Glove box protective glove for collaborative protection of radiochemical hazards and preparation method of glove box protective glove

Abstract

The invention discloses a glove box protective glove for synergistic protection of radiochemical hazards and a preparation method of the glove box protective glove, and the glove box protective glove is prepared by mold pressing of rubber in a glove mold. The rubber is prepared from 100 parts of raw rubber, 1-5 parts of a vulcanizing agent, 4-10 parts of an active agent, 2-5 parts of an accelerant, 20-40 parts of a reinforcing agent, 0-500 parts of a ray shielding component, 1-5 parts of a silane coupling agent, 0-20 parts of a homogenizing agent, 0.5-3 parts of an anti-aging agent, 2-8 parts of a softening agent, 5-10 parts of a plasticizer, 0-3 parts of a release agent and 0-50 parts of chemical-resistant filler. The method is easy to implement and high in production efficiency, and the obtained gloves not only have good mechanical properties and flexibility, but also have excellent tolerance to strong acid, strong alkali, organic reagents with different polarities and the like, and meanwhile have a good ray shielding function.

Description

Technical Field

[0001] The invention relates to the technical field of nuclear radiation protection materials, and in particular to a glove box protective glove for coordinated protection against radiation and chemical hazards and a preparation method thereof. Background Art

[0002] With the development of the nuclear industry, the demand for the operation and handling of radioactive chemicals is increasing day by day. Effective protective measures are needed to protect workers from radiation damage. Glove box protective gloves are widely used as an effective protective equipment. However, the actual use scenarios faced by protective gloves are very complex, including radiation, acid and alkali reagents, strong oxidizing reagents, organic reagents of different polarities, etc. Existing protective gloves are difficult to meet the use requirements in these environments, especially when radiation and chemical hazards exist at the same time. There is an urgent need for protective technology that can achieve coordinated protection against radiation and chemical hazards. At present, protective gloves usually use rubber materials as the base material, and add other functional additives to achieve the target function. For example, patent CN113223740A uses the impregnation process of chloroprene latex and adds a mixture of tungsten oxide and tungsten carbide particles as a shielding body to prepare a thin and elastic gamma-ray protective glove. Patent CN117757168B uses chloroprene rubber, EPDM rubber, and chlorosulfonated polyethylene rubber as substrates, nano-tungsten powder or nano-bismuth powder modified by silane coupling agent as shielding body, and barium sulfate as acid and alkali resistant reinforcing agent, and uses molding method to prepare protective gloves with good softness, mechanical properties and acid and alkali corrosion resistance. Patent CN116574335A prepares flexible shielding materials by blending gadolinium hydride, nano-boron carbide and EPDM rubber. As a rare earth material, gadolinium hydride can simultaneously shield neutrons and gamma rays. It can be seen that the rubber substrates currently used to prepare glove box protective gloves are mostly limited to chloroprene rubber, EPDM rubber and chlorosulfonated polyethylene rubber, and the selection of shielding components, reinforcing agents, plasticizers, chemical resistant fillers, etc. is relatively limited. The evaluation of the performance of the gloves is also mostly limited to shielding performance, mechanical properties, and acid and alkali corrosion resistance. It is still very urgent to improve the performance of gloves in the presence of radiation and complex chemical reagents.

[0003] The main component of the protective gloves in the existing radiation chemical hazard coordinated protection glove box is rubber. When in contact with chemical reagents, some challenges and problems may be encountered, resulting in a reduction in the service life of the gloves and even safety hazards. For example: (1) The radiation shielding function, chemical protection function and mechanical properties are incompatible: In order to improve the shielding performance, the increase of radiation shielding components will lead to a decrease in the chemical resistance and mechanical properties of the material. (2) Accelerated penetration: Chemical reagents swell, dissolve or corrode the glove material, causing the chemical substances to penetrate the glove material faster and reduce the protective effect. (3) Surface stickiness: Certain chemical reagents react with the glove material to cause the glove surface to become sticky, affecting the flexibility and comfort of the operator when using the gloves. (4) Hardening: Long-term contact with certain chemicals may cause the glove material to harden, reducing the flexibility and wearing comfort of the gloves. (5) Accelerated aging: The coupling effect of chemical reagents, especially reagents of different polarities, will accelerate the aging process of the glove material and shorten the service life of the gloves. Summary of the invention

[0004] The present invention aims to provide a glove box protective glove for coordinated protection against radiation and chemical hazards and a preparation method thereof in view of the defects of the prior art.

