Ammonium ion measuring device

Abstract

The invention discloses an ammonium ion determination device, and belongs to the technical field of building material detection, the ammonium ion determination device comprises a bottom plate, the bottom plate is provided with a mixing assembly and a detection assembly, through the arrangement of the mixing assembly, the mixing effect of a to-be-detected sample and water can be improved, and the situation that the mixture is attached to a stirring straight plate and cannot fully react can be prevented; by arranging the position adjusting unit, the positions of a circular sliding plate, a stirring straight plate and a position adjusting circular plate can be adjusted, residues in the mixing chamber can be pushed to the outside of the mixing chamber, so that workers can conveniently clean the residues, namely, the cleaning efficiency is improved, and the cleaning difficulty is reduced; according to the ammonium ion detection device, the use of motors can be reduced, the probability that excessive motors are easily damaged in a heating environment is relatively high, the ammonium ions in a to-be-detected sample can be automatically detected by arranging the detection assembly, and the accuracy of the detection structure can be improved through continuous detection.

Description

Technical Field

[0001] The invention relates to the technical field of building material detection, in particular to an ammonium ion determination device. Background Art

[0002] In the production process of ammonium-containing building materials, the content of ammonium ions is an important detection index, which directly affects the quality and performance of building materials. The existing ammonium ion determination technology for samples to be detected has gradually exposed many shortcomings during the application process. Most of the existing determination devices are cumbersome to operate and require a lot of time and manpower, which to a certain extent affects the determination efficiency of the samples to be detected. Secondly, traditional equipment is inefficient when mixing the samples to be detected and water, and the mixture is not mixed sufficiently, which further affects the reliability of the determination results. At the same time, traditional equipment also has many inconveniences in cleaning and maintenance, which increases operating costs and time costs. Therefore, the present invention provides an ammonium ion determination device. Summary of the invention

[0003] The present invention aims at the defects of the prior art and provides an ammonium ion determination device, which overcomes the problems of low efficiency when mixing a sample to be detected and water, insufficient mixing of the mixture, and many inconveniences in cleaning and maintenance.

[0004] To achieve the above-mentioned purpose, the present invention provides the following technical scheme: an ammonium ion determination device, comprising a bottom plate, on which a mixing assembly and a detection assembly are arranged, the mixing assembly comprising a mixing cylinder and a positioning circular plate, a stirring tooth ring is rotatably mounted on the mixing cylinder, a circular slide is movably arranged on the stirring tooth ring, the circular slide and the mixing cylinder are slidably matched, three stirring straight plates are fixedly arranged in a circular array on the positioning circular plate, the stirring straight plates are all slidably matched with the circular slide, an adjustment unit is arranged between the circular slide and the positioning circular plate, a fan-shaped sealing strip is rotatably mounted on the upper end of the mixing cylinder, an auxiliary unit is arranged on the mixing cylinder, and the auxiliary unit is used to adjust the position of the fan-shaped sealing strip, the detection assembly comprises a feeding circular plate, a switching circular plate is rotatably mounted on the feeding circular plate, and a plurality of glass cups are arranged in a circular array on the switching circular plate.

[0005] Furthermore, the mixing cylinder is fixedly mounted on the bottom plate, and a complete cylinder is formed when the mixing cylinder and the fan-shaped sealing strip are fully engaged. A semicircular sealing slide plate is symmetrically slidably mounted on the lower end surface of the mixing cylinder, and a closed mixing chamber is formed when the mixing cylinder, the semicircular sealing slide plate, the fan-shaped sealing strip plate and the circular slide plate are engaged. A fan-shaped heating plate is also symmetrically fixedly mounted on the mixing cylinder, and the fan-shaped heating plate is used to heat the inside of the mixing cylinder.

[0006] Furthermore, a circular slide is arranged above the circular slide, and the circular slide and the stirring gear ring are slidably matched. The positioning unit includes a positioning screw rod 1 and a positioning screw rod 2. The two ends of the positioning screw rod 1 are respectively rotatably connected to the circular slide and the circular slide. The positioning screw rod 1 and the stirring gear ring form a spiral pair. The positioning screw rod 2 is rotatably connected to the circular slide. A transmission shaft is rotatably installed on the positioning circular plate. A torsion spring 1 is arranged between the positioning circular plate and the transmission shaft. The positioning screw rod 2 and the transmission shaft form a spiral pair.

[0007] Furthermore, a transmission pulley and a linkage pulley are rotatably installed on the circular slide, a second torsion spring is arranged between the circular slide and the transmission pulley, the transmission pulley and the linkage pulley are rotatably connected, a third torsion spring is arranged between the transmission pulley and the linkage pulley, the linkage pulley and the second adjusting screw rod are rotatably connected, a fourth torsion spring is arranged between the second adjusting screw rod and the linkage pulley, the axes of the second adjusting screw rod, the transmission pulley and the linkage pulley are on the same straight line, and a transmission group is arranged between the transmission pulley and the first adjusting screw rod.

[0008] Furthermore, the elastic force of torsion spring two is always greater than the elastic force of torsion spring three, the elastic force of torsion spring four is always greater than the elastic force of torsion spring three, and the elastic force of torsion spring four is always less than the elastic force of torsion spring one.

