Purifier equipment and method for converting adsorbed chlorine into hydrogen chloride-containing water liquid

Abstract

The invention relates to the technical field of water purification equipment, and discloses purifier equipment and a method for converting adsorbed chlorine into hydrogen chloride-containing water liquid, and the purification method for converting adsorbed chlorine into hydrogen chloride-containing water liquid comprises the following steps: externally connected municipal tap water or ground surface purified water or underground purified water is input into a pre-treatment box through an A valve input pipe, and the water quality is filtered; an external chlorine generator is introduced into a chlorine detection regulator through a valve C, the chlorine detection regulator is introduced into a chlorine pipe to enter the reaction box, water is disinfected through chlorine, chlorine and water react to generate hydrochloric acid and hypochlorous acid, and the hydrochloric acid and hypochlorous acid enter a high-adsorption chlorine integrated cavity to be deeply filtered; a valve D is arranged at the side end of the high-adsorption chlorine integrated cavity and is connected to external hydrogen production equipment, the filtered water enters a temperature-controlled photosynthesis device, hypochlorous acid is decomposed by the temperature-controlled photosynthesis device to form stable water containing hydrochloric acid, and the stable water enters a pressure regulation storage tank through a detection monitor. The purification purity of drinking water containing hydrogen chloride is effectively improved.

Description

Technical Field

[0001] The present invention relates to the technical field of water purification equipment, and more specifically, to a purifier device and a method for converting hydrogen chloride-containing water liquid by adsorbing chlorine. Background Art

[0002] Water purification equipment is a device used to improve water quality. Its main function is to remove pollutants, impurities and harmful substances in tap water, thereby providing safe and clean drinking water. With the acceleration of industrialization and the development of urbanization, water pollution problems are becoming increasingly serious, the demand for safe drinking water is increasing, and the demand for water purification equipment is increasing.

[0003] Since drinking water needs to be disinfected and sterilized by adding chlorine, according to the provisions of GB5749-85 of my country: "The residual chlorine in the water at the end of the pipe network should not be less than 0.05mg / L", a certain amount of residual chlorine is maintained at the end of the urban water pipe to control bacterial growth and prevent pollution. Residual chlorine can generate a certain amount of hydrogen chloride in the water. However, the water purification equipment for chlorine components that can generate hydrogen chloride water has not been reasonably developed. Most drinking water uses residual chlorine to control the water quality to achieve the antibacterial and sterilization effect of the terminal water. Due to the large surface of the pipe network, the residual chlorine content in a certain part is high or low, resulting in unstable water quality standards, resulting in poor sterilization effect on drinking water or excessive residual chlorine, affecting the normal drinking of drinking water. In particular, drinking water usually uses boiling water to eliminate residual chlorine, and the boiling water method will destroy the nutrients in the water and produce harmful substances such as nitrite. Summary of the invention

[0004] The invention discloses a purifier device and a method for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine, which solves the technical problems in the above-mentioned background technology.

[0005] The first aspect of the present invention discloses a purifier device for converting hydrogen chloride-containing aqueous solution into chlorine adsorption, comprising a frame, a reaction box is arranged in the frame, a chlorine supply component is arranged at the bottom of the reaction box, and a water inlet pipe and a water outlet pipe are respectively installed on the surface of the reaction box; A pre-treatment box is arranged on one side of the frame, and a backwash filter, a negative resistance scale inhibitor and an ultrafiltration membrane are installed in the pre-treatment box. An input pipe and a connecting pipe are installed on both sides of the pre-treatment box, and water is introduced into the water source through the input pipe. The connecting pipe is connected to the water inlet pipe; The reaction box is provided with a partition and an extrusion plate respectively, and the partition and the extrusion plate divide the reaction box into a disinfection chamber, a reaction chamber and a high-absorption chlorine integrated chamber. The disinfection chamber is provided with a mixing assembly, and the mixing assembly includes a motor installed on the surface of the reaction box, and the output end of the motor is fixedly connected to a rotating rod, one end of the rotating rod is penetrated in the disinfection chamber, and is movably connected to a mixing piece. The partition is connected to the reaction box through a clutch assembly, and the clutch assembly is used to connect or separate the disinfection chamber and the reaction chamber; A filter assembly is arranged in the high-absorption chlorine integrated cavity, and the filter assembly includes a plurality of activated carbon filter elements arranged on a side of an extrusion plate close to the high-absorption chlorine integrated cavity, and a through hole adapted to the inner cavity of the activated carbon filter element is opened on the surface of the extrusion plate, and the extrusion plate is connected to the reaction box through a cylinder. When the cylinder is output, the extrusion plate moves horizontally in the reaction box, and the volume of the reaction cavity is gradually reduced, while the volume of the high-absorption chlorine integrated cavity is gradually increased; A plurality of temperature-controlled photosynthesizers are arranged in the reaction chamber. The temperature-controlled photosynthesizers are arranged as temperature-controlled tubes or light-illumination tubes. The temperature-controlled photosynthesizers release oxygen from water through temperature control or photosynthesis, thereby more effectively decomposing HCLO in the water liquid. The temperature-controlled photosynthesizers are connected to the reaction box through a vertical plate. The pressure regulating storage tank is arranged on a side of the frame away from the pre-treatment box, the water outlet pipe is connected to the pressure regulating storage tank, a detection monitor is installed at the connection position between the water outlet pipe and the pressure regulating storage tank, and an output pipe is installed on one side of the pressure regulating storage tank, and a positive and negative pressure controller is installed in the pressure regulating storage tank near the output pipe.

[0006] Preferably, the mixing element comprises a movable ring, the movable ring is fixedly connected to the surface of the rotating rod, a plurality of connecting rods are fixedly connected to the surface of the movable ring, and blades are fixedly connected to the surface of the connecting rods.

[0007] Preferably, the mixing element includes a movable ring, a threaded groove is provided on the surface of the rotating rod, the movable ring is threadedly connected to the surface of the rotating rod, a plurality of connecting rods are fixedly connected to the surface of the movable ring, blades are hinged on the surface of the connecting rods, and a connecting ring is rotatably connected to the bottom of the movable ring, and the connecting ring is connected to the reaction box through a spring.

