups R 41 With R 42 or R 42 With R 43 or R 43 With R 44 together to form a fused benzo group: I'; wherein I' is optionally substituted with one or more groups selected from: nitro; nitroso; M + (O - )S(O)2-; hydroxyl; mercapto; (di)(alkyl)amino; R°-C(X)-X'-; R°-X'-C(X)- and R°-X'-C(X)-X"-; wherein M + , R°, X, X' and X" are as defined above;

[0587] In particular, R 37 To R 40represents a hydrogen atom, and R 41 To R 44 , which are the same or different, represent hydroxyl or M + (O - )S(O)2-group; and when R 43 With R 44 When forming a benzo group together, it is preferably (O - )S(O)2-group substitution;

[0588] It is understood that at least one of the rings G, H, I or I' comprises at least one sulfonate (O - )S(O)2-group or a carboxylate (O - )CO-group; preferably sulfonate.

[0589] As examples of dyes of formula (L), mention may be made of: Acid Blue 1, Acid Blue 3, Acid Blue 7, Acid Blue 9, Acid Violet 49, Acid Green 3, Acid Green 5, Acid Green 50.

[0590] f) Xanthene-derived dyes of the following formula (M):

[0591] [Chemical formula 33]

[0592]

[0593] The formula (M), R 45 , R 46 , R 47 and R 48 , which are the same or different, represent a hydrogen atom or a halogen atom, and R 49 , R 50 , R 51 and R 52 , which are the same or different, represent a hydrogen or halogen atom or a group selected from the following:

[0594] -alkyl;

[0595] - alkoxy, alkylthio;

[0596] -Hydroxy, thiol;

[0597] -Nitro, nitroso;

[0598] -M + (O - )S(O)2-, where M + represents a hydrogen atom or a cationic counterion;

[0599] -M + (O - )CO-, where M + As defined above;

[0600] In particular, R 49 , R 50 , R 51 and R 52 represents a hydrogen or halogen atom;

[0601] And among them:

[0602] -G represents an oxygen or sulfur atom or an NRe group, wherein Re represents a hydrogen atom or an alkyl group; in particular, G represents an oxygen atom;

[0603] -L represents alkoxide M + O - ; Thioalcohol salt M + S - or a NRf group, wherein Rf represents a hydrogen atom or an alkyl group, and M + As defined above; M + Especially sodium or potassium;

[0604] -L' represents oxygen or sulfur atom or ammonium group: N + RfRg, wherein Rf and Rg, which are identical or different, represent a hydrogen atom or an optionally substituted alkyl or aryl group; L' represents in particular an oxygen atom or an optionally substituted alkyl or aryl group. + (O - )S(O) m - substituted phenylamino group, wherein m and M + As defined above;

[0605] - Q and Q', which are the same or different, represent an oxygen or sulfur atom; in particular, Q and Q' represent an oxygen atom;

[0606] -M + As defined above.

[0607] As colorants suitable for the present invention, mention may in particular be made of synthetic or natural water-soluble dyes such as, for example, FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 3, DC Green 5, FDC Blue 1 and mixtures thereof, more particularly chosen from FDC Red 4, DC Red 33, DC Orange 4, DC Yellow 5, DC Green 3, DC Green 5 and FDC Blue 1 and mixtures thereof.

[0608] Among the natural direct dyes which can be used according to the invention as colorants, mention may be made of leonardoquinone, juglone, alizarin, purpurin, carmine and carminic acid, cochineal acid, purpurin gallol, protocatechualdehyde, indigo, isatin, curcumin, acanthocyanin, apigenin, orcein, betanin (beetroot), chlorophyllin metal complexes, in particular chlorophyllin copper complexes, methylene blue, caramel, sandalwood, gardenia, spirulina and riboflavin.

[0609] Within the meaning of the present invention, the term "pearlescent agent" refers to any form of colored particles, which may or may not be iridescent, produced in particular by certain molluscs in their shells, or synthetically, and which exhibit a color effect via optical interference.