[0009] Furthermore, the auxiliary unit includes a fan-shaped auxiliary strip and a pressing strip. The fan-shaped auxiliary strip is slidably installed on the outside of the mixing cylinder, and the pressing strip is slidably installed on the circular slide. There is a spring between the fan-shaped auxiliary strip and the mixing cylinder. The pressing strip is used to adjust the position of the fan-shaped auxiliary strip.

[0010] Furthermore, an auxiliary gear is rotatably installed on the mixing cylinder, a gear set is arranged between the auxiliary gear and the fan-shaped sealing strip plate, an L-shaped side plate and an auxiliary rack are fixedly arranged on the side of the fan-shaped auxiliary strip plate, and a gear rack pair is formed when the auxiliary rack and the auxiliary gear are engaged, an auxiliary round block is fixedly arranged on the side of the auxiliary gear, a limiting strip block is fixedly arranged on the end of the L-shaped side plate, a sliding groove cooperating with the limiting strip block is arranged on the auxiliary round block, and the limiting strip block is used to limit the position of the fan-shaped sealing strip plate.

[0011] Furthermore, the detection component also includes a fan-shaped shell 1 fixedly mounted on the base plate, and a fan-shaped shell 2 is rotatably mounted on the base plate. When the fan-shaped shell 1, the fan-shaped shell 2 and the feed circular plate are engaged, a closed detection chamber is formed. An arc-shaped glass plate is fixedly mounted on the fan-shaped shell 2, the feed circular plate is slidably mounted on the base plate, and a plurality of electromagnets are fixedly mounted in a circular array on the switching circular plate. Circular magnets are fixedly mounted on the lower end surface of the glass cup, and the electromagnets and circular magnets are used to fix the glass cup.

[0012] Furthermore, an indicator liquid storage cylinder and a titration liquid storage box are fixedly installed on the bottom plate, a liquid guide tube 2 is arranged between the indicator liquid storage cylinder and the detection chamber, a liquid guide tube 1 is arranged between the titration liquid storage box and the detection chamber, an air guide tube is arranged between the mixing cylinder and the detection chamber, and an air pressure sensor is fixedly installed on the fan-shaped shell 1, and the air pressure sensor is used to monitor the air pressure inside the detection chamber. A camera is also symmetrically fixedly installed on the inner side of the fan-shaped shell 1, and the camera is used to monitor the volume and color changes of the solution inside the glass.

[0013] Compared with the prior art, the present invention has the following beneficial effects: (1) By providing a mixing component, the present invention can improve the mixing effect of the sample to be tested and water, and can also prevent the mixture from adhering to the stirring straight plate and failing to fully react. (2) By providing a positioning unit, the present invention can adjust the positions of the circular slide, the stirring straight plate, and the positioning circular plate, and can push the residue inside the mixing chamber to the outside of the mixing chamber, thereby facilitating cleaning by the staff, that is, improving the cleaning efficiency and reducing the cleaning difficulty. (3) By providing an auxiliary unit, the present invention can facilitate the adjustment of the position of the fan-shaped sealing strip plate, enhance the flexibility of the device, and facilitate the addition of the mixture into the mixing chamber. (4) By cooperating with the auxiliary unit and the positioning unit, the present invention can reduce the use of motors. Too many motors are more likely to be damaged in a heated environment. (5) By providing a detection component, the present invention can automatically realize the determination of ammonium ions in the sample to be tested, and can also improve the accuracy of the determination structure through continuous determination. BRIEF DESCRIPTION OF THE DRAWINGS

[0014] Figure 1 It is a schematic diagram of the overall structure of the present invention.

[0015] Figure 2 It is a schematic diagram of the structure of the mixing assembly of the present invention.

[0016] Figure 3 It is a schematic diagram of the structure inside the mixing cylinder of the present invention.

[0017] Figure 4 It is a schematic structural diagram of the fan-shaped auxiliary strips of the present invention.

[0018] Figure 5 It is a schematic structural diagram of the transmission shaft of the present invention.

[0019] Figure 6 for Figure 5 A local enlarged schematic diagram of point A in the middle.

[0020] Figure 7 for Figure 5 A local enlarged schematic diagram of point B in the middle.

[0021] Figure 8It is a cross-sectional view of the structure of the transmission pulley of the present invention.

[0022] Fig. 9 It is a front view of the overall structure of the present invention.

[0023] Fig.10 It is a top view of the overall structure of the present invention.

[0024] Fig.11 It is a schematic diagram of the structure of the detection component of the present invention.

[0025] Fig.12 It is a schematic diagram of the structure of the switching circular plate of the present invention.