[0008] Preferably, one side of the partition passes through the reaction box and extends outside the reaction box, the clutch assembly includes a connecting block fixedly connected to the side of the partition outside the reaction box, an electric push rod is fixedly connected to the surface of the reaction box, and the output end of the electric push rod is fixedly connected to the connecting block.

[0009] Preferably, the side of the partition close to the reaction box is arc-shaped, and the arc is bent toward the disinfection chamber.

[0010] Preferably, two sealing doors are provided on the inner wall of the through hole connecting the extrusion plate with the inner cavity of the activated carbon filter element. The sealing door is connected to the extrusion plate through a rotating shaft. A torsion spring is provided in the rotating shaft. The two ends of the torsion spring are respectively connected to the rotating shaft and the extrusion plate. Several of the temperature-controlled photosynthesizers are adapted to several of the through holes.

[0011] Preferably, the inner cavity of the activated carbon filter element is provided with a plurality of air outlet pipes, one end of the air outlet pipes is fixedly connected to one side of the extrusion plate, a connecting pipe is fixedly connected to the side of the extrusion plate close to the reaction chamber, an air cavity is opened in the extrusion plate, the connecting pipe is connected to the air outlet pipe through the air cavity, and a plurality of air holes for gas to pass through are opened on the surface of the air outlet pipe.

[0012] Preferably, a hydrogenation pipe is fixedly connected to the surface of the activated carbon filter element, and a plurality of hydrogen delivery control valves are arranged on one side of the reaction box. The hydrogen delivery control valves are connected to external hydrogen supply equipment, and one end of the hydrogen delivery control valve located in the reaction box is connected to the hydrogenation pipe through a connecting hose.

[0013] Preferably, the chlorine supply component comprises a chlorine generator arranged at the bottom of the frame, the chlorine generator is connected to the reaction box through a chlorine inlet pipe, and a detection regulator is installed on the surface of the chlorine inlet pipe.

[0014] The second aspect of the present invention discloses a purification method for converting aqueous solution containing hydrogen chloride by adsorbing chlorine, comprising the following steps: S1, A valve connected to the external municipal tap water or surface water or underground water, a booster pump is arranged behind the A valve, a pre-backwash filter is arranged behind the booster pump, a negative layer alloy catalyst scale inhibitor is arranged behind the filter, an ultrafiltration membrane purifier is arranged behind the scale inhibitor, a control B valve is arranged behind the ultrafiltration membrane purifier, and a reaction box is connected behind the control B valve; S2, the C valve for introducing chlorine from the external salt electrolysis chlorine generator, the rear end of the C valve is provided with a detection regulator, a mixing device and a reaction box, the chlorine introduced by the C valve is mixed with the purified water introduced by the B valve to react, and the water is disinfected, so that the water and chlorine are fully converted and reacted to generate HCL and HCLO; S3, the chlorine-water mixture treated in step 2 is introduced into the high-adsorption chlorine cavity, and a D valve is provided at the side end of the high-adsorption chlorine integrated cavity to connect to an external hydrogen production device. The hydrogen input strengthens the reaction between hydrogen and chlorine to form the required pH value. The high-adsorption chlorine integrated device is mainly composed of high-adsorption activated carbon fiber ACF, supplemented by a PP cotton layer and medical stone. The BET specific surface area of ​​ACF is 1500-3000 (㎡ / g), and the adsorption of chlorine or residual chlorine reaches 60-97%. The residual chlorine in the water is adsorbed by the activated carbon fiber filter element for effective filtration conversion, and the residual chlorine is further eliminated; S4. The adsorbed chlorine component reaches a saturated concentration to form a special chlorine membrane (high-efficiency sterilization and disinfection). The chlorine ions / chlorine molecules overflowing from the chlorine membrane are prone to hydrolysis in water. Under the action of the temperature-controlled photosynthesizer, oxygen escapes to form a stable aqueous solution containing HCL. Then, the positive and negative pressure regulating storage tanks are connected. The parameters of the aqueous solution containing HCL are detected and controlled by the detection and monitoring regulator. A controllable display screen is installed on the surface of the detection and monitoring regulator to display parameters: water temperature, concentration, residual chlorine, pH value (adjustment gradient 6.9~0.9), TDS, etc., to ensure the safety and quality of the output purified aqueous solution containing HCL; S5. Output the aqueous solution containing HCL.

[0015] The beneficial effects of the present invention are: The present invention can press down the chlorine in the water by arranging a mixing piece, so as to avoid the problem that the chlorine that has not completely reacted floats on the surface of the water liquid, resulting in incomplete reaction between the chlorine and the water liquid, thereby improving the disinfection effect of the chlorine on the water liquid. Furthermore, by arranging a spring, the movable ring is pushed up, and the blades are rotated downward due to water resistance. At the same time, the movable ring rotates on the surface of the rotating rod with a threaded groove, so that the blades drive the water liquid to generate a rotating flow, which is convenient for the water liquid and the chlorine to be introduced into the reaction chamber for full conversion reaction to produce HCL and HCLO.

[0016] The present invention strengthens the conversion of HCLO by setting up a high-adsorption chlorine device with multiple components, separates and releases oxygen in the high-adsorption chlorine integrated chamber, and more effectively decomposes HCLO in the water liquid through the temperature-controlled photosynthetic oxygen escape to generate HCL and O 2 ↑ Reduce HCLO components and improve HCL purity. At the same time, the residual chlorine in the water is adsorbed by the activated carbon fiber filter element for effective filtration conversion, which better controls the purity of HCL in the water and obtains safe, high-quality and purer HCL-containing water. BRIEF DESCRIPTION OF THE DRAWINGS

[0017] Figure 1 It is a schematic diagram of the overall structure of the present invention; Figure 2 is a front cross-sectional view of the present invention; Figure 3 is a schematic diagram of another side view used to display the entire device of the present invention; Figure 4 It is a cross-sectional view of the present invention for showing the internal structure of the disinfection chamber; Figure 5 The present invention Figure 4 A in the enlarged view; Figure 6 This is a cross-sectional view of the present invention for showing the internal structure of the reaction chamber and the high-absorption chlorine integrated chamber; Figure 7 The present invention Figure 6 The enlarged view of point B in the figure; Figure 8 It is a schematic diagram of one state of the mixing element used to show the present invention; Fig. 9 It is a schematic diagram of another state of the mixing element used to show the present invention; Fig.10 It is a cross-sectional view of the present invention for showing the internal structure of the reaction box; Fig.11 It is a schematic diagram of the internal structure of one of the activated carbon filter elements of the present invention; Fig.12 It is a flow chart of the present invention.

