Cosmetic containing crosslinked silicone resin and method for producing same

Abstract

A crosslinked silicone resin which is a product of an addition reaction between a component (A) and a component (B) described below, the amount of hydrogen gas per unit mass generated from the crosslinked silicone resin being 1.5 mL / g or less in a standard state, (A) an alkenyl group-containing silicone resin having one or more alkenyl groups per molecule, and (B) an alkenyl group-containing silicone resin having one or more alkenyl groups per molecule. (B) an organohydrogenpolysiloxane having two or more hydrosilyl groups in one molecule, the crosslinked silicone resin having excellent long-term stability and forming a coating film having excellent oil resistance, no stickiness, no brittleness, and high flexibility; when the crosslinked silicone resin is blended, a cosmetic material having a good feeling of use, good elongation, and excellent secondary adhesion resistance is obtained.

Description

Technical Field

[0001] The present invention relates to a cosmetic containing a cross-linked silicone resin and a method for producing the same. Background Art

[0002] Silicone resins can improve the durability of cosmetics by being mixed with them. However, there are two problems with mixing silicone resins with cosmetics. The first problem is that the film formed is brittle. The film formed by applying cosmetics containing silicone resins to hair, face, hands, etc., breaks or peels off due to slight movements, and thus lacks followability. In particular, the M unit (R 3 SiO 1 / 2 ) and Q unit (SiO 4 / 2 ) is very strong, so it has good mechanical strength, but it is difficult to form a self-supporting film because the film is brittle. On the other hand, MTQ, MDQ, MDTQ and DT resins introduced with T units and D units have improved film flexibility compared to MQ resins, and can form a strong self-supporting film with followability. However, the strength from the resin remains, which has problems in abrasion resistance. Patent document 1 discloses that a crack-free film can be formed by applying an emulsion containing a plasticized MQ resin to a hair cosmetic. However, when a silicone rubber is added as a plasticizer, the film strength is reduced and the adhesiveness is increased, which gives an unpleasant feeling such as a sticky feeling, and the feeling of use is deteriorated.

[0003] The second problem is oil resistance. When applied to the skin as a cosmetic, oil resistance to sebum is required. The components of sebum are mainly composed of hydrocarbon oil, ester oil, triglyceride, etc. The silicone resin used as a film-forming agent has high compatibility with these oils. Therefore, after the cosmetic is applied, the film swells over time, and there is also a problem that the physical strength of the cosmetic film is reduced and the durability of the makeup is deteriorated. On the other hand, in Patent Document 2, a highly oil-resistant composition using a silicone resin and a silicone-modified acrylic polymer is proposed. Since the silicone-modified acrylic polymer forms a soft film, it can impart some softness and followability, but it cannot obtain sufficient oil resistance and has no effect on improving the durability of the makeup.

[0004] In recent years, a cross-linked silicone resin in which a silicone resin is cross-linked with silicone has been reported. In Patent Document 3, it is reported that a silicone resin containing vinyl groups and silicone containing hydrosilyl groups are heated to produce a cross-linked silicone resin, and a cured product with high flexibility is obtained. However, since it is difficult to dissolve in volatile oils, it is difficult to use as a film-forming agent. The same cross-linked silicone resin is also reported in Patent Documents 4 and 5, but since it is a gel in nature, it does not have the ability to form a film. In Patent Document 6, a silicone resin containing hydrosilyl groups and silicone containing vinyl groups are cross-linked by heat curing to form a cross-linked silicone resin. However, the cured product obtained is sticky and has low solubility in volatile oils. In Patent Document 7, a silicone resin containing hydrosilyl groups and a silicone containing vinyl groups whose reaction points are limited are reacted to form a cross-linked silicone resin soluble in volatile oils. However, the reactivity of the hydrosilyl groups is low, and the remaining hydrosilyl groups react over time, resulting in an increase in viscosity and the generation of hydrogen, making it difficult to use. In Patent Document 8, an organopolysiloxane gel is prepared by crosslinking an organosilicone resin having an unsaturated group with an organohydrogenpolysiloxane having 30 or more D units. However, if the chain length of the crosslinking agent is long, a solvent is inserted into the network, and the property tends to become gel-like, resulting in a sticky film.

[0005] Prior art literature

[0006] Patent Literature

[0007] Patent Document 1: Japanese Patent Application No. 2015-515981

[0008] Patent Document 2: Japanese Patent Application Publication No. 2018-095617

[0009] Patent Document 3: Japanese Patent Application Publication No. 2009-052038

[0010] Patent Document 4: Japanese Patent Application Publication No. 2010-540721

[0011] Patent Document 5: Japanese Patent Application Publication No. 2015-519426

[0012] Patent Document 6: Japanese Patent Application Publication No. 2015-505878

[0013] Patent Document 7: Japanese Patent Application Publication No. 2020-007486

[0014] Patent Document 8: Japanese Patent Application No. 2020-521014 Summary of the invention

[0015] Problems to be solved by the invention

[0016] The present invention has been completed in view of the above-mentioned actual situation, and its purpose is to provide a cross-linked silicone resin that has excellent stability over time and forms a coating that is excellent in oil resistance, non-sticky, non-brittle, and highly flexible; a cosmetic material that is blended with the cross-linked silicone resin, has a good feel in use, good elongation, and excellent anti-secondary adhesion; and a method for manufacturing the same.

[0017] Means for solving problems

[0018] The present inventors have conducted intensive studies to achieve the above-mentioned purpose, and as a result, have found that, compared with silicone resins containing hydrosilyl groups, silicone resins containing alkenyl groups have high reactivity of alkenyl groups, and can reduce the amount of unreacted functional groups. Also, by controlling the ratio of the amount of hydrosilyl groups to the amount of alkenyl groups, the amount of residual hydrosilyl groups can be reduced, thereby suppressing the increase in viscosity over time and the generation of hydrogen gas.

[0019] Furthermore, the alkenyl group content of the alkenyl group-containing silicone resin and the chain length of the organohydrogenpolysiloxane were determined, and it was found that the cross-linked silicone resin obtained in this way can form a soft coating film that is not sticky and has high flexibility.

[0020] Generally, it is said that hard coatings tend to have low flexibility, and coatings with high flexibility tend to be soft, and there is a paradoxical relationship between the strength and flexibility of the coating. However, although the cross-linked silicone resin of the present invention forms a firm coating, it has high flexibility and therefore excellent followability. Furthermore, the oil resistance to oil agents such as sebum is greatly improved compared to before modification. As the molecular weight of the silicone resin increases, the oil resistance tends to increase, but there is a limit to increasing the molecular weight of the silicone resin, so the oil resistance also has a limit point. The cross-linking of the silicone resin produced by the cross-linking agent may lead to an increase in the molecular weight of the silicone resin, so it has the effect of increasing its limit point. Therefore, the cross-linked silicone resin has oil resistance that cannot be achieved for existing silicone resins. In addition, by being mixed in the cosmetic as a coating forming agent, it becomes a cosmetic that is not sticky when applied and has a good sense of use. In addition, due to the good adhesion to the skin, a cosmetic with excellent abrasion resistance such as good elongation and the effect of preventing secondary adhesion is obtained.

[0021] That is, the present invention provides the following cosmetics and a method for producing the same.

[0022] 1. A cosmetic comprising a cross-linked silicone resin which is an addition reaction product of the following components (A) and (B), wherein the amount of hydrogen gas per unit mass generated by the cross-linked silicone resin is 1.5 mL / g or less under standard conditions,

[0023] (A) an alkenyl group-containing silicone resin represented by the following formula (1) and having one or more alkenyl groups in one molecule

[0024] [Chemistry 1]

[0025] (R 1 R 2 2SiO 1 / 2 ) a1 (R 2 3SiO 1 / 2 ) a2 (R 3 3SiO 1 / 2 ) a3 (R 2 2SiO 2 / 2 ) b (R 2 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1)

[0026] [Where R 1 are independently alkenyl having 2 to 8 carbon atoms, R 2 Each of R is independently selected from an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, and an aralkyl group having 7 to 30 carbon atoms. 3 are independently selected from a group containing an organopolysiloxane, and the above R 2 The groups in each R 3 3SiO 1 / 2 Unit R 3 At least one of the above is a group containing an organopolysiloxane. a1, a2, a3, b, c and d are numbers satisfying 0<a1≤5, 0<a2≤400, 0≤a3≤400, 0≤b≤320, 0≤c≤320, 0<d≤1000, and 0.5≤(a1+a2+a3) / d≤1.5.]

[0027] (B) an organohydrogenpolysiloxane represented by the following formula (2) having two or more hydrosilyl groups in one molecule, in an amount such that the amount of the hydrosilyl groups is 0.5 to 1.2 mol per 1 mol of the alkenyl groups in the component (A);

[0028] [Chemistry 2]

[0029] (R 4 3SiO 1 / 2 ) e (R 4 2SiO 2 / 2 ) f (R 2 SiO 3 / 2 ) g (SiO 4 / 2 ) h (2)

[0030] (Where R 2 Same as above, R 4 are independently a hydrogen atom or the above R 2 The groups represented by all R 4 Two or more of them are hydrogen atoms, e, f, g, and h are 0 or positive numbers, and 2≤e+f+g+h<32. )

[0031] 2. The cosmetic according to item 1, wherein in the R 3 In the above, the group containing an organopolysiloxane is one or more groups represented by any one of the following formulae (3) to (6),

[0032] [Chemistry 3]

[0033] -C m H 2m -(CH2)2-(SiOR 2 2) i -SiR 2 3 (3)

[0034] -C m H 2m -(CH2)2-SiR 2 j1 -(OSiR 2 3) 3-j1 (4)

[0035] -C m H 2m -(CH2)2-SiR 2 j- 1-(OSiR 2 j2 (OSiR 2 3) 3-j2 ) 3-j1 (5)

[0036] -C m H 2m -(CH2)2-SiR 2 j1 -(OSiR 2 j2 (OSiR 2 j3 (OSiR 2 3) 3-j3 ) 3-j2 ) 3-j1 (6)

[0037] (Where R 2 As described above, m is an integer of 0≤m≤5, i is an integer of 0≤i≤500, and j1 to j3 are each an integer of 0 to 2.)

[0038] 3. The cosmetic according to 1 or 2, wherein in the formula (1), b=0 and c=0.

[0039] 4. The cosmetic according to any one of 1 to 3, wherein in the formula (2), g=0 and h=0.

[0040] 5. The cosmetic according to any one of 1 to 4, wherein the cross-linked silicone resin has a weight average molecular weight of 5,000 to 1,000,000.

[0041] 6. The cosmetic according to any one of 1 to 5, wherein in the formula (2), 0≤f<30, R 4 Two of them are hydrogen atoms, and the cross-linked silicone resin is solid at 25°C.

[0042] 7. The cosmetic according to any one of 1 to 6, wherein an amount of hydrogen gas per unit mass generated from the cross-linked silicone resin is 0.01 to 1.2 mL / g under a standard state.

[0043] 8. The cosmetic according to any one of 1 to 7, wherein the cross-linked silicone resin is soluble at 25°C in a volatile oil having a boiling point of 250°C or less at 1013 hPa.

[0044] 9. The cosmetic according to 8, wherein the volatile oil agent is one or more selected from silicone oil, isododecane and ethanol.

[0045] 10. The cosmetic according to any one of 1 to 9, wherein the content of the cross-linked silicone resin is 0.1 to 40% by mass.

[0046] 11. The cosmetic according to any one of 1 to 10, which is a sunscreen cosmetic or a makeup cosmetic.

[0047] 12. The cosmetic according to any one of 1 to 11, which is a non-aqueous composition.

[0048] 13. A method for producing a cosmetic according to any one of 1 to 12, comprising the steps of: reacting (A) an alkenyl-containing silicone resin represented by the following formula (1) having one or more alkenyl groups in one molecule with (B) an organohydrogenpolysiloxane represented by the following formula (2) having two or more hydrosilyl groups in one molecule in an amount such that the amount of hydrosilyl groups is 0.5 to 1.2 mol per 1 mol of the alkenyl groups in the component (A) to obtain a crosslinked silicone resin;

[0049] [Chemistry 4]

[0050] (R 1 R 2 2SiO 1 / 2 ) a1 (R 2 3SiO 1 / 2 ) a2 (R 3 3SiO 1 / 2 ) a3 (R 2 2SiO 2 / 2 ) b (R 2 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1)

[0051] [Where R 1 are independently alkenyl having 2 to 8 carbon atoms, R 2 Each of R is independently selected from an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, and an aralkyl group having 7 to 30 carbon atoms. 3 are independently selected from a group containing an organopolysiloxane, and the above R 2 The groups in each R 3 3SiO 1 / 2 More than one R in the unit 3 is a group containing an organic polysiloxane, and a1, a2, a3, b, c and d are numbers satisfying 0<a1≤5, 0<a2≤400, 0≤a3≤400, 0≤b≤320, 0≤c≤320, 0<d≤1000, and 0.5≤(a1+a2+a3) / d≤1.5.]

[0052] [Chemistry 5]

[0053] (R 4 3SiO 1 / 2 ) e (R 4 2SiO 2 / 2 ) f (R 2 SiO 3 / 2 ) g (SiO 4 / 2 ) h (2)

[0054] [Where R 2 Same as above, R 4 are independently a hydrogen atom or the above R 2 The groups represented by all R 4Two or more of them are hydrogen atoms, e, f, g, and h are 0 or positive numbers, and 2≤e+f+g+h<32. ]

[0055] Effects of the Invention

[0056] The crosslinked silicone resin of the present invention has excellent stability over time and forms a coating film that is excellent in oil resistance, non-sticky, non-brittle, and highly flexible. Cosmetics blended with the crosslinked silicone resin have good feel during use, good elongation, and excellent secondary adhesion resistance. DETAILED DESCRIPTION

[0057] The present invention is described in detail below.

[0058] A cosmetic material comprising a crosslinked silicone resin, which is an addition reaction product of the following component (A) and component (B), wherein the amount of hydrogen gas per unit mass generated by the crosslinked silicone resin is 1.5 mL / g or less under standard conditions. In the present invention, the name of the ingredient may be described as a cosmetic name or International Nomenclature of Cosmetic Ingredient (INCI). When the cosmetic name corresponds to INCI, the English description may be omitted.

[0059] [(A) ingredient]

[0060] The component (A) of the present invention is an alkenyl group-containing silicone resin represented by the following average composition formula (1) and having one or more alkenyl groups in one molecule. These resins can be used alone or in combination of two or more.

[0061] [Chemistry 6]

[0062] (R 1 R 2 2SiO 1 / 2 ) a1 (R 2 3SiO 1 / 2 ) a2 (R 3 3SiO 1 / 2 ) a3 (R 2 2SiO 2 / 2 ) b (R 2 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1)

[0063] [Where R 1 are independently alkenyl having 2 to 8 carbon atoms, R 2Each of R is independently selected from an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, and an aralkyl group having 7 to 30 carbon atoms. 3 are independently selected from a group containing an organopolysiloxane, and the above R 2 The groups in each R 3 3SiO 1 / 2 More than one R in the unit 3 is a group containing an organic polysiloxane. a1, a2, a3, b, c and d are numbers satisfying 0<a1≤5, 0<a2≤400, 0≤a3≤400, 0≤b≤320, 0≤c≤320, 0<d≤1000, and 0.5≤(a1+a2+a3) / d≤1.5.]

[0064] [(B) ingredient]

[0065] The component (B) of the present invention is an organohydrogenpolysiloxane represented by the following average composition formula (2) and having two or more hydrosilyl groups in one molecule, and one type thereof can be used alone or in combination of two or more types thereof. The addition reaction amount is such that the amount of hydrosilyl groups becomes 0.5 to 1.2 mol relative to 1 mol of the alkenyl groups in the component (A), preferably 0.5 to 1.2 mol, more preferably 0.8 to 1.2 mol, and still more preferably 0.9 to 1.1 mol.

[0066] [Chemistry 7]

[0067] (R 4 3SiO 1 / 2 ) e (R 4 2SiO 2 / 2 ) f (R 2 SiO 3 / 2 ) g (SiO 4 / 2 )h (2)

[0068] [Where R 2 Same as above, R 4 are independently a hydrogen atom or the above R 2 The groups represented by all R 4 Two or more of them are hydrogen atoms, and e, f, g, and h are 0 or positive numbers, but 2≤e+f+g+h<32. ]

[0069] In the above formula, R 1 Each of them is independently an alkenyl group having 2 to 8 carbon atoms. More specifically, vinyl, allyl, isopropenyl, butenyl, pentenyl, hexenyl, cyclohexenyl, octenyl, etc. are exemplified. Vinyl and allyl are particularly preferred.