[0026] Figure numerals: 101-bottom plate; 102-waste barrel; 103-mixing cylinder; 104-fan-shaped shell one; 105-air guide tube; 106-solenoid valve one; 107-fan-shaped shell two; 108-arc glass plate; 109-unfolding motor; 110-fan-shaped heating plate; 111-indicator liquid storage cylinder; 112-titration liquid storage box; 113-solenoid valve two; 114-solenoid valve three; 115-liquid guide tube one; 116-liquid guide tube two; 117-fan-shaped sealing strip plate; 118-air pressure sensor; 119-semicircular sealing slide plate; 120-separation screw rod; 121-double-head motor; 122-circular slide; 123-positioning screw rod one; 124-positioning screw rod two; 125-fan-shaped auxiliary strip plate; 126-pressing strip plate; 12 7-stirring gear ring; 128-stirring gear; 129-stirring motor; 130-circular slide plate; 131-stirring straight plate; 132-adjusting circular plate; 133-transmission shaft; 134-adjusting motor; 135-transmission pulley; 136-interlocking pulley; 137-driving pulley; 138-interlocking belt; 139-driven pulley; 140-L-shaped side plate; 141-transmission belt; 142-auxiliary round block; 143-auxiliary gear; 144-auxiliary rack; 145-bevel gear one; 146-bevel gear two; 147-feeding circular plate; 148-feeding electric cylinder; 149-switching circular plate; 150-glass; 151-camera; 152-switching motor; 153-electromagnet; 154-circular magnet; 155-limiting bar. DETAILED DESCRIPTION

[0027] The technical solutions in the embodiments of the present invention will be described clearly and completely below in conjunction with the accompanying drawings in the embodiments of the present invention.

[0028] Example: Reference Figure 1-Figure 12, an ammonium ion determination device, comprising a base plate 101, a mixing assembly is arranged on the base plate 101, the mixing assembly comprises a mixing cylinder 103 and a positioning circular plate 132, the mixing cylinder 103 is fixedly mounted on the base plate 101, a waste barrel 102 is fixedly mounted on the base plate 101, the waste barrel 102 is located directly below the mixing cylinder 103, a semicircular sealing slide plate 119 is symmetrically slidably mounted on the lower end surface of the mixing cylinder 103, a separation screw rod 120 is also symmetrically rotatably mounted on the mixing cylinder 103, the two separation screw rods 120 have opposite rotation directions, and the two separation screw rods 120 respectively form a spiral pair with the corresponding semicircular sealing slide plate 119, a double-headed motor 121 is fixedly mounted on the outer side of the mixing cylinder 103, and both ends of the output shaft of the double-headed motor 121 are respectively fixedly connected to the corresponding separation screw rod 120.

[0029] The double-headed motor 121 is started to drive the two separation screw rods 120 to rotate synchronously. Since the two separation screw rods 120 rotate in opposite directions, the two semicircular sealing slide plates 119 are moved toward each other or away from each other.

[0030] A stirring gear ring 127 is rotatably installed on the mixing cylinder 103, and a stirring motor 129 is also fixedly installed on the outer side of the mixing cylinder 103. A stirring gear 128 is fixedly installed on the output shaft of the stirring motor 129. The stirring gear 128 and the stirring gear ring 127 form a spiral pair. A circular slide 130 is movably arranged on the stirring gear ring 127. The circular slide 130 and the mixing cylinder 103 are slidably matched. A circular slide 122 is arranged above the circular slide 130. The circular slide 122 and the stirring gear ring 127 are slidably matched. Three stirring straight plates 131 are fixedly arranged in a circular array on the adjustment circular plate 132, and the stirring straight plates 131 are all slidably matched with the circular slide 130.

[0031] The stirring motor 129 is started to drive the stirring gear 128 to rotate, that is, the stirring gear ring 127 is rotated. Since the circular slide 122 and the stirring gear ring 127 are slidably matched, the circular slide 122, the circular slide 130, and the adjustment circular plate 132 are all rotated synchronously at this time, so that the stirring straight plate 131 stirs the inside of the mixing cylinder 103. The upper end of the mixing cylinder 103 is rotatably installed with the fan-shaped sealing strip plate 117. When the mixing cylinder 103 and the fan-shaped sealing strip plate 117 are fully engaged, A complete cylinder is formed. When the mixing cylinder 103 and the fan-shaped sealing strip plate 117 are fully engaged, the inner circumferential surfaces of the mixing cylinder 103 and the fan-shaped sealing strip plate 117 are on the same circumference. At this time, the mixing cylinder 103, the semicircular sealing slide plate 119, the fan-shaped sealing strip plate 117, and the circular slide plate 130 are engaged to form a closed mixing chamber. The mixing cylinder 103 is also symmetrically fixed with a fan-shaped heating plate 110, which is used to heat the inside of the mixing cylinder 103.

[0032] A positioning unit is arranged between the circular slide 130 and the positioning circular plate 132, and the positioning unit includes a positioning screw rod 123 and a positioning screw rod 2 124. The two ends of the positioning screw rod 123 are rotatably connected to the circular slide 122 and the circular slide 130 respectively, the positioning screw rod 123 and the stirring gear ring 127 constitute a spiral pair, the positioning screw rod 2 124 is rotatably connected to the circular slide 122, and a transmission shaft 133 is rotatably installed on the positioning circular plate 132. A torsion spring 1 is arranged between the positioning circular plate 132 and the transmission shaft 133, one end of the torsion spring 1 is fixedly connected to the positioning circular plate 132, and the other end of the torsion spring 1 is fixedly connected to the transmission shaft 133, and the positioning screw rod 2 124 and the transmission shaft 133 constitute a spiral pair.