[0610] The pearlescent agent is selected from pearlescent pigments such as titanium oxide coated mica covered with iron oxide, titanium oxide coated mica covered with bismuth oxychloride, titanium oxide coated mica covered with chromium oxide, titanium oxide coated mica covered with organic dyes and bismuth oxychloride-based pearlescent pigments.

[0611] The pearlescent agent may more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or copper color or hue.

[0612] Within the meaning of the present invention, the term "particles having a metallic sheen" refers to any compound whose nature, size, structure and surface finish make it possible to reflect incident light, in particular in a non-iridescent manner.

[0613] The particles with metallic sparkle that can be used in the present invention can be chosen in particular from particles of at least one metal and / or at least one metal derivative, particles comprising a single-material or multi-material organic or inorganic substrate at least partially covered with at least one layer with metallic sparkle comprising at least one metal and / or at least one metal derivative, and mixtures of said particles. These particles are different from metal ions.

[0614] Among the metals that may be present in the particles, mention may be made of, for example, Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te, Se, and mixtures or alloys thereof. Ag, Au, Cu, Al, Zn, Ni, Mo, Cr, and mixtures or alloys thereof (e.g., bronze and brass) are preferred metals.

[0615] The term "metal derivatives" refers to compounds derived from metals, in particular oxides, fluorides, chlorides and sulfides.

[0616] Preferably, the colorant, if present, is natural or of natural origin.

[0617] The colorants may be present in an amount ranging from 0.00005% to 0.005% by weight and in particular from 0.0001% to 0.001% by weight relative to the total weight of the composition.

[0618] Composition

[0619] As described above, the scented composition according to the invention comprises a) at least one sulphur-containing antioxidant compound as defined above, b) at least one organic UV-screening agent chosen from dibenzoylmethane derivatives as defined above, and c) at least one scenting substance as described above.

[0620] Preferably, the composition according to the invention comprises:

[0621] a') from 0.05% to 0.5%, in particular from 0.08% to 0.1%, relative to the total weight of the flavored composition, of one or more sulfur-containing antioxidant compounds chosen from dilauryl thiodipropionate, distearyl thiodipropionate, dilauryl dithiodipropionate, distearyl dithiodipropionate and mixtures thereof, in particular dilauryl thiodipropionate;

[0622] b') 0.1% to 1%, in particular 0.25% to 0.35%, relative to the total weight of the scented composition, of one or more organic UV-screening agents chosen from butyl methoxydibenzoylmethane and isopropyl dibenzoylmethane, in particular butyl methoxydibenzoylmethane;

[0623] c') 1% to 35%, in particular 10% to 25%, relative to the total weight of the flavored composition, of one or more flavoring substances.

[0624] The perfumed composition according to the invention is preferably a cosmetic composition, ie a cosmetically acceptable composition, so as to be applied to keratin materials, in particular human keratin materials, without adversely affecting them.

[0625] It may be provided in any presentation form customary for topical application, in particular in the form of an aqueous, alcoholic or aqueous / alcoholic solution or suspension or an oily solution or a solution or dispersion of the lotion or serum type, an emulsion of liquid or semi-liquid consistency of the milk type, obtained by dispersing a fatty phase in an aqueous phase (O / W) or vice versa (W / O), or a suspension or emulsion of soft consistency of the (O / W) or (W / O) cream type, or an aqueous or anhydrous gel, an ointment, or any other cosmetic form.

[0626] Preparation of the composition

[0627] The composition according to the invention may be obtained by any method known to a person skilled in the art for formulating coloured and scented compositions.

[0628] In particular, the scented composition according to the invention can be obtained by simple mixing, at ambient temperature, ie at a temperature ranging from 20°C to 25°C, of ​​the compounds constituting the composition.

[0629] Intended use of the composition

[0630] The compositions according to the invention are scented compositions, generally suitable for topical application to the skin and therefore generally comprise a physiologically acceptable medium.