[0070] In the above formula, R2 are independently selected from an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, or an aralkyl group having 7 to 30 carbon atoms. Among them, an alkyl group, an aryl group, an aralkyl group, or a fluorine-substituted alkyl group having 1 to 10 carbon atoms is preferred. More specifically, methyl, ethyl, propyl, butyl, pentyl, cyclopentyl, cyclohexyl, phenyl, tolyl, trifluoropropyl, etc. are listed. An alkyl group having 1 to 5 carbon atoms, a phenyl group, or a trifluoropropyl group is particularly preferred. In addition, R 2 A part of may contain one or more groups selected from a hydroxyl group or an alkoxy group having 1 to 8 carbon atoms.

[0071] In the alkenyl-containing silicone resin represented by the above formula (1), a1, a2, a3, b, c and d are 0<a1≤5, preferably 0<a1≤4.5, more preferably 1≤a1≤4, and further preferably 1≤a1≤3. If a1 is larger than 5, the possibility of gelation increases and the film forming property is also poor. It is 0≤a2≤400, preferably 0≤a2≤100, and more preferably 0≤a2≤50. It is 0≤a3≤400, preferably 0≤a3≤100, and more preferably 0≤a3≤50. If a3 is larger than 400, the melting point of the resin decreases, so the film forming property is poor. It is 0≤b≤320, 0≤c≤320, preferably b=0, and c=0. The number is a number satisfying 0<d≤1000, 0.5≤(a1+a2+a3) / d≤1.5, preferably a number satisfying 0.7≤(a1+a2+a3) / d≤1.2. If the value of (a1+a2+a3) / d is less than the above lower limit, the degree of crosslinking increases, the molecular weight increases, and thus the gel is formed. If the above upper limit is exceeded, the molecular weight decreases, and thus the film forming property is poor.

[0072] The alkenyl-containing organic silicone resin represented by the above formula (1) has a Q unit (SiO 4 / 2 )、M unit (R 2 3SiO 1 / 2 and R 1 R 2 2SiO 1 / 2 ) is a necessary structure, with D unit (R 2 2SiO 2 / 2 )、T unit (R 2 SiO 3 / 2) is an optional structure. It can be solid or liquid at 25°C, and is preferably solid from the perspective of film forming properties. For example, MQ resin, MTQ resin, MDQ resin, and MDTQ resin can be listed. The weight average molecular weight is preferably in the range of 1000 to 30000, and is more preferably in the range of 3000 to 15000 in terms of performance and operability such as filtration. It should be noted that the weight average molecular weight can be obtained as a weight average molecular weight converted to polystyrene in gel permeation chromatography (GPC) analysis.

[0073] In the organohydrogenpolysiloxane represented by the above formula (2) having two or more hydrosilyl groups in one molecule, R 4 are independently a hydrogen atom or a monovalent hydrocarbon group having 1 to 30 carbon atoms and having no aliphatic unsaturated bond, and all R 4 Two or more of them are hydrogen atoms.

[0074] In the above formula (2), e, f, g, and h are 0 or positive numbers, and can be selected as long as they satisfy 2≤e+f+g+h<32. Preferably, g=0 and h=0, more preferably, e=2, 0≤f<30, g=0, and h=0, and further preferably, e=2, 0≤f≤20, g=0, and h=0. If the number of silicon atoms contained in component (B) is 32 or more, the cross-linked silicone resin embraces the solvent, and the property is likely to become a gel. Therefore, after the solvent evaporates, it is easy to become a sticky film. If the number of silicon atoms contained in component (B) is less than 32, the cross-linked silicone resin dissolves in the solvent, and the property is likely to become a liquid. Therefore, after the solvent evaporates, it is easy to obtain a non-sticky film.

[0075] The above R 3 are independently selected from a group containing an organopolysiloxane, or the above R 2 The group containing the organopolysiloxane includes, for example, groups represented by the following general formulae (3) to (6). 3 3SiO 1 / 2 In each unit, one or more R 3 is a group containing an organic polysiloxane. In addition, optionally, R 3 A portion of may be a hydroxyl group.

[0076] [Chemistry 8]

[0077] -C m H 2m -(CH2)2-(SiOR 2 2) i -SiR 2 3 (3)

[0078] -C m H 2m-(CH2)2-SiR 2 j1 -(OSiR 2 3) 3-j1 (4)

[0079] -C m H 2m -(CH2)2-SiR 2 j1 -(OSiR 2 j2 (OSiR 2 3) 3-j2 ) 3-j1 (5)

[0080] -C m H 2m -(CH2)2-SiR 2 j1 -(OSiR 2 j2 (OSiR 2 j3 (OSiR 2 3) 3-j3 ) 3-j2 ) 3-j1 (6)

[0081] (Where R 2 As described above, n and i are integers satisfying 0≤n≤5, 0≤i≤500, and j1 to j3 are each an integer greater than or equal to 0 and less than or equal to 2.)

[0082] m is an integer of 0≤m≤5, preferably 0≤m≤2, and i is an integer of 0≤i≤500, preferably 1≤i≤100, more preferably 1≤i≤50. If i is greater than 500, the melting point of the resin decreases, thereby poorly forming a film. j1 to j3 are each an integer of 0 to 2.

[0083] In the above formula (1), preferably b=0 and c=0. When b and c are 0, the alkenyl-containing silicone resin does not contain a flexible skeleton such as a D unit or a T unit, and is composed only of an M unit and a Q unit. By using an alkenyl-containing silicone resin that does not contain a D unit or a T unit as a raw material, a cross-linked silicone resin as an addition reaction product can form a strong coating.

[0084] In the above formula (2), preferably g = 0 and h = 0. When g and h are 0, the organohydrogenpolysiloxane becomes a linear molecule consisting only of M units and D units without branching components such as T units and Q units. By using a linear organohydrogenpolysiloxane as a raw material, a cross-linked silicone resin as an addition reaction product can form a soft coating.

[0085] In addition, there may be two or more groups represented by formula (2). As the chain length of the group represented by formula (2) increases, it has the effect of imparting flexibility to the silicone resin. Therefore, for example, by including two groups represented by formula (2) having different chain lengths, the coating properties can be controlled.

[0086] [Physical properties of cross-linked silicone resin]

[0087] The weight average molecular weight of the cross-linked silicone resin of the present invention is preferably 5,000 to 1,000,000, more preferably 8,000 to 500,000, and further preferably 10,000 to 500,000. By being within such a range, it is more preferred in terms of performance and operability such as filtration. It should be noted that the weight average molecular weight can be obtained as a weight average molecular weight converted to polystyrene in gel permeation chromatography (GPC) analysis (the same below).

[0088] The cross-linked silicone resin can be solid, gel or liquid at 25°C. For example, by dissolving it in a liquid oil and volatilizing it, a coating can be easily formed. The coating is a brittle and strong coating before cross-linking, but its brittleness is improved after cross-linking, resulting in a non-sticky and soft coating. From the perspective of film formation, a solid or gel state is preferred, and a solid state is more preferred. The film forming ability can be determined by dropping 1.5 g of a dissolved product diluted with 30% by mass of isododecane or decamethylcyclopentasiloxane on PTFE (fluororesin), drying it at 105°C for 3 hours, and whether a self-supporting film is formed. In the case where a coating is not formed, oil seeps out from cracks in the coating, the oil resistance is significantly reduced, and the followability to the skin is low, resulting in an unnatural finish.

[0089] The cross-linked silicone resin of the present invention can be used more preferably as a film-forming agent. The silicone resin before cross-linking forms a strong film with brittleness. On the other hand, as for the cross-linked silicone resin after cross-linking, its brittleness is improved, and a non-sticky and soft film is formed. This is because the silicone resin before cross-linking forms a strong film, and the film is given softness by cross-linking with soft chains. In general, it is said that hard films have low flexibility, and films with high flexibility tend to be soft, so there is a paradoxical relationship between the strength and flexibility of the film. However, the cross-linked silicone resin of the present invention has the following characteristics: although a strong film is formed, it has high flexibility and therefore excellent followability.

[0090] In addition, the coating formed with the cross-linked silicone resin has a significantly improved oil resistance to oils such as sebum compared to the coating formed with the silicone resin before cross-linking. The oil resistance of silicone resin tends to improve as the molecular weight increases, but there is a limit to how much the molecular weight of silicone resin can be increased, so the oil resistance also has a limit point. The cross-linking of silicone resin by the cross-linking agent may increase the molecular weight of the silicone resin, which has the effect of raising its limit point. Therefore, the cross-linked silicone resin has oil resistance that cannot be achieved with existing silicone resins.

[0091] A cross-linked silicone resin in which f in the formula (2) is an integer satisfying 0<f<30 is solid at 25° C. and can provide a cross-linked silicone resin having particularly excellent film-forming properties.

[0092] In addition, f in the above formula (2) satisfies 0≤f<30, R 4 A cross-linked silicone resin in which two of the atoms are hydrogen atoms is solid at 25° C., and a cross-linked silicone resin having particularly excellent film-forming properties can be obtained. 4 When three or more of the atoms are hydrogen atoms, the possibility of becoming a gel when the diluting solvent is removed may increase. In this case, the film-forming property is maintained, but the feeling is that of a gel.

[0093] In the above formula (1), a1 is 0<a1≤3, f in the above formula (2) satisfies 0≤f<20, R 4 The crosslinked silicone resin in which two of the atoms are hydrogen atoms is solid at 25° C., and a crosslinked silicone resin having particularly excellent film-forming properties can be obtained. The obtained film exhibits particularly excellent flex resistance and oil resistance.

[0094] The amount of hydrogen per unit mass generated by the cross-linked silicone resin is 1.5 mL or less under standard conditions. If it exceeds 1.5 mL / g, the viscosity may increase over time due to hydrogen generation or reaction of the remaining hydroxyl group and alkoxy group with the hydrosilyl group, thereby deteriorating the stability over time. The amount of hydrogen generation is preferably 0.01 to 1.2 mL / g, and more preferably 0.02 to 1.0 mL / g.

[0095] The amount of hydrogen gas per unit mass can be calculated from the volume of hydrogen gas generated by the reaction of the hydrosilyl group and the base. For example, the following method can be used, but the calculation method is not limited to this.

[0096] <Method for measuring the amount of hydrogen>

[0097] 10 g of 20% by mass sodium hydroxide aqueous solution was added dropwise to a mixed solution of 50 g of a crosslinked silicone resin diluted to 50% by mass with decamethylcyclopentasiloxane and 10 g of 1-butanol. The volume of generated hydrogen gas was divided by the purity of the crosslinked silicone resin to determine the amount of hydrogen gas per unit mass.

[0098] [Manufacturing method]

[0099] Since it is difficult to completely control the amount of silanol groups on the surface of the silicone resin, it is difficult to control the amount of the cross-linked organopolysiloxane with high precision. In addition, the synthesis can be performed by an addition reaction of an organosilicone resin having a hydrosilyl group and an organopolysiloxane having alkenyl groups at both ends. However, the reactivity of the hydrosilyl groups in the silicone resin is low, and there are problems such as increased viscosity and generation of hydrogen due to the reaction of the remaining hydrosilyl groups over time. Therefore, as a method for manufacturing a cross-linked silicone resin cross-linked with silicone, it is preferred to use a synthesis method of an addition reaction of an organosilicone resin having alkenyl groups and an organopolysiloxane having hydrosilyl groups at both ends.

[0100] The method for producing a cross-linked silicone resin using the hydrosilylation reaction is described in detail below.

[0101] In the hydrosilylation reaction step of the alkenyl group-containing organosilicon resin represented by the above average composition formula (1) and the organohydrogenpolysiloxane represented by the above formula (2), the molar ratio of the terminal hydrosilyl group / unsaturated group can be selected from the range of 0.5 to 2.0, preferably 0.5 to 1.2 mol, more preferably 0.8 to 1.2, and further preferably 0.9 to 1.1. If the above ratio is too large, the residual amount of the hydrosilyl group increases, and the stability over time may deteriorate.

[0102] The hydrosilylation reaction is preferably carried out in the presence of a platinum catalyst or a rhodium catalyst. For example, preferably chloroplatinic acid, alcohol-modified chloroplatinic acid, chloroplatinic acid-vinylsiloxane complex, etc. In addition, with regard to the usage amount of the catalyst, if it is contained excessively, the sample is colored, so in terms of the amount of platinum or rhodium, preferably below 50ppm, more preferably below 20ppm.

[0103] Furthermore, the above addition reaction can be carried out in the presence of an organic solvent as required. As organic solvents, cyclic organopolysiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane can be listed; aromatic hydrocarbons such as toluene and xylene; ketone organic solvents such as acetone, methyl ethyl ketone, diethyl ketone, and methyl isobutyl ketone; aliphatic hydrocarbons such as hexane, heptane, octane, and cyclohexane; methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol, 2-butanol, 2-methyl-2-propanol, 1-pentanol, 2-methylbutanol, 2-pentanol, 1-hexanol, 2-methylpentanol, 1-heptanol, 1-octanol, 1-nonanol, 1-decanol, phenol, benzyl alcohol, ethylene glycol, and aliphatic alcohols such as 1,2-propylene glycol can be listed. In particular, from the viewpoint of reactivity, ethanol, 1-propanol, and 2-propanol are preferred.

[0104] The amount of the solvent used is preferably 1 to 80% by mass, more preferably 5 to 50% by mass of the entire reaction solution (system). Within the above range, the solvent is uniformly maintained in the reaction system, and the reaction proceeds efficiently.

[0105] The addition reaction conditions are not particularly limited, but heating is preferably performed at 50 to 150° C., more preferably 80 to 120° C., under reflux for about 1 to 10 hours.

[0106] After the addition reaction, the step of removing the used rhodium catalyst or platinum catalyst with activated carbon may also be included. The amount of activated carbon used is preferably 0.001 to 5.0% by mass of the entire system, and more preferably 0.01 to 1.0% by mass. If it is within the above range, the coloring of the sample can be further suppressed.

[0107] After the addition reaction, a step of removing the remaining hydrosilyl group may be included as needed. In particular, when used in cosmetics, the hydrosilyl group may be deactivated by dehydrogenation reaction after a period of time. Since hydrogen gas is generated, there is a problem from the perspective of safety, so it is preferred to include a step of removing the hydrosilyl group.

[0108] As a process for removing the hydrosilyl group, a formula in which an acidic catalyst equal to the molar equivalent of the alkaline catalyst is added after the unreacted hydrosilyl group is hydrolyzed can be listed. As an alkaline catalyst, a strong alkaline catalyst and a weak alkaline catalyst can be listed. As examples of strong alkaline catalysts, alkali metal hydroxides such as lithium hydroxide, sodium hydroxide, potassium hydroxide, calcium hydroxide, and barium hydroxide can be listed. As examples of weak alkaline catalysts, alkali metal carbonates such as sodium carbonate and calcium carbonate, alkali metal bicarbonates such as sodium bicarbonate and potassium bicarbonate can be listed. In terms of promoting the dehydrogenation reaction, it is particularly preferred to use a strong alkaline catalyst, specifically, sodium hydroxide is preferred. As examples of acidic catalysts, inorganic acids such as hydrochloric acid, sulfuric acid, sulfurous acid, oleum, phosphoric acid, sulfonic acids such as p-toluenesulfonic acid, methanesulfonic acid, and trifluoromethanesulfonic acid, oxalic acid, formic acid, acetic acid, propionic acid, benzoic acid, citric acid, and trifluoroacetic acid can be listed.

[0109] In addition, generally, it is preferred to use an acid or a base in combination with water and to heat at a temperature below the boiling point of water rather than using the acid or the base alone. Through this process, the hydrosilyl group (SiH group) becomes a hydroxysilyl group (SiOH group). However, when a cross-linked silicone resin is treated with an alkali catalyst, the silanol group and the alkoxy group in the silicone resin react, thereby changing the physical properties. Therefore, it is not preferred to remove the hydrosilyl group by this method.

[0110] [Cosmetics]

[0111] By blending the cross-linked silicone resin of the present invention (hereinafter sometimes referred to as component (a)) into a cosmetic, the cross-linked silicone resin functions as a film-forming agent, does not feel sticky when applied, has an excellent feel during use, has good water resistance and oil resistance, and has good adhesion to the skin, thereby obtaining a cosmetic having good elongation, excellent finishing properties, water resistance and oil resistance, excellent makeup durability (sustainability), and excellent abrasion resistance such as an effect to prevent secondary adhesion.