[0033] In the initial position, the adjustment circular plate 132 is located at the position farthest from the upper surface of the circular slide 122. At this time, the stirring straight plate 131 is completely located inside the mixing chamber, driving the adjustment screw rod 124 to rotate. Under the action of the torsion spring 1, the adjustment screw rod 124 rotates relative to the transmission shaft 133, thereby causing the transmission shaft 133 to move toward the upper surface of the circular slide 122, and the adjustment circular plate 132 moves synchronously, and the three stirring straight plates 131 on the adjustment circular plate 132 move synchronously. , the stirring straight plate 131 slides relative to the circular slide 130, and finally the adjusting circular plate 132 moves to the position closest to the upper surface of the circular slide 122. At this time, the lower end surface of the stirring straight plate 131 and the lower surface of the circular slide 130 are on the same plane. At this time, the adjusting screw rod 124 continues to rotate, and the adjusting circular plate 132 cannot continue to move. That is, the torsion spring between the adjusting circular plate 132 and the transmission shaft 133 is compressed, that is, the adjusting screw rod 124 and the transmission shaft 133 rotate synchronously.

[0034] When the positioning circular plate 132 is located at the position closest to the upper surface of the circular slide 122, the positioning screw 123 is driven to rotate, and the positioning screw 123 rotates relative to the stirring gear ring 127. Under the action of the stirring gear ring 127, the circular slide 122, the positioning screw 123, and the circular slide 130 move toward the direction close to the lower end surface of the mixing cylinder 103. At this time, the stirring straight plate 131 and the positioning circular plate 132 move synchronously toward the direction close to the lower end surface of the mixing cylinder 103, and the circular slide 130 scrapes and cleans the inner wall of the mixing cylinder 103.

[0035] A driving pulley 135 and a linkage pulley 136 are rotatably mounted on the circular slide 122, a torsion spring 2 is arranged between the circular slide 122 and the driving pulley 135, one end of the torsion spring 2 is fixedly connected to the circular slide 122, the other end of the torsion spring 2 is fixedly connected to the driving pulley 135, the driving pulley 135 and the linkage pulley 136 are rotatably connected, a torsion spring 3 is arranged between the driving pulley 135 and the linkage pulley 136, one end of the torsion spring 3 is fixedly connected to the driving pulley 135, the other end of the torsion spring 3 is fixedly connected to the linkage pulley 136, the elastic force of the torsion spring 2 is always greater than the elastic force of the torsion spring 3, the linkage pulley 136 is rotatably connected to the second adjusting screw rod 124, a torsion spring 4 is arranged between the second adjusting screw rod 124 and the linkage pulley 136, one end of the torsion spring 4 is fixedly connected to the second adjusting screw rod 124, The other end of spring four is fixedly connected to the linkage pulley 136, the elastic force of torsion spring four is always greater than the elastic force of torsion spring three, and the elastic force of torsion spring four is always less than the elastic force of torsion spring one, the axes of the positioning screw rod two 124, the transmission pulley 135 and the linkage pulley 136 are on the same straight line, a transmission group is arranged between the transmission pulley 135 and the positioning screw rod one 123, the transmission group includes a driven pulley 139 and a transmission belt 141, the driven pulley 139 is fixedly mounted on the upper end surface of the positioning screw rod one 123, the transmission belt 141 is arranged between the transmission pulley 135 and the driven pulley 139, a positioning motor 134 is also fixedly mounted on the circular slide 122, a driving pulley 137 is fixedly mounted on the output shaft of the positioning motor 134, and a linkage belt 138 is arranged between the driving pulley 137 and the linkage pulley 136.

[0036] In the initial position, the torsion spring 1, the torsion spring 2, the torsion spring 3, and the torsion spring 4 are not compressed. At this time, the positioning circular plate 132 is located at the farthest position from the positioning motor 134.

[0037] The positioning motor 134 is started to drive the driving pulley 137 to rotate. Under the action of the linkage belt 138, the linkage pulley 136 rotates synchronously. Under the action of the torsion spring 4, the positioning screw rod 2 124 and the linkage pulley 136 rotate synchronously. Since the elastic force of the torsion spring 2 is always greater than the elastic force of the torsion spring 3, the linkage pulley 136 rotates relative to the transmission pulley 135. The torsion spring 3 is compressed. Under the action of the positioning screw rod 2 124, the positioning circular plate 132 moves toward the direction close to the positioning motor 134, and finally the positioning circular plate 132 moves to the distance from the positioning motor 134. The torsion spring 3 reaches the maximum deformation, the interlocking pulley 136 continues to rotate, and the adjusting screw rod 2 124 cannot continue to rotate. The interlocking pulley 136 rotates relative to the adjusting screw rod 2 124. At this time, the transmission pulley 135 and the interlocking pulley 136 rotate synchronously, and the torsion spring 2 is compressed. Under the action of the transmission belt 141, the driven pulley 139 rotates, which makes the adjusting screw rod 123 rotate, thereby making the circular slide 122, the circular slide plate 130, the stirring straight plate 131, and the adjusting circular plate 132 move downward synchronously.