[0631] Preferably, it is a cosmetic composition.

[0632] The invention is applicable not only to perfumed products, but also to cosmetic treatment or care products for keratin materials, in particular the skin (including the scalp) and the lips, which contain odoriferous substances.

[0633] The composition according to the invention may thus constitute a composition for the cosmetic treatment, care or perfumery of keratin materials and may in particular be a light fragrance. ), eau de toilette, eau de parfum, aftershave, perfume, silicone or hydrogenated silicone care oil or eau decologne. It can also be provided in the form of a scented two-phase lotion (eau de toilette phase / hydrocarbon oil and / or silicone oil phase), body milk or shampoo. According to a particular embodiment, the composition according to the invention can also be an elixir or a gel.

[0634] Preferably, the composition according to the invention is in the form of a light fragrance (eaux ), Eau de toilette, Eau de parfum, Eau de cologne or Eau de soin, and even more preferably it is Eau de parfum.

[0635] The composition according to the invention may also constitute any type of cosmetic composition for caring for and / or making up keratin materials.

[0636] The composition of the present invention may be packaged in the form of a bottle.

[0637] The flavoring composition according to the invention can be diffused according to various systems, such as spray, aerosol or piezoelectric device.

[0638] They can also be applied in the form of fine particles by means of mechanical or propellant gas pressurization devices. The devices according to the invention are well known to those skilled in the art and include pump-action sprayers, aerosol containers containing propellants and aerosol pumps using compressed air as propellants. The latter are particularly described in patents US 4 077 441 and US 4 850 517.

[0639] Compositions packaged as aerosols according to the invention generally contain a conventional propellant such as, for example, dimethyl ether, isobutane, n-butane or propane.

[0640] Preferably, the composition according to the invention is dispersed in the form of a spray.

[0641] The present invention is illustrated in more detail by the examples given below. Unless otherwise stated, the amounts shown are expressed as percentages by weight. Example

[0642] Measurement and evaluation methods

[0643] The stability of the composition was evaluated by visual observation of the color change over time and by olfactory assessment of the change in the fragrance note of the scented composition.

[0644] Specifically, the composition was poured into a 50 ml jar made of borosilicate glass, and then stored under atmospheric pressure and various conditions for 2 months, and observations were made:

[0645] a) in a refrigerator at 4°C;

[0646] b) at ambient temperature, i.e. 20°C to 25°C, protected from light;

[0647] c) in an oven at a temperature of 37°C;

[0648] d) in an oven at a temperature of 45°C;

[0649] e) under natural light (northern orientation, Paris location) and at ambient temperature, i.e. 20°C to 25°C, then:

[0650] e.1) 16 hours in an Atlas Suntest CPS+ aging device equipped with a xenon lamp, an irradiation light source, whose spectral distribution is close to that of the sun, delivering 765 W / m 2 of energy, simulating exposure to neon lights in a store, and

[0651] e.2) 2 weeks in an oven at 55°C, simulating the extreme conditions of fragrance.

[0652] Storage of the composition at 45°C for 2 months simulates accelerated aging of the product, equivalent to a shelf life of 3 years.

[0653] Starting Materials

[0654] The compositions of the following examples employ different fragrances belonging to different olfactory categories, namely A to I, as detailed in the table.

[0655] Example 1

[0656] Preparation of flavoring compositions

[0657] Different scented compositions A, B and C according to the invention and scented compositions a, b and c outside the invention were prepared using the weight proportions detailed in Table 2 below.

[0658] The values ​​are expressed as weight percent relative to the total weight of the scented composition.