[0005] In order to solve the above technical problems, the present invention provides the following technical solutions:

[0006] The first aspect of the present invention provides a glove box protective glove for coordinated protection against radiation and chemical hazards, characterized in that the glove is molded in a glove mold using rubber, and the raw materials of the rubber include the following components: in parts by mass, 100 parts of raw rubber, 1-5 parts of vulcanizing agent, 4-10 parts of activating agent, 2-5 parts of accelerator, 20-40 parts of reinforcing agent, 0-500 parts of radiation shielding component, 1-5 parts of silane coupling agent, 0-20 parts of homogenizer, 0.5-3 parts of antioxidant, 2-8 parts of softener, 5-10 parts of plasticizer, 0-3 parts of release agent, and 0-50 parts of chemical-resistant filler.

[0007] Furthermore, the raw rubber is one or more of butyl rubber, halogenated butyl rubber, EPDM rubber, chloroprene rubber, and fluororubber;

[0008] The vulcanizing agent is one or more of sulfur and peroxide vulcanizing agent;

[0009] The active agent is one or more of zinc oxide, magnesium oxide, stearic acid, zinc stearate, and calcium stearate;

[0010] The accelerator is one or more of thiurams, thiazoles, sulfenamides, dithiocarbamates, guanidines, thiophosphates, and thioureas;

[0011] The reinforcing agent is one or more of carbon black and white carbon black;

[0012] The radiation shielding component is one or more of tungsten powder, tungsten oxide, bismuth powder, bismuth oxide, bismuth sulfide, gadolinium hydride, tin powder, and tin oxide;

[0013] The silane coupling agent is one or more of KH550, KH560, KH570 and Si-69;

[0014] The homogenizer is 60NS or FYZ;

[0015] The softener is one or more of paraffin, rosin oil, silicone oil, and butyl stearate;

[0016] The plasticizer is one or more of naphthenic oil, paraffin oil, petroleum resin, dibutyl phthalate, dioctyl phthalate, and phthalate esters;

[0017] The antioxidant is one or more of a phenolic antioxidant and an amine antioxidant;

[0018] The release agent is one or more of paraffin, surfactant, fatty acid, and fatty acid salt;

[0019] The chemical-resistant filler is one or more of barium sulfate, calcium carbonate, aluminum hydroxide, silicon dioxide, clay, nylon, polyester fiber, carbon fiber, and polytetrafluoroethylene.

[0020] Furthermore, the peroxide curing agent includes dicumyl peroxide DCP, 1,1-di-tert-butylperoxy-3,3,5-trimethylcyclohexane, benzoyl peroxide, bis(tert-butylperoxide)dibenzoyl DBPM, and 1,3-bis(tert-butylperoxyisopropyl)benzene.

[0021] Furthermore, the particle size of the radiation shielding component is less than 20 μm.

[0022] Furthermore, the length of the glove mold is (700-800)±5mm, and the cuff diameter is (150, 165, 180, 200, 285)±2mm.

[0023] Furthermore, the thickness of the glove box protective gloves includes 0.4, 0.6, 0.8, and 1.0 mm; and the curling diameter is 5±0.5 mm.