[0038] An auxiliary unit is provided on the mixing cylinder 103, and the auxiliary unit is used to adjust the position of the fan-shaped sealing strip 117. The auxiliary unit includes a fan-shaped auxiliary strip 125 and a pressing strip 126. The fan-shaped auxiliary strip 125 is slidably installed on the outer side of the mixing cylinder 103, and a spring is arranged between the fan-shaped auxiliary strip 125 and the mixing cylinder 103. The pressing strip 126 is slidably installed on the circular slide 122, and a spring is arranged between the pressing strip 126 and the circular slide 122. The pressing strip 126 is used to adjust the position of the fan-shaped auxiliary strip 125.

[0039] An auxiliary gear 143 is rotatably mounted on the mixing cylinder 103, and a gear set is arranged between the auxiliary gear 143 and the fan-shaped sealing strip plate 117. The gear assembly includes a bevel gear 145 and a bevel gear 146. The bevel gear 145 and the bevel gear 146 mesh to form a gear pair. The bevel gear 145 is fixedly mounted on the side of the auxiliary gear 143, and the bevel gear 146 is fixedly mounted on the fan-shaped sealing strip plate 117. The axis of the bevel gear 146 is in the same straight line as the center line of the fan-shaped sealing strip plate 117 and the mixing cylinder 103. The side of the fan-shaped auxiliary strip plate 125 is fixedly provided with an L The L-shaped side plate 140 and the auxiliary rack 144, the auxiliary rack 144 and the auxiliary gear 143 form a gear rack pair when they are engaged, the side of the auxiliary gear 143 is fixedly provided with an auxiliary round block 142, the end of the L-shaped side plate 140 is fixedly provided with a limiting strip 155, the auxiliary round block 142 is provided with a sliding groove that cooperates with the limiting strip 155, the limiting strip 155 is used to limit the position of the fan-shaped sealing strip plate 117, a torsion spring five is provided between the fan-shaped sealing strip plate 117 and the mixing cylinder 103, one end of the torsion spring five is fixedly connected to the mixing cylinder 103, and the other end of the torsion spring five is fixedly connected to the fan-shaped sealing strip plate 117.

[0040] When the stirring tooth ring 127 rotates, the pressing strip 126 rotates synchronously. Under the action of the fan-shaped auxiliary strip 125 and the pressing strip 126, the fan-shaped auxiliary strip 125 is always located below the pressing strip 126, that is, when the pressing strip 126 rotates to any position, the pressing strip 126 moves downward and can always contact the upper surface of the fan-shaped auxiliary strip 125.

[0041] In the initial position, that is, the adjusting circular plate 132 is located at the farthest position from the adjusting motor 134, at this time, the pressing strip plate 126 and the fan-shaped auxiliary strip plate 125 are not in contact, and the torsion spring five is not compressed. At this time, the fan-shaped sealing strip plate 117 and the mixing cylinder 103 are in a engaged state, and the springs between the fan-shaped auxiliary strip plate 125 and the mixing cylinder 103, and the springs between the pressing strip plate 126 and the stirring gear ring 127 are not compressed. At this time, the slide groove and the limiting strip block 155 on the auxiliary round block 142 are in a engaged state. Under the action of the limiting strip block 155, the auxiliary round block 142 cannot rotate freely, that is, the fan-shaped sealing strip plate 117 cannot rotate relative to the mixing cylinder 103, that is, the position of the fan-shaped sealing strip plate 117 is locked, and the auxiliary rack 144 and the auxiliary gear 143 are not in contact.

[0042] When it is necessary to open the fan-shaped sealing strip 117 on the mixing cylinder 103, the positioning motor 134 is started to drive the linkage pulley 136 to rotate, and the positioning screw rod 124 rotates. Since the positioning circular plate 132 cannot continue to move downward, the torsion spring 1 between the positioning circular plate 132 and the transmission shaft 133 is compressed, and the pressing strip plate 126 continues to move downward and contacts the upper surface of the fan-shaped auxiliary strip plate 125. The pressing strip plate 126 continues to move downward, and the fan-shaped auxiliary strip plate 125 moves downward synchronously. The springs between the fan-shaped auxiliary strip plate 125 and the mixing cylinder 103 and the springs between the pressing strip plate 126 and the stirring gear ring 127 are all compressed, and the L-shaped side plate 140, the auxiliary rack 144, and the limiting strip block 15 on the fan-shaped auxiliary strip plate 125 are compressed. 5 moves downward synchronously, and the limiting strip 155 moves downward relative to the slide groove on the auxiliary round block 142, and finally the limiting strip 155 is disengaged from the auxiliary round block 142, that is, the limiting strip 155 releases the lock on the position of the fan-shaped sealing strip plate 117, and at this time the auxiliary rack 144 contacts the auxiliary gear 143, and the fan-shaped auxiliary strip plate 125 continues to move downward. Under the action of the auxiliary rack 144, the auxiliary gear 143 rotates, and under the action of the gear set, that is, under the action of the bevel gear 145 and the bevel gear 2 146, the fan-shaped sealing strip plate 117 rotates relative to the mixing cylinder 103, that is, the fan-shaped sealing strip plate 117 on the mixing cylinder 103 is opened, so as to facilitate the addition of raw materials into the mixing chamber.