[0018] In the figure: 1, frame; 11, chlorine generator; 12, detection regulator; 13, chlorine inlet pipe; 2, reaction box; 21, water inlet pipe; 212, water outlet pipe; 22, disinfection chamber; 221, motor; 222, rotating rod; 223, movable ring; 224, connecting rod; 225, blade; 226, connecting ring; 227, spring; 23, partition; 231, connecting block; 232, electric push rod; 24, reaction chamber; 241, vertical plate; 242, temperature-controlled photosynthesizer; 25, high-absorption chlorine integrated chamber; 26. Extrusion plate; 261. Activated carbon filter element; 262. Sealing door; 263. Rotating shaft; 264. Exhaust pipe; 265. Connecting pipe; 266. Air cavity; 27. Hydrogenation pipe; 271. Connecting hose; 272. Hydrogen transfer control valve; 28. Cylinder; 3. Pre-treatment box; 31. Backwash filter; 32. Negative resistance scale inhibitor; 33. Ultrafiltration membrane; 34. Input pipe; 35. Connecting pipe; 4. Pressure regulating storage tank; 41. Detection monitor; 42. Positive and negative pressure controller; 43. Output pipe. DETAILED DESCRIPTION

[0019] The subject matter described herein will now be discussed with reference to example implementations. It should be understood that the discussion of these implementations is only to enable those skilled in the art to better understand and implement the subject matter described herein, and the functions and arrangements of the elements discussed may be changed without departing from the scope of protection of the present specification. Various examples may omit, replace, or add various processes or components as needed. In addition, the features described in some examples may also be combined in other examples.

[0020] The embodiment of the present invention discloses a purifier device for converting hydrogen chloride-containing aqueous solution into adsorbed chlorine. Figure 1 and Figure 2As shown, it includes a frame 1, a reaction box 2 is arranged in the frame 1, a chlorine supply component is arranged at the bottom of the reaction box 2, a water inlet pipe 21 and a water outlet pipe 212 are respectively installed on the surface of the reaction box 2, the water inlet pipe 21 is connected to an external water source or a water source of a water plant, and the water outlet pipe 212 is connected to an external water source storage device, a pre-treatment box 3 is arranged on one side of the frame 1, a backwash filter 31, a negative resistance scale inhibitor 32 and an ultrafiltration membrane device 33 are respectively installed in the pre-treatment box 3, and an input pipe 34 and a connecting pipe 35 are respectively installed on both sides of the pre-treatment box 3, and the connecting pipe 35 is connected to the water inlet pipe 21.

[0021] The input pipe 34 is the entrance of the water supply source of the water purifier equipment. The input pipe 34 is used to connect to an external water source, such as municipal tap water, surface water or underground water, to provide water. A booster pump can be set at the mouth of the input pipe 34 to improve and stabilize the water pressure of the water purifier to maintain the operation of the equipment. The backwash filter 31 is used to filter impurities in the water to maintain the efficiency and life of the subsequent filter membrane; the negative resistance scale inhibitor 32, that is, the negative layer alloy catalyst scale inhibitor, generates free negative electrons conducted by the electric double-layer polar fluid medium under the action of water flow through the special alloy catalyst material to react with the salts with positrons, reduce crystal flocculation and adhesion, reduce scale formation, and promote the activity of the water body; the ultrafiltration membrane device 33, that is, the ultrafiltration membrane purifier, is equipped with an ultrafiltration core membrane to purify the water quality in a series structure component, and a positive pressure control valve can be set inside it to control the backflow of the mixed liquid in the reaction box 2 to continue filtering.

[0022] like Figure 4 and Figure 5 As shown, a partition 23 and an extrusion plate 26 are respectively provided in the reaction box 2, and the partition 23 and the extrusion plate 26 divide the reaction box 2 into a disinfection chamber 22, a reaction chamber 24 and a high-absorption chlorine integrated chamber 25, wherein the water inlet pipe 21 is connected to the inside of the disinfection chamber 22, and the water outlet pipe 212 is connected to the high-absorption chlorine integrated chamber 25, and a mixing component is provided in the disinfection chamber 22, and the mixing component includes a motor 221 installed on the surface of the reaction box 2, and a locking device is provided in the motor 221, which can be used to lock its output end, and a rotating rod 222 is fixedly connected to the output end of the motor 221, and one end of the rotating rod 222 is penetrated in the disinfection chamber 22, and the connection between the rotating rod 222 and the reaction box 2 is sealed to ensure the internal sealing effect of the reaction box 2, and a mixing piece is movably connected, and the partition 23 is connected to the reaction box 2 through a clutch assembly, and the clutch assembly is used to connect or separate the disinfection chamber 22 and the reaction chamber 24.