[0659] [Table 2]

[0660]

[0661] (*) Fragrance A, characterized by:

[0662] Top notes: orange peel (bergamot, orange, lemon) (cologne effect), fragrance (sage, basil, rosemary, lavender), fruity (cucumber, melon); middle notes: floral (geranium, dihydrojasmonate, DHM); base notes: marine fragrance (ambergris, watermelon ketone), woody (cedar), musk (galaxolide);

[0663] Fragrance B, characterized by:

[0664] Top notes: orange peel (bergamot), spicy (ginger), green fruit (apple); middle notes: floral (lily, carnation, freesia, violet), aromatic (tea); base notes: musk (galaxolide), wet wood (oakmoss, patchouli), wood (sandalwood);

[0665] Fragrance C, characterized by:

[0666] Top notes: green fruity notes (apple, pear), green notes (lawn), orange peel notes (bergamot); middle notes: floral notes (magnolia, rose, jasmine, orange blossom), tea (Earl Grey tea); base notes: food notes (vanilla, caramel, pyrazine, popcorn), woody notes (patchouli, cedar), musk (galaxolide).

[0667] (**) Test A and Control a: Mixture of Blue 1 and Red 33; Test C and Control c: Ext. Violet 2

[0668] (***) Test C and Control C: Mixture of Yellow 5 and Red 33

[0669] In all tests described in the section Measurement and evaluation methods, Tests A and B were on average more stable olfactorily and in terms of color than the comparative tests a and b, respectively, which did not contain butyl methoxydibenzoylmethane and dilauryl thiodipropionate.

[0670] Furthermore, composition C according to the invention is at least as stable olfactorily and in terms of color, in fact even more stable, than composition c comprising ethylhexyl salicylate in combination with butyl methoxydibenzoylmethane and pentaerythritol tetra-di-tert-butyl hydroxyhydrocinnamate.

[0671] Example 2

[0672] Preparation of flavoring compositions

[0673] Different scented compositions D, E, F and G according to the invention and scented compositions d, e, f and g outside the invention were prepared using the weight proportions detailed in Table 3 below.

[0674] The values ​​are expressed as weight percent relative to the total weight of the scented composition.

[0675] [Table 3]

[0676]

[0677]

[0678] (*) Flavor D, characterized by:

[0679] Top notes: orange peel (bergamot, citron), spicy (pink pepper), aromatic (mint); middle notes: fruity (watermelon, melon, peach), floral (peony, jasmine); base notes: woody (cedar), amber (labdanum), musk (galaxolide);

[0680] Fragrance E, characterized by:

[0681] Top notes: orange peel (bergamot, orange, tangerine), green notes (white rosin), fruity notes (pear, apple); middle notes: floral notes (lily of the valley, peony, hyacinth, rose), fruity notes (pineapple, strawberry); base notes: food notes (vanilla, cocoa, caramel), woody notes (cedar), musk (galaxol);

[0682] Fragrance F, characterized by:

[0683] Top notes: orange peel (bergamot, lemon, grapefruit), fragrance (DHM, lavender, thyme, rosemary), ozone (ocean, iodine); middle notes: floral (methyl dihydrojasmonate, geranium); base notes: woody (cedar, cashmeran), musk (galaxolide);

[0684] Fragrance G, characterized by:

[0685] Top notes: orange peel (sweet orange, tangerine, bergamot); middle notes: floral (jasmine, orange blossom), fruity (pear, black currant); base notes: food aroma (vanilla, roasted coffee), woody (cedar, patchouli), musk (galaxolide).

[0686] (**) Test F and Control f: Ext. Violet 2; Test G and Control g: Mixture of Yellow 6 and Red 4

[0687] (***) Test D and control d: a mixture of Green 5 and Red 33; Test E and control e: a mixture of Yellow 5, Red 4 and Red 33; Test F and control f: a mixture of Orange 4, Red 4 and Blue 1

[0688] In all the tests described in the section Measurement and Evaluation Methods, composition D according to the invention was on average at least as olfactorily stable, in fact even more olfactorily stable, than composition d comprising ethylhexyl salicylate in combination with butyl methoxydibenzoylmethane.