[0024] The second aspect of the present invention provides a method for preparing the glove box protective gloves for coordinated protection against radiation and chemical hazards according to the first aspect, characterized in that it comprises the following steps:

[0025] The raw rubber is put into an internal mixer for the first plasticization, and then the active agent, antioxidant, softener, plasticizer, release agent, and homogenizer are put into the internal mixer for the first mixing, and finally the filler, radiation shielding component, and chemical resistant filler are put into the internal mixer for the second mixing, and then the rubber is discharged, and the open mixer is thinned for 3-5 times and then the sheet is produced to obtain the A-stage mixed rubber;

[0026] After the A-stage mixed rubber is parked for more than 8 hours, it is put into an internal mixer for a second plasticizing, and the vulcanizing agent and accelerator are put into the internal mixer for a third mixing and then discharged; after the open mixer is thinned 3-5 times, a rubber strip is produced to obtain the B-stage mixed rubber;

[0027] Putting the mixed rubber of stage B into a calender for calendering to obtain a mixed rubber sheet;

[0028] Finally, the mixed rubber sheet is placed in a glove mold for compression vulcanization to obtain a glove box protective glove with coordinated protection against radiation and chemical hazards.

[0029] Furthermore, the first plasticizing time is 0.5-2 minutes; the first mixing time is 1-4 minutes; the second mixing time is 2-6 minutes, and the temperature is 100-160°C.

[0030] Furthermore, the second plasticizing time is 0.5-1 min; the third mixing time is 1-6 min, and the temperature is 70-100°C.

[0031] Compared with the prior art, the present invention has the following beneficial effects:

[0032] (1) The prepared glove box protective gloves achieve synergistic protection against radiation and various chemical reagents.

[0033] (2) By adjusting the amount of shielding components, protective gloves 60 The protection capability of Co source (γ ray) can be controlled at 0-0.3mmPb, and gloves with corresponding shielding capability can be selected according to actual application needs.

[0034] (3) The addition of chemical-resistant fillers or compounding with fluororubber effectively enhances the product's tolerance to various chemical agents (strong oxidizing acids, strong bases, alcohols, hydrocarbons, esters, etc.). At the same time, the combined use of plasticizers and softeners can make the product have good flexibility and wearing comfort.

[0035] (4) In terms of formulation, the material range of glove box protective gloves for the coordinated protection of radiation and chemical hazards has been broadened through the rational design of raw rubber and multiple raw rubber compounds, shielding components, chemical reagent resistant fillers, plasticizers, softeners, reinforcing agents and vulcanization systems. In terms of function, the multifunctional integration of radiation shielding, chemical protection and wearing comfort has been achieved. BRIEF DESCRIPTION OF THE DRAWINGS

[0036] Figure 1 The present invention is a flow chart for preparing the glove box protective gloves. DETAILED DESCRIPTION

[0037] In order to deepen the understanding of the present invention, the present invention will be further described in detail below with reference to the accompanying drawings. The embodiments are only used to explain the present invention and do not constitute a limitation on the protection scope of the present invention.

[0038] Unless expressly indicated to the contrary, the numerical parameters in this specification and the appended claims may be approximate values ​​and can be changed according to the desired properties obtained by the content of the present invention. Specifically, all numbers used in the specification and claims to express the content of the composition, reaction conditions, etc., should be understood to be modified by the term "about" in all cases. In general, the meaning of the expression is to include a change of ±10% in some embodiments, a change of ±5% in some embodiments, a change of ±1% in some embodiments, and a change of ±0.5% in some embodiments by a specific number.

[0039] The terms "first", "second", and "third" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Therefore, a feature defined as "first", "second", and "third" may explicitly or implicitly include one or more of the features. In the description of the present invention, the meaning of "plurality" is two or more, unless otherwise clearly and specifically defined.

[0040] In addition, unless the steps are specifically described or must occur in sequence, the order of the above steps is not limited to the above list, and can be changed or rearranged according to the required design. And the above embodiments can be mixed and matched with each other or with other embodiments based on design and reliability considerations, that is, the technical features in different embodiments can be freely combined to form more embodiments.

[0041] Obviously, the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0042] In order to solve the problems existing in the prior art, an embodiment of the present invention provides a glove box protective glove for coordinated protection against radiation and chemical hazards. The glove is molded in a glove mold using rubber, and the raw materials of the rubber include the following components: by mass, 100 parts of raw rubber, 1-5 parts of vulcanizing agent, 4-10 parts of activating agent, 2-5 parts of accelerator, 20-40 parts of reinforcing agent, 0-500 parts of radiation shielding component, 1-5 parts of silane coupling agent, 0-20 parts of homogenizer, 0.5-3 parts of antioxidant, 2-8 parts of softener, 5-10 parts of plasticizer, 0-3 parts of release agent, and 0-50 parts of chemical-resistant filler.