[0023] like Figure 6 and Figure 7As shown, in this embodiment, a filter assembly is included, which is arranged in the high-absorption chlorine integrated chamber 25. The filter assembly includes a plurality of activated carbon filter elements 261 arranged on the side of the extrusion plate 26 close to the high-absorption chlorine integrated chamber 25. The activated carbon filter element 261 is provided with a super-absorption activated carbon fiber filter element membrane. The activated carbon filter element 261 is a parallel structure assembly. The activated carbon filter element 261 is used to filter residual chlorine and other impurities in water. A through hole adapted to the inner cavity of the activated carbon filter element 261 is provided on the surface of the extrusion plate 26. The extrusion plate 26 is connected to the reaction box 2 through the cylinder 28. When the cylinder 28 is output, the extrusion plate 26 moves horizontally in the reaction box 2, and the volume of the reaction chamber 24 is gradually reduced accordingly, while the volume of the high-absorption chlorine integrated chamber 25 is gradually increased. It also includes a plurality of temperature-controlled photosynthesizers 242, which are arranged in the reaction chamber 24. The temperature-controlled photosynthesizers 242 are configured as temperature-controlled tubes or light-emitting tubes, wherein the temperature-controlled tubes are temperature heating control tubes for heating the water source, and the light-emitting tubes are light-emitting tubes for illuminating the water source. Through temperature control or the effect of oxygen escaped from photosynthesis, HCLO in the water liquid is more effectively decomposed to generate HCL and O2↑, thereby reducing the HCLO component and improving the purity of HCL, thereby obtaining safe, high-quality and purer HCL-containing water liquid. The temperature-controlled photosynthesizers 242 are connected to the reaction box 2 through the vertical plate 241, the vertical plate 241 is fixedly connected to the inner wall of the reaction box 2 near the reaction chamber 24, and the temperature-controlled photosynthesizers 242 are fixedly connected to the surface of the vertical plate 241.

[0024] Specifically, an external water source is introduced into the disinfection chamber 22 through the water inlet pipe 21, and chlorine is supplied to the water source through the chlorine supply component to disinfect the water. After the chlorine enters the water, the motor 221 drives the surface mixing element of the rotating rod 222 to mix and stir the chlorine and water, thereby improving the mixing efficiency of the chlorine and water and improving the disinfection and mixing efficiency. Subsequently, the partition 23 is driven to move in the reaction box 2 through the clutch component, thereby connecting the disinfection chamber 22 with the reaction chamber 24, and the water mixed with the chlorine in the disinfection chamber 22 enters the reaction chamber 24. The heating effect of the combiner 242 maintains the water at a certain temperature, thereby promoting the decomposition of hypochlorous acid in the water, and then generating hydrogen chloride and oxygen. After the oxygen is generated, it gathers at the top of the reaction chamber 24. Then, under the output of the cylinder 28, the extrusion plate 26 is pushed to move toward the reaction chamber 24. Under the action of the reaction force, the water in the reaction chamber 24 enters the activated carbon filter element 261 through the through hole and is filtered by the activated carbon filter element 261, so as to facilitate the effective filtration of the residual chlorine in the water, further reduce the impurities in the water, and improve the purity of the hydrogen chloride in the water.

[0025] The pressure regulating storage tank 4 is arranged on a side of the frame 1 away from the pre-treatment box 3. The water outlet pipe 212 is connected to the pressure regulating storage tank 4. A detection monitor 41 is installed at the connection position between the water outlet pipe 212 and the pressure regulating storage tank 4. A display screen can also be arranged on the surface of the pressure regulating storage tank 4. The display screen is electrically connected to the detection monitor 41. An output pipe 43 is installed on one side of the pressure regulating storage tank 4. A positive and negative pressure controller 42 is installed in the pressure regulating storage tank 4 near the output pipe 43.

[0026] The HCL liquid in the reaction box 2 is discharged into the pressure regulating storage tank 4 through the outlet pipe 212, and the liquid is detected by the detection monitor 41, which is used to detect the water temperature, concentration, residual chlorine, pH value adjustment gradient 6.9-0.9, TDS and other parameters of the liquid, and these parameters are displayed on the display screen, so as to intuitively understand the various indicators of the HCL liquid at this time, and the liquid is output through the positive and negative pressure controller 42, and the liquid is output from the output pipe 43 for subsequent processing.

[0027] like Figure 4 , Figure 5 and Figure 8 As shown, in this embodiment, the mixing element includes a movable ring 223, which is fixedly connected to the surface of the rotating rod 222, and a plurality of connecting rods 224 are fixedly connected to the surface of the movable ring 223, and blades 225 are fixedly connected to the surface of the connecting rods 224.

[0028] Specifically, the output of the motor 221 drives the rotating rod 222 and the movable ring 223 on its surface to rotate, and then drives the blade 225 to rotate around the rotating rod 222 through the connecting rod 224 to stir the water, thereby improving the mixed disinfection and sterilization efficiency of chlorine and water.

[0029] like Figure 4 , Figure 5 and Fig. 9 As shown, in a parallel embodiment, the mixing element includes a movable ring 223, a threaded groove is provided on the surface of the rotating rod 222, the movable ring 223 is threadedly connected to the surface of the rotating rod 222, a plurality of connecting rods 224 are fixedly connected to the surface of the movable ring 223, blades 225 are hinged on the surface of the connecting rod 224, and a stopper is provided on the surface of the connecting rod 224 so that the maximum height of the blade 225 can only be rotated to a state parallel to the bottom of the reaction box 2, and a connecting ring 226 is rotatably connected to the bottom of the movable ring 223, and the connecting ring 226 is connected to the reaction box 2 through a spring 227, and the two ends of the spring 227 are fixedly connected to the connecting ring 226 and the reaction box 2 respectively, and the spring 227 is set as a rigid spring that is not easy to twist, such as a carbon steel spring or a silicon manganese steel spring.