[0112] In terms of the convenience of compounding the cross-linked silicone resin of the present invention in water-based and emulsified compositions, an O / W emulsion can be prepared to form an intermediate composition. That is, an O / W emulsion in which a dissolution product of any oil agent of the cross-linked silicone resin of the present invention is dispersed as a dispersed phase in an aqueous phase as a continuous phase becomes an intermediate composition. There is no particular limitation on the method for preparing the O / W emulsion, and it can be prepared by a known method. For example, a method of emulsifying using one or two or more active agents with an HLB of 10 or more can be cited, and as a stabilizer, an active agent with an HLB of less than 10, a higher alcohol, etc. can be used. In addition, carbomer, etc. can be used in the aqueous phase to increase the viscosity.

[0113] The content of the crosslinked silicone resin (a) of the present invention is preferably in the range of 0.1 to 40% by mass, more preferably in the range of 0.1 to 10% by mass, of the total cosmetic. If it is less than 0.1% by mass, sufficient oil resistance cannot be obtained, and if it is more than 40% by mass, the feeling of use may be deteriorated.

[0114] The cross-linked silicone resin of the present invention can also be dissolved in any solvent and provided as a dissolved product. When the solvent is a volatile oil agent having a boiling point of 250°C or less at 1013 hPa, a film can be formed by the volatilization of the solvent, and the effect as a film-forming agent can be further manifested. As the volatile oil agent having a boiling point of 250°C or less at 1013 hPa, it is preferably selected from one or more of silicone oil, isododecane and ethanol, and one or more of them can be used alone or in combination.

[0115] (b) Volatile oil

[0116] As the volatile oil agent, it is preferred that a film is formed early after the application of the cosmetic material to show its effect, and from this point of view, it is preferred to mix a volatile oil agent with a boiling point of 250° C. or less. Among these, silicone oils such as cyclotetrasiloxane (INCI) such as decamethylcyclopentasiloxane, cyclopentasiloxane (INCI), cyclohexasiloxane (INCI), dimethylpolysiloxane (INCI), disiloxane (INCI), trisiloxane (INCI), methyltrimethicone (INCI), ethyltrisiloxane (INCI), ethylmethylpolysiloxane (INCI), and hydrocarbon oils such as isododecane (INCI), undecane (INCI), dodecane (INCI), and hydrogenated polyisobutene (indicative name (INCI: Hydrogenated Polyisobutene)) are particularly preferred. In addition, lower alcohols such as ethanol (INCI: Alcohol) and isopropyl alcohol (INCI: Isopropyl Alcohol), and acetates such as ethyl acetate (INCI: Ethyl Acetate) and butyl acetate (INCI: Butyl Acetate) can be listed. These volatile oils can be appropriately selected and combined according to the type of the base of the cosmetic. For example, when the base is a silicone-based base, it is appropriate to select silicone oil in order to improve the compatibility of the entire cosmetic composition. If the base is silicone oil, a good feeling is obtained, so it is preferred, and commercially available products include TMF-1.5, KF-995, KF-96L-1cs, KF-96L-1.5cs, KF-96L-2cs, KF-4422, etc. manufactured by Shin-Etsu Chemical Co., Ltd. The amount of the volatile oil (B) is preferably in the range of 0.1 to 70% by mass, more preferably in the range of 0.1 to 20% by mass, of the total cosmetic or dissolved product. If it is less than 0.1% by mass, solubility may be lacking, and if it is more than 70% by mass, a dry feeling may be felt.

[0117] [Other ingredients]

[0118] In the cosmetic of the present invention, various ingredients used in common cosmetics can be mixed as other ingredients. As other ingredients, for example, (1) oils other than component (b), (2) aqueous components, (3) surfactants, (4) powders, (5) compositions comprising cross-linked organopolysiloxane and oils that are liquid at room temperature, (6) film-forming agents other than component (A), (7) ultraviolet light absorbing / scattering agents, and (8) other additives can be included. One of these can be used alone or two or more can be appropriately combined for use. Depending on the type of cosmetic, etc., these ingredients can be appropriately selected for use, and their blending amounts can also be set to known blending amounts that are consistent with the type of cosmetic.

[0119] (1) Oils other than component (b)

[0120] The cosmetic of the present invention may contain an oil agent other than component (B). The oil agent is nonvolatile and may be solid, semisolid or liquid at room temperature (25°C), and examples thereof include silicone oil, silicone wax, natural animal and plant oils and semi-synthetic oils, hydrocarbon oils, higher alcohols, fatty acids, ester oils, fluorine-based oils, ultraviolet absorbers, and the like.

[0121] Silicone oil

[0122] Examples of the silicone oil include alkyl-modified silicones such as hexyl dimethicone (INCI), long-chain alkyl-modified silicones such as octyl methyl polysiloxane (INCI), phenyl trimethicone (INCI), diphenyl dimethicone (INCI), diphenylsiloxy phenyl trimethicone (INCI), tetraphenyl dimethyl disiloxane (INCI), and low-viscosity to high-viscosity linear or branched organopolysiloxanes such as methyl hydrogen polysiloxane, amino dimethicone (INCI), aminopropyl dimethicone (INCI), and the like. NCI), amino-modified organopolysiloxanes such as PCA dimethylpolysiloxane (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethylpolysiloxane (INCI), pyrrolidonecarboxylic acid-modified organopolysiloxane, dimethylpolysiloxane (INCI), high-polymerization gum-like dimethylpolysiloxane, gum-like amino-modified organopolysiloxane, gum-like dimethylsiloxane-methylphenylsiloxane copolymer and other silicone rubbers, and low-viscosity organopolysiloxane solutions of silicone gum or silicone rubber, amino acid-modified silicone, fluorine-modified silicone, silicone resins, and silicone resin dissolutions. Examples of commercially available silicone oils include KF-96A-6cs, KF-54, KF-54HV, and KF-56A manufactured by Shin-Etsu Chemical Co., Ltd.

[0123] Solid oily ingredients

[0124] In the present invention, when it is desired to solidify the cosmetic, it is preferred to mix an oily component that is solid at 25° C. Examples of the oily component that is solid at 25° C. include waxes, hydrocarbons, esters, higher alcohols, and higher fatty acids having a melting point of preferably 40° C. or higher, more preferably 60 to 110° C., and are not particularly limited as long as they are raw materials that can be generally mixed in cosmetics. Specific examples include carnauba wax (INCI: Copernicia Cerifera (Carnauba) Wax), sugar cane wax, candelilla wax (INCI: Euphorbia Cerifera (Candelilla) Wax), purified candelilla wax, rice wax, wood wax, jojoba wax, kapok wax, rice bran wax, bayberry wax, shea butter, cocoa butter, Rhus Succedanea Fruit Wax (INCI: Rhus Succedanea Fruit Wax), montan wax (INCI: Montan Wax), vegetable waxes such as hydrogenated castor oil isostearate, beeswax, beef tallow, beef bone fat, pig fat (INCI: Lard), horse fat (INCI: Horse fat), and the like. Fat), lanolin, wool fat (INCI: Lanolin), animal wax such as worm wax, shellac wax, spermaceti, lanolin esters, lanolin fatty acid esters, semi-synthetic waxes such as beeswax acid esters, hardened oils such as hardened castor oil and hardened coconut oil, paraffin wax, polyethylene, ceresin, ceresin, microcrystalline wax and other hydrocarbon waxes, synthetic beeswax and other wax esters, amino acid stearyl alcohol such as dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, fatty acids such as stearic acid and behenic acid, and silicone waxes such as acrylic silicone resins of acrylic-silicone graft or block copolymers (manufactured by Shin-Etsu Chemical Co., Ltd.: acrylic-silicone graft copolymers: KP-561P, 562P, etc.), or derivatives thereof, preferably one or more selected from these.

[0125] Natural animal and plant oils and semi-synthetic oils

[0126] Examples of the natural plant and animal oils and semi-synthetic oils include avocado oil (INCI: Persea Gratissima (Avocado) Oil), linseed oil (INCI: Linum Usitatissimum (Linseed) Seed Oil), almond oil (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil), perilla oil (INCI), olive oil (INCI: Olea Europaea (Olive) Fruit Oil), torreya californica oil (INCI: Torreya Californica (California Nutmeg) Oil), citronella oil (INCI: Cymbopogon Nardus (Citronella) Oil), torreya seed oil (INCI: Torreya Nucifera Seed Oil), almond oil (INCI: Kyounin Yu)), wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil), sesame oil (INCI: Sesamum Indicum (Sesame) Seed Oil), wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil), rice germ oil (INCI: Oryza Sativa (Rice) Germ Oil), rice bran oil (INCI: Oryza Sativa (Rice) Bran Oil), camellia oil (INCI: Camellia Kissi Seed Oil), safflower oil (INCI: Carthamus Tinctorius (Safflower) Seed Oil), soybean oil (INCI: Glycine Soja (Soybean) Oil), tea seed oil (INCI: Camellia Sinensis Seed Oil), camellia oil (INCI: Camellia Japonica Seed Oil)), Evening Primrose Oil (INCI: Oenothera Biennis (Evening Primrose) Oil), Rapeseed Oil (INCI: Zea Mays (Corn) Germ Oil)Germ oils such as wheat germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil), peach kernel oil (INCI: Elaeis Guineensis (Palm) Oil), palm oil (INCI: Elaeis Guineensis (Palm) Kernel Oil), castor oil (INCI: Ricinus Communis (Castor) Seed Oil), sunflower seed oil (INCI: Helianthus Annuus (Sunflower) Seed Oil), grape seed oil (INCI: Vitis Vinifera (Grape) Seed Oil), jojoba seed oil (INCI: Simmondsia Chinensis (Jojoba) Seed Oil), macadamia seed oil (INCI: Macadamia Ternifolia Seed Oil), meadowfoam seed oil (INCI: Limnanthes Annuus (Sunflower) Seed Oil), and jojoba seed oil (INCI: Simmondsia Chinensis (Jojoba) Seed Oil). Alba (Meadowfoam) Seed Oil), cottonseed oil (INCI: Gossypium Herbaceum (Cotton) Seed Oil), coconut oil (INCI: Cocos Nucifera (Coconut) Oil), peanut oil (INCI: Arachis Hypogaea (Peanut) Oil), natural plant oils such as shark liver oil (INCI: Shark Liver Oil), cod liver oil (INCI: Cod Liver Oil), cod liver oil (INCI: Fish Liver Oil), turtle oil (INCI: Turtle Oil), mink oil (INCI: Mink Oil), egg yolk oil (INCI: Egg Oil), semi-synthetic oils such as hydrogenated coconut oil (INCI: Hydrogenated Coconut Oil), liquid lanolin (INCI: Lanolin Oil), etc.

[0127] Hydrocarbon oil

[0128] Examples of the hydrocarbon oil include linear or branched hydrocarbon oils. Specifically, examples include olefin oligomers (INCI), isoparaffins such as (C13, 14) isoparaffin (INCI), isohexadecane (INCI), hydrogenated polyisobutene (INCI: Hydrogenated Polyisobutene), squalane (INCI), mineral oil (INCI), coconut alkane (INCI), (C13-15) alkane (INCI), and petrolatum (INCI: Petrolatum).

[0129] Higher fatty acids

[0130] Examples of higher fatty acids include hydroxystearic acid (indicative name (INCI: Hydroxystearic Acid)).

[0131] ·Higher alcohols

[0132] Examples of higher alcohols include linear saturated alcohols having 6 or more carbon atoms, such as lauryl alcohol (INCI), hexyldecanol (INCI), oleyl alcohol (INCI), isostearyl alcohol (INCI), octyldodecanol (INCI), decyltetradecyl alcohol (INCI), myristyl alcohol (INCI), cetyl alcohol (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), and batyl alcohol (INCI). In addition, examples include sterols such as cholesterol (INCI), sitosterol (indicative name (INCI: Beta-Sitosterol)), phytosterol (INCI), and lanosterol (INCI).

[0133] ·Ester oil

[0134] Examples of the ester oil include diisobutyl adipate (indicative name (INCI: Diisobutyl Adipate)), dihexyldecyl adipate (indicative name), diheptylundecyl adipate (indicative name (INCI: Diheptylundecyl Adipate)), dibutyl adipate (indicative name (INCI: Dibutyl Adipate)), butylene glycol di(caprylate / caprate) (indicative name (INCI: Butylene Glycol Dicaprylate / Dicaprate)), isostearyl isostearate (indicative name (INCI: Isostearyl Isostearate)), isocetyl isostearate (indicative name (INCI: Isocetyl Isostearate)), trimethylolpropane triisostearate (indicative name (INCI: Trimethylolpropane Triisostearate)), glycol diethylhexanoate (indicative name (INCI: Glycol Diethylhexanoate), cetyl ethylhexanoate (INCI: Cetyl Ethylhexanoate), trimethylolpropane triethylhexanoate (INCI: Trimethylolpropane Triethylhexanoate), pentaerythrityl tetraethylhexanoate (INCI: Pentaerythrityl Tetraethylhexanoate), cetyl octanoate (INCI: Cetyl Ethylhexanoate), octyldodecyl stearoyl stearate (INCI: Octyldodecyl Stearoyl Stearate), octyldodecyl oleate (INCI: OleylOleate), octyldodecyl oleate (INCI: Octyldodecyl Oleate), decyl oleate (INCI: Decyl Oleate), neopentyl glycol dioctanoate (INCI: Neopentyl GlycolDiethylhexanoate), Neopentyl Glycol Dicaprate (Indicative Name (INCI: Neopentyl GlycolDicaprate)), Diethylhexyl Succinate (Indicative Name (INCI: Diethylhexyl Succinate)), Amyl Acetate (Indicative Name (INCI: Amyl Acetate)), Ethyl Acetate (Indicative Name (INCI: Etyl Acetate)), Butyl Acetate (Indicative Name (INCI: ButylAceetate), Isocetyl Stearate (INCI: IsocetylStearate), Butyl Stearate (INCI: Butyl Stearate), Diisopropyl Sebacate (INCI: Diisopropyl Sebacate), Diethylhexyl Sebacate (INCI: DiethylhexylSebacate), Isononyl Isononanoate (INCI: Isononyl Isononanoate), Isotridecyl Isonononanoate (INCI: Isotridecyl Isononanoate), Isopropyl Palmitate (INCI: Isopropyl Palmitate), Ethylhexyl Palmitate (INCI: Ethylhexyl Isopalmitate), Hexyldecyl Palmitate (INCI: Isocetyl Palmitate, Hexyldecyl Palmitate), etc. Palmitate, Isopropyl Myristate (INCI: Isopropyl Myristate), Octyldodecyl Myristate (INCI: Octyldodecyl Myristate), Myristyl Myristate (INCI: Myristyl Myristate), Ethylhexyl Laurate (INCI: EthylhexylLaurate), Hexyl Laurate (INCI: Hexyl Laurate), Dioctyldodecyl Lauroyl Glutamate (INCI: Dioctyldodecyl Lauroyl Glutamate), Isopropyl Lauroyl Sarcosinate (INCI: Isopropyl Lauroyl Sarcosinate), Coconut Oil Alkyl (Caprylate / Caprate) Ester (INCI: Coco-Caprylate Caprate).

[0135] Among the ester oils, examples of the glyceride oil include triisooctanoin (INCI), tri(caprylic / capric)glyceride (INCI: Caprylic / Capric Triglyceride), and tri(caprylic / capric / succinic)glyceride (INCI: Caprylic / Capric / Succinic Triglyceride).

[0136] Fluorine oil

[0137] Examples of the fluorine-based oil include perfluorodecahydronaphthalene (INCI), perfluorononyldimethylpolysiloxane (INCI), and perfluoromethylcyclopentane (INCI).