[0043] Preferably, the raw rubber is one or more of butyl rubber, halogenated butyl rubber, EPDM rubber, chloroprene rubber, and fluororubber; the vulcanizing agent is one or more of sulfur and peroxide vulcanizing agent; the activating agent is one or more of zinc oxide, magnesium oxide, stearic acid, zinc stearate, and calcium stearate; the accelerator is one or more of thiuram, thiazole, sulfenamide, dithiocarbamate, guanidine, thiophosphate, and thiourea; the reinforcing agent is one or more of carbon black and white carbon black; the radiation shielding component is one or more of tungsten powder, tungsten oxide, bismuth powder, bismuth oxide, bismuth sulfide, gadolinium hydride, tin powder, and tin oxide; the silane coupling agent is KH550, KH56 0, KH570, Si-69 or one or more; 60NS or FYZ is used as the homogenizer; one or more of paraffin, rosin oil, silicone oil and butyl stearate is used as the softener; one or more of cyclohexane oil, paraffin oil, petroleum resin, dibutyl phthalate (DIBP), dioctyl phthalate (DOP) and phthalate is used as the plasticizer; one or more of phenolic antioxidants and amine antioxidants are used as the antioxidant; one or more of paraffin, surfactant, fatty acid and fatty acid salt are used as the release agent; one or more of barium sulfate, calcium carbonate, aluminum hydroxide, silicon dioxide, clay, nylon, polyester fiber, carbon fiber and polytetrafluoroethylene are used as the chemical resistant filler.

[0044] Peroxide curing agents include dicumyl peroxide DCP, 1,1-di-tert-butylperoxy-3,3,5-trimethylcyclohexane (BPMC), benzoyl peroxide (BPO), bis(tert-butylperoxide) dibenzoyl DBPM, and 1,3-bis(tert-butylperoxyisopropyl)benzene (BIPB).

[0045] The particle size of the radiation shielding component is less than 20 μm.

[0046] The length of the glove mold is (700-800) ± 5mm, and the cuff diameter is (150, 165, 180, 200, 285) ± 2mm. The thickness of the glove box protective gloves includes 0.4, 0.6, 0.8, 1.0mm, with an error of -0.1mm / +0.2mm; the glove curling diameter is 5±0.5mm.

[0047] The embodiment of the present invention also provides a method for preparing the glove box protective gloves for coordinated protection against radiation and chemical hazards, comprising the following steps:

[0048] Put the raw rubber into the internal mixer for the first plastication, then put the activator, antioxidant, softener, plasticizer, release agent and homogenizer into the internal mixer for the first mixing, finally put the filler, radiation shielding component and chemical resistant filler into the internal mixer for the second mixing and then discharge the rubber, and thin the mill for 3-5 times before discharging the sheet to obtain the A-stage mixed rubber;

[0049] After the mixed rubber of stage A is parked for more than 8 hours, it is put into the internal mixer for the second plastication, and the vulcanizer and accelerator are put into the internal mixer for the third mixing and rubber discharge; after the open mixer is thinned for 3-5 times, the rubber strip is produced to obtain the mixed rubber of stage B;

[0050] The mixed rubber of stage B is put into a calender to be calendered to obtain a mixed rubber sheet;

[0051] Finally, the mixed rubber sheet is placed in a glove mold for compression vulcanization to produce a glove box protective glove with coordinated protection against radiation and chemical hazards.

[0052] Preferably, the first plasticizing time is 0.5-2 min, the first mixing time is 1-4 min, the second mixing time is 2-6 min, and the temperature is 100-160°C, the second plasticizing time is 0.5-1 min, and the third mixing time is 1-6 min, and the temperature is 70-100°C.