[0030] Specifically, different from the above-mentioned embodiment, the present embodiment adopts the method of threaded connection between the movable ring 223 and the rotating rod 222, so that when the motor 221 drives the rotating rod 222 to rotate, the movable ring 223 on the surface of the rotating rod 222 can move downward accordingly with the thread, so that the movable ring 223 drives the blade 225 to move downward to correspondingly pressurize the chlorine in the water. When the blade 225 moves downward, it will rotate upward due to the resistance of the water, thereby presenting the following Figure 7 In the state shown, the blade 225 is pressed downward to prolong the time that the chlorine is kept in the deep water, thereby further promoting the mixing reaction efficiency of the chlorine and the deep water, improving the uniformity of the reaction between water and chlorine in each depth area, and making the disinfection effect of chlorine in the water better. Furthermore, when the motor 221 drives the rotating rod 222 to rotate and the movable ring 223 moves downward with the thread, the connecting ring 226 moves downward accordingly, thereby compressing the spring 227. Since the spring 227 has a strong rigidity and is not easy to twist, the rotation of the connecting ring 226 can be effectively avoided. After the blade 225 is pressed down to a certain extent and the chlorine reaction is saturated, the motor 221 stops outputting and locks the rotating rod 222 through the locking device. At this time, under the action of the rebound force of the spring 227, the connecting ring 226 and the movable ring 223 are pushed upward to move the blade 225 upward. During the upward movement, the blade 225 is subjected to the resistance of the water and rotates downward, forming a Figure 8 In the impeller state shown, at this time, as the movable ring 223 moves up on the surface of the rotating rod 222, the movable ring 223 is synchronously driven to rotate by the action of the thread groove, thereby stirring the water source in the disinfection chamber 22, so that the water source is driven by the blades 225 to form a rotating flow. At this time, the partition 23 is opened by the clutch component, and the water source forming the rotating flow enters the reaction chamber 24 through the gap opened by the partition 23 through the diversion effect, and the partition 23 is closed in time by the clutch component to avoid the backflow of the water liquid, so as to achieve uniform mixing and transfer of chlorine gas and water liquid.

[0031] like Figure 4 As shown, in this embodiment, one side of the partition 23 passes through the reaction box 2, and the connection between the partition 23 and the reaction box 2 is sealed, coated with sealant or provided with a sealing strip, and extends outside the reaction box 2, and the clutch assembly includes a connecting block 231 fixedly connected to the side of the partition 23 outside the reaction box 2, and an electric push rod 232 is fixedly connected to the surface of the reaction box 2, and the output end of the electric push rod 232 is fixedly connected to the connecting block 231. Through the output of the electric push rod 232, the connecting block 231 can be driven to push the partition 23 to move in the reaction box 2, so that the partition 23 can separate or connect the disinfection chamber 22 with the reaction chamber 24.

[0032] Furthermore, the side of the partition 23 close to the reaction box 2 is arc-shaped, and the arc is bent toward the disinfection chamber 22. The arc-shaped partition 23 is used to guide the water, reduce turbulence in the rotating flow process, and improve the stability of the water in the process of guiding it into the reaction chamber 24.

[0033] like Fig.10 and Fig.11 As shown, in this embodiment, two sealing doors 262 are provided on the inner wall of the through hole connecting the extrusion plate 26 and the inner cavity of the activated carbon filter element 261. The sealing doors 262 are arranged in pairs, and sealing strips are provided at the contact positions between the sealing doors 262 and the inner wall of the through hole. Sealing strips are also provided on the opposite sides of the two sealing doors 262 to ensure the sealing effect on both sides of the reaction chamber 24 and the activated carbon filter element 261 when the two openings are closed. The sealing door 262 is connected to the extrusion plate 26 through a rotating shaft 263. The rotating shaft 263 is fixedly connected to the surface of the sealing door 262, and the rotating shaft 263 is rotatably connected to the inner wall of the through hole for rotating and opening and closing the sealing door 262. A torsion spring is provided in the rotating shaft 263, and the two ends of the torsion spring are respectively connected to the rotating shaft 263 and the extrusion plate 26. When the torsion spring is in a relaxed state, the two sealing doors 262 are in a state of relatively fitting and closing the through hole, and a plurality of temperature-controlled photosynthesizers 242 are adapted to the plurality of through holes.

[0034] Specifically, in the process of pushing the extrusion plate 26 toward the side of the reaction chamber 24 through the output of the cylinder 28, the squeezed water will reversely squeeze the sealing door 262 in the through hole, thereby causing the sealing door 262 to rotate relatively and open, so that the water in the reaction chamber 24 can enter the activated carbon filter element 261, and then pass through the activated carbon filter element 261 under pressure for filtration. In addition, when the water gradually reduces the pressure on the sealing door 262, since the temperature-controlled photosynthesizer 242 is adapted to the through hole, the temperature-controlled photosynthesizer 242 will be relatively inserted into the through hole, thereby propping up the sealing door 262 and keeping the sealing door 262 open.

[0035] Further, such as Figure 7 and Fig.11 As shown, in this embodiment, the inner cavity of the activated carbon filter element 261 is provided with a plurality of air outlet pipes 264, one end of the air outlet pipe 264 is fixedly connected to one side of the extrusion plate 26, and a connecting pipe 265 is fixedly connected to the side of the extrusion plate 26 close to the reaction chamber 24. The connecting pipe 265 is arranged at an upper position on the surface of the extrusion plate 26 to prevent water from mixing into the interior thereof. An air cavity 266 is provided in the extrusion plate 26, and the connecting pipe 265 is connected to the air outlet pipe 264 via the air cavity 266. The air cavity 266 is connected to the connecting pipe 265 and the inside of the air outlet pipe 264 respectively, and a plurality of air holes for gas to pass through are provided on the surface of the air outlet pipe 264.

[0036] A hydrogenation pipe 27 is fixedly connected to the surface of the activated carbon filter element 261. A plurality of hydrogen supply control valves 272 are arranged on one side of the reaction box 2. The hydrogen supply control valves 272 are connected to an external hydrogen supply device. One end of the hydrogen supply control valve 272 located in the reaction box 2 is connected to the hydrogenation pipe 27 through a connecting hose 271. The connecting hose 271 can maintain the delivery of hydrogen during the movement of the activated carbon filter element 261.