[0043] A detection component is also provided on the base plate 101, and the detection component includes a feed circular plate 147. The detection component also includes a fan-shaped shell 104 fixedly installed on the base plate 101, and a fan-shaped shell 107 is also rotatably installed on the base plate 101, and a curved glass plate 108 is fixedly installed on the fan-shaped shell 107. An unfolding motor 109 is also fixedly installed on the base plate 101, and the output shaft of the unfolding motor 109 is fixedly connected to the fan-shaped shell 107, and the axis of the output shaft of the unfolding motor 109 is in the same straight line as the axis of the rotation connection between the fan-shaped shell 107 and the base plate 101. The feed circular plate 147 is slidably installed on the base plate 101, and a feed electric cylinder 148 is fixedly installed on the base plate 101, and the piston rod end of the feed electric cylinder 148 is fixedly connected to the lower surface of the feed circular plate 147, and a closed detection chamber is formed when the fan-shaped shell 104, the fan-shaped shell 107 and the feed circular plate 147 are connected.

[0044] A switching circular plate 149 is rotatably mounted on the feed circular plate 147, a switching motor 152 is fixedly mounted on the lower surface of the feed circular plate 147, an output shaft of the switching motor 152 is fixedly connected to the switching circular plate 149, a plurality of glass cups 150 are arranged in a circular array on the switching circular plate 149, a plurality of electromagnets 153 are also fixedly mounted in a circular array on the switching circular plate 149, circular magnets 154 are fixedly mounted on the lower end surfaces of the glass cups 150, and the electromagnets 153 and the circular magnets 154 are used to fix the glass cups 150.

[0045] The bottom plate 101 is also fixedly mounted with an indicator liquid storage cylinder 111 and a titration liquid storage box 112. A second liquid guide tube 116 is provided between the indicator liquid storage cylinder 111 and the detection chamber. A third solenoid valve 114 is also fixedly mounted on the indicator liquid storage cylinder 111. The third solenoid valve 114 is used to control the flow of the second liquid guide tube 116. A first liquid guide tube 115 is provided between the titration liquid storage box 112 and the detection chamber. A second solenoid valve 113 is fixedly mounted on the titration liquid storage box 112. The second solenoid valve 113 is used to control the flow of the second liquid guide tube 116. 15, an air duct 105 is provided between the mixing cylinder 103 and the detection chamber, an electromagnetic valve 106 is fixedly installed on the air duct 105, the electromagnetic valve 106 is used to control the flow of the air duct 105, an air pressure sensor 118 is also fixedly installed on the fan-shaped shell 104, the air pressure sensor 118 is used to monitor the air pressure inside the detection chamber, and a camera 151 is symmetrically fixedly installed on the inner side of the fan-shaped shell 104, the camera 151 is used to monitor the volume and color change of the solution inside the glass 150.

[0046] The sample particles and water to be tested are added into the mixing chamber, and then the mixing chamber is stirred by the stirring straight plate 131, so that the sample particles and water to be tested are fully mixed in the mixing chamber, and then a regulator is added into the mixing chamber to make the pH value of the liquid to be tested greater than 12, and then the mixing chamber is heated by the fan-shaped heating plate 110, that is, the ammonium ions in the mixed liquid in the mixing chamber are converted into ammonia gas, and the evaporated ammonia gas enters the detection chamber along the air guide tube 105, and the air guide tube 105 is controlled by the solenoid valve 106. 5, by starting the switching motor 152 to drive the switching circular plate 149 to rotate, that is, adjusting the position of the glass cup 150 on the switching circular plate 149, so that the required glass cup 150 moves to just below the end of the air guide pipe 105, and then starting the feeding electric cylinder 148 to move the feeding circular plate 147 upward, so that the end of the air guide pipe 105 is located inside the solution in the glass cup 150. The glass cup 150 is used to contain the sulfuric acid solution. The sulfuric acid solution in the glass cup 150 absorbs the ammonia discharged from the air guide pipe 105. The camera 151 is used to detect the liquid level of the glass 150. When the required amount is reached, the electromagnetic valve 106 is closed, and the feed cylinder 148 is started to move the feed circular plate 147 upward. Then, the switching motor 152 is started to drive the switching circular plate 149 to rotate, so that the glass 150 rotates to the bottom of the end of the second liquid guide tube 116. Then, the indicator liquid in the indicator liquid storage cylinder 111 is added to the glass 150 through the electromagnetic valve 3 114 and the second liquid guide tube 116. Then, the switching circular plate 149 is rotated continuously. 9, so that the glass 150 is located just below the end of the liquid guiding tube 115, and then the titration solution in the titration solution storage box 112 is dripped into the glass 150 through the electromagnetic valve 2 113 and the liquid guiding tube 115, and the color change in the glass 150 is monitored by the camera 151. When the camera 151 detects that the color of the indicator in the glass 150 changes, the addition of the titration solution is stopped, and then the ammonium ion content in the sample can be calculated according to the volume of the sodium hydroxide standard titration solution consumed during the titration process.