[0053] Embodiment 1:

[0054] This embodiment provides a glove box protective glove for coordinated protection against radiation and chemical hazards. 60 parts of butyl rubber and 40 parts of fluororubber are used as the base material and plasticized in an internal mixer for 2 minutes. 25 parts of white carbon black, 2 parts of silane coupling agent KH560, 15 parts of homogenizer NS, 80 parts of shielding component tungsten oxide, 1 part of antioxidant N-phenyl-2-naphthylamine (antiaging agent D), 4 parts of magnesium oxide, 8 parts of DOP, 4 parts of paraffin, 2 parts of zinc stearate, 20 parts of barium sulfate, etc. are added in stages and mixed for 1-6 minutes. After the rubber temperature reaches 100-160°C, the rubber is discharged; the open mixer is thinned 3-5 times and then the sheet is produced to obtain the mixed rubber of stage A. After parking for 10 hours, the stage A rubber is plasticized for 1 minute, and 5 parts of peroxide curing agent DCP and 4 parts of accelerator triallyl isocyanurate are added. After mixing for 5 minutes, the rubber is discharged at 70-100°C, and the open mixer is thinned 3-5 times to obtain the stage B rubber. After the B-stage rubber is calendered into a sheet, it is molded at 165°C for 10 minutes and then stored in an oven at 200°C for 3 hours to obtain protective gloves.

[0055] Embodiment 2:

[0056] The present embodiment provides a glove box protective glove for coordinated protection against radiation and chemical hazards. 100 parts of EPDM raw rubber are used as a base material and plasticized in an internal mixer for 2 minutes. 15 parts of carbon black N550, 1 part of silane coupling agent KH550, 50 parts of polytetrafluoroethylene powder, 160 parts of tungsten powder, 1 part of antioxidant tris[2.4-di-tert-butylphenyl]phosphite (antioxidant 168), 4 parts of zinc oxide, 3 parts of stearic acid, 10 parts of DIBP, 6 parts of paraffin wax, 2 parts of 935P are added in stages and mixed for 1-6 minutes. The rubber material temperature reaches 100-160° C. and then the rubber is discharged. The mill is thinly passed 3-5 times and then sheets are discharged to obtain the A-stage mixed rubber. After standing for 10 hours, the rubber of stage A was plasticized for 1 minute, and then 1.2 parts of sulfur, 1 part of accelerator 2-mercaptobenzothiazole, and 1 part of accelerator zinc di-n-butyl dithiocarbamate were added. After mixing for 5 minutes, the rubber was discharged at 70-100°C, and the mixing mill was thinned 3-5 times to obtain the rubber of stage B. The rubber of stage B was calendered into a sheet and molded at 165°C for 20 minutes to obtain protective gloves.

[0057] Embodiment 3:

[0058] This embodiment provides a glove box protective glove for coordinated protection against radiation and chemical hazards. 100 parts of EPDM raw rubber are used as the base material and plasticized in an internal mixer for 2 minutes. 15 parts of white carbon black, 1 part of silane coupling agent KH550, 35 parts of carbon fiber powder, 290 parts of tungsten powder, 1 part of antioxidant N-phenyl-1-naphthylamine (antiaging agent A), 4 parts of zinc oxide, 3 parts of stearic acid, 8 parts of paraffin oil, 4 parts of paraffin, 1 part of surfactant 935P are added in sections and mixed for 1-6 minutes. After the rubber temperature reaches 100-160°C, the rubber is discharged; the open mixer is thinned 3-5 times and then the sheet is produced to obtain the A-stage mixed rubber. After parking for 10 hours, the A-stage rubber is plasticized for 1 minute and then 1.5 parts of sulfur, 2 parts of accelerator DPTT, and 2 parts of accelerator CZ are added. After mixing for 5 minutes, the rubber is discharged at 70-100°C, and the open mixer is thinned 3-5 times to obtain the B-stage rubber. The B-stage rubber was calendered into a sheet and then molded at 165°C for 20 minutes to obtain protective gloves.