[0689] In all the tests described in the section Measurement and Evaluation Methods, composition E according to the invention was on average at least as olfactory stable, in fact even more olfactory stable, than composition E comprising ethylhexyl salicylate and tris(tetramethylhydroxypiperidinol) citrate in combination with butyl methoxydibenzoylmethane.

[0690] As for composition F according to the invention, in all the tests described in the section on measurement and evaluation methods, it was on average at least as olfactory stable, in fact even more olfactory stable, than composition F comprising ethylhexyl salicylate, tris(tetramethylhydroxypiperidinol) citrate and diethylaminohydroxybenzoyl hexyl benzoate in combination with butyl methoxydibenzoylmethane.

[0691] In all tests described in the section Measurement and Evaluation Methods, Test G was on average more olfactory stable than the comparative Test G without dilauryl thiodipropionate.

[0692] Example 3

[0693] Preparation of flavoring compositions

[0694] Different scented compositions H and H' according to the invention and scented compositions h and h' outside the invention were prepared using the weight proportions detailed in Table 4 below.

[0695] The values ​​are expressed as weight percent relative to the total weight of the scented composition.

[0696] [Table 4]

[0697]

[0698] (*) Fragrance H, characterized by:

[0699] Top notes: orange peel (bergamot, sweet orange), spicy notes (pink pepper, nutmeg), green fruity notes (pear); middle notes: red fruity notes (cherry, raspberry, blackberry, red currant), rose scent (rose, peony), violet floral scent (ionone), jasmine scent (jasmine); base notes: balsam (vanilla, benzoin), coumarin (tonka bean), woody notes (sandalwood).

[0700] In all tests described in the section Measurement and Evaluation Methods, Tests H and H' were on average more olfactory stable than the comparative Tests h and h', respectively, comprising benzotriazolyl dodecyl-p-cresol and tris(tetramethylhydroxypiperidinol) citrate in combination with butyl methoxydibenzoylmethane.

[0701] Furthermore, in all the tests described in the section on measurement and evaluation methods, the composition H′ according to the invention additionally comprising α-tocopherol was on average more olfactorily stable than the composition H according to the invention without α-tocopherol.

[0702] Example 4

[0703] Preparation of flavoring compositions

[0704] Different scented compositions 1 to 6 according to the invention and scented compositions 7 and 8 outside the invention were prepared using the weight proportions detailed in Table 5 below.

[0705] The values ​​are expressed as weight percent relative to the total weight of the scented composition.

[0706] [Table 5]

[0707]

[0708] (*) Flavor I, characterized by:

[0709] Top notes: fruity (black currant, pear), orange peel (bergamot, orange); middle notes: powdery (iris, ionone), white flowers (jasmine, orange blossom); base notes: food notes (sugar almond, vanilla, tonka bean), woody (patchouli).

[0710] As described in detail in the section Measurement and Evaluation Methods, the compositions of Tests 1 to 8 were poured into 50 ml jars made of borosilicate glass and subsequently evaluated after storage for 2 months at atmospheric pressure and under condition e).

[0711] The olfactory evaluation was performed by a panel of 7 assessors by comparison with a composition having a composition stored at 4°C. The odor was graded from 0 to 10, with a rating of 10 being given for an odor identical to that of the composition stored at 4°C. Thus, a higher rating is associated with a better olfactory stability. The average values ​​obtained are given in Table 6.

[0712] [Table 6]

[0713]

[0714] The olfactory stability of compositions 1 to 6 according to the invention is improved compared to control tests 7 and 8, which do not contain dilauryl thiodipropionate and butyl methoxydibenzoylmethane, respectively. In addition, excellent olfactory stability is obtained for the compositions according to the invention, especially for the compositions of tests 5 and 6.