[0037] Specifically, through the setting of the outlet pipe 264, in the reaction chamber 24, the hypochlorous acid in the water is decomposed by controlling a certain temperature through the temperature-controlled photosynthesizer 242, and the oxygen in the decomposition product will float to the top of the reaction chamber 24. When the reaction chamber 24 is squeezed by the squeezing plate 26, the oxygen in the reaction chamber 24 will enter the air cavity 266 along the connecting pipe 265, and then enter the outlet pipe 264 through the air cavity 266, and be discharged into the water along the air holes. Then, the external hydrogen is passed into the activated carbon filter element 261 through the hydrogenation pipe 27 in conjunction with the hydrogen supply control valve 272 for mixed reaction, generating water and activating water molecules, further improving the reaction rate of the by-products, and controlling the purity of hydrogen chloride in the water. This step is completed before filtering. After controlling the purity of hydrogen chloride, the water is filtered to further filter the residual chlorine and improve the filtering stability of the water.

[0038] The chlorine supply component includes a chlorine generator 11 arranged at the bottom of the frame 1. The chlorine generator 11 is used to store chlorine. The chlorine generator 11 is connected to the reaction box 2 through a chlorine inlet pipe 13. A detection regulator 12 is installed on the surface of the chlorine inlet pipe 13. The detection regulator 12 is used to detect key factors such as the concentration and content of chlorine generated in the chlorine generator 11, and can control the chlorine intake and concentration. A valve is arranged in the detection regulator 12. By opening and closing the valve, the chlorine in the chlorine generator 11 can be passed into the disinfection chamber 22 through the chlorine inlet pipe 13.

[0039] Working principle: S1; External municipal tap water or surface clean water or underground clean water is input into the pre-treatment box through the input pipe 34. A booster pump can be set at the input pipe 34. The booster pump pressurizes the water and then filters it through the backwash filter 31. The water filtered by the filter enters the negative resistance scale inhibitor 32 for scale inhibition. An ultrafiltration membrane device 33 is set behind the negative resistance scale inhibitor 32 for further filtering the water. After passing through the ultrafiltration membrane device 33, it passes through the connecting pipe 35 and is connected to the water inlet pipe 21 to enter the reaction box 2. The external chlorine generator 11 introduces chlorine into the chlorine inlet pipe 13. The detection regulator 12 is set on the surface of the chlorine inlet pipe 13 to detect and control the chlorine content concentration, etc. The chlorine passes The chlorine inlet pipe 13 is connected to the reaction box 2, and the water is disinfected by chlorine. At the same time, the reaction products of chlorine and water generate hydrochloric acid and hypochlorous acid. The motor 221 drives the rotating rod 222 to rotate, driving the mixing piece on the surface of the rotating rod 222 to press down, and press down the chlorine that is lighter and has not reacted completely, and compress the spring 227. After the mixing piece moves down to a certain depth, the motor 221 locks the rotating rod 222. Under the action of the rebound force of the spring 227, the mixing piece is pushed up, and the blade 225 rotates downward on the surface of the connecting rod 224. During the upward movement, the movable ring 223 rotates on the surface of the rotating rod 222 with a threaded groove, and the rotation of the blade 225 causes the water to generate a rotating flow.

[0040] The clutch assembly cooperates to open the partition 23, so that the disinfection chamber 22 is connected with the reaction chamber 24. At this time, the water driven by the blade 225 to generate a rotating flow is guided into the reaction chamber 24, and the partition 23 is closed in time to prevent the water from flowing back. Then the water inlet pipe 21 repeats the water inlet disinfection operation again, and the water source mixed with chlorine entering the reaction chamber 24 is controlled to react at a certain temperature by the temperature-controlled photosynthetic device 242. Hypochlorous acid only exists in the solution, is unstable, and is easy to decompose and release oxygen. When the chlorine water is exposed to sunlight or a certain temperature, the hypochlorous acid will accelerate the decomposition to form hydrogen chloride liquid and oxygen. After the hypochlorous acid reaction is completed, it is passed through the cylinder 28. Output, push the extrusion plate 26 to move toward the direction of the reaction chamber 24, and then correspondingly squeeze the water in the reaction chamber 24, so that the water in the reaction chamber 24 enters the activated carbon filter element 261 through the through hole for filtration. The activated carbon filter element 261 is mainly composed of high-adsorption activated carbon fiber ACF. The BET specific surface area of ​​ACF is 1500-3000㎡ / g, and the adsorption of chlorine gas or residual chlorine reaches more than 95-99%. The adsorbed chlorine component reaches a saturated concentration to form a special chlorine mesh membrane for efficient sterilization and disinfection. The chlorine ions / chlorine molecules overflowing from the chlorine mesh membrane are easy to react with hydrolysis and release oxygen in temperature-controlled photosynthesis to form a stable water containing HCL. Among them, after passing through the activated carbon filter element 261, the residual chlorine in the water is filtered to further improve the filtering effect of chlorine. In the process of squeezing the water by the squeezing plate 26, the excess oxygen generated by the above-mentioned step S4 enters the air cavity 266 through the connecting pipe, and enters the outlet pipe 264, and is discharged through the pores. At this time, hydrogen is introduced through the hydrogen delivery control valve 272, and the hydrogen delivery control valve 272 is connected to the external hydrogen delivery equipment. The hydrogen enters the activated carbon filter element 261 through the hydrogenation pipe 27, reacts with the oxygen discharged from the pores, generates water and activates water molecules, and further controls the purity of hydrogen chloride in the water to achieve the required conditions of controllable pH value. The hydrogen chloride aqueous solution filtered by the activated carbon filter element 261 is then discharged through the outlet pipe 212, the end of the outlet pipe 212 is connected to the pressure regulating storage tank 4, and the pressure regulating storage tank 4 is provided with a detection monitor 41, the detection monitor 41 is used to detect water temperature, concentration, residual chlorine, pH value adjustment gradient 6.9-0.9, TDS, etc. A controllable display screen can be installed on the surface of the pressure regulating storage tank 4, connected to the detection monitor 41, for displaying parameters, and then the HCL aqueous solution controls the output water pressure through the positive and negative pressure controller 42, and is output through the output pipe 43 to ensure the safety and quality of the output purified HCL-containing aqueous solution.