[0059] Embodiment 4:

[0060] This embodiment provides a glove box protective glove for coordinated protection against radiation and chemical hazards. 100 parts of chloroprene rubber are used as the base material and plasticized in an internal mixer for 2 minutes. 8 parts of carbon black N220, 40 parts of barium sulfate, 460 parts of bismuth powder, 3 parts of antioxidant 4010NA, 5 parts of magnesium oxide, 3 parts of stearic acid, 10 parts of petroleum resin, 5 parts of paraffin wax, etc. are added in stages and mixed for 1-6 minutes. After the rubber temperature reaches 100-160°C, the rubber is discharged; the open mill is thinned 3-5 times and then the sheet is produced to obtain the A-stage mixed rubber. After parking for 10 hours, the A-stage rubber is plasticized for 1 minute and 4 parts of zinc oxide are added. After mixing for 5 minutes, the rubber is discharged at 70-100°C, and the open mill is thinned 3-5 times to obtain the B-stage rubber. After the B-stage rubber is calendered into a sheet, it is molded at 160°C for 20 minutes to obtain protective gloves.

[0061] Comparative Example:

[0062] 100 parts of butyl rubber raw rubber are used as the base material and plasticized in an internal mixer for 2 minutes. 25 parts of carbon black N110, 2 parts of silane coupling agent Si-69, 2 parts of antioxidant N-phenyl-1-naphthylamine (antiaging agent A), 4 parts of zinc oxide, 2 parts of stearic acid, 15 parts of cyclohexane oil, 2 parts of paraffin wax, and 50 parts of polytetrafluoroethylene powder are added in stages and mixed for 1-6 minutes. After the rubber temperature reaches 100-160°C, the rubber is discharged; the open mixer is thinly passed 3-5 times and then the sheet is produced to obtain the A-stage mixed rubber. After parking for 10 hours, the A-stage rubber is plasticized for 1 minute and then 1.5 parts of sulfur, 0.7 parts of accelerator TMTD, and 1.5 parts of accelerator DM are added. After mixing for 5 minutes, the rubber is discharged at 70-100°C, and the open mixer is thinly passed 3-5 times to obtain the B-stage rubber. After the B-stage rubber is calendered into a sheet, it is molded at 160°C for 10 minutes to obtain protective gloves.

[0063] The parts of the gloves that are easily exposed to chemical reagents in the above embodiments and comparative examples were selected to test the anti-penetration performance level in different chemical reagents, chemical degradation resistance (change in puncture force before and after degradation), and tensile performance comparison before and after immersion in chemical reagents for a certain period of time. The chemical reagents include: methanol, acetone, acetonitrile, dichloromethane, carbon disulfide, toluene, diethylamine, tetrahydrofuran, ethyl acetate, n-heptane, sodium hydroxide (mass fraction 40%), sulfuric acid (mass fraction 96%), nitric acid (mass fraction 65%), acetic acid (mass fraction 99%), ammonium hydroxide (mass fraction 25%), hydrogen peroxide (mass fraction 30%), hydrofluoric acid (mass fraction 40%), formaldehyde (mass fraction 37%), etc. In addition, the lead equivalent ( 60 Co source) and its uniformity were measured.

[0064] The test results of the protective gloves obtained in various embodiments and comparative examples are shown in Table 1 below:

[0065] Table 1:

[0066]

[0067]

[0068] It can be seen from the above test results that the glove box radiation protection gloves prepared in Examples 1-4 are relatively soft, have good shielding properties, and are resistant to various chemical reagents.

[0069] The above specific implementation methods are only for illustrating the technical concept and structural features of the present invention, and the purpose is to enable relevant persons familiar with this technology to implement it. However, the above content does not limit the protection scope of the present invention. Any equivalent changes or modifications made according to the spirit of the present invention should fall within the protection scope of the present invention.

Claims

1. A glove box protective glove for coordinated protection against radiation and chemical hazards, characterized in that: The glove is made by molding rubber in a glove mold. The raw materials of the rubber include the following components: by mass, 100 parts of raw rubber, 1-5 parts of vulcanizer, 4-10 parts of activator, 2-5 parts of accelerator, 20-40 parts of reinforcing agent, 0-500 parts of radiation shielding component, 1-5 parts of silane coupling agent, 0-20 parts of homogenizer, 0.5-3 parts of antioxidant, 2-8 parts of softener, 5-10 parts of plasticizer, 0-3 parts of release agent and 0-50 parts of chemical resistant filler.