Claims

1. A fragrance-enhancing composition, in particular a cosmetic composition, comprising: a) at least one sulfur-containing antioxidant compound selected from the compounds of the following formula (I) and / or (II), and their optical and geometric isomers, salts and solvates, such as hydrates: (I)R1-S-R2 (II)R1-SS-R2 Wherein formula (I) and (II): R1 and R2, which are the same or different, represent a linear or branched (C1-C 24 ) alkyl group, linear or branched (C2-C 18 )alkenyl group, (C5-C 12 ) a cycloalkyl group, a phenylalkyl group having 7 to 15 carbon atoms or a phenyl group, The alkyl groups and / or the alkenyl groups are optionally substituted by one or more groups selected from -OH, -OC(O)-R3, -C(O)-O-R3, -C(O)-R3, -OR'3 and -NH2 groups, in particular -OH, -OR'3 and -NH2 groups, and / or The alkyl group and / or the alkenyl group are optionally interrupted by one or more groups selected from heteroatoms such as -O-, or -N(H)-, -OC(O)-, -C(O)-O-, -C(O)- and -NR'3- groups, The phenyl group and / or the phenylalkyl group, such as benzyl, is optionally substituted on the phenyl group with 1 to 3 straight or branched (C1-C 10 ) substituted with an alkyl group, Wherein R3 independently represents a hydrogen atom, a linear or branched (C1-C 18 ) alkyl group, (C5-C 12 )cycloalkyl group, linear or branched (C3-C8)alkenyl group, (C6-C 14 ) aryl group or (C7-C 15 ) an aralkyl group, and R'3 represents a straight chain or branched chain (C1-C 18 ) alkyl group; b) at least one organic UV screening agent selected from dibenzoylmethane derivatives; and c) at least one aromatizing substance.

2. The composition according to the preceding claim, wherein the sulfur-containing antioxidant compound a) is selected from thiodipropionic acid, dithiodipropionic acid, thiodipropionic acid derivatives, dithiodipropionic acid derivatives and mixtures thereof, in particular diesters of thiodipropionic acid, diesters of dithiodipropionic acid and mixtures thereof.

3. A composition according to claim 1 or 2, comprising at least one sulfur-containing antioxidant compound a) selected from dilauryl thiodipropionate, distearyl thiodipropionate, dilauryl dithiodipropionate, distearyl dithiodipropionate and mixtures thereof, preferably dilauryl thiodipropionate, distearyl thiodipropionate and mixtures thereof, and most preferably comprising at least dilauryl thiodipropionate.

4. A composition according to any one of the preceding claims, comprising from 0.01% to 5% by weight, in particular from 0.03% to 2% by weight, especially from 0.05% to 1% by weight, preferably from 0.07% to 0.5% by weight, more preferably from 0.08% to 0.1% by weight, relative to the total weight of the aromatized composition, of a sulfur-containing antioxidant compound a), in particular dilauryl thiodipropionate.

5. A composition according to any one of the preceding claims, comprising at least one organic UV screening agent b) selected from butyl methoxydibenzoylmethane, also known as tert-butyl methoxydibenzoylmethane, isopropyl dibenzoylmethane and mixtures thereof, preferably comprising at least butyl methoxydibenzoylmethane.

6. Composition according to any of the preceding claims, comprising from 0.01% to 5% by weight, in particular from 0.05% to 2% by weight, especially from 0.1% to 1% by weight, preferably from 0.2% to 0.5% by weight, more preferably from 0.25% to 0.35% by weight, relative to the total weight of the perfumed composition, of an organic UV-screening agent b) chosen from dibenzoylmethane derivatives, in particular butyl methoxydibenzoylmethane.

7. A flavoured composition according to any one of the preceding claims, wherein the flavouring substance c) is chosen from essential oils, essences and aromas of synthetic or natural origin, and mixtures thereof.

8. Composition according to any one of the preceding claims, comprising at least 0.5% by weight, in particular at least 1% by weight, more particularly from 1% to 35% by weight, preferably from 5% to 30% by weight, more preferably from 10% to 25% by weight, of aromatizing substances c) relative to the total weight of the aromatized composition.