[0138] UV absorber

[0139] Examples of the ultraviolet absorber include homosalate (INCI), octocrylene (INCI), t-butyl methoxydibenzoylmethane (INCI: Butyl Methoxydibenzoylmethane), ethylhexyl salicylate (INCI: Ethylhexyl Salicylate), diethylamino hydroxybenzoyl hexyl benzoate (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate), diethylamino hydroxybenzoyl hexyl benzoate (INCI: Diethylamino Hydroxybenzoyl Hexyl Benzoate), and t-butyl methoxydibenzoylmethane (INCI: Butyl Methoxydibenzoylmethane). Benzoate), Oxybenzone-6 (INCI: Benzophenone-6), Oxybenzone-9 (INCI: Benzophenone-9), Oxybenzone-1 (INCI: Benzophenone-1), Polysilicone-15 (INCI), Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate), Oxybenzone-2 (INCI: Benzophenone-2), Terephthalylidene Dicamphor Sulfonic Acid (INCI: Terephthalylidene Dicamphor Sulfonic Acid), Ethylhexyl Triazone (INCI), Methyl Bis(trimethylsiloxy) Silyl Isopentyl Trimethoxycinnamate (INCI: Isopentyl Trimethoxycinnamate Trisiloxane), drometrizole trisiloxane (INCI), ethylhexyl dimethyl PABA (INCI: Ethylhexyl Dimethyl PABA), isopropyl p-methoxycinnamate (INCI: Isopropyl Methoxycinnamate), ethylhexyl methoxycinnamate (INCI: Ethylhexyl Methoxycinnamate), bis-ethylhexyloxyphenol methoxyphenyl triazine (INCI: Bis-Ethylhexyloxyphenol MethoxyphenylTriazine), Oxybenzone-3 (INCI: Benzophenone-3), Oxybenzone-4 (INCI: Benzophenone-4), Oxybenzone-5 (INCI: Benzophenone-5), Phenylbenzimidazole Sulfonic Acid (INCI: PhenylbenzimidazoleSulfonic Acid), Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (INCI: Methylene Bis-Benzotriazolyl Tetramethylbutylphenol), Glyceryl Ethylhexanoate Dimethoxycinnamate (INCI: Glyceryl Ethylhexanoate Dimethoxycinnamate), Glyceryl PABA (INCI: Glyceryl PABA), Methyl Diisopropyl Cinnamate (INCI: Diisopropyl Cinnamate MethylCinnamate)), Cinoxamate (INCI), Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate), etc. In addition, a UVA absorber (e.g., diethylaminohydroxybenzoyl hexyl benzoate, etc.) and a UVB absorber (e.g., ethylhexyl methoxycinnamate, etc.) may be used together, or they may be combined arbitrarily.

[0140] The amount of the oil (2) other than the component (b) is preferably in the range of 0.1 to 30% by mass of the total cosmetic, more preferably in the range of 0.1 to 20% by mass, and still more preferably in the range of 0.1 to 10% by mass. If it is less than 0.1% by mass, the solubility may be poor, and if it is more than 30% by mass, the cosmetic may feel sticky and the oil resistance may be deteriorated.

[0141] (2) Water-based ingredients

[0142] The aqueous component is not particularly limited as long as it is an aqueous component that can be generally mixed in cosmetics. Specifically, sugar alcohols such as water, sorbitol (INCI), maltose (INCI), and xylitol (INCI) can be listed. In addition, polyols such as BG (butylene glycol, indicated by the name (INCI: Butylene Glycol)), PG (propylene glycol, indicated by the name (INCI: Propylene Glycol)), DPG (dipropylene glycol, indicated by the name (INCI: Dipropylene Glycol)), pentylene glycol (INCI), 1,10-decanediol (INCI), caprylyl glycol (INCI), 1,2-hexanediol (INCI), erythritol (INCI), glycerol (INCI), diglycerol (INCI), and polyethylene glycol can be listed; glucose (INCI), glyceryl glucoside (INCI), betaine (INCI), sodium chondroitin sulfate (indicated by the name (INCI: Sodium Chondroitin Sulfate), PCA-Na (indicative name (INCI: Sodium PCA)), Methyl Gluceth-10 (INCI), Methyl Gluceth-20 (INCI), Hyaluronic Acid, Egg Yolk Lecithin, Soy Lecithin, Phosphatidylcholine, Phosphatidylethanolamine, Phosphatidylserine, Phosphatidylglycerol, Phosphatidylinositol, Sphingolipids and other moisturizing agents.

[0143] (3) Surfactants

[0144] As surfactants, there are nonionic, anionic, cationic and amphoteric active agents, and there is no particular limitation, as long as they are surfactants used in common cosmetics, they can all be used. Among these surfactants, preferably partially cross-linked polyether-modified silicone, partially cross-linked polyglycerol-modified silicone, straight-chain or branched polyoxyethylene-modified organopolysiloxane, straight-chain or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxane, straight-chain or branched polyoxyethylene-alkyl co-modified organopolysiloxane, straight-chain or branched polyoxyethylene-polyoxypropylene-alkyl co-modified organopolysiloxane, straight-chain or branched polyglycerol-modified organopolysiloxane, straight-chain or branched polyglycerol-alkyl co-modified organopolysiloxane.

[0145] Examples of partially cross-linked polyether-modified silicones include (dimethicone / (PEG-10 / 15)) cross polymer (INCI), (PEG-15 / lauryl dimethicone) cross polymer (INCI), (PEG-10 / lauryl dimethicone) cross polymer (INCI), and (PEG-15 / lauryl dimethylsiloxyethyl dimethicone) cross polymer (INCI). Examples of partially cross-linked polyglyceryl-modified silicones include (dimethicone / polyglyceryl-3) cross polymer (INCI), (lauryl dimethicone / polyglyceryl-3) cross polymer (INCI), and (polyglyceryl-3 / lauryl dimethylsiloxyethyl dimethicone) cross polymer (INCI). Furthermore, when partially crosslinked polyether-modified silicone or partially crosslinked polyglycerol-modified silicone is used, in a composition comprising the crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, the crosslinked organopolysiloxane preferably swells with respect to the liquid oil containing the liquid oil agent in an amount equal to or greater than the weight of the crosslinked organopolysiloxane.

[0146] As the liquid oil, the liquid silicone oil, hydrocarbon oil, ester oil, natural animal and plant oil, semi-synthetic oil, etc., and fluorine-based oil listed in the above-mentioned component (B) or the oil other than component (B) in the above-mentioned (1) can be used. For example, cyclopentasiloxane (INCI), dimethyl polysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (indicative name (INCI: Isotridecyl Isononanoate)), squalane (INCI), etc. can be listed.

[0147] Examples of commercially available cross-linked organopolysiloxanes that swell by containing a liquid oil include KSG-210, KSG-240, KSG-270, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-710, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, and KSG-850Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0148] Examples of surfactants other than cross-linked organopolysiloxanes include PEG-11 methyl ether dimethicone (INCI), PEG / PPG-20 / 22 butyl ether dimethicone (INCI), PEG-3 dimethicone (INCI), PEG-10 dimethicone (INCI), PEG-9 polydimethylsiloxyethyl dimethicone (INCI), lauryl PEG-9 polydimethylsiloxyethyl dimethicone (INCI), cetyl PEG / PPG-10 / 1 dimethicone (INCI), polyglyceryl-3 disiloxane dimethicone (INCI), polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), and bis-butyl dimethicone polyglyceryl-3 (INCI). Examples of commercially available products include KF-6011, KF-6011P, KF-6012, KF-6015, KF-6017, KF-6043, KF-6028, KF-6038, KF-6048, KF-6100, KF-6104, KF-6105, KF-6106, and KF-6115 manufactured by Shin-Etsu Chemical Co., Ltd.

[0149] The amount of surfactant blended is preferably 0.1 to 20% by mass of the total cosmetic. If it is 0.1% by mass or more, the dispersion and emulsification functions can be fully exerted, and if it is 20% by mass or less, there is no need to worry about the cosmetic getting a sticky feel, so it is preferred. The HLB of the surfactant is not limited, but is preferably 2 to 14.5 for the purpose of maintaining the water resistance of the cosmetic.

[0150] (4) Powder

[0151] Examples of the powder include coloring pigments, inorganic powders, metal powders, organic powders, inorganic-organic composite powders, etc. The specific examples are as follows.

[0152] Coloring Pigments

[0153] The coloring pigment is not particularly limited as long as it is a pigment used for coloring cosmetics, and includes red iron oxide (indicative name (INCI: Iron Oxides)), yellow iron oxide (indicative name (INCI: Iron Oxides)), white titanium oxide (indicative name (INCI: Titanium Dioxide)), black iron oxide (indicative name (INCI: Iron Oxides)), ultramarine (indicative name (INCI: Ultramarines)), cyan (indicative name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (indicative name (INCI: Manganese Violet)), cobalt titanate (indicative name (INCI: Cobalt Titanium Oxide)), chromium hydroxide (indicative name (INCI: Chromium Hydroxide Green)), chromium oxide (indicative name (INCI: Chromium Oxide Greens)), aluminum / cobalt oxide (indicative name (INCI: Cobalt Aluminum Inorganic brown pigments such as titanium nitride (INCI: Titanium Nitride), ferrous hydroxide (INCI: Iron Hydroxide), γ-iron oxide, and the like, inorganic yellow pigments such as loess, and colored pigments such as products obtained by laking tar pigments and products obtained by laking natural pigments can be used.

[0154] The shape of the pigment may be any shape, such as spherical, substantially spherical, rod-shaped, spindle-shaped, petal-shaped, elongated, or irregular, and the geometrical form is not particularly limited as long as it can impart color to the cosmetic.

[0155] Inorganic powder

[0156] Examples of the inorganic powder include zirconium oxide (INCI: Zirconium Dioxide), zinc oxide (INCI: Zinc Oxide), cerium oxide (INCI: Cerium Oxide), magnesium oxide (INCI: Magnesium Oxide), barium sulfate (INCI: Barium Sulfate), calcium sulfate (INCI: Calcium Carbonate), magnesium sulfate (INCI: Magnesium Sulfate), calcium carbonate (INCI: Calcium Carbonate), magnesium carbonate (INCI: Magnesium Carbonate), talc (INCI), mica (INCI), kaolin (INCI), synthetic fluorphlogopite (INCI: Synthetic Fluorphlogopite), synthetic phlogopite iron (INCI), biotite (INCI: Biotite), potassium silicate (INCI: Potassium Silicate), Silica (INCI), Aluminum Silicate (Indicative Name (INCI: Aluminum Silicate)), Magnesium Silicate (Indicative Name (INCI: Magnesium Silicate)), Silicic Acid (Aluminum / Magnesium) (Indicative Name (INCI: Magnesium Aluminum Silicate)), Calcium Silicate (Indicative Name (INCI: Calcium Silicate)), Silicic Acid (Aluminum / Calcium / Sodium) (Indicative Name (INCI: Aluminum Calcium Sodium Silicate)), Silicic Acid (Lithium / Magnesium / Sodium) (Indicative Name (INCI: Lithium Magnesium Sodium Silicate)), Silicic Acid (Sodium / Magnesium) (Indicative Name (INCI: Sodium Magnesium Silicate)), Borosilicate (Calcium / Aluminum) (Indicative Name (INCI: Calcium Aluminum Borosilicate)), Borosilicate (Calcium / Sodium) (Indicative Name (INCI: CalciumSodium Borosilicate), hydroxyapatite (INCI), bentonite (INCI), montmorillonite (INCI), hectorite (INCI), zeolite (INCI), alumina (INCI), aluminum hydroxide (INCI: Aluminum Hydroxide), boron nitride (INCI: BoronNitride)), glass (indicative name (INCI: Glass)), etc.

[0157] Inorganic colored pearl pigments include pearlescent agents such as mica (INCI) coated with titanium oxide (INCI: Titanium Dioxide), synthetic fluorphlogopite (INCI: Synthetic Fluorphlogopite) coated with titanium oxide (INCI: Titanium Dioxide), bismuth oxychloride (INCI: Bismuth Oxychloride), bismuth oxychloride (INCI: Bismuth Oxychloride) coated with titanium oxide (INCI: Titanium Dioxide), talc (INCI) coated with titanium oxide (INCI: Titanium Dioxide), fish scale foil (INCI), and colored mica coated with titanium oxide (INCI: Titanium Dioxide). The pigment may be untreated or may be subjected to a known surface treatment generally used in cosmetics, and is not particularly limited.

[0158] Metal powder

[0159] Examples of the metal powder include metal fine particles made of aluminum (INCI: Aluminum, Aluminum Powder), copper (INCI: Copper Powder), silver (INCI: Silver Powder), and gold (INCI: Gold).

[0160] Organic powder

[0161] Examples of the organic powder include powders composed of silicone, polyamide, polyacrylic acid-acrylate, polyester, polyethylene (INCI), polypropylene (INCI), polystyrene (INCI), styrene-acrylic acid copolymer, divinylbenzene-styrene copolymer, polyurethane, vinyl resin, urea resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate, cellulose (INCI), silk (INCI), nylon (indicative name), phenolic resin, epoxy resin, polycarbonate, and the like.

[0162] In particular, examples of silicone include silicone resin particles; polymethylsilsesquioxane (INCI), silicone rubber powder, silicone resin-coated silicone rubber powder; (vinyl dimethicone / methylpolysiloxane silsesquioxane) cross polymer (indicative name (INCI: vinyl dimethicone / methicone silsesquioxane crosspolymer)), (diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) cross polymer (indicative name (INCI: diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer)), polysilicone-1 cross polymer (INCI), polysilicone-22 (INCI), and the like.

[0163] Examples of commercially available powders made of silicone include KMP-590, KMP-591, KMP-592, KMP-597, KMP-598, KSP-100, KSP-101, KSP-102, KSP-105, KSP-300, KSP-411, KSP-441, KM-9729, and KM-440 manufactured by Shin-Etsu Chemical Co., Ltd.

[0164] In addition, metal soaps and the like can also be mentioned. Specific examples include powders consisting of zinc stearate (indicative name (INCI: Zinc Stearate)), aluminum stearate (indicative name (INCI: Aluminum Stearate)), calcium stearate (indicative name (INCI: Calcium Stearate)), magnesium stearate (indicative name (INCI: Magnesium Stearate)), zinc myristate (indicative name (INCI: Zinc Myristate)), magnesium myristate (indicative name (INCI: Magnesium Myristate)), cetyl phosphate (zinc / sodium) (indicative name (INCI: Sodium Zinc Cetyl Phosphate)), and potassium cetyl phosphate (indicative name (INCI: Potassium Cetyl Phosphate)).

[0165] Furthermore, organic pigments can also be mentioned. Specific examples include Red 3, Red 104 (1) (indicative name (INCI: Red 28, Red 28 Lake)), Red 106, Red 201 (indicative name (INCI: Red 6)), Red 202 (indicative name (INCI: Red 7)), Red 204, Red 205, Red 220 (indicative name (INCI: Red 34)), Red 226 (indicative name (INCI: Red 30)), Red 227 (indicative name (INCI: Red 33, RED 33 Lake)), Red 228 (indicative name (INCI: Red 36)), Red 230 (1) (indicative name (INCI: Red 22, Red 22 Lake)), Red 230 (2) (indicative name), Red 401 (indicative name), Red 505 (indicative name), Yellow 4 (indicative name (INCI: Yellow 5)), Yellow 5 (indicative name (INCI: Yellow 6, Yellow 6 Lake)), Yellow 202 (1) (Indication Name (INCI: Yellow 8)), Yellow 203 (Indication Name (INCI: Yellow 10, Yellow 10 Lake)), Yellow 204 (Indication Name (INCI: Yellow 11)), Yellow 401, Blue 1 (Indication Name (INCI: Blue 1, Blue 1 Lake)), Blue 2, Blue 201, Blue 205 (Indication Name (INCI: Blue 4)), Blue 404 (Indication Name), Green 3 (Indication Name (INCI: Green 3, Green 3 Lake)), Green 201 (Indication Name (INCI: Green 5)), Green 202 (Indication Name (INCI: Green 6)), Green 204 (Indication Name (INCI: Green 8)), Green 205 (Indication Name), Orange 201 (Indication Name (INCI: Orange 5)), Orange 203 (Indication Name (INCI: Pigment Orange 5)), Orange 204 (Indicative Name), Orange 205 (Indicative Name (INCI: Orange 4, Orange 4Lake)), Orange 206 (Indicative Name (INCI: Orange 10)), Orange 207 (Indicative Name (INCI: Orange 11)), etc., tar pigments, cochineal (INCI), lac acid (Indicative Name (INCI: Laccaic Acid)), safflower (Indicative Name (INCI: Carthamus Tinctorius (Safflower) Flower Extract)), ginkgo root extract (Indicative Name (INCI: Lithospermum OfficinaleRoot Extract)), Gardenia Yellow (indicated name), Gardenia Blue (indicated name (INCI: Hydrolyzed Gardenia Florida Extract)) and other natural pigments.

[0166] Inorganic-organic composite powder

[0167] Examples of the inorganic-organic composite powder include composite powders obtained by coating the surface of an inorganic powder with an organic powder by a known and commonly used method.