2. The glove box protective glove for coordinated protection against radiation and chemical hazards according to claim 1, characterized in that: The raw rubber is one or more of butyl rubber, halogenated butyl rubber, EPDM rubber, chloroprene rubber and fluororubber; The vulcanizing agent is one or more of sulfur and peroxide vulcanizing agent; The active agent is one or more of zinc oxide, magnesium oxide, stearic acid, zinc stearate, and calcium stearate; The accelerator is one or more of thiurams, thiazoles, sulfenamides, dithiocarbamates, guanidines, thiophosphates, and thioureas; The reinforcing agent is one or more of carbon black and white carbon black; The radiation shielding component is one or more of tungsten powder, tungsten oxide, bismuth powder, bismuth oxide, bismuth sulfide, gadolinium hydride, tin powder, and tin oxide; The silane coupling agent is one or more of KH550, KH560, KH570 and Si-69; The homogenizer is 60NS or FYZ; The softener is one or more of paraffin, rosin oil, silicone oil, and butyl stearate; The plasticizer is one or more of naphthenic oil, paraffin oil, petroleum resin, dibutyl phthalate, dioctyl phthalate, and phthalate esters; The antioxidant is one or more of a phenolic antioxidant and an amine antioxidant; The release agent is one or more of paraffin, surfactant, fatty acid, and fatty acid salt; The chemical-resistant filler is one or more of barium sulfate, calcium carbonate, aluminum hydroxide, silicon dioxide, clay, nylon, polyester fiber, carbon fiber, and polytetrafluoroethylene.

3. The glove box protective glove for coordinated protection against radiation and chemical hazards according to claim 2, characterized in that: The peroxide curing agent includes dicumyl peroxide DCP, 1,1-di-tert-butylperoxy-3,3,5-trimethylcyclohexane, benzoyl peroxide, bis(tert-butylperoxide)dibenzoyl DBPM, and 1,3-bis(tert-butylperoxyisopropyl)benzene.

4. The glove box protective glove for coordinated protection against radiation and chemical hazards according to claim 2, characterized in that: The particle size of the radiation shielding component is less than 20 μm.

5. The glove box protective glove for coordinated protection against radiation and chemical hazards according to claim 1, characterized in that: The length of the glove mold is (700-800)±5mm, and the cuff diameter is (150, 165, 180, 200, 285)±2mm.

6. The glove box protective glove for coordinated protection against radiation and chemical hazards according to claim 1, characterized in that: The thickness of the glove box protective gloves includes 0.4, 0.6, 0.8, and 1.0 mm; the curling diameter is 5±0.5 mm.

7. A method for preparing a glove box protective glove for coordinated protection against radiation and chemical hazards as claimed in any one of claims 1 to 6, characterized in that: The steps include: The raw rubber is put into an internal mixer for the first plasticization, and then the active agent, antioxidant, softener, plasticizer, release agent, and homogenizer are put into the internal mixer for the first mixing, and finally the filler, radiation shielding component, and chemical resistant filler are put into the internal mixer for the second mixing, and then the rubber is discharged, and the open mixer is thinned for 3-5 times and then the sheet is produced to obtain the A-stage mixed rubber; After the A-stage mixed rubber is parked for more than 8 hours, it is put into an internal mixer for a second plasticizing, and the vulcanizing agent and accelerator are put into the internal mixer for a third mixing and then discharged; after the open mixer is thinned 3-5 times, a rubber strip is produced to obtain the B-stage mixed rubber; Putting the mixed rubber of stage B into a calender for calendering to obtain a mixed rubber sheet; Finally, the mixed rubber sheet is placed in a glove mold for compression vulcanization to obtain a glove box protective glove for coordinated protection against radiation and chemical hazards.

8. The preparation method according to claim 7, characterized in that: The first plasticizing time is 0.5-2 minutes; the first mixing time is 1-4 minutes; the second mixing time is 2-6 minutes, and the temperature is 100-160°C.

9. The preparation method according to claim 7, characterized in that: The second plasticizing time is 0.5-1 min; the third mixing time is 1-6 min, and the temperature is 70-100°C.

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