[0047] The pressure change inside the mixing chamber is monitored by the air pressure sensor 118 to prevent the mixing chamber from exploding when the fan-shaped housing 107 is opened when the pressure inside the mixing chamber is too high. The interior of the mixing chamber is observed through the curved glass plate 108. When the glass 150 needs to be replaced, the unfolding motor 109 is started to drive the fan-shaped housing 107 to rotate, that is, the fan-shaped housing 107 is opened, and then the electromagnet 153 is turned off, that is, the electromagnet 153 releases the adsorption and fixation of the circular magnet 154, and then releases the fixation of the glass 150, so that the glass 150 can be easily taken and placed.

[0048] Working principle: the fan-shaped sealing strip 117 is controlled to open by the auxiliary unit, and then the sample to be tested and water are added into the mixing chamber, and then the fan-shaped sealing strip 117 is closed, and then the stirring motor 129 is started to make the three stirring straight plates 131 mix and stir the sample inside the mixing chamber, and in the stirring process, the stirring straight plates 131 are made to slide relative to the circular slide 130 through the positioning unit, so that under the action of the circular slide 130, the attachments on the surface of the stirring straight plates 131 are scraped off, and the stirring straight plates 131 move up and down inside the mixing chamber, which can also improve the mixing effect of the sample and water inside the mixing chamber.

[0049] A regulator is then added to the interior of the mixing chamber to adjust the pH value of the solution, and then the solution in the mixing chamber is distilled through the fan-shaped heating plate 110. Before starting the distillation, a specified amount of sulfuric acid solution is added to each of the glass cups 150 on the switching circular plate 149, and then ammonia gas is injected into a certain glass cup 150 through the gas guide tube 105. When the camera 151 detects that the liquid level line in the glass cup 150 has reached the required amount, the glass cup 150 is first moved to the bottom of the liquid guide tube 116, and an indicator is added to the glass cup 150 through the liquid guide tube 116. Then, the glass cup 150 is moved to the bottom of the liquid guide tube 1 15 for titration until the camera 151 detects that the color of the indicator in the glass cup 150 has changed, and then the addition of the titration solution is stopped. Then, the ammonium ion content in the sample can be calculated based on the volume of the sodium hydroxide standard titration solution consumed during the titration process.

[0050] By repeating the above steps, the sample can be subjected to multiple titration tests through multiple glass cups 150, thereby improving the accuracy of the measurement results.

[0051] After the measurement is completed, the double-headed motor 121 is started to move the two semicircular sealing slides 119 to the farthest positions, and the positioning circular plate 132 is first moved to the position closest to the positioning motor 134, and then the circular slide 130, the stirring straight plate 131, and the positioning circular plate 132 are synchronously moved upward, so that the circular slide 130 scrapes and cleans the inside of the mixing cylinder 103, and the residue falls into the waste barrel 102 below. When the lower end surface of the circular slide 130 and the lower end surface of the mixing cylinder 103 are on the same plane, the staff can clean the lower surface of the circular slide 130.

[0052] The present invention is not limited to the above-mentioned specific implementation modes. Various changes made by technicians in the relevant technical field based on the above-mentioned conception without creative work all fall within the protection scope of the present invention.

Claims

1. An ammonium ion determination device, comprising a bottom plate (101), characterized in that: The bottom plate (101) is provided with a mixing component and a detection component. The mixing component comprises a mixing cylinder (103) and a positioning circular plate (132). A stirring tooth ring (127) is rotatably mounted on the mixing cylinder (103). A circular slide plate (130) is movably mounted on the stirring tooth ring (127). The circular slide plate (130) and the mixing cylinder (103) are slidably matched. Three stirring straight plates (131) are fixedly mounted in a circumferential array on the positioning circular plate (132). The stirring straight plates (131) are slidably coupled to the circular slide plate (130). The circular slide plate (130) and the adjusting circular plate (132) are rotatably matched, a positioning unit is provided between the circular slide plate (130) and the adjusting circular plate (132), a fan-shaped sealing strip plate (117) is rotatably mounted on the upper end of the mixing cylinder (103), an auxiliary unit is provided on the mixing cylinder (103), and the auxiliary unit is used to adjust the position of the fan-shaped sealing strip plate (117), and the detection component includes a feeding circular plate (147), a switching circular plate (149) is rotatably mounted on the feeding circular plate (147), and a plurality of glass cups (150) are arranged in a circular array on the switching circular plate (149).

2. An ammonium ion measuring device according to claim 1, characterized in that: The mixing cylinder (103) is fixedly mounted on the bottom plate (101); when the mixing cylinder (103) and the fan-shaped sealing strip plate (117) are fully engaged, a complete cylinder is formed; a semicircular sealing slide plate (119) is symmetrically slidably mounted on the lower end surface of the mixing cylinder (103); when the mixing cylinder (103), the semicircular sealing slide plate (119), the fan-shaped sealing strip plate (117), and the circular slide plate (130) are engaged, a closed mixing chamber is formed; and a fan-shaped heating plate (110) is also symmetrically fixedly mounted on the mixing cylinder (103); the fan-shaped heating plate (110) is used to heat the interior of the mixing cylinder (103).