[0168] In addition, the above-mentioned powder can also be used as a powder whose particle surface is treated. In addition, from the viewpoint of water resistance of the cosmetic, the surface treatment agent is preferably capable of imparting hydrophobicity, and the treatment agent imparting hydrophobicity is not particularly limited, and examples thereof include silicone treatment agents, waxes, paraffins, organic fluorine compounds such as perfluoroalkyl and phosphates, surfactants, amino acids such as N-acyl glutamic acid, and metal soaps such as aluminum stearate and magnesium myristate.

[0169] More preferred are silicone treatment agents, and examples thereof include silanes or silanizing agents such as triethoxycaprylylsilane (INCI), dimethylpolysiloxane (INCI), methylpolysiloxane (INCI), hydrogendimethylpolysiloxane (INCI), triethoxysilylethyl polydimethylsiloxyethyl dimethicone (INCI), triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (INCI), and (Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / DimethiconeMethacrylate) Copolymer (Indicative name (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / DimethiconeMethacrylate Copolymer).

[0170] Specific examples of these silicone treatment agents include AES-3083, KF-99P, KF-9901, KF-9908, KF-9909, KP-574, KP-541, etc. manufactured by Shin-Etsu Chemical Co., Ltd. Furthermore, the above-mentioned surface hydrophobic treatment agents can be used alone or in combination of two or more. Specific examples of surface-treated coloring pigments include KTP-09 series manufactured by Shin-Etsu Chemical Co., Ltd., especially KTP-09W, KTP-09R, KTP-09Y, KTP-09B, etc.

[0171] Among these powders, oil-absorbing powders are particularly preferred in terms of the effects of suppressing stickiness and resisting secondary adhesion. Examples of oil-absorbing powders include silicone rubber powders, silicone resin-coated silicone rubber powders, porous powders, and fumed silica. Furthermore, the so-called oil absorption is an oil absorption of dimethylpolysiloxane (6cs) of 1.0 mL / g or more, preferably 1.2 mL / g or more, and more preferably 1.5 mL / g or more. The blending amount of the oil-absorbing powder is preferably 0.1 to 10% by mass, more preferably 1 to 8% by mass, and further preferably 3 to 8% by mass. If it exceeds 10% by mass, the spreadability of the cosmetic may sometimes deteriorate.

[0172] (5) Composition comprising a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature

[0173] In the composition comprising a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, the crosslinked organopolysiloxane is preferably swollen with respect to the liquid oil containing the liquid oil agent in an amount equal to or greater than the weight of the crosslinked organopolysiloxane. The liquid oil agent may be silicone oil, hydrocarbon oil, ester oil, natural animal and plant oil, semi-synthetic oil, or fluorine-based oil, which may be used as the component (B) or as the liquid in the oil agent (1) as an optional component. Examples thereof include cyclopentasiloxane (INCI), dimethyl polysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), and squalane (INCI).

[0174] Component (5) is different from component (3) above and is a compound that does not have a polyether or polyglycerol structure in its molecular structure. Specific examples thereof include (dimethicone / vinyl dimethicone) cross polymer (INCI), (dimethicone / phenyl vinyl dimethicone) cross polymer (indicative name (INCI: Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer)), (vinyl dimethicone / lauryl dimethicone) cross polymer (INCI), and (lauryl dimethylsiloxyethyl dimethicone / bisvinyl dimethicone) cross polymer (INCI).

[0175] Examples of commercially available compositions comprising a cross-linked organopolysiloxane and an oil that is liquid at room temperature include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-19, KSG-016F, KSG-18A, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-042Z, KSG-045Z, and KSG-048Z manufactured by Shin-Etsu Chemical Co., Ltd.

[0176] (6) Film-forming agents other than component (A)

[0177] The film-forming agent other than component (A) is mainly added to further maintain the effect sustainability of the cosmetic. Although not particularly limited, from the viewpoint of imparting water repellency, a silicone composition is preferred. Specifically, trimethylsiloxysilicate, acrylic-silicone film-forming agent, silicone-modified norbornene, silicone-modified pullulan, silicone-modified polyvinyl alcohol, etc. can be used.

[0178] Examples of the film-forming agent of the silicone composition include trimethylsiloxysilicate (INCI: Trimethylsiloxysilicate), (acrylate / dimethylpolysiloxane) copolymer (INCI), (norbornene / tris(trimethylsiloxy)silylnorbornene) copolymer (INCI), and tris(trimethylsiloxy)silylpropylcarbamate pullulan (INCI: Trimethylsiloxysilylcarbamoyl Pullulan).

[0179] The film-forming agent may be dissolved in an oily agent that is liquid at room temperature and then mixed into the cosmetic. The liquid oily agent may be silicone oil, hydrocarbon oil, ester oil, natural animal or plant oil, semi-synthetic oil, or fluorine oil, which may be the component (B) or may be used as the liquid in the oily agent (1) as an optional component. Examples thereof include cyclopentasiloxane (INCI), dimethylpolysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), squalane (INCI), and butyl acetate (INCI: Butyl Acetate).

[0180] Specific examples of commercially available silicone film-forming agents include KF-7312J, KP-545, KP-549, KP-543, NBN-30-ID, TSPL-30-ID, and TSPL-30-D5 manufactured by Shin-Etsu Chemical Co., Ltd.

[0181] (7) Ultraviolet light absorbing / scattering agent

[0182] Examples of the ultraviolet absorbing / scattering agent include particles that absorb and scatter ultraviolet light, such as microparticle titanium oxide, microparticle iron-containing titanium oxide, microparticle zinc oxide, microparticle cerium oxide, and composites thereof. A dispersion obtained by predispersing these ultraviolet absorbing and scattering particles in an oil may also be used.

[0183] As the oil agent, liquid silicone oils, hydrocarbon oils, ester oils, natural animal and plant oils, semi-synthetic oils, and fluorine-based oils listed in the above-mentioned component (B) or the oil agents other than component (B) in the above-mentioned (1) can be used, and examples thereof include cyclopentasiloxane (INCI), dimethylpolysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (INCI: Isotridecyl Isononanoate), and squalane (INCI).

[0184] Specific examples of dispersions in which particles that absorb and scatter ultraviolet rays are pre-dispersed in an oil include SPD series (trade name) manufactured by Shin-Etsu Chemical Co., Ltd., especially SPD-T5, SPD-T5L, SPD-Z5, SPD-Z5L, SPD-T6, SPD-Z6, SPD-T7, etc.

[0185] (8) Other additives

[0186] Other additives include oil-soluble gelling agents, preservatives / bactericides, antiperspirants, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin beautifying ingredients (whitening agents, cell activators, rough skin improvers, blood circulation promoters, skin astringents, anti-seborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc.

[0187] Oil-soluble gelling agent

[0188] Examples of the oil-soluble gelling agent include metal soaps selected from aluminum stearate, magnesium stearate, zinc myristate, and the like; amino acid derivatives such as lauroyl glutamic acid (indicative name (INCI: Lauroyl Glutamic Acid)) and α,γ-di-n-butylamine; dextrin palmitate (indicative name (INCI: Dextrin Palmitate)), dextrin isostearate (indicative name (INCI: Dextrin Isostearate)), dextrin myristate (indicative name (INCI: Dextrin Myristate)), stearoyl inulin (indicative name (INCI: Stearoyl Inulin)), dextrin (palmitic acid / ethylhexanoate) (indicative name (INCI: Dextrin Palmitate / Ethylhexanoate) and other dextrin fatty acid esters; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzyl derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; disteardimethylammonium hectorite (INCI), stearalkonium hectorite (INCI), organically modified clay minerals of hectorite; stearalkonium bentonite (INCI), etc.

[0189] Preservatives / fungicides

[0190] Examples of the preservative / bactericide include alkyl parabens, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, imidazolidinyl urea, salicylic acid, isopropyl methylphenol, carbolic acid, p-chloro-meta-cresol, hexachlorophene,

[0191] Benzalkonium chloride, chlorhexidine chloride, triclocarb, iodopropynyl butylcarbamate, polylysine, photosensitizer, silver, plant extracts, etc.

[0192] ·spices

[0193] As fragrances, there are natural fragrances and synthetic fragrances. As natural fragrances, there are plant fragrances separated from flowers, leaves, wood, peels, etc.; animal fragrances such as musk and civet. As synthetic fragrances, there are hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols; aldehydes such as terpene aldehydes and aromatic aldehydes; ketones such as alicyclic ketones; esters such as terpene esters; lactones; phenols; oxides; nitrogen-containing compounds; acetals, etc.

[0194] Salts

[0195] As salts, inorganic salts, organic acid salts, amine salts and amino acid salts can be listed. As inorganic salts, for example, sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, etc. of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, nitric acid, etc. can be listed. As organic acid salts, for example, salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, stearic acid, etc. can be listed. As amine salts and amino acid salts, for example, salts of amines such as triethanolamine, salts of amino acids such as glutamic acid, etc. can be listed. In addition, salts of hyaluronic acid, chondroitin sulfate, etc., and acid-base neutralization salts used in formulations, etc. can also be used.

[0196] Antioxidants

[0197] The antioxidant is not particularly limited, and examples thereof include carotenoids, ascorbic acid and salts thereof, ascorbyl stearate, tocopherol, tocopherol acetate, tocopherol, p-tert-butylphenol, butylhydroxyanisole, butylated hydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, sorbic acid and salts thereof, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, kaempferol, myricetin, quercetin, and the like.

[0198] pH adjuster

[0199] Examples of the pH adjuster include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium bicarbonate, and ammonium bicarbonate.

[0200] Chelating agents

[0201] Examples of the chelating agent include alanine, edetic acid sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like.

[0202] · Cooling agent

[0203] Examples of the cooling agent include L-menthol, camphor, and menthyl lactate.

[0204] Anti-inflammatory agents

[0205] Examples of the anti-inflammatory agent include allantoin, glycyrrhizic acid and its salts, glycyrrhetinic acid and glycyrrhetinic acid stearyl, tranexamic acid, and azulene.

[0206] Skin-beautifying ingredients

[0207] As skin beautifying ingredients, there can be listed whitening agents such as placenta extract, arbutin, glutathione, and saxifrage extract; cell activators such as royal jelly, photosensitizer, cholesterol derivatives, and calf blood extract; skin roughness improving agents, nonanoic acid valinamide, benzyl nicotinate, nicotinic acid β-butoxyethyl ester, capsaicin, ginger ketone, chelidonium tincture, ichthyol, caffeine, tannic acid, α-camphenol, nicotinic acid tocopherol, inositol hexanicotinate, cycloamycin, cinnarizine, triazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol and other blood circulation promoters; skin astringents; anti-seborrheic acid agents such as sulfur and methylthiophenol; and the like.

[0208] Vitamins

[0209] Examples of the vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate and the like, vitamin B2 such as riboflavin, riboflavin butyrate, flavin adenine nucleotide, vitamin B6 such as pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate, vitamin B6 such as vitamin B12, vitamin B13, vitamin B14, vitamin B15, vitamin B16, vitamin B17, vitamin B18, vitamin B19, vitamin B20, vitamin B21, vitamin B22, vitamin B23, vitamin B24, vitamin B25, vitamin B26, vitamin B27, vitamin B28, vitamin B29, vitamin B29, vitamin B21, vitamin B29, vitamin B21 12 Its derivatives, vitamin B 15 Vitamin B and its derivatives, L-ascorbic acid, L-ascorbyl dipalmitate, sodium L-ascorbic acid-2-sulfate, dipotassium L-ascorbyl phosphate, etc. Vitamin C, calciferol, cholecalciferol, etc. Vitamin D, α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, dl-α-tocopherol succinate, etc. Vitamin E; niacin, benzyl nicotinate, niacinamide, etc. Nicotinic acid, vitamin H, vitamin P, pantothenic acid, calcium pantothenate, D-panthenol, panthenyl ethyl ether, acetyl panthenyl ethyl ether, etc. Pantothenic acid, biotin, etc.

[0210] Amino Acids

[0211] Examples of the amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

[0212] Nucleic Acids

[0213] Examples of nucleic acids include deoxyribonucleic acid and the like.

[0214] ·hormone

[0215] Examples of the hormone include estradiol and vinyl estradiol.

[0216] Inclusion compounds

[0217] Examples of the inclusion compound include cyclodextrin and the like.

[0218] The above-mentioned cosmetic material can be in the form of an emulsified system or a non-aqueous system. When you want to give a moist feeling of use, select an emulsified form. As an emulsified form, it can be any form of an O / W type emulsion, a W / O type emulsion, an O / W / O type emulsion, or a W / O / W type emulsion. When you want to obtain oiliness and water resistance, you can select a non-aqueous composition or a powder composition, and obtain good cosmetics in all cases. In addition, in the present invention, the so-called "non-aqueous composition" refers to a composition that is intentionally not mixed with water. Among these, it is preferred to expect a particularly high oil resistance non-aqueous composition.

[0219] The crosslinked silicone resin of the present invention can be blended into cosmetics by various methods. For example, it can be prepared as a solution that is preliminarily dissolved in component (B), or it can be dried by a spray dryer or the like to prepare a state in which the solid component can be easily redissolved, or it can be prepared as an O / W emulsion and blended into cosmetics.

[0220] The cosmetics in the present invention are not particularly limited, and can be applied to various products such as beauty liquid, emulsion, cream, hair care, foundation, makeup base, sunscreen, concealer, blush, lipstick, gloss, balm, mascara, eye shadow, eyeliner, body makeup, deodorant, nail cosmetics, etc. Among these, makeup cosmetics such as foundation, makeup base, lipstick, mascara, eyeliner, and cosmetics with sunscreen effect are particularly preferred. As the properties of the cosmetics of the present invention, various properties such as liquid, cream, solid, paste, gel, mousse, spray, clay, powder, and stick can be selected.

[0221] Example

[0222] The present invention is described in more detail below using examples and comparative examples, but the present invention is not limited to the following examples. The "%" in the composition is mass % unless otherwise specified. The blending amount in the composition is the blending amount of the recorded blended product. In addition, the alkenyl-containing silicone resin used as a raw material in the following is synthesized according to a known manufacturing method. Furthermore, in the present invention, the cross-linked silicone resin and the cosmetic are respectively represented as examples. Furthermore, in the following examples and comparative examples, the reaction rate of the alkenyl group is expressed by 1 The H-NMR spectrum analysis was performed and the amount of the remaining alkenyl groups after the reaction was calculated.

[0223] [Example 1]

[0224] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0225] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 7430, vinyl value: 0.229 mmol / g) represented by the following average composition formula (E1), 700 g of decamethylcyclopentasiloxane, 126.9 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E2) (hydrogen gas generation: 20.3 mL / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 120°C for 8 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0226] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 221000). The reaction rate of the alkenyl group was 92%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.8 mL / g.

[0227] Formula (E1):

[0228] [Chemistry 9]

[0229]

[0230] Formula (E2):

[0231] [Chemistry 10]

[0232]

[0233] [Example 2]

[0234] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0235] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 8050, vinyl value: 0.224 mmol / g) represented by the following average composition formula (E3), 700 g of decamethylcyclopentasiloxane, 53.8 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E4) (hydrogen gas generation: 51.3 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 110°C for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0236] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 154000). The reaction rate of the alkenyl group was 93%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 1.0 mL / g.

[0237] Formula (E3):

[0238] [Chemistry 11]

[0239]

[0240] Formula (E4):

[0241] [Chemistry 12]

[0242]

[0243] [Example 3]

[0244] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0245] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 11450, vinyl value: 0.271 mmol / g) represented by the following average composition formula (E5), 700 g of decamethylcyclopentasiloxane, 109.0 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E6) (hydrogen gas generation: 30.6 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 90°C for 8 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0246] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 213000). The reaction rate of the alkenyl group was 93%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.8 mL / g.

[0247] Formula (E5):

[0248] [Chemistry 13]

[0249]

[0250] Formula (E6):

[0251] [Chemistry 14]

[0252]

[0253] [Example 4]

[0254] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0255] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 4180, vinyl value: 0.287 mmol / g) represented by the following average composition formula (E7), 700 g of decamethylcyclopentasiloxane, 142.4 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E8) (hydrogen gas generation: 22.6 mL / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 110°C for 3 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0256] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 58600). The reaction rate of the alkenyl group was 94%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.8 mL / g.