[0041] This embodiment also discloses a purification method for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine, comprising the following steps: S1, A valve connected to the external municipal tap water or surface water or underground water, a booster pump is arranged behind the A valve, a pre-backwash filter is arranged behind the booster pump, a negative layer alloy catalyst scale inhibitor is arranged behind the filter, an ultrafiltration membrane purifier is arranged behind the scale inhibitor, a control B valve is arranged behind the ultrafiltration membrane purifier, and a reaction box is connected behind the control B valve; S2, the C valve for introducing chlorine from an external salt electrolysis chlorine generator, the rear end of the C valve is provided with a detection regulator, a mixing device and a reaction box, and the C valve for introducing the external salt electrolysis chlorine is the entrance for the water purifier equipment to input chlorine into the detection regulator; the detection regulator controls the chlorine intake and concentration, the chlorine introduced by the C valve is mixed with the purified water introduced by the B valve for reaction, and the water is disinfected, so that the water and chlorine are fully converted and reacted to generate HCL and HCLO; S3, the chlorine-water mixture treated in step 2 is introduced into the high-adsorption chlorine cavity, and a D valve is provided at the side end of the high-adsorption chlorine integrated cavity to connect to an external hydrogen production device. The hydrogen input strengthens the reaction between hydrogen and chlorine to form the required pH value. The high-adsorption chlorine integrated device is mainly composed of high-adsorption activated carbon fiber ACF, supplemented by a PP cotton layer and medical stone. The BET specific surface area of ​​ACF is 1500-3000 (㎡ / g), and the adsorption of chlorine or residual chlorine reaches 60-97%. The residual chlorine in the water is adsorbed by the activated carbon fiber filter element for effective filtration conversion, and the residual chlorine is further eliminated; S4. The adsorbed chlorine component reaches a saturated concentration to form a special chlorine membrane (high-efficiency sterilization and disinfection). The chlorine ions / chlorine molecules overflowing from the chlorine membrane are prone to hydrolysis in water. Under the action of the temperature-controlled photosynthesizer, oxygen escapes to form a stable aqueous solution containing HCL. Then, the positive and negative pressure regulating storage tanks are connected. The parameters of the aqueous solution containing HCL are detected and controlled by the detection and monitoring regulator. A controllable display screen is installed on the surface of the detection and monitoring regulator to display parameters: water temperature, concentration, residual chlorine, pH value (adjustment gradient 6.9~0.9), TDS, etc., to ensure the safety and quality of the output purified aqueous solution containing HCL; S5. Output the aqueous solution containing HCL.

[0042] The invention effectively improves the pH value gradient of purified drinking water containing HCL water to 6.9-0.9, is safe, non-toxic and has no side effects. The HCL component is the main component of human gastric acid with a pH value of 0.9-1.5, can effectively promote food digestion, resist microbial infection, dissolve and separate calcified scale in the body, ensure the smooth flow of human pipes, protect the mucous membrane of human pipes, and can convert solid scale into liquid calcium chloride soluble in water and blood, thereby supplementing and improving human calcium.

[0043] The above describes an embodiment of the present invention, but this embodiment is not limited to the above-mentioned specific implementation mode. The above-mentioned specific implementation mode is merely illustrative and not restrictive. Under the guidance of this embodiment, ordinary technicians in this field can also make more forms of equivalent embodiments, all of which are within the protection of this embodiment.

[0044] The prior art of the patent of this invention is mature and can be fully implemented by combining various materials, instruments, equipment, etc. in a conventional manner. It meets social needs and is practical and easy to promote.

Claims

1. A purifier device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine, characterized in that: include: A frame (1), wherein a reaction box (2) is arranged inside the frame (1), a chlorine supply component is arranged at the bottom of the reaction box (2), and a water inlet pipe (21) and a water outlet pipe (212) are respectively installed on the surface of the reaction box (2); A pre-treatment box (3) is arranged on one side of the frame (1), and a backwash filter (31), a negative resistance scale inhibitor (32) and an ultrafiltration membrane (33) are installed in the pre-treatment box (3). An input pipe (34) and a connecting pipe (35) are installed on both sides of the pre-treatment box (3), and water is introduced through the input pipe (34). The connecting pipe (35) is connected to the water inlet pipe (21); The reaction box (2) is provided with a partition (23) and an extrusion plate (26), respectively, the partition (23) and the extrusion plate (26) dividing the reaction box (2) into a disinfection chamber (22), a reaction chamber (24) and a high-absorption chlorine integrated chamber (25); the disinfection chamber (22) is provided with a mixing assembly, the mixing assembly comprising a motor (221) mounted on the surface of the reaction box (2); the output end of the motor (221) is fixedly connected to a rotating rod (222); one end of the rotating rod (222) is passed through the disinfection chamber (22) and is movably connected to a mixing element; the partition (23) is connected to the reaction box (2) via a clutch assembly, the clutch assembly is used to connect or separate the disinfection chamber (22) and the reaction chamber (24); A filter assembly is arranged in the high-absorption chlorine integrated chamber (25), the filter assembly comprising a plurality of activated carbon filter elements (261) arranged on a side of an extrusion plate (26) close to the high-absorption chlorine integrated chamber (25), a through hole adapted to the inner chamber of the activated carbon filter element (261) is provided on the surface of the extrusion plate (26), the extrusion plate (26) is connected to the reaction box (2) via a cylinder (28), and when the cylinder (28) outputs, the extrusion plate (26) moves transversely in the reaction box (2), and accordingly causes the volume of the reaction chamber (24) to gradually decrease, while the volume of the high-absorption chlorine integrated chamber (25) to gradually increase; A plurality of temperature-controlled photosynthesizers (242) are arranged in the reaction chamber (24); the temperature-controlled photosynthesizers (242) are arranged as temperature-controlled tubes or light-illumination tubes; and the temperature-controlled photosynthesizers (242) are connected to the reaction box (2) via a vertical plate (241); A pressure regulating storage tank (4) is arranged on a side of the frame (1) away from the pre-treatment box (3); the water outlet pipe (212) is connected to the pressure regulating storage tank (4); a detection monitor (41) is installed at the connection position between the water outlet pipe (212) and the pressure regulating storage tank (4); an output pipe (43) is installed on one side of the pressure regulating storage tank (4); and a positive and negative pressure controller (42) is installed in the pressure regulating storage tank (4) at a position close to the output pipe (43).