9. Composition according to any of the preceding claims, additionally comprising one or more antioxidants different from the compound of formula (I) or (II), in particular chosen from tocopherol and tocopherol esters, in particular tocopherol acetate.

10. A composition according to any one of the preceding claims which is aqueous, alcoholic or aqueous / alcoholic, in particular aqueous / alcoholic.

11. Composition according to any one of the preceding claims, comprising at least 50% by weight, in particular from 60% to 95% by weight, more particularly from 70% to 90% by weight, of one or more solvents chosen from water, alcohols and mixtures thereof, relative to the total weight of the flavoring composition.

12. A composition according to any one of the preceding claims, comprising at least one colorant, in particular chosen from organic pigments, in particular from carbon black, pigments of the D&C type and lakes of cochineal based on barium, strontium, calcium and aluminium, preferably pigments of the D&C type, and synthetic or natural water-soluble dyes, more preferably chosen from synthetic or natural water-soluble dyes, in particular FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 3, DC Green 5, FDC Blue 1 and mixtures thereof, even more preferably chosen from FDC Red 4, DC Red 33, DC Orange 4, DC Yellow 5, DC Green 3, DC Green 5 and FDC Blue 1 and mixtures thereof.

13. Process for the cosmetic treatment of keratin materials, in particular the skin or clothing, comprising at least one stage of applying to said keratin materials and / or clothing a perfumed composition as defined in any one of the preceding claims.

14. Use of at least one sulfur-containing antioxidant compound selected from the group consisting of compounds of the following formulae (I) and / or (II), and their optical and geometric isomers, salts and solvates, such as hydrates, as a stabilizer in, in particular, aqueous or aqueous / alcoholic, aromatizing compositions, in particular cosmetic aromatizing compositions, which additionally comprise at least one organic UV-screening agent selected from the group consisting of dibenzoylmethane derivatives and at least one aromatizing substance: (I)R1-S-R2 (II)R1-SS-R2 Wherein formula (I) and (II): R1 and R2, which are the same or different, represent a linear or branched (C1-C 24 ) alkyl group, linear or branched (C2-C 18 )alkenyl group, (C5-C 12 ) a cycloalkyl group, a phenylalkyl group having 7 to 15 carbon atoms or a phenyl group, The alkyl groups and / or the alkenyl groups are optionally substituted by one or more groups selected from -OH, -OC(O)-R3, -C(O)-O-R3, -C(O)-R3, -OR'3 and -NH2 groups, in particular -OH, -OR'3 and -NH2 groups, and / or The alkyl group and / or the alkenyl group are optionally interrupted by one or more groups selected from heteroatoms such as -O-, or -N(H)-, -OC(O)-, -C(O)-O-, -C(O)- or -NR'3- groups, The phenyl group and / or the phenylalkyl group, such as benzyl, is optionally substituted on the phenyl group with 1 to 3 straight or branched (C1-C 10 ) substituted with an alkyl group, Wherein R3 independently represents a hydrogen atom, a linear or branched (C1-C 18 ) alkyl group, (C5-C 12 )cycloalkyl group, linear or branched (C3-C8)alkenyl group, (C6-C 14 ) aryl group or (C7-C 15 ) an aralkyl group, and R'3 represents a straight chain or branched chain (C1-C 18 )alkyl group.

15. The use according to the preceding claims, the sulfur-containing antioxidant compound as defined in claim 2 or 3, and / or the organic UV-screening agent as defined in claim 5, in particular using the sulfur-containing antioxidant compound, the organic UV-screening agent and the aromatizing substance in the form of a composition according to any one of claims 1 to 12.

16. The composition according to any one of claims 1 to 12, wherein the composition comprises less than 0.2 wt.-%, in particular less than 0.1 wt.-%, preferably less than 0.05 wt.-% and more preferably less than 0.01 wt.-% of butylated hydroxytoluene (BHT), relative to the total weight of the composition, preferably wherein the composition is free of butylated hydroxytoluene (BHT).

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