[0257] Formula (E7):

[0258] [Chemistry 15]

[0259]

[0260] Formula (E8):

[0261] [Chemistry 16]

[0262]

[0263] [Example 5]

[0264] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0265] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdery alkenyl-containing silicone resin (weight average molecular weight 6910, vinyl value: 0.333 mmol / g) represented by the following average composition formula (E9), 700 g of decamethylcyclopentasiloxane, 36.3 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E10) (hydrogen generation amount: 51.3 mL / g, hydrosilyl group / vinyl group=0.5), 92.1 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E11) (hydrogen generation amount: 20.3 mL / g, hydrosilyl group / vinyl group=0.5), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and reacted by heating at 120° C. for 8 hours. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, the mixture was filtered to obtain a decamethylcyclopentasiloxane solution of a crosslinked silicone resin.

[0266] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 184000). The reaction rate of the alkenyl group was 93%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.9 mL / g.

[0267] Formula (E9):

[0268] [Chemistry 17]

[0269]

[0270] Formula (E10):

[0271] [Chemistry 18]

[0272]

[0273] Formula (E11):

[0274] [Chemistry 19]

[0275]

[0276] [Example 6]

[0277] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0278] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 7120, vinyl value: 0.197 mmol / g) represented by the following average composition formula (E12), 700 g of decamethylcyclopentasiloxane, 47.2 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E13) (hydrogen gas generation: 51.3 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 100°C for 6 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0279] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 56000). The reaction rate of the alkenyl group was 94%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.6 mL / g.

[0280] Formula (E12):

[0281] [Chemistry 20]

[0282]

[0283] Formula (E13):

[0284] [Chemistry 21]

[0285]

[0286] [Example 7]

[0287] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0288] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 7310, vinyl value: 0.274 mmol / g) represented by the following average composition formula (E14), 700 g of decamethylcyclopentasiloxane, 135.6 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E15) (hydrogen gas generation: 22.6 mL / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 80°C for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0289] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 62800). The reaction rate of the alkenyl group was 92%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.5 mL / g.

[0290] Formula (E14):

[0291] [Chemistry 22]

[0292]

[0293] Formula (E15):

[0294] [Chemistry 23]

[0295]

[0296] [Example 8]

[0297] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0298] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 14860, vinyl value: 0.323 mmol / g) represented by the following average composition formula (E16), 700 g of decamethylcyclopentasiloxane, 160.0 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E17) (hydrogen gas generation: 22.6 mL / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 110°C for 3 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0299] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 168500). The reaction rate of the alkenyl group was 92%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.5 mL / g.

[0300] Formula (E16):

[0301] [Chemistry 24]

[0302]

[0303] Formula (E17):

[0304] [Chemistry 25]

[0305]

[0306] [Example 9]

[0307] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0308] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 6880, vinyl value: 0.276 mmol / g) represented by the following average composition formula (E18), 700 g of decamethylcyclopentasiloxane, 10.2 g of tetramethyldisiloxane represented by the following formula (E19) (hydrogen generation: 334.3 mL / g, hydrosilyl group / vinyl group = 1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 120° C. for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, the mixture was filtered to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0309] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 112000). The reaction rate of the alkenyl group was 91%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.9 mL / g.

[0310] Formula (E18):

[0311] [Chemistry 26]

[0312]

[0313] Formula (E19):

[0314] [Chemistry 27]

[0315]

[0316] (In formula (2), e=2, f=g=h=0)

[0317] [Example 10]

[0318] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0319] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 10100, vinyl value: 0.178 mmol / g) represented by the following average composition formula (E20), 700 g of decamethylcyclopentasiloxane, 42.8 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E21) (hydrogen generation: 51.3 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 90°C for 10 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0320] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 389000). The reaction rate of the alkenyl group was 92%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.7 mL / g.

[0321] Formula (E20):

[0322] [Chemistry 28]

[0323]

[0324] (* is a free radical bonded to a silicon atom.)

[0325] Formula (E21):

[0326] [Chemistry 29]

[0327]

[0328] [Example 11]

[0329] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0330] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 6700, vinyl value: 0.388 mmol / g) represented by the following average composition formula (E22), 700 g of decamethylcyclopentasiloxane, 109.2 g of an organopolysiloxane having a hydrosilyl group in a side chain represented by the following formula (E23) (hydrogen gas generation: 39.8 mL / g, hydrosilyl group / vinyl group = 1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 120° C. for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0331] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 105000). The reaction rate of the alkenyl group was 93%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.6 mL / g.

[0332] Formula (E22):

[0333] [Chemistry 30]

[0334]

[0335] Formula (E23):

[0336] [Chemistry 31]

[0337]

[0338] [Example 12]

[0339] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0340] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 8730, vinyl value: 0.275 mmol / g) represented by the following average composition formula (E24), 700 g of decamethylcyclopentasiloxane, 39.7 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E25) (hydrogen gas generation: 77.5 mL / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 120°C for 3 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0341] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 84200). The reaction rate of the alkenyl group was 95%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 1.0 mL / g.

[0342] Formula (E24):

[0343] [Chemistry 32]

[0344]

[0345] Formula (E25):

[0346] [Chemistry 33]

[0347]

[0348] [Example 13]

[0349] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0350] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 16180, vinyl value: 0.266 mmol / g) represented by the following average composition formula (E26), 700 g of decamethylcyclopentasiloxane, 63.9 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E27) (hydrogen gas generation: 51.3 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 100°C for 6 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0351] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 208000). The reaction rate of the alkenyl group was 92%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.8 mL / g.

[0352] Formula (E26):

[0353] [Chemistry 34]

[0354]

[0355] Formula (E27):

[0356] [Chemistry 35]

[0357]

[0358] [Example 14]

[0359] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0360] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 3100, vinyl value: 0.419 mmol / g) represented by the following average composition formula (E28), 700 g of decamethylcyclopentasiloxane, 100.7 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E29) (hydrogen gas generation: 51.3 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 110°C for 6 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0361] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 65000). The reaction rate of the alkenyl group was 92%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.7 mL / g.

[0362] Formula (E28):

[0363] [Chemistry 36]

[0364]

[0365] Formula (E29):

[0366] [Chemistry 37]

[0367]

[0368] [Example 15]

[0369] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0370] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 11730, vinyl value: 0.307 mmol / g) represented by the following average composition formula (E30), 700 g of decamethylcyclopentasiloxane, 78.5 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E31) (hydrogen gas generation: 43.8 mL / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 120°C for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, filtration was performed to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0371] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 96500). The reaction rate of the alkenyl group was 97%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.9 mL / g.

[0372] Formula (E30):

[0373] [Chemistry 38]

[0374]

[0375] Formula (E31):

[0376] [Chemistry 39]

[0377]

[0378] [Comparative Example 1]

[0379] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0380] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered hydrosilyl-containing silicone resin (weight average molecular weight 4420, hydrogen generation: 7.6 mL / g) represented by the following average composition formula (E32), 700 g of decamethylcyclopentasiloxane, 157 g of an organopolysiloxane having vinyl groups at both ends represented by the following formula (E33) (vinyl value: 2.16 mmol / g, hydrosilyl group / vinyl group=1.0), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 120°C for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, the mixture was filtered to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0381] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure to remove the decamethylcyclopentasiloxane, thereby obtaining a solid powder (weight average molecular weight 128000). The reaction rate of the hydrosilyl group was 71%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 2.2 mL / g.

[0382] Formula (E32):

[0383] [Chemistry 40]

[0384]

[0385] Formula (E33):

[0386] [Chemistry 41]

[0387]

[0388] [Comparative Example 2]

[0389] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0390] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered silicone resin containing a hydrosilyl group (weight average molecular weight 5180, hydrogen generation amount: 9.1 mL / g) represented by the following average composition formula (E34), 188 g of an organopolysiloxane having vinyl groups at both ends represented by the following formula (E35) (vinyl value: 2.16 mmol / g, hydrosilyl group / vinyl group=1.0), 700 g of decamethylcyclopentasiloxane, and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were charged into a reactor and heated at 100° C. for 6 hours to react. Then, the solvent was distilled off by heating under reduced pressure. Furthermore, after adding 250 g of ethanol, 5 g of a 5% sodium hydroxide aqueous solution was added to hydrolyze the unreacted hydrosilyl group, and 0.63 g of concentrated hydrochloric acid was added to neutralize. The reaction product was heated under reduced pressure, the solvent was distilled off, and the mixture was filtered to obtain a decamethylcyclopentasiloxane solution of a crosslinked silicone resin.

[0391] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a solid powder (weight average molecular weight 96000). The reaction rate of the hydrosilyl group was 78%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 2.0 mL / g.

[0392] Formula (E34):

[0393] [Chemistry 42]

[0394]

[0395] Formula (E35):

[0396] [Chemistry 43]

[0397]

[0398] [Comparative Example 3]

[0399] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdered alkenyl-containing silicone resin (weight average molecular weight 7050, vinyl value: 0.794 mmol / g) represented by the following average composition formula (E36), 700 g of decamethylcyclopentasiloxane, 190.7 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E37) (hydrogen generation: 51.3 mL / g, hydrosilyl group / vinyl group=1.1), and 0.6 g of a 0.5% 2-propanol solution of chloroplatinic acid were placed in a reactor and heated at 110°C for 5 hours to react. The viscosity increased during the reaction and gelled in the reactor. No film was formed.

[0400] Formula (E36):

[0401] [Chemistry 44]

[0402]

[0403] Formula (E37):

[0404] [Chemistry 45]

[0405]

[0406] [Comparative Example 4]

[0407] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0408] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdery alkenyl-containing silicone resin (weight average molecular weight: 8050, vinyl value: 0.224 mmol / g) represented by the following average composition formula (E38), 700 g of decamethylcyclopentasiloxane, and 190.3 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E39) (hydrogen gas generation amount:

[0409] 14.5mL / g, hydrosilyl / vinyl=1.1), 0.6g of 0.5% chloroplatinic acid 2-propanol solution was charged into a reactor and heated at 110°C for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, the mixture was filtered to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0410] The decamethylcyclopentasiloxane solution of the obtained cross-linked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a product in the form of a raw gel (weight average molecular weight 681000). The reaction rate of the alkenyl group was 98%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.3 mL / g.

[0411] Formula (E38):

[0412] [Chemistry 46]

[0413]

[0414] Formula (E39):

[0415] [Chemistry 47]

[0416]

[0417] [Comparative Example 5]

[0418] Method for producing 30% solution of cross-linked silicone resin / decamethylcyclopentasiloxane

[0419] 1000 g of a 50% decamethylcyclopentasiloxane solution of a powdery alkenyl-containing silicone resin (weight average molecular weight: 8050, vinyl value: 0.224 mmol / g) represented by the following average composition formula (E40), 700 g of decamethylcyclopentasiloxane, and 372.9 g of an organopolysiloxane having hydrosilyl groups at both ends represented by the following formula (E41) (hydrogen gas generation amount:

[0420] 7.4mL / g, hydrosilyl / vinyl=1.1), 0.6g of 0.5% chloroplatinic acid 2-propanol solution was charged into a reactor and heated at 110°C for 5 hours to react. Then, the solvent was distilled off by heating under reduced pressure. After adding decamethylcyclopentasiloxane to adjust the concentration to 30%, the mixture was filtered to obtain a decamethylcyclopentasiloxane solution of a cross-linked silicone resin.

[0421] The decamethylcyclopentasiloxane solution of the obtained crosslinked silicone resin was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane was removed to obtain a raw gel-like powder (weight average molecular weight 724000). The reaction rate of the alkenyl group was 97%, and the amount of hydrogen gas generated from the remaining hydrosilyl group was 0.3 mL / g.

[0422] Formula (E40):

[0423] [Chemistry 48]

[0424]

[0425] Formula (E41):

[0426] [Chemistry 49]

[0427]

[0428] [Comparative Example 6]

[0429] Shin-Etsu Chemical Co., Ltd.: KF-7312J (trimethylsiloxysilicate: 50%, cyclopentasiloxane: 50%)

[0430] [Comparative Example 7]

[0431] Shin-Etsu Chemical Co., Ltd.: KF-9021 (trimethylsiloxysilicate: 50%, cyclopentasiloxane: 50%)

[0432] <Temporal stability>

[0433] The decamethylcyclopentasiloxane solutions of the crosslinked silicone resin obtained in the above Examples and Comparative Examples were stored in a thermostat at 50° C., and the viscosity was measured after 2 weeks and one month, and evaluated according to the following criteria. The results are shown in Table 1.

[0434] ◎: The difference between the viscosity value immediately after production and the viscosity value after storage at 50°C is less than 5%

[0435] ○: The difference between the viscosity value immediately after production and the viscosity value after storage at 50°C is 5% or more and less than 10%

[0436] ×: The difference between the viscosity value immediately after production and the viscosity value after storage at 50°C is 10% or more

[0437] [Table 1]

[0438] 2 weeks later 1 month later Example 1 ◎ ◎ Example 2 ◎ ◎ Example 3 ◎ ◎ Example 4 ◎ ◎ Example 5 ◎ ◎ Example 6 ◎ ◎ Example 7 ◎ ◎ Example 8 ◎ ◎ Example 9 ◎ ◎ Example 10 ◎ ◎ Embodiment 11 ◎ ◎ Example 12 ◎ ◎ Embodiment 13 ◎ ◎ Embodiment 14 ◎ ◎ Embodiment 15 ◎ ◎ Comparative Example 1 ○ × Comparative Example 2 × ×

[0439] For Examples 1 to 15, the difference between the viscosity value just after manufacture and the viscosity value after 2 weeks and 1 month is less than 5%, and the stability after time is good. It is believed that the alkenyl group in the silicone resin has high reactivity and the amount of residual hydrosilyl groups is small, so the reaction after time is suppressed as the main reason. Comparative Example 1 is a solution of a cross-linked silicone resin using a silicone resin containing a hydrosilyl group as a raw material. It is believed that since the reactivity is low compared to the alkenyl group and the amount of residual hydrosilyl groups is large, the slow reaction after time is the main reason for the increase in viscosity. Comparative Example 2 is a solution of a cross-linked silicone resin using a silicone resin containing a hydrosilyl group as a raw material and subjected to an alkali treatment. It is believed that the residual hydrosilyl groups in the silicone resin cannot be completely inactivated even with an alkali treatment, and the slow reaction after time is the main reason for the increase in viscosity. Furthermore, it is believed that the main reason is that the pH is biased towards alkalinity compared to Comparative Example 1, and the rate of increase in viscosity is accelerated.

[0440] The shape at 25° C., film-forming ability, and physical properties (continuity, hardness, and bendability) of each silicone resin obtained in the above Examples and Comparative Examples were evaluated as follows. The results are shown in Table 2 below.

[0441] 1) The decamethylcyclopentasiloxane solution or other solution obtained in the above Examples and Comparative Examples was heated to 120-130° C. under reduced pressure, and the decamethylcyclopentasiloxane or other solvent was removed to obtain a silicone resin, and the shape at 25° C. was observed.

[0442] 2) Regarding the film forming ability, 1.5 g of a 30% solution diluted with a solvent (isododecane or decamethylcyclopentasiloxane) was dropped into a PTFE (fluororesin) container and then dried at 105°C for 3 hours to evaluate whether a self-standing film was formed.

[0443] 3) Regarding the continuity of the film, whether the film produced in 2) above was a continuous film (that is, whether there were cracks) was evaluated. The film without cracks was evaluated as "having continuity".

[0444] 4) Regarding the hardness of the coating, whether or not a nail could penetrate into the coating produced in the above 2) was evaluated. The coating that could be penetrated by a nail was recorded as "soft".

[0445] 5) Regarding the stickiness of the film, the stickiness of the film produced in the above 2) was evaluated as "absent" or "present".

[0446] 6) Regarding bendability, whether the coating formed by the method 2) above bends when it is bent on an aluminum dish was evaluated. If the coating is cracked, the bendability is recorded as "None".