3. An ammonium ion measuring device according to claim 2, characterized in that: A circular slide (122) is arranged above the circular slide (130), and the circular slide (122) and the stirring gear ring (127) are slidably matched. The positioning unit comprises a positioning screw rod 1 (123) and a positioning screw rod 2 (124). The two ends of the positioning screw rod 1 (123) are rotatably connected to the circular slide (122) and the circular slide (130), respectively. The positioning screw rod 1 (123) and the stirring gear ring (127) form a spiral pair. The positioning screw rod 2 (124) and the circular slide (130) are rotatably connected. A transmission shaft (133) is rotatably mounted on the positioning circular plate (132). A torsion spring 1 is arranged between the positioning circular plate (132) and the transmission shaft (133). The positioning screw rod 2 (124) and the transmission shaft (133) form a spiral pair.

4. An ammonium ion measuring device according to claim 3, characterized in that: A driving pulley (135) and a linkage pulley (136) are rotatably mounted on the circular slide (122); a second torsion spring is arranged between the circular slide (122) and the driving pulley (135); the driving pulley (135) and the linkage pulley (136) are rotatably connected; a third torsion spring is arranged between the driving pulley (135) and the linkage pulley (136); the linkage pulley (136) and the second adjusting screw rod (124) are rotatably connected; a fourth torsion spring is arranged between the second adjusting screw rod (124) and the linkage pulley (136); the axes of the second adjusting screw rod (124), the driving pulley (135) and the linkage pulley (136) are on the same straight line; and a transmission group is arranged between the driving pulley (135) and the first adjusting screw rod (123).

5. An ammonium ion measuring device according to claim 4, characterized in that: The elastic force of torsion spring two is always greater than the elastic force of torsion spring three, the elastic force of torsion spring four is always greater than the elastic force of torsion spring three, and the elastic force of torsion spring four is always less than the elastic force of torsion spring one.

6. An ammonium ion measuring device according to claim 5, characterized in that: The auxiliary unit comprises a fan-shaped auxiliary strip (125) and a pressing strip (126); the fan-shaped auxiliary strip (125) is slidably mounted on the outside of the mixing cylinder (103); the pressing strip (126) is slidably mounted on the circular slide (122); a spring is provided between the fan-shaped auxiliary strip (125) and the mixing cylinder (103); and the pressing strip (126) is used to adjust the position of the fan-shaped auxiliary strip (125).

7. An ammonium ion measuring device according to claim 6, characterized in that: An auxiliary gear (143) is rotatably mounted on the mixing cylinder (103); a gear set is arranged between the auxiliary gear (143) and the fan-shaped sealing strip plate (117); an L-shaped side plate (140) and an auxiliary rack (144) are fixedly arranged on the side of the fan-shaped auxiliary strip plate (125); when the auxiliary rack (144) and the auxiliary gear (143) are engaged, a gear rack pair is formed; an auxiliary round block (142) is fixedly arranged on the side of the auxiliary gear (143); a limiting strip block (155) is fixedly arranged at the end of the L-shaped side plate (140); a sliding groove cooperating with the limiting strip block (155) is arranged on the auxiliary round block (142); and the limiting strip block (155) is used to limit the position of the fan-shaped sealing strip plate (117).

8. An ammonium ion measuring device according to claim 7, characterized in that: The detection assembly further comprises a fan-shaped housing 1 (104) fixedly mounted on the bottom plate (101); a fan-shaped housing 2 (107) is rotatably mounted on the bottom plate (101); the fan-shaped housing 1 (104), the fan-shaped housing 2 (107) and the feeding circular plate (147) are connected to form a closed detection chamber; a curved glass plate (108) is fixedly mounted on the fan-shaped housing 2 (107); the feeding circular plate (147) is slidably mounted on the bottom plate (101); a plurality of electromagnets (153) are fixedly mounted in a circumferential array on the switching circular plate (149); circular magnets (154) are fixedly mounted on the lower end surface of the glass cup (150); the electromagnets (153) and the circular magnets (154) are used to fix the glass cup (150).

9. An ammonium ion measuring device according to claim 8, characterized in that: The bottom plate (101) is also fixedly mounted with an indicator liquid storage cylinder (111) and a titration liquid storage box (112); a second liquid guide tube (116) is provided between the indicator liquid storage cylinder (111) and the detection chamber; a first liquid guide tube (115) is provided between the titration liquid storage box (112) and the detection chamber; an air guide tube (105) is provided between the mixing cylinder (103) and the detection chamber; an air pressure sensor (118) is also fixedly mounted on the first sector-shaped housing (104); the air pressure sensor (118) is used to monitor the air pressure inside the detection chamber; and a camera (151) is also symmetrically fixedly mounted on the inner side of the first sector-shaped housing (104); the camera (151) is used to monitor the volume and color changes of the solution inside the glass cup (150).

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