2. A purification device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 1, characterized in that: The mixing element comprises a movable ring (223), the movable ring (223) being fixedly connected to the surface of a rotating rod (222), a plurality of connecting rods (224) being fixedly connected to the surface of the movable ring (223), and blades (225) being fixedly connected to the surface of the connecting rods (224).

3. A purification device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 2, characterized in that: The mixing element comprises a movable ring (223), a thread groove is formed on the surface of the rotating rod (222), the movable ring (223) is threadedly connected to the surface of the rotating rod (222), a plurality of connecting rods (224) are fixedly connected to the surface of the movable ring (223), blades (225) are hinged on the surface of the connecting rods (224), and a connecting ring (226) is rotatably connected to the bottom of the movable ring (223), and the connecting ring (226) is connected to the reaction box (2) via a spring (227).

4. A purification device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to any one of claims 1 to 3, characterized in that: One side of the partition (23) passes through the reaction box (2) and extends outside the reaction box (2); the clutch assembly comprises a connection block (231) fixedly connected to a side of the partition (23) located outside the reaction box (2); an electric push rod (232) is fixedly connected to the surface of the reaction box (2); and an output end of the electric push rod (232) is fixedly connected to the connection block (231).

5. A purification device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 4, characterized in that: The side of the partition (23) close to the inside of the reaction box (2) is arc-shaped, and the arc is bent in the direction of the disinfection chamber (22).

6. The purifier equipment for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 1, characterized in that: Two sealing doors (262) are arranged on the inner wall of a through hole connecting the extrusion plate (26) and the inner cavity of the activated carbon filter element (261); the sealing door (262) is connected to the extrusion plate (26) via a rotating shaft (263); a torsion spring is arranged in the rotating shaft (263); two ends of the torsion spring are respectively connected to the rotating shaft (263) and the extrusion plate (26); and a plurality of the temperature-controlled photosynthesizers (242) are adapted to fit into the plurality of the through holes.

7. The purifier equipment for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 1 is characterized in that: The inner cavity of the activated carbon filter element (261) is provided with a plurality of gas outlet pipes (264), one end of the gas outlet pipes (264) is fixedly connected to one side of the extrusion plate (26), a side of the extrusion plate (26) close to the reaction chamber (24) is fixedly connected to a connecting pipe (265), an air cavity (266) is provided in the extrusion plate (26), the connecting pipe (265) is connected to the gas outlet pipe (264) via the air cavity (266), and a plurality of air holes for gas to pass through are provided on the surface of the gas outlet pipe (264).

8. The purification device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 7, characterized in that: A hydrogenation pipe (27) is fixedly connected to the surface of the activated carbon filter element (261), and a plurality of hydrogen transmission control valves (272) are arranged on one side of the reaction box (2). The hydrogen transmission control valves (272) are connected to external hydrogen supply equipment, and one end of the hydrogen transmission control valve (272) located in the reaction box (2) is connected to the hydrogenation pipe (27) via a connecting hose (271).

9. The purification device for converting hydrogen chloride-containing aqueous solution by adsorbing chlorine according to claim 1, characterized in that: The chlorine supply component comprises a chlorine generator (11) arranged at the bottom of the frame (1); the chlorine generator (11) is connected to the reaction box (2) via a chlorine inlet pipe (13); a detection regulator (12) is installed on the surface of the chlorine inlet pipe (13).

10. A method for purifying aqueous solution containing hydrogen chloride by converting chlorine into hydrogen chloride by adsorption according to any one of claims 1 to 9, characterized in that: The steps include: S1, A valve connected to the external municipal tap water or surface water or underground water, a booster pump is arranged behind the A valve, a pre-backwash filter is arranged behind the booster pump, a negative layer alloy catalyst scale inhibitor is arranged behind the filter, an ultrafiltration membrane purifier is arranged behind the scale inhibitor, a control B valve is arranged behind the ultrafiltration membrane purifier, and a reaction box is connected behind the control B valve; S2, the C valve for introducing chlorine from the external salt electrolysis chlorine generator, the rear end of the C valve is provided with a detection regulator, a mixing device and a reaction box, the chlorine introduced by the C valve is mixed with the purified water introduced by the B valve to react, and the water is disinfected, so that the water and chlorine are fully converted and reacted to generate HCL and HCLO; S3, the chlorine-water mixture treated in step 2 is introduced into the high-adsorption chlorine cavity, and a D valve is provided at the side end of the high-adsorption chlorine integrated cavity to connect to an external hydrogen production device. The hydrogen input strengthens the reaction between hydrogen and chlorine to form the required pH value. The high-adsorption chlorine integrated device is mainly composed of high-adsorption activated carbon fiber ACF, supplemented by a PP cotton layer and medical stone. The BET specific surface area of ​​ACF is 1500-3000 (㎡ / g), and the adsorption of chlorine or residual chlorine reaches 60-97%. The residual chlorine in the water is adsorbed by the activated carbon fiber filter element for effective filtration conversion, and the residual chlorine is further eliminated; S4. The adsorbed chlorine component reaches a saturated concentration to form a special chlorine membrane (high-efficiency sterilization and disinfection). The chlorine ions / chlorine molecules overflowing from the chlorine membrane are prone to hydrolysis in water. Under the action of the temperature-controlled photosynthesizer, oxygen escapes to form a stable aqueous solution containing HCL. Then, the positive and negative pressure regulating storage tanks are connected. The parameters of the aqueous solution containing HCL are detected and controlled by the detection and monitoring regulator. A controllable display screen is installed on the surface of the detection and monitoring regulator to display parameters: water temperature, concentration, residual chlorine, pH value (adjustment gradient 6.9~0.9), TDS, etc., to ensure the safety and quality of the output purified aqueous solution containing HCL; S5. Output the aqueous solution containing HCL.

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