[0447] [Table 2]

[0448] shape Film forming ability Continuity of coating Hardness of coating Stickiness of the coating Flexibility Example 1 Solid have have soft none have Example 2 Solid have have hard none have Example 3 Solid have have hard none have Example 4 Solid have have hard none have Example 5 Solid have have soft none have Example 6 Solid have have hard none have Example 7 Solid have have hard none have Example 8 Solid have have hard none have Example 9 Solid have have hard none have Example 10 Solid have have hard none have Embodiment 11 Solid have have hard none have Example 12 Solid have have hard none have Embodiment 13 Solid have have soft none have Embodiment 14 Solid have have hard none have Embodiment 15 Solid have have hard none have Comparative Example 3 Gel none Comparative Example 4 Raw gelatin have have soft have have Comparative Example 5 Raw gelatin have have soft have have Comparative Example 6 Solid have none hard none none Comparative Example 7 Solid have none hard none none

[0449] Examples 1 to 15 all obtained uniform continuous films, which were non-sticky and non-brittle films. In addition, they were films with high bendability when bent. Comparative Example 3 reacted an alkenyl-rich silicone resin with an organohydrogenpolysiloxane, resulting in a high crosslinking density and a gel, without obtaining film formation properties. Comparative Examples 4 and 5 were films composed of a crosslinked silicone resin crosslinked with an organohydrogenpolysiloxane with a long chain length. They were both continuous, soft films, and were in the form of raw rubber, so they were highly sticky. Comparative Examples 6 and 7 were films composed of a non-crosslinked silicone resin composed of M units and Q units. They were non-sticky but cracked hard films, and the films could be easily cracked by bending. From the above, it can be seen that the crosslinked silicone resin of the present invention has greatly improved bending and stickiness properties compared to existing non-crosslinked silicone resins.

[0450] 3 μL of squalane, oleic acid, and triisooctanoin were dropped into each of the films obtained in Examples 1 to 15 and Comparative Examples 6 and 7, and the contact angles were measured. The results are shown in Table 3 below.

[0451] [Table 3]

[0452]

[0453] In Examples 1 to 15, the contact angles for all oils including squalane, oleic acid, and triethylhexanoin were large, indicating high oil resistance. On the other hand, in Comparative Examples 6 and 7, the contact angles for all oils were low, indicating low oil resistance. The oil resistance of non-crosslinked silicone resins tends to improve as the molecular weight increases, but since the molecular weight increase of non-crosslinked silicone resins is limited, the oil resistance also has a limit. The crosslinking of the silicone resin by the crosslinking agent may cause the molecular weight of the silicone resin to increase, and thus has the effect of increasing its limit. Therefore, the crosslinked silicone resin of the present invention can have oil resistance that conventional non-crosslinked silicone resins cannot achieve.

[0454] The solid powder obtained in Example 3 was mixed with isododecane, methyl trimethyl polysiloxane, dimethyl polysiloxane (KF-96-2cs and 6cs), triethylhexanoin, and isotridecyl isononanoate at a solid content concentration of 50%, and a solubility test was performed. The results are shown in Table 4 below.

[0455] ○: Transparent dissolution

[0456] △: Slightly turbid

[0457] ×: Separated.

[0458] [Table 4]

[0459] Oil Appearance Isododecane ○ Methyl trimethicone 〇 KF-96-2cs 〇 KF-96-6cs 〇 Triethylhexanoin 〇 Isotridecyl isononanoate 〇

[0460] Furthermore, the obtained polymer can also be dissolved in silicone and ester oils used in cosmetics other than the above-mentioned oils. In addition, the viscosity of these solutions can vary depending on the composition and molecular weight of the polymer.

[0461] [Example 16, Comparative Examples 8 and 9]

[0462] Emulsified cream foundations having the compositions shown in Table 4 below were prepared.

[0463] [Table 5]

[0464]

[0465] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-210 (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-15 (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6017 (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-56A (Note 5) Shin-Etsu Chemical Co., Ltd.: KSP-100 (Note 6) Shin-Etsu Chemical Co., Ltd.: KP-578 (Note 7) Shin-Etsu Chemical Co., Ltd.: KTP-09W (Note 8) Shin-Etsu Chemical Co., Ltd.: KTP-09Y (Note 9) Shin-Etsu Chemical Co., Ltd.: KTP-09R

[0466] (Note 10) Shin-Etsu Chemical Co., Ltd.: KTP-09B

[0467] (Note 11) Shin-Etsu Chemical Co., Ltd.: KF-9021 (trimethylsiloxysilicate: 50%, cyclopentasiloxane: 50%)

[0468] <Preparation of cosmetics>

[0469] A: Components 1 to 7 are uniformly mixed.

[0470] B: Components 8 to 13 were dispersed using a triple roll.

[0471] C: Components 16 to 19 are uniformly mixed.

[0472] D: The mixture obtained in C was added to the mixture obtained in A, emulsified, and B, component 14, and component 15 were added to obtain an emulsified foundation cream. The following evaluations were performed on the obtained emulsified foundation cream.

[0473] [Feeling of use (sticky feeling)]

[0474] The obtained emulsified foundation cream was evaluated for "stickiness" by a panel of 10 female professionals using the following criteria, and the average of the evaluation results was calculated. Based on the obtained average score, the results were judged according to the following criteria.

[0475] [Evaluation criteria]

[0476] 5 points: Very good

[0477] 4 points: Good

[0478] 3 points: Average

[0479] 2 points: Slightly poor

[0480] 1 point: Poor

[0481] [Judgment criteria]

[0482] ◎: Average score is 4.0 or above

[0483] ○: The average score is 3.0 or more and less than 4.0

[0484] △: Average score is 2.0 or more and less than 3.0

[0485] ×: Average score is less than 2.0

[0486] [Elongation (spreadability)]

[0487] The obtained emulsified foundation was subjected to dynamic friction measurement using TL201Tt manufactured by Trinita Lab Co., Ltd., and evaluated based on the following criteria in comparison with a blank.

[0488] ◎: Less than 105%

[0489] ○: 105% or more and less than 110%

[0490] △: 110% or more and less than 115%

[0491] ×: 115% or more

[0492] [Anti-secondary adhesion]

[0493] An equal amount of the obtained emulsified foundation was applied on synthetic leather and dried at 50°C for 3 hours. Then, filter paper was overlapped and a load of 500 g was applied. Transfer to the filter paper was compared and evaluated according to the following criteria.

[0494] ◎: Almost no transfer

[0495] ○: There is little transfer

[0496] △: With transfer

[0497] ×: There is considerable transfer

[0498] All scores above “0” were considered as passing.

[0499] [Table 6]

[0500]

[0501] As shown in Table 5, the cosmetic of the present invention is significantly superior to Comparative Examples 8 and 9 in terms of feeling during use, elongation (spreadability), and secondary adhesion prevention.

[0502] Examples of cosmetics are shown below. Evaluation was performed using the same criteria as above.

[0503] [Example 17]

[0504] Non-aqueous foundation

[0505] <Preparation of cosmetics>

[0506] A: Components 1 to 11 are uniformly mixed.

[0507] B: Components 12 to 15 are uniformly mixed using a homomixer.

[0508] C: The mixture obtained in B was added to the mixture obtained in A, mixed uniformly, and ingredient 16 was added to obtain a non-aqueous foundation.

[0509]

[0510]

[0511] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSP-100

[0512] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0513] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6038

[0514] (Note 4) Shin-Etsu Chemical Co., Ltd.: KP-550

[0515] (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-6115

[0516] (Note 6) Shin-Etsu Chemical Co., Ltd.: KTP-09W, Y, R, B

[0517] It was confirmed that the obtained non-aqueous foundation had a good feel during use, good elongation, and excellent secondary adhesion resistance.

[0518] [Example 18]

[0519] W / O foundation

[0520] <Preparation of cosmetics>

[0521] A: Components 2 to 9 are uniformly mixed.

[0522] B: Components 10 to 13 were uniformly mixed using a high-pressure mixer.

[0523] C: Components 14 to 17 are uniformly mixed.

[0524] D: The mixture obtained in C was added to the mixture obtained in A, emulsified, and the mixture obtained in B and component 1 were added to obtain a W / O foundation.

[0525]

[0526] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-830

[0527] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0528] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6105

[0529] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSG-18A

[0530] (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-4422

[0531] (Note 6) Shin-Etsu Chemical Co., Ltd.: KSP-105

[0532] (Note 7) Shin-Etsu Chemical Co., Ltd.: KP-578

[0533] (Note 8) Shin-Etsu Chemical Co., Ltd.: KTP-09W, Y, R, B

[0534] It was confirmed that the obtained W / O foundation had a good feel during use, good elongation, and excellent secondary adhesion resistance.

[0535] [Example 19]

[0536] O / W substrate

[0537] <Preparation of cosmetics>

[0538] A: Mix components 1 to 4 uniformly.

[0539] B: Components 5 to 14 are uniformly mixed.

[0540] C: The mixture obtained in A was added to the mixture obtained in B and emulsified to obtain an O / W base.

[0541]

[0542] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-19

[0543] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0544] (Note 3) SPD-T7 manufactured by Shin-Etsu Chemical Co., Ltd.

[0545] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-6043

[0546] (Note 5) Made by SEPPIC: SIMULGEL EG

[0547] It was confirmed that the obtained O / W base had a good feel during use, good elongation, and excellent transfer resistance of the superimposed base.

[0548] [Example 20]

[0549] Oily mascara

[0550] <Preparation of cosmetics>

[0551] A: Heat components 1 to 9 to 95°C and mix uniformly.

[0552] B: Components 10 to 14 were uniformly mixed using a DISPER.

[0553] C: The mixture obtained in B was added to the mixture obtained in A, mixed uniformly at 90° C., and slowly cooled to obtain an oily mascara.

[0554]

[0555]

[0556] (Note 1) Shin-Etsu Chemical Co., Ltd.: X-21-5595

[0557] (Note 2) Made by Chiba Flour Milling Co., Ltd.: Leopal KL2

[0558] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-9909 treatment

[0559] (Note 4) Shin-Etsu Chemical Co., Ltd.: KMP-590

[0560] (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-6028

[0561] The obtained oily mascara was confirmed to have a good feel during use, good makeup durability, good elongation, good finish, and excellent scratch resistance. In addition, by using a hard and brittle coating such as trimethylsiloxysilicate, it is possible to adjust the coating performance, finish, and other feel during use.

[0562] [Example 21]

[0563] W / O Mascara

[0564] <Preparation of cosmetics>

[0565] A: Heat components 1 to 7 to 95°C and mix uniformly.

[0566] B: Components 11 to 14 were uniformly mixed using a disper, A was added, and the mixture was heated to 90°C.

[0567] C: Add components 8 to 10 to the mixture obtained in B, heat to 85°C, and mix uniformly.

[0568] D: Heat components 15 to 17 to 85°C and mix uniformly.

[0569] E: The mixture obtained in D was added to the mixture obtained in C, and the mixture was emulsified and then slowly cooled to obtain a W / O mascara.

[0570]

[0571]

[0572] (Note 1) Shin-Etsu Chemical Co., Ltd.: KP-550

[0573] (Note 2) Made by Chiba Flour Milling Co., Ltd.: Leopal TT2

[0574] (Note 3) Shin-Etsu Chemical Co., Ltd.: KP-561P

[0575] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0576] (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-9901 treatment

[0577] (Note 6) Made by Japan AEROSIL Co., Ltd.: AEROSIL972

[0578] (Note 7) Shin-Etsu Chemical Co., Ltd.: KF-6017

[0579] The obtained W / O mascara was confirmed to have a good feel in use, good makeup durability, good elongation, good finish, and excellent scratch resistance. In addition, by using a flexible coating such as a silicone-modified acrylic polymer, it is possible to adjust the feel of use such as coating performance and finish.

[0580] [Example 22]

[0581] Lipstick

[0582] <Preparation of cosmetics>

[0583] A: Components 9 to 16 were dispersed using a triple roll.

[0584] B: Heat components 1 to 8 to 95°C and mix uniformly.

[0585] C: The mixture obtained in A, the mixture obtained in B, and components 17 to 18 were uniformly mixed and heated to 85°C.

[0586] D: The mixture obtained in C was filled into a stick-shaped container to obtain a lipstick.

[0587]

[0588] (Note 1) Shin-Etsu Chemical Co., Ltd.: KP-561P

[0589] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-54HV

[0590] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-574 treatment

[0591] It was confirmed that the obtained lipstick had a good feeling during use, good makeup durability, good elongation and finish, and excellent scratch resistance.

[0592] [Example 23]

[0593] W / O Sunscreen

[0594] <Preparation of cosmetics>

[0595] A: Components 1 to 12 are uniformly mixed.

[0596] B: Components 15 to 21 are uniformly mixed.

[0597] C: The mixture obtained in B was added to the mixture obtained in A to emulsify, and components 13 and 14 were added and mixed uniformly to obtain a W / O sunscreen lotion.

[0598]

[0599] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-18A

[0600] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-6038

[0601] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0602] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSP-105

[0603] (Note 5) Shin-Etsu Chemical Co., Ltd.: SPD-T7

[0604] (Note 6) Shin-Etsu Chemical Co., Ltd.: SPD-Z5

[0605] It was confirmed that the obtained W / O sunscreen milk had a good feeling during use, good makeup durability, and excellent elongation.

[0606] [Example 24]

[0607] W / O Sunscreen

[0608] <Preparation of cosmetics>

[0609] A: Components 1 to 7 are uniformly mixed.

[0610] B: Components 10 to 13 are uniformly mixed.

[0611] C: The mixture obtained in B was added to the mixture obtained in A, emulsified, and components 8 and 9 were added and uniformly mixed to obtain a W / O sunscreen lotion.

[0612]

[0613] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-210

[0614] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-19

[0615] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6028

[0616] (Note 4) Shin-Etsu Chemical Co., Ltd.: SPD-T5

[0617] (Note 5) Shin-Etsu Chemical Co., Ltd.: SPD-Z5

[0618] It was confirmed that the obtained W / O sunscreen milk had a good feeling during use, good makeup durability, and excellent elongation.

[0619] [Example 25]

[0620] W / O Cream Foundation

[0621] <Preparation of cosmetics>

[0622] A: Components 9 to 12 were dispersed using a triple roll.

[0623] B: Mix components 3 to 5 evenly, add components 1, 2, 6 to 8, and mix evenly.

[0624] C: Components 13 to 17 are uniformly mixed.

[0625] D: The mixture obtained in C was added to the mixture obtained in B, emulsified, and the mixture obtained in A was added to obtain a W / O foundation cream.

[0626]

[0627]

[0628] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-330

[0629] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-41A

[0630] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6048

[0631] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSP-300

[0632] (Note 5) Shin-Etsu Chemical Co., Ltd.: KP-578

[0633] (Note 6) Shin-Etsu Chemical Co., Ltd.: KTP-09W

[0634] (Note 7) Shin-Etsu Chemical Co., Ltd.: KTP-09Y, R, B

[0635] It was confirmed that the obtained W / O cream foundation had a good feeling during use, good makeup durability, good elongation and finish, and excellent scratch resistance.

[0636] [Example 26]

[0637] W / O Liquid Foundation

[0638] <Preparation of cosmetics>

[0639] A: Components 7 to 13 were dispersed using DISPER.

[0640] B: Heat and mix components 4 to 6 uniformly, add components 1 to 3, and mix uniformly.

[0641] C: Components 14 to 19 are uniformly mixed.

[0642] D: The mixture obtained in C was added to the mixture obtained in B to emulsify, and the mixture obtained in A was added to obtain a W / O liquid foundation.

[0643]

[0644]

[0645] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-210

[0646] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-18A

[0647] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6028

[0648] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0649] (Note 5) Shin-Etsu Chemical Co., Ltd.: AES-3083 treatment

[0650] It was confirmed that the obtained W / O liquid foundation had a good feeling during use, good makeup durability, good elongation and finish, and excellent scratch resistance.

[0651] [Example 27]

[0652] W / O Stick Foundation

[0653] <Preparation of cosmetics>

[0654] A: Components 10 to 14 were dispersed using a triple roll.

[0655] B: Heat components 1 to 9 to 95°C and mix uniformly.

[0656] C: A and components 15 to 16 are uniformly mixed and heated to 85°C.

[0657] D: The mixture obtained in C was added to the mixture obtained in B, emulsified at 85° C., filled in a stick-shaped container, and then slowly cooled to obtain a W / O stick foundation.

[0658]

[0659]

[0660] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-710

[0661] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-6038

[0662] (Note 3) Made by Chiba Flour Milling Co., Ltd.: Leopal ISK2

[0663] (Note 4) Shin-Etsu Chemical Co., Ltd.: KMP-590

[0664] (Note 5) Shin-Etsu Chemical Co., Ltd.: KTP-09W

[0665] (Note 6) Shin-Etsu Chemical Co., Ltd.: KTP-09R, Y, B

[0666] (Note 7) Shin-Etsu Chemical Co., Ltd.: KF-6011

[0667] (Note 8) Shin-Etsu Chemical Co., Ltd.: KF-6013

[0668] It was confirmed that the obtained W / O stick foundation had a good feeling during use, good makeup durability, good elongation and finish, and excellent rub resistance.

[0669] [Example 28]

[0670] Infusion foundation

[0671] <Preparation of cosmetics>

[0672] A: Components 10 to 14 are dispersed using a roll mill.

[0673] B: Disperse components 1 to 7 using DISPER, add components 8 and 9, heat to 95°C, and mix evenly.

[0674] C: Add the mixture obtained in A to the mixture obtained in B, mix evenly, and heat to 85°C.

[0675] D: The mixture obtained in C was filled into a container to obtain a poured foundation.

[0676]

[0677] (Note 1) Example 13 was dried using a spray dryer to obtain a solid.

[0678] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSP-101

[0679] (Note 3) Shin-Etsu Chemical Co., Ltd.: KSP-105

[0680] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSG-16

[0681] (Note 5) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0682] (Note 6) Shin-Etsu Chemical Co., Ltd.: KF-6105

[0683] (Note 7) Shin-Etsu Chemical Co., Ltd.: KF-6106

[0684] (Note 8) Shin-Etsu Chemical Co., Ltd.: KTP-09W

[0685] (Note 9) Shin-Etsu Chemical Co., Ltd.: KTP-09R, Y, B

[0686] It was confirmed that the obtained pouring foundation had a good feeling during use, good makeup durability, good elongation and finish, and excellent scratch resistance.

[0687] [Example 29]

[0688] Eye Cream

[0689] <Preparation of cosmetics>

[0690] A: Mix components 1 to 4 uniformly.

[0691] B: Components 8 to 12 are uniformly mixed.

[0692] C: The mixture obtained in B was added to the mixture obtained in A to emulsify, and components 5 to 7 were added and mixed uniformly to obtain an eye cream.

[0693]

[0694] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-350Z

[0695] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-045Z

[0696] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6038

[0697] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSP-441

[0698] It was confirmed that the obtained eye cream had a good feel during use, the makeup durability and finish of the foundation applied over it were good, and the elongation was excellent.

[0699] [Example 30]

[0700] Crease Concealer

[0701] <Preparation of cosmetics>

[0702] A: Components 1 to 7 are uniformly mixed.

[0703] B: Component 8 was added to A and mixed to obtain a wrinkle concealer.

[0704]

[0705] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-210

[0706] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-15

[0707] (Note 3) Shin-Etsu Chemical Co., Ltd.: KSG-016F

[0708] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-9028

[0709] (Note 5) Shin-Etsu Chemical Co., Ltd.: KSP-411

[0710] (Note 6) Shin-Etsu Chemical Co., Ltd.: TSPL-30-D5

[0711] It was confirmed that the obtained wrinkle concealer had a good feel during use, good makeup durability, and excellent elongation.

[0712] [Example 31]

[0713] W / O Sunscreen

[0714] <Preparation of cosmetics>

[0715] A: Components 1 to 8 are uniformly mixed.

[0716] B: Components 9 to 15 are uniformly mixed.

[0717] C: The mixture obtained in B was added to the mixture obtained in A and emulsified to obtain a W / O sunscreen.

[0718]

[0719] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-840

[0720] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-43

[0721] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6105

[0722] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0723] (Note 5) Shin-Etsu Chemical Co., Ltd.: KSP-100

[0724] The obtained W / O sunscreen had a good feel during use and was excellent in makeup durability.

[0725] [Example 32]

[0726] O / W Sunscreen

[0727] <Preparation of cosmetics>

[0728] A: Heat components 1 to 6 to 85°C and mix uniformly.

[0729] B: Heat components 7 to 15 to 85°C and mix uniformly.

[0730] C: The mixture obtained in B was added to the mixture obtained in A, emulsified at 85° C., and then slowly cooled while stirring to obtain an O / W sunscreen.

[0731]

[0732] (Note 1) Made by SEPPIC: SIMULGEL EG

[0733] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0734] (Note 3) Shin-Etsu Chemical Co., Ltd.: KSG-016F

[0735] (Note 4) Shin-Etsu Chemical Co., Ltd.: KF-6011

[0736] The obtained O / W sunscreen had a good feel during use and was excellent in elongation.

[0737] [Example 33]

[0738] Mousse blush

[0739] <Preparation of cosmetics>

[0740] A: Heat components 1 to 6 to 80°C and mix uniformly.

[0741] B: Components 7 to 12 were uniformly mixed using a Henschel mixer.

[0742] C: The mixture obtained in B was added to the mixture obtained in A, mixed uniformly at 80° C. and then slowly cooled to obtain a mousse blush.

[0743]

[0744] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-16

[0745] (Note 2) Made by Chiba Flour Milling Co., Ltd.: Leopal ISK2

[0746] (Note 3) AEROSIL 200 manufactured by Japan AEROSIL Co., Ltd.

[0747] (Note 4) Shin-Etsu Chemical Co., Ltd.: KP-574 treatment

[0748] The obtained mousse blush had a good feel during use, good makeup durability, good elongation and finishing properties, and excellent abrasion resistance.

[0749] [Example 34]

[0750] Gel Eyeshadow

[0751] <Preparation of cosmetics>

[0752] A: Heat components 1 to 5 to 80°C and mix uniformly.

[0753] B: Components 6 to 9 were added to the mixture obtained in A, heated to 90° C., and mixed uniformly.

[0754] C: The mixture obtained in B was cast into a container to obtain a gel eye shadow.

[0755]

[0756] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-16

[0757] (Note 2) Made by Chiba Flour Milling Co., Ltd.: Leopal KL2

[0758] (Note 3) Made by Japan AEROSIL Co., Ltd.: AEROSIL972

[0759] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSP-100

[0760] (Note 5) Shin-Etsu Chemical Co., Ltd.: KP-574 treatment

[0761] The obtained gel eye shadow had a good feel during use, good makeup durability, good elongation and finishing properties, and excellent abrasion resistance.

[0762] [Example 35]

[0763] Powder foundation

[0764] <Preparation of cosmetics>

[0765] A: Heat components 1 to 4 to 50°C, mix uniformly, and cool to room temperature.

[0766] B: Components 5 to 14 are uniformly mixed.

[0767] C: The mixture obtained in A was added to the mixture obtained in B, and the mixture was uniformly mixed using a Henschel mixer. The obtained powder was passed through a sieve and then molded on a metal dish using a mold to obtain a powder foundation.

[0768]

[0769] (Note 1) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0770] (Note 2) Shin-Etsu Chemical Co., Ltd.: KP-561P

[0771] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-9909 treatment

[0772] (Note 4) Shin-Etsu Chemical Co., Ltd.: KSP-300

[0773] (Note 5) Shin-Etsu Chemical Co., Ltd.: KSP-100

[0774] The obtained powder foundation had a good feel during use, good makeup durability, and was excellent in elongation and finish.

[0775] [Example 36]

[0776] After-bath hair cream

[0777] <Preparation of cosmetics>

[0778] A: Mix components 1 to 4 uniformly.

[0779] B: Components 7 to 12 are uniformly mixed.

[0780] C: The mixture obtained in B was added to the mixture obtained in A to emulsify, and components 5 and 6 were added to obtain a hair treatment cream.

[0781]

[0782] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-210

[0783] (Note 2) Shin-Etsu Chemical Co., Ltd.: KSG-19

[0784] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-6017

[0785] The obtained hair cream was easy to spread, gave gloss to hair, and was excellent in smoothness.

[0786] [Example 37]

[0787] Hair Treatment Cream

[0788] <Preparation of cosmetics>

[0789] A: Heat components 6 to 9 to 70°C and mix uniformly.

[0790] B: Heat components 1 to 5 to 70°C and mix uniformly.

[0791] C: The mixture obtained in B was added to the mixture obtained in A to emulsify, and then components 10 and 11 were added after slow cooling to obtain a hair treatment cream.

[0792]

[0793]

[0794] (Note 1) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0795] (Note 2) Shin-Etsu Chemical Co., Ltd.: X-52-2328

[0796] The obtained hair conditioner was easy to spread, gave gloss to the hair, and was excellent in smoothness.

[0797] [Example 38]

[0798] Hair Oil

[0799] <Preparation of cosmetics>

[0800] A: Components 1 to 7 were uniformly mixed to obtain a hair oil.

[0801]

[0802] (Note 1) Shin-Etsu Chemical Co., Ltd.: KF-56A

[0803] (Note 2) Shin-Etsu Chemical Co., Ltd.: X-21-5613

[0804] The obtained hair oil was easy to spread, imparted gloss to hair, and was excellent in smoothness.

[0805] [Example 39]

[0806] Hair wax

[0807] <Preparation of cosmetics>

[0808] A: Heat components 1 to 9 to 80°C and mix uniformly.

[0809] B: Heat components 10 to 16 to 90°C and mix uniformly.

[0810] C: The mixture obtained in B was added to the mixture obtained in A, emulsified at 80°C, and then cooled to room temperature.

[0811] D: Components 17 to 19 were added to the mixture obtained in C and mixed uniformly to obtain a hair wax.

[0812]

[0813]

[0814] (Note 1) Shin-Etsu Chemical Co., Ltd.: TMF-1.5

[0815] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-6011

[0816] The obtained hair wax has less stickiness and is excellent in holding power and anti-perspiration effect.

[0817] [Example 40]

[0818] shampoo

[0819] <Preparation of cosmetics>

[0820] A: Components 1 to 10 were uniformly mixed at 70° C. and slowly cooled to obtain shampoo.

[0821]

[0822] The obtained shampoo had good finger-smoothing properties, imparted gloss to hair, and was excellent in smoothness.

[0823] [Example 41]

[0824] Roll-on antiperspirant

[0825] <Preparation of cosmetics>

[0826] A: Mix components 1 to 4 uniformly.

[0827] B: Components 5 to 11 are uniformly mixed.

[0828] C: The mixture obtained in B was added to the mixture obtained in A and emulsified to obtain a roll-on antiperspirant.

[0829]

[0830] (Note 1) Shin-Etsu Chemical Co., Ltd.: KSG-210

[0831] (Note 2) Shin-Etsu Chemical Co., Ltd.: KF-6028

[0832] The obtained roll-on antiperspirant was easy to spread, did not cause whitening of the skin, and had excellent durability of the antiperspirant effect.

[0833] [Example 42]

[0834] Nail polish topcoat

[0835] <Preparation of cosmetics>

[0836] A: Mix components 5 to 8, add component 4, and mix evenly.

[0837] B: Components 1 to 3 were added to the mixture obtained in A, and mixed to obtain a nail polish top coat.

[0838]

[0839]

[0840] The obtained nail polish top coat is easy to spread, increases the gloss of nail enamel, and has excellent durability.

Claims

1. A cosmetic comprising a cross-linked silicone resin, wherein the cross-linked silicone resin is a cross-linked silicone resin that is an addition reaction product of the following components (A) and (B), and the amount of hydrogen gas per unit mass generated by the cross-linked silicone resin is 1.5 mL / g or less under standard conditions, (A) an alkenyl group-containing silicone resin represented by the following formula (1) and having one or more alkenyl groups in one molecule [Chemistry 1] (R 1 R 2 2SiO 1 / 2 ) a1 (R 2 3SiO 1 / 2 ) a2 (R 3 3SiO 1 / 2 ) a3 (R 2 2SiO 2 / 2 ) b (R 2 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1) In the formula, R 1 are independently alkenyl having 2 to 8 carbon atoms, R 2 are independently selected from an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, and an aralkyl group having 7 to 30 carbon atoms; R 3 are independently selected from the group containing organopolysiloxane and the above R 2 The groups in each R 3 3SiO 1 / 2 More than one R in the unit 3 is a group containing an organic polysiloxane; a1, a2, a3, b, c and d are numbers satisfying 0<a1≤5, 0<a2≤400, 0≤a3≤400, 0≤b≤320, 0≤c≤320, 0<d≤1000, and 0.5≤(a1+a2+a3) / d≤1.5, (B) an organohydrogenpolysiloxane represented by the following formula (2) having two or more hydrosilyl groups in one molecule, in an amount such that the amount of the hydrosilyl groups is 0.5 to 1.2 mol per 1 mol of the alkenyl groups in the component (A); [Chemistry 2] (R 4 3SiO 1 / 2 )e(R 4 2SiO 2 / 2 ) f (R 2 SiO 3 / 2 ) g (SiO 4 / 2 ) h (2) In the formula, R 2 Same as above, R 4 are independently a hydrogen atom or the above R 2 The groups represented by all R 4 At least two of them are hydrogen atoms, e, f, g, and h are 0 or positive numbers, and 2≤e+f+g+h<32.

2. The cosmetic according to claim 1, wherein In the R 3 In the formula (3), the group containing the organopolysiloxane is one or more groups represented by any one of the following formulas (3) to (6), [Chemistry 3] -C m H 2m -(CH2)2-(SiOR 2 2) i -SiR 2 3 (3) -C m H 2m -(CH2)2-SiR 2 j1 -(OSiR 2 3) 3-j1 (4) -C m H 2m -(CH2)2-SiR 2 j1 (OSiR 2 j2 (OSiR 2 3) 3-j2 ) 3-j1 (5) -C m H 2m -(CH2)2-SiR′ 2 j1 -(OSiR 2 j2 (OSiR 2 j3 (OSiR 2 3) 3-j3 ) 3-j2 ) 3-j1 (6) In the formula, R 2 Similar to the above, m is an integer of 0≤m≤5, i is an integer of 0≤i≤500, and j1 to j3 are each an integer of 0 to 2.

3. The cosmetic according to claim 1, wherein In the formula (1), b=0 and c=0.

4. The cosmetic according to claim 1, wherein In the formula (2), g=0 and h=0.

5. The cosmetic according to claim 1, wherein The weight average molecular weight of the cross-linked silicone resin is 5,000 to 1,000,000.

6. The cosmetic according to claim 1, wherein In the formula (2), 0≤f<30, R 4 Two of them are hydrogen atoms, and the cross-linked silicone resin is solid at 25°C.

7. The cosmetic according to claim 1, wherein The amount of hydrogen gas per unit mass generated from the cross-linked silicone resin is 0.01 to 1.2 mL / g under standard conditions.

8. The cosmetic according to claim 1, wherein The cross-linked silicone resin is soluble at 25° C. in a volatile oil having a boiling point of 250° C. or less at 1013 hPa.

9. The cosmetic according to claim 8, wherein The volatile oil agent is one or more selected from silicone oil, isododecane and ethanol.

10. The cosmetic according to claim 1, wherein The content of the cross-linked silicone resin is 0.1 to 40% by mass. The cosmetic according to claim 1, which is a sunscreen cosmetic or a makeup cosmetic.

12. The cosmetic according to claim 1, which is a non-aqueous composition.

13. A method for producing a cosmetic according to any one of claims 1 to 12, comprising the step of reacting the following components (A) and (B) in such an amount that the amount of hydrosilyl groups is 0.5 to 1.2 mol per 1 mol of alkenyl groups in the component (A) to obtain a crosslinked silicone resin: (A) an alkenyl group-containing silicone resin represented by the following formula (1) and having one or more alkenyl groups in one molecule, [Chemistry 4] (R 1 R 2 2SiO 1 / 2 ) a1 (R 2 3SiO 1 / 2 ) a2 (R 3 3SiO 1 / 2 ) a3 (R 2 2SiO 2 / 2 ) b (R 2 SiO 3 / 2 ) c (SiO 4 / 2 ) d (1) In the formula, R 1 are independently alkenyl having 2 to 8 carbon atoms, R 2 are independently selected from an alkyl group having 1 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, and an aralkyl group having 7 to 30 carbon atoms; R 3 are independently selected from the group containing organopolysiloxane and the above R 2 The groups in each R 3 3SiO 1 / 2 More than one R in the unit 3 is a group containing an organic polysiloxane; a1, a2, a3, b, c and d are numbers satisfying 0<a1≤5, 0<a2≤400, 0≤a3≤400, 0≤b≤320, 0≤c≤320, 0<d≤1000, and 0.5≤(a1+a2+a3) / d≤1.5, (B) an organohydrogenpolysiloxane represented by the following formula (2) having two or more hydrosilyl groups in one molecule [Chemistry 5] (R 4 3SiO 1 / 2 ) e (R 4 2SiO 2 / 2 ) f (R 2 SiO 3 / 2 ) g (SiO 4 / 2 ) h (2) In the formula, R 2 Same as above, R 4 are independently a hydrogen atom or the above R 2 The groups represented by all R 4 At least two of them are hydrogen atoms, e, f, g, and h are 0 or positive numbers, and 2≤e+f+g+h<32.

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